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| March 5, 2013 - 9:22 am
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I'm looking a mommy has kids and married or whatever my two year old son has no one play with he feel all alone i know how he feels we play together alot but he need someone his age or younger or older doesn't matter just looking someone play with that al
Comments (1)
Posted 04/28/2013
Where do you live?
Mommy to A(2000), L(2002), angel babies (2004)&(2008), J(2009), L(2011)
Stepmom to R(2003), D(2006), A(2008)
J+M=Happily married 2-14-08!!

subset: commoncrawl


text:
We are in Massachusetts and it looks like the custody agreement is heading towards my ex wife having sole physical custody and then we will have joint legal custody. I've heard that she wants to change our children's last names to hers. I'm trying to figure out if she needs my permission to be able to do this if I have joint legal custody. This is something I don't want to happen and I'd like to know the best approach to deal with it. Thanks!
Divorce / Separation Lawyer
Your wife cannot change your children's last names without permission regardless of the custody provisions of your separation agreement or judgment. You parental rights and responsibilities don't end with a divorce, in fact the court encourages your continued involvement.
This is not legal advice and is not intended to create an attorney-client relationship. You should speak to an attorney for further information.
Mr. Mason, Thanks so much for the reply. That helps a lot
I should have said she needs YOUR permisssion - but I think you got it. Good luck - enjoy your kids.
Family Law Attorney
I agree with Attorney Mason. A court would ask, "what best interests of the child" is served by changing the child's last name? I do not know what arguments mom could present other than 1) I want to make it clear that I am the "winner" of this divorce litigation and 2) I would like to alienate the child from his biological father!
The content of this answer should not be relied upon or used as a subsitute for consultation with professional advisors and it should be clearly understood that no attorney-client privilege has been created. A more complete answer and/or more accurate answer can only be provided in a more thorough examination of the facts in a consultation with my firm.
How is a child having the mothers last name alienating the child from his biological father? If that is true then all children are alienated from there biological mother?
If the children had the mother's last name all along, then there could be an argument made that there is no alienation. However, by CHANGING the name so it is no longer the father's last name is certainly alienation.
Criminal Defense Attorney
henry lebensbaum esq 300 Brickstone Sq Ste 201 andover, ma -- email@example.com (978) 749-3606.
Criminal Law (all courts), Drunk Driving, Drugs, Violence, Sex Offenses, theft, SORB, Divorce Child Custody Alimony Child Support & Modification, Contempts & Paternity Juveniles Domestic Violence & Restraining Orders, Business Law, Personal Injury, Guardianship, Conservatorship & Estate Administration & Legal Malpractice. For these & other areas, contact me. Email sent may be copied intercepted or held by computers.
Criminal Law (all misdemeanor & felonies in District and Superior Courts), Drunk Driving and Drug arrests, Sex Offenses, SORB, Crimes involving Violence or Theft, Domestic (Divorce, Child Custody, Alimony and Child Support) and Family Law (Modification, Contempts & Paternity), Juvenile Law, Domestic Violence and Restraining Orders, Business Law, Personal Injury claims, Probate Law (Guardianships, Conservatorships & Estate Administration) and Legal Malpractice. For these and other areas, contact me. NOTE: This preceding message DOES NOT create an attorney-client relationship. It is not a protected or confidential communication. The statements made herein are not to be interpreted as representations or warranties of any kind. No reliance should be placed on the statements made herein. It is recommended that the recipient(s) should undertake their own research to reach their own opinion. The writer does not accept professional responsibility on this matter. TO CREATE an attorney-client relationship REQUIRES a signed retainer/fee agreement along with a retainer fee that must be received by my office.
Juvenile Law Attorney
Absolutely not! The children have an identity and if you object, I do not believe that a court would order a name change. Not only have the kids been disrupted due to the divorce, now they won't even know who they are (slight exaggeration). Stand firm!
Best of luck!
Valerie Semensi @ 781.383.1940
Divorce / Separation Lawyer
If you object to the name change then she cannot change the children's last name. However it is important to make sure you object to her petition to change their last name.
Sign up to receive a 3-part series of useful information and advice about child custody law.
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Click here to print the obituary below
Lloyd Stout
Stout, Lloyd
Lloyd Stout, age 89 a resident of Wilton, CT for the last 10 years, formerly of Upper Arlington in Columbus, OH died Tuesday January 21, 2014 at his home. Born May 13, 1924 he was the son of the late Lloyd and Genevieve McLaughlin Stout. Lloyd was predeceased by his wife Nanciann Williams Stout in 1991.
He graduated from Upper Arlington High School, where he played varsity basketball and captained the varsity baseball team, and The
Ohio State University
, College of Business. He was a member of The Ohio State University Alumni Associate and Phi Kappa Psi fraternity. An avid sports fan, he shared his roots as an Ohio State Buckeye with his sons and grandchildren. For his achievements in baseball he was inducted to the Golden Bear Diamond Club. A proud long time member of the First Community Church, and past member of Kiwanis. He was a past director of Upper Arlington Civic Association, and served as Grand Master of the 4th of July Parade. A career salesman, he retired from real estate to join his family in Connecticut. In retirement he actively volunteered at the Waveny Care Center for which he received the 5000 Hour Service Award and the Outstanding Established Senior Individual Volunteer Award.
Lloyd is survived by his two sons, Craig Williams Stout of Redding, CT, and Lloyd Wesley Stout and his wife Sarah of Wilton, CT, and five grandchildren, Meghan Stout, Lindsay Stout, Allison Ducharme, and Blair and Ben Stout, who all loved him dearly.
A private interment will be held in the family plot in Columbus, OH
For online condolences, please visit
Funeral Home
Hoyt Funeral Home
199 Main St
New Canaan, CT 06840
(203) 966-0700
Published in News Times on Jan. 28, 2014


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Creating omni lights
Creating omni lights
To complete our introduction to Lighting, let's adds some fill lights to this scene. Throughout this chapter, we've only had this single spotlight in here. As a result, our shadows are super-black. They are 100% Black, or 0% white, and that's not terribly believable. Additionally, we are not getting enough shading and modeling on our text here. So, we can just create a few omni- directional lights that will fill in all those dark shadows. I'll go to the Create panel, and I will go to Lights > Standard.
I've got an Omni light. So, an Omni light is a point light source that radiates in all directions, like a light bulb. So, I'll click Omni, and I am just going to create a few of these here. I'll click once, twice and three times and then right-click to exit Omni Light Creation. I've got three lights in here. I am just trying to fill in the blanks, so that I don't get all these sort of really dark, black shadows. But as you can see, it's overlit, becau...
Creating omni lights provides you with in-depth training on 3D + Animation. Taught by Aaron F. Ross as part of the 3ds Max 2011 Essential Training
- Subject:
- 3D + Animation
- Software:
- 3ds Max
- Author:
- Aaron F. Ross
Related Courses
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Foundations of Programming: Fundamentals7,748,469 Views
3ds Max 2015 Essential Training514,818 Views


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Dec 14, 2012
MotorTorqueuk Profile
Forums Owned
Recent Posts
Hello people, After the massive boost in popularity of SUVs last year we thought it would be appropriate to make an SUV video acting as a sort of guide to SUVs in 2013. The video pretty much talks through a few of the different SUV styles you can buy. Anyway, here it is. Can you please tell us what you think of the SUVs in the video and let us know of any views you have on any other SUVs in the market please. http://www.youtube .com/watch?v=Xt48z 4oWIfo Cheers everyone, Rich. (Jan 11, 2013 | post #1)
Hello everyone, We have another review for you all :) Hope you enjoy it - its the brand spanking new 2013 Range Rover. Check it out: http://www.youtube .com/watch?v=2JKle m8DjpY&list=PL 6AF064202B7FC431 &index=1 (Jan 9, 2013 | post #1)
What do you think about the Mazda3?
Hello people, After realising that the Mazda3 sometimes gets forgotten when it comes to hatchbacks, we thought we would give it a review and a bit more coverage (which it rightly deserves). So, we got one and took it for a drive. We thought we would post it on here so that you can let us know what you think of it, and if you could, can you let us know what you think of our review as well, we are still in the learning process so any advice and feedback would be great. http://www.youtube .com/watch?v=Q11HC tMDmb4 Cheers, Rich. (Jan 4, 2013 | post #1)
Hello folks, Although we usually go for things like saloons and hatchbacks, we thought we would mix it up a bit, with the New Year and resolutions flying all over the place. So, we decided to do a review of the Nissan Navara which we actually really enjoyed. http://www.youtube .com/watch?v=62hNe -4fYS4 If you wouldnt mind giving our review a watch that would be great and any feedback on the video itself would also be massively appreciated as we are still in the learning process of how to make video reviews. Thanks people. (Jan 2, 2013 | post #1)
Hello people MotorTorque here, Seen as though it is the end of the year, we have made a little compilation of some of our best test drives. So, we would really appreciate it if you could give it a watch and let us know which is your favourite out of the ones we have picked. http://www.youtube .com/watch?v=7VXUM pcRrso Or not, its up to you :p Cheers. (Dec 27, 2012 | post #1)
Vauxhall Astra GTC vs Volkswagen Scirocco
Hello everyone, Hello people, After hearing countless amounts of people go on about which is better, the Vauxhall Astra GTC or Volkswagen Scirocco, we thought it would be appropriate to do a head to head review. Anyway, there is nowhere better to hear what people think about the two then a forum. So, if you have time let me know what you think - which one would you buy? Why would you buy it? and all that jazz - finally settle this debate. Here is our review by the way if you fancy a watch: http://www.youtube .com/watch?v=rNnwF cqNRl8&list=PL 6AF064202B7FC431 (Dec 21, 2012 | post #1)
Volkswagen Scirocco Confirmed For USA - Confidential Deal...
The Volkswagen Scirocco is a great car - the USA should be exited for the release. Our site drove one recently and it is even better than we expected - great fun. But what does everyone else think about the Scirocco? I have heard a few people give it a bad rep. By the way, if you are looking for a bit more info on the VW Scirocco, feel free to give our review a watch. http://www.youtube .com/watch?v=53-iv zx3KW8 (Dec 19, 2012 | post #2)
Do you like the Vauxhall Astra Tech Line?
Hello people, MotorTorque here. We have been asking people recently what their thoughts are on the Vauxhall Astra Tech Line. We recently had a test drive with one and we weren't that impressed, as the Tech Line trim is supposed to deliver a more premium take on the standard hatch model - we didn't think it did. What does everyone think? Any feedback will be massively appreciated. Here is our review of the Tech Line if you fancy giving it a watch: http://www.youtube .com/watch?v=r7x2S EdfA0I (Dec 14, 2012 | post #1)
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text:
Definición de Serbo-Croat en inglés:
(also Serbo-Croatian /ˌsəːbəʊkrəʊˈeɪʃ(ə)n/)
sustantivo[mass noun]
A term for the Southern Slavic language spoken in Serbia, Croatia, and elsewhere in the former Yugoslavia. Serbo-Croat comprises two closely similar forms: Serbian, written in the Cyrillic alphabet, and Croat, written in the Roman alphabet. Since the break-up of Yugoslavia the names of the individual languages have generally been preferred.
Oraciones de ejemplo
- The Croats and Muslims use the Roman alphabet to write Serbo-Croatian, while the Serbs use the Cyrillic alphabet.
- They translated the radio jingle into Albanian, Macedonian, Serbo-Croatian, and Serbian.
- Today each of the republics of the former Yugoslavia use their own language, but they are all Slavic languages similar to Serbo-Croatian.
Relating to Serbo-Croat.
Oraciones de ejemplo
- As one of the three Serbo-Croat speakers attached to the British contingent of the force, his role was to act as the principal military negotiator with the Bosnian Serb leadership on behalf of the UN.
- What's it supposed to be, some type of Serbo-Croatian shorthand?
- Underground's original Serbo-Croatian soundtrack is offered in Dolby stereo.
Palabras que riman con Serbo-CroatCroat
For editors and proofreaders
Saltos de línea: Serbo-Croat
Definición de Serbo-Croat en:
¿Qué te llama la atención de esta palabra o frase?
Los comentarios que no respeten nuestras Normas comunitarias podrían ser moderados o eliminados.
Muy popular en Reino Unido
Muy popular en Australia
= de moda


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Brendle got things started with this picture that is made entirely of pixels he inherited from an eccentric uncle.
punchperm has weak ears. Music isn't music unless it can make a dog shit its pants.
djmelee.com spends a lot of time coming up with rhymes for "maroon."
enki42 listens to all the popular music I have no clue about.
It's just a little confusing, is all.
The good news is the republican convention is over. The bad news is if I can escape this police car how do I anull a marriage??
Title of this one pretty much says it all. If it's what you're looking for, then uh, look no further
There is literally nothing sexier than eye contact.
A dandy fop dog gets a rhino piss party and ant enema in the Jungle. Weldcome to Hell.
Photoshop Phriday showcases the tremendous image manipulation talents of the Something Awful Forum Goons. Each week they tackle a new theme, parodying movies, video games, comics, history, and anything else you can think of. If you want in on the action, join us on the Something Awful Forums!
Copyright ©2016 Rich "Lowtax" Kyanka & Something Awful LLC.


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Entrepreneurship and Its Economic Significance, Behavior and Effects
Maria V. Bradshaw, Patricia T. Carrington, "Entrepreneurship and Its Economic Significance, Behavior and Effects"
Nova Science Publishers | 2009 | ISBN: 1606926691 | 247 pages | File type: PDF | 7,4 mb
Entrepreneurship is the practice of starting new organisations or revitalising mature organisations, particularly new businesses generally in response to identified opportunities. Entrepreneurship is often a difficult undertaking, as a vast majority of new businesses fail. Entrepreneurial activities are substantially different depending on the type of organisation that is being started. Entrepreneurship ranges in scale from solo projects (even involving the entrepreneur only part-time) to major undertakings creating many job opportunities. Many 'high-profile' entrepreneurial ventures seek venture capital or angel funding in order to raise capital to build the business. Angel investors generally seek returns of 20-30 per cent and more extensive involvement in the business. Many kinds of organisations now exist to support would-be entrepreneurs, including specialised government agencies, business incubators, science parks, and some NGOs. This book presents the latest thinking in this vibrant and essential area.
[Fast Download] Entrepreneurship and Its Economic Significance, Behavior and Effects
The Manager's Legal Handbook
Capture My Attention: How To Stand Out Online with Creative Content
Dominate Your Local Google Search: A Step-by-Step Guide For Local Businesses; How To Be #1 In Google
E-Marketing Strategy Primer: Designed For Small Business
Food Security, Gender and Resilience: Improving Smallholder and Subsistence Farming (Earthscan Food
101 Tips For Graduates: A Code Of Conduct For Success And Happiness In Your Professional Life
Getting Started in Private Practice: The Complete Guide to Building Your Mental Health Practice
Chunlin Zhang, Douglas Zhihua Zeng, William Peter Mako, James Seward - Promoting Enterprise-led Inno
Working Abroad: The Complete Guide to Overseas Employment
Research Methods for Business Students
This site does not store any files on its server. We only index and link to content provided by other sites. Please contact the content providers to delete copyright contents if any and email us, we'll remove relevant links or contents immediately.
Why Motivating People Doesn't Work and Wha(3333)
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What You Aren't Seeing: How Using Your Hid(2678)
Blue Ocean Strategy, Expanded Edition: How(2525)
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Magic Words: The Science and Secrets Behin(2412)
400+ Essential Digital Marketing Tips(2409)
Strategic Management and Competitive Advan(2275)
LinkedIn In 30 Minutes (2nd Edition): How (2145)


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1986-2016: Celebrating 30 Years of sending Scottish Music Worldwide.
10 tracks: Senorita Ana Ro'dio / Seeds To The Wind, Glenlivet, A' The Airts, Here's A Health Tae The Sauters / Cajun Two Step, Johnnie Cope, Galician Set, See The People Run, Mazurka Set, The Cowpit Yowe Set, Lord Galloway's Lamentation.
Traditional song and instrumental group featuring Gary West (bagpipes), Davy Steele (vocals, guitar) and Wendy Stewart (harp).
'They must be the envy of many better known bands.' (The Scotsman)
see other titles and news articles related to Ceolbeg
We accept PayPal and all major credit and debit cards.
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Anxious to complete your album collections? We can now offer many deleted back catalogue titles again.


text:
2014-01-15 17:19:00
Kelly Bleyer
It increased the snow depth by 20 or more inches at several sites in the northern and central Cascades.
Unfortunately though, parts of southern Oregon did not receive any new snow.
Precipitation in Oregon since October 1st has been well below normal.
Most of Oregon's streams are expcted to have below normal summer stream flows ranging from 68 to 99 percent of normal in the Umatillla, Walla Walla and Willow Basins, to 21 to 51 percent of normal in the Klamath Basin.
Jones Road, full road closure between Bennington Lane and NE Butler Market Road. May 18 – August 18, local access only.
Oregon State University off-site improvements for intersection reconstruction, July 11 – August 3, 7 a.m. – 4:30 p.m., at intersection of Chandler Avenue and Yates Drive.
Orion Drive closed in two locations for sewer work; at the intersection with Avery Lane and between Desert Woods Drive and King Hezekiah Way. From July 11 to Sept. 6. Detours marked.
Valhalla Sewer Relocation Project, Mt. Washington Drive at Shevlin Park Road intersection and North to Regency Street. Nighttime closures with detours marked during roundabout construction. Daytime closures for construction towards Regency Street. 7 p.m. – 7 a.m., July 11 – November.
Home | EEO | Employment Opportunities | Advertising Information | Links | Contact


text:
A Better America wants to
Sign the Sympathy Card to the Families of the Dallas Police
We must honor the people who protect us every day.
We must honor the people who protect us every day.
In 2016, the Court will make major decisions that'll impact our environment, immigration, and even the right to vote.
the director of the hospital admitted the drs got it wrong
Don't let Congress deny your right to know: Oppose the DARK act
Facebook needs a report function that is specific to reporting "child sexual abuse"
Remove Pages from Facebook threating the lives of our Men & Woman in Blue


text:
Skip to Main Content
IEEE membership options for an individual and IEEE Xplore subscriptions for an organization offer the most affordable access to essential journal articles, conference papers, standards,
eBooks, and eLearning courses.
Learn more about:
IEEE membership
IEEE Xplore subscriptions
We propose a method to compute a probably approximately correct (PAC) normalized histogram of observations with a refresh rate of Θ(1) time units per histogram sample on a random geometric graph with noise-free links. The delay in computation is Θ(√n) time units. We further extend our approach to a network with noisy links. While the refresh rate remains Θ(1) time units per sample, the delay increases to Θ(√n log n). The number of transmissions in both cases is Θ(n) per histogram sample. The achieved Θ(1) refresh rate for PAC histogram computation is a significant improvement over the refresh rate of Θ(1/log n) for histogram computation in noiseless networks. We achieve this by operating in the supercritical thermodynamic regime where large pathways for communication build up, but the network may have more than one component. The largest component however will have an arbitrarily large fraction of nodes in order to enable approximate computation of the histogram to the desired level of accuracy. Operation in the supercritical thermodynamic regime also reduces energy consumption. A key step in the proof of our achievability result is the construction of a connected component having bounded degree and any desired fraction of nodes. This construction may also prove useful in other communication settings on the random geometric graph.
A not-for-profit organization, IEEE is the world's largest technical professional organization dedicated to advancing technology for the benefit of humanity.© Copyright 2016 IEEE - All rights reserved. Use of this web site signifies your agreement to the terms and conditions.


text:
Tom Povey
Personal Details
Professor of Engineering Science
Contact Details
University of Oxford,
Parks Road,
Tel: +44 (0) 1865 288767
Email: firstname.lastname@example.com
Tom is a Professor of Engineering Science and a Tutorial Fellow of University College, where he is also the Tacchi Fellow in Engineering Science. He completed a degree in Physics at St Catherine's College Oxford, followed by a DPhil in Engineering Science (Turbomachinery) in the Rolls-Royce University Technology Centre in Heat Transfer and Aerodynamics at Oxford University. Following his DPhil Tom was appointed as the Rolls Royce Industrial Fellow at St Catherine's College before taking up his current post as Tutorial Fellow at University College in 2004. In 2008 he took up the Tacchi Fellowship in Engineering Science, and in 2014 became a Professor of Engineering Science.
His research group pioneered the use of liquid crystals in heat transfer experiments. He has published about 70 papers in turbomachinery conferences and journals, with an emphasis on turbine performance, heat transfer, and combined aero/cooling problems. He has supervised about 50 final year projects and eight finished PhD theses.
Research Interests
- Turbine performance
- Turbine capacity measurement
- Nozzle guide vane rotor cooling optimisation
- Combustor turbine interaction effects
- Measurement techniques in turbines
- High speed facility design
- Aerodynamic probe design and calibration


text:
It may be a while before Texans who fled the fury of Hurricane Ike will be able to go home again.
Evacuees, some with little cash and no idea of what the coming days hold, have filled shelters across the state. Thousands of people face long stays because their homes were damaged or destroyed by the storm.
Even for those who still have a home to go to, Ike's 110 mile-per-hour winds and battering waves left thousands in coastal areas without electricity, gas and basic communications. Officials estimate it may not be restored for a month.
Many people who had ignored evacuation orders and tried to ride out the storm had to be rescued. They now find themselves facing indefinite stays at shelters in San Antonio and Austin.
The death toll from Ike stands at 30 in eight states.


text:
This clear zippered custom tote bag is perfect for fans packing their game day necessities!
Made of vinyl, this clear custom drawstring backpack is perfect for fans packing their stadium and event day items safely.
Logo yoga mat with carrying case is great for yoga, exercise, or take it camping for under your sleeping bag.
Show off your logo on this great PVC promotional travel alarm clock with second hand.
A pocket sized 5" x 7" custom journal that's perfect for note taking.
Includes a 30 page 5" x 7" writing pad in this hot imprinted padfolio with a contemporary look.
Keep all your loose documents securely in place with this clip folder custom clipboard.
You can count on your marketing campaign being a success with this pig shape Promotional Piggy Bank!
Made of vinyl, this clear custom tote bag is perfect for fans packing their stadium and event day items safely.
Keep organized with this large promotional padfolio.
With a patent leather look, these custom cosmetic bags are available in bright colors to attract attention to your logo!
With numerous features and dual compartments, this rolling custom laptop briefcase has everything a business professional could want and need.
A leatherette logo envelope custom photo album that holds 24 - 4" x 6" photographs inside and has an extra outside pocket window on the back.
A three-piece promotional travel kit that includes a TSA--compliant travel pouch packed with an eye mask and earplugs for great sleep during travel.
This Club House custom travel kit by Callaway is the ultimate golfer's event kit!
Custom Insulated Lunch Bag that is perfect sized for one.
Flexible, PVC promotional watch has a digital read-out and comes in an array of vibrant colors.
Keep out the distractions with these Vibrato noise reducing custom headphones that are ideal for air travel.


text:
Independent & World Films at the Library
Showing at 2:00 p.m. on Thursday, July 28, 2016
NOTE - One showing only, at 2:00 p.m.
Coming Home (China)
In Coming Home, Lu Yanshi (Chen Daoming) and Feng Wanyu (Gong Li) are a devoted couple forced to separate when Lu is arrested and sent to a labor camp as a political prisoner, just as his wife is injured in an accident.
Released during the last days of the Cultural Revolution, he finally returns home only to find that his beloved wife has amnesia and remembers little of her past.
Unable to recognize Lu, she patiently waits for her husband's return. A stranger alone in the heart of his broken family, Lu Yanshi determines to resurrect their past together and reawaken his wife's memory.
In Mandarin with English subtitles.
Run time: 109 minutes
Indie & World Film selections will be shown at 2:00 p.m. on the 2nd & 4th Thursdays of every month. All programs at OPL are free of charge. Like us on Facebook to see what we're up to! Films shown at the library become part of our DVD collection after the final showing.
See you at the movies!
Special Events Mailing List
Sign up to receive notice of films and other programs for adults.
Already Shown
January 14: Belle (Great Britain)
January 28: Tracks (Australia)
February 11: Suffragette (U.K.)
February 23: Infinitely Polar Bear (U.S.)
March 10: The 33 (U.S.)
March 24: The Danish Girl (U.K.)
April 14: The Day I Saw Your Heart (France)
April 28: The Story of Qui Ju (China)
May 12: Marie's Story (France)
May 26: The Lady in the Van (U.K.)
June 9: The Lesson (Bulgaria)
June 23: Race (U.S.)
July 14: Touched With Fire (U.S.)
January 8: The Hundred-Foot Journey (India/U.S.)
February 12: Ilo Ilo (Singapore)
February 26: Love is Strange (U.S.)
March 12: The Theory of Everything (Great Britain)
March 26: Birdman (U.S.)
April 9: The Patience Stone (Afghanistan)
April 23: Pride (Great Britain)
May 14: For a Woman (France)
May 28: Leviathan (Russia)
June 11: The Good Lie (Canada)
June 25: My Old Lady (Great Britain/U.S./France)
July 9: Wild Tales (Argentina)
July 23: Home (U.S.)
August 13: Tangerines (Estonia and Georgia)
August 24: Far From the Madding Crowd (Great Britain)
September 10: A Little Chaos (Great Britain)
October 8: Calvary (Ireland)
October 22: The Innocents (U.S.)
November 12: Little Boy (U.S.)
December 10: Mr. Holmes (Great Britain)
March 13: Blue Jasmine (U.S.)
March 27: 12 Years a Slave (U.S.)
April 24: The Book Thief (U.S.)
May 8: Wadja (Saudi Arabia)
May 22: Inside Llewyn Davis (U.S.)
June 12: Instructions Not Included (Mexico)
June 26: Stories We Tell (Canada)
July 19: Oranges & Sunshine (Australia)
July 24: Love is All You Need (Denmark)
August 14: Still Mine (Canada)
August 28: The Lunchbox (India)
September 11: Shun Li and the Poet (Italy)
September 25: The Past (France)
October 9: Words and Pictures (U.S.)
October 23: Gloria (Chile)
November 13: Chef (U.S.)
December 11: 8 Women (France)
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text:
The Windows 10 Technical Preview was released this Thursday, but only for select phones. Now thanks to an XDA-Developers hack you can install it on just about any Lumia that you are not using.
That last bit is important since this can brick your device. People have reported success with various phones, including the Lumia 720, which has just 512MB RAM. The update is officially available for 512MB phones, though there's a possibility they won't get all features in the final build.
Anyway, the update has worked on a Lumia 930 and a Lumia 1320 bought from different carriers, though some are reporting issues on Lumia 920 and 520.
You can read the step-by-step guide for the update in this thread, plus reports on how others fared and some troubleshooting. The process is fairl involved and not for the faint of heart and once again it could brick your device.
How can I install windows 10 in Lumia 535 ?
How to upgrade windows phones
how to install win 10 preview on l920 with at&t carrier


text:
Thanks for the review! Been in the market for a hammock pillow and the HG pillow is on my maybe list, always wondered what it looked like, now I know! Thanks again!
Type: Posts; User: Dev
Thanks for the review! Been in the market for a hammock pillow and the HG pillow is on my maybe list, always wondered what it looked like, now I know! Thanks again!
How well would adding sections of velcro every couple of inches work? Keep it open then when it is time to go to bed you could velcro the two doors together than stake it down to one stake if it is...
Yes I have seen this issue as well, however instead of not allowing package sales, it might be better to not allow any "I'll take it if..." posts in that thread and if the seller sees more demand...
Welcome, your in the right place for all things hammocks!
Wouldn't you consider this to be some form of solution, I would. His intentions were clear, he came here asking if the defect could be fixed by him and was told instead to contact the manufacture...
Everyone is different but for me I was not comfortable enough to fall asleep. It was comfortable to lay in but due to the fact I can only fall asleep on my side or stomach it will take some getting...
Welcome to the place to learn about all things hammocks! The Ultimate Hang book will deffinitely be a wealth of knowledge and if you haven't already look up shugemery on Youtube and check out his...
Welcome to the forums! Nice rig you have going there!
Welcome from VA. I was just in your area the other day at Busco Beach atv park. I have set up my hammock there to test, mighty fun!
Thanks kwiktech! Will definitely be trying it out when I get a superfly!
Wow I really like that method and how you have the poles resting on the RL instead of the tarp itself. I'm having difficulty picturing the stingerz end, is the line running through the stinger which...
Still looking for a Superfly, just can't seem to snag one in time from the For Sale thread. Thankee!
Welcome buddie to the forums! Hope you enjoy your new hammock!
What about Dutch fireflyz, coat flyz with something so they glow in the dark.
Dang, missed another superfly, selling like hot cakes.
Nice choice going with sage! A tablecloth hammock was my first DIY they are fun to make and super comfy! Thanks for sharing.
nvm about my first post, I'll take the super fly, pm me the paypal info! Thanks!
do prices include shipping?
Welcome from a SoVa hanger, lol! Get your pen a paper because there is a plethora of information in these forums. Also, if you haven't already checking out Shug's videos is a great place to start....
what is the length of the Hudson River?
It seems like you have a good start and doing everything correct. Have you tried a 30 degree angle on the suspension? Other than that I would tweak sag to see if that helps. You also might of whipped...
Idk if this has been reported but the pif thread is now visible on tapatalk.
I can second thinking about a purchase too long. Also, this has happened to me as a noob, hitting the wall of discouragement. If you go out and your first hang is not pleasant don't give up, ask...
Dang it not fast enough! I'll take seconds on tarp.
Hey HF, after being away for sometime due to college I finally have the time to continue my backpacking/hammocking gear roundup. I know it might be a long shot to see if a superfly is out there...
Welcome from a fellow Virginian!
I am in on this! Thanks a bunch for this awesome giveaway! :)
count me in, mighty kind! Thanks!
Always love seeing your videos on my homepage of Youtube, and I have to say that wool hoodie looks sharp! Great video as always!
I will take the cup #1
what material is the ridgeline cup made of?
Would it hurt to wash a hammock without removing wiping in this case para cord? Idk if washing it would degrade its strength or not.
I use one of those big rubber feeling drybags that you roll the top down then snap with a buckle, I would be fairly confident in submerging it with gear but for how long is the concern. Tarp,...
Welcome from a fellow Virginian. If you haven't already definitely check out Shug's beginner hammock series, will get you going on the right track.
I really like that dome shape it has in the center. Feels good to see the fruits of your labor. Great work mate!
ahh beat me to it. Enjoy the superfly with that dutch bling :)
Do prices include shipping?
I like to whip it, whip it good. :lol:
I'm in! Mighty nice! Appreciate the giveaway.
Congrats on the new position!
No matter how hard someone tries breeding tents with hammocks is not possible in a practical sense. This would be fun in the backyard but so would a whole bunch of hammocks for that price.
Received my package yesterday, have to say this is a mighty fine first UQ! :)
ENO is like the walmart of hammocks, they're everywhere.
Luckily I was able to return it. :)
I went to check the receipt I was charged for the 8ft instead of 10.5. When I returned it I noticed I had chosen sport nylon instead of ripstop so good...
I think I just found the issue. I went to measure the length of ripstop this morning to double check it was 10.5ft well it was only 8ft and some change. No wonder it felt so tiny.
Thanks for the help. Mine is 59" wide and I think I am going to try sewn channels to see if I can get a better lay.
I tried searching this but have come up short so I have decided to ask. I have been on a DIY hammock spree to find one I can get comfortable in. I stopped by my local fabric store and picked up some...
I have been tweaking my diy tablecloth and there seems to be a lot of side material. I rewhipped it twice using the fan method and it still has sagging material. I also get this wall of fabric right...
Ordered mine the 2nd to last day and the wait is a killer. I have my email on my phone and each time it vibrates I hope its the tracking email. Based on the great quality at AHE the wait is worth it....
Looking really good! I'm in! :)
Thanks for the giveaway!


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Book your room at Extended Stay America Indianapolis - North
Get an overview of this hotelSuburban hotel with free breakfast and seasonal outdoor pool
Situated in the suburbs, this hotel is 0.8 mi (1.2 km) from Fastimes Indoor Karting and within 3 mi (5 km) of Fashion Mall at Keystone and Flowing Well Park. Waterpark at Monon Community Center and The Historic Ambassodor House & Heritage Gardens are also within 6 mi (10 km).
Hotel Features
This smoke-free hotel features coffee/tea in a common area, a seasonal outdoor pool, and a business center. Free continental breakfast, free WiFi in public areas, and free self parking are also provided. Other amenities include concierge services, laundry facilities, and barbecue grills.
Room Amenities
All 72 rooms have flat-screen TVs with cable channels and feature kitchens with refrigerators, stovetops, and microwaves. Guests will also find free WiFi, sitting areas, and coffee makers. Weekly housekeeping is available.Would you like to give us feedback? Share it! Opens in a new window
Extended Stay America Indianapolis - North9750 Lakeshore Dr. Indianapolis IN 46280
Hotel Amenities
Hotel Amenities
High-speed wireless Internet access is complimentary. This hotel offers access to a business center. A complimentary breakfast is offered. This Indianapolis hotel also offers a seasonal outdoor pool, barbecue grills, and coffee/tea in a common area. Onsite self parking is complimentary.
Extended Stay America Indianapolis - North is a smoke-free property.
- Barbecue grill(s)
- Business center
- Coffee/tea in common areas
- Concierge services
- Free breakfast
- Free long-term parking
- Free self parking
- Free WiFi
- Front desk (limited hours)
- Laundry facilities
- Number of floors - 3
- Outdoor seasonal pool
- Safe-deposit box at front desk
- Smoke-free property
- Television in common areas
- Total number of rooms - 72
- Year Built 1990
Family Friendly Amenities
- Free Wi-Fi
- Full-sized refrigerator/freezer
- Kitchen
- Laundry facilities
- Microwave
- Refrigerator
Available in all rooms: Free WiFi
Available in some public areas: Free WiFi
Free long-term parking, Free self parking
Room Amenities
- Air conditioning
- Cable TV service
- In-room climate control (air conditioning)
- Coffee/tea maker
- Free toiletries
- Cookware, dishware, and utensils
- Desk
- Flat-panel TV
- Free local calls
- Free WiFi
- Full-sized refrigerator/freezer
- Hair dryer (on request)
- Iron/ironing board
- Kitchen
- Microwave
- Phone
- Premium TV channels
- Private bathroom
- Refrigerator
- Separate sitting area
- Shower/tub combination
- Stovetop
- Weekly housekeeping provided
Where to Eat
Guests are offered a complimentary continental breakfast.
Nearby Things to Do
- Golfing nearby
To make requests for specific accessibility needs, complete the "Special or Accessibility Requests" section of "Trip Preferences" when you book your hotel.
Hotel Policies
Check-in time ends at Midnight
Check-in time starts at 3 PM
Check-out time is 11 AM
Payment types
- Pets allowed for an extra charge of USD 25 per pet, per day (maximum USD 150 per stay)
- Dogs and cats only
- 2 per room
- Restrictions apply
- For more information contact the property at the number on the booking confirmation
You need to know
Extra-person charges may apply and vary depending on hotel policy.
Government-issued photo identification and a credit card or cash deposit are required at check-in for incidental charges.
Special requests are subject to availability upon check-in and may incur additional charges. Special requests cannot be guaranteed.
No rollaway/extra beds available
No cribs (infant beds) available
A valid credit card is required at check-in for incidentals/damages otherwise a US$100 cash deposit per stay, per room will be collected. The deposit is refunded at check-out after satisfactory inspection. If refund is over US$100 a check will be mailed within 14 days of departure.
- Cash deposit: USD 100 per stay
Optional extras
- Pet fee: USD 25 per pet, per day (maximum USD 150 per stay)
Hotel Name
- Extended Stay America Hotel Indianapolis North
- Extended Stay America Indianapolis North
- Extended Stay Indianapolis
- Indianapolis Extended Stay
- Extended Stay America Indianapolis North Hotel
We should mention
Children 17 years old and younger stay free when occupying the parent or guardian's room, using existing bedding. Guests can arrange to bring pets by contacting the property directly, using the contact information on the booking confirmation (surcharges apply and can be found in the Fees section).


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In mybook®: Services
Native American Bank
510 W Tudor Rd Ste Ste 8, Anchorage, AK 99503
Closed Now
- Today
- 8:00 am - 12:00 pm
Regular Hours
- Mon - Fri
- 8:00 am - 6:00 pm
- Sat
- 8:00 am - 12:00 pm
General Info
Founded in 2001, Native American Bank (NAB) is a full-service provider of banking and financial services. Based in Anchorage, Alaska, it represents 26 federally recognized American Indian tribes and Alaska Native corporations and villages. The bank offers a range of services, such as depository accounts, loan products, cash management services and other services, to name a few. It serves its customers through five branches and offices and has 11 ATMs located in Colorado, Montana, Idaho, Alaska, and South Dakota. Native American Bank (NAB) is a member of the FDIC and an Equal Housing Lender.
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Democratic Politics and Party CompetitionTaylor and Francis 2006; US$ 54.95
This new book introduces�innovative�research on democracy from the leading Comparative Manifestos Project (CMP). It�details the key achievements of the project to date, illustrates how its findings may be applied, lays out the future challenges it faces and examines how the field as a whole can advance. It also presents a special assessment of the... more...
The Foreign Policy DisconnectUniversity of Chicago Press 2008; US$ 30.00
With world affairs so troubled, what kind of foreign policy should the United States pursue? Benjamin Page and Marshall Bouton look for answers in a surprising place: among the American people. Drawing on a series of national surveys conducted between 1974 and 2004, Page and Bouton reveal that?contrary to conventional wisdom?Americans generally hold... more...
Legislative Voting and AccountabilityCambridge University Press 2008; US$ 24.00 US$ 19.68
Carey examines individualistic and collective representation in democracies and how it is shaped by legislative party unity. more...
The Everything Robert's Rules BookF+W Media 2004; US$ 10.95 US$ 8.98
Get your meeting attendees to play by the rules! Have you ever been to a meeting that dissolved into utter chaos? Or attended a meeting that seemed unfocused and unproductive? Robert's Rules of Order have been the standard of parliamentary procedure for business and civic organizations since 1876. The Everything Robert's Rules Book fully explains... more...
The Handbook of National LegislaturesCambridge University Press 2009; US$ 56.00 US$ 45.92
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In the USA, social movements succeeded in stopping 59 proposals to build new conventional (dirty) coal-fired power stations. In the UK, there was an extended campaign to stop the expansion of Heathrow airport, primarily on the grounds of the greenhouse gas emissions from increased flights. Responding to this global epidemic, Climate Action is a campaign... more...
Democratic CommitmentsPrinceton University Press 2000; US$ 43.95 US$ 35.16
From the refusal of the U.S. Congress to approve fast-track trade authority and certain foreign aid packages to the obstacles placed by Western European parliaments in the path of economic integration, legislatures often interfere with national leaders' efforts to reach and implement predictable international agreements. This seems to give an advantage... more...
Voice and VoteStanford University Press 2011; US$ 21.95
In the months following disgraced ex-President Alberto Fujimori's flight to Japan, Peru had a political crisis on its hands. The newly elected government that came together in mid-2001 faced a skeptical and suspicious public, with no magic bullet for achieving legitimacy. Many argued that the future of democracy was at stake, and that the government's... more...
The Political Class in Advanced DemocraciesOUP Oxford 2003; US$ 214.99 US$ 184.89
This is the first comprehensive overview of professional politicians in democratic countries in Europe and North America. On a country by country basis it provides up-to-date information on when and how politicians became professionals in their own right, on the kind of institution they operate in, on typical career paths, incomes, and recent reform... more...


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Page 3 of 3
"I saw two people that looked like they needed someone," Pierce said. Jennifer was just back in Arkansas after having lived in Ireland, and she was more than a little reluctant to answer when Mathus called to ask her out. But she finally agreed to go on a date.
"Well, he was willing to drive an hour and a half from his place in Mississippi to Jonesboro, Ark.," she said. "I didn't feel like I could say no." On a hot summer day they went fishing and caught a solitary sun perch. A month later they would be engaged.
Another Arkansas/Mathus connection involves Conway native and fellow Fat Possum recording artist Jim Mize, who has been working on a new album of his own. In the past he has enlisted Tennessee guitar wizard John Paul Keith for studio work. Keith was not available for a session due to scheduling issues but Mathus was. The two had not worked together before, but Mize, familiar with Mathus' resume, was willing and eager to give it a go. He was impressed with the results. "We went into the studio as musical strangers and walked out as musical brothers," Mize said of the recording.
Going in that studio was key, because it gave Mathus a chance to walk into Fat Possum at just the right time. Given the considerable overlap between what Mathus does and what Fat Possum does, you have to ask: Why did it take so long for the two to come together? It's not for lack of trying. Mathus said he has pretty much sent the label everything he has done. This time he handed them "White Buffalo" and it was exactly what they'd been looking for from him.
" 'White Buffalo' is named for and written for Takota, the pure white (not albino) buffalo that died at Tupelo Buffalo Park in Tupelo, Miss., two years ago. They are incredibly rare and considered omens, blessings and frequently fulfill prophecy. He represents to me a deeper level of our local culture and mythology here in the hilly country of North Mississippi," Mathus told me.
There is much to like on the record, which may well be Mathus' best work to date. It's a mixed bag that conjures up everything from Hendrix to Hank Sr. without aping or simply mimicking anything along the way.
Found within the album's 10 tracks are blistering Southern rock riffs, heartfelt reflective ballads, back-road pop tunes and eerie midnight highway dirges. The record really seems to show off Mathus' songwriting and the Tri-State Coalition's versatility while Eric "Roscoe" Ambel's production keeps them reined in just enough. Ambel's relationship with Mathus is a new one and I hope it continues. It's early in '13 but I am sure that "White Buffalo" will be one of my favorite albums of the year.
Mathus isn't shy about expressing his pride in the album.
"As far as the recording itself, I've made some good recordings, but none great like this. I've had some great bands but none like Tri-State Coalition. I've written some good songs but none like these. The Mayan calendar has rolled over. This seems like a new beginning to me."
On Feb. 15, Jimbo Mathus & the Tri-State Coalition play an album release show at the White Water Tavern, a venue that has hosted Mathus and company many times. It's no surprise then that Matt White, one of the owner/operators of the White Water, is a longtime supporter and patron of Mathus and his music. So on the off chance that the record doesn't grab you, the live show certainly will. "Watch his eyes when he performs," White said. "There is an electrifying charisma and he believes in every damn word that he sings and note that he plays."
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On Second Thought is a one-hour, daily news talk show that airs at 9 a.m. ET weekdays.
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Wed., April 10, 2013 6:00am
Scalpers Selling Masters Badges On Highways
Richmond County Sheriff's Capt. Scott Gay said authorities are likely to file charges against people found scalping tickets along local highways because of safety concerns. Those arrested will be charged with improper stopping on a roadway and other offenses.
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Thu., April 7, 2011 11:29am
Masters Tickets Go Public
Golf fans around the world now have a shot at tickets to the Masters Tournament. It's the first time in decades the most coveted ticket in all of sports will be offered to the public.
Mon., April 4, 2011 3:08am
Corporate Spending Returns To The Masters
This year's Masters Golf Tournament could pack the biggest economic impact of any in recent memory. Travel agents are reporting a boost in corporate spending for Augusta's biggest annual tourist draw.


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Video: Mo. suspect strikes officer during violent club melee
Struggle between an intoxicated suspect and an officer is under review by the Springfield Police Department
By PoliceOne Staff
SPRINGFIELD, Mo. — A video capturing a struggle between an intoxicated suspect and an officer is under review by the Springfield Police Department.
According to the Springfield News-Leader, Officer Tomas Jordan and another officer were called to the scene to assist in getting "several combative people" out of a club on April 27.
Fearing for their safety as the crowd grew rowdy, officers called for backup.
It was then that Officer Tomas Jordan saw 24-year-old Courtney Lewis approach him and take a "fighting stance," according to a police statement reported by the Springfield News-Leader.
The video shows Lewis being pushed to the ground after approaching the officer. Lewis quickly stands up and begins throwing punches at Officer Jordan.
Lewis was charged with second-degree assault of a law enforcement officer. Officer Jordan suffered a scratch and swelling on his face.
The department is currently reviewing use of force in the incident.
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MMR has been showing support around $10.49 and resistance in the $14.21 price range. From the relationship between price and moving averages; we can see that: This stock is BULLISH in short-term; and BULLISH in mid-long term.Check here:'http://www.stoxline.com/quote.php?symbol=MMR'
Really bullish, I love the chart.
The only data that matters is what will come out around July 30th. Then we can think about SS188, and Lineham, and DJ2, and.....
Santa, don't rush Xmas, the man said week of.......7/30.In my book that indicates 8/2-4 likely, yet the power of imminence allows for a factor of 2 to the second power to satisfy the domain of the defined cloud.


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The Scraper is basically a weaker version of the Missionary. You can find it in the Church of Silent Hill in Silent Hill 3.
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|Publication number
|Publication type
|Application number
|Publication date
|Jun 9, 1992
|Filing date
|Jul 11, 1989
|Priority date
|Jan 6, 1988
|Fee status
|Publication number
|Robert G. Davis, Allyn R. Bell, John A. Minatelli
|Original Assignee
|Uniroyal Chemical Company, Inc.
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (12), Non-Patent Citations (6), Referenced by (6), Classifications (17), Legal Events (7)
|External Links: USPTO, USPTO Assignment, Espacenet
This application is a continuation-in-part of co-pending U.S. patent application Ser. No. 07/141,182, filed Jan. 6, 1988 now abandoned.
This invention is directed to novel heterocyclicalkylene quinoxalinyloxyphenoxypropanoate compounds which exhibit unexpectedly desirable selective herbicidal activity. In other aspects, this invention is directed to herbicidal compositions comprising such compounds as well as to a method for controlling the growth of plants employing such quinoxalinyl derivatives.
The control of undesirable grasses is important in the cultivation of many important broadleaf agricultural species such as soybeans, peanuts and cotton, as well as in the cultivation of many horticultural species. Moreover, the presence of such weeds on noncropped areas may present a fire hazard, or may result in the undesirable drifting of sand or snow or irritation to persons with allergies. Accordingly, it would be beneficial to control the growth of undesirable grasses, particularly in a manner which would allow for the selective control of such plants without concurrent injury to desirable broadleaf crops or vegetation.
Among the classes of compounds which have been employed in the past to control the growth of undesirable vegetation are certain quinoxalinyloxyphenoxy compounds. Thus, Ura et al in U.S. Pat. No. 4,629,493 disclose certain quinoxalinyl compounds, including 6-membered homocyclic ring derivatives such as benzyl 2-[4-(6-chloro-2-quinoxalinyloxy)phenoxy]-propanoate, which are useful as selective herbicides. Similarly, in European Patent Application 46,467, Ura et al show a number of quinoxalinyloxyphenoxy compounds, including a morpholino ester thereof, which are useful as herbicides.
Somewhat similarly, U.S. Pat. No. 4,429,167 to Lee discloses a broad range of 3-alkoxy-4-substituted-phenoxy-2,-3-unsaturated acids, including quinoxalinyl derivatives thereof which are selective herbicides for grasses, while U.S. Pat. No. 4,609,396 to Fawzi shows a variety of quinoxalinyloxy ethers which are useful for controlling grass weeds in broadleaf plants. Chemical Abstracts 98, 198278m (1983) discloses herbicidal glycidyl quinoxalin-2-yloxyphenoxypropionates while European Patent Application 206,772 shows quinoxalinyloxybenzyl ester compounds which are useful for the selective control of weeds in rice. Spanish Patent Application 8,603,431 shows herbicidal alkyl quinoxalinyloxyphenoxypropanoates while European Patent Application 113,831 shows selective herbicides which are carbamylethyl esters of quinoxalinyloxyphenoxypropanoic acids. European Patent Application 121,871 shows herbicidal phosphoric acid esters of quinoxalinyloxyphenoxypropanoates while U.S. Pat. No. 4,499,271 shows phosphoric acid esters of quinoxalinyloxyphenoxypropanoates. German Application 3,433,390 shows silane esters of quinoxalinyloxyphenoxypropanoic acid, while Kruger et al in U.S. Pat. No. 4,601,748 disclose herbicidal 2-phenoxypropionic acid derivatives of pentitols.
In contrast, U.S. Pat. No. 4,564,381 to Bieringer et al shows a very broad class of compounds, including many quinoxalinyloxyphenoxypropanoic esters which function as plant growth stimulants.
While many of the compounds shown in the above publications exhibit desirable herbicidal activity, it would nevertheless be desirable to possess herbicides which exhibited enhanced selective control of undesirable grasses.
Accordingly, it is an object of this invention to provide a class of novel compounds which exhibit unexpectedly desirable selective herbicidal activity.
It is a further object of this invention to provide a method of controlling undesirable weeds.
These objects and other additional objects will become more fully apparent from the following disclosure and accompanying examples.
In one aspect, this invention is directed to a novel class of compounds having the structural formula: ##STR2## wherein: n is 0, 1, 2 or 3;
R1 and R2 are each independently selected from the group consisting of halogen, hydrogen, C1 -C3 alkoxy, C1 -C3 haloalkoxy, monohalomethyl, dihalomethyl, trihalomethyl, cyanato and nitro; and
R3 is a 4-, or 5- or 6-membered saturated, unsaturated or partially unsaturated heterocyclic ring containing 1 or 2 oxygen atoms, or a 5- or 6-membered saturated, unsaturated or partially unsaturated heterocyclic ring containing 1 or 2 sulfur atoms or one sulfur atom and one oxygen atom; said ring optionally being substituted with between 1 and 3 substituents each independently selected from the group consisting of oxo, C1 -C3 alkyl and C1 -C3 alkoxy.
In another aspect, this invention is directed to a herbicidal composition comprised of:
(A) a compound having the structural formula: ##STR3## wherein: n is 0, 1, 2 or 3;
R1 and R2 are each independently selected from the group consisting of halogen, hydrogen, C1 -C3 alkoxy, C1 -C3 haloalkoxy, monohalomethyl, dihalomethyl, trihalomethyl, cyanato and nitro; and
R3 is a 4-, 5- or 6-membered saturated, unsaturated or partially unsaturated heterocyclic ring containing 1 or 2 oxygen atoms, or a 5- or 6-membered saturated, unsaturated or partially unsaturated heterocyclic ring containing 1 or 2 sulfur atoms or one sulfur atom and one oxygen atom; said ring optionally being substituted with between 1 and 3 substituents each independently selected from the group consisting of oxo, C1 -C3 alkyl and C1 -C3 alkoxy, and
(B) a suitable carrier.
In yet another aspect, this invention is directed to a method of controlling undesirable plants, which method herbicidally effective amount of a compound having the structural formula: ##STR4## wherein: n is 0, 1, 2 or 3;
R1 and R2 are each independently selected from the group consisting of halogen, hydrogen, C1 -C3 alkoxy, C1 -C3 haloalkoxy, monohalomethyl, dihalomethyl, trihalomethyl, cyanato and nitro; and
R3 is a 4-, 5- or 6-membered saturated, unsaturated, or partially unsaturated heterocyclic ring containing 1 or 2 oxygen atoms, or a 5- or 6-membered saturated, unsaturated or partially unsaturated heterocyclic ring containing 1 or 2 sulfur atoms or one sulfur atom and one oxygen atom; said ring optionally being substituted with between 1 and 3 substituents each independently selected from the group consisting of oxo, C1 -C3 alkyl and C1 -C3 alkoxy. The novel compounds of this invention are of the formula: ##STR5## wherein R1, R2, R3 and n are as defined for formula (I) above. It is to be noted that R3 may be an unsaturated, saturated or partially unsaturated (i.e., containing at least one carbon-carbon double bond and at least one carbon-carbon single bond) heterocyclic moiety.
R1 is chlorine, trichloromethyl or trifluoromethyl;
R2 is hydrogen; and
R3 is furanyl, tetrahydrofuranyl, dioxolanyl, tetrahydrodioxolanyl, dihydropyranyl, tetrahydropyranyl, tetrahydrothiophenyl, tetrahydrothiophenyl-1,1-dioxide, tetrahydrothiopyranyl, (thiophenyl)methyl, (thiophenyl)ethyl, (dimethyloxathiophenyl)methyl, (dimethyldithiolanyl)methyl or thiochromanyl; optionally substituted with 1, 2 or 3 moieties selected from the group consisting of oxo and methyl.
Particularly preferred compounds include:
2-tetrahydrofuranylmethyl 2-[4-(6-chloro-2-quinoxalinyloxy)phenoxy]-propanoate;
2-furanylmethyl 2[4-(6-chloro-2-quinoxalinyloxy)phenoxy]propanoate;
2-tetrahydropyranylmethyl 2-[4-(6-chloro-2-quinoxalinyloxy)-phenoxy]-propanoate;
2-[2-(2-methyl-1,3-dioxolanyl)]ethyl 2-[4-(6-chloro-2-quinoxalinyloxy)phenoxy]propanoate;
4-(2,2-dimethyl-1,3-dioxolanyl)methyl 2-[4-(6-chloro-2-quinoxalinyloxy)phenoxy]propanoate;
3-tetrahydrothiophenyl 2-[4-(6-chloro-2-quinoxalinyloxy)phenoxy]propanoate;
4-tetrahydrothiopyranyl 2-[4-(6-chloro-2-quinoxalinyloxy)phenoxy]propanoate;
3-tetrahydrothiopyranyl 2-[4-(6-chloro-2-quinoxalinyloxy)phenoxy]propanoate;
3-tetrahydrothiophenyl-1,1-dioxide 2-[4-(6-chloro-2-quinoxalinyloxy)phenoxy]propanoate;
2-thiophenylmethyl 2-[4-(6-chloro-2-quinoxalinyloxy)phenoxy]propanoate;
2-(2-thiophenyl)ethyl 2-[4-(6-chloro-2-quinoxalinyloxy)phenoxy]propanoate;
5-(2,2-dimethyl-1,3-oxathiolanyl)methyl 2-[4-(6-chloro-2-quinoxalinyloxy)phenoxy]propanoate;
4-(2,2-dimethyl-1,3-dithiolanyl)methyl 2-[4-(6-chloro-2-quinoxalinyloxy)phenoxy]propanoate; and
4-thiochromanyl 2-[4-(6-chloro-2-quinoxalinyloxy)phenoxy]propanoate.
The compounds of this invention may be prepared by reacting a quinoxalinyloxyphenol compound of the formula: ##STR6## wherein R1 and R2 are as defined for structure (I) above; with a substituted heterocyclicalkylpropanoate of the formula: ##STR7## wherein X is halogen, mesylate or tosylate and n and R3 are as defined for structure (I) above. This reaction is typically conducted in an organic solvent (such as dimethylformamide, dimethylsulfoxide, acetonitrile or the like) in the presence of an inorganic or organic base (such as sodium carbonate, potassium hydroxide or potassium carbonate) at suitable temperature.
The quinoxalinyloxyphenoxy starting materials may be prepared by reacting a 2-haloquinoxaline compound having the formula: ##STR8## wherein X is halogen and R1 and R2 are as defined in structure (I) above, with a phenyl benzyl ether of the formula: ##STR9## in the presence of an inorganic or organic base to produce an and hydrogenating such intermediate (employing a hydrogenation ##STR10## and hydrogenating such intermediate (employing a hydrogenation catalyst such as palladium) to produce a debenzylation thereby forming the quinoxalinyloxyphenol starting material.
The heterocyclicalkylpropanoate starting material may be produced by reacting a halogenated propionic acid halide with the appropriate heterocyclic alkyl alcohol.
Alternatively ethyl 2-halopropanoate may be reacted with the appropriate heterocyclic alkyl alcohol in the presence of an appropriate catalyst (such as tetra-isopropoxy titanium) to produce the heterocyclicalkylpropanoate halide via a transesterification process.
The compositions of this invention are comprised of (A) at least one of the quinoxalinyloxyphenoxypropanoate compounds of this invention, and (B) a suitable carrier.
To prepare such herbicidal compositions, the quinoxalinyloxyphenoxypropanoate compound may be mixed with inert ingredients to provide compositions in the form of finely-divided particulate solids, granules, pellets, wettable powders, flowable liquids, soluble powders, solutions, and aqueous or organic solvent dispersions or emulsions. Such formulations may be of several different physical and chemical types, any of which could be made by one familiar with the art. For instance, the active compound may be impregnated on finely-divided or granular inorganic or organic carriers such as attapulgite clay, sand, vermiculite, corn cob, activated carbon or other granular carriers known to the art. The impregnated granules may then be spread on the soil or incorporated into the soil.
Alternatively, the chemical may be formulated as a wettable powder by mixing it with an inactive powdered carrier to which a surface active dispersing agent has been added and grinding the mixture into a fine powder. Typical powdered solid carriers are the various mineral silicates (such as mica, talc, pyrophyllite, clays and the like) or powdered organic material (e.g., corn cob). The wettable powder may then be dispersed in water and sprayed on the soil surface, or on crop or weed plants.
Similarly, an emulsifiable concentrate may be prepared by dissolving the chemical in a solvent such as xylene, toluene, or other aliphatic or aromatic hydrocarbon to which a surface active dispersing agent generally has been added. The emulsifiable concentrate may then be dispersed in water and applied by spraying.
The concentration of active chemical in the composition may vary widely typically ranging from about 1 to about 95% by weight. The concentration of active chemical in dispersions applied to the soil, seed or foliage is typically between about 0.002% and about 80% by weight.
Formulations containing the active ingredient(s) may be dispersed in water or an organic liquid (such as oil) and applied to target plants. Surface active agents may be added to the applied solution to increase its qualitative or quantitive range of activity. Suitable surface active agents are well known to those skilled in the art. Reference may be made to McCutcheon's Detergents and Emulsifiers (1980, Allured Publ. Co., Ridgewood, N.J.) for examples of appropriate surface active agents. Suitable adjuvants containing appropriate surface active agents include "AGRI-DEX" and "INDUCE" (Helena Chemical Co.), "SUPER SAVOL" (Leffingwell), "CANPLUS 411" (Atlas), and "ASSIST" (BASF). Similarly, such formulations may be applied to the soil either as a liquid or a granule.
For use as a preemergence herbicide the compound of this invention is typically applied at a rate of from about 0.01 to about 10 pounds per acre (about 0.01 to about 11.2 kg/ha) to soil which contains weed and crop seed. Such application is made either to the surface of the soil or into the upper one to three inches (2.5 to 7.5 cm.) of soil. When employed as a postemergence herbicide the compound is typically applied at a rate of from about 0.01 to about 10 pounds per acre (about 0.01 to about 11.2 kg/ha) to the aerial portions of weeds.
The most suitable dosage of application, and the most effective type and amount of adjuvant substance will depend on a number of factors, including the plant species; the stage of plant development; the method of application; the air and soil temperature and the quantity and intensity of rainfall before and after treatment; the soil type, pH, fertility and moisture and organic matter content; the physiological condition and vigor of the target plants; the relative humidity and wind velocity of the air around the crop at the time of treatment; the extent and density of the foliar canopy of the target plant; the light quality, intensity and duration each day; the type and interval of previous and subsequent crop protectant chemical applications. However, one skilled in the art can, by routine experimentation, readily determine optimum conditions for the employment of any particular quinoxyalinyloxyphenoxypropanoate compound.
The compounds of the present invention include the isomeric forms and mixtures thereof. Thus, the invention in includes the optically active isomers and racemic mixtures. Unless otherwise specified herein, the compounds described in the examples are racemic mixtures.
The following Examples are intended to further illustrate the invention and are not intended to limit the scope of the invention in any manner whatsoever.
To a 250 milliliter three-necked flask were added 0.15 mole of 2-(hydroxymethyl)tetrahydrofuran, 0.15 mole of triethylamine, and 100 milliliters of diethylether. The flask was immersed in ice, and 0.15 mole of 2-bromopropanoyl chloride introduced dropwise. The ice bath was removed, and the reaction stirred at ambient temperature for two hours. The mixture was extracted with an equal volume of water, and the organic phase dried over sodium sulfate. Decantation and solvent removal resulted in 2-tetrahydrofuranylmethyl 2-bromopropanoate in 94% yield.
To a 500 milliliter roundbottom flask were added 0.055 mole of 2-(4-hydroxyphenoxy)-6-chloroquinoxaline, 0.055 mole of 2-tetrahydrofuranylmethyl 2-bromopropanoate, 0.110 mole of anhydrous potassium carbonate, and 250 milliliters of acetonitrile. The mixture was refluxed for 5.5 hours and the solvent removed. The residue was filtered through a column of alumina with dichloromethane. Solvent removal and recrystallization from boiling hexane resulted in an 85% yield of 2-tetrahydrofuranylmethyl 2-[4-(6-chloro-2-quinoxalinyloxy)phenoxy]propanoate. The material melted over a range of 52�-55� C.
To a 50 milliliter three-necked flask equipped with stir bar, glass stopper, rubber stopple, connecting tube, and nitrogen atmosphere were added 2.1808 grams (0.0191 moles) of 2-hydroxymethylthiophene, 2.66 milliliters (0.0191 moles of triethylamine, and 20 milliliters of anhydrous diethylether.
The flask was immersed in an ice water bath, and 2.0 milliliters (0.0191 moles) of 2-bromopropanoyl bromide added dropwise by syringe. The mixture was stirred at 0� for 5 minutes, then at ambient temperature for one hour. Triethylamine hydrochloride was removed by filtration on a Buchner funnel and with two water extractions of the organic phase. Drying of the ether solution over anhydrous sodium sulfate, decantation, and solvent removal by rotary evaporation resulted in a quantitative yield of 2-thiophenylmethyl 2-bromopropanoate as an oil.
To a 250 milliliter roundbottom flask equipped with stir bar, reflux condenser, connecting tube, and nitrogen atmosphere were added 4.3781 grams (0.0161 moles) of 2-(4-hydroxyphenoxy)-6-chloroquinoxaline, 4.000 grams (0.0161 moles) of 2-thiophenylmethyl 2-bromopropanoate, 4.4377 grams (0.0321 moles) of anhydrous potassium carbonate, and 100 milliters of acetonitrile.
The mixture was refluxed for 6 hours, then filtered while hot through a Buchner funnel. Acetonitrile was removed by rotary evaporation, and the residue plug filtered through a column of alumina with dichloromethane. Solvent removal at reduced pressure resulted in 4.6389 grams of tan solid 2-thiophenylmethyl 2-[4-(6-chloro-2-quinoxalinyloxy)phenoxy]-propanoate, a 65.3% yield.
Additional compounds within the scope of the invention were prepared using essentially the procedures outlined above. The structures and melting points are summarized in Table I below. The NMR spectra of compounds 3, 5 and 7-18 are summarized in Table II below. (Note: in such NMR data s=singlet; d=duplet; t=triplet; q=quartet; and m=multiplet).
TABLE I__________________________________________________________________________ ##STR11##Compound Number R1 R2 R3 n Melting Point (�C.)__________________________________________________________________________1 6-Cl H ##STR12## 1 130-134�2 6-Cl H ##STR13## 1 98-101�3 6-Cl H ##STR14## 1 Oil4 6-Cl H ##STR15## 1 52-55�5 6-Cl H ##STR16## 2 Oil6 6-Cl H ##STR17## 1 60-64�7 6-Cl H ##STR18## 0 78-82�8 6-Cl H ##STR19## 0 Oil9 6-Cl H ##STR20## 1 Oil10 6-Cl H ##STR21## 0 Oil11 6-Cl H ##STR22## 0 Oil12 6-Cl H ##STR23## 0 Oil13 6-Cl H ##STR24## 1 Oil14 6-Cl H ##STR25## 1 112-114�15 6-Cl H ##STR26## 2 171-172�16 6-Cl H ##STR27## 1 Oil17 6-Cl H ##STR28## 1 Oil18 6-Cl H ##STR29## 0 Oil__________________________________________________________________________
TABLE II______________________________________Nuclear Magnetic Resonance DataCom-poundNumber NMR (CDCl3)______________________________________ 3 1.38(s, 3H), 1.43(s, 3H), 1.68(d, 3H), 3.50-4.24(m, 5H), 4.80(q, 1H), 7.02(q, 4H), 7.59(s, 2H), 8.00(s, 1H), 8.61(s, 1H). 5 1.46(s, 3H), 1.77(d, 3H), 2.14(t, 2H), 3.99(s, 4H), 4.38(t, 2H), 4.81(q, 1H), 7.07(q, 4H), 7.62(s, 2H), 8.02(s, 1H), 8.62(s, 1H). 8 1.64(d, 3H), 3.70-3.96(m, 5H), 4.78(q, 1H), 5.38(s, 1H), 6.92-7.20(q, 4H), 7.54-7.68(m, 2H), 8.02(s, 1H), 8.65(s, 1H). 9 1.21(s, 3H), 1.60(d, 3H), 4.08-4.48(m, 6H), 4.78(q, 1H), 6.76-7.18(q, 4H), 7.48(m, 2H), 7.88(s, 1H), 8.52(s, 1H).10 1.63(d, 3H), 1.88-2.35(m, 2H), 2.73-3.18(m, 4H), 4.79(q, 1H), 5.57(m, 1H), 6.96(d, 2H), 7.20(d, 2H), 7.63(m, 2H), 8.03(s, 1H), 8.65(s, 1H).11 1 65(d, 3H), 1.70-2.19(m, 4H), 2.46-2.87(m, 4H), 4.78(q, 1H), 4.95(m, 1H), 6.95(d, 2H), 7.08(d, 2H), 7.63(m, 2H), 8.03(s, 1H), 8.67(s, 1H).12 1.65(d, 3H), 1.77-2.21(m, 4H), 2.45-2.82(m, 4H), 4.77(q, 1H), 4.98(s, 1H), 6.96(d, 2H), 7.17(d, 2H), 7.63(m, 2H), 8.04(s, 1H), 8.65(s, 1H).13 1.63(d, 2H), 2.47(m, 2H), 2.94-3.27(m, 4H), 4.85(q, 1H), 5.59(m, 1H), 6.96(d, 2H), 7.22(d, 2H), 7.60(m, 2H), 8.01(s, 1H), 8.65(s, 1H).14 1.64(d, 3H), 4.75(q, 1H), 5.32(s, 2H), 6.73-7.37(m, 7H), 7.55(m, 2H), 7.97(s, 1H), 8.57(s, 1H).15 1.69(d, 3H), 3.19(t, 2H), 4.42(t, 2H), 4.78(q, 1H), 6.71-7.31(m, 7H), 7.52(m, 2H), 7.96(s, 1H), 8.58(s, 1H).16 1.61(d, 3H), 1.67(s, 6H), 2.98(m, 2H), 4.38(m, 3H), 4.83(q, 1H), 6.96(d, 2H), 7.19(d, 2H), 7.62(m, 2H), 8.02(s, 1H), 8.67(s, 1H).17 1.57-1.82(m, 9H), 2.91-3.12(M, 2H), 4.11-4.39(m, 3H), 4.80(q, 1H), 6.95(d, 2H), 7.18(d, 2H), 7.63(m, 2H), 8.03(s, 1H), 8.66(s, 1H).18 1.62(d, 3H), 4.77(q, 1H), 6.08(m, 1H), 6.87-7.18(m, 4H), 6.91(d, 2H), 7.15(d, 2H), 7.61(M, 2H), 8.02(s, 1H), 8.63(s, 1H).______________________________________
To illustrate the effectiveness of the heterocyclicalkylene quinoxalinyloxyphenoxypropanoate compounds of this invention as preemergence herbicides, 300 mg of each of the below listed compounds were dissolved in 10 ml acetone to which 30 mg of an emulsifying agent, ethoxylated sorbitan monolaurate, were added. The solution was diluted to 100 ml with distilled water. Ten milliliters of this 3000 ppm solution were diluted to 250 ppm with distilled water. The chemical was applied at the rate of 10 lb/A (11.2 kg/ha) by drenching 46 ml of the 250 ppm solution on the surface of soil in 4-1/2 inch (11.25 cm.) plastic pots wherein seeds of the following weeds had been planted; velvet leaf (Abutilon theophrasti Medic.), "VL"; jimsonweed (Datura stramonium L.), "JW", or prickly sida (Sida spinosa L.), "PS"; tall morningglory (Ipomea purpurea L. Roth), "TM"; switchgrass (Panicum virgatum L.), "SG"; barnyard grass (Echinolchloa crus-galli (L.) Beauv.), "BG"; and green foxtail (Setaria viridis) (L.) Beauv.), "GF".
The percent control of the weeds compared to untreated checks was determined two weeks after treatment. The results of such testing are summarized in Table III below.
TABLE III______________________________________Preemergent ControlCompound Percent Weed ControlNumber VL JW PS TM BG SG GF______________________________________ 1 0 0 -- 0 100 100 100 2 0 0 -- 0 100 100 100 3 0 0 -- 0 100 100 100 4 0 0 -- 0 100 100 100 5 0 0 -- 0 100 100 100 6 0 0 -- 0 100 100 100 7 0 0 -- 0 100 100 100 8 0 0 -- 0 100 100 100 9 0 0 -- 0 100 100 10010 0 -- 0 0 100 100 10011 0 -- 95 0 100 100 10012 0 -- 0 0 100 100 10013 0 -- 0 0 100 100 10014 60 50 -- 75 100 100 10015 65 40 -- 15 100 100 10016 0 -- 100 0 -- 100 10017 0 -- 0 0 100 100 10018 0 -- 100 50 100 100 100______________________________________
The above data show the excellent selective preemergent herbicidal control exhibited by the compounds of this invention.
To illustrate the effectiveness of the compounds of this invention as postemergence herbicides, the 3000 ppm solutions described under Example 4 were atomized with a conventional DeVilbiss [trademark] sprayer, wetting the foliage to the drip point. The remainder of the procedure was the same as described under Example 4. The weeds, which were the same species as described under Example 4, were treated six days after emergence.
The percent weed control was evaluated two weeks after treatment. The results of such testing are summarizes in Table IV below.
TABLE IV______________________________________Postemergence TreatmentPercent Weed ControlCompoundNumber VL JW PS TM BG SG GF______________________________________ 1 0 0 -- 0 100 100 100 2 0 0 -- 15 100 100 100 3 10 90 -- 15 100 100 100 4 0 20 -- 10 100 100 100 5 0 0 -- 40 100 100 100 6 0 20 -- 10 100 100 100 7 0 0 -- 5 100 100 100 8 0 0 -- 5 100 100 100 9 0 0 -- 5 100 100 10010 30 -- 0 50 100 100 10011 40 -- 15 20 100 100 10012 0 -- 0 10 100 100 10013 0 -- 20 60 100 100 10014 15 30 -- 0 100 100 10015 30 35 -- 10 100 100 10016 100 -- 65 40 100 100 10017 10 -- 0 5 100 100 10018 0 -- 0 0 100 100 100______________________________________
The above data show the desirable selective postemergent herbicidal control exhibited by the novel compounds of this invention.
To illustrate the effectiveness of the novel heterocyclicalkylene quinoxalinyloxyphenoxypropanoate derivatives of this invention for preemergence grass control relative to prior art homocyclicalkylene quinoxalinyloxyphenoxypropanoate compounds, solutions of several of the compounds were prepared in a manner similar to that described in Example 1. The 250 ppm solutions were diluted to 3.1 ppm with distilled water to provide testing at a rate of 0.14 kg/ha as a 46 ml drench to 11.25 cm diameter pots. In a similar manner, solutions of Compound A--benzyl 2-[4-(6-chloro-2-quinoxalinyloxy)phenoxy]propanoate, a compound within the scope of U.S. Pat. No. 4,629,493 (Compound 55)--were prepared and tested.
The structures of the tested compounds are as follows: ##STR30##
The results of such testing are summarized in Table V below.
TABLE V______________________________________ Percent Weed Control Rate Wild Green BarnyardCompound kg/ha Oats Foxtail Grass______________________________________2 0.14 60 80 604 0.14 70 80 806 0.14 50 70 90A 0.14 50 65 30______________________________________
The above data clearly show the unexpected desirable activity of the compounds of the present invention relative to known homocyclic 5- or 6-membered ring derivatives.
|Cited Patent
|Filing date
|Publication date
|May 24, 1977
|Oct 7, 1980
|Hoechst Aktiengesellschaft
|Phenoxyphenoxy-propionic acid derivatives
|Jan 22, 1982
|Jan 31, 1984
|Zoecon Corporation
|3-Alkoxy-4-substituted-phenoxy-2,3-unsaturated acids, esters and derivatives
|Aug 20, 1982
|Feb 12, 1985
|Zoecon Corporation
|3-Phosphinyloxy-4-(substituted phenoxy)alkenoic acid esters
|Oct 7, 1983
|Jan 14, 1986
|Hoechst Aktiengesellschaft
|Increase of carbohydrate accumulation in plants by means of substituted derivatives of phenoxyalkanoic acids and cyclohexanediones
|Oct 7, 1983
|Jul 22, 1986
|Schering Aktiengesellschaft
|2-phenoxy propionic acid derivatives of pentite, process for the production of these compounds as well as compositions containing the same having herbicidal effectiveness
|Jun 23, 1980
|Sep 2, 1986
|E. I. Du Pont De Nemours And Company
|Quinoxalinyloxy ethers as selective weed control agents
|Jan 29, 1980
|Dec 16, 1986
|Nissan Chemical Industries Ltd.
|Heterocyclic ether type phenoxy fatty acid derivatives and herbicidal composition
|Oct 15, 1985
|Jun 14, 1988
|The Dow Chemical Company
|Certain 3,5-disubstituted-2-pyridyloxy-fluorophenoxy-alkanoic acids, derivatives thereof and herbicidal properties
|Apr 20, 1988
|Aug 14, 1990
|Tosoh Corporation
|Phenoxypropionic acid ester derivatives as herbicides
|Aug 21, 1980
|Mar 3, 1982
|Nissan Chemical Industries Ltd.
|Quinoxaline derivatives and herbicidal composition
|Apr 20, 1988
|Oct 26, 1988
|Agro-Kanesho Co., Ltd.
|Phenoxypropionic acid derivatives for use as herbicides
|Dec 20, 1988
|Jul 12, 1989
|UNIROYAL CHEMICAL COMPANY, Inc.
|Heterocyclic-alkylene quinoxalinyloxyphenoxy propanoate herbicides
|Abstract for DE 3433390 (Mar. 20, 1986).
|Abstract for EP113831 (Jul. 25, 1984).
|Abstract for EP121871 (Oct. 17, 1984).
|Abstract for EP206772 (Dec. 30, 1986).
|Abstract for ES542418 (Apr. 16, 1986).
|Nissan Chemical Industries Ltd. (Chem. Abs. vol. 98:198278m) (1983).
|Citing Patent
|Filing date
|Publication date
|Apr 30, 1992
|Jun 7, 1994
|Uniroyal Chemical Company, Inc.
|Heterocyclic-alkylene quinoxalinyloxyphenoxypropanoate herbicides
|Feb 6, 2003
|Nov 23, 2004
|Aventis Pharmaceuticals Inc.
|Quinoline and quinoxaline compounds which inhibit platelet-derived growth factor and /or p56lck tyrosine kinases
|Feb 4, 2003
|Feb 8, 2005
|Aventis Pharmaceuticals Inc.
|Quinoline and quinoxaline compounds which inhibit platelet-derived growth factor and/or p56lck tyrosine kinases
|Feb 12, 2003
|Jul 3, 2003
|Dober Chemical Corporation
|Liquid replacement systems
|Feb 4, 2003
|Jul 24, 2003
|Myers Michael R.
|Quinoline and quinoxaline compounds which inhibit platelet-derived growth factor and/or p56lck tyrosine kinases
|Feb 6, 2003
|Jul 24, 2003
|Myers Michael R.
|Quinoline and quinoxaline compounds which inhibit platelet-derived growth factor and /or p56lck tyrosine kinases
|U.S. Classification
|504/235, 549/39, 544/354, 549/23, 549/454, 549/79, 549/323, 549/427, 549/13, 549/30, 549/499
|International Classification
|Cooperative Classification
|European Classification
|Sep 5, 1989
Owner name: UNIROYAL CHEMICAL COMPANY, INC., A CORP. OF NJ, CO
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|Sep 26, 1995
|Fee payment
Year of fee payment: 4
|Nov 30, 1999
|Fee payment
Year of fee payment: 8
|Dec 9, 2003
|Fee payment
Year of fee payment: 12
|Nov 10, 2004
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|Jul 13, 2005
Owner name: UNIROYAL CHEMICAL COMPANY, CONNECTICUT
Free format text: RELEASE OF LIEN IN PATENTS;ASSIGNOR:DEUTSCHE BANK AG, NEW YORK BRANCH;REEL/FRAME:016522/0117
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|May 12, 2009
Owner name: CITIBANK, N.A., DELAWARE
Free format text: SECURITY AGREEMENT;ASSIGNORS:CHEMTURA CORPORATION;A & M CLEANING PRODUCTS, LLC;AQUA CLEAR INDUSTRIES, LLC;AND OTHERS;REEL/FRAME:022668/0658
Effective date: 20090318


text:
Worldwide Locations
The late diplomat's son, the documentarian David Holbrooke, discussed his father's difficult relationship with the president at the Asia 21 Young Leaders Summit in Hong Kong.
The rising sun casts an orange glow over the fields and trees in Victoria, Australia on November 9, 2015. (Graham Hartle/Flickr)
Each week, we'll reach into Asia Society's archives to find a photo from the organization's nearly 60-year history. This week: When Asia Society brought two titans of entertainment together in Beijing.
A row of boats wait by the banks of the Ganges river in Varanasi, India on November 23, 2015. (Juan Antonio F. Segal/Flickr)
The Iranian-born author, imprisoned in his native country for three months, explains why he documented his experience in a best-selling novel.
A lone tree in a landscape blanketed by snow in Hokkaido, Japan on December 7, 2015. (Soumei Baba/Flickr)
Saad Mohseni and Faiysal AliKhan discuss how empowered young people bring much needed creativity and boldness to tackling big challenges.
A bucket full of brightly colored carnations at the flower market in Kowloon, Hong Kong on November 21, 2015. (Tahiat Mahboob)
The retired general talks to Asia Society's Tom Nagorski about his military career, stint as CIA director, and why leadership is like "Groundhog Day."
Read an excerpt from Almira Astudillo Gilles' book "The Fire Beneath: Tales of Gold" which tells the story of how Berto Morales stumbled upon relics of the Philippines' gilded past.
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text:
The war on drugs provides the show's running theme as "The Wire" tracks the conflicts and tactics of the Barksdale gang of inner-city coke dealers and a special police investigative unit, loosely centered around electronic surveillance (the "wire" of the title). But each episode moves up and down the chain of command of both organizations, from junkies and street-corner pushers to Baltimore's most powerful elected leaders. Dominic West gets top billing as boat-rocking, bridge-burning Detective McNulty, but "The Wire" is a sprawling, superbly acted ensemble piece and not a star vehicle.
The show's ingenious second season expanded to include corruption on the waterfront, while the third season, premiering Sun., Sept. 19, at 9 p.m., puts the drug war back on the front burner and folds politics into the mix. A new plot thread includes a young city councilman who uses Baltimore's high crime statistics to elevate his own profile. Time and again, "The Wire" illustrates how clogged institutions and petty self-interests impede the progress of justice.
"The Wire's" third season boasts an impressive literary pedigree, with scripters including such novelists as Mystic River's Dennis Lehane and Clockers' Richard Price. Scenes crackle with street slang and the details of crime scene procedures, yet David Simon and his writers never dumb down the material. Once you get over the show's steep learning curve, you'll find yourself a "Wire" addict, desperately checking your cable listings for the next fix."The Wire" airs Sundays at 9 p.m. on HBO.
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