text:
|Publication number
|Publication type
|Application number
|Publication date
|Aug 27, 1996
|Filing date
|Jul 7, 1995
|Priority date
|Jul 7, 1995
|Fee status
|Publication number
|Cary Hong
|Original Assignee
|United Microelectronics Corporation
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (1), Referenced by (15), Classifications (12), Legal Events (6)
|External Links: USPTO, USPTO Assignment, Espacenet
1. Field of the Invention
This invention relates to a method for manufacturing a full-feature EEPROM (Electrical Erasable and Programmable Read Only Memory) cell, and more particularly to a manufacturing method for a full-feature EEPROM cell which allows the device to be made smaller than is possible by conventional manufacturing techniques.
2. Technical Description
A conventional full-feature EEPROM cell comprises a selective-gate transistor 10 and a stacked-gate transistor 12 which are made on a substrate 1 as shown in FIG. 1, wherein the selective-gate transistor 10 comprises a heavily n-doped drain region 14, a heavily n-doped source region 16, a selective gate 104 formed on substrate 1 and overlying a portion of substrate 1 between drain region 14 and source region 16, and a gate oxide 102 between substrate 1 and selective gate 104. Stacked-gate transistor 12 comprises heavily n-doped drain region 16 (i.e., the source of selective-gate transistor 10), a heavily n-doped source region 18, a stacked gate including a floating gate 124, a dielectric layer 126 and a control gate 128 formed on substrate 1 and overlying a portion of substrate 1 between drain region 16 and source region 18, and a tunnel oxide 122 between substrate 1 and floating gate 124. The kind of EEPROM cell shown in FIG. 1 is referred to as "full-featured" since stacked-gate transistor 12 of the EEPROM can be erased, programmed, and is free from problems due to over-erasure of stacked-gate transistor 12 in an alternative range of a byte or multiple bytes by controlling selective-gate transistor 10.
However, the dimensions of the conventional full-feature EEPROM cell cannot be scaled down because the selective-gate transistor and the stacked-gate transistor are manufactured separately in conventional manufacturing procedures.
It is therefore an object of the present invention to provide an improved technique which overcomes the drawbacks and disadvantages associated with the aforementioned full-feature EEPROM cell.
Another object of the present invention is to provide a manufacturing method for a full-feature EEPROM cell which allows the device to be made smaller than is possible by conventional manufacturing techniques.
According to one aspect of the present invention, the channel length of the stacked gate depends on the width of the sidewall spacer of the selective gate and the self-aligned implantation of the dopant.
Other objects, features and advantages of the present invention will become apparent by way of the following detailed description of the preferred but nonlimiting embodiment.
The following detailed description, given by way of example and not intended to limit the invention solely to the embodiments described herein, will best be understood in conjunction with the accompanying drawings in which:
FIG. 1 schematically illustrates a cross-sectional diagram of a conventional full-feature EEPROM; and
FIGS. 2a-2i show the cross-sectional diagrams of the procedures for manufacturing a full-feature EEPROM cell according to the present invention.
In both of the figures, identical reference numerals represent the same or similar components of the overflow-indicating apparatus utilized for the description of the present invention.
The manufacturing method for a full-feature EEPROM cell of the present invention permits the formation of a selective-gate transistor and a stacked-gate transistor on a smaller region of a substrate (for example, a p-type or N-type substrate) than is possible with conventional manufacturing techniques. The method of the present invention comprises the following steps:
Referring to FIG. 2a, a gate isolating layer 210 and a first conductive layer are sequentially formed on a substrate 2. For example, using thermal oxidation, gate isolating layer 210 can be formed with a thickness in the range of about 150Å to about 300Å. The first conductive layer can be formed by depositing a polysilicon layer. A channel region 214 is defined through a photolithography process by patterning the first conductive layer. Then the first conductive layer not positioned above channel region 214 is etched away, and the remaining first conductive layer forms a selective gate 212 of a selective-gate transistor.
Referring to FIG. 2b, a masking layer 220 (e.g. a nitride layer) with a thickness of about 500Å to about 2000Å is deposited to cover substrate 2 and selective gate 212.
Referring to FIG. 2c, an oxide layer with a thickness in a range of about 2000Å to about 6000Å is deposited by CVD (Chemical Vapor Deposition), and then the oxide layer is etched back to form sidewall spacers 230a and 230b of selective gate 212. However, one of sidewall spacers 230a and 230b, for example, sidewall spacer 230b, is employed to define the channel region of a stacked-gate transistor.
Reference is now made to FIG. 2d. Masking layer 220 (shown in FIG. 2c) is etched away beside portions 220a and 220b under sidewall spacers 230a and 230b, forming implantation openings 240a and 240b. By using selective gate 212 and sidewall spacers 230a and 230b as masks, an n-type dopant is implanted into substrate 2 through openings 240a and 240b to form lightly n-doped regions 242a-242d beside channel regions 214 and 232. For example, the dopant can be phosphorus and implanted at an energy level of about 50 KeV with a dose of about 1E14/cm2. The length of channel 232 is easily controllable when manufacturing since it depends on the width of sidewall spacer 230b and the self-aligned implantation of phosphorus.
As shown in FIG. 2e, sidewall spacers 230a and 230b, masking layer 220a and 220b, and part of gate isolating layer are removed by using selective gate 212 as the mask in an etching procedure.
Referring to FIG. 2f, an insulating layer 250 is formed on the surface of selective gate 212, and tunnel dielectric layers 252a and 252b are formed over substrate 2. For instance, an insulating oxide is formed as the insulating layer 250 and a tunnel oxide is formed as the tunnel dielectric layers 252a and 252b using a thermal oxidation procedure. Moreover, insulating layer 250 is thicker than the tunnel dielectric layer 252a, 252b, which has a thickness in the range of about 60Å to about 120Å , because the material forming selective gate 212 is heavily doped polysilicon.
Referring to FIG. 2g, a second conductive layer 260, a dielectric layer 262, and a third conductive layer 264 are sequentially formed thereon and are defined on the selective gate 212 and the channel region 232 to serve as a stacked gate 26 of the stacked-gate transistor. For example, a first polysilicon layer, an ONO (Oxide-Nitride-Oxide) layer and a second polysilicon layer are sequentially formed on the overall surface of the cell by a photolithography procedure and an etching procedure, and are defined as stacked gate 26.
Refer to FIG. 2h. By using selective gate 212 and stacked gate 26 as masks, an n-type dopant (e.g., implanting arsenic at an energy level of about 50 KeV with a dose of about 2E15/cm2) is implanted into substrate 2 to form heavily n-doped regions 270a and 270b so that each of the lightly n-doped regions 242a to 242d, which may combine with one of the heavily n-doped regions 270a and 270b to form a LDD (Lightly Doped Drain) structure, respectively forms the source and the drain of the selective-gate transistor and the stacked-gate transistor.
Reference is now made to FIG. 2i. The final step is passivation and metallization. That is, an insulator 280 such as SiO2, BPSG or PSG is deposited, and then insulator 280 is patterned and etched to form a contact hole 282 at a position above the heavily n-doped region. Afterward, a metal layer 284 such as aluminum is sputtered thereon.
As described above, the manufacturing method of the present invention allows the device to be made on a smaller region of the substrate since a portion of the stacked gate of the stacked-gate transistor is formed above the selective gate of the selective-gate transistor. Accordingly, this invention permits the scaling down in size of integrated circuits.
While the present invention has been particularly shown and described with reference to a preferred embodiment, it will be readily appreciated by those of ordinary skill in the art that various changes and modifications may be made without departing from the spirit and scope of the invention. It is intended that the claims be interpreted to cover the disclosed embodiment, those alternatives which have been discussed above, and all equivalents thereof.
|Cited Patent
|Filing date
|Publication date
|May 24, 1989
|Jan 29, 1991
|Mitsubishi Denki Kabushiki Kaisha
|Method of manufacturing non-volatile semiconductor memory device
|Citing Patent
|Filing date
|Publication date
|Mar 13, 1996
|Feb 10, 1998
|Hyundai Electronics Industries Co., Ltd.
|Method of making split gate flash EEPROM cell by separating the tunneling region from the channel
|Oct 24, 1996
|Aug 4, 1998
|Mosel Vitelic Inc.
|Method of making EEPROM cell device with polyspacer floating gate
|May 12, 1998
|Aug 1, 2000
|United Semiconductor Corp.
|Fabricating method of non-volatile flash memory device
|May 17, 1999
|Oct 17, 2000
|Halo Lsi Design & Device Technology, Inc.
|Process for making and programming and operating a dual-bit multi-level ballistic flash memory
|Sep 6, 2000
|Mar 19, 2002
|Halo Lsi Device & Design Technology, Inc.
|Process for making and programming and operating a dual-bit multi-level ballistic flash memory
|Nov 29, 2000
|Nov 19, 2002
|Taiwan Semiconductor Manufacturing Co., Ltd
|Split gate field effect transistor (FET) device with enhanced electrode registration and method for fabrication thereof
|May 12, 1998
|Dec 10, 2002
|Stmicroelectronics S.R.L.
|Process for the selective formation of salicide on active areas of MOS devices
|Jan 28, 2002
|Mar 30, 2004
|Halo Lsi, Inc.
|Process for making and programming and operating a dual-bit multi-level ballistic flash memory
|Oct 17, 2002
|Oct 5, 2004
|Stmicroelectronics S.R.L.
|Process for the selective formation of salicide on active areas of MOS devices
|Jan 27, 2005
|May 20, 2008
|National Semiconductor Corporation
|Non-volatile memory (NVM) retention improvement utilizing protective electrical shield
|Jan 26, 2010
|National Semiconductor Corporation
|Method of forming non-volatile memory (NVM) retention improvement utilizing protective electrical shield
|Jun 19, 2006
|Dec 21, 2006
|Dongbu Electronics Co., Ltd.
|CMOS image sensor and manufacturing method thereof
|Feb 4, 2008
|Sep 4, 2008
|Yuri Mirgorodski
|Non-volatile memory (NVM) retention improvement utilizing protective electrical shield
|Apr 11, 2002
|Oct 31, 2002
|Koninklijke Philips Electronics N.V.
|Semiconductor device and method of manufacturing same
|Jul 3, 2002
|Jan 16, 2003
|Koninklijke Philips Electronics N.V.
|Non-volatile memory
|U.S. Classification
|International Classification
|Cooperative Classification
|European Classification
|Jul 7, 1995
Owner name: UNITED MICROELECTRONICS CORPORATION, TAIWAN
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:HONG, GARY;REEL/FRAME:007582/0014
Effective date: 19950626
|Oct 29, 1996
|Certificate of correction
|Jan 31, 2000
|Fee payment
Year of fee payment: 4
|Mar 17, 2004
|Maintenance fee reminder mailed
|Aug 27, 2004
|Lapse for failure to pay maintenance fees
|Oct 26, 2004
|Expired due to failure to pay maintenance fee
Effective date: 20040827


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The Medela Symphony breast pump is hands down the cream of the crop when it comes to breast pumps.
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Bruno MarsThu, August 15, 2013 - 7:30 PMToyota Center - TX in Houston, TX
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March 8, 2014
Expressive Arts. Sugar-, flour- and alcohol free eating.
Sung mantra and silent mantra or prayer
Always have done, just see the appeal of a group practice.
I am Patricia. I have just moved back here from Tampa, and was involved in Expressive Arts practice and study for 2 years. EA is very meditative as well.
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Mark J. Terrill, AP
BYU women's volleyball looks to continue its success from last season as the Cougars prepare for another tough schedule in 2014.
"We're really excited about the kids that we have," head coach Shawn Olmstead said. "Getting Jen (Hamson) back from her basketball season is exciting for everyone. I think we've put together a really nice schedule both home and away. It's going to give us an opportunity to test ourselves and go up against some really quality non-conference opponents. Hopefully that will prepare us for conference play when we get to that point."
Last season BYU finished 24-7 and 15-3 in the West Coast Conference with a No. 13 final national ranking. The league record was good for second place behind conference foe San Diego. The Cougars advanced to the regional semifinals of the NCAA tournament for the second-consecutive season before falling to USC.
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Middle blocker
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Outside hitter
Junior All-American Gray returns for the 2014 season along with fellow starter Nobles. Gray led the team in kills last year, averaging 3.97 per set while hitting a .305 clip. Nobles led the team in double-doubles in 2013 with 18, while contributing the second-most digs on the team with 329.
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- Top 25 QB seasons in BYU history, part 1
- Athlete's tribute: 'Show me a legend and...
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the world's hottest hockey player visits Jimmy Fallon
An official end to the four-month N.H.L. lockout was unexpectedly delayed by technicalities Saturday morning.
At 8 a.m., N.H.L. players finished 36 hours of voting on the new collective bargaining agreement reached by their union and the league last Sunday. Approval was expected, but the announcement of the result was postponed while lawyers from both sides worked on a memorandum of understanding that officially summarized the agreement.
"Per agreement with the N.H.L., we will announce results of player vote later today," the union said in a statement about two hours after the voting concluded. "Discussions to finalize the M.O.U. continue this morning."
The players' vote came after the N.H.L. Board of Governors' unanimous approval of the deal Wednesday. Those two votes should have ended the lockout.
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The N.H.L. did not release its schedule at the conclusion of the players' vote. Commissioner Gary Bettman said Wednesday that the league would announce the schedule "instantaneously" with the players' ratification.
Other league business was also delayed, including an announcement officially calling for training camps to open Sunday, with trades, signings and all other matters common to a league in normal working mode.
N.H.L. players have been skating at team rinks since Monday, but no coaches were permitted, so the players ran the practices.
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All 30 N.H.L. clubs have received a tentative schedule, and details have leaked out.
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The Islanders and the Devils are expected to open the season against each other with a Saturday game at Nassau Coliseum.


text:
Up to 10 teachers across St. Clair County will be eligible for classroom makeovers and teacher training that will allow them to be models of 21st century learning methods, thanks to a program called, "Classroom 4 the Future." Each teacher selected through the application process will be eligible for up to $20,000 worth of furnishings and training designed to make it easier for the teacher to work with students individually or in small groups. CLICK HERE to learn more.
Students in TEC's Metal Machining Technology program have had a remarkable 10-year run, winning multiple state and national skills contests. At the center of that run has been instructor Duane Emig, who attended TEC as a student at St. Clair High School. Find out what's behind the continuing excellence of this program and the high-achieving students who are part of it.
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– Student Art and Garden Show coming up
– Woodland students to get active during ACES Day
Read the APRIL 2016 issue
GSRP is Michigan's state-funded preschool program for four-year-old children with factors that may place them at risk. Parents can submit an application online for their child to attend a Great Start Readiness Program. Children must meet eligibility and age criteria. Click here for more information and to submit information to determine if your child qualifies.
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Revel's newly named interim CEO is returning to the city where he got his start, but at a time sure to test his ability.
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Nature Unveiled and Dogs Blood Rising are Current 93's seminal first two albums. Both have been returned to their original formats of two tracks and five tracks respectively, and have been beautifully remastered by Denis Blackham. These reissues include booklets with early photographs of the group members who include David Tibet, Steven Stapleton (Nurse With Wound), John Balance (Coil), Little Annie, and Steve Ignorant (Crass) and original insert materials.
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12 of 12 people found the following review helpful
By T. Allen - Published on Amazon.com
Format: Audio CD
This is Current 93's first full length album re-issued on CD with some live tracks, 2 bonuses from a give-away that came with the first 1000 of the original and 2 songs from their first single. This one's a whopper. Intense, atomospheric, noisy, apocalyptic. Think chanting, loops slowing down and speeding up, demented opera samples, eschatology, Hell. There's still a little bit of Crowley on this one. If you know C93 from their folky, later material, this one may surprise you. Definitely my favorite from their early, noisy soundscape years. If you're looking for the end of the world, here's your soundtrack.
4 of 5 people found the following review helpful
By swamprat - Published on Amazon.com
Format: Audio CD
first of all, i have to say i think it would be "incorrect" to say that this record, and all of the early current's "soundscape" records, as people often refer to them, are better OR worse than current's recent material. they are just aesthetically different. substantially they are NOT different, if you ask me, maybe just simpler. so, i do not agree on this with the previous two reviewers. substantially, this record is mostly about apocalypse, the big ending itself, with all the small endings and deaths that we encounter every day held within. the state of the things that surround us DEMAND apocalypse, in a way. i think this is the main thought behind early current's records. all these thoughts are integral parts of more recent current's material, but the substance of current's newer material is MUCH more complex, so these feelings and thoughts are not so much in the front and isolated, but rather mixed,with love primarily. not love for this or that being, but love itself. i see no real substantial difference between early current's work and their later work, it is a steady, HONEST growth of spirituality. so, this record in particular does not WANT to be dark (ooooooh, spoooky!!), it is just an honest display of one's spiritual state, captured within the aforementioned feelings/thoughts. so, do not view this music as DARK music, it is just HONEST music, and that's what sets current's early records apart from a bunch of childish posers that try to recreate this kind of sound for the sake of "darkness". conclusion:buy this record, it is brilliant.
2 of 2 people found the following review helpful
By Maldoror - Published on Amazon.com
Format: Audio CD
This is by far one of the best Current 93 albums ever, in my opinion. I was drawn to them in their Maldoror days by their noisy soundscapes and tracks that took up almost a whole album side, and this one is a classic. Deep, droning, humming thrumming music like the stirrings of an ancient creature, singing monks, dark rumblings, and of course Tibet's distinct wailing. Some tracks are more mournful and dreamlike, some are dark and brooding, and yet others sound like Orc music. Current 93's more recent works seemed to have pulled away from this style a lot, and while anything they do will always be good IMHO, I think this time period was the greatest for them. If you find that you enjoy this album, I highly recommend you find also "Dogs Blood Order", "Live at Bar Maldoror", and "In A Foreign Town, In A Foreign Land", you will not be disappointed.
1 of 1 people found the following review helpful
By Danny Malboeuf - Published on Amazon.com
Format: Audio CD
This is in many ways the "ultimate" Current 93 release.The two extended tracks take you into pleasantly painful vistas peopled by elements that might in themselves be considered discordant,but in this context they are woven into dark and sparkling symphonies.Vague chanting,rumbling skies...even an excerpt from the Agnus Dei movement of Faure's requiem mass are drawn together to form a compelling whole.This is Current 93 at their most intense.The extra tracks consist of singles{!?}and rarities,and are a welcome addition to the package.
1 of 2 people found the following review helpful
By slug bait - Published on Amazon.com
Format: Audio CD
long out of print but word is, this album will be reissued soon (along with Dogs Blood Rising, another fantastic album from C93). Great album, scary, experimental, some really weird soundscapes.
Would you really pay one hundred bucks for a used copy? Seriously, one hundred dollars for a used copy? Ha-ha-ha-ha-ha-ha!!!
Would you really pay one hundred bucks for a used copy? Seriously, one hundred dollars for a used copy? Ha-ha-ha-ha-ha-ha!!!
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Hotels near Kojimachi Station
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"The hotel was very nice, and directly across the street for the Hanzomen station of the Tokyo subway - very convenient. The staff was great, and a few spoke English well enough to help us with our questions. The room was VERY small, but clean, and in keeping with room sizes in Japan. The only ..."
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- The Prince Gallery Tokyo Kioicho, a Luxury Collection HotelNo Guest Reviews yet
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Beautiful rooms however the drains in the bathroom sink and shower were clogged with hair. Drapes were stained. Rugs had stains. Wall in bathroom had a splatter of some type of liquid. I think the rooms need to be given a major cleaning overhall. Service and friendliness of staff
..was better than good. Food was good.
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Javascript application Bug Fix
This project received 11 bids from talented freelancers with an average bid price of $51 USD.Get free quotes for a project like this
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Project Description
You need to get it working in Chrome 100% of the time. I can get it working sometimes (e.g. I know when/what to do to get it to work).
I am reasonably confident - but not 100% sure - that the problem has to do with the order in which the scripts are loaded.
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my parents split about two years ago. my dad is an alcoholic and he has been abusive. he says cruel things to my mom. he doesnt call or test or write. he has nothing to do with his kids. he says his electronics are more important than his kids. but my mom on the other hand takes away my clothes, tells me a lot of how much my dad sucks and shes always trying to make me wanna live with her. and i have ti go to court soon and im scared that if i say something against my mom...shell freak and same with my dad. i just want to know what chance there is that my dad will get the most custody. and how old do you have to be to choose which parent you would like to live with.
Social Security Lawyers
What a difficult position your parents are putting you in. If your perceptions and decriptions are correct, neither of them should be trusted to raise you. You do not mention how old you are not, but the legal reality is that you do not get to choose where you will live is the age of majority. Is that 18 in your state? Have you been told that you will be required to testify, and that your parents will be present? This would not be allowed in many courts, but if this is what will happen in your case, here is what your testimony can be: 1) I don't think it is fair to make me choose where I will live; adults should make this decision based on my best interests and should not pressure me do that for them: 2) I want to have a positive and healthy relatiionship with each parent, free of any interference by the other parent; 3) I want my parents to show respect for my preferences and for the other parent, and the court should force them to learn how to do a better job in that regard; and 4) I want the war over me to stop, including placement for me in a foster home if my parents can't correct their harmful behavior and help me grow up properly. If it would make you less nervous, print this out and read it when you testify.
Best wishes for an outcome that truly serves your best interests and allows you to grow up free of these unfair burdens, and please remember to designate a best answer.
This answer is offered as a public service for general information only and may not be relied upon as legal advice.
Divorce / Separation Lawyer
The easiest part of the question to answer is that the court must interview children four years of age and older (assuming the younger ages are mature enough to make a decision in the judge's opinion). Your preference is only 1 factor under the Child Custody Act which a court must consider when determining what is in your best interest when it comes to which parent you will live with. The older you are the more the court will consider your preference, but your preference alone will not be the determining factor. When a child is 16 or 17, the court will generally go along with the child's preference, unless there are compelling reasons not to honor the preference. Also, be aware that your preference as to which parent is confidential. The court is never to disclose what was said in chambers where he/she will interview you.
There are a number of other factors the court must consider when determining what is in your best interest. Whichever parent has the most factors in his/her favor is generally the parent to whom your care will be entrusted.
Neil M. Colman
Mr. Colman is licensed to practice law in Michigan. The response herein is not legal advice and does not create an attorney/client relationship. The response is in the form of legal education and is intended to provide general information about the matter within the question. Oftentimes the question does not include significant and important facts and timelines that, if known, could significantly change the reply and make it unsuitable. Mr. Colman strongly advises the questioner to confer with an attorney in your state in order to ensure proper advice is received.
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Now accepting calendar photos for 201735 matches and counting so far this year!Follow us on Instagram @livinghopeadoptionWant to share your adoption story? We are looking for guest blog posts!
Adopting a child is a big step for anyone to take. At Living Hope Adoption Agency, we take pleasure in providing future parents support and guidance to make the transition of becoming a family as smooth as possible. Our enthusiastic and caring team of professionals is committed to providing you with all of the international adoption service you need.


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A Nutella Bar Hits Chicago's Eataly — Brace Yourself
Photo: Courtesy of Nutella.
Chicagoans have been counting down the days to the opening of Mario Batali's Eataly, and now, the wait is finally over. The 63,000-square-foot food paradise officially opens today, which means any attempts to start a detox after a holiday weekend of debauchery are going completely out the window.
But, wheels of cheese and pasta sauces like mama used to make aren't the only vices you'll find here. According to Jezebel, Eater Chicago reports that there is a Nutella bar on the premises, one complete with "little snacks" smeared with that chocolate-hazelnut goodness. Just look at it this way: Consuming one decadent treat (a crepe perhaps?) on site is better for your waistline than consuming an entire jar (one mind-blowing spoonful at a time) at home — or, so we tell ourselves. (Jezebel)
More from Chicago
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It's not easy attending the coolest music festival on earth. Between its expertly curated indie lineup (plus, you know, R. Kelly) and its legions of off-...
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18 Delicious Dishes Every Foodie Must Try
A restaurant review website that actually helps people find the perfect spot for any situation. Sound too good to be true? Then you haven't stumbled across The Infatuation yet. While they don't claim to be professional food critics or industry insiders, they do promise readers an honest take on where to find the best eats ...
Caroline Stanley
Jul 6, 2015


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C.Leon: Orbit: Journey to the Moon (Main Theme)
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The Sierra Nevada (Spanish for "snowy mountain range") is a mountain range located in California. The height of the mountains in the Sierra Nevada gradually increases from north to south. The crest near Yosemite National Park is roughly 13,000 feet (4,000 m) high at Mount Dana and Mount Lyell, and the entire range attains its peak at Mount Whitney (14,505 feet, 4,421 m).
See a lot of interesting photos from California in this photo gallery with detailed descriptions to each photo of the most beautiful areas, monuments, buildings and other attractions.
Awesome! You might like my photos
Photo taken in Fresno, CA, USA


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Still Alive (Remix)
Credits & Info
- Uploaded
- Jun 19, 2008 | 2:07 PM EDT
- File Info
- Song
- 2 min 31 sec
- Score
- 4.39 / 5.00
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- Score:
- Rated 4.39 / 5 stars
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- 37,256 Plays | 3,295 Downloads
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Author Comments
Rated 5 / 5 stars
Finally theres a version with some action. :D
Rated 5 / 5 stars
dude i was like sing/raving all the way thought that so...wooo
Rated 5 / 5 stars
for the people who are...
still alive. every time i hear this song...the lyrics just go screaming thru my head, its too cool to no listen to.
Rated 5 / 5 stars
I just beat portal....
...and this song is freaking awsome!
plus this is a great dance remix, it just gives the song an extra punch.
Great job!
Rated 5 / 5 stars
This gives the true meaning of 'Still Alive'.
I fucking love this song. I think you could work on the main notes, they are a tad bit too loud; just don't make it too quiet.


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A Youthful Yawn - Y, V, W: Tracing and Writing Uppercase Letters
Trace and write uppercase Y, V and W.
Subject: Alphabet Recognition, Phonemic Awareness, Pre-handwritting, Motor Skills, Handwriting Grade: PreK - Kindergarten Type: Learning Activities and Worksheets File Size: 228 KB
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Use the pictures on the page as an opportunity to develop oral language. Link the letter sound to the pictures or activity from the picture. Allow students to color the worksheet once completed correctly.


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Sun, 31 Jul, 2016, 3:22 AM EDT - Canadian Markets closed
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Kid Rock, who has been trying to sell his Balinese-by-way-of-Malibu oasis for three years now, just relisted … More » Kid Rock relists Malibu home for $11,000,000
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|Friday, January 22, 2016, 11:58:56 AM- ***Blows off cobwebs***
Hey! How's it going? Haven't checked in here in ages. It all looks so different here now, I barely recognize the place ;)
I did have messages about my "lovely" cunt though, so I knew I was in the right place LOL
I've been super busy just about all the time now and it SUCKS! I miss my NN friends :(
Hope all is right with you all, and you have the time to be extra pervy to make up for my absence. After all, what's the point of living if you can't have kinky sex? ;)
|Monday, June 16, 2014, 2:44:35 AM- Happy Daddy's day!!!
Had to come in here and blow off all the cob webs to say:
I hope all you big daddies had a great day! You deserve it!
|Sunday, April 20, 2014, 1:35:58 PM- Happy Easter everyone!
Ours is going to be very low key this year. I have no kids left in this state anymore so no one to eat all the food! LOL
That's all right I could use some low key for a change :)
Enjoy yourselves!
|Saturday, March 22, 2014, 9:25:54 PM- Did you know
that boiled eggs left on the stove until the water all boils off, will explode like bombs? Ask me how I know!
I think Dad's banned from the kitchen now! LMAO
/me has to go clean the egg off of the ceiling now. Oiiiiii
|Sunday, March 02, 2014, 2:47:24 PM- I will never understand some people
Some people are just selfish takers,and I always want to believe the best about people. It bites me in the ass A LOT. You'd think I'd learn! This one was a nine year lesson for me, and it hurts :(
Much more their loss then mine though, so oh well, hope they can live with themselves. I'll never talk to them again ever :(
|Monday, February 17, 2014, 4:40:32 PM- That bell has been rung!
And rung very well ;)
|Friday, January 31, 2014, 3:44:30 PM- Seriously
If I don't have sex soon, I think I'm going to dry up and wilt away! With the move, and the health emergencies and lack of sleep it's been weeks! I don't know how single people do it, cuz I just can't. lol I guess I've been spoiled with Country cuz he's always raring to go, so sex had never been an issue until now.
The drought stops tonight! Even if I have to drug my father so we can get some alone time LOL
Seriously I have needs damn it! ;)
|Friday, January 24, 2014, 9:47:35 PM- Thank god for Country!
I have the bestest husband in the world!
He got out of work early yesterday and took over everything for me and made me take a nap. I didn't wake up for 4 hours! LOL Now that's a nap huh? I feel so much better it's crazy. Amazing how good real sleep can make you feel.
Dad's showing some improvement too, so the blood thinners must be doing some good. He's stopped with the random yelling through out the night and has been much more lucid today. Can't wait until Tuesday to see what happens. Obviously I am hoping for more big improvements.
It's been weird living here, it just doesn't feel like home yet I guess. In time I'll get used to it, hopefully.
Maybe taking some new pics will help ;) I'm going to have to try that soon, even though I keep saying that and never actually do it any more. LOL It's not intentional, I'm just always so busy lately, it's hard to feel sexy :(
Poor Country.
|Wednesday, January 22, 2014, 11:41:14 AM- Well we're mostly moved in now
and all I want to do is go back to sleep again! Ugh!
Dad's had a rough few days, he had a TIA Saturday morning and now he's acting very weird. He spent half the night last night screaming in his sleep, not night terrors just general yelling. LOL Makes it hard to get any rest around here. Plus I am totally freaked out! They can't get him into surgery until Tuesday to clean out his carotid artery, and he won't agree to stay in the hospital (I honestly don't blame him there) so I am on pins and needles until then I guess.
He's also been caught many times going on nonsensical rants to himself about different nonsensical things. Sometimes flashing back to Nam(Super scary to watch!) and sometimes back to childhood(not good either) The best, most entertaining ones are when he gets on a good political rant. I just can't figure out who he thinks he's talking to though. LOL I'm usually not even in the room!
I know his oxygen supply is being limited to his brain right now; I just hope the surgery gives him some improvement. I wasn't expecting this so fast after moving in and honestly I think I'm too old to do this very long with little to no sleep! We'll have to hire a nurse if this keeps up.
So any of you want to be my sexy night nurse? LOL Not quite what you had in mind huh? ;)
|Wednesday, January 01, 2014, 2:18:12 AM- Have a happy one!
Enjoy yourselves but please no drinking and driving! We want you all back here, hangovers and all tomorrow.
Luv ya's!
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Explanation of Valence Bond Theory
Valence bond theory states that overlap between two atomic orbitals forms a covalent bond between two atoms.
Learning Objective
Describe valence bond theory
Key Points
- Valence bond and molecular orbital theories are used to explain chemical bonding.
- Two atoms that have unpaired electrons in their orbitals can overlap to give rise to a chemical bond.
- A sigma bond (
$\sigma$) forms when two atomic orbitals overlap between the nuclei of two atoms (also known as the internuclear axis).
- Pi bonds (
$\pi$) occur when two atomic orbitals overlap outside of the space between the nuclei (outside of the internuclear axis).
- The strongest bonds form with maximum overlap between orbitals.
valence bond theory
a covalent bond forms between the two atoms by the overlap of half-filled valence atomic orbitals from each atom.
atomic orbitals
the physical region or space where an electron may be present or found, with a probability calculated from the precise mathematical form of the orbital.
internuclear axis
The space between the nuclei of two atoms bonded to each other.
covalent bond
a chemical bond that is formed from the sharing of two electrons between two atoms.
Full Text
In chemistry, valence bond (VB) theory is one of two basic theories—along with molecular orbital (MO) theory—that use quantum mechanics to explain chemical bonding. According to VB theory, a covalent bond forms from the physical overlap of half-filled valence orbitals in two atoms.
Mechanism of Bonding in VB Theory
The VB theory describes the formation of covalent bonds from the overlap of atomic orbitals on two different atoms. Because of the overlap, it is highly probable that a pair of electrons are found in the physical region or space where the orbitals overlap.
Sigma (
$\sigma$) and Pi ( $\pi$) Bonds
There are two types of overlapping orbitals: sigma (
$\sigma$ Bond Formation
Atomic orbitals from two atoms overlap in the region between the nuclei (internuclear axis). Therefore, the resulting electron density of the shared electrons lies in the red region shown in the image.
$\pi$ Bond Formation
Two unhybridized p-orbitals can overlap so that the electron density of the shared electron pair is described by the
Both types of overlapping orbitals can be related to bond order. Single bonds have one sigma bond. Double bonds consist of one
Comparing VB and MO
VB theory complements molecular orbital (MO) theory, which does not adhere to the VB concept that electron pairs are localized between two specific atoms in a molecule. MO theory states that electrons are distributed in sets of molecular orbitals that can extend over the entire molecule. MO theory can predict magnetic and ionization properties in a straightforward manner. VB theory produces similar results, but is more complicated.
Bond Character
An important aspect of the VB theory is the condition of maximum overlap which leads to the formation of the strongest possible bonds. This theory is used to explain the covalent bond formation in many molecules. In the F2 molecule, the F–F
In an HF molecule, the covalent
Covalent bond between hydrogen atoms
Each hydrogen atom has one electron. To complete their valence shells, they bond and share one electron with each other. This allows electrons to move about both atoms and gives both atoms access to two electrons; they become a stable H2 molecule joined by a single covalent bond.
Covalent bonding in a molecule of ammonia
Each hydrogen atom needs one more electron to complete its valence energy shell. The nitrogen atom needs three more electrons to complete its valence energy shell. Therefore, three pairs of electrons must be shared between the four atoms involved. The nitrogen atom will share three of its electrons so that each of the hydrogen atoms now has a complete valence shell. Each of the hydrogen atoms will share its electron with the nitrogen atom to complete its valence shell.
Assign just this concept or entire chapters to your class for free.
Key Term Reference
- atom
- Appears in these related concepts: Description of the Hydrogen Atom, Stable Isotopes, and Overview of Atomic Structure
- atomic orbital
- Appears in these related concepts: Electron Configurations, The Expanded Octet, and The Periodic Table of Elements
- bond
- Appears in these related concepts: Factors Affecting the Price of a Bond, Current Maturities of Long-Term Debt, and Preferred Stock
- bond length
- Appears in these related concepts: Borates: Boron-Oxygen Compounds, Bond Lengths, and Fused Benzen Ring Compounds
- bond order
- Appears in these related concepts: Properties of Oxygen, Bonding in Coordination Compounds: Valence Bond Theory, and Heteronuclear Diatomic Molecules
- bond strength
- Appears in these related concepts: Physical Properties of Covalent Molecules, Double and Triple Covalent Bonds, and The Alkyl Moiety
- chemical bond
- Appears in these related concepts: Bond Order, Quantum Numbers, and Elements and Compounds
- chemistry
- Appears in these related concepts: General Trends in Chemical Properties, Mass-to-Mole Conversions, and The Study of Chemistry
- covalent
- Appears in these related concepts: Dipole-Dipole Force, Ionic vs Covalent Bond Character, and Naming Molecular Compounds
- double bond
- Appears in these related concepts: Product Selectivity, Halogenation, and Irreversible Addition Reactions
- electron
- Appears in these related concepts: Periods 1 through 3, Electrolytic Properties, and Microscopy
- ionization
- Appears in these related concepts: Electron Configuration of Cations and Anions, Acid-Base Properties of Water, and Mass Spectrometry to Measure Mass
- molecular orbital
- Appears in these related concepts: Conductors, The Phase of Orbitals, and Ethane Conformations
- molecule
- Appears in these related concepts: Molecules, Levels of Organization of Living Things, and Chemical Reactions and Molecules
- orbital
- Appears in these related concepts: Linear Combination of Atomic Orbitals (LCAO), Periodic Table Position and Electron Configuration, and Electron Orbitals
- pi bond
- Appears in these related concepts: Reactions of Alkenes and Alkynes, Properties of Alkenes, and Reaction Energetics
- quanta
- Appears in these related concepts: The Uncertainty Principle, The Bottom of the Periodic Table, and Distribution of Molecular Speeds and Collision Frequency
- quantum
- Appears in these related concepts: Particle in a Box, The de Broglie Wavelength, and Carbonyl Compounds
- sigma bond
- Appears in these related concepts: sp Hybridization, Single Covalent Bonds, and Naming Organic Compounds
- single bond
- Appears in these related concepts: Covalent Bonds, Curved Arrow Notation, and Reactions of Fused Benzene Rings
- triple bond
- Appears in these related concepts: Hybridization in Molecules Containing Double and Triple Bonds, Benzene and other Aromatic Compounds, and Nomenclature and Structure of Amines
- valence
- Appears in these related concepts: Expectancy Theory, Oxidation Numbers of Metals in Coordination Compounds, and Expectancy Theory
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Cite This Source
Source: Boundless. "Explanation of Valence Bond Theory." Boundless Chemistry. Boundless, 26 May. 2016. Retrieved 28 Jul. 2016 from https://www.boundless.com/chemistry/textbooks/boundless-chemistry-textbook/advanced-concepts-of-chemical-bonding-10/valence-bond-theory-81/explanation-of-valence-bond-theory-360-3680/


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Sony VRD-MC5 DVD recorder
Ralf Jurrien : August 2nd 2007 - 13:36 CET
Sony VRD-MC5 DVD recorder :
Sony Electronics debuted its next-generation multi-function DVDirect DVD recorder which can quickly transfer high-definition home videos to DVD discs without using a computer. The Sony VRD-MC5 DVD Recorder model can now transfer AVCHD quality videos to DVD discs in their native 1080i HD resolution when connected directly to a Sony hard drive or Memory Stick Handycam camcorder. The resulting DVD can be played back on compatible Blu-ray Disc devices, including players and computer drives. The Sony VRD-MC5 DVD Recorder can also transfer standard-definition home videos to DVD without the complexity of using a computer from virtually any camcorder, VCR or digital video recorder.
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The new Sony VRD-MC5 DVDirect DVD recorder includes Digital Video, S-Video, Composite Video inputs, and USB (for Sony hard drive, DVD, and Memory Stick Handycam camcorders). DVD video discs recorded in this manner are playable in most consumer DVD players. In addition, the Sony VRD-MC5 DVD Recorder can directly record digital photos to a DVD as a slideshow or just for photo storage from any of the five popular digital camera memory cards. It sports slots for Memory Stick Pro and Memory Stick Pro Duo media, Compact Flash, Secure Digital (SD/SDHC), and xD-picture card, or via USB from Sony hard drive, DVD and Memory Stick Handycam camcorders. Users can also import their own MP3 music files to serve as background music.
Sony MC5 DVD recorder - DVDirect
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- Member since Apr 25, 2006
- Male / 34
- Hendersonville , North Carolina
- 4 Followers
- 0 Trailforks Points
Added 4 photos to Sell
Jun 16, 2016 at 16:35Jun 16, 2016
Added 6 photos to Sell
Mar 26, 2016 at 20:57Mar 26, 2016
Added 2 photos to Sell
Mar 26, 2016 at 20:35Mar 26, 2016
Mar 26, 2016 at 20:33Mar 26, 2016
NS Bikes Clash w/ headset, seat & post$190 USD
NS Bikes Clash frame with Cane Creek 40 series headset, Odyssey Twisted pedals, seatpost, and Aitken seat. Used about 5 times and in excellent condition. The frame is designed for a 120-150mm fork and can be run geared or singlespeed, making it perfect for all-mountain, freeride, and just an all-around fun hardtail mountain bike. A straight 1 1/8" steerer fork fits the included headset, but a tapered fork will fit with a different lower headset cup. $190 plus $60 shipping. If you can pick it up, I'll include a wheelset (handbuilt w/ Sun MTX rims, Sapim Strong spokes, Formula rear hub and Notubes ZTR HD 20mm front hub) for a total of $250. Thanks for looking!
Mar 20, 2016 at 9:24Mar 20, 2016
SRAM X9 or Shimano Deore Cranks & BBs$65 USD
I'm selling either of these 2 cranksets. I have no use for both of them, so I'll keep whichever one isn't sold first. Both cranks are for standard threaded bottom brackets, 175mm long, and have been used for a year and a half. Both cranksets come with the shown chainrings and bottom brackets are included. Both cranksets work perfectly with some minor surface rub. I will throw in a brand new pair of Odyssey Twisted PC pedals if requested. Thanks for looking! The SRAM X9 crank comes with the direct mount 28t chainring pictured and a brand new double spider with guard. I need to check on the ring sizes, but I believe it is a 24/38/bash setup. $95 shipped in lower 48 states. The Shimano Deore crank comes with the 32t chainring shown or 32t Salsa stainless chainring and Shimano bottom bracket. I can also include a triple ring setup if desired. $65 shipped in lower 48 states.
Added 4 photos to Sell
Mar 20, 2016 at 9:10Mar 20, 2016