text:
|Publication number
|Publication type
|Publication date
|Oct 22, 1974
|Filing date
|Jun 5, 1972
|Priority date
|Jun 5, 1972
|Publication number
|T Shell, J Vasta
|Original Assignee
|Du Pont
|Export Citation
|BiBTeX, EndNote, RefMan
|Referenced by (37), Classifications (27)
|External Links: USPTO, USPTO Assignment, Espacenet
United States Patent Shell et al.
RADAR ABSORPTIVE COATING COMPOSITION OF AN ACRYLIC POLYMER, A POLYESTER AND AN ISOCYANATE CROSS-LINKING AGENT Inventors: Theodore Shell, Swarthmore, Pa.; Joseph A. Vasta, Woodbury, NJ.
Assignee: E. I. du Pont de Nemours and Company, Wilmington, Del.
Filed: June 5, 1972 Appl. No.2 259,677
us. 0...... 260/40 R, 117/132 13, 117/132 BE, 117/148, 252/6256. 260/41 R Int. Cl C08g 51/04 Field ofSearch.. 260/312 R, 31.2 N, 31.2 XA, 260/328 R, 32.8 N, 33.6 R, 40 R, 41 R References Cited UNITED STATES PATENTS 6/1954 Frazier et al 260/452 1/1968 Vasta 260/834 3/1968 Hicks 260/47 4/1968 Masters et al. 260/784 12/1970 Fang 260/336 R l/l97l Vasta 260/775 1451 Oct. 22, 1974 3,585,160 6/1971 Miller ct a1. 260/318 N 3.622.651 11/1971 Vasta 260/856 3.658.763 4/1972 Dehm 260/312 N Primary Examiner-Leland A. Sebastian [57] ABSTRACT A coating composition that forms a durable. flexible radar absorptive coating for aircraft that contains as the binder an acrylic graft copolymer having attached to its backbone side chain ester units having reactive hydroxyl groups; a hydroxyl terminated linear polyester of a saturated aliphatic or aromatic dicarboxylic acid and an aliphatic glycol or an olefin oxide having a terminal oxirane group; an organic polyisocyanate cross-linking agent; and contains 60-90 percent by weight, based on the weight of the binder, of a carbonyl iron pigment; the composition is particularly useful as a coating on military aircraft which absorbs radar; pigmentation of the binder with iron oxide or chromium oxide pigment provides a coating for magnetic tapes; the binder can also be used as an automotive bumper finish.
6 Claims, N0 Drawings BACKGROUND OF THE INVENTION This invention relates to a flexible, durable, thermosetting coating composition and in particular to a radar absorbing coating composition for aircraft.
Thermosetting coating compositions are well known in the art and have been widely used for autos, appliances, such as refrigerators, stoves, washers and dryers, air conditioners and the like and also for vending machines. Typical thermosetting coating compositions are shown in Frazier et al. U.S. Pat. No. 2,681,897, issued June 22, 1954; Vasta U.S. Pat. No. 3,366,706, issued Jan. 30, 1968; Hicks U.S. Pat. No. 3,375,227, issued Mar. 26, 1968;'Masters et al. U.S. Pat. No. 3,376,271, issued Apr. 2, 1968; U.S. Pat. No. 3,622,651, issued Nov. 23, 1971 and Vasta U.S. Pat. No. 3,558,564, issued Jan. 26, 1971. However, these compositions, particularly when loaded with sufficient iron pigment to absorb radar and applied at high coating thicknesses, do not provide a coating on the plane which is flexible, durable and resistant to elevated temperatures and which will not shatter when the plane is struck by a bullet or flak.
The novel coating composition provides a tough, durable, flexible, shatter resistant, radar absorbing finish for aircraft.
SUMMARY OF THE INVENTION The coating composition of this invention comprises 10-70 percent by weight of a film-forming binder in an organic solvent;
wherein the film-forming binder is essentially l. a resin blend of 50-85 percent by weight, based on the weight of the resin blend, of a graft copolymer having a backbone of polymerized monomers which are either an aromatic hydrocarbon monomer having vinylene groups, an alkyl acrylate, an alkyl methacrylate, acrylonitrile, methacrylonitrile and mixtures thereof wherein the alkyl groups have 1-8 carbon atoms and has ester groups attached directly to its backbone; these ester groups comprise about 10-75 percent of the total weight of the graft polymer and consist essentially of Ester Group (A) II 1 C O R OH and Ester Group (B), which is either a mixture of these groups; wherein the molar ratio of Ester Group (A) to Ester group (B) is from about 1:15 to 122.5; and wherein R is a saturated hydrocarbon radical having 2-10 carbon atoms, R is selected from the group consisting of alkylene, vinylene, aromatic, carbocyclic and heterocyclic radicals, R is selected from the group consisting of a saturated aliphatic hydrocarbon radical having 1 to 26 carbon atoms and an ethylenically unsaturated aliphatic hydrocarbon radical having 12 to 18 carbon atoms, and 15-50 percent by weight, based on the weight of the resin blend of a hydroxyl terminated polyester of i. an aliphatic glycol having 2-8 carbon atoms or an olefin oxide having one oxirane group and containing 2-14 carbon atoms, and
ii. an aromatic dicarboxylic acid or a saturated aliphatic dicarboxylic acid having 4-14 carbon atoms;
wherein the polyester has a weight average molecular weight of 1,000-3,000 and a hydroxyl number of 40-80; and
2. a polyisocyanate wherein the molar ratio of isocyanate to hydroxyl of the resin blend is about 1:1 to about 111.25; and
the coating composition contains about -90 percent by weight, based on the weight of the filmforming binder of uniformly dispersed carbonyl iron pigment having a particle size of 0.5-1.5 microns.
DESCRIPTION OF THE INVENTION Preferably, the novel coating composition of this ino o 0 on n It 2 II c o R o c R c 0 CH2 c H o I n 3 CH2 o c R o o o H OH II II 2 l I C 0 R1 o c R c o c CH2 0 H CH2 o c R propyl acrylate, butyl acrylate, hexyl acrylate, 2-
ethylhexyl acrylate and the like or mixtures of these monomers. Small amounts of ethylenically unsaturated carboxylic acids can also be used in the backbone, such as acrylic acid, methacrylic acid, crotonic acid, itaconic acid, maleic acid and the like.
7 Particularly useful monomers or combinations of monomers which form the backbone of high quality polymers of this invention are, for example, styrene,
methyl methacrylate, butyl methacrylate, ethyl acrylate, acrylonitrile and methacrylonitrile.
Ester Group (A) of the graft copolymer used in this invention is provided by a hydroxyalkyl substituted vinyl addition monomer, such as hydroxyalkyl methacrylate, a hydroxyalkyl acrylate, a hydroxyalkyl maleate, hydroxyalkyl itaconate, or a mixture of these in which the alkyl group contains 2-l carbon atoms. The hydroxyalkyl monomer is polymerized with the aforementioned backbone monomers.
Preferred hydroxyalkyl monomers used for forming the graft copolymer used in this invention are, for example, hydroxyethyl methacrylate, hydroxypropyl methacrylate, hydroxybutyl methacrylate, hydroxyoctyl methacrylate, hydroxyethyl acrylate, hydroxypropyl acrylate, hydroxybutyl acrylate, hydroxyoctyl acrylate and the like. Preferred are hydroxyalkyl methacrylates or acrylates in which the alkyl groups contain 2-4 carbon atoms.
Ester Group (B) is the esterification product of the aforementioned hydroxyalkyl monomers, an anhydride of a dicarboxylic acid and a glycidyl ester. This ester group is polymerized into the polymer backbone through the ethylenic unsaturation of the aforementioned hydroxyalkyl monomers.
The anhydride used for forming EsterGroup (B) has the formula wherein R is either alkylene, vinylene, aromatic, carboncyclic or a heterocyclic radical. The anhydride reacts with the hydroxyalkyl monomers and also reacts with the glycidyl ester to form Group (B).
Anhydrides useful in this invention in which R is an alkylene group are formed from dicarboxylic acids of the general formula (CH ),,(COOH) where n is from 2-l0. Typical dicarboxylic acids of this group are glutaric, adipic, pimelic, succinic acids and the like. The preferred is an anhydride of succinic acid.
Useful anhydrides in which R is a vinylene group are derived from dicarboxylic acids of the general formula C H O wherein n is from 440. Typical diearboxylic acids of this group are maleic and itaconic acids.
Another group of useful anhydrides are derived from dibasic aromatic acids, such as phthalic acid, uvitic acid and cumidic acid. Often it is desirable to use 21 ha]- ogen substituted anhydride of one of the above aromatic dicarboxylic acids, such as tetrabromo phthalic anhydride. Halogen substituted anhydrides in which the halogen substitutent is either chlorine, bromine or fluorine are particularly useful in forming fire retardant coating compositions.
Anhydrides in which R is a carbocyclic radical are useful, such as hexahydrophthalic anhydride, which has the following formula o ii 0 i or tetrahydrophthalic anhydride which has the following formula Anhydrides in which R is a heterocyclic radical are also useful. One particularly useful compound has the general formula:
where R is either chlorine, bromine or fluorine. The I preferred compound is chlorendic anhydride in which- 'R is chlorine.
The glycidyl ester used for forming Ester Group (B) has the formula u 3 -CH-Ch -O-C-R where R is a saturated aliphatic hydrocarbon group containing 1-26 carbon atoms, or R is an ethylenically unsaturated aliphatic hydrocarbon radical of l2-l 8 carbon atoms derived from a drying oil fatty acid.
Preferred for use because of the quality of the graft copolymer obtained are esters where R is a tertiary saturated aliphatic hydrocarbon group of the structure which form Ester Group (A), to form the novel polymer of this invention.
As a typical example, a hydroxyalkyl acrylate, aro- 1 matic anhydride and a glycidyl ester are charged into a reaction vessel with a suitable solvent, such as toluene, xylene, acetone or an aromatic solvent and the C RJ mixture is heated to its reflux temperature, which is 5 about 80 to 200C., for about 30 minutes to 3 hours. The backbone constituents of the graft copolymer, such as styrene/methyl methacrylate and a hydroxyalwhere R i CH d R d R are ik i groups f kyl acrylate with a suitable polymerization catalyst, 12 carbon atoms. such as tertiary butyl peroxide, are then slowly added One particularly preferred glycidyl ester of this group a 14 hour Period- The reac tion mlxture is heated because it imparts acid and alkali resistance to the final to reflux temperature Whlch S to product is a mixed glycidyl ester described in US. Pat. for about 30 mmutes hours preferably 24 hours N 3 275 5 3 issued Sept 27 1966, and i8 manufac until a graft copolymer is formed that has the desired tured d ld b the Shell Chemical Company as molecular weight, which is determined by the relative E esier This giycidyi ester is of a Synthetic i5 viscosity as described below. Additional solvent may tertiary carboxylic acid and has the general formula be to (mute the Polymer If the reaction rates of the monomer components 0 0 used to form the graft copolymer used in this invention u 7 are suitable, all of the monomers can be charged into CH CH CH O C R a reaction vessel with a suitable solvent and polymerization catalyst and heated to the reflux temperature where R is a tertiary aliphatic hydrocarbon group of 8 which is about 80t0 200C. for 60 minutes to 5 hours.
through 10 carbon atoms.
When R of thegraft copolymer is an ethylenically Another method of preparing the graft copolymer unsaturated aliphatic hydrocarbon radical of 12-18 used in this invention is to charge the anhydride,for excarbon atoms, the glycidyl ester is obtained by esterifyample, phthalic anhydride, into a reaction vessel with ing the acid chloride of one of the well known drying a suitable solvent and heat the mixture for about oil fatty acids, such as oleic acid, linoleic acid, linolenic minutes to effect solution of the anhydride. The other acid, oleostearic acid and ricinoleic acid with glycidol. monomer constituents with a suitable polymerization These acids are commonly found in tung oil, linseed oil, 30 Catalyst are then slowly added over a 1-4 hour period dehydrated caster oil and soya oil. into the reaction vessel while maintaining a reflux tem- The preferred method for forming the above unsatuperature which is about 80-200C. After the above inrated glycidyl esters is to react the sodium salt of the gredientS ha e been added, the reaction mixture is fatty acid with epichlorohydrin. The reaction is as folmaintained at its reflux temperature for an additional lows: 30 minutes to about 5 hours.
0 Quaternary 9 I Ammonium R coou CH CH CH (=1 Salt /0 R COOCH CH CH where R is from one of the aforementioned drying oil Suitable solvents which are used to prepare the graft fatty acids. copolymer used in this invention are toluene, xylene,
Preferably,the graft copolymer used in this invention b t l etate, acetone, methylisobutyl ketone, methylhas 30 to 60 percent of its total weight contributed by ethyl ketone, and other aliphatic, cycioaliphatic and Ester Group (A) and (B). Also, these groups are presaromatic hydrocarbons, esters, ethers, ketones and ent in the graft copolymer at a molar ratio of Este other solvents which are non-reactive with the mono- Group (A) to Ester Group (B) of about l:l.5 to about mers used to form the graft copolymer such as are conl:2.5 and preferably, in a ratio of about 1:2. ventionally used in coating compositions.
One preferred graft copolymer contains 30 percent Suitable polymerization catalysts that are used in the b w i h styrene, 15 percent by weight methyl methaprocess to prepare the graft copolymer are tertiary c-rylate, 16.5 percent by weight of hydroxyethyl acrybutyl peroxide, cumene hydroperoxide, azobisisobulate, 25 percent by weight of Cardura E ester an tyronitrile and the like. To prepare the Ester Group (B) 13.5 percent by weight of phthalic anhydride. esterification catalysts, such as quarternary bases or One method for preparing the graft copolymer used salts as benzyltrimethylammonium hydroxide, benzylin this invention is to first form Est r p y trimethylammonium chloride, octadecyltrimethylamacting in about an equal molar ratio the above hydroxymoni m hl id r an amine, such as triethylamine, alkyl monomers, the anhydride and the glycidyl ester. can b d This esterification product is then reacted with the The graft copolymer preferably hasa relative i backbone monomers and the hydroxyalkyl monomers, ity of 0.9 to L4. The-relative viscosity" is the value obtained by dividing the efflux time of a solution of the polymer by the efflux time of the solvent used to form the above polymer solution. The efflux times are measured according to the procedure of ASTM-D-445-46- T, Method B, using as the polymer solution 0.25 grams of the polymer in 50 cubic centimeters of ethylene dichloride as the solvent. The efflux times are measured at 25C. in a standard apparatus, sold under the designation of a modified Ostwald Viscometer.
The polymer solution resulting from the aforementioned process is suitable for direct use in the preparation of the novel coating compositions.
The polyester used in the novel coating composition of this invention preferably is the esterification product IQ an aliphatic glycol having 2-8 carbons or an olefin oxide having one oxirane group and containing 2-14 carbon atoms, and
2. an aromatic dicarboxylic acid or a saturated aliphatic dicarboxylic acid having 4-14 carbon atoms.
The linear polyester is hydroxyl terminated, has a weight average molecular weight of l,OOO3,000 and a hydroxyl number of 40-80.
The hydroxyl number is the milligrams of potassium hydroxide required to neutralize 1 gram of polyester resin.
Typically suitable glycols used to prepare the polyester have 2-8 carbon atoms and include ethylene glycol, propylene glycol, 1,3-butane diol, 1,4-butane diol, neopentyl glycol, hexylene glycol and octylene glycol and their equivalents.
An olefin oxide having 2-l4 carbon atoms can also be used to prepare the polyester. Typical olefin oxides of this type are ethylene oxide, propylene oxide, butylene oxide, hexylene oxide, octylene oxide, pent'ylene oxide, decylene oxide, laurylene oxide and the like.
Typical aromatic dicarboxylic acids that are used to prepare the polyesters are phthalic acid, isophthalic f acid, terephthalic acid, uvitic acid, cumidic acid and the like. 7
Typical aliphatic dicarboxylic having 4-14 carbon atoms that can be used to prepare the polyester are succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, brassic acid and brassylic acid. Preferred are acids that have 4-l0 carbon. atoms such as succinic acid and azelaic acid.
One preferred polyester which provides a high quality product is the reaction polyester of azelaic acid and butylene oxide having a hydroxyl number of 55-70 and a molecular weight of about l,400-2,800.
The polyester is prepared according to conventional polymerization techniques well known in the art using conventional solvents and esterification catalysts.
To provide a rapid drying and thermosetting composition, a polyisocyanate is added to the resin blend. The molar ratio of reactive isocyanate groups to hydroxyl group is maintained at about 1:1 to l:l.25. A variety of polyisocyanates can be used including aliphatic, cycloalphatic, alkaryl aralkyl, heterocyclic and aryl polyisocyanates. The following is a list of useful polyisocyanates:
butylene-l ,2-diisocyanate,
butylene-l ,3-diisocyanate,
hexamethylene diisocyanate,
octamethylene diisocyanate,
nonamethylene diisocyanate,
decamethylene diisocyanate,
2,1 l-diisocyano-dodecane and the like,
meta-phenylene diisocyanate, para-phenylene diisocyanate, toluene-2,4-dissocyanate, toluene-2,b-diisocyanate, xylene-2,4-diisocyanate, xylene-2,6-diisocyanate, dialkyl benzene diisocyanates, such as methylpropylbenzene diisocyanate, methylethylbenzene diisocyanate, and the like; 2-2 '-biphenylene diisocyanate, 3,3 '-biphenylene diisocyanate, 4,4'-biphenylene diisocyanate, 3,3'-dimethyl-4,4-biphenylene diisocyanate, and the like; methylene-bis-( l-phenyl isocyanate), ethylene-bis-(4-phenyl' isocyanate isopropylidene-bis-(4-phenyl isocyanate), butylene-bis-(4-phenyl isocyanate), hexafluoroisopropylidene-bis-(4-phenyl isocyanate),
and the like; 2,2'-oxydiphenyl diisocyanate, 3,3'-oxydiphenyl diisocyanate, 4,4-oxydiphenyl diisocyanate, and the like; 2,2 '-ketodiphenyl diisocyanate, 3,3'-ketodiphenyl diisocyanate, 4,4' ketodiphenyl diisocyanate, 2,2'-thiodiphenyl diisocyanate, 3,3'-thiodiphenyl diisocyanate, 4,4'-thiodiphenyl diisocyanate, and the like; 2,2'-sulfonediphenyl diisocyanate, 3,3-sulfonediphenyl diisocyanate, 4,4'-sulfonediphe'nyl diisocyanate, and the like; 2,2'-methylene-bis-(cyclohexyl isocyanate), 3,3'-methylene-bis-(cyclohexyl isocyanate), 4,4'-methylene-bis-(cyclohexyl isocyanate), 4,4'-ethylene-bis-(cyclohexyl isocyanate), 4,4-propylene-bis-(cyclohexyl isocyanate bis-(para-isocyano-cyclohexyl)sulfide, bis-(para-isocyano-cyclohexyl)sulfone, bis-( para-isocyano-cyclohexyl )ether, bis-(para-isocyano-cyclohexyl)diethyl silane,
- bis-(para-isocyano-cyclohexyl )diphenyl silane,
bis-(para-isocyano-cyclohexyl)ethyl phosphine oxide,
bis-(para-isocyano-cyclohexyl)phenyl phosphine oxide,
bis-(para-isocyano-cyclohexyl )N-phenyl amine,
bis-(para-isocyano-cyclohexyl )N-methyl amine,
bis-(4-isocyano-phenyl)diethyl silane,
bis-(4-isocyano-phenyl)diphenyl silane,
dichloro-biphenylene diisocyanate, bis-(4-isocyanophenyl)ethyl phosphine oxide,
bis-(4-isocyano-phenyl)phenyl phosphine oxide,
bis-(4-isocyano-phenyl)-N-phenyl amine,
bis-(4-isocyano-phenyl)-N-methyl amine,
3 ,3 "-dimethyl4,4 -diisocyano biphenyl,
3,3-dimethoxy-biphenylene diisocyanate,
2,4-bis-( B-isocyano-tbutyl )toluene,
para-bis-( 2-rnethyl-4-isocyano-phenyl )benzene,
para-bis-( l l -dimethyl-5-amino-pentyl )benzene,
3,3 '-diisocyano adamantane,
3,3'-diisocyano biadamantane,
3 ,3 "-diisocyanoethyl-l ,l -biadarnantane,
l ,2-bis-( 3-isocyano-propoxy )ethane,
2,2-dimethyl propylene diisocyanate,
3-methoxy-hexamethylene diisocyanate, 2,5-dimethyl heptamethylene diisocyanate, S-methyl-nonamethylene diisocyanate, l,4-diisocyano-cyclohexane, l ,Z-diisocyano-octadecane, 2,5-diisocyano-l ,3,4-oxadiazole, 2)s 2)2 2):; OCN(CH S(Cl-l NCO, OCN(CH N(CH NCO, polymethylene polyphenyl isocyanate; biurets of the formula c NH 12 NCO ocn R10- 0 NH R NCO where R 9 is an alkylene group having 1-6 carbon atoms, especially preferred is the biuret of hexamethylene diisocyanate;
ocn (CHQMJIQH NCO l OCH3 NCO N O no ocr 2 w j 0 CH3 The iron pigment can be mixed with the graft copolymer solution, the resin blend of the graft/copolymer and the polyester with the polyisocyanate or directly with the composition. Other pigments or colorants can be added provided the electrical properties of the composition are not changed.
Preferably, about 001-1 .0 percent by weight, based on the weight of the film-forming binder of the novel composition, of a catalyst is added to the coating composition to accelerate cross-linking of the resin blend and the polyisocyanate. Typically useful catalysts are as follows: the organo tin catalysts such as butyl tin dilaurate, dibutyl tin di-2-ethylhexoate; stannous octoate, stannous oleate, and the like; zinc naphthenate, and cobalt naphthenate; vanadium acetyl acetonate, zirconium acetyl acetonate, acetyl acetonate titanate and the like; tertiary amines such as triethylene diamine, triethyl amine and substituted morpholines.
To prevent premature cross-linking which causes gellation of the novel compositiomthe polyisocyanate is added to the resin blend just before the composition is applied. Also, to reduce settling of the carbonyl iron pigment in the composition, the pigment is mixed into the binder just before application.
The composition can be reduced to an application viscosity using conventional solvents and can be applied by conventional techniques such as spraying, brushing, flow coating, dip coating, coil coating, roller coating and the like. The coating is then air dried after application providing finishes of 0.5- mils in thickness. To provide a coating with radar absorbing characteristics, a dried coating of 10-75 mils preferably 20-50 mils is required. These thick coatings are usually applied in several layers allowing the coating to air dry between each layer. The coating can also be baked at about 60150C. to increase the rate of cure of the finish.
The novel coating composition can be applied directly over metal substrates such as steel, aluminum, wood or plastics or the composition can be applied over treated primed or previously painted substrates.
By changing the pigmentation of the novel composition, for example, substituting iron oxide or chromium oxide for the carbonyl iron pigment, provides a composition useful as a coating for recording tapes. The unpigmented composition can be used as a finish for automobile bumpers or as a finish for wood.
The following Examples illustrate the invention. All quantities are on a weight basis unless otherwise indicated.
EXAMPLE 1 A graft copolymer solution is prepared follows: Parts by weight. Portion 1:
Ethylene glycol monoethyl ether acetate 210.41 VM & P Naphtha 4-1. on lhthalie anhydride 64. 82 Benzyl trimethyl ammonium hydroxide 02 Portion 2:
Propylene glycol l H. 5-l Methyl methaerylate monomer 2. 27 Hydroxy ethyl aerylate monomer 120.45 Cardura E ester (21 mixed ester described 111 U.S. lat. 3,275,583, issued Sept. 27, 1066, and is a glycidyl ester of a synthetic tertiary carboxylic acid of the formula 0 l| Oll -CIt-(llh-n-(l-lt where R is a tertiary aliphatic hydrocarbon group of 8-10 carbon atoms) 1.3K Ethylene glycol monoetllyl ether act-later. 5. U0 lorlion 3:
Ethylene glyeol monoelhyl ether act lnte 5. till lorl ion 4:
Ethylene glycol mononthyl ether acetate...
and v CH3 CH I I ocNCH c CH2CH ca ca nco The ingredients of Portion l are blended together and charged into a reaction vessel equipped with a stirrer and a reflux condenser. Portion l is heated to its reflux temperature. Portion 2 is premixed and slowly added over a 2-hour period to the reaction mixture while the reaction mixture is held at its reflux temperature. Portion 3 is then added and the reaction mixture is held at its reflux temperature for at least 4 hours and continued at reflux until an acid number of 3.5 is reached. Portion 4 is then added and the polymer solution is cooled to room temperature.
The resulting graft copolymer solution has a Gardner Holdt viscosity at 25C. of U-X, and acid number of 2-4 and a polymer solids content of 5456 percent.
- The graft copolymer is the polymerization product of styrene/methyl methacrylate/hydroxyethyl acrylate/ fCardura E esterjphthalic anhydride in a weight ratio of 30/l5/l6.5/25.0/l3.5.
A graft copolymer and catalyst solution is prepared by blending together the following ingredients:
Parts By Weight Graft copolymer solution (prepared above) 400.0
Xylene 137.7
Catalyst solution (0.2% dibutyl tin dilaurate in ethylene glycol monoethyl ether acetate) l2.3 Total 550.0
A resin blend solution is prepared by blending together the following ingredients:
A coating composition is then prepared by thoroughly biending together the following ingredients:
Parts By Weight Resin blend solution (prepared above) 100.0
lsocyanate solution (75% solution of the biuret of hcxamethylene diisocyanate in'cthylene glycol monoethyl ether acetate) 37.8
-Continued Parts By Weight Carbonyl iron pigment (particle size 69 microns) 274.0 Total 41 l .8
An aluminum panel is grit blasted with a No. grit and a wash primer is applied and air dried. The wash primer is a composition of polyvinyl formal and phosphoric acid. Nine coats of the above prepared coating composition are sprayed onto the panel and the panel is baked at 60C. for 1 hour. Another 9 coats of the abovecoating composition are applied and the panel is baked at 60C. for 12 hours and then at C. for 48 hours and then at 200C. for 1 hour.
The resulting finish is 45 mils thick and has radar absorbing characteristics, excellent flexibility as illustrated by the panel bend test and good adhesion to the metal substrate. When the metal is punctured, the coating adheres to the metal plate and does not shatter or chip away from the point of puncture.
EXAMPLE 2 A coating composition is prepared by blending the following ingredients:
Parts By Weight Resin Blend solution (prepared in Example I) 100.00
lsocyanate solution (described in Example l) 37.80
Methylethyl ketonc l5.00 Total 152.80
The above ingredients are thoroughly blended together and then sprayed onto a wood gum stick and baked for 60 minutes at about 50C. The resulting finish is clear, glossy and abrasion resistant.
EXAMPLE 3 A coating composition for a recording tape can be prepared as follows:
Parts By Weight Resin Blend solution (prepared in Example l) loom) lsocyanate solution (described in Example l) 37.80
iron oxide pigment (recording tape grade 260.00 Total 397.80
wherein the film-forming binder consists essentially of l. a resin blend of 50-85 percent by weight of a graft copolymer having a backbone of polymerized monomers selected from the group consisting of polymerized monomers of anaromatic hydrocar-' .bon having vinylene groups, an alkyl acrylate, an alkyl methacrylate, acrylonitrile, methacrylonitrile and mixtures thereof wherein the alkyl groups have 1-8 carbon atoms and having ester groups attached directly to its backbone, said ester groups comprising about to 75 percent of the total weight of the polymer and consisting essentially of Este r Group (A) ..O-R-OH and Ester Group (13) selected from the group n l n u C 0 R O C- C 2. a polyisocyanate wherein the molar ratio of isocyanate to hydroxyl of the resin blend is about 1:1 to about 1:125; and the coating composition contains about 50-90 percent by weight, based on the weight of the film-forming binder, of uniformly dispersed carbonyl iron pigment having a particle size of 0.5 microns.
2. The coating composition of claim 1 having a' bindercontent of 30-60 percent by weight and wherein the binder consists essentially of a polymer blend 60-80 percent by weight of the graft copolymer, -40 percent by weight of the polyester and the molar ratio of isocyan'ate to hydroxyl is maintained at 1:1.
3. The coating composition of claim 2 wherein the graft copolymer has a backbone consisting essentially of styrene and an acrylic ester selected from the group consisting of an alkyl methacrylate, an alkyl acrylate and mixture thereof in which the alkyl group contains 1-8 carbon atoms; in which R is a saturated hydrocarbon group having 2-4 car- 'bon atoms,
R is an aromatic radical, and
R is a tertiary hydrocarbon group having 8 through 10 carbon atoms.
4. The coating composition of claim 2 wherein the polyester consists essentially of o o o H ll 1 ll II I -C-O-R-O-C-R-C-O-C- consisting of ll 3 CH o c R taining 2-l4 carbon atoms and ii. an aromatic dicarboxylic acid or a saturated aliphatic dicarboxylic acid having 4-14 carbon atoms; wherein the polyester has a weight average molecular weight of l,0003,000 and a hydroxyl number of 40-80; and
1. an aliphatic dicarboxylic acid having 4-10 carbon atoms and 2. an aliphatic glycol having 2-8 carbon atoms. 5. The coating composition of claim 2 in which the polyisocyanate is of the formula H vlo C-NH-R-NCO OCN R N 10 g NH R NCO where R is an alkylene group of l-6 carbon atoms.
6. The coating composition of claim 2 wherein l. the resin blend consists essentially of a graft copolymer that has a backbone of styrene and methyl methacrylate and R is ethylene, R is phenylene 9 -o-c-R and R is a tertiary aliphatic hydrocarbon group ment has a particle size of 6-9 microns.
2 3? UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION Patent No. 3, 8 4-3; 593 Dated, October 22, 197
In'ventor(s) a p e a 1 A It is certified that error appears in the above-identified patent and that said Letters Patent are hereby corrected as shown below:
Claim 1, column 13, line 26, after the formula delete comma and insert the following: i
0 v .o o H 03 H- ,11 I -c --o-R-o-c-R-c.-o c-cH cH -o-c-R or mixtures thereof, wherein the molar ratio of" Ester Group (A) to Ester Group (B) is from about 1:1.5 to 122.5;
and wherein l R is a saturated hydrocarbon radical containing 2-10 carbon atoms;
R is selected from the group consisting of alkylene,
vinylene, aromatic, carboxyclic and hetero-radicals, and v R is selected from the group consisting of a saturated v aliphatic hydrocarbon radical having 1' to 26 carbon atoms and an ethylenically unsaturated aliphatic hydrocarbon radical having 12 to 18 carbon atoms and z gf I UNITED STATES PATENT 0mm CERTIFICATE CORRECTION Patent No. 3, 3, 593 Dated October 97 l v t r( Theodore Shell and Joseph A. Vasta It is certified that error appears in the above-identified patent and that said Letters Patent are hereby corrected as shown below:
15-50% by weight, based on the weight of the resin blend of a hydroxyl terminated polyester of (i) an aliphatic glycol having 2-8 carbon atoms or an olefin oxide having one oxirane group and containing Q-l L carbon atoms and (ii) an aromatic dicarboxylic acid or a saturated aliphatic dicarboxylic acid having 4-1 carbon atoms;
wherein the polyester. has a. weight average molecular weight of 1000-3000 and a hydroxy number of 40-80; and
Claim 4, column 15, delete lines 53-67 and column in, delete lines l-B L.
Signed and sealed this 11th day of March 1975.
(SEAL) Attest:
- v C. MARSHALL DANN RUTH C. MASON Commissioner of Patents Attesting Officer and Trademarks
|Citing Patent
|Filing date
|Publication date
|Jun 8, 1977
|Sep 26, 1978
|Tdk Electronics Co., Ltd.
|Coatings for preventing reflection of electromagnetic wave and coating material for forming said coatings
|Nov 26, 1979
|Jul 28, 1981
|E. I. Du Pont De Nemours And Company
|High-solids polyurethane enamel coating composition
|Jul 19, 1979
|Feb 1, 1983
|Graham Magnetics, Inc.
|EMI-Suppression from transmission lines
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|Absorbing coating, its process of manufacture and covering obtained with the aid of this coating
|Feb 13, 1991
|Dec 8, 1992
|Commissariat A L'energie Atomique
|High frequency electromagnetic radiation absorbent coating comprising a binder and chips obtained from a laminate of alternating amorphous magnetic films and electrically insulating
|Oct 18, 1989
|Feb 23, 1993
|Minnesota Mining And Manufacturing Company
|Microwave radiation absorbing adhesive
|Dec 14, 1992
|Aug 24, 1993
|Minnesota Mining And Manufacturing Company
|Microwave radiation absorbing adhesive
|May 17, 1989
|Jan 4, 1994
|Minnesota Mining And Manufacturing Company
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|Jun 5, 1995
|Apr 9, 1996
|The Boeing Company
|Method for making multidimensional ether or ester oligomers
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|Mar 1, 1994
|Aug 13, 1996
|Martin Marietta Corporation
|Electromagnetic-attenuating coating materials
|Jun 5, 1995
|Sep 10, 1996
|The Boeing Company
|Extended end cap monomer for making advanced composites
|Jun 5, 1995
|Nov 12, 1996
|The Boeing Company
|Composites made from multidimensional oligomers
|Jun 5, 1995
|Dec 24, 1996
|Sheppard; Clyde H.
|Methods for making liquid molding compounds using diamines and dicyanates
|Jun 6, 1995
|Feb 11, 1997
|The Boeing Company
|Method of making multidimensional polyesters
|Jun 5, 1995
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|The Boeing Company
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|Magnetic recording medium comprising magnetic particles, binder, and a non halogenated vinyl oligomer dispersant
|Jun 5, 1995
|Jan 6, 1998
|The Boeing Company
|Method for making a polyimide blend
|Jun 5, 1995
|Feb 3, 1998
|The Boeing Company
|Method for making multiple chemically functional oligomers
|Jun 7, 1995
|Feb 24, 1998
|Martin Marietta Corporation
|Electromagnetic attenuating laminate and method for its formation
|Jun 5, 1995
|Apr 14, 1998
|The Boeing Company
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|Feb 12, 1997
|May 26, 1998
|The Boeing Company
|Multiple chemically functional oligomer blends
|Feb 14, 1997
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|Phenylethynyl capped imides
|Sep 5, 1996
|Mar 23, 1999
|Martin Marietta Corporation
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|Oct 21, 1994
|Oct 19, 1999
|The Boeing Company
|Oligomers with multiple chemically functional end caps
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|Akzo Nobel Coatings International B.V.
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|U.S. Classification
|524/424, 524/504, 252/62.56, 428/458, 523/181, 523/137
|International Classification
|Cooperative Classification
|European Classification


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HOME College GA Tech Yellow Jackets Gear GA Tech Yellow Jackets Auto Accessories GA Tech Yellow Jackets Auto Accessories Decals (26 items) Product ID: 659139
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Manufacturer direct items are shipped directly from the manufacturer. These items are not available for international or expedited shipping.
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subset: commoncrawl


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In memory of James Houston "Jimmie" Davis. I remember it being told how great of a governor he was for the state of Louisiana. When I was growing my family loved gospel music and we went to the Jimmie Davis Tabernaacle to listen to the gospel singers. It was a wonderful place to go to. I remember the song "You are my Sunshine", it is a beautiful song. Governor Davis rest in peace.
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Learn more about our dogs and where they come from, rescue dogs are often stereo types as problem dogs but many come from homes just like yours.
We use kennels as a last choice so we are always looking for those special people who are able to foster a dog, whilst we are looking for a forever home.
UK German Shepherd Rescue
in all regions of the UK, everybody is very welcome to join our rescue. We don't discriminate anybody and value everybody for what they can bring to our rescue. All age groups are welcome but you will need to be 21 years and over to work with our dogs due to insurance requirements, all volunteers under 21 are very welcome to fund raise, join in with breed awareness and help educate people with responsible dog ownership.
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Council pounds are not a 'rescue' for people who can't be bothered with their dogs anymore, if you hand your dog into a pound they are not a stray and could be put to sleep within minutes of you leaving them.
You could say you found them, this will give them seven days grace for their owner (you) to never come forward, if the kennels are full other dogs will die because of you. This is a real problem.
For some people, dogs are simply disposable items, for those with genuine reasons needing to rehome rescue offers a lifeline, we often hear people say we stand little or no chance of finding a rescue space as they are full of unwanted pets from people who didn't take into consideration the needs of their pet before owning one, we will always try and help a needy GSD.
If you don't want the responsibility of a dog then please do not get one....!
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Our rescue is big on social media, new dogs shown on our
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a rescue with modern ideas
Welcome to the UK-GSR
We like to do things a little different here at the
simply because we added some common sense into the way we do business. If we wanted you to jump through hoops we would have opened a circus for unwanted clowns, we certainly don't judge people simply because they don't tick all the right boxes on our adoption form, and we don't have any ego tripping staff who make you feel belittled when asking for help.
Instead have a friendly happy rehoming team who view you your family and your home on what you can offer one of our dogs.
That's three simple things that makes a world of difference.
A range of products designed for you
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to save a dog from being put to sleep, secure them from abuse and be treated for life saving medical conditions.
What I don't want is my hard earned money simply being added to the £200,00+ bank account from a good begging story. We call this accumulative fund raising and it doesn't help dogs.
We don't pick the easy dogs to rehome or avoid the sick and elderly that cost money, we rescue what is put in front of us and help those that need us most, and we do this because we are passionate about
German Shepherds
. So if you can
a little something to our shoe string budget we would by very grateful or why not join us in helping save this loyal and deserving breed.
A fencing issue has seen many a good home miss out on adopting a dog that was desperate for a family home, yet remained unwanted in a kennel system because a fence is to low, was this right or wrong?
We know some rescues adopt a "one fence rule" for every adoption regardless of the dogs age or ability, we at the
UK German Shepherd Rescue
add some common sense to our fence rules.
Fencing Policy Explained
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Keep your dogs safe - they are worth more than you think.
Learn more about why you shouldn't offer a dog "
pounds are
not rescues
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What You Should Do
Losing your pet can be one of the worse things that could happen, the not knowing where they are or how they are coping can be very stressful to both you the owner and your lost pet.
The right actions could see a fast and safe return.
Read more on what to do if your loose or find a dog.
UK German Shepherd Rescue Angels- Rescuing & Rehoming German Shepherd Dogs & Puppies throughout the UK
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Jake (Yorkshire)
11 years old - Male
Jake is good with children of all ages
Bruce (Linconshire)
5-1/2 years old - Male
Bruce 5 1/2 year old male, neutered GSD cross Rottie. With Lincoln Dog Rescue.
Twinkle (Wales)
20 months old - Female
She is vaccinated , microchipped, and spayed. Good with other dogs.
Roxie (Shropshire)
13 months old - Female
Roxie is vaccinated and microchipped, fine with children of all ages, not good with cats.
Max (Surrey)
14 months old - Male
Max is entire still, but is vaccinated and microchipped. Fine with other dogs and ok with cats, no children.
Zack (Shropshire)
9 years old - Male
Zack is not yet neutered, hasnt been vaccinated in a few years but is microchipped.
Zack is fine with children from ages 7yrs upwards.


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text:
Survivors recall fateful day
Published: Friday, December 8, 2006 at 4:30 a.m.
Last Modified: Friday, December 8, 2006 at 12:18 a.m.
FLAT ROCK -- Japanese warplanes flew low enough for Ralph Wingerter to shoot at the pilots with a rifle as Hickham Field and Pearl Harbor came under attack the morning of Dec. 7, 1941.
The 85-year-old Etowah resident was a 20-year-old Air Force sergeant stationed at the Hawaii military base when bombs began falling on ships in Pearl Harbor and military aircraft at Hickham Field. Wingerter was working the midnight-to-morning shift and was at the mess hall eating breakfast at 7:30 a.m., just before a bomb took out the hangar where the 22nd Material Squadron was headquartered.
"I had just left the building and if I had been in there a few minutes later, I would have been killed," Wingerter said. "I grabbed a rifle and ran out to the edge of the base. I could see the gunner grinning at me, (and) they were flying low, no higher than a two-story house, enough to take some of them out with rifle fire. Nearly everyone in my squadron was killed."
Wingerter said his squadron was in charge of the engineering work done at Hickham Field and that's why the hangar was targeted.
Wingerter was among the audience that filled the Bo Thomas Auditorium Thursday at Blue Ridge Community College for the third Pearl Harbor Commemorative Ceremony. Thursday marked the 65th anniversary of the day the Japanese attacked Pearl Harbor, the event that launched the United States into World War II.
The West Henderson High and East Henderson High School bands performed the national anthem and a patriotic armed-forces medley following a moment of silence for all those lost at Pearl Harbor. Retired Naval Capt. Vince Colan recognized members of the audience who were Pearl Harbor survivors, military or civilian and surviving spouses in addition to veterans of World War II and all other wars.
One of those survivors, 89-year-old Helen Leverton, remembered Pearl Harbor well. She and her husband, Bill, a Naval officer, and their twin daughters had been stationed in Pearl Harbor for a year at the time of the attack. Leverton was the guest speaker for the ceremony.
"Kimiko, our Japanese housekeeper, and I had just finished feeding the girls (18-months-old) and she took them outside that morning to play," Leverton said. "She came racing back into the house shouting that the radio said Pearl Harbor is being bombed. We were scared to death. We knew war had come. We didn't know where it would lead to or how long it would last. We just knew it was awful."
The ceremony Thursday included a military call to order by the Henderson County Color Guard and the playing of taps. The West Henderson High School AJROTC Cadets performed a flag-folding ceremony during the program.
The sacrifice many Americans made during World War II made an impression on her, said Jessica Green, overall winner of a county-wide essay contest about Pearl Harbor.
"I didn't realize how much Pearl Harbor led us into World War II," said Green, 16. "I'm glad my teacher asked everyone in our class to write an essay because I learned a lot about Pearl Harbor and how if affected our country."
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Lake Harmony is a reservoir in the Pocono Mountains. It enjoys four distinct seasons, which provide endless fun and a myriad of nature-filled activities that are fun for the whole family. The Pocono Mountains are famous not only for their natural scenic beauty, but for the variety of activities available to visitors. People staying near Lake Harmony can spend the day outdoors enjoying nature, and spend their evenings enjoying theater performances and concerts. Whether you are a hiker, biker, skier, snowboarder, botanist or water park lover, Lake Harmony promises a true Pennsylvania mountain experience.
In winter, Jack Frost and Big Boulder Ski Mountains will likely be within five minutes of your...
In winter, Jack Frost and Big Boulder Ski Mountains will likely be within five minutes of your accommodations, so you can ski the slopes, ride a snowmobile, or tube down the mountain. Adventurous visitors who want to try a truly unique winter sport can mush their own dogsled team.
Enjoy the laurel blossoms, daffodils, and native plants exploding in this colorful natural canvas in the spring. Hit the antique shops, specialty stores, and outlet malls to search for bargains or a gift for that special someone at home.
In the summer, you will be near many nature trails where you can walk, bike, or go on horseback through the mountains. Tee off at a championship golf course. Rent a canoe and float on the lake and enjoy the wooded scenery and the rushing waterfalls. If you're traveling with kids, you will love taking them to the New Split Rock Water Park.
Nota: Esta información era correcta en el momento en que fue publicada, pero está sujeta a cambios sin previo aviso. Asegúrate de confirmar todas las puntuaciones y detalles directamente con las empresas concernientes antes de planificar un viaje.


text:
Gcrest will not charge any usage fees for Trickster, however similar to MindArk's Project Entropia and GameOn's Red Stone, items have to be purchased with real-world money in the game. Among the items offered in the game are many fashion-related goods, such as sunglasses and hair coloring sets.
Boot Hill Heroes July 24 • 9:00am PDT/12:00pm EDT
Tales from the Borderlands July 31 • 9:00am PDT/12:00pm EDT
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text:
Full name Steven Andrew Baker
Born May 31, 1976, Herston, Brisbane, Queensland
Current age 40 years 55 days
Major teams Australia Under-19s, North Queensland, Queensland Country
Batting style Right-hand bat
Fielding position Wicketkeeper
Prior to moving to Townsville at the commencement of 1999 he played for Northern Suburbs in the QCA Grade competitions. He represented Queensland Under 17 in 1992-93 and Queensland Under 19 in 1994-95 and then gained selection as the Australian Under 19 keeper in the Test matches played against India Under 19. He has represented Queensland Secondary Schools in the annual competition against New South Wales Secondary Schools. In 1999-00 he appeared for North Queensland and was the Queensland Country wicket keeper for the National Country Championships played in Canberra in January 2000, winning the Fieldsman of the Series award. He holds the record score for Northern Suburbs, having recorded an innings of 238 in second grade . He was educated at Everton Park State School and Everton Park High School and is now a teacher at William Ross High School, Townsville where he conducts a cricket school of excellence. (Warwick Torrens, December 2000)
Australia Under-19s 1994/95
Club: Brothers, Townsville
Pakistan, press-ups and national redemption
The themes of redemption and rehabilitation had been a constant companion for Pakistan in the build-up to what proved to be an epic first Test, but it was only in that moment of victory that the true significance of their 75-run win could be understood
Pakistan's thrilling triumph at Lord's was underscored by their captain's serenity
West Indies need to paper over bowling cracks
The hosts' pace attack, with a combined experience of 31 Tests and 56 wickets, is a candidate for being their weakest ever, yet India cannot simply show up and expect to win
Yasir's 13 going on 100, and 42-year-old centurions
Also, losing ten-fors, and back to back Tests at Lord's
England played a full part in a compelling Test, but if they are to continue to evolve as a Test side the top order has to shape matches
West Indies need to paper over bowling cracks (62)
The hosts' pace attack, with a combined experience of 31 Tests and 56 wickets, is a candidate for being their weakest ever, yet India cannot simply show up and expect to win
Herath versus the mighty Australians? (45)
Sri Lanka's lead spinner must feel like a bus driver in charge of a spluttering vehicle as the hosts strive to challenge a strong Australian side
Australia seek returns on Mitchell Marsh investment (37)
Australia will be hoping that Mitchell Marsh grows from an emerging allrounder into a top-quality allrounder by the end of the Sri Lanka tour
Cook braves criticism as England play it safe (34)
There was enough logic in Alastair Cook's decision not to enforce the follow-on to make it understandable at worst and reasonable at best
Why close-catching standards have dropped (26)
Technique and anticipation are important for close-in fielding. Many of today's fielders lack both


text:
11th Hour - Women's Murder Club 11 (Hardback)James Patterson
Hardback Published: 01/03/2012
- Not available
Lindsay Boxer is pregnant at last! But her work doesn't slow for a second. When millionaire Chaz Smith is mercilessly gunned down, she discovers that the murder weapon is linked to the deaths of four of San Francisco's most untouchable criminals. And it was taken from her own department's evidence locker. Anyone could be the killer - even her closest friends. Lindsay is called next to the most bizarre crime scene she's ever witnessed: two bodiless heads elaborately displayed in the garden of a world-famous actor. Another head is unearthed in the garden, and Lindsay realises that the ground could hide hundreds of victims. A reporter launches a series of malicious articles about the cases and Lindsay's personal life is laid bare. But this time she has no one to turn to - especially not Joe.
Publisher: Cornerstone
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ReviewsView all Write your review
"Only OK, for die hard fans."
This starts out really good - decaptitated skulls are left on the patio of a disgraced movie star in his secluded mansion enclosure. There is also a vigilante doing the job of the SFPD. Lindsay and her friends are... More
"Keeps you guessing"
Another good yet quick read.
We would love to hear what you think of Waterstones. Why not review Waterstones on Trustpilot?


text:
- News tagged "lte"
Wednesday, 2 Jul 2014
Samsung Unveils 4.5-Inch Galaxy S5 Mini, No Plans to Launch It in Singapore
Samsung unveiled a smaller variant of its Galaxy S5 flagship smartphone. Known as the Galaxy S5 Mini, the 4.5-inch smartphone runs on a quad-core 1.4GHz processor, 1.5GB RAM and Android 4.4 KitKat.
Thursday, 26 Jun 2014
Late to the Party but MyRepublic Wants to Be Fourth Local Telco Provider
If things go according to plan, myRepublic may be the fourth local telecommunications company. The two-year old local broadband services provider intends to challenge the three incumbent telcos by bringing its disruptive energy to the fray. Read on to find out if it offers what the consumer wants.
Friday, 6 Jun 2014
LG Sold 100,000 Units of the G3 Smartphone in Five Days after Launch in Korea
The Korea IT Times reported that LG sold over 100,000 units of its G3 flagship smartphone in Korea just five days after its launch. To put that into context, the G3 is selling more than twice faster than its predecessor, the G2.
Monday, 2 Jun 2014
ASUS Announces the MeMO Pad 8, Claims Title as World's Lightest 8-Inch LTE Tablet
ASUS today announced the world's lightest 8-inch LTE tablet, the MeMO Pad 8 (ME581CL) at Computex 2014. It also unveiled two other models, the MeMO Pad 7 (ME176C) and MeMO Pad 8 (ME181C). Hit the link to find out more.
Wednesday, 28 May 2014
M1 and StarHub Announce Plans to Upgrade 4G Networks to Support 300Mbps
Both M1 and StarHub have announced their plans to upgrade their 4G networks to support download speeds of up to 300Mbps.
SingTel Rolls Out 300Mbps 4G Service, Offers 4G Roaming in China
SingTel today announced that it is the first telco in Singapore to roll out live 300Mbps 4G service. It is also the first telco in the country to offer 4G data roaming in China.
LG Unveils the 5.5-Inch G3, Comes with 2K Display and Laser Auto Focus
LG finally took the wraps off its G3 flagship smartphone. It comes with a 5.5-inch 2K (also known as Quad HD or QHD) display, Qualcomm Snapdragon 801 quad-core 2.5GHz processor and a 13-megapixel rear camera. Read on to find out more.
Friday, 23 May 2014
4.5-Inch LG F70 with 4G LTE Connectivity Available in Singapore from May 24
LG Singapore today announced that the F70 - an entry-level Android smartphone with a 4.5-inch IPS display and 4G LTE connectivity - will be available for purchase from May 24.
Tuesday, 20 May 2014
5.5-Inch HTC One (M8) Prime with Ceramic Chassis Rumored to Launch in September
HTC is rumored to be launching a 5.5-inch variant of the One (M8) in September, which comes with a ceramic chassis made up of aluminum-silicone material.
Thursday, 15 May 2014
HTC Unveils the 4.5-Inch One Mini 2, Comes with Sense 6 and 13MP Rear Camera
HTC today announced the 4.5-inch One Mini 2, a smaller variant of its flagship One (M8) smartphone. It comes in three colors: gray, silver and gold. Unfortunately, HTC has no plans to bring the device into Singapore.


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Helmut Lang
Sheer Turtleneck Top
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Sheer jersey turtleneck top with long sleeves. Available in Black. Made in U.S. Cotton/viscose. Dry clean.
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Check BNN and Bulbanews for up-to-date Pokémon news and discuss it on the forums or in our IRC channel #bulbagarden on irc.systemnet.info.
Foreign Pokédex entries
The Meister (Japanese: マイスター Meister) is a character in Pokémon Diamond, Pearl, and Platinum who upgrades the player's Pokédex with the ability to store entries in foreign languages. He lives in a small house on an island on Route 226. His sprite is the same as the Hiker Trainer class.
After he upgrades a player's Pokédex, he offers to trade the player a German Magikarp in exchange for a Finneon. This adds Magikarp's German entry to the player's Pokédex.
In the German-language versions of the games, the Meister will trade an English Magikarp. His name, in these games, is English in origin: The Master.
Pokémon with foreign Pokédex entries
Diamond and Pearl
In Diamond and Pearl, fourteen Pokémon can have foreign Pokédex entries registered. The entries come from the LeafGreen Version of the language in question when said Pokémon is received from a foreign game.
In Pokémon Platinum, Meister's upgrade instead allows the player to record foreign Pokédex entries for all 493 Pokémon. These entries are the ones used in that language's version of Diamond.
HeartGold and SoulSilver
In Pokémon HeartGold and SoulSilver, the foreign Pokédex entries are the same as in Platinum. Unlike the previous games, the ability to collect foreign Pokédex entries is available from the start.
Black, White, Black 2 and White 2
In Black, White, Black 2, and White 2, the foreign Pokédex entries are also the same as in Platinum, just like native entries. However, only non-Unova Pokémon receive foreign Pokédex entries. For Black and White this is likely because foreign entries and names of Unova Pokémon had not been finalized yet at the time of the release of the Japanese release of Black and White. However it is unknown why they were not included for Black 2 and White 2 as foreign Pokédex entries for Unova Pokémon would have been available from international releases of Black and White. The player is now able to collect Korean entries.
- Wobbuffet is the only fully evolved Pokémon that is part of a multi-stage evolution line as of Generation IV that one can collect a foreign Pokédex entry for in Diamond and Pearl.
- It is not possible to collect any foreign Pokédex entries of any Generation IV Pokémon in Pokémon Diamond and Pearl even though this feature of the Pokémon games debuted in those games. This may be due to the entries not having been translated into other languages yet. This is addressed in Pokémon Platinum, where foreign Dex entries for all Pokémon are present, and are also present in Pokémon HeartGold and SoulSilver and Pokémon Black and White.
- The four Pokémon put up and asked for in the GTS event in 2007 (Roselia, Psyduck, Heracross, and Ponyta) all have foreign Pokédex entries.
- It is possible to become stranded on the Meister's island after trading with him. If the traded Finneon was the only member of the player's party that could learn Surf, and no Pokémon in the player's party have Surf, Fly, or Teleport, the only way to leave would be to level up "Foppa" until it evolves and can learn Surf as a Gyarados, by fishing for battles or through Rare Candies. As it is possible to progress through the game fully without picking up any fishing rods or have no Poké Balls left by the time the player arrives on the island, yet still have Magikarp (through the trade), and since Rare Candies can be used up, players can become stranded on the island until they restart their game, or use a cheat code to leave.
- The Meister's Trainer ID number is 53277.
- It is possible that the reasons why any Pokémon traded from Korean language cartridges of the fourth generation games do not maintain their original names in their own languages once they are traded into the English, Spanish, French, German, Italian, or the Japanese versions is because none of these versions support any languages outside of the six given languages. This is also why they do not appear in the foreign language categories in the Pokédex. This was fixed in Generation V.
- In Pokémon Diamond and Pearl, the Meister's speech contains a French grammatical error; the words "Je suis desolee" should be "Je suis desolé".
Related articles
|This game character article is part of Project CharacterDex, a Bulbapedia project that aims to write comprehensive articles on each character found in the Pokémon games.
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Yummy Pumpkin Cake
Total Time
Prep 15 mins
Cook 1 hr
How to Make a Pull Apart Pumpkin Cake I got this recipe from http://www.homeandfamilyezine.com/2007/10/pull-apart-pumpkin-cake-recipe.html
Ingredients Nutrition
- 1 (15 ounce) can pumpkin puree
- 1 (12 fluid ounce) can evaporated milk
- 3 eggs
- 1 cup white sugar
- 4 teaspoons pumpkin pie spice
- 1 (18 1/4 ounce) package yellow cake mix
- 3⁄4 cup butter, melted
- 1 1⁄2 cups chopped maple walnuts
- Get out that big ole' mixing bowl and combine pumpkin, milk, eggs, sugar and spice.
- Pour into your greased 9 x 13 inch baking pan.
- Sprinkle the dry cake mix over top of the mixture.
- Sprinkle, don't stir.
- Drizzle melted butter over it all and top it off with a handful or two of chopped walnuts.
- Bake for 1 hour at 350 degrees F or until toothpick comes out of center clean.
- Best served with a scoop of vanilla ice cream on the side.
Most Helpful
Easy to make & wonderful on the taste buds, so it's a 5-star cake in my book! It was a great holiday treat, & a nice change from the usual pumpkin pie! Actually it'd be a very nice treat anytime of the year! Thanks for sharing the recipe! [Made & reviewed in the current Let's P-A-R-T-Y! event]
This was good. The name is kind of fooling. There is nothing to pull apart. It's kind of like a pumpkin crisp.
This was terrific. I made it for a ladies fellowship at church and it went over very well. I'm making it for thanksgiving as well. Definitely a keeper!


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About Us
Repayment Calculator
Mandurah Office
Green House Dollars
Our Staff
Andrew Butterly
Mobile :0410 588 803 |
Andrew, a leading Real Estate Agent for Pinjarra and surrounding areas, is the founder and licensee of Green House Realty.
Andrew knew before he left school that his passion was real estate and began working in the industry at the age of 21 in 1992.
During that ...
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Ian Mullett
Sales Representative
Mobile :0404 142 128 |
Ian, is one of our best Real Estate Agents for Pinjarra, Ravenswood, Dwellingup, Waroona and surrounding areas.
Looking for a challenge after a long career in sales, Ian decided to try his luck in real estate in 2012. He not only loves dealing with clients but enjoys that eve...
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Ian Lay
Sales Representative
Mobile :0407 479 747 |
Ian began his career in real estate in 1998 and has been in the sales sector for over 27 years. He has spent these 27 years specialising in the Peel Region.
Ian loves the life style that comes with being a Sales Representative; he also loves the whole process of selling, from listi...
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Amanda Gesche
Director of Property Management
After following her mother's footsteps in 1991 and beginning her career in real estate, Amanda says real estate runs in her blood, particularly property management.
Having worked as a Senior Property Manager for years, Amanda enjoys the challenges of her role as much as she enjoys...
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Jayne Colgan
Property Manager
Jane has lived in the Shire of Murray for 26 years, she loves that the area is central to everything she needs while maintaining a peaceful and relaxed lifestyle.
Having recently made the change to real estate Jane is thriving in her role as a property manager. She enjoys working ...
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Kerry Willmott
Property Manager
Kerry took several years off to raise her children all the while keeping up to date with the Real Estate market. It seems Real Estate has always been a larger part of Kerry's life, with her own mum working Real Estate for over 30 years, it's no wonder Kerry can't stay away from the industry! ...
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Leonie Fitzgerald
Property Manager
Having always had a keen interest in building and selling properties Leonie started her career in real estate in 2010 after successfully managing her own rental property.
She has a passion for home décor and enjoys helping others through the difficult process of buying, selling an...
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Tiffany Kooymans
Property Manager
After a career change in early 2014 Tiffany began working in real estate, when she qualified as a Property Manager. She enjoys the variety of skills required in succeeding in her new role, from having to organise everything to getting out and dealing with clients face to face and learning every d...
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Tracey Chrystal
Property Manager
Tracey pursued her passion for properties and home decor and begun her real estate career in 1989. Her love of houses has been her driving point throughout her career.
Tracey, a people person with a caring nature who gets on well with everyone she meets is one of the nicest proper...
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Julie Saffin
Office Administrator
Julie began working in Real Estate when she moved to Western Australia in 2011. She fell for Real Estate due to the growing market and great job opportunities that did not involve the mining sector. She loves that Real Estate allows her to constantly work with and meet new people.
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Madyson Butterly
Online Marketing
Madyson is the face behind our online media, from the various websites we manage to our growing facebook page. She joined the company in 2010 after graduating high school and has never left. While she completes her degree she is only available in the office on certain days.
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Emma Falshaw
Sales Coordinator
Emma originally joined the Green House Realty team as a fresh new face to the real estate industry as our friendly receptionist at the beginning of 2013.
After spending just over a year as the team's receptionist she has moved on to study her real estate course and become the Sal...
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Rhiannon Tomlinson
Rhiannon began working in real estate in the beginning of 2014, after completing high school. She was told about the opportunity through a staff member at the local high school and says although she hadn't thought about the real estate industry she is beginning to love it.
Rhiannon ...
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My best wishes, May
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Current Tally
Alakazam: 2
Gengar: 1
Garchomp: 1
Voting ol chompers.
Current Tally
Alakazam: 2
Gengar: 1
Garchomp: 1
Voting ol chompers.
Spoiler:- Want my Friend Code?:
Give me a reason to give you it then.
Voting out Alakazam.
Voting mini-alakazam.
I will keep making that joke until it's gone.
Dynamite ~ Hologram ~ Plundermouse ~ Alto~ Lolly ~ Flirt
Badges: 7
Deaths: 7
Alakazam, that Magic Guard is lost.
FireRed Nuzlocke Team:
AlphaSapphire Nuzlocke Team:
Voting Garchomp cuz I'll be nice to Gengar this time.
New Face-Offs coming soon! If you're curious about what they are then just click the spoiler:
Spoiler:- Spoiler:
Pokkén Tournament Fighters Face-Off
Video Game Console/Handheld Face-Off
Fire Emblem Character Face-Off
Fairy Type Pokemon Face-Off
Alakazam out.
Pokémon XY
Kalos, Where Dreams and Adventures Begin!
Gengar out.
I'll vote Alakazam. Don't like it that much.
Credit to Rayquaza The First
I can't seem to stay here, can I?
I'll vote banette once more.
Look up!
I vote Garchomp.
Join Hachiko's PokeKingdom today!
*Credit to Conquer Phoenix
I want to Banette or Aerodactyl, but since Banette already has a vote, then Banette
I'll vote for Alakazam.
Credit to cloneydew2000 for the sprites.
Current Tally Cause Our Tallyists.....Iunno Here's The Tally:
Alakazam: 10
Garchomp: 3
Gengar: 2
Banette: 2
Voting Gyrados
Pokemon isn't real, I'm sorry
Current Tally:
Alakazam: 10
Garchomp: 3
Banette: 3
Gengar: 2
Gyarados: 1
| Backloggery | MyAnimeList | Last.fm | VGMdb | Banner adapted by me from here. |
Voting Alakazam.
Gardrevereior please teehee
Switching from Gengar to Garchomp. I'd rather see it go than Alakazam
I switch from Banette to Garchomp
Current Tally:
Alakazam: 12
Garchomp: 6
Banette: 2
Gengar: 1
Gyarados: 1
I'd rather see Alakazam gone than Garchomp, so I'm voting for the former.
Alakazam I guess.
How the hell was Mawile saved...
Life's obstacles are like a Snorlax. They can impede forward progress, they may weigh heavily on you, and you might need to seek others out to overcome them. But if you keep working at it, they can indeed be overcome, and open up new avenues for you to explore.
Voting out Garchomp.
Stationary -- Soda Pop -- Humans of Hoenn -- 24 Months -- Exit Interview
Trainers of Hoenn (Tumblr) -- Author's Profile
All images were obtained from Serebii.net.


text:
Nice Riad but is not like what i expected from photos, all other reviews speck about the positive things, but i allow my self to explain some negative things ; my room was not that clean, there was some dusts not cleaned (I am asthmatic, so i worried about that ). when i wished to use the sanitary for first time i saw trace of urine was not cleaned on the sanitary, so i cleaned it my self before setting on it. For 3 consecutive days i found cockroach which comes from pipe lines, so i kept my bags closed all time there to avoid some getting inside them. You should remix the hot & cold water at Shower place a lot of times as the pressure of water is variable al the time. in my room there was not TV eventhough they say in their website that there is TV. Internet is only in hall. the trip to the desert which is proposed by the owner of the Riad is not like which was shown in the album of photos, the trip to the desert was 12 hours (instead of that the owner has said 4-5 hours) , and we did not reach the real desert where should be the real sand. but the nice thing is riding the camel for about one hour.
There is miscommunication between the owner and the staff, as we have discuss things with the owner and made conclusions and she did not communicate them to staff of hotel. A/C is wonderful, but the remote control does not change the degree of temperature wanted.
- Official Description (provided by the hotel):
- Riad Jonan is a traditional house of Marrakesh recently renewed. It offers you all the comfort of a modern hotel in a sumptuous decor . You have the choice between 10 comfortable rooms complemented with hand made furniture from the craftsmen of the Medina. All rooms are en-suite and have heating and air-conditioning. Some have satellite television, English speaking channels and music system, a safe and a mini-bar. The breakfast is a delightful moment at Riad Jonan, and is usually served in the courtyard around the fountain or on the roof terrace. Our cook can prepare all kinds of delicious traditional Moroccan dishes (couscous, tajines, vegetable salads... ) All homemade with fresh products, or little snacks. Our staff, all English speaking, can help you in any situation and can advise you excursions and visits,and book them for you. ... more less
- Reservation Options:
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- Also Known As:
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Charlie's Angels 1976 | TV Show Watchlist
Season 3, Episode 12 Angels Belong in Heaven
First Aired: December 6, 1978
An embezzler uses Kelly's best friend to set up Kelly for murder. Gorman: Don Galloway. Sabrina: Kate Jackson. Sally: Tracy Brooks Swope. Kris: Cheryl Ladd. Jellek: Lloyd Bochner. Norton: Eddie Firestone. Jarvis: Barry Quinn. Stashu: John Voldstad.
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M & A Exxon
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18 Morris Tpke
Summit, NJ 07901 USA
Summit, NJ 07901 USA
(908) 277-6170
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text: A friend and I met for an early dinner. The restaurant has a very pleasing atmosphere. The service was attentive without being overdone. Our server did an excellent job. Both of us were happy with our food. A salmon salad and pork tenderloin. Well prepared and presented. Always a favorite place.


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Maria Callaloro added the Spanish common name "viborera" to "Echium vulgare L.".
Maria Callaloro added the Spanish common name "Cerifllor" to "Cerinthe major L.".
Joshua McDill marked "Nama hispidum" as trusted on the "Nama hispidum" page.
C. Michael Hogan marked "National Distribution" as hidden on the "Cryptantha setosissima (Gray) Payson" page.
C. Michael Hogan commented on an older version of National Distribution:
Lacks detail. Unsourced. Other sourced entry on eol page holds more detail.
C. Michael Hogan marked the common name "bristly catseye" in an unknown language from "Cryptantha setosissima (A. Gray) Payson" as trusted.
C. Michael Hogan marked the common name "bristly cryptantha" in an unknown language from "Cryptantha setosissima (A. Gray) Payson" as trusted.
C. Michael Hogan added the English common name "bristly hiddenflower" to "Cryptantha setosissima (A. Gray) Payson".
Bob Corrigan added text to "Text" on "Cryptantha angustifolia (Torr.) Greene".
Panamint cat's eye (Cryptantha angustifolia) - also known as the Popcorn...
Bob Corrigan added the English common name "borage family" to "Boraginaceae".
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Lorna, Editor's Archive
Ashley Tisdale in J Brand
Ashley Tisdale held on to her hair as the wind blew it around after leaving the Byron & Tracey Salon in Beverly Hills, California yesterday. Ashley went in to get a touch up on her new blonde locks. I wonder what she went blonde again for?
She chose to wear a pair of J Brand 901 leggings in grey with knee high boots and a slouchy sweater. I absolutely love this look on her! Her Chanel bag compliments the outfit too. I think she looks great! I love neutrals paired together, they just blend so well and work. On another note though, that is one huge Balenciaga! You can buy J Brand jeans online at Singer22.com.
Halle Berry in Raven Denim
Halle Berry was seen doing some grocery shopping in Beverly Hills, California a couple of days ago. It looks like she didn't want to crush her baguette so she carried it to the front seat of the car.
Halle chose to wear her Raven Denim shorts again for the errand. Halle seems to live in shorts at the moment. I know it's probably really hot in LA but I find that she favours shorts over jeans whenever she can. I would love to see Halle in some Siwy shorts! Preferably the Love Song Alexa shorts I just reviewed here.
Images courtesy of INFdaily.com
Jennifer Garner in Earnest Sewn & Ben Affleck in RRL
Jennifer Garner and her husband Ben Affleck were seen going to get some dinner with their daughter Seraphina in Los Angeles, California. Jennifer was also seen going to pick up Violet from her ballet practice.
Jen chose to wear a very old pair of Earnest Sewn jeans while Ben wore his RRL jeans for the day. It's really nice to see Jen wearing a tighter fitting pair of jeans that are really flattering on her actually, I really like how they look on her! I've never tried Earnest Sewn jeans though. How many of you are fans of the brand?
Images courtesy of INFdaily.com
Tom Felton in Tommy Hilfiger
Tom Felton attended the 2011 Teen Choice Awards which were held at the Gibson Amphitheatre in Universal City, California. He accepted some Harry Potter awards on stage as well.
Tom chose to wear a grey pair of Tommy Hilfiger jeans with a Joe's cream and black shirt. I think he looks really good in this outfit. Everything seems to fit him well. I always find it weird seeing Tom smile though, I am so used to his looks as Malfoy!
Images courtesy of Wireimage.com