text:
Vt. woman sentenced to 2 years in heroin caseThe Associated Press | January 17,2013A Vermont woman has been sentenced to serve over two years in federal prison after pleading guilty to conspiring to distribute heroin.
Maria Hunton of South Burlington had faced a longer term, but the judge considered her lack of a criminal record in imposing the sentence.
Court records said the 23-year-old Hunton and her boyfriend sold large amounts of controlled substances from his home in South Burlington. The boyfriend, Ryan Orvis, has pleaded guilty to conspiring to distribute cocaine.
She was sentenced Tuesday.MORE IN This Just In
MIDDLEBURY — Middlebury Police arrested Ronald Bean, 52, on two counts of... Full StoryHUBBARDTON Vermont State Police said a fallen tree struck and killed a man on the north end of... Full StoryMore than 26,000 people were without power when severe thunderstorms rolled through the state in... Full Story
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Legal Lore: Curiosities of Law and Lawyersby Various
View All Available Formats & Editions
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At the very outset of any treatment of so delicate a subject as that indicated by the title of this chapter, we are met by no small difficulty. This consists in the danger of committing unintentional errors of irreverence, and thus offending the prejudices of those who are more or less pledged to their belief in the verbal inspiration of every Bible chapter and verse. With this risk before us, we can only trust to our own sense of a rational view of a subject so full of capabilities of misconstruction. Those of us who can remember the outburst of righteous indignation at the publication of the �Essays and Reviews� and of �Ecce Homo,� feel surprise at the quiet indifference with which views expressed in them are now received. This does not at all, or necessarily, mean that men�s faith is colder, or that the spirit of reverent religious feelings has died away. The advance of accurate scientific investigation may have upset the faith of some, and given a subject for outbursts of intolerant pulpit denunciations, but we must think that there are signs plainly discernible of a quiet acceptation of modern discovery by the majority of thoughtful and devout believers in the inspiration of Holy Scripture. These remarks will be found not unneedful as we pursue the examination of this particular branch of Biblical study, namely, the Law as it is found in the Bible, and this will be seen at once when it is laid down as an absolutely necessary condition of our investigation that this same Law can plainly be divided into two distinct portions�that which is of Divine, and that which is of human origin. The bare statement of this fact will offend certain prejudices. The Divine �Fiat� stamps with as marvellous and undoubted clearness, certain portions, as other parts are marked by the progress of human intelligence, the needs of human society, and the force of the human will.
The very fact of the existence of Law entails the necessity of Penalty, and this may be spiritual or corporal. The former depends on the acknowledgment of the rule over us of a Superior Being. The latter is a necessary accompaniment of all and every human life, believing or unbelieving. So in the Bible Law we can easily distinguish between the penalty affixed to the breaking of the first of the Ten Commandments, and that which followed on the breaking of the sixth. On the authority of Hebrew scholars, we are told that the use of the Hebrew Article shows that The Law refers to the expressed will of God. If this rule be invariable, it would be of great value, and especially so in the use of the Greek Article.
Product Details
- 2940014094078
- Publisher:
- Library of Alexandria
- Publication date:
- 02/01/2012
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- Barnes & Noble
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News and Events
Day Camp Registration is OPEN! Click HERE for the brochure and registration form.
Uncorked and On Tap will be on October 15, 2016! Save the Date for this fun annual event that includes wine and beer tasting, auctions, and fellowship with your Camp friends and family.
CLICK HERE to be a part of this event by placing a Journal Ad, Sponsoring the Event, or donating items to our Auctions.


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Raising Izzie, DVD
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14-year old Gertie (Victoria Elizabeth Staley) is singlehandedly raising her little sister, Izzie (Kyla Kenedy). Orphaned after their mother's death, the two girls are secretly living on their own, attempting to stay under the radar so they can remain together. Meanwhile Gertie's new teacher, Mrs. Freeman (Vanessa Williams), and her husband (Rockmond Dunbar) struggle with their inability to have a child. Both Gertie and Mrs. Freeman have fallen from faith, but can these two "broken" families find renewed devotion by coming together? Gifted with an inspired cast and uplifting message, Raising Izzie will touch your heart with the healing power of faith and family. Widescreen. Approx. 87 minutes.
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ginger2 Stars Out Of 5More modest clothing would improve an otherwise good showMarch 6, 2015gingerQuality: 2Value: 2Meets Expectations: 2I actually quite liked the show, but was disturbed by the continual cleavage shown by the main actress. Shouldn't we not have to worry about this in Christian programming? Isn't the main point in these types of movies the message, not the sexiness of the actors and actresses? As they'd say on Shark Tank, "For this reason, I'm out!"
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text:
You may apply online at www.rhlapps.com/kjones or give me a call.
K.C. Jones
RH Lending
firstname.lastname@example.com ... more
FHA has an upfront PMI
VA has no PMI
FHA has PMI until you reach 78% LTV or 5yrs(whichever is longer
VA is zero down
FHA is 3.5% down minimum
... more
The answer is yes, but there will be the big question of "income". If you have no way to pay off the loan, who would provide you a loan?
Your track record will help, but y ... more
I bet the Police Credit Union would be happy to help him.
Try this link to find homes for sale in Lebanon Tennessee.


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- Product Information
Product DescriptionIt's a birthday party for a princess! Little girls love to be a princess. Why not use the princess theme for your daughter's birthday party? Our pink princess party paper goods is accented with hearts, rings, princess wands and glass slippers. Pink princess luncheon napkins are sold 16 to a pack. Please order in increments of 1 pack.
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Top Definition
The wet fart noise a vagina makes when being pounded hard and fast due to air
I was pumping my bitch so hard and fast she squelched so loud, it was embarrassing for her.
Por Djc2508 16 de enero de 2014
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Green Planet Blues: Four Decades of Global Environmental Politics / Edition 4by Ken Conca
View All Available Formats & Editions
Pub. Date: 01/12/2010
Publisher: Westview Press
Revised and updated throughout, this unique anthology examines global environmental politics from a range of perspectives: contemporary and classic, activist and scholarly, and reflecting voices of the powerless and powerful. Paradigms of sustainability, environmental security, and ecological justice illustrate the many ways environmental problems and their
Revised and updated throughout, this unique anthology examines global environmental politics from a range of perspectives: contemporary and classic, activist and scholarly, and reflecting voices of the powerless and powerful. Paradigms of sustainability, environmental security, and ecological justice illustrate the many ways environmental problems and their solutions are framed in contemporary international debates about climate, water, forests, toxics, energy, food, biodiversity, and other environmental challenges of the twenty-first century. Organized thematically, the selections offer a truly global scope. Fourteen new readings discuss globalization and environmental change; transnational activist networks; the UN Environment Programme; environment-conflict linkages, including the case of Darfur; environmental peacebuilding; the debate on greening foreign aid; and the linkages between climate change and human rights. This book stresses the underlying questions of power, interests, authority, and legitimacy that shape environmental debates, and it provides readers with a global range of perspectives on the critical challenges facing the planet and its people.
Product Details
- 9780813344119
- Publisher:
- Westview Press
- Publication date:
- 01/12/2010
- Edition description:
- Fourth Edition, Fourth Edition
- Pages:
- 400
- Sales rank:
- 929,847
- Product dimensions:
- 6.00(w) x 8.90(h) x 1.00(d)
Table of Contents
Preface ix
Introduction: Four Decades of Global Environmental Politics Ken Conca Geoffrey D. Dabelko 1
Part 1 The Debate at Stockholm 15
1 The Limits to Growth Donella H. Meadoaws Dennis L. Meadows Jørgen Randers William W. Behrens III 25
2 Environment and development: The case of the developing Countries João Augusto de Araujo Castro 30
3 The tragedy of the Commons Garrett Hardin 38
4 No Tragedy on the Commons Susan J. Buck 46
Part 2 Ecology and the Structure of the International System 55
5 Rethinking the Ecology-Soverignty debate Ken Conca 65
6 Environment and Globalization: Five Propositions Adil Najam David Runnals Mark Halle 76
7 Fight for the Forest Chico Mendes Tony Gross 94
8 Kenya's Green Militant: An Interview with Wangarei Muta Maathai Ethirajan Anbrasan 99
9 Globalization, Global Alliances, and the Narmada Movement Smitu Kothari 106
Part 3 Institutions of Global Environmental Governance 117
10 Governance with Multilateral Environmental Agreements: A Healthy or III-Equipped Fragmentation? Norichika Kanie 126
11 Moving Forward by Looking Back: Learning from UNEP's History Maria Ivanova 143
12 A Participatory Approach to Strategic Planning Richard E. Bissell 161
13 The Evolution of the Trade and Environment Debate at the WTO Hugo Cameron 168
14 Has Foreign Aid Been Greened? Timmons Roberts Bradley C. Parks Michael J. Tierney Robert L. Hicks 177
15 Report and Findings on the Qinghai Project: Executive Summary, World Bank Inspection Panel 193
Part 4 The Sustain Ability Debate 199
16 Towards Sustainable Development, World Commission on Environment and Development 207
17 Whose Common Future? LarryLohmann 218
18 Sustainable Development: A Critical Review Sharachchandra M. Lélé 224
19 Expanding the Capital Stock Ismail Serageldin Andrew Steer 237
20 Shifting the Pain: World's Resources Feed California's Growing Appetite Tom Knudson 243
Part 5 From Ecological Conflict to Environmental Security? 247
21 Demography, Environment, and Civil Strife Colin H. Kahl 256
22 Sudan: Conflict and the Environment, United Nations Environment Programme 267
23 The Case Against Linking Environmental Degradation and National Security Daniel Deudney 279
24 The Violence of Development Balakrishnan Rajagopal 290
25 An Uncommon Peace: Environment, Development, and the Global Security Agenda Geoffrey D. Dabelko 292
Part 6 Ecological Justice 307
26 Two Agendas on Amazon Development, Coordinating Body for the Indigenous Peoples' Organizations of the Amazon Basin (COICA) 316
27 A Voice for the Forest and Its People Silas Kpanan' Ayoung Siakor 323
28 Coercing Conservation Nancy Lee Peluso 326
29 The Relationship Between Climate Change and Human Rights, Office of the United Nations High Commissioner for Human Rights 338
Index 353
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text:
Today ought to be good.AGTHX has a lot of exposure to railroads.BRK is buying BNI and is the #1 institutional shareholder.AGTHX is also the #1 shareholder of CSX and UNP.
I did not see AGTHX holding CSX. Holdings are MSFT, ORCL, GOOG and APPL. Are you sure about CSX. Thanks.
I think he is right.http://finance.yahoo.com/q/mh?s=CSX


text:
Courtyard By Marriott Hong Kong
Courtyard By Marriott Hong Kong
Hotel Guest Rating: 8.6/10
167 Connaught Road West
Hong Kong
Hotel Freebies Available*
• APAC Leisure Offer show dates
• Stay for Breakfast Promotion: Rate includes breakfast for two adults and 2 children 12 and under, when staying in the same room show dates
• Free Internet in Room show dates
Welcome to the Courtyard By Marriott Hong Kong
A complimentary downtown shuttle, internet access and bottled water are some of the reasons that the non-smoking Courtyard by Marriott Hong Kong is one of the city's most popular hotels.
Hotel Features
Spread over 25 stories, the 405 non-smoking rooms and suites at the Courtyard let in lots of sunlight through floor-to-ceiling windows. Pillowtop beds covered with luxe linens and bathrooms with rainforest showerheads make you feel pampered. LCD TVs with pay-per-view movies are among the contemporary comforts, as are docks for your iPods and complimentary wired and wireless internet access. Also on the house is chilled bottled water. The handsome fitness room is stocked with cardio and strength-training equipment. A restaurant on the second level serves breakfast, lunch and dinner, and room service is an option. Same-day dry cleaning comes in handy. A downtown shuttle is free, and parking is available nearby.
Hotel Location
In the popular Hong Kong Island West neighborhood, the Courtyard is close to attractions like the Hong Kong Zoological and Botanical Gardens and the University of Hong Kong. If you have kids in tow, about 15 miles away you'll find Hong Kong Disneyland. Hong Kong International Airport is 23 miles west.
Guest Favorites
With a "great location" in a residential neighborhood, Priceline guests say the Courtyard By Marriott Hong Kong offers "modern" rooms with "comfy" beds and a "friendly and courteous" staff.
Courtyard By Marriott Hong Kong Amenities
- 24-Hour Front Desk
- 24-Hour Room Service
- Air Conditioning
- Airport Transfer
- Alarm Clock
- American Express
- Bathrobes
- Business Center
- Chinese (Cantonese)
- Chinese (Mandarin)
- Coffee Shop
- Coffee/Tea Maker
- Complimentary Bottled Water
- Concierge
- Currency Exchange
- Daily Housekeeping
- Daily Newspaper
- Desk
- Diners Club
- Dry Cleaning
- Elevator
- English
- Executive Floor
- Executive Lounge Access
- Facilities For Disabled Guests
- Fitness Center
- Free Wi-Fi In All Rooms
- Hair Dryer
- In Room Safe
- In Room Video Games
- Inhouse Movies
- Interconnecting Room(S) Available
- Internet Access - Lan
- Internet Access - Lan (Complimentary)
- Internet Access - Wireless
- Internet Access - Wireless (Complimentary)
- Ipod Docking Station
- Ironing Facilities
- Jcb
- Laptop Safe Box
- Laundry Service
- Mastercard
- Meeting Facilities
- Mini Bar
- Non Smoking Rooms
- Photocopying
- Refrigerator
- Restaurant
- Room Service
- Safety Deposit Boxes
- Satellite/Cable Tv
- Seating Area
- Shower
- Shuttle Service
- Smoking Area
- Telephone
- Television Lcd/Plasma Screen
- Toiletries
- Visa
- Wi-Fi In Public Areas
Hotel Guest Reviews of the Courtyard By Marriott Hong KongOur hotel ratings and reviews are from real hotel guests. Priceline.com ensures that its reviews are guests-only by proactively sending hotel surveys to customers after they've completed their hotel stays. In the post-stay surveys, priceline.com hotel customers are asked a number of questions about their stay and the hotel. On a scale of 1-10 with 10 being the best, the survey asks guests to rate their overall experience and specifically rate the hotel's cleanliness, staff and location. Priceline.com does not allow site visitors to post unsolicited hotel reviews.
Sort by: All Travelers | Business Traveler(8) | Solo Traveler(5) | Traveling as Couple(15) | Family with Young Children(2) | Family with Teens(1) | Group Traveler(5)
Verified Hotel Guest from Burlington, Canada
February 16, 2016
February 16, 2016
Location is good and fairly new hotel. Comfortable bed and good shower.
some staff were not friendly, the room was so small that we barely fit our suitcase in.
Eunyoung from New Castle, DE
January 5, 2016
January 5, 2016
This guest did not leave comments about this hotel.
Ashok Kumar from Noida, India
November 23, 2015
November 23, 2015
Helpful and courteous staff
Verified Hotel Guest from Crofton, MD
September 24, 2015
Business Traveler
September 24, 2015
Business Traveler
Beautiful view of the harbour.Very helpful staff.
Verified Hotel Guest from Portland, OR
May 26, 2015
May 26, 2015
the restaurant was SORELY lacking in service
Verified Hotel Guest from Stockton, CA
May 16, 2015
May 16, 2015
Staff was friendly & helpful and they made sure you had a great stay with them .
Krishna from Mississauga, Canada
May 5, 2015
May 5, 2015
The Hotel was good. The staff was very helpfull. The neighbour was a little run down.Bus service was good but the MTR was a 10 minute walk from the Hotel.
Not too close to the MTR but the Bus to Town was good.
Jang from Seoul, Republic Of Korea
April 21, 2015
April 21, 2015
The room was clean chincheolham was good also. If you have a Starbucks around the staff, also meets tram stop right in
Not a good location is also far distance to Shungnak complete translation, novice travelers've positions poorly. Not much sound around a restaurant
Jihoon from Clarksville, TN
April 14, 2015
April 14, 2015
it's nice and seems to be far from downtown, but it may gice you a chance to ride a tram and bus from downtown. it only takes 5~10 mins.
Jack from West Palm Beach, FL
April 7, 2015
Business Traveler
April 7, 2015
Business Traveler
View of Hong Kong harbor from room was amazing. Staff was perhaps the best I've ever seen with regards to giving you attention and overall service.
Reviews of Courtyard By Marriott Hong Kong
(1 - 10 of 36 reviews)
(1 - 10 of 36 reviews)
from $139
- Ramada Hong Kong Hotel from $61 (0mi)
- Bridal Tea House Hotel - Western District (0.1mi)
- Bridal Tea House Western District Hotel (0.1mi)
- Island Pacific Hotel from $85 (0.2mi)
- Best Western Hotel Harbour View from $44 (0.3mi)
Most Popular Guest-Rated Hotels in Hong Kong
Most Popular Business-Friendly Hotels in Hong Kong
- Bishop Lei International Hotel
- Cordis Hong Kong At Langham Place
- Metropark Hotel Causeway Bay Hong Kong


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Community Listing > Art & Music News
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Vandini Magic & Escapes ShowActon, MEcome and see Vandini Comedy Magic & Rope & Chain Escape Acts, TWO SHOW 3:30 pm - 6:30 pm , THURSDAY 25/ 2016 , opening Day only, see you ...andre c. · 1 day ago
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text: When agile appeared, it solved (some of) the problems we were facing at that time. It changed the idea that months-long iterations were the way to go. We learned that delivering often provides numerous benefits. It taught us to organize teams around all the skills required to deliver iterations, as opposed to horizontal departments organized around technical expertise (... Read more about The DevOps 2.0 Toolkit


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ACE Fit Share
Fit Life Articles
When it comes to grocery shopping, it's a good idea to stick to the perimeter of the store. That's where you'll find the healthiest, freshest foods. You can certainly find healthy options in a store's interior as well—just make sure you read the labels so you know what...
Maintaining a healthy weight can be challenging and, for some people, even more difficult than losing weight. The good news is that achieving lasting weight maintenance is possible. Use these 13 tips to help you succeed at maintaining your weight-loss goals.
Summer has arrived! Here is a leg workout that will have you feeling strong, agile and amazing in your favorite shorts, skirt or swim suit.


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EDDMapS Distribution - This map is incomplete and is based only on current site and county level reports made by experts, herbaria, and literature. For more information, visit www.eddmaps.org
|Kingdom: Plantae
|Phylum: Magnoliophyta
|Class: Liliopsida
|Subclass: Commelinidae
|Order: Cyperales
|Family: Poaceae
|Genus: Digitaria
|Subject: Digitaria setigera Roth ex Roemer & J.A. Schultes


text:
Gig Harbor, WAUSA
Hometown: Gig harbor,w.a
June 23, 2013
Hot air balloon, sky dive, live in Mexico.
Hung out with Fleetwood Mac, from Brooklyn, jersey shore too.
Gig harbor
Hi, I am an active semi-retired nurse, counselor. I love the outdoors, kayaking, walks, horses, photography, music always! Love meeting new interesting folks in my area who also enjoy art, exploring new interests and camping. Not a big drinker.
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Engine Performance problem
2000 Chrysler Town and Country 6 cyl All Wheel Drive Automatic 125000 miles
I am trying to locate the fuel filter on a 2000 Town and Country. Is there one somewhere besides in the fuel tank with the fuel pump?
Monday, July 21st, 2008 AT 9:58 AM


text:
you are viewing a single comment's thread.
Fanofstan, how did you come by your appreciation of the company? Are you a past or present employee or an acquaintance of one, a user of their products or just an investor? From your posts I understand that you have a core position that you trade around, but what initially caught your eye? I have been following the company for a few years and have been in and out a couple of times for small moves, but picked up a more serious position on the recent downturn and plan on holding Good luck.
I am a diabetic and use the produc, I was also very familair withy the Medtronic product. This product is vastly superior and he folks I deal with there are superb in all areas of customer support. I also talk with my Endocrinologist regualrly to see how the competition is stacking up and I am the CEO of a Pharmacuetical ocmpany so I am wired into the industry. I absolutely love this company. I own 200,000 shares and my cost basis is virtually zero if you factor in past gains. I styarted buy it 4-5 years ago at $7 and had a nice position and hten the market crashed and it went to $1.78. I bought 150,000 share below $2.50 and had 350,000 at one point. I like a core posiiton of around 200,000 and peeled aton of it at $13. I truly beleoive this stock sees mid 20's with 18 months and is eventually bought out at 30 or above. You could not have a better market to be addressing than diabetes, it is the fastest growing segment of health care.
Fanofstan: I am a follower of DXCM but a shareholder of Echo Theraputics and wanted to get your feedback on the company. Thanks and may you have a happy, healthy prosperous new year.


text:
Witch & Wizard: The Gift - Witch & Wizard 2 (Paperback)James Patterson
Paperback Published: 03/03/2011
- In stock
Click & Collect From your local shop
Ever since Whit and Wisty Allgood were torn from their home and family in the middle of the night, the soldiers of the New Order government have relentlessly tried to capture and execute them for 'collusion, conspiracy, and experimentation with the dark and foul arts'. But this supremely skilled witch and wizard have instead boldly spearheaded the fight against the cruel and brutal regime. The villainous leader of the New Order is just a breath away from the ability to control the forces of nature and to manipulate his citizens on the most profound level imaginable - through their minds. There is only one more thing he needs to triumph in his evil quest: the Gifts of Whit and Wisty Allgood. And he will stop at nothing to seize them.
Publisher: Cornerstone
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"Witch & Wizard: The Gift"
This is the second in Patterson's Witch and Wizard series and it is just as good and engrossing as the first, perhaps even more so as we discover more about the New Order and The One Who is the One and what... More
"The Gift - With & Wizard 2"
Quote from my 10 yr old son who I purchased the book for.
"It is an amazing book and I couldn't put it down!"
We would love to hear what you think of Waterstones. Why not review Waterstones on Trustpilot?


text:
7 Reviews
Yummy! This is delicous! I used it to marinate boneless chicken breasts, then make them into chicken sandwiches on kaiser rolls as suggested. I will try it on BBQ'd chicken this Spring. This time I broiled the chicken breasts. I let the chicken breasts sit in the marinade for about 2 days. They were an ugly color, but very flavorful.
Very juicy and tasty. I used 3 times the lemon because we love it and made one fourth the recipe for 2 breasts (which was way more than enough). I might do even half of that - even with the reduced sodium soy sauce, it does have a fair amount of saltiness.
This was a tasty marinade! I started mine very early in the morning, and that was plenty of time. Tender and moist after grilling, it also had a great flavor! I may try it on a sandwich next time! Thanks for sharing, SuzieQ in Fairfax!
This marinade made the most delicious, succulent grilled chicken breasts! The next time I make it I'll take your suggestion and make chicken sandwiches on Kaiser rolls. Yum! Made for Spring 2010 Pick A Chef.
Very easy to throw together using chicken thighs last night! Cooked in a frying pan tonight, we enjoyed the thighs cut up in wraps with avocado, tomato, lettuce, a bit of cheese and sour cream. Made for 2009 Favourites tag and I would make it again. Thanks SuzieQ! :)
I made chicken kabobs with this marinade. They were awesome! I am looking forward to using this marinade again!


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Disparities in Health and Health Care: Five Key Questions and Answers
Executive Summary 1. What are Health and Health Care Disparities? Health and health care disparities refer to differences in health and health care between population groups. "Health disparity," generally refers to a higher burden of illness, injury, disability, or mortality experienced by one population group relative to another group. A…Issue Brief Read More
The Ohio Health Care Landscape
This fact sheet provides an overview of population health, health coverage, and health care delivery in Ohio under the Affordable Care Act (ACA).Fact Sheet Read More
A Guide to the Supreme Court's Review of the Contraceptive Coverage Requirement
This issue brief dissects the issues raised by the legal challenges to the Affordable Care Act's requirement that private insurance plans include contraception as part of their coverage of preventive services for women. Over 40 for-profit corporations and over 40 nonprofit corporations have filed lawsuits claiming that the requirement to provide their employees with contraceptives violates their religious rights. On November 26, 2013, the Supreme Court agreed to hear two cases filed by for-profit corporations, Hobby Lobby and Conestoga Wood Specialties, that claim that this requirement violates their religious rights. At the crux of these cases is a question that the Supreme Court has not previously addressed: Do for-profit corporations have religious protections under the 1993 Religious Freedom Restoration Act and the First Amendment? The brief provides background on how the ACA's contraceptive requirement works, summarizes some of the legal challenges brought by for-profit and non-profit organizations and discusses the implications of potential rulings by the Supreme Court.Issue Brief Read More
Assessing the Impact of the Affordable Care Act on Health Insurance Coverage of People with HIV
This analysis provides the first national estimates of the expected impact of the Affordable Care Act's (ACA) coverage expansions on people with HIV. The brief finds that close to 70,000 uninsured people with HIV who are in care could gain new coverage, including 47,000 through Medicaid were all states to expand their Medicaid coverage.Issue Brief Read More
The Affordable Care Act, the Supreme Court, and HIV: What Are the Implications?
This brief explores key provisions of the Affordable Care Act (ACA) for people with HIV, and the opportunities and challenges for using the law to improve HIV care, particularly in light of the Supreme Court's 2012 ruling on the law.Report Read More
The Utah Health Care Landscape
This fact sheet provides an overview of the population health, health coverage, and health care delivery in Utah in the era of health reform.Fact Sheet Read More
State Medicaid Coverage of Perinatal Services: Summary of State Survey Findings
The report examines state Medicaid program policies regarding coverage of pregnancy-related services. It details state-level Medicaid eligibility and enrollment policies for pregnant women, as well as scope of coverage for prenatal and screening services, delivery and post-partum care, educational classes and support services.Report Read More
Explaining Health Reform: Benefits and Cost-Sharing for Adult Medicaid Beneficiaries
This brief provides details of the benefit and cost-sharing rules that will govern the coverage available under health reform to these newly eligible adults Medicaid beneficiaries, and it identifies key considerations for state policymakers making Medicaid benefit design choices.Issue Brief Read More
Women and Health Care in the Early Years of the ACA: Key Findings from the 2013 Kaiser Women's Health Survey
This report addresses a wide range of topics that are at the heart of women's health care, as well as changes that women may experience as a result of the Affordable Care Act (ACA). The findings in the report, based off a nationally representative survey conducted by the Kaiser Family Foundation, highlight differences in health care for uninsured, low-income, and minority women. Other focus areas include: coverage, access, and affordability; connections to health providers; access and utilization of preventive services; and reproductive and sexual health services for women of reproductive age, such as contraception and family planning services and screenings for sexually transmitted infections (STIs).Report Read More
Report, Briefing Examine How Seniors Choose Among Their Medicare Plan Options
Report & Briefing Examine How Seniors Choose Among Their Medicare Plan Options Seniors appreciate having a wide range of Medicare private plan choices available to them but often feel unqualified to choose among them, a new Kaiser Family Foundation report concludes. Based on discussions with seniors in four cities around…News Release Read More


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Dear Secretary Chu:
The Committee on Natural Resources ("Committee") is conducting oversight on issues surrounding your March 16, 2012 Memorandum to the Power Marketing Administrations ("PMAs"). After two full Committee hearings and a number of congressional letters of concern, it is abundantly clear that there are many unanswered questions on the reasoning and implementation of this Memorandum. This letter seeks to determine some answers.
Your thorough response is important for the Committee to carry out its oversight responsibilities. Through this letter, the Committee requests that the Department of Energy ("DOE") produce documents and communications described below. Your complete written response to all items should be received by the Committee no later than November 11, 2012.
Read the entire letter HERE.
Yesterday, the Government Accountability Office (GAO) released a report on the Bureau of Land Management's (BLM) accounting and management of natural gas emissions on onshore federal lands. Committee ......
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Today, the U.S. Fish and Wildlife Service (FWS) removed the lesser prairie chicken from the list of threatened and endangered under the Endangered Species Act (ESA) in response to a 2015 court ruling.......
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Today, House Committee on Natural Resources Chairman Rob Bishop (R-UT), Senate Committee on Agriculture, Nutrition, and Forestry Chairman Pat Roberts (R-KS) and Representative Bruce Westerman (R-AR) p......
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looks like Go Green Racing is sharing the #52 for the Sprint Cup Series along with BK Motorsports and Hamilton-Means Racing for select races, more info on the #52 Team News and Links page.
FAS Lane and Go Green Racing enter joint venture: FAS Lane Racing owner, Frank Stoddard, and Go Green Racing owner, Archie St. Hilaire, announce that they have entered into a joint venture for the 2014 NASCAR Sprint Cup Series season and beyond. "Frank has a great program here at FAS Lane Racing and we believe that by combining our resources, we can take the program to the next level," said St. Hilaire. "It's been my goal to race in the Sprint Cup Series on a weekly basis and this joint venture makes the most sense for both parties." Stoddard and St.Hilaire both recognize the increasing challenges to being competitive at the Sprint Cup level. By combining resources from both their teams, they believe the joint venture will strengthen the overall program of the #32 Ford. Two-time NASCAR Sprint Cup Series Champion Terry Labonte will return to the teams #32 entry to compete in the season opening Daytona 500. The driver list for the remaining races will be announced in the coming weeks. The team also announces that they have hired veteran crew chief Dan Stillman, giving Stoddard more time to focus on the business side and assist in securing marketing and sponsorship opportunities for the team. The team will continue to operate out of the FAS Lane Racing shop in Mooresville, North Carolina where they will continue to field Fords and utilize Roush/Yates engines.(Integrity Sports Marketing)(12-24-2013)
Changes with the #44 and #19 teams? UPDATE: been told that crew chief Peter Sospenzo has left the #19 Humphrey-Smith Racing team and is the new crew chief for the #44 Xxxtreme Motorsports team. Supposedly Mike Bliss, currently the driver of the #19 Toyota could move to the #44 Ford for Xxxtreme Motorsports. Scott Riggs has ran three races for Xxxtreme Motorsports this season. Supposedly the next race for Xxxtreme Motorsports will be at Charlotte Motor Speedway, possibly as soon as the Sprint Showdown on May 18th. Former #44 crew chief has supposedly moved on to the #79 Go Green Racing team in the Nationwide Series and Sprint Cup Series. No word who the new crew chief for the #19 team will be.
UPDATE: been told that Furr is not working with the #79 team and that Ben Leslie is working with the team as the crew chief.(5-1-2013)
Go Green Racing Announces First Cup Race of 2013: Go Green Racing announced that they will attempt their first NASCAR Sprint Cup series race of the 2013 season at Richmond International Raceway on April 27th for the Toyota Owners 400. The #79 Ford Fusion team had plans to start their season earlier in the year, but with the limited availability of parts for the new Gen 6 cars, as well as building them, delayed the start. Go Green Racing expects to compete in 8-10 events this season with hopes of running the entire races as funding permits. The team has had conversations with several drivers for the #79 Ford Fusion and hopes to make an announcement in the coming weeks as to who that will be. Go Green Racing, founded by Maine native Archie St. Hilaire, has enjoyed success in the NASCAR Nationwide series over the past several years before fielding a NSCS entry last season on a limited schedule. The team qualified for six races including the Southern 500, Brickyard 400, and both races at New Hampshire Motor Speedway.(Go Green Racing)(4-3-2013)
Re-Load joins the #79 as a primary sponsor: Re-Load Wellness will join Go Green Racing and driver Reed Sorenson for the Ford EcoBoost 400, this weekend for the final race of the season. "This has been a great experience this year with Go Green Racing and NASCAR, in getting awareness to our brand and we will be at Homestead to sit down with both parties to discuss a bigger role for the 2013 season" said Ken Lewis CEO of CleanPath Resources, the parent company of Re-Load.biz.(DBM Marketing Group)(11-17-2012)
Go Green Racing gets associate sponsor for Texas: Re-Load has agreed to be a major associate sponsor this week for the AAA Texas 500. Re-Load.biz will be on Go Green Racing's #79 driven by Kelly Bires.(DBM Marketing)(11-2-2012)
#79 gets a sponsor for Kansas: CleanPath Resources will sponsor Go Green Racing's #79 driven by Kelly Bires in the Hollywood Casino 400 at Kansas. CleanPath with be putting their line of Wellness products Re-Load on the hood.(DBM Marketing Group)(10-17-2012)
Bires returns to the #79 at New Hampshire: According to his Facebook page Kelly Bires will return to the seat of the #79 Go Green Ford at New Hampshire Motor Speedway for the Sylvania 300.(9-14-2012)
Skinner to make Indy attempt with Go Green Racing: Bebida Beverage Company, a developer, manufacturer and marketer of liquid relaxation products, will reunite for their second time with #79 Go Green Racing and team owner Archie St Hilaire, for the Crown Royal presents the Curtiss Shaver 400 at the Brickyard Sprint Cup Series race at Indianapolis Motor Speedway. Behind the wheel will be former Camping World Truck Series Champion Mike Skinner. This will be the second time Koma Unwind will be primary sponsor of the Go Green Racing #79 Ford. Earlier in the year the company backed the effort at Darlington Raceway with driver Scott Speed that started 29th and finished 42nd.(BeBevCo PR)(7-24-2012)
Bires to make Sprint Cup debut: Kelly Bires Will Drive The #79 Team Kyle / Bestway Ford at New Hampshire Motor Speedway For the LENOX Industrial Tools 301. Bires locked himself into the race during qualifying Friday and will make his Sprint Cup Series debut. Said Bires: "I am really looking forward to making my NASCAR Sprint Cup Series debut at NHMS. New Hampshire reminds me a lot like Milwaukee where I grew up. It's a technical track that produces hard racing and the track suites my style. I know how much this race means to Go Green Racing and we are looking forward to putting on a good show for the home fans."(kellybires.com)(7-14-2012)
Go Green Racing honoring "Team Kyle" at Darlington: Go Green Racing will make their second NASCAR Sprint Cup Series attempt of the season this upcoming weekend at Darlington Raceway for the Bojangles' Southern 500. Driving the #79 Go Green Racing Ford Fusion will Scott Speed. The team will be honoring seven-year old Kyle St. Clair of Scarborough, ME. Kyle was born seven weeks early and has spent much of his life at hospitals in Maine, Boston, and Columbus. Kyle has had over 45 surgeries and suffers from lung disease and severe immobility. Recently, his family has been able to bring him home on hospice. "I had the chance to meet Kyle and his family a couple weeks back and he is truly an amazing boy," said Archie St. Hilaire, Go Green Racing Team Owner. "The strength and love he has is contagious. I hope we can get our car into the race and put on a good show for Kyle." Fans are encouraged to show your support for Kyle by following "Team Kyle" on Facebook.
AND: Bebida Beverage Comapny, a developer, manufacturer and marketer of liquid relaxation products, announced the company has made a deal with Go Green Racing to be the primary sponsor on their Sprint Cup series Ford. The fastest-growing relaxation drink in the world, KOMA UNWIND, will join Go Green Racing and their driver Scott Speed for this week's installment at the "Too Tough to Tame" Darlington Speedway for the Bojangles Southern 500.(BeBevCo) see images of the car on my #79 Team Schemes page.(5-11-2012)
Go Green Racing to make Sprint Cup debut: #79-Go Green Racing plans to make its NASCAR Sprint Cup Series debut at Kansas Speedway for the STP 400 on April 22 with driver Tim Andrews. Calling the shots will be former NSCS Champion crew chief, Paul Andrews. The team will run the #79 BBI / Bestway Disposal Ford Fusion. Go Green Racing has purchased their NSCS cars from Roush Fenway Racing and will run the Roush / Yates FR9 engines. "Tim proved to us last year that he can get a car into the show, and at this level, that is what it is all about," said Archie St. Hilaire, Team Owner for Go Green Racing. "The chemistry between Paul and Tim is outstanding. I think that Tim has shown us that he deserves a shot and I have always been a believer in giving a guy an opportunity." Kansas Speedway will also mark the first Sprint Cup attempt for Tim Andrews. "I feel very fortunate to get this opportunity," said Tim Andrews. "I have dreamed about being in a Cup car and to do it with my father's help is unbelievable. I believe in him and he believes in me, it just gives us that much more confidence. I've raced at Kansas before and can't wait to go back."(Go Green Racing PR), see an image of the car on my #79 Team Schemes page.(4-17-2012)
Go Green Racing Signs Paul and Tim Andrews; Forms Cup Team: Go Green Racing announced the addition of Paul and Tim Andrews to an already impressive list of talented crew members to Go Green Racing for the 2012 NASCAR season. Paul Andrews, a former NASCAR Sprint Cup Series Champion Crew Chief, will lead the #19 [changed to #79] Go Green Racing Ford Fusion in the NASCAR Sprint Cup Series beginning at Bristol Motor Speedway on March 16th. Bristol Motor Speedway will also mark the first Sprint Cup Series attempt for Tim Andrews. Following Bristol, the team expects to compete in an additional ten NSCS races. Tim Andrews is also scheduled to compete in select NASCAR Nationwide Series races as driver of the #37 Go Green Racing Ford Mustang. Calling the shots as crew chief on the #37 will be Dave Ingram. Ingram joins Go Green Racing after serving as crew chief for MacDonald Motorsports last season. Go Green Racing has purchased their NSCS cars from Roush Fenway Racing and will run the Roush/Yates FR9 motor at all 2012 Cup races.(Go Green Racing)(1-20-2012)
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Born in JULY
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29 Bernie Bisciotti, Harry Goularte, J.T. Hayes, Pete Orr
30 Robert Grey Allison, Ben Arnold, Neil Bonnet, Henry Ford, Ricky Sanders, Ward Towers
31 Mike Alexander, Bill Cintia, Bill Deakin, Flossie Johnson, Kyle Larson, Billy Rafter, Buck Simmons, Louise Smith, Bob Tomlinson
Born in AUGUST
1 Bobby Issac, Bob Keselowski, Ronnie Hornaday III, Alison Poling McCabe
2 Brian France
3 Tracy Adamczyk-Dowd (sister), Brad Baker, Terri Parsons
4 Jeff Gordon, Kurt Busch, Bob Calkins, Amy Hair, Bob Hubner, Allen Styers
5 Josh Browne, Alan Gustafson, Kenny Irwin Jr., Chad Knaus, Paul Lamach, Pattie Petty, Rich Woodland
6 Jeb Burton, Gail Connor, Tom Hubert, Kendall McReynolds, Rick Ware, "Amish" John Stewart
7 Pete White, Steve Loyd, Kyle Drum
8 Gail Norton, Parker Kligerman, Tommy Ellis, Jack Sprague, Don Leo
9 Tom Higgins, Cindy Shepherd, Lloyd Dane, Leo Gordon
10 Doug Hewitt, Donnie Neuenberger, Murray Timm, Chris Heroy, Ryan Moore
11 Lennie Pond, H. Clay Earles, Glenn Jarrett, Lonnie Rush Jr., Frankie Schneider, John Dodson, Zachary Gay
12 Dick Bown, Richard Everett Craven, Michelle Durkin, Tony Furr Jr., Scott Gaylord, Jordan Irvan, Parnelli Jones, George Lubejko, Ryan Reed, Carolyn Rudd Wax
13 John Feeney, John Baden, Patrick Carpentier, Hideo Fukuyama, Jim Roper, Bill Wilsey
14 Rusty Wallace, Lee Spencer
15 Andy Petree, Carl Edwards, Newt Moore, Robin Pemberton, Mark Kennerly
16 Ronald Allison, Donald Allison, Diane Hawkins, Lenny Batycki
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18 Drew Markle, Matt McLaughlin, Steve Wallace, Rachel Wood, Steve Lowery, Andrea Sospenzo, Andy Pilgrim
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22 Collin Houston, Tommy Mullis, Elmo Langley
23 Steve Park, Kenny Wallace, Scott Miller, Ashlie Garone, Robert Larkins, Ralph Sheheen, Shane Sieg, Mike Janssen
24 David Bonnett, Lee McCall
25 T.J. Bell, Casey Atwood, David Smith, Shane Hall, Kelly Bires, Sarah Catlin Waltrip,
26 Jayski.com, Ray Evernham, James Hylton, Landon Rudd, Greg Engle, Ken Duan, Adam Gravitt, Daniel Rankin
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Today at a customer we analysed the logs of the previous weeks and we found the following issue regarding Windows Azure Service Bus Queues:
The request was terminated because the entity is being throttled. Please wait 10 seconds and try again.
After verifying the code I told them to use the Transient Fault Handing Application Block (TOPAZ) to implement a retry policy like this one:
var retryStrategy = new Incremental(5, TimeSpan.FromSeconds(1), TimeSpan.FromSeconds(2));
var retryPolicy = new RetryPolicy<ServiceBusTransientErrorDetectionStrategy>(retryStrategy);
The customer answered:
"Ah that's great, so it will also handle the fact that it should wait for 10 seconds when throttled."
Come to think about it, I never verified if this was the case or not. I always assumed this was the case. In the Microsoft.Practices.EnterpriseLibrary.WindowsAzure.TransientFaultHandling assembly I looked for code that would wait for 10 seconds in case of throttling but didn't find anything.
Does this mean that TOPAZ isn't sufficient to create resilient applications? Should this be combined with some custom code to handle throttling (ie: wait 10 seconds in case of a specific exception)?


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Finite-Difference Time-Domain (FDTD) calculations are used to characterize the electric field in the vicinity of a sharp silver or gold cone with an apex diameter of 10 nm. The simulations are utilized to predict the intensity and the distribution of the locally enhanced electric field in tip-enhanced Raman spectroscopy (TERS). A side-by-side comparison of the enhanced electric field induced by a radially and a linearly polarized light in both gap-mode and conventional TERS setup is performed. For this purpose, a radially polarized source is introduced and integrated into the FDTD modeling. Additionally, the optical effect of a thin protective layer of alumina on the enhancement of the electric field is investigated.
© 2013 Optical Society of America
1. Introduction
The development of tip-enhanced Raman spectroscopy (TERS) is a revolutionary advancement in vibrational spectroscopy of materials and biomaterials, providing a spatial resolution and sensitivity on the scale of a few nanometers [1–3]. For example, TERS has been successfully employed to study a large variety of samples such as isolated carbon nanotubes [2,4], individual RNA strands [5], isolated mitochondria of cells [6], or interactions of proteins with biocrystals [7]. The principle of TERS is based on the excitation of the localized surface plasmon resonance (LSPR) at the extremity of a sharp metallic tip with a typical radius of 20-40 nm. The optimal excitation of the LSPR is thus critical to provide maximum enhancement from the tip apex which acts as a nanoantenna for both excitation and emission processes [8]. In the best conditions, Raman intensity maps with lateral resolution of less than 15 nm can be obtained [9], in contrast to the resolution limit of conventional optical microscopy limited by the the Abbe' criterion (~250 nm) [10]. The enhancement of the electric field in TERS depends critically on various parameters such as the polarization of the excitation beam, the metallic nature and the geometry of the metallic tip, as well as the sample substrate [11]. So far, finite-difference time-domain modeling (FDTD) of the electromagnetic field has been applied successfully to optimize TERS parameters such as the length and the radius of the tip, the material of the tip and the tip-sample distance [12–14]. In this work, we use FDTD to precisely estimate the impact of both radially and linearly polarized sources on the enhancement of the electric field. While a linearly polarized source is commonly used for TERS, radially polarized modes are of great interest to conduct TERS experiments in axial illumination geometry [15–17]. Laser beams with radial polarization provide unique focusing properties including a strong longitudinal electric field component generated at the focal point [18]. In TERS, a polarization component of the incident light along the tip axis induces a strong surface charge density at the sharp apex of the metallic tip which is a prerequisite for local enhancements [10]. To conduct the presented calculation, a radially polarized source is designed and integrated into the FDTD modeling. The choice of the material for simulated tip and substrate is limited to silver and gold as they are the two most popular metals that are successfully tested for TERS measurements in UV-Vis range [9,19]. The presented simulations are performed at two distinct wavelengths of 532 and 632.8 nm, in order to excite the LSPR of silver and gold tips, respectively. These parameters also match our practical TERS experimental conditions [7,20]. Furthermore, we analyze how a thin protective layer of alumina alters the confinement of the enhanced electric field. Although such protective layer does extend the lifetime of the metallic tip by preventing the rapid oxidation and mechanical wear under ambient conditions, it also interferes with the local enhancement [21–23].
2. Results and discussion
Finite-difference time-domain approach is a reliable method for solving Maxwell's equations in complex geometries [24]. FDTD provides time domain information, offering insight into electrodynamics of the system [25]. In FDTD, the electromagnetic field and structural materials of interest are described on a discrete mesh composed of so-called Yee cells. Maxwell's equations are solved discretely in time, where the time step used is related to the mesh size through the stability criterion. This technique is an exact representation of Maxwell's equations in the limit that the mesh spacing goes to zero. To simulate the TERS tip, a silver or gold rounded-tip cone with the tip diameter of 10 nm, and a cone angle of 25° is utilized. These parameters are estimated based on SEM images of typical tips that are used in TERS measurements. To illustrate gap-mode geometries, a film of silver or gold with 5 nm thickness is introduced inside the simulation area and located 1 nm below the cone apex. The simulation area is set up as a three-dimensional system of 100x100x126 nm3 surrounded by the perfectly matched layer (PML) boundary, wide enough in order to limit its impact on the resonance of the system. A spatial mesh of 0.15 nm and a temporal mesh of 2.8x10−16 s are set, which guaranteed numerical convergence of the results. The optical constants of alumina is described by Palik [26], and the one of silver and gold are obtained from CRC [27]. All the calculated and reported intensities are normalized with respect to the intensity of the incident light. A radially polarized light has polarization vectors oriented radially in the transverse plane with respect to the propagation direction. Under a tight focusing of a radially polarized light by a high numerical aperture (N.A.) lens, the focal longitudinal electric field and the focal transverse electric field could be expressed by the following equations [28]:Eqs. (1) and (2) was created to describe a focused radially polarized light inside the simulation area. The script was written in Matlab programming language and integrated into FDTD. This light source has been utilized for the corresponding calculations that are reported in this article. The transverse and longitudinal electric field components of the described beam are shown in Figs. 1(a) and 1(b) in 3D and 2D presentations. Focal components of a linearly polarized light are also presented for comparison. To create Figs. 1(c)-1(f), the Gaussian light is focused by passing a 1 mm diameter beam consisting of 1500 plane waves through a thin lens of 5 mm diameter and 1.2 numerical aperture.
Fig. 1
The transverse component of a radially polarized beam consists of several concentric rings with variable intensities and a minimum intensity at the middle [Fig. 1(a)]. The longitudinal component of this beam is another set of concentric rings with overall intensities lower than the transverse component and with a maximum intensity at the center [Fig. 1(b)]. The enhancement phenomenon that occurs in TERS originates from the interaction of the longitudinal component of the focused light with the apex of the sharp metallic tip. The top view of a focused Gaussian beam consists of several concentric rings in the xy plane with a maximum intensity in the middle [Fig. 1(c)]. From the side view, the beam would be relatively elongated in the direction of propagation along z [Fig. 1(d)]. As shown in Figs. 1(e) and 1(f), the z component of the electric field in a focused Gaussian beam has two lobes in the direction of propagation with zero intensity in the middle. This minimum intensity results in the absence of significant excitation of plasmon resonances at the tip apex if the tip is located in the center of the focal region. However, tip-enhanced Raman should be observed more significantly in the case where the tip is located inside one of the two lobes of the excitation laser. For the presented simulations where the structures of a few nanometers (less than 20 nm) are studied, focused Gaussian beam are approximated with a plane wave. Here, total field scattered field (TFSF) was used to prevent the possible couplings with the boundaries of the simulation area. TFSF is a special case of plane wave that separates the computation region into two distinct regions: one contains the total field which is the sum of the incident field and the scattered field, while the second region contains only the scattered field. As depicted in Figs. 2(a)-2(f), a comparison of the localized electric field enhancement at the tip apex is performed for linear and radial polarizations. A linearly polarized source was set to propagate along the tip axis (axial illumination) or perpendicular to it (side illumination). In side illumination, the light is linearly polarized along the tip axis, while in axial illumination, the polarization of light is perpendicular to the tip axis (linear polarization) or along the tip (radial polarization). The results of these simulations are shown in Figs. 2(a), 2(c) and 2(e) when only the tip is involved in the simulation and in Figs. 2(b), 2(d) and 2(f) for gap-mode TERS. In gap-mode TERS, thin and flat gold nanoplates are generally utilized as substrate for the sample. Since the molecules or nano-object of interest are sandwiched between the two metallic interfaces formed by the tip and the metallic nanoplate, larger local enhancement of the Raman signal can be achieved [29]. As shown in Figs. 2(a) and 2(b), for a linearly polarized beam with axial illumination configuration, the presence of the tip results in an overall electric field intensity of zero below the apex.
Fig. 2
Here the electric field is enhanced in two areas located on two sides of the tip with respect to the tip symmetry axis. When the tip is illuminated from the side with a linearly polarized light, the electric field is confined at the tip apex [Figs. 2(c) and 2(d)]. Side illumination is specifically useful when probing opaque samples. However, microscope objectives with long working distances, and therefore low focusing power, are generally used in side illumination setups. The creation of an intensified electric field at the tip apex can also be obtained through axial illumination with a tightly focused radially polarized light. The longitudinal component of the electric field in this case is significantly enhanced at the tip apex [Figs. 2(e) and 2(f)]. The presence of thin layer of metal gives rise to a more localized confinement area around the tip apex [Fig. 2(b), 2(d) and 2(f)] when compared to the conventional TERS setup [Figs. 2(a), 2(c) and 2(e)]. The simulations show an increase of the normalized intensity of the electric field at the junction between the tip and the metal substrate. An improvement of the enhancement factor from 8 to 10 for axial illumination, from 82 to 322 for side illumination and from 720 to 11510 for radial polarization are predicted, when comparing conventional TERS and gap-mode TERS under distinct polarization configurations. Similar calculations are performed for different combinations of silver/gold tips with gold/silver substrates upon axial and side illumination by linearly and radially polarized light. The results of the 18 possible combinations are summarized in Table1.
Noticeably, under an irradiation at 532 nm, these results predict a larger enhancement factor when using a silver tip and a gold substrate as compared to the case involving a silver tip and a silver substrate. This observation is presumably related to the extinction coefficients of silver (kag(532 nm) = 3.49) and gold (kau(532 nm) = 2.1). Silver absorbs a larger part of the incident light compared to gold, thus reducing local enhancement of the electric field. This absorption weakens the excitation beam that reaches the tip apex. The absorption of the light by the silver substrate could also be quite high, breaking the observed trend for the confinement factor of the electric field. A similar trend is observed when using gold tip at 633 nm irradiation. However, this phenomenon is not observed for axial illumination with linearly polarized light, therefore, this could also be due to the orientation of the polarization direction with respect to the tip axis. The optical effect of a dielectric protective layer is investigated by adding a 1 nm thick alumina layer over the surface of the metallic cone as shown in Figs. 3(a)-3(c). The thickness and the material of the protective layer have been chosen according to the previously published studies [30].
Fig. 3
Adding 1 nm of dielectric protective layer decreases the enhancement of the enhanced electric field by 50%. The observed decrease could originate from a shift in the frequency of the surface plasmon resonance. If the apex of the metallic TERS tip is considered as a nanosphere, the quasi-static dipolar plasmon resonance condition for this tip follows where and are the permittivities of the metallic sphere and the surrounding medium, respectively [31]. In conclusion, the addition of a dielectric layer would change the plasmon resonance of the tip/substrate junction thus reducing enhancement of the local electric field. The presence of the alumina dielectric layer could also cause destructive interference of the incident light and the scattered electric field from the different interfaces.
3. Conclusion
The present work aims at exploring the influence of the incident laser polarization, and the presence of a thin metallic substrate in distinct configurations for tip-enhanced spectroscopy. We conclude that by utilizing a thin film of transparent gold or silver as a substrate for TERS measurements, a considerable increase in the sensitivity can be achieved. With regard to the polarization of the incident light, we conclude that for a linear input polarization, a side illumination is preferable with polarization axis oriented along the tip axis. Meanwhile, axial illumination by a radial polarization promotes the strongest confinement of the electric field, which is ideal for tip-enhanced measurements. However, the excitation depends on the optical properties of the junction formed by the metallic tip and substrate. The hetero-metallic junction formed by a silver tip and a gold thin film appears to be very efficient. These investigations are in good agreement with our recent study where the impact of a thin film of gold as substrate along with radially polarized Raman laser is experimentally investigated in TERS detection of a monolayer of molecules [20]. Additionally, we demonstrate that adding a thin protective layer to the TERS tip to reduce oxidation and mechanical wear decreases the intensity of the electric field by 50%.
This research was funded by the Natural Sciences and Engineering Research Council of Canada Discovery Grant and by the Canada Research Chairs program.
References and links
1. E. A. Pozzi, M. D. Sonntag, N. Jiang, J. M. Klingsporn, M. C. Hersam, and R. P. Van Duyne, "Tip-enhanced Raman imaging: an emergent tool for probing biology at the nanoscale," ACS Nano 7(2), 885–888 (2013). [CrossRef] [PubMed]
2. A. Hartschuh, "Tip-enhanced near-field optical microscopy," Angew. Chem. Int. Ed. Engl. 47(43), 8178–8191 (2008). [CrossRef] [PubMed]
3. S. Kawata, "Plasmonics for nanoimaging and nanospectroscopy," Appl. Spectrosc. 67(2), 117–125 (2013). [CrossRef] [PubMed]
4. M. Nicklaus, C. Nauenheim, A. Krayev, V. Gavrilyuk, A. Belyaev, and A. Ruediger, "Note: Tip enhanced Raman spectroscopy with objective scanner on opaque samples," Rev. Sci. Instrum. 83(6), 066102 (2012). [CrossRef] [PubMed]
5. E. Bailo and V. Deckert, "Tip-enhanced Raman spectroscopy of single RNA strands: towards a novel direct-sequencing method," Angew. Chem. Int. Ed. Engl. 47(9), 1658–1661 (2008). [CrossRef] [PubMed]
6. R. Böhme, M. Mkandawire, U. Krause-Buchholz, P. Rösch, G. Rödel, J. Popp, and V. Deckert, "Characterizing cytochrome c states--TERS studies of whole mitochondria," Chem. Commun. (Camb.) 47(41), 11453–11455 (2011). [CrossRef] [PubMed]
7. N. Kazemi-Zanjani, H. Chen, H. A. Goldberg, G. K. Hunter, B. Grohe, and F. Lagugné-Labarthet, "Label-free mapping of osteopontin adsorption to calcium oxalate monohydrate crystals by tip-enhanced Raman spectroscopy," J. Am. Chem. Soc. 134(41), 17076–17082 (2012). [CrossRef] [PubMed]
8. L. Novotny, "Optical antennas tuned to pitch," Nature 455(7215), 887 (2008). [CrossRef]
9. L. G. Cançado, A. Hartschuh, and L. Novotny, "Tip-enhanced Raman spectroscopy of carbon nanotubes," J. Raman Spectrosc. 40(10), 1420–1426 (2009). [CrossRef]
10. L. Novotny, E. J. Sánchez, and X. S. Xie, "Near-field optical imaging using metal tips illuminated by higher-order Hermite-Gaussian beams," Ultramicroscopy 71(1-4), 21–29 (1998). [CrossRef]
11. J. Stadler, B. Oswald, T. Schmid, and R. Zenobi, "Characterizing unusual metal substrates for gap-mode tip-enhanced Raman spectroscopy," J. Raman Spectrosc. 44(2), 227–233 (2013). [CrossRef]
12. R. Treffer, X. Lin, E. Bailo, T. Deckert-Gaudig, and V. Deckert, "Distinction of nucleobases - a tip-enhanced Raman approach," Beilstein J Nanotechnol 2, 628–637 (2011). [CrossRef] [PubMed]
13. A. L. Demming, F. Festy, and D. Richards, "Plasmon resonances on metal tips: understanding tip-enhanced Raman scattering," J. Chem. Phys. 122(18), 184716 (2005). [CrossRef] [PubMed]
14. M. Sukharev and T. Seideman, "Optical properties of metal tips for tip-enhanced spectroscopies," J. Phys. Chem. A 113(26), 7508–7513 (2009). [CrossRef] [PubMed]
15. N. Hayazawa, Y. Saito, and S. Kawata, "Detection and characterization of longitudinal field for tip-enhanced Raman spectroscopy," Appl. Phys. Lett. 85(25), 6239–6241 (2004). [CrossRef]
16. C. Höppener, R. Beams, and L. Novotny, "Background suppression in near-field optical imaging," Nano Lett. 9(2), 903–908 (2009). [CrossRef] [PubMed]
17. J. Steidtner and B. Pettinger, "Tip-enhanced Raman spectroscopy and microscopy on single dye molecules with 15 nm resolution," Phys. Rev. Lett. 100(23), 236101 (2008). [CrossRef] [PubMed]
18. R. Dorn, S. Quabis, and G. Leuchs, "Sharper focus for a radially polarized light beam," Phys. Rev. Lett. 91(23), 233901 (2003). [CrossRef] [PubMed]
19. M. Paulite, C. Blum, T. Schmid, L. Opilik, K. Eyer, G. C. Walker, and R. Zenobi, "Full spectroscopic tip-enhanced Raman imaging of single nanotapes formed from β-amyloid(1-40) peptide fragments," ACS Nano 7(2), 911–920 (2013). [CrossRef] [PubMed]
20. F. Pashaee, R. Hou, P. Gobbo, M. S. Workentin, and F. Lagugné-Labarthet, "Tip-enhanced Raman spectroscopy of self-assembled thiolated monolayers on flat gold nanoplates using Gaussian-transverse and radially Polarized excitations," J. Phys. Chem. C 117(30), 15639–15646 (2013). [CrossRef]
21. C. A. Barrios, A. V. Malkovskiy, R. D. Hartschuh, A. M. Kisliuk, A. P. Sokolov, and M. D. Foster, "Extending lifetime of plasmonic silver structures designed for high-resolution chemical imaging or chemical and biological sensing," Proc. SPIE 6954, 69540C (2008). [CrossRef]
22. X. Cui, D. Erni, W. Zhang, and R. Zenobi, "Highly efficient nano-tips with metal - dielectric coatings for tip-enhanced spectroscopy applications," Chem. Phys. Lett. 453(4-6), 262–265 (2008). [CrossRef]
23. R. L. Agapov, A. P. Sokolov, and M. D. Foster, "Robust probes for high resolution chemical detection and imaging," Proc. SPIE 8378, 8378131–83781310 (2012). [CrossRef]
24. A. Taflove and S. C. Hagness, in Computational Electrodynamics: the Finite - Difference Time - Domain Method (Artech House, 2000).
25. B. C. Galarreta, I. Rupar, A. Young, and F. Lagugné-Labarthet, "Mapping hot-spots in hexagonal arrays of metallic nanotriangles with azobenzene polymer thin films," J. Phys. Chem. C 115(31), 15318–15323 (2011). [CrossRef]
26. E. D. Palik and G. Ghosh, Handbook of Optical Constants of Solids II (Academic, 1998).
27. D. R. Lide, CRC Handbook of Chemistry and Physics (CRC, 2009).
28. F. Lu, W. Zheng, and Z. Huang, "Coherent anti-Stokes Raman scattering microscopy using tightly focused radially polarized light," Opt. Lett. 34(12), 1870–1872 (2009). [CrossRef] [PubMed]
29. T. Deckert-Gaudig and V. Deckert, "Ultraflat transparent gold nanoplates - ideal substrates for tip-enhanced Raman scattering experiments," Small 5(4), 432–436 (2009). [CrossRef] [PubMed]
30. C. A. Barrios, A. V. Malkovskiy, A. M. Kisliuk, A. P. Sokolov, and M. D. Foster, "Highly stable, protected plasmonic nanostructures for tip enhanced Raman spectroscopy," J. Phys. Chem. C 113(19), 8158–8161 (2009). [CrossRef]
31. S. Vedraine, P. Torchio, D. Duche, F. Flory, J.-J. Simon, J. Le Rouzo, and L. Escoubas, "Intrinsic absorption of plasmonic structures for organic solar cells," Sol. Energy Mater. Sol. Cells 95, S57–S64 (2011). [CrossRef]


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One snowy morning, Doc and the toys venture outside for some winter fun. But when Chilly begins to feel like a real frozen snowman, Doc diagnoses him with a case of "Brrrrritis." The cure: Chilly needs to warm up!
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Talk:Roseanne Roseannadanna
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I wrote this version for the character under the misspelled "Roseanne Rosannadanna" and didn't realize this page was here. Nevertheless, I read this page the way it was and thought it was pretty insufficient (so I replaced it with the version you see now). It basically just compared Roseannadanna with Emily Litella, which I don't think is relevant. 'Lisa Loobner' (sic) was mentioned as a character that appeared on Update which was inaccurate, and I didn't think it went in-depth enough. Following is the original version. If anybody thinks that some aspects of it deserve to be mentioned in the article, you can put it in:
- Roseanne Roseannadanna was one of three characters created by Gilda Radner (the others being Emily Litella and Lisa Loobner) who appeared in the Weekend Update segments of the early seasons of Saturday Night Live. Like Litella, Roseanne was brought in to give editorial replies to current issues. Unlike Emily Litella, however, Roseanne Roseannadanna was not meek or apologetic, but rather very explosive in her reactions, and the tangents she would go off on invariably had the result of co-anchor Jane Curtin cutting her off and telling her that "Roseanne, you're making me sick!" The topic at hand would also usually remind her of a poem or song told to her by a relative in her childhood.
I changed it from saying that the name was inspired by Rose Ann Scamardella to saying that both the name and character by her. I will also make the change on the Scamardella page. This is based on my own memory of the both - early in her career, Scamardella stood out for her editorializing in her reporting - that might have changed later, I don't know, but it was obvious to the point of being funny and Radner ran with it. Alexgriz (talk) 12:59, 5 March 2011 (UTC)
Roseannadanna? Rosanadana?[edit]
The article spells it both ways. We need to figure out which is right, and fix this.
—überRegenbogen (talk) 03:50, 30 April 2013 (UTC)
- Back in November, someone changed it in several places to Rosanadana, saying it was spelled that way somewhere on the SNL site. I've restored the earlier version that consistently uses Roseannadanna, because a) it's consistent with the title, and b) it's how the NY Times spelled it in their obit for Gilda. If someone thinks a different spelling is correct, that should be discussed here, and the article title should be changed at the same time the article is changed. Theoldsparkle (talk) 12:48, 30 April 2013 (UTC)
Feder? Fader?[edit]
Same as above, the article bounces back and forth between both. --Arvedui (talk) 02:59, 11 July 2013 (UTC)
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Hotel Features
WiFi in public areas, coffee/tea in a common area, and laundry facilities are available at this hotel. Self parking is free.
Room Amenities
All 132 rooms feature kitchenettes with refrigerators and microwaves, plus WiFi and cable TV. Coffee makers and free local calls are among the other amenities available to guests. Weekly housekeeping is available.Would you like to give us feedback? Share it! Opens in a new window
InTown Suites4409 Hearst Street Metairie LA 70001
Hotel Amenities
Hotel Amenities
InTown Suites features coffee/tea in a common area, laundry facilities, and an elevator (lift). Public areas are equipped with high-speed wireless Internet access (surcharge). Complimentary self parking is available on site.
- Coffee/tea in common areas
- Elevator/lift
- Free self parking
- Laundry facilities
- Number of floors - 3
- Total number of rooms - 132
- WiFi (surcharge)
Family Friendly Amenities
- Kitchenette
- Laundry facilities
- Microwave
- Refrigerator
Available in all rooms: Wireless internet access ( USD .99 per night )
Available in some public areas: Wireless internet access ( USD .99 per night )
Free self parking
Room Amenities
- Access via exterior corridors
- Air conditioning
- Cable TV service
- Coffee/tea maker
- Cookware, dishware, and utensils
- Free local calls
- Iron/ironing board (on request)
- Kitchenette
- Microwave
- Phone
- Premium TV channels
- Private bathroom
- Refrigerator
- Weekly housekeeping provided
- WiFi (surcharge)
Hotel Policies
Check-in time ends at 10 PM
Check-in time starts at 3 PM
Special check-in instructions:
- Monday - Saturday: 10 AM - 10 PM
- Sunday - Sunday: 10 AM - 3 PM
Check-out time is 11 AM
Payment types
- Pets allowed for an extra charge
You need to know
Extra-person charges may apply and vary depending on hotel policy.
Government-issued photo identification and a credit card or cash deposit are required at check-in for incidental charges.
Special requests are subject to availability upon check-in and may incur additional charges. Special requests cannot be guaranteed.
No rollaway/extra beds available
This property requires a deposit for any bookings where payment will be made in cash. Nightly guests paying cash require a USD25 total deposit daily. Weekly guests paying cash require a USD100 total deposit weekly. For more details, please contact the office using the information on the reservation confirmation received after booking.
Optional extras
- Fee for in-room wireless Internet: USD .99 per night (rates may vary)
- Fee for wireless Internet in public areas: USD .99 per night (rates may vary)
- A pet fee will be charged
Hotel Name
- Sun Suites
- InTown Suites Hotel Metairie
- Sun Suites Hotel Metairie
- Sun Suites Metairie
- Sun Hotel Metairie
- Sun Suites Metairie/New Orleans West Hotel Metairie
- Sun Suites Metairie Hotel
- InTown Suites Metairie
- Sun Suites Of Metairie