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Ambae, Vanuatu
Ambae Island showing main settlements, districts names, roads and volcano, Manaro. [00-323]
Aneityum, Vanuatu
Detailed map of 1853 Aneityum showing dominion and district boundaries, shore settlements and location of high chief settlements. [04-018]
Australia's neighbours
Country: Australia , Fiji , New Caledonia , New Zealand , Niue , Samoa
Cambodia Laos Vietnam
2011 Cambodia, Laos and Vietnam, colour relief, major rivers and lakes. [11-123a]
Cambodia, Laos and Vietnam
Colour elevation map of Cambodia, Laos, Vietnam and eastern Thailand showing international borders, main rivers and major cities including the country capitals. [00-137]
Choiseul and Shortland Islands
Colour elevation map of the islands in the north-west corner of the Solomons - Choiseul and Shortland Islands. [00-218]
Choiseul Island
The Island of Choiseul showing elevation, main islands and settlements.[00-344]
East Asia to west Pacific
Regional map that extends from India north to Korea and east to Vanuatu. [14-159]
Region: Asia, Asia - Southeast
Efate, Vanuatu
Efate showing its location in Vanuatu. Enlarged map of the island shows settlements, main road, rivers and lakes. [00-324]
Efate, Vanuatu
Colour relief map of Efate showing main roads, rivers and airfields. [10-018f]
Espitiru Santo, Vanuatu
Espiritu Santo showing main towns and elevation using graduated contours. [03-115]
Relief map of Guadalcanal showing main settlements, airport and road from Lambi to Aola.
Himalayan rivers
Rivers of the Western Himalayan Mountains originating in Tajikistan, Northeast Afghanistan, Northern Pakistan and India.
Region: Asia
Country: Afghanistan , India , Pakistan , Tajikistan
Ho Chi Minh Trail, Laos
Logistical system of the Ho Chi Minh trail, 1967.
Languages of Pentecost Is
Austronesian languages associated with Pentecost Island, Vanuatu.
Laos - District borders
District borders of Laos highlighting six central area districts.
Laos - Yunnan, China
Colour elevation map of Laos extending north ti include the Chinese province of Yunnan.
Laos base
Laos with province borders and names and provincial capitals - 2012. PNG versions of the base map can be downloaded with or without elevation shading.
Makira Island
The island of Makira (formerly San Cristóbal) showing elevation, districts and main islands.
Malaita languages
Languages of the island of Malaita, Solomon Islands showing language names, borders nd select settlements.
Northwest Malakula showing villages and rivers around Tenmiel and Tenmaru, with location map of Vanuatu.
Malo Island, Vanuatu
Malo Island, off the southern coast of Espiritu Santo, showing location of settlements, plantations, contours, rivers and roads.
Malo, Vanuatu
Malo in colour showing main settlements, plantations, elevation using graduated contours and ferry routes to Espiritu Santo.
A subregion of Oceania extending from the western end of the Pacific Ocean to the Arafura Sea, and eastward to Fiji
Country: Fiji , Kiribati , New Caledonia , Solomon Islands , Vanuatu
Melanesian, a subregion of Oceania, showing the countries and main islands and their relation to Australia and Indonesia
Country: Fiji , New Caledonia , Solomon Islands , Vanuatu
Myanmar (Burma) to Australia
Southeast Asian countries.
Nakhon Phanom area, Laos
Hydroelectric system in the Nakhon Phanom area, Laos.
New Caledonia and Vanuatu
Colour elevation map of New Caledonia and Vanuatu showing island names and capital cities.
Country: New Caledonia , Vanuatu
New Georgia Islands
New Georgia Islands with inset showing position within the Solomon Islands.
NPA's in Laos
National Protected Areas in Laos surrounding the Nam Theum river.
Oceania subregion - Melanesia
The Pacific islands of Melanesia, a subregion of Oceania, from Papua New Guinea in the west to Fiji in the east.
Country: Fiji , New Caledonia , Papua New Guinea , Solomon Islands , Vanuatu
Pentecost Island, Vanuatu
Pentecost Island, Vanuatu showing administration names and borders and location of villages.
Provinces of Vanuatu
Vanuatu showing province boundaries, names and capital cities.
Rendova Island
Rendova Island (New Georgia Island Group) showing relief and the names of main rivers, islands and high points.
Santa Cruz Islands
The Santa Cruz Islands group showing elevation, main islands and settlements.
Santa Isabel Island
Santa Isabel Island (also known as Isabel and Ysabel) showing elevation, main islands and settlements.
SE Asia to west Pacific
Region: Asia, Asia - Southeast, Pacific
Shortland Islands
Shortland Islands showing active plantations in 1941.
Solomon Is-PNG border
Points of tension along the Papua New Guinea - Solomon Islands border - 1997.
Solomon Island Provinces and capitals
Provinces of the Solomon Islands showing provincial capitals.
Solomon Islands
Solomon Islands showing the position of the eastern group in relation the the main islands.
Solomon Islands
Solomon Islands and its nearest neighbours.
Solomon Islands
Solomon Islands with colour elevation highlighting Guadalcanal and The Weather Coast.
Solomon Islands - Provinces
A colour relief map of the main Solomon Islands showing province borders and including a location inset.
Solomon Islands base
Solomon Islands showing island names with Santa Cruz islands inset - 2012. PNG versions of the base map can be downloaded with or without elevation shading.
Solomon Islands with location map
The provincial names and borders of the nine Solomon Islands provinces with inset showing its proximity to nearby countries.
Southeast Asia
Countries and capital cities of Southeast Asia from Myanmar to Indonesia.
Southeast Asia
Southeastern Asia from the east coast of India to the eastern extent of Papua New Guinea. Map shows all countres and capital cities along with major river systems on a colour elevation background.
Country: Bangladesh , Bhutan , Brunei Darussalam , Cambodia , China , India
The island of Tikopia, Solomon Islands showing both topographic features and Polynesian cultural features on separate maps.
Upper Mekong
The combined border area of Myanmar, Thailand and Laos on the Upper Mekong River showing border towns and the central location of the Golden Triangle in the Southeast Asian border mountains.
The major islands of Vanuatu showing location of capital Port Villa and Loganville.
Colour map of Vanuatu with two insets of southern Espiritu Santo and Malo and northeast Malakula.
Vanuatu base
Vanuatu showing island names and administrative capitals - 2012. PNG versions of the base map can be downloaded with or without elevation shading.
Vanuatu in the Pacific
Vanuatu and its location in the Pacific Ocean.
Vanuatu trade routes
Traditional trade routes for materials, cultural items and pigs within the northern islands of Vanuatu.
Vella Lavella
Solomon Islands highlighting the location of Belle Lavella and the area on the island where the bilua language is spoken.
Western District, Solomon Is.
The islands of the Western District of the Solomon Islands.


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The Ontario Labour Relations Board has held that an employee who was fired two months after injuring her knee at work, was not dismissed for asserting her safety rights under the Ontario Occupational Health and Safety Act.
The employee claimed, in her application to the Ontario Labour Relations Board, that she injured her knee at work in April 2011 and was told by a manager to "walk it off and take it easy over the next few weeks". She did not lose any work time.
She asserted in her application that in May 2011 her knee injury worsened and she sought medical assistance, and that during June 2011 her employer starting putting together the paperwork to report the injury to the Workplace Safety and Insurance Board.
The Ontario Labour Relations Board stated:
"There is nothing pleaded by the applicant to even remotely suggest that her loss of employment was the direct result of acting in compliance with, or seeking the enforcement of, the Act or its regulations, or of giving evidence in a proceeding in respect of the enforcement of the Act or its regulations. As noted by the responding party in its response, the applicant's only complaint relates to the Workplace Safety and Insurance Act, 1997, S.O. 1997, c. 16, legislation that is separate and distinct from the Act."
The OLRB thus dismissed the employee's application without a full hearing.
This decision shows that the fact that an employee had a recent injury...

subset: commoncrawl


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Nurse, Peds/Special Care Nursery, Part Time, Nights, Sign on Bonus Eligible
Company: BJC HealthCare
Location: O Fallon
Posted on: November 23, 2019
Job Description:
Keywords: BJC HealthCare, O'Fallon , Nurse, Peds/Special Care Nursery, Part Time, Nights, Sign on Bonus Eligible, Other , O Fallon, Missouri
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Here at MCM, we recognize and value success: for our consumers, for our communities, for you as an individual, and for us as a team. We support your career aspirations and provide the benefits you need to live the fulfilling life you want. You make a difference for us through your attitude and achievements and we will always strive to make a difference for you. Be part of MCM's amazing journey, where your success is valued!
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At MCM, the work we do every day helps pave the way to brighter futures, and our Account Managers are the reason for our phenomenal success. This exciting position will give you the opportunity to earn substantial financial incentives while assisting consumers down the path to financial recovery. We'll provide you the support and training you will need to learn our business and be successful! The skills you'll learn, will not only benefit your career, but all areas of your life.
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Check out the video below to find out why Russell loves working for MCM, an Encore Capital Group Company!
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"Applicants must be currently authorized to work in the United States on a full-time basis."
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Established in 1953, Midland Credit Management, Inc. (MCM), a wholly-owned subsidiary of Encore Capital Group, Inc., is a specialty finance company providing debt recovery solutions for consumers across a broad range of assets. We are the market leader in portfolio purchasing and recovery in the United States, and we lead the industry with consumer-centric practices that drive results. We have operations in India, Costa Rica, and 35 US Sites.
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text: CLUB NEWS Ash ends eventful week on high Author titans.com.au Timestamp Sun 20 Mar 2016, 09:44 AM Share on social media Share via Facebook Share via Twiiter Share via Whats-app Share via Reddit Share via Email Aquis Titans halfback Ash Taylor completed a week he'll never forget by scoring 14 points in the victory over Wests Tigers. He spoke to Luke O'Dwyer after the match. Related / Club News 02:01 Club News Burleigh and Tweed to Remain as Titans Feeder Clubs 6 days ago Club News Burleigh Bears, Tweed Seagulls Renew Affiliation With Gold Coast Titans 6 days ago Club News Don goes fishing for talent in Northern Rivers 1 week ago Club News Titans' Back-To-Basics Approach Gets The Thumbs-up From Don 1 week ago Club News Boyd credits Meninga and Roberts for firing his Titans dreams 1 week ago


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Check out this gently-used 2018 Subaru Forester we recently got in. This Subaru Forester offers all the comforts of a well-optioned sedan with the utility you demand from an SUV. The Subaru Forester Limited is economically and environmentally smart. Subaru clearly delivers on its promise to provide a fuel-efficient vehicle that has the great qualities you need in a vehicle. This Subaru Forester Limited is equipped with AWD for improved handling. Whether you're faced with inclement weather or just out enjoying the twisting back road, you'll have the grip of AWD on your side. There is no reason why you shouldn't buy this Subaru Forester Limited. It is incomparable for the price and quality.
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One of the more talked about integrations has been Taco Bell's announcement that it is working on a Slackbot (appropriately named Tacobot) which will not only take your Gordita Supreme order but will do it with the same "witty personality you'd expect from Taco Bell." Consumer demand for such a service remains to be seen, but it hints at the potential for brands to leverage Slack's platform and growing audience.
This means our questions must fit with the programming they have been given. Using our weather bot as an example once more, the question 'Will it rain tomorrow' could be answered easily. However if the programming is not there, the question 'Will I need a brolly tomorrow' may cause the chatbot to respond with a 'I am sorry, I didn't understand the question' type response.
There is a general worry that the bot can't understand the intent of the customer. The bots are first trained with the actual data. Most companies that already have a chatbot must be having logs of conversations. Developers use that logs to analyze what customers are trying to ask and what does that mean. With a combination of Machine Learning models and tools built, developers match questions that customer asks and answers with the best suitable answer. For example: If a customer is asking "Where is my payment receipt?" and "I have not received a payment receipt", mean the same thing. Developers strength is in training the models so that the chatbot is able to connect both of those questions to correct intent and as an output produces the correct answer. If there is no extensive data available, different APIs data can be used to train the chatbot.
[In] artificial intelligence ... machines are made to behave in wondrous ways, often sufficient to dazzle even the most experienced observer. But once a particular program is unmasked, once its inner workings are explained ... its magic crumbles away; it stands revealed as a mere collection of procedures ... The observer says to himself "I could have written that". With that thought he moves the program in question from the shelf marked "intelligent", to that reserved for curios ... The object of this paper is to cause just such a re-evaluation of the program about to be "explained". Few programs ever needed it more.
Love them or hate them, chatbots are here to stay. Chatbots have become extraordinarily popular in recent years largely due to dramatic advancements in machine learning and other underlying technologies such as natural language processing. Today's chatbots are smarter, more responsive, and more useful – and we're likely to see even more of them in the coming years.
One pertinent field of AI research is natural language processing. Usually, weak AI fields employ specialized software or programming languages created specifically for the narrow function required. For example, A.L.I.C.E. uses a markup language called AIML, which is specific to its function as a conversational agent, and has since been adopted by various other developers of, so called, Alicebots. Nevertheless, A.L.I.C.E. is still purely based on pattern matching techniques without any reasoning capabilities, the same technique ELIZA was using back in 1966. This is not strong AI, which would require sapience and logical reasoning abilities.


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A company named in CBI case in coal block allocation scam had allegedly projected a net worth of Rs 1 lakh crore by showing short term MoUs with two international power majors at the time of applying for blocks.
CBI sources claimed that its probe has shown that Navbharat Power Private Limited had allegedly shown inflated financial strength to bag two coal blocks, Rampia and dip side of Rampia in Odisha by entering Memorandum of Understanding(MoU) for short periods with two different foreign companies at different stages.
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Why does my dog like to lay on the heater?
She does this all the time. Whenever I go look for her in the house, I always find her laying on the heater vent and she also loves to sleep on it. Does she like the warm feeling of the heater? We live in Alaska if you guys are wondering where I live.
12 Answers
- daniel gLv 72 weeks ago
Sure, it is the warm.
- Anonymous2 weeks ago
She probably does, Pets love heat! My dog will sleep anywhere by the heater or fireplace and we live in the South.
- VerulamLv 72 weeks ago
When we had forced air central heating, with a vent half-way up the stairs, our then only hound used to lie across that stair tread because he enjoyed the warmth being pumped out. However, we'd not letl him actually lie across a vent in the floor like that - any more than to lie for hours in the full sun!! That's not a great idea. Why don't you put a fixture that vents the warm air across the room so he can't lie there? Not to cover the vent, but to redirect the warmth.
- pattyLv 52 weeks ago
Get her a nice woolen coat. A friends cat sit on top of the heater. its obviously cold where u are.
- What do you think of the answers? You can sign in to give your opinion on the answer.
- 2 weeks ago
Dogs, just like humans, are warm-blooded creatures, and as such, it is more energy-efficient for both to make our environment warm in the winter.
- Anonymous2 weeks ago
I don't think it's about the heat.
I think it's more about her liking the smell of burning dog hair.
- VeschengroLv 62 weeks ago
Because you are stupid enough to allow it to, very obviously
- Gian Louis2 weeks agoReport
Did someone hurt you?🤣
- Bone AloneLv 72 weeks ago
She's cold. The fur only provides so much warmth. If she's sleeping, her body temperature cools a little. It's the same reason she sleeps next to you. You body provides some heat.
It's the same with my cat. He likes to sleep around the window when there's sunshine. When there's no sunshine, he'll sleep on top of the fridge or on a rug in the bathroom or on my bed.
- SusieLv 62 weeks ago
Get her a warm dog bed or fold up a blanket for her to sleep on. Even in Florida some dogs like that at night, even to be covered.
- 2 weeks ago
Because it's warm.


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A while ago I got introduced to Pacsafe and I thought – how handy this would be while biking around. So here is my way, how to use their "Portable Safe". When I'm going biking to the city to get some stuff done or just a quick ride into the woods – I always carry some stuff with me. Not necessary super important stuff, but still – Continue reading "Biking around with PacSafe"
Category: ACTION
Lovely Things – Always into the woods
Just some favorite things right now. The perfect autumn boots – as you can see, I wear them a lot and the most beautiful backpack I own right now. I love this material… Oh and the little backpacker's cologne is my favorite scent… the smell of the trees! Continue reading "Lovely Things – Always into the woods"
Biking around with a Toddler
We live in a small town, where you can reach everything by bike. Supermarkets, the old town, small lakes, the river or the next small town. I try to do most of it by bike. I'm definitely not perfect – when it's raining a lot or the opposite, when it's way to hot (for longer distances) I maybe take the car. We have a bike trailer, which I absolutely love! We bought one for two children, but for now I use the empty second child seat for all kinds of stuff. 😉 It's amazing what you can transport with it! Anyway… but Continue reading "Biking around with a Toddler"
Bouldering in Western Australia
Because it's cold outside, I thought I'll warm you up with a view images from an amazing place in Down Under – nearly a year ago! Tiny Clara, oh gosh! So this is one of the favorite places we went bouldering in Western Australia. It's called "Contos" and nobody is there. We didn't bring a crash pad, so couldn't try any harder problems, but I think the husband had fun. I was mostly baby sitting and jumping around. Which is fun there, too. But if you're into bouldering, this is the spot. There's also a really great campsite nearby… oh and fishing is nice there as well, no other boulderer around, just a couple of fishermen. Continue reading "Bouldering in Western Australia"
Bouldering with prAna
A short walk from our home, is an old ruin, where you can boulder around a little bit. You can even climb up to the top – with a rope of course, but it's also fun to just play around on the first few meters. A couple of weeks ago (last year, haha) we walked to a Christmas market near by and on the way was "our" boulder ruin. So we made a quick stop and I felt extra awesome in my new climbing outfit. 😉 Hope you enjoy the outfit/photos! Last week a guy in the climbing gym even asked me where this top is from, he wanted to buy it for his girlfriend for Christmas! Lucky girl! Continue reading "Bouldering with prAna"


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This North Latin America Weatherization Services Market market study offers a comprehensive analysis of the business models, key strategies, and respective market shares of some of the most prominent players in this landscape. Along with an in-depth commentary on the key influencing factors, market statistics in terms of revenues, segment-wise data, region-wise data, and country-wise data are offered in the full study. This study is one of the most comprehensive documentation that captures all the facets of the evolving North Latin America Weatherization Services Market market.
Weatherization is a process of sealing the cracks and insulating the walls and windows to stop air and heat from getting through. It is a service provided at low cost to the tenant or owner of a home. Weatherization services consist of cost-effective energy efficiency measures for residential and multifamily housing with low-income residents. It reduces the building energy use by 36%. The benefits of weatherization includes reducing the energy bills of recipients for a long period of time. Some measures, such as insulating walls or roofs, can provide savings for a house for 30 years or more. There was a significant increase of around 1 million weatherized home from year 2012 to 2013. Americans spend 30% of their annual income in energy bills and with the help of weatherization those bills can be reduced up to 50%. Other benefits includes reduced environmental impact, improved indoor air quality, lowers heating and cooling costs, makes your home more energy efficient, makes your home safer and healthier etc. More efficient heating and cooling equipment can provide cost saving for 10-15 years.
Weatherization services can be segmented by type and by applications. On the basis of type, it can be segmented as, Attic Insulation, Sidewall Insulation, Perimeter/Rim Joist/Floor Treatment, and Health & Safety Inspections. On the basis of application it can be segmented as, Window and Door frame, Air conditioner, Heating and Cooling Duct, Ventilator and Siding, Gutter and Downspouts. Some of the major trends in weatherization services are, focus on energy efficiency and renewable energy, education and training related to these activities.
Basic weatherization work includes Sealing drafts and air leaks, improving the efficiency of your heating system, Hot water heater tank blankets, Adding insulation installing other energy-saving devices etc. Weatherization today covers a complete series of energy efficiency measures that are based on detailed analyses of individual homes. These analyses take the whole-house approach, which maximizes energy and saves dollar. Because of this vital approach and analyses, weatherization has become a leader in advancing home energy science and helps to boost a new industry, providing home energy efficiency services to the wider public. Other factors which promotes the growth of weatherization are, reduced use of energy and increased saving, reduced pollution due to low energy consumption, increased comfort level because of safety measures, government energy grants, and tax rebates, etc.
Market Growth Analysis
Disclaimer: This data is only a representation. Actual data may vary and will be available in the report.
These companies exercise various strategies to be competitive in the market such as competitive prices, business expansion through partnership for example Home Insulation Company is in partnership with RESNET (Residential Energy Service Network), use of latest technologies to reduce air infiltration and to apply insulation, , use of quality products in order to offer quality services, for instance, Green Home uses 2-Part Closed Cell Spray Foam which has the highest R-value ( measure of thermal resistance used in the building and construction industry) on the market which is used for roof tiles, wall cavities etc., recruitment of highly trained employees and lot more other strategies. These strategies help these companies to grow in this competitive market and mark their significance presence in weatherization service market.
The research report presents a comprehensive assessment of market and contains thoughtful insights, facts, historical data, and statistically supported and industry validated market data and projections with suitable set of assumptions and methodology. Research report provides analysis and information by categories such as market types and application.
The report is a compilation of first-hand information, qualitative and quantitative assessment by industry analysts, inputs from industry experts and industry participants across value chain. The report provides in-depth analysis of parent market trends, macro-economic indicators and governing factors along with market attractiveness as per segments. The report also maps qualitative impact of various market factors on market segments and various geographies.
Unique Requirements? Customize this Report
- Customize by Region, Country, Application, Product, & other segments
- Integrate our Insights with your Existing Data
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- Gain Insights on Key North Latin America Weatherization Services Market Impacting Forces
- Know the Winning Strategies of Market Leaders
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Report covers exhaustive analysis on
- Market Segments
- Market Dynamics
- Market Size
- Supply & Demand
- Current Trends/Issues/Challenges
- Competition & Companies involved
- Technology
- Value Chain
Regional analysis includes
- North America
- Latin America
Report Highlights:
- Detailed overview of parent market
- Changing market dynamics of the industry
- In-depth market segmentation
- Historical, current and projected market size in terms of volume and value
- Recent industry trends and developments
- Competitive landscape
- Strategies of key players and product offerings
- Potential and niche segments/regions exhibiting promising growth
- A neutral perspective towards market performance
- Must-have information for market players to sustain and enhance their market footprint
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Relate a chemical's properties to its accumulation within organisms, such as PCBs in the fatty tissues of fish.
Organisms are linked to one another in an ecosystem by the flow of energy and the cycling of materials. Humans are an integral part of the natural system and human activities can alter the stability of ecosystems.
Matter needed to sustain life is continually recycled among and between organisms and the environment. Energy from the Sun flows irreversibly through ecosystems and is conserved as organisms use and transform it.


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I keep wanting to really deep dive on my points, but there is always something in the way. I'll get back to expound eventually, but I don't think...
There is no shortage of great Jacky play. He's in literally every tourney, so I'm posting this to highlight a pretty sick wall combo at 1:29:28....
Time to put down the crack pipe if Lau is gonna be a tier below Jeffry. Someone has lost their mind off the hype of just now discovering the...
Nice extension of 6K combo near wall at 4:47:29
Nice wall combo at 2:01:07
I've been running Jeffry for so long and so often he's now my main. With that being said Vanessa is still a far easier character to win with
Several hours of Jeffry in the wild
@Myke just had to log on to say you're still the man!
Just a reminder for folks out there that Taka is trash and will give you cancer. That is all.
I'll be on the east coast during this time. Not sure if I can make the trip up to NYC, but I'm considering it.
@Jacko get on the PC bruh asap. Thank you for once again putting this fraud in his place.
you're the man now dawg
any video record of this Homestay triple demotion??
You'll never learn with that attitude that's for sure.
TIM STFU you're trash and no one likes you.
2_3P is definitely a top 5 move if you can get the input for it consistently. It's the best opener for threat stance because it staggers on hit,...
Sees Shang on status updates. What universe is this???
Separate names with a comma.


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West Bengal: Man arrested for making anti-Mamata remark on Facebook
Bapi Pal was arrested on Tuesday night after a Trinamool Congress supporter filed a complaint at Harishchandrapur police station, police said.
Bapi Pal was arrested on Tuesday night after a Trinamool Congress supporter filed a complaint at Harishchandrapur police station, police said.
Malda: A man was arrested in Malda district of West Bengal on the charge of making a derogatory remark against Chief Minister Mamata Banerjee on Facebook.
The police said that Bapi Pal (25) of Janakinagar village, who worked as a Civic Police Volunteer, but now unemployed, was arrested on Tuesday night after a Trinamool Congress supporter filed a complaint at Harishchandrapur police station.
Pal was produced before a local court today which remanded him in 14-day judicial custody. It was not immediately known as to what was the content of the post. The Civic Police Volunteer Force was introduced by the Kolkata civic body in 2008 to assist Kolkata Police in traffic management.
A Jadavpur University professor was arrested in April 2012, for posting a cartoon on Facebook featuring Banerjee with the then Railway Minister Mukul Roy and his predecessor Dinesh Trivedi.
The 2012 cartoon had showed the chief minister and the railway minister exchanging dialogues from popular Bengali film 'Sonar Kella', a detective thriller by Satyajit Ray, which alluded to the replacement of Trivedi by Roy as Railway Minister.
The arrests had triggered angry reaction from opposition CPI-M which dubbed the police action as "atrocious" and an assault on the fundamental right of freedom of expression and a grim reminder of oppression during Emergency.
Get the best of News18 delivered to your inbox - subscribe to News18 Daybreak. Follow News18.com on Twitter, Instagram, Facebook, Telegram, TikTok and on YouTube, and stay in the know with what's happening in the world around you – in real time.
Monday 25 November , 2019 How Ajit Pawar May Have Changed Maharashtra's Political Dynamics | Crux+
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Catalysis Communicationsj o u r n a l h o m e p a g e : w w w. e l s ev i e r. c o m / l o c a t e / c a t c o m
Short Communication
a r t i c l e
i n f o
a b s t r a c tA highly loaded and dispersed Ni/SiO2B catalyst was prepared by the precipitation method with an n-butanol drying process. Drying with n-butanol signicantly increased the surface area of the catalyst as well as the reducibility and dispersion of supported nickel, leading to the high active nickel surface area (66 m2/gcatalyst). In addition, the surface acidity of the Ni/SiO2-B catalyst was signicantly enhanced, as probed by the microcalorimetric adsorption of ammonia. Accordingly, this catalyst adsorbed great amount of toluene with the high initial heat of about 140 kJ/mol, and exhibited high activity for the hydrogenation of toluene to methyl cyclohexane. 2010 Elsevier B.V. All rights reserved.
Article history: Received 11 June 2010 Received in revised form 21 September 2010 Accepted 4 October 2010 Available online 21 November 2010 Keywords: Ni/SiO2 catalyst Drying with n-butanol Active metal surface area Microcalorimetric adsorption Surface acidity Hydrogenation of toluene
1. Introduction Ni/SiO2 catalysts are often used for industrial hydrogenation processes, such as hydrogenation of olens and aromatics, methane reforming, watergas shift reaction, and so on due to their high activity and economics. It is well known that the hydrogenation activity depends on the number of surface active nickel atoms, which in turn depend on the loading, reducibility and dispersion. Higher loading, reducibility and dispersion lead to the more surface active nickel atoms, but these parameters are usually contradictory and special preparation techniques are required to maximize these parameters simultaneously. Different preparation methods have been employed, including precipitation [1], incipient wetness impregnation [2,3], ion-exchange [4], homogeneous depositionprecipitation [2,3,510] and solgel techniques [11,12]. It is usually difcult to prepare highly loaded and dispersed nickel catalysts with a simple method. Precipitation is a frequently used method for the preparation of supported metal catalysts. However, the precipitated small particles may agglomerate during the drying process owing to the removal of water of high surface tension. Such coagulations may be avoided in the supercritical uid drying process, by removing water at low surface tension conditions. However, the supercritical uid process is expensive and hazardous [13]. Alternatively, a solvent (usually n-butanol) replacing technique of drying may be used to effectively reduce the possibility of formation of chemical bonds between particles and thus to prevent the formation of hard agglomerates [1416].
In our previous work [1719], high surface area VOx, VAgO and Ni/MgO catalysts were prepared by using n-butanol to replace water in the samples during the drying process so that water may be removed from the solution of n-butanol, rather than removed directly from the samples. In this way, the catalysts with high surface areas were prepared. In this work, we extended the technique to the preparation of 60%Ni/ SiO2 catalysts. 2. Experimental 2.1. Preparation of catalysts Ni/SiO2 with 60% Ni by weight was prepared by the precipitation method. Specically, an aqueous solution containing the required amount of nickel nitrates was precipitated at 353 K with a solution containing sodium silicate and a slightly excess of sodium carbonate. The nal pH was maintained at about 9 and a green precipitate was formed. It was then ltered and washed thoroughly with de-ionized water. The lter cake was evenly divided into two parts. One was directly dried at 353 K for 12 h and then at 393 K for another 12 h. This sample was denoted as Ni/SiO2. Another part was added into 200 g nbutanol and heated at 353 K for 12 h during which water and n-butanol were evaporated and could be collected. The collected mixture contained about 195 g n-butanol and 60 g H2O. The sample was then further dried at 393 K for 12 h and denoted as Ni/SiO2B. 2.2. Characterization of catalysts
Corresponding author. Tel./fax: +86 25 83594305. E-mail address: firstname.lastname@example.com (J. Shen). 1566-7367/$ see front matter 2010 Elsevier B.V. All rights reserved. doi:10.1016/j.catcom.2010.10.002
X-ray diffraction (XRD) patterns were collected at ambient atmosphere by an X'TRA diffractometer with a Cu K radiation
( = 1.5418 ). The applied voltage and current were 40 kV and 40 mA, respectively. The surface areas and pore sizes were measured by the Gemini V analyzer. Experiments were performed at 77.3 K using N2 as an adsorbate. The samples were degassed at 573 K for 1 h before the measurements. The chemical compositions of catalysts were analyzed by an ARL9800 X-ray uorescence spectrometer (XRF). Transmission electron microscopic measurements (TEM) were carried out using a JEOL electron microscope (JEM-2010), with an accelerating voltage of 200 keV. The catalysts were usually reduced in owing H2 at 673 K for 2 h. Reduced catalysts were passivated in N2 containing about 0.1% O2 at room temperature for 48 h before the BET, XRD and TEM measurements. Temperature programmed reduction (TPR) was performed by using a quartz U-tube reactor loaded with about 50 mg of a sample. A mixture of N2 and H2 (5.13% H2 by volume) was used as the reacting agent and the ow rate was maintained at 40 ml/min. The temperature was raised at a programmed rate of 10 K/min from 303 to 1273 K. H2 and O2 adsorptions were performed on the home-made volumetric adsorption system at room temperature and 673 K, respectively. The catalyst was reduced in H2 at 673 K for 2 h and evacuated at 673 K for 1 h before the measurements. After cooling the catalyst to room temperature, doses of H2 were admitted sequentially and coverage of H2 was measured until the equilibrium pressure (PH2) reached about 50 kPa. An isotherm (coverage versus PH2) was then obtained. The uptake of H2 for the saturation coverage of hydrogen on a nickel surface was determined by extrapolating the coverage of isotherm to PH2 =0. The surface area of metallic nickel was calculated by the uptake of H2 assuming the molar ratio of H/Nisurf = 1 and a surface area of 6.5 2 for a Ni atom [20]. Microcalorimetric adsorption of NH3 and toluene was performed on a TianCalvet heat-ux apparatus. A C-80 calorimeter (Setaram, France) was connected to a volumetric system equipped with a Baratron capacitance manometer (USA) for the pressure measurement and gas handling. Prior to the microcalorimetric adsorption, the samples were typically reduced in H2 at 673 K for 2 h followed by the evacuation at the same temperature for 1 h. 2.3. Hydrogenation of toluene The catalytic hydrogenation experiments were performed at atmospheric pressure in a continuous down-ow xed-bed microreactor. The catalyst was reduced in owing H2 at 673 K for 2 h before the reaction. An n-hexane solution containing toluene (toluene: n-hexane=1:2 w/w) with H2 was fed into the reactor for the hydrogenation reactions. The reaction was performed at 423 K with the weight hourly space velocity (WHSV) of toluene from 28 to 106 h1. 3. Results and discussion 3.1. Textural and structural properties of catalysts Table 1 summarizes the chemical compositions, specic surface areas and pore structural parameters of the Ni/SiO2 and Ni/SiO2-BTable 1 Surface area and pore structure of the 60%Ni/SiO2 and 60%Ni/SiO2B catalysts. Catalyst Ni loading by XRF (wt%) 59.4 58.1 Surface area (m2/g) Dried 105 142 Calcined 248 574 Reduced 141 373 Pore size (nm) Reduced 2 2 Pore volume (cm3/g) Reduced 0.13 0.51
( (Intensity (a.u.)
2 theta (degree)Fig. 1. XRD patterns of the 60%Ni/SiO2 and 60%Ni/SiO2B catalysts after drying and reduction in H2 at 673 K (with R in parentheses), respectively.
catalysts. The results from XRF showed that the loadings of nickel were 59.4% and 58.1% for the Ni/SiO2 and Ni/SiO2B, respectively. Thus the compositions of catalysts analyzed were close to the values desired (60%). The data in Table 1 showed that the treatment with nbutanol signicantly increased the surface areas of catalysts. For example, the surface area was 141 and 373 m2/g for the reduced Ni/ SiO2 and Ni/SiO2B, respectively. The pore volume was also increased signicantly from 0.13 to 0.51 cm3/g for the reduced catalysts. Fig. 1 shows the X-ray diffraction patterns for the Ni/SiO2 and Ni/ SiO2B catalysts after drying at 393 K and reduction in H2 at 673 K. After dried at 393 K, the two catalysts exhibited broad and weak peaks around 24, 36 and 63, probably belonging to basic nickel carbonate and nickel hydrosilicate [21]. No distinct XRD peaks were observed for silica in the two catalysts. After reduction at 673 K, two broad diffraction peaks around 44 and 52 for metallic Ni were detected for the two catalysts. These diffraction peaks were weaker for Ni/SiO2B than for Ni/SiO2, indicating the more highly dispersed metallic Ni in Ni/SiO2B than in Ni/SiO2. The average particle sizes of metallic nickel were calculated to be 6.3 and 3.4 nm, respectively, in the Ni/SiO2 and Ni/SiO2B, according to the Scherrer equation.
3.2. Reducibility and dispersion of supported nickel Fig. 2 shows the TPR proles for the Ni/SiO2 and Ni/SiO2B catalysts. It is seen that the Ni/SiO2 began to reduce at about 680 K with a broad reduction peak with a maximum around 821 K, while the Ni/ SiO2B began to reduce at about 620 K with a relatively narrower
821H2 consumption
Ni/SiO2 712
Ni/SiO2-B400 600 800 1000 1200
Ni/SiO2 Ni/SiO2-B
T (K)Fig. 2. TPR proles of the 60%Ni/SiO2 and 60%Ni/SiO2B catalysts.
The catalysts were dried at 393 K, followed by calcination in N2 at 673 K or by reduction in H2 at 673 K for 2 h.
Table 2 Chemisorption of H2 and O2 on the 60%Ni/SiO2 and 60%Ni/SiO2B catalysts reduced at 673 K. Catalyst Ni/SiO2 Ni/SiO2B H2 ads. (mol/g) 476 848 O2 ads. (mol/g) 2350 2646 Ni surf. area (m2/g-cat.) 37 66 d (nm) 5.1 3.2 Disp. (%) 20 32 Redu. (%) 54 61
3.3. Microcalorimetric adsorption of NH3 and toluene The results of microcalorimetric adsorption of NH3 on the Ni/SiO2 and Ni/SiO2B catalysts were shown in Fig. 4. Fig. 4(a) showed that SiO2 possessed only weak surface acidity with the adsorption heat lower than 20 kJ/mol. The Ni/SiO2B evacuated at 673 K displayed strong surface acidity with the initial heat of 160 kJ/mol and coverage of 1200 ml/g. The strong acidity may be assigned to the nickel hydrosilicate, since both SiO2 and NiO processed weak surface acidity (the initial heat of ammonia adsorption on NiO was lower than 40 kJ/ mol [23]). The initial heat for the adsorption of ammonia on the reduced Ni/SiO2B was almost not changed. On the other hand, the Ni/ SiO2 evacuated at 673 K showed the relatively weaker surface acidity with the initial heat of about 90 kJ/mol for the adsorption of ammonia. The initial heat was increased to about 120 kJ/mol for the reduced Ni/ SiO2, which might be due to the dissociative adsorption of NH3 on the metallic Ni [24,25]. This phenomenon was not observed for the reduced Ni/SiO2B probably owing to its strong surface acidity that generated higher heat than that for the adsorption of ammonia on metallic nickel. Fig. 4(b) presents the microcalorimetric adsorption of toluene on the Ni/SiO2 and Ni/SiO2B catalysts. The initial heat and coverage for the adsorption of toluene over SiO 2 B was 63 kJ/mol and 1100 mol/g, respectively. The initial heat and coverage were increased to 84 kJ/mol and 1800 mol/g, respectively, on the Ni/ SiO2B, due to its stronger surface acidity. The initial heat was increased to 140 kJ/mol on the reduced Ni/SiO2B, much higher than that on the un-reduced catalyst, indicating the adsorption of toluene on the surface of metallic nickel [25]. The adsorption heat was dropped rapidly with the increase of coverage of toluene, indicating that only a small amount of toluene could be adsorbed on some highly active metallic nickel sites and generated the high heat. The initial heat for the adsorption of toluene was also higher over the reduced Ni/SiO2 than the un-reduced Ni/SiO2B.
Notes: Reduction degree (Redu.) was calculated according to the uptake of O2. Average diameter (d) and dispersion (Disp.) of supported nickel particles were calculated according to the uptake of H2 and the amount of reduced nickel.
peak with a maximum around 712 K. Thus, the treatment with nbutanol favored the reduction of supported nickel species. The adsorption of H2 and O2 on the reduced catalysts was carried out at room temperature and 673 K, respectively, according to which the dispersion, reducibility and nickel surface area of supported nickel could be derived [20,22]. Table 2 summarizes the information obtained by the adsorption of H2 and O2. According to O2 uptakes, the degrees of reduction were found to be 54% and 61% for the Ni/SiO2 and Ni/SiO2-B catalysts, respectively, suggesting that the n-butanol treatment increased the reducibility of nickel, consistent with the TPR results. In addition, the n-butanol treatment signicantly increased the dispersion of Ni from 20% to 32%, probably due to the increased surface area of the catalyst. The H2 uptake was measured to be 476 and 848 mol/g for the Ni/SiO2 and Ni/SiO2B, corresponding to the active nickel surface area of 37 and 66 m2/g-catalyst, respectively. The average particle sizes of reduced Ni were then calculated to be 5.1 and 3.2 nm for the Ni/SiO2 and Ni/SiO2-B, respectively, in agreement with the results of XRD and TEM. Fig. 3 displays TEM images for the Ni/SiO2 and Ni/SiO2B reduced in H2 at 673 K. The images showed that the size distribution of nickel particles was quite uniform in the two samples. The Ni particles were obviously smaller in Ni/SiO2B than in Ni/SiO2.
Fig. 3. TEM images of the 60%Ni/SiO2 (a and b) and 60%Ni/SiO2B (c and d) reduced in H2 at 673 K.
(a)Adsorption at 423 KNi/SiO2-B Ni/SiO2-B (R) Ni/SiO2 Conversion (%)80 100
TOF (s-1)0.04
Ni/SiO2 (R)
0 40 80 120
0.00 40 80 120
WHSV (h-1)
Adsorption at 303 K
Fig. 5. Conversion (a) and TOF (b) of toluene versus WHSV of toluene on the 60%Ni/SiO2 and 60%Ni/SiO2B catalysts reduced in H2 at 673 K. Reaction conditions: P = 1 atm, T = 423 K and H2/toluene = 5 (molar ratio).
4. Conclusions Ni/SiO2 catalysts with the high loading (60% by weight) were prepared by the precipitation method. It was found that a drying process with n-butanol signicantly increased the surface area of catalyst due to the removal of water at the condition of low surface tension of n-butanol. In addition, the number of surface active nickel sites was also signicantly increased due to the improvement of reducibility and dispersion of supported nickel. The reduced nickel particles on the SiO2 support could be as small as 4 nm, even at the high loading of 60 wt.%. Such a catalyst possessed high active nickel surface area and thus was highly active for the hydrogenation of toluene to methyl cyclohexane. It is interesting to note that the surface acidity was also signicantly increased for the 60%Ni/SiO2B prepared with the treatment of nbutanol, which favored the adsorption and hydrogenation of toluene. Acknowledgements
3.4. Catalytic hydrogenation of toluene Fig. 5 presents the results of hydrogenation of toluene at 423 K on the Ni/SiO2 and Ni/SiO2B catalysts. Methyl cyclohexane was found to be the only product. The conversion of toluene was 32% over the Ni/ SiO2 at the WHSV of toluene of 28 h1, while it was 100% over the Ni/ SiO2B at the same reaction conditions. Thus, Ni/SiO2B was much more active than Ni/SiO2 for the hydrogenation of toluene, apparently due to the much higher active nickel surface area on Ni/SiO2B than on Ni/SiO2. Since the uptake of H2 measured the number of active sites of surface nickel, the activity could be expressed in turnover frequency (TOF) as shown in Fig. 5(b). The TOF of toluene for Ni/SiO2 was relative steady around 0.02 s1, while it increased to about 0.11 s1 with the increase of WHSV for Ni/SiO2B. The higher activity of Ni/SiO2B could not be ascribed to its higher active nickel surface area only, since the TOF of toluene for Ni/SiO2B was also signicantly increased. Studies have shown that the activity of aromatic hydrogenation depended not only on the amounts of accessible active metal sites, but also on the surface acid-base properties [2426]. The surface acidity favored the adsorption of toluene since toluene can be taken as a Lewis base due to the enriched electron density on the aromatic ring. This has been proved by the results of microcalorimetric adsorption of toluene presented above. So the higher activity may also be due to the stronger surface acidity of Ni/SiO2-B.
Financial supports from NSFC (21073089), MSTC (2005CB221400) and Jiangsu Province, China (BE2009145) are acknowledged. References[1] F.F. Castillon, N. Bodganchikova, S. Fuentes, M. Avalos-Borja, Appl. Catal., A 175 (1998) 5565. [2] M.P. GonzBlez-Marcos, J.I. Gutikrez-Ortiz, C.G. Elguea, J.R. GonzSlez-Velasco, J. Mol. Catal., A 120 (1997) 185196. [3] M.P. GonzBlez-Marcos, J.I. Gutikrez-Ortiz, C.G. Elguea, J.A. Delgado, J.R. GonzSlezVelasco, Appl. Catal., A 162 (1997) 269280. [4] M. Yonemitsu, Y. Ranaka, M. Iwamoto, J. Catal. 178 (1998) 207213. [5] M. Kermarec, J.Y. Carriat, P. Burattin, M. Che, A. Decarreau, J. Phys. Chem. 98 (1994) 1200812017. [6] P. Burattin, M. Che, C. Louis, J. Phys. Chem. 104 (2000) 1048210489. [7] R. Gmez-Reynoso, J. Ramrez, R. Nares, R. Luna, F. Murrieta, Catal. Today 107108 (2005) 926932. [8] R. Nares, J. Ramrez, A. Gutirrez-Alejandre, R. Cuevas, Ind. Eng. Chem. Res. 48 (2009) 11541162. [9] P. Burattin, M. Che, C. Louis, J. Phys. Chem. B 101 (1997) 70607074. [10] M. Stankovic, M. Gabrovska, J. Krstic, P. Tzvetkov, M. Shopska, T. Tsacheva, P. Bankovic, R. Edreva-Kardjieva, D. Jovanovic, J. Mol. Catal. A: Chem. 297 (2009) 5462. [11] S. Tomiyamaa, R. Takahashi, S. Sato, T. Sodesawa, S. Yoshida, Appl. Catal., A 241 (2003) 349361. [12] R. Takahashi, S. Sato, T. Sodesawa, M. Yoshida, S. Tomiyama, Appl. Catal., A 273 (2004) 211215. [13] S.S. Prakash, C.J. Brinker, A.J. Hurd, S.M. Rao, Nature 374 (1995) 439443. [14] Z.S. Hu, J.X. Dong, G.X. Chen, J. Colloid Interface Sci. 208 (1998) 367372. [15] H. Shan, Z. Zhang, J. Eur. Ceram. Soc. 17 (1997) 713717. [16] G.M. Gao, H.F. Zou, S.C. Gan, Z.J. Liu, B.C. An, J.J. Xu, G.H. Li, Powder Technol. 191 (2009) 4751. [17] M. Xue, H. Chen, J. Ge, J. Shen, Microporous Mesoporous Mater. 131 (2010) 3744.
M. Xue et al. / Catalysis Communications 12 (2011) 332336 [22] [23] [24] [25] [26] R.B. Pannell, K.S. Chung, C.H. Bartholomew, J. Catal. 46 (1977) 340347. M. Xue, J. Ge, H. Zhang, J. Shen, Appl. Catal., A 330 (2007) 117126. H. Chen, M. Xue, J. Shen, Catal. Lett. 135 (2010) 246255. S. Hu, M. Xue, H. Chen, J. Shen, Chem. Eng. J. 162 (2010) 371379. S.D. Lin, M.A. Vannice, J. Catal. 143 (1993) 563572.
[18] J. Shen, M. Xue, J. Ge, Y. Fu, CN Patent 200710024880.6 (2007), to Nanjing Univ. [19] J. Shen, M. Xue, H. Chen, J. Li, J. Chen, CN Patent 200910232931.3 (2009), to Feixiang Chem. Co. Ltd. and Nanjing Univ. [20] S. Narayanan, G. Screekanth, J. Chem. Soc. Faraday Trans. I 85 (1989) 37853796. [21] K.D. Ghuge, A.N. Bhat, G.P. Babu, Appl. Catal., A 103 (1993) 183204.


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Uber CEO to Meet With London Transport Regulator About Operating License
Company seeks details of specific complaints and will ask how to resolve them
Uber Technologies Inc.'s new chief executive plans to meet Tuesday with London's top transport regulator to plead for a reversal of last week's decision to strip the ride-hailing company of its operating license.
The agency, Transport for London, a week ago cited what it called a lack of corporate responsibility as the reason for not renewing Uber's license to operate a private-hire car service in the city. It specifically raised issues with how Uber reported serious crimes and how it conducted driver background checks.
Uber has said it complies with all laws about reporting crime and conducts the same background checks as London's licensed black cabs. It is appealing the ruling in court.
But it has also turned on the charm. Chief Executive Dara Khosrowshahi, who took the reins at Uber earlier in September, plans at Tuesday's meeting with the agency's commissioner, Mike Brown, to ask for more details of specific complaints and ask how the company could resolve them, an Uber spokeswoman said.
"We want to work with London to make things right," the spokeswoman said.
A spokesman for Transport for London confirmed it is arranging the meeting "following an approach from Uber."
Related Coverage
Mr. Khosrowshahi's decision to travel halfway around the world for the London meeting is the latest step in his effort to prove Uber is changing its ways after the departure of former CEO Travis Kalanick. On Monday, he published an open letter to Londoners, apologizing "for the mistakes we've made." While he reiterated Uber would still appeal the ruling in court, he added the company would do so "with the knowledge that we must also change."
London Mayor Sadiq Khan welcomed Mr. Khosrowshahi's apology, and was pleased the executive acknowledged the issues Uber faces in London, a spokesman for the mayor's office said.
Mr. Khan won't be present at Tuesday's meeting. But the mayor asked transport agency officials to make themselves available for the meeting with Uber, and to remain open to discussions with the company, the spokesman added.
London is an important market for Uber. While the company doesn't break out revenue by market, it said London accounts currently for about 5% of the 65 million people around the world who use the service at least once a month.
Write to Sam Schechner at firstname.lastname@example.com and Wiktor Szary at firstname.lastname@example.com
Copyright ©2019 Dow Jones & Company, Inc. All Rights Reserved. 87990cbe856818d5eddac44c7b1cdeb8
Appeared in the October 2, 2017, print edition as 'Uber CEO Heads for London.'


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Training Tuesday Update from Stuart Kennedy 20 August
20 August 2019
Official Coach Stuart Kennedy shares his latest #TrainingTuesday update! Stuart is coaching our Challenge 13.1 team who are all training for their 1st Half Marathon - in Belfast on Sunday 22 September!
"5 weeks until Half Marathon Sunday!
I'm currently being asked...how many long runs people should do and how far should their longest run be.
Obviously there's no one answer for these questions because everyone has a different journey to the half marathon. Some are seasoned half marathon runners, others are experienced runners that are moving up distance and looking for a certain time...and others are first timers that might have started on C25K programmes; the longest distance they might have ran could have been 10k (or a Team Relay distance in May) when the thought of running the Deep RiverRock Belfast City Half Marathon entered their heads.
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Take heart in what you have achieved since you started this process & bring the determination you have shown time & time again to the half marathon starting line. Rely on your fitness and run with your heart."
✅ Need some help with your training? Stuart can provide a tailored training plan & one to one coaching for a 10K, Half Marathon or Marathon. Contact Stuart via our website HERE.
Still not signed up for the 7th Deep RiverRock Belfast City Half Marathon? Or know someone who wants to register? Sign up NOW HERE & don't forget to select one of our charity partners when registering!
❗Final deadline for entry will be at midnight on Friday 30 August 2019...unless we sell out before. ❗Less than 700 entries left!


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Recent automotive trends, reviews, test drives and the latest news from the world of cars
Alfa Romeo back to the United States with the 4C
Alfa Romeo's return to the United States after nearly 20 years out of this market, the Italian brand will reestreiar Hall in New York, in April, with the 4C model.
Kia to launch coupe version of the Soul
Kia is seriously considering to launch new versions of the Soul, including a coupe and a station wagon.
Next-generation Ford Focus coupe will carry lightweight design
Ford recently took the new restyled Focus (pictured) for the Geneva Motor Show , but that has not stopped the company to talk about the next generation model.
Mercedes-Benz launches limited editions of three models in Japan
Japan seems to be showing a good niche for the German premium car manufacturer. With this, Mercedes-Benz took the opportunity to announce three new models, special and limited editions, but with the same performance as their standard versions for the Japanese market: E250 Coupe Limited Edition Sport Night A250 and A45 AMG Petronas.


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Iggy Azalea Lost 15lbs Twerking
Australian rapper, Iggy Azalea, claims that she's lost 15 pounds in one week thanks to twerking in her latest music video.
She said, "I did a lot of rehearsals actually, and man I lost 15 pounds in a week dancing to that song!"
The new song is called "Mo Bounce" and Iggy explained, "It's a lot – I went on a meal plan before the video because I knew I would have to be dancing fairly skimpily dressed."
Iggy said of the dancing, "It just has to come naturally," but she confessed to having had a little help. She said, "I did take classes. I do have someone who is very, very good at twerking and she helped me. I never realized how flexible you have to be to do that stuff."
Twerking tips? Iggy said, "My teacher was like 'I really suggest you take yoga' and I didn't know you had to take yoga to be a twerker but apparently you do."
Source: Page Six