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The Tehachapi Valley Recreation & Park District may soon invite residents to public workshops to define improvements at Philip Marx Central Park, Meadowbrook Park, West Park and a possible community center in Sand Canyon. This will assist the district in applying for new state funding.
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The Kern County Board of Supervisors unanimously voted to increase entry-level sheriff's deputy pay by 18.5 percent at a meeting Tuesday in an attempt to stop deputies from leaving the Sheriff's Office at high rates.
Our Tehachapi branch of the Kern County Library has been putting on additional programs with events for children, teens and adults. These include: storytime for preschoolers, various teen fandom events, book clubs for adults and teens, painting events, and 3D printing workshops. All of these…
District 3 of the California State Old Time Fiddlers Association will hold its 10th Annual Amateur Old Time Fiddle Contest on Saturday, March 23, at Christian Life Assembly Church, 920 W. Valley Blvd. in Tehachapi. Registration for contestants will open at 8 a.m., and the actual contest will…
Spring is just around the corner, and the Summit Singers are preparing to celebrate this most beautiful season of the year with you. Their Spring Concert will be held Saturday, May 11, at the First Baptist Church on Curry Street. We hope you've already marked your calendar for this event, as…
Encompassing more than 275 square miles with a population of more than 36,880 people according to the 2010 census, the Greater Tehachapi area includes the City of Tehachapi as well as a number of unincorporated communities and areas within the 93561 ZIP code.
Visitor Guide: Introducing Tehachapi
People from all over California are moving to Tehachapi in search of a small-town feel, a high standard of living and the opportunity to live in "The Land of Four Seasons." The community welcomes visitors to stop and take a tour around downtown, enjoy the varied restaurants, stay for the fam…
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The Tehachapi Visitor Center made its downtown debut two years ago, but the enthusiasm of its volunteers parallels the first day it opened.

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Location: WA
Ahoy mateys and give a hearty welcome back to Captain!
Captain is a sweet five-year-old dog on wheels, and was adopted out earlier this year. But when his person ran into some rough waters, he returned to the safe harbor of the FBRN.
Once in our care, he has had the usual once-over and was diagnosed with cellulitis and a UTI. He was also underweight, with sores on his back legs and yeasty ears and skin.
He's in good hands, but still has a way to go before he's ship-shape. To sponsor Captain, click on his picture.
Megan Stevick
This is for poor, sweet Captain! I have never seen a sadder face on a pup. I wish I could give him some pets!! Channon Conner


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Cairo Knife Fight
By Jackie Cular
Nick Gaffaney and George Pajon Jr. are the duo known as Cairo Knife Fight, a rock bandfrom Christchurch, New Zealand known for its technical flare. Now settled in Los Angeles, the pair is currently touring Australia in support of their EP The Isolator. The band's sound clearly has international influences and appeal. See the new video for "Rezlord" if you're 18 or older. See the band's exclusive South by Southwest interview from Austin, Texas.


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Join us to kickoff Pablove Across America!
We're kicking off Pablove Across America with our friends at Whole Foods Market Prospect Street! Join us for a community breakfast courtesy of our sponsors at 8:00 am Saturday. Fuel up to cheer our riders on at 9:00 am as they depart for the 1000-mile ride to Raleigh!
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When June turns into July, it is highly anticipated that Atletico Madrid forward Antoine Griezmann will leave the club and complete his long-awaited move to Barcelona. It was mid-May when the French forward confirmed he would be leaving the capital club, with the Camp Nou widely spoken of as being his next destination.
On 1 July, the 28-year-old's release clause will drop from a whopping €200m to 'just' €120m – making him affordable for the world's leading clubs. His proposed transfer is not without its complications, with many members of Barca's squad said to be uncomfortable with signing a player who publicly rejected the switch just 12 months ago. Continue reading


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Podcast by Jennifer Jaden
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This film is part of Rentals
The Blair Witch Project
Three student filmmakers attempt to make a documentary about a local urban legend, in this terrifying and groundbreaking pioneer of the 'found-footage' genre.
Horror 1999 81 mins
Director: Eduardo Sanchez
Three student filmmakers attempt to make a documentary about a local urban legend, the 'Blair Witch' – but all that's left of them is the footage that comprises this film. Horror was never the same after this film, a pioneer of the 'found-footage' genre, and its groundbreaking marketing campaign convinced people (for a while) that the events depicted in it were true.
The Dead Don't Die The Dead Don't Die
Horror 2019 104 mins Director: Jim Jarmusch
Bill Murray, Adam Driver and Tilda Swinton lead this star-studded, bonkers addition to the zombie canon from cult director Jim Jarmusch.
Little Shop of Horrors Little Shop of Horrors
Comedy 1986 94 mins Director: Frank Oz
Frank Oz's vivid adaptation of the cult sci-fi musical, with Rick Moranis as a flower-shop assistant battling a 'Mean Green Mother from Outer Space'.
Werewolf Werewolf
Drama 2018 88 mins Director: Adrian Panek
Children liberated from a Nazi concentration camp have to overcome hunger, thirst and vicious dogs in this chilling postwar thriller.
The Wicker Man The Wicker Man
Horror 1973 88 mins Director: Robin Hardy
Christopher Lee and Edward Woodward star in the folk horror classic about a policemen investigating an island given over to paganism.
The Shining The Shining
Horror 1980 144 mins Director: Stanley Kubrick
Jack Nicholson revels in his terrifying performance as Jack Torrance, the would-be writer who becomes the minotaur trapped in Kubrick's supernatural maze.
Possum Possum
Horror 2017 85 mins Director: Matthew Holness
"Can you spy him deep within? Little Possum. Black as sin." The reliably deranged Sean Harris is plagued by an evil puppet in this dark, brooding fable from Matthew Holness.
Nineties Rentals
Remembrance of Things Fast Remembrance of Things Fast
Animation & Artists Moving Image 1993 62 mins Director: John Maybury
John Maybury's dark, queer state of the nation film starring Tilda Swinton and Rupert Everett
Eve's Bayou Eve's Bayou
Drama 1997 115 mins Director: Kasi Lemmons
Samuel L. Jackson stars in this seething slice of Southern Gothic, about the travails of a Louisiana family bedevilled by infidelity, incest and witchcraft.
Daughters of the Dust Daughters of the Dust
Drama 1991 112 mins Director: Julie Dash
Julie Dash's groundbreaking Daughters of the Dust remains urgent and poetic and continues to resonate, most recently inspiring Beyoncé's Lemonade.
Sixth Happiness Sixth Happiness
Biopic 1997 94 mins Director: Waris Hussein
Funny, acerbic and moving story of a young man's sexual awakening as family life crumbles around him.
Children of Heaven Children of Heaven
Comedy 1997 88 mins Director: Majid Majidi
Iranian siblings Ali and Zahra lose the latter's pair of shoes – but devise a plan to survive and obtain new ones in this family drama.
Live Flesh Live Flesh
Drama 1997 97 mins Director: Pedro Almodóvar
Pedro Almodóvar's sexy and suspenseful thriller follows the intertwining destinies of a cop (Javier Bardem) and the criminal who paralyses him.
Men of Hard Skin Men of Hard Skin
Drama 2019 95 mins Director: José Celestino Campusano
A history of abuse is uncovered in this provocative and challenging coming-of-age drama from Argentina.
Pin Cushion Pin Cushion
Drama 2017 82 mins Director: Deborah Haywood
Lyn (Joanna Scanlan) and Iona (Lily Newmark) are excited to be starting afresh in a new town, but trouble comes along when Iona becomes besties with the local mean girls.
Permission Permission
Drama 2018 88 mins Director: Soheil Beiraghi
Powerful and piercing story of an Iranian Futsal star who is refused permission from her husband to attend an international tournament.
The Amazing Johnathan Documentary The Amazing Johnathan Documentary
Documentary 2019 91 mins Director: Benjamin Berman
A fascinating documentary about the famed comic-magician John Edward Szeles as he makes a surprising comeback.
Jonathan Agassi Saved My Life Jonathan Agassi Saved My Life
Documentary 2018 106 mins Director: Tomer Heymann
The private life of a renowned gay porn legend is laid bare in this intimate and insightful documentary.
The Dead Don't Die The Dead Don't Die
Horror 2019 104 mins Director: Jim Jarmusch
Bill Murray, Adam Driver and Tilda Swinton lead this star-studded, bonkers addition to the zombie canon from cult director Jim Jarmusch.


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Social networking sites such as Facebook, Instagram, Twitter, MySpace etc. have all influenced the buzz of word of mouth marketing. In 1999, Misner said that word-of mouth marketing is, "the world's most effective, yet least understood marketing strategy" (Trusov, Bucklin, & Pauwels, 2009, p. 3).[79] Through the influence of opinion leaders, the increased online "buzz" of "word-of-mouth" marketing that a product, service or companies are experiencing is due to the rise in use of social media and smartphones. Businesses and marketers have noticed that, "a persons behaviour is influenced by many small groups" (Kotler, Burton, Deans, Brown, & Armstrong, 2013, p. 189). These small groups rotate around social networking accounts that are run by influential people (opinion leaders or "thought leaders") who have followers of groups. The types of groups (followers) are called:[80] reference groups (people who know each other either face-to-face or have an indirect influence on a persons attitude or behaviour); membership groups (a person has a direct influence on a person's attitude or behaviour); and aspirational groups (groups which an individual wishes to belong to).
Provide full functionality on all devices. Mobile users expect the same functionality - such as commenting and check-out - and content on mobile as well as on all other devices that your website supports. In addition to textual content, make sure that all important images and videos are embedded and accessible on mobile devices. For search engines, provide all structured data and other metadata - such as titles, descriptions, link-elements, and other meta-tags - on all versions of the pages.
Websites such as Delicious, Digg, Slashdot, Diigo, Stumbleupon, and Reddit are popular social bookmarking sites used in social media promotion. Each of these sites is dedicated to the collection, curation, and organization of links to other websites that users deem to be of good quality. This process is "crowdsourced", allowing amateur social media network members to sort and prioritize links by relevance and general category. Due to the large user bases of these websites, any link from one of them to another, the smaller website may in a flash crowd, a sudden surge of interest in the target website. In addition to user-generated promotion, these sites also offer advertisements within individual user communities and categories.[62] Because ads can be placed in designated communities with a very specific target audience and demographic, they have far greater potential for traffic generation than ads selected simply through cookie and browser history.[63] Additionally, some of these websites have also implemented measures to make ads more relevant to users by allowing users to vote on which ones will be shown on pages they frequent.[64] The ability to redirect large volumes of web traffic and target specific, relevant audiences makes social bookmarking sites a valuable asset for social media marketers.
Traditional advertising techniques include print and television advertising. The Internet has already overtaken television as the largest advertising market.[90] Web sites often include the banner or pop-up ads. Social networking sites don't always have ads. In exchange, products have entire pages and are able to interact with users. Television commercials often end with a spokesperson asking viewers to check out the product website for more information. While briefly popular, print ads included QR codes on them. These QR codes can be scanned by cell phones and computers, sending viewers to the product website. Advertising is beginning to move viewers from the traditional outlets to the electronic ones.[citation needed]
These posts can be one or more of the following: images, photo sets, animated GIFs, video, audio, and text posts. For the users to differentiate the promoted posts to the regular users' posts, the promoted posts have a dollar symbol on the corner. On May 6, 2014, Tumblr announced customization and theming on mobile apps for brands to advertise.[72]
In 2012 during Hurricane Sandy, Gap sent out a tweet to its followers telling them to stay safe but encouraged them to shop online and offered free shipping. The tweet was deemed insensitive, and Gap eventually took it down and apologized.[96] Numerous additional online marketing mishap examples exist. Examples include a YouTube video of a Domino's Pizza employee violating health code standards, which went viral on the Internet and later resulted in felony charges against two employees.[93][97] A Twitter hashtag posted by McDonald's in 2012 attracting attention due to numerous complaints and negative events customers experienced at the chain store; and a 2011 tweet posted by a Chrysler Group employee that no one in Detroit knows how to drive.[98] When the Link REIT opened a Facebook page to recommend old-style restaurants, the page was flooded by furious comments criticizing the REIT for having forced a lot of restaurants and stores to shut down; it had to terminate its campaign early amid further deterioration of its corporate image.[99]
Data-driven advertising: Users generate a lot of data in every step they take on the path of customer journey and Brands can now use that data to activate their known audience with data-driven programmatic media buying. Without exposing customers' privacy, users' Data can be collected from digital channels (e.g.: when customer visits a website, reads an e-mail, or launches and interact with brand's mobile app), brands can also collect data from real world customer interactions, such as brick and mortar stores visits and from CRM and Sales engines datasets. Also known as People-based marketing or addressable media, Data-driven advertising is empowering brands to find their loyal customers in their audience and deliver in real time a much more personal communication, highly relevant to each customers' moment and actions.[37]
Smartphone - In this document, "mobile" or "mobile devices" refers to smartphones, such as devices running Android, iPhone, or Windows Phone. Mobile browsers are similar to desktop browsers in that they can render a broad set of the HTML5 specification, although their screen size is smaller and in almost all cases their default orientation is vertical.
Shifting the focus to the time span, we may need to measure some "Interim Metrics", which give us some insight during the journey itself, as well as we need to measure some "Final Metrics" at the end of the journey to inform use if the overall initiative was successful or not. As an example, most of social media metrics and indicators such as likes, shares and engagement comments may be classified as interim metrics while the final increase/decrease in sales volume is clearly from the final category.
Notice that each of these accounts has a consistent voice, tone, and style. Consistency is key to helping your followers understand what to expect from your brand. They'll know why they should continue to follow you and what value they will get from doing so. It also helps keep your branding consistent even when you have multiple people working on your social team.
SEO is the discipline that allows people and websites to access the potential of the internet. It's about knowing when your site is the right result, and admitting to yourself when it is the wrong result. SEO is making your company and services more accessible to your prospective customers by studying what they need and creating the resources to serve them.
Creating the link between SEO and PPC represents an integral part of the SEM concept. Sometimes, especially when separate teams work on SEO and PPC and the efforts are not synced, positive results of aligning their strategies can be lost. The aim of both SEO and PPC is maximizing the visibility in search and thus, their actions to achieve it should be centrally coordinated. Both teams can benefit from setting shared goals and combined metrics, evaluating data together to determine future strategy or discuss which of the tools works better to get the traffic for selected keywords in the national and local search results. Thanks to this, the search visibility can be increased along with optimizing both conversions and costs.[21]
In-game advertising - In-Game advertising is defined as "inclusion of products or brands within a digital game."[49] The game allows brands or products to place ads within their game, either in a subtle manner or in the form of an advertisement banner. There are many factors that exist in whether brands are successful in their advertising of their brand/product, these being: Type of game, technical platform, 3-D and 4-D technology, game genre, congruity of brand and game, prominence of advertising within the game. Individual factors consist of attitudes towards placement advertisements, game involvement, product involvement, flow or entertainment. The attitude towards the advertising also takes into account not only the message shown but also the attitude towards the game. Dependent of how enjoyable the game is will determine how the brand is perceived, meaning if the game isn't very enjoyable the consumer may subconsciously have a negative attitude towards the brand/product being advertised. In terms of Integrated Marketing Communication "integration of advertising in digital games into the general advertising, communication, and marketing strategy of the firm"[49] is an important as it results in a more clarity about the brand/product and creates a larger overall effect.
Learn the steps of Internet analysis, if you want to learn Internet marketing for free. For anyone who knows the basics of social media, search engine optimization (SEO), Google news and website building blocks, then you can likely learn Internet marketing on your own. A big part of marketing is understanding your competitors, data and market analysis.
Often the line between pay per click advertising and paid inclusion is debatable. Some have lobbied for any paid listings to be labeled as an advertisement, while defenders insist they are not actually ads since the webmasters do not control the content of the listing, its ranking, or even whether it is shown to any users. Another advantage of paid inclusion is that it allows site owners to specify particular schedules for crawling pages. In the general case, one has no control as to when their page will be crawled or added to a search engine index. Paid inclusion proves to be particularly useful for cases where pages are dynamically generated and frequently modified.
Social media marketing provides organizations with a way to connect with their customers. However, organizations must protect their information as well as closely watch comments and concerns on the social media they use. A flash poll done on 1225 IT executives from 33 countries revealed that social media mishaps caused organizations a combined $4.3 million in damages in 2010.[93] The top three social media incidents an organization faced during the previous year included employees sharing too much information in public forums, loss or exposure of confidential information, and increased exposure to litigation.[93] Due to the viral nature of the Internet, a mistake by a single employee has in some cases shown to result in devastating consequences for organizations. An example of a social media mishap includes designer Kenneth Cole's Twitter mishap in 2011. When Kenneth Cole tweeted, "Millions are in uproar in #Cairo. Rumor has they heard our new spring collection is now available online at [Kenneth Cole's website]".[94] This reference to the 2011 Egyptian revolution drew an objection from the public; it was widely objected to on the Internet.[94] Kenneth Cole realized his mistake shortly after and responded with a statement apologizing for the tweet.[95]
Search engines attempt to rank results for a given search based on their relevance to the topic, and the quality and reliability a site is judged to have. Google, the world's most popular search engine, uses an ever-evolving algorithm that aims to evaluate sites in the way that a human reader would. This means that a key part of SEO involves ensuring that the website is a unique and relevant resource for readers.
We expect advertisements to be visible. However, you should not let the advertisements distract users or prevent them from consuming the site content. For example, advertisements, supplement contents, or interstitial pages (pages displayed before or after the content you are expecting) that make it difficult to use the website. Learn more about this topic.38
Another ethical controversy associated with search marketing has been the issue of trademark infringement. The debate as to whether third parties should have the right to bid on their competitors' brand names has been underway for years. In 2009 Google changed their policy, which formerly prohibited these tactics, allowing 3rd parties to bid on branded terms as long as their landing page in fact provides information on the trademarked term.[27] Though the policy has been changed this continues to be a source of heated debate.[28]


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I just played an ARAM game, and the matchmaking seemed way off. Their Team: Plat V Diamond V Gold II Diamond V Plat II. Our Team.
Table of contents
- Matchmaking for ARAM in League of Legends
- Support [email protected]
- Lol Matchmaking Aram – No Interracial Dating
Because ARAM now has matchmaking, people are punished for dodging, which discourages players from doing it. If you want casual fun, just click on the ARAM gametype and sit in queue for maybe half a minute. It's a much better experience just from that alone. However, the new ARAM mode also blind-picks teams, meaning you don't know what the other team randomly rolled. Before, if the enemy team had some really dominating character like Nidalee, someone would generally dodge. Now you don't know, and that is kind of a nice change.
Matchmaking for ARAM in League of Legends
It is "all random," after all, and part of "all random" means sometimes the RNG picks Jayce. Additionally, if you get a champion you don't like, the new ARAM mode includes a reroll mechanic that allows you to change your character!
- match making relationship?
- The Summoner's Guidebook: Playing LoL's new ARAM mode.
- Log In to GameFAQs.
You build points toward rerolls by playing ARAM games; you build these points more quickly if you have more characters in your roster since you're more likely to get someone you don't want. In practice, you seem to get a reroll about once every 3 to 6 games, so you do still have to play with the spirit of "all random. You can store up to two rerolls at a time, which forces you to think a bit about them but still lets you save up if you have a lot of good picks in a row. This helps curb dodging even more, since there's a mechanic in place to allow you to avoid playing characters you really don't like.
Just as in all other modes, you can also swap characters with your team. Recently, I had an interesting situation where I got Janna, whom I was pretty happy with. I accepted the trade and spent a reroll, since I had my second reroll almost fully charged. I got Yorick, whom I am also pretty happy with.
However, our Sivir player saw that I got Yorick and asked me to trade, which I was more than happy to do, as I really like Sivir.
Support [email protected]
Another time though, our Master Yi player traded him away for Sona, then rerolled her. We lost that game. A little pro tip: Don't reroll if you have Sona, ever. Statistically influencing random behaviors Naturally, like anything I do in any game ever, I think of ways to game the system. The ARAM game mode has plenty of ways to exploit little advantages. My champion roster is not especially large. I own around 40 characters, which is a fairly small roster for someone who has been playing League for over a year.
Because my roster is kind of small, it doesn't work as well for ARAM; I get fewer rerolls than someone with a bigger roster. Additionally, my roster is heavily diluted by the free week champions.
Of course, there's a way to game the system a bit. I went to the shop and looked for low-hanging fruit -- champions who are good or decent in ARAM, like Annie, whom I don't own yet yes, I played League for well over a year without unlocking her , and picked them up for low cost. This helps pad my roster so the free week champions are less likely. At the same time, it also gives me more rerolls since my roster is bigger.
Of course, people who bought champion packs are basically hosed. Aren't all games made by matching? And I have RP but whats the point of spending it on this if i can just win it somehow? I have gotten one about every other game so far, so just play more matches and you will get some. As of patch 6.
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A fix is planned to be released in the next patch. By clicking "Post Your Answer", you acknowledge that you have read our updated terms of service , privacy policy and cookie policy , and that your continued use of the website is subject to these policies. Home Questions Tags Users Unanswered. What is considered a matchmade game in LoL?
Lol Matchmaking Aram – No Interracial Dating
The article i posted in that link above says: ARadish ARadish 1 1 6. Dragonrage although according to the Patch 6.
Fixing that is on our list of things that need to be done before we can consider Hextech Crafting fully launched, and we're working on a solution for an upcoming patch. ARadish more like, "if they aren't bot games or custom games, then they can drop keys. Sign up or log in Sign up using Google. Sign up using Facebook.


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How can I remove the bar from WordPress backoffice?
Since the latest update of Woocommerce, while using the backoffice in WordPress, there's an annoying Woocommerce bar that always appears on the upper part of the screen.
The bar has 3 buttons: inbox, orders and stock.
Is it possible to remove this bar?
How can I do it?
Thanks in advance.
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PETALING JAYA: For slightly over RM100 per guest, would-be sugar daddies can attend a party scheduled to take place in Kuala Lumpur as part of the official launch of thesugarbook.com website.
The announcement of the private party, tagged as "where romance meets finance", which had gone viral on social media, raised eyebrows, resulting in the management of the top city entertainment outlet, where the event was scheduled, to cancel its booking.
It is learnt that the entertainment outlet had called off the event, which was scheduled for April 27, as it had been involved as the venue for a controversial product launch event by a celebrity entrepreneur three weeks ago.
Its management was worried the party, which has a sexual connotation, could put the company in a spot again.
However, thesugarbook.com founder and chief executive officer Darren Chan said the show would go on but at a different venue.
"It has been called off but not cancelled. We are negotiating with several posh entertainment outlets in the city to host the event.
"We have yet to firm up the new venue. It will be announced later," he said.
Thesugarbook.com is Asia's first sugar daddy dating site.
Unlike other dating sites, the website, which was launched in December 2016, is known for its money-for-love dating platform.
It marketed itself as a site to link up "well-established wealthy individuals" who "wish to pamper sugar babies with financial support in return for love and companionship" and those who "appreciate the glamorous life indulging in the luxuries that life has to offer".
Chan said the party was only for 250 people.
The website also stated that there were no charges for women, who are referred to as sugar babies, to attend the party.
However, men have to pay to attend the party.
Individual ticket costs between RM100 and RM150. The organiser of the event is also selling tables for the event.
A table costs between RM1,700 and RM3,500 for a specific number of people.
MCA Public Services and Complaints Department head Datuk Seri Michael Chong said women attending the party should be careful.
"They should use their judgement when meeting and making friends at such parties," he said.
Chong said they should go to the event with their eyes wide open.
Kuala Lumpur police chief Comm Datuk Seri Mazlan Lazim said police were aware of the party and were monitoring the event.
"Action will be taken if the organiser or the event breaks any law," he said.
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Lithium Patents (Class 423/179.5)
Patent number: 10443111Abstract: The present invention provides a method for removing iron from an iron-containing solution containing an iron ion, comprising adding a lithium ion battery cathode material containing manganese to an acidic sulfuric acid solution to obtain a cathode material-containing solution, and then precipitating a manganese ion as manganese dioxide in a mixed solution obtained by mixing the iron-containing solution with the cathode material-containing solution while precipitating the iron ion contained in the iron-containing solution as a solid.Type: GrantFiled: March 29, 2016Date of Patent: October 15, 2019Assignee: JX NIPPON MINING & METALS CORPORATIONInventors: Junichi Arakawa, Junichi Ito, Takuya Yokota
Patent number: 10439200Abstract: The present invention relates to the extraction of lithium from liquid resources such as natural and synthetic brines, leachate solutions from clays and minerals, and recycled products.Type: GrantFiled: August 1, 2018Date of Patent: October 8, 2019Assignee: LILAC SOLUTIONS, INC.Inventors: David Henry Snydacker, Alexander John Grant, Ryan Ali Zarkesh
Patent number: 10333183Abstract: Examples are disclosed of methods to recycle positive-electrode material of a lithium-ion battery. One example provides a method including relithiating the positive-electrode material in a solution comprising lithium ions and an oxidizing agent, and after relithiating, separating the positive-electrode material from the solution.Type: GrantFiled: January 9, 2017Date of Patent: June 25, 2019Assignee: Hulico LLCInventor: Steven E. Sloop
Patent number: 10280083Abstract: A method for producing complexed particles including obtaining a good solvent solution, by dissolving Li2S, and LiX (X is at least one selected from a group consisting of F, Cl, Br, and I) in a good solvent, and precipitating particles by contacting the good solvent solution with a poor solvent having a temperature at least 165° C. higher than the boiling point of the good solvent, to evaporate off the good solvent. The method further satisfies at least one of the following: (i) the good solvent solution being obtained by further dissolving H2S in the good solvent, and (ii) H2S being dissolved in the poor solvent.Type: GrantFiled: November 27, 2017Date of Patent: May 7, 2019Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventor: Takuo Yanagi
Method for producing lithium carbonate from low-lithium brine by separating magnesium and enriching lithiumPatent number: 10246341Abstract: The present invention discloses a method for producing lithium carbonate from a low-lithium brine by separating magnesium and enriching lithium. A salt-lake brine is used as a raw material and is converted into halide salts through dehydration by evaporation and separation by crystallization; the halide salts are directly extracted using trialkyl phosphate or a mixture of trialkyl phosphate and monohydric alcohol, and an organic extraction phase as well as remaining halide salts are obtained after solid-liquid separation; reverse extraction is performed on the organic extraction phase to obtain a lithium-rich solution with a low magnesium-to-lithium ratio, and lithium carbonate is obtained after concentration and removal of magnesium by alkalization. The used solid-liquid extraction method is simple with no co-extraction agent used, and a solute distribution driving force is strong, unaffected by phase equilibrium of the brine extraction agent.Type: GrantFiled: October 21, 2017Date of Patent: April 2, 2019Assignee: XIANGTAN UNIVERSITYInventors: Lixin Yang, Mi Fu, Yi Wang, Hongyu Qi, Yu Xu, Yali Liu, Yalin Gui, Jing He
Patent number: 10177365Abstract: The fabrication of robust interfaces between transition metal oxides and non-aqueous electrolytes is one of the great challenges of lithium ion batteries. Atomic layer deposition (ALD) of aluminum tungsten fluoride (AlWxFy) improves the electrochemical stability of LiCoO2. AlWxFy thin films were deposited by combining trimethylaluminum and tungsten hexafluoride. in-situ quartz crystal microbalance and transmission electron microscopy studies show that the films grow in a layer-by-layer fashion and are amorphous nature. Ultrathin AlWxFy coatings (<10 ?) on LiCoO2 significantly enhance stability relative to bare LiCoO2 when cycled to 4.4 V. The coated LiCoO2 exhibited superior rate capability (up to 400 mA/g) and discharge capacities at a current of 400 mA/g were 51% and 92% of the first cycle capacities for the bare and AlWxFy coated materials.Type: GrantFiled: April 22, 2015Date of Patent: January 8, 2019Assignee: UChicago Argonne, LLCInventors: Anil U. Mane, Jeffrey W. Elam, Joong Sun Park, Jason R. Croy
Patent number: 10150056Abstract: The present invention relates to the extraction of lithium from liquid resources such as natural and synthetic brines, leachate solutions from minerals, and recycled products.Type: GrantFiled: November 13, 2017Date of Patent: December 11, 2018Assignee: LILAC SOLUTIONS, INC.Inventor: David Henry Snydacker
Patent number: 10096821Abstract: An object of the present invention is to provide a lithium secondary battery that has a lithium nickel phosphate compound in the positive electrode, is free of collapse of the crystal structure even at high potentials and is resistant to cycle deterioration. The lithium secondary battery according to the present invention has a positive electrode active material. This positive electrode active material contains a lithium nickel phosphate compound that is represented by the general formula LiNi(1-x)MnxPO4 (wherein 0<x?0.15) and that has an orthorhombic crystal structure belonging to space group Cmcm.Type: GrantFiled: May 2, 2011Date of Patent: October 9, 2018Assignee: Toyota Jidosha Kabushiki KaishaInventor: Jun Yoshida
Patent number: 10090519Abstract: An electrochemical cell includes a cathode including an early transition metal fluoro-bronze; an anode including magnesium metal; and an electrolyte; wherein: the early transition metal fluoro-bronze is configured for intercalation of magnesium ions.Type: GrantFiled: April 20, 2015Date of Patent: October 2, 2018Assignees: UCHICAGO ARGONNE, LLC, NORTHWESTERN UNIVERSITYInventors: Kenneth Poeppelmeier, John T. Vaughey, Jared Incorvati, Lindsay Fuoco
Benzocrown ether graft polymer with lithium isotopic separation effect and preparation method thereofPatent number: 9988466Abstract: Disclosed in the present invention is a benzocrown ether graft polymer with a lithium isotopic separation effect and a preparation method thereof. The polymer is a benzocrown ether graft polymer formed by the linkage of chemical bonds, which takes the main chain of a polymer containing chloromethyl group, chloroformyl group or hydroxyl group as main chain, and takes a benzocrown ether as pendant group.Type: GrantFiled: February 2, 2015Date of Patent: June 5, 2018Assignee: TIANJIN POLYTECHNIC UNIVERSITYInventors: Jianxin Li, Feng Yan, Benqiao He, Hong Wang
Patent number: 9988280Abstract: A process for reducing the amount of magnesium in a lithium-containing brine by adding an aqueous solution of KCl to the brine to precipitate at least some of the magnesium as carnallite salt is disclosed. Lithium salts prepared using this magnesium removal process are also disclosed.Type: GrantFiled: February 22, 2016Date of Patent: June 5, 2018Assignee: ROCKWOOD LITHIUM INC.Inventors: Andrew John Donaldson, Daniel Alfred Boryta
Patent number: 9963760Abstract: Provided is a backflow cascade novel process for producing a lithium-7 isotope. The process comprises an upper backflow section, an extraction section, an enrichment section, a lower backflow section, and a product acquiring section. Upper backflow phase-conversion liquid and lower backflow phase-conversion liquid are respectively added to the upper backflow section and the lower backflow section, and upper backflow phase-conversion liquid and lower backflow phase-conversion liquid of the lithium material are controlled; the product is precisely acquired in the product acquiring section; an organic phase is added to the upper backflow section, and is recycled in the lower backflow section. By means of cascade connection with a high-performance liquid separator, environmental protection, high efficiency, and multi-level enrichment of the lithium-7 isotope are achieved, and a high-abundance lithium-7 isotope product is obtained.Type: GrantFiled: March 28, 2014Date of Patent: May 8, 2018Assignee: Shanghai Institute of Organic Chemistry, Chinese Academy of SciencesInventors: Jinbo Hu, Wei Zhang, Weiqin Zheng, Guanghua Chen, Xiao Shi, Yongchang Xu, Honggui Lv, Chengye Yuan
Patent number: 9890053Abstract: There are provided methods for preparing lithium carbonate. For example, such methods can comprise reacting an aqueous composition comprising lithium hydroxide with CO2 by sparging the CO2 the said composition, thereby obtaining a precipitate comprising the lithium carbonate. The methods can also comprise inserting at least a portion of the precipitate into a clarifier and obtaining a supernatant comprising lithium bicarbonate and a solid comprising the lithium carbonate, separating the solid from the supernatant; and heating the supernatant at a desired temperature so as to at least partially convert the lithium bicarbonate into lithium carbonate.Type: GrantFiled: June 23, 2016Date of Patent: February 13, 2018Assignee: NEMASKA LITHIUM INC.Inventors: Guy Bourassa, Gary Pearse, Stephen Charles Mackie, Mykolas Gladkovas
Patent number: 9748616Abstract: Lithium metal oxides may be regenerated under ambient conditions from materials recovered from partially or fully depleted lithium-ion batteries. Recovered lithium and metal materials may be reduced to nanoparticles and recombined to produce regenerated lithium metal oxides. The regenerated lithium metal oxides may be used to produce rechargeable lithium ion batteries.Type: GrantFiled: August 20, 2014Date of Patent: August 29, 2017Assignee: University of CalcuttaInventor: Nilanjan Deb
Method for the hydrometallurgical recovery of lithium, nickel and cobalt from the lithium transition metal oxide-containing fraction of used galvanic cellsPatent number: 9702024Abstract: A method for the hydrometallurgical recovery of lithium from a lithium transition metal oxide containing fraction of used galvanic cells is disclosed. According to the method, the lithium transition metal oxide containing fraction is introduced into sulphuric acid or hydrochloric acid, and hydrogen peroxide is added in an amount that is at least stoichiometric relative to the transition metal content to be reduced of the lithium transition metal oxide-containing fraction.Type: GrantFiled: October 9, 2013Date of Patent: July 11, 2017Assignee: Rockwood Lithium GmbHInventors: David Wohlgemuth, Mark Andre Schneider, Rebecca Spielau, Johannes Willems, Martin Steinbild
Patent number: 9694344Abstract: Provided is a novel continuous single-step method of manufacturing a multilayer sorbent polymeric membrane having superior productivity, properties and performance. At least one layer of the polymeric membrane comprises sorbent materials and a plurality of interconnecting pores. The method includes: (a) coextruding layer-forming compositions to form a multilayer coextrudate; (b) casting the coextrudate into a film; (c) extracting the film with an extractant; and (d) removing the extractant from the extracted film to form the multilayer sorbent polymeric membrane. The sorbent membrane of this disclosure can find a wide range of applications for use in filtration, separation and purification of gases and fluids, CO2 and volatile capture, structural support, vehicle emission control, energy harvesting and storage, device, protection, permeation, packaging, printing, and etc.Type: GrantFiled: May 2, 2016Date of Patent: July 4, 2017
Method for the hydrometallurgical recovery of lithium from the fraction of used galvanic cells containing lithium, iron and phosphatePatent number: 9677153Abstract: A method for the hydrometallurgical recovery of lithium from the fraction of used galvanic cells containing lithium, iron and phosphate is disclosed. According to the method, lithium-iron-phosphate-containing fraction is introduced into sulfuric acid and/or hydrochloric acid, and hydrogen peroxide is added in an amount that is at least stoichiometric relative to the iron content to be oxidized of the lithium-iron-phosphate-containing fraction.Type: GrantFiled: October 9, 2013Date of Patent: June 13, 2017Assignee: Rockwood Lithium GmbHInventors: David Wohlgemuth, Mark Andre Schneider, Rebecca Spielau, Johannes Willems, Martin Steinbild
Patent number: 9562303Abstract: A mixed oxide containing a) a mixed-substituted lithium manganese spinel in which some of the manganese lattice sites are occupied by lithium ions and b) a boron-oxygen compound. Furthermore, a process for its preparation and the use of the mixed oxide as electrode material for lithium ion batteries.Type: GrantFiled: November 16, 2015Date of Patent: February 7, 2017Assignee: Johnson Matthey PLCInventors: Christian Vogler, Gerhard Nuspl, Margret Wohlfahrt-Mehrens, Peter Axmann, Gisela Arnold
Patent number: 9306213Abstract: To provide a process for producing a cathode active material for a lithium ion secondary battery, a cathode for a lithium ion secondary battery, and a lithium ion secondary battery. A production process which comprises contacting a lithium-containing composite oxide containing Li element and a transition metal element with a composition (1) {an aqueous solution containing cation M having at least one metal element (m)} and a composition (2) {an aqueous solution containing anion N having at least one element (n) selected from the group consisting of S, P, F and B, forming a hardly soluble salt when reacted with the cation M}, wherein the total amount A (mL/100 g) of the composition (1) and the composition (2) contacted per 100 g of the lithium-containing composite oxide is in a ratio of 0.1<A/B<5 based on the oil absorption B (mL/100 g) of the lithium-containing composite oxide.Type: GrantFiled: December 24, 2013Date of Patent: April 5, 2016Assignee: Asahi Glass Company, LimitedInventors: Kentaro Tsunozaki, Haisheng Zeng, Takeshi Kawasato
Patent number: 9284626Abstract: The invention relates to a method for purifying impure lithium bicarbonate by means of a cation exchange resin. In addition to solution purification by ion exchange, the treatment stages include the regeneration of impurity metals bound to the resin. Regeneration consists of washing the resin with water, elution with acid solution, washing with water, neutralization with alkali solution and washing with water. It is characteristic of the method that neutralization is performed with sodium hydroxide solution.Type: GrantFiled: March 1, 2010Date of Patent: March 15, 2016Assignee: Outotec OyjInventor: Marika Tiihonen
Patent number: 9255012Abstract: A method and arrangement for recovering lithium carbonate from a raw material containing lithium, which method comprises pulping (1) the raw material containing lithium in the presence of water and sodium carbonate for producing a slurry containing lithium from the raw material containing lithium. After pulping the lithium-containing slurry is leached (2) for dissolving the lithium in the solution thus producing a solution containing lithium carbonate. After pulping and leaching the method comprises carbonating (3) the solution containing lithium carbonate by using carbon dioxide under atmospheric conditions for producing a solution containing lithium bicarbonate and separating (4) the solids form the solution. The solution containing lithium bicarbonate is purified (5) to produce a purified solution containing lithium bicarbonate, and recovering by crystallizing (6) lithium carbonate from the purified lithium bicarbonate-containing solution.Type: GrantFiled: March 19, 2013Date of Patent: February 9, 2016Assignee: Outotec (Finland) OyInventors: Marika Tiihonen, Liisa Haavanlammi
Patent number: 9255011Abstract: The present invention relates to a method for producing lithium carbonate, which is important as a raw material of a lithium ion battery and the like, from brine resources. More specifically, the invention relates to a method for producing lithium carbonate, in which carbon dioxide gas obtained by calcining limestone is introduced, in the presence of ammonia, into a concentrated brine, which is prepared from a lithium-containing brine as a raw material through an evaporative concentrating step, a desulfurizing step and an electrodialysis step, thereby depositing lithium carbonate crystals, and the crystals thus deposited are recovered through solid-liquid separation.Type: GrantFiled: November 29, 2012Date of Patent: February 9, 2016Assignees: NITTETSU MINING CO., LTD., TOYO ENGINEERING CORPORATION, SUMITOMO CORPORATIONInventors: Masanobu Kawata, Hirohumi Tanaka, Kohei Mitsuhashi, Ryo Kawarabuki, Youichi Yamamoto, Keita Kamiyama, Atsushi Moriya, Norifumi Sakai
Patent number: 9243308Abstract: The apparatus for recovering Lithium comprises: a supply unit (1) in which lithium-containing water is passed through a filter membrane to yield lithium solution; an adsorption unit (2) in which said solution adsorb the lithium in a column; an elution unit (3) by which hydrochloric acid elute the lithium in the column, yielding a lithium elute containing hydrochloric acid and lithium chloride; a cleaning unit (4) by which the column is washing; a condensing unit (5) in which the lithium elute is circularly vaporized, and the vapor is condensed to yield concentrated lithium chloride solution; a collecting unit (6) in which sodium carbonate is added to lithium chloride solution to collect the lithium as concentrated lithium solution; and a hydrochloric acid recycling unit (7) in which the residue from lithium chloride solution is cooled to yield the hydrochloric acid as used in the elution unit (3).Type: GrantFiled: October 19, 2012Date of Patent: January 26, 2016Inventor: Haruo Uehara
Patent number: 9169125Abstract: Disclosed is a method for producing high-purity lithium carbonate. The method includes: removing magnesium and boron from a brine; separating and removing the remaining magnesium and calcium; concentrating the resulting brine by spray drying to form a powder; washing the powder to concentrate lithium; and carbonating the lithium ions with sodium carbonate (Na2CO3).Type: GrantFiled: December 2, 2011Date of Patent: October 27, 2015Assignee: KOREA RESOURCES CORPORATIONInventors: Dong Jun Kang, Mi Hee Yoon, Jeon Woong An
Publication number: 20150147248Abstract: The invention relates to a process for producing a lithium-containing solution from a lithium-containing raw-material solution, by: a) precipitating a first part of magnesium and calcium from the lithium-containing raw-material solution, b) extracting a second part of calcium and magnesium from the lithium-containing solution by liquid-liquid extraction, a resultant product being a lithium-containing solution. The invention also relates to equipment for producing a lithium-containing solution from a lithium-containing raw-material solution, including a precipitation unit to remove a first part of magnesium and calcium and an extraction unit to receive the lithium-containing raw-material solution and to remove therefrom a second part of calcium and magnesium by liquid-liquid extraction, and control unit to control the operation of the precipitation unit.Type: ApplicationFiled: June 4, 2013Publication date: May 28, 2015Applicant: OUTOTEC (FINLAND) OYInventors: Hannu Laitala, Janne Karonen, Liisa Haavanlammi
Publication number: 20150140332Abstract: The present invention relates to a process for preparing high-purity lithium fluoride proceeding from lithium carbonate, and to lithium fluoride having a preferred morphology.Type: ApplicationFiled: May 23, 2013Publication date: May 21, 2015Inventors: Matthias Boll, Wolfgang Ebenbeck, Eberhard Kuckert
Publication number: 20150132202Abstract: This invention relates to a method for preparing a lithium activated alumina intercalate solid by contacting a three-dimensional activated alumina with a lithium salt under conditions sufficient to infuse lithium salts into activated alumina for the selective extraction and recovery of lithium from lithium containing solutions, including brines.Type: ApplicationFiled: October 31, 2014Publication date: May 14, 2015Inventors: Stephen Harrison, C. V. Krishnamohan Sharma, M. Scott Conley
Patent number: 9005557Abstract: A process for reducing the amount of magnesium in a lithium-containing brine by adding an aqueous solution of KCl to the brine to precipitate at least some of the magnesium as carnallite salt is disclosed. Lithium salts prepared using this magnesium removal process are also disclosed.Type: GrantFiled: October 28, 2011Date of Patent: April 14, 2015Assignee: Rockwood Lithium Inc.Inventors: Andrew John Donaldson, Daniel Alfred Boryta
Method for Manufacturing Lithium Hydroxide and Method Using Same for Manufacturing Lithium CarbonatePublication number: 20150071837Abstract: The present invention relates to a method of manufacturing lithium hydroxide and a method of manufacturing lithium carbonate using the same. The method of manufacturing lithium hydroxide includes: preparation of a lithium phosphate aqueous solution including lithium phosphate particles; addition of a phosphate anion precipitation agent to the lithium phosphate aqueous solution; and precipitating a sparingly soluble phosphate compound through a reaction of cations of the phosphate anion precipitation agent with anions of the lithium phosphate.Type: ApplicationFiled: December 27, 2012Publication date: March 12, 2015Inventors: Uong Chon, Im Chang Lee, Ki Young Kim, Gi-Chun Han, Chang Ho Song, So Ra Jung
Patent number: 8932545Abstract: A method is provided for the synthesis of a mesoporous lithium transition metal compound, the method comprising the steps of (i) reacting a lithium salt with one or more transition metal salts in the presence of a surfactant, the surfactant being present in an amount sufficient to form a liquid crystal phase in the reaction mixture (ii) heating the reaction mixture so as to form a sol-gel and (iii) removing the surfactant to leave a mesoporous product. The mesoporous product can be an oxide, a phosphate, a borate or a silicate and optionally, an additional phosphate, borate or silicate reagent can be added at step (i). The reaction mixture can comprise an optional chelating agent and preferably, the reaction conditions at steps (i) and (ii) are controlled so as to prevent destabilization of the liquid crystal phase. The invention is particularly suitable for producing mesoporous lithium cobalt oxide and lithium iron phosphate.Type: GrantFiled: October 19, 2009Date of Patent: January 13, 2015Assignee: Qinetiq LimitedInventors: Gary Owen Mepsted, Emmanuel Imasuen Eweka
Publication number: 20140377154Abstract: To provide a lithium recovery method which is capable of efficiently recovering lithium without containing impurities, such as phosphorus and fluorine. In the present invention, an alkali is added to a discharge liquid and/or a cleaning liquid containing lithium discharged in a process of recovering valuable metals from a lithium ion battery, an acidic solvent extractant is caused to be in contact with the discharge liquid and/or the cleaning liquid under a condition of pH 9 or less and a temperature of 0 to 25° C. and lithium ions are extracted, and the acidic solvent extractant having extracted the lithium ions is caused to be in contact with an acid solution of pH 3 or less and the lithium ions are stripped.Type: ApplicationFiled: February 3, 2012Publication date: December 25, 2014Applicant: SUMITOMO METAL MINING CO., LTD.Inventors: Hitoshi Ishida, Satoshi Asano
Publication number: 20140348734Abstract: A method of extracting lithium from a lithium bearing solution and specifically, economically extracting lithium from a lithium bearing solution comprising the steps of: adding a nucleus particle to a lithium bearing solution; and precipitating the dissolved lithium in the lithium bearing solution as lithium phosphate by adding a phosphorous supplying material to the lithium bearing solution including the nucleus particle is provided.Type: ApplicationFiled: December 10, 2012Publication date: November 27, 2014Inventors: Uong Chong, Ki Young Kim, Gi-Chun Han, Chang Ho Song, Young Seok Jang, Kee-Uek Jeung, So Ra Jung
Publication number: 20140334997Abstract: Disclosed are methods for a simplified process for preparing lithium carbonate from concentrated lithium brine which can be used for battery grade, pharmaceutical and other high purity grade applications. Impure lithium carbonate is precipitated from lithium concentrated brine, preferably lowered in magnesium, subsequently suspended in aqueous solution and reacted with carbon dioxide to form dissolved lithium bicarbonate. The insoluble impurities are filtered and the dissolved boron and metal impurities such calcium, magnesium and iron are physically separated from the lithium bicarbonate solution using ion selective mediums or other selective processes. Lithium carbonate is then subsequently precipitated.Type: ApplicationFiled: September 15, 2011Publication date: November 13, 2014Applicant: OROCOBRE LIMITEDInventors: Peter Ehren, Jose De Castro Alem
Patent number: 8877690Abstract: A method of treating a wastewater is provided and can be used, for example, to treat a gas well production wastewater to form a wastewater brine. The method can involve crystallizing sodium chloride by evaporation of the wastewater brine with concurrent production of a liquor comprising calcium chloride solution. Bromine and lithium can also be recovered from the liquor in accordance with the teachings of the present invention. Various metal sulfates, such as barium sulfate, can be removed from the wastewater in the production of the wastewater brine. Sources of wastewater can include gas well production wastewater and hydrofracture flowback wastewater.Type: GrantFiled: August 31, 2011Date of Patent: November 4, 2014Assignee: ProChemTech International, Inc.Inventor: Timothy Edward Keister
Method for manufacturing positive active material for rechargeable lithium battery and rechargeable lithium battery using samePatent number: 8877382Abstract: A method for preparing a positive active material for a rechargeable lithium battery includes: a) providing a furnace and a crucible that is included in the furnace; b) putting a mixture of a composite metal precursor and a lithium compound into the crucible; and c) preparing a positive active material for a rechargeable lithium battery by firing the mixture in the crucible, wherein during the process b), the mixture in the crucible is positioned so that a minimum distance from a predetermined position inside the mixture to an exterior of the mixture in the crucible is about 5 cm or less. A rechargeable lithium made by this method is disclosed.Type: GrantFiled: May 24, 2011Date of Patent: November 4, 2014Assignee: Samsung SDI Co., Ltd.Inventors: Min-Han Kim, Do-Hyung Park, Seon-Young Kwon, Yu-Mi Song, Ji-Hyun Kim, Kyoung-Hyun Kim
Publication number: 20140322110Abstract: Provided are continuous methods and processes for removing Li ions from an aqueous feed solution.Type: ApplicationFiled: November 1, 2012Publication date: October 30, 2014Applicant: ADVANCE LITHIUM PROJECTS LTD.Inventors: Jonathan Lipp, Baruch Grinbaum
Publication number: 20140301922Abstract: This invention relates to a method for the preparation of lithium carbonate from lithium chloride containing brines. The method can include a silica removal step, capturing lithium chloride, recovering lithium chloride, supplying lithium chloride to an electrochemical cell and producing lithium hydroxide, contacting the lithium hydroxide with carbon dioxide to produce lithium carbonate.Type: ApplicationFiled: April 21, 2014Publication date: October 9, 2014Applicant: Simbol Inc.Inventor: Stephen Harrison
Patent number: 8852452Abstract: A lithium transition metal oxide powder for use in a rechargeable battery is disclosed, where the surface of the primary particles of said powder is coated with a LiF layer, where this layer consists of a reaction product of a fluorine-containing polymer and the primary particle surface. The lithium of the LiF originates from the primary particles surface. Examples of the fluorine-containing polymer are either one of PVDF, PVDF-HFP or PTFE. Examples of the lithium transition metal oxide are either one of —LiCodMeO2, wherein M is either one of both of Mg and Ti, with e<0.02 and d+e=1; —Li1+aM?1?aO2±bM1kSm with ?0.03<a<0.06, b<0.02, M? being a transition metal compound, consisting of at least 95% of either one or more elements of the group Ni, Mn, Co and Ti; M1 consisting of either one or more elements of the group Ca, Sr, Y, La, Ce and Zr, with 0?k?0.1 in wt %; and 0<m<0.6, m being expressed in mol %; and —LiaNixCOyM?zO2±eAf, with 0.9<a?<1.1, 0.5?x?0.9, 0<y?0.4, 0<z?0.35, e<0.Type: GrantFiled: October 19, 2010Date of Patent: October 7, 2014Assignee: UmicoreInventors: Jens Paulsen, Randy De Palma, HeonPyo Hong, KyuBo Kim
Recovery and synthesis method for metaloxidic cathodic active material for lithium ion secondary batteryPatent number: 8835026Abstract: Disclosed are a recovery for a metaloxidic cathodic active material for a lithium ion secondary battery and a synthesis thereof by the recovery method, wherein the recovery method includes (a) dissolving a cathodic active material from a waste lithium ion secondary battery using sulfuric acid solution containing sulfurous acid gas to generate a solution containing metal ions, (b) injecting sodium hydroxide solution and ammonia solution in the solution containing the metal ions to fabricate an electrode active material precursor, and (c) filtrating the active material precursor, followed by drying and grinding, thus to fabricate a solid-state cathodic active material precursor, and the synthesis method is achieved by mixing the electrode active material precursor fabricated according to the recovery method with lithium carbonate or lithium hydroxide, followed by heat treatment, to generate a metaloxidic cathodic active material.Type: GrantFiled: January 27, 2011Date of Patent: September 16, 2014Assignee: Korea Institute of Science and TechnologyInventors: Kyung Yoon Chung, Hwa Young Lee, Byung-Won Cho
Publication number: 20140227153Abstract: The invention relates to a method for recycling lithium batteries and more particularly batteries of the Li-ion type and the electrodes of such batteries.Type: ApplicationFiled: September 5, 2012Publication date: August 14, 2014Applicant: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENE ALTInventors: Richard Laucournet, Sandrine Barthelemy, Nathalie Diaferia
Publication number: 20140227154Abstract: This invention relates to a method for the preparation of lithium carbonate from lithium chloride containing brines. The method can include a silica removal step, capturing lithium chloride, recovering lithium chloride, supplying lithium chloride to an electrochemical cell and producing lithium hydroxide, contacting the lithium hydroxide with carbon dioxide to produce lithium carbonate.Type: ApplicationFiled: April 21, 2014Publication date: August 14, 2014Applicant: Simbol Inc.Inventor: Stephen Harrison
Patent number: 8795614Abstract: The present invention relates to a method of economical extraction of magnesium, boron and calcium, while minimizing the loss of lithium, from a lithium bearing solution. More specifically, the present invention provides a method for economical extraction of magnesium, boron, and calcium, while minimizing the loss of lithium, from a lithium bearing solution comprising the steps of: (a) adding an alkali in the lithium bearing solution to precipitate magnesium hydroxide; (b) absorbing boron ions on the surface of the magnesium hydroxide by adjusting the pH to about 8.5 to about 10.5; and (c) simultaneously extracting magnesium and boron by filtering the magnesium hydroxide absorbed with the boron ions from the lithium bearing solution.Type: GrantFiled: January 8, 2013Date of Patent: August 5, 2014Assignee: Research Institute of Industrial Science & TechnologyInventors: Uong Chon, Gi Chun Han, Ki Hong Kim, Chang Ho Song, Ki Young Kim
Patent number: 8778289Abstract: The present invention relates to a method of extracting lithium from a lithium bearing solution. More specifically, the present invention provides a method of economical extraction of lithium from a lithium bearing solution by adding a phosphorous supplying material to the solution to precipitate lithium phosphate from the dissolved lithium.Type: GrantFiled: January 8, 2013Date of Patent: July 15, 2014Assignee: Research Institute of Industrial Science & TechnologyInventors: Uong Chon, Oh Joon Kwon, Ki Hong Kim, Chang Ho Song, Gi Chun Han, Ki Young Kim
Patent number: 8753594Abstract: This invention relates to a method for preparing a lithium aluminate intercalate (LAI) matrix solid and methods for the selective extraction and recovery of lithium from lithium containing solutions, including brines. The method for preparing the LAI matrix solid includes reacting aluminum hydroxide and a lithium salt for form the lithium aluminate intercalate, which can then be mixed with up to about 20% by weight of a polymer to form the LAI matrix.Type: GrantFiled: November 12, 2010Date of Patent: June 17, 2014Assignee: Simbol, Inc.Inventors: John L. Burba, III, Ray F. Stewart, Brian E. Viani, Stephen Harrison, Christine Ellen Vogdes, John Galil Salim Lahlouh
Patent number: 8691169Abstract: It is possible to produce battery grade metallic lithium from naturally occurring or industrial brine by a process comprising the following steps: (i) precipitating magnesium with calcium hydroxide; (ii) removal of boron via extraction of solvents; (iii) precipitation of lithium with sodium carbonate; (iv) transformation of lithium carbonate to bicarbonate of lithium with carbonic acid; (v) decomposition of bicarbonate of lithium into high purity lithium carbonate as a result of heating of the solution. Re-precipitation of lithium carbonate by the formation of bicarbonate of lithium allows for the removal of the majority of contaminants which co-purify with lithium carbonate and yield battery grade highly purified lithium carbonate.Type: GrantFiled: September 26, 2012Date of Patent: April 8, 2014Inventors: Waldo Perez, Hugo Adan Carlos Barrientos, Claudio Suarez, Marcelo Bravo
Patent number: 8679428Abstract: The present disclosure provides a method of preparing highly pure lithium carbonate from brine. The method includes adding an adsorbent to the brine, from which the magnesium ions Mg2+ have been removed, to adsorb lithium ions Li+ to the adsorbent, followed by providing the adsorbent having the lithium ions Li+ adsorbed thereto to a strong acid solution to desorb the lithium ions Li+ from the adsorbent; enriching the strong acid solution in which the lithium ions Li+ are desorbed from the adsorbent; and obtaining lithium carbonate Li2CO3 through chemical reaction between the lithium ions Li+ in the enriched solution and a carbonate precursor.Type: GrantFiled: October 12, 2011Date of Patent: March 25, 2014Assignee: Korea Institute of Geosciences and Mineral Resources (KIGAM)Inventors: Joon-Soo Kim, Kyeong-Woo Chung, Jin-Young Lee, Sung-Don Kim
Publication number: 20140044622Abstract: A process for reducing the amount of magnesium in a lithium-containing brine by adding an aqueous solution of KCl to the brine to precipitate at least some of the magnesium as carnallite salt is disclosed. Lithium salts prepared using this magnesium removal process are also disclosed.Type: ApplicationFiled: October 16, 2013Publication date: February 13, 2014Applicant: Rockwood Lithium Inc.Inventors: Andrew John Donaldson, Daniel Alfred Boryta
Mixed material of lithium iron phosphate and carbon, electrode containing same, battery comprising such electrode, method for producing such mixed material, and method for producing batteryPatent number: 8647777Abstract: Disclosed is a mixed material of lithium iron phosphate and carbon, which contains secondary particles as aggregates of lithium iron phosphate primary particles and a fibrous carbon which is present inside the secondary particles. An electrode containing such a mixed material, a battery comprising such an electrode, a method for producing such a mixed material, and a method for producing a battery are also disclosed.Type: GrantFiled: October 13, 2006Date of Patent: February 11, 2014Assignee: GS Yuasa International Ltd.Inventors: Yoshinobu Yasunaga, Tokuo Inamasu, Akihiro Fujii, Toshiyuki Nukuda
Processes for Preparing Highly Pure Lithium Carbonate and Other Highly Pure Lithium Containing CompoundsPublication number: 20140037521Abstract: The invention generally relates to methods of selectively removing lithium from various liquids, methods of producing high purity lithium carbonate, methods of producing high purity lithium hydroxide, and methods of regenerating resin.Type: ApplicationFiled: October 3, 2013Publication date: February 6, 2014Applicant: Simbol Inc.Inventors: Stephen Harrison, Robert Blanchet
Patent number: 8641992Abstract: There is disclosed herein a process for recovering lithium from an impure natural or industrial brine, the process comprising adjusting the pH of a feed brine containing lithium to a value of no less than 11.3 and separating the waste solids and a solution containing lithium values. The solution may be further concentrated and treated to obtain lithium carbonate and a lithium chloride solution suitable for obtaining electrolytic grade lithium chloride.Type: GrantFiled: July 15, 2009Date of Patent: February 4, 2014Assignee: ADY Resources LimitedInventors: Daniel Ernesto Galli, Demetrio Humana, Maria de las Mercedes Otaiza, Claudia del Rosario Cachagua, Rene Enrique Santillan


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René van der Klooster is multifaceted. Besides an author of poetry and plays (in Dutch and English) and prose (in Dutch), he practices visual arts, including drawing, painting and sculpting, moreover, formerly he worked as an architect and in that capacity he is currently designing lamps. The writing and the arts mainly originate from a vast dream world, a certain grip on the subconsciousness and frequent pre mystical and mystical experiences.
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In 2017 he was with nine works a participant of the exhibition Beeldenstorm in the Abbey of Middelburg in the Netherlands.
In October 2019 he exhibited five works of art, w11, w12, w13, w22, w29, at the Art Shopping Carrousel du Louvre, Paris, represented by Mona Youssef Gallery.
Forty of his works are published on ArteLagunaWorld/ArteLagunaPrize 2019/2020: René van der Klooster artist from St-Annaland, Netherlands …
Recently two of his poems are published, his poem The Road is published in Universal Oneness, An Anthology of Magnum Opus Poems, in India. His poem The Lamb is published in VerbalArt, a global journal devoted to poets and poetry, also in India.
René van der Klooster lives and works in The Netherlands.


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As part of his official visit to Armenia, Russian Minister of Foreign Affairs Sergey Lavrov visited the Tsitsernakaberd Armenian Genocide Memorial in Yerevan.
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- Last On:
9days 20 hours ago
Hey, YT, guess what? I tried!
As of last week, Walmart has been cutting overtime, and I'm okay with it because if it we're for management, I'd never be allowed to go home. It's only me and two other employees who get singled out every. f*cking. night to pick up everyone else's slack. I am sick and tired, so to speak, of staying hours past my shift while everyone else VANISHES 15 minutes before their shift is scheduled to end. Management is aware of this and does f*ck all about it.
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KLEE Application Form 2020 - CEE, Thiruvananthapuram will accept KLEE 2020 application form, tentatively form the first week of May, 2020 onwards. KLEE application form 2020 will be available only in online mode at the official website of the Commissioner for Entrance Examinations, Kerala. Candidates looking for admissions in law colleges of Kerala will have to apply through the application form of KLEE 2020. Filling up the online application form of KLEE 2020 will include steps like, online registration, filling the personal, educational details, uploading documents and fee payment etc. The application form of KLEE 2020 must be filled carefully, as any incorrect information, or incomplete application form will be rejected by the conducting body. To know about the procedure to fill KLEE application form 2020, important dates, and other exam related information, read the complete article below.
Kerala Law Entrance Exam will be conducted tentatively in the second week of June, 2020. Admissions will be offered in 3-year LLB or 5-year integrated LLB courses in 4 government law colleges and some other self financing law institutes of Kerala.
Dates (Tentative)
Issue of notification
First week of May 2020
Start of filling application form
Last date to apply
Third week of May 2020
KLEE 2020 exam date
Second week of June 2020
While applying for KLEE 2020, candidates will have to keep some data and documents along with them. The conducting body has given a list of documents that candidates will have to upload at the time of filling the application form of KLEE 2020
Scanned copies of marksheets and certificates of qualifying exam.
Candidate's photograph and signature in prescribed format.
Nativity proof
Age certificate (HSLC or birth certificate)
Cast certificate and community certificate (if applicable)
Income certificate
Candidates will have to apply online through the official website of CEE; The application form of KLEE will be filled in the 5 steps given below.
Step 1 - Registration
Visit the official website; www.cee.kerala.gov.in.
Select the course for which you are applying (3-year LLB or 5-year LLB)
Click on 'apply online'
Register by using a valid email id and mobile number and create a password.
Click on 'Confirm' link to complete registration.
On successful registration, candidates will receive an 'application form number' at the registered mail address.
Step 2 - Fill the application form
Login using application form number and password.
Select any three exam centres in the order of preference.
Enter your personal details such as name, address, contact information, educational qualification,category etc.
Check that all the data provided by you is correct.
Click on 'submit and finalize'
Candidates should note that the data provided here will be used for admission process, any incorrect information provided here may lead to disqualification of candidate. So, it is advised to take utmost care while filling out the application form, as the conducting body will not allow any modifications to application form once it is submitted.
Step 3 - Fee payment
After filling the application form, candidates will have to pay the prescribed application fee. The conducting body has provided two modes for fee payment; online mode and E-challan mode
KLEE 2020 - Application form fee
Fee amount to be paid
Online mode
Click on 'pay application fee'.
The online payment gateway will open in a new tab.
Candidates can pay using debit card/credit card/net-banking method.
E-challan method
After clicking on 'pay application fee', select e-challan mode for fee payment.
Take print - out of e-challan by clicking on 'print e-challan'
Pay the fee in cash at any of the Head and Sub Post Offices in Kerala.
Handover the e-challan along with the fee amount at post office counters of Head and Sub-Post Offices in Kerala
Candidates are advised to check their payment status after submitting the application fee.
Step 4 - Upload images and certificates
Upload a passport size studio generated photo and signature.
Upload all necessary documents in pdf format, the size of file should be between 10 - 30 kb.
Photo and signature specifications
15 - 30 kb
10 - 30 kb
KLEE Application form 2020 - Documents to be uploaded
Cast certificate (if applicable)
Age certificate (Birth certificate of HSLC certificate)
Certificate in case of special reservation
Any other documents mentioned in the notification.
Step 5 - Print application form
Candidates are advised to take print out of application form by clicking on 'Print Confirmation Page'. The soft copy of application form will be used during the admission process.
The conducting body will release admit card of KLEE 2020 for successfully registered candidates. KLEE admit card 2020 will be released tentatively in the first week of June, 2020. The admit card of KLEE 2020 will inform about the exam centre, date and time, candidate's roll number and other exam related information. It will be mandatory for all applicants to carry KLEE admit card to the exam centre.
In such a case, you should immediately contact the concerned post office and get the payment status updated.
No, you don't have to send the confirmation page to the CEE office. Keep it safe for future reference.
There are two UG law programmes namely; 5-year LLB and 3-year LLB.
As of 2019, there are 1295 seats in 5-year LLB courses and 625 seats in 3-year LLB programme offered by all participating colleges.
You will have to submit your e-challan and the fee amount at a nearby post office in Kerala to pay application fee.
KLEE Result 2020 will be released tentatively in fourth week of June, 2020. KLEE 2020 result will...
KLEE Answer Key 2020 - CEE will release KLEE 2020 answer key tentatively in the second week of Ju...
KLEE 2020 - CEE will conduct KLEE 2020 for admissions to 3-year LLB and 5-year LLB. KLEE 2020 app...
KLEE Admit card 2020 - CEE, Kerela will release admit card of KLEE 2020 applicants respectively f...
KLEE Important Dates 2020 - CEE Kerala will release KLEE 2020 important dates including notificat...
Hello Farzana,
The official dates are not yet announced. But the exam for 5 year LLB course will be conducted on 8th June, 2020 and for 3 year LLB the exam will be conducted of 9th June, 2020. Both the dates are tentative which means they are subjected to change after the official announcement. The application process may start from last week of April, 2020 which is also tentative.
You can check new updated information by using the link below
Your KLEE brochure has been successfully mailed to your registered email id .
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