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aSentiment - Matrimoniale cu poze, relat..
Patimile nasc pasiuni, cresc sentimente si atrag simpatii. Pasiunile duc la relatii matrimoniale si prietenii. Love Dating inseamna pasiune...
Pymaxe - Free the music..
Easily download music for free from internet. Pymaxe is an open-source application that allow downloading music from several sites. By defa...
NAVTEQ Map24 - Harti online si Planifica..
MapTP este "Map Transfer Protocol" (Protocol de transfer harti) si sta la baza unor aplicatii de mapare geografica. Caracteristica ap...
Carti online - biblioteca virtuala, unde..
Domeniile la care gasiti carti online gratuite sunt: Administratie, Agronomie, Arte Plastice, Astronomie, Biologie, Chimie, Contabilitate, Come...
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Hi5 Email Finder - afla id-ul unui profi..
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Currently 4.02/5
/5(2151 voturi)
HD Hacker Backs Up Your Master Boot Record
The Master Boot Record contains important boot information which are essential to boot a computer system. A corrupted master boot record usually makes a system. HD Hacker is a free application which allows you to backup and restore sectors on your hard drives. You can backup and restore the master boot record, the boot sector from logical drives, or any other user specified sector you need to backup. Backing up the master boot record is an advised step before messing around with repartitioning or installing a new operating system to create a dual boot system. Backing up the master boot record is an advised step before messing around with repartitioning or installing a new operating system to create a dual boot system. For other boot record magic, check out how to fix your master boot record with an Ubuntu Live CD. HD Hacker is freeware, Windows only. HDHacker is a stand-alone micro-utility that saves, visualizes, and restores the MBR (from a physical drive), the BootSector (from a logical drive) or any specified sector from any disk (even removable disks). HDHacker can be used, for example, to save and restore a particular boot manager (such as LILO, for example) before a new Windows setup (which, obviously, overwrites it). An MBR and BootSector backup can also be useful for simple precautionary purposes too, since sometimes viruses or other OS setup (like Linux) could overwrite and/or alter the MBR/Boot Sectors, making it impossible to start up previous OS and/or access datas stored on the disk. HDHacker can provide "insurance" against all these types of loss.
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Currently 2.93/5
/5(610 voturi)
Best Google Search Tricks and Tips
When it comes to the Google search box, you already know the tricks: finding exact phrases matches using quotes like "so say we all" or searching a single site using site:wikipedia.com gmail. But there are many more oblique, clever, and lesser-known search recipes and operators that work from that unassuming little input box. Dozens of Google search guides detail the tips you already know, but today we're skipping the obvious and highlighting our favorite obscure Google web search tricks. Using a combination of advanced search operators that specify music files available in an Apache directory listing, you can turn Google into your personal Napster. Go ahead, try this search for Nirvana tracks: -inurl:(htm html php) intitle:"index of" -"last modified" -"parent directory" -description -size -(wma mp3) "Nirvana". (Sub out Nirvana for the band you're interested in; use this one in conjunction with number 7 to find new music, too.) The same type of search recipe can find comic books as well.
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Currently 4.08/5
/5(2105 voturi)
VideoLAN Movie Creator - a free video editing software
VLMC (VideoLAN Movie Creator) is a free video editing software, offering features to realize semi-professional quality movies, but with the aim to stays simple and user-friendly. VideoLAN Movie Creator is a non-linear editing software for video creation based on libVLC and running on Windows, Linux and Mac OS X! It is a free software distributed under the terms of the GPL v2.
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Currently 4.09/5
/5(2055 voturi)
Gantto - Easy to Present Gantt Charts online
Automatically turn project schedules into effective presentations in minutes. Gantto was conceived to fill one obvious gap in our weekly management routine. Each week we would collect status information based upon what was really happening inside the organization and then update our project models to reflect and digest the changes. Then we would spend tedious hours manually creating presentations based upon the same underlying project data that we had already updated. After a long search for a good solution we set out to create our own. Features: Navigation * Pan by clicking and dragging the background * Zoom in time with horizontal slider bar or CTRL-scroll * Zoom in font size with the vertical slider bar or ALT-scroll * Use the fit all vertical and fit all horizontal buttons to see the big picture * Use Marquee tool to zoom back into the details. Data import. * Gantto imports MS Project files exported in .xml format * Gantto allows you to create, load and save your own schedule files Data manipulation. * Drag and drop tasks in the task list to reorder them * Edit task details by double-clicking or pressing ENTER on a selected task * Leave sticky notes attached to tasks to follow up on later * Change tasks duration and start time by dragging with your mouse...
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Currently 4.07/5
/5(2181 voturi)
Best of Symbian - S60 Software Application Freeware Reviews
Best of Symbian offers reviews of the best software and freeware for Symbian OS Smartphones, especially S60 3rd Edition. There are hundreds or maybe thousands of programs for symbian platforms. Because of our passion for symbian smartphones, especially S60, we will pick out really useful software and would like to introduce and review these for you. ABBY Foto Translate was installed on a Nokia 5800 XPressMusic, an S60 5th edition device with Symbian OS 9.4. Installation Installation is simply via the Nokia Application Installer available in the Nokia PC Suite. You get different .sis files for different languages. First View ABBY Foto Translate, as the name suggests, instantly translates words captured on your S60 Symbian camera phone into the desired language. The concept of snapping a few foreign words and getting their meaning immediately is very exciting. Lets see how well this ambitious idea has been implemented for daily use. Batch Uninstall your Symbian applications How often do you find a cluttered application folder in you Symbian S60 device with too many applications that you had installed over several months? I am usually lazy in removing applications from my phone because its a tedious affair, picking each application one by one and removing it manually. ThinkChange obviously have had this problem and have released a free BatchUninstaller application for Symbian S60 devices that removes multiple applications in one shot.
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Currently 4.07/5
/5(2074 voturi)
VisualSVN - Subversion-based source control for Windows
VisualSVN is a Visual Studio plug-in that integrates Subversion and TortoiseSVN seamlessly with Visual Studio. VisualSVN virtually eliminates the management of your project source code files within Subversion. Program, design, debug and deploy with VisualSVN as your silent partner that safeguards your source code. With VisualSVN deployed throughout your development organization, all of your developers will be using Subversion confidently and effectively to manage and safeguard your organization's work product. VisualSVN Server allows you to easily install and manage a fully-functional Subversion server on the Windows platform. Thanks to its robustness, unbeatable usability and unique enterprise-grade features, VisualSVN Server is affordable both for small business and corporate users. VisualSVN Server is based on open standards and offers rock-solid stability, security and performance. Its key features are: * Works out-of-the-box * Powerful management console * Integrated Windows Authentication * Remote Server Administration * Access and Operational Logging
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Currently 4.06/5
/5(2215 voturi)
APWG - Committed to wiping out internet scams and fraud
The Anti-Phishing Working Group (APWG) is the global pan-industrial and law enforcement association focused on eliminating the fraud and identity theft that result from phishing,pharming and email spoofing of all types. Our mission is to provide a resource for information and solutions for eliminating the fraud, identity theft and electronic crime that result from phishing, pharming and email spoofing of all types. The APWG Public Education Initiative (PEI) identifies and organizes the most broadly useful counter-ecrime educational programs and forges the essential logistics to deliver them to the largest victimized cohort possible, in every language in which phishing, directed at consumer and enterprise desktops and communications devices, has become a problem. Phishing and crimes that leverage it exploit a small number of transactional exposures, the most obvious being the capture (and criminal abuse) of online user credentials. PEI seeks to provide focused and most exposure-relevant instruction wherever and whenever possible to help consumers and enterprise users protect themselves and minimize the number of vulnerabilities that electronic crime gangs can count on being able to abuse.
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Currently 4.08/5
/5(2105 voturi)
Snipt - long-term memory for coders
Snipt is your collection of frequently used commands or code snippets. Because even Subversion gurus forget the 'svn merge' syntax sometimes. So, what exactly is Snipt good for? It's good for storing small pieces of code or commands that you use rather frequently, and will probably forget...
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Auto Shutdown - Tool for Firefox Built-in Download Manager or DownThemAll!
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The 'Water From A Stone' is a beautiful glass bubble that waters your plants so you don't have to. Water From A Stone embeds itself in your garden and slowly releases water throughout the day. Each glass container is able to water your plants over the course of 3-4 days. As a result, users can avoid the constant hassle of watering their plants.
Designer Casey Scheider created the elegant garden tool in order to help gardeners out while keeping their homes stylish. The glass structure makes for a sophisticated accessory for any garden.
Water From A Stone works by releasing water through a cork. A cork stopper at the end of the stone slowly lets water out into the surrounding soil.
The 'Water From A Stone' Sits in Your Garden to Hydrate Plants
Alexander Lam — August 20, 2013 — Art & Design
References: kikkerland & fancy


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5/5 - Excellent
Verified traveller2 Dec. 2019
Beautiful area out of the hustle and bustle but close to all facilities.
Reviewed on 24 Nov. 2019
Reviewed on 4 Dec. 2019
Reviewed on 10 Nov. 2019
4.5/5(1,583 reviews)
World-class shopping at over 700 stores, farm animals and even a few ghosts make this much more than a typical shopping mall.
4.5/5(589 reviews)
Tour the stadium, witness an AFL showdown, see a game of rugby or cricket, browse the Bradman Collection, dine in style or rock out at a concert.
4.5/5(620 reviews)
See how roses are tested for Australia's climate while you return to nature in these historic gardens.
4/5(640 reviews)
In the centre of Adelaide's CBD, this large city square is where you will find some of the most important buildings in the state, including many historic sites.
4.5/5(239 reviews)
Visit one of Australia's most important collections of indigenous art at this cultural institution.
4.5/5(1,353 reviews)
This historic settlement is a thriving cultural destination, right on the beach.
Travel to the Barossa Valley and marvel at its stunning vineyards and Bavarian influence. Breathe in the fresh air and the beauty of Adelaide Hills, dotted with peaceful villages wrapped in leafy greenness. Enjoy a local lunch and taste some of South Australia's best wines at Creek Wines.
DAY 1 The Adelaide to Melbourne tour departs from Adelaide in the morning making it's way towards the National Heritage listed Grampians National Park to see the majestic mountain ranges and iconic views such as 'The Balconies'.
Take an easy 2 hour stroll down North Terrace in Adelaide, known locally as our "Cultural Boulevard". Hear about the unique way in which South Australia was colonised, as well as some of the stories behind some of our colonial characters who helped shape our society.
Explore the natural highlights and wildlife of stunning Kangaroo Island. The beauty starts on the drive, continues on a ferry ride, and extends to the Remarkable Rocks and Flinders Chase National Park, to the playful fur seal colony, and even a break for a delicious 2-course lunch.
After collection from your hotel or other accommodation, your day starts with a visit to the boutique cellar door of Dell'Uva wines to sample from the wide selection of varietals on offer, one of the largest range of Europeans grape varietals in the country (44 different varietals) are planted over the 50-hectare property.
This is the Yorke Peninsula Tour that has it all! Aboriginal Culture, Wildlife, Beaches, Rugged Cliffs and Coastline, Fishing, Surfing, Spectacular Scenery and even a visit to a local winery.
Top Destination
Verified traveller2 Dec. 2019
Beautiful area out of the hustle and bustle but close to all facilities.
Verified traveller12 Nov. 2019
Really well run Hotel. Dining room and staff Excellent. Food and service first class.
Verified traveller6 Aug. 2019
A must stay if in Adelaide!! Definitely an unforgettable fantastic experience. Close to everything & we found traveling around the city was easy & we were within half an hour for everywhere. Very highly recommended, especially Room "One".
Verified traveller29 Apr. 2019
Great area to relax
Verified traveller21 Apr. 2019
Perfect for a few days away from it all.
Louise2 Apr. 2019
It was noisy. Lots of noise in the outdoor cafe and the road.


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Featuring Drake, Future, Jay-Z, Cardi B, 21 Savage, Young Thug, Rick Ross, and more.
Album Reviews
Mike WiLL Made-It-produced compilation also includes Nicki Minaj, Nas, ASAP Rocky, Vince Staples, Pharrell, and Juicy J, among others.
Expect appearances from Quavo, 21 Savage, Bruno Mars, Kodak Black, and more.
The two-day event also promises Lil Uzi Vert, Young Thug, Wiz Khalifa, Ty Dolla $ign, Kodak Black, Playboi Carti, and more.
The track marks Kodak Black's first piece of new music since getting released from prison last month.
In January, the 21-year-old rapper was arrested following an Instagram Live stream in which he appeared next to his child while in possession of a gun and marijuana.
The follow-up to 2015's At.Long.Last.ASAP features Frank Ocean, Ms. Lauryn Hill, FKA twigs, and more.
The 20-year-old rapper was broadcasting live on Instagram at the time of the arrest.
In a year full of alternative facts, here are its alternative best lyrics…
The rapper could face up to 30 years behind bars
Following cosigns from Beyoncé and Janet Jackson.
Featuring Beyoncé, Drake, Rihanna, Chance the Rapper, Future, JAY-Z, and so much more.


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The Westhampton Beach Historical Society serves the communities of Westhampton, Westhampton Beach, Westhampton Dunes, Westhampton Dunes, Quiogue, Remsenburg and Eastport. Our mission is to … read more» about About the Westhampton Beach Historical Society
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Where does a sub q shot gone
Diagram 1: A subcutaneous injection into the fatty layer of will discuss appropriate needle and syringe sizes If the medication vial can be used for more. For small amounts of delicate drugs, a subcutaneous injection can be a convenient way of getting a medication into your body. Here's how to. Video on How to Give a subcutanous injection shot, also called a Sub-Q shot, with insulin, lovenox, or heparin in the fat of the abdomen/belly.
The needle goes into your skin. The barrel holds the medicine The following are sites where you can give a subcutaneous injection: Abdomen: Uncover your . How to do a subcutaneous injection. To give a subcutaneous injection, people should follow these steps: Choose a fatty area of the. In this Article:Preparing for a Subcutaneous InjectionDrawing a Dose of .. the SC injection, then it can cause adverse reaction if it all goes into the bloodstream .
Once the ID injection is completed, a bleb (small blister) should appear . Subcutaneous (SC) injections are administered into the adipose tissue layer just . How you insert the needle can also make a difference. The needles are designed so that the sharp end is cut at a 45 degree angle. If you insert the needle with. A subcutaneous injection is administered as a bolus into the subcutis, the layer of skin directly The injection should be given under the skin, into the fat layer. When the air bubble goes to the top of the syringe, push the plunger tip up to push the The medication prescribed should be injected into subcutaneous tissue. How to administer subcutaneous (Sub-Q) injections for your child and what supplies you will Giving medicines this way is sometimes called "Sub-Q" injection.
The term "sub-Q" is short for "sub-cutaneous," which means. "under the skin." Your doctor has prescribed a medication that you will give yourself by injection. This type of injection is also called a subq injection, pronounced "sub Q" ("sub cue"). Dr. Thompson, a rheumatologist, will demonstrate using a 2 mL vial of . If you are missing any of the required supplies, talk to your local pharmacist. The needle used for a sub-Q injection is very small and doesn't cause much pain. You can buy a sharps container at a pharmacy or medical supply store. the stopper, push the plunger on the syringe so that the air goes into the vial. Subcutaneous (SQ or Sub-Q) injection means the injection is given in the fatty tissue, just under the skin.
A subcutaneous (sub-Q) injection is a shot that delivers medication into the layer of fat Do not change the direction of the needle as it goes in or comes out. This is a good process for those who cannot or will not inject, but it does SUBQ: This means 'under the skin' and the most common shot in this. As we state above, there are different reasons a dog will need a shot. Here are some of the types of injections a dog. A subcutaneous injection, as illustrated in the figure to the right, is given into the fatty injection. Plan to do your injection at the same time each day if you will need . Don't change the direction of the needle as it goes in or comes out. • Do not.


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Pelajari selengkapnya tentang Keanggotaan Sribd
Temukan segala yang ditawarkan Scribd, termasuk buku dan buku audio dari penerbit-penerbit terkemuka.
Determination of Order-Order and Order-Disorder Transition Temperatures of SIS Block Copolymers by Differential Scanning Calorimetry and RheologyJin Kon Kim,*, Hee Hyun Lee, Qi-Jiang Gu, Taihyun Chang, and Yoon Hee JeongDepartments of Chemical Engineering and the Polymer Research Institute, of Chemistry, and of Physics, Pohang University of Science and Technology, Pohang, Kyungbuk 790-784, Korea Received December 30, 1997 Revised Manuscript Received April 22, 1998
Numerous studies have been reported on the orderdisorder transition (ODT) of block copolymers experimentally determined by either rheology1,2 or small-angle X-ray (or neutron) scattering (SAXS or SANS) methods. Recently, it was found that some block copolymers have multiple ordered states. The transition from one ordered state to another is referred to as the order-order transition (OOT).3,4 Previously, the OOT was determined by an abrupt increase in dynamic shear modulus (G) or by a change in the positions of higher order peaks in SAXS profiles with increasing temperature. Leibler5 and Fredrickson and Helfand6 predicted that both ODT and OOT are first-order transitions. However, first- and second-order transitions are not determined in principle by rheological methods,1-4 for instance, the temperature sweep of the storage shear modulus (G) or logarithmic plots of G and the loss shear modulus (G), since shear moduli obtained under a flow condition are not a thermodynamic property. To test whether OOT or ODT is a first-order transition, first-order thermodynamic properties such as volume and entropy should be investigated. However, due to difficulty in measurement of entropy change experimentally near a transition, a heat flow or enthalpy change using differential scanning calorimetry (DSC) can be measured. When either an exothermic or endothermic peak is observed from DSC thermograms at a specific transition temperature except a peak corresponding to an enthalpy relaxation near the Tg, such a transition is considered as a first-order transition. Recently, using DSC, some research groups observed an endothermic peak occurring at TODT for polystyrene-block-polyisoprene (SI) copolymers7 and for other block copolymers.8 However, to the best of our knowledge, there is no report that investigates the OOT of a block copolymer using DSC. Thus it is not known whether the OOT is indeed a first-order transition. In this paper, we demonstrate by using DSC that an OOT between a hexagonally packed cylinder (HEX) and body-centered cubic (BCC) is indeed thermally reversible, and we demonstrate a first-order transition in an SIS copolymer having a weight fraction of the PS block of 0.183. Two polystyrene-block-polyisoprene-block-polystyrene (SIS) copolymers, Vector 4111 (total weight-average* To whom correspondence should be addressed. E-mail: jkkim@ postech.ac.kr. Department of Chemical Engineering and Polymer Research Institute. Department of Chemistry. Department of Physics.
Figure 1. (A) Temperature sweep of G at ) 0.1 rad/s and o ) 0.05 for SIS-L1 obtained during heating (b) and cooling (O) at a rate of 1 C/min. (B) DSC thermograms for SIS-L1. Curves a-c were obtained during the first heating at rates of 20, 10, and 5 C/min, respectively. Curve d was obtained during the first cooling at a rate of 20 C/min after annealing for 10 min at 190 C. Curve e was obtained during the second heating at a rate of 20 C/min. Heat flows in curves d and e are multiplied by a factor of 4.
molecular weight (Mw) of 143 800 and the weight fraction of the PS block of 0.183) and SIS-L1 (Mw of 37 600 and the weight fraction of the PS block of 0.595), were employed in this study. Using synchrotron SAXS and transmission electron microscopy (TEM), we found that SIS-L1 has lamellar microdomains, while Vector 4111 has an OOT between HEX and BCC microdomains.9 Samples were prepared by solution casting in toluene (10 wt % in solid) in the presence of an antioxidant (Irganox 1010; Ciba-Geigy Group) and then annealed for 2 days at 100 C for SIS-L1 and at 140 C for Vector 4111 in a vacuum oven. Vector 4111 was shear-aligned by an oscillatory shearing with large strain amplitude (100%) to obtain aligned HEX microdomains on a macroscopic scale. Using an advanced rheometric expansion system (ARES) with parallel plates of 25 mm in diameter, dynamic temperature sweep experiments were performed at the frequency () of 0.1 rad/s and the strain amplitude (o) of 0.05 under a nitrogen environment to reduce a possible thermal degradation. DSC thermograms were obtained by using a Perkin-Elmer DSC-7 series under a nitrogen atmosphere at various heating and cooling rates with a baseline correction. The upper panel in Figure 1 gives the results of temperature sweep of G during heating and cooling at a rate of 1 C/min for SIS-L1, from which we observe that G decreases precipitously at 158 ( 1 C. According to a rheological criterion,10 the order-to-disorder transition (ODT) temperature, TODT, is taken as the temperature where a precipitous decrease in G appears; the value of TODT is 158 ( 1 C. It is of interest to note that the disorder-to-order transition (DOT) during cooling occurs at a temperature almost the same as the TODT
S0024-9297(97)01879-2 CCC: $15.00 1998 American Chemical Society Published on Web 05/27/1998
obtained during heating. The lower panel of Figure 1 gives DSC thermograms obtained at various conditions for SIS-L1. It was found that during the first heating, in addition to an enthalpy relaxation peak of the PS block occurring at 80 C, an endothermic peak near 165 C is clearly observed. It is of interest to find that (1) the area of endothermic peak (enthalpy change; H) and the peak temperature gradually decrease with decreasing heating rate, which is generally observed for the DSC melting peak of a semicrystalline polymer; (2) when the heating rate is 5 C/min (curve c), the peak temperature is almost the same as the TODT determined from temperature sweep experiments of G; (3) when the first cooling scan at a rate of 20 C/min is performed from a disorder state (190 C) to 40 C, a small exothermic peak is clearly seen (curve d); and (4) during the second heating at a rate of 20 C/min, we again observe an endothermic peak (curve e). It should be mentioned that the difference in peak positions during cooling and heating scans is due to a large scan rate of 20 C/min. The confirmation of exothermic and endothermic peaks during the first cooling and the second heating scan is very important to determine the ODT since the first heating scan may reflect many thermal histories of a sample. For instance, one may argue that an endothermic peak during heating might result from the flowing of a block copolymer in the DSC sample pan due to a rapid decrease in the modulus. Notice that when the original solid sample is placed in the DSC pan, there always exist some empty spaces in the DSC pan where the solid sample does not cover. Thermal conduction through the polymer might be different from that through the empty spaces in the DSC pan. Once a block copolymer begins to flow and becomes molten, the bottom of the DSC sample pan is entirely covered with the block copolymer. Thus, it is speculated that a small amount of heat may be required when a solid sample becomes molten. This suggests that an endothermic peak may be observed even at the temperature where the modulus decreases significantly and the block copolymer starts to flow. Thus, this temperature is not necessarily the same as the TODT. However, during the cooling from the disordered state and the second heating scans, the above effect could be negligible. Therefore, the endothermic peak obtained during the second heating and exothermic peak obtained during the first cooling, as shown in Figure 1, clearly correspond to the ODT and DOT, respectively. These DSC results are in excellent agreement with rheological results. The upper panel in Figure 2 gives the results of temperature sweep of G and G during heating for Vector 4111. G first decreases slowly with increasing temperature and reaches a minimum. Then, G increases and reaches a maximum and finally decreases again. This behavior was previously reported by Sakamoto et al.11 When the OOT is taken as the temperature where a minimum in G appears,4 the TOOT is estimated to be 181 ( 1 C. The highlights of DSC thermograms for Vector 4111 are given in the lower panel in Figure 2. We found that all transitions in thermograms are reproducible and quite reliable. It can be seen in curve a that in addition to an enthalpy relaxation peak near Tg of the PS block, there exist two additional peaks: one is an exothermic peak (represented by an upward arrow, v) occurring at 192 C, and the other is an endothermic peak (represented by downward arrow, V) occurring at 275 C. When the
Figure 2. (A) Temperature sweep of G (b) and G (O) at ) 0.1 rad/s and o ) 0.05 for Vector 4111 during heating at a rate of 1 C/min. (B) DSC thermograms for Vector 4111. Curves a and b were obtained during the first heating at rates of 20 and 5 C/min, respectively. Curve c was obtained during the first cooling at a rate of 20 C/min after annealing at 200 C for 2 h. Curve d was obtained during the second heating at a rate of 20 C/min after the above cooling scan was performed and followed by annealing at 160 C for 2 h.
heating rate was reduced to 5 C/min (curve b), the exothermic and endothermic peak temperatures were reduced to 183 and 255 C, respectively. The reduction in the transition temperatures with decreasing heating rate is due to a kinetic effect, as shown in the lower panel of Figure 1. It is noted that the temperature where an exothermic peak occurs at 183 C in curve b is almost the same as the TOOT determined from temperature sweep experiment of G. Therefore, we conclude that the OOT from HEX to BCC becomes an exothermic process. To the best of our knowledge, it is the first observation that an OOT from HEX to BCC microdomains as determined by DSC becomes a firstorder transition and an exothermic process. Now, we consider why an exothermic peak is observed during a transition from HEX to BCC microdomains. The Gibbs free energy change (G) from HEX to BCC microdomains can be written as
in which is the Flory interaction parameter and N is the total number of segments in the block copolymer. The positive value of Sconf is attributed to the fact that, in order to satisfy the uniform density requirement, matrix chains in BCC are less stretched than those in HEX, because the curvature of microdomains in BCC is larger than that in HEX. Although Matsen and Bates theory had been developed for a diblock copolymer, Sconf for a triblock copolymer might be assumed to be positive even if bridge and loop conformations of block chains must be considered, which is inconsistent with the above results. Thus, in this study, in addition to Sconf, we consider the other entropy, namely, the packing entropy (Spack) resulting from the distribution of many microdomains (or regularity in the packing of the microdomains) in a given volume. The Spack of HEX seems to be similar to that of BCC because both microdomains are fixed in their space groups. Thus, when HEX microdomains are directly transformed into BCC microdomains, an endothermic peak is expected. However, once undulated cylinders are formed near the transition between HEX and BCC microdomains, the situation becomes quite different. Many research groups13-16 suggested the formation of undulated cylinders during the transition from HEX to BCC microdomains. We consider that the Spack of undulated cylinders would be much larger than that of BCC microdomains because in the latter the microdomains are fixed at the BCC configuration. Although Sconf of undulated cylinders seems to be smaller than that of BCC microdomains, the difference is not large. This is because the curvature in undulated cylinders is similar to that of BCC and there are bridge and loop conformations of block chains preventing free relaxation in matrix phases. Therefore, during the transition from undulated cylinders to BCC microdomains, Spack would dominate over Sconf, which leads us to conclude that the entropy change from undulated cylinders to BCC microdomains becomes negative. This implies that an exothermic peak is expected during this transition, which is consistent with results given in the lower panel of Figure 2. However, one might consider that for a diblock copolymer, Sconf becomes more important compared with a triblock copolymer, since there is no bridge and loop conformation in the diblock copolymer. The investigation of heat flow change near the OOT in a diblock copolymer is in progress. Then, a question may be raised as to why an endothermic (or exothermic) peak is not observed in the transition from HEX microdomains to undulated cylinders (or vice versa) at temperatures lower than the TOOT. Although a detailed explanation on this is beyond the scope of this paper, this transition might not be first order. In other words, since HEX microdomains might continuously change their shapes to undulated cylinders as the temperature approaches the TOOT, there is no need for a discontinuity in enthalpy (or in entropy) in DSC thermograms; rather, a slope change in heat flow can be expected. This implies that during the transformation of HEX microdomains into undulated cylinders, both Sconf and Spack increase gradually with increasing temperature. We observed that during heating and cooling, a slope change in heat flow near 150 C (open arrow, w) in curves a and c in the lower panel of Figure 2 was detected. It is noted that this change was very reproducible even if very small. We speculate that an undulated cylinder might start to form at this
Figure 3. Schematic of the enthalpy change near the OOT between HEX and BCC microdomains.
temperature, although more investigation for this behavior should be done using a synchrotron SAXS near 150 C. On the basis of the above argument, we consider that the transition path between HEX and BCC microdomains might be qualitatively drawn in Figure 3. The transition from undulated cylinders to BCC microdomains would be an exothermic first-order transition, while the transition from BCC microdomains to undulated cylinders would be an endothermic first-order transition. This is in qualitative agreement with the result given in curve c of the lower panel in Figure 2, where a clear endothermic peak (V) is observed at 165 C during cooling. The difference in the OOT temperature obtained during cooling and during heating is due to different ordering kinetics between the ordering of HEX from BCC and the ordering of BCC from HEX in addition to a large scanning rate. Previously, we reported that even when a temperature sweep of G was performed during heating and during cooling at the rate of 0.5 C/min, the TOOT from HEX to BCC during heating was found to be 15 deg higher than the TOOT from BCC to HEX during cooling.17 From curve d of the lower panel in Figure 2, we confirmed again the exothermic and endothermic peaks (represented by an upward arrow (v) and by downward arrow (V)) during the second heating after annealing at 160 C for 2 h. Finally, we briefly mention the ODT of Vector 4111. On the basis of an endothermic peak in curves b and d in the lower panel of Figure 2, the TODT would be 260270 C.18 This value is consistent with results investigated by Sakamoto et al.11,20 that the TODT for Vector 4111 is larger than 220 C11 and estimated to be 270280 C by the extrapolation, based on a dilution theory, of experimentally measured TODTs for several solutions consisting of Vector 4111 and dioctyl phthalate.20 On the basis of the results in Figures 2, the TODT of Vector 4111 determined by DSC is 50-60 deg higher than that obtained by the temperature sweep of the G experiment if the TODT is assumed to be the temperature where G drops precipitously. This suggests that the temperature sweep of the G experiment might not be useful to detect the TODT for a block copolymer with a lattice disordering transition (LDT), which is often found at a highly asymmetric composition.11 The existence of LDT or spheres in liquidlike short-range orders before reaching the ODT of a block copolymer with highly asymmetric composition has been suggested by SAXS and log G versus log G plots.11,20,21 For instance, Schwab and Stuhn21 showed that, for an asymmetric SI copolymer (volume fraction of PS is 0.11), spheres in liquidlike short-range orders existed between BCC and the homo-
geneously disordered state, which was deduced from the existence of high-order peaks not corresponding to BCC microdomains in SAXS profiles. However, the existence of LDT might be speculated from the behavior of G in Figure 2. After a drop in G at 210 C, G decreases very gradually with increasing temperature up to 270 C. It can be considered that as spheres in liquidlike short-range order disappear gradually, the G (or viscosity) would be decreased gradually, not sharply. Therefore, we speculate that spheres in liquidlike shortrange orders for Vector 4111 can exist from 220 C up to 260-270 C, which is consistent with results investigated by Sakamoto et al.11,20 Before closing, we mention that there might exist a broad exothermic peak between the OOT and ODT (curves a and b in the lower panel of Figure 2) and this might be related to the LDT process. However, we found that this change in heat flow (or enthalpy) near the temperature was not quite reproducible, because in the second heating run (curve d) after 2 h annealing at 200 C, we barely see an exothermic peak, as seen in curve b in the lower panel of Figure 2.22 In summary, we have shown that an OOT from HEX to BCC microdomains for the SIS copolymer with the weight fraction of the PS block of 0.183 is an exothermic process due to the undulated cylinders formed during the transition and that the DSC technique can give an alternative method to determine the TODT of a block copolymer having an LDT. Acknowledgment. This work was supported by POSTECH/BSRI special fund and the Korean Foundation of Science and Engineering (No. 97-05-02-03-013). We acknowledge Professors S. Sakurai at KIT, S. Okamoto at NIT, and T. Lodge at the University of Minnesota for discussing the OOT mechanism. References and Notes(1) Bates, F. S.; Fredrickson, G. H. Annu. Rev. Phys. Chem. 1990, 41, 525. (2) Han, C. D.; Baek, D. M.; Kim, J. K.; Ogawa, T.; Hashimoto. T. Macromolecules 1995, 28, 5043. Han, C. D.; Baek, D. M.; Kim, J. K. Macromolecules 1990, 23, 561. (3) Sakurai, S.; Kawada, H.; Hashimoto, T.; Fetters, L. J. Macromolecules 1993, 26, 5796. (4) Almdal, K.; Koppi, K. A.; Bates, F. S.; Mortensen, K. Macromolecules 1992, 25, 1743. Khandpur, A. K.; Forster, S.; Bates, F. S.; Hamley, I. W.; Ryan, A. J.; Bras, W.; Almdal, K.; Mortensen, K. Macromolecules 1995, 28, 8796. (5) Leibler, L. Macromolecules 1980, 13, 1602. (6) Fredrickson, G.; Helfand, E. J. Chem. Phys. 1987, 87, 697. (7) Stuhn, B. J. Polym. Sci., Part B: Polym. Phys. Ed. 1992, 30, 1013. Kasten, H.; Stuhn, B. Macromolecules 1995, 28, 4777. Hajduk, D. A.; Grunmer, S. M.; Erramilli, S.; Register,
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Media Releases
A new program to strengthen South Australia's farm biosecurity and animal health management was officially launched today at the Eyre Peninsula Field Days.
Don't miss this opportunity to reinvigorate your regions. Now is the time to start finalising applications for the State Government's first round of the Regional Growth Fund, which closes on 31 August.
Experienced forester, Mr Keith Lamb, has today been appointed to the Board of ForestrySA to strengthen the organisation's strategic asset management capability.
The Marshall Liberal Government has today convened a working group with key industry stakeholders and support agencies to discuss the challenging seasonal conditions farmers and communities are experiencing in parts of South Australia.
The clean-up of abandoned aquaculture infrastructure at Anxious Bay near Elliston on the Eyre Peninsula is now complete and the area has been remediated – with more than 50 tonnes of netting alone removed.
A Marshall Liberal Government will undertake a business case and develop detailed plans for a state-of-the-art Wine and Food Centre to be established in the Riverland.
Sporting participation in the Chaffey Electorate is set for a boost with a Marshall Liberal Government, if elected, doubling the current sports voucher value from $50 to $100.
The Weatherill Government's proposal for licensing and regulating the labour hire industry in South Australia has been opposed by the State Liberals in Parliament this week.
If passed, the legislation would require people who provide labour hire services to be licensed and face a 'fit and proper person test', amongst other draconian measures.
The State Liberals are demanding the Weatherill Government clears the backlog of prescribed burns in South Australia, ensuring the Riverland and Mallee are well prepared before another sweltering summer arrives.
During a recent Parliamentary Budget and Finance Committee hearing, the Environment Department revealed that only 38 per cent of prescribed burns were undertaken in autumn 2017 with just 20 of 53 prescribed burns completed across the state.
State Liberal Leader Steven Marshall will engage with the local community and industry with a focus on jobs and the economy during a visit to the Riverland this month, including a public forum to be held at the Berri Town Hall.
Hosted by Member for Chaffey Tim Whetstone, Mr Marshall has an extensive itinerary during the August 15 visit.


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The hefty wood home at rue Potagere 79, when you look at the multicultural neighbourhood of Saint-Josse-Ten-Noode in Brussels, opens on a full world of tranquil, religious retreat. The "Beguine convent of Dominican spirituality" of Bethel welcomes females looking for a life of community and faith, into the medieval tradition of Begijnhof or beguinage.
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Buick Enclave: Audio/Video (A/V) Jacks
A. Yellow: Video Input
B. White: Left Audio Input
C. Red: Right Audio Input
The A/V jacks are color coded to match typical home entertainment system equipment.
The A/V jacks, located on the rear of the floor console, allow audio or video signals to be connected from an auxiliary device such as a camcorder or a video game unit to the RSE system. Adapter connectors or cables (not supplied) might be required to connect the auxiliary device to the A/V jacks.
Refer to the manufacturer's instructions for proper usage.
Power for auxiliary devices is not supplied by the radio system.
To use the auxiliary inputs of the RSE system, connect an external auxiliary device to the color-coded A/V jacks and turn both the auxiliary device and the video screen power on. If the video screen is in the DVD player mode, pressing the AUX (auxiliary) button on the remote control switches the video screen from the DVD player mode to the auxiliary device. The radio can listen to the audio of the connected auxiliary device by sourcing to auxiliary. See Auxiliary Devices for more information.
Battery ReplacementTo change the batteries on the headphones: 1. Turn the screw to loosen the battery door located on the left side of the headphones. Slide the battery door open. 2. Replace the two batteries in th ...
How to Change the RSE Video Screen SettingsThe screen display mode (normal, full, and zoom), screen brightness, and setup menu language can be changed from the on screen setup menu by using the remote control. To change a setting: 1. Press ...
See also:
Fuels in Foreign Countries
Never use leaded gasoline or any other fuel not recommended in the previous text on fuel. Costly repairs caused by use of improper fuel would not be covered by the vehicle warranty. To check the ...
Gasoline Specifications (U.S. and Canada Only)
At a minimum, gasoline should meet ASTM specification D 4814 in the United States or CAN/CGSB-3.5 or 3.511 in Canada. Some gasolines contain an octane-enhancing additive called methylcyclopentadieny ...
Child safety
WARNING Do not allow children to play with the seat belts. Most seating positions are equipped with Automatic Locking Retractor (ALR) mode seat belts. If the seat belt becomes wrapped aroun ...


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Interview Etiquette What To Keep Away From Inquiring At An Job Interview... Information Number 8 Of 818
If you are requested by the recruiter to complete an application, take your time in filling it out. Even if the information requested already appears on the resume you have handed them, it still will make an impression if you go the extra step of filling it in again by hand.
When you are unemployed, life can be very difficult and you may feel very insecure until you have a new job. Put the insights you've gained here to work for you and move forward with https://penzu.com/public/2344fab2 confidence. Be persistent and positive, knowing that you will soon be back in the rat-race with a steady paycheck again.
If you plan to use current or former coworkers and supervisors as a business or personal reference, stay in touch. Maintaining contact with these people is important because it ensures that you have accurate, current information. Periodically verify your contacts' telephone numbers, mailing address, current place of employment and email address. Providing incorrect contact information to a potential employer may hurt your chances for success.
Send a thank you letter. A https://backforgood.faith/wiki/La_Contratacion_Publica_Administrativa_es_un lot of people don't do this, so if you use this one tip, you may put yourself ahead of the pack very quickly. Simply write a short letter thanking the person for their time, reiterating that you want the job, and reminding him or her of your unique qualifications.
When going into an interview, it is just as important to be polite and friendly to the receptionist as it is to be polite to the interviewer. You never know if the interviewer will ask the receptionist how your demeanor was toward them. It will make you look better if the receptionist says you were polite.
If you focus, you can find a job. The question is whether you'll find a job you want. That's why you need to use the information here. That way, you'll be desirable to any company who wants a good person to work with them. Use these tips and be strong!
Do not always trust jobs you see on the Internet. While certain sites are safe, other sites, such as Criagslist, have many scammers that not only are false employers, but are looking to take your money. The best way to go job hunting is by asking people you can trust or by going to establishments to ask if they are hiring.
Update your resume. You should always keep your resume current, even when you are not on the hunt for a job. You never know when an opportunity may present itself, so have a copy of your resume ready and available. It will also be easier to keep track of previous employment when you don't have to track down each bit of info as you need it.
Call your local colleges and universities and inquire about what sort of free job assistance they provide. They may have a job board listing local opportunities, resume writing help or even positions within the college they need to fill. They'll often have a variety of services for the benefit of students which they'll share with you.
Many people complain about their jobs, their bosses and colleagues until they end up with no job. Then they realize how lucky they were just to have a job! If you are unemployed don't worry, there is help available. Use this advice to do well in your interviews, so that you can get back to work.
Find out a little about the company you are interviewing with. Don't go in there blind. For starters, you may discover you don't want to be involved with anything they are doing, or you may be able to glean some nuggets that you can impress your interviewer with, so you appear to care about this particular company.
When you are applying for jobs, make sure that you have a list of three reliable references prepared for potential employers. Do not add friends or relatives to the list since they may not be aware of your work ethic. Good references include former supervisors, co-workers and your college classmates.
Jobs are not as plentiful as they once were. Therefore, you have to make yourself into a better candidate than you've ever been. You need to take job hunting very seriously, and you need to have some techniques that can help you. This article has some effective ways of going through your job search so you can be successful.
If you are an older job seeker, understand that you do not have to include the dates of your high school and college graduation or dates of courses you may have taken early in your career. Additionally, you do not have to list high school at all if you graduated from college. It is understood that you also have a high school diploma.
Meeting a potential employer in person is often much better than applying for a job online. licitacion publica definicion You should print some resumes and visit local businesses to ask if they are currently hiring. You will have the opportunity to talk to potential employers, ask questions and make a good first impression.
You should avoid being set on a single position. It might look promising, but anything can happen before you get the job. Continue to keep all your options open. If your job search is broadened, you have a better chance to secure a position.


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Job description
- Entry level
- No Education
- Salary to negotiate
- Hartford
Company Information
Solid reputation, passionate people and endless opportunities.
That's Travelers.
Our superior financial strength and consistent record of strong operating returns mean security for our customers
- and opportunities for our employees.
You will find Travelers to be full of energy and a workplace in which you truly can make a difference.
Job Summary
Under moderate supervision, works in collaboration with UX colleagues.
UX specialist partners with a collaborative, cross-functional team to research, design and usability test digital experiences.
This job does not manage others This job works under Moderate Supervision: Incumbent performs standard and routine assignments independently to conclusion; unusual problems which may require exceptions to procedures or processes are referred to the supervisor.
Primary Job Duties & Responsibilities
Advocates for user-centered design approaches and ensures adherence to UX guidelines at the project level.
Practices collaboration, experimentation, agility, and vigorous inquiry, while maintaining high standards and attention to detail.
Implements and provides feedback on UX best practices and objectives.
Serves as observer for, and may facilitate, UX research and testing efforts.
Helps conduct competitive research and analysis.
Translates research findings into design solutions.
Creates artifacts that include personas, journey maps, user workflows, information architecture, wireframes, and interactive prototypes, within project timelines and budgets.
Perform other duties as assigned.
Minimum Qualifications
Bachelor's degree in graphic design, psychology, human factors, social sciences or related field or 1 year of User Experience work experience required.
Education, Work Experience & Knowledge
Typical incumbent experience level 0-2 years (including prior internship experience).
Job Specific & Technical Skills & Competencies
Strong communication, organization, time management and interpersonal skills.
Familiarity or basic understating of web-based technologies.
Experience with wireframing / prototyping software preferred.
Familiarity with conducting end user interviews.
Environmental/Work Schedules/Other
Work Schedules Weekend work hours (Occasionally) Other Travel (Occasionally)
Physical Requirements
Operates standard office equipment (Continuously) Sitting (Can stand at will) (Continuously) Use of Keyboards, Sporadic 10-Key (Continuously) Driving (Occasionally)
Equal Employment Opportunity Statement
Travelers is an equal opportunity employer.
- architecture
- designer
- education
- ms project
- software


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10 Best Celebrity Engagement Rings of 2019 – Katy Perry, Kate Middleton's brother, Corrie stars……
We went on a mission to find the 10 best celebrity engagement rings of 2019 – plus gorgeous lookalike rings that you can shop RIGHT NOW!
We went on a mission to find the 10 best celebrity engagement rings of 2019 – plus gorgeous lookalike rings that you can shop RIGHT NOW!
We've gathered 23 stunning winter wedding ideas and tips to inspire you. Embrace the season's plushest colours, glittery decor, roaring log fires and snow.
What jewellery suits my dress? These 4 rules help you pick the right jewellery to match your dress shape and neckline – so you can create a stylish party look
If you're buying a women's diamond bracelet, it's a good idea to read this handy diamond bracelet buying guide. We tell you everything you need to know – including how to pick the best style, what diamonds to choose and how to measure your wrist. 1. Choose the right style If you're buying a bracelet for yourself, it's easy to choose the one you like. However, if you're buying a gift for someone, you should choose a style they love. Read our guide to buying jewellery as a gift for expert tips. 2. Decide between a bracelet and a bangle Bracelets: Traditionally, a bracelet is made with a linked or woven chain of metal. It has a clasp of some kind to attach it securely to your wrist. Bangles: A bangle is made from rigid metal. A join bangle has a join that opens and a clasp to close it, and a cuff bangle has an opening that you pass your wrist through to slip it on 3. How should a bracelet fit? A perfect chain …
What is sterling silver? We explain what it's made from, what to look for in sterling silver jewellery, how it compares to gold, and how to care for it.
11 tried and tested winter proposal ideas for snowy romance, Christmas and New Year. You cannot go wrong if you pop the question with one of these!
Best guide to buying rubies. Includes top 10 facts – to help you shop with confidence. Colour, cut, where to shop, and reading the jeweller's small print.
These 13 gorgeous pieces of black diamond jewellery for Halloween are so stylish you'll want to wear them all year round, not just on October 31st.
What colours do diamonds come in? Discover 5 best diamond colours – white, yellow, black, pink and brown – plus their characteristics, quality and prices.
Discover the 5 best jewellery gifts this autumn for her… or self-gift to keep your style chic and up to date! Pearls, statement rings, hoops and more.


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Certified Nurse Midwife - CNM - Downtown Denver
Saint Joseph Hospital, Denver, CO
A Certified Nurse-Midwife (CNM) provides full-scope care in the prenatal, intrapartum, post-partum and triage settings in both inpatient and outpatient settings from low to moderate risk patients in accordance with Clinical Practice Guidelines. Candidates must meet the criteria for Certified Nurse-Midwives as defined by the ESJH Medical Staff Bylaws, Clinical Rules and Medical Staff Rules and functions in accordance with the American College of Nurse-Midwives Standards for Nurse-Midwifery Practice. CNM's work in a collaborative relationship with attending physicians and residents from the ESJH OB/GYN Residency Program and the ESJH Family Practice Residency Program. Experience as faculty for medical students, residents and nurse-midwifery students is preferred. The practice works closely with ESJH nursing and ancillary staff to provide high-quality, satisfying care to patients and their families. CNM's participate in the ESJH outreach and community education to foster the Exempla Mission and promote business growth initiatives. In addition to the responsibilities described above, the role may include such other responsibilities and duties as assigned from time to time, based upon Exempla Healthcare needs or requirements.
Education Requirements:
- Graduate from an accredited school of nursing
- Bachelor's Degree in Nursing
- Master's Degree (Nursing, Public Health)
- Graduation from an ACNM or ACME accredited nurse-midwifery education program
- One year full-scope nurse-midwifery practice
Licensure & Certification:
- Current license to practice nursing in Colorado
- Registered as an Advanced Practice Nurse in Colorado
- Current ACNM Certification
- Current enrollment in the AMCB CCA or CMP
- Colorado Prescriptive Authority (provisional accepted)
- Current DEA Number
About the area
If you are a collaborative provider who puts patients first, you're an excellent fit for SCL Health's mission-based not-for-profit health ministry. You'll find you can deliver big-city medicine with high acuity throughout Denver's welcoming communities. Join us here at SCL Health, delivering holistic care that heals patients — mind, body and spirit.
Interested in joining us?
I would be happy to help you with any questions you might have about this position. You can apply online below or contact me, and I will get back in touch with you shortly.


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Guide To Buying table lamps Update* [[December 11, 2019]]
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