text:
Beautiful Private Beachfront Palapa Eco Preserve(13 Reviews)
The owner has been emailed.
To book this property, you need to complete your booking through checkout on the VRBO website. We can't protect your payment if we don't know you've booked through us. Learn more
- Minimum stay:2 nights
- Sleeps:4
- Bedrooms:1
- Bathrooms:1
- Property type:Bungalow
- Internet:Yes
- Pets considered:No
- Wheel chair accessible:No
About the Property
Bungalow, 1 Bedroom, 1 Bath (Sleeps 4)
We are located on a 25 acre preserve with 24 other palapas sprinkled around the property. Ours is very private and serene, with one of the best panoramic views of sea and mountains. The palapa is located on Los Chonchos beach, which is one hour south of Puerto Vallarta. It is accessible only by water taxi, which leaves twice daily from Boca de Tomatlan. We have all the comforts of home with a kitchen including refrigerator, freezer, gas-burner cook top, spring fed water. The kitchen is well-stocked with dishes, glasses and utensils. Dining area with hand-hewn table/chairs w seating for four or more. Full bathroom with hot shower, sink, flush toilet. Bedroom has new king sized bed. Amazing views from the deck with hammock and chaise lounge chairs to sunbathe and watch for whales (in season), dolphins and parrots during the day and watch the sunset and incredible starry sky at night. Relax in paradise and go off the grid! The palapa is run by solar power for electricity and propane for the refrigerator/freezer and cook top. Charging station for laptops and cell phones. This is an ideal spot to unplug for a romantic getaway or vacation for the adventure minded. Perfect for relaxing under the sun, snorkeling, swimming, fishing and kayaking. You will have easy access to three beautiful beaches, one nearly a mile long which you will sometimes have all to yourself. There is a hiking trail to the small fishing village of Chimo, two miles from Chonchos. Chimo has an oceanfront restaurant and two small markets. Tired of cooking? There is a restaurant on-site at Chonchos that will serve you three meals a day. Just let Chef Alphonso know what your preferences are! Or order your meal to be delivered to your palapa. Fresh local fish; guacamole made from avocados just picked from the tree! Palapa area has year-round staff (English-speaking) who will help you get settled in upon your arrival and make sure your stay is safe and comfortable.
When you're ready to book, here are some tips to keep in mind.
Paying with a credit card on VRBO protects your payment for up to $10,000 against listing fraud. We recommend completing your booking on VRBO.Learn more
Member since: 2015
Property Type
- Bungalow
- 700 sq. ft.
House Rules
- Max. occupancy 4
- Events Allowed
- Children Welcome
- Non Smoking Only
- Pets Not Allowed
Accommodation Type
- Vacation Rental
- Guests Provide Their Own Meals
- Long-Term Renters Welcome
- Wheelchair Inaccessible
- Adventure
- Away From It All
- Romantic
Leisure Activities
- Beachcombing
- Bird Watching
- Eco Tourism
- Shelling
- Walking
- Whale Watching
- Wildlife Viewing
Sports & Adventure Activities
- Fishing
- Kayaking
- Scuba Diving Or Snorkeling
- Snorkeling
- Snorkeling/Diving
- Surf Fishing
- Dining
- Dining Area
With a cell phone data signal only. This can be a little unreliable, though we can usually get a signal from the deck...moreless
- Linens Provided
- Towels Provided
- Dishes & Utensils
- Kitchen
- Refrigerator
- Stove
- Deck / Patio
- Kayak / Canoe
RatesCurrency Conversion
|Weekend Night
|Monthly *
My Standard Rate
2 night min stay
Additional information about rental rates
- Cleaning fee $50
- Taxes Not included
NO additional, hidden fees! Our rate includes cleaning, provision of bath and beach towels, linens, snorkeling equipment and use of community kayaks.
Owner's cancellation policy:
50% refund for cancellations more than 14 days before check-in date.
100% refund for cancellations more than 30 days before check-in date.
Don't forget your vacation protection! Get protected now
Adding our Vacation Protection services can make sure your getaway goes smoothly, no matter what. We offer Cancellation Protection and Damage Protection so you can truly relax.
Owner info
Year Purchased: 2015
About the owner: We are both college professors who love to travel. We are happy to share our little bit of paradise with you.
Why the Owner Chose Chimo, Jal., Mexico:
We visited Chonchos in January of 2015 and fell in love with the place. It's beautiful, quiet, and serene, and we really loved being 'off the grid.' We sat on our deck and watched whales and manta rays in the ocean, iguanas on the rocks below, and parrots overhead. The stars at night were like nothing we had ever seen. We loved our vacation so much that we bought our own palapa, and we get back as often as we can.
Contact us
Send email
- Primary: +1 6094290787
Links to more information:
- Click Here to see All My Rental Listings
View from the dining room - great for watching the sunset after dinner
Shower on the deck for rinsing the sand from your feet.
View from the deck looking toward Puerto Vallarta
Loft above the kitchen for extra sleeping space
Looking into the jungle from the back of the palapa
Hammock on the deck for relaxing
Bedroom window with local driftwood
The big beach, about 2 minutes from your door. Yours may be the only footprints
The namesake of our palapa. Organ pipe cactus, many decades old!
Our location - Latitude 20°28'59.68'N Longitude 105°34'26.53'W (approximately)
Bedroom with king-sized bed
Comfortable bench on our wide deck overlooking the ocean
Fully equipped kitchen
Enjoy this view with your morning coffee
Kitchen view - counter is polished concrete, posts from local wood
View from the deck. Perfect for whale watching or stargazing
Sunset at Chonchos
Pathway through the jungle between palapas
This listing was first published here in 2015.
Date last modified - Sunday, April 30, 2017
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Let us know when your receive great advice so we can thank our lawyers and point others with similar questions in the right direction.Got it!
Over 5 years now I had 3 knee surgeries, The insurance company not only neglected to maintain support and it's obligations, but at the 5 year time filed fraud with the district attorney's office which I am fighting now as we speak. The second surgery for the knee was totally butchered by a surgeon Dr. Kharazi and he was appointed by the insurance company, my knee went crooked and for 2 years I was left limping with pain and a crooked knee, I had to ask my Medi-Cal for the proper knee replacement surgery because the insurance company neglected to pay. I want to hold the insurance company responsible for their, inability to deal with the patient, defamation of character, lies & harassment in this case, Dr.'s who are appalled when they heard that the insurance company decided to file charges.
What is your question?? Do you currently have an attorney ?? I see a possible medical malpractice case based on your story. We usually refer medical malpractice matters to an associate firm of ours who handle strictly medical malpractice matters. I would recommend getting a free consultation from a personal injury attorney and a medical malpractice attorney who can guide you in the right direction and answer all your questions.Ask a similar question
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subset: commoncrawl


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The money market is a subsection of the fixed income market. We generally think of the term fixed income as being synonymous to bonds. In reality, a bond is just one type of fixed income security. The difference between the money market and the bond market is that the money market specializes in very short-term debt securities (debt that matures in less than one year). Money market investments are also called cash investments because of their short maturities.
Money market securities are essentially IOUs issued by governments, financial institutions and large corporations. These instruments are very liquid and considered extraordinarily safe. Because they are extremely conservative, money market securities offer significantly lower returns than most other securities.
One of the main differences between the money market and the stock market is that most money market securities trade in very high denominations. This limits access for the individual investor. Furthermore, the money market is a dealer market, which means that firms buy and sell securities in their own accounts, at their own risk. Compare this to the stock market where a broker receives commission to acts as an agent, while the investor takes the risk of holding the stock. Another characteristic of a dealer market is the lack of a central trading floor or exchange. Deals are transacted over the phone or through electronic systems.
The easiest way for us to gain access to the money market is with a money market mutual funds, or sometimes through a money market bank account. These accounts and funds pool together the assets of thousands of investors in order to buy the money market securities on their behalf. However, some money market instruments, like Treasury bills, may be purchased directly. Failing that, they can be acquired through other large financial institutions with direct access to these markets.
There are several different instruments in the money market, offering different returns and different risks. In the following sections, we'll take a look at the major money market instruments.
Money Market: Treasury Bills (T-Bills)
Money Market vs. Short-Term Bonds: A Compare and Contrast Case StudyDiscover characteristics of money market and short-term bonds, including how the investments are alike and different, and the benefits and risks each offers.
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5 Mistakes You're Making With Money Market AccountsMoney market accounts can be helpful "parking spots" for investors. Here are five key things to keep in mind when opening an account.
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Money Market Mutual Funds: A Better Savings AccountAn good alternative to the traditional savings account is the money market mutual fund. It's easy, safe and has better returns.
The Pros And Cons Of Money Market FundsThe pros to investing in the money market include the chance to park money in a safe haven during volatile times.


text:
RF Cafe Software
About RF Cafe
1996 - 2022
Kirt Blattenberger,
RF Cafe began life in 1996 as "RF Tools" in an AOL screen name web space totaling 2 MB. Its primary purpose was to provide me with ready access to commonly needed formulas and reference material while performing my work as an RF system and circuit design engineer. The Internet was still largely an unknown entity at the time and not much was available in the form of WYSIWYG ...
All trademarks, copyrights, patents, and other rights of ownership to images and text used on the RF Cafe website are hereby acknowledged.
My Hobby Website:
Try Using SEARCH
to Find What You Need.
There are 1,000s of Pages Indexed on RF Cafe !
For the sake of avid cruciverbalists amongst us, each week I create a new crossword puzzle that has a theme related to engineering, mathematics, chemistry, physics, and other technical words. You will never be asked the name of a movie star unless he/she was involved in a technical endeavor (e.g., Hedy Lamarr). Enjoy!
Reproduction of this puzzle without the express permission of RF Cafe
is prohibited.
acr. = acronym, abbr. = abbreviation, pl. = plural, wds. = words
2. The "IP" in IP2 and IP3 (2 wds.)
13. Related to FM by a differential
14. One component of a complex number (abbr.)
15. Chemical symbol for radium
16. Army-Navy specification prefix
17. Chemical symbol for rubidium
18. Chemical symbol for aluminum
20. Test point (abbr.)
22. They have units of degrees or radians
25. Chemical symbol for neon
26. Part of a FOR loop
27. Constellation : The lion
28. Read-only (abbr.)
30. Morse Code for "from"
31. Minutes of Use (abbr.)
32. Opposite of I.D.
33. Electrical overstress (abbr.)
34. Mr. Blattenberger of RF Cafe
35. System for guiding aircraft (abbr.)
37. Chemical symbol for niobium
38. Electronic warfare defense (abbr.)
39. Chemical symbol for molybdenum
40. Type of flip-flop
42. 3 GHz to 30 GHz
43. Abbreviation for peak voltage
45. Unit of power
46. BS__ - the degree held by many RF Cafe visitors
47. Regarding light
48. 1/000 of an amp (abbr.)
49. Chemical symbol for polonium
50. Longitudinal shape-forming structural elements
51. Chemical symbol for lithium
52. Classification
53. Unit of inductance (abbr.)
54. Stock symbol for National Semiconductor
56. Chemical symbol for selenium
57. Front edge of a wing (abbr.)
58. World's largest yearly convention of gadget and device manufacturers (abbr.)
59. Chemical symbol for mendelevium
61. 30 GHz to 300 GHz
63. Solid state power amplifier (abbr.)
64. Software drafting tool (abbr.)
65. Write-Once (abbr.)
66. Electronics Industry Association (abbr.)
67. Unix, Linux or Windows (abbr.)
68. __ + 58 Down, the name of this website
69. On-the-air meeting of hams at a set time, day and radio frequency
70. Test equipment (abbr.)
71. Chemical symbol for arsenic
72. Circular mounting hardware
76. Equalizer (abbr.)
78. Chemical symbol for bismuth
79. Unit of time (abbr.)
80. Chemical symbol for beryllium
81. 300 kHz to 3 MHz
82. Small unit of capacitance (abbr.)
84. Chemical symbol for nobelium
86. Uncertainty in timing (2 wds.)
1. Instrument for measuring potential difference using a taut band indicator (2 wds.)
2. Internet protocol (abbr.)
3. Nordic Mobile Telephone
4. Chemical symbol for erbium
5. Government program to bring electricity to farms (abbr.)
6. Unit of energy
7. Programmable logic device (abbr.)
8. Last stage in transmitter (abbr., pl.)
9. Switch position
10. The design component of total product cost (abbr.)
11. Chemical symbol for terbium
12. Systematic approach to locating the cause of a fault in an electronic circuit or system
19. Semiconductor lamp
21. Type of data storage IC (abbr.)
23. Engineer who experimented with extremely high voltages (2 wds.)
24. Make assumptions about the future behaviour of a system, based on current trends
25. On-the-air meeting of hams at a set time, day and radio frequency (pl.)
26. Unit of weight
29. Unix, Linux or Windows (abbr.)
30. 10E1 numerical prefix
33. Occlusion of one heavenly body by another
36. Divided into chunks
39. Moon of Saturn discovered in 1789
41. Retain a charge
44. Computer monitor resolution measure (abbr.)
46. Effective Radiated Power (abbr.)
55. Unit of admittance (pl.)
58. 68 Across + ____, the name of this website
60. Singulated piece of IC wafer
62. Start frequency (abbr.)
64. Chemical symbol for chromium
65. One of the Ws in WWW
71. MS's server-side script engine for dynamically-generated web pages (abbr.)
72. Term used in soldering to achieve the condition that occurs when the metals being soldered are hot enough to melt the solder so it flows over the surface
73. Specialized mobile radio (abbr.)
74. Gary Breed's fine magazine on RF & microwaves topics (abbr.)
75. Radio frequency interference (abbr.)
77. Ham's code for "Entire net stand by."
79. Last stage in a transmitter (abbr.)
80. Filter type that blocks frequencies in a specified band (abbr.)
83. Unit of length (abbr.)
85. Type of logic gate
Answer below
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December 25
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Hollywood history abounds in these L.A. mansions
Listing date: 06/26/2016


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Need russian / english translator
This project received 18 bids from talented freelancers with an average bid price of $341 USD.Get free quotes for a project like this
Project BudgetN/A
Total Bids18
Project Description
I need someone to provide translation services within the following dates April 8th, 2010 to April 17th, 2010. The approximate number of translation hours is estimated to be around 50 hours. A tentative schedule will be as follows:
April 8th (6PM-10PM)
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theater group dzieci is a company that embodies the Sacred+Profane. Their work explores the ancient texts, sometimes religious, sometimes secular, to find the spirit within. They re-imagine the human journey as one of graceful exploration and intent. We were thrilled and lucky to have them take part in our service on THE FOOL this past Sunday – they came in their fool outfits, complete with prosthetic teeth, and ran around throughout the service, filling in as ushers, helpers, distractors, rebels and makers of chaos. And, within that, real beauty emerged, as it does with all of their work. This is a sacred song they sang at the very end of the service.
Posts In Theatre Group Dzieci
Theatre Group Dzieci | Featured Performers1
For the theme of THE FOOL, I'm thrilled to announce that Theatre Group Dzieci will be playing with us. They're a really fabulous troupe of actors/artists and clowns. Here's a bit about them:
Theatre Group Dzieci, founded in 1997 by Matt Mitler, is an international experimental theatre ensemble dedicated to a search for the "sacred" through the medium of theatre. Utilizing techniques garnered from such theatre masters as Jerzy Grotowski, Eugenio Barba, and Peter Brook, ritual forms derived from Native American and Eastern spiritual disciplines, and an ethic based securely in Humanistic Psychology, Dzieci aims to create a theatre that is as equally engaged with personal transformation as it is with public presentation.


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First National Fleet and Lease Sales Reviews
- 12800 Aurora Ave N
- Seattle, WA 98133 (map)
- (888) 891-5924
- Visit dealer's website
- See dealer special offers
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Sales Reviews
Recommend this dealer? Yes Purchased a vehicle from this dealer? No
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text:
Rule to expand auditor's report delayed again
The PCAOB has again delayed finalizing a rule to expand the auditor's report and make it more useful for investors, according to the updated standard-setting agenda published on April 3, 2017.
The long-running project has been a priority for PCAOB Chairman James Doty, who pushed for completion by the end of 2016. At the end of December, the board said it wanted to wrap it up in the first quarter of 2017. With the most recent agenda, the anticipated publication has been pushed back to the second quarter.
The latest delay is not a surprise because the board normally does not make major decisions until the chairman of the SEC has reviewed the board's work. The SEC has to approve all important PCAOB decisions, including its standards and annual budget. The Senate Banking Committee approved President Donald Trump's nominee, Jay Clayton, to head up the SEC on April 4. But the full Senate has yet to vote on the nomination. Clayton is a partner with the law firm Sullivan & Cromwell LLP.
It has taken the board a few tries before moving close to finishing the standard because the auditor's reporting model has been a controversial project among companies, and to a lesser extent, among audit firms.
The rule, if finalized, will represent a major change in the content of the auditor's report and require auditors to describe the critical audit matters (CAMs), or issues they found the most challenging, subjective, or complex while examining a client's financial statements. The standard is expected to be based on a revised proposal issued in May 2016 as Release No. 2016-003, Proposed Auditing Standard—the Auditor's Report on an Audit of Financial Statements When the Auditor Expresses an Unqualified Opinion and Related Amendments to PCAOB Standards.
The current auditor's report is a pass-fail model and investor advocates want more insight from auditors who know critical details about the company's financial conditions that are not divulged to the public. Critics of the bare-boned auditor's report pointed out in the aftermath of the 2008 financial crisis, some large companies failed or had to be rescued by the government soon after receiving clean audit opinions. But companies and auditors have been concerned that new requirements may cause auditors to overstep their role and reveal information that management has not disclosed. The PCAOB addressed the concerns and big accounting firms were largely satisfied with the planned changes. But public companies said they remain worried.
In the meantime, it is unclear whether the PCAOB will finalize a small but controversial provision in Release No. 2016-003 that requires auditors to disclose in the audit report the number of years they have worked for a client.
Companies and auditors say that putting tenure in the auditor's report could give the false impression that there is a link between tenure and audit quality when there is no evidence to support that argument.
Some investors want the information because they believe a long tenure leads to too close of a relationship between auditors and their clients and chips away at an auditor's skepticism and independence.
For more information on this topic, or to learn how Baker Tilly accounting and assurance specialists can help, contact our team.
We have partnered with Thomson Reuters to issue our monthly SEC Accounting Update. Please feel free to contact Baker Tilly at firstname.lastname@example.com if you have any questions related to these articles or Baker Tilly's Accounting and Assurance Services. © 2017 Thomson Reuters/Tax & Accounting. All Rights Reserved.


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text:
Forum - View topicThe X Button - Robot Monsters
Goto page Previous 1, 2, 3, 4, 5, 6, 7 Next
Note: this is the discussion thread for this article
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Posts: 1147
A veteran voice actor, probably best known in the gaming community for playing Liquid Snake in the Metal Gear series and Kratos in Tales of Symphonia. But yeah, I'm pretty sure Troy is doing the unknown guy's voice.
Anyway, on to other stuff:
Katawa Shoujo: Todd, you are saying the kind of crap ignorant people say. You're two steps away from being that idiot woman who criticized Mass Effect despite never playing it. No, it's not fetishizing anything and the writing is very good. What's kind of amusing is the illustration that inspired the game was by Raita Honjou, the character designers for Valkyria Chronicles.
RE6: Looking forward to this as I like the idea of three separate routes. What's funny is I made an idea for an RE JUST like this.
FFXIII-2: Too bad they didn't fix the BIGGEST problem with XIII: the god awful writing and story telling. Seriously, it was PAINFUL to hear great VA's like Laura Bailey, Troy Baker, and Ali Hillis spout that terrible dialogue and havbe to trudge through the worst narrative in the series since FFVIII. Toriyama poisons and destroys anything he touches as evidenced with Front Mission: Evolved killing the franchise and 3rd Birthday having some of the most sexist overtones I've ever seen in a game.
SCV: Long time fan of the series. I can't wait to see how newcomers like ZWEI and Viola play as well as learning what's been up with everyone else (like who fathered Hilde's kids)
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Posts: 4036
I blame the rise in popularity of mindless shooters. The more casual frat-boy gamers who just play Call of Duty/Battlefield/Halo. "Too much story, not enough killing things" and all that. This generation ushered in a lot of new faces to gaming, not only from those shooters, but also the Wii's casual crowd grabbing thing. So while a generation ago people loved JRPGs just fine, the same people still love them, there's just more people in the room now so it might be perceived as different. FFXIII still sold well (better than some other FFs even), so yeah, it's just a vocal minority complaining about them, don't worry about it.
Agreed. The only time I can see the narrative being slightly confusing is the flashbacks to the days before the present events are occurring, but that's reaching. Especially for an anime fan who's used to creative and unconventional narratives (Haruhi was a lot more unconventional) And comparing Hope to Jar Jar is laughable hyperbole.
Last edited by TitanXL on Wed Jan 25, 2012 3:08 pm; edited 1 time in total
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Posts: 3435
Kawato Shoujo: I wondered why this game was number one on GameFAQs. I admit I know next to nothing about it, but after reading the premise you put here I have a fair idea. People with disabilities are often a rare subject in games (and when they do show up in them, it's usually as an NPC you spend little time with). I likely won't play it, but I'm sure people are enjoying it.
Tokitowa: The presentation looks excellent for this. Toki's dragon is also awesome. :3
Heroes Fantasia: This looks like a great game, but it's Namco x Capcom all over again: we're not getting it. Too many licenses, too many characters to voice (though we dubbed them all, I imagine they couldn't get all the actors under one roof for this game) and the tagline is for RPG enthusiasts. I admit I haven't seen Louie, Orphen, My-HiME, Darker than Black or Sgt. Frog.
FFXIII-2: I really would like to get this but I'm on the fence...only due to the fact I'm in the middle of a mess of RPGs to finish currently. Key points for XIII-2 are the monster system (come on, you know you want a badass Behemoth on your side like I do) and the vaster freedom with the Crystarium. I know there's already been some intense hate for the story; I've heard comments like "a plot that seriously insults your intellect for time traveling stories" and "Why is Lightning even on the cover?". After playing through the demo twice, I just want to give it a full shot for myself.
I really don't see where you're even beginning to draw comparisons between Hope and Jar Jar, odd one. Hope develops and struggles to mature while Jar Jar is largely static in every appearance he's made.
When I brought up shooters being mindless this one time, I got chewed out by this snarky person who said I was no different from the Westboro Church for hating on FPSs.
Last edited by belvadeer on Fri Mar 16, 2012 1:39 pm; edited 2 times in total
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Posts: 5586
Location: USA
Seems Gust returns with more moe goodness. Interesting premise. Eventually want to hear more. Had a chance to see Tokitowa's trailer. Wow, this is an interesting mix though I can't think of any game it resembles. It's like combines all the things you enjoyed during the CD days, plus some arcade. Suddenly I'm reminded of Dragon's Lair to some degree. I need to see more since the trailer only gives you some elements. Heroes Fantasia, Branpresto the master of we can make a game out of any show that's out there. I doubt this will see a port, but that if you can still get a disc and and old PSP it's solid. Didn't expect to see My-HiME in a Branpresto game.
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Posts: 4421
I wonder what will be the next big thing once first-person shooters have plateaued. Its popularity can't last forever, can it?
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Posts: 2081
Location: Here!
1- Yeahno. I happen to like a story in games, provided it's not an overly blase narrative like FF13. You know, the cardboard cutouts, the whiny emo kid, the general feeling nothing's accomplished. All of that, told in a way to seem artsier than it is when it's a very dumb story.
2- Maybe Hope is more similar to Superboy Prime than Jar Jar. "Wah wah wah! Life isn't fair! I'm going to kill you Snow with my whining!" Get a LiveJournal you twit. Also, Vanille likes Fang, not you you whiny emo.
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Posts: 4036
I think because he assumed by 'mindless shooters' it was an insult to every FPS out there. Not really the case as there is such a thing as tactical shooters, it's just they're an endangered species in this day and age. Something like SWAT 4 where you moved slowly, had to actually be conscious of your surroundings and the like. That's not a mindless shooter. Mindless shooters are designed to be, well, mindless. You spawn, run in, shoot everything, die, respawn, and do it again. It's all about the death-match gameplay in multi-player. Quick respawn times to get back into the action and 'pwnz some n00bs'.
Hope got over his tiff with Snow fairly early on. By the time he reached his home that issue was pretty much resolved. Also he learned and grew from that experience and developed into a more stern character just like his mother, willing to put his life on the line to protect people and follow in her footsteps.
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Posts: 227
Location: Iowa City, IA
As I have noticed is the many complaints of FFXIII are in the way the game is played. Linear, yes it may be. First Final Fantasy to be linear, no it is not. I played the demo for FFXIII-2 and I loved most of it. The only things that irked me the wrong way were the action combination timing and the shopkeeper... I'm still getting it and I'm debating on getting the special edition or not...
Also, was I the only one that noticed that Heroes Phantasia was listed as Heroes Fantasia?
Tokitowa looks good.
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Posts: 3435
Probably, I guess I should have been more clear about which shooters I was talking about. Plus it was actually a girl who threw the remark at me.
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Lynx Amali
Posts: 1039
Location: Ontario, Canada
It's really got nothing to with the Cybuster anime (which DOES not exist at all and has no relation to Masoukishin at all other than a few names and the main mech's loose design.) I mean, The Granzon's a TANK in that! No Akashic Buster, Cosmo Nova, High Familiar, etc...
Also; ATLUS is in the way of another company localizing any SRW games. They've pretty much killed the franchise in the West because of, wait for it, lack of promotion. Also; The OGS/OGG controversy on the forum too. Could've got Masoukishin DS and Endless Frontier EXCEED but alas, it was not to be.
Heroes Phatasia is fun from what I've played so far. It's actually mildly hard (Well done, Banpresto...) which is more or less all about positioning. And hey! I resent the comment about the specials! I like them! Kazuma comes to mind, well, Kazuma and the Mai-Hime characters.
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Posts: 1008
So, how much Japanese do you need to know to be able to play a game like Heroes Phantasia? I've just bought a PSP, and am considering starting to import.
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Posts: 723
I just got a PS3 and am like 15 hours into Final Fantasy 13. I am freaking loving it; not every game needs to be a sandbox or be about exploring. I pre-ordered the collector edition of Final Fantasy 13-2.
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Eternal September
Posts: 24
That might be a reason why it quickly spread in some gaming circles, where it was seen as a new thing, but among visual novel fans, it's not particularly exceptional. Eg.: ef has a half-blind girl with anterograde amnesia, several stories like Clannad or Kira Kira, play the "ill girl" trope almost like a disability, etc. VNDB.org lists dozens of Visual novels witht he "disabled heroine" tag as well.
It was just hyped as the first large-scale, high quality original english language VN. It's kinda like naional pride, but for weeaboos.
As in "YES! We proved it! Our boys can also make a Visual Novel around the level of Clannad, Little Sister Kana, Fate/Stay Night, and Ever 17!
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Posts: 1491
I myself can't help but be reminded of the scene in Welcome to the NHK where the main character and a friend try to make "The Perfect and most Lovable Visual Novel Heroine!" and ended up with some rediculous creation that was something like a blind/deaf/catatonic alien-maid girl.
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Lynx Amali
Posts: 1039
Location: Ontario, Canada
If you want the story, yeah, you need a fair bit. However; for the actual where you need to go, there's a map button (Square) that has different icons (H-Healing, S-Saving, a red exclamation mark for current objective) The only thing you might have trouble with is increasing stats and the quest menu (which are filled as you progress). An easy way to remember it is strength, defense, charisma (used to convince and stuff like that) and AP Amount. I know for a fact that the fifth option increases base attacks of default attacks and Super moves though but I haven't bothered with anything else.
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Popular shows like To Love Ru get OVA episodes that sometimes take forever to get licensed for release in the US or just never show up at all - what's the deal? ― mattrinstl asks: Why is it so hard for companies to license OVA's? There are any number of series with plot moving events that happen between series in OVA form, and most of the time we have to end up looking at Quasi legal sites to watch ...
The Biggest Animated Moments of Winter 2017
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just for fun
What do you do with a stained waifu? Vice is about to find out the hard way. ―
The Spring 2017 Anime Preview Guide: Simuldub Edition
The Spring 2017 Anime Preview Guide Simuldub Edition has begun!
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Answerman - How Are TV Networks Associated With Anime?
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Shelf Life - Is It Wrong To Try To Pick Up Girls In A Dungeon?
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Scrapped Princess BD+DVD
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text: Seller: ancient_art4wuz (10,151) 100%, Location: London, Ships to: Worldwide, Item: 331310874057 ROMAN EMPIRE Roman glass ring Roman glass ring with applied glass inlay of the head of Medusa. A rare piece. This item is accompanied with an illustrated Certificate of Authenticity. OBJECT INFORMATION £ 195.00 | SIMILAR PRICED ITEMS 1.5cm(D) / 1"(D) | About Us | Contact | Antiquities.co.uk Condition: Very good., Type: Rings, Culture: Roman, Colour: Multi-Coloured


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(if this is a private computer)
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When you purchase a digital subscription to Cake Central Magazine, you will get an instant and automatic download of the most recent issue.
Thought I'd have fun w/my camera.lol
CC are half strawberry & half chocolate w/whipped filling and mmf toppers
Easter Basket Cake Pop Arrangement
Easter Chick
Easter Bunny, Chick And Lamb Cupcakes


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Hugh Jackman has indicated that the upcoming, third Wolverine solo movie will be his last portrayal of the clawed Canadian mutant, and that news has resulted in no shortage of speculation regarding who — if anyone — has the claws to pick up where the franchise star left off. Thankfully, there are some people out there who have the sort of high-level access to provide fans with a much-needed update on the search for a new Wolverine.
On a recent episode of his late-night show, Conan O'Brien screened a brief segment featuring some of the Wolverine auditions that have taken place behind the scenes as 20th Century Fox prepares for Jackman's departure. Among the familiar faces attempting to win the role were Parks and Recreation actor Nick Offerman, fellow talk-show host Larry King, Agents of S.H.I.E.L.D. actor Patton Oswalt (who manages to capture Jackman's affinity for showtunes, if nothing else), and with possibly the best audition of them all (no surprise there), 93-year-old Golden Girls actress Betty White.
Okay, so they weren't real auditions, but honestly, who wouldn't want to see Nick Offerman's Ron Swanson-ized version of Wolverine?
Also appearing in the segment are Silicon Valley actor Thomas Middleditch, Saturday Night Live actor/writer Hannibal Buress (who thinks he'd make a better Gambit), Masters of Sex actor Michael Sheen (who may be confusing the character a bit), and The Last Man on Earth actress Kristen Schaal (who makes a pretty good case for a role in the Ghostbusters reboot).
O'Brien's late-night talk show Conan airs weeknights at 10pm ET on TBS.
As for Jackman, he'll appear as Wolverine in the upcoming X-Men: Apocalypse, hitting theaters May 27, 2016. After that, he'll star in the still-untitled Wolverine solo movie that will be his swan song as the character. That film is scheduled to premiere March 3, 2017.


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Italian translation of 'hearing'
Word Frequency
- (sense of hearing)
uditoshe has excellent hearing
ha un udito eccellenteto be within/out of hearing (distance)
essere/non essere a portata di vocein my hearing
in mia presenza
- (law)
udienzato give sb a hearing
dare udienza a qn(of witnesses)
audizione f,
escussione fthe hearing was adjourned
l'udienza è stata aggiornata
Example Sentences Including 'hearing'
They both decided, in Lirael's hearing , that they would need to call Filris down from her dreaming room.LIRAEL: DAUGHTER OF THE CLAYR (2001)
When we stop hearing about you, we assume the hunter has become the hunted.CHAMELEON (2002)
She couldn't bear the idea of Banks hearing she had been such a fool.AFTERMATH (2001)
Trends of 'hearing'
View usage over:
Word forms: past tense past participle heard (hɜːd)
transitive verb
I can't hear you
- (gen)
- (be informed of, piece of news)
- (news on radio, TV)
- (lecture)
assistere a
- (law, case)
non ti sentocan you hear me?
mi senti?I could hardly make myself heard
facevo fatica a farmi sentireI didn't hear anything
non ho sentito nienteI hear you've lost your watch
ho saputo che hai perso l'orologioto hear him speak you'd think ...
a sentirlo parlare si direbbe che...have you heard the one about the Irishman who ...
la sai quella dell'irlandese che...
- (gen)
intransitive verb
she can't hear very well
- (gen)
- (get news)
aver notizie
non sente molto beneto hear about
sentire parlare di(have news of)
avere notizie diI heard about her from her mother
ho avuto sue notizie tramite sua madredid you hear about the move?
hai saputo del trasloco?to hear from sb
ricevere notizie da qnshe was never heard of again
non se ne seppe più nullaI've never heard of that book
non ho mai sentito parlare di quel libroI've never heard of such a thing
non ho mai sentito una cosa simileI won't hear of it (allow)
non ne voglio proprio sapereI won't hear of you paying for this
non è proprio il caso che tu paghihear! hear! (bravo)
- (gen)
Example Sentences Including 'hear'
I could hear him climbing the stairs, two or three at a time.THE EXECUTION (2002)
You can send back a finger from his brother's hand each time you hear from me.TREASON KEEP (2001)
Perhaps even Prince Cratyn or King Jasnoff would want to hear his information.TREASON KEEP (2001)
'hearing' in Other Languages
- Arabic: سَمْع
- Brazilian Portuguese: audição
- Chinese: 听力
- Croatian: sluh
- Czech: sluch
- Danish: hørelse
- Dutch: gehoor
- European Spanish: oído sentido
- Finnish: kuulo
- French: ouïe
- German: Gehör
- Greek: ακοή
- Italian: udito
- Japanese: 聴力
- Korean: 듣기
- Norwegian: hørsel
- Polish: słuch
- Portuguese: audição
- Romanian: auz auzuri
- Russian: слух
- Spanish: oído
- Swedish: hörsel
- Thai: การได้ยิน
- Turkish: işitme
- Ukrainian: слух
- Vietnamese: thính giác
Translation of hearing from the Collins English to Italian Dictionary
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Midi skirts are extremely feminine and give the perfect shape to your body, hugging it in all the right places. Because the Midi skirt covers so much of your legs, it is only appropriate to wear a skin-baring top to balance it out. It gives your outfit a sexy edge while still looking dainty. This is a great look …
How to Dress Like an A-lister
1. H&M// 2. Urban Outfitters // 3. Daily Look// 4. Kate Spade// 1. La Maison Sequin Top // 2. Daily Look// 3. Marina Pleated Skirt// 4. Urban Outfitters // 5. BCBG Heels // 1. Coggles// 2. Pixie Market// 3. Steve Madden// 4. Jcrew // 5. ASOS //
Every Story Begins With A Girl
Crop Top: ASOS (similar here and here) // Skirt: ZARA (similar here and here) // Heels: ZARA (similar here and here) // Bag: Forever21
12 Ways to Wear 2015's Pantone Color
I am not going to lie, when I saw this year's pantone color I was not very pleased. However, in the last couple of months I've started to notice the color almost everywhere and it started to grow on me. I especially love this color option in makeup and nail polish. Hope you guys like some of the items …
Ultimate Gift Guide for The Shoe Addict
1.Luxury Rebel// 2. Michael Michael Kors//3.Tibi Suvi Booties//4.BCBG Maxazria Polaris// 5.L.A.M.B. Ward//6.Schutz Nadely// 7.Fergie Reign// 8.Guess Odeum// 9. Steven Majisty//
Camo Love
Pants: Zara (similar here) | T-Shirt: Zara (similar here, here, here) | Shoes: Chinese Laundry (similar here, here & here) | Bag: Forever21


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June 2014 - Rhapsody of the Seas to Alaska - Inside Passage
Cruise was excellent! We all had a rocky 1st day in the North Pacific but the inner passage was smooth as glass. The cruise up Tracy Arm Fjord to Sawyer Glacier was the high point of the week. We plan to return to Alaska in the future and do a cruise/land tour.


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Item: 281887770765
A precolumbian figural bead. Ex. Segy collection 1960s
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View of the fjord
Location in Sogn og Fjordane county
Nordfjord, Sogn og Fjordane
61°48′10″N 6°06′42″E / 61.8027°N 6.1116°E / 61.8027; 6.1116Coordinates: 61°48′10″N 6°06′42″E / 61.8027°N 6.1116°E / 61.8027; 6.1116
Primary inflows
Gloppeelva river
Primary outflows
Basin countries
Max. length
12 kilometres (7.5 mi)
Max. width
2.7 kilometres (1.7 mi)
Sandane, Vereide, Sørstranda
Gloppefjorden or Gloppenfjorden is a fjord in Gloppen Municipality in Sogn og Fjordane county, Norway. The 12-kilometre (7.5 mi) long fjord flows from the village of Sandane in the southeast to its mouth at the Nordfjorden in the northwest. The river Gloppeelva is the primary inflow on the fjord. The river comes from the large lake Breimsvatnet. The 2.7-kilometre (1.7 mi) wide fjord has a lot of settlements along the inner parts of the fjord, especially on the eastern side of the fjord. The most notable village areas are Sandane, Vereide, and Sørstranda. The European route E39 highway runs along the eastern side of the fjord. Sandane Airport, Anda is located near the mouth of the fjord.[1]
See also[edit]
List of Norwegian fjords
^ Store norske leksikon. "Gloppenfjorden" (in Norwegian). Retrieved 2013-10-23.


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For all the buzz about data-driven marketing today, it can mean very different things depending on the type of company that tries to adopt it.
A study from Mediakix shows that we're probably spending more time on social media than we think.
Imagine a perfect tandem: machines delivering huge amounts of organized data to a human, who caps it off with creative insight to craft the perfect marketing campaign.
Here are 3 reasons why visuals—videos, images, VR and the like—will be the predominant form of content we interact with in the next decade.
Blockchain technology will enable customers to verify your value proposition in entirely new ways.
The complexity of today's marketing landscape has grown exponentially in recent years, and marketers need the right ammunition to approach each marketing decision intelligently.
A comprehensive Google Maps strategy is essential for any retailer -- whether they're managing a single mom-and-pop location or a large enterprise with thousands of franchises -- to drive store traffic.
Marketing leaders share their thoughts on the biggest challenges facing the digital ad industry right now.
GeoMarketing's Lauryn Chamberlain tells SmartBrief about the changes afoot in retail thanks to the on-demand, or sharing, economy.
Have you considered how marketing will be upended by Bitcoin technology?


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There should be a way to remove yourself from your party. Also, how about deleting your account.
I would really like to be able to leave my party and start a new one! I'm in a completely different state/household now and can't do anything other than give up the username I use everywhere.
I'd really like to be able to delete old characters. I hate that they're just sitting there.
You can ask your Dungeon Master to exile a character to effectively remove it from the party, although I agree it'd be useful to have the option to exile yourself.
Exiling a character does not remove them from the party and does not allow them to join another party. The character's name is stuck tied to the old party no matter what. There needs to be an option to leave parties in case someone moves out of a household and goes somewhere else (Kids moving out of their parental house, for instance) so they can keep the stats of their old character and bring it into the new household. There also needs to be an option to delete a character. How many zombie accounts do you think you have on your site? Seriously, do a check up on how many accounts are accessed infrequently or have not been accessed for years. There needs to be a way for people to delete these accounts if only for database cleanup, if not to open up their usernames again for themselves or others to use. I have one account which is stuck in a highly inactive group of people, some of which I do not even have contact information for. This is not a setting in which I will want to continue using your site. I need the option to leave my current party, or delete my character. It is about the most requested topic on this getsatisfaction site of yours.
Yes, but the DM can't exile himself. Mean that if the DM wishes to join a new party, they have no choice but to create a new profile.
I found it useful to make a "mule" account as the original dungeon master. That way you could remove people from the party as necessary, including yourself, in the case of changing parties. I don't really know how exiling works, though, as I've never seen the need to do so, so maybe it would not be as simple, but this is the best thing I can think of.
I got exiled by my DM, so that I could reuse my account for a different party, but don't get access to the join party tab (it still shows the old party) so I can't create a new party with this username :( help?
I feel the option to leave a party is incredibly important. Some people may leave a household and want to join another (leave old party, join new party). I don't even think most people would mind losing all of their progress as long as they could keep their Username. Please make this option available in the near future.


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11月 29, 2014 合計視聴数:: 4872 今日: 1
Hotel City Realty Central Apartments on Barrikadnaya Moscow, City Realty Central Apartments on Barrikadnaya are located in Moscow city centre, on the Kudrinskaya Square. They feature elegant décor, と無料のWi-Fiが提供されています. All well-lit apartments come with air-conditioning, a TV and a washing machine. Free toiletries and a hairdryer are available in a bathroom. 様々なカフェ, bars and restaurants can be found within a 5-minute walk from the properties. Also guests can cook in a fully equipped kitchen. The Red Square is 20 minutes' walk from Apartments on Barrikadnaya, and the lively Tverskaya Street is 900 メートル. Barrikadnya Metro Station is 5 アパートから数分の徒歩, and Belorussky Train Station, where the Aeroexpress Train from Sheremetyevo International Airport arrives, です。 2 地下鉄は直ちに終了します. (Hotel City Realty Central Apartments on Barrikadnaya Moscow hotels 予約).


text:
|Publication number
|Publication type
|Application number
|Publication date
|May 3, 1977
|Filing date
|Dec 9, 1975
|Priority date
|Dec 9, 1975
|Also published as
|Publication number
|Verner Alexanderson, James Bryant Trecek, Cornelius Marsden Vanderwaart
|Original Assignee
|American Cyanamid Company
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (3), Referenced by (51), Classifications (17)
|External Links: USPTO, USPTO Assignment, Espacenet
This invention relates to an improved process for the mononitration of a nitratable aromatic compound. More particularly, it relates to an improved adiabatic process for the mononitration of a nitratable aromatic compound, and still more particularly to a continuous or batch adiabatic process for the production of nitrobenzene.
The nitration of nitratable aromatic compounds is old and well known. The nitration of benzene to mononitrobenzene is widely practiced commercially, particularly for the manufacture of aniline. Conventional commercial processes for nitrobenzene ordinarily utilize either a batchwise or continuous addition of a mixture of sulfuric acid and nitric acid, commonly referred to as mixed acid, to benzene. The nitration reaction is ordinarily conducted at a temperature in the range 60�-70� C. or lower and involves removal of heat by cooling. Mixed acids are used containing high nitric acid content, i.e. in the order of 20-30%, and as a result the volume of mixed acid is relatively low; ratio of mixed acid to benzene is ordinarily about 2.9-3.6 to 1. The spent acid, i.e., the mixed acid essentially completely depleted of nitric acid, generally about 70% sulfuric acid, is then reconcentrated to 93-95% sulfuric acid or fortified with sulfur trioxide or oleum to 100-105% for recycle and reuse.
One of the disadvantages inherent in the conventional processes, primarily the extensive cooling required to remove the heat of reaction, was recognized by Castner (see U.S. Pat. No. 2,256,999) who disclosed an adiabatic nitration process in which the total heat of mixing and heat of reaction was retained and utilized in the reaction to increase the rate thereof and also to raise the temperature of the spent acid to a peak of about 110� C., thereby permitting more efficient concentration of the spent acid by conventional means, such as flash evaporation.
The Castner process for the nitration of benzene is conducted with the reactants at an initial temperature of approximately 90� C. This is a temperature appreciably higher than the boiling point of benzene, and thus unless the benzene is added slowly, or the entire reaction system is under pressure, benzene would boil violently and thus disrupt the reaction. If the benzene is added slowly, the amount of dinitrobenzene produced increases. This result is illustrated by Example 17 in which the conditions of the Castner process are shown to yield nitrobenzene containing appreciable quantities of dinitrobenzene. It is, of course, possible to have a high initial reaction temperature without creating an excessive final temperature if the amount of nitric acid in the mixed acid is small. This technique, however, leads to inconveniently large volume of reactants and does not represent a practical solution. Even if an aromatic material with a boiling point greater than 90� C. is being nitrated, the high starting temperature of Castner process is a disadvantage because if a reasonable amount of nitric acid (i.e., more than about 5%) is used in the reaction mixture, the temperature of the final reaction mixture will be excessive. If the final reaction mixture is too hot, not only will side reactions be likely to occur, but the reaction may be hazardous as well. Insofar as we are aware, the adiabatic nitration process has not met with commercial success, probably for these reasons.
It is desirable to minimize dinitro formation since their presence is potentially hazardous. Although dinitrophenol, for example, may be removed from nitrobenzene reaction mixtures by a simple alkaline wash, dinitrobenzene is not so readily removed therefrom. In fact, removal of dinitrobenzene requires distillation of the product mononitrobenzene therefrom, which can lead to high concentrations of dinitrobenzene in the still bottom, which is a potentially hazardous situation. Similar dinitrobenzene buildup may occur in any process where mononitrobenzene is vaporized, such as in catalytic vapor phase aniline processes. Such buildups may also occur during use or processing of other mononitro materials and present a sever risk of explosion or fire whenever they occur. There is need for an efficient process for the production of mononitro compounds which are relatively free of contamination with dinitro compounds. Because of the many advantages of an adiabatic nitration process, it would be particularly desirable to have an adiabatic process which delivered a product low in dinitro compounds.
It is an object of the present invention to provide a continuous or batch adiabatic process for the production of mononitro aromatic compounds containing less than 500 ppm of the dinitrated species thereof. It is yet another object of the present invention to provide such a process for the production of nitrobenzene. Other objects and advantages will be set forth in the following description of the invention.
In accordance with the above stated objectives we have now discovered an improved adiabatic process for the nitration of a nitratable aromatic compound, stable in the presence of hot sulfuric acid, which produces a mononitro compound containing less than 500 ppm of the dinitrated species thereof, which comprises continuously contacting a nitratable aromatic compound with a mixed acid reactant consisting of about 60-70% sulfuric acid, 5-8.5% nitric acid, and not less than 25% water at an initial temperature of about 40� C. to 80� C., for a period of time ranging from about 0.5 to 7.5 minutes, whereby the reaction temperature does not exceed about 145� C.
In order to insure complete denitration of the mixed acid, the aromatic nitratable compound is used in slight excess (about 1-10%) over the nitric acid, and preferably about 1-5%.
If the process of the present invention is conducted as a batch process, the nitratable aromatic compound is added with stirring to the mixed acid in an insulated vessel. It is desirable that the nitratable aromatic compound be added to the mixed acid as quickly as possible. When the nitration reaction has gone on for the desired period of time, the nitrated aromatic material may be separated from the mixed acid by standard methods. If the process of the present invention is conducted as a continuous process, a stream of the nitratable aromatic compound is contacted with a mixed acid reactant stream with adequate mixing and for the appropriate period of time to form a nitration reaction mixture which is separated into two streams, one stream consisting mainly of the mononitrated aromatic compound and the other stream consisting mainly of spent sulfuric acid. Whether the reaction is run as a continuous or batch process, however, the entire reaction mixture is appreciably warmed by the heat of the reaction, and this heat is useable to aid in the restoring of the sulfuric acid to its original concentration by removal of both the water formed in the nitration reaction, and the water in the nitric acid originally employed.
The process of the present invention has advantages over the method of Castner in that it utilizes initial reaction temperatures below the boiling point of the aromatic compound to be nitrated; it avoids the use of pressure or refluxing means; and controls the amount of water in the mixed acid, to an extent which minimizes dinitration.
As stated above, the mixed acid used in the process of this invention contains from about 5.0% to 8.5% nitric acid, preferably about 6.0% to 8.0% nitric acid; from about 60% to 70% sulfuric acid, preferably 62% to 68% sulfuric acid, and not less than about 25% water.
When the mixed acid contains less than about 5% nitric acid, the volume of mixed acid which must be handled becomes too high, i.e., the ratio of mixed acid to organic substrate is too high and becomes uneconomical. It will be understood, however, that the process of the invention is otherwise operable at lower than 5% nitric acid concentration. If the nitric acid concentration appreciably exceeds about 8.5% the nitration reaction tends to produce excessive amounts of dinitrated products (from an otherwise unnitrated organic species). When the nitration mixture contains about 60% to 70% sulfuric acid, the mixture (assuming essentially complete denitration thereof by the organic compound) will contain residual sulfuric acid (spent acid) having a concentration ranging from about 64% to 72%. We have found that when the spent acid concentration is appreciably less than about 64% sulfuric acid the nitration reaction is too slow and incomplete conversion results during the reaction times of the invention. On the other hand, when the spent acid contains appreciably more than 72% sulfuric acid, excessive dinitration results. Thus, we prefer to use a mixed acid which will result in a spent acid in the range 64-70% sulfuric acid.
A critical factor influencing the amount of dinitration is the amount of water in the mixed acid. We have found that if the mixed acid contains appreciably less than about 25% water, excessive dinitration will result. In particular, if the mixed acid contains less than about 25% water, nitration of benzene will result in greater than 500 parts per million of dinitrobenzene.
The reaction may be conducted at an initial temperature in the range of about 40� C. to 80� C. depending on the nature of the organic substrate, provided that the heat generated thereby does not result in a peak temperature exceeding about 140-145� C. In the mononitration of benzene, we prefer to use an initial reaction temperature in the range of about 60� C. to 75� C.
To accomplish the mononitration reaction continuously in the shortest time, vigorous agitation is required to achieve intimate contact of the substrate and nitration medium. Vigorous agitation may be achieved by any means suitable, but can be defined generally as that degree of agitation which will result in completion of the nitration under the conditions described herein from about 0.5 to 7.5 minutes. Vigorous agitation is most important in conducting the nitration under conditions which result in the shortest reaction times. Preferably the reaction will be completed in about 0.5 to 3 minutes.
The process described herein for the mononitration of a nitratable aromatic compound will function with any aromatic hydrocarbon or halogen substituted aromatic hydrocarbon which is not degraded by hot sulfuric acid and whose nitration product is also stable in the presence of hot aqueous sulfuric acid, provided that the aromatic compound may be liquidified at a temperature within the range of about 40� to 80� C. Thus, the process may be used to produce mononitroderivatives of compounds such as benzene, toluene, dimethyl benzene, halobenzene, naphthalene, methylnaphthalene, halonaphthalene, halotoluene and halomethylnaphthalenes, etc. Hereafter, the term nitratable aromatic hydrocarbon shall refer to any aromatic hydrocarbon, or halo derivative of an aromatic hydrocarbon which is stable in the presence of hot sulfuric acid, liquifiable within the temperature range from about 40� to 80� C., and whose nitration product is also stable in the presence of hot aqueous sulfuric acid.
The process of the invention is not limited to any particular apparatus or assemblage thereof or to any particular method of operation. The reaction is preferably conducted continuously, ideally using a plug flow reactor. However, it may be carried in a series of staged reactors, or in a stirred cylindrical reactor.
The following examples are provided for illustrative purposes and may include particular features of the invention. However, the examples should not be construed to limit the invention, many variations of which are possible without departing from the spirit or scope thereof.
A reactant stream of benzene (1.1 molar proportions) and a reactant stream containing 5.2% nitric acid (1 molar proportion), 67.6% sulfuric acid and 27.2% water, were mixed and immediately metered at 68� C. into a vigorously agitated tubular reactor 40 inches in length and 1 inch in diameter. Residence time in the reactor was 4 minutes. The reaction stream at 116� C. exiting the reactor was allowed to separate and the crude nitrobenzene phase withdrawn from the spent acid. Analysis of the organic phase showed 94% mononitrobenzene, 5.9% benzene, 0.02% m-dinitrobenzene and 0.02% 2,6-dinitrophenol. Spent acid concentration was 70.48% sulfuric acid. No nitric acid was present.
A vigorously agitated insulated reaction vessel containing a mixed acid consisting of 5.2 percent nitric acid, 67.6% sulfuric acid and 27.2% water was heated to 60� C. Benzene in stoichiometric amount, was added thereto over a period of 0.15 minutes. The temperature increased to 106� C. during a total reaction time of 2.4 minutes. The organic phase was then separated from the residual sulfuric acid and the organic phase analyzed for m-dinitrobenzene. There was found to be 0.008% m-DNB or 80 ppm.
Following the procedure of Example 2, except that a 5% excess of benzene was used, a number of experiments were conducted as shown in Table 1.
TABLE 1__________________________________________________________________________ ReactionMixed Acid Reaction Temperature, �C. Spent Acid m-DNB 2,6-DNPExample% HNO3 % H2 SO4 % H2 O Time, Min. Initial Final (% H2 SO4) % %__________________________________________________________________________3 6.2 61.0 32.8 7.5 60 104 63.8 ND** 0.0794 6.2 61.0 32.8 3.5 80 124 63.8 ND 0.125 6.2 64.0 29.8 2.25 60 112 67.0 ND 0.0716 6.2 64.0 29.8 1.5 80 132 67.0 0.01 0.137 6.2 68.0 25.8 0.8 60 120 71.2 0.01 0/088 6.2 68.0 25.8 0.75 80 135 71.2 0.051 0.139 8.2 61.0 30.8 5.0 60 122 64.8 NK 0.1110 8.2 61.0 30.8 3.5 80 135 64.8 NS 0.1611 8.2 64.0 27.8 2.5 60 128 68.0 ND 1.1012 8.2 64.0 27.8 1.75 80 145 68.0 0.036 0.1813 8.2 68.0 23.8* 0.8 60 132 72.2 0.09* 0.1214 8.2 68.0 23.8* 1.0 80 148 72.2 0.38* 0.1915 5.2 68.0 26.8 1.75 80 123 70.6 0.035 --16.sup.(1)4.0 70.2 25.8 1.0 90* 124 72.3 0.11* 0.12717.sup.(1)4.0 70.2 25.8 10.0*** 90 119 72.3 1.80 0.153__________________________________________________________________________ *Note: these examples are outside the scope of the invention; product doe not meet specification. **None detected ***Benzene addition time .sup.(1) 1% benzene excess
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|Bayer Aktiengesellschaft
|Process for the polynitration of aromatic compounds
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|Jul 15, 1997
|Bayer Aktiengesellschaft
|Process for the adiabatic preparation of mononitrotoluenes
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|Sep 2, 1997
|Bayer Aktiengesellschaft
|Process for the production of dinitrotoluene and isomeric mixtures of dinitrotoluene
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|Bayer Aktiengesellschaft
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|Nov 18, 1997
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|Jul 10, 2001
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|Process for ring nitrating aromatic compounds in a tubular reactor having static mixing elements separated by coalescing zones
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|Dec 4, 2007
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|Tubular reactor having static mixing elements separated by coalescing zones
|Nov 20, 2006
|Dec 15, 2009
|Poehlmann Juergen
|Process for the preparation of nitric esters of monohydric alcohols
|Sep 28, 2009
|Apr 10, 2012
|H R D Corporation
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|Method of making alkylene glycols
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|Method of making alkylene glycols
|Nov 14, 2008
|Dec 10, 2013
|Noram International Limited
|Method for reducing the formation of by-product dinitrobenzene in the production of mononitrobenzene
|Nov 10, 2008
|Apr 8, 2014
|Noram International Limited
|Adiabatic process for making mononitrobenzene
|Mar 22, 2012
|Dec 9, 2014
|Noram International Limited
|Process for adiabatic production of mononitrotoluene
|Jul 3, 2002
|Jan 9, 2003
|Gillis Paul A.
|Tubular reactor having static mixing elements separated by coalescing zones
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|Jun 7, 2007
|Jurgen Pohlmann
|Process for the preparation of nitric esters of monohydric alcohols
|Sep 28, 2009
|Jan 21, 2010
|H R D Corporation
|System and process for production of nitrobenzene
|Apr 25, 2008
|Jul 22, 2010
|Huntsman International Llc
|Process for preparing mixtures of diphenyl-methane diisocyanates and polyphenyl-polymethylene polyisocyanates
|Nov 14, 2008
|Sep 8, 2011
|Noram International Limited
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|Nov 13, 1993
|Oct 28, 1998
|Process for the prepn. of dinitrotoluene
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|Sep 5, 2001
|Process for the adiabatic prepn. of mononitrotoleunes
|Jul 7, 2009
|May 30, 2012
|Rapid material cooling and waste acid recycling process after chlorobenzene thermal insulation nitration
|Jul 7, 2009
|Aug 22, 2012
|Washing impurity-removing technology of crude nitrochlorobenzene products after chlorobenzene thermal insulation nitration
|Nov 10, 2008
|Apr 15, 2015
|Adiabatic process for making mononitrobenzene
|Mar 22, 1993
|Sep 20, 2001
|Bayer Ag
|Verfahren zur Herstellung von Dinitrotoluol
|Feb 23, 2001
|May 8, 2002
|Bayer Ag
|Continuous production of nitrochlorobenzene, used as intermediates for dye, pharmaceutical and pesticide production, uses specified adiabatic conditions and acid composition in nitration of chlorobenzene
|Nov 30, 2005
|May 16, 2007
|Meissner Gmbh & Co Kg Josef
|Preparation of nitric acid esters of univalent alcohols comprises reacting the univalent alcohols or its mixture with nitric acid esters in the presence of sulfuric acid under adiabatic reaction condition
|Mar 18, 1988
|Jul 14, 1993
|Nippon Kayaku Kabushiki Kaisha
|Process for producing a fluoromononitrobenzene
|Feb 1, 1995
|Aug 23, 1995
|Bayer Ag
|Process for the adiabatic preparation of mononitrotoluenes
|Mar 17, 1995
|Oct 4, 1995
|Bayer Ag
|Process for adiabatic preparation of mononitrohalogenbenzenes
|Jul 31, 1995
|Feb 14, 1996
|Bayer Ag
|Process for the preparation of dinitrotoluene
|Oct 9, 1995
|Apr 24, 1996
|Bayer Ag
|Process for the dinitration of aromatic compounds
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|Dec 18, 1996
|Bayer Ag
|Process for the preparation of dinitrotoluene
|Oct 27, 2000
|May 16, 2001
|Bayer Ag
|Process for the adiabatic preparation of 3,4-dichloronitrobenzene
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|Bayer Ag
|Continuous adiabatic process for the preparation of nitrochlorobenzene
|Jul 26, 2011
|Feb 2, 2012
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|Method for continuously producing nitrobenzene
|Oct 15, 2012
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|Council Of Scientific & Industrial Research
|Continuous two step flow synthesis of m-amino acetophenone
|Jul 23, 2014
|Jan 29, 2015
|Council Of Scientific And Industrial Research
|Continuous flow liquid phase nitration of alkyl benzene compounds
|U.S. Classification
|568/939, 568/937, 568/929, 568/940
|International Classification
|Cooperative Classification
|European Classification


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Some facets will have to be thought about when you are about to buy a boat, one of those will be whether it is best to purchase a brand new boat, or a used boat. This is actually is dependent on your individual preference, and there are some great deals to be had it does not matter what you select. The prime consideration which is advisable to look for is class. If a boat is clean and in a good condition, then it is more likely that it will be trouble free for its owners.
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SPC is inviting applications for the position of Team Leader Non-communicable Diseases (NCD) in its Public Health Division located at its regional office in Suva, Fiji.
The Secretariat of the Pacific Community (SPC) works with its 22 Pacific Island member countries and territories, providing technical and scientific assistance across a wide range of sectors to enhance economic, environmental, social and human development in this region.
The Public Health Division (PHD) has staff based in Noumea (New Caledonia), Suva (Fiji), Honiara (Solomon Islands) and Pohnpei (Federated States of Micronesia). It supports member countries in improving the health of Pacific Island people and communities by providing assistance in public health surveillance and the prevention of communicable and non-communicable diseases. Under PHD's strategic plan 2013-2022, the division is organised into two programmes: (i) Research, Evidence and Information (REI), and (ii) Policy, Planning and Regulation (PPR). REI focuses on developing the evidence base and information for policy and actions directed at strengthening core public health functions in member countries and territories. The aim is to enable and support member countries to respond effectively to all public health threats rather than single disease or risk factors. PPR focuses on supporting the development of appropriate policy options in member countries in order to improve the health of Pacific people and contribute to national development plans. PHD's overall goals are to: (i) improve population health and well-being, and prevent disease and injury; (ii) reduce gender disparities in health; and (iii) reduce the incidence of prevalent and/or priority diseases. Priority areas are: (i) non-communicable disease (NCD) prevention and control, including the major risk factors; (ii) communicable disease surveillance and response; and (iii) sexually transmitted infection (STI) prevention and control, including HIV/AIDS.
Applications due 13th August 2015.


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Gabriel Jacobs is President of Sales & Marketing for Blo Dad & Sons, the Boozelator Breathalyzer Vending and Advertising Machine company. Headquartered in Cape Coral, Fla., the company is determined to make a difference in the world by reducing the amount of drunk drivers on the road, one bar at a time. Drunk driving is a real and present danger that claims the lives of nearly 10,000 Americans every year, more than one life every hour.
In our Q&A with Jacobs, we learn the idea behind the franchise, what he would've done differently and where he sees the company in five years.
Read Full Article Here: https://www.business-opportunities.biz/2015/06/22/boozelator-aims-reduce-drunk-drivers-one-bar-time/


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Bruno Mars Addresses 'Disgusting' Criticisms Over His Super Bowl Gig on 'Ellen'
Bruno Mars amazed the crowd with his killer vocals and energetic dance moves when he performed at Super Bowl halftime show on February 2. However, not everyone is a fan of the Hawaiian singer's performance.
Mars appeared in the Monday, February 10 episode of "The Ellen DeGeneres Show" to talk about the gig and address some criticisms he received. "You know, you know what they said, but they basically didn't think he was a star. They said he wasn't a star because he wasn't in the tabloids and he doesn't have a fragrance," host Ellen DeGeneres said, referring to a New York Times article.
"I did hear that and I think that was by far the most disgusting thing I think I've heard," Mars responded. "Not because it was taking a shot at me, but I was thinking about aspiring young musicians who want to do this and even hearing the thought you need a fragrance or something like that..."
Mars then delivered an inspiring speech to aspiring musicians who are pursuing their dreams. "Any young, aspiring musicians out there, if music is what you want to do, if music is what you love and your passion. It doesn't take a fragrance, it's not about the tabloids, it's about you putting in the work, practicing every day, practicing your vocals, practicing your instrument, practicing songwriting," he said.
"I promise you one day you're going to have your moment to shine and you're going to have a lot of people saying that you can't do it and you're not good enough," he continued. "But I promise you, if you go out there and sing and you put your heart and soul into it and you follow your dream, one day you're going to be sitting next to Ellen DeGeneres, talking about how you broke records and rocked the Super Bowl. Stand up America!"
During the interview with DeGeneres, Mars also revealed that he spent "months" rehearsing for his Super Bowl performance. "As soon as we got the call I was thinking about ideas and, you know, how are going to pull this off? It's the biggest stage on Earth," he explained.
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UP Police Recruitment 2017 is going to recruit 3789 contenders for the post of Jail Warder and Fireman, to get more details check the below mentioned information.
UP Police Recruitment 2017
Are you interested in the police sector??? Grand openings of the UP police recruitment 2017!!! If yes then we have excellent news for you. Uttar Pradesh Police Recruitment & Promotion Board has been released a new notification as UP police recruitment 2017. The total no. of recruitments is 3789 for the post of Jail Warder and Fireman. Interested contenders can apply for the UP police recruitment 2017. If you want to apply for the police recruitment 2017 then first of all you should check the eligibility criteria. Eligible contender should fill the application form on or before the last date that is 4th February 2017. for more details regarding police recruitment 2017 check the below mentioned information.
Vacancy details
|Jail Warder (Male)
|Jail Warder (Female)
Required Eligibility criteria of UP Police Recruitment 2017
If you are applied for the UP police recruitment 2017 then first of all you should check the eligibility criteria. Under the age criteria applicant's age should not be less than 18 years and should not be more than 22 years as on 1st July 2017. Age relaxation will also give to the reserved categories. Contenders must have to pass 10th or 12th class certificate from any recognized institute or board. Contenders if you want to more Govt jobs in Uttar Pradesh then click here for apply online.
Other Information of UP Police Recruitment 2017
To apply for the UP police recruitment 2017 contenders have to pay the application fee that is Rs. 200/- through online mode. The selection procedure of the UP police recruitment 2017 selection procedure is based on the merit list of the 10th and 12th marks short listed contenders will call for the Physical Standards Test. Recruited contenders will get an attractive amount of salary. The pay scale is Rs. 5, 200/- to Rs. 20, 200/- with a grade pay of Rs.2000/-.
Read Also: How to Pay Fees Online
Important links
|Download Syllabus 2017 New Exam Pattern
|Click Here
|Download Previous Papers
|Click Here
|Download Admit Card After Releasing
|Click Here
|Download UP Police PET & Salary Details
|Click Here
|Download Results After Releasing
|Click Here
Process to Apply for UP Police Recruitment 2017
To apply for the UP police recruitment 2017 first of all log in to the official website of the UP police dept. on the mid of the home page click on the link named as Important News and Alert section. A new page will appear on that page click on the suitable link related to the recruitment. A new page will appear having notification, read it carefully and then click on the apply online link. A blank form will appear. Fill that form properly and attach required documents and click on the submit tab. at last take a print out of it for future reference.
Check: How to Fill Application form
Important dates
|Closing date for UP Police Registration
|30th January 2017
|Last date for payment of Application Fee
|01st February 2017
|Last date to submit Online Application
|04th February 2017
Some Useful Links
|State wise Govt jobs 2017
|Central Govt jobs 2017
|Railway Recruitment 2017
|Bank Jobs 2017
|Latest Sarkari Naukri 2017
|Defence Jobs 2017
Important links
|UP Police Recruitment 2017
|Official Notification 1
|Official Notification 2
|Official Notification 3
|Apply Online
|Pay Fees
|UP Police Jail Warder Recruitment 2017
|Download Syllabus 2017
|Download Previous Papers
|Official website