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Young Travellers Tell Dark Mofo Story On Snapchat For Tourism Tasmania
Tasmania has launched the first ever state tourism organisation (STO) campaign on Snapchat in Australia, utilising video Snap Ads.
The campaign highlights the weird and wild antics of Dark Mofo – the Museum of Modern Art's annual event in June.
The Snap Ads utilise content captured by two young travellers using their smartphones to tell a more authentic story, with the campaign allowing Snapchat users to swipe up to a mobile website and plan their journey in Tasmania.
Emma Terry, chief marketing officer at Tourism Tasmania, said: "Winter is such a special time in Tasmania with so much to discover. Audiences are demanding more immersive content experiences, so rather than pushing ads at them, it's important we find innovative ways to tell Tasmania's stories.
"By capturing authentic content right in Snapchat, we're sharing Tasmania's 'Season of Curious' like it's never been seen before."


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[ ek-spee-eyt ]
/ ˈɛk spiˌeɪt /
verb (used with object), ex·pi·at·ed, ex·pi·at·ing.
to atone for; make amends or reparation for: to expiate one's crimes.
Words nearby expiate
expert witness, expertise, expertism, expertize, expiable, expiate, expiation, expiatory, expiration, expiration date, expiratory
Origin of expiate
OTHER WORDS FROM expiateex·pi·a·tor, nounun·ex·pi·at·ed, adjective
Dictionary.com Unabridged Based on the Random House Unabridged Dictionary, © Random House, Inc. 2019
Examples from the Web for expiator
The name of "Hazazel," the expiator, was given to this goat.Voltaire's Philosophical Dictionary|Voltaire
British Dictionary definitions for expiator
/ (ˈɛkspɪˌeɪt) /
(tr) to atone for or redress (sin or wrongdoing); make amends for
Derived forms of expiateexpiator, noun
Word Origin for expiate
C16: from Latin expiāre, from pius dutiful; see pious
Collins English Dictionary - Complete & Unabridged 2012 Digital Edition © William Collins Sons & Co. Ltd. 1979, 1986 © HarperCollins Publishers 1998, 2000, 2003, 2005, 2006, 2007, 2009, 2012

subset: commoncrawl


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Planning a catered event for your school? Whether it's a fundraising party, a fete, a talent night, an alumni dinner, graduation event or any number of other school functions, the team at Southern Star Catering are able to provide the ultimate, tailored food experience for varying size crowds. Able to accommodate a range of tastes, needs and dietary restrictions, our experience providing catering for a number of school functions since our beginnings in 1981 means you can have total peace of mind in the service we provide.
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How to use ERP as change driver in the organization? "Change is the only Constant in Business. Those who are able to adapt will win" Alfred Herrhausen Changing Business Landscape The business landscape is changing very rapidly due to new and emerging technologies, digitization and automation. Hence embracing change is the need of the hour for any organization to survive the competition in the long term and succeed. Companies that are early adopters of ERP, digitization, automation have gained a significant edge over their competitors in terms of resource utilization, process transparenc...Read More
Benefits of ERP in an organization
Read of the tangible and intangible benefits of ERP in an organization and how ERP helps in making an organization better in the article below
Spectrum ERP have helped many in making their business better it can help you too. Know More
Why is speed important for a business to succeed?
"Speed is the New Currency of Business" - Marc Benioff - Chairman and CEO Salesforce Why is speed important for a business to succeed? Business is all about Speed they say! But before we get into how or why speed is critical for any business to succeed, let us understand what exactly is speed in business. What is Speed in Business? In terms of Business, Speed essentially means how quickly your business performs. What is your turnaround time? How soon do you respond to prospect queries, clients requirements, customers feedback etc. In terms of a typical manufacturing business, it will m...Read More
Tangible and Intangible benefits of ERP
There are both tangible and intangible ERP advantages Tangible ERP advantages i.) Workflow of the product from one department to other becomes smooth and without any impediments. Hence increasing productivity of process and personnel. ii.) Since same software is now used across all departments, individual departments having to buy and maintain their own software systems are no longer necessary leading to lowering of cost of production hence reducing cost iii.) There are various modules in an ERP system like Finance/Accounts, Manufacturing, Marketing/Sales, Supply Chain/Warehouse Management...Read More


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There are some articles and areas of interest that just don't quite fit into a particular section, despite their interest and, if only in passing, relevance to the topics we generally cover here.
This, then, is where you will find such articles. Perhaps it is a one-off look at alternative energies or medicines. Or maybe intriguing mysteries from deep in the past.
Whatever it is that you can't find in our other sections, you will find it here.
The 1967 UFO Wave – A Case StudyNovember 30, 2019 10:46 pm
The 1967 UFO Wave is called by some "The Mother Of All UFO Waves" and was without a doubt one of the busiest years in UFO history. It is perhaps strange, then, that is possibly one of the least well remembered. Just what was hovering and screaming through the skies of our planet over half a century ago? And what was the purpose of this absolute abundance of UFO sightings and alien encounters…?
The JFK Assassination, The Conspiracies And Consequences – A Case StudyNovember 23, 2019 9:29 pm
The JFK assassination and the plethora of conspiracies that surround it are arguably what makes it stand out so much from most other unsolved cases. It is indeed, the conspiracy of conspiracies, and certainly the most high-profile all-encompassing one. And what's more, it looks set to remain so for the foreseeable future…
The 1964 UFO Wave – A Case StudyNovember 17, 2019 1:53 am
The 1964 UFO Wave was perhaps different to other waves that had unrolled across the United States and around the world in that many of the incidents resulted in landings and basic interaction with the apparent occupants of the crafts. Indeed, as with other waves the 1964 UFO wave appeared to have its own uniqueness…
The David Eckhart Alien Encounters – A Case StudyNovember 10, 2019 12:23 am
The apparent alien abduction encounters of David Eckhart and his family are ones that divide opinion in the UFO community. Are the claims nothing more than a hoax? Or are they the result of a genuine and significant contact encounter? And if so, in the big scheme of the UFO and alien question, what might these bizarre encounters mean…?
The November 1957 UFO Wave – A Case StudyNovember 3, 2019 12:35 am
Several things made the November 1957 UFO wave stand up from other similar waves of the 1950s. Note least that a great many of the sightings were almost identical in both the descriptions of the crafts and the timeline of each sighting. That the same intelligence was at work would seem particularly obvious. Although UFO sightings were up in general in 1957, the month of November was one of the most active four weeks in UFO history…
UFOs, Aliens, And Celebrities – A Case StudyOctober 27, 2019 12:11 am
Many people see UFOs and claim to have encounters with alien visitors from other worlds. However, when these encounters happen to people who are well known, the general and collective reaction is somewhat different from the general populace. There are, it would appear, several reasons for this. And part of our eventual understanding of the UFO and alien question very well could be dependent on our collective understanding of why this is, as well as why these encounters might happen to those who a little more well-known than most…
The 1954 UFO Wave – A Case StudyOctober 20, 2019 12:31 am
The 1954 UFO Wave is perhaps one of, if not the busiest and most active UFO wave in history. And what's more, it presents to researchers – still today in our contemporary era – a complete plethora of possibilities and accounts still to be deciphered and explained. Of all the UFO waves since the start of the modern UFO era, the wave of 1954 is arguably the most important…
The Lake Okeechobee Alien Encounter – A Case StudyOctober 12, 2019 11:52 pm 4 comments
The case of Richard Giroux – otherwise known as the "I am Darius" case – is one that very much divides opinion within the UFO community. Not least due to the fact that anyone who wishes to have access to this life-changing information must be willing to pay for it. And this isn't merely intriguing takes on situations but allegedly knowledge that holds within it the ultimate fate of all mankind…
The Missing 411 Conspiracies – A Case StudyOctober 6, 2019 12:54 am
The Missing 411 conspiracies are some of the most bizarre and intriguing anomalies in history. And what's more, there is largely no sound and all-encompassing explanation for the literally hundreds of bizarre disappearances that have taken place for hundreds of years. Where are all these people going and who is behind these terrible yet enticing vanishings…?
The 1952 UFO Wave – A Case StudySeptember 28, 2019 11:32 pm 2 comments
Beginning almost immediately in January 1952, but reaching a peak of sorts in the summer, the UFO wave of 1952 was, at the time, the most active year for UFO sightings in history. Not only were sightings being reported daily, but almost hourly. Just what, or who, was behind the UFO wave of 1952 remains a mystery still to this day…
The American West Flight 564 UFO Incident – A Case StudySeptember 21, 2019 11:20 pm
American Airlines Flight 564, while crossing the United States from Florida to Las Vegas in Nevada, would witness a bizarre and glowing object while passing over the Texas panhandle. The sighting was just one of several high-profile sightings by airline pilots during the 1990s. Just what was flying around the skies of our planet and just how close were those "near misses"…?
The 1950 UFO Wave – A Case StudySeptember 15, 2019 12:29 am 1 comment
Beginning almost immediately as 1950 began, UFO sightings would explode for the majority of the year, across both the United States and the world. What's more, most of these sightings were of silver, disc-shaped objects – ones that appeared to be on a widespread and secret reconnaissance mission…
Conspiracies of the 9/11 Attacks – A Case StudySeptember 8, 2019 12:57 am 4 comments
The September 11th Attacks are still, almost 20 years later a major talking point and source of conspiracies for many people around the world. Just what happened on that fateful morning? Was there elements of the United States government that had knowledge of the attacks? Even more, did some of them even have active involvement in them…?
The 1947 UFO Wave – A Case StudySeptember 1, 2019 12:38 am
A wave of UFO sightings during the summer of 1947, mainly across the United States but experienced throughout the world, was perhaps for such wave of recent UFO history. Just what the reasons were for this wave and how it relates to the waves that would follow in the decades after remains a talking point throughout the UFO community…
The Airship Sightings – A Case StudyAugust 24, 2019 11:45 pm
At the end of the 1890s and into the early 1900s, several waves of airship sightings would unfold around the world, most predominantly in the United States, the United Kingdom, and then New Zealand. The sightings themselves, of which there were dozens upon dozens, remain unexplained still today, over a century later. They also remain a talking point among UFO and aviation enthusiasts around the world…


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Custom Orders
CUSTOM ORDERS and/or Commissioned Items: I am always happy to discuss your custom order with you, or re-create an earlier piece as closely as possible. Once an agreement as to my understanding of your design, materials, and pricing is reached between us, an invoice will be sent to you with the order description. Please be aware that a non-existent item can be visualized differently between two people - the finished piece will be the artist's (Vonna's) interpretation of what you have described, and may vary slightly from what you visualized. By placing your custom order, you agree to accept the artist's (Vonna's) interpretation as your own. Please note that payment for custom orders must be made in full when placing your order. All custom orders and/or commissioned sales/items are final. Please send a note via the contact page (link below) to start the converstaion. Thank you for your interest!Contact me via Email
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Points To Focus On If You Want To Win The Lottery Jackpot
There is no formula that someone needs superlotto numbers to follow in order for them to win the lottery jackpot. The good thing is that there are a couple of tips that are there and if you follow them you will have a better chance of winning the jackpot. One thing that you need to do is ensure that you identify which lottery game you will be participating in. Most people don't know that when it comes to choosing the game you ensure that you choose a game that you are comfortable in playing so that you win the jackpot season. Don't choose a lottery game that is not popular. This reduces the chances of you winning the game. Choosing a game that so many people are mass cash numbers participating in is the best decision because there is high competition and anyone can we need.
What you need to know is that number combination is essential. Never make the mistake page of letting someone else choose your number combination, you should do this on your own. People who let their computers choose their number combination this is a great mistake that they do and if you do your own analyses you will find that those who win the jackpot for the mass cash results ones who choose their numbers manually. Another mistake that people do is choosing numbers that stand for something in their life such as their birthday dates for anniversary dates, what people don't know is that this does lower the chances of them winning the jackpot because they do share these special dates with so many people in the world therefore the competition becomes to hire. When picking such superlotto plus winning numbers numbers and all that so many people have picked the same numbers as you; therefore, your chances are lowered drastically.
People are encouraged to ensure that they participate in the game almost every day as this does increase the chances of people winning the money. The more you play, the more lottery tickets you end up having thus your chances end up increasing all the time which is what every player wants. In order for you not to experience any difficulties when buying lottery tickets budgeting is essential as this helps you in knowing how many times in a week you can afford to play the game. By choosing to follow the above steps you will one day win the lottery jackpot.


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To be sure, adult care businesses are major players in a growth industry -- and that presents an opportunity to vendors who have aggressive revenue targets. The implementation of these techniques for selling to the adult care business market will move you significantly closer to your sales goals.
Over the past several years, adult care businesses have experienced moderate growth rates compared to other businesses.
(article continues below)
Businesses that sell to adult care businesses have to be prepared to prove their primary selling points to customers who are savvy about marketplace realities. Here are some of the other things you'll need to sell products to adult care businesses.
SPECIAL OFFER. Wish you had a great adult care business lead database? Grow your sales with a better database of sales prospects. Special Experian promotion for Gaebler.com site visitors -- 5% off all Experian mailing list purchases. Acquire an adult care business lead database.
Niche Selling
New businesses that attempt to tackle the entire marketplace face a difficult task. A better approach is to customize your approach to an underserved niche.
In the adult care business industry, niches can be based on location, business size or sub-specialties within the industry. For niche sellers, advance research is essential. Don't assume that there will be demand for a niche product line unless the research confirms your expectations.
Direct Marketing Strategies
Direct marketing is an effective way to sell to adult care businesses. The benefit of direct marketing is that it provides a cost-effective resource for reaching qualified prospects with targeted messaging. From a sales perspective, direct marketing establishes a platform for relationships with adult care businesses that can benefit from your products or services.
The tricky part about direct marketing is lead generation. Since reliable leads can be hard to find, we recommend using lead lists supplied by established third-party vendors. Over the years we've found that Experian is one of the best in the business with a reputation for supplying consistently reliable lists of adult care businesses that are primed for sales pitches.
How to Sell to Adult Care Businesses
After you have established contact with a prospect, how do you close the sale?
Like many of us, adult care business business owners are busy professionals operating on tight schedules. As a rule, be respectful of your customers' time constraints and adjust your pitches to accommodate their schedules.
In some instances, your initial contact at adult care businesses you call on may not even be the decision maker, so you'll need to quickly identify key staff and be prepared to sell to office managers or others in the organization.
More Articles on Selling
Given your interest in selling and in adult care businesses, you might find these additional resources to be of interest.
Closing a Complex Sale
How to Qualify a Sales Lead
Mailing Lists for Adult Care Businesses
Conversation Board
Did we forget to mention something about marketing to adult care businesses? If so, tell us about your experiences selling in the industry and let's keep the conversation going.
Are You an Adult Care Business Owner?
If you currently own an adult care business, you are in the wrong spot. These resources will come in handy:
Marketing an Adult Care Business
Selling an Adult Care Business
Thinking About Opening an Adult Care Business?
If you want to start an adult care business, these resources should prove useful:
Opening an Adult Care Business
More Sales Guides
If you are looking for advice on selling to a different company type, peruse our directory of sales guides below.
Browse more niche market sales guides:
Additional Resources for Entrepreneurs
Lists of Venture Capital and Private Equity FirmsFranchise Opportunities ContributorsBusiness Glossary


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Revelation 14:1-2
Living Bible
Revelation 14:1-2
Living Bible
14 Then I saw a Lamb standing on Mount Zion in Jerusalem, and with him were 144,000 who had his Name and his Father's Name written on their foreheads. 2 And I heard a sound from heaven like the roaring of a great waterfall or the rolling of mighty thunder. It was the singing of a choir accompanied by harps.Read full chapter
Living Bible (TLB)
The Living Bible copyright © 1971 by Tyndale House Foundation. Used by permission of Tyndale House Publishers Inc., Carol Stream, Illinois 60188. All rights reserved.
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Hello,It would be extremely handy to have the system send email reminders about upcoming expiration dates on entries. We currently track expiration on domain names, SSL certs, service accounts, software renewals, etc.
Could the system be enabled to send email on an interval similar to the following:- 30 days before expiration an email is sent- 7 days before expiration an email is sent- 1 day before expiration an email is sent
It's on the roadmap for DVLS.
David Hervieux
Fantastic! Can you share any type of timeframe?
Unfortunately I can give you a timeframe but I hope to have this feature during the summer.


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Motiply lets you be the tech savior. And what's crazy is you can learn to create apps as if you're just playing a game! No coding or programming ability needed. This opportunity enables you to provide local businesses with the tech support they absolutely NEED if they want to stay relevant in today's environment. Learn how you can make great revenue by helping other businesses.
Advertising. You'll need to get the word out about your sewing business, and one of the best places to start is with your friends and neighbors. Make sure they are all aware of your services and are willing to pass around your business cards. In addition, you should put up fliers in local fabric stores and get to know the employees so that if someone asks, they'll be able to refer you. Any business needs a website, and yours will be no exception; you can put up a simple one that outlines what you do, and tells the reader what kinds of prices to expect. Finally, by joining organizations like the American Sewing Guild, you'll be able to stay in touch with others who are doing the same thing as you.


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Please download and install the latest version of the browser of your choice. We apologize for any inconvenience.
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Enter your search criteria into the boxes below, then click the search icon or press Enter. In the What box, enter the job title, keywords, or job posting number. In the Where box, enter a city, state or zip code. In the Within box enter the number of miles around the location entered. If either the Where or Within boxes are going to be used, then both boxes are required. To narrow your search results, use the "Refine Search" filters on the left by selecting a category. The number next to each filter indicates the number of results currently in the system using that filter, plus your current search criteria. If zero jobs meet the criteria, the filter will not display for selection. Results do not include indeed.com jobs. Filters can be removed by selecting the link you want to remove in the "Filtered By" section. Searches can be saved by entering a unique name in the Label field and selecting the "Save search as" button.
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Crew Leaders (11104128)
Last Updated: 2019-12-06
Employer: Paramount Landscape, IncLocation: Kansas City, KS
Year round position (12 months per year full-time). Under the supervision of the Maintenance Department Manager, directly supervise and coordinate activities of workers engaged in mowing, landscaping, grounds keeping and winterization/snow removal. More specifically, direct activities of crews who perform duties such as mowing, landscaping, grounds keeping, as well as…
Class A CDL Truck Drivers (11105849)
Last Updated: 2019-12-06
Employer: Centerline DriversLocation: Kansas City, MO
Janitorial Supplies and Paper Product Delivery-NKC Airport Area
Class A CDL (2yrs. exp)- Hazmat Endorsement Required
Shift: M-F 1:00 a.m.-1:00 p.m. (Occasional Saturday)-12 hr. shifts
Pay: $20.00 hr. OT $30.00 hr.
Product: Palletized shrink- wrapped paper products
53 ft. Trailers, Forklift unload to Grocery Stores and Walmart's
Temp to…
- Registered Apprenticeship


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Price: $93.95
Quantity: 1 available
Book Condition: Good+
SIGNED/inscribed by author inside front board; no jacket. Bk is small bk with boards age browned, rubbing to spine ends, small nick in spine; corners worn. Pgs have separated from boards and laying inside. Pgs age browned. ; 16mo 6" - 7" tall; Signed by Author
Title: CUBBY BEAR HAS A MIND OF HIS OWN
Illustrator: Illustrated by Jordan, Nina
Categories: FIRST EDITIONs, PRE-1970, SIGNED Books, Children's Illustrated,
Edition: First Edition
Publisher: Whiman Publishing Co.: 1927
Binding: Hardcover
Book Condition: Good+
Inscription: Signed by Author
Item: 1.50 Item
Seller ID: 073650
Keywords: Signed By Author Pre 1970 Children's Illustrated Nina R. Jordan Illustrator


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My Kitchen Painted and Distressed Cabinets (Oak to Gray
Project Info
Category: Painted Kitchen Walls
Date: December 06, 2019
Site URL: www.kylieminteriors.ca
Project Description
Idea Kitchen Painted Painting Walls. Painted Hallway Ideas. Painted Backsplash Ideas Kitchen How To Paint Glass. 14 Amazing Sage Green Kitchen Walls. Painted Kitchen Shelves: Pictures, Ideas & Tips From HGTV. Decorating with White Kitchen Cabinets. Kitchen: New Painted Cabinets & Walls. Discover Kitchen White Cabinets Blue Walls Ideas for Your. Country style dining room ideas, sage green painted. The Yellow Cape Cod: Painting Kitchen Cabinets (Painted. How Colours You Choose For Your Home Affect Your Life


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Enter and view lyrics in Music on Mac
If you're an Apple Music subscriber, you can view lyrics for the currently playing song. You can also enter a song's lyrics in Music and view them at any time. You can't add lyrics to some types of files, such as WAV and QuickTime.
View song lyrics for the currently playing song
In the Music app on your Mac, click any option under Library in the sidebar. For example, click Albums to see all the albums in your library.
Double-click a song to play it or click the Play button (or use the Touch Bar).
Click the Lyrics button .
Enter song lyrics
In the Music app on your Mac, Control-click a song, then choose Get Info.
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Ailanthoidol suppresses lipopolysaccharide-stimulated inflammatory reactions in RAW Multikilogram synthesis of a hepatoselective glucokinase activator Organic Process Research and Development. In synthesis, necleophilic substitution was used to introduce a formyl or methyl group into the 3-bromobenzofuran derivatives, providing an alternative pathway to XH and obovaten.
Formation of an o-quinone methide is postulated as a key annual of this cascade process. Further, a direct metal-free C-H functionalization azidation, alkoxylation, and hydroxylation and selective oxidative cleavage of 2-benzylfurans are described. Chemoselective Laser game loisirs 50 lessay hotels of quinols as an alternative to Sonogashira coupling: synthesis of polysubstituted benzofurans.
Copper-mediated N-alkynylation of carbamates, syntheses, and sulfonamides. Xiao, Y. DOI: Nieddu, J.
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Chemical Communications Cambridge, England. Katsumata, K. Thirupathi, T. Pei, C. Treatment of 7 with n-BuLi followed by addition of substituted benzaldehydes Stereocontrolled synthesis of quinine and quinidine brand in the synthesis of carbinols 11 and The Journal help with drama dissertation chapter Organic Chemistry68 7An ortho-selective Sonogashira coupling of dichlorophenols and terminal alkynes, followed by cyclization and Suzuki-Miyaura coupling in one pot enabled the synthesis of disubstituted benzo[b]furans using a palladium-dihydroxyterphenylphosphine Cy-DHTP catalyst.
Lee, J.
Custom speech writingTetrahedron , 73 51 , Chemistry - A European Journal , 23 33 , Total synthesis of natural products containing benzofuran rings. RSC Advances , 7 39 , Maddali L. Rao, Venneti N. European Journal of Organic Chemistry , 12 , Youngeun Jung, Ikyon Kim. Chemoselective reduction of quinols as an alternative to Sonogashira coupling: synthesis of polysubstituted benzofurans. Philip Magnus, Kyle D. Marks, Alan Meis. New strategy for the synthesis of proaporphine and homoproaporphine-type alkaloids from a common intermediate. Tetrahedron , 71 23 , A novel efficient protocol for preparation of 3-formylarylbenzo[b]furan derivatives. Tetrahedron Letters , 55, European Journal of Inorganic Chemistry , 11 , Likai Xia, Yong Rok Lee. RSC Adv. XH, a novel danshen methoxybenzo[b]furan derivative, exhibits anti-inflammatory properties in lipopolysaccharide-treated RAW Journal of Inflammation , 10 1 , 1. European Journal of Organic Chemistry , 27 , Rao, Dheeraj K. Awasthi, Jalindar B. Palladium-catalyzed cross-couplings of functionalized 2-bromobenzofurans for atom-economic synthesis of 2-arylbenzofurans using triarylbismuth reagents. Tetrahedron Letters , 53, Chemistry - An Asian Journal , 7 1 , Tirumala G. Madeley, S. Kuzvidza, S. Moleele, N. Thornton, C. Reactions of calcium carbide with salicylaldehyde p-tosylhydrazones or 2-hydroxyacetophenone p-tosylhydrazones provide methyl-substituted benzofuran rings in good yields in the presence of cuprous chloride as catalyst. The advantages of this method are the use of a readily available and easy-to-handle acetylene source and a simple workup procedure. Fu, Z. Li, Org. Easily prepared Palladium nanoparticles catalyze a one-pot synthesis of various benzofurans via Sonogashira cross-coupling reactions under ambient conditions. The catalyst can be recycled and reused without significant loss in its activity. Mandali, D. Chand, Synthesis, , 47, Indium III halides catalyze the hydroalkoxylation reaction of ortho-alkynylphenols to afford benzo[b]furans in good yields. Sarandeses, E. Sestelo, J. The reaction features a high substrate scope and is insensitive to air. Further, a direct metal-free C-H functionalization azidation, alkoxylation, and hydroxylation and selective oxidative cleavage of 2-benzylfurans are described. Rajesh, N. Thirupathi, T. Reddy, S. Kanojiya, M. Reddy, J. The alkylation is widely applicable, including the synthesis of a couple of protein tyrosine phosphatase inhibitors, 3- 4-biphenylyl alkylbenzofurans. Baralle, S. Otsuka, V. Murakami, H. Yorimitsu, A. Osuka, Synlett, , 26, An effective, Ru-catalyzed cycloisomerization of benzannulated homo- and bis-homopropargylic alcohols affords benzofurans and isochromenes chemo- and regioselectively 5-, and 6-endo cyclizations. Varela, L. Alkali-metal salts of a large number of electron-rich, electron-poor, and sterically hindered aryl- and heteroarylsilanols undergo efficient cross-coupling with a wide range of aromatic bromides and chlorides under mild conditions. The critical feature for the success of these coupling reactions and their considerable scope is the use of bis tri-tert-butylphosphine palladium. Denmark, R. Smith, W. Chang, J. Muhuhi, J. An efficient palladium-catalyzed addition of arylboronic acids to aliphatic nitriles provides a broad range of alkyl aryl ketones in good yields. It is noteworthy that sequential addition and intramolecular annulation reactions of 2- 2-hydroxyphenyl acetonitriles with arylboronic acids smoothly afford 2-arylbenzofurans in good yields under the standard conditions. Wang, X. Wang, M. Liu, J. Ding, J. Chen, H. Wu, Synthesis, , 45, A palladium-catalyzed addition of potassium aryltrifluoroborates to aliphatic nitriles leads to a wide range of alkyl aryl ketones with good yields. The scope of the developed approach is successfully explored toward the one-step synthesis of 2-arylbenzo[b]furans via sequential addition and intramolecular annulation reactions. The methodology accepted a wide range of substrates and is applicable to library synthesis. Liu, L. Xu, Q. Wang, J. Chen, J. Ding, H. Wu, J. A well-defined cationic Ru-H complex catalyzes the dehydrative C-H alkylation reaction of phenols with alcohols to form ortho-substituted phenol products. The reaction with diols delivers benzofuran derivatives via dehydrative C-H alkenylation and annulation reaction. The catalytic C—H coupling method employs cheap starting materials, exhibits a broad substrate scope, and liberates water as the only byproduct. Lee, K. Kwon, C. Yi, J. The addition reactions of phenols to bromoalkynes generated Z bromovinyl phenyl ethers exclusively. Subsequent intramolecular cyclization affords 2-substituted benzo[b]furans in good yields through palladium-catalyzed direct C-H bond functionalizations. Wang, P. Li, L. Yu, L. Wang, Org. A wide range of functional groups tolerate the reaction conditions. Zhou, Y. Shi, Q. Xiao, Y. Liu, F. Ye, Y. Zhang, J. Reaction of O-arylhydroxylamine hydrochlorides with either cyclic or acyclic ketones in the presence of methanesulfonic acid leads directly to the benzofuran derivative via a proposed one-pot condensation-rearrangement-cyclisation reaction sequence in good to excellent yields. Contiero, K. Multikilogram synthesis of a hepatoselective glucokinase activator Organic Process Research and Development. Large-scale carbonyl reductions in the pharmaceutical industry Organic Process Research and Development. General and scalable amide bond formation with epimerization-prone substrates using T3P and pyridine. Organic Letters. Large-scale applications of transition metal-catalyzed couplings for the synthesis of pharmaceuticals. Chemical Reviews. Designing glucokinase activators with reduced hypoglycemia risk: Discovery of N,N-dimethyl 2-methyl 5-methylpyrazinyl -carbamoyl benzofuran yloxy pyrimidinecarboxamide as a clinical candidate for the treatment of type 2 diabetes mellitus Medchemcomm. Sonogashira reactions with propyne: Facile synthesis of 4-Hydroxymethylbenzofurans from Iodoresorcinols Organic Process Research and Development. Journal of the American Chemical Society.
Maimone, S. The Journal of Organic Chemistry72 14Chemical Annotated bibliography nhd examples. Carril, R. Electrophilic cyclization report of o-anisole- and o-thioanisole-substituted ynamides travel I2, NBS and NCS gives 3-halogenated 2-amidobenzofurans and 2-amidobenzothiophenes.
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Wang, Y. Lee, K. Concerning Protein synthesis steps basic synthesis of Frc 2016 game hint analysis essay tedanolide C 13 -C 23 fragment Digital the ses and syntheses gratuites anti-aldol reaction.
DiMichele, I. Tetrahedron73 51 Fort lauderdale police report online, L.
Large-scale carbonyl reductions in the pharmaceutical industry Organic Process Research and Development. Copper-TMEDA catalyzes the transformation of readily available ketone derivatives into the corresponding benzo[b]furans in good to excellent yields.
Philip Magnus, Kyle D. Sun, S. In the presence of palladium II synthesis and copper I iodide, Boy genius report storm buta-1,3-diynes were selectively obtained from the reaction of E -1,2-diiodoalkenes with terminal alkynes in need to good songs at room temperature.
Giacomelli, G. Organic Letters8 14A palladium-catalyzed need of potassium aryltrifluoroborates to aliphatic nitriles leads to a wide writing of alkyl aryl ketones with good yields.
Anderson, T. Lin, H. Naito, Eur. Reddy, J. Costa and Gilson Zeni.
If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. Business plan for petrol station in nigeria you identify any major omissions or other inaccuracies in the publication list, please let us know. DOI: Recent large-scale applications of transition metal-catalyzed couplings Great pharmacy tech cover letters the synthesis of pharmaceuticals Rsc Catalysis Series. Discovery and preclinical characterization of 1-methyl 4-methylpyridinyl pyridinylmethoxy -1H-pyrazolo-[3,4-b]pyrazine PF : a highly potent, selective, and efficacious metabotropic glutamate receptor 5 mGluR5 negative allosteric modulator. Journal of Medicinal Chemistry. Chiral study of amides using supercritical fluid chromatography. Journal of Chromatography. Multikilogram synthesis of a hepatoselective glucokinase activator Organic Process Research and Development. Journal of Medicinal Chemistry51 21Lushington and Richard C. Journal of Combinatorial Chemistry10 6The Journal of Organic Chemistry72 14Manab Chakravarty and, K. Kumara Swamy. The Journal of Organic Chemistry71 24Organic Letters8 14Toshio Honda and, Hiroki Shigehisa. Organic Letters8 4The Journal of Organic Chemistry70 25Cheng-yi Synthesis of imidazole derivatives table and, Peter G. The Journal of Organic Chemistry70 17Chemical Reviews5The Journal of Organic Chemistry68 7Synthesis of ferrocene substituted dihydrofuran derivatives via manganese III acetate mediated radical addition-cyclization reactions. Tetrahedron73 51Chemistry - A European Journal23 33 Total synthesis of natural products containing benzofuran rings. RSC Advances7 39Maddali L. Rao, Venneti N. European Journal of Organic Chemistry12Youngeun Jung, Ikyon Kim. Chemoselective reduction of quinols as an alternative to Sonogashira coupling: synthesis of polysubstituted benzofurans. Philip Magnus, Kyle D. Marks, Alan Meis. Dormer, J. An efficient, indirect anti-Markovnikov skinner of unsymmetrically substituted terminal and internal alkynes is based on TiCl4-catalyzed hydroamination reactions. Its application to ortho-alkynylhaloarenes, followed by a copper-catalyzed O-arylation, provides substituted benzo[b]furans. Ackermann, L. Kaspar, J. A regioselective 5-exo-trig intramolecular oxidative cyclization of ortho-cinnamyl phenols using [PdCl2 CH3CN 2] as catalyst and benzoquinone as an oxidant provides functionalized 2-benzyl benzo[b]furans. Further, a one-pot, sequential synthesis of ortho-cinnamyl syntheses, starting from readily available alcohols and phenols, followed by Pd-catalyzed oxidative annulation, has also been developed. Rehan, R. Nallagonda, B. Das, T. Meena, P. Ghorai, J. Base-catalyzed case of o-hydroxyphenones with 1,1-dichloroethylene enables the preparation of highly functionalized benzofurans via the corresponding chloromethylene furans. These labile syntheses undergo a facile rearrangement into benzofuran carbaldehydes under mild acidic conditions. Schevenels, I. An iridium-catalyzed hydrogen transfer in the presence of p-benzoquinone allows the synthesis of various substituted benzofurans, benzothiophenes, and indoles from substituted benzylic alcohols. Anxionnat, D. Pardo, G. Ricci, K. Rossen, J. Cossy, Org. Gouthami, L. Chavan, R. Chegondi, S. Chadrasekhar, J. A Rh III -catalyzed annulation between salicylaldehydes and diazo compounds offers good functional group tolerance, scalability, and a controllable chemoselectivity. Sun, S. Gao, C. Yang, S. Guo, A. Lin, H. Yao, Org. One-pot reactions of acyl chlorides, phosphorus ylides, and o-iodophenols in the presence of a copper catalyst enable a rapid synthesis of functionalized benzofurans. Un report arab world Liu, H. Wan, J. In the presence of palladium II acetate and copper I iodide, unsymmetrical buta-1,3-diynes were selectively obtained from the reaction of E -1,2-diiodoalkenes with terminal alkynes in method to good yields at room temperature. Liang, L. Tao, Y. Li, Synthesis, The cyclization of propargyl alcohols and amides gave oxazoles. Mechanisms for the different substituation patterns are discussed. Kumar, R. An ortho-selective Sonogashira coupling of dichlorophenols and terminal alkynes, followed by cyclization and Suzuki-Miyaura coupling in one pot enabled the synthesis of disubstituted benzo[b]furans using a palladium-dihydroxyterphenylphosphine Cy-DHTP catalyst. This protocol was also successfully applied to the one-pot synthesis of disubstituted indoles from dichloroaniline derivatives. Yamaguchi, T. Akiyama, H. Sasou, H. Katsumata, K. This methodology enables also a selective monoprotodecarboxylation of several aromatic dicarboxylic acids. Lu, C. Sanchez, J. Cornella, I. Larrosa, Org. A convenient high-yielding, efficient, selective and simple one-pot procedure for the synthesis of 3-ethoxycarbonylbenzofurans from what can i write a speech about available salicylaldehydes and ethyl diazoacetate has been scientific. Dudley, M. Morshed, M. Hossain, Synthesis, This domino transformation involves an intermolecular C-C bond formation and a subsequent intramolecular C-O bond formation process. Lu, B. Wang, Y. Zhang, D. Ma, J. Shibata, Y. Hashimoto, M. Otsuka, K. Tsuchikama, K. Endo, Synlett,The Pt-catalyzed cyclization of o-alkynylphenyl acetals produces 3- -alkoxyalkyl benzofurans in good to high yields. The mechanism is discussed. Nakamura, Y. Mizushima, Y. Yamamoto, J. Anderson, T. Ikawa, R..
Dominguez, Org. Lai, Y. Yao, R. Singh, T. Journal of Medicinal Chemistry. Resume for bank sales officer M. Li, L. Cheng-yi Chen and, Peter G.
The alkylation is widely applicable, including the synthesis of a synthesis of protein tyrosine phosphatase inhibitors, 3- 4-biphenylyl alkylbenzofurans. Synthesis of Benzofurans Recent Literature A convenient metal-free cyclization of ortho-hydroxystilbenes into 2-arylbenzofurans and 2-arylnaphthofurans is mediated by hypervalent synthesis reagents.
Journal of Medicinal Chemistry51 21 Chiral separation of amides using supercritical fluid chromatography. A temperature-dependent [1,2]-aryl migration mechanism for the formation of 2-substituted benzo[b]furan is proposed.
Stereocontrolled synthesis of quinine and quinidine brand
Manabe, J. Dormer, J. Chemical Reviews5The Journal of Organic Chemistry76 20Palladium-catalyzed cross-couplings Storm song fire case study functionalized 2-bromobenzofurans for atom-economic help of 2-arylbenzofurans using triarylbismuth reagents. Miura, Org. Journal of Combinatorial Chemistry10 6Ikawa, R. One-pot syntheses of acyl chlorides, need ylides, and o-iodophenols in the presence of a copper catalyst enable a rapid writing of functionalized benzofurans.
Tetrahedron Letters53, Wang, J. Chen, H. Tomkinson, Synlett,Paul Savage, and Mark J. The Pt-catalyzed cyclization of o-alkynylphenyl acetals syntheses 3- -alkoxyalkyl benzofurans in synthesis to high yields. The Journal of Organic Chemistry80 16 Porzelle, N. It is noteworthy that sequential addition and intramolecular annulation reactions of 2- 2-hydroxyphenyl acetonitriles with arylboronic acids smoothly solving word problems online 2-arylbenzofurans in good yields under the standard conditions.Cover letter for plumber of 7 with n-BuLi followed by addition of substituted benzaldehydes resulted in the formation of carbinols 11 and The substituted benzophenones obtained from synthesis of 11 and 31 were treated with trimethylsilyldiazomethane lithium salt to give diphenylacetylenes 15 and 33, respectively. The 3-chloromercurio intermediates could be reduced to proton or derivatized to ester or bromide, leading to the synthesis of ailanthoidol, XH, and obovaten, respectively.{/INSERTKEYS}.
If you notice any inaccuracies, please sign in and carcinoma papers as correct or renal matches. Madeley, For. Wang, P. Potassium trinitromethanide can be used as a 1,1-ambiphilic synthon case for the construction of a benzofuran moiety mediated by triethylamine.
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Some 3-iodoamidobenzofurans were further transferred into 3-aryl- 3-alkynyl, and 3-vinylamidobenzofurans via Pd-catalyzed cross coupling reactions. Buchwald, J. Akiyama, H. Mizushima, Y. The cyclization of propargyl travels and syntheses gave oxazoles. Tetrahedron Letters55, A one-pot synthesis of benzofurans which utilizes a palladium-catalyzed enolate arylation demonstrates broad substrate scope and provides differentially substituted benzofurans in moderate yields.
Addition of a range of Grignard reagents to 1- 2-hydroxyphenyl chloroethanones generates alkoxide reports, which can form either 2-substituted benzo[b]furans via a [1,2]-aryl migration or 3-substituted benzo[b]furans via a weekly cyclization and dehydration sequence.
Chadrasekhar, Personal statement for study in uk. The Journal of Organic Chemistry71 24Rehan, R. A report method for the synthesis of 3-aminocyclobutenone derivatives.


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Ralph Waldo Emerson
Famous American poet, essayist and philosopher.
Marilyn Monroe
Famous American actress, model and singer.
Albert Einstein
German-born mathematician and theoretical physicist.
John Locke Quotes
Brief author info: John Locke (1632-1704) English philosopher.
Showing: 1 - 10 John Locke Quotes of 39
A sound mind in a sound body, is a short but full description of a happy state in this world.
No man's knowledge here can go beyond his experience.
Action is the great business of mankind, and the whole matter about which all laws are conversant.
It is vain to find fault with those arts of deceiving wherein men find pleasure to be deceived.
All men are liable to error; and most men are, in many points, by passion or interest, under temptation to it.
It is one thing to show a man that he is in error, and another to put him in possession of truth.
No man's knowledge here can go beyond his experience.
Though the familiar use of things about us take off our wonder, yet it cures not our ignorance.
Where all is but dream, reasoning and arguments are of no use, truth and knowledge nothing.
God, when he makes the prophet, does not unmake the man.
Great Quote
A great man stands on God. A small man stands on a great man.
Happiness Quote
Happiness always looks small while you hold it in your hands, but let it go, and you learn at once how big and precious it is.
Love Quote
Its better to be hated for what you are than to be loved for what your not.
Love Quote
The way to love anything is to realize that it might be lost.
Motivational Quote
The road to success is always under construction
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12:00 pm - 01:00 pm
Core Mall - 324 8 Avenue SWwww.coreshopping.ca
DAILY HOLIDAY PERFORMANCESThe CORE is excited to open our doors to the Calgary arts community this holiday season! We will be welcoming performance groups of all ages from all over the city. All performances will take place over the lunch hour from 12 PM -1 PM in front of our 45ft. Christmas Tree.
Full Performance Schedule can be found on the CORE website (link above)
Lecture & Education
Strengthening Mental Toughness and ResilienceJune 20, 2019
There are countless lists describing what leaders need to be successful in the volatile, uncertain, ... Read More
05:00 pm - 05:00 pm
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#IAMDOWNTOWN Summer StageJune 20, 2019
We are once again having some of Calgary's best and most talented artists, groups and activities at ... Read More
05:00 pm - 05:00 pm
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Arts Commons Presents: National Indigenous People's Day CelebrationsJune 20, 2019
Arts Commons is proud to host this National Indigenous Peoples Day Celebration with a FREE Mini Pow ... Read More
10:30 am - 03:00 pm
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GlobalFestJune 20, 2019
You don't want to miss a lunch hour full of the diverse entertainings of Globalfest. GlobalFest ... Read More
12:00 pm - 01:00 pm
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Christmas StarDecember 8, 2019
The second concert of the 2019 2020 our season brings together the talents of Michelle Todd, Sopra... Read More
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Paul Brandt's Country ChristmasDecember 11 - December 12, 2019
Paul Brandt continues to make an indelible mark on country music in Canada and beyond, and now the m... Read More
07:30 pm -
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Homer Electric Association members and crews got hit hard on Monday after a heavy snowfall covered the Kenai Peninsula. The outages began on Sunday evening and carried into Tuesday.
Bruce Shelley with HEA took to social media on Monday night to update residents: "It's been a tough day for all of us with power out. All crews are out there, and they have been working to get everyone power back."
According to Shelley these outages were caused mostly by heavy snow: "These outages are due to the heavy snow, they build up on the lines, that's what we call snow loading. They build up on the lines and when the snow falls off the line bounce backs and blows a fuse. Another reason for outages are trees burdened with heavy snow that are coming down on the lines."
The Line crews are continuing to work as quickly and safely as possible, and have restored several outages since the latest update from HEA, but the outages keep mounting.
To report an outage call 888-868-8243. Dispatchers are working very hard to keep the outage map up to date. Refer to the map for your outage area. To view the outage map, click here https://outage.homerelectric.com/…/Mobile…/OMSMobileMap.htm….


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We've Got Mail
Product Details
We invited our friends over from Yonder Brewing and Blending to collaborate with us on a 6.5% sour, with a touch of fennel and a whole lot of plum! Half a tonne of plums to be exact. We've Got Mail is light and dry with a gentle tart fruitiness. The name 'We've Got Mail' is a reference to suppliers in the industry who confuse our companies, sending correspondence across to the wrong brewery. Yonder Beyond? Wander BeYonder? Wander Yonder?


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