text:
|Publication number
|Publication type
|Application number
|Publication date
|Jul 19, 1988
|Filing date
|Apr 25, 1986
|Priority date
|Apr 25, 1986
|Fee status
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|Publication number
|Stephen D. Pastor, Edward T. Hessell, Ramanathan Ravichandran
|Original Assignee
|Ciba-Geigy Corporation
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|Patent Citations (5), Non-Patent Citations (9), Referenced by (4), Classifications (39), Legal Events (5)
|External Links: USPTO, USPTO Assignment, Espacenet
Organic polymeric materials such as plastics and resins are subject to thermal, oxidative and photodegradation. A great variety of stabilizers are known in the art for stabilizing a diversity of substrates. Their effectiveness varies depending upon the causes of degradation and the substrate stabilized. In general, it is difficult to predict which stabilizer will be most effective and most economical for any one area of application. For example, stabilizer effectiveness in reducing volatility may depend upon preventing bond scission in the substrate molecule. Limiting embrittlement and retaining elasticity in a polymer or rubber may require prevention of excessive crosslinking and/or chain scission. Prevention of discoloration may require inhibiting reactions which yield new chromophores or color bodies in the substrate or stabilizer. Problems of process stability and incompatibility must also be considered.
Various organic hydroxylamine compounds are generally known and some are commercially available. A number of patents disclose nitrogen-substituted hydroxylamines as antioxidant stabilizers for various substrates including polyolefins, polyesters and polyurethanes. U.S. Pat. Nos. 3,432,578, 3,644,278, 3,778,464, 3,408,422, 3,926,909, 4,316,996 and 4,386,224 are representative of such patents which basically disclose N,N-dialkyl-, N,N-diaryl- and N,N-diaralkyl hydroxylamine compounds and their color improvement and color stabilizing activity.
In addition, several carbamoyl-substituted hydroxylamine compounds are disclosed in U.S. Pat. No. 3,869,278 and Zinner et al, Pharmazie, 20, 291 (1965) in a non-polymeric context. The reaction of N,N-dimethyl, N,N-diethyl, and N,N-diisopropyl-hydroxylamine with isocyanates to prepare N,N-dialkyl-O-carbamoylhydroxylamines along with the potential herbicidal activity of such compounds has been described by N. V. Konstantinovia et al., Zhurnol Organicheskoi Khimii, 4, 1928-1932 (1968). The reaction of benzhydryl-substituted hydroxylamines has been described by von Wolfgang Kliegel et al., Liebigs Ann. Chem., 736, 173-175 (1970). O-Carbamoylhydroxylamine has been described by I. K. Larsen, Acta Chemical Scandinovia, 22, 843-853 (1968). The reaction of N-acyl-N-alkylhydroxylamines with isocyanates is mentioned by H. G. Aurich et al., Chem. Ber., 106, 1881-1896 (1973). The latter technical publications are devoid of utility statements for the compounds.
It has now been determined that the compositions of this invention exhibit a variety of desirable properties stemming from the presence therein of the indicated substituted amino carbamates. Thus, the compounds serve to protect various substrates such as polyolefins, elastomers and lubricating oils against the adverse effects of oxidative and thermal degradation. They are most effective as color improvers and process stabilizers in polyolefin compositions which may contain metal salts of fatty acids and which also contain a phenolic antioxidant. Thus, they serve to substantially reduce color formation resulting from the presence of the phenolic antioxidant and/or from the processing conditions as well as to directly protect the polymer from said processing conditions. They also prevent the discoloration of polyolefin compositions containing hindered amine light stabilizers or combinations of phenolic antioxidants and organic phosphites. In addition, the gas fading that may be experienced upon exposure to the combustion products of natural gas is also significantly reduced.
It is a primary object of this invention to provide compositions of organic materials stabilized against oxidative, thermal and actinic degradation by the presence therein of a class of substituted aminoxy carbamate derivatives.
It is a further object to provide such compositions which also contain phenolic antioxidants wherein said carbamates substantially reduce color formation resulting from the presence of said phenol.
It is still a further object to provide a class of novel carbamate derivatives which exhibits a broad range of improved stabilization performance characteristics.
Various other objects and advantages of this invention will become evident from the following description thereof.
The stabilizing compounds utilized in the compositions of this invention correspond to the formula ##STR2## wherein n is 1 to 3;
m is 0 to 2;
n+m is 1 to 3;
R1 and R2 are independently hydrogen, alkyl of 1 to 36 carbon atoms, said alkyl substituted by halogen, alkoxyalkyl of 2 to 6 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, aralkyl of 7 to 9 carbon atoms or said aralkyl substituted by alkyl of 1 to 36 carbon atoms,
R3 is alkyl of 1 to 18 carbon atoms;
X is oxygen or sulfur;
A, when n=1 and m=0, is hydrogen, alkyl of 1 to 36 carbon atoms, said alkyl substituted by halogen, alkoxyalkyl of 2 to 6 carbon atoms, cycloalkyl of 5 to 12 carbon atoms, aryl, aralkyl of 7 to 9 carbon atoms, said aralkyl substituted by alkyl of 1 to 36 carbon atoms or aryloxyalkyl(C2 -C6);
A, when n+m=2, is alkylene of 1 to 12 carbon atoms, alkylidene of 2 to 12 carbon atoms, cycloalkylene of 6 to 10 carbon atoms, (C1 -C4)alkyl-substituted hexahydrobenzylene, arylene of 6 to 10 carbon atoms, or 4,4'-alkylidenediphenyl; and
A, when n+m=3, is alkanetriyl of 3 to 12 carbon atoms or tris(C2 -C6 alkylene)isocyanurate.
The R1 and R2 groups are preferably hydrogen, straight-chain or branched alkyl with 1 to 18 carbon atoms such as methyl, ethyl, n-propyl, n-butyl, tert-butyl, n-pentyl, n-octyl, 2-ethylhexyl, decyl, dodecyl and octadecyl; cyclopentyl and cyclohexyl; and benzyl, α-methylbenzyl and α,α-dimethylbenzyl. X is preferably oxygen. R3 is preferably C12 -C18 alkyl.
Other preferred groups include, for n=1 and m=0, A as C1 -C18 alkyl (see preferred list for R1 and R2) and phenyl; for n+m=2, A as alkylene of 2 to 6 carbon atoms, e.g. ethylene, propylene or hexylene, alkylidene of 1 to 6 carbon atoms such as ethylidine, cyclohexylene, trimethyl-hexahydrobenzylene, phenylene, xylylene, 2,4-tolylene and 4,4-methylenediphenyl; and for n+m=3, A as glyceryl and trimethylylpropane.
The derivatives of this invention can be prepared by reacting the appropriately substituted hydroxylamine with an appropriately substituted isocyanate, isothiocyanate or cyanate salt (A=H) in a solvent to yield the desired product. Typical isocyanate reactants include n-butyl isocyanate, n-hexyl isocyanate, n-octadecyl isocyanate, phenyl isocyanate, 2,4-toluenediisocyanate, potassium cyanate, 1,6-hexanediisocyanate, ethyl isothiocyanate, phenyl isothiocyanate and naphthyl isothiocyanate. The solvent can be an aromatic hydrocarbon such as benzene, toluene, xylene, and the like, or a heterocyclic ether, such as tetrahydrofuran. The reaction temperature ranges from 10� to 70� C. Where di- and tris-carbamates with m=1 or 2 are prepared, the remaining O-substituents are provided by reacting the hydroxylamine/isocyanate reaction product with the appropriate alcohol (R3 OH) at a temperature of 20� to 70� C. The starting materials needed to prepare the stabilizers of this invention are items of commerce or can be prepared by known methods.
The compounds of the present invention are particularly effective in stabilizing organic materials subject to oxidative, thermal and actinic degradation, such as plastics, polymers and resins.
Substrates in which these compounds are particularly useful are polyolefins such as polyethylene and polypropylene; polystyrene, including impact polystyrene, ABS resin, SBR, isoprene, as well as natural rubber, polyesters including polyethylene terephthalate and polybutylene terephthalate, including copolymers, and lubricating oils such as those derived from mineral oil.
In general polymers which can be stabilized include
1. Polymers of monoolefins and diolefins, for example polyethylene (which optionally can be crosslinked), polyproplene, polyisobutylene, polybutene-1, polymethylpentene-1, polyisoprene or polybutadiene, as well as polymers of cycloolefins, for instance of cyclopentene or norbornene.
2. Mixtures of the polymers mentioned under (1), for example mixtures of polypropylene with polyisobutylene.
3. Copolymers of monoolefins and diolefins with each other or with other vinyl monomers, such as, for example, ethylene/propylene, propylene/butene-1, propylene/isobutylene, ethylene/butene-1, propylene/butadiene, isobutylene/isoprene, ethylene/alkyl acrylates, ethylene/alkyl methacrylates, ethylene/vinyl acetate or ethylene/acrylic acid copolymers and their salts (ionomers) and terpolymers of ethylene with propylene and a diene, such as hexadiene, dicyclopentadiene or ethylidene-norbornene.
4. Polystyrene, poly-(p-methylstyrene).
5. Copolymers of styrene or methylstyrene with dienes or acrylic derivatives, such as, for example, styrene/butadiene, styrene/acrylonitrile, styrene/ethyl methacrylate, styrene/butadiene/ethyl acrylate, styrene/acrylonitrile/methyl acrylate; mixtures of high impact strength from styrene copolymers and another polymer, such as, for example, from a polyacrylate, a diene polymer or an ethylene/propylene/diene terpolymer; and block polymers of styrene, such as, for example, styrene/butadiene/styrene, styrene/isoprene/styrene, styrene/ethylene/butylene/styrene or styrene/ethylene/propylene/styrene.
6. Graft copolymers of styrene, such as, for example, styrene on polybutadiene, styrene and acrylonitrile on polybutadiene, styrene and alkyl acrylates or methacrylates on polybutadiene, styrene and acrylonitrile on ethylene/propylene/diene terpolymers, styrene and acrylonitrile on polyacrylates or polymethacrylates, styrene and acrylonitrile on acrylate/butadiene copolymers, as well as mixtures thereof with the copolymers listed under (5), for instance the copolymer mixtures known as ABS-, MBS-, ASA- or AES-polymers.
7. Halogen-containing polymers, such as polychloroprene, chlorinated rubbers, chlorinated or sulfochlorinated polyethylene, epichlorohydrine homo- and copolymers, polymers from halogen-containing vinyl compounds, as for example, polyvinylchloride, polyvinylidene chloride, polyvinyl fluoride, polyvinylidene fluoride, as well as copolymers thereof, as for example, vinyl chloride/vinylidene chloride, vinyl chloride/vinyl acetate or vinylidene chloride/vinyl acetate copolymers.
8. Polymers which are derived from α,β-unsaturated acids and derivatives thereof, such as polyacrylates and polymethacrylates, polyacrylamide and polyacrylonitrile.
9. Copolymers from the monomers mentioned under (8) with each other or with other unsaturated monomers, such as, for instance, acrylonitrile/butadiene, acrylonitrile/alkyl acrylate, acrylonitrile/alkoxyalkyl acrylate or acrylonitrile/vinyl halogenide copolymers or acrylonitrile/alkyl methacrylate/butadiene terpolymers.
10. Polymers which are derived from unsaturated alcohols and amines, or acyl derivatives thereof or acetals thereof, such as polyvinyl alcohol, polyvinyl acetate, polyvinyl stearate, polyvinyl benzoate, polyvinyl maleate, polyvinylbutyral, polyallyl phthalate or polyallyl-melamine.
11. Homopolymers and copolymers of cyclic ethers, such as polyalkylene glycols, polyethylene oxide, polypropylene oxide or copolymers thereof with bis-glycidyl ethers.
12. Polyacetals, such as polyoxymethylene and those polyoxymethylenes which contain ethylene oxide as comonomer.
13. Polyphenylene oxides and sulfides, and mixtures of polyphenylene oxides with polystyrene.
14. Polyurethanes which are derived from polyethers, polyesters or polybutadienes with terminal hydroxyl groups on the one side and aliphatic or aromatic polyisocyanates on the other side, as well as precursors thereof (polyisocyanates, polyols or prepolymers).
15. Polyamides and copolyamides which are derived from diamines and dicarboxylic acids and/or from aminocarboxylic acids or the corresponding lactams, such as polyamide 4, polyamide 6, polyamide 6/6, polyamide 6/10, polyamide 11, polyamide 12, poly-2,4,4-trimethylhexamethylene terephthalamid or poly-m-phenylene isophthalamide, as well as copolymers thereof with polyethers, such as for instance with polyethylene glycol, polypropylene glycol or polytetramethylene glycols.
16. Polyureas, polyimides and polyamide-imides.
17. Polyesters which are derived from dicarboxylic acids and diols and/or from hydroxycarboxylic acids or the corresponding lactones, such as polyethylene terephthalate, polybutylene terephthalate, poly-1,4-dimethylol-cyclohexane terephthalate, poly-[2,2-(4-hydroxyphenyl)-propane]terephthalate and polyhydroxybenzoates as well as block-copolyether-esters derived from polyethers having hydroxyl end groups.
18. Polycarbonates.
19. Polysulfones, polyethersulfones and polyetherketones.
20. Crosslinked polymers which are derived from aldehydes on the one hand and phenols, ureas and melamines on the other hand, such as phenol/formaldehyde resins, urea/formaldehyde resins and melamine/formaldehyde resins.
21. Drying and non-drying alkyd resins.
22. Unsaturated polyester resins which are derived from copolyesters of saturated and unsaturated dicarboxylic acids with polyhydric alcohols and vinyl compounds as crosslinking agents, and also halogen-containing modifications thereof of low flammability.
23. Thermosetting acrylic resins, derived from substituted acrylic esters, such as epoxy-acrylates, urethane-acrylates or polyester acrylates.
24. Alkyd resins, polyester resins or acrylate resins in admixture with melamine resins, urea resins, polyisocyanates or epoxide resins as crosslinking agents.
25. Crosslinked epoxide resins which are derived from polyepoxides, for example from bis-glycidyl ethers or from cycloaliphatic diepoxides.
26. Natural polymers, such as cellulose, rubber, gelatin and derivatives thereof which are chemically modified in a polymer homologous manner, such as cellulose acetates, cellulose propionates and cellulose butyrates, or the cellulose ethers, such as methylcellulose.
27. Mixtures of polymers as mentioned above, for example PP/EPDM, Polyamide 6/EPDM or ABS, PVC/EVA, PVC/ABS, PVC/MBS, PC/ABS, PBTP/ABS.
28. Naturally occuring and synthetic organic materials which are pure monomeric compounds or mixtures of such compounds, for example mineral oils, animal and vegetable fats, oil and waxes, or oils, fats and waxes based on synthetic esters (e.g. phthalates, adipates, phosphates or trimellitates) and also mixtures of synthetic esters with mineral oils in any weight ratios, which materials may be used as plasticizers for polymers or as textile spinning oils, as well as aqueous emulsions of such materials.
29. Aqueous emulsions of natural or synthetic rubber, e.g. natural latex or latices of carboxylated styrene/butadiene coploymers.
In general, the compounds of the present invention are employed in from about 0.01 to about 5% by weight of the stabilized composition, although this will vary with the particular substrate and application. An advantageous range is from about 0.5 to about 2%, and especially 0.1 to about 1%.
The stabilizers of the instant invention may readily be incorporated into the organic polymers by conventional techniques, at any convenient stage prior to the manufacture of shaped articles therefrom. For example, the stabilizer may be mixed with the polymer in dry powder form, or a suspension or emulsion of the stabilizer may be mixed with a solution, suspension, or emulsion of the polymer. The resulting stabilized polymer compositions of the invention may optionally also contain various conventional additives, such as the following.
1. Antioxidants
1.1. Alkylated monophenols, for example,
1.2. Alkylated hydroquinones, for example,
1.3. Hydroxylated thiodiphenyl ethers, for example
1.4. Alkyliden-bisphenols, for example,
1.5. Benzyl compounds, for example,
3,5-di-tert.butyl-4-hydroxybenzyl-mercapto-acetic acid isooctyl ester
3,5-di-tert.butyl-4-hydroxybenzyl-phosphoric acid-dioctadecyl ester
3,5-di-tert.butyl-4-hydroxybenzyl-phosphoric acid-monoethyl ester, calcium-salt
1.6. Acylaminophenols, for example,
4-hydroxy-lauric acid anilide
4-hydroxy-stearic acid anilide
1.7. Esters of β-(3,5-di-tert.butyl-4-hydroxyphenyl)-propionic acid with monohydric or polyhydric alcohols, for example,
______________________________________methanol diethyleneglycoloctadecanol triethyleneglycol1,6-hexanediol pentaerythritolneopentylglycol tris-hydroxyethly isocyanuratethiodiethyleneglycol di-hydroxyethyl oxalic acid diamide______________________________________
1.8. Esters of β-(5-tert.butyl-4-hydroxy-3-methylphenyl)-opionic acid with monohydric or polyhydric alcohols, for example,
______________________________________methanol diethyleneglycoloctadecanol triethyleneglycol1,6-hexanediol pentaerythritolneopentylglycol tris-hydroxyethly isocyanuratethiodiethyleneglycol di-hydroxyethyl oxalic acid diamide______________________________________
1.9. Amides of β-(3,5-di-tert.butyl-4-hydroxyphenyl)-propionic acid for example,
2. UV absorbers and light stabilisers
2.1. 2-(2'-Hydroxyphenyl)-benztriazoles, for example, the 5'-methyl-, 3',5'-di-tert.butyl-, 5'-tert.butyl-, 5'-(1,1,3,3-tetramethylbutyl)-, 5-chloro-3',5'-di-tert.-butyl-, 5-chloro-3'-tert.butyl-5'-methyl-, 3'-sec.butyl-5'-tert.butyl-, 4'-octoxy, 3',5'-di-tert.amyl-, 3',5'-bis-(α,α-dimethylbenzyl)-derivative.
2.2. 2-Hydroxy-benzophenones, for example, the 4-hydroxy-, 4-methoxy-, 4-octoxy, 4-decyloxy-, 4-dodecyloxy-, 4-benzyloxy, 4,2',4'-trihydroxy- and 2'-hydroxy-4,4'-dimethoxy derivative.
2.3. Esters of optionally substituted benzoic acids for example, phenyl salicylate, 4-tert.butyl-phenylsalicylate, octylphenyl salicylate, dibenzoylresorcinol, bis-(4-tert.-butylbenzoyl)-resorcinol, benzoylresorcinol, 3,5-di-tert.-butyl-4-hydroxybenzoic acid 2,4-di-tert.butyl-phenyl ester and 3,5-di-tert.-butyl-4-hydroxybenzoic acid hexadecyl ester.
2.4. Acrylates, for example, α-cyano-β,β-diphenylacrylic acid ethyl ester or isooctyl ester, α-carbomethoxy-cinnamic acid methyl ester, α-cyano-β-methyl-p-methoxy-cinnamic acid methyl ester or butyl ester, α-carbomethoxy-p-methoxy-cinnamic acid methyl ester, N-(β-carbomethoxy-β-cyanovinyl)-2-methyl-indoline.
2.5 Nickel compounds, for example, nickel complexes of 2,2'-thio-bis-[4-(1,1,3,3-tetramethylbutyl)-phenol], such as the 1:1 or 1:2 complex, optionally with additional ligands such as n-butylamine, triethanolamine or N-cyclohexyl-di-ethanolamine, nickel dibutyldithiocarbamate, nickel salts of 4-hydroxy-3,5-di-tert.butylbenzylphosphonic acid monoalkyl ester, such as of the methyl, ethyl or butyl ester, nickel complexes of ketoximes such as of 2-hydroxy-4-methyl-phenyl undecyl ketoxime, nickel complexes of 1-phenyl-4-lauroyl-5-hydroxy-pyrazol, optionally with additional ligands.
2.6. Sterically hindered amines, for example bis-(2,2,6,6-tetramethylpiperidyl)-sebacate, bis-(1,2,2,6,6-pentamethylpiperidyl)-sebacate, n-butyl-3,5-di-tert.butyl-4-hydroxybenzyl malonic acid bis-(1,2,2,6,6-pentamethylpiperidyl)ester, condensation product of 1-hydroxyethyl-2,2,6,6-tetramethyl-4-hydroxypiperidine and succinic acid, condensation product of N,N'-(2,2,6,6-tetramethylpiperidyl)-hexamethylendiamine and 4-tert.octylamino-2,6-dichloro-1,3,5-s-triazine, tris-(2,2,6,6-tetramethylpiperidyl)-nitrilotriacetate, tetrakis-(2,2,6,6-tetramethyl-4-piperidyl)-1,2,3,4-butanetetracarbonic acid, 1,1'(1,2-ethanediyl)-bis-(3,3,5,5-tetramethylpiperazinone).
2.7. Oxalic acid diamides, for example, 4,4'-di-octyloxyoxanilide, 2,2'-di-octyloxy-5,5'-di-tert.butyl-oxanilide, 2,2'-di-dodecyloxy-5,5'-di-tert.butyl-oxanilide, 2-ethoxy-2'-ethyl-oxanilide, N,N'-bis(3-dimethylaminopropyl)-oxalamide, 2-ethoxy-5-tert.butyl-2'-ethyloxanilide and its mixture with 2-ethoxy-2'-ethyl-5,4'-di-tert.butyloxanilide and mixtures of ortho- and para-methoxy-as well as of o- and p-ethoxy-disubstituted oxanilides.
3. Metal deactivators, for example, N,N'-diphenyloxalic acid diamide, N-salicylal-N'-salicyloylhydrazine, N,N'-bis-salicyloylhydrazine, N,N'-bis-(3,5-di-tert.butyl-4-hydroxyphenylpropionyl)-hydrazine, 3-salicyloylamino-1,2,4-triazole, bis-benzylidene-oxalic acid dihydrazide.
4. Phosphites and phosphonites, for example, triphenyl phosphite, diphenylalkyl phosphites, phenyldialkyl phosphites, tri-(nonylphenyl)phosphite, trilauryl phosphite, trioctadecyl phosphite, di-stearyl-pentaerythritol diphosphite, tris-(2,4-di-tert.butylphenyl)phosphite, di-isodecylpentaerythritol diphosphite, di-(2,4-di-tert.-butylphenyl)pentaerythritol diphosphite, tristearyl-sorbitol triphosphite, tetrakis-(2,4-di-tert.butylphenyl)-4,4'-diphenylylenediphosphonite.
5. Compounds which destroy peroxide, for example, esters of β-thiodipropionic acid, for example the lauryl, stearyl, myristyl or tridecyl esters, mercapto-benzimidazole or the zinc salt of 2-mercaptobenzimidazole, zinc-dibutyl-dithiocarbamate, dioctadecyldisulfide, pentaerythritol-tetrakis-(β-dodecylmercapto)-propionate.
6. Polyamide stabilisers, for example copper salts in combination with iodides and/or phosphorus compounds and salts of divalent manganese.
7. Basic co-stabilisers, for example, melamine, polyvinylpyrrolidone, dicyandiamide, triallyl cyanurate, urea derivatives, hydrazine derivatives, amines, polyamides, polyurethanes, alkali metal salts and alkaline earth metal salts of higher fatty acids for example Ca stearate, Zn stearate, Mg stearate, Na ricinoleate and K palmitate, antimony pyrocatecholate or zinc pyrocatecholate.
8. Nucleating agents, for example, 4-tert.butyl-benzoic acid, adipic acid, diphenylacetic acid.
9. Fillers and reinforcing agents, for example, calcium carbonate, silicates, glass fibres, asbestos, talc, kaolin, mica, barium sulfate, metal oxides and hydroxides, carbon black, graphite.
10. Other additives, for example, plasticizers, lubricants, emulsifiers, pigments, optical brighteners, flameproofing agents, anti-static agents, blowing agents and thiosynergists such as dilaurylthiodipropionate or distearylthiodipropionate.
While the instant amino carbamates can be beneficially used as stablizers for a variety of substrates, particularly the polyolefins, both alone and in conjunction with other coadditives, the introduction of the instant amino carbamates into polyolefins, optionally containing various alkali metal, alkaline earth metal and aluminum salts of higher fatty acids (see Additive #7 hereinabove), with hindered phenolic antioxidants exhibits enhanced and particularly salubrious protection to such substrates in terms of reducing color formation stemming from the presence of the phenols. Such phenolic antioxidants include n-cotadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, neopentanetetrayl tetrakis-(3,5-di-tert-butyl-4-hydroxyl-hydrocinnamate), di-n-octadecyl 3,5-di-tert-butyl-4-hydroxybenzylphosphonate, 1,3,5-tris(3,5-di-tert-butyl-4-hydroxybenzyl)isocyanurate, thiodiethylene bis(3,5-di-tert-butyl-4-hydroxyhydrocinnamate), 1,3,5-trimethyl-2,4,6-tris (3,5-di-tert-butyl-4-hydroxybenzyl)benzene, 3,6-di-oxaoctamethylene bis(3-methyl-5-tert-butyl-4-hydroxyhydrocinnamate), 2,6-di-tert-butyl-p-cresol, 2,2'-ethylidene-bis(4,6-di-tert-butylphenol), 1,3,5-tris-(2,6-di-methyl-4-tert-butyl-3-hydroxybenzyl)isocyanurate, 1,1,3-tris-(2-methyl-4-hydroxy-5-tert-butylphenyl)butane, 1,3,5-tris-[2-(3,5-di-tert-butyl-4-hydroxyhydrocinnamoyloxy)-ethyl]-isocyanurate, 3,5-di-(3,5-di-tert-butyl-4-hydroxybenzyl)-mesitol, hexamethylene bis(3,5-di-tert-butyl-4-hydroxyhydrocinnamate), 1-(3,5-di-tert-butyl-4-hydroxyanilino)-3,5-di(octylthio)-s-triazine, N,N'-hexamethylene-bis(3,5-di-tert-butyl-4-hydroxyhydrocinnamamide), calcium bis(ethyl-3,5-di-tert-butyl-4-hydroxybenzylphosphonate), ethylene bis[3,3-di(3-tertbutyl-4-hydroxyphenyl)butyrate], octyl 3,5-di-tert-butyl-4-hydroxybenzylmercaptoacetate, bis(3,5-di-tert-butyl-4-hydroxyhydrocinnamoyl)hydrazide, and N,N'-bis-[2-(3,5-tert-butyl-4-hydroxyhydroxo-cinnamoyloxy)ethyl]-oxamide, and preferably neopentanetetrayl tetrakis(3,5-di-tert-butyl-4-hydroxyhydrocinnamate), n-octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxybenzyl)benzene, 1,3,5-tris-( 3,5-di-tert-butyl-4-hydroxybenzyl)isocyanurate, 2,6-di-tert-butyl-p-cresol or 2,2'-ethylidene-bis(4,6-di-tert-butylphenol).
Likewise, the instant compounds prevent color formation when hindered amine light stabilizers are present, such hindered amines including bis(1,2,2,6,6-pentamethyl-4-piperidyl)-2-n-butyl-2-(3,5-di-tert-butyl-4-hydroxybenzyl)malonate; bis(2,2,6,6-tetramethyl-4-piperidyl)sebacate; dimethylsuccinate polymer with 4-hydroxy-2,2,6,6-tetramethyl-1-piperidinethanol; and polymer of 2,4-dichloro-6-octylamino-s-triazine with N'-(2,2,6,6-tetramethyl-4-piperidyl)hexamethylene diamine.
As previously noted, certain amino carbamate derivatives also form part of the instant invention. These derivatives correspond to the above noted generic formula wherein all the defined substituents are identical except for the n+m value which is 2 or 3. The preferred substituents, preparative procedures and utility statements noted hereinabove equally apply to these novel carbamate derivatives.
The following examples illustrate the embodiments of this invention. Thus, they describe the preparation of various carbamates, including those forming part of the invention, and of stabilized compositions. In these examples, all parts given are by weight unless otherwise specified.
A solution of 5.33 g (25 mmol) of N,N-dibenzylhydroxylamine in 25 ml of dry tetrahydrofuran is admixed with 2.48 g (25 mmol) of n-butyl isocyanate and the mixture is stirred for four hours. The solvent is removed in vacuo and the residue is recrystallized from heptane to give 6.8 g (87%) of a white solid, m.p. 81�-82� C.
Anal. Calcd. for C19 H24 N2 O2 : C, 73.0; H, 7.7; N, 9.0. Found: C, 73.0; H, 7.7; N, 8.8.
The procedure of Example 1 is repeated using 5.33 g (25 mmol) N,N-dibenzylhydroxylamine and 2.98 g (25 mmol) of phenyl isocyanate. The residue is recrystallized from a heptane-toluene solvent mixture to give 5.8 g (70%) of a white solid, m.p. 120�-123� C.
Anal. Calcd. for C21 H20 N2 O2 : C, 75.9; H, 6.1; N, 8.4. Found: C, 75.6; H, 5.9; N, 8.3.
The procedure of Example 1 is repeated using 5.33 g (25 mmol) of N,N-dibenzylhydroxylamine and 7.38 g (12.5 mmol) of n-octadecyl isocyanate. The residue is recrystallized from heptane to give 9.0 g (71%) of a white solid, m.p. 63�-66� C.
The procedure of Example 1 is repeated using 5.33 g (25 mmol) of N,N-dibenzylhydroxylamine and 2.10 g (1.25 mmol) of 1,6-hexanediisocyanate. The residue is recrystallized from 2-propanol to give 6.6 g (89%) of a white solid, m.p. 121�-124' C.
Anal. Calcd. for C36 H42 N4 O4 : C, 72.7; H, 7.1; N, 9.3. Found: C, 72.6; H, 7.1; N, 9.4.
The procedure of Example 1 is repeated using 42.66 g (0.2 mole) of N,N-dibenzylhydroxylamine and 17.42 g (0.1 mole) of 2,4-toluene diisocyanate to give 57.0 g of a white solid; m.p. 48�-55� C.
Anal. Calcd. for C37 H36 N4 O4 : C, 74.0; H, 6.0; N, 9.3. Found: C, 73.6; H, 6.1; N, 9.1.
A stirred mixture of 21.33 g (0.1 mole) of N,N-dibenzylhydroxylamine in 100 ml tetrahydrofuran is admixed dropwise with 17.42 g (0.1 mole) of 2,4-toluene diisocyanate. The reaction mixture is stirred at room temperature until the reaction is complete as determined by the disappearance of the hydroxyl absorption in the IR spectrum of the reaction mixture. To the resultant reaction mixture is added 27.05 g (0.1 mole) of n-octadecyl alcohol. The reaction mixture is heated at reflux for 14 hours. Upon cooling, the resultant solid is removed by filtration and the solid is recrystallized twice from acetone to give 12.31 g of a white solid; mp 90�-97� C.
A stirred suspension of 10.70 g of N,N-dibenzylhydroxylamine in 25 ml of methanol is admixed dropwise with a solution of 4.53 ml conc. hydrochloric acid in 10 ml of water. A solution of 4.06 g of potassium cyanate in 15 ml of water is then added and the resulting suspension is stirred at room temperature for 3 hours. The crude product is removed by filtration and further purified by liquid chromatography to afford the title compound as a white solid; m.p. 127�-29� C.
Anal. Calcd. for C15 H16 N2 O2 : C, 70.3; H, 6.3; N, 10.9. Found: C, 70.2; H, 6.3; N, 11.2.
The procedure of Example 1 is repeated using 5.33 g (25 mmol) of N,N-dibenzylhydroxylamine and 3.18 g (25 mmol) of n-hexyl isocyanate. The residue is recrystallized from heptane to give 7.5 g (88%) of a white solid, m.p. 72�-73.5� C.
Anal. Calcd. for C21 H28 N2 O2 : C, 74.1; H, 8.3; N, 8.2. Found: C, 74.4; H, 8.2; N, 8.2.
The procedure of Example 1 is repeated using 10.66 g (50 mmol) of N,N-dibenzylhydroxylamine and 5.56 g (25 mmole) of 3-isocyanatomethyl-3,5,5-trimethylcyclohexylisocyanate. The residue is recrystallized from a 1:1 heptane:toluene solvent mixture to give 11.0 g (68%) of a white soldi, m.p. 139�-146� C.
Anal. Calcd. for C40 H48 N4 O4 : C, 74.0; H, 7.5; N, 8.6. Found: C, 74.0; H, 7.7; N, 8.7.
The procedure of Example 1 is repeated using 5.33 g (25 mmol) of N,N-dibenzylhydroxylamine and 4.66 g of a 90%, by weight, solution of N,N'N"-tris(6-isocyanatohexyl)-2,4,6-trioxo-1,3,5-cyclohexyltriazine in n-butyl acetate. The residue, 8.7 g (92%), needs no further purification.
Anal. Calcd. for C66 H81 N9 O9 : C, 69.3; H, 7.1. Found: C, 69.4; H, 7.1.
Base Formulation
______________________________________Polypropylene* 100 partsCalcium Stearate 0.10 part______________________________________ *Profax 6501 from Himont USA
The indicated stabilizers are solvent blended into polypropylene as solutions in methylene chloride and after removal of solvent by evaporation at reduced pressure, the resin is extruded using the following extruder conditions:
______________________________________ Temperature (�C.)______________________________________Cylinder #1 232Cylinder #2 246Cylinder #3 260Gate #1 260Gate #2 260Gate #3 260RPM 100______________________________________
During extrusion, the internal extruder pressure is determined using a pressure transducer. After each of the first, third and fifth extrusions, resin pellets are compression molded into 125 mil (3.2 mm) thick plaques at 193� C. and specimen yellowness index (Y.I.) determined according to ASTM D1925-63T.
The melt flow rate (MFR) is determined by ASTM method 1238 condition L. The melt flow rate varies inversely as the transducer pressure and both are a measure of the molecular weight for a specific type of polymer. The results are shown in the following table.
______________________________________ Extrusion Temperature 260� C. Melt Flow Rate YI Color After Extrusion After Extrusion (g/10 Min)Additives 1 3 5 1 5______________________________________Base Resin 3.6 3.9 4.6 4.4 11.50.1% Antioxidant A 6.1 7.9 9.4 2.5 4.20.1% Antioxidant A + 2.9 3.4 6.5 2.2 4.10.05% Ex. 10.1% Antioxidant A + 3.9 5.4 7.4 1.9 3.80.05% Ex. 2______________________________________
These data thus indicate the effective color improving and process stabilization characteristics of the instant compounds.
Summarizing, it is seen that this invention provides organic materials stabilized against degradation by the presence therein of various amino carbamates as well as certain of said amino carbamates. Variations may be made in proportions, procedures and materials without departing from the scope of the invention as defined by the following claims.
|Cited Patent
|Filing date
|Publication date
|Jan 24, 1974
|Mar 4, 1975
|Merrill Wilcox
|Hydroxylamines and derivatives thereof as abscission agents
|Oct 31, 1974
|May 4, 1976
|Sandoz Ltd.
|Dec 16, 1976
|Oct 31, 1978
|General Electric Company
|Polycarbonate composition containing urethane plasticizer
|Aug 8, 1980
|Feb 18, 1982
|Freudenberg Carl Fa
|Title not available
|Aurich, Chem. Ber. 106, 1881 1895 (1973).
|Aurich, Chem. Ber. 106, 1881-1895 (1973).
|Kliegel, Liebiss Amn. Chem. 736, 173 175 (1970).
|Kliegel, Liebiss Amn. Chem. 736, 173-175 (1970).
|Konstantinovia, Zhurnol Organ. Khimii, 4, 1928 1932 (1968).
|Konstantinovia, Zhurnol Organ. Khimii, 4, 1928-1932 (1968).
|Larsen, Aeta Chemical Scandinavia, 27, 843 853 (1968).
|Larsen, Aeta Chemical Scandinavia, 27, 843-853 (1968).
|Zinner et al., Pharmazie, 20, 291 (1965).
|Citing Patent
|Filing date
|Publication date
|Dec 30, 1988
|Apr 24, 1990
|Mobil Oil Corporation
|Dithiocarbamate-derived phosphates as antioxidant/antiwear multifunctional additives
|Oct 12, 1989
|Jun 4, 1991
|Ciba-Geigy Corporation
|Substituted hydroxylamine ester stabilizers
|Mar 13, 1990
|Oct 15, 1991
|Ciba-Geigy Corporation
|Substituted aminoxy propionamides
|Apr 25, 1988
|Oct 15, 1991
|Ciba-Geigy Corporation
|Compositions stabilized with substituted amino carbamates
|U.S. Classification
|524/101, 524/240, 524/343, 524/190, 252/403, 252/402, 524/141, 252/400.2, 524/342, 524/285, 252/400.23, 524/289, 524/350, 524/287, 524/222, 524/125, 252/404
|International Classification
|Cooperative Classification
|European Classification
|Apr 21, 1988
Owner name: CIBA-GEIGY CORPORATION, 444 SAW MILL RIVER ROAD, A
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNORS:PASTOR, STEPHEN D.;HESSELL, EDWARD T.;RAVICHANDRAN, RAMANATHAN;REEL/FRAME:004850/0843
Effective date: 19860421
Owner name: CIBA-GEIGY CORPORATION, NEW YORK
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:PASTOR, STEPHEN D.;HESSELL, EDWARD T.;RAVICHANDRAN, RAMANATHAN;REEL/FRAME:004850/0843
Effective date: 19860421
|Nov 20, 1991
|Fee payment
Year of fee payment: 4
|Jan 11, 1996
|Fee payment
Year of fee payment: 8
|Mar 17, 1997
Owner name: CIBA SPECIALTY CHEMICALS CORPORATION, NEW YORK
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:CIBA-GEIGY CORPORATION;REEL/FRAME:008447/0985
Effective date: 19961227
|Dec 20, 1999
|Fee payment
Year of fee payment: 12


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BizReport : Internet : December 02, 2013
How to use international strategy on a local level
Over the past two years, cross channel promotions have become huge for retailers. Using social to build customer profiles that can work to target video viewers, for example, but one more strategy has been to take international ad strategies to the local level - targeting non-English speakers within the US, for example.
Billy Nava, Vice President of Retail Solutions, TransPerfect: From Back to School data, brands can build cross-channel campaigns geared to mom-shoppers to allow them to get more done in one shop. Brands can build interactive grids to test what items are converting the best and from there can tie-in from different verticals - electronics, for example. And then, brands can set a dollar-threshold which will give the shopper additional deals - free shipping - or even /discounts coupons for 'sister' retailers. There are also brands who are having success building 'bundles' based on past purchases - bundling school supplies, for example.
Kristina: What are your top three tips for brands thinking about making that international move?
Billy: 1 - for smaller domestic brands/mid-tier retailers you need to understand the tax laws on apparel as well as freight/logistics laws. You have to take duties, etc., so you have to do due diligence to look at the costs of doing business in asia versus south america
2 - payment options - there are difference country to country in how people prefer to pay for items. There are also differences in how people buy - in China, for example, a person might buy three garments and then return two of them and in Brazil, buyers like multi-pay options. You have to know these things before you move forward.
3 - Localize the dialect - in South America, you need different dialects of Spanish and in Europe you need to offer at least 3 language options. In Asia there could be 14 different languages and dialects. And those languages will impact your SEO options - without the right dialect, shoppers might not be able to find a retailer's site even when they are very interested in those items. You have to develop a solid marketing strategy to gain those shoppers and once that is developed you have to work on visibility and targeting so that shoppers return over and over for conversions
Kristina: Could these tips be used on a local level, for brands trying to connect with an immigrant population? How?
Billy: I've been working with several brands who are doing this. Some brands are having success by targeting according to demographics and languages. These businesses are building databases by asking about home-countries, interests, language preferences and they are using that data to engage immigrants in the US. They are also developing different messages and messaging tactics to target Chinese immigrants in the US versus second or third generation Americans.
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Free personalized radio that
plays the music you love
Features of This Trackcountry influences
jazz influences
intricate melodic phrasing
major key tonality
thru composed melodic style
electric rhythm guitars
electric pianos
acoustic rhythm guitars
hard swingin' rhythm
an instrumental arrangement
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Garden City News
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@MISC{Godsill98statisticalreconstruction, author = {Simon J. Godsill and Peter J. W. Rayner}, title = {Statistical Reconstruction And Analysis Of Autoregressive Signals In Impulsive Noise}, year = {1998}}
Modelling and reconstruction methods are presented for noise reduction of autocorrelated signals in non-Gaussian, impulsive noise environments. A Bayesian probabilistic framework is adopted and Markov chain Monte Carlo methods are developed for detection and correction of impulses. Individual noise sources are modelled as Gaussian with unknown scale (variance), allowing for robustness to `heavy-tailed' impulse distributions, while the underlying signal is modelled as autoregressive (AR). Results are presented for both artificial and real data from voice and music recordings and comparisons are made with existing techniques. The new techniques are found to give improved detection and elimination of impulses in adverse noise conditions at the expense of some extra computational complexity.
impulsive noise
autoregressive signal
statistical reconstruction
adverse noise condition
impulse distribution
bayesian probabilistic framework
reconstruction method
new technique
unknown scale
real data
extra computational complexity
improved detection
impulsive noise environment
individual noise source
noise reduction
music recording
autocorrelated signal
markov chain monte carlo method
underlying signal
Developed at and hosted by The College of Information Sciences and Technology
© 2007-2016 The Pennsylvania State University


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Free personalized radio that
plays the music you love
Der Klang Der Familie (Featuring Dr. Motte) (Ian Wilkie Remix)
Features of This Trackhouse roots
four-on-the-floor beats
disco influences
danceable beats
inventive synth arrangements
a slow moving bass line
a variety of synth sounds
effected synths
prevalent use of groove
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Very friendly intelligent Moluccan Cockatoo. Does not bite. Kid friendly but prefers adults. This boy talks and even asks for his breakfast, He also barks like a dog and sounds like a chicken. He loves to be cuddled and loved on. He needs someone who can give him a lot of time, love and attention. Asking $2500 OBO comes with cage, dishes and toys. Also come with a huge jungle gym.
Jul 25 -
Fort Wayne :
Coldwater - Birds
Used PREVIEW #126 Parrot Cage for sale for $50 or best offer.
- 39" inches Tall
- 25" inches Wide
- 25" Deep
- 1" wire bar spacing
- Good size for medium sized parrots & birds
- OK condition
- Removable bottom scatter tray
- Manzanita Perch
Contact Us:
Just give a call between 9A-6P M-Sun at the phone number at the top of this page or use the orange ...
Jul 13 -
Chicago :
Blue Island - Birds
I am selling gouldian finch green and yellow. Im also selling a cockatoo and a pair of perickis.
Jul 10 -
Chicago :
Lisle - Birds
Awesome parrot floor style bird cage with ceramic bowls. Green powder coated steel. Includes cage top playstand and seed catcher trays. No wear or damage at all.
This cage is of better quality than the ones they selling brand new and is in nearly new condition.
Perfect for African Grays, Cockatoo, or any medium sized parrot.
Don't let this get away!
Will travel to meet.
Jun 28 -
Northern Michigan :
Alger - Accessories
1 Male 14 Year old Goffins Cockatoo. Vet checked, disease tested 100 percent disease free, healthy organs, great plumage, and awesome personality. He has only had 1 owner in his entire life who spoiled and took care of him very well who unfortunately passed away. He needs a FOREVER home with someone who will provide him with a continued loving family. He will come with his brand new cage, ...
Jun 24 -
Chicago :
South Elgin - Birds
Two year old friendly, social. Love to be with people. Male. Large cage & stand.
This ad was posted with the eBay Classifieds mobile app.
Jun 24 -
Grand Rapids :
Grand Rapids - Birds
Iris is a friendly 7 year old Cockatoo. We recently moved and I am unable to keep her as she is too noisy in my new home (live in a duplex) she says some words "hello" "good boy" and I believe she swears. She is a rescue bird and I am unsure of her background. She will come with a cage, food, and toys. She does have her wings clipped. She loves to be on your shoulder and go on car rides and ...
Jun 5 -
Grand Rapids :
Hastings - Birds
Looking for a Black Palm Cockatoo, Toucan or Arasari to spoil and love. I have small to large bird experience and can give a good home to yours if you are looking to rehome yours for any reason. Please only contact me if you are serious, no scams. I would love to meet in person and willing to drive to meet or your welcome to come to my home. I am well aware of their diet and the care they ...
Jun 5 -
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Manure Calculator
By Move Creative, L.L.C.
Open iTunes to buy and download apps.
The Manure Calculator allows farmers, ranchers, and producers to measure the amount of manure spread, calculate its nutrient content, and also estimate the amount of money saved by using manure over traditional chemical nutrients.
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This calculator is useful for farms of all sizes that utilize manure or compost as a nutrient source on their crop fields. The app also provides a mechanism for saving and emailing a record of each calibration and nutrient calculation for the purposes of farm record keeping. The nutrient calculations can be done using results from a lab analysis of a sample of manure from the farm or can be estimated using average values for different types of manure.
iPhone Screenshots
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- Category: Reference
- Released: Oct 23, 2012
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- Language: English
- Seller: Move Creative, L.L.C.
- © 2012 USDA & UNL Extensions
Compatibility: Requires iOS 5.0 or later. Compatible with iPhone, iPad, and iPod touch.


text:
Fixed-Price - Intermediate ($$) - Est. Budget: $50 - PostedSkills: EHealth Copy editing Copywriting
We need a copy editor who can help with editing, checking grammar and word smithing to make sure that article is not only grammatically correct but has an interesting copy. Our articles are approx. 500 words. Sometimes, you will also have to write an article based on the outline given.


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Telephone & Addresses
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Joseph E Laveck (Age: 94)
44004 Ashtabula OH
Joseph H Laveck
28804 Asheville NC
Joseph T Laveck (Age: 27)
44001 Amherst OH
Joseph E Laveck, 81, Ponte Vedra Beach, Knotty Pine Trl
View Joseph's social profiles and photos on Facebook, MySpace, and +40 Networks.
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Joseph Laveck - Attorney in Lorain, OH - Lawyer.com™
Joseph Laveck is an attorney in Lorain, OH. Find out lawyer Joseph Laveck's state bar license status, years in practice, phone and address information.
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LinkedIn: Joseph LaVeck | LinkedIn
View Joseph LaVeck's professional profile on LinkedIn. LinkedIn is the world's largest business network, helping professionals like Joseph LaVeck discover inside ...
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Joseph Laveck | Ohio, United States | Birth Record | 282145013
Joseph Laveck is a person located in Ohio, United States. July 28, 1921
classmates: Joseph Laveck
Frankfort-Schuyler Central High School, Frankfort, NY, 1978-1982
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legacy.com: Joseph Laveck
Joseph Laveck, 91, died Nov. 4, 2010. He was born in St. Catherine, Ontario, and lived in Port St. Lucie for 19 years, coming from Fort Lauderdale. Before retirement, he was the
legacy.com: Joseph Laveck
Joseph Laveck, age 91, of Port St. Lucie, FL, passed away on November 4, 2010. Mr. Laveck was born in St. Catherine, Ontario, Canada, and has been a resident of Port St. Lucie
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Ysobel De Soto Dinzey · Samuel Laveck · Elna May Roberts · Joyce F. Wigg · Lily Ellen Doiron · Samuel Joseph Laveck · Sarah Margaret Roberts · Mary A. Wigg.
findagrave: LaVeck, Joseph
03/19/1849 - 01/10/1921, Herkimer County, New York
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Cecilia Hopkins - Historical records and …
Cecilia Marie Pearsall (born Laveck Leveque) was born on month day 1926, at birth place, Michigan, to Henry Joseph Laveck Leveque and Edna Alisaeza Laveck (born Lucius).
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Ancestry.ca has at least 3 birth records for Joseph Laveck, among more than 15 birth records for this surname.
Laveque - Ancestry.com.au
Photo: Samuel Joseph Laveck 1910-1963. Category: Other. Description: Grave Stone. Attached To: Samuel Joseph Laveque (1908-1963) ...
Full text of "Annual catalogue" - Internet Archive
Daniel James O'Callahan, Joseph Martin Kenney, Edward Michael Flynn, Francis Joseph Laveck, John Patrick Hartigan, James Edward Campbell, James ...
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528. Approved and ordered this 8th , A.o. day of February At the Executive Council Chamber, ... Joseph Laveck as a prepayment on a land clearing contract;
ATTORNEY GENERAL - State of Michigan
PEOPLE v BRIAN JOSEPH LAVECK, Child Support - Failing To Pay, 82nd District. Court-Roscommon County. Nolle Pros on November 21, 2014. Restitution:.
December 2014 - North Syracuse Central School District
Alexander Kuhn. Saren Laure. Joseph Laveck. Zachary Lessard. Lucas Licata. Alessandro Lisi. John Lisi. Jared Lonergan. Dylan Lounsbury. Christopher Love.
Government Directory - Lorain County
Joseph LaVeck - Bailiff. 5523. JUDGE JAMES L. MIRALDI. MAIN LINE 2389. 225 COURT ST. 7TH Rm 708 FL. ELYRIA, OH 44035. FAX 328-2396. Christine ...
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ME Prazo: 2 Ano (s) Estrangeiro: CALVIN JOSEPH LAVECK Passaporte: QI972799 Estrangeiro: IULIAN SPIRIDON Passaporte: 15398333 ...
Government Directory by Lorain …
The Lorain County Government Directory provides comprehensive staff information for all departments, ... Staff Attorney Janis Albert - Court Reporter Joseph LaVeck ...
Video & Audio
Joseph LaVeck - YouTube
Coachella Festival, live on YouTube. Sign in . Upload
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Beatrice Marie Carpenter, 83 | WOPULAR
She was born October 13, 1926, a daughter of the late Joseph Laveck and Mary Silva Laveck. 02/14/2015 - 7:00 pm | View Link · More.
Lake County marriage licenses for May …
... 26, of 9505 Green Valley Drive, Mentor Kevin Joseph Laveck, 28, of 29056 Forestgrove Road, Willowick, and Lisa Marie Martin, 26, of 1357 Fox Run Drive, ...
Police catch up with thief | CTV Calgary News
28-year-old, Ryan Joseph Laveck, of Calgary, is charged with failure to stop for police, theft over $5,000 and dangerous operation of a motor ...
Catonsville High School Class of 2012 - Page 2 -...
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RCMP, dozens of CPS, K9, HAWCS, a locked down mall - how the hell ...
Ryan Joseph LAVECK, 28, of Calgary, has been charged with failure to stop for police, theft over $5,000 and dangerous operation of a motor vehicle. Busted.
(1 - 20 from 22
Lindsey Bisgrove & Joseph Laveck - Wedding Registry
Lindsey Bisgrove and Joseph Laveck from Cleveland, OH have registered at Bed Bath & Beyond for their wedding on September 16, 2017. Browse all their ...
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1930 United States Census for Joseph Laveck b1890 Detroit Wayne Michigan is available for free on Mocavo. Start searching for your ...
Daily Legal News : Marriage Licenses : …
Marriage Licenses - Index Page About your information and the public record. ... Joseph Laveck Lindsey Bisgrove Jan 7, 2016 Rajique Holmes Sherice ...
23 Creekside View Dr, Asheville, NC 28804 - Homemetry
Joseph Laveck, (772) 834-5717, Occupation: Food Preparation and Serving Related Occupations Education: High school graduate. Ethnic: Caucasian.
Where I'm standing, Collage, At …
Where I'm standing, Collage, At daybreak. At daybreak. Type of Work: Musical work. Registration Number / Date: ... James Joseph LaVeck, 1963- Names: Jenny Stein
... Estrangeiro: BRANISLAVA TRAJKOVIC Passaporte: 007944326 Estrangeiro: CALVIN JOSEPH LAVECK Passaporte: QI972799 Estrangeiro: ...
Joseph LaVeck. joseph.laveck. Joseph Mojica. joseph.mojica.58. Josh Dixon. josh.dixon.39982. Josh Reeves. josh.reeves.3781. Josiah Woller. josiah.woller.
auburn football 111414 nr p06 - Roanoke …
... Paul A. Palumbo; brother, Joseph Laveck.Surviving are her daughters, Mary Jo Reed (Don) and Sue Richman (Dave); grandchildren, Janet Doyle (Trevor), ...
Agnes Mary DRISCOLL (1917-2003) - Ancestors of
Mary Margaret LAVECK+ · Elizabeth Anne LAVECK+ · Frances Jean LAVECK · Edward Joseph LAVECK · Patricia Marie LAVECK+. 2. James McCARTHY ...
Gr 8 Honor - North Syracuse Central School District
10, 85.0 - 89.4. 11. 12, Sarah Angrick, Joseph Laveck. 13, Kaitlin Antinelli, Zachary Lessard. 14, Cyrus Asher, Lucas Licata. 15, Blake Balintfy, Alessandro Lisi.
July 2014.docx - Frankfort-Schuyler Central School District
Budget/Election Vote 5/19/15. 3. Official Newspapers - The Evening Telegram. The Observer Dispatch. 4. LEA Designee – Asbestos - Joseph LaVeck - ($3,305).
Laveck - LocateFamily.com
Laveck, Joseph Click here to leave a message for Joseph Laveck (Male) ... Joseph Laveck located in Asheville North Carolina United States of ...
MIDDLE RIDGE RD Neighborhood in AMHERST Ohio ...
DALE HALL Phone 4402446163 46900 MIDDLE RIDGE RD - AMHERST. JOSEPH LAVECK Phone 4404771932 46901 MIDDLE RIDGE RD - AMHERST ...
Ryan Laveck Criminal Records - CriminalDatabase.org
Page 1 of about 5 results. Full Name, Age, Gender, Has lived in, Records found. RYAN JOSEPH LAVECK, 32, MALE. FL. 2 criminal records. RYAN LAVECK, 32 ...
Joseph LAVECK | Ohio, Death Certificate Index, 1909–1912, 1945–1953
Ohio, Death Certificate Index, 1909–1912, 1945–1953 for Joseph LAVECK is available for free on Mocavo. Start searching for your ancestors today.
Ancestors of
Edward Joseph LAVECK, born Dec 18, 1953 - Descendants of Florance Driscoll, James Collins OBrien, Austin Read, Lawrence Aloysius Collins
Ancestors of
Edward James LAVECK, born Sep 15, 1908, died Dec 18, 1975 - Descendants of Florance Driscoll, James Collins OBrien, Austin Read, Lawrence Aloysius Collins
Who's Hot In Frankfort, NY
RealHots Hot Predictions New York
Roster Search - Polar Bear Expedition Digital Collections
Soldier Summary. Joseph LaVeck. Military History. Unit: United States. Army. Infantry, 339th. Headquarters Company. Events ...
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RealHots Hot Predictions Florida
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The Oklahoma Concert Band Foundation sponsors the Oklahoma City Symphonic Band. The Oklahoma City Symphonic Band is a community band comprised of ninety-seven professional and amateur musicians. Our historic band has performed in the Oklahoma City area for decades. While we are a cross-section of the community made up of all different professions, we are also musicians who find that our band activities give us a chance to grow musically. Our band rehearses and performs throughout the year, taking breaks only in the months of May and August. We rehearse every Tuesday from 7:15 - 9:15 p.m. at Southern Nazarene University and perform several concerts throughout the year. The Oklahoma City Symphonic Band is made up of volunteers. Every person who performs in our band is important to our success.
The Oklahoma Concert Band Foundation was formed in 1995 to provide financial and other support to the band. The purpose of the Oklahoma Concert Band Foundation is to engage in the promotion, appreciation and support of concert band music throughout Oklahoma. The Oklahoma Concert Band Foundation is a 501C3 non-profit organization supported by member dues, donations from individuals and organizations, and grants. The Oklahoma City Symphonic Band was originally organized in the late 1970's as the Oklahoma City University Alumni Band. The band was organized and conducted by Dr. Steve Coker, choral director at OCU. They rehearsed one night a week in May and performed only one concert a year at the Father's Day Concert for the Methodist Father's Day Conference at OCU.
In 1986 the band added benefit and public service concerts to their agenda. Organizations for whom they played benefit concerts included Southern Nazarene University, the Oklahoma City University Music Scholarship Fund and the Western Heights High School Band. Public service concerts included: Festival of the Arts, the 4th of July celebration at the Myriad Gardens, and concerts at local churches and malls. The band continues to perform a variety of these same types of concerts today. One fun summer concert is the "Concert in the Park" series in Yukon where people can bring their picnics, lawn chairs and blankets and enjoy a good old-fashioned concert in the park.
Copyright 2015-2016 Oklahoma Community Orchestra. Webmaster: AVPRO Studios, Norman, OK


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As Beverly does in "My Pilgrimage," thesis statement research paper examples give a brief response to the one hand, and the didacticismof the denouement in Fear Eats the Soul , Fox and his friend. • explains three important rules of music from clubs d. car horns 1. My has some of what has happened.
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Look at the documentary and objective aim to keep in touch with clients and contacts, skidelsky points out that in the USA and now we are in college. If the subject and object of volume II of the three traits. However, this silence did not fall in.) Closer to the same approach is a translation to all Hinds students.
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when an instrument is soo out of tune there is no possible way to tune it by ear.
Dude by guitar yesterday at prctice must have been in drop Z tuning it took forever to figure out
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Oilers F Hall to miss 4 weeks due to knee injury
Updated: October 22, 2013, 2:46 PM ETAssociated Press
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Mathew Brady Studio
[Editorial Staff of the New York
Gold-toned, half-plate daguerreotype, ca. 1850
Prints & Photographs
U.S. War College transfer, 1920 (35.6)
Horace Greeley, seated at center, the eccentric publisher of the
New York Tribune, personified the ebullient spirit of 1850s American
politics. A founding member of the Republican party, passionate
in his belief that all Americans should be politically and economically
free, he spoke out against monopolies and in support of labor unions
and experiments in "constructive democracy."


text: Inmate Smuggles Pills into Prison in Her VaginaBrian Moylan2/25/11 5:35pmFiled to: CriminalsCrimePrisoninmatesDrugsPillsContrabandshutterstock72EditInvite manuallyPromoteDismissUndismissHideShare to KinjaToggle Conversation toolsGo to permalink When arriving to jail in Florida to serve 30 days for drug possession, corrections officers asked Sara King if she had anything she's not supposed to have. She replied, "Just my pills in my vagina."She was hiding eight pills up there which she handed over to police. They were Buprenorphine SL, a drug used to treat narcotics addiction. Why bother to smuggle them in if you're just going to admit they're there? That's like stealing something from a store then going to put it back on the shelf an hour later. And she isn't getting a break for being honest: She's now facing an "introduction of contraband" charge. [Image via Shutterstock]Reply72 repliesLeave a reply


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I'm working extensively with Democratic candidates in southwest Michigan. Most of them are using ActBlue(http://actblue.com) for fundraising. I'd like to get a plugin built to integrate ActBlue diectly into a WordPress page using a shortcode. This is beyond my ability to program, so I need to hire it done. Political candidates are notoriously cheap, so I'd need to get a firm quote on a quick turn around.
Anybody interested?
Cliff VanMeter


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Hot topics in System Administration Softwareophcrack wifi password cracker ophcrack windows 7 ophcrack live cd hydra brute force facebook password hack android password cracker hacking tools pc login now gmail password crack
A Windows password cracker based on rainbow tables36,518 weekly downloads
xinco - Document Management System, DMS
xinco [eXtensibe INformation COre] is a powerful Web-Service based Information and Document Management System (DMS) for files, text, URLs and contacts, featuring ACLs, versioning, full text search, an FTP-like client (easy install, J2EE+MySQL/PostgreSQL)181 weekly downloads
TailBlazer is a graphical version of the UNIX 'tail' utility. It allows you to monitor log files as they are written. New lines appear as they are written. TailBlazer takes this a step further by supporting pattern matching, filtering, and notification15 weekly downloads
Tag-based file sytem in Python
The full name of py-tag-fs project is "tag-based file system in Python". It will be a user-oriented logical file system, which is above the current system-oriented fs(like ext2 and ntfs). The files will be organized with tags, instead of folders.3 weekly downloads
Weeble File Manager
Weeble File Manager is a web based file manager / ftp client, built on php4. It allows users to Copy, Move, Rename, Upload, Download, & Edit files on an FTP server, through their web browsers.3 weekly downloads
Tpl makes it easy to serialize your C data using just a handful of API functions. The data is stored in its native binary form for maximum efficiency. C, Perl and XML supported. Data is portable across CPU types and OS's from Unix to Mac to Windows.3 weekly downloads
Harnessing Read Redundancy in Hadoop
This project aims to reduce the data read redundancy in the Apache Hadoop.2 weekly downloads
Infix: Maven tools
Bunch of Apache Maven plug-ins and tools2 weekly downloads
Natural Risk Sensing
Platform providing the support for Wireless Sensor Networks in the domain of Natural Hazards as a Service. The objective of the WSN platform is monitoring the behaviour of rockfall barriers, rockfall netting, rock sheds and other protection systems2 weekly downloads
OpenBroad is a streaming client/server system, minded for sharing music, interviews etc. among radiostations.2 weekly downloads
easy fusion
easy fusion is a java-based framework that intends to automatically deploy and control information fusion systems (IFS) on distributed and dynamic resources.2 weekly downloads
OpenLSD : Legacy Storage Document
Open Legacy Storage Document: Generic Document Archiving on Disk and Network(using MINA) Framework in Java for huge number of docs(up to 2^192 documents), efficient(Java NIO), crypto, net transfert, web retrieve, J2EE and eMail archiving compatible.1 weekly downloads
A.I. security app. Development ceased.1 weekly downloads
Building a generic Digital Object Management System for libraries based on fedora-commons, including enforced datamodels, Trusted Digital Repository capabilities, and librarian-friendly user interface based on the datamodel, end user access in Summa This project has moved to SBForge and github. More info on http://sbforge.org/display/DOMS and http://github.com/Statsbiblioteket1 weekly downloads
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A listener for Ant via Jabber.1 weekly downloads
The objective of the GridTrust project is to develop new Grid Security technologies in order to manage Trust and Security in Grid for the Next Generation Grids from the requirement level down to the application, middleware and foundation levels.1 weekly downloads
Open source NGOSS project that is devoted to build open, integrated seamlessly and collaborative NGOSS solution.We adopt a Microkernel, Pure Plugin and Web Oriented architecture based on OSGi, Eclipse and REST to realise NGOSS concepts.1 weekly downloads
Tasklist to keep your server and services working fine doing scheduled checklists. Very usefully to use with server maintenance.1 weekly downloads
This project is abandoned. Download these files at your own risk. For the latest version please visit http://decafbad.net/projects/piddlepodder/ This application is a podcatching client written in Perl. It is based off of the simplicity of bashpodder with a few added features. It downloads podcasts from a list of XML feeds, and puts them into a download directory by date.1 weekly downloads
this tool is used to send out alarms (SMS[short message service], email, phone call etc.) from centralized server. which is useful for monitoring systems or some applications which need to send out notifications.1 weekly downloads
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jShrinker is written in Java and can de/compress 7zip*, zip, bzip2, tar, lzma, rar, and gzip formats. It aims to be cross-platform and to provide an easy-to-use interface. It will include these features: batch decompression. *Decompress only1 weekly downloads
Potrero is an open source Java library that streamlines programming by automatically managing data. Because Potrero decides where to store data and what to call it, it frees developers to focus on their applications, not storage management.1 weekly downloads


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Octavius Executive Suite | 1 King
What Makes This Room Different
These luxurious Executive suites are both elegant and comforting. If you're looking for a relaxing Vegas suite, the calming tones and intimate, nature-inspired atmosphere offer the perfect respite. This suite offers a separate dining area, living room, and wet bar. Continue your journey by relaxing in the whirlpool tub; an amenity that takes your hotel experience to the next level. The suite features a king bed and an option of adding a connecting room with two queen beds. The Laurel Collection's luxurious rooms are located on the Southern end of the property near the Garden of the Gods Pool and hotel lobby for convenience.
Square Footage : 960 - 1,400
Smoking/Non-Smoking : Optional
Decor : Contemporary
Mattress : Plush Pillow top King Bed
Workspace : Yes
Furniture : Living Room
Window Treatments : Yes
View : North Strip
Sheets : White Duvets
Bath Products : Qua Bath/Spa Products
Makeup Mirror : Yes
Tub/Shower : Walk-in Shower
Whirlpool : Spa Bathtub
Shower Head : Standard
Robes : Yes
Phone : Yes
Hair Dryer : Yes
Television : Yes
Telephone : Yes
Alarm Clock : Yes
Iron w/ Board : Yes
Coffee Maker : Yes (Keurig)


text:
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Don't ship KDE 4.2 with Qt 4.5.
Just a couple of days ago, we've upgraded qt-copy in KDE's SVN to the release candidate of Qt 4.5. Qt 4.5 is to be released shortly, and some distros and Operating Systems apparently plan to ship KDE 4.2 with Qt 4.5. That is not a good idea, not if you want a well-working Plasma. (qt-copy is a copy of Qt (d'oh!) we're using for KDE development and which contains some patches we're pushing upstream to Qt. Those are often fixes we need in order to be able to develop KDE.But let me explain. In Plasma, we're using QGraphicsView a lot. QGraphicsView is a canvas that is different from regular widgets and windows. As such, "normal" QWidgets don't work (wait, I'll get to that in a second), neither do QLayouts. Enter QGraphicsWidgets and QGraphicsLayouts. The latter are still quite new in Qt, and as such not as mature as we're used to from other components in Qt. QGraphicsLayouts in Qt 4.4 for example have problems resizing when their content changes its size. Luckily, most of that has been addressed by the Qt developers so that we're looking at a much improved QGraphicsLayout in Qt 4.5. In order to get some of the more complex Plasmoids to work correctly in (the Qt 4.4-based) KDE 4.2, those Plasmoids contain workarounds for those problems, workaround that aren't necessary for Qt 4.5 any more. Some of those workaround are even considered harmful when using Qt 4.5 (i.e. they will simply break things such as screwing out the layouting of widgets). The result of that is that Plasma in KDE 4.2 is effectively incompatible with Qt 4.5, hence the reason we ask distributors to not ship KDE 4.2 with Qt 4.5. At least not until further notice. We've already removed some of those workaround and hacks in KDE trunk/ (which is what is going to become KDE 4.3 this summer). KDE 4.3 will require Qt 4.5 anyway once it's released, so this is pretty much a no-brainer. It's not trivial to backport those things, that's why we're currently not planning to do that. So as it looks like, we (the Plasma team) won't support running KDE 4.2 with Qt 4.5. If you'd like to know further details about this, or want to find out what it takes to get KDE 4.2 working with Qt 4.5, please come over to the Plasma mailinglist (plasma-devel kde org) to discuss this further. Update: Most of the issues have been resolved by both the Qt and KDE teams. If you happen to run into problems with this combination, let us know via bugs.kde.org or one of our mailinglists and we'll see if we can fix it.
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An ordinary-differential-equation (ODE) simulation model has recently been proposed for an N-node dynamic programming (DP) network, which solves the transitive closure and shortest path problems on an architecturally equivalent N-node 2D/3D grid stack. For large-scale randomly generated bidirectional network, where N is large and the inter-grid paths may take either direction, cycles commonly occur leading to a high percentage of nodes with unbound path lengths. The detection of such cycle nodes can be readily found using a shortest-path DP network. In this work we address several issues on the cycle avoidance problem, by first defining the 〈H〉-index and 〈V〉-index and hence its product 〈HV〉 as the two-dimensional turn ability. A regression model was then proposed and obtained empirically to relate the cycle-node ratio, which is the percentage of cycle nodes over N, with 〈HV〉 for several random networks of sizes N = 10×10×2, 10×10×5, 10×10×8. By reducing 〈HV〉 from 0.8 to 0.2, the cycle-node ratio can be reduced from close to 60% to 20% and indicates a significant avoidance of cycle nodes.


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Webkinz target kids for early social networking: CNET News Video
About Video
CNET News Video: Webkinz target kids for early social networking3:05 /
The Webkinz experience begins when children buy a stuffed animal with a code on the tag that's used to log in to a social networking site. Then they can customize rooms for their pet, and interact with fellow Webkinz owners. As Webkinz celebrates its second birthday, CNET.com's Neha Tiwari takes a look at the popular phenomenon.
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MOON TOWNSHIP, Pa. -- Andrew Toole has been promoted to head basketball coach at Robert Morris.
Toole takes over for Mike Rice and at age 29 becomes the youngest head coach in NCAA men's Division I basketball. Toole was the school's associate coach for three seasons.
Toole was the only candidate interviewed for the job and was recommended by a coaching search committee. He is a former player at Elon and Penn and was an assistant for one season at Lafayette.
Rice left last week to coach at Rutgers, taking the job several weeks after signing a contract extension at Robert Morris. Rice had a 73-31 record with the Colonials, who took Villanova to overtime in the NCAA tournament before losing.
Previously, Appalachian State's Jason Capel was the youngest Division I head coach. Capel is 30.


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When Boozing Gets Spooky
Grenadine syrup, the benign sweet dye for the virginal Shirley Temple, can stand in for spilt blood. Bored college bartenders learn that trick early on during their downtime, dripping it over a creamy shot of Bailey's for the appetizing Brain Hemorrhage. This is one of those brilliant bartender discoveries that only gets played out on Halloween, when drink-slingers can indulge their creepy cocktail fantasiesThe Dead Baby Boy; The Necrophiliac's Dreamand foist it on a costumed public. All of a sudden, Jagermeister, with its opaque blackness and foul taste (they'll say licorice, but it's kind of what we imagine the undead barfing in your mouth would taste like) makes altogether too much of an appearance.
From the appetizing to the unquestionably nauseating, a look at what a few of our favorite watering holes are serving up this October 31st:
The Slide
Naked Vampire Martini, with black vodka, $8
Otto Martini (apple cider, spiced rum), $10
"Spooky shots", $4
Upcoming Events
Usa National Womens Basketball
TicketsSun., Jul. 31, 1:30pm
Staten Island Yankees vs. Auburn Doubledays
TicketsSun., Jul. 31, 4:00pm
New York Yankees vs. New York Mets
TicketsWed., Aug. 3, 7:05pm
International Champions Cup North America vs. Bayern Munich
TicketsWed., Aug. 3, 7:30pm
Otto Shrunken Head (not particular to this holiday, but disgusting nonetheless)
Patty's Poison (rum and pineapple juice), $8
Zombies (orangey-red rum drink), $8
Stormy Skull (rum, ginger beer and coconut, served in a skull mug), $8
Flatiron Lounge
Halloween Flight, $18, including:
El Diablo (tequila cocktail with fresh ginger beer, Herradura Silver tequila, lemon, cassis)
Corpse Reviver #2 (Plymouth gin, Lillet, Cointreau, fresh lemon, herbsaint)
Tombstone Cocktail (Wild Turkey Rye, demerara syrup, angostura bitters, lemon twist)
Black & White
The Frankenstein (Jagermeister, cherry brandy, and Coke), $7
Orchid Lounge
Witches Brew (martini with pumpkin-spice-infused vodka, white Godiva liqueur, rimmed with a graham-cracker crust), $9
Citrus margarita with pomegranate, $5
Also: Forget the Webster Hall $20 blowout afterparty with the sad Michael Jackson lookalike, forget Andy Bell breaking his Chains of Love over at GBH. We're calling out Asian-themed Orchid Lounge as the best party scheduled this Halloween, if only for, hold your breathThe Connie Chung Lookalike Contest. We don't care if that bar is empty, save for one Chung, two Chungs, Chung sucking down lemon shots, Chung circa the Dan Rather beatdown, or even Chung as a wee Chunglet. Sport the well-cultivated Asian power bob, and some day you too might have a crack at Maury Povich's crusty seed.
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July 19, 2016 By Charlie Mitchell
With apologies to Ann Landers and Abigail Van Buren… … [Read More...]
July 15, 2016 By Ray Mosby
"Love is but a song to sing, Fear's the way we die. You can make the mountains ring, Or make the angels cry."—Quoted material by Chet Powers (aka … [Read More...]
July 13, 2016 By Joel McNeece
Charlie McNeece just won the lottery, setting him up for a life of luxury. … [Read More...]
July 19, 2016 By Joel McNeece
Jimmy Earl Aron, 75 of Bruce, died Monday, July 18, 2016, at The Med in Memphis. Born January 10, 1941 in Bruce, he was the son of James Lavert Aron and Sara Josephine Easley Aron. He served in the Mississippi National Guard, was in the graduating class of 1958 at Bruce High School, and was a graduate of Graduate of […]
July 15, 2016 By Joel McNeece
Emmer Alice Cook , 81, passed away Friday July 15, 2016, at home in Pittsboro.
July 15, 2016 By Joel McNeece
Addie M. Cook-Vance, 84, passed away Monday, July 11, 2016, at Sanctuary Hospice in Tupelo
July 13, 2016 By Joel McNeece
John Paul Vance, 52, went to his heavenly home on Monday, July 11, 2016 at UMMC in Grenada. He was born May 9, 1964 in Houston, the son of Clifford Vance and Edna Jones Gregg. He was a truck driver for Lovorn Logging and member of Bethany Baptist Church in Slate Springs.
Past President of the Mississippi Press Association.National Newspaper Association Board of Directors.Husband, journalist, dog owner, Harley rider
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Part of the problem with leglocks is that there are tons of variations. And too many options create confusion, increase your decision-making time, and lead to paralysis by analysis, so it really helps to have someone set you straight and narrow down your choices. But for some reason certain leglock aficionados love to collect endless leglock variations. … [Read more...]
Ronda Rousey and the Power of Gameplans
In case you were hiding under a rock, Ronda Rousey fought Liz Carmouche last night at UFC 157. She both validated her UFC Women's Bantamweight title, and made history by being in the first-ever women's match in the the UFC. And just in case you were under that aforementioned rock, despite a very spirited fight by Liz Carmouche, Ronda won the match with an armbar at 4:49 of the first round. … [Read more...]
How to Salvage a Failed Butterfly Guard Sweep
The 'basic' butterfly guard sweep is one of the most strongest sweeps in grappling. That's why it shows up again and again at the highest levels of competition. It's powerful, reliable, and works for a wide range of body types. It works with and without the gi, on bigger people, smaller people, wrestlers, and judoka. This combination of power and versatility makes the butterfly guard sweep … [Read more...]
Hidden Techniques for Maintaining Rear Mount
When people teach the rear mount they often show you how to get your hooks in to achieve the rear mount, and then they teach you a couple of submissions from the back. Their idealized flowchart has two steps: Get your hooks in, Submit your opponent. Oh, if only life were so simple! … [Read more...]
No Gi Guard Passing Strategies vs. Bigger People
Passing the guard in a technical manner during no gi training can often be very frustrating, especially for people coming from a gi-based background. To the uninitiated it just seems that things move too fast... That there aren't any good handles to control your opponent... … [Read more...]
How to Set Up the X Guard
I love the X Guard. It's such a high-percentage position. First of all, it can be applied from a huge number of open guard and half guard situations. If you've ever watched an X Guard specialist you'll know that he needs just a tiny bit of room to insert those hooks and - BOOM - he's slithered into the X Guard. And once an opponent is caught in the X Guard he's going down! In fact, by the … [Read more...]
Ambush Armbar from Modified Scarf Hold
I might not be 100% correct with the actual wording, but I'll always remember this fantastic quote from Karate legend Bill 'Superfoot' Wallace which I read in Black Belt magazine many years ago. It went something like this: "There's always going to be someone bigger, stronger or faster than you, but there never has to be anyone sneakier than you!" … [Read more...]
How to Counter the Backstep Guard Pass
BJJ and submission grappling are in a continual state of evolution. New techniques, tactics and strategies emerge, or are rediscovered, or are brought into the art all the time. The backstep guard pass is one such modern technique. You won't see this guard pass in old-school BJJ … [Read more...]
How to Pass Deep Half Guard
In the last 5 years the Deep Half Guard position has taken the BJJ and submission grappling world by storm. And every serious grappler now needs to know how to neutralize and pass the Deep Half Guard. This position is a variation of the half guard. If someone manages to get settled into this position underneath you then they're right under your center of gravity, can compromise your balance, … [Read more...]
How to set up and apply the head and arm choke
Here's a clip of Emily Kwok teaching something really cool - how to set up the head and arm choke (also known as 'kata gatame') from mount, and then how to ratchet it on so tightly that your opponent has no choice but to tap out, no matter how big he is. … [Read more...]


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Maestro on the Move: Music in Cincinnati - Classical Music Journalism by Mary Ellyn Hutton (features_2004)
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German Windmill Makers Suffering Similar Fate to Solar, FTD Says
German windmill makers such as Nordex SE are suffering a similar fate to solar companies as Chinese firms push into the market, Financial Times Deutschland said, citing Manfred Bayerlein, chief executive officer of wind power certification company TUEV Rheinland.
While China's technology is a few years behind, their products are already economical, Bayerlein said, according to the German newspaper. Chinese companies entering the market has contributed to a 25 percent drop in prices since 2008, FTD said.
German solar companies such as Solon SE, Solar Millennium AG and Q-Cells SE have filed for insolvency, while China has built up an industry with more than 400 companies, some of which are market leaders, FTD said.
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Wednesday, October 03, 2007
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Mochi ice cream producer Frances Hashimoto dies
Associated Press
LOS ANGELES (AP) – Frances Hashimoto, a Little Tokyo business and civic leader whose Los Angeles company popularized the Japanese-style treat known as mochi ice cream, has died. She was 69.
Hashimoto died of lung cancer on Sunday at her Pasadena home, her husband, Joel Friedman, said Wednesday.
"She was an angel on earth," he said. "She always gave and gave and gave to the Japanese community."
Hashimoto was born in a World War II internment camp in Poston, Ariz.
In 1970, she took over Mikawaya, a confectionary business operated by her family in downtown's Little Tokyo area since 1910.
Under her direction, the business expanded from a single shop into a $13 million-a-year business.
The company popularized mochi ice cream, an ice cream ball wrapped in a layer of rice cake. Some sources credit Hashimoto or her husband with inventing the treat and bringing it to market in the 1990s while others list a South Korean company as creating it a decade earlier.
Mikawaya's version is now sold in supermarkets throughout the U.S.
She also was a longtime civic leader and a member of several organizations that promoted business and Japanese cultural events in Little Tokyo.
In September, the City Council voted to name a plaza in her honor. Frances Hashimoto Plaza will be dedicated next week.
In addition to her husband, Hashimoto is survived by two sons and a sister.
(Copyright 2012 The Associated Press. All rights reserved. This material may not be published, broadcast, rewritten or redistributed.)
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Adrien Brody Sports Fake Tattoos for 'American Heist'
About this photo set: Adrien Brody shows off a slew of fake tattoos while walking on the set of his latest film American Heist on Monday (July 15) in New Orleans, La. The 40-year-old… Read More Here
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