text:
I have set a sticky post for my homepage but want to display the entire post but keeping all other posts on the home page as showing excerpts and "read more"
I have set a sticky post for my homepage but want to display the entire post but keeping all other posts on the home page as showing excerpts and "read more"
In your template for the homepage make sure you are using the_content() and not the_excerpt(). If this is does not work for you, please post some code from the template here so we can help you easier.
Not sure i fully follow you, where am i looking for this code, in the loop?
Correct, in your loop you should find either the_content or the_excerpt.
Find what page you should edit by looking at this - http://codex.wordpress.org/Template_Hierarchy
If i use the_content() in the loop it will show the full content of all posts. This is not what i am looking for. I only want the sticky post to display the entire content. The remaining posts i want to display the excerpt.
esmi has it on this one.
Thanks esmi. Where in the loop do i put this code?
Check out the comments in that code example.
Maybe its me but actually the comments are what is confusing me.
// Declare global $more (before the loop)
// Set (inside the loop) to display all content, including text below more.
So is that inside the loop or before the loop or part before and part after.
global $more; goes before the Loop.
$more = 1; is declared inside the Loop
Thanks for your patience esmi but i still don't think i get it.
if (is_sticky()) {
global $more;
goes before the loop and the rest of the code goes inside the loop???
<?php global $more;
if ( have_posts() ) : while ( have_posts() ) : the_post(); ?>
if (is_sticky()) $more = 1;
else $more = 0;?>
<?php the_content();?>
<?php endwhile; endif; ?>
perfect, that makes sense now. Thanks for your patience esmi!!!
Sorry but this still isn't working out for me. If you have the time, can you check it out http://www.mijasguide.com/
Now its displaying the sticky post in double.
That looks like the initial text isn't part of the main Loop.
I've removed it now but the code was placed after <?php while ( have_posts() ) : the_post(); ?>, which i thought was the start of the main loop.
There is no sticky() in my loop.php file
Right, I think I see what the problem was. You were meant to adapt your Loop using the example code as just that - an example. Not add it "as is" to your Loop.
Ah ok, back to the drawing board then.
I am also trying to remove "read more" from my sticky post. I am using Magazine Basic theme, WordPress 3.3.2 and the loop.php file has me stumped trying to find where to put what before and after. I keep breaking my test site (http://golfforethegood.org/1_test), obviously not placing new code properly. Too complex for my wordpress experience. Can anyone assist? Thanks. loop.php file is HUGE so I was prompted to use pastebin. Code here http://pastebin.com/Yuqf9rq3
This topic has been closed to new replies.


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Anthony Mustafa Adair, a 24-year-old rising star in Philadelphia's theater scene, chats with us about his experiences as an openly gay Afghan performer and his role in Theatre Exile's Philadelphia premiere of The Invisible Hand.
What inspires you to entertain?
I love storytelling. Although I imagine plenty of it is a need for attention, I truly believe there's something innately human about telling a story to someone else, and seeing in their eyes that they're listening and engaged. I also believe that my taste is what drives me to entertain. I know what's good, I know what's tired and boring — and I think that alone can be enough for me sometimes. Read more »

subset: commoncrawl


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Liverpool Message Board
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Rafa leaving: Announcement next week
Hopefully this will be the end of another era at the club if we can get rid of the owners as well (which looks like its in full swing) coz Liverpool: The Soap Opera is not to my liking.Sort: Newest | Oldest | Most Replied Expand all replies
Hope it´s true but, cynic that I am, I´ll believe it when it´s for real, not until!
A Yahoo! User Apr 30, 2010 01:15 Flag
eloader, who's your first choice? Hodgson is on the top of my list.
- 1 Reply to A Yahoo! User
Yellow Bob ring ring hahahahahahha Yellow Bob ring ring hahahahahahha Apr 30, 2010 02:24 Flag
...ya ma, down the dock road is everyones choice BUM..................how is the fwcking 'ole hoe..


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Five classical music clips in the movies
Some lesser known classical music appearances in the movies
Garrett Harris 7 p.m., July 25
In the markets of Kolkata, this vegetable vendor has made himself a true space of his own. Quintessential India.
Photo by kroopsydaisy
Posted February 13, 2012
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Millions of computer users were advised Friday to temporarily disable Oracle's Java software because of security weaknesses that make their machines vulnerable to everything from virus-infected websites to "ransomware," which often locks users out of their computers until they pay the perpetrators.
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The Richard Stockton College men's soccer team lost 2-1 to Lebanon Valley at the Stockton Seashore Classic in Galloway Township on Friday night.
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|Publication number
|Publication type
|Application number
|PCT number
|Publication date
|Mar 27, 2007
|Filing date
|Jun 3, 2003
|Priority date
|Jun 11, 2002
|Fee status
|Also published as
|Publication number
|Jean-Pierre Wolf, Gebhard Hug
|Original Assignee
|Ciba Specialty Chemicals Corporation
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (13), Non-Patent Citations (3), Referenced by (1), Classifications (18), Legal Events (5)
|External Links: USPTO, USPTO Assignment, Espacenet
The present invention relates to new dimer and multimer forms of monoacylphosphine oxides (MAPO), bisacylphosphine oxides (BAPO), to new cyclic forms of bisacyl phosphine oxides (BAPO), to a process for their preparation and to new acylphosphine compounds obtained as intermediates in said process.
The preparation of dimer forms of monoacylphosphine oxides of the general formula
has been described in the European Patent Publication EP-A 0 601 413. Said process is characterized in that an arene-bisacyl chloride is reacted with e.g. an alkoxy-diphenyl-phosphine. The compounds obtained are due to the alkoxy-diphenylphosphine reactant symmetric dimer forms of monoacylphosphine oxides, i.e. the residue R5═R6. Concerning asymmetric forms one of the residues R5 or R6 must be an alkoxy group.
The U.S. Patent Publication 2001/0031898 describes the preparation of monomer forms of bisacylphosphine oxides
by reacting an acyl halide Ar—CO—X with a dimetalated phosphine RP(M)2 and subsequent reaction of the product obtained with an acyl halide. Dimer forms of BAPO compounds are encompassed by the general definition of the compounds described in U.S. Patent Publication 2001/0031898 but they have not been actually and explicitly disclosed in this patent publication, nor the preparation thereof has been exemplified.
There is still a need to find a method for preparing both, dimer and multimer symmetric and asymmetric forms of BAPO and MAPO compounds as well as cyclic forms of BAPO compounds, whereby said method should, in case of MAPO compounds, have a broad latitude in the choice of substituents on the phosphor atom.
In one aspect the invention relates to dimer and multimer forms of BAPO compounds of the formula I
The invention further relates to dimer and multimer forms of MAPO compounds of the formula II
The invention further relates to a process for the preparation of dimer or multimer forms of BAPO compounds of the formula I and of dimer or multimer forms of MAPO compounds of the formula II,
characterized in that (n+m) equivalents of a dimetalated-phosphine R1P(M)2 are reacted with one equivalent of a di- or polycarboxylic acid halogenide
to form an intermediate of the formula III
the intermediate is then reacted either with (n+m) equivalents of a further carboxylic acid halogenide (R2—CO-Hal) to form dimer or multimer forms of bisacylphosphine-intermediates of the formula IV
or with a halogenide R3-Hal to form dimer or multimer forms of monoacylphosphine intermediates of the formula V
said phosphines IV or V are then oxidized to form phosphine oxides of the formula I or II, wherein M is Li, Na or K and R1, R2 and R3; Q, n and m are as defined above.
The intermediate compounds of the formula III are novel and are also part of the invention. Thus, the invention further relates to compounds of the formula III as defined above. The compounds of the formula III are identified by 31P-.NMR spectroscopy and are stable in solution under inert gas at room temperature for a number of weeks.
The invention further relates to cyclic forms of BAPO compounds of the formula VI and VII
The invention further relates to a process for the preparation of cyclic forms of BAPO compounds of the formula VI
characterized in that one equivalent of a dimetalated-phosphine R1P(M)2 is reacted with one equivalent of a dicarboxylic acid halogenide
to form an intermediate of the formula III′
said intermediate cyclizes and is then oxidized to form phosphine oxides of the formula VI wherein R1, M and U are as defined above.
The invention further relates to a process for the preparation of cyclic forms of BAPO compounds of the formula VII
characterized in that two equivalent of a dimetalated-phosphine R1P(M)2 are reacted with one equivalent of a tetracarboxylic acid halogenide
to form an intermediate of the formula III″
said intermediate cyclizes and is then oxidized to form phosphine oxides of the formula VII wherein R1, M and U′ are as defined above.
Preference is given to using compounds of the formula I or II in which n is 1 and m is 1.
C1–C12alkyl is linear or branched and is, for example, C1–C12alkyl, C1–C8alkyl, C1–C6alkyl or C1–C4alkyl. Examples are methyl, ethyl, propyl, isopropyl, n-butyl, sec-butyl, isobutyl, tert-butyl, pentyl, hexyl, heptyl, 2,4,4-trimethylpentyl, 2-ethylhexyl, octyl, nonyl, decyl, undecyl, dodecyl. The alkyl groups may be interrupted once or more than once by O, S or N(C1–C12alkyl). If the radicals are interrupted by two or more O, S or N(C1–C12alkyl) then the O atoms, S atoms or N(C1–C12alkyl) groups are in each case separated from one another by at least one methylene group. The O atoms, S atoms or N(C1–C12alkyl) groups are thus not directly consecutive. For example, structural units such as —CH2—O—CH3, —CH2CH2—O—CH2CH3, —[CH2CH2O]z—CH3, where z=1 to 9, —(CH2CH2O)7CH2CH3, —CH2—CH(CH3)—O—CH2—CH2CH3, —CH2—CH(CH3)—O—CH2—CH3, —CH2SCH3 or —CH2—N(CH3)2 arise.
The alkyl groups may be mono- or polysubstituted by C1–C12 alkyl; C1–C12 alkoxy, —S—C1–C12alkyl, phenyl, phenoxy, —COOC1–C12alkyl, —COO—C5–C14aryl or CN.
As used herein, the term "C1–C12alkoxy" refers to a group O—C1–C12alkyl, wherein the alkyl radical is as described above.
Examples of C3–C6cycloalkyl groups are cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl. The C3–C6cycloalkyl groups may be substituted by C1–C12 alkyl, C1–C12 alkoxy, —S—C1–C12alkyl, phenyl, phenoxy, —COOC1–C12alkyl, —COO—C5–C14aryl or CN. Examples are 2,4,6-trimethyl-cyclohexyl, 2,6-dimethylcyclohexyl and 2,6-dimethoxycyclohexyl.
C5–C14aryl is phenyl, naphthyl, biphenyl, anthracyl and the like.
The aryl radicals may be mono or polysubstituted by halogen, phenyl, C1–C12alkyl and/or C1–C12alkoxy, —S—C1–C12alkyl, CF3, Cl, —N(C1–C12alkyl)2 or —N(C1–C 12alkyl interrupted by O)2.
Examples are:
Q is a di-tri or tetravalent arylene residue derived from the following di or polycarboxylic acid halogenides, preferably chlorides.
Compounds of the Formula A
Commercial compounds of the formula A are:
wherein R is as defined in formula A.
Commercial compounds of the formula B are 1,4,5,8-naphthalene tetracarboxylic acid or 1,4,5,8-naphthalene tetracarboxylic acid hydrate.
Compounds of the Formula C
wherein R is as defined in formula A.
Commercial compounds of the formula C are 2,3-naphthalenedicarboxylic acid or 1,4-naphthalene dicarboxylic acid.
Compounds of the Formula D
wherein R is as defined in formula A and X is a bond, —O—, —S—, methylene, —CH(CH3)—, —C(CH3)2—, —C(CF3)2—, —C(O)—, —S(O)— or —S(O)2—.
Commercial compounds of the formula D are 3,3′,4,4′-benzophenonetetracarboxylic acid, 2,3,2′-biphenyltricarboxylic acid or 4,4′(hexafluoroisopropylidene)phthalic acid.
Compounds of the Formula E
wherein R is as defined in formula A and Y is H2, O, S or CH2.
Commercially available is 9-fluorenone-2,7-dicarboxylic acid
Compounds of the Formula F or G
wherein R and Y are as defined above, and W is O, S, CH2 or N(C1–C12alkyl).
Commercially available is 2,7-di-tert-butyl-9,9-dimethyl-4,5-xanthenedicarboxylic acid.
Compounds of the Formula H, I, J, K, L, M, N or O.
The group A may be substituted by C1–C12alkyl, C1–C12 alkoxy, —S—C1–C12alkyl, phenyl, phenoxy, —O—COC1–C12alkyl, —O—COC5–C14aryl, —COOC1–C12alkyl, —COO—C5–C14aryl, CN, CF3, F or Cl.
Concerning cyclic forms of BAPO compounds of the formula VI
wherein R and X are as defined above.
Concerning cyclic forms of BAPO compounds of the formula VII
The Process Starting Compounds:
The preparation of the metalated phosphines R1P(M)2 can, for example, be carried out by reacting suitable phosphorus halides R1P(Hal)2 (preparation of which is known and disclosed, for example, by W. Davies in J. Chem. Soc. (1935), 462 and J. Chem. Soc. (1944), 276 with the corresponding alkali metal. Suitable as metal (M) are lithium, sodium or potassium. Lithium is preferred. The use of mixtures of these metals is also possible. 4 to 8 molar equivalents of the alkaline metal are advantageously used. The reaction is advantageously carried out in a solvent. In particular, as solvents, it is possible to use ethers which are liquid at atmospheric pressure and, room temperature. Examples are dimethyl ether, diethyl ether, methyl propyl ether, 1,2-dimethoxyethane, bis(2-methoxyethyl) ether, dioxane or tetrahydrofuran. Preference is given to using tetrahydrofuran. The reaction temperatures are advantageously −60� C. to +120� C.
Another conceivable method for the preparation of metalated phosphines is, for example, the reaction of suitable phosphines R1P(H)2 with the corresponding alkali metal hydride or an alkyllithium compound with the exclusion of air in an inert solvent at temperatures of e.g. −80� C. to +120� C. Advantageously, 2 to 4 mol equivalents of the alkali metal hydrides or alkyllithium compound are used. Suitable solvents are e.g. ethers as described above, or inert solvents, such as alkanes, cycloalkanes, or aromatic solvents such as toluene, xylene, mesitylene.
Suitable aryl phosphines can be prepared by reduction of the corresponding aryldichloro-phosphines [Ar—P—Cl2], arylphosphonic esters [Ar—P—O(OR′)2) and arylphosphonous esters [Ar—P(OR′)2] using LiAlH4; SiHCl3; Ph2SiH2 (Ph=phenyl): a) LiH, b) H2O;
a) Li/tetrahydrofuran, b) H2O or a) Na/toluene, b) H2O. These methods are described, for example, in U.S. Pat. No. 6,020,528 (col. 5–6). Hydrogenations using LiAlH4 are given, for example, in Helv. Chim. Acta 1966, No. 96, 842.
The di- or poly carboxylic acid halogenides used as starting material are known substances, some of which are available. Examples are listed above.
Carboxylic acid chlorides which are not commercially available may be prepared starting from the corresponding carboxylic acids using known reactions. The corresponding carboxylic acids may be prepared as follows.
Compounds H: by reaction of an anhydride with a di-, tri- or tetrafunctional alcohol.
Compound I: by reaction of an anhydride with a di-, tri- or tetrafunctional amine.
Suitable anhydrides are, for example, phthalic anhydride, hemimellitic anhydride, trimellitic anhydride, tetrafluorophthalic anhydride or 4,5-dichlorophthalic anhydride.
Compound J: by transesterification of a hydroxy carboxylic acid with a di-, tri- or tetra-functional ester.
Suitable hydroxy carboxylic acids are, for example, 4-hydroxyphthalic acid, 5-hydroxyisophthalic acid, 3-hydroxy- or 4-hydroxybenzoic acid or salicylic acid.
Compound K: by reaction of an aminocarboxylic acid with a di-, tri- or tetrafunctional acid chloride
Suitable aminocarboxylic acids are, for example, 3-amino- or 4-aminophthalic acid, 5-aminoisophthalic acid, 2-aminoterephphthalic acid, antranilic acid, 3-amino- or 4-aminobenzoic acid.
Compounds L, M or N: by reaction of a halogen substituted carboxylic acids with a di-, tri- or tetrafunctional alcohol, amine or thiol
Suitable halogen substituted carboxylic acids are, for example, 3-fluoro- or 4-chlorophthalic acid, 2-fluoroisophthalic acid, 2-fluoro- or 4-fluorobenzoic acid or 4-chlorobenzoic acid.
Compound O: by reaction of a hydroxy carboxylic acid with a di-, tri- or tetrafunctional chloroformiate.
Suitable hydroxy carboxylic acids are, for example, 4-hydroxyphthalic acid, 5-hydroxyisophthalic acid, 3-hydroxy- or 4-hydroxybenzoic acid, salicylic acid.
Cyclic forms of Bapo compounds may be prepared starting from the following dicarboxylic acid chlorides of the formula U1: phthalic acid, tetrafluorophthalic acid, 4,5-dichlorophthalic acid, 4-hydroxy-, 3-fluoro- or 4-chloro phthalic acid; of the formula U2 2,2-oxydibenzoic acid or diphenic acid; of the formula U3 naphthalene-1,8-dicarboxylic acid; of the formula U4 2,3-naphthalene dicarboxylic acid; or starting from the following tetracarboxylic acids: 3,3′,4,4′-benzophenone tetracarboxylic acid or 4,4′-(hexafluoroisopropylidene)diphthalic acid.
Inventive Process
The process starts by reacting a carboxylic acid halogenide with a metalated phosphine preferably in an inert solvents such as THF, dioxane or diethylether at a temperature from −20 to 80� C.
An important feature of the process for preparing dimer or multimer forms of BAPO or MAPO compounds comprises the control of the mole ratio of metalated phosphine to di- or poly-carboxylic acid chloride. It is desirable that about one equivalent of metalated phosphine groups be available per equivalent of acid chloride groups. The carboxylic acid chloride is preferably dropped into the phosphine in order to maintain an excess of the phosphine. Using about 0.5 equivalents of metalated phosphine groups per equivalent of acid chloride groups results in cyclic bisacylphosphine oxides.
The reaction between the di- or polycarboxylic acid chloride and the metalated phosphine produces an intermediate having the structural formula III.
To prepare MAPO compounds the intermediate is treated with an alkyl or aryl halogenide resulting in P-alkylation of the phosphine. The alkylating agent is added slowly. The reaction is preferably carried out in the same solvent and temperature range as in the first reaction step providing the intermediate.
To prepare BAPO compounds the intermediate is treated with another carboxylic acid halogenide resulting in P-acylation of the phosphine. The acylating agent is added slowly. The reaction is carried out in the same solvent and temperature range as in the first reaction step providing the intermediate.
The oxidation of the phosphine is carried out using oxidizing agents customary in the art. Suitable oxidizing agents are, for example, hydrogen peroxide, air or pure oxygen.
The MAPO and BAPO compounds of the formula I and II as well as the cyclic BAPO compounds of the formula VI or VII can be used as photoinitiators for the photo-polymerization of ethylenically unsaturated compounds or mixtures which comprise such compounds. This use can also take place in combination with other photoinitiators and/or other additives.
Thus, the invention also relates to a photopolymerizable composition comprising
The unsaturated compounds can contain one or more olefinic double bonds. They can be of low molecular weight (monomeric) or relatively high molecular weight (oligomeric). Examples of monomers with a double bond are alkyl or hydroxyalkyl acrylates or methacrylates, for example methyl acrylate, ethyl acrylate, butyl acrylate, 2-ethylhexyl acrylate or 2-hydroxy-ethyl acrylate, isobornyl acrylate, methyl methacrylate or ethyl methacrylate. Also of interest are silicon- or fluorine-modified resins, e.g. silicone acrylates. Further examples are acrylonitrile, acrylamide, methacrylamide, N-substituted (meth)acrylamides, vinyl esters, such as vinyl acetate, vinyl ethers, such as isobutyl vinyl ether, styrene, alkyl- and halostyrenes, N-vinylpyrrolidone, vinyl chloride or vinylidene chloride.
Examples of monomers having two or more double bonds are ethylene glycol diacrylate, propylene glycol diacrylate, neopentyl glycol diacrylate, hexamethylene glycol diacrylate or bisphenol A diacrylate, 4,4′-bis(2-acryloyloxyethoxy)diphenylpropane, trimethylolpropane triacrylate, pentaerythritol triacrylate or tetraacrylate, vinyl acrylate, divinylbenzene, divinyl succinate, diallyl phthalate, triallyl phosphate, triallyl isocyanurate or tris(2-acryloylethyl) isocyanurate.
Examples of higher molecular weight (oligomeric) polyunsaturated compounds are acrylicized epoxy resins, polyurethanes, polyethers and polyesters which are acrylicized or contain vinyl ether or epoxy groups. Further examples of unsaturated oligomers are un-saturated polyester resins which are mostly prepared from maleic acid, phthalic acid and one or more diols and have molecular weights of from about 500 to 3,000. In addition, it is also possible to use vinyl ether monomers and oligomers, and maleate-terminated oligomers having polyester, polyurethane, polyether, polyvinyl ether and epoxy main chains. In particular, combinations of oligomers which carry vinyl ether groups and polymers as described in WO 90/01512 are highly suitable. However, copolymers of vinyl ether and maleic acid-functionalized monomers are also suitable. Such unsaturated oligomers may also be referred to as prepolymers.
Examples of particularly suitable compounds are esters of ethylenically unsaturated carboxylic acids and polyols or polyepoxides, and polymers containing ethylenically unsaturated groups in the chain or in side-groups, for example unsaturated polyesters, polyamides and polyurethanes and copolymers thereof, alkyd resins, polybutadiene and butadiene copolymers, polyisoprene and isoprene copolymers, polymers and copolymers containing (meth)acrylic groups in side chains, and mixtures of one or more such polymers.
Examples of unsaturated carboxylic acids are acrylic acid, methacrylic acid, crotonic acid, itaconic acid, cinnamic acid, unsaturated fatty acids such as linolenic acid or oleic acid. Preference is given to acrylic acid and methacrylic acid.
Suitable polyols are aromatic and, in particular, aliphatic and cycloaliphatic polyols. Examples of aromatic polyols are hydroquinone, 4,4′-dihydroxydiphenyl, 2,2-di(4-hydroxy-phenyl)propane, and also novolaks and resols. Examples of polyepoxides are those based on said polyols, particularly aromatic polyols and epichlorohydrins. In addition, polymers and copolymers which contain hydroxyl groups in the polymer chain or in side groups, for example polyvinyl alcohol and copolymers thereof or hydroxyalkyl polymethacrylates or copolymers thereof, are also suitable as polyols. Further suitable polyols are oligoesters containing hydroxyl end-groups.
Examples of aliphatic and cycloaliphatic polyols are alkylenediols having, preferably, 2 to 12 carbon atoms, such as ethylene glycol, 1,2- or 1,3-propanediol, 1,2-, 1,3- or 1,4-butanediol, pentanediol, hexanediol, octanediol, dodecanediol, diethylene glycol, triethylene glycol, poly-ethylene glycols having molecular weights of, preferably, 200 to 1,500, 1,3-cyclopentanediol, 1,2-, 1,3- or 1,4-cyclohexanediol, 1,4-dihydroxymethylcyclohexane, glycerol, tris(β-hydroxy-ethyl)amine, trimethylolethane, trimethylolpropane, pentaerythritol, dipentaerythritol and sorbitol.
The polyols may be partially or completely esterified using one or different unsaturated carboxylic acids, where the free hydroxyl groups in partial esters may be modified, e.g. etherified or esterified with other carboxylic acids.
Examples of esters are: trimethylolpropane triacrylate, trimethylolethane triacrylate, trimethylolpropane trimethacrylate, trimethylolethane trimethacrylate, tetramethylene glycol dimethacrylate, triethylene glycol dimethacrylate, tetraethylene glycol diacrylate, pentaerythritol diacrylate, pentaerythritol triacrylate, pentaerythritol tetraacrylate, dipentaerythritol diacrylate, dipentaerythritol triacrylate, dipentaerythritol tetraacrylate, dipentaerythritol pentaacrylate, dipentaerythritol hexaacrylate, tripentaerythritol octaacrylate, pentaerythritol dimethacrylate, pentaerythritol trimethacrylate, dipentaerythritol dimethacrylate, dipentaerythritol tetramethacrylate, tripentaerythritol octamethacrylate, pentaerythritol diitaconate, dipentaerythritol trisitaconate, dipentaerythritol pentaitaconate, dipentaerythritol hexaitaconate, ethylene glycol diacrylate, 1,3-butanediol diacrylate, 1,3-butanediol dimethacrylate, 1,4-butanediol diitaconate, sorbitol triacrylate, sorbitol tetraacrylate, pentaerythritol-modified triacrylate, sorbitol tetramethacrylate, sorbitol pentaacrylate, sorbitol hexaacrylate, oligoester acrylates and methacrylates, glycerol di- and triacrylate, 1,4-cyclohexane diacrylate, bisacrylates and bismethacrylates of polyethylene glycol having molecular weights of from 200 to 1,500, or mixtures thereof.
Also suitable as component (a) are the amides of identical or different unsaturated carboxylic acids of aromatic, cycloaliphatic and aliphatic polyamines having, preferably, 2 to 6, particularly 2 to 4, amino groups. Examples of such polyamines are ethylenediamine, 1,2- or 1,3-propylenediamine, 1,2-, 1,3- or 1,4-butylenediamine, 1,5-pentylenediamine, 1,6-hexylenediamine, octylenediamine, dodecylenediamine, 1,4-diaminocyclohexane, isophoronediamine, phenylenediamine, bisphenylenediamine, di-β-aminoethyl ether, diethylenetriamine, triethylenetetramine, di(β-aminoethoxy)ethane or di(β-aminopropoxy)-ethane. Further suitable polyamines are polymers and copolymers with or without additional amino groups in the side chain and oligoamides containing amino end groups. Examples of such unsaturated amides are: methylenebisacrylamide, 1,6-hexamethylenebisacrylamide, diethylenetriaminetrismethacrylamide, bis(methacrylamidopropoxy)ethane, β-methacryl-amidoethyl methacrylate, N[(β-hydroxyethoxy)ethyl]acrylamide.
Suitable unsaturated polyesters and polyamides are derived, for example, from maleic acid and diols or diamines. The maleic acid may be replaced by other dicarboxylic acids. They can be used together with ethylenically unsaturated comonomers, e.g. styrene. The poly-esters and polyamides may also be derived from dicarboxylic acids and ethylenically unsaturated diols or diamines, particularly from relatively long chain compounds containing, for example, 6 to 20 carbon atoms. Examples of polyurethanes are those constructed from saturated or unsaturated diisocyanates and unsaturated or saturated diols.
Polybutadiene and polyisoprene and copolymers thereof are known. Suitable comonomers are, for example, olefins, such as ethylene, propene, butene, hexene, (meth)acrylates, acrylonitrile, styrene or vinyl chloride. Polymers containing (meth)acrylate groups in the side chain are likewise known. These may, for example, be products of the reaction of novolak-based epoxy resins with (meth)acrylic acid, homc- or copolymers of vinyl alcohol or hydroxy-alkyl derivatives thereof which have been esterified using (meth)acrylic acid, or homo- and copolymers of (meth)acrylates which have been esterified using hydroxyalkyl(meth)acrylates.
The photopolymerizable compounds may be used on their own or in any desired mixtures. Preference is given to using mixtures of polyol (meth)acrylates.
It is also possible to add binders to the compositions according to the invention; this is particularly advantageous if the photopolymerizable compounds are liquid or viscose substances. The amount of binder may, for example, be 5–95% by weight, preferably 10–90% by weight and particularly 40–90% by weight, based on the total solids. The binder is chosen depending on the field of application and on the properties required therefore, such as the facility for development in aqueous or organic solvent systems, adhesion to substrates and sensitivity to oxygen.
Examples of suitable binders are listed in U.S. Patent Publication 2001/0031898 which publication is included in the present Application by reference.
Apart from the photoinitiator, the photopolymerizable mixtures can also contain various additives such as thermal inhibitors, compounds to increase the storage stability, light protection agents such as for example the following light protection agents listed in US Patent Publication 2001/0031898
2-(2′-Hydroxyphenyl)benzotriazoles, 2-hydroxybenzophenones, esters of unsubstituted or substituted benzoic acids, acrylates, sterically hindered amines, oxalamides, 2-(2-hydroxy-phenyl)-1,3,5-triazines, phosphites and phosphonites.
The photopolymerizable mixtures can also contain photosensitizers such as for example the following photosensitizers listed in U.S. Patent Publication 2001/0031898: Triethanolamine, N-methyldiethanolamine, ethyl p-dimethylaminobenzoate or Michlers ketone, benzophenone, thioxanthone, in particular also isopropylthioxanthone, anthraquinone and 3-acylcoumarin derivatives, terphenyls, styryl ketones, and 3-(aroyl-methylene)thiazolines, camphorquinone, but also eosin, rhodamine and erythrosine dyes.
Depending on the intended use, further customary additives are optical brighteners, fillers, pigments, both white and coloured pigments, dyes, antistats, wetting agents or levelling auxiliaries.
The choice of additives depends on the field of application in question and the properties desired for this field. The above-described additives are customary in the art and are accordingly used in amounts customary in the art. Concrete examples for possible additives are given in US Patent Publication 2001/0031898
In certain cases, it may be advantageous to use mixtures of two or more of the photoinitiators according to the invention. It is of course also possible to use mixtures with known photoinitiators.
The photopolymerizable compositions advantageously comprise the photoinitiator in an amount of from 0.05 to 20% by weight, e.g. 0.05 to 15% by weight, preferably 0.1 to 5% by weight, based on the composition. The amount of photoinitiator stated is based on the total of all added photoinitiators if mixtures thereof are used.
The photopolymerizable compositions can be used for various purposes, for example as printing inks, such as screen printing inks, flexographic printing inks or offset printing inks, as clearcoats, as colour coats, as white coats, e.g. for wood or metal, as powder coatings, as paints, inter alia for paper, water, metal or plastic, as daylight-curable coatings for marking buildings and roads, for photographic reproduction processes, for holographic recording materials, for image recording processes or for the production of printing plates which can be developed using organic solvents or aqueous-alkaline media, for the production of masks for screen printing, as dental filling materials, as adhesives, as pressure-sensitive adhesives, as laminating resins, as photoresists, e.g. galvanoresists, etch or permanent resists, both liquid and dry films, as photostructurable dielectrics, and as solder stopping masks for electronic circuits, as resists for the preparation of colour filters for any type of screen or for producing structures in the production process of plasma displays and electroluminescence displays, for the production of optical switches, optical gratings (interference gratings), for the preparation of three-dimensional objects by mass curing (UV curing in transparent moulds) or by the stereolithography process, as is described, for example, in U.S. Pat. No. 4,575,330, for the preparation of composite materials (e.g. styrenic polyesters which may contain glass fibres and/or other fibres and other auxiliaries) and other thick-layer materials, for the coating or sealing of electronic components or as coatings for optical fibres. The compositions are also suitable for the preparation of optical lenses, e.g. contact lenses and Fresnel lenses, and for the preparation of medical instruments, auxiliaries or implants.
1. Preparation of Dimer Bisacylphosphine Oxide. (BAPO)
Formula I, R1=phenyl, R2=mesityl, Q=mesitylene, n=1, m=1
120 ml (0.191 mol) buthyllitium were dropped at a temperature of −20� C. to a solution of 10.0 g (0.091 mol) phenylphosphine in 150 ml tetrahydrofurane. A Yellow suspension was obtained. Subsequently 11.2 g (0.0455 mol) 2,4,6-trimethylbenzol-1,3-dicarboxylic acid dichloride diluted with 50 ml tetrahydrofurane were added dropwise at a temperature of 0� C. The reaction mixture was kept at that temperature during 30 min under stirring. Subsequently 16.6 g (0.091 mol) 2,4,6-trimethylbenzoylchloride were added dropwise and stirred at the same temperature for 2 hours. Subsequently the reaction mixture was allowed to reach room temperature. The solvent was rotatory evaporated. The residue is taken up in 200 ml toluene. The solution was diluted with water and the layers were separated. 10.3 g (0.091 mol; 30%) hydrogen peroxide were added to the organic phase. After stirring for 2 h, the organic phase was washed with water and with aqueous saturated NaHCO3, dried over MgSO4 and filtered. Evaporation and Flash column chromatography (eluent: Hexan/ethylacetat 3:1) gave the title compound as a yellow viscous resin. 31P-NMR 8.30 ppm
1H-NMR (ppm) 7.72–7.80 (m), 7.45–7.47 (m), 6.76 (s), 6.62–6.67 (m), 2.11 (s), 2.05 (s), 1.96 (s) und 1.89–1.92 (d) determined in CDCl3.
The following BAPOs may be prepared analogously.
Ex Product Educt NMR of the Product 1.a Phenylphosphine,Phtaloyldichloride,2,4,6-Trimethylbenzoylchloride. 31P-NMR 13.12 ppm1H-NMR (ppm) 8.26–8.28 (d), 7.92–7.95(d), 7.57–7.72 (m),7.03–7.29 (m), 6.49(s), 2.06 (s), and 1.60(s) in CDCl3.Smp. 202–203� C. 1.b Isobutylphosphine,2,4,6-Trimethylbenzol-1,3-dicarboxylic acidchloride,2,4,6-Trimethylbenzoylchloride. 31P-NMR 29.45 ppm1H-NMR (ppm) 6.87(s), 6.77–6.78 (d),1.97–2.20 (m) und0.96–0.98 (t) inCDCl3. 1.c Phenylphosphine3,3′,4,4′-benzophenonetetracarboxylic aciddichloride2,4,6-trimethylbenzoylchloride
2. Preparation of Dimer Monoacylphosphine Oxide. (MAPO)
Formula II, R1=isobutyl, R3=benzyl, Q=mesitylene, n=1, m=1
120 ml (0.191 mol) buthyllitium were dropped at a temperature of −20� C. to a solution of 8.2 g (0.091 mol) isobutylphosphine in 150 ml tetrahydrofurane. Subsequently 11.2 g (0.0455 mol) 2,4,6-trimethylbenzol-1,3-dicarboxylic acid dichloride diluted with 50 ml tetrahydrofurane were added dropwise at a temperature of 0� C. The reaction mixture was kept at that temperature during 30 min under stirring. Subsequently 15.56 g (0.091 mol) benzylbromide were added dropwise and stirred at the same temperature for 2 hours. Subsequently the reaction mixture was allowed to reach room temperature. The solvent was rotatory evaporated. The residue is taken up in 200 ml toluene. The solution was diluted with water and the layers were separated. 10.3 g (0.091 mol; 30%) hydrogen peroxide were added to the organic phase. After stirring for 2 h, the organic phase was washed with water and with aqueous saturated NaHCO3, dried over MgSO4 and filtered. Evaporation and Flash column chromatography (eluent: Hexan/Ethylacetat 3:1) gave the title compound as a viscous resin. 31P-NMR 40.04 ppm
1H-NMR (ppm) 7.13–7.28 (m), 6.76 (s), 3.14–3.41 (m), 2.01–2.0 (d), 1,60–1.97 (m) und 0.89–0.95 (q) determined in CDCl3.
The following MAPO's may be prepared analogously.
Product Educt Phenylphosphine2,4,6-Trimethylbenzoylchloriden-Butylbromide PhenylphosphinePhthaloyldichloriden-Butylbromide Phenylphosphine3,3′,4,4′benzophenonetetracarboxylic aciddichloriden-Butylbromide
3. Preparation of Cyclic Bisacylphosphine Oxide (BAPO)
Formula VI, R1 is phenyl, U is isophthaloyl.
120 ml (0.191 mol) buthyllitium were dropped at a temperature of −20� C. to a solution of 10.0 g (0.091 mol) phenylphosphine in 150 ml tetrahydrofurane. A Yellow suspension was obtained. Subsequently 18.4 g (0.091 mol) of phthalic acid chloride diluted with 50 ml tetrahydrofurane were added at a temperature of 0� C. The reaction mixture was stirred at this temperature for 30 minutes and gently warmed up to room temperature with additional stirring for 2 hours. The solvent was evaporated on a rotatory evaporator and the residue diluted with 200 ml of toluene and washed with water.
10.3 g (0.091 mol; 30%) hydrogen peroxide was added to the organic phase. After 2 hours at room temperature, the organic phase was separated, washed with water and with aqueous saturated NaHCO3, dried over MgSO4 and filtered. Evaporation of the solvent and flash chromatography gave the title compound.
Weight (g)
Ebecryl 605
Epoxyacrylate (UCB)
Ebecryl 7100
Aminoacrylate (UCB)
Ebecryl 40
Propoxylated Pentaerythrol
Acrylated trifuntional
oligomer based on a glycerol
derivative (UCB)
Tripropylene glycol diacrylate
Ebecryl 1360
Silicone hexaacrylate
Dow Corning 57
Siliconeadditive, Dow Corning
Total OPV Formulation
Photoinitiators were investigated with a concentration of 10% and 8% based on 100% weight of the formulation.
For the determination of the cure speed the formulations were applied to white card boards (400 μm) and exposed to the UV light of a medium pressure mercury lamp with a power output of 120 W/cm. The speed of the conveyor belt at which the formulation was completely cured and track free, corresponds to the cure speed.
The results are shown in Table 1
white cardboard (400 μm)
Application equipment
Layer thickness
5 μm
1 m.p. Hg 120 W/cm (IST)
Cure speed (m/min)
10% Photoinitiator
8% Photoinitiator
Example 1
Example 1.b
Example 2
For the determination of the gloss the formulations were applied to chip boards and cured using the UV light of a medium pressure mercury lamp with a power output of 120 W/cm at a conveyor belt speed of 10 m/min. The gloss of the cured films was measured after the samples were post-exposed under a lamp of the type TKL 40/05 for 22 hours.
The results are shown in Table 2.
chip boards
Layer thickness
100 μm
1 m.p. Hg 120 W/cm (IST), TLK 40/05
Cure Speed
10 m/min
gloss: Haze-Gloss (Byk-Gardner)
Gloss 20�
10% Photoinitiator
6% Photoinitiator
Example 1
Example 1.b
Example 2
|Cited Patent
|Filing date
|Publication date
|May 9, 1980
|Apr 13, 1982
|Basf Aktiengesellschaft
|Acylphosphine oxide compounds
|Jan 18, 1984
|Dec 1, 1987
|Basf Aktiengesellschaft
|Photocurable compositions with acylphosphine oxide photoinitiator
|Aug 28, 1991
|Jun 8, 1993
|Ciba-Geigy Corporation
|Mono- and di-acylphosphine oxides
|Dec 2, 1993
|Apr 25, 1995
|Basf Aktiengesellschaft
|Process for preparation of arenebisphosphine oxides
|Jun 27, 1996
|Mar 3, 1998
|Ciba Specialty Chemicals Corporation
|Dimeric bisacylphosphines, oxides and sulfides
|Feb 5, 2001
|Jun 4, 2002
|Ciba Specialty Chemicals Corporation
|Organometallic monoacylarylphosphines
|May 31, 2001
|May 18, 2004
|Ciba Specialty Chemicals Corporation
|Organometallic monoacylalkylphosphines
|Feb 5, 2001
|Oct 18, 2001
|Jean-Pierre Wolf
|Organometallic monoacylarylphosphines
|Nov 13, 2002
|Jan 6, 2005
|Jean-Pierre Wolf
|Multimer forms of acylphosphines and their derivatives
|Sep 19, 1972
|Mar 28, 1974
|Dynamit Nobel Ag
|Halogenated di-phosphonic esters - useful for flame proofing plastics, having good compatibility and solubility and low flow temp
|Jul 9, 1979
|Feb 6, 1980
|BASF Aktiengesellschaft
|Acylphosphinoxide compounds, their preparation and their use
|Jul 27, 1990
|Feb 20, 1991
|Ciba-Geigy Ag
|Mono- and diacyl phosphine oxides
|Nov 26, 1993
|Jun 15, 1994
|BASF Aktiengesellschaft
|Arene bisphosphinoxides
|A. R. Barron et al, Journal of the Chemical Society, vol. 23, (1987), pp. 1753-1754.
|Derwent Abstract 2516V/14 for DE 2245817 (1974).
|L. Macarie et al., Revista de Chimie, vol. 53, No. 7, (2002), pp. 568-571.
|Citing Patent
|Filing date
|Publication date
|Jul 17, 2013
|Apr 5, 2016
|Lambson Limited
|Photopolymerisation processes and novel compounds therefor
|U.S. Classification
|568/14, 568/15
|International Classification
|Cooperative Classification
|European Classification
|Jul 25, 2005
Owner name: CIBA SPECIALTY CHEMICALS CORP., NEW YORK
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:WOLF, JEAN-PIERRE;HUG, GEBHARD;REEL/FRAME:016792/0857;SIGNING DATES FROM 20040823 TO 20040824
|Sep 21, 2010
|Fee payment
Year of fee payment: 4
|Nov 7, 2014
|Maintenance fee reminder mailed
|Mar 27, 2015
|Lapse for failure to pay maintenance fees
|May 19, 2015
|Expired due to failure to pay maintenance fee
Effective date: 20150327


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City police seek home invadersBy Josh OGorman
STAFF WRITER | February 04,2013Rutland City Police are searching for at least four assailants who broke into an apartment and pistol whipped the occupants.
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Bought around 20000 shares @ $3.87 when the market was going down and the losers were selling.
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Vibration Control Companies serving Lesotho
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based in St. Petersburg, FLORIDA (USA)
Industrial and Environmental Health and Safety Instrumentation: Air Sampling Pumps, Calibrators, Equipment, and Accessories. Colorimetric Gas Detector Tubes. Point Gas Monitors. Open Path Gas Detection. Sound, Noise, and Vibration Measurement Instruments. Real-time Dust Monitors. Flame Detectors.
SGS - Climate Change Programme
based in Geneva, SWITZERLAND
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Windsens GmbH
based in Munich, GERMANY
The "lower tail" development has become a more and more important role in the wind industry. The formerly adapted sensors from other industry are no longer the best solution, special developments and adaptations are required meanwhile. Windsens is taking action to support both sides (sensor suppliers and turbine developers) in creating a winwin situation.
based in Winterthur, SWITZERLAND
Sulzer is a global partner offering reliable and sustainable solutions for performance-critical applications. Our innovative solutions add value and strengthen the competitive position of our customers. Experience how Sulzer helps to cover the global demand for oil and gas. Pumps for up-, mid- and downstream applications, separation and process technologies for downstream ...
dBLab, Lda
based in Rio de Mouro (Sintra), PORTUGAL
dBLab is an Iberian company, with several offices across Portugal and Spain, and is part of Absorsor group, specialized in acoustics, noise and vibration control. It provides services for Noise Mapping by computer modelling of industrial sites, power plants, transportation infrastructures and urban areas, according to European Noise Directive, as well as Action Plans, ...
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VDH Industrial Hygiene CC
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Pelrine & Buchanan's Maritime Trading Worldwide Ltd
based in Halifax, NOVA SCOTIA (CANADA)
Pelrine & Buchanan's Maritime Trading Worldwide Ltd. is located in beautiful Nova Scotia, Canada. We have been supplying used and surplus power generation equipment to customers worldwide for over 23 years. We offer diesel generator set, natural gas generators, gas turbines, coal fired power plants, steam turbines and cogeneration power plants. We offer equipment by world ...
KONCAR - Electrical Engineering Institute Inc.
based in Zagreb, CROATIA
We are currently monitoring over 3 GVA on more than 50 hydro generators in over 15 countries worldwide. Our mission is to preserve the value of power equipment. Our expertise lies in condition monitoring systems that increase productivity of hydro turbines, motors, power generators and all types of rotating machines. For our customers we create value through online ...
Fluid Components International LLC.
based in San Marcos, CALIFORNIA (USA)
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Cirrus Research plc
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Nixalite of America Inc.
based in East Moline, ILLINOIS (USA)
Nixalite of America Inc has specialized in the expert control of pest birds and climbing animals since 1950. Nixalite is the designer and manufacturer of Stainless Steel Needle Strips called Nixalite. These strips are the most reliable and long lasting bird control available today.
Delta OHM S.r.L.
based in Caselle di Selvazzano, ITALY
Delta Ohm develops and manufactures instruments for measuring:Temperature, humidity, dew point, pressure, BAR, mBar, Pascal, mmH2O, InchHG, psi, air speed, light, Phot, UVA, UVB, UVC, UVindex, Solar Radiation, PAR, Acoustic, Sound meter, Vibration, Noise, CO, CO2, Air Quality, pH, ORP, Redox, Dissolved Oxygen, Turbidity, Data loggers, WBGT microclimate, PPV, PMV, Heat ...
Millennium Enterprises, Inc. (MEI)
based in Marietta, GEORGIA (US) (USA)
Millennium Enterprises, Inc. (MEI) has been solving customers` pollution prevention concerns. We are the exclusive supplier of the SafeGuards line of pollution prevention products ranging from large volume, proactive secondary spill containment (tanker truck containments / drums / totes); emergency response products (ruptured saddle tanks/ leaking equipment / HazMat decon ...
Felix Technology Inc.
based in Concord, ONTARIO (CANADA)
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SIPOS Aktorik GmbH
based in Altdorf, GERMANY
SIPOS Aktorik is a manufacturer of electric actuators. The main focus of the corporate activities is: Design and development, manufacturing and sales of electric actuators; Conceptual design and realisation of solutions in water/waste water plants and power plants; Development of tailor-made customer solutions; Worldwide service.
based in Besançon, FRANCE
With a wide range of products from industrial piezoelectric accelerometers, vibration sensors, vibration transmitters, signal conditioners to junction boxes, low noise cable assemblies, connectors, accessories and calibration equipment, VibraSens , an European company, is one of the best designer and manufacturer of Vibration instrumentation with a glorious track record ...
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Ashtead Technology Ltd
based in Letchworth, UNITED KINGDOM
Ashtead Technology was formed in 1985 when Ashtead Group plc acquired SubSpek Limited, which at the time provided underwater positioning, survey and inspection equipment rental from a base in Aberdeen. In 1994 the Singapore base was opened, focussing on the offshore oil and gas industry and the subsea telecommunications cable market in Asia Pacific. The first US ...
Monition Limited
based in Worksop, UNITED KINGDOM
The Industry Standard - Trusted throughout industry to improve plant reliability and boost production capacity where it matters most - Monition continues to set the standard for Asset Management and contract Condition-Monitoring services. Providing the means to monitor how productive plant is performing & the expertise to identify where & how machinery will develop ...
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Hey everybody dis your boi BODAHO, just wanted to let you fans and (real artist) out there know a little about me and my crew.. We All Hungry For (SUCCESS)... need i say more...
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Roberta Gambarini - Jazz Singer Roberta Gambarini Saturday 29th August 2009 at J&R Musicfest New York City, USA (5 Pictures)
Roberta Gambarini
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Roberta Gambarini
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View All: Roberta Gambarini - Jazz Singer Roberta Gambarini...
Next Nikki Yanofsky Slideshow: at J&R MusicFest 2009 at City Hall Park - New York City, USA - Saturday 29th August 2009
The 1969 session, including the only known recording of 'Sunshine Woman' by the band, will be included on a re-issue of 'The Complete BBC Sessions'...
The 55 year old actor joined Chris Martin and co. on stage in New Jersey to perform 'Earth Angel' and 'Johnny B. Goode'.
Bjork Digital comes to London's Somerset House in September, along with a single live show at the Royal Albert Hall.
Kim Kardashian released an audio excerpt from a phone call between Kanye and Taylor Swift over the lyrics of 'Famous' - but if it was recorded...
There's very much a strength of conviction in remaining what you were, but arguably more so in becoming what you want to be.
The BBC drama starring Aidan Turner returns to BBC One on September 4th.
Guns N' Roses were detained at the Canadian border last week for gun possession but they're adamant the weapon didn't belong to them.


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Portland Trail Blazers vs. Dallas Mavericks
* Additional fees apply. No coupon or promo codes necessary to enjoy the displayed discount price.
The last date listed for Portland Trail Blazers vs. Dallas Mavericks was Saturday January 18, 2014 / 7:30pm.
Currently at American Airlines Center
Demi Lovato & Nick Jonas: Future Now
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Two stars, one fantastic summer concert. Demi Lovato and Nick Jonas join forces this summer for… More
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Featured review from Goldstar Member
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Goldstar tickets were not available until 75% of the 1st quater was over. After standing in line for a very long time I get to the window only to be told there is no ticket for me. I was mortified because I looked like some jerk that couldn't afford tickets! I was even more embarrassed because I bought the tickets to take my husband to see his favorite team (Portland) and almost couldn't come through with it.


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- Overview
- Specs
- Reviews
Ergon GS1 Mountain Bike Grips SmallDeveloped for endurance or marathon riders, the Ergon GS1 Grips provide optimal long ride comfort, thanks to even pressure distribution and stable flex. Internal construction has dual supports that are individually tuned for perfect rebound and control. Each grip is ergonomically shaped with lightweight Direct Control rubber for precision steering and high damping. The days of numb hands, painful forearms and stiff fingers are over.
- Perfect for MTB, Marathon and XC
- Decreases hand fatigue and increases control
- 100% palm contact surface area reduces pressure on the ulnar nerve
- Corrects hand position, so the median nerve isn't absorbing unnecessary shock (a leading cause of carpel tunnel syndrome)
- Lightweight Direct Control rubber construction
- Aircraft aluminum clamp for fast and secure installation
- Size: Small (6.5-8.5")
Ergon GS1 Mountain Bike Grips Small
- material:
- Rubber/Aluminum
- weight:
- 146g/pair
- rating:
- 5
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SPECIAL OFFERTake An Extra 25% Off This Item, Discount Taken in Cart. See details
Anniversary Sale: Event available 7/22/16 - 7/31/16 at all Performance Bicycle Retail locations, online and by phone. Advertised category and/or brand savings taken off lowest marked price on all applicable items during the event period. Some brand and/or item exclusions may apply to this promotion – visit Terms and Conditions for details. Bikes and items labeled Doorbusters are priced as marked and are excluded from advertised category and/or brand discounts. Doorbuster availability limited to stock on hand. Online, discount taken at checkout. Taxes, gift cards, Team Performance memberships/renewals, Spin Doctor Services/Service Plans or shipping and handling on web/phone orders are not eligible to receive discounts. Discounts cannot be applied to previous purchases. Sorry, no rainchecks. In retail stores, colors, styles and select brand availability varies by location. Photographic, typographic and pricing errors are unintentional and subject to change.


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Air & Climate Companies serving Panama
Current filtering criteriaYou can remove a filter by clicking on the x
Category: Air & Climate ×
Employees number: 101-1000 ×
Industry: Manufacturing, Other ×
Serving: Latin America ×
Serving: Panama ×
Therma-Flite Inc.
based in Benicia, CALIFORNIA (USA)
Therma-Flite has a long history of screw conveyor technology and auger design, manufacturing equipment for chemical and process industries all over the world. Therma-Flite (then known as Christian Engineering) designed, built and sold the first hollow screw heat exchanger in 1939 for the food industry. After World War II holo screw heat exchangers became more widely used ...
TerraSource Global
based in St. Louis, MISSOURI (USA)
TerraSource Global's mission is to be the global partner today and tomorrow of industrial users of material handling and processing equipment by providing the best technology, quality and service for their specific project.We have a long history of providing a complete range of processing solutions to serve the power, mining, forest products, cement, steel, aluminum and ...
General Monitors
based in Lake Forest, CALIFORNIA (USA)
General Monitors is dedicated to benefiting society through leading-edge combustible gas, toxic gas, and flame detection monitoring products of the highest quality that protect life and property. With over 50 sales representatives around the globe, we provide exceptional service and after-sales support. Combining advanced sensing technology with superior service, General ...
Det-Tronics - Detector Electronics Corporation
based in Bloomington, MINNESOTA (USA)
Det-Tronics is a global leader in industrial hazard safety solutions, providing flame detection, gas detection, and hazard mitigation systems for critical industrial applications. We design, build, test, and commission SIL-2 flame and gas safety systems that range from conventional panels to fault-tolerant, addressable systems. Our flame and gas detectors are globally ...
EnGlobe Corp.
based in Quebec, QUEBEC (CANADA)
EnGlobe Corp. is a worldwide leader when it comes to integrated environmental services. We have developed a unique expertise in the management of organic waste materials and in reusing or recovering decontaminated soils as well as in the precision testing and calibration of bulk tanks and storage systems. Our clients are in public administration, in business and industry ...
Ocean Optics - a Halma Company
based in Dunedin, FLORIDA (USA)
Ocean Optics is a diversified photonics technology firm and a global leader in optical sensing. With full-service locations in the United States, Europe and Asia, we serve a wide range of markets, including process control, consumer electronics and medical diagnostics.
United Air Specialists, Inc. (UAS)
based in Cincinnati, OHIO (USA)
United Air Specialists, Inc. (UAS), a dust collector manufacturer, was founded in 1966, with the mission of designing and manufacturing air purification equipment of the highest quality. With this commitment to quality driving company policy, UAS has become a global industry leader in air cleaning and air pollution control. Our most well-known commercial air cleaner is ...
Crowcon Detection Instruments Ltd - a Halma company
based in Milton Park, UNITED KINGDOM
Crowcon Detection Instruments develop, manufacture and market a complete range of portable and fixed gas detection products you can trust to protect people and plant against gas hazards. Established over 40 years the company has strong regional centres in North America, Singapore, The Netherlands and India, with a mature network of trained distributors covering almost ...
The EI Group, Inc.
based in Morrisville, NORTH CAROLINA (USA)
Founded in 1988 solely as an environmental consulting firm, EI's response to its clients' needs led to a natural progression for the company to widen its scope of services. As a result, EI began providing comprehensive consulting in areas including industrial hygiene, safety and occupational health. To further meet client needs, EI opened its Training and Compliance ...
ADI Systems Inc.
based in Fredericton, NEW BRUNSWICK (CANADA)
At ADI Systems Inc., industrial wastewater treatment and waste-to-energy technology is our specialty. Our experience spans over three decades, hundreds of projects, and diverse industrial sectors. With an extensive portfolio of the world's leading industrial wastewater treatment, waste-to-energy, and biogas treatment and utilization technologies, plus an understanding ...
Dwyer Instruments Inc
based in Michigan City, INDIANA (USA)
Dwyer Instruments Inc. produces a broad range of competitively priced precision instruments for measuring, transmitting and controlling pressure, temperature, level and flow. In addition to making and selling quality precision instruments, Dwyer is committed to a standard of customer service-including competitive prices and knowledgeable, courteous technical support-that ...
based in Courbevoie, FRANCE
Enablon is the world's leading provider of Sustainability, EH&S and Operational Risk Management Software. More than 1,000 global companies and 1 million users rely on Enablon software solutions to manage their environmental and social performance, minimize risks and improve profitability. Enablon offers the most comprehensive platform in the industry, and is consistently ...
Global Finishing Solutions LLC
based in Osseo, WISCONSIN (USA)
Engineering and Manufacture of simple and complex Turnkey finishing systems for the Aerospace, Automotive, and Industrial markets. Complete Turn key System with full Engineering, Design detais, Fabrication, Installation, start=up and service.Company makeup includes, JBI, Blu-Surf Systems, Team Blowtherm, (Binks Envirptech waterwash), and MilBank Systems bringing hundreds ...
China Expansion Joints Company
based in Donggang, CHINA
We uses the most advanced tools necessary to design safe and reliable expansion joints.We plan and execute our work to meet our customers`s specifications. We also strive to deliver these products in the shortest time possible and at a competitive price.
American Hofmann Corporation
based in Lynchburg, VIRGINIA (USA)
American Hofmann Corporation is a design and production facility of balancing machines in Lynchburg, VA USA. American Hofmann balancing machines cover a wide range of sizes & applications -- from simple bench-top models to fully automatic, multi-station measuring & correction systems, & portable field balancers. American Hofmann serves the automotive, electric motor, ...
Peak Scientific Instruments Ltd
based in Inchinnan, UNITED KINGDOM
Peak Scientific Instruments Ltd are a manufacturer of laboratory gas generators including nitrogen (both Membrane Technology & Carbon Molecular Sieve systems), hydrogen and zero air suitable to operate most laboratory analytical applications such as LCMS (liquid chromatography mass spectroscopy) and GC (gas chromatography). With varying flow rates, purities & ...
PRAB, Inc
based in Kalamazoo, MICHIGAN (USA)
PRAB, Inc. is a leading engineer and manufacturer of industrial wastewater filtration and distillation systems. Our broad spectrum of equipment ranges from metal particle separation and filtration, to ultrafiltration, to distillation and evaporation. Industrial wastewater applications include parts washing, surface treatment, industrial cleaning, exhausted oil emulsions, ...
Kexing Special Ceramics Co., Ltd
based in Toronto, ONTARIO (CANADA)
Kexing Special Ceramics, founded by Liling Kexing Industry Co., Ltd. in Hunan, China was established in 2012. While maintainingits manufacturing base in China, it is headquartered inToronto, Ontario Canada. Kexing Special Ceramics integrates scientific research and production with international trade. Establishing long-term relationships with Central South University, ...
Huadong Blower Co.,Ltd
based in CHINA
roots blower, centrifugal fan, multi-stage centrifugal blower,rotary blower, ring blower,biogas blower, aeration blower, aquaculture aeration blower, stainless steel blower, axial fanShandong Huadong Blower Co.,Ltd, covering an area of 38000 square meters, is located at Taiping Industrial Park, Xiuhui town, Zhangqiu City,Shandong Province, China, which is close to Qingdao ...
TR Solid Control
based in Xi'An,China, CHINA
Xian TianRui Petroleum Machinery Equipment Co., Ltd (Short name: TR Solids Control ), the Professional manufacturer of solid control equipments/system and shale shaker screen. TR Solid Control is located in No.60 Caotang Industrial Park, Hu County, Xi'an City, Shaanxi Province, China. Founded in recent years, TR Solid Control is becoming more competitive in the field of ...
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All of the posts on our blog are scheduled (in 30 minute increments), sometimes days in advance. We only allow guest commenting (ie. reader accounts). As a result hours (or days) can go by without anyone logging into WordPress.
While cron is running and posts are being published on schedule (and being republished on Facebook, Twitter, etc) the super cached home page is not expiring as I would expect. As soon as someone logs into WordPress (admin, writer, etc), however, the home page is marked as expired and a new page is generated.
I've seen a few other mentions of schedule posts and home page not expiring, curious if there is any special configuration or separate cron I should be running for this type of setup.


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Smith & Nephew Education and EvidenceA powerful knowledge resource created with surgeons, for surgeons
Expert anatomical demonstrations
Video Collection: Global Tribology Summit
Watch presentations recorded at the 2016 Global Tribology Summit in London. This meeting...
Retrieval studies of femoral and polyethylene components
Dr Thomas Heyse (DE). Jul 2016
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NPWT Expert Meeting: Challenging Wounds
Copenhagen, Denmark Nov 10, 2016 - Nov 11, 2016
Surgical Technique: SMF™ Short Monolithic Femoral Hip System
Jun 2016
Video Collection: 2016 Vail Hip Symposium
Watch presentations recorded at the 2016 Vail Hip Symposium on January 14-16, 2016. The faculty...
Lateral Meniscal Root Repair using FIRSTPASS™ ST and ULTRATAPE
Mr James Robinson, (UK). May 2016
Medial Patellofemoral Ligament Reconstruction: Technique for...
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Visiting Surgeon Programme - Total Knee Replacement
Jessa Ziekenhuis, Hasselt, Belgium Jul 30, 2015 - Dec 31, 2016
2008 - 2016 Smith & Nephew Plc. ◊ Trademark of Smith & Nephew


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Art Exhibit: Early Birds paintings by Cathe Gill, Beth Means & Anni Leedy opens June 17
Early Birds is an exhibit of small paintings done on location around the Center for Urban Horticulture by three local landscape artists, who, over many years, have often walked the trails and stopped to paint and sketch. The exhibit runs through July 28th.
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Join us as we celebrate thirty years of service and the extraordinary support of people like you.
Create an anniversary book dedication to show the public that this library is possible through the generosity of our patrons!
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Story Program
WHO: Kids ages 3 to 8 and their parents.
WHAT: Enjoy stories about plants and nature.
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The library stays open until 7pm before scheduled Northwest Horticultural Society lectures. Lectures are open to the public, $5 members, $10 non-members.
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With over 15,000 books on gardening techniques, garden design and history, native floras from around the world, and 400 magazine titles, the Miller Library has the most extensive horticulture collection in the Pacific Northwest. More about the Miller Library.
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The property is very well maintained and the staff very kind and helpful. We stayed one week in a "hillside room with wiev", e g the room is located om the other side of the road. Very, very nice room! Afternoon tea in the garden every day. Free wireless in the garden area and in the hotel reception. A pool area was finished the week we stayed there. They also worked with a "sea pool". Free beach towels and a nice little beach dowm by the hotel. Easy to go by bus til Beau Vallon (costs 5 SR/person) and its nice, long beach and restaurants. Very good breakfast. Dinner alternatives at the hotel, was... nothing to write home about. Bu threre is a restaurant, Lounge8, just beside the hotel. Expensive, but very good! One secret 5-course dinner och one 3-course dinner every night. Very relaxed and nice place. Recommended!
- Official Description (provided by the hotel):
- Set between white sandy beaches and lush tropical vegetation, Bliss Hotel is located in the northern part of Mahe Island. Hide away in our secret dreamy bay and enjoy the amazing sunset views overlooking both North and Silhouette Islands. ... more less
- Reservation Options:
- TripAdvisor is proud to partner with Booking.com, Hotels.com, Agoda, Travelocity, Expedia, Hotwire, Priceline and Odigeo so you can book your Bliss-Hotel Seychelles reservations with confidence. We help millions of travelers each month to find the perfect hotel for both vacation and business trips, always with the best discounts and special offers.
- Also Known As:
- Bliss-Hotel Seychelles Mahe Island


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Live updates
- ITV Report
Fred Goodwin avoids criminal charges over RBS failure
The Crown Office said there was "insufficient evidence" to take action against Goodwin or any other individuals over the bank's failure.Read the full story ›
RBS losses more than double last year's figure
The Royal Bank of Scotland has reported a first quarter pre-tax loss of £968 million - more than double last year's of £446 million.
The loss reflects the impact of its £1.2 billion payment last month to the Treasury to buy out a crucial part of its £45 billion bailout.
The payment ended a dividend access share (DAS) agreement with the Government which was put in place in 2009 and prevented it paying dividends to any shareholders before the Treasury.
The bank said: "RBS remains on track with its plan to build a strong, simple, fair bank for customers and shareholders."
RBS loss-making, paying bonuses and (slowly) on the mend
There are reasons to be optimistic about the future of RBS but the current picture isn't pretty.Read the full story ›
- ITV Report
RBS sets aside £2bn to cover mistakes
Chief executive Ross McEwan has promised to "clean up" the bank.Read the full story ›
RBS blame 'cyber attack' for banking glitch
A fault which left RBS and NatWest customers unable to login to their online banking yesterday has been blamed on a 'cyber attack'.
A spokesman for the bank said: "The issues that some customers experienced accessing online banking on Friday was due to a surge in internet traffic deliberately directed at the website.
"This deliberate surge of traffic is commonly known as a distributed denial of service (DDoS) attack. At no time was there any risk to customers."
RBS online banking glitch fixed after disruption
A fault which left RBS, NatWest and Ulster Bank customers unable to login to their online banking this morning has been fixed, RBS has said.
The cause of the problem, which lasted around 50 minutes, was still being investigated.
We are aware that some customers experienced issues with online banking this morning.
This has now been resolved and our service is operating as normal. We apologise to those customers who experienced difficulties."
It's remarkable that the taxpayer is profiting from RBS
Why is the Chancellor selling now? ITV News Economics Editor explains.Read the full story ›
Banks 'working to restore trust' after Forex scandal
Antony Jenkins, chief executive at Barclays, apologised for the bank's role in the scandal.
The misconduct at the core of these investigations is wholly incompatible with Barclays' purpose and values and we deeply regret that it occurred.
I share the frustration of shareholders and colleagues that some individuals have once more brought our company and industry into disrepute.
RBS has also so far dismissed three staff and a further two are suspended.
The serious misconduct that lies at the heart of today's announcements has no place in the bank that I am building.
Pleading guilty for such wrongdoing is another stark reminder of how badly this bank lost its way and how important it is for us to regain trust.
RBS fined £430 million by US authorities in Forex scandal
Royal Bank of Scotland i among five banks hit with fines over involvement in the rigging of global currency markets and has agreed to pay $669 million (£430 million) to US authorities.
It comes on top of a £399 million penalty last November, including £217 million by the FCA and $290 million (£186 million) by the US Commodity Futures Trading Commission (CFTC).
RBS posts £446m loss after currency-rigging probe
RBS has reported a £446 million loss in Q1 after restructuring and currency-manipulation probes, the state-backed lender has revealed today.
The bank, which is 80% owned by the taxpayer, was hit by restructuring costs of £453 million and £856 million in "litigation and conduct" charges.
Adjusted operating profit, excluding one-off charges, was up 16% to £1.63 billion as the bank benefited from "generally benign credit conditions".


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JACKSON, Mississippi Mississippi hunters smashed back-to-back records on the opening weekend of the state's 10-day alligator season by bagging some of the biggest critters on the books.
Within hours of the August 30 opener, one hunting party caught the state's longest and heaviest female gator at 10 feet and 295.3 pounds (134 kg), according to the Mississippi Department of Wildlife, Fisheries and Parks.
A second record was broken shortly after midnight on September 1, when a different group of hunters nabbed the state's heaviest male alligator at 723.5 pounds (328 kg).
That distinction lasted about an hour, until another party captured one weighing 727 pounds (330 kg), and measuring 13 feet (3.96 m.)
Dustin Bockman, a 27-year-old UPS driver, and his crew spotted the mammoth creature in the Mississippi River and trailed it for two hours before getting close enough to spear it. It took another two hours to hook it with a second line and noose its neck.
Eventually, Bockman had to shoot the alligator.
It took another two hours and two extra men to hoist the gator on the boat, capping a grueling hunt that had Bockman's girlfriend understandably nervous.
"I had sent him a text message at four in the morning, asking him, 'Are you alive?'" said Amy Parsons. "I was afraid. I hadn't heard from him all night and he hadn't come home."
Larger alligators have been trapped in Florida, weighing up to 1,000 pounds (454 kg), and one last year measured 14-feet.
This is Mississippi's ninth annual alligator season in a sport with growing popularity, said the state's alligator program coordinator Ricky Flynt.
"It is quite an adventure and is perceived as being dangerous game," he said.
Despite its inherent dangers, alligator hunting has produced just one injury in Mississippi, Flynt said. A man required surgery to his thumb after getting bit while trying to reel in a gator.
Flynt attributed the multiple records to an expanded territory - this is the first year Mississippi has allowed statewide hunting - and to normal water levels in the rivers. Last year's droughts hindered the hunts, he said, despite a total haul of 513.
Mississippi does a lottery for alligator hunting licenses. More than 7,100 people applied this year and the state gave out just 920 permits. Also, the state requires hunters attend a mandatory alligator hunting safety course.
(Editing by David Adams and Leslie Gevirtz)
Trending On Reuters
Beyonce dominates MTV video nominations, Taylor Swift shut out
Beyonce's critically-praised visual album "Lemonade" on Tuesday earned the R&B singer a career-best 11 nominations for the MTV Video Music Awards, in a list that included multiple nods for Adele and rapper Kanye West but nothing for Taylor Swift. Full Article
Reuters Showcase
Reuters India App
Download the Reuters app from the Apple App Store, Google Play and Amazon. Select the India edition from settings. Full Coverage


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Shorebird season is on the horizon, and many birds are already heading back south. Time to get reacquainted with some of the more common migrants like Solitary Sandpiper, as Tom Johnson lays out at View from the Cape.
Solitary Sandpipers are small members of the genus Tringa, the same genus that includes the yellowlegs and [read more…]


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Join the 'Reclast' group to help and get support from people like you.
Reclast Support Group
Our support group for Reclast has 44 questions and 41 members. Updated 25 Jul 2016.
Latest News
Growth Hormone May Lower Odds of Fractures in Older Women
THURSDAY, Aug. 27, 2015 – Older women with osteoporosis could get lasting benefits from a few years on growth hormone, a new, small trial suggests. Researchers found that when women with the ...
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Noisey Blog
Iggy Pop Discusses His New Album with Josh Homme, 'Post Pop Depression': "I'm Closing Up After This"
Internet Videos Of Particular Importance
About a year ago, Iggy Pop and Josh Homme started working on an album together in secret. That album, Post Pop Depression, is coming out in March. Iggy Pop was excited to work on something new and bring people together—but he also knows that this latest chapter of music is likely his last. "I feel like I'm closing up after this," he tells us. We sat down, in collaboration with Beats1, with Iggy and his band to break down the punk legend's career. Check out more about the album on Apple Music and watch a clip of the interview below:


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The Guardian
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Major Issues
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NSW, Qld, SA, Vic, WA
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Current Issue of The Guardian
July 20, 2016 - click here for index of articles.
The decision of the arbitral tribunal in The Hague is nothing short of provocative. As is the response of the Australian and US governments. They wasted no time in springing to the defence of the ruling of a tribunal that has found against the People's Republic of China's historical claim to a disputed maritime zone in the South China Sea. The authority of the body to determine such a question is doubtful, as is the process used. But that hasn't stopped the usual supporters of US military and economic interests from lecturing China about respect for "international law" and threatening grave consequences starting with sanctions. more ...
The ongoing commemorations marking battles in World War I continue, glorifying the carnage and death of the first global conflict fought for the division of markets. In Australia ANZAC Day commemorations this year took place in the growing shadow of the build-up of US military forces in Australia's north. It is natural that families wish to recall the memories of the tens of thousands who have been killed and wounded in the succession of wars in which Australian servicemen and women have been involved. more ...
On Monday July 4 the Seoul Central District Court sentenced Han Sang-Gyun, President of the Korean Confederation of Trade Unions (KCTU) to five years in jail. more ...
The Abbott/Turnbull's Australian Building and Construction Commission (ABCC) is a reincarnation of former PM John Howard's ABCC, but with additional draconian, anti-union measures. It imposes hefty penalties of $36,000 for individuals and $180,000 for trade unions for each offence. These are three times higher than for other workers under the Fair Work Act. more ...
In an announcement that is sending shockwaves through the mining industry, a report from medical experts investigating rates of Black Lung disease amongst Australian miners has revealed the problem is much worse than anticipated. more ...
Ross Gittins' Sydney Morning Herald article could not be more wrong when he says – "The real winners of the Mediscare campaign are doctors and the medical industry" – SMH July 6, 2016. more ...
Wonderful, bountiful. The ever-youthful prince of Facebook, Mark Zuckerberg, told the world that he and his wife Priscilla Chan would be giving away 99 percent of their shares to charitable causes during the course of their lifetimes. A gesture so bold and generous: almost enough to rekindle the notion that tech billionaires were something different. A far cry from those grey and grubby bankers clutching their bonuses in so unseemly a fashion, or the brash property tycoons with exclusively located follicles and vacant consciences. more ...
I wrote this poem in response to hearing that political prisoner Sundiata Acoli, 78 years old and a former Black Panther Party activist had been denied parole again. He has spent 42 years in jail for struggling against injustice and racism. There is a campaign to win his release through a presidential pardon. more ...
Here's a question for you: Did Britain's Brexit vote really upset the USA? Yes, I know US Secretary of State Kerry shot off to Europe in a hurry immediately after the vote, ostensibly to mend fences but there could have been a much more serious reason. more ...
You can't have capitalism without racism.
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Wednesday, July 20, 2016


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|Sent on:
|Saturday, February 16, 2013 10:24 PM
Hi Members: Here are the discussion questions for "The Unlikely Pilgrimage of Harold Fry"
As always, please bring a snack to share and I will provide the wine. See you then!
1. Talk about the obvious—why Harold Fry never returns from the mailbox. Is he experiencing a mid-life crisis, or spiritual crisis...or what? Has anything like that ever happened to you—a snap decision that turned out to be not just of-the-moment, but momentous as well?
2. What is the significance, thematically, of Harold's yacht shoes?
3. "Life might appear ordinary simply because the person living it had been doing so for a long time." One of the themes in Unlikely Pilgrimage is how a seemingly ordinary life can take on extraordinary aspects. Do you consider your own life ordinary or extraordinary? In what way might we see our own lives or, say the lives of our neighbors, as remarkable?
4. How has Harold's past—his upbringing—shaped his adult life, especially his relationship with his wife and son?
5. Talk about the evolution of Harold Fry. What is his state of mind as he begins the journey, and how does he change during his long walk? What does he learn—about life and about himself?
6. Discuss the marital relationship, at the book's beginning, between Harold and Maureen. Maureen wants to believe that Harold's desertion has more to do with Queenie than with the state of the couple's marriage. Is she right...or not?
7. Why do couples continue in a relationship that no longer seems to fulfill a mutual need for either?
8. Describe Harold's relationship with his son, David.
9. What was Harold's relationship with Queenie...and in what way does he feel he betrayed her?
10. What does the waitress mean when she tells Harold that "if we don't go mad once in a while, there's no hope"? Have you ever felt like that?
11. What role does religious belief play in this novel?
12. What is Rachel Joyce satirizing as crowds begin to gather and Harold's journey becomes a cause celebre—with its t-shirts, Tweets, and Facebook posts? How do the people who join Harold in his trek see his journey—what are they looking for, or what do they expect from Harold? Why do the crowds eventually leave him behind?
13. What do Harold and Maureen come to understand about one another and marriage—and how does their marriage change? What do they come to realize about one another?
14. Why is Harold's journey called a "pilgrimage" in the title?
15. What is the relationship between the epigraph from John Bunyan's Pilgrim's Progress and this contemporary novel? Why does Rachel Joyce use Bunyan's book at both beginning and end?
16. Do you find the novel's end satisfying? Why or why not?
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