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Architectural Digest
The latest interior design, architecture, shopping, travel, great design items and more from ArchitecturalDigest.com.
I'm Rick. I am an independent IT contractor. My live partner is Julie and we...More
The latest interior design, architecture, shopping, travel, great design items and more from ArchitecturalDigest.com.
Bookish is the new online home for book discovery. Personalized recommendations, book previews and unique editorial are coming soon: http://bookish.com
Gilt City Boston provides members with unique access to Boston's best services at top restaurants, spas, entertainment venues, museums & more.
Gizmag covers the full spectrum of emerging technologies, invention and innovation - from automotive to aerospace, from handhelds to supercomputers, from robotics to home automation, the site reports on all major announcements across 40 categories
Harvard University, which celebrated its 375th anniversary in 2011, is committed to excellence in teaching, learning, and research, and to developing leaders who make a difference globally. See updates on science, humanities, campus life, and more.
HISTORY is the leading destination for revealing, award-winning original non-fiction series and event-driven specials that connect history with viewers in an informative, immersive and entertaining manner across multiple platforms.
LIFE.com is the largest collection of professional, editorially-curated photography on the Web. The site features more than 15 million images with thousands of new photos added daily. Visitors have access to LIFE's legendary photo archives, as well as up-to-the-minute pictures of the people and places shaping our world today. LIFE's StumbleUpon channel brings you expertly curated galleries selected by LIFE's editors - follow LIFE on SU to see your world - yesterday and today.
Scientific American, the oldest continuously published magazine in the U.S., has been bringing its readers unique insights about developments in science and technology for more than 165 years. More than 140 Nobel laureates have written for Scientific American, most of whom wrote about their prize-winning works years before being recognized by the Nobel Committee. The website, launched in 1996, is a dynamic science resource of daily news, archived articles, podcasts, videos, educational, and community tools. To reach readers in other corners of the internet, Scientific American is also on Twitter (@sciam) and Facebook.
Stanford University is one of the world's leading research & teaching institutions.
TEDTalks capture the world's most fascinating mavericks, icons and geniuses, all giving the talk of their lives in 18 minutes from the TED stage. We're proud to share these ideas worth spreading with the world, for free. TED stands for Technology, Entertainment, Design, but the ideas here are far broader: art, science, business, politics, space, love, and more. Join the conversation on www.TED.com or on Facebook at www.facebook.com/TED. The full list of talks is available on our Website.
Follow Travel Channel on StumbleUpon for travel tips, articles, resources, inspiration, and clips from our shows.
Get the latest news and insight from across the The Wall Street Journal Digital Network. Follow the top reads from The Wall Street Journal, All Things Digital, MarketWatch and SmartMoney.
The latest news and trending content from Forbes.com, the homepage for the world's business leaders.
Join us in discovering the grandeur of innovation, ranging from today's newest technologies to Edison's earliest inventions 130 years ago.
Where knowledge junkies get their fix.
PCMag.com is seen as the trusted online brand for labs-based product reviews, tech news, buying guides, market-leading opinion, proprietary downloads, special features, and much more.
FitSugar inspires a healthy, balanced lifestyle by giving women tips on the latest workout trends and gear, common sense advice on healthy eating, and exercises for relieving stress.
GeekSugar takes a unique approach to tech and gadget tips and tricks, enabling all users (from the novice to the most tech savvy) to glean valuable tech insights.
Commentary, Research and News that cover all aspects of Human Behavior, from the workings of the brain, to relationships and the larger cultural forces that influence our decisions.
THE X FACTOR USA official channel featuring the latest on THE X FACTOR USA show, videos, photos, news, contestants and judges. Your official source for Simon Cowell's new singing competition.


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GORGEOUS Seal Pointed Male Siamese Himalyian Kiteen
I have a sweet big boy up for sale! He is a seal pointed, male and has his first set of shots, and vet exam. Parents are a blue point Siamese and a seal pointed himilayian. Kitty will have medium to longer length coat. Tested for feline leukemia and FIV
He is very cuddly and sweet, and he has a great temperament, He will do very will in a home with small children or other animals. He is ...
Oct 7 -
Due to an illness in the family, we are forced to rehome some of out cats and kittens from our cattery. First is a 2 year old Flame Point Male Siamese with an extremely lovable disposition. He would be an exceptional pet for an elderly or senior person because he loves affection. Next, we have a 2 year old Seal Point Female that thinks she is the boss of the cattery. Next is a 7 month old ...
Oct 5 -
TICA Snow Bengal Kittens
I have 3 females and 1 male seal lynx bengal kittens for sale. They are completely up to date on shots and vaccinations. TICA Registered. They are 12 weeks old and ready for new homes today. The pictures that I have posted are the best that I have at the moment. Their markings are very faint at this time but in about 2 months or so they will really start to come out more up until they are the ...
Sep 29 -
Bengal kittens & Young adults available
Apologies for the pictures, our computer is not cooperating with recent upgrade.
Asian Grace Bengals has gorgeous Bengal kittens & Young adults available! Deposits are being now being accepted to reserve the kitten of your choice. Kittens should be able to go home with their new families between 10-12 weeks old. Kittens have wild exotic heads, glittered coats with beautiful rosettes! We have ...
Sep 27 -
lovable long haired siamese female. 1 year old
Need to find a home for my long haired siamese female. Used to other cats and dogs and children. She prefers older kids or adults but will tolerate younger kids. Never clawed them, just runs to the cloest adult. :) inside family pet only. $300 cash only. 330-423-8679
Sep 21 -
Lilly the calico
Lilly is loving and loves to give love she is very friendly and needs a good home with loving family loves to play can keep her self entertained for hours.
Sep 20 -
Siamese Kittens Beautiful-Healthy
Gorgeous Siamese Kittens located in Ashtabula Ohio. Available now,are two Male Flame Points age 13 weeks and One Male Blue Point age 13 weeks. Available in two weeks are Male Seal Points and Male Blue Points age 6 weeks. They can be held for the next two weeks with a deposit made via PayPal. Available in eight weeks are Seal Point Male Kittens, and Blue Point Male Kittens also female Seal ...
Sep 18 -
Purebred Manx Kittens
Show stock purebred rumpies, blue female, blue tabby or oscelot marked make.furst shots wormed, no shipping cash only
Supply's given. Serious Manx enthusiast only, email for pics have hospital family emergency lowered from $225 to $100, no holds
Sep 18 -
Rosetted Female Bengal Kitten
Rayni is now available and can leave me the first week in October!
When our pet kittens leave us they are TICA litter registered, vet checked, spayed/neutered, current on vaccinations, and come with a written health guarantee. Adults in our program are HCM and PK Def screened. Show/breeder kittens also available. Proud TICA registered breeder for 15 + years. Our kittens are healthy, well ...
Sep 17 -
F2 Bengal Kitten
This wonderful little silver F2 Bengal (grandfather is an Asian Leopard Cat) is now available for his forever home. Richey's coat is as soft as cotton and will get very pelt like when grown. He is currently in his fuzzy stage and will develop beautiful rosetting over the next few months. Richey's color reminds me of the "ghost" version of mom. I can just imagine how beautiful he will be when ...
Selkirk Rex Kittens for Sale
Sweet Teddy Bear kittens. The breed is Selkirk Rex, the cat in sheep's
clothing...We have both curly & silky coats.They have sweet
personalities, huge eyes & expressions that'll melt your heart.
These lil sweeties are ready for a forever loving pet/companion home. Eating premium kibble and canned wet food. Using the litter box.
Dewormed & vaccinated. Written health guarantee.
Call/text 330 ...
Sep 15 -
Maine Coon Kittens Available
Maine Coon Kittens available at Maine Villa Cattery @ MaineVilla.com. Please call if you are interested in a Maine Coon Kitten, call 330-620-5861. thank you. Pictures available .
Sep 15 -
Adorable Siamese Kittens! Update 2 left! Price Reduced!
Update we have 2 left one blue point and one seal point. Price Reduced to $250.
We have 3 adorable Siamese Kittens available.
They are all males.
These kittens were born 7-7-15 and will be 10 weeks old tomorrow and ready for their new homes.
They have been vet checked, dewormed three times, and received their first vaccine.
They will come with their vet papers, a small bag of the food ...
Sep 14 -
Munroe Falls
CFA Reg. Cream and White BiColor Male Persian Kitten Born July 30/2015
CFA Registered Cream and White BiColor Male Persian Kitten available as a pet. Breeding rights would be additional cost. Please email or call us for additional information about this kitten.
Sep 13 -
CFA Reg. Blue and White Male Persian Kitten Born Aug. 5, 2015
CFA Registered Bllue and White BiColor Male Persian Kitten. He may possibly be a blue smoke and white as it is to soon to tell. He is available as a pet or as a breeder. Price listed is with full breeding rights. Pet price would be reduced. Please email or call us for further information about him.
CFA Registered Blue and White Male Persian Kitten Born Aug. 5, 2015
CFA Registered Blue and White Male Persian. He is available as a pet or as a breeder. He may possibly a blue smoke and white as it is to soon to tell with him. Please email or call for additional information about him. Price posted is for full breeding rights for him and a pet price will be less.
CFA Reg. Silver Tabby and White Female Persian Kitten
CFA Registered Silver Tabby and White Van Female Born August 17, 2015. Kitten is available as a breeder or as a pet.Full price includes full breeding rights for her. Pet price will be less. Please call or email us for further information about her.
Black Female Kittens
Black female kittens for sale, very affectionate and litter trained. $25 each.
This ad was posted with the eBay Classifieds mobile app.
Sep 13 -
North Lawrence
CFA Reg. Brown Tabby and White Female Persian Kitten
CFA Registered Brown Tabby and White Female Persian Kitten Born July 30, 2015. Kitten is breeder/show quality. Price includes full breeding rights to the kitten. Please email or call 330-602-1744.
CFA Registered Black Smoke and White Van Male
CFA Registered Black Smoke and White Van Male of Breeder/Show Quality. Price includes full breeding rights. Please email or call for additional information on this kitten. 330-601744. Kitten was born August 5, 2015.

subset: commoncrawl


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Cyanide in Apricot & Cherry Pits
Even before I wrote the maraschino cherry post, a number of people had asked me whether the quantity of cyanide in fruit pits / stones (apricot, peach, cherry, etc.) was significant enough to harm someone and whether there was a way to remove the cyanide from the kernels. Since the world has a fascination with deadly ingredients, let's talk about the toxicity of fruit… [Continue]
Follow Art of Drink on Twitter
Twitter Updates
Labatt buys Mill Street brewery drnk.ca/millstblue #beer #news via @CBCNews
Future Bulleit Bourbon Distillery Coming Along Quite Nicely drnk.ca/1WQfG5q
The Harper government gave $8M in taxpayers money to a US Republican Institute drnk.ca/harper8M #elxn42 #cdnpoli
Introducing The Boylan Heritage Line of Craft Cocktail Mixers drnk.ca/1VIciMN #Soda
Whisky pours into Dumfries and Galloway and the Borders bbc.com/news/uk-scotla…
Thanks @dawinship I still have a bottle of Abbott's for you, PM your mailing address.
@JustinTrudeau please ask @CPC_HQ if Jews will be charged with barbaric acts if they perform a circumcision on their child? #sliperyslope


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Securing your remote agents
We strongly recommend that you do not enable remote agent installation without securing them on any Bamboo instance accessible from a public or untrusted network. Creating remote agents is disabled by default. If you choose to enable your remote agents without securing them, please read this Security Advisory to understand the security implications.
You can secure your remote agents by configuring them to use SSL (Secure Sockets Layer). This protocol provides a secure mechanism for communication between your Bamboo server and remote agents. The information below describes how to configure your remote agents to use SSL.
On this page:
Step 1. Create keys, stores and certificates
The first step in configuring your remote agents to use SSL is to create the required keys, stores and certificates. These artefacts are created using a keytool, as described below:
To create the required keys, stores and certificates for your server and agents:
Using a keytool, create a certificate for your server by entering the following command:
The server's certificate will be created. Export the certificate, so it can be shared with clients, by entering the following command:
Each client should now be able to access the server's certificate. Create a keystore for each client, by entering the following command:
Create a truststore for each client and import the server's certificate, by entering the command below. This establishes that the client "trusts" the server:
Step 2. Tell your Bamboo server and agents where to find the stores
The second step in configuring your agents to use SSL is to instruct your Bamboo server and agents to use the keystores and truststores that you have just created.
To tell your server where to find the keystore:
- Add the system properties '
javax.net.ssl.keyStore=/path/to/server.ks' and '
javax.net.ssl.keyStorePassword=password' to your VM, by carrying out any of the following three steps:
Set the SSL_OPTS environment variable to hold the '
javax.net.ssl.keyStore=/path/to/server.ks' and '
javax.net.ssl.keyStorePassword=password' properties.
To tell your agents where to find the keystore and truststore:
For each agent,
Tell your agent where to find the keystore and the trust store, by executing the following command to run the agent,
including the following command line parameters,
where <agentserverURL> is the URL of the agent's server, e.g.
For example,
Step 3. Configure your Bamboo server to use SSL
Once the server and agents know where to find the keystores and truststores, the final step is to instruct your Bamboo server to start using SSL so that agents will be able to authenticate the server.
To configure your Bamboo server to use SSL:
If you are setting up Bamboo for the first time,
- Launch the Bamboo Setup Wizard and change the protocol of the 'Broker URL' to 'SSL'.
Or, if you are configuring an existing installation of Bamboo,
- Shut down your Bamboo server and agents.
- Change the protocol of your 'Broker URL' in the bamboo.cfg.xml file to 'SSL'. Note, do not change the address of this URL.
<property name="bamboo.jms.broker.uri">ssl://myhost:myport?wireFormat.maxInactivityDuration=0</property>
- Start up the Bamboo server.
- Start up the Bamboo agents. If your agents do not start up, please check that you have set up your certificates correctly.
Was this helpful?
Thanks for your feedback!
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5 Archived comments
The last time I was running through this process I believe I got this working correctly. This time however I have run into a problem (whose solution I have now found) but it made me wonder if these directions are missing a step or if I missed a step in some other part of the process this time which I did not miss the last time.
Adding the javax.net properties to SSL_OPTS was not enough, by itself, to allow the brokers to work correctly. Nothing that I can see uses that variable by default. I needed to add those arguments to JAVA_OPTS instead for them to work.
I seem to recall seeing the SSL_OPTS="-Djavax.net...." JAVA_OPTS="$SSL_OPTS" pair in the documentation before but cannot find it now.
Additionally, the SSL_OPTS line is not valid shell (there are invalid spaces around the equals sign and no quotes on the right-hand side of the assignment). Also, the erroneous "one of the following three steps" text that was previously removed was added back recently for some reason.27 May 2014
I just confirmed that adding keystore defines to JAVA_OPTS was necessary with Bamboo 126.96.36.199 Oct 2014
I see that Bamboo broker allows multiple transports besides tcp. I am wondering how to setup a Bamboo server that allows broker communication (i.e. JMS payload) over https.
We have Bamboo server located at one of our company locations. Lets call this locationA. We like to run Bamboo agent from a different location. Lets call this locationB. The only ports allowed from locationB to locationA are http and https. The default broker port 54663 is not open at firewall. I am looking for ways to make this work. One idea is to tunnel agent to broker communication happen over https.
I don't see any examples. I appreciate any pointers.
Thanks25 Jun 2015
Although the HTTP transport works in general, we've never stress tested it and we won't provide guidance on its setup until we feel that it's safe for use.
We have a project planned short-term that will test that transport, it may be finished within the next two months (but as usual, we do not commit to deadlines).25 Jun 2015
I don't think we can wait two months. We have a big installation of Bamboo and other Atlassian products (10s of thousands of users).
What do we need to do to make this a high priority project for you?
Thanks26 Jun 2015


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Official Website of the New York City Department of Parks & Recreation
Find A Park > Westwood Park
Lost and Found Information
7-day forecast
Zip Code: 10314Community Board: 02Council Member:Steven MatteoPark ID: R075BAcreage: 6.56Property Type: Nature Area
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3 bd2 ba
house1248 sqftPrivate recently refurbished 3br-2 bth chalet. Private dock, backyard, deck. Adjacent to public... More
You know what you want.
Unfortunately nothing matches this search criteria. Try removing a filter or two
Or check out these popular homes
Summary for Sandy Creek
There are currently 43 resale and new homes in Sandy Creek on Trulia, including 1 open house. The average listing price for homes for sale in Sandy Creek NY was $143,983 for the week ending Sep 30, which represents a decrease of 5.7%, or $8,667, compared to the prior week.


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Get the latest Flash player
Date: 3 years ago
Runtime: 17:41
Views: 126,345
Top Comments
All Comments
omg die sehen so süß aus die beiden undetwaspeinlich ist das auch so einfach vor der Kamera rum zu machen
si my papa playing with some dirty cunts, he so hot, i want to join, grr
hot daddy, too bad he's with two chicks....be hotter with a couple bears or cubs
Love to join that party.
i only came for him, hehe.
Why do all the handsome straight men surround themselfs with unattrcative women?
he's damn gorgeous!!!!
he is gorgeous
i love blondes
so nice BBW & BHM i love it!
I love that big bear husband....great fur, nice cock!
The girl in the middle is so cute and sexy and has a lucious soft sexy body! The boyfriend has a very nice sexy cock!
I don't know german but the chubby guys is so charmingly handsome and hot.He's got a great body and dick too
very niicee bear..
OMG, he's just my type!!
German Is Sexy!
lovely chub!
That was great!! Love to watch chubbys fuck!!
what a beautiful bear! Get rid of the ladies, he needs boys.
The chubby couple is so hot!! I like how the other lady turns them on as well :o))
Is that Honey Boo Boo's mom?
Roseanne & Dan


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Alastair John Campbell(1957-), Journalist, political aide and writer; Director of Communications and Strategy (1997-2003)
Sitter in 4 portraits
'The "den", 10 Downing Street' (Tony Blair and Alastair Campbell)
by Nick Danziger
bromide print, 14 March 2003
NPG x131293
'Press Quarters of PM's Boeing 777 en route to Washington' (sitters including Tony Blair, Alastair Campbell)
by Nick Danziger
bromide print, 26 March 2003
NPG x131295
'The Road to Camp David Heliport' (sitters including Tony Blair and George W. Bush)
by Nick Danziger
bromide print, 27 March 2003
NPG x131296
Alastair John Campbell; Peter Benjamin Mandelson, Baron Mandelson
by Richard Ansett
C-type colour print, February 2005
NPG x131415
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Shop All Products
We carry over 15,000 of the very best supplements, vitamins and natural products for your health, wellness and fitness. Use the filtering options on the left to narrow your options by category, brand, price or flavor!
Supreme Protein
Supreme Protein Bar, Carb Conscious Caramel Nut Chocolate
12 Bars
List Price: $39.99
Save: $10.00 (25% off)


text:
Pretty Cougar Sucks Off And Gets Fucked By A Younger Guy
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Young guy gets caught sniffing friends mom's bra. He kisses her and rubs her small boobs, she blows him and lets him fuck her
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The health of IBM's Watson: Its future lies in startups
Tech companies, including IBM, see medical technology as important to the future health of populations - and their own.
Tech companies, including IBM, see medical technology as important to the future health of populations - and their own.
IBM is launching technology that will secure cloud apps employees use on their own for work purposes.
Identity Mixer's technology uses an algorithm to encrypt personal data that's verified---age, birthdates, address, credit card number etc.---and share only what's needed with third parties.
The Queensland government has said that it will be taking legal action against IBM to make it pay for the malfunction that occurred in the state's health payroll in 2010.
Australian-listed enterprise technology consultancy firm Oakton has received the green light from the Supreme Court of Victoria to go ahead with its acquisition by Dimension Data Australia.
IBM has named Martin Jetter as senior vice president and head of its global technology services unit.
IBM rolls out Power Systems Linux support and training across its customer-facing technology centers.
Bank extends its long-term service and technology relationship with IBM to accelerate the roll-out of new digital products and services.
IBM launched a Talent Management and Change consulting unit as it aims to court more chief HR officers.
US law can apply anywhere in the world, so long as a technology company has control over foreign data, a court rules.
The aim of DARPA's CORONET project, which included IBM, AT&T, Applied Communications Sciences and others, was to create technology that could string together cloud networks on the fly to keep the Internet and government running.
The industry group representing Apple, Microsoft, HP and IBM has argued that if Australian competition law is changed to ban the so-called Australia tax on technology, it might drive companies out of the country.
IBM has aggressively building out its marketing suite as it tries to land chief marketing officers, which increasingly control more technology buying power.
IBM has been chosen by BP to support its global workforce and launch new collaboration capabilities to support 60,000 of BP's global employees.
Cognitive computing technology such as Watson, cloud computing and systems of engagement will reinvent IBM, says CEO Ginny Rometty in a shareholder letter. But the big question is how long the transition will take.
The company launches a developer challenge to prime the app ecosystem pump for its Watson cognitive computing platform.
The Delhi High Court calls for laws to adapt to changing times, since they were last formed when technology was nascent.
Consumer NAND flash technology has serious problems in enterprise applications, leading the industry to look for better non-volatile semiconductor storage. Researchers at IBM have been characterizing just such a new drive from Micron.
Researchers reveal a technology that IBM says is an important first step towards enabling superfast data transfer.
The Defence Science and Technology Organisation and IBM have signed a partnership deal to collaborate on cybersecurity research.
For privacy and security, change these iOS 9 settings immediately
Windows 10
What to expect on Windows 10 front at Microsoft's new devices launch


text:
Prada did something unusual for its men's wear show: it stocked the cast with famous actors. Willem Defoe, Jamie Bell, Adrien Brody, Gary Oldman, Tim Roth, Emile Hirsch, and Garrett Hedlund all walked around modeling Miuccia Prada's latest collection of snobby, bemedaled clothes for playboys. The Times rated them as models, and opined that Hedlund
Committed at least two cardinal sins of modeling — first making eye contact with the audience and, second, he didn't seem to know what to do with his hands. At the end of the show, he was pretending to play piano along with the soundtrack.
Oh, Garrett. Meanwhile, Hirsch and Bell "lacked in height," and Defoe impressed by "turning on a dime." The Times rated Adrien Brody the all-around best, possibly because he was tasked with making that red velvet overcoat with a fur collar look alluring and very nearly managed it. [On The Runway]
- We have a wrinkle in the Official Authorized Charlize Theron Profile Form, and it's thanks to boobs. Or, more precisely, chicken cutlets. Theron told Vogue a story about chicken cutlets that she said she used as "inspiration" for her character in Young Adult, Mavis. When she relayed the anecdote to the magazine, it was in the first person.
"I was on this date and started making out, and it was moving a little further, so I realized I had to get the cutlets out," Theron recalls. "But my bag was small, and I couldn't fit them in the thing. Jason [Reitman] was like, 'No way. That doesn't happen!' But that stuff happens to girls all the time."
Whatever happened to the cutlets?
Theron pauses. "I may have hid them in his trash with lots of toilet paper."
But! In a profile in the new W, she tells the same story — but this time, it's about "a girl." The actress is quoted as saying,
"If you don't have boobs, you wear those cutlets. I heard a story of a girl who was on a date, started making out, and thought, Oh, he's going to touch the cutlets! So she went to the bathroom to take them off, but her purse was too small to put them in there. I always thought that was a funny image, a woman not knowing what to do with these things that you stick onto your boobs."
Now we may never know if Charlize Theron has ever stuffed her bra with chicken cutlets, or merely has "a friend" who does so. [The Cut]
- Of course Lil Wayne has a clothing line. Of course it's named "TRUKFIT." Of coures that stands for "The Reason U Kill For It." Of course he painted all of the male models in his presentation silver from head to toe. We wonder if they were even paid for enduring this series of indignities or if instead the dudes just got a lot of TRUKFIT trade. [The Cut]
- Donna Karan has taken to pointing out that her new ad campaign, which was shot in Haiti and features a glamourous white model posing while uncredited Haitian men linger in the background, and which recalled racist ethnic-person-as-prop connotations for some people, employed 85 Haitians for the production. [WWD]
- Time thinks that Tilda Swinton and Madonna dressed well last night at the Golden Globes, but that Elle MacPherson's frock was "too youthful." [Time]
- Speaking of which, seeing Hailee Steinfeld described as "youthful" really is the most sublime part of this boring Times piece about stylists. Hailee Steinfeld is 15. If that's not "youthful," then what is? [NYTimes]
- Miranda Kerr is now a face of Qantas, the airline. [Vogue UK]
- Jason Wu and his boyfriend, company C.F.O. Gustavo Rangel, met on New Year's Eve in 2005. Their first date was to see Mary Poppins. [Out]
- Protests are continuing outside Dolce & Gabbana's Hong Kong store. The store security guards allegedly stopped locals from taking pictures of the building's façade, even from the public street — while allowing tourists from mainland China to photograph whatever they wanted inside or outside. There is tension between Chinese tourists and Hong Kong residents, and it often finds a focal point around luxury stores — Dolce & Gabbana may have threatened the would-be photo-takers at the behest of a Communist Party dignitary who did not want to be seen shopping inside. An incident where a prominent party official was photographed buying luxury goods in Hong Kong recently sparked a scandal in China. The protesters demand an apology and an end to the photo ban, which they say infringes on their freedoms. [WWD]


text:
USM football: More than just a game for fans
12:37 AM, Sep. 1, 2013
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USM football: More than just a game for fans
As tailgaters swarmed Southern Miss' campus to set up their tailgating sites on Saturday, spirits were as bright as the sun beating down on Golden Eagles fans young and old as they awaited the long-
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All Stories
Goodell's new mandate is sad, but necessary
It seems as if at least once a month, regardless if it's during the season or offseason, we're bombarded with news of alleged criminal activities involving NFL players.
Little known GI Bill funds could benefit many
By Johnny Jackson
A self-proclaimed nerd's journey, 15 years later - Jason A. Smith
As I considered what to write about this week, I looked at the calendar on my desk, and realized something.
Clayton probably won't qualify for FEMA assistance
By Joel Hall
CAU grad boosts self-esteem of local girls
By Joel Hall
Rep. Glanton donates $1,000 to fund scholarships
By Curt Yeomans
DA considering reopening case of murdered child
By Daniel Silliman
Leaps & Bound Mundy's Mill hurdler Sarah Omotoyo becomes first female athlete to sign Division I scholarship
By Rory Sharrock
BOE considers adding meeting for community comment
By Curt Yeomans
Obituaries - May 28, 2008
John Gregory Burell
Police identify murdered man, but have no leads
By Daniel Silliman
Murder suspect has history of mental illness, violence
By Daniel Silliman


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Transports Kidderminster
(86) for Transports in Kidderminster
Standard Motor Transport Ltd16 Lisle AvenueDY11 7DJ Kidderminster01562 745308
Standard Motor Transport Ltd. was founded in the late 1920's when motor transport was a serious alternative to steam lorries and horses and carts! At the same time. G. Batsford and Sons began to...
Fransen Transport Ltd6 Lisle Avenue, Foley ParkDY11 7DE Kidderminster01562 820261
... patio, road haulage company, road haulage transport, BRICKWORK, patios, BRICKWORKS, haul, Road...
Request for Quotation
Are you looking for Road Haulage & Freight Forwarding ?Use our "Request for Quotation" service to get customized offers from companies in Kidderminster, tailored for your exact needs!
BreakwellsRoad No. 2 Firs Industrial Estate, Stourport RoadDY11 7QN Kidderminster01562 755494
Breakwells is a family-owned road haulage and logistics business started in the 1960s. Over the past 50 years, we have earned a reputation for our excellent service and reliability in all aspects of...
Hickmans of KidderminsterFoley Drive Stourport RoadDY11 7PS Kidderminster01562 514890
We offer Local, National and International transport and warehousing solutions. Vehicles can be sign written with your name and special requirements are a challenge we endeavour to meet, do try us....
N.gill Exports & Imports LimitedOffice 4, Foley House, 123 Stourport RoadDY11 7BW Kidderminster+44 (0) 1562 742221
Based in the UK, N.Gill Exports and Imports Ltd are long established freight forwarders, providing Air Freight, Sea Freight and Land Freight services worldwide.
Haysite Reinforced Plastics Ltd.Greenhill Industrial Est, C/O Universal Automotive LtdDY10 2RN Kidderminster
... Transportation Support
James Lawley Transport Limited21 Stretton RoadDY11 6NG Kidderminster
... road freight
Avonline Transport LimitedRf Aimes Yard Arthur Drive, Hoo Farm Industrial EstateDY11 7RA Kidderminster
... road freight
Bridgnorth Transport Company Limited10 Comberton HillDY10 1QG Kidderminster
... road freight
Npm Transport LimitedThe Croft Lowe Lane, WolverleyDY11 5QR Kidderminster
... road freight
Moreton Transport Limited189 Sutton RoadDY11 6QJ Kidderminster
... road freight
Mt Transport (Uk) Limited91 Walter Nash Road EastDY11 7EE Kidderminster
... road freight
Standard Motor Transport Limited14 Lisle AveDY11 7DE Kidderminster
... road freight
A.P.Q. Transport LimitedExchequer House, 117 Lea StreetDY10 1SN Kidderminster
... road freight
S D K Transport Limited3 Church StreetDY10 2AD Kidderminster
... road freight
Alpine International Xpress Transport Limited1 Franchise StreetDY11 6RE Kidderminster
... road freight
J Langner Transport & Driver Services Ltd376 Stourbridge RoadDY10 2QE Kidderminster
... road freight
British Transport ServicesHead Office: Suite 10, Campion House, Green StDY10 1JL Kidderminster
Welcome to British Transport Services! We are the leading international freight forwarding specialist, dedicated to providing great value, prompt and reliable services, time and time again. ...
A & P Transport36 Middleton RoadDY11 5EZ Kidderminster01562 66017
... logistic services, transport logistics, transportation logistics, Road Haulage Contractors, Haulage...
APQ Transport Ltd9 Wolverhampton Road SouthDY10 2UR Kidderminster01562 69220
APQ Transport LTD is a friendly, family owned company that was established in 1993. In that time the company has grown from strength to strength APQ Transport LTD is run by Managing Director Andy...
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If you are conducting a prospective investigator-initiated study, please contact the McLaren Center for Research and Innovation at (810) 342-1025 for assistance with protocol writing and statistical considerations.
For questions related to eProtocol, IRB forms, policies, or review procedures, our Office of Education, Training, and Resources holds open office hours to assist you. Please contact Markeda Richards at (810) 342-4174 or firstname.lastname@example.com for more information.


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View all lawyer profiles from this firm
Butt, Matthew
Matthew Butt has experience of high-profile cases across chambers' practice areas. He is independently recognised as a leading practitioner in crime, licensing, extradition and professional discipline by The Legal 500 and Chambers UK.
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Dolphin Beach Club
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TripAdvisor Reviews Dolphin Beach Club Daytona Beach
Travel Blogs from Daytona Beach
Two for Tuesday
... a great time getting an inside look at the venue. I will certainly be watching more closely next time a race is televised. We also plan to come back here in the future to watch a Daytona 500 race live.
After our tour we headed down the road a bit to eat at Chipotle Mexican Grill. This is one of our favorite places to eat and we hadn't eaten at one since our visit with Missy and Bill in Texas. It was good eating.
Once lunch was done we ...
Lost track
... for bike week, It's realy nuts here during bike week and it's also spring break and the hotels are full of a mix of ...
Deland and Daytona bike week continued
... all the Harley's, it looked very out of place. Even though Main Street was closed off to all other vehicles there was very little parking and they were charging between $5 and $7 dollars down some of the adjoining streets which were also closed off the only free parking was on the pavement on Main Street.
There were bands playing to very small crowds and all the shops and stalls were almost empty. ...
Daytona and Deland Bike week
... a bike I did not want to put her off for good. We had a good days riding and found an old settlement Museam which was quite interesting we even found some roads that had bends in them, we then took a quick dip at the springs before heading back for a home cooked meal by our hosts Lauretta and Kit. Shortly after dinner we went for a guided tour through the ...
Blue Springs State Park
... to head off to Daytona Beach Flea and Farmers market. There was 3 miles of indoor and outdoor shops and stalls, I think we walked through about half a mile it's just insanely big out here compared to the UK, it's been very hot again today with a nice cool breeze. There were a few more bikes out on the roads today, but still surprisingly few ...


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Postgame: Ugly Trend
Nation World HQ
December 30 2011 08:42PM
For a third straight game, the Calgary Flames were noticeably controlled by an opponent with an inferior record. On Friday night in Ottawa, they staked themselves to a 3-0 first period lead that was not in line with the way they played. Even with that lead, nothing changed, and that allowed the Senators to claw back and force overtime, eventually using career goal #400 from Daniel Alfredsson to skate to a well earned 4-3 victory.
Flames Scoring Chances - Game 39 vs Ottawa Senators
Kent Wilson
December 30 2011 08:29PM
Final Score - 4-3 OTL
Game 39 - Flames vs Senators LIve Chat
Kent Wilson
December 30 2011 04:56PM
For those who stop by the live chat or want to follow along at a friends house or bar, the Charlie Simmer drinking game:
- drink whenever he starts a sentence with "again..." if it's the first time he's mentioned the issue that night.
- drink whenever he says "keep(ing) their feet moving".
- drink whenever he notes the team must "keep it simple"
- drink when he mentions the key to the attack or the power play is getting pucks/bodies to the net
- have a shot whenever items 2-4 appear together in the same sentence
- drink whenever Charlie mixes metaphors or messes up a common colloquialism
FGD: Double Up
Nation World HQ
December 30 2011 11:42AM
After a fairly flat performance Thursday night in a 3-1 loss to the New York Islanders, the Calgary Flames get right back at it toinght, visiting the Ottawa Senators for the only time this season (5:30 pm, Sportsnet West and Sportsnet 960). That's two consecutive meh performances for the Flames, and the Islanders were able to take advantage of them, winning on the scoresheet and in the scoring chance battle, snapping Calgary's four game win streak in the process.
Iginla Reflections and Feaster Audio
Kent Wilson
December 30 2011 10:42AM
I stumbled on some worthwhile Flamess material to share this morning before the game tonight
First up, we have a Jay Feaster interview courtesy Timo Seppa of Hockey Prospectus. Timo attended the Flames/Islanders game last night and managed to ask the Flames GM about the team's recent success, as well as Calgary's main challenges and the acquisition of Blake Comeau.


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|Número de publicación
|Tipo de publicación
|Número de solicitud
|Fecha de publicación
|28 Jun 1994
|Fecha de presentación
|22 Dic 1992
|Fecha de prioridad
|23 Dic 1991
|También publicado como
|Número de publicación
|Stefanio Bonsignore, Rino D'Aloisio, Paolo Soncini, Carlo Venturello
|Cesionario original
|Enichem S.P.A.
|Exportar cita
|BiBTeX, EndNote, RefMan
|Citas de patentes (1), Citada por (10), Clasificaciones (29), Eventos legales (5)
|Enlaces externos: USPTO, Cesión de USPTO, Espacenet
{[(O5 WO)2 OP-(CXX')n -PO(OWO5)2 ]2 WO5 } Q5 (I)
The present invention relates to a class of compounds based on tungsten and diphosphonic acids, which contain active oxygen atoms and cationic groups deriving from onium salts.
According to a second aspect thereof, the present invention relates to the method for preparing the above said class of compounds.
A further aspect of the present invention is using said class of compounds for oxidation reactions.
From Italian Patent Application 24 154 A/82 to the name of Montedison S.p.A., compositions of general formula:
Q3 XW4 O24-2n (a)
in which:
Q stands for the cation of an onium salt;
X is a P or As atom;
n is an integer selected from 0, 1 or 2, are known.
The onium cation may also be in immobilized form on a macroporous polymeric matrix.
The above said compositions are prepared by reacting, in an acidic aqueous phase, an oxygen containing derivative of tungstenVI, an oxygen containing phosphorus or arsenicV derivative and hydrogen peroxide, with an onium salt or a precursor thereof, possibly contained in an organic phase immiscible with the aqueous phase.
These compositions are used as catalysts for oxidation reactions, both in homogeneous and in heterogeneous phase, preferably according to the phase transfer technique, in the presence of hydrogen peroxide.
The present Applicant has found now that particular diphosphonic acids, combined with an oxygen-containing derivative of tungstenVI, hydrogen peroxide and a suitable onium salt, are capable of yielding per se novel compounds.
Such compounds result to be good oxidizing agents, and furthermore may be used as additives in detergency field.
The subject-matter of the present invention is hence a class of compounds based on tungsten and particular diphosphonic acids, which contain active oxygen atoms and cationic groups deriving from onium salts.
The compounds belonging to the class of compounds according to the present invention have the general formula:
{[(O5 WO)2 OP-(CXX')n -PO(OWO5)2 ]2 WO5 } Q5 (I)
n is either 1 or 2;
X and X', which may be the same or different from each other, are H or F;
Q is the cation of an onium salt constituted by quaternary salts having the formula (II):
in which:
M stands for a pentavalent element belonging to Group VA of the Periodic System of Elements, such as N, P, As, Sb;
Y- is a stable inorganic anion, such as Cl-, HSO4 -, NO3 -, and so forth;
R1, R2, R3, R4, which may be the same, or different from each other, represent H or alkyl radicals, wherein at least one of said radicals may also be linked to a polymeric matrix of either organic or inorganic type.
When R moieties are alkyl radicals, they can be selected from univalent hydrocarbyl radicals containing a total number of carbon atoms of up to 70, and preferably comprised within the range of from 25 to 40.
The compounds falling within the scope of the above mentioned formula (I) are synthetized by causing an acidic aqueous phase (pH<1) containing the diphosphonic acid, a suitable oxygen-containing tungstenVI compound and hydrogen peroxide, to react with an organic media substantially immiscible with water, containing an onium salt, according to preestablished--although not critical--molar ratios, under substantially room conditions of pressure and at temperatures preferably comprised within the range of from 20° to 80° C.
Diphosphonic acids which may be used are methylenediphosphonic acid [Formula (I) wherein n=1 and X=X'=H] and ethylenediphosphonic acid [Formula (I) wherein n=2 and X=X'=H].
In the preparation of the compounds of formula (I), as tungsten derivatives, preferably oxygen-containing derivatives of tungstenVI are used, such as tungstic acid or its alcali metal salts.
However, in general, any tungsten derivatives, or tungsten itself, may be used, provided that, under the conditions provided for the reaction, said tungsten derivative, or metal tungsten, may originate in situ said oxygen containing derivative of tungstenVI, as specified hereinabove.
Therefore, for example, WO2, W2 O5, WO3, WS2, WS3, tungsten oxychloride, tungsten chloride and tungsten hexacarbonyl, may be used.
The onium salts are constituted by quaternary compounds of general formula (II), as already defined above.
According to whether M is an N, P, As, Sb atom, the corresponding onium salts are obtained, i.e., ammonium (N) salts, phosphonium (P) salts, arsonium (As) salts, stibonium (Sb) salts; methyl trioctyl ammonium chloride, dimethyl [dihexadecyl (24%)+dioctadecyl (76%)] ammonium chloride (Arquad 2HT), tetraalkylammonium chloride, tetraalkylphosphonium chloride, trialkylammonium chloride and trialkylphosphonium hydrogensulfate are preferred.
Furthermore, as the source for onium salt, onium salts, preferably onium chlorides, may be used, which are immobilized on polymeric macroporous matrices of organic type (polystyrene type) or of inorganic type (based on silica, alumina, titanium-silicalite, and so on), which can be prepared according to techniques known from the prior art, or are available from the market.
In this case, products are obtained which are insoluble in aqueous and organic solvents, and hence are suitable for those reactions in which the compounds of formula (I) are used as phase transfer catalysts, according to the triple-phase (aqueous phase--organic phase--solid phase) technique.
The supported compounds are particularly interesting, because they supply the possibility of recovering the catalyst, which has now been made insoluble both in water and in common organic solvents.
As the organic solvents for the onium salt, inert solvents are generally used which are substantially immiscible with the aqueous phase containing the tungsten compound and phosponic acid, and are capable of dissolving the catalyst which is the reaction product.
Aromatic hydrocarbons, such as benzene, toluene, several xylenes, and so forth; chlorohydrocarbons, such as dichloromethane, dichloroethane, trichloroethane, chlorobenzene, and so forth, and their mixtures, have proven to be particularly suitable.
As regards the molar ratios of the reactants, their values are never critical for the purposes of the formation of the compounds (I); however, the following values represent, as to said ratios, the operating values which secured advantageous results from the viewpoints of yield and product purity.
Therefore, per each mol of diphosphonic acid, at least 4.5 mols of tungsten compound and up to 2 mols of onium salt are used.
These are optimal values; in any case, the use of larger amounts of tungsten compounds does not yield any advantages, and larger amounts of onium salts imply a gradual purity decrease.
As regards H2 O2, from 2.5 to 6 mols per each mol of tungstenVI compound suffice. Larger amounts are compatible.
When compounds of less than-hexavalent tungsten are used, to the above said amount of H2 O2, that amount should be added which is necessary in order to bring tungsten to its oxidation state of tungstenVI.
The concentration of the reactants, in the aqueous phase as well as in the organic phase, does not represent a critical parameter; the same holds true for the reaction times.
The products of formula (I) obtained according to the present invention are in the physical states of solids, or oily, thick liquids.
They are generally soluble in aromatic hydrocarbons and chlorohydrocarbons; on the contrary, they are poorly soluble, or insoluble, in water, as a direct function of the number of carbon atoms and/or of the nature of the radicals R1, R2, R3 and R4 and of the onium salt used.
The compounds (I) obtained in that way display interesting applications; thanks to active oxygen present in them, they may hence find use as oxidizer agents in general and, in particular, e.g., in the reactions of epoxidation of olefinic compounds, for which they showed a high epoxidating activity.
Thanks to their characteristics of good solubility in the usual organic solvents and of negligible solubility in water, the compounds of formula (I) are suitable for use as (ep)oxidation catalysts according to the phase transfer technique, using hydrogen peroxide as the primary oxidizer agent.
The use of the compounds of formula (I) according to the phase transfer technique, makes it possible very diluted hydrogen peroxide to be used, even at a lower concentration than 10%, with a high conversion of same H2 O2 being obtained simultaneously, associated with a high selectivity to the epoxide of the olefin, with no need--as it occurs, on the contrary, with other types of processes--for the system having to be homogenized with the use of suitable solvents and, above all, without having to resort to any burdensome operations of water removal from reaction environment.
For merely exemplifying purposes, in greater detail, a possible route for preparing the compounds of formula (I) may be as follows: an aqueous solution of the oxygen containing derivative of tungstenVI (e.g., tungstic acid) and of diphosphonic acid, in the preselected molar ratios, is treated, with stirring, with an aqueous solution of H2 O2 in the desired ratio, at a temperature comprised within the approximate range of from 20° C. to 80° C.
Then, still with stirring, the amount is added, preferably at room temperature, of the selected onium salt dissolved in an organic, water-immiscible, solvent, e.g., dichloroethane or benzene.
The resulting two-phase mixture is stirred for a further 15-30 minutes.
Then the organic phase is separated and is evaporated under vacuum at 40°-30° C., the desired product being obtained as a solid, or a thick liquid substance.
In the case of compounds supported on matrices, they are obtained by treating, in the aqueous phase, the tungsten compound (tungstic acid) and the suitable diphosphonic acid, with H2 O2, as already disclosed hereinabove.
Then, the organic solvent and the onium salt supported on the polymeric carrier are added and the resulting mixture is kept stirred 2 hours at 80° C.
The solid product is then separated by filtering.
The characteristics which characterize the products of formula (I) make it possible them to be used as catalysts in reactions of olefin (ep)oxidation with diluted H2 O2, by means of the phase transfer technique.
Schematically summarized, the phase transfer technique used for the compounds in question consists of carrying out the reaction in a double-phase system (immiscible liquids), in particular in an aqueous liquid/organic liquid system, essentially constituted by:
an organic phase containing the compound of formula (I), the olefin to be (ep)oxidated and the possible solvent;
an aqueous phase, containing hydrogen peroxide.
However, the supported compound may constitute a third, solid, phase.
The reaction of olefin (ep)oxidation with the use of the catalysts (I) according to the present invention is preferably carried out under the following operating conditions: as said hereinabove, it is preferably carried out in a binary aqueous/organic system, with strong stirring, in the presence of the catalyst (I).
The organic phase is constituted by the organic substrate (e.g., the olefin), and a possible organic solvent, and the hydrogen peroxide containing aqueous phase.
When the catalyst supported on a matrix is used, the reaction is carried out under the same operating conditions, but in the presence of an aqueous/organic liquid/solid three-phase system.
The operating temperature and pressure are determined by the reactivity and nature of the substrate, by the stability of hydrogen peroxide, and by the catalyst used.
Temperatures comprised within the range of from 0° C. to 120° C. and pressures ranging from room pressure up to 100 atm should be regarded as sufficient from the operating viewpoint.
In the case that the substrate is constituted by olefins, these can be represented by the following formula: ##STR1## in which R5, R6, R7 and R8, which may also be substituted with functional groups inert under the reaction conditions, indifferently represent hydrogen atoms or hydrocarbyl moieties, such as alkyl and alkenyl radicals of up to 30 carbon atoms, cycloalkyl and cycloalkenyl radicals of from 3 to 12 carbon atoms, which may also be branched, aryl, alkylaryl, alkenylaryl radicals of from 6 to 12 carbon atoms; and, furthermore, one of R5, R6, R7 and R8 radicals, taken jointly with an adjacent group, may represent alkyl or alkenyl radicals or up to 12 carbon atoms in the resulting ring structure.
Substituent groups inert under the reaction conditions are, e.g., the hydroxy radicals, halogens (Cl, Br, F, I), nitro, alkoxy, amino, carbonyl, carboxy, ester, amido, nitrilo groups, and so forth.
As said above, the radicals R5, R6, R7 and R8 may also be alkenyls; in other terms, the process according to the present invention may also be applied to poly-unsaturated olefins, such as dienes, trienes, which may be conjugated, or less.
The reaction time depends on the nature of the catalyst and on the type of solvent and olefin used; in general, times comprised within the range of from a few minutes, up to some hours, are enough in order to complete the reaction.
The catalyst is used in amounts comprised within the range of from 0.0001 to 1 g-atom of metal, approximately per each mol of hydrogen peroxide, and preferably of from 0,005 to 0,05 g-atom approximately per each mol of hydrogen peroxide. As said hereinabove, the reaction is carried out under phase transfer conditions, e.g., in a double-phase aqueous liquid/organic liquid system.
In particular, the organic phase may indifferently be constituted by the same olefin used as the reactant, used in a suitable excess thereof, or it may be constituted by the reactant olefin dissolved in true organic solvents substantially immiscible with the aqueous phase.
The selection of the type of organic phase will be clear for those skilled in the art according to the reactivity of the olefin used as the starting material, and to the processing parameters used.
When in the organic phase inert solvents immiscible with water are used, the concentration of the olefin in the solvent is not critical for the purposes of process operations.
Operating values for olefin concentration in the organic phase are comprised within the approximate range of from 5% to 95% by weight; higher or lower values are compatible within their feasibility limits.
Hydrogen peroxide concentration in the aqueous phase should suitably be kept comprised within the approximate range of from 0.1 to 70%.
The present invention is disclosed in the following in greater detail on the basis of the following examples supplied for merely illustrative, non-limitative purposes.
2.50 g of H2 WHO2 (10 mmol) and 7 mL of H2 O2 at 30% w/v (weight/volume) (about 62 mmol) are charged to a beaker.
The suspension of tungstic acid is kept at about 60° C., with stirring, until tungstic acid is completely dissolved.
After cooling, 0.39 g of methylenediphosphonic acid CH2 - [PO(OH)2 ]2 (2.20 mmol) is added to the resulting colourless solution.
The solution obtained in that way is diluted with H2 O to a total volume of 30 mL, is filtered, and is charged to a reaction vessel equipped with dripping funnel and stirring means and, with stirring, 1.60 g of methyl-trioctyl-ammonium chloride (3.96 mmol) dissolved in 40 mL of methylene chloride is added dropwise during approximately 2 minutes.
After a further 15-minute stirring, the organic phase is separated and is evaporated under vacuum at 40°-50° C.
2.71 g is obtained (97% relatively to onium salt used) of a thick, colourless oil.
Elemental analysis: Calculated for C202 H436 N8 P4 W9 O57 : C: 42.80; H: 7.75; N: 1.98; P: 2.19; W: 29.19; Found: C: 42.92; H: 7.83; N: 2.01; P: 2.03; W: 29.2;
Active oxygen found: 5.10%;
31 P NMR (CDCl3, 85% H3 PO4 as external reference): Delta: +28.2 (broadened td), +17.1 (td, J1 =19.7 Hz, J2 =7.3 Hz);
I.R. (KBr): 3035, 2955, 2925, 1711, 1485, 1467, 1378, 1189, 1119, 1061, 1002, 972, 895, 855, 845, 815, 761, 724, 650, 589, 577, 540, 519, 502, 434 cm-1.
The process is carried out as in Example 1, with methylenediphosphonic acid being replaced by 0.42 g of ethylenediphosphonic acid (2.20 mmol).
2.70 g (96%) of product is obtained as a thick, colourless oil.
Elemental analysis: Calculated for C204 H440 N6 P4 W9 O57 : C: 43.01; H: 7.79; N: 1.97; P: 2.18; W: 29.05; Found: C: 42.48; H: 7.89; N: 1.94; P: 2.08; W: 28.9;
Active oxygen found: 5.15%;
I.R. (KBr): 3035, 2956, 2921, 2857, 1713, 1485, 1467, 1379, 1202, 1165, 1119, 1087, 996, 961, 890, 856, 845, 768, 724, 646, 587, 574, 550, 515, 447 cm-1.
5.1 ml of H2 O2 at 40% w/v (weight/volume) (60 mmol), 0.84 g of the compound of Example 1 (equivalent to 1.34 mmol of tungsten) dissolved in 10 ml of 1,2-dichloroethane and 11.5 g of 1-octene (100 mmol) are charged to a 4-neck reaction vessel of 250 ml, equipped with blade stirrer, thermometer and reflux condenser.
With strong stirring, the mixture is rapidly heated up to 70° C. and is kept 45 minutes at that temperature.
At the end of the heating period, by iodometric way 0.6 mmol of unreacted H2 O2, and by gas-chromatography 56.4 mmol of 1,2-epoxyoctane are detected in the aqueous phase and in the organic phase respectively. These values correspond to a hydrogen peroxide conversion of 99%, with a selectivity to epoxide, relatively to reacted hydrogen peroxide, of 95%.
Example 3 is repeated using 12.7 ml of H2 O2 at 16% w/v (60 mmol) instead of 40% H2 O2.
At the end of the reaction, the analyses demonstrate the presence of 3.0 mmol of unreacted H2 O2 (conversion: 95%) and 53 mmol of 1,2-epoxyoctane (selectivity 93%, as referred to reacted H2 O2).
Example 4 is repeated, with the reaction mixture being kept stirred at 70° C. for 30 minutes, instead of 45 minutes.
At the end of the reaction, the analyses demonstrate the presence of 3.2 mmol of unreacted H2 O2 (conversion: 95%) and 52 mmol of 1,2-epoxyoctane (selectivity 92%, as referred to reacted H2 O2).
Example 3 is repeated, using 18.3 g of 1-dodecene (100 mmol) instead of 1-octene, and with the reaction mixture being stirred for 60 minutes at 70° C.
At the end of the reaction, the analyses demonstrate the presence of 1.96 mmol of unreacted H2 O2 (conversion: 97%) and 54 mmol of 1,2-epoxydodecane (selectivity 93%, as referred to reacted H2 O2).
Example 3 is repeated, using 11.7 g of allyl chloride (153 mmol) instead of 1-octene, and with the reaction mixture being kept stirred 150 minutes at 55° C.
At the end of the reaction, the analyses demonstrate the presence of 10.5 mmol of unreacted H2 O2 (conversion: 82.5%) and 43 mmol of epichlorohydrin (selectivity 87%, as referred to reacted H2 O2).
Example 3 is repeated, using 11.22 g of 4-octene (100 mmol) instead of 1-octene.
At the end of the reaction, the analyses demonstrate the presence of 0.1 mmol of unreacted H2 O2 (conversion: 99%) and 58.7 mmol of 3,4-epoxyoctane (selectivity 98%, as referred to reacted H2 O2).
Example 3 is repeated, using 0.85 g (equivalent to 1.34 mmol of tungsten) of compound of Example 2 in lieu of the compound of Example 1.
At the end of the reaction, the analyses demonstrate the presence of 1.8 mol of unreacted H2 O2 (conversion: 97%) and 54 mmol of 1,2-epoxyoctane (selectivity 93%, as referred to reacted H2 O2).
Example 4 is repeated, using 0.85 g (equivalent to 1.34 mmol of tungsten) of compound of Example 2 in lieu of the compound of Example 1.
At the end of the reaction, the analyses demonstrate the presence of 20.4 mmol of unreacted H2 O2 (conversion: 66%) and 53.9 mmol of 1,2-epoxyoctane (selectivity 90%, as referred to reacted H2 O2).
8.76 ml of H2 O2 at 40% w/v (weight/volume) (103 mmol), 0.84 g of the compound of Example 1 (equivalent to 1.34 mmol of tungsten) and 6.0 g of oleic acid (20.6 mmol) are charged to a 4-neck reaction vessel of 250 ml, equipped with blade stirrer, thermometer and reflux condenser.
With strong stirring, the mixture is rapidly heated up to 60° C. and is kept 7 hours at that temperature.
At the end of the heating period, the reaction products are extracted from the mixture with ethyl ether.
In the aqueous phase, by iodometric way, 1 mmol of unreacted H2 O2 (conversion 98%), and in the organic phase, by chromatography 16.76 mmol of pelargonic acid (yield, referred to the amount of oleic acid: 81%) and 16.44 mmol of azelaic acid (yield: 79.71%) are detected.
13.76 ml of H2 O2 at 40% w/v (weight/volume) (165 mmol), 0.84 g of the compound of Example 1 (equivalent to 1.34 mmol of tungsten) dissolved in 10 ml of 1,2-dichloroethane and 7.12 g (50 mmol) of phenylethyleneglycol are charged to a 4-neck reaction vessel of 250 ml, equipped with blade stirrer, thermometer and reflux condenser.
With strong stirring, the mixture is rapidly heated up to 75° C. and is kept 5 hours at that temperature.
At the end, the reaction mixture is diluted with water and its pH value is approximately adjusted at 8 by means of the addition of a 1N solution of NaOH.
The aqueous phase is separated and then is acidified with concentrated HCl.
An extraction with ethyl ether is then carried out; from the organic phase, separated and subsequently evaporated, 5.45 g of benzoic acid is weighed (yield, as referred to the amount of phenyl ethylene glycol: 89%).
|Patente citada
|Fecha de presentación
|Fecha de publicación
|10 Nov 1983
|23 May 1984
|Montedison S.p.A.
|Peroxide compositions based on tungsten and phosphorus or arsenic, and a process for preparing the same
|Patente citante
|Fecha de presentación
|Fecha de publicación
|5 May 1997
|14 Jul 1998
|Arco Chemical Technology, L.P.
|Epoxidation process using a phosphate-stabilized peroxotungstate compound as catalyst
|14 Mar 2000
|11 Sep 2001
|Huish Detergents, Inc.
|Compositions containing α-sulfofatty acid esters and methods of making and using the same
|3 Abr 2002
|25 Feb 2003
|Albemarle Corporation
|Epoxidation of olefins
|3 Abr 2002
|4 Mar 2003
|Albemarle Corporation
|Preventing undesired odor in and/or purifying alkanediols
|29 Nov 2001
|1 Nov 2005
|China Petroleum & Chemical Corporation
|Oxidation reaction process catalyzed by phase-transfer catalyst controlling reaction
|8 Sep 2005
|29 Jun 2010
|Saudi Arabian Oil Company
|Diesel oil desulfurization by oxidation and extraction
|28 Jun 2010
|6 May 2014
|Saudi Arabian Oil Company
|Process for oxidative conversion of organosulfur compounds in liquid hydrocarbon mixtures
|8 Sep 2005
|8 Mar 2007
|Martinie Gary M
|Diesel oil desulfurization by oxidation and extraction
|29 Nov 2001
|26 Oct 2006
|China Petroleum And Chemical Corporation
|Durch reaktionskontrollierten Phasentransferkatalysator katalysiertes Oxidationsreaktionsverfahren
|29 Nov 2001
|6 Jun 2002
|China Petroleum & Chemical
|An oxidation reaction process catalysized by phase-transfer catalyst controlling reaction
|Clasificación de EE.UU.
|Clasificación internacional
|Clasificación cooperativa
|Clasificación europea
|19 Feb 1993
Owner name: ENICHEM, S.P.A., ITALY
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNORS:BONSIGNORE, STEFANIO;D ALOISIO, RINO;SONCINI, PAOLO;ANDOTHERS;REEL/FRAME:006454/0356
Effective date: 19930211
|15 Dic 1997
|Fee payment
Year of fee payment: 4
|22 Ene 2002
|Maintenance fee reminder mailed
|28 Jun 2002
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|27 Ago 2002
|Expired due to failure to pay maintenance fee
Effective date: 20020628


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Duran Duran Tickets
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Duran Duran Ticket Information
Best known for high-energy hits like "Rio" and "Hungry Like the Wolf," Duran Duran introduced the fresh sounds of new wave to mainstream audiences around the world with its 1981 Platinum-certified debut album. Duran Duran rose to fame on the strength of innovative music videos that helped to pioneer the path of MTV, and over the years, the Simon Le Bon-led band has come to be known as one of the most iconic groups of the '80s. First, use the filter tools to choose your concert from the dates featured in the schedule above. Choose the red tab next to your preferred date and venue to browse a large pool of open seats. After making your selection, log in to a Vivid Seats account to reach checkout, and then enter billing information for your Duran Duran tickets. Your purchase will not be made final until it's approved by the seller.
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Last month we released our first responsive WordPress theme at Theme Trust, and it was well received. Since viewing of the web is no longer limited to only desktops and laptops, it's clear that responsive design will soon be the norm. That's why we've decided to take this approach with all future themes including our newest one that we've just launched.
Clean is a responsive and minimal theme that looks amazing across multiple devices and screen resolutions. It's a versatile theme can be used as a blog or a portfolio to show off your work. Some key features include infinite scrolling and a touch swipe slideshow.
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Boto Sushi took over Yummy Sushi in Carmel Mountain some time ago. They revamped the entire restaurant and I must say it's quite beautiful. Boto means "boat" in Japanese so the interior has darker wood tones that I personally like. Plus, they aren't cheap with their a/c which has been a blessing during this summer's heat wave.
Tajima Izakaya
Tajima Izakaya is the restaurant my guy friends (who could care two sh*ts about food) prefer to eat when they're done partying. These are the same guy friends that think Guy Fieri is a wonderful man and want to be friends with. SO, not sure if that gives Tajima Izakaya cred or no cred if you know what I mean. I had lunch here several years ago with sis and we both found the food to be shrug-alright at best. The restaurant has been remodeled so I thought lunch was worth another try.
Oceana Coastal Kitchen (Yelp Event)
How is it that I've never been to Catamaran Hotel & Resort all this time I've lived in San Diego. How. I think I grew up thinking it was an older hotel with a Three's Company kinda vibe to it. I don't even know why. Oceana Coastal Kitchen is the restaurant that's within Catamaran Hotel and they recently partnered with Yelp to host a pretty memorable dinner.
Sis and I saw the sign for Tasty Noodle House some weeks ago when we were in Convoy for lunch. We knew Yu's Garden had closed but had no idea what type of cuisine Tasty Noodle House served. We promised one another our first visit here would be together but I totally couldn't wait so went without her recently (she doesn't read this blog so I don't care if I kinda lied to her).
Taste of Old Town 2015
These tasting events have become almost a mission for me. I'm a curious type of foodie blogger but I'm also a fiercely competitive kinda gal. I want to see if I can sample MORE than previous tastings AND if I can find the unicorn taco. Ok. Just re read that last sentence and it's ridiculous. I don't eat Mexican food all that often so trying out these events in Old Town has been such a treat for me and this food blog. Sometimes I wonder if cosmic forces are colliding together to somehow show me there's another side to Mexican food that I'm missing out.
Costco Breakfast (for 60 Sorority Girls)
College was a decent time for most of us but it was in the past. I have fun stories from way back when but hardly ever 'live' in those memories. It baffles me when I hear people still reminiscing about their college glory days as it just seemed so long ago. But then again, I'm only connected to a few college friends and they even annoy me when they say 'remember when…'. Like no man.
I volunteered to get breakfast for a group of girls recently as I owed their house mom a favor. Both parties were excited as 1) they get free breakfast and 2) I get an exclusive practice run of their Rush performance. The house mom said the songs/chants are pretty cool and endearing so I was curious. They were totally fine with me getting Costco breakfast items as I was kinda on a budget.
Fresco Urban Cafe
Fresco Urban Cafe has been around for enough years to call it a neighborhood restaurant. I haven't visited in years but recently saw some new lunch specials that they were offering. Fresco Urban Cafe offers NY Pizzas, pastas, burgers, and salads. They added an outdoor patio with an outdoor tv as well. What I also appreciate about this place is that they turn on the a/c INSIDE the restaurant even though the pizza oven is by the dining area.
San Diego Restaurant Week Launch Party 2015
San Diego Restaurant Week recently threw a Launch Party showcasing their September "Celebrate Local" theme. The event would take place at Go Green Agriculture located in Encinitas. I was excited upon hearing that 20 food vendors would be participating in this launch as what better way to sample all the various dishes you can try out during San Diego Restaurant week.
This particular Saturday was scorching blistering hot. It took place outdoors at noon so the heat played a huge part on how this blogger tasted and sampled items that day.
Continue reading San Diego Restaurant Week Launch Party 2015
Marketplace Grille – Carmel Valley, CA
I'm a creature of habit and that holds pretty much true to places I frequent often to eat. Lunch can be boring because I sometimes just want to eat and get the heck outta there. No disrespect to whatever habitual restaurant I go to. It's just I have my blinders on when I'm on a time frame and can't deviate from said time frame. So, I was surprised when, one day, I noticed Marketplace Grille in the Carmel Valley Plaza.
I was going to go my standard AYCE Indian restaurant but the lunch specials at Marketplace Grille caught my eye.
Lemonade UTC
Who hasn't heard of Lemonade opening in UTC. There was a palpable buzz and anticipation for this restaurant opening since people saw their colorful logo put up when they started the build out of this popular cafeteria style eatery. Shamps had gone to their new Hillcrest location and had raved about it. So I was excited with foodie love when I received an invite to try out the summer menu here at Lemonade UTC.
Their website states: " Lemonade captures the L.A. spirit of adventure about food, an appreciation of the freshest seasonal ingredients, and a desire to reinterpret familiar dishes with unexpected twists. Our food is for people who care about what they eat. It's clean, healthy, and inventive cuisine. "
I went to college in LA so understand a bit about the food culture and scene there. I never tried Lemonade since I left Los Angeles so that was another reason to be giddy to try their famed salads/braises/desserts here at their UTC location.


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(De)Constructing Contenders: Stanley Cup Arms Race – Part 1 (1991-1995)
(Click Here for Full Size Image) As we saw yesterday, teams during the dynasty era primarily built their clubs through the draft and other young players. Each of the three main organizations went about this task in a slightly different way – Montreal through acquiring picks in trades, the Islanders by using their own, and Edmonton through a series of claims and good first...
Via BSN Denver
August 12, 2015 | Discuss
(De)Constructing Contenders: Stanley Cup Dynasty Years (1976-1990)
(Click Here for Full Size Image) Have you ever wondered how the great dynasties of the 1970s and 80s were created? There's no doubt they had great players, with nine future Hall of Famers on Montreal's rosters (ten if you count Roy in '86), five from the Islanders, and another six from the Oilers. Even the Calgary Flames, the only team to crash the party during this...
Via BSN Denver
August 11, 2015 | Discuss
Watch Mike Modano get dropped from a stretcher
When the New York Rangers played the Dallas Stars on Feb. 26, 1994, Mike Modano skated into the Rangers defensive zone. As he crossed the blue line, he received the puck, looked down, and was nstantly met by Rangers captain Mark Messier. Modano went down in a heap, and appeared to be knocked out from the blow to the head.Modano had to be carried off the ice on a stretcher. But as...
Via Fox Sports
July 16, 2015 | Discuss
Sather Steps Aside; Gorton Era Begins
On Wednesday, the Rangers announced that Jeff Gorton was named as the 11th General Manager in the history of the NY Rangers, replacing Glen Sather who has been in the position since 2000. Sather turns 72 in September and rumors of him stepping down have been rampant in recent years, especially after Mark Messier was named as Sather's "special assistant." Sather leaves the...
Via NY Rangers Blog
July 03, 2015 | Discuss
Chicago's Jonathan Toews wins Messier Leadership Award
LAS VEGAS (AP) Chicago Blackhawks captain Jonathan Toews has won the Mark Messier NHL Leadership Award for his commitment to charities and service. Toews accepted the award Wednesday night at the NHL Awards show in Las Vegas. Toews participates in several off-ice endeavors with the Blackhawks, including Make-A-Wish Foundation activities and other charities back home in Winnipeg...
Jonathan Toews Wins Messier Leadership Award
Jonathan Toews was named the winner of the 2015 Mark Messier NHL Leadership Award presented by Bridgestone, beating out Andrew Ladd and Ryan Getzlaf. The post Jonathan Toews Wins Messier Leadership Award appeared first on Committed Indians.
Via Committed Indians
June 24, 2015 | Discuss
Why the Chicago Blackhawks Are the NHL's Dynasty (Instead of the Pittsburgh Penguins) by @DXTraeger
Life Truly Sucks When Vince Vaughn Gets to Celebrate Instead of You All hail the Chicago Blackhawks, the 2015 Stanley Cup Champions and a true hockey dynasty! With his third Cup win, Blackhawks Captain Jonathan Toews has effectively eliminated any and all discussion about being hockey's greatest leader (sorry Mark Messier, and sorry Sidney Crosby). Go ahead, read the rest »
Via PensInitiative
June 15, 2015 | Discuss
Your 2015 Stanley Cup Final Announcing Schedule
2015 Stanley Cup Final Tampa Bay Lightning vs Chicago Blackhawks TV USA NBC- Mike Emrick, Eddie Olczyk, Pierre McGuire NBC Studio- Liam McHugh, Mike Milbury, Keith Jones Streaming- NBC Live Extra Canada CBC – Jim Hughson, Craig Simpson, Glenn Healy; Reporters: Scott Oake, Christine Simpson CBC Studio- George Stroumboulopoulos, Elliotte Friedman, Kelly Hrudey, Mike Johnson, Nick...
Via Awful Announcing
June 02, 2015 | Discuss
Messier, Gretzky ... Brassard? Center enjoys historic night after challenge from coach
Derick Brassard is not the type of player who frequently draws comparisons to some of the game's greats such as Mark Messier and Wayne Gretzky. In fact, the talk about Brassard ahead of Game 6 of the Eastern Conference finals Tuesday was more about his meeting with coach Alain Vigneault early in the day. According to NHL.com, Brassard and teammate Derek Stepan both earned an invitation...
Via Fox Sports
May 27, 2015 | Discuss
Islanders Insight's Top Shelf: 5|27|15
The Rangers dominated Game 6 in Tampa, beating the Lightning 7-3 in what became a blowout in the third period. The series is now tied at 3 games apiece, and a decisive Game 7 will be played on Friday in New York. The Rangers yet again silenced their critics by scoring an abundance of goals in a lopsided game, just as they did in Game 4. The seven goals scored by New York are the...
Via Islanders Insight
May 27, 2015 | Discuss
Rangers 7, Tampa Bay 3
The New York Rangers defeated the Tampa Bay Lightning by a score of 7-3 to force a Game 7 in the Eastern Conference Finals. For a box score, click here. the city is going to be nuts on friday. can't wait. — Neill Fowler (@NYRblogneill) May 27, 2015 OK, this has already been a strange series. This one… I don't know how I'm not writing a season eulogy. Even in a 7-3 game...
Via NY Rangers Blog
May 26, 2015 | Discuss
#Elimin8ted: Rangers fans let Ovie have it after guarantee goes up in smoke
In looking back, Alexander Ovechkin's Game 7 guarantee was doomed to backfire. After all, he plays in Washington, where a politician's promise is about as air tight as the Edmonton Oilers defense. And he was guaranteeing a win in New York, where Mark Messier became "The Messiah" after delivering on his own guarantee (then going on to deliver a Stanley Cup in 1994) and Joe Namath...
Via Fox Sports
May 14, 2015 | Discuss
Western Conference Finals Preview
The Anaheim Ducks will be facing the Chicago Blackhawks in the 2015 Western Conference Finals. The Ducks just finished up their series against the Calgary Flames in 5 games, easily handling the young inexperienced Flames. The Blackhawks swept the Minnesota Wild easily. This will be the Ducks first trip to the conference finals since their 2007 run when they won the Stanley Cup. The...
Via TopSportsReport
May 12, 2015 | Discuss
Capitals' Alexander Ovechkin Guarantees Game 7 Win Vs. Rangers (Video)
Alexander Ovechkin has never played in an Eastern Conference final, but he's very confident it will happen this season. The Washington Capitals captain channeled his inner Mark Messier after losing Game 6 on Sunday night and guaranteed a win in Tuesday's Game 7 at Madison Square Garden. Alex Ovechkin still confident: "The character of this group, it shows a lot. We gonna come...
He's a tough Ladd: Jets captain to undergo surgery in light of Messier nomination
Jets' captain Andrew Ladd must have quite the pain threshold. While speaking on a media conference call about his recent nomination for the Mark Messier NHL Leadership Award, Ladd revealed that the sports hernia he suffered during winter of the regular season will require surgery, which he will undergo Friday in St. Louis. Despite having to regularly miss team skates in order to...
Via Fox Sports
May 07, 2015 | Discuss
Cup Dumps 5/5/15
MONTREAL, QC – MAY 03: Brandon Prust #8 of the Montreal Canadiens skates in Game Two of the Eastern Conference Semifinals against the Tampa Bay Lightning during the 2015 NHL Stanley Cup Playoffs at the Bell Centre on May 3, 2015 in Montreal, Quebec, Canada. The Tampa Bay Lightning defeated the Montreal Canadiens 6-2 and take a 2-0 lead in the series. (Photo by Minas Panagiotakis...
Via Barry Melrose Rocks
May 05, 2015 | Discuss
Jonathan Toews Named Messier Award Finalist
On Monday afternoon, Chicago Blackhawks captain Jonathan Toews was named one of three finalists for the 2014-15 Mark Messier NHL Leadership Award. The other two finalists are former Blackhawk and current Winnipeg Jets captain Andrew Ladd and Anaheim Ducks captain Ryan Getzlaf. The selection of the three finalists and winner are made by Mark Messier. The post Jonathan Toews Named...
Via Committed Indians
May 04, 2015 | Discuss
Who Served As Rangers Captain Between Mark Messier And Chris Drury?
Rangers defenseman Ryan McDonagh hasn't donned the "C" for long, but he joins an elite group of leaders in the New York organization. The first-year captain was handed the reins after forward Ryan Callahan was dealt to the Tampa Bay Lightning in exchange for veteran Martin St. Louis last season at the trade deadline. Callahan earned the "C" after Chris Drury — who served...
Which Defenseman is the Odd Man Out for the Playoffs? by @DXTraeger
Mark Messier at the NYSE Imitating Ray Shero at the Deadline by Buying & Selling Shares of Mark Messier-Brand EgoBefore we launch into the debate of which Penguin defenseman rides the pine for the post-season, a "How We Got Here" summary is important to understand the background and gravity of the situation facing both Mike Johnston and Jim Rutherford.The legacy of the Ray Shero...
Via PensInitiative
March 11, 2015 | Discuss
Farewell to the Nassau Coliseum: Day 84
Talk about a Friday night heavyweight tilt. Tonight's game at the Coliseum between the Islanders and Penguins will be an absolute barn burner. Those in attendance will surely have some kind of hearing loss and there will be approximately zero complaints about it when you wake up tomorrow morning with your ears still ringing. I'll be in Section 337 with the missus. If you need...
Via Islanders Insight
January 16, 2015 | Discuss
Mike Francesa had Mark Messier on his show despite it being 'football, playoff time' and all
Mike Francesa interviewed the legendary Mark Messier because he (Mark) wanted to talk about 'a couple of things,' even though Mike knows its football, playoff time. And then a woefully unprepared Francesa went on to read through notes given to him by his EP...not all having taken the time to have read them beforehand. Follow us on Twitter for exclusive stories, Subscribe by Email...
Via Bob's Blitz
January 08, 2015 | Discuss
Stars troll visiting New York Rangers with scoreboard list
The Dallas Stars found a clever way to get under the skin of the visiting New York Rangers Monday night. In honor of the Rangers' visit to the American Airlines center, the Stars' scoreboard operator thought it would be nice to honor the all-time greatest Rangers. However the list turned out a bit different than one would expect. If the photo is a bit hard to make out, the list...
Via Fox Sports Southwest
December 29, 2014 | Discuss
Could we steal one tonight? Why bother.
The Edmonton Oilers are going to get spanked hard tonight by the New York Rangers. On Saturday, the team from Manhattan manhandled the Vancouver Canucks. Could the Oilers get lucky facing a road-weary team on the second night of a back-to-back? Perhaps. I mean, the Oilers can't lose every single game, no matter how awful the roster is. This blog is going to be a number of random...
Via Puckrant.com
December 14, 2014 | Discuss
This Week in Flyers History: Week ending November 16
It was one of the most emotional games in Flyers history, regular season or playoffs. Just days after the tragic loss of their All-Star goalie, Pelle Lindbergh in a car accident, the Flyers had to somehow summon their strength and push forward. They had to go on, emotionally numb as they were and find their way without their star in net. Awaiting them on this night was none other...
Via Flyerdelphia
November 16, 2014 | Discuss
Dallas Eakins' job saved by Oilers winning streak
The Edmonton Oilers were able to string together three consecutive wins over the past week and it couldn't have come at a better time. After starting the year 0-4-1, the Oilers were floundering and barely looked competitive. The blame, as always, fell on the head coach and Dallas Eakins' job appeared to be in serious jeopardy. It turns out those three wins at home may have spared...
Via Puck Drunk Love
October 26, 2014 | Discuss
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Book your room at Mill Farm
Double Room, EnsuiteMax Occupancy: 2 guests (up to 1 child)
Double Room Single Use, EnsuiteMax Occupancy: 1 guest
Twin Room, EnsuiteMax Occupancy: 2 guests (up to 1 child)
Family Room, EnsuiteMax Occupancy: 3 guests (up to 2 children)
Triple Room, EnsuiteMax Occupancy: 3 guests (up to 2 children)
Family Room, EnsuiteMax Occupancy: 4 guests (up to 3 children)
Get an overview of this hotel4-star Exeter farm stay in Kenton with free breakfast
Located in Kenton, this farm stay is 1.7 mi (2.8 km) from Powderham Castle and within 9 mi (15 km) of Northbrook Approach Golf Course and Exeter Cathedral. 21 The Mint and St Nicholas Priory are also within 9 mi (15 km).
Property Features
This smoke-free farm stay features tour/ticket assistance, free breakfast, and free self parking. WiFi in public areas is free.
Room Amenities
All 5 rooms offer free WiFi, coffee makers, and TVs.Information missing or incorrect? Tell us!
Hotel Amenities
Hotel Amenities
A complimentary breakfast is offered each morning. Public areas are equipped with complimentary high-speed wireless Internet access. Complimentary self parking is available on site.
Mill Farm is a smoke-free property.
- Free breakfast
- Free self parking
- Free WiFi
- Front desk (limited hours)
- Number of buildings/towers - 1
- Number of floors - 1
- Smoke-free property
- Total number of rooms - 5
- Tours/ticket assistance
Available in all rooms: Free WiFi
Available in some public areas: Free WiFi
Free self parking
Room Amenities
- Coffee/tea maker
- Free WiFi
- Private bathroom
- Television
Where to Eat
Guests are offered a complimentary full breakfast each morning.
Hotel Policies
Check-in time ends at 10 PM
Check-in time starts at 4:30 PM
Special check-in instructions:
Check-out time is 10 AM
Payment types
Children and extra beds
- Children are welcome.
You need to know
Extra-person charges may apply and vary depending on hotel policy.
Government-issued photo identification and a credit card or cash deposit are required at check-in for incidental charges.
Special requests are subject to availability upon check-in and may incur additional charges. Special requests cannot be guaranteed.
Only service dogs are allowed
No rollaway/extra beds available
No cribs (infant beds) available


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China Gets Serious About Its Pollutant-Laden Soil
Last week, China's environment ministry reportedly began hammering out a plan to curb all sources of soil pollution by 2020 and to begin remediating filthy areas.
25 Years After the Exxon Valdez, Where Are the Herring?
Twenty-five years after the Exxon Valdez oil spill, researchers are still puzzling out the disaster's ecological impacts.
U.S. Releases Controversial New Stream Protection Rules
Small, ephemeral water bodies would get greater protection
U.S. and Mexico Unleash a Flood Into Colorado Delta
Hoping for a boost to native vegetation, scientists will study the effects of an experimental flood of the Colorado River delta on trees, soil salinity, and ground water.
U.S. and Mexico Unleash a Flood to Restore Colorado River Delta
Hoping for a boost to native vegetation, scientists will study the effects on trees, soil salinity, and ground water
Water's Tough Skin
Surface tension is a force to be reckoned with, especially if you are small.
Major Conservation Group Guts Science Team
Laying off staff scientists, the World Wildlife Fund moves away from centralized research to rely more on outsourced expertise.
Welcome to Beringia
A flurry of studies suggests that instead of being simply a bridge from Asia to the Americas, Beringia may have beckoned the ancestors of the first Americans to linger.
The World's Forests at Your Fingertips
New mapping tool offers new opportunities for research
Interactive Gallery: Seeing Sound
Data visualization reveals ecological patterns hidden in the acoustic realm
Eavesdropping on Ecosystems
Researchers are collecting terabytes of recordings, from bird chirps to chainsaw roars. The emerging field of soundscape ecology has a lot to offer … and a lot to prove.
Scientists Blast Plans for Nicaraguan Grand Canal
An alternative to the Panama Canal would harm wildlife, ruin lake, and disrupt indigenous communities, they say
Melting Arctic Ice Releases Deadly Seal Parasite
Climate change is exposing marine mammals to new pathogens
Natural Gas for Coal a Good Climate Trade-Off Despite Leaks, Researchers Argue
The official estimate of U.S. methane leaks is low, but the few big leaks could be effectively targeted
Science Behind Plan to Ease Wolf Protection Is Flawed
The U.S. government is relying on flawed science to support a proposal to lift endangered species protections for gray wolves in the continental United States.
U.S. Announces Crackdown on Ivory Sales
Move is part of larger strategy to combat wildlife trafficking
Cultivation of Unpopular GM Maize in Europe Hangs in the Balance
European Commission entitled to approve Pioneer's maize 1507 after states fail to reach a formal majority
Pesticide Study Sparks Backlash
Anti-GM crusader says pesticides are more toxic than thought; critics say study is flawed
U.S. Plan to Lift Wolf Protections in Doubt After Experts Question Science
Government says an "eastern wolf" species once existed, but outside review panel skeptical
ScienceShot: Acidic Oceans Could Impair Fish Vision
Damselfish exposed to high levels of carbon dioxide have difficulty discerning rapid light flickers
A New Top 10: Policymakers Reveal Their Top Questions About Ecosystems
Poll shows that land managers and scientists share similar concerns
New U.S. 'Climate Hubs' to Provide Data to Farmers
Initiative aims to help prepare food producers for a shifting climate
As Lionfish Invade, Divers Defend Threatened Ecosystems
New studies are giving ecologists some hope of controlling red lionfish, a voracious predator that has invaded the Atlantic.
The Mountaintop Witness
Margaret Palmer started out just studying streams. She's ended up in court, passionately defending them from coal mining.
Great Barrier Reef to Become Sludge Repository
Scientists blast decision to allow dredging and dumping inside protected area


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An Iraqi Christian and his 6-year-old daughter were killed in a bombing in the northern city of Mosul on Tuesday, a day after two Christian men were killed in their homes by intruders.
The attacks, the latest in an escalating spree of violence against the country's shrinking Christian population, come on the heels of an Oct. 31 siege of a Baghdad cathedral that left 58 dead and more than 70 wounded. The Islamic State of Iraq, a militant Islamist group, claimed responsibility for that attack.
Christians, who comprise not much more than 1 percent of Iraq's population, have borne a disproportionate share of the attacks on civilians that have plagued the country since the 2003 U.S. invasion.
The U.S. Commission on International Religious Freedom estimates that 900,000 of the 1.4 million Christians who lived in Iraq under Saddam Hussein have fled the country since 2003.
© Copyright 2015 The Washington Times, LLC. Click here for reprint permission.


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Posted by yaz
2 years ago
"Good stuff on home teams in tourney games. Looks like UNLV may be worth a look."
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