text:
Paula's Choice Beautypedia.com
131 reviews
58% would repurchase
Package Quality: 3.1
Price: $$
Package Quality: 3.1
Price: $$
Not tested on animals
on 2/3/2015 12:00:00 PM
Age: 19-24
Skin: Dry, Medium, Warm
Hair: Black, Straight, Medium
Eyes: Brown
I think Beautypedia is a helpful resource when searching for a new product. For me, it's certainly not the end-all and be-all (and I don't think any single resource could or should be) but I like seeing the different takes that are out there. Beautypedia does try to bill itself as the absolute best resource out there which gets a bit over-the-top in my opinion, but is easy enough to ignore and doesn't detract from its utility.
I don't go by the ratings and reviews strictly, but I think the pro's and con's breakdown is adequate at explaining why something got a positive or negative rating so I can evaluate the product by my own standards. For example, perhaps one of the dealbreaker con's for Paula might not be that big a deal to me (super inflated claims -- it's okay, I didn't really expect to wake up looking like a supermodel after using a cream) and overall the product may be a good match.
For me, it's most useful function is actually not the reviews or the ratings. The search function pulls up the products and readily displays the price and size. When I'm considering multiple products, it can be tedious to compare the price per oz (searching through various websites to locate the necessary information, sometimes not being able to find it at all especially on large non-beauty focused retailers like Amazon) but Beautypedia is simple and clean. If they added a price per oz column that would be even better however for now I'm fine doing a couple mental calculations. I also appreciate the ingredients lists.
Overall, while I do think there are some drawbacks to Beautypedia, I find it helpful when searching for a new product especially for its easily sorted price and size information.
on 2/2/2015 1:44:00 PM
Age: 19-24
Skin: Combination, Fair, Not Sure
Hair: Brunette, Wavy, Other
Eyes: Blue
At first I was interested to read Paula's reviews because they seemed to tell things that other reviewers/bloggers does not say, even though her comments were a bit too criticizing. Sometimes it really influenced my decision wether to make the purchase or not.
However, after some time I noticed that basically any product that I was interested in had the highest rating of "good". I realized that some of the products that have been working very well or even excellent are rated by "poor" or "average".
My positive opinion crashed completely when:
1)I realized she has her own products that all are rated "best" while she scorns huge majority other skincare brands
2)I read her comment on Caudalie C15 Overnight Detox Oil. She praises the oil ingredients a lot, also the price, BUT, she gives rating "poor" JUST because its name says "Detox" while according to Paula no skincare can do that. Okay, I can understand that, but is it good reason enough to put the lowest rating if everything else (even for picky Paula) is good?
on 1/26/2015 3:59:00 PM
Age: 25-29
Skin: Sensitive, Medium, Not Sure
Hair: Other, Other, Other
Eyes: Brown
I find the Beautypedia website indispensable. Their articles and reviews alerted me to the ingredients I was having irritation and rashes from--esp Methylwhatever, that long name. That's why products that people generally rave about (eg WnW coverall foundation) destroy my skin. They point out fragrance/formula/etc issues, and are quite generous in recommending all kinds of brands for all budgets. To those reiterating that Paula doesn't have specialized degrees/ experience: she hires a team for this stuff, you can't miss their names on the site. Duh.
People (beauty writers) I used to trust incl my fave (charming writing but full of misinformation) Zoe foster, have all rec'd products and things which MUA generally hates, and I do too. The products Paula's choice recommend I always, or usually, love.
They aren't as quickly updated as MUA when it comes to specific products. They hate Lush, but I have found some gems from there which haven't been reviewed on BP website.
They tend not to review the smaller indie brands, but I can search the ingredients dictionary and antioxidant info to get a sense of the benefits of the smaller skincare lines.
As for their videos/radio shows (you can get the link to hear the recordings as well as read the transcripts), there's good info there too, although I do think they tend to pooh-pooh DIY a tad too much. For instance they dismissed henna as 'drying' because 'the women I saw growing up...' Etc, but properly used, henna can coat your hair shaft, strengthen hair, add gloss just like any good deep conditioner, and mixed with beneficial oils offsets the brittle look that you get from improper use. Also using cassia or indigo blends, you can completely avoid the flaming red collur and get various shades of brown and even strawberry blonde or black. It even adds a bit of a low SPF protection, which Paula is relentlessly obsessed with. Similarly, they dismiss DiY vit C serums because the alcohol used is damaging for skin but most diy vit c serum recipes i see on mua don't contain alchohol. There is an element of snobbish disdain which kind of blinds them to giving a fair overview of the Diy side of things. I feel like they don't delve into researching homemade treatments or indie brands enough, but fair enough, that's not really their aim anyway.
Their articles have helped me pick out effective fproducts for hair, skin, makeup. It is a great resource combined with MUA for a broader range of opinions and experiences. I don't understand the bad reviews at all.... The reviewers always leave a margin for preference, but with makeup it's obvious they prefer a certain aesthetic. So what? It's actually changed over time now they give equally high ratings to shimmer and brights. They always mention products other than their own. If you think they are too biased towards PC items you haven't seen their videos. They sometimes mention PC products not being optimal for them. E.g one of them mentioned that the PC array of sunscreens don't work for him, the finish or feel of them, so he goes for Skinceuticals. There are more examples of this type of honest feedback.
Have not purchased even one PC item and have used Beautypedia as a resource for years.
on 1/24/2015 11:07:00 AM
Age: 44-55
Skin: Combination, Fair-Medium, Not Sure
Hair: Brunette, Other, Other
Eyes: Brown
Paula has saved my skin more than once. In the late 90's, I read her book, "Don't Go to the Cosmetics Counter Without Me," and learned why all of the acne products never worked at clearing up my skin. Even worse, they were breaking me out even more. So basically, I was paying money for more acne. I started using the cleansers she recommended, then purchased her BHA 2% Gel when she first came out with it in the late 90's. This has kept my skin clear for more than 15 years. Yes, I'm 55 and I still break out.
Now, I have new issues. I've suddenly developed very sensitive skin. Everything she has said about fragrance, plant and chemical, has proven true for me. It breaks me out horribly around my eyes. I can't even use it in my shampoos and conditioners. The Ingredient Dictionary on her website has been a skin lifesaver for me. On a side note, my skin and hair have never looked better using completely fragrance free products.
I've also found her reviews on makeup to be accurate about 90% of the time. I'll buy a product some You Tuber recommends, then find it doesn't work for me. I'll look it up on Beautypedia, and will discover a poor or average review. I don't always agree with her reviews on her own makeup products. I think that's an area where that still needs some work.
I also like the company's honesty over how much their products can do for you. If you watch their Q&A You Tube videos, they admit the limits, and that it's not Botox in a jar.
Do I consider them infallible or completely unbiased? No. However, no one on the planet is infallible or unbiased. I appreciate what Paula has done for the skincare industry, and I think we've all benefitted, whether you use her products or not.
on 1/24/2015 10:11:00 AM
Age: 36-43
Skin: Combination, Fair-Medium, Not Sure
Hair: Brown, Other, Other
Eyes: Blue
While I find some of Paula's reviews to be over the top with the warnings about fragrance and natural oils, I do regard Beautypedia as a fantastic resource for sensitive skin care products.
I have purchased many products based on the "Best" rating and found them to be very effective. I do hesitate to purchase any product that she has given a poor rating to, and I really appreciate the ingredients list. Several products I used to wear were loaded with alcohol, and I had no idea until I read the review on Beautypedia.
My skin has improved since switching to alcohol-free products (less dry patches and sensitivity) and I am much more aware of the ingredients to avoid now.
My only issue with the website is that makeup reviews only give the perspective from one person, and makeup is such a YMMV item that you do need several reviews to get a feel for a product, hence my love for MUA.
So MUA and Beautypedia together give me a wide range of viewpoints plus a comprehensive ingredients list and products to avoid. I do check Beautypedia daily for new product reviews, and I am so glad that this website exists.
on 1/24/2015 1:02:00 AM
Age: 19-24
Skin: Combination, Fair-Medium, Not Sure
Hair: Brunette, Wavy, Other
Eyes: Blue
I really like Paula's reviews. I have very sensitive combination skin so her reviews have been of great use to me with finding products that will work for me. Many of her reviews also helped me to understand why previous products that I was using were causing irritation to my skin (looking at you, Lush's Celestial moisturizer and Philosophy's Purity face wash).
She is indeed very biased towards her own products but I would expect that from someone who made their own products. She does however give credit to other brands when they create something truly exceptional, and because of that I have found products that ended up working for me because of Paula (Kiss My Face sunscreen, Olay sensitive face wash, Eucerin daily replenishing lotion, the list goes on).
If Paula and MUA both have good reviews about a product, then it helps me to feel more comfortable about purchasing the product.
on 1/24/2015 12:25:00 AM
Age: 19-24
Skin: Very Dry, Fair, Not Sure
Hair: Blond, Other, Other
Eyes: Blue
Honestly, I'm at a loss why people are bashing Paula Begoun so much. Before I learned of Beautypedia, I primarily read reviews of beauty products by consumers, which yes, many times was helpful, especially with makeup, but after trying countless popular skin- care products, my face was still a red, flaky, pimply mess. It made perfect sense to go to Beautypedia, because, after all, everyone wants what is best for their skin, and Paula's reviews are backed by science- what ingredients have proven to irritate skin and what ingredients help it function more normally. Not every one of her recommendations has worked miracles for me, but in general, her research is solid, and my skin is nowhere near as bad as it used to be. If you take her reviews with a grain of salt like you should with everything, this website will prove very handy for you.
on 1/8/2015 5:31:00 PM
Age: 36-43
Skin: Dry, Fair-Medium, Not Sure
Hair: Brown, Other, Other
Eyes: Brown
So when you go shopping for a product, do you step into the stores of certain brands and ask them to rate the products of other companies? I didn't think so. Why would you do it with Paula?
on 1/1/2015 1:14:00 PM
Age: 19-24
Skin: Combination, Fair, Neutral
Hair: Brunette, Other, Other
Eyes: Other
Having a scientist or research papers to quote does not a reliable source make, nor does it mean the conclusion is correct. Bottom line is that any personailty, guru or otherwise, has a stake in making money. I would suggest EWG website over Paula's after having a look through. http://www.ewg.org/skindeep/
on 1/1/2015 11:44:00 AM
Age: 19-24
Skin: Normal, Fair, Not Sure
Hair: Brown, Other, Other
Eyes: Green
I really don't understand why so many people hate her.
Sure, when creating your own line of cosmetic products you might fall into the same mistakes that the other companies you are criticizing made, but as common sense suggests, we all have to take reviews (from ANYONE) with a grain of salt.
--Edit: what I mean is: if a product contains a potential irritant ingredient, she can't say "oh hey use it as you please you definetly won't get a reaction from it!" Because there are people out there that will. But how common sense suggests, if you know that your skin is not sensitive, and the only drawback of the said product is that irritant ingredient, then you can do the math yourself and buy it. That's commonsense. I see many people criticizing Paula for rating products as "poor" when then can be good for some people and I really don't get it.--
what I think she is trying to do is EDUCATING consumers: that's why she's fighting against emotional marketing and one-star-ingredient skin care lines! brands worldwide are always trying to convince us to buy more and more things we don't need by putting exotic and fascinating ingredients in them, such as argan oil (which is an absolutely plain oil alike many others, now WAY overpriced thanks to marketing) or goji extact and so on.
remember: companies may have scientist working for them, but that's exactly why they should not be trusted in totum: they work to make the company earn more money. if a lower quality ingredient is cheaper, they won't really take into consideration the fact that it could irritate consumers' skin in the long run.
plus, she was one of the first to fight against fragrance-free products (remember, fragrance might not irritate YOUR skin, but it does have a huge potential irritant effect on many people, and this is why companies should not use it, hence the bag rating. just because YOUR skin didn't react it does not mean that that product is safe for everyone!), alcohol free skin care, sunblocks, jar packaging and so on.
personally, when eyeing a new product, I always look it up on beautypedia. that does not mean that I take her word like liquid gold and neither should you, but she and her team sure know better than me and most of you all how to read and ingredient list and how will they work and react to one another and how a product will work.
plus, nowadays there are way too many "beauty gurus" here on the internet that talk like they got a degree in chemistry and cosmetology, so it's nice to have someone who makes an attempt to tell you the truth and quotes scientific papers to prove himself.
Yes, she has her own standards and rate products based on those standards, and if you don't agree with them well that doesn't mean she is wrong anyway, you two just have different opinions on what a good product should be/contain.
overall, I think that what Paula's trying to do is educating comsumers, and if she's not perfect, well no one is.
(this is not a review on paula's products but only on Beautipedia. I personally find that many people are reviewing both in this thread)
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Revision Information
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- Review Date: 08/2015 -
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Welcome to the Star Formation Group
We study the physics of star formation from 100AU to 100kpc scales, from individual protostars in our Galaxy to compact groups of galaxies. This breadth allows us to ground galaxy-scale star formation in an understanding of the microphysics, and place individual nearby regions in broader environmental context. We use observational techniques from X-ray to centimeter, with particular recent focus on infrared and (sub)millimeter, as well as radiative transfer and other numerical models.
HERACLES Adam Leroy PI'd the HERACLES survey, now available through their online database. The HERA CO-Line Extragalactic Survey (HERACLES) is a Large Program that used the IRAM 30-m telescope to map CO emission from 48 nearby galaxies. As the second most common molecule, CO acts as our primary tracer of molecular, star-forming gas in galaxies. HERACLES covered a wide area in each target (out to the 'optical' radius, r25) with good sensitivity. We built HERACLES to complement THINGS, SINGS, and associated surveys. As a result we know the detailed distributions of atomic gas (HI), infrared, ultraviolet, and optical light across each galaxy. This makes HERACLES a powerful data set to study the formation of stars from molecular gas, the assembly of molecular clouds out of atomic gas, the distribution of matter (dark, light, stellar, and gaseous) in galaxies, and the dynamics and structure of the interstellar medium.
Faculty and Staff
- Crystal Brogan (NRAO)
- Jennifer Donovan Meyer (NRAO)
- Todd Hunter (NRAO)
- Remy Indebetow
- Kelsey Johnson
- Duncan Christie
- Amanda Heiderman
- Amandy Kepley
- Sabrina Stierwalt
Grad Students
- Loreto Barcos
- Lauren Bittle
- Cheoljong Lee
- Sandy Liss
- Kim Sokal
Former Members
- Natalie Butterfield
- Rosie Chen
- Ian Czekala
- William Dirienzo
- Meredith Drosback
- Amanda Kepley
- Adam Leroy
- Paul Martini
- Josh Nunn
- Karin Öberg
- George Privon
- Amy Reines
- Scott Schnee
- Lisa May Walker
- David Whelan
- Catherine Zucker
Star Formation at UVa+NRAO Projects
Compact Groups of Galaxies
How does star formation and gas processing proceed in these systems reminiscent of the era of galaxy formation? What is the relationship between the evolutionary states of compact groups and their gas and dust content? How is this affected by multiple simultaneous interactions?
Recent Papers
- Walker et al. (2013) "The Optical Green Valley versus Mid-infrared Canyon in Compact Groups"
- Walker et al. (2012) "Examining the Role of Environment in a Comprehensive Sample of Compact Groups"
- Walker et al. (2010) "Mid-Infrared Evidence for Accelerated Evolution in Compact Group Galaxies"
- Gallagher, Johnson, et al. (2008) "The Revealing Dust: Mid-Infrared Activity in Hickson Compact Group Galaxy Nuclei"
- Johnson et al. (2007) "The Infrared Properties of Hickson Compact Groups"
Nearby Luminous and Ultra-Luminous Infrared Galaxies
What is the true distribution of the star formation in these compact, dust embedded systems? How does the range in star formation rate surface density compare with theoretical estimates? Are these systems producing stars at the Eddington limit set by radiation pressure on dust? What is powering their luminosities?
GOALS website
Recent Papers
- Barcos-Muñoz, L. et al. (2015) "High Resolution Radio Continuum Measurements of the Nuclear Disks of Arp 220"
- Stiwerwalt, S. et al. (2014) "Mid-IR Properties of LIRGs II: Probing the Dust and Gas Physics of the GOALS Sample"
- Stierwalt, S. et al. (2013) "Mid-Infrared Properties of Nearby Luminous Infrared Galaxies. I. Spitzer infrared Spectrograph Spectra for the GOALS Sample
- Privon, G., C. et al. (2013) "Dynamical Modeling of Galaxy Mergers Using Identikit"
- Leroy, A. et al. (2011) "Complex Radio Spectral Energy Distributions in Luminous and Ultraluminous Infrared Galaxies"
Resolved Nearby Galaxies
What determines the rates and history of star formation within galaxies? What are the extremes of this process, for example star formation at low metallicity (SMC) and tidal features (Magellanic Bridge)?
SAGE and HERITAGE projects
Recent Papers
- Andrews & Martini (2012) "The Mass-Metallicity Relation with the Direct Method on Stacked Spectra of SDSS Galaxies"
- Leroy et al. (2012) "Estimating the Star Formation Rate at 1 kpc Scales in nearby Galaxies"
- Schruba, Leroy et al. (2012) "Low CO Luminosities in Dwarf Galaxies"
- Bolatto, Leroy et al. (2011) "The State of the Gas and the Relation between Gas and Star Formation at Low Metallicity: The Small Magellanic Cloud"
- Leroy et al. (2011) "The CO-to-H2 Conversion Factor from Infrared Dust Emission across the Local Group"
- Kepley et al. (2011) "Unveiling Extragalactic Star Formation Using Radio Recombination Lines: An Expanded Very Large Array Pilot Study with NGC 253"
- Lawton et al. (2010) "Spitzer Analysis of H II Region Complexes in the Magellanic Clouds: Determining a Suitable Monochromatic Obscured Star Formation Indicator"
- Bigiel, Leroy et al.(2010) "Tightly Correlated H I and FUV Emission in the Outskirts of M83"
Super Star Clusters
What causes this most extreme mode of star formation? Where and what kinds of super star clusters form, what are their properties at the earliest evolutionary stages? What special physics arises in and near these extraordinary objects?
Recent Papers
- Whelan et al. (2011) "The Infrared Properties of Super Star Clusters: Predictions from Three-Dimensional Radiative Transfer Models."
- Brogan, Johnson, & Darling (2010) "Water Masers associated with Star Formation in the Antennae Galaxies"
- Reines et al. (2010) "The Importance of Nebular Continuum and Line Emission in Observations of Young Massive Star Clusters"
- Johnson, Hunt, & Reines (2009) "Probing Star Formation at Low Metallicity: The Radio Emission of Super Star Clusters in SBS 0335-052"
(Proto)stellar Feedback
What effects do protostars and young massive stars have on their circumstellar and interstellar medium? How does this regular further star formation? We are studying this in the Magellanic System on region and galaxy scales using primarily Spitzer and Herschel, and in Galactic molecular clouds with our own near-IR narrow-band survey of outflow activity. Under what circumstances does feedback lead to triggered star formation?
Recent Papers
- Indebetouw et al. (2014) "Dust Production and Particle Acceleration in Supernova 1987A Revealed with ALMA"
- Dirienzo et al. (2012) "Testing Triggered Star Formation in Six H II Regions"
- Desai et al. (2010) "Supernova Remnants and Star Formation in the Large Magellanic Cloud"
- Hony et al. (2010) "The Herschel revolution: Unveiling the morphology of the high-mass star-formation sites N44 and N63 in the LMC"
- Meixner et al. (2010) "HERschel Inventory of The Agents of Galaxy Evolution (HERITAGE): The Large Magellanic Cloud dust"
- Kemper et al. (2010) "The SAGE-Spec Spitzer Legacy Program: The Life Cycle of Dust and Gas in the Large Magellanic Cloud"
- Indebetouw et al. (2009) "Physical Conditions in the Ionized Gas of 30 Doradus"
- Rubin et al. (2009) "A spatially resolved study of photoelectric heating and [C II] cooling in the LMC. Comparison with dust emission as seen by SAGE"
Formation of Massive Stars
Massive stars drive the evolution of the visible universe - does their formation require different physics from solar-mass stars? What can we learn from the highest-resolution observations of young massive stars, and from their outflows and environments in our Galaxy and the Magellanic System? What properties of a molecular cloud lead to massive star and cluster formation, contrasted with distributed low-mass star formation?
Recent Papers
- Chen et al. (2010) "Spitzer View of Young Massive Stars in the Large Magellanic Cloud H II Complexes. II. N 159"
- Romita et al. (2010) "Young Stellar Objects in the Large Magellanic Cloud Star-forming Region N206"
- Sewiło, Indebetouw et al. (2010) "The youngest massive protostars in the Large Magellanic Cloud"
- Fleener et al. (2010) "Massive Star Formation in NGC 2074"
- Vaidya et al. (2009) "A Hubble Space Telescope View of the Interstellar Environments of Young Stellar Objects in the Large Magellanic Cloud"
- Oliveira et al. (2009) "Ice Chemistry in Embedded Young Stellar Objects in the Large Magellanic Cloud"
- Brogan et al. (2009) "Digging Into NGC 6334 I(N): Multiwavelength Imaging of a Massive Protostellar Cluster"
- Seale et al. (2009) "The Evolution Of Massive Young Stellar Objects in the Large Magellanic Cloud. I. Identification and Spectral Classification"
- Povich et al. (2009) "The Extended Environment of M17: A Star Formation History"
- Chen et al. (2009) "Spitzer View of Young Massive Stars in the Large Magellanic Cloud H II Complex N 44"
- Churchwell et al. (2009) "The Spitzer/GLIMPSE Surveys: A New View of the Milky Way"
Chemistry and Star Formation
The formation of stars (and planets) is accompanied by molecular formation and destruction. The chemistry of many species depends strongly on the local environment and how this environment has evolved. Molecular spectra can therefore be used as probes of key aspects of star formation, from cloud formation and evolution, through cloud collapse and the protostellar phase, to the formation of accretion disks and planetary systems. Within the star formation group we observe molecular spectral features from IR to mm wavelengths to explore the evolution of molecular clouds and protostars, and to test our chemical understanding of proposed molecular probes.
Astrochemistry Group
Recent Papers
- Öberg et al. (2011) "The Spitzer Ice Legacy: Ice Evolution from Cores to Protostars"
- Öberg et al. (2011) "Complex Molecules toward Low-mass Protostars: The Serpens Core"
- Öberg et al. (2010) "A Cold Complex Chemistry Toward the Low-mass Protostar B1-b: Evidence for Complex Molecule Production in Ices"
- Schnee et al. (2012) "An Observed Lack of Substructure in Starless Cores. II. Super-Jeans Cores"
- Schnee et al. (2012) "How Starless are Starless Cores?"
- Schnee et al. (2010) "An Observed Lack of Substructure in Starless Cores"
- Schnee et al. (2010) "The Dust Emissivity Spectral Index in the Starless Core TMC-1C"


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Aug 13, 2012
Commentary by Stephen Downes
The question of free speech is an issue both in online discussions and in edcuational institutions. And with the fluid state of governance worldwide - from Russia to Egypt to Singapore - the question of what sort of speech ought to be allowed, and what sort prohibvited, occupies all nations. Few supposes that all speech ought to be allowed; even those radical supporters of unrestrained expression (mostly south of the border here) bristle when you challenge their core beliefs. To my mind, the line is a simple one, though in prasctice not always easy to discern: the only speech that should be prohibited is a speech act, and the only act that should be prohibited is one which deliberately causes harm to another.


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NFL Nation
Print without images
Tuesday, October 9, 2012
Report: Saints' punishment coming shortly
By Pat Yasinskas
Huddle up again because, for the second time, NFL commissioner Roger Goodell is expected to announce player punishments in the alleged New Orleans Saints bounty program.
ESPN's Adam Schefter reports an announcement is coming momentarily. Goodell initially issued suspensions for four players, but the punishments were set aside momentarily while an appeals board asked the commissioner to look at his decision again.
As soon as I get the official announcement, I'll be back with analysis.


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Lightweight TOF Mass Spectrometer with Atmospheric Pressure Inlet
Award Information
Small Business Information
Msp Corp
1313 Fifth Street Se, Suite, 206, Minneapolis, MN, 55414
Principal Investigator:
David Thimsen
(612) 379-3963
(612) 379-3963
Business Contact:
() -
Research Institution:
AbstractThe objective of the proposed work is to design a lightweight mass spectrometer system based on a time of flight mass spectrometer with atmospheric pressure ion source. It is expected that this device will be able to measure ppb concentrations of atomic species in the 50-300 charge-to-atomic mass ratio range. Supporting electronics will be engineered from experience on constructing electronics packages for rocket launching into the upper atmosphere of Earth and Mars. The supporting vacuum system will be engineered as part of the entire package. Design limitations for the package are a maximum weight of 20lb, maximum power consumption of 250 wt.
* information listed above is at the time of submission.
An Official Website of the United States Government


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|Número de publicación
|Tipo de publicación
|Número de solicitud
|Fecha de publicación
|31 Mar 1992
|Fecha de presentación
|7 Jun 1989
|Fecha de prioridad
|9 Jun 1988
|También publicado como
|Número de publicación
|Michael Schreck, Volker Dolle
|Cesionario original
|Hoechst Aktiengesellschaft
|Exportar cita
|BiBTeX, EndNote, RefMan
|Citas de patentes (10), Citada por (31), Clasificaciones (12), Eventos legales (4)
|Enlaces externos: USPTO, Cesión de USPTO, Espacenet
The present invention relates to a process for the preparation of a polypropylene having a narrow molecular weight distribution and good processing properties.
A catalyst system using which polypropylene is obtained with good isotacticity and high yield is known (cf. German Offenlegungsschrift 3,241,999). The catalyst system comprises the following components (A), (B) and (C):
(A) a solid component, containing magnesium, titanium, halogen and an ester, the component being obtained by bringing a solution of (i) a magnesium compound into contact with (ii) a liquid titanium compound in the presence of (D) at least one electron donor and, during or after the formation of the solid product (A), into contact with (E) an ester,
(B) an organometallic compound of a metal of groups I to III of the Periodic Table, and
(C) an organosilicon compound containing an Si-O-C bond or an Si-N-C bond.
Due to its molecular weight distribution, however, the polymer obtained using this catalyst s rheological properties which are unfavorable for a number of processing processes, for example injection molding, and which must be corrected by a work-up step by such as, for example, thermal degradation, following the polymerization.
Furthermore, a catalyst system is known which is obtained by reacting anhydrous magnesium chloride with an ester, ether or alkoxysilane compound, a titanium halide and an organoaluminum compound (cf. JP 58-65,709). Although the molecular weight distribution of the polypropylene obtained by means of this catalyst is narrow, the isotacticity is, however, still not adequate.
Another catalyst prepared from compounds of magnesium, titanium, silicon and aluminum gives polyolefins having a narrow molecular weight distribution and good isotacticity (cf. JP 62-179,511).
Furthermore, a catalyst system is known which contains a solid comprising magnesium chloride, titanium tetrachloride and an electron donor, a trialkylaluminum as cocatalyst and, in addition, two different stereoregulators (cf. EP-A 155,716). The catalyst system has acceptable polymerization activity, but the stereospecificity is not satisfactory.
The object was therefore to find a catalyst system which gives a high yield of polypropylene having a narrow molecular weight distribution and high isotacticity.
It has been found that a catalyst system based on a magnesium halide, an electron donor, a titanium compound, a trialkylaluminum and two different organosilicon compounds as stereoregulators is capable of achieving the object.
The invention thus relates to a process for the preparation of a polypropylene by homopolymerization of propylene or copolymerization of propylene with ethylene or a 1-olefin having 4 to 10 carbon atoms, in suspension or in the gas phase, at a temperature of from 40° to 100° C. and at a pressure of from 1 to 49 bar, in the presence of a catalyst comprising a transition-metal component (component A), obtained by reacting a magnesium halide first with at least one electron donor and then with a tetravalent titanium compound of the formula TiXm (OR1)4-m in which R1 is an alkyl radical having 2 to 10 carbon atoms, X is a halogen atom and m is a number from 0 to 4, in the presence of an ester of an aromatic carboxylic acid, and comprising a halogen-free organoaluminum compound (component B) and an organosilicon compound as stereoregulator (component C), which comprises carrying out the polymerization in the presence of a catalyst which contains two different organosilicon compounds having Si-0-C bonds as stereoregulator (components C and D).
For the preparation of component A, an anhydrous magnesium halide, such as magnesium chloride or magnesium bromide, preferably magnesium chloride, is employed.
The product of the reaction of the magnesium halide with the electron donor is prepared in a manner known per se in the presence of an inert solvent, for example by heating the magnesium halide in a solution of the coreactants or suspending the Mg halide in the liquid coreactant.
The molar ratio between the magnesium halide employed and the electron donor compound is greater than 2:1. A molar ratio of from 3 to 15:1 is preferred, and a molar ratio of from 4.5 to 8:1 is particularly preferred.
The electron donor compounds used are C1 -C20 -monocarboxylic acid esters, C1 -C20 -aliphatic carboxylic acids, C4 -C20 -carboxylic anhydrides, C3 -C20 -ketones, C2 -C16 -aliphatic ethers, C3 -C20 -aliphatic carbonates, alcohols containing a C3 -C20 -alkoxy group, alcohols containing a C3 -C20 -aryloxy group, organosilicon compounds having an Si-O-C bond, in which the organic group has 1 to 10 carbon atoms, and organophosphorus compounds having a P-O-C bond, in which the organic group has 1 to 10 carbon atoms.
Examples of suitable electron donors are methylpentanol, 2-ethylhexanol, 2-ethylhexanoic acid and phthalic anhydride.
A reactor fitted with stirrer, heating device and protective-gas blanket (N2, Ar) is used for the reaction. The reaction medium initially introduced is expediently the dispersant also used in the polymerization. Suitable dispersants are aliphatic or cycloaliphatic hydrocarbons, such as butane, pentane, hexane, heptane, cyclohexane, methylcyclohexane, isooctane and aromatic hydrocarbons, such as benzene, toluene and xylene; it is also possible to use petroleum fractions and hydrogenated diesel oil fractions which have been carefully freed from oxygen, sulfur compounds and moisture. The dispersant must not contain any compounds having double bonds. The reaction is carried out at a temperature of from 0° to 200° C., preferably 30° to 150° C.
Depending on the reactivity of the reactants, the reaction time is 0.5 to 5 hours, preferably 1 to 3 hours. The solution obtained is then cooled.
The complex obtained in this manner is reacted immediately with a tetravalent titanium compound of the formula TiXm (OR1)4-m in which R1 is an alkyl radical having 2 to 10 carbon atoms, X is a halogen atom, preferably chlorine, and m is an integer from 0 to 4, but preferably 2 or 4. It is possible to employ a mixture of several of these compounds.
Examples of preferred compounds are TiCl4, TiCl3 (OEt), TiCl3 (O-iPr), TiCl2 (OEt), TiCl2 (O-iPr)2, TiCl2 (O-CH2 C6 H5)2, TiCl(O-iBu)3, Ti(OEt)4, Ti(O-Pr)4 or Ti(O-iPr)4.
Very particularly preferred compounds are TiCl4, TiCl2 (OEt)2 and Ti(OEt)4, or a mixture of these compounds.
In the reaction described above, the titanium compound is employed in an amount of from 0.1 to 2 moles, preferably 0.8 to 1.8 moles, based on one gram-atom of magnesium in the complex. The reaction temperature is 30° to 150° C., preferably 60° to 120° C., and the reaction time is 30 minutes up to several hours, preferably 1 to 5 hours.
The reaction is carried out in the presence of an ester of a polyhydroxyl compound, in particular an ester of a C6 -C16 -aromatic polyhydroxyl compound with a C1 -C12 -aliphatic carboxylic acid. Preferred compounds of this type are diesters of phthalic acid with a C1 -C12 -aliphatic or aromatic alcohol, for example diethyl phthalate or diisobutyl phthalate.
The catalyst component A prepared in this manner is finally freed from soluble impurities, such as metal or halogen compounds, by repeated washing with an inert hydrocarbon at a temperature of from 0° to 100° C., preferably 10° to 50° C.
Suitable halogen-free organoaluminum compounds (component B) are, in particular, branched, unsubstituted alkylaluminum compounds of the formula AlR3 where R denotes an alkyl radical having 1 to 10 carbon atoms, such as, for example, trimethylaluminum, triethylaluminum, triisobutylaluminum and tridiisobutylaluminum. Further suitable compounds are the products of the reaction of triisobutylaluminum or diisobutylaluminum hydride and isoprene, which are commercially available under the name isoprenylaluminum. Triethylaluminum and triisobutylaluminum are particularly suitable.
The catalyst components C and D are organosilicon compounds of the formula Rn 2 Si(OR3)4-n, in which R2 denotes a C1 -C10 -alkyl group, C5 -C12 -cycloalkyl group, C6 -C20 -aryl group, C1 -C10 -alkenyl group, C1 -C10 -haloalkyl group or C1 -C10 -amino group, R3 denotes a C1 -C10 -alkyl group, C5 -C12 -cycloalkyl group, C6 -C20 -aryl group, C1 -C10 -alkenyl group or C2 -C16 -alkoxyalkyl group, and n denotes an integer, and the R2 groups or (4-n) OR3 groups may be identical or different.
Examples of components (C) and (D) are organosilicon compounds, such as trimethylmethoxysilane, trimethylethoxysilane, dimethyldimethoxysilane, dimethyldiethoxysilane, diphenyldimethoxysilane, methylphenyldimethoxysilane, diphenyldiethoxysilane, ethyltrimethoxysilane, methyltrimethoxysilane,vinyltrimethoxysilane,phenyltri-methoxysilane, γ-chloropropyltrimethoxysilane,methyltriethoxysilane,ethyltriethoxysila butytriethoxysilane, phenyltriethoxysilane, γ-aminopropyltriethoxysilane, chloropropyltriethoxysilane, cyclohexylmethyldimethoxysilane, cyclohexylmethyldiethoxysilane, di-n-octyldimethoxysilane, di-n-octyldiethoxysilane, i-octyltrimethoxysilane, i-octyltriethoxysilane, methylphenyldiethoxysilane, dibutyldimethoxysilane, dibutyldiethoxysilane, di-i-butyldimethoxysilane, di-i-butyldiethoxysilane, di-t-butyldimethoxysilane, di-t-butyldiethoxysilane, t-butyltrimethoxysilane, t-butyltriethoxysilane, di-p-toluyldimethoxysilane, di-p-toluyldiethoxysilane, dicyclohexyldimethoxysilane, dicyclohexyldiethoxysilane, ethyltriisopropoxysilane, vinyltributoxysilane, ethyl silicate, butyl silicate, trimethylphenoxysilane, methyltriallyloxysilane, vinyltris(β-methoxyethoxy)silane, vinyltriacetoxysilane, dimethyltetraethoxydisilane and phenyldiethoxydiethylaminosilane.
Of these, methyltrimethoxysilane, phenyltrimethoxysilane, methyltriethoxysilane, ethyltriethoxysilane, phenylmethyldiethoxysilane, cyclohexylmethyldimethoxysilane, cyclohexylmethyldiethoxysilane, vinyltriethoxysilane, phenyltriethoxysilane, vinyltributoxysilane, ethyl silicate,diphenyldimethoxysilane,diphenyldiethoxysilane and methylphenyldimethoxysilane are preferred.
Diphenyldimethoxysilane, diphenyldiethoxysilane, cyclohexylmethyldimethoxysilane, cyclohexylmethyldiethoxysilane, phenyltrimethoxysilane and phenyltriethoxysilane are particularly preferred.
Component D is always different from component C.
Component A is employed for the polymerization of propylene in the form of a suspension in an inert hydrocarbon or alternatively in dry form after removal of the suspension agent. The copolymerization of propylene with ethylene and/or a 1-olefin having 4 to 10 carbon atoms and one or more double bonds, for example 1-butene, isobutene, 1-hexene or 1,3-butadiene, is also possible.
The process according to the invention can be carried out in one or several steps in the gas phase, in the liquid monomer or in a solvent which is inert and liquid at the reaction temperature under atmospheric pressure, it being possible to carry out the reaction either continuously or batchwise. The polymerization is preferably carried out in the liquid monomer.
The catalyst concentration is selected at a level which is customary for a propylene polymerization. The concentration of component A is therefore 0.001 to 1 mmol/dm3, based on titanium, preferably 0.001 to 0.1 mmol/dm3.
Component B is initially introduced in a concentration of from 0.001 to 5 mmol/dm3, preferably 0.1 to 5 mmol/dm3, component C in a concentration of from 0.003 to 2 mmol/dm3, preferably 0.03 to 1.2 mmol/dm3, and component D in a concentration of from 0.003 to 2 mmol/dm:, preferably 0.03 to 1.2 mmol/dm3. The molar ratio between components C and D can vary here from 1:99 to 99:1. A ratio of from 20:80 to 80:20 is preferred. The polymerization is carried out by pumping liquid propylene, a suspension of the solid catalyst component in an inert suspension agent, and the other liquid catalyst components into a suitable reaction vessel. This reaction vessel can be an autoclave, a customary reactor or a tubular reactor in coil form, adequate mixing being ensured as usual by built-in stirrers or circulation pumps.
The heat of reaction is dissipated by jacket cooling, by internal cooling built into the vessels or by evaporative cooling.
The liquid propylene itself, which serves both as the monomer and as the suspension agent, can contain varying amounts of inert, low-boiling, dissolved components, such as, for example, propane or nitrogen, but these have no effect on the products produced in this process.
A reaction temperature of from 40° to 100° C., preferably a reaction temperature of from 50° to 75° C., is maintained. The pressure is 1 to 49 bar, preferably 20 to 35 bar.
The establishment of the molecular weight desired for the polymer is effected by adding hydrogen to the batch. The amount added is adjusted so that the product produced has a melt flow index MFI 230/5 of from 0.05 to 5000 g/10 min.
After the polymerization has been carried out, the polymer produced is separated off from the suspension agent and the other soluble reaction products. This can be effected by a filtration, decantation or centrifugation step in pressure-tight units which are suitable for this purpose, for example in pressure filters, sedimentation towers, centrifuges or decanters. In order to complete the removal of the soluble reaction products, separation can be preceded by a washing step in which the suspension is subject, for example, to a countercurrent wash with fresh liquid propylene. The washing and separation can also be carried out in a single unit which carries out both tasks, such as, for example, a washing and sedimentation tower operating on the countercurrent principle. In this case, a greatly thickened suspension of the polymer powder in substantially pure suspension agent is withdrawn at the lower end of the tower.
As a consequence of the very high activity of the catalyst employed according to the invention, it is generally not necessary to remove catalyst residues. If, however, an extremely low content of catalyst residues should be desired, a vessel in which improved removal of catalyst residues is effected at a temperature of from 50° to 80° C., preferably 60° to 70° C., by adding hydrogen-acidic compounds which decompose the organoaluminum compounds and simultaneously complex the magnesium halide present in the polymer powder, can be introduced between the second polymerization step and the separation step. Examples of suitable compounds of this type are higher aliphatic carboxylic acids, such as 2-ethylhexanoic acid.
The propylene-moist polymer powder obtained after the liquid components have been removed is now dried completely.
The process according to the invention thus makes it possible to prepare propylene homopolymers and copolymers with a high catalyst yield and high isotacticity, it being possible to control the molecular weight distribution of the polymer through a suitable choice of catalyst components C and D and the concentration ratio thereof.
The properties of the polymers prepared in accordance with the examples below were determined individually by the following methods:
The melt flow index MFI 230/5 was measured in accordance with DIN 53 735 and is given in g/10 min.
The molecular weight distribution Mw /Mn was determined by gel permeation chromatography at 150° C. using 1,2-dichlorobenzene as the solvent.
9.52 g (100 mmol) of anhydrous magnesium chloride, 50 cm3 of decane and 46.8 cm3 (300 mmol) of 2-ethylhexyl alcohol were reacted for 2 hours at 130° C., during which time the magnesium chloride dissolved. 2.22 g (15.0 mmol) of phthalic anhydride were added to the solution. The mixture was stirred for a further 1 hour at 130° C. until the phthalic anhydride had dissolved. The solution obtained was cooled to room temperature and added dropwise over the course of 1 hour to 400 cm3 (3.6 mol) of titanium tetrachloride at -20° C., after which the mixture was heated to 110° C. over the course of 4 hours. When the temperature of 110° C. had been reached, 5.36 cm3 (25.0 mmol) of diisobutyl phthalate were added. The mixture was kept at this temperature with stirring for a further 2 hours. The batch was then filtered while hot, and the solid component was re-suspended in 400 cm3 of titanium tetrachloride and reacted for 2 hours at 100° C. The solid was then collected by hot filtration and washed with decane and hexane at 100° C. until free titanium compound could no longer be detected in the washing solvents.
The solid catalyst component A obtained in this way was stored in the form of a suspension in hexane. Some of the suspension was dried in order to investigate the composition of the catalyst. Analysis gave 2.5% by weight of titanium, 56.4% by weight of chlorine, 17.5% by weight of magnesium and 21.0% by weight of diisobutyl phthalate.
In a reactor with a capacity of 70 dm3 fitted with an impeller stirrer, 15 dm3 (s t.p.) of hydrogen and 40 dm3 of liquid propylene were initially introduced, and 200 mmol of triethylaluminum, 20 mmol of phenyltriethoxy-silane 20 mmol of cyclohexylmethyldimethoxysilane and 2.83 cm3 of the above catalyst suspension (100.04 mmol of Ti) were metered in successively. The reactor contents were then heated to 70° C. and kept at this temperature for 60 minutes. After the mixture had been cooled and excess monomer had been evaporated, 2.42 kg of polypropylene were obtained. The polymer had an MFI 230/5 of 19.5 g/10 min, a xylene-soluble content of 1.8% by weight and an Mw /Mn value of 4.7.
The example was repeated, but 37 dm3 (s.t.p.) of H2 were initially introduced and the two silanes were replaced by 40 mmol of phenyltriethoxysilane. 1.28 kg of polymer having an MFI 230/5 of 13.5 g/10 min, a soluble content of 2.7% by weight and an Mw /Mn value of 7.2 were obtained.
Comparative Example A was repeated, but the silane used was replaced by 40 mmol of cyclohexylmethyldimethoxysilane. 1.66 kg of polymer having an MFI 230/5 of 17.4 g/ 10 min, a soluble content of 2.4% by weight and an Mw /Mn value of 7.3 were obtained.
|Patente citada
|Fecha de presentación
|Fecha de publicación
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|18 Sep 1984
|Montedison S.P.A.
|Components and catalysts for the polymerization of olefins
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|22 Sep 1987
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|13 Ago 1981
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|Components and catalysts for the polymerization of olefins
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|Título no disponible
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|Dow Global Technologies Inc.
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|17 Sep 2004
|17 Feb 2009
|Dow Global Technologies Inc.
|Self limiting catalyst composition and propylene polymerization process
|27 May 2004
|21 Abr 2009
|Union Carbide Chemicals & Plastics Technology Llc
|Catalyst composition and polymerization process using mixture of silane electron donors
|12 Ene 2009
|16 Mar 2010
|Dow Global Technologies Inc.
|Self limiting catalyst composition and propylene polymerization process
|24 Jun 2008
|30 Mar 2010
|Dow Global Technologies Inc.
|Catalyst composition with monocarboxylic acid ester internal donor and propylene polymerization process
|12 Ene 2009
|24 Ago 2010
|Dow Global Technologies Inc.
|Self limiting catalyst composition and propylene polymerization process
|10 Mar 2003
|25 Ene 2011
|Bassell Poliolefine Italia S.P.A.
|Polypropylene resin composition and film thereof
|4 Ago 2010
|2 Ago 2011
|Dow Global Technologies Llc
|Self limiting catalyst composition and propylene polymerization process
|28 Abr 2010
|24 Ene 2012
|Iris Engines, Inc.
|Radial impulse engine, pump, and compressor systems, and associated methods of operation
|10 Mar 2003
|28 Jul 2005
|Tetsuya Fudaba
|Polypropylene resin composition and film thereof
|20 May 2003
|27 Jul 2006
|Linfeng Chen
|Catalyst composition and polymerization process using mixtures of selectivity control agents
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|5 Oct 2006
|Linfeng Chen
|Catalyst composition with mixed sca and propylene polymerization process
|27 May 2004
|23 Nov 2006
|Wilson Stanley E
|Catalyst composition and polymerization process using mixture of silane electron donors
|15 Nov 2001
|4 Jul 2002
|Exxonmobil Chem Patents Inc
|Multi-donor catalyst system for the polymerization of olefins
|17 Sep 2004
|7 Abr 2005
|Dow Global Technologies Inc
|Self limiting catalyst composition and propylene polymerization process
|18 Ago 2004
|21 Abr 2005
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|Self-extiguishing catalyst compostion with monocarboxylic acid ester internal donor and propylene polymerization process
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|Catalyst composition with monocarboxylic acid ester internal donor and propylene polymerization process
|Clasificación de EE.UU.
|526/125.6, 526/351, 502/125
|Clasificación internacional
|Clasificación cooperativa
|Clasificación europea
|7 Jun 1989
Owner name: HOECHST AKTIENGESELLSCHAFT, D-6230 FRANKFURT AM MA
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNORS:SCHRECK, MICHAEL;DOLLE, VOLKER;REEL/FRAME:005088/0223
Effective date: 19890511
|7 Nov 1995
|Maintenance fee reminder mailed
|31 Mar 1996
|Lapse for failure to pay maintenance fees
|11 Jun 1996
|Expired due to failure to pay maintenance fee
Effective date: 19960403


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Here, fantastic recipes for sweet and colorful beets like delicious salads, healthy juices, refreshing chilled soups and more.
Beet-and-Red Sorrel Salad with Pistachio
More ∨
Sorrel is a leafy green that gives dishes a tart, almost sour flavor. For this salad, Paul Liebrandt likes using red ribbon sorrel—a European variety with bright green leaves and intense red veins—because it's so pretty with the beets and because its tang is so nice with the nutty pistachio sauce.


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I've written for a range of venues, academic journals, online, magazines, newspapers and an entire book. I write about toddlers, children, working mothers and parenting but never as a blog. On a daily basis, I observe or think about issues related to children or myself as a parent that I imagine would be interesting to a wider range of parents. Yet, I've never put the proverbial pen to paper until now.
I began writing How Toddlers Thrive on cross country airplane trips, to visit a cousin and her family. She was ill at the time (better now) and I wanted to help with their kids. The distance across country felt so far away, the only way to be a support was to be there in person. And anyhow, I had these ideas for a book. The plane rides became a bit of a haven for me. When you're a parent, there is little alone time. Before children, I had time before work, after work and in between as un-devoted time I could grab for myself. Since becoming a mother over 17 years ago, the allotment of the hours in the day changed. Work time, family time. So the plane ride provided me that 'other time', a captivated space without responsibilities. No laundry, bills to pay, piles of last week's mail or toys to put away. No distractions. Just stuck on an airplane. And I began to write a book. [Read more…]


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The Library will be closed
Monday, September 7th, 2015
for the Labor Day holiday
RSSC's Featured Image
Fejervary Park
Trees in fall color. Photo by Grover C. von der Heyde [Oct 1948]
Events Calendar
For your convenience, please explore our page of upcoming genealogical and local history events in the Quad-City area.
Be sure to mark these dates down in your own calendar!
Recent Posts
DPL on Social Media
Links of Interest
Tag Archives: Alfred Sanders
Davenport's first daily newspaper
Volume 1, Number 1 of the Daily Davenport Gazette* was published on Monday, October 16th, 1854. It was the first daily newspaper ever published in Davenport. The Gazette had been published weekly for the previous 13 years, and started out with about … Continue reading
Posted in Local History Tagged Alfred Sanders, Davenport (Iowa), Davenport Gazette, firsts, newspapers Leave a comment


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Aggregate Purchase Program for SANS Training
Steeply discounted pricing for exceptional SANS security awareness and technical training is available through REN-ISAC during special aggregate purchase periods. This offer is open only for accredited educational institutions, including universities, colleges, technical training institutes, and K-12 schools, in the United States and Canada.
The next purchasing window is scheduled for June 1, 2015 - July 31, 2015. For details on the specific offerings, visit:
|Online Technical Training and GIAC Certification
|Securing The Human - End User Awareness Training
|Securing The Human - Developer Training
|Securing The Human - Phishing
Webcast to Learn About the Program
On May 22, persons from SANS and REN-ISAC held a webcast to discuss the special offerings. Watch to learn how your institution can improve its security posture through SANS awareness and technical training, and how to take advantage of steeply discounted pricing during the partnership window.
This offer is valid for any accredited educational institution, including universities, colleges, technical training institutes, K-12 schools, or any institution with an .edu domain name, in the United States and Canada.
For more information on these programs, contact firstname.lastname@example.com.


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|No booking or creditcard fees!
|Best Price Guaranteed
La Mansarde
65 rue de Boulogne, 62170, Neuville-sous-Montreuil (View on the map)
Bed and Breakfast La Mansarde in Neuville-sous-montreuil is a B&B with 1 room.
La Mansarde is located in Neuville-sous-Montreuil, 14 km from Le Touquet-Paris-Plage and 29 km from Boulogne-sur-Mer.
Rooms have a flat-screen TV. La Mansarde features free WiFi .
Wissant is 46 km from La Mansarde, while Saint-Valery-sur-Somme is 34 km from the property.
Rooms have a flat-screen TV. La Mansarde features free WiFi .
Wissant is 46 km from La Mansarde, while Saint-Valery-sur-Somme is 34 km from the property.
Reservation possible without a credit card!
Facilities of La Mansarde
|Common areas
|Non-smoking rooms, Family rooms, Free parking, Heating, On-site parking.
|Internet services, WiFi, Free WiFi.
|Free! WiFi is available in public areas and is free of charge.
|Free public parking is possible on site (reservation is not needed).
Policies of La Mansarde
|17:00 - 17:30 hours
|10:00 - 11:00 hours
|Cancellation / prepayment
|Cancellation / prepayment
Cancellation and prepayment policies vary according to room type. Please enter the dates of your stay and check the conditions of your required room.
|Children and extra beds
All children under 2 years stay free of charge for children's cots/cribs.
The maximum number of extra beds in a room is 1.
Supplements are not calculated automatically in the total costs and will have to be paid for separately when checking out.
Any type of extra bed or child's cot/crib is upon request and needs to be confirmed by the innkeeper.
|Pets are not allowed.
|Accepted credit cards
|No credit cards accepted, only cash.
We guarantee
- Booking is safe. When you book with us your details are protected by a secure connection.
- Your privacy is protected. Your details will only be used to guarantee your booking.
- No booking fees. You only pay the bed & breakfast. Bedandbreakfast.eu will never charge your credit card.
- Best Price Guarantee. Found your room online at a lower price? We'll match it.
You'll find more information in our privacy statement and terms and conditions.
No pictures available
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Entrepreneurs invest many years building successful businesses. Selling your business, or buying an existing one, is a life-changing event. It is the mission of Truforte to help goal-oriented individuals realize their dreams. Our professionals have successfully handled hundreds of business sales throughout the USA for buyers and sellers. This provides valuable experience that better qualifies Truforte to help with the purchase or sale of your business entity. Business brokers are intermediaries who facilitate the sale of privately held businesses by working with both buyers and sellers. Confidentiality is critical to the successful transfer of a business. If it becomes known that a business is for sale, several things start happening and none of them are beneficial for either the seller or buyer of the business. Professional intermediaries are keenly aware of this and are experts at maintaining confidentiality. Truforte's professionals have decades of experience, handling the sale of hundreds of businesses in a wide range of size and industries.
Manchester, NH
Steal this Business. $350,000 is cheap for a turn key, walk right in and own an established location-with over 75 on-site parking spaces. There's plenty of room to expand for a function room, and even larger patio or nightclub/bar. Lease/Rent is negotiable and financing may be available for the right buyer. Are you ready to own and operate a turn-key business? What are you waiting for? Why buy a new place, with high rent and deal with the permitting process and the high costs of construction and purchasing equipment and hope customers will come? Where are you going to find a location with so much parking? Theo's is open-turn key- and ready for a new energetic owner. Let get this done! Don't miss out on this deal, it is a perfect place for someone who wants to own and operate a business and is willing to put in the time and effort.
Claremont, NH
This is an excellent opportunity for an experienced and/or first time owner going into a low risk and established profitable restaurant. Current owners are looking to grow and expand business but need someone invested to take ownership and manage one of their already profitable locations. Option to buy out current owners is a possibility. Financials are in order and available upon request. This restaurant has received many accolades including best chili, best burger challenge, best chowder and best night out by different publications and area competitions. This concept also receives 4.5 stars from Yelp and Trip Advisor customers. Two of our concepts have been consistently rated in the top 3 restaurants in the area.3
North Conway, NH
Located in one of New Hampshire's premiere tourist destinations, this local hot spot attracts a diverse crowd every night of the week. Dart league, pool league, nightly entertainment including bands, DJs, Open Mic, Karaoke etc. Billiards Hall liquor license means that food service is optional. We have a kitchen with fryolator, pizza oven, griddle, stove, freezer, fridge, prep station etc. Smoking section (indoors!) permitted under NH law. Consistent core business with upside growth potential! Owner bartender can bring home $100k annually. Owner is living out of state part time and wishes to move full time.
Rockingham County, NH
Outstanding Restaurant offers Eclectic American Cuisine with an authentic Mediterranean Flair in a "blue jean fine dining" venue. From fresh pasta, homemade fettuccine & meatballs, scampi, eggplant, steak, duck, lamb, chicken and salmon to light dining including angus burgers and smokehouse bacon, your palate can be rewarded in numerous ways. Happy Hour is from 4-6:00PM, Monday – Fridays and offers a cornucopia of refreshing drinks, tasty snacks and specials. Full service catering, hosted or prepared for delivery is available for small or large groups.
Portsmouth, NH
Wonderful opportunity to open your own restaurant and invest in real estate in downtown Portsmouth, NH. Portsmouth is one of the hottest small cities in the country with a thriving downtown dining, shopping and arts scene, lots of new commercial and residential development and an active tourist destination. During peaks seasons, it's not easy to get a table at a local restaurant. Many of the current restaurants downtown have been in existence for years and their sales have only grown with the town's popularity. There is plenty of room for a new player, with a strong vision and quality food. Only two years ago this restaurant underwent a $600,000 renovation. The interior is in mint condition and a new owner could get up and running in few weeks. It is on one of the best blocks in the town surrounded by great restaurants, shops, entertainment venues and several hotels. As of July 2013, the real estate is valued on town books for over $1 million. The real estate market has been really strong in Portsmouth. A terrific investment. Restaurant and Property is being offered without anything in it for $1.1 Million or $1.3 Million with everything (over $600K in leasehold, equipment etc. - all of which is in mint condition). Negotiable!
Strafford County, NH
Business is a neighborhood restaurant and bar serving American, Italian, and Chinese cuisine. The place is cozy with the lounge with full bar, TVs, & digital jukebox to the left side and separated dining room to the right. The lounge is visible from the dining room through glass windows and door. Though separated dining areas, the place shares a common atmosphere. The menu offerings include typical pub fare including appetizers, sandwiches, wraps, subs, clubs, pasta, steaks, seafood, pizza, calzones, plus the Chinese items including egg rolls, rangoons, lo mein, Gen Tso's chicken, sweet & sour chicken, soups (wonton, egg drop, hot & sour). "A bit of Cheers in NH. A great variety of ample portions and delicious food can be found here amidst a warm and friendly crowd of patrons and staff. Come once and you are a guest. Come back for more and you are a member of the community." In addition to being a nice, local restaurant with a wide variety of choices, It is simply a fun spot to drop by. Whether it be for occasional holidays or special events, or maybe a political race, this is the place to go!6
Bradford, NH
The inn was built circa 1850 and was completely restored to its prior grandeur in the early 2000's. The Inn has a total of 11 guest rooms consisting of nine suites and two deluxe guest rooms. Many of the rooms have the true amenities that today's guests desire including Jacuzzi tubs, fireplaces (9 out of 11), flat screen TV's/VCR's and double showers.
Put your stamp on this successful, well established Central New Hampshire gourmet café with gorgeous lake views. TripAdvisor gives an almost perfect rating of 4.5 out of 5.0. It is conveniently located within a short walk to the town docks providing easy access for boaters, snowmobilers and ice fishing enthusiasts. The location is also highly visible on a heavily traveled route to the White Mountains. This well maintained and recently renovated establishment offers full-service creative cuisine serving breakfast, lunch and dinner with a full bar. This restaurant occupies a particular niche in the area as a popular casual upscale gourmet café/pub. It also provides private and commercial catering services and meals to go for boaters. This is a true turnkey opportunity ideally suited to an owner/operator. Included in the sale are the website domain/content; furniture, fixtures, and equipment; training/consulting periods; non-compete agreement; long-term lease.
Hillsborough County, NH
Established and well known Sports Bar & Nightclub with a history of success. The top-notch facility has an A+ build-out and is in excellent condition. The Site is located in the middle of the action and has a design that allows for multiple revenue streams. It has a 460 person capacity, and a Cash Flow of $321,000 per year. This turn-key operation is a rare opportunity!
Thornton, NH
This business has been in existence since 2008, created by the current owner. The business operates as an LLC with a NNN lease and the real estate is owned by the owner of the business, under another LLC Offered for sale is a successful Italian Restaurant and Grille, including two dining rooms and pub. Over the last few years, the current owners have continued to improve the property structurally and functionally. The building itself was completely remodeled in 2008. Recently, a new septic system was replaced four years ago. In addition to the building in which the restaurant is housed, there is also a two bedroom cabin which can be used as an income property, employee housing, or as owners' accommodations.
North Conway, NH
Looking to own a perfect size restaurant in the most desirable location of charming North Conway Village in New Hampshire. This special opportunity is completely equipped, furnished and turn-key ready. With 64 dining room seats and 23 in bar/pub, more seating is available in a third room which currently has a pool table. Location and setting is walking distance to all village activities. Additional outdoor seasonal seating for 8 guests on brick paver sidewalk. Convenient and quiet office space on second floor. Municipal water and sewer in place. Opportunity is knocking at this price ~ don't miss it!
North Woodstock, NH
This business has been in existence since 1978 with the most recent owners operating the restaurant since 2003. It operates as a Subchapter "S" Corporation. The real estate is owned by the owners of the business, under an entity called Merland Group LLC. Truants' Taverne, Inc. operates under a triple net lease held by Merland Group LLC. Offered for sale is the business and real estate. Over the last few years, the current owners have continued to improve the property structurally and functionally. The building itself has had major roof improvements, new gutters, increased insulation, new windows, and updated heating systems. The owners have also improved the upstairs and downstairs lounge areas of the restaurant with larger seating capacity and the addition of an upstairs "Varsity" room complete with pool tables, foosball tables, etc. The restaurant has continued to increase its market share over the last 11 years in both the dining areas and in the lounge areas with their improvements. Aside from the commercial space, the building also includes three apartments. The apartments are currently leased to employees as follows: one bedroom apartment, $400; two bedroom apartment, $400; and the three bedroom apartment (which could easily be an owner's apartment), $450. These are lower than market rents, but it works for the current owners as employee housing. Seller may also consider selling the business only and leasing the real estate for a qualified buyer.
Cheshire County, NH
Outstanding Pizza and Sub Restaurant with Full Liquor license. Growing sales, up over 10% in the past year. Currently open 6 days a week, open on Mondays and add another $100k in revenues. Southern New Hampshire location. 2,700 square foot space with full liquor license, entertainment, karaoke, open mic nights, bands and more. Business owner is the property owner and is wiling to write a long term lease. Option to purchase property. Current owner is semi-absentee with good managers in place. Great for someone in a similar situation or fantastic for a hands on owner/operator who will benefit form reduced payroll. Outstanding Food and reputation in the area. They make hand tossed Italian style pizza. Close to a nearby college with 3200 students. Delivery makes up 40% of sales, Dine in 30% and pick up 30%. Patrons also enjoy pool table, darts, juke box and games. Seats 98 and has an outdoor deck. Great location, great reputation, great price with seller financing! Call today at 1-877-735-5224 or refer to the Confidentiality Agreement below for more information.
Established 45 seat Breakfast & Lunch spot with Friday night dinner business and full liquor license. Has room to grow with room to expand with bar and outside area for seating in summer. Busy road on main street near downtown. Owner has been at this location for 7 years and is known for quality food, reasonable prices and a retro-diner ambiance! For More Information -Contact Your Local Vested Business Broker at 1-877-735-5224 or refer to the Confidentiality Agreement below for more information.
Cheshire County, NH
Our client is a restaurant/ bar that serves primarily American and European style foods. The on-site brewery is currently acting as a brew-pub for a local craft brewing company. The Company has a recognizable and appealing brand, and has a loyal customer base that can be leveraged. This is a great opportunity for an individual interested in taking an existing and well-established business to the next level, or for another operator in the industry looking to expand their market presence.
Center Harbor, NH
An excellent opportunity to purchase an established and profitable 96-seat restaurant and tavern. This would be appealing with its present management arrangement to a husband and wife team, partnership, established sports-bar chain or experienced restaurateur. With its Lakes Region location as a very popular 4-season tourist destination, their customer base consists of many year-round regular customers, tourists, as well as a multitude of returning seasonal renters and second home owners. The building is 6,003 sq. ft. and includes an apartment. The property has 225 feet of road frontage, nearly 2 acres of real estate assessed at over $400,000, and ample paved parking. Good gross sales have remained steady for the past three years.
Newport, NH
Have you ever thought about taking your barbecue expertise to the next level by owning a joint of your own? Here is your chance to buy an established and operating business with all of the equipment and permits in place. Just bring your talent and creativity to succeed. Price includes business, furniture, fixtures and equipment. Owner training available.
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You may recall from our post last week that Brian Wilson is playing The Ryman November 10. And yes, tickets are still available. Well Grimey's has just announced that they'll be hosting the wacky Beach Boy at an in-store signing and brunch on November 9 at 1 p.m. The only catch: you have to buy Wilson's latest album That Lucky Old Sun in order to meet him.
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Best in Town
Great service, extensive menu, eclectic atmosphere, and great food can be found here. I highly recommend to all.
Great Service
They not only offered the best warranty ever on their work but implemented practical solutions for my problems. A rare offering in today's world.
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FDA Reviewing Risk With Off-Label Tramadol Use in Children »
"The US Food and Drug Administration (FDA) is investigating the "rare but serious" risk for slowed or difficult breathing in children 17 and younger treated with the opioid analgesic tramadol.
"This risk may be increased in children tr"...
Read the FDA Reviewing Risk With Off-Label Tramadol Use in Children article »
(Generic versions may still be available.)
While there has been no reported case of overdosage, should it occur, symptomatic supportive measures should be taken.
Clofibrate is contraindicated in pregnant women. While teratogenic studies have not demonstrated any effect attributable to clofibrate, it is known that serum of the rabbit fetus accumulates a higher concentration of clofibrate than that found in maternal serum, and it is possible that the fetus may not have developed the enzyme system required for the excretion of clofibrate.
It is contraindicated in patients with clinically significant hepatic or renal dysfunction. Rhabdomyolysis and severe hyperkalemia have been reported in association with pre-existing renal insufficiency.
It is contraindicated in patients with primary biliary cirrhosis, since it may raise the already elevated cholesterol in these cases.
It is contraindicated in patients with a known hypersensitivity to clofibrate.
It is contraindicated in nursing women (see PRECAUTIONS ).
Last reviewed on RxList: 12/8/2004
This monograph has been modified to include the generic and brand name in many instances.
Atromid-S FDA Prescribing Information
Additional Atromid-S Information
Report Problems to the Food and Drug Administration
You are encouraged to report negative side effects of prescription drugs to the FDA. Visit the FDA MedWatch website or call 1-800-FDA-1088.
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