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Why It's Good to Keep Tabs on Your Furry Friend's Health
Proper diet, exercise, grooming, vaccinations, and preventative care are essential to helping our pets live their best lives. It takes a village to raise a healthy pet; your veterinary team, groomer, trainer, dog walker, and pet sitter are all integral parts of managing and maintaining your best friend's physical and mental well-being. But who keeps an eye on the front line? You do! And as the person who monitors your pet's daily habits and appearance, the pet parent will be the first to spot signs they aren't feeling well. Even a first-time pet owner can quickly assess these health parameters. By noticing any deviation in your pet's "normal," you can seek medical attention and resolve problems quickly.
First Things First: Checking Your Dog's Mood and Body Condition
Initial assessment of your pet begins upon approach. A healthy pet is alert, shoulders relaxed, tail wagging, weight evenly distributed or even in a bow, and ready to engage in play or other activities. Though shape among breeds differs, pets of an ideal weight and body condition will have a slight tuck upwards of their abdomen and, from above, an hourglass shape. You should be able to feel, but not see, their ribs. Diet and exercise play a significant role in maintaining an ideal weight which is critical for managing the onset of problems such as respiratory and orthopedic disease. A change in weight that isn't intentional should be cause for concern and discussed with your veterinarian.
From Head to Paws: Examining Their Body
Once you've evaluated their body condition and attitude, you can do a nose-to-tail check on other body systems. A wet nose doesn't indicate hydration status or health, but discharge from the nose or eyes can indicate disease. The nose can be black, pigmented, light pink, or have spots. But any changes in appearance, color, crusting, or swelling are abnormal. Eyes should be clear, track movement, not be sunken or dull, and have no discoloration of the eye or surrounding tissues. That thin triangular piece of pink skin in the corner of your dog's eye? Normal and healthy! The third eyelid provides additional protection and distributes tear film.
Dogs with healthy ears will have no odor, redness, swelling, discharge, or touch sensitivity. You may expect a small amount of yellow to tan wax, but your pet should exhibit no other symptoms of infection or illness. Head shaking, whining, or obvious growths in or on the ear canal should prompt a visit to the veterinarian. Allergies or unaddressed trauma usually cause ear infections. Handle your pet's healthy ears often and introduce them to cleansing solutions and gentle inspection. They will be more agreeable to future examinations and treatment if and when that time should come.
Making Sure Those Chompers are in Good Shape
What's not to love about puppy breath? For most dogs, that sweet smell disappears by 3-6 months when their adult teeth replace their baby teeth. But that doesn't mean you should stop opening your pet's mouth to evaluate teeth, gums, and odor! Gently rub your dog's cheek, raise their lips, and open them wide. Gum color in dogs is variable; some are more highly pigmented than others. That's why it's best to do regular home checks to detect changes in your pet's appearance. Moist, pink gums, tongue, and fresh breath are signs of good health. Foul odor, pale, dry gums, heavy tartar, missing teeth, bleeding, or oral masses are not. Maintain oral hygiene with daily brushing, rinses, and even treats or specially formulated kibble. Because oral health affects the heart, kidneys, and other body systems, staying on top of home care and performing regular checks is critical.
Checking Your Pet's Tummy
As you slide your hands past your dog's head and shoulders, there shouldn't be resistance from a bit of pressure on the belly. A regular appetite and daily bowel movements are indicators of good health. The stool should be brown and firm but not hard, absent of blood or mucous, and easy to pick up. Regular eating habits amongst dogs can differ wildly; some prefer moist to dry food, some eat once daily, while others are grazers or need an audience. Tell your vet about unexpected changes in your pet's appetite, food preference, stool consistency, color, and frequency. Stress, parasites, pancreatitis, and other mild to severe diseases can affect your pet's gastrointestinal system.
Inspecting Under the Tail
Even healthy dogs don't generally like to be inspected under the tail. But check, you must! Signs your pet is healthy include a lack of odor or discharge from around your pet's genito-urinary tract, no signs of excessive licking such as hair loss or wetness, and the ability to urinate a good stream of light yellow, clear urine several times daily (preferably outside, on command) without obvious pain or strain. Healthy dogs with ample clean, fresh water should have no problems eliminating routinely 3-5x a day. Issues within the urinary tract can escalate quickly; if you notice your pet's voiding routine has changed, call your vet immediately.
Feeling for Lumps, Bumps, and Parasites
Reward your pet's cooperation during their at-home exam with lots of kisses and snuggles. Rub your hands through their fur and feel for any lumps or bumps. Notice the texture and thickness of their coat, and be aware of any sensitive or itchy spots, dandruff, or redness. Like the gums and nose, their skin may normally be darkly pigmented, spotted, or all pink. All coats should be free of mats, smells, scales, and oil. As a grand finale, check for parasites. Ticks lurk on the ears, under the armpits, and even between the toes. Fleas may only leave tell-tale "dirt" behind, or you may be able to spot the fast-moving buggers. While skin disease isn't usually a medical emergency, checking in with the pros should your dog not pass a cursory exam with flying colors is always best.
Expert Vet Advice
At Pet Butler, we want you and your pet to live your best and healthiest lives, which is why we offer pet waste removal and other services year-round. We offer weekly, bi-weekly, monthly and one-time clean-up services to work with your schedule and needs.

subset: commoncrawl


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Contact information
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"If I was, it wouldn't be any of your business. I'd let you know if I was and I wanted you to know."
-- Gibson, asked by Nick Piecoro if he is considering a change in the rotation
I haven't got the audio yet from after this afternoon's game. It may show up later (yesterday's eventually rolled in post-midnight, so I didn't bother with it), but before 'Pit Your Wits shows up, wanted to post the clip of the pre-game conference in which Gibby bites Nick Piecoro's head off. "Let me assure it, it was a doozy of a pregame session, as I'm sure you the tone of Gibson's answer there would lead you to believe," Tweeted Nick.
One wonders if we will see an epic blow-up from Gibson - like the one where he got ejected - against the media at some point this season. Makes me glad to be writing this from Das SnakePitBunker.
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Characteristics and movement patterns of a recently established invasive Pacifastacus leniusculus population in the river Mura, Croatia
Knowl. Managt. Aquatic Ecosyst., 403 (2011) 07
Published online: 2011-11-25
The Citing articles tool gives a list of articles citing the current article.
The citing articles come from EDP Sciences database, as well as other publishers participating in CrossRef Cited-by Linking Program. You can set up your personal account to receive an email alert each time this article is cited by a new article (see the menu on the right-hand side of the abstract page).


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High Level Synthesis Scheduling with Evolutionary Programming
Journal: International Journal of Science and Research (IJSR) (Vol.2, No. 1)Publication Date: 2013-01-05
Authors : Shilpa Gundagi; Sangamesh;
Page : 355-358
Keywords : ASAP; ALAP; Time constraints; ILP; Evolutionary Algorithms;
Time as a constraint finding the optimal solution of scheduling in High level synthesis using Evolutionary Programming. Because of pressure of designing high performance chip may be in terms of the cost or speed scheduling plays very important role, without proper scheduling it is nearly impossible to meet the desired objective with the current challenge and the complexity of the circuit there is a very important requirement of automated tool which could deliver the optimal solution. In this regard rather than applying the conventional method it is always better to apply the algorithms which are nature inspired. Hence genetic algorithms opted for this purpose.
Other Latest Articles
Last modified: 2021-06-30 20:10:51


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More UK families relying on food donations amid cost of living crisis
A record number of food parcels were handed out in the past year in the UK by the country's largest food-bank provider, amid Britain's cost of living crisis.
The Trussell Trust charity distributed nearly 3 million food parcels in 2022-23, its highest ever total and a year-on-year increase of 37%.
One in five people using a Trussell food bank over the period were in work, the charity said, reflecting the difficulties many low-income households have in affording everyday essentials amid soaring energy bills and food prices.
Trussell's chief executive, Emma Revie, said the demand for food parcels last year was higher than it had been during the first year of the Covid pandemic, "which we had all assumed was a once-in-a-lifetime level of need".
The number of Trussell Trust food parcels distributed had grown by 120% over the past five years, Revie said. In 2017-18 it gave out 1.4 million parcels, at the time a record. The figure increased in four of the following five years before hitting its current peak.
Rising food and energy costs in particular have seen many households struggling over the past year - but neither the pandemic nor recent cost-of-living pressures could explain the rising demand over the past five years, Revie said.
Food bank use soared across all regions of the UK, with the biggest annual increase in food parcel distribution – 54% – seen in the north-east of England.
"We are experiencing an unprecedented rise in the number of people coming to the food bank, particularly employed people who are no longer able to balance a low income against rising living costs," said Brian Thomas, the chief executive of Trussell's South Tyneside food bank.
Until relatively recently, the bulk of people using food banks were in effect destitute, but static incomes and rising prices have changed that profile. People in low-paid and insecure jobs, typically in retail, social care, hospitality and warehousing, are increasingly reliant on charity food, food banks say.
The Trussell figures, taken from its 1,646 outlets, are a reliable general indicator of worsening trends in levels of UK hunger and poverty, although the trust is clear they are only "part of the picture" of people struggling to afford food.
The trust does not operate in about a quarter of UK local authority areas, and thousands of food banks and food aid charities exist outside its network. Food banks as a whole do not capture the full extent of hunger, with government figures suggesting just 14% of people in severe food insecurity visit food banks.
Source: BBC and Guardian


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Mantuan Sentence Examples
In superintending the distribution of the Mantuan territory amongst the veterans, he used his influence to save from confiscation the property of the poet Virgil.
The Marquis Lodovico Gonzaga of Mantua had for some time been pressing Mantegna to enter his service; and the following year, 1460, was perhaps the one in which he actually established himself at the Mantuan court, residing at first from time to time at Goito, but, from December 1466 onwards, with his family in Mantua itself.
Some of his early Mantuan works are in that apartment of the Castello which is termed the Camera degli Sposi - full compositions in fresco, including various portraits of the Gonzaga family, and some figures of genii, &c. In 1488 he went to Rome at the request of Pope Innocent VIII., to paint the frescoes in the chapel of the Belvedere in the Vatican; the marquis of Mantua (Federigo) created him a cavaliere before his departure.
The pope treated Mantegna with less liberality than he had been used to at the Mantuan court; but on the whole their connexion, which ceased in 1490, was not unsatisfactory to either party.
They were sold in 1628 along with the bulk of the Mantuan art treasures, and were not, as is commonly said, plundered in the sack of Mantua in 1630.
The influence of Mantegna on the style and tendency of his age was very marked, and extended not only to his own flourishing Mantuan school, but over Italian art generally.
The fourth is based on Mantuan's eclogue, De consuetudine divitum erga poetas, with large additions.
The fifth, printed by Wynkyn de Worde, also without date, is entitled the "Fyfte Eglog of Alexandre Barclay of the Cytezen and the uplondyshman" and is also based on Mantuan.
Aldus in his edition of Cicero's De universitate (1583), dedicated to Crichton, laments the 3rd of July as the fatal day; and this account is apparently confirmed by the Mantuan state papers recently unearthed by Mr. Douglas Crichton (Proc. Soc. of Antiquaries of Scotland, 1909).
He therefore took counsel merely with his interest as a temporal prince, threw in his lot with France, supported the duke of Nevers in the Mantuan Succession, and, under stress of ' fear of Habsburg supremacy, suffered himself to be drawn into closer relations with the Protestants than beseemed his office, and incurred the reproach of rejoicing in the victories of heretics.
AdvertisementAnd this was only the forerunner of more signal reverses; for, in a short time, Villeroi was forced to abandon the whole of the Mantuan territory and to take refuge in Cremona, where he seems to have considered himself secure.
The Mantuan peasant was grieved at the notion of his harvest being gathered by barbarian soldiers, and the Irishman could not be better pleased to see his destroyed.
The Socialist party, which had grown powerful under a series of weak-kneed administrations, now began to show signs of division; on the one hand there was the revolutionary wing, led by Signor Enrico Fern, the Mantuan deputy, which advocated a policy of uncompromising class warfare, and on the other the riformisti, or moderate Socialists, led by Signor Filippo Turati, deputy for Milan, who adopted a more conciliatory attitude and were ready to ally themselves with other parliamentary parties.


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Introducing Dwgmerge 2022
Tailor Made Software's® DwgMerge 2023™ is a command-line interface application designed to designed to merge XML or JSON content into AutoCAD DWG files. DwgMerge 2023 can add graphical entities, layers, bitmap references and blocks.
It supports any version of AutoCAD up through AutoCAD 2022 (released March 2021).
DwgMerge 2023 can be installed and utilized on any server that utilizes one of the following operating systems:
- Microsoft Windows 10
- Microsoft Window 8 and 8.1
- Microsoft Windows 7
- Microsoft Windows Vista
- Microsoft Windows XP
- Microsoft Windows Server 2000, 2003 or 2008
- Microsoft Windows NT (4.0) or 2000
- Windows 95 or 98
- Red Hat Linux (v6.1 or later) or corresponding CentOS version
- Debian
DwgMerge 2023 should work on most Linux installations but has only been tested on the systems mentioned
If need arises, DwgMerge 2023 can also be utilized via a scripting application to manually convert single files or batches of files.


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– ¼ cup melted coconut oil – 1 cup all-purpose flour – 3 teaspoon ground ginger powder – 1½ teaspoon cinnamon powder – 1½ teaspoon baking powder – ¼ teaspoon salt – 2 large eggs – ½ cup brown sugar – 1½ cup grated carrot (see tips) – 1 cup coarsely grated coconut FOR ICING – ⅓ cup thinly shredded coconut – ⅓ cup powdered white sugar – ¼ teaspoon vanilla extract – ½ teaspoon coconut milk
While the cake cools down, place the coconut flakes for decoration on a baking tray and bake until most turn golden brown. Remove from the oven and let it cool down to room temperature. Combine the powdered sugar with vanilla extract and coconut milk and stir to mix well. It should be very thick but pourable. Pour this mix on the cake, and top with the toasted coconut.


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Join Barrington Area Special Voices to help area families with special needs children at their third annual Shamrock Shindig coming up at McGonigal's Pub in Barrington from 7 to 11 p.m. on
Join Barrington student volunteers and models on a mission to help build homes for families living in and around the Guatemala City garbage dump at their second annual Hope's in Style Fashion
Citizens for Conservation is hosting a series of Saturday morning winter programs to offer suggestions for simple ways we can maintain our yards and homes in a more earth-friendly manner. This month's
Student performers at Barrington High School are preparing for final rehearsals and proud to present their production of the musical CATS which opens at the end of February. The show is based
The Barrington Area Park District is hosting one of the sweetest events of the year coming up on Friday, March 7th. It's the Daddy Daughter Date Night and dance and our 5-year-old
Get your groove on and have a blast from the past while supporting the programs of JourneyCare at their annual Decades Dance coming up on Saturday, February 22, 2014, at the Holiday
When the Barrington Area Library asked me last fall if I would interview the author of this year's fiction selection for their annual Barrington Reads community reading campaign, I was honored for
With the new wedding engagements that come with each holiday season, a bevy of new brides-to-be are busy lining up locations and vendors for their upcoming "I-Do's". Barrington event planner, Christina Currie,
Don't let the "Sold Out" sign go up at Barrington's Catlow Theater before you get your tickets to the second annual Afternoon of 2014 Oscar Nominated Short Films coming up at the


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212 Men was created by Alberto Morillas, Top notes are spices, petitgrain, lavender, green notes, grapefruit and bergamot; middle notes are ginger, green pepper, gardenia, violet and sage; base notes are labdanum, sandalwood, musk, guaiac wood, vetiver and incense
Carolina Herrera 212 Men EDT 100ml Spray (Men's fragrances)
212 Men by Carolina Herrera is a Woody Floral Musk fragrance for men.
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Purpose of reviewThis review explores trends in the United States (US) transplant surgery workforce with a focus on historical demographics, post-fellowship job market, and quality of life reported by transplant surgeons. Ongoing efforts to improve women and racial/ethnic minority representation in transplant surgery are highlighted. Future directions to create a transplant workforce that reflects the diversity of the US population are discussed.Recent findingsRepresentation of women and racial and ethnic minorities among transplant surgeons is minimal. Although recent data shows an improvement in the number of Black transplant surgeons from 2% to 5.5% and an increase in women to 12%, the White to Non-White transplant workforce ratio has increased 35% from 2000 to 2013. Transplant surgeons report an average of 4.3 call nights per week and less than five leisure days a month. Transplant ranks 1st among surgical sub-specialties in the prevalence of three well-studied facets of burnout. Concerns about lifestyle may contribute to the decreasing demand for advanced training in abdominal transplantation by US graduates.SummaryMinimal improvements have been made in transplant surgery workforce diversity. Sustained and intentional recruitment and promotion efforts are needed to improve the representation of women and minority physicians and advanced practice providers in the field.
Original language | English (US) |
Pages (from-to) | 560-566 |
Number of pages | 7 |
Journal | Current opinion in organ transplantation |
Volume | 26 |
Issue number | 5 |
DOIs | |
State | Published - Oct 1 2021 |
- burnout
- diversity
- gender parity
- job market
- transplant surgery
ASJC Scopus subject areas
- Transplantation
- Immunology and Allergy


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Investing in Strong Consumer Brands for Long‑Term Success
Topspin Consumer Partners is a Mamaroneck, NY-based private equity firm that makes investments in established, profitable and fast-growing middle-market consumer businesses. The firm invests across a number of subverticals within consumer, including health & wellness, personal care & beauty, food & beverage, household goods, pet, and children's products. The Topspin team has considerable operational expertise in consumer products and services and collaborates with founder-owners and management teams to build businesses of varying stages and sizes.
Representative Investments
"We thank the Topspin team for the value and support they provided to PlayMonster as our partners over the past four years. From the beginning, they shared our view for the potential of our business and helped us execute on both our M&A and organic growth strategies."
Bob Wann, CEO of PlayMonster


text: Hi, I'm currently trying to set up a brand new home cluster : - 5 nodes, with each : - 1 HCA Mellanox ConnectX-2 - 1 GB Ethernet (Proxmox 5.1 Network Admin) - 1 CX4 to CX4 cable All together connected to a SDR Flextronics IB Switch. This setup should back a Ceph Luminous (V12.2.2 included in proxmox V5.1) On all nodes, I did: - apt-get infiniband-diags - modprobe mlx4_ib - modprobe ib_ipoib - modprobe ib_umad - ifconfig ib0 IP/MASK On two nodes (tried previously on a single on, same issue), i installed opensm ( The switch doesn't have SM included) : apt-get install opensm /etc/init.d/opensm stop /etc/init.d/opensm start (Necessary to let the daemon create the logfiles) I tailed the logfile and got a "Active&Running" Setup, with "SUBNET UP" Every node is OK regardless to IB Setup : - All ib0 are UP, using ibstat - ibhosts and ibswitches seem to be OK On a node : ibping -S On every other node : ibping -G GID_Of_Previous_Server_Port I got a nice pong reply on every node. Should be happy, but... But i never went further.. Tried to ping each other. No way to get into this (mostly probably) simple issue... Any hint to achieve this task ?? Thanks for all Best regards


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Buying a MacBook on eBay is easy and safe so long as you do your homework. Here are a few tips to make your MacBook buying experience a happy one.
1. Is it the MacBook deal for you? Avoid buying on impulse. Take your time and do your homework before committing to the deal. Buy in haste, repent at leisure
2. Does the seller have good feedback? Check the seller's history and feedback rating. Be wary of sellers with zero or low feedback or a record of bad deals. If in doubt, contact them through eBay's the 'Ask seller a question' link – your message will go through the real account owner
3. Is there enough detail in the description? Check the description carefully. You need to know the specs and the condition of the MacBook you're interested in. If there is not enough detail, ask for more. It's easy with the 'Ask seller a question' link and good sellers are happy to supply more info.
4. Is the photo adequate? Photos are the only visual information you have to judge the condition of the MacBook, and wise sellers use good pictures. If you're interested in a listing but the photo's poor, do not be afraid to ask for more. Again, good sellers are happy to supply more info.
5. What does the deal include? Ideally you'll get the MacBook with all its bits – charger and cord, remote, display adapter, install disks and manual, all in the original packaging. If it's not clear in the description, ask.
6. Is the original receipt available? This is useful to prove ownership and also in case of hardware issues if the MacBook is still in warranty.
7. Is the MacBook still in warranty? If you buy one that's less than a year old you still have the option to buy AppleCare for another two years' coverage.
8. What are the shipping costs? A deal may look cheap 'til you see the shipping fees. Do not wait until after you've bought it to discover you're being ripped off. If shipping is not stated, ask. If shipping insurance is offered, get it. If it's not, ask for it. The small extra cost is worth it for your peace of mind while your MacBook is in transit.
9. How is payment to be made? Pay by credit card or use PayPal as they provide another layer of protection in the event of a transaction going wrong.
10. A word of warning! Be wary of really cheap offers. Many eBay accounts get hijacked every year and you may be dealing with a scammer. As a rule of thumb, if it looks too good to be true, chances are it probably is.
To sum up Do not bid on impulse, do your homework and do not be afraid to ask questions.


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Another Day Brings Another National Consortium Agreement for ORCID
Yesterday, we posted about a new national implementation of ORCID in 70 universities and research centers in Italy.
Today, news of a new arrangement that will offer ORCID, "to UK higher education institutions through a national consortium arrangement operated by Jisc."
From Today's ORCID Announcement:
The agreement, negotiated by Jisc Collections, will enable universities to benefit from reduced ORCID membership costs and enhanced technical support. This should accelerate adoption and provide a smoother path to ORCID integration for UK universities
More than 50 UK universities have expressed an interest in joining an ORCID consortium in 2015, with a further 22 saying they intend to join at a later stage.
Feedback from a recent pilot study with eight UK universities showed that organisations that have adopted ORCID expect to see measurable efficiency improvements within two years of implementation – especially in internal data quality, streamlining of publications management, and enhanced reporting to funders – with accrued benefits increasing steadily over the following three to four years.
The importance of this endeavor to research is also demonstrated by the increasing number of funders requesting ORCID identifiers on grant applications. The Wellcome Trust will make ORCID a mandatory requirement from August 2015, while both HEFCE and RCUK have shown high levels of support for the initiative.
See Also: New from JISC: "Institutional ORCID Implementation and Cost-Benefit Analysis Report" (May 18, 2015)
See Also: Persistent, Global Identity for Scientists via ORCID & ORCID Pilot Project Reports From the UK (February 24, 2015)
Filed under: Data Files, Funding, Management and Leadership, News, Public Libraries, Reports
About Gary Price
Gary Price (email@example.com) is a librarian, writer, consultant, and frequent conference speaker based in the Washington D.C. metro area. He earned his MLIS degree from Wayne State University in Detroit. Price has won several awards including the SLA Innovations in Technology Award and Alumnus of the Year from the Wayne St. University Library and Information Science Program. From 2006-2009 he was Director of Online Information Services at Ask.com.


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7 Office Safety Suggestions Your Workers Require To Know
09 Oct 2018 07:55
Many hotels and neighborhood governments offer free of charge maps of the area for travelers. This is a fantastic resource that shows you the layout of the city and, because they're geared toward travelers, also show landmarks, which can be useful to know in times of civil unrest.She always personalizes her appeals: To her pals, she says, It is totally free!" To reporters, she points out that it will protect their sources. Whoever her subjects happen to be, Ms. Sandvik desires to help them fit info security into their lives with out getting to think about it.These attacks can contain trolling, threats and harassment, as well as persistent and innovative phishing emails that can look as if they come from other colleagues within the newsroom or even close friends outdoors of operate. And after a hacker gets a journalist's user names and passwords, there's nothing at all that you can do to get that information back," she said.Each and every company needs to have a security policy in location to keep staff, equipment and goods safe and safe. Having the right security measures can aid avoid and deter burglars or individuals who intend to enter the house with out permission. Security is anything to constantly be concerned about, so take the time to carry out some security checks.But exactly where do you commence? Several SMEs really feel that becoming as safe as a massive company is impossible. Corporations have large budgets, chief security officers and complete teams committed to cybersecurity. This perception stems from the impression that hacks are vastly complicated, and rely on a tireless horde of very skilled attackers. Most hacks aren't like that. The majority depend on poor passwords and a lack of awareness of what a hacker in fact needs to compromise your systems - a basic phishing email or a leaked password and they are in. It really is that straightforward.Windows ten brings with it a new interface for viewing the contents of your tough drive, creating it considerably less difficult for visit the website you to see how all of those gigabytes are getting utilized. From the Settings app, click or tap on Method, pick the Storage choice and select the drive you want to take a closer appear at — the subsequent screen breaks up utilised storage space into images, documents, videos, email, music and so on, offered all of this content is saved into the proper folders. Click or tap on a specific entry in the list for far more details. This is a tip that is more helpful on smartphones, visit the website but tablets and laptops can advantage from it as nicely: Windows 10 lets you save maps to your device in case you must lose a Wi-Fi or data connection while you are attempting to scout out the nearby location. Head to the Settings app then choose Technique and Offline maps to decide on which maps to download (each and every region comes with an estimate of how a lot storage space will be taken up). You can then launch and use the Maps app regardless of whether or not you can get on the internet.Museums and visit the website art galleries. Safety guards in these areas operate to shield the paintings and exhibits from the individuals at the museums. They may also work at a safety line near the entrances and could have to look through handbags of patrons.Factories, government buildings, and military bases. Here, the security guards not only safeguard the workers and the equipment, but they also check the credentials of the people and the vehicles that enter and leave the premises to make sure that no unauthorized individuals enter these areas.When you commence to type in the name of the recipient, some email application will suggest comparable addresses you have employed before. If you have previously emailed many men and women whose name or address begins the same way - eg Dave" - the auto-complete function may possibly bring up several Daves". Make sure you decide on the correct address prior to you click send.Factories, government buildings, and military bases. Right here, the security guards not only defend the workers and the gear, but they also verify the credentials of the men and women and the automobiles that enter and leave the premises to make confident that no unauthorized men and women enter these places.When you adored this post along with you wish to get more information concerning visit the website (caitlynbalke07877.soup.io) generously visit the website our own web site. For bigger firms with hundreds or thousands of staff, applying security updates organizationwide can be hard. If 1 employee's machine lacks the newest safety software, it can infect other machines across the company network.Windows machines and Xbox One consoles are friendlier than ever right after the roll-out of Windows 10, and a single of the new functions is the ability to stream gameplay from an Xbox 1 to a Windows 10 desktop or laptop seamlessly. To get began, allow game streaming from inside the Xbox One particular settings, then go to the Xbox app that is component of Windows ten and select Connect from the panel on the left — choose your console from the list to establish a hyperlink. For the stream to perform, each devices need to have to be on the very same regional Wi-Fi network.
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SBS is located in Steinreich, campo 38 1/2. This is 18 kilometers north of the town Alvaro Obregon (Rubio) and it is an approximate 45 minute drive from the city of Cuauhtemoc
There are nine buildings on campus. (The three newest buildings are on the far east side and are not shown on the photos. Two of these buildings are used for staff residence and one in progress of becoming a Multi-purpose building.
East Side
The dormitory on the east side of the campus has two floors. The main floor is for the girls and the second floor is for married couples. Next to it, further to the south, you find a playground for children.
West Side
The building on the west side includes the dining room, kitchen and men´s dorm. Part of the building has two floors, on the main floor you find a lounge; on the second floor is a meeting room a staff housing.
In between these two buildings is a 4-plex which is used for staff housing.
South Side
The main building is on the far south side. It includes all the class rooms, the main office, the library and the gym. In 2015 the Auditorium of the school was finished.


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Value Creation in the Offshore Wind Energy in Germany:
Distribution, Scope, Development of Market Participants and Employment
In 2011 we, wind:research, published in cooperation with WAB and PWC a widely recognized study on "Value Creation in the Offshore Wind Energy in Germany". Currently we are working on a new edition of the study to get up-to-date data and numbers for the currently ongoing political discussion in Berlin regarding the future expansion goals and the currently capped on 15 GW offshore wind expansion.
Therefore e.g. the importance of operation and services as well as further investments into the German economy are analysed and emphasised, to use profound data to influence political decision makers regarding the future of the offshore wind industry. Especially reaching decision makers from alleged "non-offshore-states" is of utmost importance, to reach a positive or at least neutral opinion on this topic. In this context, plant manufacturers, operators, service providers and associations are interviewed. We would be delighted if you take the time to answer a few questions for us and therefore increase representativity.


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Albert Einstein once mused, "If a cluttered desk is a sign of a cluttered mind, of what, then, is an empty desk a sign?" What we believe Einstein was stating here is the importance of self-expression.
Many people might be under the false assumption that recovery must be strictly administered and regimented. Here at Clearview Girls Academy, we do not believe that. Of course, we have rules and our utmost priority is keeping your child safe. At the same time, we believe it is vital to our students' recovery to express their emotions and thoughts to the fullest.
In our therapeutic boarding school, we call self-expression allowing ourselves to be "messy." After all, life is messy sometimes. What happens first, though, is that the "mess" must reveal itself. Once you know what it looks like, you'll know how best to clean it up.
The Joys of "Messiness"
You may have heard of Marie Kondo and her popular book The Life-Changing Magic of Tidying Up. In the book, Kondo discusses the importance of discarding things that don't bring you joy. Believe it or not, our policy of "messiness" is a similar concept. While for Marie Kondo, this may be deciding that a pair of socks should be thrown out. For our students, the stakes are much higher, and letting go is more abstract. They may decide that the trauma that they are holding onto is destroying their joy. Hence, it must be "thrown out." We believe trauma can only be thrown out one way: by expressing it!
At Clearview Girls Academy, we encourage our students to be authentic. We want them to be open and honest, not only with us but also with themselves. Teenagers often keep secrets buried within themselves. This is understandable. Being a teenager is a difficult time in life. When you begin to add issues like trauma, and life-controlling issues, it can be utterly miserable.
There is a saying in many 12-Step programs that "you are only as sick as your secrets." At Clearview Girls Academy, we subscribe to this belief. It takes time and trust for girls to become comfortable expressing the secrets they hold inside. This is why our program requires a one-year stay minimum. During that time, things may get a little messy for a while. Things might seem a little worse before they seem better. This is all part of the healing process.
Creating a Healthy "Mess" at Clearview Girls Academy
Granted, if you feel like your and your daughter's world is falling apart, the last word you want to hear is "messy." You may have even thought to yourself, "How are we going to get out of this mess?" This is not the type of mess we are referring to here at Clearview Girls Academy.
Yes, we are going to get messy. But that mess will be an experience that may change your and your daughter's life for the better, forever. That mess may involve going out into nature and reconnecting with the wonders that are all around them. Another type of mess may be learning how to lead a horse and connect with someone like she never thought possible. It might mean being brave and disclosing shameful thoughts.
Yes, that mess might even look scary at times. We want our students to express all of their emotions, whether they're mad, glad, sad, or afraid. Hopefully, they will express all of them at some point in their journey here. This is why we have trusted professionals who can help them when these emotions rise to the surface and feel overwhelming.
Recovery Out of Love, Not Enforcement
Tuesdays with Morrie author Mitch Albom once said, "Nothing haunts us like the things we don't say." Sadly, our children often fail to express their true feelings. If your child has shut down, they may very well be going through some emotional pain. Of course, we don't want our children to feel pain. The humbling truth is that pain is a part of life. Instead of hiding, rationalizing, or "putting a happy face" on their pain, we help our girls to expel it.
Here at Clearview Girls Academy, we believe in the teachings of Jesus Christ. Jesus said, "Love your neighbor as yourself, no other commandment is greater than these." That is why we treat all of our students with the love and compassion we would want ourselves. We don't judge the messes that girls make at our treatment center. We offer compassion. There are no exceptions here.
Also, we know it takes having experiences to truly change. No one makes lasting changes just by following rules and guidelines. It's not our policy to simply tell someone to do better, to act better, or to be better. What's more, we don't teach our students to put on a show so they can go out and play characters in the world. Instead, we help our students to grow into fully realized people.
Arriving at Authentic Self-Love
The truth is, many young women arrive at our facility with a lack of self-love. Our belief is that you can love someone until they learn to love themselves. We can help your daughter to recognize the beauty of her inner self and her true perfect spiritual nature. While she is here, we will encourage her to seek out her own truths, even when that feels difficult. From this place of increased power and authenticity, she can begin to feel self-acceptance and self-love.
We want your daughter to be as messy as she wants to be while she's here. This will help her healing process. As she grows, she can feel cleansed of all that is stopping her from becoming the greatest version of herself.
We believe self-expression is vital to a full and well-balanced recovery. At Clearview Girls Academy, we insist that our students feel entirely safe and comfortable to express themselves fully at all times. We are not here to change our students into something new and unrecognizable. We are here to help our students become the powerful young women they were always meant to be. If you feel your daughter has shut down and don't know what to do, please reach out. We are here to help her to open up, grow, and ultimately succeed. Please call Clearview Girls Academy at (888) 796-5484 for more information.


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By Lily Nothling
Aug 29, 2021
When Zoe Eaton fell pregnant during high school, she knew she wanted an abortion, but getting one didn't come without hurdles.
"I didn't expect that I was going to be pregnant at 17. It was not something I wanted for myself," Ms Eaton said. "To me, my future looked pretty bleak if I had to go through with that pregnancy."
Continued: https://www.abc.net.au/news/2021-08-30/access-to-abortion-really-difficult-in-regional-qld/100414012


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A former staff of the Savelugu National Disaster Management Organisation (NADMO), Alhassan Seidu Mahama, has been arrested over a GHS43,000 salary.
Mr Mahama, despite vacating his post, is said to have had his name on NADMO's payroll, hence receiving the amount which he did not work for.
He has received up to the tune of GHS 43,846.92 currently.
The Auditor-General in its report recommended that the former two directors at the Savelugu NADMO office, Alhassan Sulemana and Mahama Nasiru should be surcharged if action to block the salary of the defaulter is not taken.
The chairman of the Public Accounts Committee, James Avedzi Klutse, on Wednesday, therefore, inquired from the Director-General of NADMO, Nana Agyemang Prempeh, the status of the said inquiry raised in the 2018 Auditor-Generals report.
In response, Mr Prempeh told the committee Mr Mahama was on Saturday arrested to assist in investigations and retrieval of the funds.
"An embargo was first placed on the salaries of the former Directors as a way to help us get the suspect. He has written his statement and is expected to be arraigned within the week," he told the Committee.


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Q.1. Carbon exists in the atmosphere in the form of
(a) carbon monoxide only
(b) carbon monoxide in traces and carbon dioxide
(c) carbon dioxide only
(d) coal
Ans: c
Q.2. Which of the following statements are usually correct for carbon compounds? These
(i) are good conductors of electricity
(ii) are poor conductors of electricity
(iii) have strong forces of attraction between their molecules
(iv) do not have strong forces of attraction between their molecules
(a) (i) and (iii)
(b) (ii) and (iii)
(c) (i) and (iv)
(d) (ii) and (iv)
Ans: d
Carbon compounds form covalent bonds hence they have very weak force of attraction. Carbon compounds are poor conductors of electricity.
Q.3. A molecule of ammonia (NH3 ) has
(a) only single bonds
(b) only double bonds
(c) only triple bonds
(d) two double bonds and one single bond
Ans: a
Nitrogen has three electrons in its outermost shell and hydrogen has 1. 3 hydrogen atoms combine with 1 nitrogen atom to make ammonia. These bonds are single bonds.
Q.4. Buckminsterfullerene is an allotropic form of
(a) phosphorus
(b) sulphur
(c) carbon
(d) tin
Ans: c
Diamond, Graphite, Lonsdaleite, C60 (Buckminsterfullerene or buckyball), C540, C70, Amorphous carbon, and a single-walled carbon nanotube, or buckytube. Are the allotropes of Carbon.
Q.5. Which of the following are correct structural isomers of butane?
(a) (i) and (iii)
(b) (ii) and (iv)
(c) (i) and (ii)
(d) (iii) and (iv)
Ans: c
Chemical formula of Butane isC4H10, here option iii) and iv) have 8 hydrogen atoms, hence they are wrong.
Q.6. CH3 – CH2 – OH Alkaline KMnO Heat 4 + → CH3 – COOH
In the above-given reaction, alkaline KMnO4 acts as
(a) reducing agent
(b) oxidising agent
(c) catalyst
(d) dehydrating agent
Ans: b
Two Hydrogen atoms are replaced by an atom of oxygen making oxidation of ethanol. Here addition of oxygen is provided by potassium.
Q.7. Oils on treating with hydrogen in the presence of palladium or nickel catalyst form fats. This is an example of
(a) Addition reaction
(b) Substitution reaction
(c) Displacement reaction
(d) Oxidation reaction
Ans: a
Here Hydrogen is added to oil, hence it is an addition reaction.
Q.8. In which of the following compounds, — OH is the functional group?
(a) Butanone
(b) Butanol
(c) Butanoic acid
(d) Butanal
Ans: b
Compound with OH Functional group will have a suffix ol in them hence answer is (b) Butanol.
Q.9. The soap molecule has a
(a) hydrophilic head and a hydrophobic tail
(b) hydrophobic head and a hydrophilic tail
(c) hydrophobic head and a hydrophobic tail
(d) hydrophilic head and a hydrophilic tail
Ans: a
Because of hydrophobic tail Oil and grease is trapped inside a micelle. Hydrophobic head makes the outer surface of micelle. Hence micelle is easily washed by water.
Q.10. Which of the following is the correct representation of the electron dot structure of nitrogen?
Ans: d
In this structure Nitrogen atoms get 8 electrons whereas in other options it is different.
Q.11. Structural formula of ethyne is
(a) H - C ≡ C - H
(b) H3 - C ≡ C - H
Ans: a
Chemical formula of Ethyne is C2H2, Hence answer is a)
Q.12. Identify the unsaturated compounds from the following
(i) Propane
(ii) Propene
(iii) Propyne
(iv) Chloropropane
(a) (i) and (ii)
(b) (ii) and (iv)
(c) (iii) and (iv)
(d) (ii) and (iii)
Ans: d
Propene has double bond and Propyne is having a triple bond. Hence they are unsaturated compounds.
Q.13. Chlorine reacts with saturated hydrocarbons at room temperature in the
(a) absence of sunlight
(b) presence of sunlight
(c) presence of water
(d) presence of hydrochloric acid
Ans: b
In the presence of sunlight, Chlorine reacts with Hydrocarbons and displaces Hydrogen atoms.
Q. 14. In the soap micelles
(a) the ionic end of soap is on the surface of the cluster while the carbon chain is in the interior of the cluster.
(b) ionic end of soap is in the interior of the cluster and the carbon chain is out of the cluster.
(c) both ionic end and carbon chain are in the interior of the cluster
(d) both ionic end and carbon chain are on the exterior of the cluster
Ans: a
A micelle is a spherical aggregate soap molecules in soap solution. In the soap micelles, the ionic end of soap is on the surface of the cluster while the carbon chain is in the interior of the cluster.
Q.15. Pentane has the molecular formula C5 H12. It has
(a) 5 covalent bonds
(b) 12 covalent bonds
(c) 16 covalent bonds
(d) 17 covalent bonds
Ans: c
Q.16. Structural formula of benzene is
Ans: c
Chemical formula of Benzene is C6H6. In option call the arms of carbon atoms are occupied hence it is the right answer.
Q.17. Ethanol reacts with sodium and forms two products. These are
(a) sodium ethanoate and hydrogen
(b) sodium ethanoate and oxygen
(c) sodium ethoxide and hydrogen
(d) sodium ethoxide and oxygen
Ans: c
2Na+2CH3CH2OH →2CH3CH2ONa+H2
Q.18. The correct structural formula of butanoic acid is
Ans: d
Q.19. Vinegar is a solution of
(a) 50% – 60% acetic acid in alcohol
(b) 5% – 8% acetic acid in alcohol
(c) 5% – 8% acetic acid in water
(d) 50% – 60% acetic acid in water
Ans: c
Q.20. Mineral acids are stronger acids than carboxylic acids because
(i) mineral acids are completely ionised
(ii) carboxylic acids are completely ionised
(iii) mineral acids are partially ionised
(iv) carboxylic acids are partially ionised
(a) (i) and (iv)
(b) (ii) and (iii)
(c) (i) and (ii)
(d) (iii) and (iv)
Ans: a
Mineral acids are completely ionized whereas carboxylic acids are partially ionized. Hence mineral acids are stronger than carboxylic acids.
Q. 21. Carbon forms four covalent bonds by sharing its four valence electrons with four univalent atoms, e.g. hydrogen. After the formation of four bonds, carbon attains the electronic configuration of
(a) helium
(b) neon
(c) argon
(d) krypton
Ans: b
After sharing four valence electrons with univalent atoms. Electronic configuration of Carbon becomes 2.8 which is same as the electronic configuration of Neon.
22. The correct electron dot structure of a water molecule is electron dot structure of a water molecule
Ans: c
Option c) represents a complete octet configuration. Hence it is the right answer.
23. Which of the following is not a straight-chain hydrocarbon?
Ans: d
Q. 24. Which among the following are unsaturated hydrocarbons?
(a) (i) and (iii)
(b) (ii) and (iii)
(c) (ii) and (iv)
(d) (iii) and (iv)
Ans: c
Option (ii) and (iv )having double and triple bonds, hence they are unsaturated hydrocarbons.
Q.25. Which of the following does not belong to the same homologous series?
(a) CH4
(b) C2 H6
(c) C3 H8
(d) C4 H8
Ans: d
General formula for C4H8 is CnH2n and for other option it is CnH2n+2
Q.26. The name of the compound CH3 — CH2 — CHO is
(a) Propanal
(b) Propanone
(c) Ethanol
(d) Ethanal
Ans: a
This compound has 3 carbon atoms and an aldehyde which add suffix al to 3 carbon compound.
Q.27. The heteroatoms present in CH3 — CH2 — O — CH2— CH2 Cl are
(i) oxygen
(ii) carbon
(iii) hydrogen
(iv) chlorine
(a) (i) and (ii)
(b) (ii) and (iii)
(c) (iii) and (iv)
(d) (i) and (iv)
Ans: d
Oxygen and chlorine are not among essential components of Hydrocarbon hence they are heteroatoms.
Q.28. Which of the following represents the saponification reaction?
(a) CH3COONa + NaOH → CH4 + Na2CO3
(b) CH3COOH + C2H5OH → CH3COOC2H5 +H2O
(c) 2CH3COOH + 2Na → 2CH3 COONa + H2
(d) CH3COOC2H5 + NaOH → CH3 COONa + C2H5OH
Ans: d
Saponification is a reaction in which ethanol and sodium ethanoate are produced upon treatment of ester with an alkali.
Q.29. The first member of the alkyne homologous series is
(a) ethyne
(b) ethene
(c) propyne
(d) methane
Ans: b
Q.30. Draw the electron dot structure of ethyne and also draw its structural formula.
It is the electron dot structure of ethyne (C2H2)
is its structural formula.
Q.31. Write the names of the following compounds.
(a) Pentanoic acid
(b) But-1-yne
(c) Heptanal
(d) pentan-1-ol
Q.32. Identify and name the functional groups present in the following compounds.
Functional group | Name |
(a) | Alcohol |
(b) | Carboxylic acid |
(c) | Ketone |
(d) | Alkene |
Q.33. A compound X is formed by the reaction of a carboxylic acid C2H4O2 and an alcohol in presence of a few drops of H2SO4. The alcohol on oxidation with alkaline KMnO4 followed by acidification gives the same carboxylic acid as used in this reaction. Give the names and structures of
(a) Carboxylic acid
(b) Alcohol and
(c) The compound X.
Also write the reaction.
(a) Carboxylic acid is ethanoic acid (CH3COOH)
(b) Alcohol is ethanol (C2H5OH).
(c) 'X' is ethyl ethanoate (CH3COOC2H5)
Q.34. Why are detergents better cleansing agents than soaps? Explain.
Ans. It is because detergents form a lot of lather even with hard water. Hard water contains Ca2+ and Mg2+ ions which react with soap to form insoluble salts of calcium and magnesium called scum and soap goes waste. Detergents do not form insoluble compounds with Ca2+ and Mg2+ ions, therefore these are more effective.
Q.35. Name the functional groups present in the following compounds.
(a) CH3COCH2CH2CH2CH3
(b) CH3CH2CH2COOH
(c) CH3 CH2 CH2 CH2CHO
(d) CH3CH2OH
(a) Ketone
(b) Carboxylic acid
(c) Aldehyde
(d) Alcohol
Q.36. How is ethene prepared from ethanol? Give the reaction involved in it.
Ans. Ethanol is heated at 443k along with excess Sulphuric acid to obtain Ethene.
Q.37. Intake of small quantity of methanol can be lethal. Comment.
Ans. Methanol is oxidised to methanal in liver. Methanal is highly reactive and good reducing agent. It causes protoplasm to coagulate. It also affects the optic nerve and leads to blindness.
Q.38. A gas is evolved when ethanol reacts with sodium. Name the gas evolved and also write the balanced chemical equation of the reaction involved.
Ans: When ethanol reacts with sodium it gives Sodium ethoxide with the liberation of hydrogen gas.
2CH3- CH2-OH +2Na——>2 CH3- CH2- ONa + H2
Q.39. Ethene is formed when ethanol at 443K is heated with excess of concentrated sulphuric acid. What is the role of sulphuric acid in this reaction? Write the balanced chemical equation of this reaction.
Ans: Sulphuric acid acts as a catalyst and a dehydrating agent in the formation of ethene.
Q.40. Carbon, Group (14) element in the Periodic Table is known to form compounds with many elements. Write an example of a compound formed with:
(a) Chlorine (Group 17 of Periodic Table)
(b) Oxygen (Group 16 of Periodic Table)
(a) CCl4 (Carbon tetrachloride)
(b) CO2 (Carbon dioxide)
Q.41. In electron dot structure, the valence shell electrons are represented by crosses or dots.
(a) The atomic number of chlorine is 17.
Write its electronic configuration.
(b) Draw the electron dot structure of chlorine molecule.
(a) Cl(17)
Electronic configuration:
Q.42. Catenation is the ability of an atom to form bonds with other atoms of the same element. It is exhibited by both carbon and silicon. Compare the ability of catenation of the two elements. Give reasons.
Ans. Carbon shows catenation to a large extent as compared to silicon as well as any other element due to smaller size of carbon. C—C bond is stronger than Si-Si bond because Si is larger in size, so it forms a weaker bond.
Q.43. Unsaturated hydrocarbons contain multiple bonds between the two C-atoms and show addition reactions. Give the test to distinguish ethane from ethene.
Ans. Add bromine water. Ethane will not react. Ethene will decolourise bromine water.
Alternative Method:
Combustion test:
Ethane, a saturated hydrocarbon, will bum with blue flame which is non-smoky, whereas ethene, an unsaturated hydrocarbon, will bum with yellow flame which is smoky due to the presence of unburnt carbon particles.
Q.44. Match the reactions given in Column (A) with the names given in Column (B).
(a) - (iv) Esterification reaction because ester is being formed from carboxylic acid and alcohol.
(b) - (i) Addition reaction as hydrogen is being added.
(c) - (ii) Substitution reaction because hydrogen of methane is being substituted by chlorine atom.
(d) - (iii) Neutralisation reaction because acetic acid reacts with sodium hydroxide to form salt and water.
Q.45. Write the structural formulae of all the isomers of hexane.
Q.46. What is the role of metal or reagents written on arrows in the given chemical reactions?
(a) Ni is used as a catalyst
(b) Cone. H2SO4 acts as a dehydrating agent.
(c) Alkaline KMnO4 is an oxidising agent.
Q.47. A salt 'X' is formed and a gas is evolved when ethanoic acid reacts with sodium hydrogen carbonate. Name the salt 'X' and the gas evolved.
Describe an activity and draw the diagram of the apparatus to prove that the evolved gas is the one which you have named. Also write the chemical equation of the reaction involved.
The salt 'X' is sodium ethanoate. The gas evolved is CO2.
Pass the gas through lime water. It will turn milky. It shows that gas evolved is CO2.
Ca(OH)2 + CO2→ CaCO3 + H2O
Aim: To demonstrate the reaction of carboxylic acid with sodium carbonate and sodium hydrogencarbonate.
Materials Required: Ethanoic acid , sodium carbonate, sodium hydrogen-carbonate, lime water.
1. Set the apparatus as shown in diagram.
2. Take 1g of Na2CO3 and add 2 ml of ethanoic acid into it.
3. Pass the gas formed through lime water and note down the observations.
4. Repeat the same procedure with sodium hydrogen-carbonate and record your observations.
Fig: Evolution of Carbon dioxide Gas by Reaction of Ethanoic Acid with Sodium Hydrogen Carbonate
Observation: Brisk effervescence due to carbon dioxide formed which turns lime water milky.
Chemical Reaction:
2CH3COOH(l) + Na2CO3(s) → 2CH3COONa(aq) + H2O(l) + CO2(g)
CH3COOH(l) + NaHCO3 → CH3COONa(aq) + H2O(l) + CO2(g)
Conclusion: Carboxylic acid reacts with sodium carbonate and sodium hydrogencarbonate to liberate CO2 gas which turns lime water milky.
(a) What are hydrocarbons? Give examples.
(b) Give the structural differences between saturated and unsaturated hydrocarbons with two examples each.
(c) What is a functional group? Give examples of four different functional groups.
(a) Hydrocarbons are the compounds made up of carbon and hydrogen atoms only, e.g. CH4 (methane), C2H6 (ethane), CH2= CH2 (ethene), etc.
(b) Saturated hydrocarbons contain single covalent bonds only, and (ethane) are saturated hydrocarbons.
Unsaturated hydrocarbons contain double or triple covalent bonds, e.g.
(c) Functional group is an atom or group of atoms or reactive part of the compound which determines chemical properties of the those compounds, e.g.
(i) —OH (Alcohol)
CH3CH2OH (Ethanol)
Q.49. Name the reaction which is commonly used in the conversion of vegetable oils to fats. Explain the reaction involved in detail.
Addition reaction is involved in the conversion of oils into fats. This process is known as Hydrogenation. Here Unsaturated vegetable are converted to saturated fats which have saturated carbons.
Nickel is used as a catalyst in the hydrogenation process and the reaction is given below
Q.50. (a) Write the formula and draw the electron dot structure of carbon tetrachloride.
(b) What is saponification? Write the reaction involved in this process.
(a) Carbon tetrachloride- CCl4
(b) When an ester is heated with sodium hydroxide solution, ester gets hydrolyzed (breaks down) to form the parent alcohol and sodium salt of carboxylic acid.
CH3COOCH3 + NaOH → CH3COONa+CH3OH
Q.51. Esters are sweet smelling substances and are used in making perfumes. Suggest one activity and the reaction involved for the preparation of ester with a well labelled diagram.
Materials Required : Beaker, water, test tube, ethanol, acetic acid, conc. H2SO4, tripod stand, burner, wire gauze, etc.
1. Take 2 ml of ethanol in a test tube.
2. Add 2 ml of ethanoic acid (acetic acid) into it.
3. Add few drops of cone. H2SO4.
4. Warm it in a beaker containing water.
5. Observe the smell of the products formed.
Fig: Reaction of dil. CH3COOH and Ethonal in the presence of conc. H2SO4 - formation of ester
Observations: Pleasant fruity smelling compound (called ester) is formed.
Chemical Reaction Involved:
Conclusion: Carboxylic acid reacts with alcohol in presence of conc. H2SO4, which acts as a dehydrating agent to form esters.
Q.52. A compound 'C' (molecular formula, C2H4O2) reacts with Na-metal to form a compound 'R' and evolves a gas which burns with a pop sound.
Compound 'C' on treatment with an alcohol 'A' in presence of an acid forms a sweet smelling compound 'S' (molecular formula C3H6O2). On addition of NaOH to 'C', it also gives R' and water. 'S' on treatment with NaOH solution gives back 'R' and 'A'. Identify 'C', 'R' 'A', 'S ' and write down the reactions involved.
H2 gas burns with 'pop' sound
'C' is ethanoic acid, 'R' is sodium ethanoate, 'A' is methanol and 'S' is methyl ethanoate.
Q.53. Look at figure and answer the following questions:
(a) What change would you observe in the calcium hydroxide solution taken in tube 'B' ?
(b) Write the reaction involved in test tubes 'A' and 'B' respectively.
(c) If ethanol is given instead of ethanoic acid, would you expect the same change?
(d) How can a solution of lime water be prepared in the laboratory?
(a) Lime water will turn milky.
(b) Test tube A:
2CH3COOH(l) + Na2CO3(s) → 2CH3COONa(aq) + H2O(l) + CO2(g)
Test tube B:
Ca(OH)2(aq) + CO2(g) → CaCO3(s) + H2O(l)
(c) Ethanol will not react with Na2CO3.
(d) Add Ca(OH)2 in water, shake it well. Filter the solution. The filtrate is lime water.
Q.54. How would you bring about the following conversions? Name the process and write the reaction involved.
(a) Ethanol to ethene
(b) Propanol to propanoic acid
The reaction is called dehydration.
The reaction is called oxidation.
Q.55. Draw the possible isomers of compound with molecular formula C3H6O and also give their electron dot structures. [CBSE Sample Paper 2018]
Ans: C3H6O represents aldehyde as well as ketone.
Q.56. Explain the given reactions with the examples
(a) Hydrogenation reaction
(b) Oxidation reaction
(c) Substitution reaction
(d) Saponification reaction
(e) Combustion reaction
(a) Hydrogenation reaction: When hydrogen is added to unsaturated hydrocarbons having double or triple bond in presence of Ni as catalyst, the reaction is called hydrogenation, e.g.
(b) Those reactions in which oxygen is added or hydrogen is removed are called oxidation reactions, e.g.
(c) Substitution reaction: The reaction in which one or more atoms of compound is replaced by another atom or group of atoms, it is called substitution reaction, e.g.
(d) Saponification reaction: When an ester reacts with sodium hydroxide to form sodium salt of carboxylic acid and alcohol, it is called saponification, e.g.
(e) Combustion reaction : When an organic compound burns in presence of air to form CO2 and H2O along with heat and light is called combustion reaction, e.g.
Q.57. An organic compound 'A' on heating with conc. H2SO4 forms a compound B, which on addition with 1 mole of hydrogen in presence of Ni forms a compound 'C' One mole of compound 'C' on combustion forms two moles of CO2 and 3 moles of H2O. Identify the compounds A, B and C and write the chemical equation of the reactions involved. [HOTS]
Ans. The compounds are as follows:
A—Ethanol, B—Ethene, C—Ethane
105 videos|457 docs|112 tests
1. What is carbon and its compounds? |
2. Why is carbon considered unique? |
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CFMEU chief loses entry rights as watchdog targets leadership
The powerful head of the Queensland CFMEU has lost his right to enter worksites after he was forced to comb through more than a decade of emails and documents to prove he did not condone law-breaking and was not paying his officials' fines.
Michael Ravbar, secretary of the Construction, Forestry, Maritime, Mining and Energy Union's Queensland construction branch, abandoned his bid for an entry permit last week in the face of the building industry watchdog's new strategy to hold the union's leadership to account for their officials' misconduct.
The move means almost the entire CFMEU leadership has now lost their entry permits, including Victorian secretary John Setka, NSW secretary Darren Greenfield, West Australian secretary Mick Buchan and South Australia head Andrew Sutherland.
ACT chief Jason O'Mara had his permit suspended for three months, but that ended last week.
Australian Building and Construction Commissioner Stephen McBurney said the watchdog had sought to hold the CFMEU leadership to "a higher standard", and it would continue to do that for future permits.
He said Mr Ravbar has failed to take "meaningful or effective steps to curb the repeated contravening conduct of union officials".
"This is a failure of governance by Mr Ravbar," he said.
ABCC's new approach
The ABCC traditionally intervenes in the Fair Work Commission to challenge construction union officials' permit applications by citing their law-breaking conduct.
However, it took on a new approach this year by using Mr Ravbar's leadership position against him and arguing he should be denied a permit because he had presided over "a history of defiance of industrial laws".
While Mr Ravbar had been fined for unlawful industrial conduct in the past, it was only $5000, and over a matter that occurred almost a decade ago.
But under his leadership, Queensland officials had breached industrial laws on 175 occasions in 28 separate proceedings.
The ABCC argued the officials' conduct reflected on Mr Ravbar and claimed he condoned their law-breaking by paying their fines, which it said was "inconsistent with what is expected of a permit holder" and was "undermining the purpose of such penalties".
The watchdog said Mr Ravbar had made no real effort to improve compliance in the branch, and that "such governance is virtually non-existent".
Its submissions cited a Federal Court judgment from 2014 on the Queensland branch that said the CFMEU's history of law-breaking meant "the only reasonable conclusion to be drawn is that the organisation either does not understand or does not care for the legal restrictions on industrial activity imposed by the legislature and the courts".
In a key development in May, the Fair Work Commission granted the ABCC's proposed orders that Mr Ravbar provide emails and documents covering the past 14 years of his leadership to assess if he had sought to temper his organisation's rule-breaking ways.
Mr Ravbar produced the documents and was set to be cross-examined in a two-day hearing starting next week, but in a surprise development withdrew his application just days beforehand, despite fighting the case for the past four months.
Mr McBurney said "the law provides that only individuals who pass the fit and proper person test are eligible to hold a federal right-of-entry permit".
"This is a diminishing number among the senior leadership of this particular union."
The CFMEU has been contacted for comment.
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Each villa represents very good value at 7.75MB7750000.00
- Country: Thailand
- Province / State: Hua Hin Central
- City / Town: Hua Hin Central
- Neighborhood: Hua Hin Central


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"This agreement is a step forward in recognising the significant contribution that diaspora communities make in time of emergencies and crises" says IOM UK's Head of Office Tauhid Pasha.
Diasporas have long been engaged in humanitarian assistance in multiple ways, including by contributing financial resources, skilled volunteering, in-kind donations as well as by mobilising social, political and cultural capital. In times of crisis or during emergencies, diaspora members are often among the first responders, but they also contribute their skills and expertise to support the transition from crisis to post-crisis phases, ensuring the sustainability of actions and increasing the localisation of assistance.
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Besides strengthening the cooperation between IOM and Shabaka on research projects and events related to diaspora participation and humanitarianism, this agreement contributes to the advancement of national and global frameworks towards effective development and humanitarian action.
Bashair Ahmed, CEO at Shabaka and Tauhid Pasha, IOM UK's Head of Office
• Find out more about diaspora engagement in times of crisis
• IOM's iDiaspora provides a platform for the global diaspora community to share their experiences, knowledge and ideas of how and where they can engage.
• The Diaspora Engagement in Humanitarian Assistance webinar series, jointly organised by IOM, Shabaka and ADEPT explored different perspectives on diaspora humanitarianism.
• The Framework for Diaspora Engagement in Humanitarian Assistance is a suggested guide to support more streamlined coordination among Diasporas and Institutional Humanitarian Actors towards more effective humanitarian assistance worldwide.
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APCO Files a Project Initiation and Seeks Working Group Members to Revise the American National Standard Minimum Training Standard for Public Safety Telecommunicator
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For investors eyeing to invest in the food processing business, Odisha offers an exclusive investment opportunity as it is fortunate to have varied agro-climatic zones and 11 per cent of India's water resource and offers ready-to-move infrastructure setup, said state Industries Department on Wednesday in a national webinar.
Participating in the Invest India webinar on 'Food Processing Opportunities in the Indian States', the national investment promotion and facilitation agency of the Odisha Industries Department offered advantages to choose Odisha among other states of India.
'With an award-winning investment-friendly portal GO SWIFT for investment facilitation and state of the art Industrial infrastructure, Odisha is taking rapid strides in development if food processing sector which is identified as a focus sector in Odisha" said Hemant Sharma, Principal Secretary, Department of Industries, Government of Odisha during the presentation.
"The Food park at Khordha houses many food processing companies, including the multinational Indo-Nissin and produces varieties of processed foods such as soft drinks, biscuits and noodles among other things," he added.
Hemant Sharma also mentioned that the Japanese food processing giant Indo Nissin with its brands such as Top Ramen, has been operating out of Khordha food park for last 30 years and it is in the process of setting up its second unit in the same vicinity, which will be their largest unit in India.
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"We have one of the best manufacturing efficiencies at Odisha which is a benchmark for us. With the expansion of our facilities at Khordha, we will have our largest facility in the country at Odisha. The noodle maker has so far invested $20 million in its manufacturing units in Odisha and will continue to do so," he added.
Captain Dibya Shankar Mishra, Minister for Energy, MSME at the event said food processing offers opportunities for employment directly and indirectly.
"Sourcing the locally produced fruits and other ingredients will benefit rural and especially tribal women of the state. I would request the investors to choose Odisha for food processing investment which has the potential to change lives and empower the rural and tribal women," he added.


text: Just as a warning: changing commits after the fact can cause git.webkit.org to get out of sync (it can mirror before the username change goes through). I don't think that's a reason to not make a change like this, but it would be good to figure out how to handle this before you make it live. On Wed, Mar 17, 2010 at 4:42 PM, Eric Seidel <eric at webkit.org> wrote: > Woh. Looks like this is the real deal: > https://svn.apache.org/repos/asf/subversion/trunk/contrib/server-side/svn-tweak-author.py > > I'll work with Bill and see if we can wire up some magic. :) > > -eric > > On Wed, Mar 17, 2010 at 4:40 PM, Eric Seidel <eric at webkit.org> wrote: >> http://home.introweb.nl/d/dodger/svnauthor.html >> >> Could it be? Anyone know if that could actually work for changing >> authorship after-the-fact? >> >> -eric >> > _______________________________________________ > webkit-dev mailing list > webkit-dev at lists.webkit.org > http://lists.webkit.org/mailman/listinfo.cgi/webkit-dev >