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India A vs South Africa A team will be going to played on Tri Series match with South Africa A team on 12th August 2013. Here all fans are enjoy with us Shikhar Dhawan 248 Runs Highlights Video vs South Africa A Team 12 Aug 2013. This game is very important for India A cricket cause they are on third position before this match. India team Played first on 12 Aug and his opening batsman gave a very positive response to India A cricket team. Specially Shikhar Dhawan who are played very out standing in this match.
Shikhar Dhawan made a big score record in in the history of List A games. India and South Africa both team are face to face at LC de Villiers Oval, Pretoria cricket stadium and match will be begin at 09:30 local | 07:30 GMT | 12:30 PKT. All fans are eyes are on India A team cause if they lost the match when South Africa A team played with Australia in Final Tri Series match. So India fans are very exiting about this match.
Ind A team opening batsman gave a good score for a big target Dhawan make a history record 248 on 150 but Shikhar Dhawan misses world record by 20 runs if will be able to make a another 20 score when his name was on the top of highlight score in One Day cricket history in A Games.
CA Pujara captian also played well he make 109 on 97 balls and the end match match India lost only three wickets after played the 50 overs. On ther other hand South African A team opener batsman RR Hendricks try best he made 106 score and VB van Jaarsveld made 108 but could not be able to chase the target SA A team made 394 score in 48.4 overs and all team out. India won this big game from South Africa A Team now next game with Australia A team so let see who is the Winner Of South Africa Tri Sereis final match 2013 for more stay here.Shikhar Dhawan 248 Runs Highlights Video vs South Africa A Tri Series 12 Aug 2013,
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Poll: What kind of interactions do you prefer in a ticket?
What happens after a customer raises a support ticket asking for some help?
You wade through the ticket to find out what information is available. Once you ingest that, you try to find the simplest possible solution for the customer. But, a little later, you realize there's not enough information for you to suggest anything yet.
So, you write back to the customer asking for some information. This is often a cycle and it happens once or twice again before you find a solution. Sometimes, it takes longer because the most common solutions don't work. Sometimes it's over in the first couple of interactions and everyone's happy.
But, then, how many interactions is the most optimal number? When does it start becoming uncomfortable for the customer? How much information can the customer absorb from a single interaction? These questions only become more relevant as you scale up your business.
The question on our poll, this week, is about interactions with customers while handling a ticket. What you'll read below is a brief look at the various ways of looking at this seemingly paradoxical situation.
Giving vs Asking
You have a few common solutions in your mind for the customer. You can put them all in a single interaction. One of them will work and job is done. You'll save the day faster than your peers. But, what's the use in giving so much information if the customer can't ingest as much?
So, what CAN you do? You can always write to the customer asking for more information. That'll help you narrow down your suggestions. If you ask too much information, one at a time, it will lead to dissatisfaction.
Resolution Time vs Response Time
Customers come to you asking for your help. You owe that to them as well. By getting as much information as possible, you can suggest the best possible solution every time. You'll resolve every issue that's within your control. What can be more important than that, right? Ummm… there's something called Resolution Time. If you have many interactions in a ticket, your resolution time soars. But, it's not supposed to. And, that's the tricky part.
There's also something called Response Time. When you try to squeeze in a few common solutions into a single interaction, you think that one of them will work. Surprise! Surprise! None of them work, because you didn't receive one little detail. That's unfortunate, because your response time just shot up.
Manager vs Agent
This is essentially a matter of the big picture versus the small picture. At the level of an agent, each ticket is an experience. It's a chance to create customer happiness. It's a path to win the customer's respect. Naturally, an agent is likely to spend time non-uniformly across interactions in a ticket.
A manager looks at the big picture. Most of the information ingested at the managerial level is aggregate. So, in a sense, even the extra time spent by an agent on a few tickets looks more prominent to the manager.
A manager and an agent are two people who see the same customer support operation in different ways. That's exactly why we're asking this week's question to both managers and agents.
We're really curious to see what you think about this topic. Tell us in the comments section below.
Happy Polling and have a great week ahead!
All in a day's work..
Recently, I came across a wonderful article shared by a friend on 6 personality and work environment types. The work environments recommended according to personality types made a lot of sense.. I found myself mentally screening myself and other friends, if we were in the right jobs.. Most of us, thankfully, are.
What also set me thinking was, is it possible for one person to assimilate in himself all the personality types and thus be suitable for any work environment?
The answer stared at me like a writing on the wall. YES. If we consider each personality type to be a hat, wearing a different hat at different times is what we all do. Only we don't do it consciously. And more importantly we are not forced to do it. But what about those who do it consciously and with elan? Who you ask.
Results: Insights about customer support channels
About a fortnight ago, on our poll, we asked you all a question on support channels used by your customers. Before we get to the results, let's also see a few myths.
Myth 1: Email is so passe. It's a thing of the 90s. Customers don't use it much.
Reality: About 88% of respondents in our poll said that email was a channel that their customers used to reach them.
Myth 2: Social Media is the place for customer support. It has become mainstream channel.
Reality: Although social media is very very important, it's not the mainstream channel for customer support yet.
Myth 3: The fewer channels, the more efficiently the helpdesk performance.
Reality: By automating a few tasks and setting up some notifications, you can have as many channels as you want and still operate very efficiently.
There are two key insights from the poll results. The first one is about number of channels.
About 73% of respondents said customers use more than one channel to reach them. Around 46% of respondents said customers use three or more channels to reach them. This goes on to show how helpdesk software can make it really easy to handle so many channels efficiently. If they had to handle each of these channels using different software, it would've taken a miracle to make things happen so well everyday! So, if you're a business handling just one or two channels, this would be a good time to try Zoho Support! 😉
The second key insight from this poll is about which channels enjoy widespread adoption.
Contrary to popular perception, email is still the most widely used customer support channel. And, it's definitely here to stay. About 88% of respondents chose email as one channel, in their response. 'Phone' came second, with about 70% of respondents to its support.
Web forms and customer self-service portal come (a really close!) third and fourth respectively. Over 35% of respondents chose web forms while about 34% of respondents chose self-service portal. Most businesses use these two channels quite interchangeably.
Live chat was chosen by over 24% of respondents, while social media was chosen as a channel by about 20% of respondents.
If you're thinking about taking up some new support channels, you might want to check out this post from our blog.
We'll return next week with another interesting question. Have a great weekend!
Customer Appreciation in Numbers: Infographic
In February, we were flooded with positive comments (perhaps in the spirit of Valentine's Day) on our Facebook and Twitter pages.
Below is a visual representation of all the customer love we got last month. Thank you for your feedback! We always appreciate hearing from you.
How do you harness your customers' positive feedback on social media? Share your thoughts with us in the comments below or on our Facebook page.
Latest Zoho Calendar Updates: Sync for Google Calendar, Birthday Calendar
Managing your daily appointments, events and meetings can get overwhelming as you switch between your favorite calendar applications; on your mobile, desktop, web browser. Keeping them all in sync is no easy task and to do this manually will simply not be pleasant.
With Zoho Calendar, we would like our users to be in sync with their daily events automatically, even while using other calendar apps. In this light, we are glad to announce 2-way sync for Google Calendar, available for users of organizations / businesses subscribed to a Zoho Mail suite standard plan.
You can enable this feature from the Zoho Calendar settings page by selecting 'Sync' from the left options and then following a few simple steps. Once the synchronization is complete, whenever you create, edit or modify event details in your Google calendar, the same will reflect in your Zoho Calendar and vice versa. Please be advised that it takes around 5 minutes for changes to sync at this time. We are working towards making this instantaneous.
On a lighter note, we have also rolled out a birthday calendar feature to keep track of your contacts' special day. After all, however grown up and mature we may consider ourselves to be, doesn't a birthday wish invoke a smile at the least? In fact, a simple birthday wish may even score some brownie points with a business prospect. Just subscribe to Zoho Contacts' birthday information in a few simple steps from Zoho Calendar and be prompt with your good wishes.
We hope to come up with more updates that will help you stay in sync and be on top of your daily agendas. Please spare some time to provide feedback and suggestions on how else we can improve your calendar experience.
Customer Spotlight: OxyHealth is more productive with Zoho CRM and Google Apps
This is a guest blog post by Brandon Wilson, CRM Consultant of Viwo, a leading cloud solutions provider and a Zoho partner. Viwo has successfully deployed 3000 organizations onto cloud solutions.
The Business
Located in Sante Fe Springs, CA, OxyHealth LLC is a manufacturer and seller of Hyperbaric Chambers – medical devices used to increase the uptake of oxygen by a body's red blood cells. Since its start 10 years ago, OxyHealth has seen the popularity of hyperbaric chambers expand into many areas of medicine.
The Challenge
Many of OxyHealth's business systems were created and setup several years ago, due to which they were unable to keep up with the growing challenges and needs.
Their biggest and most pressing issue was CRM. Their sales team, over the years, became increasingly mobile and access became a huge issue for OxyHealth. To top it all, their current CRM solution, Goldmine, was increasingly hard to maintain and was getting less and less suitable for their workflow.
They needed a cloud based CRM solution, which is highly accessible from mobile devices and integrates with their email system.
A Solution with Zoho CRM
OxyHealth's CEO, Samir Patel, landed on Zoho CRM as the best solution. What put Samir over the top was the breadth of features and most importantly, that Zoho CRM was part of a larger integrated suite of applications. The price was just the cherry on top.
OxyHealth approached us to manage the implementation in the following areas:
- Solution Design
- Evaluation Support
- Project Planning
- Customization and Integration
- Training
- Ongoing Technical Support
Mobile Team
Travel had become a regular part of OxyHealth's sales process. They continually found themselves needing to input and review data or manage tasks on the go. Now with Zoho CRM, they can input leads from their Smartphones or tablets instead of heading back to the office to hop on a server.
"With the ability to work everywhere, not just in the office, I see high potential for not only making more money, but saving a lot of money as well." CEO, Samir Patel
Easy Communication Tracking
Tracking email communication in high fidelity is critical for OxyHealth. And Goldmine required a lot of manual work to associate emails to records, making it error prone.
We integrated OxyHealth's Google Apps account with the Zoho Mail Add on. This solution gave them automated email tracking, logging all inbound and outbound email communication and accessible at the click of a button from within their contacts.
"We quickly became more productive and efficient. I found myself simply getting more done." CEO, Samir Patel
The Result
The result, OxyHealth became more productive and efficient. With the ability to work everywhere, not just in the office, Samir says that he sees high potential for not only making more money, but saving money as well. You can check out the full story here.

subset: commoncrawl


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I received such a beautiful bouquet at the end of our Nativity Play and this is a single Pink taken as it stands in the vase with lilies and carnations in the background. Hand held camera and no special lighting but I just liked the softness of the image.
|nikon d 50 Check out Nikon Nation!
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Beautiful soft colours and nicely out of focus background - and beautifully presented as always.
Definitely deserves an RC. It's a beautiful image - the background is superb and the pink is so lovely against it.
Lovely Di', and so nice to be given such a gift no doubt. I bet you're very popular.
Soft and gentle, but with those wonderfully crisp frilly edges to the petals showing up well. I'm glad they appreciate you, I bet you worked hard for this!
Such a lovely colour and I like the blurred b/g. It's a lovely image Di.
This is so so good....Colours and light are just magic...
So beautiful and soft, love the delicate colour and intricate detail
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Raise all kinds of hell in this orange leather vintage skirt with a high waist and exposed zip front. Fully lined.
The Details
Waist: 25"/64cm
Length: 21.5"/54.5cm
Circa: 80s
Label: Yucatan Bay
Marked Size: 8
Estimated Size: S/M
Color: Orange
Fabric: 100% Genuine Leather
Condition: Good vintage condition
If you're not utterly obsessed with your recent purchase, it's now so easy to send it back! All US returns can be completed online using our fast, hassle-free system. Check out the links below for more details.
Hair accessories, opened makeup, earrings, ear cuffs, panties and bodysuits cannot be returned.


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I have a requirement where content like specific cartridges should be copied from one application to another application.
I cannot use export and import commands as this will overwrite the content in the second application. I want to achieve the similar functionality where user copies pages/cartridges within application.
Is there any way to do it?


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Try The Emotion Code here - release trapped emotions so the body can heal itself.
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Hi there, i am giving permission for myself and i have the permission of my children for your help.... we need it and thank you.. LRS /40 DATS/23 DLS/22 EDG/19.....IM LOOKING FORWARD TO YOUR REPLY....
Anonymous Coward 19842141
The following were found in DLS and released:
age 20
Psychic trauma
taken for granted / unsupported
age 22
Psychic trauma
overwhelm / depression
age 19
Psychic trauma
overwhelm / worthless
age 22
age 22
age 19
age 20
low self esteem
age 22
The ages can be off a year or two.
These are not all of the emotions that can be felt. If it does not resonate that you had that exact emotion, the one listed may have the next closest vibration to the actual emotion - such as worthless & useless, or humiliation and embarrassment. Even if the age is off, or the exact emotion is off, that ball of energy was released...
-----Psychic Trauma - When 2 emotions are felt simultaneously, they can become trapped into one ball of energy
this is all your body wanted to release at this time, it needs to process.
"Doing The Emotion Code is like doing surgery on the energy body. We are literally looking for "malignant" or harmful energies that need to be removed, then we remove them, and the energy body has to heal and reorganize or regain it's balance. If you were to do actual surgery to have a tumor removed, you would expect to have at least a few days of downtime afterward. Your surgeon would also likely tell you what to expect during this healing time, and he or she would also advise you to get extra rest in order to allow the body to heal. The advice after a session with The Emotion Code is just about the same! Be aware that if you feel out of sorts, have changes in your sleeping pattern, vivid dreams or emotional ups and downs, this is totally normal! Drink lots of water, eat healthy and get lots of rest, and let your energy body heal itself. You may not notice anything weird or negative, you might just feel great, but it's better to be aware just in case."
Give it a couple of days and let me know how DLS is doing.
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Aliens Exist: Here Is The PROOF
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America's cities will collapse into utter chaos the day the EBT cards stop working
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This Mind-Blowing Video About The Universe Is The Reason You Won't Sleep Tonight
This Flag Represents The Principle, "Fight For What You Believe In."
This Is The Rebel Flag, "You're Either Free Or You're Not."
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Watch Movies Online
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Not only you can Watch Movies Online on 10StarMovies, but you can also participate in the Watch Movies forum with a wide variety of topics?
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Watch Convoy Online
Release:June 28, 1978
RunTime:1 hr 50 min
IMDB Rating:6.2/10 (8904 votes)
Director:Sam PeckinpahActors:Kris Kristofferson, Ali MacGraw, Ernest Borgnine, Burt Young, Madge Sinclair(View All)
Description: Watch Convoy full movie online for free directed by Sam Peckinpah produced in 1978. Genres are Action, Comedy, Drama.
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Book your room at Lifton Hall Hotel
Twin Room, 2 Single Beds, EnsuiteMax Occupancy: 2 guests (up to 1 child)
Double Room, EnsuiteMax Occupancy: 1 guest
Double Room, EnsuiteMax Occupancy: 1 guest
Family Room, EnsuiteMax Occupancy: 1 guest
Twin Room, 2 Single Beds, EnsuiteMax Occupancy: 1 guest
Double Room, EnsuiteMax Occupancy: 2 guests (up to 1 child)
Double Room, EnsuiteMax Occupancy: 2 guests (up to 1 child)
Family Room, EnsuiteMax Occupancy: 3 guests (up to 2 children)
Family Room, EnsuiteMax Occupancy: 4 guests (up to 3 children)
Get an overview of this hotel3-star inn with free breakfast and restaurant
Situated in Lifton, this inn is 7.1 mi (11.5 km) from Brent Tor and 9 mi (14.5 km) from Lydford Gorge. The Hurlers and Cotehele House and Gardens are also within 16 mi (25 km).
Property Features
Along with a restaurant, this smoke-free inn has a bar/lounge and free breakfast. Free WiFi in public areas and free self parking are also provided.
Room Amenities
All 10 rooms offer free WiFi, coffee makers, and flat-screen TVs with digital channels.Information missing or incorrect? Tell us!
Hotel Amenities
Hotel Amenities
The inn offers a restaurant. A bar/lounge is on site where guests can unwind with a drink. Guests can enjoy a complimentary breakfast. Public areas are equipped with complimentary high-speed wireless Internet access.
Onsite self parking is complimentary.
Lifton Hall Hotel is a smoke-free property.
- Bar/lounge
- Free breakfast
- Free long-term parking
- Free self parking
- Free WiFi
- Number of buildings/towers - 1
- Number of floors - 2
- Restaurant
- Smoke-free property
- Total number of rooms - 10
Available in all rooms: Free WiFi
Available in some public areas: Free WiFi
Free long-term parking, Free self parking
Room Amenities
- Coffee/tea maker
- Digital TV service
- Flat-panel TV
- Free WiFi
- Hair dryer
- Iron/ironing board (on request)
- Private bathroom
Where to Eat
Guests are offered a complimentary full breakfast.
Onsite venue - This restaurant specializes in British cuisine and serves breakfast, lunch, and dinner.
Hotel Policies
Check-in time ends at 11 PM
Check-in time starts at 3 PM
Special check-in instructions:
Check-out time is 11 AM
Payment types
Children and extra beds
- Children are welcome.
Pets allowed
You need to know
Extra-person charges may apply and vary depending on hotel policy.
Government-issued photo identification and a credit card or cash deposit are required at check-in for incidental charges.
Special requests are subject to availability upon check-in and may incur additional charges. Special requests cannot be guaranteed.
No rollaway/extra beds available
No cribs (infant beds) available
Optional extras
- Pet fee: GBP 5 per pet, per stay plus GBP 5 one-time cleaning fee


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Tag "developers"
Rumor: In-App Purchases to Happen "Early March at Latest"
Whispers of the Android Market allowing purchases within applications have been circulating for quite some time, even in official circles. Giving developers a way to further make money off of
COMMUNITY ALERT: DavinciDevelopers Stealing Apps To Sell As Own Creations
The people over at Android Community are reporting today that a group known as the "DavinciDevelopers" has been doing something pretty lowdown with the Android Market. Namely, taking apps that are in development and in the hands of beta testers and posting them to the Android Market as their own creations. A quote from the Android Community article:
Change in URL Structure is Latest Sign of Web-Based Android Market
The long, grueling wait for a fully functional web-based Android Market may be just about over. We've been asking for one since the Market launched back in 2008, but it wasn't until Vic Gundotra got on stage at 2010's Google I/O that we saw what was in store for us. Given all the recent changes, it looks as if the new desktop client is upon us.
Developers Now Have 4,000 Characters to Describe Android Apps in Market
ne of the biggest complaints around the Android Market has long been the tiny amount of space given to developers to describe the app. For companies who roll out multiple updates in a short window, they previously had to resort to using some of that precious space to note changes in the app/game. That went away with the new "recent changes" feature, and developers had those characters freed up for descriptions. Apparently, Google thinks developers need more space yet. Way more space.
Android Helps fring Earn $10,000 Per Day
Fring, the first company to offer video chat for Android, has been doing rather well for itself lately. As some of you know, the app launched with the HTC EVO
Zedge Discovery Network Launches, Aimed at Independent App Developers
Zedge has officially opened the doors up to their Discovery Network, which aims to level the playing field for independent Android developers. With over 30 million unique visitors a month, they have learned what it is that users are looking for in their smart phones. Taking everything they know into consideration, they decided they could help put the best stuff in front of these users.
Android Market: Behold, The Change is Coming
I just received very interesting notification from Android Market notifying me that the developer console will be out of service Nov 18 for whole 6 hours. Now, I've had apps
Ads Within Apps, the Rovio Approach
Simply put, ads within apps can be a sore topic on all sides. Nobody likes to see ads popping up every time they perform an action on their phone. Yet
Global App Revenue made Possible by BuzzCity
Mobile media company BuzzCity launched its new Android SDK this Tuesday following success of its recent release for BlackBerry. The new SDK will allow developers to embed advertisements in their
Amazon Sweetens the Pot for Developers, Waives $99 Fee
Amazon is doing their part to cozy up next to Android developers. We recently saw the terms and conditions leak online which showed a $99 annual fee that devs were
Developers Seeing Long Term Promise in Android
Apple rules the short term but Android holds more promise in the long term. At least this is what a majority of those survey by Appcelerator and IDC are saying. A survey released today shows that most of the 2,400 developers polled believe Android will be the platform best positioned to "power a large number and variety of connected devices in the future".
Wallpaper Apps Exonerated, Google Posts Guidelines (UPDATED)
Last week, we were among dozens of media outlets that reported that sketchy wallpaper apps were sending your personal data to servers in China. It turns out, those claims were
Sprint Customers Can Pay Bills, Manage Accounts, and More with Sprint Zone
Today finds Sprint announcing their free Sprint Zone application to help customers pay bills, check voice and data usage, and manage accounts. Available as an icon on the EVO 4G
App Inventor for Android
Google just released App Inventor for Android, a web based application builder that will help aspiring young developers create Android applications with just few drags and drops and no need
Take the Paid App Pledge!
Android users get a bad rap. They say we expect apps to be free, that we won't pay for apps like users of other platforms will, and that consequently it's


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Joseph: Meaning, Popularity, Origin of Baby Name Joseph
Origin of the name Joseph:
Derived from the Hebrew yōsēf (may he add, God shall add). The name is borne in the Bible by a favorite son of Jacob and Rachel (GEN. 30), by the husband of the Virgin Mary and foster father of Jesus (MATT. 1), and by Joseph of Arimathea, a rich Jew and secret follower of Jesus, who helped take Jesus' body from the cross to prepare it for burial, and supposedly took the Holy Grail to England (JOHN 19).
From A World of Baby Names by Teresa Norman.
Looking for the perfect name? Try the Name MatchMaker to find the perfect baby name for you!
US Popularity of Joseph Over Time
Sister & Brother Names
Know a Joseph? What are his siblings named?
Name Lists Featuring Joseph
- Australian Boys Names: Most Popular Names for Boys in Australia (New South Wales)
- Australian Boys Names: Most Popular Names for Boys in Australia (Victoria)
- New Zealand Boys Names: Most Popular Names for Boys in New Zealand
- Irish Boys Names: Most Popular Names for Boys in the Republic of Ireland
- English and Welsh Boys Names: Most Popular Names for Boys in England and Wales (2013)
- Irish Boys Names: Most Popular Names for Boys in Northern Ireland
- Scottish Boys Names: Most Popular Names for Boys in Scotland
- Australian Boys Names: Most Popular Names for Boys in Australia (New South Wales), 2010
- Australian Boys Names: Most Popular Names for Boys in Australia (Victoria), 2010
- New Zealand Boys Names: Most Popular Names for Boys in New Zealand, 2010
- Irish Boys Names: Most Popular Names for Boys in Ireland, 2010
- Scottish Boys Names: Most Popular Names for Boys in Scotland, 2011
- English and Welsh Boys Names: Most Popular Names for Boys in England and Wales
Contribute your knowledge to the name Joseph
- Comments and insights on the name Joseph: | Edit
I met the most beautiful man who has become my best friend, soul mate, partner, lover, etc. and when first introduced to me by others(family,friends) as JoJo/JoeJoe which didn't quite sound or feel right for me, I asked if his real name was JoJo, etc. or Joe. Upon hearing his real name of Joe I wondered aloud if he might mind me calling him Joe. I have always loved the name Joseph and Joe as well. Anyway our names said together beginning with his as Joe just sounded perfect, like my name had been waiting for his. I laughed that I some how new it would be him (My Joe) cause I always said things like ready to go joe? why so slow joe? time to go joe! etc. See we were always meant for each other. He is a truly precious blessing/gift I treasure daily! I love you My Joe!!!
I really love the name Joseph, but I hate the abbreviation Joe!
Joseph is such a masculine, handsome name. And Joey is a cute nickname!
I love the name Joseph. It's so easy to say and spell and hear and remember. Also, Joe, in my opinion, is the best nickname for a Joseph.
- Personal experiences with the name Joseph: | Edit
Hello. My Son, Joseph Alan was born in 2003. He is tall, beautiful, athletic, intelligent, and very popular at at school. He always has girlfriends (Despite only being 11) and NO ONE can make fun of his name (Unless they say it's too common!) Don't name your boy a name that YOU like, but nobody else will (You shouldn't let what others think get in the way)...the boy-names out there right now are pathetic and sound feminine (i know i'm being homophobic) i.e. Jayden, Jaxxon, Aaiden, Braiden etc...Your little baby will be a MAN one day-so name him a manly name!! My other son is Robert.
Our son Joseph Matthew was born in 2007, we called him Joseph as we wanted something traditional and classic that would suit a baby and an elderly man (didnt want a pensioner lumbered with a daft name)!!! we call him Joe, Jo-Jo and Joey, i love the name and pleased we chose it!!!
Okay, well, I know somone at my daugter's school named Joseph. He is, according to my daghter, sweet, nice, kind of quiet, cute, and VERY funny. She has a different insight, though, of him, since she is crushing on him. Even so, I've met him, and his is everything my daughter says he is. And, if you, my daughter, or Joe(that's his most common nickname-he has other's) are reading this, just to let you know, I am fine with you dating. Sorry, if I embarrassed you, but, you have my permission Joe.
- Nicknames for Joseph: | Edit
Jack, Jody, Joe, Joey, JoJo, Joss, Seppi, Jo, Seph, Jose, Joker
- Meanings and history of the name Joseph: | Edit
Of Hebrew origin, meaning "He will Increase," from Genesis 30:24: "And she called his name Joseph, saying: 'The LORD add to me another son.' "
- Famous real-life people named Joseph: | Edit
Joseph Gordon-Levitt, American actor
Joseph Fiennes, actor and brother of Ralph
Joseph "Joe" Jackson, Michael and Janet's father
Joseph "Joe" Biden, vice president of the United States
Joseph Heller, American writer
Joseph Campbell, inventor of Campbell's soup
Joseph McCarthy, US Senator
Joseph Lieberman, US Senator
Joseph Duggar, Jim Bob and Michelle Duggar's 7th child (they have 19 children)
Joseph "Joe" Sugg, YouTuber known as ThatcherJoe, brother of Zoe Sugg (Zoella)
Joseph Morgan, British actor, plays Niklaus Mikaelson in the CW Network Shows The Vampire Diaries and The Originals. Also plays Lysander in the 2011 film, Immortals.
- Joseph in song, story & screen: | Edit
Joe Gargery, the blacksmith and Pip's loving and protective father-figure in Dicken's novel Great Expectation. (The loveliest character in literature!)
"Joseph and the Amazing Technicolor Dreamcoat" is a Musical written by Andrew Lloyd Webber and Tim Rice. The play is based on the biblical story of Joseph and his brothers.
St. Joseph, husband of the Virgin Mary in the Bible
Joseph 'Seph' McCauley- Main Character of Cinda Williams Chima's novel The Wizard Heir.


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We were given 1st class service the moment we touched down in Bali. We were ushered thru the immigration gates without the need to queue. Then, cold towels, bottled water and fruits were served in the 7 seater free airport transfer. We arrived at the Samaya approximately 20 mins later and were welcomed with delightful flower garlands. Our villa was at the far end of the compound so a buggy was necessary to take us and our luggage to the villa (there is a short cut through the café which we realised later on)
The villa itself was readied with the air condition switched on and 2 glasses of fancy orange juice prep nicely on the coffee table. The villa is huge for 2 persons. It has all the basic needs as well as the luxury bits that makes it stand out with the rest. As mentioned by many, renovation works are ongoing on the beach villa so our villa is situated on the opposite side of the main road (the samaya split their accommodations in 2 parts). Buggy services can be requested for those who wish to go to the restaurant, spa or even the reception area (though the latter would take barely 5 mins to walk to). As published in their website we were offered free 2 pieces of laundry each everyday (necessary in the blistering heat). We wine and dine in the villa for free! (well, a bottle of free sparkling wine and breakfast in villa is included). We enjoyed a dip in the pool especially after a long day out. We had breakfast in villa one day and another at breeze restaurant. Do take note that the breakfast selection at the breeze is more extensive and we ate like kings and queens. Breakfast is served all day so dine late morning and there won't be a need to have lunch at all. Then came tea time. Drinks selection is wide (they tried doing an ice blended coffee for my partner which I would give thumbs up for 1st try) though the cakes and pastries is forgettable. The view however is breathtaking and the fact that the area is private, we did not need to worry about random sellers coming right up to your face. Dinner was good. We had a table right at the edge of the compound (within a metre from the beach) and were able to catch the sunset. Unfortunately, one of the spot lights fused and flying bugs were attacking our table since the little candle on the table attracted them. We were quickly moved to another area and service staffs were profusely apologizing to us which we accept since it is not their fault that the lights decide to give in. Food was amazing. My partner had a full Indonesian cuisine and the taste was true to its origin. As for myself, I had the green tea risotto with scallops (appetizer – forgotten) and I love it a lot. Definitely a must go for food lovers. Due to the low season, I ask for an extension on the last day since our flight was at 9pm. Instead of giving us the usual 2pm-3pm like most hotel do, we were allowed to stay in our villa till 7pm! The Samaya also provides free shuttle van to Kuta and nearby areas though take note that the place they stop is about a 15 mins walk to Kuta. My only disappointment was that we didn't spend enough in the villa (Which villa provides 2 shower heads??) We did a one day tour with a brilliant tour guide named Putu (pm me for more details). The Samaya is definitely a luxury place but with practicality.
- Official Description (provided by the hotel):
- Samaya Seminyak has an outdoor pool, a steam room, a sauna, and a fitness facility. This 5-star Luxury Boutique Seminyak property features massage and treatment rooms, body treatments, and facial treatments. Business amenities at this 5-star Luxury Boutique property include complimentary wireless Internet access and business services. Samaya Seminyak has an award winning restaurant Breeze and a bar/lounge. 24-hour room service is available. Transportation services at this property include a complimentary airport shuttle (available on request) and a complimentary area shuttle within 2000metres. The staff can arrange wedding services, dry cleaning/laundry services, currency exchange, and computer rentals. Additional amenities include valet parking, a concierge desk, and a garden. ... more less
- Reservation Options:
- TripAdvisor is proud to partner with Travelocity, Expedia, Hotels.com, Booking.com, Orbitz, HotelTravel.com, Odigeo, Priceline, Agoda and Low Cost Holidays so you can book your The Samaya Bali reservations with confidence. We help millions of travelers each month to find the perfect hotel for both vacation and business trips, always with the best discounts and special offers.
- Also Known As:
- The Samaya Bali Hotel Seminyak
- Samaya Bali Seminyak
- Samaya Bali Hotel Seminyak
- The Samaya Bali Seminyak


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Marvel, Netflix Debut Free "Jessica Jones" Digital Comic
TV, Digital Comics
Comic Books
Film, Comic Books, TV
The Mission
Shelf Life
The Buy Pile
In Your Face Jam
Spinoff Online
Robot 6
Robot 6
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Robot 6
Spinoff Online
Oct 07, 09:33am
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Muncie, IN
Political cartoons | "I think it might be pretty risky to go back home," says Chinese cartoonist Wang Liming, who's on Japan in a business trip and is thinking about staying there. "If I go back, they might use my cartoons as an excuse to detain me." Liming, whose pen name is Biantai Lajiao (Perverted Chili Pepper), was arrested and briefly detained in 2013 on charges of "rumor-mongering," stemming from a post on the microblog site Weibo. This time, an anonymous commenter on a state-owned discussion board called Liming a "traitor" because of a cartoon he posted online that showed mainland Chinese being sent to Hong Kong to oppose the Occupy Central pro-democracy campaign and demonstrate how to kowtow to the government. "That post is written like something out of the Cultural Revolution," Liming said, calling it a "smear campaign." He has 500,000 followers on Weibo and another 340,000 on Sina Weibo, and he says he is losing income because his accounts have been shut down. [Radio Free Asia]
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Attention, folks who purchased the TomTom car kit for their iPhone 3G or 3GS, only to upgrade to a won't-fit-quite-right iPhone 4: you're in luck. TomTom is now providing a free adapter for the aforementioned car kit that allows an iPhone 4 to fit properly.
Apparently the adapter is simply a piece of plastic that one sticks into place over a spot at the bottom of the dock. It's included in the kit packaging from September 1, though if you bought a car kit before then, you can claim your adapter from TomTom for free.
The TomTom car kit retails for about $120. Obviously, to make full use of the TomTom car kit at all, you'll want to have the $40 iPhone app to go along with it.
[via Electronista]
Apple iPhone 6
- Key specs
- Reviews • 45
- Prices
- Discussions
- Type Smartphone
- Operating system iOS (8)
- Screen size 4.7 inches
- Internal memory 16 GB
- Camera 8 megapixels
- Dimensions 5.44 x 2.64 x 0.27 in
- Weight 4.55 oz
- Released 2014-09-19
Apple iPhone 4


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The monochrome filter picture shows Shah Rukh and Kajol sharing a moment in the backdrop of a bustling street
We'd like to thank Robert Downey Jr for posting this completely shareworthy (already shared over 5,500 times) GIF on Facebook
It was like a scene straight out of a Bollywood film
A Busy Day For Aishwarya's Jazbaa 10 on 10 for her style!
RT @prdp: 30 Tweets or more and you will be watching #PremLeela first! So tweet NOW! @BeingSalmanKhan @sonamakapoor @rajshri @foxstarhindi Wed Oct 07 07:09:32 , 2015
Whole cast of Dilwale on sets.Nice to meet all my friends together.Now 2 writing speech for Edinburgh. Life lessons/Success or on Education? Tue Oct 06 13:23:07 , 2015
RT @Fact: After 3 to 4 months of having a crush on someone, you either fall in love with that person or become interested in someone new. Tue Oct 06 08:48:13 , 2015
Each film is a part of me. Good Bad Ugly. Don't know which part of me 2 show first or judge. I am the sum of my work https://t.co/uR1RrLQpCl Mon Oct 05 15:38:18 , 2015


text: We have just returned from a week stay at this hotel and really couldn't fault it. We arrived at the hotel very late and the reception swiftly checked us in and got us into our room with no delay. We then had a great stay from then on, the hotel pool is huge and one of the best at any... More


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Shepherd NeameVisitor Centre,11 Court Street,Faversham,ME13 7AX
Mon - Sun10:30 - 16:30
For help with your order,call us on01795 542014
Thrice-hopped and bottle conditioned, 6.5% abv 1698 is the connoisseur's choice, a beer to be savoured. Originally brewed to celebrate our tercentenary, 1698 was a silver medal winner in the Taste of Britain Awards, was included in the International Beer Challenge's World's Top 50 Beers and has won a Gold Award from the British Bottlers' Institute. Two cases of 8 x 500ml bottles.
Go green with this re-usable, 1698 branded hessian Jute Bag.
A pale, golden, brilliantly bright, hoppy ale, brewed with 100% pale malt and the choicest East Kent Golding hops. This was a hugely popular ale in its day and has now risen Phoenix-like for the modern drinker to enjoy. Two cases of 8 x 500ml bottles
Holding approximately four pints, this traditional jug is decorated with the oldest known image of the brewery, an 1865 advertisement featuring a lithograph depicting Faversham's Old Steam Brewery, the first outside London to use a steam engine from 1789.
A historic brew which conjures up images of high seas and faraway places. At 6.1% abv, this IPA retains the strength and character that is typical of this iconic, internationally renowned beer. Shepherd Neame's India Pale Ale is hopped at three stages of the boil, with two varieties of Kentish hops – Fuggles and East Kent Goldings – resulting in a deep golden ale, with spiced fruit notes and a distinctive, heavily hopped bitterness. Two cases of 8 x 500ml bottles
Pint-sized, individually-boxed pewter tankard engraved with the Shepherd Neame logo.
Mash Tun No.1 is a very special beer, brewed to celebrate the 100th anniversary of the oldest of our two mash tuns. Mash Tun No.1 and No.2 are the last remaining pair of solid oak tuns, housed here in Faversham at Shepherd Neame, and still used to brew our ales today. In its lifetime, Mash Tun No.1 has brewed over a billion pints of Kentish ale - now that's something worth celebrating!
This certificate entitles two people to visit us for an Evening Brewery Tour, tutored beer tasting and Ale Sampler's Supper, served in the Visitor Centre Bar. This is a full evening experience, including a visit to the brew house, the heart of the brewery. After their 80 minute tour, visitors will return to the bar for a beer tasting, and learn how the masterbrewer's assess every beer. This is followed by a delicious two course supper. Also includes a sturdy Shepherd Neame jute bag filled with a selection of six different beers to sample at home.
Beers, chutneys, mustard and marmalade, all packed in a sturdy re-usable Jute Bag. 1 bottle of 1698 Bottle Conditioned Ale, 1 bottle of Spitfire Premium Kentish Ale, 1 bottle of Bishop's Finger, 3 jars of chutney (1 each of Whitstable Bay, Bishops Finger and 1698), a delicious Bishops Finger marmalade, and a tangy Spitfire mustard.
A collection that is bound to set the taste-buds racing! Contents may vary depending on availabilty of products.
This gift box is the ultimate Shepherd Neame gift experience, including some of our favourite items from the brewery shop, an excellent selection of our classic Kentish ales, pint glass, some luxury food items, and even an Oxford Die-cast of the Shepherd Neame Reliant tricycle van.
The Ultimate Collection is a stunning 12 bottle mixed case, showcasing 12 different bottled beers.This marvellous case of ales includes popular favourites like Spitfire and the legendary Bishops Finger, as well as the entire Classic Collection - including an India Pale Ale, the beautifully pale Brilliant Ale, a luxurious Double Stout, and the sumptuous bottle-conditioned beer, 1698.
Master Brew is brewed using only the finest Kentish barley and hops and is Shepherd Neame's 'Local Hero', a distinctive, mid-brown 4.0% abv bitter ale, with all the hoppy aroma you would expect of a beer brewed in the heart of the hop country. Two cases of 8 x 500ml bottles
A great 16 bottle mixed pack for those who like a stronger ale.
8 x 500ml bottles of '1698'Thrice hopped, complex, Gold medal winning bottle conditioned ale
8 x 500ml bottles of Bishops FingerRich, ruby coloured, malty ale - a firm favourite since 1958
Treat yourself - order now!
Celebrate the Bottle of Britain with this excellent Premium Kentish Ale. Named after the legendary Supermarine Spitfire this spicy, hoppy bitter is our most popular bottled ale. Abv 4.5%. Two cases of 8 x 500ml bottles
Contact us by email
Contact us by phone
Shepherd Neame LimitedThe Faversham Brewery17 Court StreetFavershamKent. ME13 7AXUnited Kingdom


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Earlier in the year, The Kayak Fishing Show with Jim Sammons attended the Kayak Fishing Boondoggle in the Everglades. We thought it would be cool for everyone to see what goes into making a prime time fishing show. Follow Jameson behind the scenes in YakAngler's Inside and Out Episode 2 – Behind The Kayak Fishing Show.
Posted on 27 August 2015 | 2:15 pm
Burkeville, VA, August 12, 2015 – Inc. magazine today ranked YakAttack LLC No. 507 on its 34th annual Inc. 5000, an exclusive ranking of the nation's fastest-growing private companies.
Posted on 24 August 2015 | 4:51 pm
Hurricane Kayaks and Legacy Paddlesports are pleased to announce an agreement to combine their companies. The owners of Hurricane and Legacy will each have a significant stake in the new entity. Don Grigg, co-owner of Hurricane, will serve as Chief Executive Officer.
Posted on 29 July 2015 | 4:18 pm
"YakAngler's Inside and Out" - What is it? What does it mean? Why are we doing it?
These are the questions that came to mind when we started the long journey to develop this series. It all started at the Kayak Fishing Boondoggle™, when Adam Hayes, Mark Watanabe, and I discussed what we could do to promote the sport we all love and show why we love it so much.
Posted on 27 July 2015 | 7:26 pm
Earlier this month, we dropped the press release about "YakAngler's Inside and Out", the new web series brought to you by YakAngler.com and host Jameson Redding.
Posted on 24 July 2015 | 4:00 am
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WP Cumulus Flash tag cloud by Roy Tanck and Luke Morton requires Flash Player 9 or better.


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Emi-Jay 'Silver Crystal Bead' Hair Tie
Details & Care
Buy three hair accessories from Emi-Jay and we'll automatically deduct the cost of the lowest-priced one in Checkout. No promo code required. Online and in stores. Free item can only be shipped to the same destination as your order and cannot be shipped to international addresses. If you return the qualifying item(s), please return the gift as well.Tired of traditional ponytail holders that pull and dent your hair? ...See More Details


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Capital Markets
Company Overview of African Capital Alliance
Executive Profile
Afolabi Oladele
Executive and Partner, African Capital Alliance
|Total Calculated Compensation
|This person is connected to 2 Board Members in 2 different organizations across 3 different industries.
See Board Relationships
Mr. Afolabi Oladele is an Executive and Partner at African Capital Alliance. Mr. Oladele joined the firm in 1999. Currently, he is responsible for leading firm's investments strategy in Sub-Saharan Africa. Mr. Oladele has worked with many of the firm's portfolio companies in various value-adding roles, including serving on boards and providing the interface with the oil and gas industry. Prior to that, he was the Group Executive Director at the National Petroleum Investment ...
Corporate Headquarters
8th FloorPhone: 234 1 277 7000
Lagos, -- 74085
Fax: 234 1 270 6908
Board Members Memberships
Director and Member of Technical & Reserves Committee
Postgraduate Diploma
University of Southern California
Bachelor's Degree
University of Ife
Unknown/Other Education
Ecole du Pétrole et des Moteurs - Paris
Other Affiliations
Annual CompensationThere is no Annual Compensation data available.
Stocks OptionsThere is no Stock Options data available.
Total CompensationThere is no Total Compensation data available.
|There is no Competitor Compensation data available.
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Our data partners will research the update request and update the information on this page if necessary. Research and follow-up could take several weeks. If you have questions, you can contact them at firstname.lastname@example.com.


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Lang Campbell played like an All-American even against major
college competition.
The William & Mary quarterback started the season with two
touchdown passes and two TD runs against North Carolina, nearly
leading his I-AA team to an upset of the Tar Heels from the
Atlantic Coast Conference.
Campbell went on to throw for 3,998 yards and 30 touchdowns, and
earned a spot on The Associated Press I-AA All-America team announced
The senior said that first game set up the Tribe for success.
"It helped a lot," Campbell said Wednesday. "We had
confidence in the preseason that offensively we could be successful
and put up some numbers. Having that kind of success against a
Division I-A team, it kind of solidified our confidence."
Led by Campbell, the Tribe (11-3) shared the Atlantic 10
Conference crown and set a school record for victories.
"If we didn't have him in there, we're not in the playoffs,"
Tribe coach Jimmye Laycock said.
He was one of four A-10 players selected first-team
All-American, along with offensive lineman Matt Magerko of James
Madison, defensive back Shannon James of Massachusetts and
linebacker Liam Ezekiel of Northeastern.
Ezekiel, the A-10 defensive player of the year, was one of five
players to repeat as a first-team All-American.
The others were Tennessee State tailback Charles Anthony, the
nation's leading rusher (158.1 yards per game), offensive linemen
Buster Ashley of Western Kentucky and Eric Deutsch of Wofford, and
linebacker Boomer Grigsby of Illinois State.
Wofford and Cal Poly were the only schools with multiple players
on the first team, each getting two.
Deutsch was joined by defensive lineman Lee Basinger while Cal
Poly was represented by defensive back Kenny Chicoine and defensive
lineman Chris Gocong.
The All-American receivers were two of the best players in I-AA.
Appalachian State's Davon Fowlkes led the nation in catches
(103), yards receiving (1,618) and all-purpose yards (2,313).
Northern Colorado's Vincent Jackson is considered a possible
first-round NFL draft choice. He caught 80 passes for 1,382 yards.
"In summation, he's as good as we've ever had," Northern
Colorado coach Kay Dalton said. "He's the kind of guy you build a
game plan around."
Dustin Long of Sam Houston State, a transfer from Texas A&M, was
the second-team quarterback.
Campbell, Fowlkes and Long were the finalists for the Walter
Payton Award, which is given to the best player in I-AA and will be
handed out Thursday night in Chattanooga, Tenn.
"I'd love to get it," Campbell said. "Any national
recognition like this, they are team awards because not everyone
can see every player play."
James Madison and Montana, who will play in the Division I-AA
championship game on Saturday in Chattanooga, each had two players
on the three AP All-America teams.
Besides Magerko, James Madison had freshman defensive back Tony
LeZotte on the second team.
LeZotte and Drake running back Scott Phaydavong, a third-teamer,
were the only freshmen on the teams.
Montana was represented by offensive lineman Cory Procter and
defensive lineman Mike Murphy on the second team.
Harvard running back Clifton Dawson, Lehigh tight end Adam
Bergen and offensive linemen Ben Bainbridge of Furman and Elmer
McDaniel of Southern Illinois completed the first-team offense.
Jerome Mathis of Hampton, who returned an NCAA record five
kickoffs for touchdowns was picked as an all-purpose player. Jon
Scifres of Missouri State is the All-American kicker and Paul
Ernster of Northern Arizona is the punter.
Tad Kornegay of Fordham and Southern's Ahmad Treaudo, who leads
the nation with nine interceptions, round out the first-team
secondary. Linemen Brady Forsmark of Weber State and Harold Wells
of Gardner-Webb complete the first-team defense.


text:
|Publication number
|Publication type
|Publication date
|Mar 19, 1974
|Filing date
|Dec 10, 1971
|Priority date
|Dec 10, 1971
|Also published as
|Publication number
|M Matzner, J Mcgrath
|Original Assignee
|Union Carbide Corp
|Export Citation
|BiBTeX, EndNote, RefMan
|Referenced by (3), Classifications (11), Legal Events (2)
|External Links: USPTO, USPTO Assignment, Espacenet
United States Patent O 3,798,289 VINYL HALIDE POLYMER-OLEFIN COPOLYIVIER ALLOYS James Edward McGrath, Somerville, and Markus Matzner, Edison, N.J., assiguors to Union Carbide Corporation, New York, NY. No Drawing. Filed Dec. 10, 1971, Ser. No. 206,851 Int. Cl. C08f 33/08, 37/18 US. Cl. 260895 12 Claims ABSTRACT OF THE DISCLOSURE Compatible alloys or blends of at least one vinyl halide polymer and at least one copolymer of an olefin and a nitrogen-containing comonomer having a basic characteristic are produced; e.g. an alloy of poly(vinyl chloride) and a copolymer of ethylene and N-methyl-N-vinylacetamide or N,N-dimethylacrylamide.
BACKGROUND OF THE INVENTION The preparation of blends of two or more polymers has been practiced for many years. However, in many cases mixtures are produced that have little or no utility in practical application because of their poor physical properties and/or the non-compatibility of the polymers. Industry has expended huge sums to produce compatible blends having improved physical properties or to modify the properties of polymers to permit their use in different applications. Among such systems have been the attempts to produce blends of vinyl halide polymers with olefin copolymers.
SUMMARY OF THE INVENTION It has now been found that certain vinyl halide polymers can be blended with certain olefin copolymers to produce compatible alloys possessing excellent mechanical and physical properties. At high olefin copolymer contents, above about 40 weight percent, the alloys are low tensile modulus, tough, flexible compositions useful as films or as insulation for appliance and automotive electrical conductors. At high vinyl halide polymer contents, the alloys are rigid and flame resistant; they also show improved impact properties as compared to vinyl halide polymers per se and they can be used in the manufacture of pipe and similar applications. It was found that the olefin copolymer functions as a processing aid to the vinyl halide resin making it easier to process the vinyl halide polymers, and that even small amounts of the vinyl halide polymer added to the olefin copolymer render the olefin copolymer paintable. While the alloys of this invention are compatible mixtures and have good mechanical properties, it is known that mixtures of polyethylene and poly(vinyl chloride) are unattractive, incompatible systems with poor mechanical properties.
Poly(vinyl chloride) and ethylene copolymers have many known uses. The vinyl halide polymers are relatively tough, rigid, halogen-containing materials that possess good flame retardant properties, and the ethylene copolymers are tough, rather flexible, possess outstanding chemical resistance and good electrical properties but their flame resistance is poor. The combination of the two, the vinyl halide polymers and the olefin copolymers, into one tough product having the best of the physical and mechanical properties of each would be of great practical importance. Such a product would have the fireretardancy and rigidity of the vinyl halide polymer with the toughness, chemical resistance and flexibility of the olefin copolymer; this is what has now been accomplished.
The compositions of this invention are homogeneous,
compatible alloys or mixtures of a vinyl halide polymer, e.g. poly(vinyl chloride) and certain copolymer of an olefin with a nitrogen-containing comonomer having a basic characteristic, e.g., ethylene/N-methyl-N-vinylacetamide copolymer. The excellent properties of these alloys are believed to be due to the compatibility of the components thereof with each other, which compatibility was completely unexpected in view of the chemical dissimilarities of the two polymers.
The preferred olefin copolymers are those of ethylene with N-methyl-N-vinylacetamide or with N,N-dimethylacrylamide and the preferred vinyl halide polymer is poly- (vinyl chloride) or the copolymer of vinyl chloride with up to 2 weight percent ethylene. The olefin copolymer can have a melt index of from about 0.1 to about 200 dgm./ min., preferably from about 1 to about 10 dgm./min.
The alloys can have present therein minor amounts of other polymers. Among the most beneficial one can mention poly-epsilon-caprolactone and the copolymers of epsilon-caprolactone, especially the copolymers thereof with oxiranes or epoxides. These polymers are well known and commercially available.
The compositions of this invention are compatible mixtures of at least one vinyl halide polymer and at least one copolymer of an olefin with a nitrogen-containing comonomer having a basic characteristic as hereinafter defined. The vinyl halide polymer can be modified by the presence therein of up to about 25 weight percent of another polymerizable monomer, including, for example, ethylene, propylene, acrylic acid and methacrylic acid and their esters, acrylonitrile, vinyl esters of aliphatic and aromatic carboxylic acids, vinyl alkyl ethers, hydroxyalkyl acrylates and methacrylates, etc. As used in this specification the term poly(vinyl halide) includes the homopolymers and such copolymers of vinyl chloride and vinylidene chloride.
The compatible alloys can contain from about 1 weight percent to about 99 weight percent of the poly(vinyl halide) and from 99 weight percent to 1 weight percent of the ethylene copolymers in the blend. At high poly(vinyl halide) content the alloys are rigid and possess improved impact properties as compared to the unblended poly(vinyl halide). As the concentration of the poly(vinyl halide) decreases and the concentration of the olefin copolymer increases, the alloys become less rigid and more flexible. The alloys are prepared by conventional blending methods, using such known devices as roll mills, mixing extruders, Banbury and Brabender mills, or by solution mixing. The compositions can have present there in antioxidants, asbestos, glass fibers, fillers, pigments, carbon black, titanium dioxide, slip additives, light stabilizers, and other additives in the usual quantities conventionally added to polymers. The compositions can in some instances, be cured, vulcanized or crosslinked by conventional methods known to those skilled in the art to further enhance or modify the physical properties thereof.
The poly(vinyl halide) polymers are well known and require no further description as to their production. Any vinyl halide polymer wherein the vinyl halide is vinyl chloride or vinylidene chloride having up to 25 weight percent of another polymerizable monomer, as these were hereinbefore described, can be used. Illustrative thereof are poly(vinyl chloride), poly(vinylidene chloride), vinyl chloride (95)/methyl acrylate (5), vinyl chloride (98)/vinyl acetate (2), vinyl chloride (97)/ethylene (3), vinylidene chloride (96.5 )/acrylic acid (3.5), vinyl chloride (95 )/propylene (5), vinyl chloride ()/2-hydroxypropyl acrylate (10), vinyl chloride ()/acrylonitrile (5), and similar copolymers known in the art.
The nitrogen-containing comonomers having a basic characteristic used in the production of the olefin copolymer are those of the formula:
wherein R is hydrogen or alkyl of from 1 to 8 carbon atoms; R is an --NHJCH3 group, an --OCONHR" group, a -CONR group, a -(CH COOYNR group, a pyridyl group, a
group, a quinolyl group, a --(CH quinolyl group or a CN group; R" is lower alkyl of from 1 to about 8 carbon atoms or phenyl wherein the phenyl group can be substituted with a lower alkyl group or a halogen atom; R taken singly is hydrogen, alkyl of from 1 to about 8 carbon atoms, aryl or substituted aryl of from 6 to 20 carbon atoms (such as phenyl, naphthyl, tolyl, xylyl, benzyl, etc.) or cycloalkyl of from 5 to about 20 carbon atoms (such as cyclopentyl, methylcyclopentyl, dimethylcyclopentyl, cyclohexyl, etc.); both R taken together with the N atom to which they are attached can form a heterocyclic ring having from 3 to 12 ring atoms; Y is a divalent alkylene group having from 1 to about 8 carbon atoms; X is nothing or -O or S; and m has a value of to 8. Illustrative of useful polymerizable basic monomers one can mention N-methyl- N-vinylacetarnide, vinylacetamide, acrylamide, methacrylamide, N-methylacrylamide, N-isopropylacrylamide, N-t-butylacrylamide, N-hexylacrylamide, N-phenylacrylamide, N cyclopentylacrylamide, N,N dimethylacrylamide, N,N-diethylacrylamide, N-methyl-N-phenylacrylamide, N,N-diphenylacrylamide, the 2-, 3- and 4-vinylpyridines, vinyloxypyridine, vinyl pyridyl sulfide, alloxypyridine, allyl pyridyl sulfide, vinylquinoline, vinyl isoquinoline, vinyloxyquinoline, vinyloxy-isoquinoline, vinyl quinolyl sulfide, allyloxyquinoline, allyloxy-isoquinoline, allyl quinolyl sulfide, allyl isoquinolyl sulfide, aminomethyl methacrylate, aminomethyl acrylate, S-aminopentyl acrylate, 2-aminoisopropyl acrylate, N-methylaminomethyl acrylate, N-butylaminomethyl acrylate, N, N-dimethylaminoethyl acrylate, N-phenylaminoethyl acrylate, N-cyclohexylaminomethyl acrylate, aminophenyl acrylate, N-methylaminophenyl acrylate, aminomethyl butenoate-l, 6-aminohexyl butenoate-l, N-methylaminopropyl butenoate-l, N,N-diethylaminoethyl butenoate-l, N-phenylaminomethyl butenoate-l, N-cyclopentylamino phenyl butenoate-l, Z-carbamylbicyclo[2.2.1]hept--ene, 2-(N-methylcarbamyl)bicyclo [2.2.1]hept 5 ene, 2-(N- pentylcarbamyl) bicyclo [2.2.1] hept-S-ene, 2- N,N-dimethylcarbarnyDbicyclo[2.2.1]hept 5 ene, 2-(N-phenylcarbamyl)bicyclo[2.2.1]hept 5 ene, 2-(N-cyclopentylcarbamyl)bicyclo[2.2.1]hept-5-ene, bicyclo [2.2.1 hept-Z-en- S-yIacetamide, 4-(bicyclo[2.2.1]hept 2 en-S-yDbutyramide, bicyclo[2.2.l]hept 2-en-5yl-N-methylacetamide, bicyclo[2.2.l]hept-Z-en-S-yl N,N dimethylacetamide. Compounds wherein the two R" units taken with the N atom form a heterocyclic ring such as Z-(pyridylcarbonyl)bicyclo[2.2.1]hept-5-ene, as well as urethane compounds such as vinyl N-methyl carbamate, vinyl N-ethyl carbamate, vinyl N-phenyl carbamate, are also included.
The olefins used to produce the olefin polymers are those of the formula CH =CHR wherein R is hydrogen or alkyl having from 1 to about 8 carbon atoms. Illustrative thereof are ethylene, propylene, butene-l, isobutylene, pentene-l, hexene-l, neopentene-l, octene-l, 3-methylbutene-1, 4-methylpentene-1 and the other known olcfinst 4 The vinyl halides are represented by the formula:
RV CHz=-Halogen comonomer having a basic characteristic contain the following units in the molecule:
CHzH- and The concentration of the nitrogen-containing monomer in the copolymer thereof with an olefin can vary from about 3 weight percent to about 50 weight percent, and is preferably from about 5 weight percent to about 25 weight percent. These copolymers are well known and they can be produced by the conventional free-radical initiation or emulsion or suspension processes. Illustrative of a few suitable solid copolymers one can mention ethylene/N-methyl-Nvinylacetamide,
ethylene/ propylene /N-methy1-N-vinylacetamide,
ethylene/ N,N- dimethylacrylamide,
ethylene/propylene/Z- N,N-dimethylcarbamyl bicyclo- [2.2.1]hept-5-ene and ethylene /2-aminoethyl acrylate.
The copolymers containing the urethane linkage OH H l are most readily produced by reacting an ethylene/ vinyl alcohol copolymer with a monoisocyanate (methyl isocyanate, butyl isocyanate, cyclohexyl isocyanate, phenyl isocyanate, etc.), under anhydrous conditions with a conventional urethane-forming catalyst, e.g. stannous octoate or dibntyltin dilaurate.
The following examples serve to further describe the invention. In this specification the following test procedures were used:
Melt index, dgrn./min. ASTM D 123 8-65T Density, g./ cc ASTM D 1505-63T Tensile modulus, p.s.i ASTM D 63 8-64T Tensile strength, p.s.i ASTM D 638-64T Elongation, percent ASTM D 63 8-64T Pendulum impact, ft.-lb./in. ASTM D 1822-61T Izod impact, -ft.-lb./in. ASTM D 256-56 EXAMPLE 1 Ninety parts of a poly(vinyl chloride) resin having 1.5 weight percent ethylene copolymerized therein was fluxed on a two-roll mill at C. with 2 percent of an alkyl tin mercaptide stabilizer (Advastab TM-). To the clear melt there was added 10 parts of an ethylene copolymer having a 9.1 weight percent content of N-methyl-N- vinylacetamide and a melt index of 5 dgmjmi The melt remained clear and this was indicative of a high degree of compatibility between the two resins. Compression molded plaques were prepared at a temperature of 175 C. and a pressure of 20,000 p.s.i., these plaques were 20 mils thick. The plaques had a tensile modulus of 240,000 p.s.i., tensile strength of 6,100 p.s.i., elongation at 'break of 90%, pendulum impact of 60 ft.-lb./in. and Izod of 1.4 ft.- lb./in. notch. For comparative purposes plaques were compression molded from the same unmodified poly(vinyl chloride) resin; these plaques had an elongation of only 8% and an Izod of only 0.34 ft.-lb./in.3.
EXAMPLE 2 Fifty parts of the same poly(vinyl chloride) resin used in Example 1 and containing the same amount of the tin stabilizer were blended with fifty parts of an ethylene copolymer having 18.4 weight percent N-methyl-N-vinylacetamide and a melt index of 1.5 dgm./min. and then the plaques were compression molded by the same procedure described in Example 1. The molded plaques had a tensile modulus of 21,000 p.s.i., tensile strength of 3,300 p.s.i. and elongation at break at 225% and a pendulum impact of 447 ft.-lb./in. These plaques were clear and transparent. The properties of these plaques are to be compared with the properties of the comparative plaques produced in Example 1 using the unmodified po1y(vinyl chloride) resin and the improvements in the properties of the novel alloy are readily apparent as compared to the properties of the control.
To the clear blend prepared above, there was added two weight percent dicumyl peroxide and plaques were then compression molded and subsequently crosslinked at 160 C. for 10 minutes. The crosslinked composition had a tensile modulus of 19,000 p.s.i., tensile strength of 3,600 p.s.i., and elongation at break of 255% and a pendulum impact of 468 ft.-lb./in.
Attempts to prepare a homogeneous blend of the same poly(vinyl chloride) resin with polyethylene homopolymer produced a cheesy mixture having no practical utility.
When two weight percent of antimony oxide was added to the clear, homogeneous alloy of this example and the mixture then molded into sixty mils thick test plaques it was observed that the plaques self-extinguished in one second after the flame was removed in a simulated vertical fire test.
EXAMPLE 3 Thirty grams of the poly(vinyl chloride) resin of Example 1, containing two weight percent of the same tin stabilizer were fluxed with ten grams of ply(epsiloncaprolactone) having a reduced viscosity of 0.7 (0.2 gram per 100 millilters of benzene at 30) at 175 C. Then sixty grams of the same ethylene/N-methyl-N-vinylacetamide copolymer of Example 2 was added to the clear melt and fluxing was continued until homogeneity was achieved. The final melt, which was clear and transparent, was compression molded into plaques 20 mils thick, as described in Example 1. These plaques had a tensile modulus of 12,- 700 p.s.i., tensile strength of 3,200 p.s.i., elongation at break of 325% and pendulum impact of 500 ft.-lb./in.
EXAMPLE 4 In the same manner as described in 'Example 1 30 parts of the same poly(vinyl chloride) resin were blended with 70 parts of an ethylene copolymer having a 15 weight percent acrylamide content and a melt index of 15 dgm./ min. The alloy was compression molded as described in Example 1 to produce plaques 20 mils thick. These plaques had a tensile modulus of 23,000 p.s.i., tensile strength of 1,900 p.s.i., elongation at break of 175% and pendulum impact of 200 ft.-lb./in.
EXAMPLE 5 An ethylene copolymer having a 22 weight percent vinyl alcohol content and a melt index of 20 dgm./min. was reacated with n-butyl isocyanate in anhydrous chlorobenzene using 0.1% stannous octoate as the catalyst. This converted all of the hydroxyl groups into urethane groups.
Fifty parts of the ethylene/n-butylurethane copolymer produced above were blended with 50 parts of the same poly(vinyl chloride) used in Example 1 under the same conditions therein set forth. Plaques prepared from this alloy were homogeneous, clear, flexible and transparent. In comparison, when the unmodified ethylene/vinyl alcohol was fluxed with the poly (vinyl chloride) resin, hazy opaque plaques resulted.
Similar results are obtained when methyl isocyanate is substituted for the n-butyl isocyanate.
EXAMPLE 6 Fifty parts of the same stabilized poly(vinyl chloride) used in Example 1 and 50 parts of an ethylene copolymer having an 11 weight percent 4vinyl pyridine content and a melt index of 10 dgm./min. were dissolved in tetrahydrofuran at 60 C. to give a clear one phase solution. The alloy was precipitated by coagulation with methanol and after separation it was vacuum dried. The dried flulfy alloy was a compatible mixture and plaques were compression molded therefrom.
EXAMPLE 7 In the same manner described in Example 1, fifty parts of the same stabilized poly(vinyl chloride) resin were fluxed with fifty parts of an ethylene copolymer having an 11 weight percent N,N-dimethylaminoethyl methacrylate content and a melt index of 25 dgm./min. The alloy was clear and compatible; tough, flexible films were produced by compression molding at 20,000 p.s.i. at a temperature of 175 C.
EXAMPLE 8 In the same manner described in Example 1, parts of the same stabilized po1y(vinyl chloride) was fluxed with 5 parts of an ethylene copolymer having a 13 weight percent acrylonitrile content. The alloy was a tough, rigid, clear and transparent composition having an Izod impact value of 8 ft.-lb./in. as compared to a control value of 0.34 ft.-lb./in. for the poly (vinyl chloride) per se.
EXAMPLE 9 In the same manner as described in Example 1, twenty parts of the same stabilized poly(vinyl chloride) resin, parts of polyethylene having a melt index of 1 dgm./ min. and a density of 0.96 g./cc., 30 parts of inch long glass fibers and 10 parts of the same ethylene/N-methyl- N-vinyl acetamide copolymer used in Example 2 were fluxed to yield a homogeneous compatible mixture. This mixture was injection molded at 200 C. to produce tough, rigid plaques that were 60 mils thick. These plaques had a very slow burning rate in contrast of the very rapid burning observed with plaques produced from the polyethylene and glass fibers only. The plaques produced from the alloy had a tensile modulus of 370,000 p.s.i., a tensile yield strength of 4,300 p.s.i. and the heat deflection temperature (264 p.s.i.) was 183 F.
EXAMPLE 10 Poly (vinyl chloride), parts 30 50 Ethylene copolymer, part 70 50 Tensile modulus, p.s.i. 12,600 29,000 Tensile strength, p.s.i. 4, 100 3, 600 Elongation, percent 350 265 Pendulum impact, ft.-lb./1n. 630 580 In comparison, the tensile modulus of the ethylene copolymer itself was only 3,200 p.s.i.
What is claimed is:
1. A polymer alloy comprising at least one vinyl halide polymer selected from the group of homopolymers of said vinyl halide and copolymers of said vinyl halide with up to about 25 weight percent of another polymerizable monomer and at least one olefin copolymer of an olefin of the formula:
with a nitrogen-containing comonomer having a basic characteristic selected from the group:
wherein R is hydrogen or alkyl of from 1 to 8 carbon atoms, R is an group, an -OCONHR" group, a CONR group, a --(CH COOYNR group, a pyridyl group, a
group, a quinolyl group, a (CH Xquinolyl group, or a -CN group; R is lower alkyl of from 1 to 10 carbons, phenyl, lower alkyl substituted phenyl or halogen substituted phenyl; R taken singly is hydrogen, alkyl of from 1 to 8 carbons, aryl of from 6 to carbons, or cycloalkyl of from 5 to 20 carbons; and both R' groups when taken together with the N atom form a heterocyclic ring having from 5 to 12 ring atoms; R is hydrogen, or alkyl of 1 to 8 carbons; Y is divalent alkylene of 1 to 8 carbon atoms; X is noting or O or S--; and m has a value of 0 to 8.
2. A polymer alloy as claimed in claim 1 wherein the vinyl halide polymer is a polymer of a vinyl halide of the formula:
R v C HF-HBJOEGD wherein R is of the group hydrogen or halogen and wherein said polymer constitutes from about 1 weight percent to about 99 weight percent of the total weight of the vinyl halide polymer plus the olefin copolymer.
3. A polymer alloy as claimed in claim 1 wherein the olefin copolymer is a copolymer of ethylene and N- methyl-N-vinylacetamide.
4. A polymer alloy as claimed in claim 1 wherein the olefin copolymer is a copolymer of ethylene and acrylamide.
5. A polymer alloy as claimed in claim 1 wherein the olefin copolymer is a copolymer of ethylene and n-butylcarbamylethylene.
6. A polymer alloy as caimed in claim 1 wherein the olefin copolymer is a copolymer of ethylene and 4-vinyl pyridine.
7. A polymer alloy as claimed in claim 1 wherein the olefin copolymer is a copolymer of ethylene and N,Ndimethylaminoethyl methacrylate.
8. A polymer alloy as claimed in claim 1 wherein the olefin copolymer is a copolymer of ethylene and acrylonitrile.
9. A polymer alloy as claimed in claim 1 wherein the olefin copolymer is a copolymer of ethylene and N,N- dimethylacrylamide.
10. A polymer alloy as claimed in claim 1 wherein a third polymer is additionally present in said alloy.
11. A polymer alloy as claimed in claim 10 wherein said third polymer is poly-epsilon-caprolactone.
12. A polymer alloy as claimed in claim 10 wherein said third polymer is polyethylene.
References Cited UNITED STATES PATENTS 3,584,079 6/1971 Trementozzi et a1. 26()876 FOREIGN PATENTS 924,457 4/ 1963 Great Britain 260-897 MURRAY 'I'ILLMAN, Primary Examiner C. SECCURO, Assistant Examiner US. Cl. X.R. 260896, 897 C
|Citing Patent
|Filing date
|Publication date
|Jul 10, 1985
|Sep 13, 1988
|Minnesota Mining And Manufacturing Co.
|Polymer blends with high water absorption
|Jun 13, 1988
|Aug 22, 1989
|Minnesota Mining And Manufacturing Company
|Polymer blends with high water absorption
|Jul 19, 1988
|Dec 26, 1989
|Solvay & Cie
|Flexible compositions based on vinyl chloride polymers comprising poly-ε-caprolactone
|U.S. Classification
|525/186, 525/210, 525/218
|International Classification
|Cooperative Classification
|European Classification
|Oct 8, 1986
Owner name: UNION CARBIDE CORPORATION,
Free format text: RELEASED BY SECURED PARTY;ASSIGNOR:MORGAN BANK (DELAWARE) AS COLLATERAL AGENT;REEL/FRAME:004665/0131
Effective date: 19860925
|Jan 9, 1986
Owner name: MORGAN GUARANTY TRUST COMPANY OF NEW YORK, AND MOR
Free format text: MORTGAGE;ASSIGNORS:UNION CARBIDE CORPORATION, A CORP.,;STP CORPORATION, A CORP. OF DE.,;UNION CARBIDE AGRICULTURAL PRODUCTS CO., INC., A CORP. OF PA.,;AND OTHERS;REEL/FRAME:004547/0001
Effective date: 19860106


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Latest Releases
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I Can't Wait – International Remix Contest
Calling all DJs and producers! SIPREC is raising the stakes with a remix contest by strangers from a house minded paradise. Fab Morvan (aka. Milli Vanilli), UK's finest Miss Mavrik and Bombasquad along with Strangers in Paradise Recordings (SIPREC) teamed up to give music fans a chance to remix one of their upcoming singles "I Can't Wait" (more…)
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WOW!!! After the exclusive documentary last weekend on Oprah Winfrey … Our release "Mind Over Matter" has also being featured on the official Oprah Winfrey site: http://www.oprah.com/own-where-are-they-now/Fab-Morvans-Mind-Over-Matter-Song-Stream-Video #WorldPremier (more…)
Official Music Video – Dance With Me
De La Rock's debut on SIPREC is already one to remember, with heavy hardhitting remixes by the one and only Ron Carroll, 1st Lady of House Carita La Nina and Remix Heavyweight Melvin Reese promises to be one of Strangers in Paradise's biggest releases of 2013. De La Rock's "Dance with Me" features the beautiful voice of Lysa and is all about that hard to get attractive eye catchy look you have on your radar from the moment you walk into a club! (more…)


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A single mother still living in the house she grew up in struggles to deal with her drifter brother when he comes home for a visit.
Genre: Feature Film-Drama
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3 bedroom detached house to rent Clyfford Road, Ruislip, HA4A MUST SEE A well presented end terraced family home located on a popular road in the heart Ruislip. The property as been recently refurbished and has a large living room, three bedrooms, one bathroom, eun suite and a large kitchen diner. More details ›
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2 bedroom terraced house to rent RuislipSituated on a popular road in Ruislip Manor this much improved upon two bedroom terrace house has been tastefully decorated by the current owner. Having been skilfully designed it provides comfortable family living and is set in this convenient location, a short walk from Ruislip Manor, Ruislip G... More details ›
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2 bedroom flat to rent Carmichael Close, Ruislip, Middlesex, HA4A modern and spacious TWO bedroom top floor apartment set in Carmichael Close just off West End Road and offers fantastic transport links with Ruislip Gardens Tube Station (Central Line) a stones throw away. This light and airy apartment comprises: entrance hallway, modern kitchen with white... More details ›
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3 bedroom end of terrace house to rent RuislipOrchard Property Services are delighted to present to the market this lovely three/ four bedroom end of terraced, located in a popular residential road a moments walk from Ruislip Gardens station. Available NOW and presented UNFURNISHED More details ›
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2 bedroom flat to rent West End Road, Ruislip GardensSpacious, light-filled interiors and an ultra convenient location give this two bedroom flat enormous appeal. The property is ideal for tenants seeking a well presented home, close to the areas amenities.The property has been refurbished to include a new kitchen, new flooring and new paintwork. More details ›
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Country Hearth Inn Camden
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Jordan Hall at New England Conservatory Tickets and Upcoming Events
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DEFINITION of 'Coinsurer'
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BREAKING DOWN 'Coinsurer'
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Easy Recipes for a First Thanksgiving
From a simple ancho-scallion roast turkey breast to puff pastry apple pie, here are easy recipes for a first Thanksgiving.
Herbed Crème Fraîche Dip with Crudités
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In colder weather, food blogger Pim Techamuanvivit might serve radishes, asparagus and baby carrots with a simple dip like this tarragon-spiked crème fraîche. Although Pim usually serves the vegetables whole, occasionally she'll slice them paper-thin on a mandoline and toss the strips together.