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Clear your Saturday night, Marvel movie fans, because Chris Hemsworth is making his "Saturday Night Live" debut. The actor that has brought Thor to life in three Marvel Studios films will trade in his cape for a number of ridiculous costumes during his first tour of duty at the legendary sketch comedy show. Will he get gnarly in one of Kyle Mooney and Beck Bennett's off-kilter "Inside SoCal" videos? Will he make a purposefully awkward walk-on during a former porn star commercial? Will he get sassy as a nurse at an animal hospital? You'll have to stay in and stay up late on Saturday night to find out.
RELATED: "Saturday Night Live" and Chris Pratt Reveal Marvel Studios' Next Blockbusters?
When Hemsworth takes the stage in Studio 8H, he'll stand in the very spot where other inhabitants of the Marvel Cinematic Universe have previously launched into monologues. Over the past three decades, more than a dozen actors from Marvel Studios' ten released feature films have hosted "Saturday Night Live." To get you psyched up for Thor's "SNL" debut, here are sketches from 13 other Marvel actors' turns at hosting.
Jeff Bridges
Marvel Role: Obadiah Stane
Bridges may have only made one appearance in a Marvel film, but his turn as Obadiah Stane in 2008's "Iron Man" makes him the very first actor to play a villain in the Marvel Cinematic Universe. Bridges first hosted "SNL" on February 26, 1983 alongside his brother Beau in one of the handful of hosting duos in the show's history. Bridges hosted the show solo 28 seasons later in 2010, but we can't pass up the opportunity to show a sketch featuring baby-faced Bridges from the early '80s.
Robert Downey Jr.
Marvel Role: Iron Man
Unlike the other entries on this list, Downey is the only MCU actor to have actually been an "SNL" cast member. Yep, a 20-year-old Iron Man joined the cast in the fall of 1985 and departed the show at the end of the TV season. He returned to host again in 1996 and hasn't been back since. While his brief stint as a cast member didn't result in any memorable characters, it did result in this sketch where RDJ plays a confrontational suitcase.
Glenn Close
Marvel Role: Nova Prime
Glenn Close brought a real air of dignity to "Guardians of Galaxy" in her role as the Nova Corp leader, but Close has also shown that she's not afraid to go for laughs as well. Close first hosted "SNL" on February 25, 1989 where -- as seen below -- she spoofed her star-making turn in the thriller "Fatal Attraction."
Samuel L. Jackson
Marvel Role: Nick Fury
Samuel L. Jackson has made a lot of appearances as Nick Fury, but he's only ever hosted "SNL" once. This sketch from January 10, 1998 puts Jackson up against other "SNL" cast members in "audition footage" for the role of Vincent Vega in "Pulp Fiction." If you thought Nick Fury got tired of dealing with aliens and gods, just wait until you see him react to "Brady Bunch" and "Leave It To Beaver" cast members.
Gwyneth Paltrow
Marvel Role: Pepper Potts
Paltrow's no-nonsense Pepper Potts has appeared in four Marvel movies to date, which makes her one of the most prominent actors in the MCU. She's also hosted "SNL" three times, which makes her tied for the number of most host appearances on the sketch show. Her first go as host on February 6, 1999 put her in a sketch with "Saturday Night Live's" bad ass ladies of the late '90s: Cheri Oteri, Ana Gasteyer and -- as Mary Katherine Gallagher -- Molly Shannon.
Scarlett Johansson
Marvel Role: Black Widow
Tied with Paltrow for the lead on this list of hosts is Scarlett Johansson, who has also headed up the sketch show three times. Johansson made back-to-back appearances in seasons 31 and 32 and was last seen hosting in season 36 -- her only turn as host after her Black Widow debut in "Iron Man 2." In her first episode from January 14, 2006, Johansson got to utilize her singing chops alongside Will Forte in a surreal sketch called "Fly High Duluth."
John C. Reilly
Marvel Role: Nova Corpsman Rhomann Dey
Because of his gregarious nature and gung-ho attitude, a little John C. Reilly goes a long way -- as evidenced in his handful of "Guardians of the Galaxy" scenes and his ridiculous tour de force appearance as "SNL" host in October 2006. Reilly has only hosted the show once, but the comedic actor really put it all out there in his "SNL" episode. Really, he put it all out there. Just watch Reilly's turn as dream dust-coated swimming instructor Doug Frangello.
Natalie Portman
Marvel Role: Jane Foster
The confidence Foster brings to the very human role of Jane Foster has been enough to overcome Dark Elves and Destroyers, and that confidence was on full display in her sole "SNL" appearance on March 4, 2006. Odds are you remember Portman's turn as host because it featured one of the first breakout "SNL" Digital Shorts, the hilariously extreme "Natalie's Rap."
Bradley Cooper
Marvel Role: Rocket Raccoon
Years before he voiced a gun-toting raccoon in "Guardians of the Galaxy," Bradley Cooper played a dudebro and a runway coach on "Saturday Night Live." In this sketch from his February 7, 2009 appearance, Cooper plays the host of a game show called "I'm Gonna Have Sex With Your Wife." Try your hardest to watch this sketch without picturing Rocket saying every line.
Josh Brolin
Marvel Role: Thanos
Brolin's appearance as Thanos may have been brief in "Guardians of the Galaxy," but he's going to be a major player by the time Marvel's Phase Three slate of films wraps up with "Avengers: Infinity War." Brolin got to play a big role in "Saturday Night Live" when he first hosted back in October 2008. Like Close and Bridges before him, Brolin has hosted the show twice. Here's a sketch from his April 2012 appearance, which sees him playing a tipsy teacher in one of Jay Pharaoh's Principal Frye sketches.
Jeremy Renner
Marvel Role: Hawkeye
Renner was the first Marvel actor to host "Saturday Night Live" following "The Avengers'" record-smashing theatrical run. This appearance in November 2012 included a sketch that tried to answer the question "what happens when Hawkeye runs out of arrows" and also, as you can see below, featured Renner in a three-way stand off with Bobby Moynihan and Taran Killam.
Edward Norton
Marvel Role: The Hulk
Mark Ruffalo may soon eclipse Norton in terms of screentime as Bruce Banner, but Marvel's original Hulk still has the current one beat when it comes to "SNL" appearances. Ruffalo has yet to make a trip to Studio 8H whereas Norton hosted the show for the first time back in October 2013. What do you do when you have an actor noted for his quirky roles in Wes Anderson films hosting so close to Halloween? Well, you do this:
Chris Pratt
Marvel Role: Star-Lord
The last Marvel actor to host "SNL" was "Guardians of the Galaxy's" Chris Pratt. With his comedy background and gleeful, limitless energy, the actor behind Peter Quill proved himself game for anything -- including dressing up like both He-Man and Princess Leia. He also proved that he can handle dropping fast-paced rhymes on live television in this sketch with Aidy Bryant.
Chris Hemsworth hosts NBC's "Saturday Night Live" with musical guest Zac Brown Band on March 7.

subset: commoncrawl


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The Whole Heart of a Woman Weekend
Imagine you have escaped for a romantic Valentine's weekend away… just for yourself in a luxury barn conversion, in the Heart of Wales, overlooking hills and farmland.
Here you find yourself with an amazing group of women for a glorious weekend of yoga, meditation, nature, laughter and love. We will be connecting with our divine selves, for inner love and to empower our spirits in a safe and supportive environment. You will leave our weekend together feeling uplifted and loved.
Why should you join us?
Wouldn't it be energizing to meet new people, who value you as a woman regardless of your relationship status?
Get ready to embrace yourself! We will spend time each day with positive uplifting exercises and practices that reaffirm how important it is to honour and follow our instinct, to live a guilt free life of creativity and love.
How would it feel…
- to really understand and OWN your value?
- to exercise your power in your decision making and to feel confident when asserting yourself?
- to really live from your centre with love and respect?
- to explore just how perfect you already are with some fun new practices?
Our daily yoga practice will explore how mudras, meditations, mantras and pranayama's work alongside our asana postures to bring a greater self-awareness and confidence to our everyday life. They will help you access a much deeper self-awareness and self-appreciation.
Our Love Nest…
Llandrindod Wells, nestled in the middle of Wales, this Victorian Spa Town boasts independent shops, bistros and even an award winning micro pub. Take a deeper look and it's also an energetic and natural wonderland of un-spoilt green landscape, prehistoric burial mounds and standing stones, natural healing wells, with miles and miles of rambling opportunities. A truely beautiful mix of ancient and new.
Brynhir Farm is situated in Howey, just outside Llandrindod Wells. It offers award winning farmhouse accomodation In an ancient, character filled, luxury farmhouse, a relaxed and friendly atmosphere greets you.
We will be calling the luxury converted barn on the farm our home for the weekend. Beautifully furnished it is light and airy, and will make a perfect studio space for our 'inside time'. The balcony also offers a hottub for night time star gazing with a difference!
The Venue.
Completely secluded in its own mountain valley, the farm offers unique feeling of peace and quiet for guests at all times.
Boasting exceptional standards, the farm has been run by the Nixon family for over sixty years and extends to approximately 300 acres. The hill farm has some of the best view-points in Radnorshire, especially from the hill overlooking the house which rises to 1,200 feet. To the south peaceful walks by the small stream can be enjoyed; Pied Flycatchers, Redstarts, Buzzards, Barn Owls and Herons can be seen close by.
This is a rural idyll less than an hour from Hereford, a 10 minute drive from Llandrindod Wells train station connecting you to Shrewsbury and Swansea.
Indeed, you can walk from the farm in any direction to connect with the nature surrounding us. Trees, water, grass and sky. Feel yourself unwinding and breath into this space. You deserve it!
2 Guest Bedrooms are appointed in the barn, and further accommodation for the group is in the farmhouse itself. With views of the surrounding farmland and hills. The atmosphere is relaxed, traditional and understated quality.
To set you up for the day Ceinwen's famous full Welsh breakfast is included!
Our 'outside time' will take in the beauty of the surrounding hills, woodland and lake. If the weather is good we will take to the hillside (or top!) for some of our yoga practice.
Only a couple of miles out of Llandrindod, it also offers free parking.
The Food!
A selection of breakfast options is available at The Farm House each morning.
Friday and Saturday's evening meals will be provided by our local bistro Sugar and Spice. Jess and her husband Paul lovingly create home-made culinary delights.
Using quality seasonal and local produce they will deliver our vegetarian feasts to the Barn. Puddings will be included to fuel the walking we will be doing!
You have special dietary requirements? Don't worry, let me know when you book and I can let Ceirwen and Jess know. I can double check anything you need clarifying before we go too.
Our Program…
4 onwards – Arrive, check in, make yourself comfortable, rest!
6-6.30 Welcome Circle
6.30-7.30 A yoga based practice focusing on opening the heart and receiving love and relaxation
7.30 Dinner
9.30-11 Gentle asana with guided meditation and reflection. Looking at what is holding you back from receiving love from self and others
11-11.30 Break
11.30-12.30 Explorative walking group meditation. Releasing old patterns, baggage, emotions. Creating and establishing positive relationships with our power and security as women
12.30-2 Lunch and free time in Llandrindod Wells
2-5.30 Making our way back to the farm via my parents ancient farmstead along the hillside on the way
Dropping into their pole barn for a relaxation yoga practice on expressing yourself. Owning your value, honouring that and communicating it to yourself and others
Drinking in the views, staying warm by the fireplace, we will also have some tea and cake before making our way back to Brynhir a ten minute walk away
5.30-6.30 Break
7 Dinner
9-11 A yoga based workshop focusing on Joy. Exploring concepts like play, happiness, joy, fun, excitement
11-11.30 Guided meditation and reflection. Exploring our wildest dream and aspirations for ourselves, introducing Deva's and architypes
11.30 – 12.30 Closing Circle. Exploring our meditation and reflections, our breakthroughs and 'aha' moments in the physical world. Sharing stories and celebrating each other
12.30 Tidy up and finish.
Trains leave Llandrindod Wells station approximately an hour later. Taxies or lifts can be arranged.
Booking Info…
All this wonderfulness from just
£309 pp double occupancy in a shared twin room
£349 pp single occupancy
Deposit (£100) can be made in my secure online shop, I will confirm your booking and invoice you for the balance due by 31 January 2019.
If you have any questions please get in touch!
This is deeply restorative work, enjoy it! Indulge in it! Receive it!
Also note that this itinerary is a guide and may be subject to change. The content and ordering will be the same even if the timings shift a little.
The walking is an important part of this weekend. It will be gentle and nature orientated. Please come ready for a ramble. Your current fitness and ability is unimportant. This is an inclusive group activity where you will be shown patience and respect.
You will need to bring…
Comfortable loose clothing suitable for yoga practice and meditation.
Warm layers, suitable outdoors coat and walking boots or wellies.
I will have a selection of spare mats, blocks and belts you can borrow. Please bring any other props or equipment you need, in particular a blanket and cushion.
A sense of fun, good manners and the willingness to help keep our area clean and tidy up after yourself!
What's not included…
Transport, travel and lunches.
Please make sure to arrange your travel and accommodation to be ready for the opening circle at 6pm on Friday. It's important to get here safely so please do not rush if running late. As this is a group weekend your effort to arrange your journey to be on time is appreciated, and you are welcome to arrive at Brynhir Farm from 4pm
Free parking is available at the Farm. Taxies can be picked up from Llandrindod Wells rail station. Taxi sharing is possible so let me know if you are coming by train and if you would like to share a taxi with another yogi.
Car sharing may be possible and I will help to hook you up if I can!
If you are travelling and/or booking further accommodation it is strongly recommended that you take out personal travel insurance.
Please note refunds will only be made if you are able to find a replacement for your spot.
If, for any reason, I am unable to deliver this retreat I will offer an alternative weekend, if you are unable to make the alternate weekend I will, of course, offer you a full refund.
Travelling to Brynhir Farm
Brynhir Farm, Chapel Road, Howey, Llandrindod Wells, Powys, LD1 5PB.
By Car – You will come in on the A483 from the south via Builth, or north via Llandrindod Wells. Turning into the small village of Howey follow the road round to the left on the one way system, past the pub, over the bridge and take the right hand turn up Chapel Road.
Head up Chapel Road, Brynhir Farm is signposted and will be found on the right after Three Wells B&B and a few more bends!
Brynhir Farm
Booking Info…
All this wonderfulness for just
£309 pp double occupancy in a shared twin room
£349 pp single occupancy
Deposit (£100) can be made in my secure online shop, I will confirm your booking and invoice you for the balance due by 31 January 2019.
If you have any questions please get in touch!
If you would like to run this event exclusively for your Hen Party get in touch!
About Charlotte:
Hello! I discovered meditation 10 years ago now and down the rabbit hole I fell!
Finding myself in a wonderland of yoga and personal and spiritual development classes, workshops, text and trainings. I became a total devotee.
This work is the best thing that ever happened to me. I am passionate about sharing it with you.
Having taught both physical and on-line classes, workshops, courses and retreats I am offering this special weekend as a deep exploration and celebrations of a woman's heart. Of love. If you would like to know more about me and my training please visit the "Meet Charlotte" page in the menu.


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State University of New York at Syracuse
Santa Barbara Cottage Hospital
California Pacific Medical Center
She was amazing
incredible experience, can't wait to see the Dr again! very pleased!
*Maria Wilson always takes the time to listen. I never feel rushed - excellent!
Maria Wilson is unique. She seems to really care about me and takes time to listen


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It's All About Consensus – Preparing for the College Draft
As the General Manager of a National Football League team, I thrived in and loved the grind of the process of preparing for the college draft. The thoroughness required when listening to opinions and input from everyone involved is the most important skill set, and the one that gets overlooked the most when people try to get behind the walls of an organization's draft/War room.
Compromising in the Draft Room
I am all about building a consensus in the room and stacking the board accordingly. None of us alone are smarter than all of us together. It's not about
That's why at this point in the process, (2 weeks out) I stopped watching TV, stopped listening to the media experts and tried to block out the noise. The talking heads are very much informed, but their opinions are just one person and they don't know your criteria or specific needs as they relate to your coach's schemes, etc. We have job descriptions for our players. These outside sources do not know what that criterion consists of. The only opinions that matter, at this point, are the ones in our room and those have now been examined and considered at the risk of nausea. The same goes for the MOCK DRAFT phenomenon. Everyone nowadays has one and I like to use and consider them all, but at a later date and for different reasons in the process (more to come on Mock Drafts).
Building a Consensus
We have taken input from all scouts, directors, and coaches and used that to build a consensus to line up the players according to value by position. Said another way, "stack them in the order we like them". Once this is done, I then like to consider a TOP 160, on a separate board, regardless of position. In a high percentage of NFL drafts, you will get your seven selections (plus a few more) in cases when your team has multiple picks from these 160 players. With compensatory picks, (32 slots) a draft has 256 drafting slots, but no team has their draft stacked the same so the magic task for me is getting the 160 lined up correctly. This becomes your FRONT BOARD.
You'll have a backboard of players (approx 161- 300) where your undrafted college free agents will come from. I would let the scouts stack this backboard and in a lot of cases, this is where the scouts would earn their keep. Scouts have hunches and grades that can be justified in late rounds or when signing free agents immediately after the draft. They have spent countless time and energy researching and evaluating these guys for, in some cases, two years and are the best resources for lining these players up. Assistant coaches weigh in with these players as well because in some cases, they have spent time with them at the combine or at individual pro days at colleges. These players will have been recruited by multiple teams over the two/three weeks preceding the draft just in case they don't get drafted. You want to have a relationship with these players so that they are comfortable signing a contract with you immediately after the draft. Each team signs between 8 and 15 college free agents in the hours after the draft concludes. The stacking of this front board will be the most important task you have as a staff because this is how you see the draft. This is your worksheet to draft off of. We used to literally lock this board up every night. Your front board (160 or so players) is reflective of how "we, as a team, would take these players." A team's needs will be reflected on this board within a certain grade parameter. Players can't jump grade groups just because you have a higher need, but you can adjust the board within a specific grade area based on needs. You must stay true to your process and grades. You must keep the integrity of the board based on the value you put on the players when you stacked the positional board. The idea is to stack this board according to VALUE FOR YOUR TEAM, not for any specific person, not for the league and surely not for any other team. Building CONSENSUS is the total key to his whole year long process and decision makers sleep easily once this task is complete
Photo Credit: Shutterstock | Melinda Nagy


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Wet Pour Suppliers
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Wetpour is a popular flooring option for play areas in the UK. This is because the range of benefits associated with it.
Wetpour Rubber Granules Supplies
We can supply wetpour rubber granules to create a great surface for playgrounds. The EPDM rubber surface consists of a two layer porous impact absorbing system.
This makes it a safe flooring which meets the critical fall height (CFH) requirements. Wetpour safety surfacing contains a two tier system, this is a shock pad and the wearing course.
The impact absorbing base layer depth can be changed to meet the CFH of each area. The base layer thickness varies from 30mm to 150mm.
The wearing course normally consists of 1-4mm EPDM rubber. We then mix this with the polyurethane resin and pour it onto the surface. The appearance of the EPDM will depend on the colours that the school or nursery chooses to have. We offer a range of colours for wetpour including:
- Black
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We also offer a range of colour mixes with many colours together in one design. The choice is completely up to you, but premium colours will come at a higher price. View our full wet pour colour chart to see all the options we have.
Our team will be more than happy to provide more information on the supply of wetpour rubber granules. We will also offer details on the various colours we can supply. If you have any questions or queries, please do not hesitate to contact us.
"The workmen were friendly, efficient and not only did they do a fantastic job they tidied away after themselves. We are exceptionally happy with the outcome of the surface provided. Keep up the good work."
Get In Touch
Our expert team of wet pour rubber suppliers are always on hand to offer advice. We can help with designs and installation of a new playground safety surfaces.
You can contact us through the contact form on this page if you would like to talk about the costs for our services. We would be happy to get back to you and provide an in depth quote for any work you need us to carry out. Please let us know what you need and we'll get all the information together for you.


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Research Paper: South Africa Economy History
Pages: 10 (3087 words) · Bibliography Sources: 0 · Level: Master's · Topic: Literature - African · Buy This Paper
South Africa Economy
History of South Africa
Political Situation of the Country
South African Economy
Key Macroeconomic Variables
Justice/Judiciary System of the Country
Environmental Concerns
Health Concerns in South Africa
Society/Family/Culture of the Nation
Religion practiced in South Africa
History of South Africa
South Africa has been a land of people with multiple cultural backgrounds since it was inhabited. Several centuries ago, people from different corners of African land migrated towards south and settled there with families. Additionally, many settlers came from European countries during the period of colonization together with black individuals from other African nations who were hired as slaves. Furthermore, many Asians travelled to South Africa in search of better employment and dwelled there.
Amongst the initial groups of foreigners that visited South Africa in sixteenth century, Portuguese were the prominent ones because they had established sea routes that made travelling convenient for them. Afterwards, European individuals entered the region and colonized it during mid-seventeenth century. They started businesses that mainly consisted of farming, which demanded cheap labor; therefore, slaves from other nations as well as locals were hired as servants. Although white population never outnumbered the locals; however, their power and superiority remained dominant.
Racial discrimination was prominent throughout the history of South Africa where whites were superior to blacks. When precious gemstones were explored in this territory, the local market position strengthened; thus, black population tried to improve their economic status by working extensively on farmlands. However, whites designed policies that dragged local people away from farms into slavery at mines.
A war was then waged between the local tribes and British leaders. After fierce confrontation and widespread destruction, whites stood victorious. During elections in twentieth century, whites became the ruling body who intensified Racial discrimination, as they declared it official.
Although South Africa became a republic after few years, its racial prejudice policies remained unchanged. This triggered nationalism amongst the locals to an extent that under the leadership of their prominent leaders they led an enthusiastic and vigorous revolutionary movement. Consequently, South Africa became independent from the British rule in the last decade of the century.
2. Political Situation of the Country
When the British left South Africa, elections were held in which all local parties participated. Following to it, government was established in which the highest position and power was held by the president who was not only responsible of running the government but also was in charge of directing the matters of state. Furthermore, there was no separate individual who was elected as a prime minister of the state; hence, the duties were performed by the president himself.
South African parliament was based on houses, amongst which lower house that consisted of representatives of the elected as well as opponent parties had rights to choose the president by voting method. During the first free election of the state, the most popular party of that time namely African National Congress, which was headed by the most prominent revolutionary leader won a majority of votes and formed the government. Moreover, other local party and the one that was initially created by the whites formed the opposition in the parliament.
South Africa was primarily engrossed in economic decline and social discrimination for which the government took grave measures to eliminate them by forming groups of government-appointed individuals who were assigned to work in collaboration with the locals for the betterment of their living status. Similarly, government also aimed to elevate South Africans in all facets of life so that they can incorporate themselves in the globalized world and perform well.
As the years passed by, the party formed by the whites during colonial period began to lose its popularity, as it often withdrew itself from any unified pact that it formed with other parties. Another local party gained massive recognition after the second elections, which formed democratic alliance with the former party of the whites, as it was experiencing a drastic decline. This alliance was successful in gaining support of business and white community. However, the popularity of African National Congress remained high at this point also.
3. South African Economy
The economic situation in South Africa is very much similar to the political situation, which appears to be ambiguous and uncertain. This means that South Africa is a mixed economy that has the access to plentiful resources. The developed industries in South Africa mainly include agricultural, mining, manufacturing, engineering, power-producing and financial sectors. The export of various products such as gold, platinum, wine, fruit and coal also add a significant percentage to the economy and the GDP of the country.
South Africa initially did not have the advantage of hi-tech infrastructure, as the country's infrastructure was archaic and outdated, which constrained the growth of the country. However, in the recent times, the country has experiences a significant growth in terms of its infrastructure. This means that South Africa now has a modern infrastructure and sophisticated communication facilities. Overwhelming economic problems that include poverty, lack of economic empowerment especially amongst the underprivileged groups, and a shortage of public transportation are few of the grave issues that impede the economic growth of the country to a great extent.
Tourism is also one of the key economic sectors of South Africa that has great potential for growth. The tourism industry largely contributes to the economy of the country. Indeed, the government is developing strategies and plans with the core objective to enhance and enlarge the tourism industry of the nation, which can be of more valuable contribution to the gross domestic product of the country. Besides, the government also aims to provide development to the people so that more sophisticated jobs can be initiated for the locals as well as embed traditions of travel amongst the general public. The natural environment is also one of the value added feature of the tourism recourses.
The inflation rate of South Africa over the years has demonstrated an increasing pattern due to various factors. This is usually due to the increasing rates of the foreign currencies and increase in the GDP per capita on annual basis.
4. Key Macroeconomic Variables
South Africa is a region that demonstrates middle-income and emerging market, which is rich in its supply of natural resources. In other words, South Africa is a productive and industrialized economy, where the Growth Domestic Product (GDP) or the economic growth is expanded in the recent years. Even though, the facts and figures portrayed fall in the country's GDP fell nearly in 2009, but it was recovered in the years 2010 and 2011. The principal source of economy for the country comes from the manufacturing, services, mining, and agriculture industries, which are well developed. Moreover, financial, legal, communications, energy, and transport sectors are also well-developed that adds to the economic value of the country.
While looking at the unemployment rate, the statistical analyses have indicated the fact that more or less 15% of the students are likely to get a job within one year who has completed their studies up to matriculation. However, the majority of the students that almost makes more than 60% of the students remain unemployed after five years. This signifies the fact that a substantial proportion of the South African population is unemployed, which states that the unemployment rate is high to a considerable level.
National estimates of South Africa with reference to the percentage of the population that falls far below the poverty line have revealed apparent results, where almost fifty percent of the total population is below the poverty line. Considering the investments that include the total business spending on fixed assets, such as factories, machinery, equipment, and inventories of raw materials, the records have exposed that more or less 15% of the total GDP is spent on the investments within the region.
5. Justice/Judiciary System of the Country
South Africa has a unified and cohesive judicial system. The judiciary system of South Africa is an amalgamation of judges and magistrates, who are present in the court of the country. The judiciary is one of the branches of the government that works on an independent basis. The judiciary is basically dependent upon the constitution as well as the laws of the country. They are key responsible body for interpreting the laws of South Africa, which is constituted by the legislature in the enactment.
Rules, regulations and policies are defined by the Integrated Justice System (IJS) of the country, with the primary aim to elevate the effectiveness and efficiency of the criminal justice process. In order to achieve the aims, the justice system created high probability for successful investigations, prosecution, punishment for priority crimes and so forth.
The Supreme Court of South Africa is one of the superior courts of law, which is made up of various divisions based on local and provincial basis. The provincial and local divisions of the Supreme Court have specific authorities that are based over the geographical locations. Appellate Division is considered to be the highest division of the… [END OF PREVIEW]
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Insights into functional-group-tolerant polymerization catalysis with phosphine-sulfonamide palladium (II) complexes
AuthorsJian, Zhongbao
Falivene, Laura
Wucher, Philipp
Roesle, Philipp
Caporaso, Lucia
Cavallo, Luigi
Gçttker-Schnetmann, Inigo
Mecking, Stefan
KAUST DepartmentKAUST Catalysis Center (KCC)
Physical Sciences and Engineering (PSE) Division
Chemical Science Program
Permanent link to this recordhttp://hdl.handle.net/10754/563915
MetadataShow full item record
AbstractTwo series of cationic palladium(II) methyl complexes {[(2-MeOC6H4)2PC6H4SO2NHC6H3(2,6-R1,R2)]PdMe}2[A]2 (X1+-A: R1=R2=H: H1+-A; R1=R2=CH(CH3)2: DIPP1+-A; R1=H, R2=CF3: CF31+-A; A=BF4 or SbF6) and neutral palladium(II) methyl complexes {[(2-MeOC6H4)2PC6H4SO2NC6H3(2,6-R1,R2)]PdMe(L)} (X1-acetone: L=acetone; X1-dmso: L=dimethyl sulfoxide; X1-pyr: L=pyridine) chelated by a phosphine-sulfonamide were synthesized and fully characterized. Stoichiometric insertion of methyl acrylate (MA) into all complexes revealed that a 2,1 regiochemistry dominates in the first insertion of MA. Subsequently, for the cationic complexes X1+-A, β-H elimination from the 2,1-insertion product X2+-AMA-2,1 is overwhelmingly favored over a second MA insertion to yield two major products X4+-AMA-1,2 and X5+-AMA. By contrast, for the weakly coordinated neutral complexes X1-acetone and X1-dmso, a second MA insertion of the 2,1-insertion product X2MA-2,1 is faster than β-H elimination and gives X3MA as major products. For the strongly coordinated neutral complexes X1-pyr, no second MA insertion and no β-H elimination (except for DIPP2-pyrMA-2,1) were observed for the 2,1-insertion product X2-pyrMA-2,1. The cationic complexes X1+-A exhibited high catalytic activities for ethylene dimerization, affording butenes (C4) with a high selectivity of up to 97.7% (1-butene: 99.3%). Differences in activities and selectivities suggest that the phosphine-sulfonamide ligands remain coordinated to the metal center in a bidentate fashion in the catalytically active species. By comparison, the neutral complexes X1-acetone, X1-dmso, and X1-pyr showed very low activity towards ethylene to give traces of oligomers. DFT analyses taking into account the two possible coordination modes (O or N) of the sulfonamide ligand for the cationic system CF31+ suggested that the experimentally observed high activity in ethylene dimerization is the result of a facile first ethylene insertion into the O-coordinated PdMe isomer and a subsequent favored β-H elimination from the N-coordinated isomer formed by isomerization of the insertion product. Steric hindrance by the N-aryl substituent in the neutral systems CF31 and H1 appears to contribute significantly to a higher barrier of insertion, which accounts for the experimentally observed low activity towards ethylene oligomerization. Coordination switch: Analysis and comparison of the reactivity of new neutral and cationic PdII phosphine-sulfonamide complexes towards olefins in stoichiometric insertion and pressure-reactor experiments, complemented by DFT studies, elucidated the decisive factors for their catalytic behavior, including N versus O coordination modes (see figure).
SponsorsZ.J. is grateful to the Alexander von Humboldt Foundation for a postdoctoral research fellowship and to the University of Konstanz for a EU FP7 Marie Curie Zukunftskolleg Incoming Fellowship Programme (grant no. 291784).
JournalChemistry - A European Journal


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The Alaska Department of Fish and Game (ADF&G) is accepting public comment from January 1-January 30, 2018 on its 2018 Statewide Stocking Plan for Sport Fisheries.
Increased fishing pressure on Susitna River tributaries led ADF&G to begin stocking king salmon in Deception Creek, a Willow Creek tributary, in 1983 as a supplement to Willow's wild run of kings. The first significant return of stockers showed up in 1988.
ADF&G states that, "Harvest opportunities for Chinook salmon on Southcentral Alaska's road system are limited and already at or near saturation. Many Northern Cook Inlet (NCI) streams have populations of wild Chinook salmon that are too small to sustain a recreational fishery, while others have been impacted by urbanization and only produce small numbers of fish. Increased fishing effort and reduced natural production during the late 1980's and early 1990's have led to restrictions on several popular NCI Chinook salmon fisheries resulting in decreased Chinook salmon fishing participation. The primary purpose of this program is to maintain or increase Chinook salmon fishing opportunities in NCI while reducing angling pressure on the areas wild stocks. Enhancement is a tool we can use to potentially create more angling opportunity. We are attempting to supplement Willow Creek's natural run of Chinook salmon with hatchery fish without significantly altering historical Chinook salmon age and sex compositions."
ADF&G's objectives for Willow Creek are:
1. Produce a return of an additional 4,000 adult Chinook salmon to Willow Creek, while assuring that about 1,750 Chinook salmon spawn naturally, as assessed by aerial survey.
2. Generate 10,000 angler-days of fishing opportunity during the three 3-day weekends directed at stocked Chinook salmon in Willow Creek.
View the plan in it's entirety here.
Submit public comments to Andrew Garry by email email@example.com.


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Sachem North's Jonathan Lauer sets 2017 national mark in steeplechase
Jonathan Lauer didn't think he deserved the accolades that followed his performance in the 3,000-meter steeplechase, but the clock doesn't lie.
The Sachem North senior used a shockingly powerful kick from the bell of the final lap to outlast Smithtown West's Michael Grabowski in 9 minutes, 14.14 seconds at the Suffolk County track and field state qualifiers Saturday in Port Jefferson. Lauer's time bested Grabowski's for the county record and is the fastest time in the country this season, bettering the previous mark of 9:17.99.
"I feel like I'm just a Long Island kid, and I can't even really compare myself to the rest of the country because they're so much better than I am," Lauer said.
The race proved otherwise. He stayed on Grabowski's shoulder and somehow summoned the strength to create space with 400 meters remaining in a grueling race that includes jumping over barriers and pushing through a water pit.
"I was nervous as hell, honestly," Lauer said. "I got sick before the race just out of pure nerves because I knew Grabowski always puts up an outstanding fight."
Many times a runner comes in with a plan, waiting for the right moment to strike. This race wasn't that, but rather a test of pure stamina.
"With 350 to go, I felt it under my legs," Lauer said. "You can't explain the feeling. Your mind takes over your body and you focus on that finish line no matter what. You do whatever it takes to get to the finish line."
He'll head to the state championships in Endicott this coming weekend with expectations, but before then, he'll have to get used to being at the top of the national leader board.
"That's sweet," he said.
Floyd's Nigel Greene found the space he needed in the last 10 meters of the 100 to win in 10.76. He leaned his chest across the finish with stretched arms, not wanting to put anything to chance after not qualifying for states by three-hundreths of a second last year.
"I did get a slow start," he said. "A little nervous because this is big-time stuff, but I used my effort at the end and now I'm ready to go to states."
He went on to set a meet record in the 200 in 21.44.
Smithtown East's Daniel Claxton set a county record in the high jump with a 7-foot, 1 3⁄4-inch leap. Huntington's Kyree Johnson won the 400 in 46.68, the fastest time in the state this season.
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text: This is not the best news heading in cold and flu season. Echinacea, the popular herbal remedy, does not really help anyone get better any sooner. The study of more than 700 adults and children showed that only a few hours was shaved off of a week-long cold and slightly milder symptoms—which could have happened by chance. Echinacea is one of the top cold and flu products in terms of sales, although it has its critics. University of Wisconsin's Dr. Bruce Barrett used participants between the ages of 12 and 80 and gave them either the herb, a dummy pill, or nothing at all and compared results. The ones who took echinacea had shorter and slightly less severe colds, but the researchers said echinacea's benefits did not justify its cost and the trouble of taking it.


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admin / May 21, 2019
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How Much Does a Website Design Cost in South Africa? What is the cost of creating a website in South Africa? Website design prices in South Africa varies from R500 – R30 000+ for the exact same website depending on the skill and experience a designer has, and programming language/s or content management systems (CMS) they use. When you're thinking of getting a website design done for.
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Top Picks at the Toronto International Film Festival 2019
We are very excited for the new line-up of films at the Toronto International Film Festival 2019.
So we've chosen our top 6 Asian-related films we think you might enjoy and why!
All images courtesy of TIFF.net
Saturday Fiction
Lou Ye
Synopsis via TIFF: In 1941, a Chinese actress returns to Japanese-occupied Shanghai, ostensibly to star in a play, but her true motivations become complicated as she learns of the imminent Pearl Harbor attack and struggles to differentiate friend from undercover enemy. 126 mins
Reasons You Might Like it:
The world-renowned Chinese-born Singaporean actress, Gong Li, is the lead star in the film. You may remember her from Memoirs of a Geisha (2005) and Curse of the Golden Flower (2006).
Game of Thrones actor and theatre actor Thomas Wlaschiha is her opposite.
It was selected to compete at the 76th Venice International Film Festival.
The director Lou Ye has worked with stars such as Zhang Ziyi and has a record for complex narratives.
No Crying at
Dinner Table
Carol Nguyen
Synopsis via TIFF: Filmmaker Carol Nguyen interviews her own family to craft an emotionally complex and meticulously composed portrait of intergenerational trauma, grief, and secrets in this cathartic documentary about things left unsaid. 15 minutes.
Reasons You Might Like it:
You like complex family dramas but can only take small doses in film.
You want to see something cinematic that speaks to the Asian diaspora experience in Canada.
Carol Nguyen is a Sundance Ignite Fellow 2018 and her work has been showcased in various film festivals in North America and she is only 21.
Wet Season
Anthony Chen
Synopsis via TIFF: A teacher and student at a Singapore high school form a special, self-affirming bond in writer-director Anthony Chen's (Ilo Ilo) highly anticipated second feature. 103 mins.
Reasons You Might Like it:
The director's first feature film won the coveted Camera d'Or at the Cannes Film Festival, which can only be won by a director's first film.
Anthony Chen also received four Golden Horse Awards in Asia, including Best New Director.
This film is nominated for a TIFF Platform Prize and Chen is known for delivering meaningful pieces.
A Sun
Chung Mong-Hong
Synopsis via TIFF: A family of four fractures under the weight of unmet expectations, unexpected tragedy, and uncompromising pride, in the latest from Taiwanese maverick Chung Mong-Hong (Godspeed). 155 mins.
Reasons You Might Like it:
One of the lead stars from Taiwan, Greg Han, debuted in a Jay Chou music video (2003) to start his career and has appeared in the 2019 Netflix Series, Nowhere Man.
The director, also known as Nagao Nakashima, won the coveted Golden Horse Best Cinematography Award in 2013.
Chung has produced psychological horror films before and we expect to see more!
No. 7 Cherry Lane
Synopsis via TIFF: Set in the politically charged Hong Kong of the 1960s, iconic Chinese director Yonfan's animation debut is an atmospheric story of an English literature student who enters into a love triangle with the woman he is tutoring and her middle-aged mother. 125 mins.
Reasons You Might Like it:
You enjoy animated features in general. (This is one of the handful of animated films as part of the TIFF Festival line up this year!)
The daughter is voiced by Zhao Wei (Vicky Zhao), the popular Chinese actress from The Return of the Pearl Princess (1999).
Director Yonfan has worked with Maggie Cheung, Chow Yun-fat, and you may remember him as the mastermind behind Bishonen (美少年の戀, 1998) with Shu Qi, Stephen Fung, and Daniel Wu.
The Wild Goose Lake
Diao Yinan
Synopsis via TIFF: A wounded gangster recounts the bloody story of why he is on the run to a sex worker he's not sure he can trust, in Diao Yinan's ultra-violent, noir crime thriller. 113 minutes.
Reasons You Might Like it:
You like thrillers and crime.
The lead actors are crowd favourites: The Disguiser's Hu Ge (Hugh Hu) is the male lead, while Black Coal, Thin Ice (2014) and Girlfriend/Boyfriend (2012)'s Gwei Lun-mei is the female lead.
The film was selected to compete for the highest prize in the 2019 Cannes Film Festival: the Palme d'Or, although it lost to another Asian film, Parasite (2019).
The film is set in Wuhan with various dialects being spoken throughout the film.


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[ ĕks văk′yōō-ō ]
A hydrocephalic condition resulting from the loss or atrophy of brain tissue.
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A woman whose drug dealing was uncovered during an investigation related to a record 500kg meth bust in 2016 has been jailed for five years and five months.
Arna Iwi Odette Smith was sentenced in the Auckland High Court on six charges of possessing methamphetamine for supply and one representative charge of supplying methamphetamine.
Smith supplied more than a quarter of a kilogram of methamphetamine in the last quarter of 2016. She pleaded guilty in May 2017, five and half months after she was charged.
Justice Mathew Downs gave Smith discounts on a starting point of seven and a half years for a guilty plea, the impact on her four children and attempts at rehabilitation.
Justice Downs noted that Smith used methamphetamine herself, and had begun - but not finished - a rehabilitation programme.
"You describe using methamphetamine at least four or five times a week. Clearly, you have, or at least had, a drug problem."
"On 2 June 2017, another judge granted you bail so you could complete a residential rehabilitation programme.
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and associated programme. You were remanded in custody on 7 November 2017. The judge who did so told you, 'you blew it'."
"You sought bail again on 9 February 2018. Bail was declined: there was insufficient confidence you would not revert to your habits."
Smith's offences were discovered during investigations related to a 500kg methamphetamine bust in the Far North in June 2016.
A number of people were found to be involved in importation of the methamphetamine, including one who was sentenced to 24 years in prison.


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About Anthony
My wife won't let me get a dog.
I grew up with a Golden Retriever and fostered Boxer-Shepherd mix puppies for a summer while in college. I enjoy running, walking, throwing a frisbee, and playing catch/fetch with dogs. In addition, I love training puppies and providing fun activities for dogs of all ages to do. A few friends have hired me in the past to help train their puppies and to even re-train their rambunctious dogs. I recently dog-sat for a week for ...
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If the dog has any issues with strangers, or any aggressive behaviors


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Call the Shop 7 days a week
This Caper has a 3/16" thick convex ground 1095 blade with nice clear deep stamps and a silver soldered nickel guard. Blade is just a bit over 4" long and about 1 1/4" wide. The hidden tand runs almost to the end of the handle. Walrus artifact Ivory with a few this spacers and red stag with a musk ox butt cap. OAL is about 8". The sheath is a real gem with a real crocodile front and herman oaks 8/9oz leather with stainless steel rivets. Perfect all around field knife and priced to sell. Thanks, Jim


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Nevada pledges to use 80% renewables by 2040
The Nevada Assembly has passed a bill to increase the state's renewable portfolio standard (RPS) to 50 per cent by 2030 with a goal to reach 80 per cent by 2040.
At present, Nevada plans to have 25 per cent of its electricity come from renewable sources by 2025.
The bill passed with a bipartisan vote in the Assembly and had the support of several clean energy advocates, environmental groups and the business community.
Elspeth DiMarzio, Sierra Club's Campaign Representative in Nevada, said: "Increasing our clean energy goals is not a party issue. This is bill for all Nevadans' which is why it passed with bipartisan support. Nevada's leaders are serious about making the state a clean energy leader.
"We have so much clean energy potential and this bill taps into that to create jobs, increase energy security, and protect our air and water," she added.
Click here to view roles that are currently available across the Renewables sector.
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SAMPLE MENU - Prices and details subject to change
- Freshly made Buttermilk Cranberry Scones / Treacle Brown Scones with jam and butter
- Granola Pots / Fruit compote / Greek yogurt
- Fresh Fruit Pots
- Arbutus Croissants / Pain Au Chocolat
- Jack McCarthy Black pudding and Cheddar / Thyme Frittata served with Roots Kitchen chutney
- Homemade Sausage Rolls
- (Veggie Option available too)
24 hours notice required
Contact us for a quote
- Glazed Bacon
- Harissa Marinated Chicken breast
- Roots rainbow slaw
- Roast Squash, Feta, Coriander and Hazelnut salad
- Lebanese bulgar wheat with Riata
- Mixed leaves and dressing
- Brown Bread and Butter
Sandwiches are filled with home cooked meats and fresh salads on Arbutus bread
(1 full sandwich, half a wrap and a Sweet Treat per person)
SOUP with HOMEMADE BROWN BREAD
Menus will change day to day with salad boxes due to seasons and whats the best local produce available at the time. However pre orders can be arranged with notice.
- Mostly will be consisting of Chicken breast, Fresh tuna , Ham hock or Spiced beef
- Salad, mixed leaves and dressing
Choose 3 items:
- Donna's Chicken Liver Pate on crostini with apricot chutney
- Freshly baked bite sized Cheese scones, Free Range egg and cress Mayo v
- Coated Ardsallagh goats cheese balls rolled in Dukkah seeds and fresh herbs v
- Chicken Caser Skewers
- Sweetcorn Fritter with Smoke Salmon dill creme Fraiche
At Roots Kitchen we have a passion for great food. We aim to source all our ingredients locally because we believe fresh, homegrown food tastes better. We will supply down2earth platters that are functional, good to look at and fully compostable.
Please let us know of any requirements and dietary needs before confirming your menu with us.
Our Suppliers
Eggs - Beechwood Farm BallyRegan Kinsale
Fish - K O'Connell's English Market
Seasonal Veg (lettuce, wild garlic, purple broccoli and kale) - Horizon Farms Kinsale
Veg All Fresh - Last Cork owned Veg Company
Micro Herbs - Green Space
Duhallow Pastrami, Black Pudding, Spiced Beef - Jack McCarthy's Kanturk
Irish Chicken - P O'Connell's
Arbutus Bread
Ham and Bacon - Crowes Farms Dundrum Tipperary


text:
Jordan L. Fischer
Attorney Profile
Top Rated Technology Transactions Attorney in Downingtown, PA
Xpan Law Group LLC
| 342 East Lancaster Avenue, Downingtown, PA 19335
Selected To Rising Stars: 2019
Licensed Since: 2013
Practice Areas:
- Technology Transactions (80%),
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Attorney Profile
Jordan L. Fischer is an attorney providing legal services covering Technology Transactions and E-Discovery.
Jordan Fischer, who practices law in Downingtown, Pennsylvania, was selected to Rising Stars for 2019. This peer designation is awarded only to a select number of accomplished attorneys in each state. The Rising Stars selection process takes into account peer recognition, professional achievement in legal practice, and other cogent factors.
Prior to becoming an attorney, she studied at Drexel University Thomas R. Kline School of Law. She graduated in 2013. After passing the bar exam, she was admitted to legal practice in 2013.
Jordan L. Fischer:
Last Updated: 8/13/2019


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LaserCam-HR II User Manual
3 - 2
USB Cable Connect the USB 2.0 cable to the USB 2.0 connector on the
LaserCam-HR II camera (see Figure 3-1).
Do not connect the USB cable to the computer until instructed
to do so.
LaserCam-HR II will interface through the USB 2.0…
…information about the LaserCam-HRTM camera, refer to the LaserCam-HR User Manual (1126917). For instructions on how to connect additional LaserCam-HR cameras to USB 2.0 PC ports, refer to either the LaserCam-HR User Manual (1126917), or the BeamView-USB software Help file. Unpacking The LaserCam-HR…
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Risk factors: Except for the historical information contained here, many of the matters discussed in this Web site are forward-looking statements, based on expectations at the time they were made, that involve risks and uncertainties that could cause our results to differ materially from those expressed or implied by such statements. These risks are detailed in the "Factors That May Affect Future Results" section of our latest 10-K or 10-Q filing. Coherent assumes no obligation to update these forward-looking statements.
I have read the terms and conditions


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City of the Dead
City of the Dead
City of the Dead is an ambient track composed by Mark Morgan for the original Fallout, released in 1997. It was later re-used in Fallout 2 and Fallout: New Vegas. A remastered version of the track was released on Morgan's Vault Archives album in 2010.
Overview[edit | edit source]
A dark and oppressive track designed to complement the forbidding feel of Necropolis.
Appearances[edit | edit source]
Fallout[edit | edit source]
Fallout 2[edit | edit source]
Fallout: New Vegas[edit | edit source]
- Black Mountain
- Nipton
- Camp Searchlight
- Caesar's Legion territories
Video[edit | edit source]
Notes[edit | edit source]
- "City of the Dead" has a similar composition as "Tassels" by Aphex Twin from his album Selected Ambient Works Volume II but with a the prominent hum of a synthesizer removed.


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Chile and Coconut Green Beans
This is my all-time favorite green bean recipe that takes me back to one of my favorite countries, India. The chiles and cumin provide a warm spice to the dish, and the coconut cools it all down. It's a perfect vegetarian dish, and if you make it for your friends and family, they'll be begging for the recipe.
Ingredients (serves 8):
1 pound fresh green beans, stems trimmed
2 tablespoons coconut oil (or canola oil)
10 dried red chiles, small (Indian red chiles or chiles de árbol)
1 teaspoon cumin seeds (whole)
1 teaspoon black mustard seeds
1/2 cup unsweetened grated coconut
salt and pepper
Method: Heat a pot of water (6 cups) over high heat and bring to a boil. Add 1 tablespoon of salt, and then add the beans. Reduce heat to a simmer and cook for 8 minutes. If beans are very thin, cook for less time. Immediately drain beans into a bowl and run under cold water until they are cooled. Remove beans to a sheet pan lined with paper towels so they can dry (don't need to completely dry).
In a large skillet, heat oil over medium high heat. Add the chiles, cumin seeds, and mustard seeds. When you hear the mustard seeds start to pop add the green beans and stir to coat them in the oil and spices. When they are warm, add the coconut and gently stir. Add salt and pepper, to taste. Transfer to a platter and serve.


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Answer by Shiva Shankar on Aug 1, 2009


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