text:
Buckeye Housekeepers
Choose from 53 housekeepers in Buckeye, AZ! Average rate: $11.75/hr. Join for free today and make sure to share this rate with friends!
Part-time Housekeeper Available — Buckeye, AZ
I am an experienced cleaner available part-time during the week. In addition to keeping my own home of four children for 20+ years, I have cleaned homes individually and as a team for a living. I was ...
5 yrs of exp.
Housekeeper — Buckeye, AZ
Hi, I'm Melody and I am seeking a job for housekeeping. When I used to live in Dallas, I worked for a cleaning company and then decided to have my very own successful cleaning company. I moved out her...
10 yrs of exp.
Experienced Housekeeper — Buckeye, AZ
I have worked in the YMCA and private homes. I've done buffing, mopping, carpet shampooing. I also vacuum, do the dishes, the laundry, clean the toilets, restocking, shower, etc. I have also worked in...
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Buckeye, AZ
I have been in the housekeeping field for 20 years now. I started cleaning houses with my mother when I was a young girl. So when I got older, I had a passion to clean and to help family's with their ...
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Apartments in New York City with - Soaking Tub
A soaking tub adds a touch of luxury to your bathing routine. Unlike traditional bathtubs, soaking tubs are longer and deeper allowing you stretch out and fully submerge your whole body in the comfort of a warm bath so you can soak the stress of the day away. If you can get a place with a soaking tub, grab a book and a glass of wine and lay back for a nice long soak.
The Stanhope
From $10,999,000 to $13,375,000
On request
300 East 64th Street
On request
From $3,000 to $6,600
Gregory Towers
From $1,469,000
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The Bamford
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From $3,950
80 East End Avenue
From $1,200,000
On request

subset: commoncrawl


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Season TWO OFFICIAL TNG Blu-Ray Discussion Thread
View Single Post
September 28 2012, 08:34 PM
Fleet Captain
Location: TrekCore.com
Re: Season TWO OFFICIAL TNG Blu-Ray Discussion Thread
Sho wrote:
Nice interview, one thing in the way of feedback though: I realize you need to pay the bills somehow and that progressive disclosure helps drive clicks, but this (lack of) length was a wee bit above the frustration threshold for me as a reader.
Excuse me?? What a stupid thing to say. We do not pay the bills by getting clicks, we are charged MORE because of bandwidth.
The interview is broken up because it was so long and i dont have the time to put so much out at once... Its a hell of a lot of work and i am one man. You want to minimize your frustration? You try running something as big as this on your own - you have no idea just how much time and effort it takes, completely unpaid for a website which isnt supported by advertizing.
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Heartwarming: What Women Want
- Nick goes to Erin's apartment after he thinks she's going to commit suicide and gives her a better job at the company.
- And another moment, in a bathroom stall adjacent to his daughter, after he's lost his mindreading powers.
- Nick pretending to be gay so he doesn't crush Lola and make her think she's undesirable.
- Nick giving the women at work advice on dealing with their boyfriends. When one woman is writing down what she plans to say, "Either I'm interesting or I'm not." she suddenly asks herself, "What if he says I'm not?" Nick leans over and says, "He won't say you're not. Trust me."
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Beautiful afghans are always a welcome addition to any home and this week Maggie will show us how to knit the Moth Wing afghan designed by Michael Del Veccio. Ellen is up next with the Quantum Granny crochet afghan designed by Carrie Carpenter. Knit square this week is the Scalloped Shell.
Visit the Website: http://www.knitandcrochetnow.com
Episode #304 / Length: 26 minutes
On TV
- Tuesday, September 15th at 5:00 AM on KLRU Create
- Tuesday, September 15th at 11:00 AM on KLRU Create


text:
A judge is allowing former Penn State assistant coach Jerry Sandusky to leave his state prison cell in order to appear next week at a court hearing.
The hearing will address Sandusky's post-sentencing motions. Sandusky maintains his innocence and is pursuing appeals.
Judge John Cleland signed the order Thursday permitting Sandusky to travel next Thursday from the State Correctional Institution at Greene in western Pennsylvania to the hearing at the Centre County Courthouse in Bellefonte in central Pennsylvania. He was convicted in Centre County court in June on 45 counts of child sexual abuse involving 10 boys.
Sandusky will be picked up and transported by Centre County sheriff's deputies.
Authorities have said Sandusky molested victims inside university facilities, area hotels and inside his home.
Judge allows Jerry Sandusky to appear at appeal hearing next week
A judge is allowing former Penn State assistant coach Jerry Sandusky to leave his state prison cell in order to appear next week at a court hearing.
Copyright 2013 WFMZ. The Associated Press contributed to this report. All rights reserved. This material may not be published, broadcast, rewritten or redistributed.
More Pennsylvania Headlines
- Dems outraise GOP in race for the state's high court
- Pennsylvania's budget train wreck unfolded over past year
- Debate swirls as proposed gas pipeline inches forward
- Gov. Wolf imposes state hiring freeze and travel restrictions
- Pennsylvania attorney general charged with 2nd perjury count
- Pennsylvania emergency officials prepare for Joaquin's impact
- NWS confirms EF-1 tornado touched down in Lancaster County
- Impact of Pa. budget impasse: 'It's just heartbreaking'
- Demolition contractor goes on trial in building collapse deaths
- State Supreme Court upholds cop killer's death sentence
- Some Pennsylvania schools hurting as budget battle continues
- Pa. Turnpike to test cashless toll system next year
- Festival of Families in Philadelphia
- Churches from Lehigh Valley head to Philadelphia for pope's historic visit
- Pope Francis inspires thousands in attendance at Independence Hall
- Crowds pack the streets of Philadelphia to catch a glimpse of the pope
- WFMZ's coverage of Pope Francis' visit to Philadelphia
- Philadelphia quiet before papal visit
- Berks K9 unit, others dispatched to Philly for papal visit
- Man gets life term in fatal shooting at hospital
- Suspended license puts AG's re-election bid in jeopardy
- Seminary puts pope-inspired beer on tap for Francis' stay
- Downtown Philadelphia deserted ahead of Pope Francis' visit
- State House passes short-term spending plan
- Kutztown EMS crew chosen to work pope's Mass in Philadelphia
Pennsylvania Sports
- Phantoms win final preseason game
- Jesse Biddle to have Tommy John surgery
- Cousins burns Eagles late as Washington tops Philadelphia
- Kutztown hammers Millersville to go to 2-0 in league play
- Phantoms fall to Hartford in tuneup
- Fordham runs past Lafayette in Patriot League opener
- Hall of Fame coach Bob Hurley visits Berks County
- Moravian, Muhlenberg win at home; Albright goes to 4-0
- Yale too much for Mountain Hawks
- Royals to open training camp Saturday


text:
Wesley College Professor of Chemistry, Dr. Malcolm J. D'Souza, was recently invited to guest edit a special issue of the peer-reviewed International Journal of Molecular Sciences (IJMS), covering solution chemical kinetics. The publication is an open-access (free for readers) journal that provides an advanced forum for chemistry, molecular physics and molecular biology research. Published online (http://www.mdpi.com/journal/ijms) monthly by the Multidisciplinary Digital Publishing Institute,...[more]
Dr. Agashi Nwogbaga, professor of mathematics at Wesley College, was recently selected as one of the editorial board members of the Journal of Mathematics and Statistics. The publication is a peer-reviewed, international journal from the company Science Publications that offers original and valuable research in areas of applied and theoretical mathematics and statistics. As a member of the editorial board, Nwogbaga will review and evaluate manuscripts submitted to the journal. This is an...[more]
Wesley College has been awarded a $1.7 million IDeA Network of Biomedical Research Excellence (INBRE) grant through National Instititutes of Health and National Institute of General Medical Sciences (NIH-NIGMS). The funding, which will be utilized through 2019, will allow Wesley to broaden its programs and support additional Science Technology Engineering and Mathematics (STEM) students. "This funding is directly responsible for Wesley introducing a new minor in informatics – the science of...[more]
More than two dozen Wesley College freshmen teamed with the Food Bank of Delaware on November 24 to provide Thanksgiving food to low-income senior citizens. The project was part of the school's Living Learning Communities program and associate professor Jessica James' Hungry for Change: Food Culture in America seminar, in which freshmen study the relationships between food and socio-economic classes. The food distribution was part of an effort to help those students work with people living in...
As a part of a DE-EPSCoR and DE-INBRE community outreach program, undergraduates from the Wesley College science program participated in an event to inspire students in grades 1 – 8 to think about the elementary principles in chemistry. The event was held at the Independence School in Newark, DE on Nov.1. Nearly 80 volunteers assisted with the demonstrations and experiments for 231 children, as well as their families and troop leaders. The Wesley effort was led by Dr....[more]
Wesley College science, technology, engineering and math (STEM) students Megan Durrant, Jasbir Deol, Catherine Gross, Alora Wilson, Ariel Bilbrough, Dionne Williams, James Welsh, Kyle Frame and John Dougherty presented posters at the 17th Undergraduate Research Symposium in the Chemical and Biological Sciences at the University of Maryland, Baltimore County (UMBC) in Baltimore, Md. on October 25. The symposium is open exclusively to undergraduate students in the STEM areas of biology,...[more]
Dr. Agashi Nwogbaga, Wesley College professor of mathematics, led and mentored Wesley math senior Rebecca Miller in presenting her honors thesis research work, "Math Modeling of the West Africa Ebola Outbreak" at the University of the Sciences in Philadelphia, Pa., on Oct. 25, 2014. Miller was awarded with a Mathematical Association of America (MAA) Certificate of Recognition at the culmination of her presentation. Miller is also a Cannon Scholar under the National Science...[more]
Several Wesley football players and coaches read to students at Fairview Elementary last week as part of the Jumpstart Read for the Record program. The book of choice was "Bunny Cakes," a comical story of sibling bonding and story shenanigans.
Wesley College's music department dazzled a packed house of guests at Wesley Chapel last year with the opera "Suor Angelica." This weekend will see an encore of that production but, this time around, the department will be taking the show on the road for two performances at Epworth United Methodist Church in Rehoboth Beach. Opening night is Oct. 24 with a finale on Oct. 26.
Wesley College Professor of Business Management Dr. Kathleen Jacobs was asked to represent the Delaware Commission for Women by attending the 6th annual Kent County Economic Summit held at the Conference Center at Delaware Tech Terry Campus on September 23. The event was presented in collaboration with the Central Delaware Business and Entrepreneurship Consortium and the topic was "Building a Better Community."The purpose of the Summit was to accelerate economic progress in Kent County,...[more]


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With Rhode Island, 50 Million Americans Will Now Live in States with Marriage Equality
May 2, 2013 by HRC staff
Today the Rhode Island state House passed marriage equality legislation, putting the Ocean State on track to become the tenth state in America where gay and lesbian couples can legally marry. The legislation, which passed with bipartisan support, will be signed into law by Gov. Lincoln Chafee later today in a historic signing ceremony on the steps of the Rhode Island State House.
"The unprecedented momentum for marriage across the country continues, with Rhode Island becoming the first state of 2013 to say yes to marriage equality," said HRC President Chad Griffin. "As the Supreme Court deliberates the fundamental right to marry the person you love, these historic and bipartisan victories keep mounting and prove the country is ready for marriage equality."
The House passed a modified version of legislation it had previously passed in January, which was then amended and passed by the Senate last week. Same-sex couples in Rhode Island can begin applying for marriage licenses August 1, 2013.
The nation's largest LGBT civil rights organization, HRC has been an integral financial and strategic player in winning marriage in each of the ten states and DC. In Rhode Island, HRC has provided significant financial investment, staff and technical resources over many years to amplify the historic grassroots effort of the Rhode Islanders United for Marriage coalition.
"For several years HRC has been a true partner in Rhode Island's efforts to win marriage equality in the Ocean State," said Rhode Islanders United for Marriage campaign manager Ray Sullivan. "HRC provided us with key boots on-the-ground that added to our state's unprecedented grassroots campaign to win marriage. Thank you, HRC."
The passage of marriage equality in Rhode Island comes as the U.S. Supreme Court is expected to hand down decisions on two marriage-related cases by the end of June. Hollingsworth v. Perry challenges the constitutionality of California's Proposition 8, and United States v. Windsor, challenges the so-called Defense of Marriage Act.
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June 1, 2015
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June 15, 2015
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June 5, 2015
Watch: HRC Answers Your SCOTUS Questions
June 19, 2015


text:
Wyndon in Wynnewood
Very spacious apartments close to Lankenau Hospital and within walking distance to train, restaurants, and fine stores. WASHER/DRYER in your apartment, renovated kitchens and baths and beautiful hardwood floors. Extra storage and reserved garage spaces are available.Manager's Special 1 Bedroom: $1195
St. Georges in Ardmore
St. George's features new windows, modern kitchens, dining room and large closets, WASHER/DRYER in your unit. Suburban Square Shopping Center is only one block away featuring top retailers and some of the best restaurants on the Main Line. Ardmore Train Station and buses are a block away. The St. Georges offers free parking or choose a reserved space in our garage.1 Bedroom: $1175, Manager's Special 2 Bedrooms $1445.
Racquet in West Chester
Our apartments offer ample space at a reasonable price. Fully equipped kitchens, tile bath, wall-to-wall carpet, air-conditioning, extra-carpeted storage room in addition to the good closet space. All units have a large patio or balcony. 24 hour maintenance available, cable & high-speed internet ready. Laundry facilities in each building for your convenience. Parking is free.Manager's Special 2 Bedroom: $925
All Specials are subject to change without notice.
101 Mill Creek Road Ardmore, PA


text:
December 4, 2011
was fuer ein langweiliges video
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All Comments (11)
was fuer ein langweiliges video
so nicely made
i'm so exited
Wow so hot......
nice so big
No, your wrong! I love the storylines in the beginning!
the storylines are the best part!
storylines make it cool ;)
who's that girl at 7:00?


text:
For 14 years, Gary worked as the editorial cartoonist for the Suburban Journals of Greater St. Louis. His work on Illinois state-issues was distributed by Copley News Service, and has been reprinted in The Washington Post, as well as some textbooks. His work has also appeared in "Best Editorial Cartoons of the Year" (Pelican Publishing Co.).
Gary is the main cartoonist for Vivid, an English language magazine dealing with art, culture, lifestyle and politics, published in Bucharest, Romania. He also freelances as a cartoonist and humor illustrator.
Gary's work as a graphic artist and freelance cartoonist has generated an impressive client list including companies such as Anheuser-Busch, Gibson Greetings, Disney's ABC.com, NobleWorks, Inc., Marcel Schurman Design, and Playboy magazine.
His work for these clients garnered him three consecutive nominations from the National Cartoonists Society—two as best gag cartoonist of the year, and one as best greeting-card cartoonist. Gary also dabbled in stand-up comedy, winning HBO's Stand-Up Stand-Off contest for the St. Louis area in mid-90s.
COMMENTS UPDATE: Scammers, Spammers, and Trolls, I'm Afraid You'll Find Our Moderation Tool Quite Operational | Townhall.com Staff
Loose Lips: Longtime Clinton Ally Trashes 'Buffoon' Biden, 'Sanctimonious Flip-Flopper' Sanders in Train Ride Rant | Guy Benson


text:
An exciting look back at all of the historic Indian Motorcycle® moments from Sturgis 2013: The Indian® Chief® Reveal Party, the first demo rides of the all-new Chief Classic®, Chief Vintage® and Chieftain™ Indian Motorcycle® night at the Sturgis Buffalo Chip® - and much more.
Always wear a helmet. Never drink and ride. © 2015 Indian Motorcyle International, LLC


text:
Originally posted on Fox Sports Wisconsin | Last updated 4/10/12
The Lakeshore Chinooks, the newest team in the Northwoods wooden bat baseball league won't play their first game until June but they already lead the circuit in at least two categories. The Chinooks have the most NBA general managers in their ownership group. Bucks GM John Hammond is a minority owner of the team, which is based in Mequon. "I love baseball," Hammond said. "I've always been a big fan of baseball. Grew up in a baseball home, my father loved the game, played the game. So for me, it's going to be a lot of fun, I'm going to be excited about it." The Chinooks, one of 17 teams from Wisconsin, Minnesota, Michigan, Iowa and Ontario competing in the league this summer, also lap the field when it comes to owners who are enshrined in Cooperstown. "I wonder if this is how Mr. Selig started," said Robin Yount, who along with fellow minority owner Bob Uecker is in the Major League Hall of Fame. "I don't know if I have commissioner in my future but it certainly is exciting to be...
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Weekly crop report: Corn a foot high, apple crop fruiting heavily
7:08 AM, Jun. 27, 2013
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Weekly crop report: Corn a foot high, apple crop fruiting heavily
The corn crop is about 92 percent planted in Wisconsin and about 12 inches tall, according to the June 25 state crop report . The first cutting of alfalfa is 61 percent harvested, with mixed quality.
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Hwy. 100 & I-44
P.O. Box 38
Gray Summit, MO 63039
Open 7 days a week
7 a.m. until sunset
Visitor Center:
8 a.m. to 4:30 p.m. weekdays
9 a.m. to 5 p.m. weekends
Bascom House:
10 a.m. to 4 p.m.
$5 general admission
$3 students
$3 seniors 65 & over
Free children 12 & under
Free for Shaw Nature Reserve passholders and Missouri Botanical Garden members.
Wheelchair Accessibility:
Bascom House, Maritz Trail House, Whitmire Wildflower Garden, Wetland Trail, Crescent Knoll Overlook, Glassberg Family Pavilions and restrooms.
Non-smoking. No pets. Professional photographers must pay a fee.
Saturday, October 17, 1–5 p.m.
Celebrate Native Plant School's 10th Anniversary with exhibitors and a guest speaker.
Download a flyer
Saturdays and Sundays in October, 1 p.m., 2 p.m., 3 p.m. $1 per person. The narrated wagon ride travels the three-mile Trail House Loop Road, with stops at the Trail House and wetland bus stop.
Learn more
Support the work of the Shaw Nature Reserve to restore land to its original state and preserve the peace and natural beauty of our grounds.
Learn more
Registration for Fall/Winter classes is now open! Check out our weekday, evening and weekend classes.
Register now!
Teachers, call (636) 451-3512 today to be added to the Maple Syrup Making field trip list. This class is for grades 4–8 and will be held late January and/or early February. Class is weather dependent.
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Shaw Nature Reserve strives to inspire responsible stewardship of our environment through education, restoration and protection of natural habitats and public enjoyment of the natural world.
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The Garden wouldn't be the Garden without our Members, Donors and Volunteers.
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4344 Shaw Blvd., St. Louis, MO 63110(314) 577-5100 hours and admission
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Shaw Nature Reserve
Hwy. 100 & I-44 Gray Summit, MO 63039(636) 451-3512 hours and admission


text:
Audi: Fuel efficient, 3
The new more fuel efficient Audis.
Advertising Agency: BBH London, UK
Executive Creative Director: Nick Gill
Creative Directors: Nick Kidney
Creative Team: Nick Kidney& Jim Hilson
Typographers: Sharon Chong, Rich Kennedy, Chris Chapman
Designers: Alex Trochut, Mission Possible
Photographer: Sean & Ben
10 comments
GuestSep 13, 2009 - 23:33
I think this a great time to send my portfolio to BBH London![2]
GuestJun 29, 2010 - 5:26
Dunno wat y'all talkin bout.
Dunno wat y'all talkin bout.
Ma own take out is that the Audi is so fuel efficient,
so much so u wont need a gigantic fuel tanker to supply its fuel.
I tot that was really obvious.
GuestAug 05, 2010 - 17:14
the last comment is great.
the last comment is great.
yeah, this ad means that exactly.
But as everyone can see here with all the comments this ad wouldn't work for the big public


text:
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After quote several Hotels in Guadalajara Mexico, I found this great deal, the service is just the best, The property is more like an apartment complex with a plus, has hotel service and the feeling that you are at home.
Location is also very good, close to everything and at the same time in a quiet neighborhood.
If you are planning to visit Guadalajara don't hesitate this is the best place you can find.


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Helmut Lang's monochrome modal tank will add an cool urban edge to every look. Simply wear it with micro shorts or skinny jeans. Shown here with Helmut Lang shorts, Burberry sandals, a Sissi Rossi bag and a Luc Kieffer bangle
Black and white marble print demi-sheer modal tank with racer back. Helmut Lang tank has a scoop neck and simply slips on. Dry clean.
Product code: 41378 - Need help? Contact us


text:
Fallen Leaves, Part 3: Into the Red (PFRPG) PDF
Animal Races: Clan of the Swan (PFRPG) PDF
Fallen Leaves, Part 2: Into the Woods (PFRPG) PDF
Pathfinder Society Scenario #5–24: Assault on the Wound (PFRPG) PDF
Pathfinder Society Scenario #3-04: The Kortos Envoy (PFRPG) PDF
Freeblades—Black Rose Bandits: Poacher
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Top 32 Contestants Named in Paizo's RPG Superstar,
Big Finish and Paizo Announce the Launch of New Mummy's Mask Audio Adventure Series,


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awful and ugly animation
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All Comments (15)
awful and ugly animation
00:08 that face will bring me nigthmares
the sound effects here are hilarious. The fucking sounds like a machine putting caps on bottles
hey magic . you dont need a dildo , just tell me and i can fuck you so hard , i hav an 8"penis , it is also moving ;)
I wish I had a dildo that moved on it's own...
she sounds like shes even eating a sausage.
I never understood Japanese. It's a CG and they still censored the genitals.
is it me.... or is the beginning sorta creepy?
Damn japanese just keep on teasing me man. Now they just half ass censor it.
Simple wonderfull!
why cant they leave english subs yo


text:
Runners take off for the start of the C. Clyde Run on the K-State campus Saturday morning. The proceeds from the run benefited Shepherd's Crossing.
K-State football player Cre Moore was arrested early Sunday morning by Riley County Police.
Kody Cook passed for two touchdowns — a 4-yard fade to Glenn Gronkowski and a 17-yard strike to Deante Burton — while adding a 3-yard score on the ground. The feel-good and unlikely story for the Wildcats, however, had a nightmare ending.
The Kansas State volleyball team erased a two-set deficit on Saturday at TCU, but the Horned Frogs hit .368 in the fifth to stave off the comeback attempt as the Wildcats fell.
The K-State equestrian team prospered in their first road meet of the season on Saturday afternoon at DeHaan Equestrian Center, as Kansas State defeated South Dakota State in a head-to-head battle, 11-8.
Oklahoma State has used both of its quarterbacks this season, but unlike many two-QB systems, the Cowboys have found a way to be successful sharing the ball.
Manhattan Area Habitat for Humanity volunteers finish construction on the organization's latest project.
Facing an offense that likes to throw the ball, Manhattan High tightened up its coverage and contained the pass game in a 50-7 win over Topeka West on Friday at Bishop Stadium.
It's difficult to sugarcoat the latest Kansas revenue report, one in which the state in September collected almost $32 million less than it had projected.
Both of my daughters left KSU for other insti-tutions after one semester (and with all A's) due to excessive use of profanity and sexually explicit comments by professors.
Thank you to all the individuals, businesses and volunteers who contributed to the success of the Manhattan Catholic Schools 32nd benefit auction, "Fall in the Flint Hills," Sept.26 at the St. Thomas More Utopia Room.
The Kansas State Association of Letter Carriers will continue to diligently work with members of Kansas' congressional delegation to ensure that rural and small-town Kansans' need for universal postal access at a universal price, is not trampled in Wall Street's undying greed.
Don't you think it's a bit bizarre that Americans are so hooked on the customs, history, language, music and dress of a country that counts just 6 million residents?
"The Other Wes Moore: One Name, Two Fates" is a book about two men whose strikingly parallel childhoods lead them down divergent paths.
News coverage often portrays black men as ghettoized caricatures, a simplification in the media that undermines their capacity for success.
To the author's credit, his portrayal of scheming within the sultan's palace is compelling, as are the details of life in Constantinople, a city that Bess says dwarfs her London both in size and majesty. And the author spins a good yarn.
MHS (4-1) coach Joe Schartz said his defense did a good job of keeping Topeka West from big gains through the air. Just three of the Chargers' 13 completions went for more than 10 yards.
The Manhattan High cross country teams swept the Junction City Invitational on Saturday, with both the boys' and girls' teams taking first.
At Wamego, the Red Raiders led by seven in the first quarter but played catch up the rest of the night, as Clay Center edged Wamego, 27-19, at the Wamego Sports Complex.
At Blue Rapids, Valley Heights picked up an important district win on Friday in a home contest with Valley Falls.
PORTLAND, Ore. (AP) — Sporting Kansas City made its path to the playoffs a little easier Saturday night.
ARLINGTON, Texas (AP) — Cole Hamels and the Texas Rangers finally clinched the AL West title on the last day of the regular season.
ST. PETERSBURG, Fla (AP) — Mark Buehrle failed to become the fifth major leaguer to pitch 200 innings or more in 15 consecutive seasons, and the AL East champion Toronto Blue Jays missed out on home-field advantage throughout the playoffs as they lost to the Tampa Bay Rays 12-3 Sunday in their regular-season finale.
LOS ANGELES (AP) — Zack Greinke places no emphasis on individual statistics and is loath to consider his potential place among baseball's greatest pitchers.
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KAS Catalina 0738 Black Peacock Feathers Area Rug
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Yahoo's Second Quarter Struggles Eased by Alibaba
July 15 (Bloomberg) -- Yahoo is retaining more of its stake in Alibaba under a new agreement and promised to return cash to shareholders from at least half of any proceeds from the Chinese e-commerce company's initial public offering. Cory Johnson reports on "Street Smart." (Source: Bloomberg)
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08:00 - Morgan Stanley's Jay Sole discusses his outlook for athletic apparel companies. He speaks on "Bloomberg ‹GO›." Morgan Stanley owns stock in Nike. (Source: Bloomberg)


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Parents need to know that this downloadable application and corresponding website are a generally safe way for kids to learn a few programming basics. They'll be able to read about programming language, test simple examples using the application, and can then extend their knowledge by trying to create their own simple programs to perform actions like drawing a shape or asking a question. Users don't need to register to use the application, but if they want to post questions or share programs they've created, they'll need to enter a username, password, and email address. No age limit or verification is required.
Kids can test examples, which should make them feel involved. But they don't receive individual feedback or instruction, which would help them understand programming on a deeper level (and prevent them from getting confused).
Kids learn how to write and save simple code examples. Content progresses from basic to slightly more complex, but doesn't constantly offer new challenges; for further learning, kids have access other sites or can ask users questions.
Kids can check out the FAQ or submit questions on the site for other community members (and possibly a site administrator) to answer. Links to other sites provide some extra information on Ruby and other programming topics.
The HACKETY HACK application provides detailed information on understanding and writing simple programming code using the Ruby programming language, created in 1995 by a programmer in Japan. Kids can read what steps to take and then test them out by copying and pasting examples from the text. They can read the same lesson information on the website and application and can also post programming instructions they've created or questions and responses for other users on the site.
Hackety Hack provides clear, fairly easy-to-understand programming instruction. Users learn general programming tips and find out how to write a few types of coding instructions using Ruby, a simplified programming language created more than 15 years ago. Kids probably won't be able to create their own website after using the site or application, but the information they learn can be used to help them understand a little bit about programming -- and enhance their reading, logic, and other critical thinking abilities.
Families can talk about what other actions, like homework or household projects, can be divided into a series of tasks, like programming. How could that make them easier to complete?
Programming involves communicating commands in a specific order. What other examples can your kids think of that echo that process in real life? Can you see any connection between conveying information clearly in programming and communicating with other people verbally or through writing?
Ask your kids what learning techniques made the most sense on the site. Is it easier to understand new concepts when visual examples are included? Does reading about new information help?
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Sunday, September 20, 2015
Homecoming Liturgy and Spirit of Saint Xavier Awards
11 a.m., McDonough Chapel of the Mother of Mercy
What better way to begin Homecoming week than by celebrating our faith! The SXU community is welcome to join us for the Liturgy of the Word at which the Spirit of Saint Xavier Awards will be presented to those alumni who in word and deed exemplify Saint Xavier University's core values of respect, excellence, compassion, service, hospitality, integrity, diversity and learning for life.
A reception honoring the alumni awards recipients will immediately follow in the Fourth Floor Board Room.
Monday, September 21, 2015
Students Today, Alumni Tomorrow (STAT) Brown Bag Project
6 p.m., SXU Diner Atrium
All are welcome - alumni, students, staff and faculty - to help us make lunches for local shelters that serve our neighbors in need. Donations of peanut butter, jelly, snacks and juice pouches (or monetary donations to offset the cost of this project) are always appreciated. Please contact Alumni and Parent Relations at firstname.lastname@example.com or 773-298-3316 for additional details. ** Parents are welcome!
Tuesday, September 22, 2015
Academic Distinguished Alumni and the O'Brien Student Leadership Awards
6:30 p.m., Butler Reception Room
The SXU community will honor those alumni and students whose words and actions emulate the operating ethos of Saint Xavier University.
Wednesday, September 23, 2015
Spirit of Mercy Day
Noon Liturgy, McDonough Chapel
Mass of the Holy Spirit
Pray with the entire SXU community that the special gifts of the Holy Spirit -- awe, counsel, fortitude, knowledge, piety, understanding and wisdom -- will mark the new academic year.
3:30 p.m., Leadership Commissioning, Academy Bell
Call forth and commission representative SXU leaders -- students, alumni, staff, faculty, administrators, trustees and Sisters of Mercy -- blessing them for a leadership of service in the year ahead.
4 p.m., Meet some Mercy Sisters, Student Lounge
Welcome and converse with Sister of Mercy leaders whose years of service have been guided by the Holy Spirit and inspired by Mercy founder Catherine McAuley's love of God, compassion for others and commitment to education.
** Parents are welcome!
Thursday, September 24, 2015
Family Love Letter (Planned Giving Event)
4-5:30 p.m., Butler Reception Room
Presented by Cheri Brooks of Neuberger Berman
Comics for Cougars
Shannon Athletic Center Auxiliary Gymnasium
6:30 p.m. Doors Open
7:00 p.m. Reception
8:00 p.m. Performance
Back by popular demand, local comedians, Pat McGann (Late Night with David Letterman) will be joined by Pat Tomasulo (WGN News anchor) and Dwayne Kennedy (Comedy Central) for an evening of laughs during Homecoming 2015!
Register online. $40 per person (includes show admission, light appetizers and refreshments.) Cash Bar.
Limited seating in the Scarlet Section is available for those who wish to purchase tables of 10. ** Parents are welcome!
Saturday, September 26, 2015
Cougar 5K Run/Walk
9 a.m., Smith Morris Quad
All are welcome to take part in the 15th Annual Cougar 5K Run/Walk. Participants receive a t-shirt, refreshments and a ticket to the football game upon request. The course starts and finishes on the campus and runs through Evergreen Park. For additional information or to register please visit our Cougar 5K web page.
"Cougar's Corner" - the official SXU Homecoming Tailgate!
Noon, Bruce R. Deaton Memorial Field
Alumni and friends are invited to join us under the big top as we celebrate Homecoming 2015. Guests will have an opportunity to watch the game from the tent.
This is a milestone reunion year for all those who graduated in years ending in an "0" or a "5" so don't miss this opportunity to catch up with old friends!
Register online. $25 (21+) includes admission to the tent, food, beverages - water, soda, wine and beer (featuring SXBrew - a handcrafted beer created especially for SXU by Horse Thief Hollow Restaurant and Brewery). **Parents are welcome!
Children (12 and under) accompanied by a paid adult are free.
Back by popular demand - Cougar Cubs - an entertainment area for kids which will include a jumping jack; craft projects; and more!
SXU vs. Siena Heights University
1 p.m., Bruce R. Deaton Memorial Field
All alumni who register at the SXU Alumni Hospitality Tent will be given free admission to the game!
Alumni Games
Various Times
Please contact the Athletics Department.
Gilhooley's 5th Quarter Party
5 p.m., Gilhooley's Grande Saloon
Immediately following the game head over to Gilhooley's for a 5th quarter celebration and an awesome finale to Homecoming 2015! ** Parents are welcome!
If you have any questions please email email@example.com or phone 773-298-3316.


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The browser you are using is out of date and is no longer supported. To view and use this site correctly, please update your browser to the latest version.
We are creating a new public body, Historic Environment Scotland, which will come into effect from 1 October 2015. While we work on shaping our future we can reassure you that all services and products will continue as normal. We will continue to keep you up to date on developments. Please follow our progress and find out more about our new organisation.
14 June 2011Around fifty more sites are likely to be scheduled for the first time in Shetland, following a visit throughout May by Historic Scotland's Scheduling and Marine team. The team was in the islands to assess which sites are of national importance and should be added to the Schedule, which means they are protected by law.
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text:
|Publication number
|Publication type
|Application number
|Publication date
|15 Nov 1988
|Filing date
|28 Apr 1987
|Priority date
|28 Apr 1986
|Fee status
|Also published as
|Publication number
|Peter Jeschke, Eva Kiewert, Ludwig Schieferstein, Klaus Schumann, Klaus-Dieter Wisotzki
|Original Assignee
|Henkel Kommanditgesellschaft Auf Aktien
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (10), Non-Patent Citations (6), Referenced by (64), Classifications (25), Legal Events (5)
|External Links: USPTO, USPTO Assignment, Espacenet
1. Field of the Invention
This invention relates to liquid aqueous cleaning preparations for hard surfaces, and more particularly to such preparations for use in the home and in institutions which provide thorough cleaning and antistatic properties to surfaces which tend to develop static charges without leaving behind any visible residues.
2. Discussion of Related Art
Cleaning preparations based on surfactants with or without the addition of builders are normally used for cleaning hard surfaces both in the home and in institutions. It is known that natural or synthetic polymers may be added to such cleaning preparations to enhance their cleaning power. Thus, German Patent Applications Nos. 28 40 463 and 28 40 464 describe the use of high molecular weight polyethylene glycols, and German Patent Application No. 29 13 049 describes the use of polyvinyl alcohols, polyvinyl pyrrolidones, cellulose ethers, polysaccharides, proteins and polyacrylamides as cleaning enhancers.
According to Great Britain Patent Specification No. 1,073,947, polyacrylamides inter alia improve the soil suspending power of liquid cleaning preparations for hard and irregular-shaped surfaces.
U.S. Pat. No. 3,696,043 describes polymers of aromatic monovinyl monomers with unsaturated dicarboxylic acids, and U.S. Pat. No. 4,508,635 describes the same class of compounds, but in partially esterified form, for improving the visual residue behavior of the cleaned surfaces and for avoiding the coating by glass of remaining water vapor.
Finally, British Patent Specification No. 2,104,091 describes liquid cleaning preparations which, together with standard anionic, nonionic, cationic or amphoteric surfactants, contain an addition of an amphoteric polymer compound prepared by polymerization of a cationic vinyl monomer with an anionic vinyl monomer. This addition, which is used in small amounts compared with the surfactant, brings about an improvement in detergency.
Unfortunately, none of these known liquid cleaning preparations is able to prevent freshly cleaned plastics material from attracting dust particles from the air and thus appearing as if it has not been cleaned.
Therefore, with the increasing number of plastics surfaces in the home, it would make cleaning very much easier and more efficient if those surfaces could be antistatically finished during cleaning. It would also be of value to the consumer if one and the same cleaning preparation could be used for a wide range of applications to enable optimal effects to be obtained both on hydrophobic surfaces, i.e., antistatic effects, and also on hydrophilic surfaces, i.e., anti-coating effects.
Accordingly, an object of the present invention is to provide cleaning preparations which are suitable for cleaning all washable hard surfaces in the home and in institutions and which at the same time bring about both thorough cleaning and antistatic finishing of surfaces which tend to develop static charges, and also anti-coating effects on mirrors without leaving behind any visible residues in the form of streaks, patches or the like on the treated surfaces. With prior art polymers and their end-use formulations, it is not possible to satisfy all the above-mentioned requirements with one and the same cleaning preparation.
Other than in the operating examples, or where otherwise indicated, all numbers expressing quantities of ingredients or reaction conditions used herein are to be understood as modified in all instances by the term "about".
Surprisingly, it has been found that the aforementioned objects can be accomplished by using selected amphoteric copolymers which contain both anionic and cationic centers in the molecule, and are characterized by certain hydrophilization properties, together with surfactants in certain critical quantitative ratios.
It is thus a particular characteristic of the cleaning agent in accordance with this invention that, in contrast to the teaching of British Patent No. 2,104,091, it contains quantitatively less surfactant than polymer compound, and at most small quantities of surfactant and polymer compound.
The present invention pertains to liquid aqueous cleaning agents for hard surfaces which contain at least one amphoteric polymer compound obtained by copolymerizing a cationic vinyl monomer with an anionic vinyl monomer in a quantity of 0.01 to 10% by weight, as well as an anionic, nonionic, cationic or amphoteric surfactant or mixtures thereof, characterized in that the amphoteric polymer compounds with anionic and cationic centers in the molecule are selected from among polymer compounds which in 0.1% solution in water of 16°d bring about an irreversible hydrophilization of PVC with increments of the wetting tension of at least 3 milli-Newton per meter (mN/m), and wherein the surfactant quantity is selected such that the weight ratio of amphoteric polymer to surfactant is 20:1 to 1:1, preferably 10:1 to 1:1.
The amount of amphoteric polymer compound present in the cleaning preparations may be from 0.01 to 10% by weight, based on the weight of the cleaning preparation. Preferred preparations according to the invention contain the amphoteric polymer compound in quantities of from 0.02 to 5% by weight of the preparations.
Where the preparations according to the invention are applied to the hard surfaces to be cleaned, they produce not only a good antistatic effect, but also a good anti-coating effect coupled wtih good residue behavior.
It is possible to use virtually any of the surfactants and surfactant mixtures hitherto typically used for cleaning preparations of the type herein. Non-ionic surfactants of the amine oxide type containing at least one C10 -C20 alkyl group are particularly preferred. Typical representatives include, for example, the compounds N-dodecyl-N,N-dimethylamine oxide, N-tetradecyl-N,N-dihydroxyethylamine oxide, and N-hexadecyl-N,N-bis-(2,3-dihydroxypropyl) -amine oxide.
Favorable effects are also obtained with other nonionic surfactants, for example with adducts of from 4 to 40 moles, and preferably 4 to 20 moles of ethylene oxide or ethylene oxide and propylene oxide with 1 mole of fatty alcohol, alkane diol, alkane phenol, fatty acid, fatty amine, fatty acid amide or alkane sulfonamide. Particularly useful are the adducts of from 5 to 16 moles of ethylene oxide or ethylene oxide and propylene oxide with coconut oil or tallow fatty alcohols, with oleyl alcohol or with secondary alcohols containing from 8 to 18, and preferably from 12 to 18 carbon atoms and with mono- or dialkylphenols containing from 6 to 14 carbon atoms in the alkyl groups. In addition to these water soluble nonionics, however, polyglycol ethers containing from 1 to 4 ethylene glycol ether residues in the molecule, which are insoluble or not completely soluble in water, are also useful, particularly where they are used together with water-soluble nonionic or anionic surfactants.
Other suitable nonionic surfactants include the water-soluble adducts, containing from 20 to 250 ethylene glycol ether groups and from 10 to 100 propylene glycol ether groups, of ethylene oxide with polypropylene oxide, alkylenediamine polypropylene glycol and alkyl polypropylene glycols containing from 1 to 10 carbon atoms in the alkyl chain, wherein the polypropylene glycol chain acts as a hydrophobic residue.
Anionic surfactants may also be used in this invention either individually or in combination with nonionic surfactants. It is preferred to use surfactant combinations of anionic surfactants selected from the group of sulfonate and sulfate surfactants, and nonionic surfactants of the ethoxylated alkanol, alkenol and alkylphenol type.
Suitable anionic surfactants include, for example, soaps of natural or synthetic fatty acids and of resinic or naphthenic acids. Suitable synthetic anionic surfactants include those of the sulfonate and synthetic carboxylate type.
Suitable surfactants of the sulfonate type include alkylbenzene sulfonates containing 9 to 15 carbons in the alkyl group, mixtures of alkene and hydroxyalkane sulfonates and also disulfonates, such as those obtained, for example, from monoolefins containing a terminal or internal double bond by sulfonation with gaseous sulfur trioxide and subsequent alkaline or acidic hydrolysis. Alkane sulfonates obtainable from alkanes by sulfochlorination or sulfoxidation and subsequent hydrolysis or neutralization or by addition of bisulfites onto olefins are also suitable. Other suitable surfactants of the sulfonate type include the esters of α-sulfofatty acids, for example, the α-sulfonic acids from hydrogenated methyl or ethyl esters of coconut oil, palm kernel oil or tallow fatty acid.
Suitable surfactants of the sulfate type include the sulfuric acid monoesters of primary alcohols, for example, from coconut oil fatty alcohols, tallow fatty alcohols or oleyl alcohol, and those of secondary alcohols. Sulfated fatty acid alkanolamides, fatty acid monoglycerides or reaction products of from 1 to 4 moles of ethylene oxide with primary or secondary fatty alcohols or alkylphenols are also suitable.
Other suitable anionic surfactants herein include the fatty acid esters of amides of hydroxy or amino-carboxylic acids or sulfonic acids, such as for example, fatty acid sarcosides, glycolates, lactates, taurides or isethionates.
The anionic surfactants may be present in the form of their alkali metal, alkaline earth and ammonium salts and as soluble salts of organic bases, such as mono-, di- or triethanolamine. The sodium salts are generally preferred for reasons of cost.
The cationic surfactants which may also be used in this invention contain at least one hydrophobic group and at least one basic, water-solubilizing group optionally present in salt form. The hydrophobic group may be an aliphatic or cycloaliphatic hydrocarbon group preferably containing from 10 to 22 carbon atoms or an aromatic alkyl or cycloalkyl group preferably containing from 8 to 16 aliphatic carbon atoms. Suitable basic groups include primarily basic nitrogen atoms which may even be repeatedly present in a surfactant molecule. The compounds herein are preferably quaternary ammonium compounds, such as for example, N-dodecyl-N,N,N-trimethylammonium methosulfate, N-hexadecyl-or N-octadecyl-N,N,N-trimethylammonium chloride, N,N-dicocosalkyl-N,N-dimethylammonium chloride, N-dodecyl-N,N-dimethyl-N-benzylammonium bromide, the reaction product of 1 mole of tallow alkylamine with 10 moles of ethylene oxide, N-dodecyl-N,N'N'-trimethyl-1,3-diaminopropane, and N-hexadecyl pyridinium chloride. Where cationic surfactants are used, they should of course be tested in the customary way for their compatibility with other constituents of the formulation.
The amphoteric copolymers used in accordance with the invention include copolymers containing anionic and cationic centers in the molecule prepared in accordance with British Patent Specification No. 2,104,091 from two or three of the following monomers:
AS- acrylic acid or salts thereof,
DMAEM- dimethylaminoethyl methacrylate,
DMANA- dimethylaminoneopentyl acrylate,
DMAPMA- dimethylaminopropylmethacrylamide,
EA- ethylacrylate,
MAPTAC- methacrylamidopropyltrimethylammonium chloride,
MAS- methacrylic acid or salts thereof, and
MMA- methylmethacrylate,
and which contain at least 1 mole of a nitrogen-containing acrylic acid derivative per mole of acrylic acid. The salts include the alkali metal, ammonium and/or alkanolamine salts thereof.
The measurement of the irreversible hydrophilization of plastics was achieved with the aid of wetting tension measurements as described in Colloid and Polymer Science, Vol. 264, pp. 56-64, (1986). The polymers in 0.01% solution in 16°d hard water were tested on PVC. The surface tension YL in mN/m (previously known as dyn/cm, see DIN 1301) according to the equation
j=YL. cos θ(=F/P)
is the upper limit of the wetting tension j for θ→0. Other values can be adopted numerically without alteration, e.g., for pure water at 25° C., YL =72 mN/m=72 dyn/cm.
θ in degrees is the equilibrium marginal angle measured in the liquid between a flat solid measurement piece and the tangent to the surface of the drop at the wetting point.
In the technological determination of the wetting tension j against water, a measurement is performed of the force (F) with which a measurement piece of circumference P (e.g., PCC film) is drawn into or pushed out of water. Thus the measurement value is a measure of the wettability (wetting tension j=F/P) of a measurement piece with water.
The efffective irreversible adsorption of amphoteric polymers on a test piece changes this force more or less depending on the hydrophilicity or hydrophobicity of the molecular structure.
In the case of a hydrophilization effect, the force with which the measurement piece is pulled into the water is greater than in the initial state. Thus, positive increments of the wetting tension result from this (+Δj). (In the case of a hydrophobization effect, the force with which the measurement piece is pulled into the water becomes smaller than in the initial state. Negative increments of the wetting tension (-Δj) would result from this.) (Also see B. Miller and R.A. Yound in Textile Res. J., Vol. 45, pp. 359-365, 1975.)
The use of water-soluble or solution-promoting solvents is not essential to the effects obtained in accordance with the invention, although their presence can have a positive effect on the evaporation behavior of residues of the cleaning preparation on the treated surfaces. Examples of suitable solvents include linear, branched and cycloaliphatic C2 -C12 alcohols and ethers of identical or different polyhydric alcohols or the partial ethers of polyhydric alcohols. Solvents such as these include, for example, di- or triethylene glycol polyglycerols and the partial ethers of ethyleneglycol, propylene glycol, butylene glycol or glycerol with aliphatic monohydric alcohols
Suitable water-soluble or water-emulsifiable organic solvents also include ketones, such as acetone, methyl ethyl ketone, and also aliphatic, cycloaliphatic, aromatic and chlorinated hydrocarbons as well as the terpenes.
In addition, it is possible to incorporate solution promoters known per se, including or in addition to the water-soluble organic solvents, such as in particular low weight aliphatic C1 -C4 alcohols, so-called hydrotropes of the lower alkylaryl sulfonate type, for example toluene, xylene or cumene sulfonate. They may also be present in the form of their sodium and/or potassium and/or alkylamino salts. The water-soluble or solution-promoting solvents may be present in quantities of from 0 to 15% by weight, and preferably in quantities of from 0 to 10% by weight, based on the preparation as a whole.
Known builders, particularly inorganic or organic complexing agents, which are preferably present in the form of their alkali metal or amine salts, particularly the potassium salts, may also be added to the cleaning preparations according to the invention in quantities of from 0 to 3% by weight and preferably in quantities of from 0 to 2% by weight, based on the preparation as a whole. The builders may also include alkali metal hydroxides. Suitable inorganic complexing builders include, in particular, the alkaline-reacting polyphosphates, particularly the tripolyphosphates, and also the pyrophosphates. They may be completely or partly replaced by organic complexing agents. Other inorganic builders which may be used in accordance with the invention include, for example, dicarbonates, carbonates, borates, silicates or orthophosphates of the alkali metals.
Organic complexing agents of the aminopolycarboxylic acid type include, inter alia, nitrilotriacetic acid, ethylenediamine tetraacetic acid, N-hydroxyethylethylene -diamine triacetic acid and polyalkylene polyamine -N-polycarboxylic acids as well as di- and polyphosphonic acids, and their alkali metal salts.
Various generally N- or P-free polycarboxylic acids have recently been proposed as builders in the literature, the compounds often, although not always, being polymers containing carboxyl groups. Many of these polycarboxylic acids are capable of complexing calcium. This is the case, for example, with citric acid, tartaric acid, benzene hexacarboxylic acid, tetrahydrofuran tetracarboxylic acid, gluconic acid, etc. Since the preparations of this invention should preferably show a neutral to mildly alkaline reaction, acidic or alkaline components may have to be added to regulate the pH-value.
Suitable acidic substances include typical inorganic or organic acids or acidic salts, such as for example, hydrochloric acid, sulfuric acid, bisulfates of the alkali metals, aminosulfonic acid, phosphoric acid or other acids of phosphorus, particularly the anhydric acids of phosphorus or acidic salts thereof or acid-reacting solid compounds thereof with urea or other lower carboxylic acid amides, partial amides for phosphorus acids or anhydric phosphoric acid, citric acid, tartaric acid, lactic acid and the like. Where the alkaline builder content is not sufficient to regulate the pH-value, alkaline-acting organic or inorganic compounds, such as alkanolamines, namely mono-, di-or triethanolamine, or ammonia may also be added.
Other additives typically used in cleaning preparations, such as for example, viscosity regulators, antimicrobial agents, dyes and perfumes, may also be present in the subject cleaning preparation providing they are compatible with the other constituents of the formulation.
The following procedures were practiced in the examples.
1. Preparation of the amphoteric polymers:
(a) Procedure for preparing a copolymer of DMAEM:AS, molar ratio 5:1
306 g of water, 26.8 g (0.17 mole) of dimethylaminoethyl methacrylate and 2.46 g (0.034 mole) of acrylic acid were first weighed with external cooling into a 2 liter flask surmounted by a metering vessel. A pH value of approximately 6 was adjusted by addition of approximately 21 g of 30% sulfuric acid. The internal temperature of the mixture was kept below 25° C.
A solution of 346 g of water, 241.2 g (1.54 moles) of dimethylaminoethyl methacrylate, 22.5 g (0.31 mole) of acrylic acid and approximately 200 g of 30% sulfuric acid prepared as described above was introduced into the metering vessel.
The contents of the flask were then heated to a temperature of 80° C. and polymerization initiated by addition of a solution of 2.6 g of ammonium peroxydisulfate in 20 g of water.
The solution in the metering vessel was then introduced to the flask contents over a period of 1 hour. The internal temperature was kept between 78° and 83° C. by external cooling. On completion of the addition, a solution of 1.3 g of ammonium peroxydisulfate in 10 g of water was added and the mixture stirred for about 1 hour at 80° C.
A clear, yellow, moderately viscous polymer solution was obtained after cooling.
At relatively low concentrations, the reaction may even be carried out in a single stage because in that case the reaction is less exothermic. This procedure is described below.
(b) Procedure for preparing a copolymer of DMAEM:AS:MMA, molar ratio 3:1:1
95.4 g of dimethylaminoethyl methacrylate (0.61 mole), 60.8 g of methylmethacrylate (0.61 mole), 0.7 g of azodi (isobutyronitrile) and 159 g of isopropanol were weighed into a 2 liter flask. 43.8 g of acrylic acid (0.61 mole) in 635 g of water were added with stirring. Heating beyond 22° C. was avoided by external cooling. The mixture was then carefully adjusted to a pH value of approximately 6.0 by addition of approximately 5 g of 30% sulfuric acid and was then stirred under nitrogen for 2.5 hours at 65° to 80° C. A colorless, clear, slightly viscous polymer solution was obtained after cooling.
The other substances were similarly prepared without any difficulty for the expert.
2. Test Methods
The properties of the preparations of the invention were determined by the following tests:
(a) Antistatic effects
(a1) Measuring method
15 cm×15 cm plates of polyvinyl chloride (PVC), polyethylene (PE), and acrylic glass were treated with the test products, acclimatized in a control environment (20° C./65% relative humidity) and their electrical surface resistance measured using the ring electrode according to DIN 54 345, Part 1. Three plates of the same material were used for each test product. Similar plates which had been treated either only with water or with recommended prepared solutions of commercial polymer-containing cleaning preparations were used for comparison.
The measured resistance values (in ohms) of the plates treated with the cleaning preparations according to the invention were lower by several powers of 10 than the blank values and considerably more favorable than the comparison values obtained with the state-of-the-art cleaning preparation.
(a2) Qualitative test
As a rapid preliminary test, the plates were tested for their tendency to attract soot particles. The soot was prepared by burning cellulose. The plates described in (a1) which had been treated with the cleaning preparations therein and then dried were rubbed with a woolen cloth and held over the soot at a distance of 5 cm. Whereas the plates treated with the state-of-the-art cleaning preparation attracted the soot, the plates treated with the products according to the invention remained clean.
(b) Anti-coating effects
30 cm×40 cm mirrors were treated wtih the products according to the invention and, for comparison, with the state-of-the-art cleaning preparation and placed in a domestic refrigerator. After 30 minutes, the mirrors were visually assessed.
Whereas the preparations according to the invention prevented coating of the mirrors, the mirrors treated with the comparison preparation were coated.
(c) Residue behavior
Surfaces of mirror glass, glazed tiles, PVC, PE, acrylic glass and Resopal were treated as recommended with the preparations according to the invention and, for comparison, with the state-of-the-art cleaning preparation.
After the surfaces had dried, their appearance for homogeneity was visually assessed. In every case, the preparations according to the invention showed distinctly more favorable residue behavior than the comparison product.
(d) Cleaning effect
To test its cleaning effect, the cleaning preparation to be tested was applied to an artificially soiled PVC surface. A mixture of carbon black, machine oil, a saturated fatty acid trigyceride, and a low-boiling aliphatic hydrocarbon was used as the artificial soil. The 26×28 cm test area was uniformly coated with 2 g of the artificial soil using a surface spreader.
A plastic sponge was wetted with 12 ml of the cleaning preparation solution to be tested and moved by machine over the test surface. After 6 wiping movements, the cleaned test surface was held under running water and the loose soil removed. The cleaning effect, i.e. the whiteness of the plastic surface thus cleaned, was measured using an LF 90 photoelectric colorimeter (Dr. B. Lange). The clean white plastic surface served as the white standard.
Since in the measurement of the cleaned surface the colorimeter was set at 100% while the soiled surface produced a zero reading, the values read off in the case of the cleaned plastic surfaces could be equated with the percentage cleaning power (%CP). (Quality standards of the Industrieverband Putz-und Pflegemittel (IPP), published in Seifen, Ole, Fette, Wachse, 108, No. 16, page 527, (1982)).
(e) Composition of a state-of-the-art cleaning preparation
The state-of-the-art cleaning preparation comprised an aqueous solution of 7.0% by weight of a straight-chain primary C9 -C11 alkanol reacted with 5 moles of ethylene oxide, 2% by weight of sodium lauryl ether sulfate, 1% by weight of a partial ester of styrene-maleic acid anhydride polymers, and 0.45% by weight of hydroxyethyl cellulose.
The following examples were prepared simply by mixing the given components. All the percentages are percentages by weight.
0.1% cocosalkyldimethylamine oxide
0.15% amphoteric polymer DMAEM/AS (molar ratio 10:1)
4% ethanol
2% isopropanol
1% propylene glycol butylether
0.1% perfumes
ad 100% fully deionized water
This cleaning preparation showed a very good anti-coating effect on mirror glass. It provided PVC and PE surfaces with an antistatic finish and left no visible residue behind on the treated surfaces. The IPP cleaning power is considerably better than that of an in-use solution of a commercial cleaning preparation for hard surfaces based on a nonionic and an anionic surfactant and a partially esterified styrenemaleic anhydride copolymer according to European Patent No. 66342.
In the basic formulation of Example I, the amphoteric polymer was varied as follows:
DMAEM/AS molar ratio 1:1
DMAEM/AS molar ratio 2:1
DMAEM/AS molar ratio 5:1
DMAEM/MAS molar ratio 2:1
DMAEM/MAS molar ratio 5:1
DMAEM/AS/MMA molar ratio 1:1:1
DMAEM/AS/MMA molar ratio 3:1:1
DMAEM/AS/MMA molar ratio 5:1:1
DMAPMA/AS molar ratio 2:1
In every case, the cleaning preparation obtained could be sprayed by commercial spray pumps and produced the same favorable results as the formulation of Example I in the tests for anti-coating effect, antistatic effect, residue behavior and cleaning power.
0.05% sec. C11 -C18 alkane sulfonate
0.1% fatty alcohol containing 5 moles ethylene oxide and 4 moles of propylene oxide (based on coconut oil)
7% ethanol
1% isopropanol
0.01% pine oil
0.15% polymer DMAEM/AS
ad 100% fully deionized water
The molar ratio of the monomers in the polymer ofExample XI was 3:1 and, in the case of Example XII, 5:1.
Both cleaners showed irreversible hydrophilicization on PVC which led to good antistatic effects and high cleaning power. The residue behavior on glass and plastic surfaces was very good.
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|3 Oct 1972
|Dow Chemical Co
|Cleaning composition for glass and reflective surfaces
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|15 May 1984
|Lever Brothers Company
|Article suitable for wiping hard surfaces
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|Lever Brothers Company
|General-purpose cleaning composition comprising nonionic surfactant and alcohol esterified resin copolymer
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|The Drackett Company
|Composition for cleaning and imparting antistatic properties to plastics surfaces
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|3 Sep 1985
|The Clorox Company
|Outside window cleaner containing polyvinyl alcohol and amine-containing polymer
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|7 Jul 1987
|The Procter & Gamble Company
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|The Clorox Company
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|Unilever N.V.
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|Title not available
|Colloid & Polymer Science, vol. 264, pp. 56 64, (1986).
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|Burke John J
|Hard surface cleaning composition containing polyacrylate copolymers as performance boosters
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|Taiho Industries Co., Ltd.
|Rust removing agent for stainless steel surface
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|Reckitt & Colman Products Limited
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|L'ORéAL S.A.
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|27 May 2003
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|The Procter & Gamble Company
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|5 Aug 2003
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|9 Mar 2004
|Rhodia Chimie
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|Dominic Wai-Kwing Yeung
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|27 May 2008
|3M Innovative Properties Co
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|The Procter & Gamble Company
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|Rhodia, Inc.
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|9 Jun 2005
|The Procter & Gamble Company
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|Chandrika Kasturi
|Hand dishwashing compositions comprising polymeric suds volume and suds duration enhancers and methods for washing with same
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|Ecolab Inc.
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|16 Feb 2006
|The Procter & Gamble Company
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|Lubrizol Advanced Materials, Inc.
|Stable Soap Based Cleansing System
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|Rhodia Chimie
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|Surfactant composition having stable hydrophilic character
|26 Feb 1993
|15 Sep 1993
|Rohm And Haas Company
|Use of water-soluble polymers in cleaning compositions, and water-soluble polymers for such use
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|13 Oct 1989
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|Procter & Gamble
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|25 May 2000
|30 Nov 2000
|Procter & Gamble
|Compositions and methods for using polymeric suds enhancers
|25 May 2000
|30 Nov 2000
|Howard David Hutton
|Detergent compostitions comprising polymeric suds enhancers which have improved mildness and skin feel
|25 May 2000
|30 Nov 2000
|Procter & Gamble
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|30 Nov 2000
|Procter & Gamble
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|13 Jul 2000
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|Eric Aubay
|Cleansing composition for hard surfaces
|26 May 2003
|4 Dec 2003
|Eric Aubay
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|3M Innovative Properties Co
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|U.S. Classification
|510/394, 510/502, 510/434, 510/244, 510/503, 510/400, 510/432, 510/182, 510/476, 510/421, 510/426, 510/424, 510/433
|International Classification
|Cooperative Classification
|European Classification
|28 Apr 1987
Owner name: HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN (HENKEL KG
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNORS:JESCHKE, PETER;KIEWERT, EVA;SCHIEFERSTEIN, LUDWIG;AND OTHERS;REEL/FRAME:004699/0888
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|28 Apr 1987
|Assignment of assignor's interest
|5 May 1992
|Fee payment
Year of fee payment: 4
|2 May 1996
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|Fee payment
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text:
U of M's human research re-accreditation on hold
The decision comes seven months after a critical report found "many weaknesses" in the university's efforts to protect people who participate in research experiments.
The decision comes seven months after a critical report found "many weaknesses" in the university's efforts to protect people who participate in research experiments.
John King Jr. is Arne Duncan's deputy and was New York's education commissioner before heading to Washington. Like the man he's replacing, he's no stranger to controversy.
Also, the Department of Education Office of Civil Rights has wrapped up its investigation into the athletics program related to a Title IX complaint filed in 2014.
Sidestepping a nomination fight in Congress, President Obama has tapped John King Jr., a senior official at the Education Department, to run the department in an acting capacity for the remainder of his administration.
Noah Atlas, director of child nutrition for the district, says meal debt grew by almost 50 percent between the last two school years.
A group of protesters, angry about Minneapolis Public Schools' contract with Utah-based Reading Horizons, disrupted the meeting. Teachers discovered some books contained offensive stereotypes.
The so-called "cost of attendance" policies go beyond the tuition, fees and room and board expenses covered by traditional scholarships.
A discussion about sex education and health in Minnesota.
US Secretary of Education Arne Duncan told the National Press Club audience today that institutional racism and class inequality is one of the "hardest conversations to have in education," but it's the most important.
That's the conclusion of a new poll of 30,000 graduates of four-year colleges.
Can colleges provide due process for defendants accused of rape, and adequate justice for the victims? Or do these cases belong in the criminal courts? An Intelligence Squared debate featuring law professors from Harvard, Yale, CUNY and NYU.
The plaintiffs include former women's hockey coach Shannon Miller, who led the Bulldogs to five NCAA national championships, and two other female coaches.
A special election could change the balance of power on the Columbia Heights board.
The children's TV show ran for just five years in the U.S. in the 1990s. But it's still hugely popular in Latin America, and a stage version of the show attracts audiences in the thousands.
The union push originally involved just part time and non-tenured professors, but has grown to also include tenured faculty.
The Catholic Church in the U.S. has been aging, along with its dwindling priestly ranks. But in the increasingly secular world, there's been a recent uptick in younger men studying to become priests.
At a Columbia Heights school board meeting Tuesday night, dozens of students, teachers and residents called for Grant Nichols to step down.
Will it be the University of North Dakota Roughriders, North Stars, Fighting Hawks, Nodaks or Sundogs?
A study says 23.5 percent of undergraduate female respondents at the U's main campus have experienced sexual assault "by physical force, threats of physical force or incapacitation."
Talk of a gun in the building led officials to put St. Paul's Como Park High School into lockdown Monday. The lockdown was lifted just before 1 p.m. Students are safe.


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PROVIDENCE, R.I. [Brown University] Lake Tanganyika, the second oldest and the second-deepest lake in the world, could be in for some rough waters.
Geologists led by Brown University have determined the east African rift lake has experienced unprecedented warming during the last century, and its surface waters are the warmest on record. That finding is important, the scientists write in the journal Nature Geoscience, because the warm surface waters likely will affect fish stocks upon which millions of people in the region depend.
The team took core samples from the lakebed that laid out a 1,500-year history of the lake's surface temperature. The data showed the lake's surface temperature, 26 degrees Celsius (78.8F), last measured in 2003, is the warmest the lake has been for a millennium and a half. The team also documented that Lake Tanganyika experienced its biggest temperature change in the 20th century, which has affected its unique ecosystem that relies upon the natural conveyance of nutrients from the depths to jumpstart the food chain upon which the fish survive.
"Our data show a consistent relationship between lake surface temperature and productivity (such as fish stocks)," said Jessica Tierney, a Brown graduate student who this spring earned her Ph.D. and is the paper's lead author. "As the lake gets warmer, we expect productivity to decline, and we expect that it will affect the [fishing] industry."
The research grew out of two coring expeditions sponsored by the Nyanza Project in 2001 and 2004. Cores were taken by Andrew Cohen, professor of geological sciences at the University of Arizona and director of the Nyanza project, and James Russell, professor of geological sciences at Brown, who is also Tierney's adviser.
Lake Tanganyika is bordered by Burundi, the Democratic Republic of Congo, Tanzania, and Zambia four of the poorest countries in the world, according to the United Nations Human Dev
|Contact: Richard Lewis
Brown University


text:
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A lady sits under a mosquito net near the White Nile at a site used... News PhotoAdult,Conflict,District,Horizontal,Internally Displaced Person,Mosquito,People,Sitting,South Sudan,South Sudanese Conflict 2013-2014,Violence,White Nile,WomenPhotographer PHIL MOORECollection: AFP 2014 AFPA lady sits under a mosquito net near the White Nile at a site used by internally displaced persons in Minkamen in Awerial county, South Sudan on January 11, 2014. According to the latest figures from the United Nations, some 75,000 people have settled in Minkamen following clashes in nearby Bor, 40km away, between the South Sudanese army and rebels led by Riek Machar. Shelling could be heard today. AFP PHOTO/PHIL MOORE (Photo credit should read PHIL MOORE/AFP/Getty Images)