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hi heroes here with Sun science org and let's talk about the Capricorn woman in the cancer man the relationship between the Capricorn woman in cancer man is a supportive one the female goat is solid and reliable and the male crab is dedicated and intuitive she can help to keep his emotions in check while he helps her to appreciate all the beauty in life although she is in our sign-in he is a water sign the Capricorn cancer pairing creates a beautiful lake rather than muddy waters the different their differences are complementary where the Capricorn woman creates a strong foundation off of which to build their relationship and the cancer mad cancer man adds the emotional depth to sustain it the Capricorn female works hard all day and comes home to the comfort comfortable household that he is established he helps her to relax and enjoy the finer things in life things she would never have noticed without his keen eye and she listens and aids in calming his emotional outbursts when he's having a rough day since both the Capricorn and cancer um work hard to take care of different aspects of their relationship there is an automatic balance in their daily routine and with her patients in his caring nature this couple will have no problem moving things into the bedroom because both Sun signs take their time with decisions they will both be ready to build their sexual union the cancer male will start things off with a slow romantic courtship nothing too fancy just the basics to get them in the mood he knows she's not into mind games or fantasies so he keeps it genuine with affectionate gestures and simple foreplay the Capricorn woman appreciates him into detail and offers him a steady devoted partner even though she doesn't experience their lovemaking on the same emotional plane she shows him how much she cares in her own way his loyalty matches hers and that helps to strengthen their love bond the cancer man will do anything for his lover which can sometimes work in his favor and other times not but her planning does come in handy outside the bedroom with her ambition and his persistence this relationship can go further than either zodiac sign to match impossible the Capricorn woman likes to take the reins when it comes to the responsibilities and he doesn't mind but she knows the cancer man also pitches in to do whatever is necessary to keep things running smoothly and she can trust him to handle anything she misses and they divvy up each other's deep and they divvy up details that may require a gentler touch which the cancer man can take care of easy anything more serious in the Capricorn woman steps in to handle it with that kind of harmony their relationship is smooth and free of drama and this is important for both these star signs the Capricorn woman is not as invested in the actual act as he is so she may come off cold or distant at times this can be alarming for the cancer man for he needs reassurance at all as well she will have to focus on being in the moment with him rather than looking off into the future the only thing they will have to watch out for is her detached manner the Capricorn female may hurt his feelings from time to time and he will retreat into his shell for a while and his ever-changing feelings may annoy her on occasion but the rest of the time this is a lovely match indeed in conclusion Capricorn is a cardinal or Sun wears cancer is a cardinal water sign the Capricorn woman cancer man compatibility gets a 1 hearts rating the Capricorn woman cancer man love compatibility will succeed only if both the partners have the patience to list to each other I'm Vera Rose with Sun science org please visit Sun sign store for more articles and videos and don't forget to like and share us with your friends thank you you
6 thoughts on "Capricorn Woman Cancer Man – Be Patient & Supportive"
Only 17 and my girl crazy asf
a while before I was reborn (christian reborn in the leo period in 2010) in 2008 a man with Sun in Cancer( and I had Sun in cancer) Had a obsession towards me, I had to flee for my life, it was a terror, he was a son of satan, abusive, obsessive a control freak and he abused me..he was the worst possible version or one of the worst of a man with sun in cancer
Hahahaa! True. My spouse (now 40 yrs old) and I have been together for almost 24 years… married for 16 years.
We do quarrel from time to time. But we are very much still in love with one another. We still stay up late to chitchat and cuddle. He is loving, nurturing and loyal (thank goodness) But he is super sensitive. Ack!
He loves holding my hand even while dining (although I find it ridiculous) at times. And our teenage sons would tease us from time to time 😂
Capricorn women are crazy im a Cancer im 2 nice with it


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BLACKPINK's Hairstyles and Colors in 2019
2019 may be an epic year for Blackpink because of their increasing popularity and recognition. In fact, Blackpink has entered the European music market and successfully topped a number of charts there, becoming a highly anticipated Korean idol group. Blackpink fever has plagued various Asian and European countries, proving that the group's hard work has been paying off.
Lisa changed her hair color again to blonde, but unlike 2017, this time the blonde color on Lisa's hair is slightly mixed with gray, so that the color is not too bright or not too flashy.
Jisoo appeared a little bolder by changing her hair color to red in 2019 for the comeback with Let's Kill This Love. With hair like this, Jisoo looks very mature and sexy and shows a brave aura. Netizens are very impressed with how Jisoo looks with the red hair..
Jennie managed to surprise everyone because she changed her entire hair color to blonde for Blackpink's latest comeback teaser, Let's Kill This Love. Previously, Jennie's hairstyle was not too flashy, she only used brown and gray to be her flagship colors, but in 2019 she changed for a platinum blonde which made her look sexy and elegant.
Rose also changed the color of her hair, a little brighter blonde color mixed with a little brown so that she looks more radiant. With hairstyles like this, many netizens say Rose looks very mature and elegant compared to the previous looks.
Well, what do you think about that? Which one hair style that suits with Blackpink's members?
Blackpink Latest News
DJ Snake Collaboration with Blackpink Soon!
As we have seen before, Blackpink has entered the European market, as well as being famous in Asia. On May 14, 2019, a fan asked DJ Snake via Instagram, "Will you make a song with Blackpink?" He's short, yet exciting, answer was "Yes."
Well, let's wait for that! Are you guys feeling excited?

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Constituency Question – North East Rail
My constituency question is to the Minister for Public Transport. After years of problems with rail services to the Northern Victorian region, we have now learnt again that only 69% of V Line train services on the North East Line arrived on time in January; and only 88% of train services were even delivered at all, with 22 trains cancelled completely. I wish to ask the Minister for the latest update on progress on the North East Line Upgrade?


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Fort Bragg will operate on a reduced manning status Thursday, as it awaits the impact of Hurricane Dorian.
Post officials announced Wednesday that adverse weather personnel, including contractors, will report to work as directed by their supervisors or chains of command.
Fort Bragg supports a total population of more than 280,000 that includes more than 51,000 troops and more than 14,000 civilians.
All service members need to contact their commanders for guidance.
As of 3 p.m. Wednesday, officials expected Hurricane Dorian's "overall impacts to Fort Bragg," to be increased, based on National Hurricane Center data, officials said.
Officials said the Department of Defense Education Activity schools at Fort Bragg will close Thursday, and are expected to open during normal hours Friday unless "the weather drastically changes."
"We are working closely with our installation partners," said Jade Fulce, a spokeswoman for the agency.
If a decision is made about Friday, it will be announced on the DoDEA Americas Facebook page, Fulce said.
All Family and Morale, Welfare and Recreation facilities and services, including child development centers and child youth services, will be closed Thursday, except for for Callahan gym.
To further reduce the need to have service members and civilian security guards work during Hurricane Dorian, eight of Fort Bragg's access control points will remain open Thursday.
Those include: Chicken Road, Yadkin Road, Longstreet Road, All American, Simmons Airfield, Honeycutt Road and Randolph Street.
Womack Army Medical Center's Emergency Department will remain open, along with inpatient care, officials said.
The center's urgent care clinic will be open from 7:30 a.m. to 7 p.m. Thursday, and the Womack Family Medicine Residency Clinic will operate as a walk-in clinic from 7:30 a.m. to 4 p.m.
Officials said outlying and specialty care clinics will be closed Thursday, and information can be tracked online or through Womack Army Medical Center's Facebook page.
The North and South Post Commissaries and Exchanges will be closed, but Old Glory Express, at the corner of Reilly and Gruber roads, will be open from 6 a.m. until 10 p.m.
Officials said all of the 82nd Airborne Division's dining facilities will remain open Thursday, except for Victory.
Power outages in barracks and other non-housing buildings should be reported by calling 910-396-0321, and backed up water should be reported by calling the same number.
Residents are asked to report power outages and maintenance emergencies to the Corvias Work Order Hotline at 866-206-1365.
"We are asking the community to take the time to help clear debris from the streets. Please move debris to a location where it will not flow back into drainage systems," officials said.
Staff writer Rachael Riley can be reached at firstname.lastname@example.com or 910-486-3528.
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recettes gateaux de Choumicha: madeleine au chocolat onjour tout le monde, qui Desserts. 1 Confiture d'abricots. Other. 80 g R beurre fondu puis mis a. There is always a room for dessert Souvenir de Casablanca, birthday party # choumicha #shadahassoun #maroc #كويت #عراق #مغرب #اخوة Choumicha: Cuisses de Poulet à la Sauce Barbecue. I love making a sugar free dessert where no one can tell. A great Saturday. Ouvrir. More information.
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I also post my full food diary on Instagram https: This roast vegetable and couscous salad could easily be Topped with olives that I spend the night surreptitiously stealing. So I obviously volunteered to make the little verrines.
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Accompanied by a tomato sauce where boiled carrots and potatoes, red peppers and olives stewed for a long time, the final result was astounding. Well in this particular case, the taste was exquisite.
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Let's Make Dinner with Choumicha !
Previous Post Next Post. Fine g couscous 2 tbsp sunflower oil ml milk pinch of salt 80g currants 3 tbsp sugar 3 tbsp chopped almonds Decoration: Their cooking workshop is still a thing of beauty, the table setting was once again exquisite, and the event was sponsored by the cute girly team of Dalaa.
A wee video of how to make choumucha favourite ever slimming world breakfast! She made a menu designed for moms to be, healthy and full of flavors. With all my unhealthy pregnancy cravings recently, it was time to whip up something a tad healthier! Please hit the like button and subscribe for future updates.
Please remember that the best Learn how to prepare 3 recipes of Couscous on Udemy, here's a discount coupon fro just 9. How that was yum. Couscous is so easy to make, check out this simple deasert for a delicious couscous with almonds, dates, raisins, and pistachios.
Boju coming thru with the juice. Coconut flakes, your favorite nuts, more Next were the main dish which was a revelation.
And it was awesome. Step-by-step video on how to steam couscous using a traditional couscous pot.
Recette Roulé imprimé aux fraises | Choumicha | Pinterest | Birthdays and Youtube
Stare at the beauty. Sweet Couscous with Nuts and Dried Fruit Sugar syrup may be made in bulk and used when Did I nail it or what? The best sweet couscous Sweet Couscous With Fruit Couscous is a type of North African semolina made from crushed durum wheat. A delightful evening surrounded by beautiful people and making amazing food. You expect to have a crunchy bite and it turns out to be a soft one.
The starters were a combination of eggplants caviar and sardine rillettes on toasted bread.
Semolina, which is coarsely ground wheat, is mixed with flour, pressed and then Easy Recipes with Tuc Crackers. Ingredients 1 c couscous. You can also serve them steamed with some soy sauce. Makes a great breakfast or special dessert.


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"Night for Neil" Fundraiser Aims to Erect Statue
Supporters are conducting another fundraiser to have a statue of Chillicothe High School grad Neil Johnston erected in front of Hatton Memorial Gym.
Johnston was a 1946 graduate of CHS, who went on to a great NBA career and is in the Naismith National Basketball Hall of Fame in Springfield, Mass.
"A Night for Neil", will take place at the Chillicothe Elks Hall the evening of September 29th. The fundraiser plans to raise $50,000 for a statue.
Organizer Jhan Corzine says the event will be catered by Spaghetti Warehouse and ticket information for the September 29th event can be found on the "Night for Neil" Facebook page.


text:
- This event has passed.
The Rose Tattoo
October 15
Event Navigation
Nearly 50 years after the play's stage debut, Academy Award-winning actress Marisa Tomei and Emun Elliot (Game of Thrones), co-star in the Broadway revival of Tennessee Williams' The Rose Tattoo. This dramatic tale, which was adapted for film in 1955, follows the weary life of an Italian-American mother who has become distraught and disconnected from the world following the tragic death of her husband.
Opens October 15th
Related Events


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All weekend long, Amplitude Studios' games are free to play. The more we play them, the more, cool new content we unlock, too! Check out this site for more details: https://www.amplitude-freeweekend.com/ The other great news is that Endless Space 1 is now free forever. That will now make it an EASY recommendation to anyone looking … Continue reading Amplitude Studios' Free Weekend
Tag: Endless Space 2
Let's eXamine Endless Space 2: Penumbra
Join me as I provide a short overview of the upcoming "Umbral Choir" eXpansion to Endless Space 2, Penumbra! Yet another perk of being an Amplitude VIP member, I've been playing this a bit (though not as much as I'd like) and can share with you guys a general understanding of the gameplay mechanics that … Continue reading Let's eXamine Endless Space 2: Penumbra
My Most Anticipated 4X Expansions
As a companion piece to my "Most Anticipated 4X Games" article I wrote last weekend, I figured I'd also highlight the expansions to existing 4X games that I know about and talk about them a bit. First, to be clear, I only can confidently list a few expansions, but there are also a few that … Continue reading My Most Anticipated 4X Expansions


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Download Primera y Segunda de Corinitos ebook free
Type: ebook pdf, ePub, fb2, DjVu, txt, Mobipocket
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¡Jesús, SÍ! ¡Iglesia, NO! Esta es la actitud de muchos hoy. Todas las iglesias tienen problemas. Pero considere el caos de los corintios: División-cada grupo en la iglesia exaltaba a su líder favorito 1 Co 1-4. o-un hombre vivía con su madrastra 1 Co 5. Litigios-un creyente estafó a otro, y los dos… read more >>>
As a pedagogical tool, such a summation and a "further reading" list would have made what is already a wonderful book even more useful to the general reader. I'm currently taking an EMT course and this is definitely the handbook of it all.
Sie beschließt, seinem merkwürdigen Verhalten auf den Grund zu gehen und kommt einem uralten Geheimnis auf die Spur …So geheimnisvoll und romantisch wie Romeo und Julia. I had heard that some people found diagramming sentences fun, Primera I often hoped Primera y Segunda de Corinitos could learn how, and that I might enjoy it also.
Goudge was awarded the Carnegie Medal for The Little White Horse (1946), a book which JK Rowling, author Corinitos the Harry Potter series, lists among her childhood favourites. I am not sure whether the story will have withstood the test of Segunda since it Corinitos a very different world in the early 60's.
When we fully realize the potential of specific interventions to help clients arrive at certain outcomes, then we can choose these interventions and techniques with greater skill and confidence. Perkins, and Theodore Roosevelt. In terms of the text, it's okay, although condensed and assumes that you've either gotten the info somewhere else, or will.
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"If I had money, I would be happier. " This sets the tone and while it may not lend itself to mundane personal facts and observations, it allows the writer to focus on Corinitos and primary influences regarding his "education.
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An award-winning teacher, he has also published extensively about the Primera past. Prior to joining the department as a Lecturer in Modern European History in 2012, Christopher Dillon taught at the University of London's Birkbeck, Queen Mary, and Goldsmiths colleges.
Primera y Segunda de Corinitos Lesen ist somit erschwert, da Wortstellungen ungewohnt sind und ein Segunda des Primera y Segunda de Corinitos stark von der Muttersprache abweicht. It is well-written and put together in such a way that it doesn't feel like a traditional history textbook, but rather the opener for a broader discussion about the Renaissance.
… useful for researchers and investigators who would like to understand the application of statistical principles in clinical trials. Otherwise, it might put you off which, despite Twain's arguments to the contrary, is still a shame.
When does temptation become sin. Siedenberg é Administrador (UNIJUÍ), com Mestrado em Planejamento Regional (Universität KarlsruheAlemanha) e Doutorado em Geografia Econômica (Universität TübingenAlemanha).
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5.3.1 The node
Euralille is a development centred on a complex transport interchange that includes two railway stations: Lille-Flandres (currently with TGV services to Paris and regional trains) and Lille-Europe (with international HST services). In the transport node, the following converge: high-speed lines (in the three directions of Brussels, Paris and London), conventional trains, the underground, rapid trams, buses, through roads, and a motorway bypass (Figure 5.2).
Thanks to the TGV, Lille is just 1 hour from Paris (53 minutes from Roissy Airport), and will be 25 minutes from Brussels and 2 hours from London. Before the TGV these times were 2 hours 7 minutes, 1 hour 30 minutes, and 4 hours 45 minutes respectively. In 1995, 70 000 passengers a day passed through Lille Flandres and 8000 through Lille-Europe. In the first quarter of 1997, on an average weekday, 45 000 passengers used the TER (Train Express Regional) and 13500 the TG
The transport infrastructure that had to be built (a programme now virtually completed) included the new TGV line and station, a new metro underground line and station, a new rapid-tram stop, the reconstruction of the motorway bypass next to the TGV line, a new road viaduct, and underground parking providing a total of 6100 places
The place
The development site of Euralille lies in between peripheral, lower-density neighbourhoods and the historical centre of Lille (Figure 5.3). Lille itself is a city of just 168 000 inhabitants, but it is also the core of a truly polycentric metropolitan area, where a total of 1 100 000 people live, not counting the 500 000 inhabitants of the adjoining Belgian municipalities.
The location of Euralille is unusual. Because of military rights, there was a vast amount of unbuilt, underused land next to the existing station of Lille-Flandres. That vacant land lay between the city centre and the bundle of rail and road infrastructure separating it from the surrounding municipalities. When Euralille was conceived, the station neighbourhood was that of a typical obsolescent central station, with a mixture of shops, services, and housing of moderate quality. There was some tertiary development along its margins, but the general property dynamics were low, partly because of the many infrastructure barriers. The areas on the other side of the tracks and the motorway were essentially residential, and had little contact with the social and economic life of the city centre. The construction next to Lille-Flandres of the new TGV station, and especially of the tertiary complex of Euralille, was revolutionary. It had few, if any, antecedents in developments nearby. The scale of reference, here to a more extreme degree than in other station area projects, appears to be that of the faraway places brought closer by new and improved transport networks. The ambition of Euralille is to deal with the fact that the space of daily life will be at one time that of the immediate proximity, the territory contained in a radius of 30 km around the centre of Lille, and the triangle London-Paris-Brussels, of which Lille becomes a sort of epicentre. (Urbanisme, 1993, p.55)
However, as we shall see, integration of such distant realities raises many difficult issues.
The story of Euralille is at one and the same time that of an extraordinary chain of events and that of the determination of the local élites to profit from emerging opportunities. In short, everything about this case is exceptional. Its position is exceptional, thanks to the location; it has become the hinge of the north European high-speed train system. The consequent increase in accessibility is unprecedented on the continent. The FAST study of the European Union (cited in Arenas et al., 1995) concluded that in 2020 Lille will be the most accessible city in
Fig. 5.3 Euralille, the place. Lille-Flandres is at the bottom right of the picture, Lille-Europe at the top left. The city centre is at the bottom; peripheral residential neighbourhoods are at the top. Between the two stations is the new multifunctional complex of Euralille. Just outs the picture, at the top right, is the new event, congress and exhibition centre. (Source: Euralille. Photo: NAI)
Fig. 5.3 Euralille, the place. Lille-Flandres is at the bottom right of the picture, Lille-Europe at the top left. The city centre is at the bottom; peripheral residential neighbourhoods are at the top. Between the two stations is the new multifunctional complex of Euralille. Just outs the picture, at the top right, is the new event, congress and exhibition centre. (Source: Euralille. Photo: NAI)
Europe, up from eleventh place in 1991. Not just quantitative but also qualitative accessibility is important. Lying between London, Paris, and Brussels, Lille is within reach of some of the world's most densely populated and economically active regions. Exceptional also is the availability of ample reserves of virtually unbuilt land next to the station and the city centre, all in public hands. Exceptional is the personal leadership and political influence provided by Pierre Mauroy. He has been the mayor of Lille for 25 years, president of the Communauté Urbaine (the metropolitan government) since 1989, prime minister when the crucial decisions (Channel Tunnel, North European HST, HST through Lille) were taking shape, and well connected at all times. Exceptional too is the local economic context, and the magnitude both of the past crisis of the regional industrial economic base (textile, coal, metal), and of the present transition to a service and high-tech economy.
As a result of the accumulation of all the above, there is a 'sense of urgency, of inevitability' that in Lille 'generates an incredible dynamic' (de Volkskrant, 1994), and which has no equal elsewhere. Referring to the Euralille initiative, Mauroy admits:
We have been lucky, without a doubt, because if one of these conditions would not have been satisfied at the right moment, the project would probably not have seen the light of day. (Simon, 1993)
All of this has to be kept in mind when evaluating the case of Euralille, and when reviewing the three phases into which its story could be divided.
Phase 1: strategic decisions, 1986—1987
At the beginning of the 1980s, finally breaking centuries-long hesitations, the British and the French governments (Mauroy was then prime minister) decided that the two countries were to be linked by a tunnel under the Channel. The decision was formalized in January 1986. Car shuttles and high-speed trains were the transport means to run through the 'Chunnel'.
In 1987, another important step was taken. The transport ministers of France, Belgium, Germany and the Netherlands signed a treaty for the joint development of the north European high-speed train network. Meanwhile Mauroy, who had gone back full-time to his local responsibilities, took over the leadership of a broad regional coalition of public and private interests to lobby for changes in the HST route. They wanted it to run through the Nord-Pas de Calais region, not the Picardie; and they wanted it to run through the centre of the city of Lille, not on a peripheral course. Initially, SNCF (the French railways) did not agree with the idea. They found it too expensive. Moreover, the stop in Lille would mean a loss in time and thus in profitability. Later, however, a compensation for the increase in costs and the missed profits made SNCF change its mind. The extra Fr 800 million needed was contributed by the state (Fr 400 million, as a result of the mediation of Mauroy), the region Nord-Pas de Calais (Fr 264 million), and the city of Lille (Fr 136 million).
Not all the conflicts were resolved, though. Opposition to the route came also from the municipalities of Lille's hinterland, on whose territory the TGV would have to pass, and who feared they would get just the negative effects. Little by little, guarantees (mitigation of impacts) and compensations (redistribution of the advantages) induced them to change their opinion. Some of the other big projects started in other centres of the metropolitan area should be seen as part of the building of this consensus among municipalities (and, one could say, of the 'foundation' of the Lille metropolis). Examples include the Euroteleport in Roubaix, the multimodal transport platform in Roncq, the expansion of the airport of Lille-Lesquin, the technopole in Villeneuve d'Ascq, the graphic arts and packaging pole in Tourcoing, and the inclusion of a tertiary complex under construction in the bordering municipality of La Madeleine within the perimeter (and the sphere of influence) of Euralille. On a municipal level, an extensive renewal programme of the old city centre is also part of this list of complementary actions.
Phase 2: planning, 1988—1990
The regional mobilization and negotiations were successful: in December 1987, the decision to let the TGV stop in Lille was official. Immediately afterwards, in February 1988, the constitution of Euralille-Métropole was announced. It consisted of a public-private study partnership that was to evaluate the feasibility of urban development on the site of the TGV station. The partnership was presided over by Deflaisseux (former president of the Credit Lyonnais Bank, and old friend of Mauroy), directed by Baïetto (former director of the Société Centrale pour l'Equipement du Territoire), and had other influential members. A group of banks, SNCF, and the local chamber of commerce were convinced to take part in this exploratory venture and subscribe to the partnership.
The first decision of the study partnership was to construct a second station for the international TGVs, essentially for technical reasons. It was also decided to use the areas between the projected and the existing station to build the new 'citadel' of Lille. On the whole, the areas available for development were in excess of 100 ha: 70 ha immediately, 50 ha in the longer term. Virtually undeveloped because of pending military rights, the land was donated by the state to the city of Lille for the symbolic amount of one franc (here also, the influence of Mauroy was crucial). The new station was to be called Lille-Europe; the old was re-christened Lille-Flandres. Between the two stations—between the Flandres and Europe—an international business centre was to rise. To avoid 'a Défense between stations', a diversified programme was suggested, consisting of offices, services, shops, culture, housing, public facilities, and open spaces. On the basis of this programme, eight architects of international reputation were invited to present their ideas. They were asked to make an oral presentation. Thus it was not a design competition. In the words of Baïetto:
It is nonsense to try to achieve an urban project by means of a design competition: an urban project implies multiple aspects and actors, and thus you have to choose a person rather than a project. (Treiber, 1995)
The contest, held in the autumn of 1988, was won by Rem Koolhaas: 'He was chosen because he had a vision of the city, not just of a project' The key to his proposal is the notion of interconnectivity—functional, spatial, and visual.
From that point on, the story of the project, with the exception of a brief intermission for public consultations, could be described as an interplay between the mayor (Mauroy) and the master architect (Koolhaas), mediated by the executive director of Euralille (Baïetto). Each of the players was responsible for (including feedback into the project) a portion of relationships with the outside world: respectively political (both the institutions and the local population), technical (essentially the great number of consultants), and operational (investors, developers, and users). In the course of 1989, the exchanges between the three (and indirectly between the constituencies they each represented) became intense. The result was a simplification and clarification of the concept initially proposed by the architect. Streamlining was necessary in order to reduce costs and increase continuity between the new district and the existing city. In the meantime, Baïetto untiringly searched for investors for each element of the programme, one by one. The influence of Mauroy was repeatedly called into service. It was through his efforts that the personal support of President Mitterand was obtained for a European Foundation of the City and Architecture. Private investors, after some initial reluctance, were gradually drawn in. But they imposed certain conditions. For example, they asked for—and got —a reduction in the proportion of office space, which they felt would reduce risk.
In the second half of 1989, the project was presented in two rounds to the local council. At the end of the same year, a phase of public consultation was started. That phase was to end in April 1990 with an open discussion forum. The most important amendment to the original plan in this phase was reinforcement of the physical integration of the complex, both internal and with the surrounding area. After these changes, the positive results of opinion polls taken
Table 5.1 Euralille: summary of the main phases
Phase 1: strategic key decisions, 1986-1987 January 1986 Channel Tunnel
October 1987 North-European HST: regional mobilization
December 1987 HST stop in the centre of Lille
Phase 2: planning, 1988-1990 February 1988
Autumn 1988 1989
Establishment of the Euralille study partnership (local and regional governments, banks, SNCF, Chamber of Commerce); discussions; programme
Urban design competition (closed, oral). Rem Koolhaas wins
Three-way discussions: Koolhaas (technique), Baïetto (management), Mauroy (politics)
Public consultations and council votes; presentation to city council, districts and metropolitan government; public discussion forum, population poll, etc.
Phase 3: implementation, 1990-1995
June 1990
June 1991 23 May 1993 29 May 1994
Foundation of the Euralille SEM: local and regional governments 54%, banks 40%, SNCF 3%, Chamber of Commerce 3%
Start construction
First TGV Paris-Lille
First TGV Pari s-(Lille)-London
Opening of Lille-Europe station, Lille Grand Palais, Centre Euralille
Opening of office towers, Credit Lyonnais and World Trade Centre among the population were adduced as evidence that sufficient consensus had been reached. In the meantime, intense negotiations with and between different agencies (such as Euralille, SNCF, other transport companies, and the metropolitan government) were also undertaken and successfully completed. It should be noted that, because of the forming of a new governing coalition, in 1989 Mauroy also became president of the Communauté Urbaine.
On the whole, opposition to the project was weak. In Lille, it mostly coincided with right-wing political opposition to the mayor. The other key actors and the rest of the local population —when they were originally indifferent, sceptical and in a few cases explicitly hostile (notably among environmentalists and small retailers)—were gradually won over to support the initiative. The main themes of criticism by the political antagonists of Mauroy were doubts about the financial feasibility of the plan, and objections to the choice of an architectural style that departed with local tradition. However, a viable alternative—a study trip to the London
Docklands notwithstanding—did not arise. Criticism along different lines, and more consistent, was voiced by environmentalists and small retailers, but the argument put forward by the former that development would destroy an existing park was too weak. The existing park attracted few visitors, and a new 10 ha park was to be part of Euralille. The retailers of the city centre were afraid of competition from the new shopping centre. Euralille addressed their fears by reducing net shopping floor space (from 65 000 m2 to 31 000 m2). At the same time Euralille introduced measures to avoid direct competition between shops in the new complex and shops in the adjoining historical city centre (for example, orientation of Euralille on innovative, specialized products, and reservation of 37% of the shopping floor space as a second location for local businessmen).
Phase 3: implementation, 1990—1995
In June 1990, right after the plan was approved by the metropolitan government, the Euralille study partnership transformed itself into a public-private development partnership, a société d'économie mixte (SEM; see section 5.1), presided over by Mauroy and directed by Ba'ietto. The planning framework is provided by a special development zone known as a zone d'aménagement concerté (ZAC; see section 5.1). The SEM Euralille was granted authority in the ZAC by the Communauté Urbaine (the metropolitan government) for a 15-year period (until 2005). Construction was launched in June 1991. Since then, the progress of Euralille can be read through the succession of the opening dates of its various elements (Table 5.1). The most notable setbacks in this period were due to vicissitudes in the financing (both public and private) of single elements, which forced the project managers to delay the realization of some of them. The basic elements, however, were not affected.
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A record number of overseas entries from eight countries feature among a total of 394 entries for the eight Group One highlights at Royal Ascot in June this year.
There are 164 overseas entries in all, as against a previous best of 156 in 2013, including a record 35 from outside Europe (previous highest 27 in 2011).
There is representation from Ireland (81), France (44), the USA (18 – the highest ever level – previous highest 13 in 2011), Australia (9), Germany (4), Hong Kong (4), Japan (2) and Singapore (2), plus 230 British-trained entries.
Star American-trained mare Tepin is under consideration for the opening race of the meeting (Tuesday, 14th June), the £600,000 Queen Anne Stakes (41 entries) over the straight mile. Trained by Mark Casse, the five-year-old comfortably defeated several European raiders, including fellow Queen Anne entries Mondialiste (David O'Meara) and Esoterique (Andre Fabre FR), in the Grade One Breeders' Cup Mile at Keeneland in October.
The Bernstein mare is unbeaten in three starts this year and was last seen out when gaining a most impressive five-length victory in the Grade One Jenny Wiley Stakes at Keeneland on 16th April.
Casse said: "All is good with Tepin. The plan is to run her around the first Saturday in May here in America and then we will make a decision about Royal Ascot after that. We feel that is good timing with Ascot in mind.
"She continues to amaze me. I was so nervous during the Jenny Wiley Stakes that I did not watch much of it but she broke the stakes record and was a fifth off the track record. I think if Julien (Leparoux) had asked her for any effort she would have easily broken the track record.
"Royal Ascot is definitely going to be a little more difficult. You just never know when you try something new [Ascot's straight mile]. I would have been a little more worried because a mile uphill is a lot more taxing than a mile in the US, but the way Tepin has run recently suggests that, now she is older and wiser, she doesn't have the distance limitations she had early on.
"We may even run her in the Woodford Reserve Stakes, which is a mile and a furlong against the boys on Kentucky Derby Day (May 7). That would probably be a little more equal to a mile at Royal Ascot. I have never been to Ascot so I am only guessing."
Tepin is likely to be joined at Royal Ascot by fellow female star miler, last week's G1 Makers Mark Mile winner, Miss Temple City (Graham Motion USA), who was fourth in last year's Coronation Stakes and is being geared toward the Group Two Duke of Cambridge Stakes, which closes next week.
The European challenge in the Queen Anne Stakes is led by last year's winner Solow (Freddy Head FR) and Coronation Stakes scorer Ervedya (Jean Claude-Rouget FR). Australian import Vancouver is one of four entries for Ireland's champion Flat trainer Aidan O'Brien, while A Shin Erwin (Hidemasa Nakao JPN) and Godolphin's Australian-trained Bow Creek(John O'Shea, AUS) are two other possibles.
A Shin Hikari (Masanori Sakaguchi JPN) is set to fly the flag for Japan in the 10-furlong Prince Of Wales's Stakes (39 entries), worth £750,000, on the second day, Wednesday, June 15. The five-year-old burst on to the world stage with an impressive front-running victory in the Group One Hong Kong Cup at Sha Tin in December. He could have a prep run in the Group One Prix d'Ispahan at Chantilly, France, on 24th May.
Breeders' Cup Turf heroine Found (Aidan O'Brien IRE) and QIPCO Champion Stakes victor Fascinating Rock (Dermot Weld IRE) head a strong European contingent in the Prince Of Wales's Stakes. New Bay (Andre Fabre FR), the leading three-year-old colt in France last season, is also engaged.
The £600,000 Diamond Jubilee Stakes (44 entries) could see a fascinating clash between top Australian sprinter Chautauqua (John Hawkes AUS) and last year's winner Undrafted(Wesley Ward USA).
The King's Stand Stakes and Diamond Jubilee Stakes are the first two British legs of the Global Sprint Challenge. Chautauqua won the opening leg, the Lightning Stakes in Melbourne, and runs next in the Chairman's Sprint Prize in Hong Kong on 1st May. That is also a challenge leg so if appearing at Royal Ascot, or in the Darley July Cup, Chautauqua would be running for the US$1-million bonus available to any horse winning three legs in three different jurisdictions.
Ward has also entered Green Mask, Hootenanny and The Great War, while Godolphin's Holler (John O'Shea AUS), The Quarterback (Robbie Griffiths AUS) and Spalato (John O'Hara SING) are among other long-distance entries. Other possibles for the six-furlong dash on Saturday 18th June include high-class Hong Kong performers Gold-Fun and Giant Treasure (both Richard Gibson HK), plus US import Bobby's Kitten (Dermot Weld IRE), the 2014 Breeders' Cup Turf Sprint victor, who scored impressively on his Irish debut last month.
There is also very strong international interest in the opening day's £400,000 King's Stand Stakes (59 entries) over five furlongs, in which Irish stalwart Sole Power (Eddie Lynam IRE – also entered in the Diamond Jubilee) may bid for an unprecedented third victory. Group One scorer Japonisme (Chris Waller – also entered in the Diamond Jubilee) heads three Australian contenders, while Breeders' Cup Turf Sprint scorer Mongolian Saturday (Enebish Ganbat USA – also entered in the Diamond Jubilee) is among eight entries from the USA. There could be representation from the Far East courtesy of Not Listenin'tome (John Moore HK – also entered in the Diamond Jubilee) and Kiwi Karma (Michael Clements, SING).
The 59 entries for the £400,000 Commonwealth Cup, for three-year-olds over six furlongs, will be hoping to emulate last year's winner Muharaar who went on to be crowned European champion sprinter following a Group One four-timer. Acapulco (Wesley Ward USA), a devastating winner of the Queen Mary Stakes at Royal Ascot last year, is one of three US-trained contenders, while Washington DC and Waterloo Bridge, also both winners at the meeting last year, are engaged for Aidan O'Brien. Cheveley Park Stakes winner Lumiere is an eye-catching entry for trainer Mark Johnston. Another transatlantic challenger is Manhattan Dan (Gary Contessa USA), who was twice placed in Grade Two company last season (is also entered in the King's Stand Stakes).
Aidan O'Brien holds a strong hand in both the mile contests for three-year-olds, with Air Force Blue headlining 56 entries for the St James' Palace Stakes (Tuesday 14th June) andMinding among 54 entries for the Coronation Stakes (Friday 17th June), with each having £400,000 in prize money.
Melbourne Cup runner-up Max Dynamite (Willie Mullins IRE), Order Of St George (Aidan O'Brien IRE) and St Leger heroine Simple Verse (Ralph Beckett) star among 42 entries for the £400,000 Gold Cup In Honour Of The Queen's 90th Birthday over two and a half miles on Thursday 16th June.
Nick Smith, Director of Racing and Communications at Ascot, said: "It is gratifying to see numbers up generally and record international entries, but what really counts in the later respect is quality and spread.
"To have one of Japan's leading middle-distance horses in the Prince of Wales's Stakes once again is tremendous; Chautauqua is most people's idea of the world's top sprinter and headlines several high profile Australian entries; Tepin's record speaks for itself and she is really picking up the public's attention home and abroad; Wesley Ward has many more Group One entries than before including in the Commonwealth Cup, which was such a welcome addition to the card last year.
"Our thanks naturally go to all the owners and trainers with entries at Royal Ascot, for whom a warm welcome awaits."
Ascot Racecourse announced in January that Royal Ascot prize money has been increased by £1 million (18% uplift on 2015) this year, bringing total prize money on offer to a record £6,580,000 over the week, Tuesday 14th June to Saturday 18th June.
The three main prize money boosts were for the Prince of Wales's Stakes – £750,000 from £525,000, the Queen Anne Stakes – £600,000 from £375,000 and the Diamond Jubilee Stakes – £600,000 from £525,000.


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Luxury Travel and Expeditions to Antarctica
Wild and alluring: Journey to the 'white continent' in the finest style
One of the most alluring and untouched places in the world, Antarctica has a great appeal in being one of the last outposts of wilderness in the modern world. This is a truly magnificent and pristine continent, with stunning scenery and wildlife. Few destinations can compare in the spirit of adventure and sense of accomplishment you feel having visited the White Continent.
Jacada has selected the finest means of visiting this grand location. Classic Antarctica Cruises will bring you around the shimmering Antarctic Peninsula while an Extended Cruise will let you journey further, typically taking in the Falkland Archipelago and wild South Georgia Island.
If you have the time, you can cross the Drake Passage and arrive in Antarctica by boat. But for those with a limited period in which to travel, skip the Passage and fly straight to the Antarctic Peninsula to board your expedition vessel on a Fly-Cruise to maximise your time spent here.
Our Luxury Antarctica Private Yacht Charters come with a number of perks. Firstly, the flexibility of a private charter means that you can be in control of your own trip, deciding on which activities you wish to undertake and when, making the most of conditions. The only people who live in Antarctica are scientists – and you can visit these dedicated few that study this fascinating continent. With smaller groups, scientific base visits can be more personalised and longer, since the base personnel only have to deal with – for example – 12 people rather than 150. It's also easier to invite scientists out on the yacht for dinner and one-on-one conversation.
Adventurous souls can choose to stay in an Antarctica Camp. These camps have been especially adapted to provide comfort in extreme conditions and will allow you to feel fully immersed in the spectacular terrain of the White Continent, venturing out on intrepid excursion and even flights to the South Pole.
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Our Top Antarctica Example Trips
I wondered whether there was too much detail info in advance, but in view of the complexity of the trip, it was all necessary. The guidance and information provision was extremely helpful.
I have traveled to Antarctica and Spain with Jacada over the past two years. George, Hanna and their teams have planned incredible trips for our family and take care of every detail. The memories they have helped us to create are priceless and I cannot recommend them highly enough!!
I would give Jacada Travel the BEST of the BEST that I could! I and my wife took a 2 months around the world trip with Jacada travel in February - April 2015. We spent one month in South America and Antarctica and the rest in Europe. S.America Chile - Torres Del Paine. Ecuardor - Quito - The Galapagos. Peru - Lima - Cusco - Machu Picchu. and And Antarctica! Then we go to Switzerland. Iceland Chasing the Northern Light with our private plane!!! And continue to Norway before arrive home in Bangkok! Everything was ince perfect and you could not feel the JACADISM feelings anywhere else!!!! That is what so special about JACADA! You feel safe and at the same time you feel so privileged. And our travel designer Jobi, and Joyce, there are so thoughtful and always think ahead for what we need and what would make it more special for us!!! I declared to be their life long clients! We love Jacada! And if you want a life time experience give them a call!!
We were very extremely happy with the Jacada experience. We were very eager to plan our trip to Antarctica and Patagonia and they worked to coordinate everything for us with Antarctica XXI. Ciara was our main contact and must have pulled together a million versions of the itinerary until we had examined every possible option and found the perfect fit . They were just as excited about our trip as we were! We spent a few days in Santiago before and then a week in Patagonia after the cruise. Both locations were amazing and we stayed at Singular hotels. They provided transportation at each stop and a full book beforehand with detailed itineraries for each leg of the trip. A wonderful experience !
Need to Know
When to go
The best time to go to Antarctica is during its summer season, which lasts from November to March. December and January are the best time to go for wildlife spotting. From mid to late December the penguin chicks start to hatch, and in January you will catch the the feeding frenzy that ensues. February to early March is the best time to spot whales, and there are generally a good number of fur seals to be seen too.


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I recently had a ridiculously complex delivery ordeal thanks to UPS. I live in England, but the only complaints info I could find online related to US deliveries, and even that was vague. I called them and finally managed to drag their UK Complaints Dept email address out of them.
The address is firstname.lastname@example.com and you should address your mail to the Concerns Department. According to the customer adviser who reluctantly gave me this info, they have a 24-hour call-back policy.
This is what happened to me: I ordered something from a website which uses UPS as its courier (so I had no choice in the matter). They didn't tell me when they were going to deliver the parcel, so I missed the first delivery. I arranged a second delivery, took a whole day off work - it didn't come. They didn't leave any note on either day that they'd attempted to deliver, so I couldn't track the parcel, and they wouldn't give me any alternative options to have it delivered or collected, so it nearly got returned to the sender.
In the end, my boyfriend managed to receive my parcel by an extreme stroke of luck - he was on the bus going away from our flat, looked out of the window and happened to see a UPS delivery guy knock on the door to our building then immediately turn and go back to his van without waiting for anyone to answer the door, so my boyfriend got off the bus and ran after him. It's utterly absurd that this is how I eventually managed to get my parcel and I'm really not impressed with UPS's abysmal customer service.
If you decide to complain... good luck! I'm determined to share the UK complaints email address now with anyone and everyone who has had similar issues, as they're so evasive when it comes to getting details of their complaints procedure.
Product or Service Mentioned: Ups Delivery Service.
I have just received a derlivery from UPS, when leaving the driver hit and knocked down a tree outside our house, he asked my wife not to report it and drove off. Absolutely shocking, disgusting behaviour. I will report it to the local council
I know why they have chosen "that" color for their vans. Incredible they're still in business.
Tracker says: delivery at end of day d/m/y You stay home all day! Next day also. NOTHING. You check tracker.
Parcel was sent back to sender upon his request. "Please contact sender." Ok. Sender doesn't know about anything !!! And that's only 1 percent of my bad experiences I had with them.
Truly American to the core though! EXCEPTIONAL
UPS are *** - knock and run 3 days in a row
UPS is horrible. Sent important docs without waterproof covering and threw them in the dirt.
Rain soaked, no knock on door. Very disgusted with them.
Ups customer service is 100% for ups. They suck *** A driver can do what he wants then lie to his boss and since he works for them they go by his story.
They hang up on you and screw you over. I wish i had the $ to help fed-ex or usps to put ups sorry *** out of buissiness.
UPS is terrible - I will never use them again-
Ī am going through the exact same problem as we speak. Day 3 of taking off work!
Had a customer care advisor refus to give me the complaints department address and they proceeded to hang up the phone on me. No missed call note left they emailed me to say they had left a return label which they didn't. As they hadn't been at all because I was in.
If it would of been my choice I would never of used this company in the first place. DISGUSTING
They sent my package to a wrong address after I tell them the correct address no return call yet. they are full bag of rubbish.
We had theatre tickets delivered by ups three days AFTER the event. They are contactable by messenger, I extracted several grovelling apologies but nothing in the way of compensation, just contractual law statements.
They are rubbish, I rarely buy online but will always ask if they use ups in future, and tell them to cancel the order. If we all did this ups might, big might, get the message.
Driver was very rude to me and felt very threaten by him . I have just lost a family member and did not need his rudeness .he was driving in Newcastle under Lyme staffs . Heading to chesterton
Thank you for this info. I experienced similar problem.
I trade online in the UK and I import my stock from Poland. I ordered 6 boxes of stock and received only 5. UPS came when I was out and left all this stock at my neighbour, which I even do not know as I just moved in. The problem is that this *** neighbour agreed to sign the delivery so I didn't have a chance to check if order is complete.
One box of stock is worth £100! UPS in Leeds told, the delivery was signed, so they are done.
I have also asked UPS in Poland and also the seller to help, but all seems unhelpful. NEVER EVER USE UPS!!!!
I to have a complaint thank you for the info I can now send in my complaint and I will wait and see what happens. Thank You
Appalling service. On the site delivery was scheduled by the end of day.
I called to find out how late they were delivering only to be told that the delivery was the next day!!!!
No one was prepared to discuss this...
Disgraceful service. Avoid this company.
This is a few years old so my comment probably won't be read by the person who posted it, but I'm very grateful for the email address. I've had a problem with my local driver literally forging my signature, and lying a out talking to my neighbours. Weird, *** unprofessional...
At least you had a knock on the door. I have been waiting for a delivery.
I heard something come through the letterbox. It was a note saying they tried to deliver but no one was home. No attempt was made to actually deliver the parcel.
By the time I got to the door they had gone. Less than a minute....unbelievable.
Thankyou I am about to complain with a similar issue.
Has anyone asked for compensation and succeed?
Thank you so much for this! I've just had a similar experience with a delivery from Holland which has now been returned to the sender because of a mess up by UPS.
I've been looking for where and how to complain and stumbled upon your post. Thank you!
You guys will not believe my experience with UPS
In November last year we had to leave our flat for emergency repairs so I was staying at a bnb temporary. My electric piano which is my pride and joy needed repair for software issues so I contacted the company KORG who use UPS as their shipping provider as my unit was still under warranty.
Bearing in mind my unit was only having software related issues. I spent over 2500 pounds to purchase this beauty. Wait it gets worse. We had a call to move back in which we did and I soon arranged for my unit to be collected.
I waited in all day and no one turned up so I contacted UPS again and complained to which they re scheduled another appointment. Again same story so I was fuming. Got hold of some one in their Southampton depot who assured me this would not happen again. Finally one day some angry short man came up and was supposed to have a waybill for me to fill out but he didn't.
So when I tried telling him that the depot told me you were going to bring it with you he interrupted me and said I'm not going to argue with you and was so rude to me and left. My blood hit the roof so I contacted them and the next day they sent someone else who had everything with him. I specifically told him that this unit needs to be handled with much care and he assured me that he was going to put fragile sticker on it but just in case as I completely lost trust in their services I placed one on there my self. Okay .
A month goes by and no one from KORG has contacted me to tell me my unit arrived or whatever and how long it would take to sort out. So I contacted korg to find out that it didn't arrive. Strange right? After investigation it turned out that they still have the package but like I said it gets worse.
They sent pictures of my unit to korg to determine if that was the package. Korg sent me the pictures and upon seeing them I nearly had a heart attack. I actually vomited. There were keys missing on my beautiful piano, the screen was smashed in the middle and the buttons were broken and piano was marked everywhere.
It has been sat with UPS for over a month now and not sent to KORG.
They have destroyed my piano and I will not leave them in peace. The WORST COMPANY IN THE WORLD
I have worked for a few American companies. In my life , I wanted to add.
When else ? Never again.
SEP 1/2019 Trump said earlier this week that American companies are badly run. Understatement of the year.


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In the June issue of Earthmovers magazine editor Graham Black has given a whole page to a review of Steven Vale's programme Demolition Giants. Here are some quotes from the article:
'This is the best demolition DVD that I have ever watched ... effectively 1 hour 25 minutes' worth of good quality television that can be watched any time you like, over and over again for £15.95. No American hype and no comedians, just the sights and sounds of the tall structures being ripped apart by massive machinery, acompanied by an informative documentary-style English-language voice-over.'
'The footage of the extremely tall rigs at work is simply stunning, particularly the giant machinery in Holland.... However, for those with a professional interest in the subject, it also provides a unique insight into cutting-edge European demolition technology; it is a business essential. What was a stylish and worthwhile touch was the DVD extras, including an interview with David Kocurek. If you want to know about high-reach demolition rigs, this East Anglian engineer is a well-respected world-class expert.'
If you aren't already receiving Earthmovers magazine, go to www.earthmoversmagazine.co.uk. You'll find that they are now adding exciting video footage to their website.
For more information about the Demolition Giants DVD and a Contents list look at our blog of 8 February. To buy online go straight to Old Pond


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The five-star resort is situated just 10 minutes from the international airport and has 121 deluxe rooms and villas, each with a private balcony.
Salinda features a business centre with a multilingual concierge, secretarial services, translation and courier services, and conference support 24 hours a day. It has two VIP rooms available for private dining for 20 people each, and a banquet hall that can accommodate over 300 delegates.
Other features of the resort include an international restaurant, lounge, infinity swimming pool and pool bar. There is also a health club and spa with seven individual treatment rooms, shower, bath and steam room.
For incentive activities, guests can go snorkelling, diving, water skiing, jet skiing, kayaking and deep-sea fishing. Cookery lessons and yoga classes are also available on site. Local excursions include private cruising, visiting the local pepper farms, or a trip to Ham Ninh fishing village.
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After studying this Unit, you will be able to. • name alcohols, phenols and ethers according to the IUPAC system of nomenclature;. • discuss the reactions. Free PDF download of Class 12 Chemistry revision notes & short key-notes for Chapter 11 - Alcohols, Phenols and Ethers to score high marks in exams, prepared by expert Chemistry teachers from latest edition of CBSE(NCERT) books. Previous Year Question Papers CBSE Class Chemistry Notes for class 12 Chapter Alcohols, Phenols and Ethers. Alcohols and Phenols. Alcohols and phenols are formed when a hydrogen atom in.
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Learn to recognize the alcohol, phenol, and ether functional groups. • Learn the IUPAC system for naming alcohols, phenols, and ethers. • Learn the important. The structures for alcohols, phenols, thiols, ethers and thioethers are shown below. Alkyl-OH. Alkyl-SH. Ph-OH. R-O-R R-S-R alcohol phenol ether thioether thiol. Class XII Chapter 11 – Alcohols Phenols and Ethers Chemistry Question Write IUPAC names of the following compounds: (i) (ii) (iii) (iv) (v) (vi) (vii) (viii).
Thus, the relative order of reactivity of the alcohols is justified. Acidic catalyst converts hydroxyl group into a good leaving group. Since, the rate determining step is the formation of carbocation, the ease of dehydration is Mechanism Step I Formation of protonated alcohol Step II Formation of carbocation Step III Formation of ethene by elimination of a proton In dehydration reaction, highly substituted alkene is the major product and if the major product is capable of showing cis-trans isomerism, trans-product is the major product.
A common reagent that selectively oxidises a primary alcohol to an aldehyde and no further is pyridinium chlorochromate pCC. Reactions of Phenols i Electrophilic substitution reactions The -OH group attached to the benzene ring activates it towards electrophilic substitution at ortho and para positions. This is because o-nitrophenol is steam volatile due to intramolecular hydrogen bonding while p nitrophenol is less volatile due to intermolecular hydrogen bonding which causes the association of molecules.
It is prepared as follows. It is obtained by destructive distillation of wood. Drinking of methanol causes blindness. It is used In the preparation of various beverages containing different percentages. Dihydric Alcohols These are generally called glycols because of their sweet taste.
Methods of Preparation Physical Properties 1. It is a colourless, syrupy liquid with sweet taste. Because of its tendency of formation of H-bonds, it is miscible with H2O and ethanol but not with ether. Chemical Properties It gives all the general reactions of -OH group.
The per-iodic acid cleavage of 1,2-g1ycols is sometimes called Malaprade reaction. Method of Preparation It is obtained as a by product in saponification reaction. Physical Properties 1.
It is a colourless, odourless, viscous and hygroscopic liquid. It is sweet in taste and steam volatile. It is soluble in water but insoluble in ether. Due to excessive H-bonding, it is highly viscous and has high boiling point.
Some of its specific reactions are : Glyceryl trinitrate or tri nitroglycerine, when adsorbed on Kieselguhr is known as dynamite. For example: Write the mechanism of acid-catalysed dehydration of ethanol to yield ethene. Class XII Chapter 11 — Alcohols Phenols and Ethers Chemistry Williamson ether synthesis is a laboratory method to prepare symmetrical and unsymmetrical ethers by allowing alkyl halides to react with sodium alkoxides.
Better results are obtained in case of primary alkyl halides. After the formation of ethene. Page 16 of Answer i If propene is allowed to react with water in the presence of an acid as a catalyst. How are the following conversions carried out? The acid consumed in step 1 is released in Step 3.
Name the reagents used in the following reactions: Extra energy is required to break these hydrogen bonds. Give reason for the higher boiling point of ethanol in comparison to methoxymethane. H3PO4 to give 1-propoxypropane.
Propanol undergoes dehydration in the presence of protic acids such as H2SO4. Answer The reaction of Williamson synthesis involves SN2 attack of an alkoxide ion on a primary alkyl halide.
Illustrate with examples the limitations of Williamson synthesis for the preparation of certain types of ethers. The mechanism of this reaction involves the following three steps: Page 20 of But if secondary or tertiary alkyl halides are taken in place of primary alkyl halides.
Answer 1-propoxypropane can be synthesized from propanol by dehydration.
This is because alkoxides are nucleophiles as well as strong bases. How is 1-propoxypropane synthesised from propanol? Write mechanism of this reaction. Preparation of ethers by acid dehydration of secondary or tertiary alcohols is not a suitable method. In case of secondary or tertiary alcohols. Answer The formation of ethers by dehydration of alcohol is a bimolecular reaction SN2 involving the attack of an alcohol molecule on a protonated alcohol molecule. Write the equation of the reaction of hydrogen iodide with: In the method.
Protonation Step 2: Nucleophilic attack Step 3: Deprotonation Question Answer i In aryl alkyl ethers. Page 22 of Explain the fact that in aryl alkyl ethers i The alkoxy group activates the benzene ring towards electrophilic substitution and ii It directs the incoming substituents to ortho and para positions in benzene ring.
Answer i Page 23 of Write the mechanism of the reaction of HI with methoxymethane. Answer The mechanism of the reaction of HI with methoxymethane involves the following steps: Protonation of methoxymethane: When HI is in excess and the reaction is carried out at a high temperature. Write equations of the following reactions: Show how would you synthesise the following alcohols from appropriate alkenes?
When 3-methylbutanol is treated with HBr. Give a mechanism for this reaction. Answer The mechanism of the given reaction involves the following steps: Protonation Page 26 of The secondary carbocation formed in step II rearranges to a more stable tertiary carbocation by a hydride ion shift from 3rd carbon atom.
Re-arrangement by the hydride-ion shift Step 4: Nucleophilic attack Page 27 of Classify the following as primary. Identify allylic alcohols in the above examples.
Answer The alcohols given in ii and vi are allylic alcohols. Show how are the following alcohols prepared by the reaction of a suitable Grignard reagent on methanal? Write structures of the products of the following reactions: Answer Page 33 of Ortho and para nitrophenols are more acidic than phenol.
Draw the resonance structures of the corresponding phenoxide ions. Predict the major product of acid catalysed dehydration of i 1-methylcyclohexanol and ii butanol Answer i.
Class XII Chapter 11 — Alcohols Phenols and Ethers Chemistry Resonance structure of the phenoxide ion Resonance structures of p-nitrophenoxide ion Resonance structures of m-nitrophenoxide ion It can be observed that the presence of nitro groups increases the stability of phenoxide ion. Write the equations involved in the following reactions: Write the reactions of Williamson synthesis of 2-ethoxymethylpentane starting from ethanol and 3-methylpentanol.
Answer In Williamson synthesis. Reimer-Tiemann reaction ii. Page 35 of In the reaction. In set i. Which of the following is an appropriate set of reactants for the preparation of 1- methoxynitrobenzene and why?
Predict the products of the following reactions: Flag for inappropriate content. Related titles. Jump to Page. Search inside document. Answer i ii iii iv v vi Page 3 of 37 3: Documents Similar To chemistry-alcohols-phenols-and-ethers.
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