text:
|Publication number
|Publication type
|Publication date
|Jul 13, 1954
|Filing date
|Jan 17, 1952
|Priority date
|Jan 17, 1952
|Publication number
|Hampel Clifford A, Williamson Hilding V
|Original Assignee
|Cardox Corp
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (3), Referenced by (5), Classifications (9)
|External Links: USPTO, USPTO Assignment, Espacenet
Patented July 13, 1954 UNITED STATE ATENT OFFICE NONEXPLOSIVE CHLGRINE DIOXIDE HY- DRATE COMPOSITION AND PROCESS FOR PRODUCING SAME Hilding V. Williamson, Chicago, and Clifford A. Hampel, Homewood, lit, assignors, by direct and mesnc assignments, to Cardox Corporation, Chicago, 111., a corporation of Illinois Application January 1'7, 1952, Serial No. 266,814
11 Claims. 1
shipping of large quantities of water, since about 97% of the mixture was inert water.
We have discovered that pure chlorine dioxide hydrate is stable and cannot be detonated even by a percussion cap. The hydrate was found to be stable even when a gas mixture above it was exploded. The hydrate exists at temperatures below about 18 C. but exerts a considerable vapor pressure. In the range of temperatures at which fects something like chlorine. It is highly un- 10 the material is stored and transported, the vapor stable when subjected to sunlight or heat. It pressure is substantially less.
is also unstable in concentrated form either as However, the liquid is dangerous both because a liquid or a gas. Consequently it has heretofore of the high vapor pressure of gaseous chlorine been handled either in aqueous solution or didioxide over the liquid and because the liquid luted with an inert gas such as air, nitrogen, 15 itself will detonate in the event of a gas explo carbon dioxide and the like. sion.
The solubility of low partial pressure chlorine The hydrate can be manufactured by mixing dioxide in water is low. At less than '70 mm. liquid chlorine dioxide with water at about C. p al pressure it is sligh ly lu at However, mixing of the liquid with water is at- At 2 C. a gas containing 7% chlorine dioxide 20 tended by hazards. Severe explosions resulting was bubbled through water yielding a solution in injury to personnel have been experienced containing only 1.4% chlorine dioxide. Mixtures when it was attempted to manufacture the hyof air and more than about of chlorine I drate in this manner. The mixture does not dioxide decompose upon sparking at 25 C. and explode on every occasion but its behavior can- 60" C. and decompose spontaneously at tempera- L not be predicted. It is possible that the reason tures in excess of about 70 C., the rate and for this lies in the fact that when the liquid tendency to decomposition increasing as the conchlorine dioxide is introduced into the water, centration of chlorine dioxide increases. At concrystals f hydrate immediately form which tend centrations up to the explosions are not vioto surround or include droplets of unconverted lent. Decomposition becomes less vigorous as the liquid chlorine dioxide and, when these are subtemperature is decreased below C. Because jected to the proper conditions, the liquid exof the high partial pressure of chlorine dioxide plodes violently. As previously mentioned, the above a solution of even relatively low concenhydrate itself can be handled safely, but mixtures tration the handling and shipping of aqueous with any substantial quantities of liquid chlorine solutions of chlorine dioxide would obviously be we dioxide are extremely dangerous because of the both unsafe and uneconomical. unstable character of the unhydrated chlorine Recently the interest in chlorine dioxide as dioxide.
a flour bleaching and ageing reagent has in- Merely passing a gas containing chlorine creased tremendously because it has replaced dioxide in low concentrations into water does nitrogen trichloride for this purpose in the specifi- 40 not necessarily result in the formation of hydrate. Catio s Of the U. S. F Od a d Drug Ad tra- With low concentrations of gas the water meretion. The hazards of handling chlorine dioxide 1y becomes saturated and the hydrate does not both because of its poisonous nature and its inform even at 0 C. or slightly below. We have stability have posed a real problem in the art. found that at 1 C. the solution must contain at 0 6 o ut 0 the problem 15 to install Small least about 3% chlorine dioxide before the hygenerators at the point of use, the chlorine didrate can be made to precipitate. At lower conoxide evolved being immediately diluted with centrations cooling the solution merely results in large amounts of air, which is used to sweep it its freezing to ice. from the generator and into contact with the We have discovered that a critical gas conflour or other material undergoing treatment. It 59 centration and temperature relationship exists has heretofore been impractical to produce chlorine dioxide at a central point and ship it to the point of consumption because of the explosive hazards involved. In Germany dilute aqueous solutions were employed but this required the 5 which makes possible the formation of the chlorine dioxide hydrate, and that certain steps must be followed in order to produce it at a practical rate and in practical amounts. We have also discovered that the solid hydrate can be formed into shapes convenient for handling, which can be stored or transported safely and economically under practical conditions and in commercial amounts. The most hazardous operation in connection with chlorine dioxide manufacture thus can be carried out at a central point under carefully controlled conditions, and the hydrate can be transported safely and easily to the point of consumption where the gas can be regenerated and diluted with the requisite proportions of air for use in flour bleaching, paper pulp bleaching and the like or the hydrate can be dissolved in water where an aqueous solution is desirable.
The invention will be described in conjunction with the appended drawing of which the figure is a curve of the vapor pressure, and concentra tion versus temperature.
According to one embodiment the invention comprises passing a gas containing chlorine dioxide into a saturated aqueous solution of chlorine dioxide, at a temperature below about C. and in concentrations such that the partial pressure of the chlorine dioxide in the gas is at least equal to the vapor pressure or" the chlorine dioxide in solution over the chlorine dioxide by diate present, the upper limit of gas concentra tion being governed by the safety with which the gas can be handled, and further by the upper concentration at which the chlorine dioxide will remain gaseous, i. e., will not condensate, at the operating temperature used, and recovering the chlorine dioxide hydrate formed substantially free of liquid chlorine dioxide.
The minimum concentration of chlorine dioxide in the gaseous mixture will depend upon a numb r of factors. When the absorption is carried out at atmospheric pressure the minimum concentration will be about 3.3% of chlorine dioxide vapor in the mixture. When superatmospheric pressure is applied in the absorption step the minimum concentration in the gas is reduced correspondingly. Pressures generally not exceeding 15 pounds per square inch gauge can be employed.
Partial pressures of chlorine dioxide gas in mixture above 90 mm. and generally above 100 mm. of mercury define the lower limits of operation when absorbing chlorine dioxide in saturated aqueous solutions thereof. With partial pressures lower than this chlorine dioxide hydrate does not form regardless of the length of time the gaseous mixture is passed through the aqueous phase.
The upper limit of chlorine dioxide concentration in the gaseous mixture is generally related to the degree of safety with t hich the mixture can he handled. The temperature and concentration of chlorine dioxide in the gas mixture affects its explosive characteristics. The lower the temperature the higher the concentrations of chlorine dioxide which can be safely handled. We have successfully and safely used gaseous mixtures containing 13 to and even or more at temperatures from just above the freezing point or" the aqueous phase up to about 15 C. Under proper conditions of producing and handling the gaseous mixture, proportions as high as 59% to chlorine dioxide may be used for absorption under at; lospheric pressure.
The maximum concentration is about 500 mm. of mercury partial pressure of chlorine dioxide. If higher concentrations are used not only is the tendency to decompose increased but there may be a tendency, at temperatures below the boiling point, for some of the chlorine dioxide to condense from the gaseous mixture. This may result in inclusions of liquid chlorine dioxide in the hydrate, with the undesirable results referred to above. The concentration of chlorine dioxide in the diluent gas expressed in terms of partial pressure should be below that at which condensation of chlorine dioxide from the can occur within the operating conditions employed and above about mm. of mercury. Thus, below about 490 mm. partial pressure of chlorine dioxide in the gas no chlorine dioxide can condense at a temperature above about C. It is iinportant to this invention that substantially no liquefaction of chlorine dioxide occur.
Figure 1, appended hereto, sets forth 5' aphically the minimum concentration requirements of the gas at any temperature within operating range in order for chlorine dioxide hydrate to be precipitated from a saturated aqueous solution of chlorine dioxide.
It is necessary that the aqueous phase be saturated with chlorine dioxide before precipitation of the hydrate can occur. A saturated aqueous phase particularly, one under euperatniospheric pressure within the range above set forth, has a freezing point substantially below that of pure water. Thus, by operating under a pressure of about 5 pounds gauge the absorption temperature can be carried down to a minimum of about 6 (3. below which the aqueous phase freezes. In general, temperatures of about l C. to about 3 C. are preferred and in this the gas must contain at least 13% chlorine dioxide and preferably 14% to about 25% when operating at atmospheric pressure. reposition of about 1 atmosphere pressure would permit the use of minimum concentrations as low as about 7.5 since the partial pressure of chlorine dioxide in the gas measured over a saturated solution of chlorine dioxide and solid hydrate would have a minimum partial pressure of about we ram.
The use of a small superatrnospherie pressure is desirable in view of the fact that it permits a greater amount of absorption of chlorine dioxide from gases containing of the order of 20% to 30%, so that the amount of chlorine dioxide recycled, as above described, is materially reduced.
Chlorine dioxide may be generated by any satisfactory process. Glle which is particularly beneficial is disclosed in United States Reissue Patout No. 23,111, to Gustav Holst. According to this process, air or other inert diluent gas is mixed with sulfur dioxide and is passed through a fairly concentrated solution of sodium chlorate acidified with sulfuric acid or other znneral acid except halogen acids.
Other known methods include reacti g chlorates with mineral acids such as sulfuric or hydrochloric, sometimes in the presence of a reducing agent such as hydrogen peroxide, persulfuric acid, organic acids, formaldehyde, manganese dichloride and other salts of inuitiwalent metals. It has also been produced by electrolytic vapor pressure in mms. of mercury and the right hand abscissa shows the vapor pressure in atmospheres, which can be converted to percent equilibrium concentration of chlorine dioxide in gas and liquid phases by multiplying by 100. Be-
cause of safety precautions necessary in making the determinations the readings on which the curves are based are accurate only to :4 mm. It will be seen that chlorine dioxide hydrate exerts a substantially lower vapor pressure in the operating ranges contemplated than does chlorine dioxide. Generally speaking pure water is used in the manufacturing steps. Consequently, temperatures below -1 C. are not employed since the water would freeze. However, it is within the contemplation of this invention to add various inert materials to the water, which will depress its freezing point and, therefore, permit the use of temperatures substantially below 0 C. Such materials must be inert to chlorine dioxide and chlorine at the temperatures used for hydrate formation as well as the range of temperatures at which the chlorine dioxide is regenerated from the hydrate. Various types of freezing point depressants may be used. These include electrolytes such as calcium chloride, sodium chloride, magnesium chloride; various mineral acids including sulfuric and phosphoric acids; organic compounds such as aliphatic alcohols including methyl, ethyl and propyl alcohol; polyhydroxy alcohols such as glycerol, ethylene glycol and other glycols. It will be observed from Figure 1 that the partial pressure of chlorine dioxide in the gas phase can be substantially reduced when the temperature is reduced to say C. At this temperature a partial pressure equal to mms. or a concentration of about 7% can be used in formation of the hydrate. This is an advantage from a safety standpoint. When pure water is used above 0 C. and atmospheric pressure, a partial pressure above 100 mms. or a concentration of about 12-13% minimum is required.
As previously mentioned, if superatmospheric pressure is used in the absorption step the mini mum chlorine dioxide partial pressure of 100 mm. would be expressive of a percentage concentration somewhat less than the minimum above stated for atmospheric pressure.
If contact between the gas and aqueous phase is efficient, the hydrate forms rapidly as pale yellow crystals. To initiate and facilitate crystallization the solution may be seeded with previously formed hydrate crystals. The use of concentrations of chlorine dioxide greater than the minimum is desirable in view of the fact that a larger proportion of hydrate will form for a given quantity of feed gas, which in turn reduces the amount of recirculation.
The reaction to form the hydrate is generally so rapid that the concentration of the effluent gas will be of about the equilibrium concentration. Therefore, the effluent gas will contain a substantial proportion of chlorine dioxide. Rather than install a recovery system or a concentrating system for this gas, it is recycled to the generator as a sweep gas especially when a process such as that described by Holst is used. It is thu enriched by chlorine dioxide from the generator and returned to the absorber.
As hydrate formation occurs the crystals sep arate from the aqueous phase, the material in the absorption zone may eventually become a thick mush. If the absorption is carried out to this point the entire mixture of water and crystals can be withdrawn from the absorber and frozen into cakes, spheres, cubes or other shapes, or can be frozen into a block and granulated if desired.
The crystals after separating the excess water can be treated with gas containing chlorine dioxide of the above defined concentrations and temperature conditions so that occluded water can be converted to the hydrate. This may be done by passing the gas through the filter cake before pressing.
As previously pointed out, the solid hydrate has an appreciable vapor pressure and must be stored at low temperatures. Temperatures below zero are employed and preferably in the neighborhood of 20 C.
In order to reduce the tendency of chlorine dioxide to sublime from the blocks, we have adopted a novel and effective scheme of coating the exterior of the blocks or other shapes, with water ice. This can be done by cooling the blocks below the freezing point of water and then dipping them into cold water or by spraying water over the exterior. Since the blocks are at a temperature below the freezing point of water, a thin layer of ice is immediately formed and this prevents the chlorine dioxide from escaping from the hydrate. As a consequence, the blocks can be stored for long periods of time without appreciable escape of chlorine dioxide, which reduces hazards and greatly simplifies storage and transportation problems. This ice coating method can be resorted to for protecting other shapes such as spheres, cubes or even granules. There is a tendency for chlorine dioxide to eventually diifuse through the ice, but since the vapor pressure at commercial storage temperatures is low, the diffusion rate is slow. There is a tendency for the chlorine dioxide to combine with the ice layer during the diffusion. These shapes particularly when coated with ice constitute new and highly useful compositions of matter.
The shaped hydrate is stored and transported in refrigerated containers much like those used for the transportation and storage of solid carbon dioxide. These resemble the well-known domestic deep freeze units. However, they should be equipped with means by which the box can be ventilated in order to sweep out accumulated chlorine dioxide gas especially before loading and unloading so as not to expose the operator to the fumes, and to avoid hazards from decomposition of accumulated gas. The containers should be equipped with explosion relief lids. At the low temperatures the material can be stored and handled without hazard. Thus even though accidentally subjected to a spark or the like which at room temperature or above would cause decomposition of chlorine dioxide gas, the hazard is nil below 0 C. However, in case of failure of the refrigeration equipment, the partial pressure of chlorine dioxide may build up and conditions could conceivably arise in which an unstable con centration of gas existed. By use of suitable re lief means even if decomposition occurred pres sures developed would dissipate without damage to the box. As previously stated, the hydrate in the absence of liquid chlorine dioxide is stable and has resisted all attempts to detonate it even when subjected to the firing of a percussion cap.
The following examples are given to illustrate the process but should not be considered as un duly limiting it.
Example I Chlorine dioxide hydrate was made by cooling water to 0 C. and bubbling through the water a gas mixture containing air and 13% chlorine dioxide gas. After the gas had been passed through until 2.9% of chlorine dioxide was dissolved, crystallization was initiated by adding several small pieces of solid carbon dioxide to the water. A mush of yellow hydrate crystals formed which contained 17% of chlorine dioxide. The crystals were filtered and could be pressed into a solid cake.
Example II A similar run was made to that of Example I using a gas containing 16% chlorine dioxide. The amount of chlorine dioxide dissolved in the water was about 3%. The crystals which formed contained 23.4% chlorine dioxide.
Example III Chlorine dioxide hydrate was made under con- .iti-ons similar to those described in Example I with the water temperature at 1 C. and with a gas of 26.6% chlorine dioxide content. The water contained about 3% chlorine dioxide.
Example IV Chlorine dioxide hydrate was made with a 15.1% chlorine dioxide containing gas and the water at 1 C. The water contained 2.9% chlorine dioxide and had a specific gravity of 1.03. The hydrate crystals contained 24.9% chlorine dioxide.
Example V Chlorine dioxide hydrate was made under the conditions of Example I using gas containing 18.2% chlorine dioxide. The aqueous phase contained 3.5% chlorine dioxide. The yellow crystals of hydrate contained 20.3% chlorine dioxide.
The analysis on the hydrate of the above examples varies because of the presence of free water. The true water of hydration is nearer the decahydrate.
The chlorine dioxide used contained less than 1.5% and in general about 0.5% chlorine.
Example VI A mixture of chlorine dioxide and air was cooled to C. and was passed through watercontaining absorbers and held at various ternperatures from 0 C. to 5 C. Concentrations of gas ranging from 14 to 23% chlorine dioxide were sed. Crystallization was initiated by adding solid carbon dioxide to the saturated solutions which promoted immediate precipitation of the hydrate. Hydrates containing an indicated to 13 molecules of water of crystallization were formed. In. these runs the excess water was filtered from the crystals and a gas containing 16.5 to 17.9 915 of chlorine dioxide mixed with air was passed through the mass of crystals. In this way, a hydrate having indicated water of crystallization of more than 13 molecules was converted to a hydrate having 10 molecules of water of crystallization. The time used for this gas treatment ranged from about 10 to about minutes. The docahydrate was formed after about 10 minutes treatment with the gas containing 17.9% chlorine dioxide and after about 20 minutes when the gas contained about 16.5% chlorine dioxide. The crystals were held just above the freezing point of water during the gas treatment.
These compositions were formed into blocks by pressing. After cooling the bloclcs to about 20 C. they were dipped briefly in water at a temperature of about 1 C. whereupon a thin coating of ice formed. Blocks made in this Way could be stored for long periods of time with evolution of little or no chlorine dioxide. In general, a coating of ice from about 1% to about /4 inch may be used. Thicker coatings have been found generally unnecessary. A coating in the neighborhood of A; inch is preferred.
This application is a continuation in part of our copending application, Serial No. /184, filed June 21, 1949, now abandoned.
We claim as our invention:
1. A process for forming non-explosive chlorine dioxide hydrate free of liquid chlorine dioxide which comprises the steps of absorbing chlorine dioxide vapor from a gaseous mixture consisting essentially of chlorine dioxide vapor and inert diluent gas, in a saturated aqueous solution of chlorine dioxide maintained at a tern perature below about 15 C. and above the freezing point of the aqueous phase, the partial pres sure of said chlorine dioxide in the gas m xture being at least equal to the vapor pressure of the chlorine dioxide in the aqueous phase measured over chlorine dioxide hydrate and, in any event, being at least about 100 mm. and below 565. mm. of mercury, and recovering the chlorine dioxide hydrate product formed and forming it into a solid coherent body containing up to by weight of chlorine dioxide.
2. The process of claim 1 wherein the recovered chlorine dioxide hydrate is formed into a solid shaped body by applied mechanical pressure.
3. The process of claim 1 wherein the hydrate is recovered as a slurry of crystals in water and the resultant mass is frozen.
4. The process of claim 1 wherein the recovered hydrate is first compressed into a solid shaped body, then cooled below the freezing point of water and coated with a layer of ice.
5. The process of claim 1 wherein the aqueous solution contains a freezing point depressant.
6. The process of claim 1 wherein the aqueous solution contains a freezing point depressant comprising sulfuric acid.
'7. The process of claim 1 wherein the body is coated with water ice.
8. A process for forming non-explosive chlo rine dioxide hydrate substantially free of liquid chlorine dioxide, comprising the steps of generating chlorine dioxide gas, diluting it with an inert gas to form a gaseous mixture in which the partial pressure of said chlorine dioxide is least 100 mm. and below 500 min. of mercury, abso b ing chlorine dioxide gas from said mixture in a saturated aqueous solution of chlorine dioxide at a temperature below about 15 C. and above the temperature at which the aqueous phase freezes, to form chlorine dioxide hydrate, separating the gaseous mixture containing a reduced chlorine dioxide content from the absorption step, recycling it to said generation step as a source of said inert gas therein, increasing the chlorine dioxide content to a partial pressure above 100 and below 500 mm. of mercury, and recovering the chlorine dioxide hydrate product from the absorption step containing up to about 24.9% by weight of chlorine dioxide.
9. The process of claim 8 wherein the hydrate is recovered from the absorption step a slurry of crystals, removing the aqueous phase from said slurry, and recycling it to the absorption step.
10. A process for forming non-explosive chlorine dioxide hydrate substantially free of liquid chlorine dioxide which comprises absorbing chlorine dioxide vapors from a gaseous "ixturc consisting essentially of chlorine dioxide vapor and an inert diluent gas, in a saturated aqueous solution of chlorine dioxide maintained at a temperature below about 7 C. and above the freezing point of the aqueous phase, the partial pressure of said chlorine dioxide in the gas mixture being at least about 100 mm. and below 500 mm. of mercury, recovering the chlorine dioxide hydrate crystals formed, and passing a mixture of chlorine dioxide gas and an inert diluent gas over said crystals at a temperature of about 1 C. to about 7 C., the partial pressure of the chlorine dioxide in said last mentioned gas being at least about 100 mm. and below 500 mm. of mercury, thereby forming additional chlorine dioxide hydrate from the aqueous phase occluded to said hydrate crystals.
11. A process for forming non-explosive chlorine dioxide hydrate free of liquid chlorine dioxide, which comprises the steps of absorbing, at a super-atmospheric pressure, chlorine dioxide vapor from a gaseous mixture consisting essentially of chlorine dioxide vapor and inert diluent gas in a saturated aqueous solution of chlorine dioxide maintained at a temperature below about 15 C. and above the freezing point of the aqueous phase, the partial pressure of said chlorine dioxide in the gas mixture being at least equal to References Cited in the file of this patent UNITED STATES PATENTS Number Name Date Re. 23,111 Holst May 10, 1949 2,335,808 Soule Nov. 30, 1943 2,489,572 Hampel Nov. 29, 1949 OTHER REFERENCES J. W. Mellors "A Comprehensive Treatise on Inorganic and Theoretical Chemistry, vol. 2, 1922 ed., pp. 289, 290; Longmans, Green and C0., New York.
Ephraims Inorganic Chem., 4th ed., revised, page 377; Nordeman Publishing Co., Inc., New York.
|Cited Patent
|Filing date
|Publication date
|Sep 26, 1941
|Nov 30, 1943
|Mathieson Alkali Works Inc
|Method for producing chlorine dioxide
|Feb 13, 1946
|Nov 29, 1949
|Cardox Corp
|Process for the production of perchlorates and chlorine dioxide
|May 10, 1949
|Process foe producing chlorine
|Citing Patent
|Filing date
|Publication date
|Jan 5, 1953
|Apr 3, 1956
|Cardox Corp
|Process for manufacture of chlorine dioxide hydrate
|Feb 23, 1956
|Nov 13, 1962
|Hooker Chemical Corp
|Chlorine dioxide separation
|Dec 16, 1960
|Apr 9, 1963
|Fmc Corp
|Process for storage of chlorine dioxide
|Sep 4, 1963
|Nov 16, 1965
|Gen Foods Corp
|Method of handling gas
|Apr 4, 1995
|Jan 13, 1998
|Rio Linda Chemical Co., Inc.
|Generation and storage of chlorine dioxide in a non-aqueous medium
|U.S. Classification
|423/477, 252/67, 62/1, 62/46.1, 252/187.21
|International Classification
|Cooperative Classification
|European Classification


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Author: Naomi Duguid, Rivers of Flavour
Published Wednesday, December 19, 2012 11:26AM EST
Last Updated Wednesday, December 19, 2012 1:04PM EST
Writer, photographer, traveller and cook Naomi Duguid has written a book about Burma, also known as Myanmar.
Her book includes several recipes, one of which, for Lemongrass-Ginger Sliders, is included below.
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Kleintje's Tribute
All about Kleintje
Pet Tip
Tip 46 – Life expectancy in dogs – How long will my dog live?
We all want our pet dogs to live as long as possible, but the fact of the matter is that on average, certain dog breeds live longer than others. This might be a consideration when choosing a dog breed and …
- Owner:
- Sarah Baker
- City:
- Kortrijk
- Province, Country:
- Not Provided
- Type/Breed:
- Hamster
- Date of Birth:
- unknow
- Date of Death
- 14 juli 2005
- Sex:
- Unknown
- Height:
- Not Provided
- Weight:
- Not Provided
- Coat Colour:
- brown with white
- Eye Colour:
- black
Dear Kleintje
Your dead came very sudden. We don´t know what happend and we will never know, but remember that we will always love you and miss you!
Love, Familie van Dooren


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It's exciting to see Shyamalan on such confident footing once more, all these years later.
It's exciting to see Shyamalan on such confident footing once more, all these years later.
The last forty minutes of the movie do come together in a pretty diverting way.
Roger Ebert on James Ivory's "Howards End".
"The Ballad of Narayama" is a Japanese film of great beauty and elegant artifice, telling a story of startling cruelty. What a space it opens…
Meryl Streep and other awards recipients shared their thoughts on an America under Donald Trump during last night's Golden Globes ceremony.
"La La Land" made Golden Globes history last night with seven awards, including Best Picture (Comedy/Musical).
Chaz Ebert highlights films with the potential to get us through the confusing political times of the Trump presidency.
Molly Haskell speaks with Matt Zoller Seitz about "From Reverence to Rape," "Love and Other Infectious Diseases," "Steven Spielberg: A Life in Films" and more.
FFC Seongyong Cho explores Frederick Wiseman's 2014 documentary, "National Gallery."
The forces behind San Diego Comic-Con have launched a new con-centric channel, featuring "Kings of Con," "Con Man" and "Mark Hamill's Pop Culture Quest."
Whenever people ask about what the Black Lives Matter movement is, whether it's a year or 50 from now, I will tell them to see…
A review of two opening night films from Sundance 2017.
Ken Loach took home the top prize at this year's Cannes Film Festival, winning the Palme d'Or for his widely acclaimed picture, "I, Daniel Blake." In this latest video dispatch, Chaz Ebert provides an overview of the big winners announced yesterday, as well as a candid report on the cheers and boos from members of the press.
Click on the video below to view Chaz's commentary, as well as footage of Loach and jury president George Miller at post-awards press conferences.
2016 Cannes Final Awards: RogerEbert.com from The Mint on Vimeo.
Purchase Roger Ebert's "Two Weeks in the Midday Sun" here.
Next Article: Cannes 2016 Videos: Table of Contents Previous Article: Video: Critic's Roundtable at Cannes
This message came to me from a reader named Peter Svensland. He and a fr...
Chaz Ebert highlights films with the potential to get us through the confusing political times of the Trump presidenc...
A review of Netflix's new series, Lemony Snicket's "A Series of Unfortunate Events," which premieres January 13.
One of the most audacious American films from the 1960s is now available via the Criterion Collection.


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Thomas Kamann
Keep the News and C-Tube are two designs from Thomas Kamann that are handy ways to store your everyday items. They're no frills and in…
Keep the News and C-Tube are two designs from Thomas Kamann that are handy ways to store your everyday items. They're no frills and in…
Sneak Salone peek from Pallucco.
A sneak preview of the good stuff from Diamantini & Domeniconi for Salone.
These pieces, designed by Sergey Saava, remind me a lot of tic-tac-toe.
Oja furniture looks to be some of the earlier foldable/flat-pak furniture designs.
Bird-related but not a bird, this adorable wall shelf from Alex Hellum would be the cutest in a child's room on a wall that had a tree…
Twist Cubes. [via Furniture Seen]
Nureyev is the name of this circular bookshelf designed by Roderick Vos.
The Rek bookcase from Reinier de Jong is super compact, but can be adjusted for your space. [via Dezeen]
Lili Lite is a reading light, a bookmark and a bookshelf combined into one smart product — talk about multifunctional! And, it's…
Sammy Engramer designed this super cool kanji shelf. [via Cribcandy]
OVO Editions has been working with Pol Quadens to create some fantastic pieces made from Corian and carbon fiber. I'm so excited to sh…
My favorite piece is the light, which is named the Guernica light. Guernica is one of my favorite paintings. [via Blue Ant Studio]
One of my favorite designs of late is this bookshelf, and there are no shortage of options. Spine Book Tower ($119)
Does this bookcase remind anyone else of Plinko or is it just me?
Stanislav Katz's designs are super cool. These are my favorites.


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The mobile phone industry - from manufacturers and application developers to network operators - is becoming corporate Britain's latest whipping boy.
Many companies want to raise productivity and improve customer service by embracing mobile technology, but that requires the right tools and services at an affordable price. The problem, it's argued, is that the industry is too focused on consumers, who buy 80 per cent of phones, according to analyst group Gartner.
At the Security Industry Authority [SIA], which polices private security firms, Tim O'Neill, an assistant director for IT, wants to turn home workers into mobile workers. The SIA's 50 investigators use a hefty laptop, with a fixed broadband connection, but they could be using hand-held devices with a fast wireless data service.
So what's stopping Mr O'Neill? Mobile data services are insufficiently fast, reliable or secure, pricing is uneconomic and unpredictable, and he can't find a suitable device that works with an external keyboard, screen and mouse.
The number-one gripe from IT directors is that consumer fashion determines mobile phone production. The range of business phones is growing, but camera phones still accounted for 55 per cent of output this year.
"Feature-heavy phones cause major headaches to businesses, particularly from the security perspective," says Will McMeechan, the lead business developer at Nationwide building society. "Bluetooth connectivity, cameras and the ability to download and store data give these devices the capacity to be misused."
Corporate customers are crying out for stable, secure devices employees can use to access applications such as email and customer records, or file a report. So-called smart phones are beginning to address this, but they come at a price.
In an industry striving to bring out the latest thing, handsets come and go quickly. That's great for a consumer, but it's irritating for a business that has invested in equipment and applications that don't work with upgraded phones.
"As a replacement for the much-loved Nokia 6310i, we've been offered camera phones and even a phone with a useless flip-out Qwerty keyboard," says David Geliher, the IT manager at Charles Wells, a large independent brewer. "Each of these means replacing the car kit throughout the company fleet."
IT directors also complain that suppliers keep product "roadmaps" under wraps. The more a company invests in technology, the more vulnerable it is to products being prematurely discontinued or a lack of information on future products.
Take, for example, eCourier. It prides itself on its technological edge over rivals. As customers place orders online, jobs are automatically dispatched to each courier. Customers can then track the package and receive an alert when it arrives. ECourier has worked extensively on the mobile devices and GPS systems carried by the couriers, to ensure they run seamlessly. Its chief technical officer, Jay Bregman, expects the XDA II, which it now uses, to be superseded but does not know if the XDA III will be compatible with the GPS device. "Everyone is really scared of a new device coming out," he admits.
Working with continually evolving platforms is just part of the headache. At Hogg Robinson, a travel management company, customers are sent itiner-aries and alerts to their phones. The next step is enabling them to access systems to make or modify a booking.
"The underlying issue is the lack of standards across the various devices and providers: some are Java based, some use Microsoft technology and others are proprietary," said Paul Saggar, director of technology development at Hogg Robinson's business technology division.
Businesses budget for expenditure in advance, but the unpredictability of mobile billing can cause friction between customer and operator. "I find the whole market holds the customer to ransom," argues the SIA's Mr O'Neill. "Buy a 3G phone, pay for GPRS monthly rental, pay for 3G monthly rental, pay on top per MB of data, pay for each photo message, pay for email. It's like buying a car and paying to push on the brake pedal."
For companies used to bartering with suppliers, it is frustrating that their wish lists appear to fall on deaf ears.
That is not to say the mobile industry ignores the corporate market. Operators and manufacturers have divisions dedicated to corporate customers - Orange points out that its 1,000-strong Orange Business Solutions team is big enough to be a FTSE-100 company in its own right. In the long run, most think the prognosis for the relationship between the industry and corporate customers is good.
But while the mobile heartland - the volume-driven, easy-to-please consumer space - remains highly profitable, operators won't be rolling out the red carpet for cost-conscious, demanding corporate customers just yet. As Andy Mulholland, global chief technology officer at consultants Capgemini, points out: "Ring tones are currently a better bet than a serious attack on the business market."Reuse content


text: Opera's Mini Browser Coming to iPadGary Cutlack2/11/11 4:20amFiled to: appsCellphonesOperaBrowsersOpera MiniipadApple15EditPromoteShare to KinjaToggle Conversation toolsGo to permalink In its latest press release about how well everything's going and how popular it is, Opera has revealed plans for an iPad version of its popular Opera Mini browser. It'll also be showing off updates of the app for "Android, iPhone, J2ME, BlackBerry, Symbian" at Mobile World Congress next week. If you're new to Opera Mini, there's a clever little emulator over on Opera's mobile site. [Opera]Gear from Kinja DealsProtect Your iPhone SE With These Cheap iPhone 5 Cases The Kole is a Beautiful, Thermal, Easily Pocketable Flask for EverythingAmazon's Graco Gold Box Makes Childcare A Little More AffordableReply15 repliesLeave a reply


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Content tagged "Queen of Green"
Secret ingredients stink
Secret ingredients used to scent products like deodorant, shampoo, dryer sheets, and air freshener may actually be hazardous to your health, and the planet's. You have a right to know what's in the products you use on your body or in your home. More »
Go fragrance-free
Join the growing movement for fragrance-free homes and workplaces! More »
Show the planet some love
Whether you're a hopeless romantic or see Valentine's Day as just a greeting-card holiday, there are lots of ways to love the planet (and the ones you're with) on February 14th and beyond. More »
Light up your life
If you're reading this, chances are you've switched many of your incandescent light bulbs for more efficient and long-lived CFLs. But I've learned that one kind of bulb isn't the perfect fit for every socket. More »
What the phth? Safer kids' toys just a baby step.
Phthalates. Hard to say but finally banned from children's soft vinyl toys as of June 2011. (For the record, it's pronounced thal-ate.) Mainly used as plasticizers, these were added to polyvinyl chloride (PVC) to make products flexible. 'Cause who wants a square rubber ducky? More »
The dish on dishwasher soap
Phosphates in laundry detergents during the '60s and '70s might have had our mothers seeing whiter whites, but they also turned our streams, rivers and lakes green. Last year a ban on phosphates was introduced for a product you may not have even realized contained phosphates. More »
New Year's resolve: clean up your trash habits
January is not known as trash season, though your garbage collector might disagree. This year, ring in the New Year by changing the way you throw things out. More »
Inspiration is only a flush away
The Smiths have just started their "greening" and already they're inspiring others. (And by others, I mean me, the Queen of Green!) Find out how a beloved bathtub toy seahorse inspired two toilet replacements. More »
Breaking up with your garburator
When you put stuff down your garburator, do you think you're feeding the fish? Whatever goes into an in-sink disposal unit gets cleaned and treated in the sanitary sewer system, wasting energy and water. Why wash organics that can be composted into soil? More »
Five tips for a happy, healthy and green holiday season
Every holiday season I receive a sack full of requests from Canadians on how to celebrate a more environmentally friendly Christmas. Here are this year's tips on how to stay green, long after the snow flies. More »


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Students are introduced to the use of symbolism and how it can change one's view of a piece of art. Using a piece of art, they view it as if they were the artist and create a symbol that accompanies it. They discuss the impact of two- and three-dimensional artwork and create a mask based on a specific culture.
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The Chip with Dale's Treeseed thrill ride, which recently celebrated its mousey anniversary
Nobody knows what the purpose of Chip with Dale's Treeseed is. It once had free beer, but some stuck-up paralegals had it remodeled to make it harder for kids to get exercise.
Avoid Princess Mode
© copyright 2011–2017
A Pants Aflame production


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Bulk Food
- Sauces and Bases
- Ham Base
- Ham Base and Granulars (3)
- Custom Foods Ham Base (4)
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- "I really appreciate your website. I make occasion cakes for family & friends mostly. Thanks to you, I can get the ingredients I need. I cannot find them anywhere in my area.
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Treat yourself or someone you care about to a night off. Create a special occasion, even if you are cooking challenged! Just set the table, light the candles and take all the credit! Our splendid range of Ham Base items will make you a star in a matter of few minutes. We challenge you that after having our Ham Base items once, your guests could not resist the temptation and would definitely long for more and more. For your convenience, we have tied up with 4 top notch Ham Base manufacturers and you can choose from their 8 tempting varieties.


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Nina Dobrev photo
Most popular Nina Dobrev photos, ranked by our visitors.
Top pics of Nina Dobrev
Nina Dobrev photo galley
Check out full gallery with 3361 pictures of Nina Dobrev. Only high quality pics and photos with Nina Dobrev. Last update date: 21 January 2017.
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Popular photo galleries of celebrities
Most popular celebrity photogalleries:
See Nina Dobrev's Bikini Look At The Beach In Brazil
Nina Dobrev showed off her toned body once more. The star wore a blue and white patterned strappy bikini while resting in São Paulo (Brazil). This happened on Saturday. The beachy look of the actress was complemented with huge sunglasses and a white hat.
© ThePlace2.ru - Celebrity photos
mail: email@example.com
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Our search has the following Google-type functionality:
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eg. Harry -Potter
Search results will not contain 'Potter'.
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eg. Harry AND Potter
Search results will contain both 'Harry' and 'Potter'.
If you use 'OR' between 2 words, then either or both of those words will be present in the search results.
eg. 'Harry OR Potter'
Search results will contain just 'Harry', or just 'Potter', or both 'Harry' and 'Potter'.
If you use 'NOT' before a word, that word will be absent in the search results. (This is the same as using the minus symbol).
eg. 'Harry NOT Potter'
Search results will not contain 'Potter'.
If you use double quotation marks around words, those words will be present in that order.
eg. "Harry Potter"
Search results will contain 'Harry Potter', but not 'Potter Harry'.
If you use '*' in a word, it performs a wildcard search, as it signifies any number of characters. (Searches cannot start with a wildcard).
eg. 'Pot*er'
Search results will contain words starting with 'Pot' and ending in 'er', such as 'Potter'.
Incorporating examples from areas ranging from epigenetics to value investing, from chess tactics to quantum physics, this... [more]
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Self-contained development of cohomological theory of manifolds with various sheaves and its application to differential geometry... [more]
From Uluru to the Great Dividing Range, The Geology of Australia explores the timeless forces that have shaped this continent.... [more]
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In this compelling journey through peaks both real and imaginary, Veronica della Dora explores how the history of mountains... [more]
State of the World first puts our current moment in context, tracing cities in the arc of human history. It also examines... [more]
The search for the fundamental nature of reality [more]
Blowout is the first comprehensive account of the legal, economic, and environmental consequences of the April 2010 blowout... [more]
Examines 100 extraordinary projects, theories and experiments that have been conducted in the name of science. From spider... [more]
Did you ever wonder why some insects can walk on water? Or how the Ancient Egyptians made mummies? Are you curious about why... [more]
Freakonomics for our modern online lives from the world's leading cyberpsychologist and inspiration for CSI Cyber, Mary Aiken.... [more]
Scientist Richard Fortey chronicles what he found on his four acres of woodland in the Chiltern Hills of Oxfordshire, England... [more]
A philosopher dons a wet suit and journeys into the depths of consciousness. [more]
From the best-selling authors of London: The Information Capital comes the first book to use big data to map the movements... [more]
An encyclopaedia and an atlas of water on planet Earth featuring astonishingly detailed photographs from cameras aboard orbiting... [more]
Ideas about numbers, magnitudes and frequencies shape and give texture to almost everything we feel, say, dream and do. In... [more]
<b>A captivating introduction to the physics of how animals do what they must do to survive.</b> [more]
Photographer Beth Moon revisits the world's oldest trees in the darkest places on earth, using colour photography to capture... [more]
In his latest book, Eric Scerri presents a completely original account of the nature of scientific progress. It consists... [more]
<i>Wildlife Spectacles </i>is an awe-inspiring exploration of the most remarkable displays of animal behavior in North America.... [more]
A history of science distilled into 100 notable experiments - epic moments that have fuelled our understanding of Earth and... [more]


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Big Ego Gets Paulina Porizkova Fired From 'America's Next Top Model'
Paulina Porizkova's job in "America's Next Top Model" is short-lived. The supermodel who joined in the 10th cycle to replace Twiggy as one of the judges has shared that she was fired by "someone" from the show and it's probably due to her "gigantic huge ego".
"Listen, do you know why I am in Los Angeles? Because I am looking for a job," Porizkova explained to Craig Ferguson when she appeared on "The Late Late Show" on Tuesday, May 12. "Because I was fired by America's Next Top Model on my birthday." Porizkova turned 44 on April 9 which means that she may be excluded from the judging panel in the upcoming 13th cycle.
When asked what could possibly be the reason, Porizkova claimed that she has no clue but had a theory for it. "The reason I was told I was fired was because, it seemed, that America's Next Top Model has gotten too fat and they needed to cut some fat and the fat was me," she said. "So I figured it was either that or my gigantic huge ego. Which I wasn't aware of until I was told by the producers that I have an ego problem."
Craig then said that he didn't think she has a big ego. To this Porizkova said, "I didn't either. But Tyra (Banks)... I really believe that just felt they didn't need me, which of course they don't, so that's okay."
- 'Saturday Night Live' Taps Kristen Stewart as the Next Host
- Armie Hammer Responds to 'Green Lantern Corps' Rumor
- Big Sean Performs 'Bounce Back', Premieres 'Sunday Morning Jetpack' on 'Saturday Night Live'
- Louis Tomlinson Reunites With Briana Jungwirth to Celebrate Their Son's 1st Birthday
- Luke Bryan to Sing National Anthem at Super Bowl
- 'Veronica Mars' Boss Hints at Potential Revival
- Artist of the Week: Kehlani
- Ivanka Trump's Brother-In-Law Joshua Kushner Joined Women's March on Washington


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Discover a selection of top forums browns sports on the internet. Come to share your passion on forums browns sports and meet other fans of browns sports. Then, why don't you create your own forum of browns sports ?
A place on the internet to discuss MSU sports, bourbon, and cigars, tell made up stories and generally act like an idiot when no one is watching. Sarcasm allowed.
spartans, michigan, state, football, basketball, izzo, dantonio, message, board, rose, bowl, neotantra, parsnip, margaret, 31st, countess, 24th, lady, garioch
Free forum : General discussion: family, friends, music, movies, TV, celebrities, games, hobbies, pets, art, literature, sports, news and politics, every day life.
free, forum, crimson, cafe, general, discussion, family, friends, music, movies, celebrities, games, hobbies, pets, literature, news, politics, #sports, transportation, paranormal, every
Free forum : Ukraine English news, World News, Sports News, Ukie Pub Entertainment, Ukrainian News, Ukraine news in Ukrainian, Ukraine, Donetsk, Odessa, Kyiv, Kiev, Lviv, Ukraine forum, Ukraine news, Maidan
ukraine, news, english, world, #sports, Україна, новини, світові, спорту, ukie, Розваги, Новини, України, мовою, Дон, Майдан
Sports Card Trading Site
detnews.com sports talk alternative forum.
pistons, detnews.com, forums, detroit, news, #sports
Free forum : SPORTS MESSAGE BOARDS WITH PICKS, PLAYS, AND SPORTS RELATED INFORMATION. FREE CONTESTS. FREE PLAYS FROM A PROFESSIONAL HANDICAPPER.
free, forum, #sports, handicapping, picks, message, board, plays, football, basketball, baseball
The AALoA, a community of sports video games running different online leagues. #PS4, #PS3, #PSVita, #PS4Share. Follow us on twitter, @_AALoA and on facebook.
aaloa, playstation, madden, online, franchise, video, game, community, dynasty, league
Here for fun picking all kinds of sports
Forum football europe
forusports, football, #sports, match, barcelone, real, madrid, championnat, ligue1, ligue2, champions, league, news, kooora, fifa, actualités
A place to exchange ideas and to discuss the shooting sports.
camp, sumter, members, place, exchange, ideas, discuss, shooting, #sports
Free forum : EA Sports' NHL Hockey Ultimate Team mode re-visioned to make it more competitive.
official, website, hutvs, sports', hockey, ultimate, team, mode, re-visioned, competitive, nhl16, league, franchise, vghl, opgl
Rules discussion for high school sports officials
We are a crime and current events blogging site about high profile murder cases, missing kids and adults. Our members only section contains sports news, celebrity news, humor and much more.
jodi, arias, travis, alexander, bill, cosby, holly, bobo, allana, gallagher, sharman, odom, olivia, culbreath, maggie, daniels, sanel, saint, simon, alexandria, chery, april, millsap, melinda, munoz, grace
Free forum : Bass Fishing Club Sports and Recreation.
bass, fishing, club, pacific, coast, association, #sports, recreation, forum, lower, mainland
A friendly, relaxed community where you can talk about whatever you want.
vestibule, friendly, relaxed, community, talk, forum, forums, discussion, movies, #sports, anime, video, games, politics, science, religion, civil, rights, random, message, board, thread, topic
This forum talks about every thing happening eg sports entertainment career politics health jobs animals science&technology business love&romance pets etc.
general, talk, talks, happening, #sports, entertainment, career, politics, health, jobs, animals, business, love&romance, pets
This forum provides a platform for members, either living inside or outside the City of Hobsons Bay, to discuss stuff related to the local area.
hobsons, forum, community, local, western, suburb, altona, meadows, williamstown, north, brookyln, laverton, seaholme, seabrook, kingsville, melbourne, victoria, australia, environment, liveable, heritage, arts, culture, #sports, recreation, nature
A forum for discussion regarding the great sports entertainer, actor, and orator, Glenn "Kane" Jacobs.
veil, fire, forum, discussion, regarding, great, #sports, entertainer, actor, orator, glenn, "kane", jacobs
Dynamic Chat is a general discussion chat forum where you can talk about anything that you like!
baking, cooking, arts, current, events, beauty, health, politics, nature, #sports, celebrations, holidays, hobbies, literature, music, television, technology
All sports, all of the time.
Free forum : A place for fanatics of Wisconsin sports where all are invited to talk/vent about sports AND everything else.
free, avant, garde, packers, brewers, beer, favre, dali's, mike, mccarthy, warhol, blair, kiel, badgers, bucks, venison, kierkegaard, super, doper, batboy, rodgers, thompson
Free forum : This is a forum where you can discuss sports and money.
chatcube, kids, finance, money, management, bank, account, teens, #sports, talk, forum, discussions
Sports Gaming Franchises for all sports across all gaming platforms.
#sports, gaming, franchises, platforms
Donkhard. com | Poker | Rakeback | Freerolls | Passwords | Sportsbooks | Casinos | Bingo
donkhard, freeroll, password, donkhard.com, rakeback, poker, rake, back, sportsbooks, #sports, betting, casino, bingo, online, horse, racing, racebook, wager
Clarkson Sports Car Club
Reign e-Sports is a premier media and eSports organization that strives to produce the best quality content for its daily thousands of viewers.
reign, esports, e-sports, premier, media, organization, strives, produce, quality, content, daily, thousands, viewers
Free forum : Forum for discussing sports cards and purchasing box and case breaks. Check out all the great Topps baseball and football cards that we will be opening. Buy your favorite team!
case, breaks, topps, erik's, sportscards, dover, platinum, tier, chrome, bowman, museum, collection, auto, relic, bryce, harper, darvish, andrew, luck, robert, griffin, trent, richardson, matt, moore, brett, lawry
PMS Madden
online, franchise, madden, football, #sports, league, group, 2011, fantasy, default, news, notes, advice, tips, schemes, plays, formations


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Ignite Your Leadership
Ignite Your Leadership Panelists Marie Tuite, Deputy Director of Athletics, San Jose State University Charles Harris, Executive Vice President, Averett University Heather Weems, Director of Athletics, St. Cloud State University Moderator: Patti Phillips, Chief Executive Officer, NACWAA
Personal Growth "To be successful, don't ask yourself what you need to do, ask who you need to become." – Darren Hardy "We do not attract that which we want; we attract that which we are." –Wayne Dyer "We cannot become what we need to be by remaining what we are." –Max De Pree
"Ah-Ha" Moments "There is a lesson in almost everything you do, and getting the lesson is how you move forward." –Oprah "She wasn't where she has been. She wasn't where she was going. But she was on her way." – Anonymous
Authentic Leadership "Authentic leadership is all about being the person you know in your heart you have always been destined to be. Authentic leadership does not come from your title or from the size of your paycheck. Instead, this form of leadership comes from your being and the person that you are." –Robin Sharma
X-Factor "Success is not something you pursue. Success is something you attract by the person you become." –Jim Rohn
Ignite Your Leadership Marie Tuite, Charles Harris, Heather Weems, Patti Phillips, For more information regarding NACWAA, please visit: On
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Question about Canon PIXMA iP1600 Printer
Posted by ellisjames08 on
Driver could be corrupt.
Disconnect the printer or at least be sure it is turned off. I'd do both and reinstall the CD software program that came with the printer. When the software program asks you to connect the printer to the USB port, do so and it should again work properly.
Hope this helps. Bud
Posted on Jan 26, 2009
SOURCE: I have freestanding Series 8 dishwasher. Lately during the filling cycle water hammer is occurring. How can this be resolved
a 6ya expert can help you resolve that issue over the phone in a minute or two.
best thing about this new service is that you are never placed on hold and get to talk to real repairmen in the US.
the service is completely free and covers almost anything you can think of (from cars to computers, handyman, and even drones).
click here to download the app (for users in the US for now) and get all the help you need.
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Trekking in the Congo Rainforest
Written by Alex Woolf
Illustrated by
Part of the Travelling Wild Series
Lovereading4kids Price £7.64
£8.99 saving £1.35 (15%)
Trekking in the Congo Rainforest by Alex WoolfFollow a traveller's journey through the African rainforest and learn about the unusual animals and plants, peoples, landscape, climate and industry. Find out how to survive on your journey when you meet poisonous insects, venomous snakes and learn how to build a shelter and makeshift campfire!
About the Author
Other Formats
Book Info
32 pages
Alex Woolf
More books by Alex Woolf
Author's Website
Wayland (Publishers) Ltd an imprint of Hachette Children's Group
Publication date
26th June 2014
At @HHSHaringey we love @lovereading4kids because our pupils can practice reviewing & get free upcoming books before anyone else!Helen Swinyard – Heartlands High
We love Lovereading4kids because they put books in front of us we wouldn't otherwise have read. They make us more adventurous readers!Emily Jacques
LoveReading4Kids is a modern and creative way of emphasising the value and importance of books in this digital age #booksforlifeAmrit Bunet – Teen
I think Lovereading4kids is an amazing company because of the friendly staff and the fabulous chance to read great books before publication.Adam Graham
We love Lovereading as my 5 year old loves to read new books before anyone else has a chance, she says it makes reading exciting!Tracey Chorley
I love lovereading4kids because I've read amazing books I would never have picked up, and its opened doors to new genre's I now love.Harriet Cunningham
I love finding new books to read. My mummy and me look at the new ones coming out. I have written reviews of some of them!Jessica Cobbin – age 7
We love Lovereading4kids because it promotes reading choices, new authors and a sense of community for children of all ages!Rachel Bridgeman


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Luxury Hotels in Darmstadt
Search for luxury hotels in Darmstadt
Get Secret Prices on select hotels
These prices aren't available to everyone.
Trending now in Darmstadt
Luxury hotels in Darmstadt
- Most bookedMaritim Konferenzhotel Darmstadt
Most recent review
"Perfect location next to central train station, and local bus and tram service."
A Traveller, Oct 2016, US
Most recent review
"Excellent for travelling without a car. Free ticket for bus and tram, which goes directly to the city center in a few minutes. Ticket valid as far as Grube Messel. Right next to train station, still not noisy as there are good windows, and not a bad area. Nice, modern design. Very good breakfast ..."
A Traveller, Sep 2016, US
Most recent review
"We stayed here because of it's convenient location to our conference. However, we were delighted by the cleanliness and comfort of the rooms. Food served at breakfast, lunch and dinner was delicious with lots of variety. The staff were very helpful and friendly. We had been travelling thr..."
A Traveller, Aug 2016, GB
Most recent review
"The hotel is clean and comfortable, and within easy access to the city centre and the Darmstadtium (where I was attending an event). A simple breakfast is offered in the price, which was a bonus, but you can pay for a bigger selection including hot food in the sister hotel next door, if you wish..."
A Traveller, Dec 2016, IE
Most recent review
"Old network hotel with good enough comfort and location. Near the train station with a direct trains to Frankfurt main train station (aprx 20 min) and Frankfurt Messe (aprx 45 min direct S line)."
A Traveller, Oct 2016, US
Luxury hotels within 5 miles of Darmstadt
Luxury hotels within 10 miles of Darmstadt
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"The hotel was located close to the airport. Rooms were big, clean and very comfortable. There is a nice restaurant across the hotel. Breakfast was amazing."
A Traveller, Dec 2016, CA
Most recent review
"Typical German hotel with nice comfortable beds and pillows. Very clean and renovated. We didn't get breakfast because we left too early, however we got some freshly baked croissants from the cleaning lady. The owner was there and he was very kind checking on us by calling our rooms and asking if..."
P, Nov 2016, US
Most recent review
"Shuttle pick-up and return to the Air Port was a great plus."
A Traveller, Sep 2016, US
Most recent review
"We had a wonderful stay at the Adler in Gross-Gerau and an amazing dinner as well! My husband and I highly recommend it! If you will be staying anywhere near Frankfurt, this hotel is a must!"
A Traveller, Nov 2016, US
Darmstadt Luxury Hotels
Most luxury hotels are located near the city center and are near popular tourist destinations and landmarks. Whether you are searching for a place to crash after a busy day of business meetings, or looking for the perfect family-friendly hotel that everyone can enjoy, the perfect luxury hotel in Darmstadt can be found on Hotels.com. Here are luxury hotels in Darmstadt travelers have booked in the last hour:
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Signing up for Hotels.com emails gives you access to Secret Prices and exclusive offers that aren't available anywhere else on the internet. Joining our Welcome Rewards Program gives you a chance to win a free night at one of our luxury hotels. Book online today and get up to 50% off your reservation. When you download the Hotels.com app, you can book your reservations in on the go, read guest reviews and save the hotel reservations you want to view and compare later.


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The admins are aware of site instability throughout the day today. We have our crack technical staff checking it out, but it is probably the Russians. If you are having any specific issues, please post them to the Customer Service Support Forums and we will get to them in the next 24 to 48 weeks. Thank You
Former NBA Ref Eddie Rush named Coordinator of PAC-12 Men's Basketball Officiating
Discussion in 'Colorado Basketball Message Board' started by buff4bcs1985, May 16, 2012.
Ignore Threads by Nobita


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Obama Makes Fun of Jesus, Calls the Bible "Radical" – BuzzPo In case you were wondering if the President claims to be a Christian solely for political reasons, the answer is yes and this vintage footage from 2006 will serve… http://buzzpo.com/obama-makes-fun-jesus-calls-bible-radical/
Instructions Re-Imminent Asteroid Judgment
ATTN: WORLD: Instructions Re-Imminent Asteroid Judgment by Prophet Efrain Rodriguez Prophet Efraín Rodríguez announced in his last presentation in Texas, on June 6th and 7th, 2014, that this trial would take place WITHIN a period of 7 months. He did not mean "in" 7 months exactly. The key phrase is "within a period". This means […]
The NAMES OF GOD
Gilbert Manzano 17 August 2015
If Christianity is valid, why is there so much evil in the world?
Warriors for Christ with Anthony Hall. 8 September 2016
The Alien Races Book – Over 82 Species On Earth!
What They Don't Want You To Know Published on 25 Jul 2016 Aliens have been living on planet Earth before the Human race was born. – according to Paul Hellyer, former Canadian Defense Minister. There are 82 alien races living on Earth, which include the aliens caught on tape, and the ones listed in the […]
Apostacy! The Queen James Bible for GAYS!
A Call For An Uprising Published on 28 Aug 2016 MUST WATCH THIS! THE QUEEN JAMES BIBLE FOR GAYS!
Giant "Human" Skeletons – Mass Illuminati Cover-Up
Giant "Human" Skeletons – Mass Illuminati Cover-Up [Full Documentary] 2015 FisherOfMen Published on 3 Dec 2014 During the days of Noah Satans fallen angels were going around having sex with women, an even mixing their DNA with fish, and animals. No one knows for sure how this works, but what we know for sure is that […]
Mandela Effect – Acts 17:5-9
Laura Marconi 9 August 2016 Acts 17:5-9 Jason was NEVER in the BIBLE BEFORE NOW it is!!!#MandelaEffect
Underwater Alien City In Tasmania
Mike Jasper Published on 31 Dec 2012 Would you look at that, and its right under their noses! This is a populated area, and it doesn't appear these people have a clue whats under their lake!!! Don't you love digital photography?!! https://www.youtube.com/watch?v=seRUeaZgbL4
Israeli Tanks And Bulldozers Cross Into Syria
Steven Ben-Nun Published on 13 July 2016 Breaking News Israeli Tanks with Bulldozers cross into Syria seemingly not hindered, but Russia TV 24 calls the action and Invasion Into Syria. What will come next? Israel knows it needs to prepare as Iran and Hezbollah prepare a war for Israel, and Lebanon is to purchase Russian […]


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She's got a great set of everything, from her tits to her legs - Check out sexy momaof3's PV profile ...
Hi friends: this contri it's for who asked to see the 'pee flowin' chiks.
See ya, Peterspy
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Thousands protest Trump in NYC
Anti-gay protesters picket gay-owned D.C. restaurant
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[caption id="attachment_42166" align="alignright" width="600" caption="Members of the Washington Capitals have contributed to the 'You Can...
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Pool Shark Blueeyedcajun posted on Blueeyedcajun's wall.
happy birthday darlin !!
Pool Shark posted a comment on onehotbikerchick13's photo
ain't that the truth !!!!
I'll be working in York this weekend. I will be doing some riding in the evening. I hope everyone has a safe holiday.
Took this at work yesterday. It was way to hot to be working in a boiler room.
Taken just the other day !
Recent Activity
Thanks for the add


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Behaviour change, by design
We're living in an age of unprecedented change. We experience with Oculus Rift, invest with Acorns, consume video through Hyper, tune into Pandora and navigate with Waze.
New Altimeter Group report finds content marketing is a top priority for marketers, but most organisations are ill-equipped and lack the strategic or tactical capabilities to be successful
Content marketing may be the hot area of investment for marketers, but most organisations are still failing to address their activities either strategically or tactically.
According to a new whitepaper from analyst firm, Altimeter Group, brands have evolved into media companies responsible for 178 social media properties on average, as well as corporate websites, blogs and other owned media properties. This media and device pool is only increasing as more smartphones, tablets and emerging platforms such as Google Glass enter the market.
In Altimeter's Organizing for Content 2013: Models to incorporate content strategy and content marketing in the enterprise supporting survey, 57 per cent of 130 respondents cited content marketing as the top external social strategy objective, followed by developing an ongoing dialogue and engagement with customers.
Yet for most companies, content responsibility and oversight is reactive and highly fragmented, Altimeter claimed, and brands are finding themselves ill-equipped and scrambling to create content that meets both company and user needs.
"Content marketing budgets have been increasing for years. Yet few organisations have actually made a place for content," report authors, Rebecca Lieb, Chris Silva and Christine Tran, stated. "Instead, most toss content duties or assignments to already-busy employees who are untrained, ill-prepared and lack a strategic mandate or incentives to source, create, product, disseminate, benchmark, measure or manage content."
Altimeter's whitepaper is based on 78 interviews with executives of business and consumer companies, representing 27 brands, between January and March 2013.
In one company example, Altimeter found corporate communications and PR were managing some social media sites such as Instagram and Google +, marketing was managing Facebook and Twitter and agency content creation, the website team was in charge of SEO, YouTube, Pinterest, blogs and external forums, customer service staff delivered how-to content for blog posts and .com plus social customer care content, and HR used Facebook and LinkedIn for recruitment.
"The overwhelming majority of organisations don't have content divisions in their organisational charts. Very few have staff with the world 'content' or 'editor' in their title, and only nine of the brands interviews for this report have made explicit content hires," the authors stated. "This lack of orchestration results in duplicative efforts that waste time and money while producing inconsistent messaging."
In order to get on top of content marketing, Altimeter said an organisation's c-suite executives must first recognise and understand content is needed and is growing in importance. It also outlined an enterprise model including a content department, content centre of excellence, editorial board or content council, content lead, executive steering committee and a cross-functional content chief.
Altimeter Group: How to prepare for real-time marketing
Tips for improving content management
Follow CMO on Twitter: @CMOAustralia or take part in the CMO Australia conversation on LinkedIn: CMO Australia.
We're living in an age of unprecedented change. We experience with Oculus Rift, invest with Acorns, consume video through Hyper, tune into Pandora and navigate with Waze.
I'm sure that many of you out there have heard a lot about chat bots (aka messaging bots) recently, and the fact that they are here to stay is pretty evident by now.
An in-depth understanding of consumers sits at the heart of what we all need to do, but we know it's not always easy to uncover insights that will unlock a true innovation opportunity.
Thanks, Nadia. It was so interesting blog for me because it helps me able to understand well on the basics of business and marketing conc...
Having been to the AO on Wednesday for the first time in a number of years I was very impressed with the new branding. The event has evol...
This was amazing and so inspiring. Thanks for sharing.
Great read, thanks for posting. MR should be seen as the holy grail for marketers and brands, as it offers an unprecedented capability to...
what a load of shit, and what a major stuff up... the new brand device is sterile, boring and just plain bad. Would be better suited to a...
In the 11th and final episode of the Closing the Gap podcast series, produced by Brandhook, Asahi Beverages' former marketing strategy director, Darryn Wallace, chats about delivering a true ROI on marketing programs.


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Relay Specialist
Sprint - Austin, TX
The Relay Specialist relays telephone conversations between hearing or speech-impaired customers using a computer or TTY and a voice customer using a regular...
Security Intervention Specialist
Thrive Intelligence - Richardson, TX
Additional requirements of the Security Intervention Specialist position include, but are not limited to:. Qualified applicants for the Security Intervention...
Specialist Client Services, Engagement
Wood Mackenzie - Houston, TX
Role Title: Client Services – Engagement Division/Function: Sales and Marketing Reports to: Director of Client Services - Americas Location: Houston Role
Inventory Management Specialist
MSC Industrial Supply Co. - Houston, TX
The level III IM Specialist is expected. Inventory management specialist able to mentor and perform duties such....
Grant Development Specialist
Methodist Healthcare Ministries - San Antonio, TX
Grant Development Specialist. These regulations prohibit discrimination against qualified individuals based on their status as protected veterans or individuals...
Clinical Documentation Integrity Specialist
UT Southwestern Medical Center - Dallas, TX
And with a (CCDS) Certified Clinical Documentation Specialist, or (CDIP) Certified Documentation Improvement Practitioner, or must attain CCDS or CDIP within 6...
FERC Reporting Specialist
Valero Energy Corporation - San Antonio, TX
All qualified applicants are encouraged to apply and will receive consideration for employment without regard to legally protected status including sexual...
Inside Sales Representative
Lifesize - Austin, TX
You will need to grow opportunities, move opportunities through the pipeline, and be an overall product specialist for Value Added Resellers and end users....
Manufacturing Supervisor
Philips Lighting - San Marcos, TX
Coordinates with other specialists (Maintenance, Engineering) to handle more critical issues. Manages a team of production workers in a production unit,...
Quality Analyst I
Davita - Coppell, TX
The Quality Specialist I will be responsible for creating, and maintaining, documentation (Job Aids and Standard Operation Procedures) for "end to end"...


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Status Activity Feed | switch to normal view
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This view shows you all status activity - both comments and new updates with the latest at the top.
try it if you like mild, i use eco raw sugar,,, but maybe their are other ways to get it mild if you dont want sugar?
(56 minutes ago)
It's pretty easy to make a green curry from scratch as well with fresh ingredients...
(45 minutes ago)
Okay, you'll need to run by a hardware store and get the following: roofing tar, duct tape, a pipe snake, and a variable speed drill.
(3 minutes ago)
Priceless advice aussieguy. Already have some of my own sexy buns x, good afternoon mrs metal xx
(16 minutes ago)
Its Mrs metal !! Big kisses and pinch on the bum and put my face in your boobs and go brrrrrr and more big kisses x
(11 minutes ago)
lol Mrs F. she probably is. She probably died in some bizarre set of circumstances that advanced trigonometry could possibly have saved her but she only knew calculus....ohh the irony lol
(36 minutes ago)
Have to say I don't recall using much of that "absolutely necessary" algebra stuff since my last exam!
(35 minutes ago)
some people just thrive on it and can't survive without drama. Pity.
(42 minutes ago)
Thought you profile established you as "boss",....hmmmm, PC destroyed the fun being one of those too
(3 hours ago)
I'm guessing you're not in the porn industry then?
(2 hours ago)
Not sure guys appreciate how many pms women get here *brushes tumbleweed from inbox*
(1 hour ago)
Coffee? At this hour? It's 5:30 am. Time for a stiff drink and bed......... oh wait - maybe that is just me?
(2 hours ago)
You know what's good for the goose? A hot oven, potatoes and carrots.
(5 hours ago)


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Holy wow. I typed in "serenity" and this is what I got.
Turn-around poses
Je suis bien, Acrylic on canvas, 48" X 24", Artist: Virginie Bocaert
Makeup or photoshoot ideas i would like to try and volunteer models for photoshoots contact me...
Cirkelträning i solen: 20 minuter som ger dig kvinnlig råstyrka | I FORM
Boudoir Lace Brief from BHLDN
Bee, white, lace, mesh, and delicate detail love.
Fashion photography
WBFF Pro & Fitness Model Brittany Coutu Talks With Simplyshredded.com


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了解语法差异,请查看本文的Python3节 使用reload 引自python docs When reload(module) is executed: Python modules' code is recompiled and the module level code reexecuted, defining a new set of objects which are bound to names in the module's dictionary.test babyliss miracurl original COPYRIGHT ©AUSTRALIAN GOVERNMENTSYDNEY HARBOUR FEDERATION TRUSTPO BOX 607, MOSMAN NSW 2088, AUSTRALIA. Posted in Uncategorized Nightgown Posted on September 20, 2012 by admin Teen Model Masturbation Video In White Lingerie Here Horny petite teen shows the petite blonde bombshell ready for some action.
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Strictly Themed Children's Parties.
From: 6th January 2017 at 11:00 AM until 31st March 2017 at 8:00 PM
Held at: Lower Kingwood Hall, Kingswood
Supplied By: Balliamo Strictly Come Dancing Themed Children's Parties
Find local dance workshops and events in the UK. To find out more information on a dance class event, dance workshop, taster dance classes and open days click on the dance instructor or studio link below. Check out dance events in the UK.
Please note that places on events and workshops may be subject to availability and individual dance instructors or studios terms and conditions.
Held at: Lower Kingwood Hall, Kingswood
Held at: Sacred Heart School, Teddington
Held at: Southport Theatrical Arts, Southport
Held at: La Divina - Marylebone, Marylebone
Held at: Woodhouse College, Finchley
Held at: Twickenham Road, LONDON
Held at: Eddie Catz Putney, London
Held at: Octagon Studios, Ely
Held at: Black Cat Freestyle, Bedford
Held at: The Bedford Pub, Wandsworth


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Travel AccessoriesHome
Travel Accessories
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Beauty: Hair Care
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$26.00 $18.00
Lightweight, Cordless Hair Styling Powered by a replaceable cartridge, this ceramic-coated curling iron heats up in just two minutes without a cord, plug or adapter. Comes with one butane cartridge that lasts for 2–3 months of daily use (both the TSA and the FAA allow one butane cartridge...
$29.00 $20.00
Foldable Conair® Dryer Lets You Style with Style An impressive 1875 watts of drying power is packed into this affordable folding hair dryer. Adjusts from 110V to 240V; no converter required. Two heat/speed settings and one cool-shot button (for use in U.S. only). At 220V, it operates on high...
Category:178637-Hair Care


text:
Two Farms
Written by Bett Taylor
Illustrated by
Lovereading4kids Price £29.20In Stock
Delivery time approx. 1 week
Two Farms by Bett Taylor
About the Author
Other Formats
Book Info
368 pages
Bett Taylor
More books by Bett Taylor
Xlibris Corporation
Publication date
1st September 2012
I think Lovereading4kids is an amazing company because of the friendly staff and the fabulous chance to read great books before publication.Adam Graham
We love Lovereading4kids because they put books in front of us we wouldn't otherwise have read. They make us more adventurous readers!Emily Jacques
It's a community united by a passion for books and promoting the best there is in children's literature.Sam Bateman and family
Writing reviews help the children with their literacy skills and we always read the books together which gives us good quality family time!Cat Bisland (on behalf of the Bi
I love Lovereading as it provides an honest opinion and showcases a range of fiction. Suited to both parents & kids alike, it's a must-use.Georgie Rowe – age 16
A great way to introduce kids to great books, authors & genres. Parents can find age-appropriate books to share with their children.Judi Davies – Aberdare Girls Sch
It gives me a chance to read types of books that I would not normally try, and it motivates me to read every night to finish it!Alice Horncastle, age 14
I am so pleased to have signed my kids up as they are reading a much wider range of books and even choosing books out of their comfort zone.Angela East


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2007: 25% elementary students went to high school. Biggest challenges: access, (11 secondary schools in 25,336sq km) quality, the cost of school fees, uniforms and supplies. 2011: only 6, 500 secondary schools spread across the country. The closest high school to Aremiet is16km. 2013: areas of Kenya have a high literacy rate, 87% ; pastoralist communities' can be as low as 8.1%. Many Kenyan youth have only a basic level of education, few usable skills, and minimal employment opportunities.
"Education is the most powerful weapon you can use to change the world."-Nelson Mandela. GCA increases access and serves the pastoralist community. GCA integrates critical thinking, problem solving and life skills in each individualized curriculum plan, increasing the skills sets and employability of graduates. GCA operates year round with special options available during traditional holidays strengthening the opportunity for success. GCA offers alternative payment options.
It is expected that in five years GCA will impact over 1,000 students. Construction will provide a boarding capacity of 200 students, adequate classrooms, vocational training classrooms, a multipurpose room and teacher housing. Active and personalized integration of life skills, art, culture, and music, lifelong learning, portable curricula, flexible boarding and response to community need ensures that GCA will meet the needs of the community of Aremiet and its surroundings for years to come.
This project has provided additional documentation in a XLSX file (projdoc.xlsx).


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Service Times
Sundays @ 9:30 am and 11:00 am
Life Point Church
10822 FM 1560 @ Braun Road
San Antonio, TX 78254
Building faces Braun Road
I've been attending Life Point for a little over a year now. Prior to then, my relationship with God was non-existent. I lived my days with stress, fear, and anxiety. I was short-tempered with my family, frustrated with my career, and guilt-ridden about my divorce. Something was missing and I tried filling it with food, … Continue reading
The Spring Semester of Life Groups is just around the corner and there is a group for you! Check out this semester's selection after 2nd service this Sunday. If you are interested in leading a group this semester, please email Andy Garcia at email@example.com or visit Next Steps Central. To...More Information >
This year Life Point will be going to Haiti from June 20th-26th. If you are interested or would like more information, please make plans to attend an interest meeting on January 15th or 22nd immediately after 2nd service in the library.More Information >
This Sunday, Jan 22nd, LP Students will be going to Thin Air. The cost is $15/student and we will begin festivities at 5:00 pm at the Thin Air facility at 4902 Fredericksburg Rd., San Antonio, TX 78229. If you have any questions or would like to sign your students up...More Information >


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Get Luxury Home at RG Luxury Homes
Category : Property for sale Posted : 17/10/2014 Price : 3500000.00 INR
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