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Document Type : Original Article
Organic and Nano Group (ONG), Department of Chemistry, Iran University of Science and Technology (IUST), PO Box 16846-13114, Tehran, Iran
In this report, an IRMOF-3 was prepared via a solvothermal method, and a post-synthesis modification approach was employed for its Schiff-base functionalization with salicylaldehyde (SI). Next, Pd(II) ions were encapsulated into the pores of the Schiff-base modified MOF by an impregnation method. Reduction of Pd(II) to Pd NPs was performed by two distinct methods, namely reduction by NaBH4 and reduction in ethanol. This study showed that the reduction of Pd NPs in ethanol solution resulted in larger NPs with better dispersity between the layers of the catalyst. In comparison, the reduction of Pd NPs with the NaBH4 resulted in smaller NPs, positioning into the pores of the IRMOF-3 structure, which reduced the leaching of the catalyst. IRMOF-3-SI-Pd NPs was characterized with FT-IT, XRD, SEM, and TEM techniques. The results showed that the Schiff-base functionality of MOF helped stabilization of the Pd entities, and the catalyst successfully synthesized and preserved its structure during the synthesis and application steps. The synthesized IRMOF-3-SI-Pd NPs was used as a catalyst for the Suzuki cross-coupling reaction, which exhibited promising results.
Graphical Abstract
Main Subjects
Organic synthesis has long been a fascinating area of study in chemistry [1, 2]. In particular, carbon-carbon synthesis strategies that yield more robust and complex molecules are a hot topic in this area [3]. Akira Suzuki, the Nobel prize laureate who discovered Suzuki cross-coupling reactions, developed one of the most widely used protocols to form carbon-carbon bonds [4, 5]. Availability, stability, and sustainability of precursors, along with a mild condition and applicability for a wide range of substrates possessing various functional groups, are the main reasons for the popularity of Suzuki cross-coupling reactions [6].
In organic solvents and, more recently, in aqueous environments, soluble palladium (Pd) complexes have been used to promote these reactions [7, 8]. Although homogeneous catalysts have proved great activity and selectivity, their laborious separation procedure has driven researchers to employ heterogeneous catalysts [9]. Heterogenization of homogeneous catalysts on solid supports with high surface area seems to be a reasonable choice to overcome such obstacles [10]. To date, various heterogeneous solid supports, including graphene, graphene oxide, perovskites, metal-organic frameworks, etc., have been employed for the heterogenization of soluble metal nanoparticles (NPs) [11–13].
Metal-organic frameworks (MOFs) are porous crystalline reticular materials with ultrahigh surface area, tunable structure, and permanent porosity [14, 15]. These materials can be constructed from various inorganic nodes and almost infinite organic linkers, which cause their exceptional structural diversity and chemical tunability. Such features lead to their broad application in catalysis, electrocatalysis, photocatalysis, separation, drug delivery, organic transformations, etc. [16, 17]. Among theme IRMOF-3 (isoreticular MOF-3 as an isoreticular structure of MOF-5), constructed from the amino-functionalized terephthalic acid (H2ATA), linker and octahedral [Zn4O]6+ inorganic nodes have attracted a great deal of attention due to their high porosity and increased stability [18–20]. Amine functionality of organic linker in IRMOF-3 structure heightens its water resistance and provides the opportunity for the post-synthesis modification (PSM) of MOF structure [21–23].
Here, we prepared IRMOF-3 through a solvothermal synthesis method and employed the post-synthesis modification strategy for the Schiff-base functionalization of MOF with salicylaldehyde ligand (IRMOF-3-SI). Finally, an impregnation method was hired to incapsulate palladium ions (Pd2+) into the cavities of MOF, followed by a reduction to Pd NPs with NaBH4 reductant and also a reduction in ethanol. Structural studies with FT-IR spectroscopies showed that the Schiff-base pendants helped stabilize Pd(II) ions. Synthesized IRMOF-3-SI-PdNPs was successfully employed to promote Suzuki cross-coupling of various aromatic compounds, which showed promising results.
Materials and Methods
Chemicals and apparatus
Zinc(II) nitrate hexahydrate (Zn(NO3)2), amino-functionalized terephthalic acid (H2ATA), salicylaldehyde, palladium(II) acetate (Pd(OAc)2), sodium borohydride (NaBH4), ethanol, N,N-dimethyl formamide (DMF), CHCl3, and CH2Cl2 were purchased from Merck.
Synthesis of IRMOF-3
To prepare IRMOF-3, 12.5 mmol of Zn(NO3)2 (2.36 g) and 4.1 mmol H2ATA (0.74 g) were dissolved in 100 mL dry DMF. A Teflon-lined autoclave was used to seal the solution and keep it at 100 °C for 17 hours after being stirred for 60 minutes at room temperature. Following the formation of brown solids, DMF and CHCl3 were used to wash the synthesized IRMOF-3, and then 60 °C vacuum drying was used to dry the solids.
Synthesis of IRMOF-3-SI
First, 1 g IRMOF-3 was dispersed in a 15 mL CH2Cl2 solution. In another vessel, 107 µL of salicylaldehyde (1mmol) was dissolved in a 15 mL CH2Cl2 solution and added to the dispersed IRMOF-3 solution. Finally, the yellow solid was collected by centrifugation and dried at 60 °C in a vacuum.
Synthesis of IRMOF-3-SI-Pd(II) and IRMOF-3-SI-Pd NPs
First, 0.5 g of synthesized IRMOF-3-SI and 20 mg Pd(OAc)2 were added to a 6 mL acetonitrile solution. The mixture was vigorously stirred for six hours to stabilize Pd(II) ions in the MOF cavities. Then, the IRMOF-3-SI-Pd(II) was collected by centrifugation and dried at 60 °C in a vacuum.
Two different methods were employed for the preparation of IRMOF-3-SI-PdNPs. In the first method, IRMOF-3-SI-PdNPs were prepared by refluxing IRMOF-3-SI-Pd(II) in an ethanol solution for 24 h. In the second method, 0.5 g IRMOF-3-SI-Pd(II) was dispersed in 5 mL of solvent, and then 0.3 g of NaBH4 solution was added to this mixture. To ensure complete reduction of Pd(II) to Pd(0), this solution was vigorously stirred for 2 h. Finally, IRMOF-3-SI-Pd NPs were collected by centrifugation, washed, and dried at 60 °C in a vacuum.
General Suzuki cross-coupling procedure
Aryl halide (1 mmol), phenylboronic acid (1 mmol), and potassium carbonate (2 mmol) were dissolved in a 3 mL DMF/H2O solution. Then, 0.5 mol% Pd encapsulated IRMOF-3 was added to this solution as a catalyst, and the solution was refluxed at 80 °C. Solid products were separated from the solution using CH2Cl2 and distilled water. Column chromatography was used for the purification of the products. The concentrated products were added to the silica gel column and extracted by EtOAc in an n-hexane (3:10) solution.
Results and Discussions
Scheme 1 illustrates preparation steps of IRMOF-3, IRMOF-3-SI, IRMOF-3-SI-Pd(II), IRMOF-3-SI-Pd NPs prepared by the reduction in ethanol and IRMOF-3-SI-PdNPs prepared via reduction by NaBH4.
The FT-IR spectra of a series of IRMOF-3 PSM are presented in Figure 1. In the case of IRMOF-3, the peaks that appeared at 3359 and 3470 cm-1 are related to the amino group of the organic linker. The peaks at 1385 and 1575 cm-1 represent the C-O group of carboxylic acid. The sharp peaks at 1421, 1496, and 1656 cm-1 show the C=C bonds of the aromatic ring. The peak at 1257 cm-1 is related to the C-N bond between the aromatic ring and the amino group. FT-IR spectra of IRMOF-3-SI show a decrease in the intensity of -NH2 peaks that appeared at 3359 and 3470 cm-1. Also, the peak related to the C-N bond red-shifted to 1250 cm-1. As can be seen from these two differences, post-synthesis modification was a success. Furthermore, the week peak appeared at 1490 cm-1, showing the formation of an azomethine group. The FT-IR spectra of IRMOF-3-SI-Pd NPs show a decrease in the intensity of the peaks related to the -NH2 group and the azomethine group, which prove the coordination of Pd NPs to these functional groups.
Scheme 1: Schematic synthesis of IRMOF-3-SI-PdNPs
Figure 1: FT-IR spectra of IRMOF-3, IRMOF-3-SI, and IRMOF-3-SI-PdNPs
The crystallinity and the phase purity of the synthesized IRMOF-3, IRMOF-3-SI, and IRMOF-3-SI-Pd NPs were investigated by X-ray diffraction analysis (XRD) (Figure 2). The XRD pattern of the IRMOF-3 shows sharp peaks, which proves the crystallinity of the synthesized MOF. Also, the position of the peaks are in good coordination with reported examples, which proves the successful formation of the structure. The ZnO lattice parameters were compatible with the JCPDS-36-1451 dataset and may be used to index a hexagonal wurtzite structure. The XRD patterns of modified MOF show that even after the post-synthesis modification of IRMOF-3 with salicylaldehyde ligand and reduction of Pd NPs, the crystallinity of IRMOF-3 was preserved.
Figure 2: XRD pattern of IRMOF-3, IRMOF-3-SI, and IRMOF-3-SI-PdNPs
The morphology of as-synthesized MOFs was investigated by scanning electron microscope (SEM) images. Figure 3a and 3b show the sheet-like morphology of bare IRMOF-3 by studies of optical photomicrograph and SEM analysis of MOF. In this structure, noncovalent interactions such as hydrogen bondings, π-π interactions, and aromatic-metal interactions between the IRMOF-3 layers led to the aggregation of the MOF. The SEM image of IRMOF-3-SI shows that even after its post-synthesis modification with salicylaldehyde, the sheet-like morphology of IRMOF is preserved (Figure 3c). Figure 3d images show the IRMOF-3-SI-PdNPs surface. This image indicates that after the reduction of Pd NPs, the relatively smooth surface of IRMOF-3 becomes extremely rough.
Figure 3: (a, b) Optical photomicrograph and SEM images of IRMOF-3 [18], (c) SEM image of IRMOF-3-SI (d) SEM image of IRMOF-3-SI-Pd NPs
The transmission electron microscopy (TEM) image of IRMOF-3-SI-Pd NPs is represented in Figure 4. This image demonstrates that Pd NPs with a size distribution between 4-12 nm were obtained, which indicates that the Pd NPs are formed between the layers of MOF on its outer surface. This image also indicates that the proposed support perfectly prevented the aggregation of the NPs, and Pd NPs are perfectly dispersed through the entire IRMOF-3-SI support.
Figure 4: TEM images of IRMOF-3-SI-PdNPs prepared by the reduction in ethanol
The reaction between 4-bromoacetophenone and phenylboronic acid was chosen as the model reaction to test the efficiency of three catalysts (IRMOF-3-SI-Pd(II), IRMOF-3-SI-Pd NPs reduced by NaBH4 and alcohol) in the Suzuki coupling reaction (Scheme 2). There were no discernible differences in the catalytic activity of these three catalysts. The efficiencies of the products produced from all three catalysts were quite similar, and the only difference was in the time of the reaction.
Scheme 2: The fragmentation pattern of ligand (LH)
Various conditions, including the base, solvent, mol% of loaded Pd on the MOF, and the reusability of the catalyst, were tested to obtain the optimized condition for the Suzuki cross-coupling reaction. We initiate our study by selecting the best base for this reaction. In this regard, several bases, including K2CO3, NaOAc, Na2CO3, and Cs2CO3, were used as a base in the model reaction, in which K2CO3 and Cs2CO3 showed the most promising results. Next, the progress of the reaction in various solvents, including DMF, toluene, MeOH, EtOH, and a mixture of DMF/H2O (2:1), was monitored to select the best solvent for this reaction. This study showed that a mixture of DMF/H2O (2:1) is the best solvent. Still, due to the insignificant difference between the yield of the reaction in this solvent and EtOH and considering the fact that EtOH is a green solvent; EtOH was chosen as the optimum solvent (Table 1). Next, we investigate the effect of mol% of loaded Pd on the solid support. To reach this goal, the progress of the reaction in the presence of solid MOF support containing 0.1, 0.3, 0.5, and 1 mol% of the Pd NPs were investigated. As shown in Table 1, 0.1 mol% of Pd NPs loaded on the solid support showed the least catalytic activity, and the 0.5 mol% of Pd NPs loaded on the solid support showed the highest catalytic activity. Further increase in mol% of loaded Pd NPs did not increase the catalytic activity, and hence 0.5 mol% was selected as the optimum amount.
Table 1: Optimization of the conditions for Suzuki cross-coupling reaction
To test the generality of the proposed catalyst, we studied the Suzuki cross-coupling reaction of a variety of aryl halides and phenylboronic acids in the presence of three synthesized catalysts. The fact that all three catalysts show superior catalytic performance even at low concentrations of Pd ions or NPs proves the constructive interactions between the pores of the IRMOF-3-SI and the Pd entities. This synergic effect between Schiff-base functionalized IRMOF-3 and Pd entities result in the facile progress of the Suzuki cross-coupling reaction for a variety of organic precursors possessing various functional groups. Such structure results in a high dispersity of Pd entities, preventing the homocoupling of aryl halides. Table 2 summarizes the product of this reaction in the presence of IRMOF-3-SI-Pd NPs reduced by NaBH4 (Cat. a) and alcohol (Cat. b).
Studies on the leaching of Pd NPs over the surface of IRMOF-3-SI was performed by the ICP technique. This study shows that the leaching of IRMOF-3-SI-Pd NPs reduced by NaBH4 is less than 0.6 % of all the Pd NPs in the catalyst (4.69 ppm), and the leaching of the sample reduced in ethanol is 1.2 % of all the Pd NPs in the catalyst (8.27 ppm). The results could be due to the fact that the Pd NPs reduced by NaBH4 are smaller in size and are positioned into the pores of the MOF.
Table 2: Generality of proposed catalyst for the Suzuki cross-coupling reaction
One of the most important features of any catalyst is its reusability. To test the reusability of the proposed catalyst, we separated the catalyst from the reaction media and washed it with dichloromethane several times. IRMOF-3-SI-Pd (II) for four cycles, IRMOF-3-SI-Pd NPs reduced by NaBH4 for three cycles, and IRMOF-3-SI-PdNPs reduced in ethanol for four cycles showed excellent recyclability (Figure 5).
Figure 5: Reusability of IRMOF-3-SI-PdNPs for Suzuki reaction
In conclusion, we synthesized a Schiff-base modified IRMOF-3 as a support for Pd NPs. We used synthesized IRMOF-3-SI-PdNPs as a catalyst for the Suzuki cross-coupling of various organic linkers, in which the catalyst showed excellent performance. This study demonstrates that the Schiff-base functionality of manufactured catalyst helps stabilize Pd entities. In this method, we used reduction by NaBH4 and reduction in ethanol solution to prepare Pd NPs. Results showed that the obtained catalyst with reduction of NPs in ethanol solution benefits high dispersity of the Pd NPs while the obtained catalyst by reducing NPs in the presence of NaBH4 as reductant agent benefits from low leaching.
This research did not receive any specific grant from fundig agencies in the public, commercial, or not-for-profit sectors.
Authors' contributions
All authors contributed toward data analysis, drafting and revising the paper and agreed to responsible for all the aspects of this work.
Conflict of Interest
We have no conflicts of interest to disclose.
Sadegh Rostamnia
Reza Taghavi, Sadegh Rostamnia. Schiff-base Post-Synthetic Modification of IRMOF-3 to Encapsulate Pd Nanoparticles: It's Application in C-C Bond Formation Cross-Coupling Suzuki Reaction. Chem. Methodol., 2022, 6(8) 629-638


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CBD patches are an innovative way to use cannabidiol (CBD) for its healing benefits. These patches provide a convenient, discreet and long-lasting method of delivering CBD into the body. The patch adheres to the skin and slowly releases CBD over the course of several hours, allowing it to be absorbed directly into the bloodstream for maximum effectiveness. Research has shown that these patches can help with pain relief, anxiety relief, inflammation reduction, improved sleep quality, and more. .CBD oil comes from the flowers, leaves, and stalks of Cannabis sativa. It is also called hemp oil or hemp seed oil. While it contains no THC, it does contain trace amounts of tert-butyl alcohol which is a psychoactive compound found in liquor.Medical marijuana can refer to the use of cannabis as a physician-recommended herbal therapy as well as synthetic cannabidiol (CBD) products made with CBD extracted from the cannabis plant or marijuana. There are many different forms of medical marijuana currently being used by people worldwide for different conditions such as chronic pain, epilepsy
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text: James Gordon has only one POP action figure in his effigy! Character very present in Gotham, we can hope to see Funko offer more James Gordon action figures. In the meantime you can still complete your collection of POPs from the same universe with Harvey Bullock, of Bruce Wayne or the ones of Penguin (Oswald Cobblepot).


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WITHIN RECENT TIMES, several households and businesses in communities across this country have been confronted by criminals whose modus operandi would have left many more than their immediate victims afraid for their safety.
It certainly was not the first time Barbados faced a sudden spike in violent crimes, but after an extended period of relative calm, these incidents would have had a jarring impact on citizens.
And while the causes of crime, particularly violent crime, can be many, we don't believe that anyone would argue against the position that regardless of the origin, a strong and decisive reaction from the police, along with structured appropriate social programmes by Government and civil society, is vital.
We believe it is necessary to make this point in light of a number of concerns expressed on Sunday when police mounted multiple operations across the country, stopping and searching vehicles and their occupants as well as pedestrians. In every instance, the complaint related to the use of convoys of marked police vehicles and officers who were clearly detailed to take a zero tolerance approach to lawbreaking. This method of policing offended some segments of the population, even though we heard nothing to suggest that anyone's rights were trampled.
For the record, we offer our unqualified support to the high command and rank and file of the Royal Barbados Police Force on the operations mounted over the weekend. The brazenness of the criminals who in recent weeks appeared to have had no fears when preying on innocent Barbadians requires robust policing.
If you were a law-abiding citizen going about your business on Sunday and happened to be stopped by or found yourself caught up in the backup from one of these operations, you might have considered it inconvenient – but we believe it was a small price to pay for your continued security.
Criminals don't find guns at the scenes of their deadly acts – they travel with them. And if the police are to break the back of this scourge, then we have to be prepared to support them when they act to confiscate these weapons on our streets. By the same token, those who come into our communities and push dope to our children don't grow or manufacture it at the point of sale – it has to be transported on our streets.
As law-abiding citizens we must be prepared to pay a small price for our safety and security, which includes living with the inconvenience of these police operations; or we will have no choice but to pay an even bigger price as we lock ourselves away in our homes.
If Acting Commissioner of Police Tyrone Griffith believes it is necessary from time to time to blanket our roads and communities with every working police patrol vehicle and every available man and woman of the constabulary, then we have a duty to support rather than complain.
In fact, we wish he would do it more often, because if as many lawmen and marked vehicles were on the road on April 6, perhaps bandits would not have been able to kidnap and rob the St Philip gas station proprietor and get away with it. If the streets of St Peter were being criss-crossed by police convoys, robbers might not have been able to hold up the KFC Speightstown branch on the night of April 15 and get away with it.
Let the police do what they must, within the confines of the law, while understanding the need to win and maintain the cooperation of Barbadians generally, and criminals will find it much harder to terrorise the country.


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By Jessica Long
For almost a decade, a limited number of minimally invasive surgeries (MIS) were being completed at Colchester East Hants Health Centre (CEHHC). This was mainly because there were not enough surgeons with advanced training in specific surgical procedures.
To address this gap in available health services, Dr. Ahmed Jad, general and bariatric surgeon at CEHHC in Truro, obtained special training and then set to work both reinstating laparoscopic surgeries and establishing a bariatric surgery program in the Northern Zone.
"We are trying to utilize CEHHC to its deserved capacity and potential by offering laparoscopic surgery, which is standard of care across most of Canada, and starting a bariatric surgery program to help the patients who will benefit from weight loss," explained Dr. Jad.
Originally from a small town in Egypt, Dr. Jad completed medical school and residency training at Dalhousie University. He worked at St. Martha's Regional Hospital in Antigonish before completing a fellowship in bariatric and metabolic surgery at Université Laval in Quebec City. He then returned to Nova Scotia and is currently a general and bariatric surgeon at the CEHHC.
Minimally invasive surgery is designed to cause less damage to the tissues than open surgery. It is associated with less pain, faster recovery and shorter hospital stay and it involves using small incisions (cuts). The surgeon can see inside of the body using a camera and perform the surgery through the small incisions. This type of procedure can effectively treat colon tumors, hernias and in some cases bowel obstructions and it is also used for bariatric surgeries. For cases that require two surgeons, for example colon cancer surgeries and bariatric surgeries, Dr. Jad works with Dr. Najeeb Abdul Kadir, a general surgeon with over 30 years of experience in minimally invasive procedures.
Bariatric surgery, a procedure not previously available at CEHHC, is commonly referred to as a weight-loss surgery. Bariatric surgeries require a larger team, including Dr. Jad and Dr. Kadir, dietitians, and nurses. Dr. Jad worked to establish this team to provide a post-operative management plan to follow weight loss surgeries, including dietary guidelines. Dr. Jad also provides education sessions to health care staff about post-operative management of bariatric surgery patients and soon sessions will be available for other CEHHC surgery patients.
"We are now able to keep our patients who desire laparoscopic surgery and keep them closer to home for care. Until last year, bariatric surgery was only available in the Central Zone, and through the collaboration with Dr. James Ellsmere, who is a pioneer in bariatric surgery in Central Zone, we were able to bring bariatric surgery to CEHHC," said Dr. Jad.
Dr. Jad is also helping to reducing patient wait times for general surgery procedures by accepting patients from the Central Zone. Dr. Jad is proud of the patient outcomes he is seeing because of the initiative. Patients have a role in decision making for their procedure as they can decide between minimally invasive and open surgeries.
Dr. Aaron Smith, Executive Medical Director, Northern Zone, said timely access to both laparoscopic and bariatric surgical services is crucial in ensuring optimal patient outcomes.
"Laparoscopic techniques often result in shorter operation times and reduced recovery periods compared to open surgery. This allows patients to return to their daily activities and work more quickly, minimizing the potential for prolonged disability or time away from productive endeavors," explained Dr. Smith. "Similarly, bariatric surgery, when performed in a timely manner, can prevent or mitigate the development of obesity-related complications, leading to improved long-term health outcomes for individuals struggling with obesity."
Dr. Smith said access to laparoscopic and bariatric surgical services is integral to providing timely and high-quality surgical care due to the minimally invasive nature of these procedures, their effectiveness in treating specific conditions, and the potential for improved patient outcomes.
"By ensuring availability and accessibility to these services, Nova Scotia Health can enhance the overall quality of surgical care, alleviate the burden of chronic diseases, and improve the well-being of patients," he said.
Dr. Jad is closely collaborating with physicians in the Central Zone to bring new surgical techniques to CEHHC. Many of the physicians he is now collaborating with were his mentors during residency training. Recently, Dr. C. Marius Hoogerboord, an expert in MIS surgeries and general surgeon at Nova Scotia Health, visited CEHHC to assist Dr. Jad with some complex cases using an advanced surgical technique.
"This collaboration is a key part of continuing to advance this initiative and utilizing the talents of physicians from other facilities," said Dr. Jad.
This initiative supports Action for Health Care, Nova Scotia's roadmap for a health system where Nova Scotians can access world-class healthcare in a timely manner. Thank you, Dr. Jad, for your commitment to better health and better health care for Nova Scotians.


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what did jesus say about religion? (mk.7:1-23) what did jesus say about… heaven following him...
What did Jesus say about Religion?(Mk.7:1-23)
What did Jesus say about… • Heaven • Following Him• Suffering • Patience
What did Jesus say about Religion?(Mk.7:1-23)
The Hostility of the Religious Elite
• Grain fields (Mk.2:23-28)
• Man with shriveled hand (Mk.3:1-6)
• 'By the prince of demons…' (Mk.3:22-30)
The Hostility of the Religious Elite
'They ran throughout that whole region and carried the sick on mats to wherever they heard he was. And
wherever he went—into villages, towns or countryside—they placed the sick in the marketplaces. They begged him to let them touch even the edge of his cloak, and all
who touched it were healed.' (Mk.6:55,56)
The Tradition of Men
"Why don't your disciples live according to the tradition of the elders instead of eating their food
with 'unclean' hands?" (Mk.7:5)
Jesus' answer – 'their hearts are far from me'
'traditions of men' - 'commands of God'
'unclean' - 'clean'
'outside' - 'inside'
Jesus' answer – 'their hearts are far from me'
'These people honor me with their lips, but their hearts are far from me. They worship me in vain; their
teachings are merely human rules.' (Mk.7:6,7)
'You have let go of the commands of God and are holding on to human traditions.'
Jesus' answer – 'their hearts are far from me'
'You have a fine way of setting aside the commands of God in order to observe your own traditions! For Moses said, 'Honor
your father and mother,' and, 'Anyone who curses their father or mother is to be put to death.' But you say that if anyone declares that what might have been used to help their father or mother is Corban (that is, devoted to God) — then you no longer let them do anything for their father or mother. Thus you nullify the word of God by your tradition that you have handed down. And you do
many things like that.' (Mk.7:9-13)
Jesus' answer – 'their hearts are far from me'
'Nothing outside a person can defile them by going into them. Rather, it is what comes out of a
person that defiles them.' (Mk.7:15)
Is your heart clean or unclean?
'What comes out of a person is what defiles them. For it is from within, out of a person's heart, that
evil thoughts come—sexual immorality, theft, murder, adultery, greed, malice, deceit, lewdness, envy, slander, arrogance and folly. All these evils
come from inside and defile a person.' (Mk.7:20-23)
Is your heart clean or unclean?
'Do not consider his appearance or his height, for I have rejected him. The LORD does not look at
the things people look at. People look at the outward appearance, but the LORD looks at the
heart.' (1 Sam. 16:7)
Is your heart clean or unclean?
'Above all else, guard your heart, for everything you do flows from it.'
(Prov. 4:23)
"Going to church doesn't make you a Christian any more than eating at McDonald's makes you a hamburger!"
Jesus declared all foods clean
"Jesus is saying, As of now I make these foods clean. I called the world into being; I called the
storm to a halt; I called a girl back from death. And now I call all foods clean."
Tim Keller
Jesus declared all foods clean
'The blood of Jesus, [God's] Son, purifies us from all sin.' (1 Jn.1:7)
'God made him who had no sin to be sin for us, so that in him we might become the
righteousness of God.' (2 Cor.5:21)
Jesus declared all foods clean"Through Jesus Christ, at
infinite cost to himself, God has clothed us in costly
clean garments. It cost him his blood. And it is the only thing that can deal with the
problem of your heart."'Jesus the King' Tim Keller
What did Jesus say about Religion?(Mk.7:1-23)
'These people honor me with their lips, but their hearts are far from me.'


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The ultimate Microsoft Fabric, Power BI, Azure AI & SQL learning event! Join us in Las Vegas from March 26-28, 2024. Use code MSCUST for a $100 discount. Register Now
Hello I annoy you because I need to generate a list of incidents uploaded to the spiceworks cloud system and indicates that to generate lists and reports recommends using Power BI.
Additional fields called address, incidente_origen, etc. were generated to the spiceworks help desk structures.
There are 6 custom fields.
I now have 13 tickets uploaded and in the tickets detail table there are 13 records. In the custom attribute tickets table generate a record for each Custo Field and there are more than 30 re. This is seen in the first image.que attached.
Now I do not know how to generate a report that in the same line puts all the information corresponding to the same ticket. The second image is seen.
Can you help me?
I am looking to have a Spiceworks Ticket report that shows the ticket (and description) with the comments pertaining to that ticket indented under it. Has anyone come up with a smilar report?
Hello Caitlyn Yan, thank you for answering my question. In the attached image you can see that the lines are repeated for each number of tickets. just changing the information in the "Ticket Custom Attributes" table. The tables are unit by the ticket number but I can't do to see all the information in the same line. I don't know if I was clear in my explanation?
Hi @Syndicate_Admin ,
I'm not sure I've understood your needs accurately.
Do you expect the output to be like the second picture?
You can try to create this list by using table visual and dragging all the required fields into this visual.
If I have not understood your needs correctly, please do not hesitate to inform me.
Hope it helps,
Community Support Team _ Caitlyn Yan
If this post helps then please consider Accept it as the solution to help the other members find it more quickly.
Join us at our first-ever Microsoft Fabric Community Conference, March 26-28, 2024 in Las Vegas with 100+ sessions by community experts and Microsoft engineering.
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Exposure to wildfire smoke was associated with worse overall survival in patients recovering from lung cancer surgery, a cohort study found. (JAMA Oncology)
Increased skin cancer screening for people of color is not enough to overcome disparities in melanoma outcomes. (University of Pittsburgh Medical Center, JAMA Dermatology)
Children living in extreme poverty during maintenance therapy for childhood acute lymphoblastic leukemia (ALL) have nearly a twofold greater risk of relapse compared with those not living in extreme poverty. (University of Alabama at Birmingham, Blood)
The Department of Veterans Affairs (VA) announced that veterans under 40 are now eligible for breast cancer assessments and mammograms if exposed to burn pits and other toxic exposures.
The VA is also reviewing whether there is a possible link between acute leukemia, chronic leukemia, and multiple myeloma and toxic exposures while serving in Iraq, Afghanistan, Somalia, Djibouti, Egypt, Jordan, Syria, Yemen, Uzbekistan, and all of the Southwest Asia theater of operations.
The Community Oncology Alliance filed a lawsuit over a recent change in federal health policy that restricts cancer practices from delivering drugs to patients.
Injectable forms of widely-used cancer drugs may avoid Medicare pricing negotiations. (Reuters)
UroGen announced that the phase III ATLAS and ENVISION trials of UGN-102 -- an investigational formulation of mitomycin -- for the treatment of patients with low-grade, intermediate-risk non-muscle-invasive bladder cancer met their primary endpoints.
COVID-19 vaccination in the U.K. reduced deaths from the virus in cancer patients by 84%, a new study found. (University of Birmingham, Scientific Reports)
Moderna and Merck are enrolling patients in a phase III study evaluating the personalized mRNA-based cancer vaccine mRNA-4157 (V940) in combination with pembrolizumab (Keytruda) as an adjuvant treatment for patients with resected high-risk melanoma.
And Merck said the phase III KEYNOTE-756 trial met its primary endpoint, with the addition of pembrolizumab (Keytruda) to neoadjuvant chemotherapy significantly improving pathologic complete response rate in high-risk, early-stage estrogen receptor (ER)-positive/HER2-negative breast cancer.
Meanwhile, Gilead announced it will discontinue its phase III ENHANCE trial of magrolimab plus azacitidine in higher-risk myelodysplastic syndromes following a futility analysis.
A study of 1,325 women with dense breasts showed that the use of a commercial artificial intelligence tool provided no additional benefit when added to mammography with supplementary breast ultrasound. (American Journal of Roentgenology)
The Biden administration has launched an effort under the Advanced Research Projects Agency for Health (ARPA-H) to develop novel technologies that will allow surgeons to remove cancerous tumors with more precision and accuracy.


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Choosing the Perfect Outdoor Ceiling Lights: A Comprehensive Guide
The right ceiling lights can make a big difference if you're looking to enhance the beauty and functionality of your outdoor spaces. Whether you want to create a cozy atmosphere on your patio, light up a garden path, or add style to your porch, we have it all.
Let's understand the different types of outdoor ceiling lights, their features, and how to choose the perfect lights according to your needs and preferences.
What are Outdoor Ceiling Lights?
Outdoor path lights, or ceiling lights, are lights that are specially designed for installation in the ceiling of outdoor areas such as porches and terraces. These outdoor wall lights are essential for providing lighting and enhancing the ambience of your entire outdoor space. The big advantages of indoor ceiling lighting are security lights that help extend the availability of indoor spaces beyond daylight hours. By installing it on the ceiling of an indoor space with shade, you can enjoy the room even after it gets dark.
The right ceiling lighting and outdoor lighting fixtures can complement your existing décor and create a cozy atmosphere. From a variety of accent lights to sleek modern pendant light designs to rustic lantern-style porch lights, there are many outdoor lighting options available to suit different architectural styles and personal tastes.
What are the Benefits of Outdoor Ceiling Lights?
Ceiling lighting for outdoor use, such as porch and patio lights, can greatly enhance an outdoor space. A good ceiling light will be capable of adjusting the brightness to create the perfect ambience. Some of the benefits of ceiling lights are:
Increased safety: Outdoor overhead lighting that illuminates outdoor walkways and stairs increases safety by providing a clear view. This will prevent accidents and make it easier for everyone to move through these areas.
Extend Usability: Outdoor ceiling lighting can extend the usability of your outdoor area in the evening or at night. Whether you're throwing a party or enjoying a quiet night outside, you can make the most of your patio or garden with additional light.
Enhance Ambiance: Outdoor ceiling lights serve a practical purpose and add ambiance to your outdoor space. The soft light creates a welcoming atmosphere for gatherings, making it a more welcoming space for family and friends. Choosing ceiling lights, porch lights, and outdoor lights can increase the appeal and functionality of your home's exterior.
Types of Outdoor Ceiling Lighting
Flush Mount Outdoor Lighting
Provides a sleek, modern look to your outdoor space. Perfect for low ceilings or where vertical space is limited, pendant lights are the perfect lighting fixture to add style and functionality to any room. Pendant lights are a versatile option that can improve the ambience of your entire space.
Semi-Flush Mount Outdoor Lighting
It combines the advantages of recessed lighting and pendant lighting. Hall lights are suspended slightly lower from the ceiling to create a more dramatic shadow effect. Porch lights add an elegant touch to your outdoor space without overwhelming it. With its stylish design and adjustable shade, the ceiling light is perfect for any porch or terrace. Whether used as functional lighting or decorative accents, ceiling lights add both beauty and utility to your outdoor living space. A variety of designs are found, including traditional, modern, and rustic.
Outdoor LED Ceiling Lighting
An energy efficient option that helps reduce your electricity bill. A durable ceiling light requires less frequent replacement than traditional ceiling lights. These lights are made from durable glass. Provides bright, focused lighting in conjunction with exterior lighting to enhance visibility and safety. Use LED ceiling lights or ceiling lamps to illuminate your outdoor space. Options include dimmable LEDs for adjustable lighting levels. Consider these factors when choosing outdoor ceiling lights to create a bright and visually appealing covered porch area that suits your landscape lighting preferences.
Important Factors To Consider When Buying Outdoor Lighting
Whether you're installing pendant lights, outdoor wall lights, or garden lights, here are some tips to keep in mind:
Energy efficiency
Choose energy efficient lighting which reduces your energy expenditure and your carbon footprint. You should consider using LED lights as they are much more energy efficient than traditional options. Another energy efficient option is solar powered lighting.
Another important factor to consider is the material of the luminaire. We recommend using copper, aluminium, brass and ceramic. Not only are they durable, but they can withstand harsh weather conditions as well.
A tight budget can limit your options. However, outdoor lights have become quite cheap these days. This means that you are likely to find a durable and attractive model at a price point that suits you.
Higher wattage lights are great for lighting dark outdoor areas, while lower wattage lights can be used for decorative purposes.
How to Choose the Right Outdoor Ceiling Lighting?
When choosing outdoor ceiling lighting, consider your particular needs for brightness levels and fashion inclinations. Evaluate item quality by assessing durability, climate resistance, and client reviews for quality. Also, don't forget to take into consideration the shade, stars, alternatives, and size of the lighting.
Planning Placement for Outdoor Lighting
Good outdoor lighting depends on finding a fresh look that suits your taste and the style of your home. If you rush to the nearest outdoor lighting supplier without a plan, you will soon find yourself overwhelmed by the range of attractive designs available. Rather, spend time imagining what effect you want to create and how best to achieve it. Start with a rough layout of your outdoor spaces and highlight the areas you want to light up. Measure these spaces and write down the measurements. Pay attention to your power points. There are also great solar powered lighting options on the market. They make it easy to put the lights where you want them. Consider the style and size of the light fixtures you choose.
Choosing outdoor lighting according to the purpose of use
Divide the area by activities. For example, you can mark areas for entertainment, safety, and efficiency. Note these ideas on the plan. Make sure to include the three main types of lighting in your design.
Ambient lighting: Ambient lighting is similar to the ceiling lights in your home that add an overall glow to your surroundings. These types of lighting can be suitable for outdoor entertainment venues and include wall lamps, pendant lights and post lights.
Task lighting: Task lighting provides targeted lighting that increases safety. Driving lights, emergency lights, and deck lights fall into this category.
Accent lighting: Accent lighting is purely decorative. It is usually used to highlight bodies of water, trees, or sculptures.
Spot lights: Spotlights are the most common type of accent lighting.
Wet and damp lighting fixtures: Wet lights are suitable for areas that are directly exposed to the weather and receive little sunlight. Don't forget to look for these features when choosing post lights, wall lamps, motion sensors, pendant lights, and outdoor ceiling lights.
Lighting by purpose
Dark places, such as rarely used entrances and passageways, can be attractive to burglars. Illuminate them with security light options:
Dusk till dawn: These lights have light-sensitive sensors that ensure the lights turn on when it gets dark. This is useful if you are on vacation or regularly come home from work late.
Motion sensor lights: Any movement in the vicinity will trigger these lights. They are a great way to alert you to movement in your yard and can deter intruders.
Combination lights: These come with both of the above functions. These innovations help conserve electricity by turning it off when not needed.
Before you buy outdoor lighting, it's important to plan. This will help you know what works best for your space. It also helps you create a lighting strategy that suits your personal needs and preferences. We hope this post has helped you decide on the best outdoor lighting for your place.


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Mooring caisson removal
Five caissons which have been used to moor a spare lock gate needed to be removed and transported.
The heavy lift shipping market is one like no other, it entails the hoisting of heavy cargoes (>300 tons) using shipboard cranes.
Our markets
The heavy lift shipping market is undergoing a significant shift from exclusively topside operations to subsea installation and decommissioning work. Heavy lifting on land, with a solid foundation under the crane, is already a complex procedure, however when the whole system is on a floating vessel, a whole new set of variables gets introduced. Vessel stability, ballast to correct heel and trim and the restricted space available all play a role in the engineering of a heavy lift. Stowage plans, hoisting plans, rigging arrangements and seafastening are all items that require expertise and experience.
Since most heavy lift cargoes are unique, they require very careful planning and coordination down to the smallest detail. Detailed information about the cargo and of the loading and discharging locations are studied in the preparation phase, often even before a contract is actually booked. In certain instances the cargo requires specialized lifting tools that need to be designed and engineered so that the cargo can even be lifted onto the heavy lift shipping vessel. Our unique approach and out-of-the-box mentality ensures safe loading that meets client requirements and surveyors' standards for warranty at sea.
Naval Architect
The actual size and weight of the cargo often determine whether a load is lifted with a single crane or with two cranes simultaneously. Both types of lifting create their own set of challenges and have specific advantages and disadvantages. During dual lifts, the cargo is very stable, in other words it doesn't swing around the hook as with a single lift. On the other hand, dual lifts restrict access to the vessel's hold and also require the load to be displaced between the cranes during the loading process.
In order to lift any specific load, the heavy lift operators have a number of specific equipment at their disposal. Shackles, grommets and lifting / spreader beams are all items that are required to secure a load in a safe and effective way. The combination of the various items is typically described in a detailed rigging plan that takes safe working loads and all angles in to account.
Are you facing a challenge?
What sets us apart?
Saltwater positions itself as a partner for custom engineering solutions. A proven track-record demonstrates that we are competent and that we are able to face any naval engineering challenge. What makes us stand out is our agility. Being agile is in our DNA and enables us to adapt quickly and move fast when needed.
We pride ourselves in being transparent and reliable. These are bold claims that we are staking every day. We communicate loud and clear, we manage expectations, we commit to promises made and we take ownership of a situation when needed.
The expertise of Saltwater in practice
Five caissons which have been used to moor a spare lock gate needed to be removed and transported.
Saltwater was contracted to assist with the verification of the mooring lay-out for several vessels.
The system can be disassembled and placed inside 40-foot containers, allowing the structure to be transported across the globe.
Exchanging lock doors at the Volkeraksluizen to keep them running smoothly.
This three mast clipper needs refitting and upgrading before starting the SDG World Tour.
Our clients
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Chapter 863: Return One Hundred Fold of What She Suffered
Jiang Yucheng was suddenly stunned. How familiar is this scene! Some time ago, that person also stood here smiling and said that her heart was already taken! The same place, the same words, the same smile.
The only thing different is that I never had the chance to express what I felt when that person said those words.
He had put himself down and sincerely invited Chu Liuyue to go with him, but he got rejected!
At one moment, these two scenes seemed to mix in front of Jiang Yuchengs eyes.
He couldnt differentiate if the person in front was Chu Liuyue or Shangguan Yue!
Something tumbled in his heart, and he clutched Chu Liuyues wrist! "That wont do!"
Ch u Liuyue easily avoided it.
Even though Jiang Yuchengs cultivation level was higher than hers, her movement techniques were now much better after the intense training at the Red Moon Desert.
It wasnt hard for her to deal with Jiang Yucheng.
Chu Liuyue moved a step back and raised her brows slightly, the smile on her face fading.
"Eldest Young Master Jiang, please respect yourself."
Hatred and contempt flashed across her eyes, forming a steel needle that deeply stabbed into Jiang Yuchengs heart!
The vengeance Jiang Yucheng had suppressed for many years suddenly rushed up and overwhelmed his head!
As if he had blurted it out, he angrily said, "I dont allow it! Other than me, you cant like anyone else!"
Jiang Yucheng suddenly erupted and frightened Chu Liuyue. In my memory, no matter the situation, Jiang Yucheng rarely showed such enraged moments.
Even when he harmed others, his expression was always calm.
Why… does he seem to be so agitated
Chu Liuyue was alerted and moved a step back.
Then, she raised her brows slightly and coldly said, "You originally cant force someone to like you.
Jiang Yucheng, please wake up!"
When he saw her angry, Jiang Yuchengs heart trembled for some reason.
Looking into those furious and black gem-like eyes, his expression changed as he opened his mouth and lowered his voice.
"AYue, dont be angry…"
As if he was begging, he softly muttered and wanted to reach out to pull her back.
Chu Liuyue felt that Jiang Yucheng was indeed crazy. What is he doing! AYue Who is he calling
The deep hatred emerged from her heart, and she was about to turn around to leave.
But at this moment, an enraged voice filled with hatred sounded by the side.
"Jiang Yucheng!"
Chu Liuyue looked up. Hah, what a coincidence.
The incoming person is actually Shangguan Wan.
When I was tangled with Jiang Yucheng just now, I didnt notice that someone had come.
From the looks of it, she shouldve heard quite a bit, right But no matter how much she has heard, Jiang Yuchengs every single word and sentence are like sharp knives stabbing into her heart.
The Third Princesss sharp shrill finally made Jiang Yucheng recover his senses, and he looked at his empty hands.
Chu Liuyue stood at the side, far away from him.
Her entire body exuded her hatred for him—it was as if another glance would dirty her eyes.
His heart suddenly ached. It was like this in the past, and its the same even now!
Emotions rapidly gathered in his eyes coldly as he looked at Shangguan Wan and coldly asked, "Why are you here"
Shangguan Wan sneered.
"Im the Third Princess, and this Xin Li Garden is the royal familys garden.
Why cant I be here! But you, Jiang Yucheng—were already getting married tomorrow, yet what are you doing Youre actually proposing to another woman! Jiang Yucheng, do you have a heart!"
Only she knew how much her heart hurt when she heard those words just now! She originally thought that her heart was already numb after she saw the painting.
But when she came here and saw how her husband-to-be treated Chu Liuyue, she then realized that it could hurt even more!
It was like someone had gripped her heart tightly, yanked it out, threw it onto the ice-cold floor, and stepped on it harshly!
Ridiculous! How laughable!
Seeing Shangguan Wan yelling at the top of her lungs, Jiang Yucheng knitted his brows tightly.
The nearby guards had already been deployed away by him earlier since he originally wanted to talk to Chu Liuyue properly, but he didnt expect Shangguan Wan to barge in and cause such a scene.
"Calm down! As the princess, how are you different from a crazy b*tch by screaming like this!" scolded Jiang Yucheng coldly.
This sentence completely ignited the fire in Shangguan Wans heart! "Hahahaha! Crazy b*tch You think Im a crazy b*tch"
Shangguan Wan pointed at her own nose and shrilly scolded as if she had heard the biggest joke in the world.
"Jiang Yucheng, you betrayed me first!"
Then, she harshly pointed toward Chu Liuyue at the side.
"Whats so good about this b*tch that you can do this! Shes just a lowly thing.
Youre actually treating me like this because of her!"
Chu Liuyue squinted dangerously.
But before she could act up, Jiang Yucheng already coldly spoke.
"Shangguan Wan, watch what you say! Dont forget your status!"
Shangguan Wan suddenly laughed, and her five features contorted.
Her gaze turned crazy as she slowly said, "Jiang Yucheng, dont think I dont know why you like her.
Isnt it because she looks very similar to Shangguan Yue!"
Jiang Yuchengs heart skipped a beat, and his expression turned sharp.
"What nonsense are you saying!"
However, Shangguan Wan ignored his anger and turned to look at Chu Liuyue with a mocking gaze.
"Chu Liuyue, do you really think hes genuine to you Youre just a substitute! Your eyes look exactly the same as those of my short-lived elder sister, Shangguan Yue! He misses that person so much, and now that hes looking for you, youre just her substitute!"
"Shangguan Wan!" Jiang Yucheng cried out.
He instinctively felt that something was wrong as he hurriedly went forward and wanted to pull Shangguan Wan away.
"Your brain is messed up.
Ill bring you away to wake you up!"
Shangguan Wan flung his hand away.
"Dont touch me! Im very sober!"
Her eyes turned red as she stared at Jiang Yucheng while laughing coldly.
Then, she lightly asked, "Jiang Yucheng, what are you afraid of Are you afraid that she will know that you just treat her as Shangguan Yues substitute, or are you afraid of people knowing that you still miss Shangguan Yue even though youre marrying me tomorrow Or… Youre most afraid of people knowing that youve liked Shangguan Yue for ten years, yet you personally—"
A resounding slap sounded!
Shangguan Wan was thrown back and immediately collapsed onto the floor as half her face rapidly swelled up.
Blood then flowed out from the corner of her mouth.
One could tell how harsh this slap was!
Jiang Yucheng looked down at her from above, and his eyes had murderous intent.
"Shangguan Wan, youre crazy!"
Chu Liuyue stood at the side and coldly watched this scene as if it had nothing to do with her.
Staring at the duo going for each others throats, her lips suddenly curled up as her gaze was cold and nonchalant. What a joke.
The scene from two years ago actually happened again, but this time, everyone has changed their positions.
All the pain and suffering I previously went through will slowly be repaid to them now.
If you find any errors ( broken links, non-standard content, etc..
), Please let us know so we can fix it as soon as possible.
Tip: You can use left, right, A and D keyboard keys to browse between chapters.


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The draw for the upcoming tournament took place with the 32 participants discovering their group-stage opponents.
The long-awaited draw for the World Cup 2022 finally took place on Friday. After dividing the teams into four pots, a host of eight football legends, including Jay-Jay Okocha and Rabah Madjer, made the draws.
After a brutal qualifying campaign, Senegal, Tunisia, Ghana, Cameroon, and Morocco made it to the tournament from Africa.
African Cup of Nations champions Senegal will face hosts Qatar, Netherlands, and Ecuador in Group A.
Tunisia will compete against France, Denmark, and UAE/Australia/ Peru in Group D.
Morocco, who arguably have the easiest draw among the African nations, will meet Belgium, Canada, and Croatia in Group F.
Ghana defenders will prepare to face Cristiano Ronaldo and Portugal in Group H, with Uruguay and South Korea being the other teams in this group.
Cameroon, whose controversial qualification made the headlines earlier this week, will have to battle it out against Brazil, Switzerland, and Serbia for a place in the last 16.
Here is the full draw for the 2022 World Cup
- Group A: Qatar, Ecuador, Netherlands, Senegal
- Group B: England, Iran, USA, Scotland/Wales/Ukraine
- Group C: Argentina, Saudi Arabia, Mexico, Poland
- Group D: France, UAE/Australia/Peru, Denmark, Tunisia
- Group E: Spain, Costa Rica/New Zealand, Germany, Japan
- Group F: Belgium, Canada, Morocco, Croatia
- Group G: Brazil, Serbia, Switzerland, Cameroon
- Group H: Portugal, Ghana, Uruguay, South Korea


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My Guide Website?
Awarded 6 AA Rosettes for 6 consecutive years in recognition of its culinary excellence, YMing serves healthy Chinese cuisine of the highest quality in a relaxed and peaceful atmosphere. Listed in the Hardens and Square Meal restaurant guides, this friendly and welcoming West End restaurant is an acclaimed hidden gem with a menu focused on traditional food from the northern provinces of China. The Double Braised Pork in Hot Pot is a delectable speciality dish recommended by Jay Rayner of The Observer, whilst the Whole Fresh Lobster special can be served steamed or poached according to your tastes. There is also a wide selection of rice and noodle, lamb, beef and pork, and poultry dishes to choose from. Each dish is prepared with the utmost care and originality, ensuring that you can experience an authentic Chinese meal with each visit.


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Around NYC is a roundup of noteworthy local stories the StreetEasy editorial team read this week.
In NYC's Amazon HQ2 bid, which became public this week, officials replaced the heart in the classic "I Love NY" logo with an Amazon smile. "I Amazon New York," it seems to say. Milton Glaser, the noted designer who created the logo, was not thrilled. [Fast Company]
Speaking of Amazon, its execs faced some serious heat from the City Council this week. But after lots of chanting and intense questioning, few seemed satisfied with the answers they got. [Curbed]
And why wasn't Brooklyn chosen for Amazon's HQ2? The city's proposal had suggested Brooklyn as a possible location. Here's why the borough may have lost to Queens. [The Bridge]
Continuing the Seattle-ification of NYC, Starbucks is opening a 23,000-square-foot, upmarket coffee bar in the Meatpacking District. Because Downtown Manhattan doesn't already have enough places to get expensive coffee. [Seattle Times]
Buyers of some upscale condos won't have to pay common charges for up to five years. Extell Development is waiving the common charges in several luxury buildings to drum up sales before the end of the year. [Brick Underground]
Where is the surge in 311 complaints about business signage coming from? Small business owners in Brooklyn and Queens feel they are being targeted for having foreign languages on their signs. [The New York Times]
After 41 years, the Cornelia Street Cafe is closing. The coffee shop was a local landmark and gathering place for downtown artists, including Suzanne Vega and the Roches. [Vanishing New York]
A team of working dogs is out controlling the geese population on Governor's Island. The average cuteness level of NYC city employees has just gone up a whole lot. [Gothamist]
Hey, why not like StreetEasy on Facebook and follow @streeteasy on Instagram?


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1. Investor information: Phu My Co., Ltd 2. Attractive industry - Electrical industry, manufacturing machinery and auxiliary equipment industrial and household electrical spare parts; - Electronics, informatics, telecommunications industry; - Light industry: children's toys, imitation jewelry, sewing, footwear, ceramic products, glass, crystal; - Storage - Processing consumer goods and exporting (food, instant noodles); - Mechanical processing industries such as manufacturing and assembling watches, optical devices and instruments; - Mechanical engineering industry, manufacturing and repairing machinery, construction mechanics; - Industry producing fine art wood for export, office equipment, hotels, interior decoration; - Plastic products, metal, household tools. 3. Information about IP 3.1. Information Address: Tan Dong Hiep B Industrial Park, Tan Dong Hiep Commune, Di An Town, Binh Duong Province. - Geographical location: 19 km from Tan Son Nhat Airport; Saigon Port: 20 km; Song Than Station: 2.5 km; City. Ho Chi Minh: 18 km. - Total investment capital: 302,406 billion VND - Industrial land area for lease: 103 hectares - Characteristics of the industrial park: - Technical infrastructure: under construction - Concentrated wastewater treatment plant: 2,500 m3/day. - Year put into operation: 2001 - Total realized investment capital: 170,127 billion VND - Area of land sublease: 80 ha; achieve occupancy rate: 78% - Decision approving the EIA report: No. 114/QD-BTNMT dated January 28, 2003 of the Ministry of Natural Resources and Environment Power supply: - Power infrastructure through 110/22kV transformer station located in Tan Dong Hiep B Industrial Park with capacity: 80 MVA. – Backup power: a generating plant with a capacity of 650MVA will be located in South Binh Duong. Water supply: – Clean water is supplied from Di An water plant through the treatment system and supplied directly to each plant. Total capacity plus 20,000 m3/day and night. - Wastewater treatment: + The industrial park's centralized wastewater treatment plant is designed according to American technology, with a capacity of 5,000 m3/day. The wastewater drainage system is pulled to the side of the fence of factories, enterprises, - Telecommunication: + Ensure to meet communication needs by phone, fax, ADSL... + Investment company: Viettel, VNPT - Traffic road : The internal roads are designed with asphalt concrete with a load of H30, with main roads 31m wide connected to the main road. It seems that DT 743 connects the arterial traffic routes. With a lighting system and green strips of grass to ensure circulation convenient for people and vehicles, and at the same time creating a green, clean and beautiful environment for the entire industrial park. 3.2. Industrial land and factories transferred: See selling information here: https://nso.com.vn/ Or contact us at hotline: 0919 882 738 / 0908 069 399 / 0931 799 377
3.3. Enterprises in the industrial zone: - Phu My Co., Ltd Profession: Industrial Park - Export Processing.
- Ameco . Industry Joint Stock Company Category: Construction - Equipment - Viet Rubber Co., Ltd Category: Rubber - Products. - Hoang Lam Mechanical Manufacturing Co., Ltd Profession: Mechanical - Machining & Manufacturing. - OSEVEN JOINT STOCK COMPANY Industry: Paint - Manufacturing & Trading. - Southern Technology Co., Ltd Profession: Mechanical - Machining & Manufacturing. - Thuan Loi Co., Ltd Category: Plastic - Products. - Viet Hoa Plastic International Co., Ltd Category: Plastic - Products. 4. Utilities in the IP 4.1. Neighborhood residential area The residential area is located next to Tong Dong Hiep B industrial park with a large area, densely populated and very close to the industrial park. The buildings are almost completed and fill the residential area, meeting all the needs of the workforce and the services that meet the needs of the workers here. 1.1. Catering and accommodation services Administrative center, general hospital, school from kindergarten to university, commercial center. Accommodation and dining services here are almost complete with a system of houses, inns, motels and hotels, large and small, located in residential areas. Full clinics, markets, supermarkets, transportation services, banks are located around the residential area to serve the needs of the people. Diverse food service includes many restaurants to serve the dining needs of everyone.


text: Josef Ajram, in addition to his stock market activities, is an athlete who participates in endurance races such as triathlons, cycling, mountain biking and marathons. He has finished several Ironmans including Austria, Switzerland, Germany and South Korea. He is the first Spaniard to finish the Ultraman of Canada, Hawaii and the Titan Desert. In recent years his life has taken a radical turn, since he started with the Kundalini Activation Process, the yoga of consciousness. In this conference he will talk about believing in oneself, not giving up to achieve goals and how the spiritual part has given him a more holistic vision to all this.


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A qualified physician specializing in mini-invasive and injecting procedures in Aesthetic Medicine. Holder of certificates for implants and botulinum toxin application, also for chemical peeling and lasers.
Expert instructor and author of articles and lectures. Member of the editorial board of the Health & Beauty magazine. From 2011, international expert and lecturer at Anteis (Geneva, Switzerland)
Leading physician and head of the Aesthetic and Corrective Dermatology Department.


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"It's putting a smile on farmers' and ranchers' faces across the state," said Ron Gibson, Utah Farm Bureau President. "This program right here is the one that is really exciting."
Gibson talks about the Touch of Utah Box, a program that brings local produce and farm products to Utah residents. The idea began to ensure Utah farmers' crops and livestock would not go to waste due to supply chain and environmental issues and has developed into a popular subscription service for families in need and those who want to buy locally.
The box, sponsored by Farmers Feeding Utah, is filled with products from Beehive State farmers only. It's a great example of the way to help families struggling with food insecurity and local farms. In a state that has faced a record-breaking drought over the past two years, it's a way to help numerous people affected by it.
"This drought has been really hard, COVID has been really hard, and the trade wars before that," Gibson continued. "This is now our opportunity as a state to say we want local agriculture here in the state of Utah."
Utah is coming out of one of its worst droughts on record, which has made farmers' jobs even harder across the state's already-arid lands. In addition to programs like this one, farmers join in on a state program that increases their water use efficiency, and each is designed to make farming more sustainable.
The box, similar to national subscriptions services like Blue Apron, includes high-quality products fresh from the state's fields. Recent boxes have included various options, everything from peaches, cherries, mushrooms, and butter to Red Butte Hatch Chile cheese, burgers, ribeye steaks, and even fine chocolate. Though the program is barely six months old, it's already distributed more than 1 million pounds of food to hundreds of food-insecure families throughout the state, including more than 300 in the Kanab area alone. Many farmers have refused anything other than wholesale prices for any products to such families. Each month the box has unique contents, and a subscription gives members unique access to purchase these Utah-grown foodstuffs. Utah residents can subscribe to the program for less than $100 per month.
The Touch of Utah box is vital to a circular economy that helps Utah farmers, small businesses, and families in need across the state. As the state and farmers work together to ensure a viable farming future despite environmental and economic challenges, programs like Touch of Utah are the building blocks to success.


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As summer ends, you're left with great memories, vacation souvenirs, and…sun damage. While you've been having fun in the sun, the sun has likely been putting some serious stress on your skin. This damage can happen in as little as 5 minutes! Sun damage can create unsightly skin issues like uneven skin tone and loss of elasticity, often aging you beyond your years. Luckily, chemical peels can help reduce these unwanted effects. However, many people are apprehensive about the treatment. Read more to learn how chemical peels can help wipe away sun damage, from Premier Cosmetic Surgery, cosmetic surgery near me.
A chemical peel aims to resurface the skin by applying a mixture of chemicals to the skin that eats away dead, dull skin. Once the damaged skin is peeled off, the new, unblemished skin grows in its place. Chemical peels are non-invasive, quick, and easy procedures that can be done in-office by the best plastic surgeons in delaware. There are three main types of chemical peels.
Superficial chemical peels focus on the outer layer of the skin or the epidermis. This type of peel is best used to treat issues like fine lines, acne, slight skin discoloration, and dryness. Medium-grade peels penetrate the epidermis and go into your skin's middle layer, the dermis. These peels typically treat concerns like acne scarring, uneven skin tones due to medications, and deeper wrinkles. Finally, deep chemical peels dive deep into the skin, into the mid-reticular layer. This level of chemical peel is used to treat the direst of cases of issues like deep-set wrinkles, benign growths, and more pronounced scars.
Before undergoing a chemical peel, you'll first need to figure out which one is best for you. For fair-skinned individuals, our cosmetic surgery near me office suggests medium or deep peels. These peels can cause discoloration in people with deeper skin tones. If you're unsure of which category you fall under, your best plastic surgeon delaware can help determine the best course of action during your consultation. Before your chemical peel, you'll also need to stop or refrain from certain activities, skin treatments, or medications as they can create reactions. Some of these include:
A chemical peel may sound scary to many. After all, we're told to avoid harsh chemicals when it comes to our skin! However, this procedure is perfectly safe. Your best plastic surgeon delaware has been trained on how to use these chemicals and has likely done many before yours, so you can sit back and relax. However, if you're still anxious about the procedure, hearing a step-by-step breakdown of what to expect can help.
Step 1: Our cosmetic surgery near me office will talk with you about your medical history and make sure you've followed all necessary pre-procedure precautions.
Step 2: Your physician may then cleanse your skin and do a patch test to make sure your skin can tolerate the full peel.
Step 3: After this, your plastic surgeon will use a soft piece of gauze to spread the solution onto your skin. You'll likely feel a little bit of stinging while the solution works its magic.
Step 4: After the solution has sat for a few moments, your doctor will cool your skin off with a compress to neutralize any residual stinging or warmth you may feel. Know that it's normal to feel those uncomfortable sensations for up to 20 minutes after application. However, make sure to let your doctor know if the feeling reaches a painful level!
Just like with preparing for a peel, there are some actions and medications you'll want to refrain from taking. Your specialist will typically give out a sheet with post-procedure instructions on what to do following your appointment. Everyone is different, and each type of peel may warrant another regimen. That said, there are some common things most offices will suggest you not do after a chemical peel. This includes:
Your cosmetic surgery near me results will vary based on your peel type. For light chemical peels, you'll see results in as little as 24 hours or as long as a week. Medium grade peels will take a little longer, with results appearing in seven to 14 days. Finally, deep penetration chemical peels can take up to two full weeks to see results. When your healing period is over, your new skin will be extra sensitive, so be sure to go easy on it. Once healed, a chemical peel will provide you with brighter, smoother, and healthier-looking skin you can feel confident in!
We hope this breakdown of chemical peels helped! Does your skin suffer from discoloration? Do you have severe acne scarring? Feel like all those hours at the beach may have been a mistake? You may benefit from a chemical peel! Premier Cosmetic Surgery, best plastic surgeons in delaware, provides all three types of peels for our patients. If you're interested in learning more about chemical peels, check out our chemical peel page. At Premier Cosmetic Surgery, cosmetic surgery near me, we believe you deserve to love the skin you're in. If you're ready to see a difference in your skin, contact our offices for a consultation today!


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There are [0] photos and [3] stories about Laos
Wednesday, 27 May 2009 | Views [1571] | Comments [2]
Ou est la biblioteque? Croque monsieur! These are a few of the many French turns of phrase I have picked up here in Laos's capital, Vientiane. The French influence is apparent in the wide, tree-lined streets and abundant fragrant bakeries. It is ... Read more >
Tags: laos, vientiane
Monday, 25 May 2009 | Views [769] | Comments [1]
We spent yesterday basically bumming around- one day was enough to take in all the sights of Luang Prabang, and it was way too hot to just walk around and see them again. It is such a nice place, though, that it was nice to hang around and just chill ... Read more >
Tags: laos, luang prabang, vang vieng
Saturday, 23 May 2009 | Views [801] | Comments [2]
Greetings, comrades, from our first-ever Communist country! It was not easy getting here, but it was a picnic compared with the upcoming workers' global revolution. The last two days we spent on a long, narrow boat puttering down the Mekong. The ... Read more >
Tags: laos, luang prabang


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At the International Alpha Omega Convention in Tel Aviv last year, the Trudi Birger Award was presented to Dr. Isaac Perle. We congratulate Dr. Perle for receiving this award in recognition of his support of dental care for the indigent children of Jerusalem.
Trudi Birger's sons Doron, Oded, and Gil were in attendance.


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The Quintopia system is continuously being extended and updated and so it is best if you can to make sure all items you are using are at the same version level.
Whenever possible an updater will be made available that allows you to run it and it will scan for and update all items of a particular type. Note that you must be the owner of the items to be able to update them this way. Updater's can be found in the main store on Mintor (see chapter 12)
For storage, there may be a 'migrator' that will take all the stock from your existing storage and transfer it into the new version of that storage unit for you.
When a major release is made it often is not possible to make something to automatically update items and in that case it is recommanded to replace items.
One way to do that is to 'paint everything red' so you know what are old items, then work through gradually replacing them.
To 'paint' things, right click one item and select Edit, then you can 'shift click' on more items to select them as well. Next click on the Texturetab and here click on the Coloroption. Pick a nice bright red! You may also want to click on Full Brightand also set some Glowto help you see what are the old items.
This work by Buzzy Cnayl is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
Based on a work at https://satyrfarm.github.io/


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If you are using a Regus office on demand in Aberdeen, we recommend booking in advance via the Regus app, by phone or online to ensure a space is available. However, if you have rented a full-time serviced office in Aberdeen, you can simply turn up as and when you need to and get to work.
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"Aberdeen is tipped for an economic boom over the next few years and is conveniently located for both national and international visitors."


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RA Deputy Minister of Education, Science, Culture and Sports Narine Khachaturyan and head of construction companies Norayr Martirosyan signed a memorandum today on the restoration of the roof and the narthex of St. Nshan church in Astvatsinkal monastic complex of Hartavan community, Aragatsotn region.
Deputy Minister Narine Khachaturyan expressed her gratitude to the benefactor for the offer of cooperation and support and highlighted the importance of such activities: "Thank you for cooperation. It is highly important not only to build churches and create new spiritual and cultural values, but also to preserve and restore the existing rich heritage. In this regard, this is a very important and joyful event, which I hope will be a good example. The signing of the memorandum is a nice example of cooperation between the state and the private sector for the benefit of cultural heritage and future." Narine Khachaturyan stated and underlined that the Ministry will monitor the progress of restoration works and will always support it.
N. Martirosyan noted that he was impressed by the quick response of the Ministry to their proposal, which increased his enthusiasm and willingness to complete the work in short terms: "I am grateful to the Ministry for quick response to our proposal and cooperation. This is a very important initiative for me. The development of spiritual culture should be promoted not only by building new churches in crowded cities, but also by restoring our spiritual centers in abandoned places. I think, if you have the opportunity to earn money, you also need to be able to support and invest in important activities. I hope that after the restoration works, this cozy Church will attract many tourists" stated the benefactor, assuring that the work will be carried out at a proper level.
It is envisaged that the restoration works of St. Nshan Church will take 3 years, but according to the parties, the joint efforts will promote to complete the works in a shorter period.


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Year | 2014 |
Fuel type | Petrol |
Body | Station Wagon |
Model | Wish |
Make | Toyota |
Engine | 2000 CC |
Transmission | Automatic |
Drive | 4WD |
Exterior Color | Grey |
Interior Color | Black |
Door | 5 |
Stock Status | Sold Stock |
Looking for fantastic, trustable car dealers in Kenya? Khushi Motors is the place to go! We are one of the best top dealers in the country, offering a diverse selection of new and used vehicles. We also have competitive prices and excellent after-sales service, so you can be sure that you're getting the best value for your money.
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Account Name: Khushi Motors Limited
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Branch Code 068
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Currency : Kenyan Shillings
Bank Detail: Equity Bank Kenya Limited
Account Name: Khushi Motors Limited
Account No: 0250268562174
Bank Code: 025
Branch Code: 068
Branch Address: Moi Avenue Mombasa
Swift Code: EQBLKENA
Currency: USA Dollar


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Sunday, February 25, 2024
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LARGO, FL – According to WTSP, an elderly man was injured after crashing into a tree at Seminole Blvd and 8th Ave SW Monday.
The driver was operating a Ford Explorer when he collided with the tree at around 8:50 p.m.
First responders transported the victim to a nearby hospital in critical condition.
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Mesa, the engineering and maintenance company arm of the Hi Fly group, has officially opened its new hangar at Beja's Civil Terminal for maintenance of Airbus aircraft. The facilities cover an area of about 9,500 m² for aircraft maintenance, and includes workshops, warehouse, offices, training facilities and other support premises.
The new hangar operates around the clock and will serve as a base maintenance unit for Hi Fly's Airbus fleet, as well as for other airlines which have maintenance contracts with MESA. The hangar is ready to receive and service Airbus A319, A320, A321, A330, A340 and A350 aircraft, and has the capacity to perform maintenance works on up to three aircraft at a time.
Mesa invested €30million (US$36 million) in the project, which will create about 150 jobs in its first three years of activity.


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Police investigate homicide near Sioux Falls
August 4, 2020
SIOUX FALLS, S.D. (AP) – Authorities are investigating the death of a man near Sioux Falls as a homicide.
A Minnehaha County sheriff's captain says the body was found in a ditch Monday morning west of Sioux Falls with gunshot wounds.
Deputies were called after a landowner found the man. Gunshot wounds were found on the body, but no firearm was present.
Authorities believe the shooting happened around 11 p.m. Sunday when a person reported hearing gunshots, An autopsy is planned today (Tuesday).
The age and name of the victim are not being released until his family has been notified.


text: We believe sharing our own journeys with following Jesus is a big step in growing as believers. Your story may relate with someone who has experienced something similar, encourage someone in the midst of fighting a battle, and help reenergize our church to keep making a difference. Are you ready to share your story? Fill out the form below to get started!


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Snowbirds US to Canada
Wednesday, Nov 8, 2023 by Professional Car CarriersHeading back to Canada for the summer? PCC has you covered! Allow us to serve your auto transportation needs to simplify your trip up north. There are many benefits to shipping your vehicle over driving the long haul yourself, and we are happy to provide a shipping solution that not only preserves your vehicle's mileage and avoids any unnecessary wear and tear, but also offers a quick and reliable process.
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Prismarine is a stone that is found under the ocean in the ocean monuments. You can craft a block of prismarine and use it for decoration.
To make a Prismarine Block, you'll need to find the Ocean Monuments to get Prismarine shards by killing Guardian under the sea. Please follow the following steps to make a Prismarine Block.
Ocean Monuments
In order to make sponge we first need to find ocean monuments. You will have to prepare some potions (potion of water breathing, potion of night vision, potion of regeneration) and then find ocean monuments. Go towards the ocean to find a monument deep down in the ocean. These potions will help you find and see the monument from above the water and also help you to breathe after getting down in the ocean. Drink all the potions one by one before finding monuments.
Kill Guardian To Get Shards
After going down into the ocean you need to find and kill a guardian so that you can get four prismarine shards. It can take some time to kill them, be patient until you get the required shards.
Crafting Prismarine
Move out of the ocean and go towards the crafting table. Open up the 3*3 crafting grid and add two prismarine shards in the lower two cells of the first column and two shards in the lower two cells of the second column. This will craft a prismarine block for you. Add this item in your "ready to use" stock.


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Women's Power Lunch Against Cancer
The Women's Power Lunch Against Cancer, benefiting cancer research at Southern Illinois University Medicine's Simmons Cancer Institute, is a remarkable opportunity to combine our efforts in the fight against cancer.
Funds raised at this inspirational event are invested in all cancer research at SCI.
This year's guest speaker is sociologist Bertice Berry, PhD, who is a best-selling author and speaker she has appeared on The Tonight Show, Oprah Winfrey, Crossfire, 20-20, PBS's Between The Lions, Comedy Central, CNN and NPR. She has written more than a dozen books and been named Comedian, Lecturer and Entertainer of the Year at different times.
"If you ain't dead, you ain't done," a character in one of Berry's novels says. She isn't done yet either. Berry believes that every one of us has been given a unique purpose, and it is our obligation to find it and use it to improve first ourselves and then those around us.
11:00 a.m. Check-in and networking
11:45 a.m. Welcome, lunch, raffle/door prizes
12:30 p.m. Speaker, Bertice Berry, PhD


text: Our Beer Garden is situated outside the main bar area and features undercover heaters for the Winter months and cooling misters for the Summer heat. This outside area is ideal for cocktail gatherings of 80-100 people and provides a relaxing atmosphere for you and your guests. Perfect for baby showers, kids birthday parties and engagement parties.


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Some Jefferson City customers experienced disruptions to CenturyLink internet service Monday.
All services were restored at approximately 1:45 p.m., company representative Michael Baker told the News Tribune in an email.
formatting link
Cabling-Design.com Forums website is not affiliated with any of the manufacturers or service providers discussed here. All logos and trade names are the property of their respective owners.


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Memphis Depay watched from the bench as Manchester United earned a manner of revenge over rivals Manchester City in the EFL Cup at Old Trafford.
Juan Mata scored the only goal of the game as Jose Mourinho's men knocked Pep Guardiola's side out of the competition on Wednesday.
It was a welcome result for the hosts after City had won the Premier League encounter earlier in the season and on the back of a chastening defeat at Chelsea on Sunday.
Manchester is Red again... #GGMU #ManUtd pic.twitter.com/Cm2DVgRLkA
— Memphis (@Memphis) October 26, 2016
And Memphis took to Twitter after the result on Wednesday night to declare that his United teammates had taken control of Manchester again after dumping City out of the EFL Cup.


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HEYSTOP Switch Carrying Case for Nintendo Switch Case with Screen Protector, 9 in 1 Nintendo Switch Accessories Kit and 6 Pcs Thumb Grip, Nintendo Switch Protective Case
Price: [price_with_discount]
(as of [price_update_date] – Details)
Nintendo Switch Accessories Kit Nintendo Switch Carry Case + Nintendo Switch Case Clear Cover + Switch Glass Film + Joy-Con Thumb Cap Large Capacity / Full Protection / Shock Resistance, make your Switch even more portable & travel friendly. Great storage capacity Designed with plenty of space to store your Nintendo Switch, game cards, Joy-Cons, Joy-Con Straps, cables, headphones, AC adapter and other accessories. Good protection With 10 game cards and a zipper component, Nintendo Switch EVA Carry Case and Soft microfiber interior, which effectively protects your device from scratches and falls. Waterproof Design High quality materials prevent the erosion of moisture, steam and other harmful gases and liquids in the air
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Easy Seat Toilet Trainer
The Puj Easy Seat Toilet Trainer provides your child with the safety, comfort, and confidence to succeed in potty training! Designed as one solid piece, there are no crevices, creases, or cracks to clean! The Puj Easy Seat Toilet Trainer fits most toilet seats and has a built-in splash guard to help keep your bathroom and child clean. Lightweight material allows for easy hanging and storage – your kids can even do it themselves! Compact design – perfect for storage and travel. Ultra-soft material – durable, non-absorbent, non-staining, and non-slip.
Soft and comfortable. Strong and durable. Won't harbour bacteria or mould; non-staining. Easy to keep clean (no small parts).
Grippy, non-slip material. Built-in Splash Guard protects from the misdirected spray. BPA and PVC Free. Hangs for easy storage. Compact for travel.
Ages 18+ months. So easy to use, kids can do it themselves!