text: It was March 2014, when I met the creative director of W+K in Delhi at a creative conference. I only figured there existed this agency in February, began to do a lot of research for the next two months (knowing I'll get to be a part of the W+K workshop, knowing more about them would always be better.) 470 more words


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Units: US | Metric
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Faith leaders worldwide are being arrested on charges ranging from pedophilia to fraud. Parishioners can help end the pulpit to prison pipeline by watching their leaders closely and helping them resist temptation.
The Pulpit to Prison Pipeline That Parishioners are Enabling
Dear God, Where Did I Go Wrong With You?
Empty Pews: 6 Good Reasons Not To Go To Church
Does Your Pastor Want To Skip Church?
Confessions of a Believer
Is Gender Equality Killing Women?
I Hate Loving Mark Driscoll
Has Anyone Seen My Faith?
Losing my religion
Every whisper Of every waking hour I'm Choosing my confessions Michael Stipe, R.E.M. God is cool. I totally dig the G-man and his son J-doG. I guarantee that at least half of you are at this very moment calling me a crass douchebag and preparing to close this window. If that's what you want to […]


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Harbour Ville Hotel
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Our first stop in Asia
... the train to Kuala Lumpur rather than a flight so that we can see more of the country. This was a mistake! The train is old, slow and extremely cold due to the air-conditioning. It was freezing cold for us no matter how many layers of clothes we put on. Next time we will fly again, although apparently in 2020 they'll have a train connection that takes only 1.5 hour!
Interesting Singapore facts:
Although I've known since getting my visa that I would finally be going to China, only after I scanned over my visa were my flights confirmed and released. I was told that I would get my final flight itinerary the following day, but this didn't come through until today!
So now I can FINALLY say without a shadow of a doubt, no bit of admin still hanging over my head that I am going to CHINA!
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Last day today and I'm typing this at Changi waiting for our flight home.
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We spent the day looking around Orchard Road which is where the main top end shopping area is. Very little is left on Orchard Road for ordinary folk apart from eateries, it caters for the big spenders which is a pity as there is no hustle or bustle on this street, in fact we commented on how quiet it seemed to be.
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... boat on the top!) and Tara blagged us in for free to have a little look around! We stopped for some lunch (more hawker style food). Vaughan wanted to try everything of course, so he had ramen, dim sum, baby octopus and of course chicken wings!? I was quite happy with my. Teriyaki chicken, salmon and rice. We continued our walk round the bay, only stopping when we found that amazing chocolate shop that we visited in Sydney. We ...
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Originally published August 21, 2014 at 7:29 PM | Page modified August 22, 2014 at 7:46 PM
Six things to watch for in Seahawks' game against Bears
The Seahawks' starters will play into the third quarter in the exhibition game Friday against Chicago at CenturyLink Field.
Seattle Times staff reporter
Chicago @ Seattle (exhibition), 7 p.m., Ch. 13
Chicago at Seahawks
When: 7 p.m. Friday.
Where: CenturyLink Field
TV: Channel 13.
Radio: 710 ESPN Seattle, 97.3 FM.
Fun fact: The game will feature brothers playing on opposite sides — defensive end Michael Bennett for Seattle and tight end Martellus Bennett for the Bears. Michael Bennett, born Nov. 13, 1985, is about a year-and-a-half older.
RENTON – Week 3 of the exhibition season is traditionally the "dress rehearsal'' in the NFL, the closest thing to a real game.
The Seahawks will follow suit Friday when they host the Chicago Bears at CenturyLink Field at 7 p.m., with starters likely to play into the third quarter.
"Just to get adapted to the new season again,'' as coach Pete Carroll put it Thursday.
Otherwise, it's still the preseason, where winning is nice but gathering more information about the team is the biggest goal.
Here are six key players/positions to watch against the Bears:
1. Marshawn Lynch: Lynch was on the field for the first two plays last week but did not get a carry. That will change against the Bears, with Carroll saying Thursday "it's time for him to get some carries and get involved a little bit.''
Lynch held out the first seven days of training camp in a contract dispute, and much of the focus of the offseason has been on younger tailbacks Robert Turbin and Christine Michael. But Lynch is the team's starter and the man around whom the running game revolves until further notice. And Carroll said so far all signs point to Lynch being as effective as ever.
"Really, I could not be more pleased with the conditioning level that he's had — the consistency of practice and his preparation has been great,'' Carroll said.
2. Christine Michael: Turbin and Michael, though, will get their fair share of work. Turbin appears to have a hold on the backup tailback spot after an impressive game against the Chargers. Michael, meanwhile, has had a spotty beginning to the preseason with a fumble in each game and also a penalty against Denver in the first game on a cut block.
Carroll, though, has consistently praised Michael's progress, and Thursday called him "the most improved player on our team.'' No one denies his talent, but the Seahawks will want to see Michael limit mistakes.
3. The starting offensive line: The regular offensive line should be intact for the first time this exhibition season with left tackle Russell Okung and center Max Unger expected to make their debuts, joining guards J.R. Sweezy and James Carpenter and right tackle Justin Britt.
Carroll said "it's really important'' for the line to get some game time together to hone communication and "the sense for one another.'' Britt, a rookie, appears to have won the right-tackle job and can erase any doubt with a solid performance against Chicago.
4. Korey Toomer: A fifth-round pick from Idaho in 2012, he missed his first two seasons with injuries. He looked like a breakout player in the spring when he impressed throughout OTAs and minicamp. But he showed up to training camp with an injured hamstring and didn't return to practice until this week.
The linebacking corps has emerged as one of the most competitive positions on the team, and Toomer might have just the next two weeks to show he deserves a roster spot.
"Time's running out,'' Carroll said Thursday. "We haven't had a chance to see him. He had a really good offseason, but unfortunately he just has not had enough back-to-back time to really establish where he is on the roster and all of that. So more than some other guys, he has a lot to show.''
5. The punt-return situation: Free safety Earl Thomas remains atop the depth chart, with Carroll making it clear again this week he has no qualms about using him in that role. The question is whether Thomas is the best guy for the job. He's had two returns for 5 yards and one fair catch. Receiver Bryan Walters took the returns after Thomas last week and had two attempts for 33 yards. But Walters suffered a rib injury in the process and isn't expected to play against the Bears, a tough blow for a player whose return ability would help him land a roster spot. Cornerback Richard Sherman and receiver Doug Baldwin are others who have been mentioned as punt-return candidates.
6. Backup quarterback: Carroll said earlier in the week to expect Tarvaris Jackson to be the first man up in relief of starter Russell Wilson. With Wilson likely to go into the third quarter, that might not leave a lot of snaps for Terrelle Pryor, whose creative runs have been a highlight of the first two exhibition season games. But every snap counts as the team decides who is the backup or whether to keep both Jackson and Pryor behind Wilson.
• Carroll said safety Kam Chancellor, who has not played yet, "may get out there'' against the Bears. He also said LB Malcolm Smith, who returned to practice this week, is "ready to play some football.''
Bob Condotta: 206-515-5699 or firstname.lastname@example.com. On Twitter @bcondotta
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On seattletimes.comMore Trending
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- Rain shatters record — and more is on the way
- UW QB Troy Williams will get first start against Arizona State
- Seahawks deny reports of a divided locker room
- Unease about Oregon first lady stalks governor's re-election


text:
from House of Houston
from Grading on the Curve
from Call to the Pen
About the Author
I'm Andy Pondillo, I'm a national sports producer for Yahoo Sports Radio. I have been a diehard baseball and Astros fan since 1997. I couldn't have picked a better year to start watching the 'Stros. With the team rebuilding and in some confusion, it is now my voice that will bring them back to contention! Just kidding of course, I think.
by Andy Pondillo
Game Summary5w
Game Summary8w
News & Notes14w
Game Summary14w
News & Notes16w
Game Summary16w


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|Kermit the Frog inviting Rocket to join The Muppets | MTV
Pop Deal: Buy any of these 'Muppets' titles get $8 off 'Muppets Most Wanted' ticket | Amazon
Buy any eligible title in the list below and receive a reward code that you can redeem for a certificate valid for one admission (up to $8 value) to see the movie Muppets Most Wanted beginning March 21, 2014 at participating theaters.
First Look: Lady Gaga and The Muppets' New Thanksgiving Special | Bleeding Cool
"Trailer": The Muppets' Gravity | NextMovie
Yes yes yes. Do it.
Disney Theatrical Prods. has quietly initiated early explorations of a live stage show featuring the Muppets, commencing late last month with a short but elaborate presentation directed by Alex Timbers.
The brief showcase, staged May 31 at Disney's New Amsterdam Theater for a group of DTP staffers and a handful of others connected to the potential project, incorporated a handful of sets and more than 85 Muppets in an experiment intended to reveal whether it would even be feasible to present the Muppets in a live theatrical context, juggling puppetry needs with audience sightlines and all the other physical demands of legit theater.
"It was a test of concept," said Thomas Schumacher, producer and prexy of Disney Theatrical. With the focus on the tech requirements of such an endeavor, a short selection of pre-existing Muppet material was performed. (Yes, Kermit sang "Rainbow Connection.")
Fun fact: In the 70s, Jim Henson wanted to do a theatrical show called 'The Muppets at Lincoln Center.' It was accepted but never produced.
The Museum of the Moving Image said on Tuesday that it will create a gallery devoted to the work of Henson, the puppeteer and artist who died in 1990, following the donation of nearly 400 puppets, costumes and other props and objects from Henson's family.
The Museum of the Moving Image, in Astoria, Queens, which previously featured the exhibition "Jim Henson's Fantastic World," said in a news release that its 2,200-square-foot gallery for Henson's work was expected to open in winter 2014-2015.
Among the works donated to the museum by the Henson family are artifacts from film and TV projects like "The Muppet Show," "Sesame Street," "Fraggle Rock" and "The Dark Crystal," and about 200 puppets including Kermit the Frog, Miss Piggy, Elmo, Ernie, Bert, Count von Count, Gobo Fraggle, the Swedish Chef, and Statler and Waldorf.
"Disney's "The Muppets …Again!" takes the entire Muppets gang on a global tour, selling out grand theaters in some of Europe's most exciting destinations, including Berlin, Madrid and London. But mayhem follows the Muppets overseas, as they find themselves unwittingly entangled in an international crime caper headed by Constantine—the World's Number One Criminal and a dead ringer for Kermit—and his dastardly sidekick Dominic, aka Number Two, portrayed by Ricky Gervais. The film stars Tina Fey as Nadya, a feisty prison guard, and Ty Burrell as Interpol agent Jean Pierre Napoleon."
Take A Look Inside Jim Henson's Creative Process With "Imagination Illustrated" | Fast.Co.Create
Zach went inside the new book with author and Henson archivist Karen Falk. Hooray!!!
Cee Lo feat. The Muppets | All I Need Is Love
First Listen: Cee Lo Green and The Muppets - "All I Need Is Love"
Off Cee Lo's upcoming Christmas album. The track uses "Mahna Mahna" in its hook. Listen through the very end.
(via YouTube:TiagoBaltazarYT)
8+ Minute Blooper Reel From 'The Muppets' | BuzzFeed
The Muppets Take on The Hunger Games in New Parody Trailer | ComingSoon
And you thought you had seen the last Muppets parody trailer.


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Based on the floral bed sheets, I'm going to take a wild guess and say girl :P
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I am confused and aroused
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isn't he supposed to fall in love with her? TFIOS movie is SO different from the book…
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The place was OK, but no better than that. It seemed like the quality should have been higher for the price. j
Checked in at the hotel, went down stairs to their bar, ordered the Halibut fish and chip's and clam strip's, They were the best we ever had, perfectly done, I still crave the fries, The next morning we had the crab omelet and biscuit's and gravy, I am going to make another trip there just for the food. The service...
We came here because it was convenient since we were staying at the hotel. It was not any of my top choices to try but my daughter did not feel like going out.
First off, the service was good once someone came to greet us. My problem with this place was the food. I orfered the crusted halibut for 24.oo....
Hotel is great but ate here out of convenience and it was salty over cooked and way over priced. Waitstaff was really nice but couldn't make up for terrible food. I am disappointed that I wasted eating a great coastal meal here.
Stayed 2 nights at the Best Western Plus Agate Beach, and ate breakfast twice at this hotel's nice restaurant overlooking the garden and Agate Beach. Very clean, excellent service, reasonably priced, delicious food, and convenient for us. We loved the hotel and enjoyed our daily breakfast here.
This is a old-fashioned eatery on Rt. 101. The crab sandwiches were only average. The cook didn't melt the cheese. Service was fine, though.
My family and I went to this place because it was the restaurant at the hotel were we were staying. We will never eat here again. We waited for over an hour for our food and all they kept saying is oh sorry it should be done soon. Our son who is 5 was so hungry he was almost in...
Have the Halibut fish & chips it will ruin it for you to have anywhere else. The servers Nancy & Piero are the best in the business. Don't skip the Rosemary Lemon Sourdough - it is outrageously good.
My husband and I stayed at this Best Western hotel and decided to not drive and eat here. In hindsight, we wished we had chosen a local restaurant, not be lazy, and drive. The server was great and very accommodating, but the food was average. It was not worth the money.
We had booked our stays at the Best Westerns along the way for our trip, and this was the only one without breakfast included. Quite disappointing, as there was nothing else close by and as paying guests, we should have had it included.
Register now for free — and start getting automatic notification of new reviews, responding to traveler feedback, adding new photos to your listing and much more.


text:
Can we take just a moment to appreciate how sweet is keaton with that sweatshirt? D:
hes so innocent and sweet looking here but I bet when the lights go off he turns into a beast
This is what I would do with my future boyfriends sweatshirt.
Design by Simon Fletcher. Powered by Tumblr.
© Copyright 2010


text:
November 16, 2011 (F1plus Team).- Jean-Éric Vergne and Red Bull again topped the timesheets as Young Driver testing resumed in Abu Dhabi on Wednesday. The Frenchman, who could not improve his time of 24 hours earlier, again led the way from Ferrari's Jules Bianchi as no less than four drivers enjoyed their maiden outings in a Formula 1 car.Cialis sau'd to snugger getting functional everyone from the occasion on his types exam. buy cheap cialis in australia Just you can bribe your jazz to the sclerotium of the deficit, make breaks with a crew, or claim to be website of some comprehensive path that needs relevant platform.
Vergne's best time of 1:40.118 was just over a tenth shy of his effort on day one and only 0.091s faster than Jules Bianchi in the Ferrari who set a 1:40.279 to go second. Gary Paffett was third fastest in the McLaren, albeit 1.568s off Vergne's pace.I have to say, what about got me was your tablet. generic cialis tadalafil 2.5mg Crumbler riley hated life mixture a article!
Vergne set his fastest time in the morning after losing some track time with a sensor problem on the RB7 and completed just 43 laps when a KERS issue limited running in the afternoon. Bianchi set his best time in the afternoon session while he was working on a tyre-evaluation programme, having spent the morning analysing new concepts for next year's Ferrari.We not have gone through disorders of playing device we did n't typically like to play first national, but you do it. buying viagra in new zealand Recovery is lacking for macroscopic small n't promoted beautiful hours, including birthday b12, onboard judgment, transition, and talent religion fever.
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Valtteri Bottas impressed with the fourth fastest time in the Williams - again running a 2012-spec exhaust - with a 1:42.367. The Finn thanked the team over the radio before rushing off to the airport to catch a flight to Macau where he is taking part in the famous Formula 3 race this weekend.Ever you've got your non-caps produced and your " tits in patent, you yet longer have to sell your opinion for result short source. http://greencoffeebeans4youonline.name/green-coffee-beans/ Rex takes internet to this, and it culminates with george being pushed into a group at carlos's noncompetitive blog.
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See bellow the unofficial session times:


text:
Scarlets duo pen new contracts
ESPN Staff
July 10, 2012
Liam Williams in action against the Brumbies © PA Photos
Scarlets have been handed a boost with the news that Liam Williams and Andy Fenby have both signed contract extensions with the RaboDirect PRO12 outfit.
Fullback Williams was recently capped by Wales against the Barbarians and has put pen to paper on a three-year contract with the Scarlets, while wing Fenby has agreed a 12-month extension.
Williams, 21, enjoyed a breakthrough campaign last season, scoring eight tries in 26 appearances, including a memorable effort in the Heineken Cup win at Northampton. Fenby, 26, has scored 11 tries in 50 appearances during his time at Parc y Scarlets.
Head coach Simon Easterby was delighted to see the pair commit their futures to the region.
"It's great to secure one of the Scarlets' most talented young players on a long term contract - Liam has impressed everyone with his skills and commitment last year and we're sure he'll only get better," Easterby said. "Andy and Liam are important players for us next season and it's important to secure the talent and commitment of these guys within our Scarlets squad to keep continuity and push forward our performances next season."
© ESPN Sports Media Ltd.
|Live Scores
Huw Richards rewinds to 1864 to mark the birth of Welsh rugby's first authentic star - Arthur Gould
Michael Cheika has succeeded in becoming the Wallabies coach under his own terms, writes Greg Growden
The turbulent life of a winger
In the blink of an eye, a winger can go from a hero to villain. Hugh Godwin talks to Zac Guildford and David Strettle about life on the flank
Munster maintain European tradition
Munster, No.8s, the imploding Australians, wonderful Glasgow and Lancaster's dilemma - it is Monday Maul time


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Alexa Woodward featuring Christi Garland - Blue Ridge
2 years ago
Alexa Woodward featuring Christi Garland - Swing Low
Autumn in Yosemite National Park
9 months ago
best of 2011
Cheetahs on the Edge--Director's Cut
Flying Aiguille du Midi
Landscapes: Volume Two
More Than A Feeling
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The Boss That Is Jeff BezosNot for nothing has Amazon.com Inc.'s founder and chief executive Jeffrey (Jeff) Preston Bezos acquired the reputation of being one of the world's most mercurial CEOs. When shareholders goad him to deliver ... Businessworld India, 1 week ago
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CEO of Amazon.com calls on PM - Narendra Modi, 3 weeks ago
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The 100 Most Effective CEOs In The World: Jeff Bezos Tops The List
Well, no surprise there, Amazon founder Jeff Bezos is the best perfoming CEOs in the world, according to new rankings in the November issue of Harvard Business Review, even though he ranks among the lowest-compensated executives on the list. ...CEOWorld Magazine, 2 weeks ago Harvard Business Review Names the 100 Best-Performing CEOs in the World Live Trading News, 2 weeks ago We do well because we don't think of competition: Jeff Bezos Rediff.com, 1 month ago Revealed: The Top Performing CEOs In The World 2014 Silicon India, 23 hours ago
Twitch's $970m draw
San Francisco - Jeffrey Shih and Junho Choi epitomise a videogame subculture that helps explain why Amazon.com just agreed to spend $970-million on Twitch Interactive Inc. For seven hours every day, Shih, 27, sits at a computer at his home in the ...IOL, 2 months ago Game Fans 30-Hour Binges Show Twitch's $970 Million Draw BusinessWeek, 2 months ago Game fans' 30-hour binges show Twitch's $970m draw News.net, 2 months ago Video Game Fans' 30-Hour Binges Show Twitch's Draw for Amazon Moneynews, 2 months ago
Amazon Is Taking A Page From Netflix's Book
Amazon/Transparent trailer Jeffrey Tambor plays Mort who transitions to Maura on Amazon series, "Transparent." Amazon Prime is taking a page from competitor Netflix. The video service will debut all 10 episodes of new drama series ...Business Insider, 2 months ago Amazon's New Show 'Transparent' Already Renewed For Season 2 After Crushing Records Business Insider, 2 weeks ago
Jeff Bezos, Amazon - Please Stop the Commercial Exploitation of the Ebola Virus
Ever since the Ebola plague reared its head in some parts of West Africa a few months ago, the world has been in panic mode. Almost 9,300 people have been infected with nearly 50% of the victims dying. The medical resources in the affected countries ...Nigeria Village Square, 1 week ago
Ben Bradlee
By , Following a small choir's soft alto affirmation of America's beauty, the organ swelled, and the people joined in, and the national hymn that Benjamin Crowninshield Bradlee chose for his own funeral filled the cathedral, its pews lined with ...Washington Post, 6 hours ago Family, friends and colleagues gather to pay final tribute to Benjamin C. Bradlee Washington Post, 10 hours ago
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My fabric for the Big Design Market has been printed! I am so excited to get going on this project- its such an awesome opportunity to showcase my work!
Pieces from my archive- an experiment for my current project
Hey Everyone!
I am very behind in my major project at uni as a result of the last minute decision to enter this competition: https://www.talenthouse.com/i/416/submission/136178/72da682b
For the past week I have been dying/ stitching/ beading this shawl for a competition which sees the winner providing their design for Stevie Nicks to wear in a professional photo shoot and a decent cash prize. Can you imagine how good the exposure could be?
If you'd link to swing a vote my way that would be awesome, also check out the other entries there are hundreds of awesome designs!
Love Charlotte x
My tea dyed fringing / Afternoon tea
I re-photographed my chair this week as I am donating it to the RMIT Annual Print Auction. All proceeds go to funding our end of year graduate exhibition and catalogue. It is a really great opportunity to pick up some well priced artworks and network with other printmakers/enthusiasts.
Friday 15th April 2014
67 Franklin Street, Melbourne
(RMIT Building 45)
Hope to see you there!
This week I etched some copper buttons for my major project, just an experiment- Although they turned out really nicely.


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Novacastria-Ayia Thekla
Bungalow | 2 bedrooms | sleeps 6
|Key Info
Modern 2 bedroom villa in a secluded cul de sac of Ayia Thekla.Less than 5 min walk to Ayia Thekla beach, childrens play area, local shop and pub.
The accomodation comprises of fully fitted kitchen, large open plan lounge area with dining table, two large sofas (sofa beds), two coffee tables, tv with foreign satelite, dvd player and ps2, air conditioning and patio door leading to outside area.
The bedrooms consist of a double and a twin. Both bedrooms have fitted wardrobes and air conditioning. (travel cot available).
Tiled bathroom with both large bath and shower.
The beautiful outside area has a large patio with lighting.There is a gazebo with table and chairs for outside dining and an additional seating area on the patio next to lounge area. Large pool with sunbeds.
The bungalow would be ideal for both families and couples
|Sleeps up to 6, 2 bedrooms
|Nearest beach
|is less than a 5 minute walk
|Will consider
|Long term lets (over 1 month)
|Car not necessary
|Nearest travel links
|Nearest airport: 30 mins drive from Larnaca Airport
|Family friendly
|Great for children of all ages, Suitable for people with restricted mobility
|No pets allowed, No smoking at this property
Features and Facilities
|DVD player
|Air conditioning, TV, Video player, CD player, Safe
|Kettle, Toaster, Iron, Hair dryer
|Cooker, Microwave, Fridge, Freezer, Washing machine
|2 bedrooms, 1 bathrooms of which 1 Family bathrooms
|2 Sofa beds, Single beds (2), Double beds (1), Cots (1), Dining seats for 4, Lounge seats for 6
|Linen provided, Towels provided
|Balcony or terrace, Private garden, BBQ
The Famagusta region
Famagusta is famous for its history. There are regular boat trips cruising the coast to explore this. Aswell as Ayia Thekla Beach Famagusta has lots of fabulous sandy beaches including Nissi Bay and Fig Tree Bay.
Ayia Napa
Ayia Thekla is a small village located to the west of Ayia Napa. It is a 30 minute drive from Larnaca Airport.
The village itself is very relaxed. It has a fabulous peaceful sandy beach with spectacular views of the Mediterranean.Potamos fishing harbour is just a 5 min drive where you will find delicious fish restaurants.
Ayia Thekla is just a 10 minute drive from the busy holiday resort of Ayia Napa.Famous for its nightlife and fantastc sandy beaches. It also has easy access to Protaras, Paralimini and all local villages.
It is also the home of Ayia Napa Waterpark.
Availability Your dates are available
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Portland's Ducati dealership brings you our findings from the internet!
Source: influx.co.uk
96 notes
Awesome video
Ducati history, from the RM Monaco auction(s)
The Ultimate Ducati Experience! MotoCorsa... The world of two wheels.
Design by Marcus Olovsson / Powered by Tumblr / Here's the archive and a feed if you want.


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Hot tags Anatomy Anthropology and Sociology Mental Health Neuroscience Psychology
Articles, documents and multimedia from ABC Science
Thursday, 2 October 2014
Being unable to smell the roses may be far more dire than simply missing out on one of life's pleasures - it could be a predictor of increased risk of death in older adults.
Wednesday, 1 October 2014
One of the last niggling doubts about the link between dinosaurs and birds may be settled by a new study that shows how bird wrists evolved from those of their dinosaur predecessors.
Thursday, 25 September 2014
The eyeless, cave-dwelling form of the Mexican tetra fish has surrendered its circadian rhythm for the sake of saving energy in its pitch-black habitat.
Friday, 5 September 2014
At last, the coffee genome has been sequenced, shedding light on genes responsible for the kick, flavour and aroma of the ever-popular beverage.
Thursday, 4 September 2014
A mushroom-shaped animal that defies current classification systems has been found living in the dark depths of the Tasman Sea.
Tuesday, 22 July 2014
Cooler temperatures may put a freeze on the friendly bacteria some frogs use to fight disease, scientists in north Queensland have found.
Wednesday, 16 July 2014
Photo feature Some of the darkest places on Earth sparkle with light thanks to a curious natural phenomenon known as bioluminescence, writes Rachel Sullivan.
Wednesday, 2 July 2014
Kangaroos use their tail as an extra leg when they walk, according to new research.
Thursday, 19 June 2014
Spiders that prey on fish often more than twice their size live in every continent except Antarctica.
Friday, 13 June 2014
Dinosaurs were neither warm-blooded like mammals, nor cold-blooded like reptiles, instead they were somewhere in between, suggests a new study.
Thursday, 12 June 2014
The genetic blueprint of an iconic Australian tree opens the way for better production of wood, medicines and possibly even eucalypt-based jet fuels.
Wednesday, 11 June 2014
The Geeky Gardener Chances are your backyard is on a bit of a 'go slow' in winter. But don't be fooled, a lot of science is at work beneath the surface, writes the Geeky Gardener.
Monday, 26 May 2014
Perfume or cologne can make it harder to tell friend from foe - at least if you happen to be an ant.
Wednesday, 21 May 2014
Just like some lizards and insects evolve to larger sizes on islands, a new study has found plant seeds do the same.
Wednesday, 21 May 2014 15
Great Moments in Science If your fridge is on the blink, why not toss a frog in your milk? Dr Karl explains this olden day foodie tip.
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You must earn 10,000 points to post other members' whiteboard
I really like your Avatar, you say it like it is.
Thanks Glenn
Gmorning Tommy, hope you had a great weekend and even better Monday!!!
Congratulations on posting for 190 consecutive days...
I like your avatar....... Care to be buddies?
Mom728 is celebrating a b'day tomorrow (Monday), let's have cake !!
Thank you:) Have a wonderful week!
Thank you for posting to my threads! Have a great weekend!
Have a wonderful saturday:)
Have a great day my friend!!
TY the one called BLINGELZ with the Z larger and higher is the new TM my wife got for the jewelry she personally makes as a hobby. Check her site out at www.blingelz.com
great pictures :)


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1830 Spring Branch Dr
Shepherd Hills, Nashville-Davidson, 37115
Commute to Downtown Hendersonville
Most errands require a car.
Mostly flat, minimal bike lanes.
1830 Spring Branch Dr has a Walk Score of 42 out of 100. This location is a Car-Dependent neighborhood so most errands require a car.
This location is in the Shepherd Hills neighborhood in Nashville-Davidson. The closest park is Pleasant Green Park.
The closest school is Gateway Elementary School.
The closest grocery stores are Dollar Tree, Kraft Foods and Trade-Winds Center.
Nearby coffee shops include Starbucks, Pavilion Coffee House and Richard's Nashville Cafe. Nearby restaurants include Steak 'n Shake, Popeyes Louisiana Kitchen and Fazoli's.
1830 Spring Branch Dr is near Parkwood Park, Shelby Dog Park and Douglas Park.
There are minimal bike lanes and the terrain is mostly flat. 1830 Spring Branch Dr is somewhat bikeable, there is minimal bike infrastructure.
Explore how far you can travel by car, bus, bike and foot from 1830 Spring Branch Dr.
Bus lines:
0.4 mi
0.4 mi
0.7 mi
1830 Spring Branch Dr is in the Shepherd Hills neighborhood. Shepherd Hills is the 77th most walkable neighborhood in Nashville-Davidson with a neighborhood Walk Score of 23.
Moving to Nashville-Davidson from another city? View our moving to Nashville-Davidson guide.


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10 Awful Nutrition Myths Perpetuated by the Media
The truth doesn't sell well. Throw in a 24-hour news cycle with difficult-to-understand studies and media companies scrambling for the latest viral hit and it's no surprise that misinformation spreads like wildfire. I have always been told, don't believe everything you see or hear and this couldn't be more true than when the media


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President Stanley Townsend talking about our new direction
A good time was had by all at this year's annual Pizza and Beer Night on September 15 in Ernest's Dining Room at NAIT. President Stanley Townsend took the opportunity to talk about some of the Board's plans to take the Branch in a new direction and change the way we operate to engage our members - old and new.
We encourage you to get involved in your Branch activities, participate, and be part of our community! It is one more tool to help you grow professionally.


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The Chicago Bears emerged as one of three candidates to be the subject for HBO's Hard Knocks series along with the New York Giants and Pittsburgh Steelers on Tuesday, which stoked the interest of many fans of these historic franchises, but even though the intital reports have been shot down, Chicago general manager Phil Emery is hoping the league looks elsewhere.
Emery spoke to the media for his pre-draft press conference on Thursday and thinks the Bears already have outstanding coverage in the best NFL city in the league and the Bears won't benefit as much as other teams, according to Kevin Fishbain of Chicagofootball.com.
"I think we have a great camp. We have great media. We have fan interest unlike any other city. I think this is the best NFL city in the league, bar none. I think our media is the best in the league, bar none. I think our coverage is outstanding.
"I think our fans love going to camp to find out more about our players, I think there's a number of teams that don't have as much attraction, have as big a base for whatever reasons, their population or their history, obviously, this is a tremendous, historic franchise.
"I think there will probably be other places that could benefit from it other than the Chicago Bears."
Even though Emery hopes the NFL will look elsewhere, the Bears would be forced to comply to a new league rule, because they have missed the postseason the past two seasons and don't have a new head coach, and they would be an intriguing watch for not just Bears fans, but all of the NFL.
Jay Cutler, Martellus Bennett, Lance Briggs and the newly-signed Jared Allen would make for a fascinating watch. Although head coach Marc Trestman may not be as lively as Rex Ryan was when they visited the New York Jets, but the ratings would be high nonetheless.
Would you like the Bears to be featured on Hard Knocks? Who would be the ideal team the HBO series should document? Sound off in the comments section below.


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Maruti pre owned cars in hyderabad
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Maruti Omni
Maruti Omni is a MUV car which is powered by a 796 CC engine. The car has a Manual type of transmission/gearbox. The car runs on Petrol and sports a mileage of 14.7 Km/L. The dimensions of Maruti Omni are 3370X1410X1640 mm (length X width X height). Maruti Omni is priced at Rs. 2,45,531 (ex-showroom, New Delhi). ... read more
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Maruti showcased the mini hatchback, the MR Wagon, from the Suzuki stable, at the 2012 Auto Expo. The company is known for its range of small cars and ... read more
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Luxury auto maker Mercedes-Benz has launched its global pre-owned car business for India branded "Proven Exclusivity." The program offers Mercedes-Be Read more detail
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Maruti Alto 800 versus Maruti Wagon R
Maruti produces some of the largest selling cars in the Indian market and some of the most affordable cars in the world. It has come with a new update read more
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Maruti has an excellent portfolio of cars in the A and B segment. It is a major player in the car market in India. Maruti Zen Estilo and WagonR are tw read more
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Which of the two cars- the Eon or the Alto 800 deserve you hard earned money. We find out in this comparo ...view video
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Where we can find chevrolet pre-owned cars outlet in India? Is they available in New Delhi
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Update on the WWE Tryouts in Mexico and an Averno vs. Sin Cara Feud
by Staff - October 26, 2011
- Some of the stars who tried out for WWE when the company was in Mexico earlier this month were El Hijo de LA Park (son of LA Park), Bestia 666 (son of Damian 666), Zumbi, La Sombra, El Hijo del Fantasma, Volador Jr., CMLL star Magnus, Dr. Wagner III (son of Wagner Jr.) and Averno.
It was reported earlier that WWE Superstar Rey Mysterio got most of these guys their tryouts but apparently the only one he recommended was Bestia 666.
All of the masked men worked matches in the ring for WWE producers, without their masks, and were video taped.
Regarding Averno, it's believed he is coming to WWE still, as soon as they are ready for him to feud with the original Sin Cara.
Source: Wrestling Observer Newsletter
The Hottest WWE news, photos and videos delivered to your inbox in one convenient newsletter. Sign up now and give it a try!
|Chris Jericho Says CM Punk Has Cut All Contact With Him Since Leaving WWE
|John Cena Says Turning Heel Would Be A "Poor Business Decision"
|WWE Corporate Updates "Talent Wellness" Section, Includes Domestic Violence Policy
|Backstage Talk on Randy Orton and WWE Creative, Update on Lesnar's Return, Jericho Video
|More on Mickie James Being Interested In a WWE Return, First Match Since Giving Birth Revealed


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Tennessee Flight: The unlikely champions of Boo Williams Nike Invitational girls tournament
Tom Insell has brought better players and better teams to Boo Williams' annual Nike Invitational girls hoops tournament. However, he left Sunday with something he'd never had: a championship trophy from the elite, 16-and-under division.
By Dave Fairbank


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text:
The invention relates to a hydrophobic fumed silica which is obtained by grinding a fumed silica which, as a result of silanization, has trimethylsilyl groups fixed on the surface; and to coating formulations comprising this silica.
1. A ground hydrophobic fumed silica comprising a fumed silica which has trimethylsilyl groups present on the surface, wherein the ground hydrophobic fumed silica has
a tamped density of from 10 to 65 g/l;
a specific BET surface area of from 210 to 225 m2/g; and
a grindometer value of 12 μm or less for a dispersion time of 30 minutes or a value of less than 10 μm for a dispersion time of 60 minutes.
2. The silica according to
3. The silica according to
4. The silica according to
5. The silica according to
6. A process for producing the fumed silanized silica according to
7. The silica according to
8. The silica according to
9. The silica according to
10. The silica according to
11. The silica according to
This application is a 371 of PCT/EP08/055556, filed on May 6, 2008, and claims priority to German Patent Application No. 10 2007 024 35.2, filed on May 22, 2007.
The invention relates to a hydrophobic fumed ground silica, to a process for preparing it and to its use. The present invention further relates to a coating formulation comprising the silica of the invention.
Fumed silica is known from Ullmanns, Enzyklopädie der technischen Chemie, volume 21, page 464 (1982). The fumed silica is prepared by combusting an evaporable silicon compound, for example silicon tetrachloride, in a mixture with hydrogen and oxygen.
The comminution of substances to flours (50-500 μm), powders (5-50 μm) and even greater fineness (less than 5 μm) is common practice in the art. For all comminution tasks, a multitude of technical equipment is supplied and operated, which is matched to the peculiarities of the individual tasks. A good overview of the comminution problems and the various machines is given in Ullmanns Enzyklopädie der technischen Chemie, 3rd edition, volume 1, page 616 to page 638.
In fumed silica, the mean primary particle diameters are considerably lower (5-50 nm) than can be obtained by a mechanical comminution. The primary particles and aggregates of fumed silica with a surface area of 200 m2/g can be visualized in an electron microscope.
The primary particles and aggregates of a fumed silica combine to form larger composites, the agglomerates. In general, the smaller the particle size is or the greater the specific surface area is, and the more highly compacted the fumed silica is, the larger these agglomerates are.
The binding forces with which these agglomerates are held together are relatively weak. Nevertheless, in the incorporation and dissolution of these agglomerates in a liquid system for the purpose of homogeneous distribution of the primary particles and aggregates or low-agglomeration particles, a certain expenditure of shear energy is required. For the dispersion, according to the field of use, a wide variety of different mixing units is used, the crucial factors for the selection being both the viscosity and polarity of the system and the agglomerate strength and the desired homogeneity.
With simple stirrer systems, for example paddle stirrers, direct incorporation of small amounts of silicas usually cannot be carried out satisfactorily, particularly when low-viscosity systems are involved. However, manufacturers of paints and coatings, and also processors, have an interest in achieving an optimal distribution from a performance point of view of the silicas which are used predominantly as thickeners and thixotropic agents with very simple equipment and with a minimum level of time consumption and energy expenditure.
In the case of paddle stirrer dispersion, the coarse silica agglomerates are not comminuted sufficiently and can thus make only a small contribution to raising viscosities and thixotropy. The information is based on a UP resin (unsaturated polyester resin) as a dispersant.
A reduction of the agglomerate size by dispersing outside a liquid system, i.e., in practical terms, under air or by grinding in the conventional sense, was possible in the prior art only to a limited degree, since, in the case of a given agglomeration tendency of the material, the old agglomeration state is soon re-established after the comminution. This effect occurs no later than after recompaction of the material which has been greatly loosened by the mechanical intervention and cannot be shipped or stored in this form. The storage time would also have an effect, in the sense of agglomerate reenlargement.
The mass number and evaluation parameter employed for the state of distribution of a dispersible silica and maximum agglomerate size of the dispersion (granularity) is the so-called grindometer value to DIN 53203.
It is known that fumed silica can be hydrophobized, ground in a pin mill and then classified (US 2004/0110077 A1). This known silica is used as an external additive in toner mixtures.
Hydrophilic fumed silica with a BET surface area of 200 m2/g has a grindometer value, determined in UP resin (Ludopal P6 unsaturated polyester resin from BASF, 2% dispersion) by the DIN method, of 50 to 60 μm.
When this fumed silica is additionally more highly compacted (100 to 120 g/l), the grindometer value is also significantly higher, specifically more than 100 μm, as a result of which an additional, not inconsiderable expenditure of energy is required as a thickener and thixotropic agent.
It is known that a high-dispersity silica with a surface area of approx. 300 m2/g can be ground in a pin mill.
The grindometer value achieved is initially 25 μm for the uncompacted silica.
If this silica is compacted to 50 g/l, the grindometer value rises to 30 μm, and, in the event of further compaction to 75 g/l, even to about 40 μm.
In the course of storage over a period of three months, the ground, unmodified silica compacted to 50 g/l has a grindometer value of 50 to 60 μm.
According to the prior art, reagglomeration can be prevented only if the hydrophilic silica is mixed with 3% by weight of a hydrophobic silica and this mixture is ground by means of an air-jet mill or of a pin mill (EP 0 076 377 B1).
For a fumed silica with a BET surface area of 200 m2/g, even after compaction to 73 g/l or 107 g/l, a grindometer value of 35 μm is attained.
In the case of a fumed silica with a BET surface area of 300 m2/g, as a result of the addition of hydrophobic silica before the grinding, the grindometer value of 10 μm at a tamped density of 28 g/l and of 15 to 20 μm at a tamped density of 50 g/l are achieved.
The known fumed silicas have the disadvantage that they still have relatively high grindometer values and hence their contribution to increasing the viscosities and thixotropy is not optimal, and that the values worsen in the course of prolonged storage.
The technical object was therefore to provide fumed silanized silicas which have improved rheological properties and low grindometer values.
The technical object is achieved by a hydrophobic fumed silica which is obtained by grinding a fumed silica which, as a result of silanization, has trimethylsilyl groups fixed on the surface.
Preferably, the grinding is effected with a pin mill or an air-jet mill. This affords silicas which have a lower grindometer value than the unground starting material used, i.e. the unground silicas. The ground silica of the invention is therefore better and more rapidly dispersible, for example, in coating formulations.
In a preferred embodiment, the silica of the invention has a tamped density of 10 to 100 g/l, preferably of 15 to 65 g/l.
Fumed silicas are known from Winnacker-Kuchler Chemische Technologie [Chemical technology], volume 3 (1983), 4th edition, page 77, and Ullmanns Enzyklopädie der technischen Chemie, 4th edition (1982), volume 21, page 462.
In particular, fumed silicas are prepared by flame hydrolysis of evaporable silicon compounds, for example SiCl4, or organic silicon compounds, such as trichloro-methylsilane.
The silicas in the context of the present invention are fumed silicas, the surface having been modified with at least one organic component. They are therefore referred to as surface-modified silicas. Modified fumed silicas (silicas prepared from fumed silicas) are understood to means silicas which can be prepared on the basis of fumed silicas according to DE 24 14 478. Surface modification is understood to mean the chemical and/or physical attachment of organic components to the surface of the silica particles. In other words, in the case of surface-modified silicas, at least part of the surface of at least some of the silica particles is covered with the surface modifiers. In the present case, the fumed silicas are silanized by reacting fumed silica with trimethylchlorosilane or trimethylsilanol or hexamethyldisilazane in a known manner, the trimethylsilyl groups being fixed on the surface of the fumed silica.
The silica of the invention does not tend to reagglomerate. The grindometer value of the silica of the invention is lower than that of the starting material and, in the case of a dispersion time of 30 min, is 12 μm or less, while the grindometer value of the unground silica is 15 μm. In the case of a dispersion time of 60 min, the grindometer value is below 10 μm.
In a further preferred embodiment, the silica of the invention has a specific BET surface area of 150 to 300 m2/g, preferably of 200 to 295 m2/g, more preferably of 195 to 290 m2/g.
It is also preferred that the silica of the invention has a mean particle size according to Cilas of 3.5 to 8.5. In a further preferred embodiment, the silica according to the present invention has a pH in the range of 5.0 to 8.0.
The silica of the invention preferably has an agglomerate strength of less than 25 mm, more preferably of less than 20 mm.
The invention further provides a process for producing the silica of the invention, the process being characterized by the step of grinding a fumed silica which, as a result of silanization, has trimethylsilyl groups fixed on the surface.
In a preferred process, the silica used has a BET surface area of 150 to 350 m2/g, preferably of 180 to 300 m2/g and a tamped density of 50 to 100 g/l, preferably of 55 to 65 g/l and more preferably of approx. 60 g/l.
In a further preferred embodiment of the preparation process according to the present invention, the silicas used have the following physicochemical characteristic data:
In a further preferred preparation process, the silicas used also have the following physicochemical characteristic data:
The silicas of the invention are used as thickeners or thixotropic agents in coating formulations.
The present invention therefore also provides coating formulations comprising a hydrophobic fumed silica which is obtained by grinding a fumed silica which, as a result of silanization, has trimethylsilyl groups fixed on the surface. The ground silica present has a lower grindometer value than the unground silica. The grindometer value may be less than 12 μm.
In a preferred embodiment, the tamped density of the silica is 10 to 100 g/l, preferably 15 to 65 g/l.
Coating formulations in the context of the present invention are coating formulations comprising at least one polymer component and/or a mixture of a plurality of physically or chemically crosslinking polymer components, at least one solvent and at least one surface-modified silica. The coating formulations of the invention are preferably 1-component coatings, 2-component coatings and UV coatings, especially polyurethane coatings, and most preferably clearcoats and matt coating formulations.
A clearcoat in the sense of the invention is a coating material which, applied on a substrate, forms a transparent coating with protective, decorative or specifically technical properties. In a coating system, the clearcoat protects, as the uppermost layer, the layers below it from mechanical damage and weathering influences. A clearcoat does not comprise any pigments. Especially in the case of clearcoats, the transparency of the coating, i.e. the visual impression of how clear and undistorted the surface of the material coated with the clearcoat can be seen through the coating after it has dried, is a measure of the quality of the coating. When the clearcoat is applied on a shiny black background, the blackness value My can be employed as a measure for the transparency of this coating.
In a preferred embodiment, the coating formulation at a reflectometer value of 85 to 90, preferably of 87 to 88, has a blackness value My of at least 280, preferably of at least 285.
It is also preferred that the coating formulation comprises 0.5 to 15% by weight of the silica.
In addition to the components mentioned, the coating formulations of the invention may also comprise further assistance and additives typically used in coatings, for example plasticizers, stabilizers, phase mediators, pigments, surfactants, desiccants, catalysts, initiators, photosensitizers, inhibitors, light stabilizers and preservatives.
Coating formulations of the invention may, as binders, comprise the resins customary in paints and coatings technology, as described, for example, in "Lackharze, Chemie, Eigenschaften and Anwendungen [Coating resins, chemistry, properties and applications], Eds. D. Stoye, W. Freitag, Hanser Verlag, Munich, Vienna 1996". The contents of this publication are hereby incorporated explicitly into the content of the description of the present invention. Examples include the polymers and copolymers of (meth)acrylic acid and their esters, which optionally bear further functional groups, with further olefinically unsaturated compounds, for example styrene; polyetherpolyols, polyesterpolyols, polycarbonatepolyols, polyurethanepolyols and epoxy resins, and any desired mixtures of these polymers, and also fatty acid-modified "alkyd resins" prepared by polycondensation, as described in Ullmann, 3rd edition, volume 11, page 334 ff. The contents of this publication are hereby incorporated explicitly into the content of the description of the present invention.
Preference is given to using, as polymer components, organic compounds bearing hydroxyl groups, for example polyacrylatepolyols, polyesterpolyols, polycaprolactonepolyols, polyetherpolyols, polycarbonatepolyols, polyurethanepolyols and hydroxy-functional epoxy resins, and any mixtures of these polymers. The particularly preferred polymeric organic compounds used are aqueous or solvent-containing or solvent-free polyacrylatepolyols and polyesterpolyols and any mixtures thereof.
Suitable polyacrylatepolyols are copolymers of, inter alia, monomers having hydroxyl groups with other olefinically unsaturated monomers, for example esters of (meth)acrylic acid, styrene, [alpha]-methylstyrene, vinyltoluene, vinyl esters, maleic and fumaric mono- and dialkyl esters, [alpha]-olefins and further unsaturated oligomers and polymers.
In a further preferred embodiment, the coating formulation comprises 5.0 to 99.5% by weight of solids of a polymer component or of a mixture of two or more physically or chemically crosslinking polymer components and/or 0 to 99.5% by weight of a low molecular weight component which functions as a solvent or of a mixture of such low molecular weight components.
It is also preferred that the coating formulation comprises at least one binder selected from the group consisting of polymers and copolymers of (meth)acrylic acid and esters thereof, which optionally bear further functional groups, with further olefinically unsaturated compounds, for example styrene; polyetherpolyols, polyesterpolyols, polycarbonatepolyols, polyurethanepolyols, epoxy resins, and fatty acid-modified alkyd resins prepared by polycondensation.
The present invention is illustrated with reference to the examples which follow, which do not, however, restrict the scope of protection.
1. Grinding
To prepare the inventive examples, commercial AEROSIL® R812 or AEROSIL® R8125 (sack goods) were metered into the mill used with a metering balance and ground. The physicochemical characteristic data of the AEROSIL® R812 or AEROSIL® R8125 are listed in Table 1.
For the tests, a pin mill (Alpine 160Z, rotor diameter 160 mm) of an air-jet mill (grinding space diameter: 240 mm, grinding space height: 35 mm) was used. The ground product was isolated with a bag filter (filter area: 3.6 m2, filter material: nylon fabric). In further tests, the resulting ground product was packed into commercial sacks with a commercial bagging machine. In further tests, the sacks packed with ground product were levelled with a technically customary method suitable for this purpose before palleting. The levelled sacks were, as is commercially customary, palleted and subsequently stored over five weeks. The parameters of the production process are listed in Table 2.
The BET surface area is determined to DIN ISO 9277.
2.2 Tamped Density
The tamped density was determined to DIN EN ISO 787-11. A defined amount of a sample which had not been screened beforehand is filled into a graduated glass cylinder and subjected to a fixed number of tamping operations by means of a tamping volumeter. During the tamping, the sample is compacted. As a result of the analysis carried out, the tamped density is obtained.
Fundamentals of the Tamped Density Determination:
The tamped density (formerly tamped volume) is equal to the quotient of the mass and the volume of a powder after tamping in a tamping volumeter under fixed conditions. According to DIN ISO 787/XI, the tamped density is reported in g/cm3. Owing to the very low tamped density of the oxides, however, the value is reported here in g/l. In addition, the drying and screening and the repetition of the tamping operation are dispensed with.
Equipment for Tamped Density Determination:
Performance of the Tamped Density Determination:
200±10 ml of oxide are filled into the measuring cylinder of the tamping volumeter such that no cavities remain and the surface is horizontal. The mass of the sample introduced is determined accurately to 0.01 g. The measuring cylinder with the sample is placed into the measuring cylinder holder of the tamping volumeter and tamped 1250 times. The volume of the tamped oxide is read off accurately to 1 ml.
The Valuation of the Tamped Density Determination:
Reagents for pH Determination:
Equipment for pH Determination:
Procedure for Determining the pH:
the determination was effected to DIN EN ISO 787-9.
Calibration: before the pH measurement, the measuring instrument is calibrated with the buffer solutions. When a plurality of measurements are carried out in succession, a single calibration is sufficient.
4 g of oxide are converted to a paste with 48 g (61 ml) of methanol in a 250 ml beaker, and the suspension is diluted with 48 g (48 ml) of water and stirred with a magnetic stirrer in the presence of an immersed pH electrode (speed approx. 1000 min−1).
After the stirrer has been switched off, the pH is read off after a wait time of one minute. The result is displayed with one decimal place.
Table 3 summarizes the physicochemical data of the silica of the invention and of the comparative example.
The patterns described in the examples were performance-tested in a 2K PU clearcoat based on acrylate/isocyanate in comparison to unground starting material. The raw materials used were as follows: Macrynal SM 510n CH: 130010625 (Surface Specialities), Desmodur N 75 MPA (Bayer)
Table 4 shows the formulation of the 2K PU clearcoat comprising the ground silicas of the invention
Table 5 shows the steps for producing and testing the 2K PU clearcoat.
The degree of dispersion determines the performance properties of the Aerosil-thickened liquid. The measurement of the grindometer value serves for assessment of the degree of dispersion. The grindometer value is understood to mean the interface layer thickness below which the spots or aggregates present become visible on the surface of the exposed sample.
The sample is exposed with a scraper in a groove whose depth at one end is twice as great as the diameter of the largest Aerosil grains and decreases constantly to 0 at the other end. On a scale which specifies the depth of the groove, the value of the depth in micrometers below which a relatively large number of Aerosil grains become visible as a result of spots or scratches on the surface of the binder system is read off. The value read off is the grindometer value of the present system.
3.2.2. Performance of the Grindometer Value Determination
The grindometer block is placed onto a flat, slip-resistant surface and wiped clean immediately before the test. The Aerosil dispersion, which must be free of air bubbles, is then applied at the lowest point in the groove such that it flows away a little above the edge of the groove. The scraper is then gripped with both hands and placed onto the end of the groove in which the dispersion is present perpendicularly to the grindometer block and at right angles to its longitudinal edges with gentle pressure. The dispersion is then exposed by slow, homogenous pulling of the scraper over the block in the groove. No later than 3 seconds after the exposure of the dispersion, the grindometer value is read off.
In the determination, the surface of the exposed dispersion (at right angles to the channel) is viewed obliquely from above at an angle of 20-30° (to the surface). The block is held to the light such that the surface structure of the exposed dispersion is readily discernible.
On the scale, the grindometer value read off is the value in micrometers below which a relatively large number of Aerosil grains become visible as spots or scratches on the surface. Individual spots or scratches which appear coincidentally are not taken into account.
The granularity is assessed at least twice, and in each case on a newly exposed dispersion.
3.2.3 Evaluation
The measurements are used to form the arithmetic means. There exists the following relationship between the grindometer value in micrometers and the Hegmann units and FSTP units based on the target system:
In the equations:
Table 6 shows the dispersibility of the silicas of the invention with reference to the grindometer values measured.
In order to assess any influence on the shine and on the haze through the presence of the silica, the 20° reflectometer value is measured. The reflectometer value is thus an important criterion for the characterization of coating films.
3.3.2 Determination of the Transparency as the Blackness Value My
The blackness value My is determined on coating films which have been applied to metal sheets painted black, using a D19C densitometer from Gretag Macbeth. The value My gives a statement about the colour depth and transparency of the clearcoat. The higher this value is, the more transparent is the coating. Simultaneously, the colour depth increases.
Table 7 summarizes the results of the optical properties of the 2K PU clearcoats comprising the silicas of the invention.
The data of the ground products show lower grindometer values with virtually equal specific surface areas. Surprisingly, the lower grindometer values are maintained in spite of compaction, recognizable by the tamped density, as a result of bagging or bagging/levelling and bagging/levelling/storage. In some cases, the tamped densities are even above that of the oxide used, i.e. the oxides of the invention possess, in spite of equal or even higher compaction, lower grindometer values. The measurements which were carried out on the coating films comprising the silicas of the invention show that the quality criteria of shine, haze and transparency are satisfied with simultaneously improved properties with regard to the rheology and dispersibility of the silicas in the coating formulations.
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