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Gear Spotlight: Is the 24-70mm f/4 IS Canon's Best General-Purpose Zoom?
The 24-70mm zoom range is one of the most popular zoom ranges on any camera, and most manufacturers have at least one lens in that category. Canon's 24-70mm f/2.8 zoom was getting fairly long in the tooth, and its replacement, the Mark II, has garnered widespread praise and accolades from users and reviewers alike. Lost […]
Moose Peterson's Shooting Tips for the Nikon 800mm f/5.6 Super Telephoto Lens
Moose Peterson is a Nikon Legend Behind the Lens, Lexar Elite Photographer, recipient of the John Muir Conservation Award, and a Research Associate with the Endangered Species Recovery Program. Moose has a passion for photographing wildlife and wild places and educating the public about our wild heritage. He has been published in over 142 magazines […]
Break the Rules: An Interview with Landscape Photographer Varina Patel
Varina Patel is a freelance wilderness and landscape photographer. She is drawn to the challenge of finding her next photograph and mastering the skills required to capture it effectively. Her photographs have been published in various magazines, calendars and advertising materials throughout the world. She teaches workshops on landscape photography and processing along with her husband and colleague, photographer Jay Patel.
New Gear: The Fuji X-E1 Is Here
The Fuji X-Pro1 has been in our inventory for some time now, and we're pleased to add its newer sibling, the X-E1, to our rental offerings. This younger, lighter, and smaller version of the X-Pro1 ditches a few features of the critically acclaimed (and very successful) X-Pro1, while adding a few welcome ones. Read on […]
Quick Look at the Sony HVL-F60M Flash with LED Video Lights
Sony has started releasing cameras and flashes with hot shoes that abandon the previous proprietary Minolta-style hot shoe which means the Sony HVL-F60 pairs well with the NEX line, the RX line, and the A99. This is also our first flash gun that is suitable for both photographers and videographers thanks to the inclusion of […]
5 Lies Your Camera Likes to Tell
Think your camera is your best friend? Think again. Heed these 5 warnings and better equip yourself with the knowledge needed to walk away with better images! Your camera is a marvel of amazing technology but you still need to use your brain when you shoot. Even if you're in full Auto mode, don't assume your […]
Break Out of Your Routine: An Interview with Nature Photographer Jim Goldstein
Jim Goldstein is a professional photographer based out of San Francisco, California who specializes in outdoor and nature photography. Jim infuses elements of the natural world into his commercial and editorial work to express his passion about nature and the environment. A member of the American Society of Media Photographers (ASMP), Jim produces the highest quality photography for both commercial clients and fine art photography collectors.
Behind the Scenes of a Saloon Shoot with Photographer Peter Phun
Peter Phun is a freelance photographer in Riverside California. An alumni of Kent State University in photojournalism, he was among the first at his local paper to make the transition from film to digital with zero training. Phun is currently an adjunct instructor of photography at Riverside Community College. Go behind the scenes with Phun and a […]
Shoot Often to Build Confidence: An Interview with Portrait Photographer Neil Creek
Neil Creek is a photographer with ten years of experience and a passion for teaching. He has helped tens of thousands of people improve their photography with his eBooks, successful video training courses, photography workshops, and years of photography blogging. As a professional photographer specializing in portrait photography, Neil has picked up lots of ideas, techniques and problems to watch out for that are usually learned the hard way. Neil has a talent for taking difficult-to-understand concepts and making them accessible
New Gear: The Metabones Nikon to Fuji Speedbooster
Not too long ago, following the release of Fuji's most recent firmware update for its X lineup of cameras, I posted an article about extending the Fuji system with Leica lenses using the Fuji X mount to Leica M mount adapter. Indeed, this adapter, along with the Leica 90mm Summarit f/2.5 lens, is my standard […]
Sample Images: Benefits of Shooting Olympus and Four Thirds/Micro Four Thirds
Mirrorless cameras and the Micro Four Thirds (MFT) system are gaining in popularity. From Panasonic's GH3 to the Blackmagic, more and more cameras are coming out in MFT mount. Olympus originally pioneered the Four Thirds system and, along with Panasonic, announced a new Micro Four Thirds standard in 2008. This new system increased in quality while decreasing in bulk.
Establish Your Brand: An Interview with Creative Marketing Strategist Lawrence Chan
Lawrence Chan is a marketing strategist for smart creatives. He is also a photographer and traveler and is the author of several books on marketing and social media. His work has been published in Grace Ormonde Wedding Style Magazine. He wants creatives to keep honing their craft but also become better marketers. Many of his eBooks are available for free.
Featured Photographer Guy Tal
Technique, knowledge, inspiration – gain it all from seasoned photographers with years of experience and many tips to share with both burgeoning photographers and pros looking to gain a new perspective. Visit our entire collection of interviews, which are full of amazing images and valuable advice. Guy Tal is a professional artist, author, photographer, educator and public […]
Three Key Methods For Backing Up Your Photographs
Zach Egolf is an IT professional and freelance photographer in the Baltimore area. In this guest post, he explains three methods for backing up your files in preparation for the worst possible scenario. The Importance of Back…Back…Backing Up reprinted with permission by Zach Egolf Wandering into the world of photography without a backup plan is […]
BL's Orderly (and Massive) GoPro Order
Someone's going to have a lot of fun this weekend. We can't say for sure what all of these will be used for on this order but it's pretty safe to say it is bullet-time related. Enjoy the pictures, GoPro fans!
BL's Efficient GoPro Resetting Tip
This is how it's done! David Claar, one of BorrowLenses.com's inventory receivers, saves time by resetting 4 GoPro memory cards at once.
Develop Your Style: An Interview with Photojournalist Enzo Dal Verme
Enzo Dal Verme's work has been published in Vanity Fair, l'Uomo Vogue, Vogue Sport, The Times, Marie Claire, Gioia, Grazia, Flair, Amica, D di Repubblica, l'Espresso, Madame Figarò, Elle, Glamour, Class, Max, Panorama and many other magazines. He is currently based in Milan.
SnapKnot's Favorite Beach Wedding & Engagement Photos
Photographers are always seeking ways to land that one awesome wedding shot. The unique setting, timing, and location of each photo opportunity is what makes the final product so special. In order to share some brilliant inspiration, we had our friends at SnapKnot send five of their favorite beach wedding and engagement photos from their […]
Master the Basics: An Interview with Beauty Photographer Julia Kuzmenko McKim
Julia Kuzmenko McKim is an internationally published beauty, fashion, and portrait photographer, digital artist, retoucher, and educator. She is an International College of Professional Photography (Melbourne) graduate represented by Aston Models Agency in Beverly Hills, CA.
Hidden Gems – The Canon 400mm f/5.6L
Here's something that's going to make Canon shooters looking to get started in wildlife or sports photography pretty darn happy. For years, Canon has made this often-overlooked piece of glass that, as the headline for this blog entry suggests, is a true hidden gem. Presenting: The Canon 400mm f/5.6L USM lens.
Tips for Saving Your Photographs for Optimal Printing Results
Your amazing collection of digital photographs deserves to be printed with the best possible quality. When you use a photo printing service, a lot will depend on the materials and printing techniques used, of course, but there are steps you can take to help minimize the risk of disappointing results.
Focus on Composition: An Interview with Nature Photographer Ian Plant
Ian Plant is a world-renowned professional nature photographer, writer, and adventurer who has been photographing the natural world for almost twenty years. Plant is a frequent contributor and blogger for Outdoor Photographer Magazine, a Contributing Editor to Popular Photography Magazine, and a monthly columnist for Landscape Photography Magazine. He is also is the photographer/author of several dozen print and electronic-format nature photography books and his work has appeared in a number of other books, calendars, magazines, and advertising campaigns worldwide.
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Twenty-three states already have "right-to-work" laws on the books. Is yours one of them?
After another week of rainfall in the wrong places, the Oklahoma drought climbs to a severe level, says KOCO meteorologist Jonathan Conder.
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Latest Europe News
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Whitfield sprints to Kitzbuhel win
22/07/07 - In the most exciting sprint finish of the year, Simon Whitfield of Canada has just won the 2007 Kitzbuhel BG Triathlon World Cup in a time of 1 hour 42 minutes and 56 seconds. Whitfield used his... |Full Story
Brits sweep U23 European champs
21/07/07 - It was a banner day for Great Britain at the ETU European U23 triathlon Championships in Kuopio, Finland as Rosie Clarke and Ritchie Nicholls won gold. In the women's field, a group of five women that... |Full Story
Kitzbuhel World Cup this weekend
17/07/07 - Nestled at the foot of the majestic Austrian Alps, Kitzbuhel is synonymous with winter sports bliss. Home to the legendary Hahnenkamm and one of the most storied downhill ski races in the world,... |Full Story
French and Brits dominate in Lorient
15/07/07 - Julien Loy of France and Leanda Cave of Great Britain were crowned the new ITU Long Distance World Champions today in Lorient, France. After finishing in fourth and fifth place at the last two world... |Full Story
Long Distance Worlds this Sunday
11/07/07 - This weekend the world's best long distance triathletes head to northern France for the 2007 Lorient ITU Long Distance Triathlon World Championships. The City of Lorient and its Metropolitan district,... |Full Story
Zemanova And Sysoev Took The gold In Holten
07/07/07 - Zemanova and Sysoev took the gold in Holten Lenka Zemanova from Czech Republic and Igor Sysoev from Russia crowned king and queen at the 2007 Holten ITU Triathlon Premium European Cup. In the women's... |Full Story
Overwhelming Interest All Categories Triathlon Holten
06/07/07 - This Saturday the International Triathlon Holten starts with with almost no empty spots at the start of every category. The race, a Qualifying Event for the Olympics in Beijing in 2008, only has a few... |Full Story
Gomez, Fernandes win European Championships
03/07/07 - World number one triathletes Javier Gomez and Vanessa Fernandes have a lot in common. Both are the 2006 overall world cup series champions, both are young stars known for winning races in the run, and... |Full Story
Fab Four for Fernandes
30/06/07 - The irrepressible Vanessa Fernandes has done it again. The Portuguese star won her fourth consecutive European Championship in Copenhagen, Denmark today, adding another title to an already impressive... |Full Story
Gomez grabs first European title
30/06/07 - World number one Javier Gomez won his first European Championship today in Copenhagen, Denmark. He becomes the second Spaniard to win this event and the first since teammate Ivan Rana won back-to-back... |Full Story
Long Distance Champions!
24/06/07 - Frederik van Lierde from Belgium and Charlotte Kolters from Denmark grabbed the European title on the 2007 Brasschaat ETU Long Distance Triathlon European Championships. Frederik van Lierde dominated the... |Full Story
European Champs this weekend
22/06/07 - More than 140 of Europe's best triathletes from 32 countries will descend on Copenhagen, Denmark this weekend for the 2007 ETU Triathlon European Championships. All medalists from 2006 will return to... |Full Story
Top triathletes in Brasschaat
20/06/07 - On Sunday, on June 24th about 600 athletes from 21 countries will start in the 25th edition of Triathlon Vlaanderen, which is held as the 2007 ETU Long Distance Triathlon European Championships. About 50... |Full Story
Duathlon European Champions!
16/06/07 - Duathlon European Champions! The local favorite Catriona Morrison representing Great Britain and the former multiple European and World Champion from Belgium, Benny Vansteelant won the 2007 Edinburgh ETU... |Full Story
European Cup in Schliersee
16/06/07 - Jeanne Cologne of France and Pavel Simko from Slovakia won the 2007 Schliersee ITU Triathlon European Cup. Cologne finished with a time of 2 hours 18 minutes and 09 seconds in the women's field and... |Full Story


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Industry News
PR Newswire - 07/28/2016 9:00 AM ET
RCI Hospitality Holdings, Inc. will report financial results for the fiscal 2016 third quarter on Thursday, August 4, 2016, following the market close. The company will hold a related conference call that day at 4:30 PM ET. Afterward, investors can meet management at Rick's Cabaret New York, Manhattan's No. 1 gentlemen's club, at 6:00 PM ET."/>
PR Newswire - 07/28/2016 9:00 AM ET
PR Newswire - 07/28/2016 9:00 AM ET
Build-A-Bear Workshop, Inc., an interactive destination where guests can create personalized furry friends, today unveiled its newest propriety property, Mixters, a mixable, one-of-a-kind collection. The first Monster Mixters line includes two body options, four leg designs and four arm styles, which are sold together as a set. Additional Monster Mixters parts, including hands, feet and wings, a monster sound chip and costumes, are sold separately."/>
PR Newswire - 07/28/2016 9:00 AM ET
Embedded Systems Conference (ESC) Minneapolis Announces Keynote Speakers Chuck Carter, Founder of Eagre Games, and Renowned Technology Author George Leopold
PR Newswire - 07/28/2016 9:00 AM ET
Peak Resorts, Inc., a leading owner and operator of high-quality, individually branded ski resorts in the U.S., today announced that the company has promoted Christopher J. Bub to the newly created position of vice president and chief accounting officer, effective August 1, 2016. He currently serves as Peak Resorts' corporate controller.. "Chris has been a tremendous asset to our company, serving as corporate controller for the past year," said Stephen J...."/>
GlobeNewswire - 07/28/2016 9:00 AM ET
BBX Capital Corporation on behalf of its shareholders. BBX announced that it has entered into a definitive agreement to be acquired by its parent company,
BFC Financial Corporation for 5.4 shares of BFC's Class A Common Stock or $20.00 in cash for each share of BBX's Class A Common Stock held by them."/>
BBX CAPITAL BUYOUT ALERT - National Securities Law Firm Seeks Higher Price for BBX Capital Shareholders in Connection with Proposed Buyout, and Encourages Shareholders to Contact Law Firm for More Information
PR Newswire - 07/28/2016 8:58 AM ET
Cogeco Inc. announces that the Toronto Stock Exchange has accepted its notice of intention for a normal course issuer bid in respect of its Subordinate Voting Shares. Purchases pursuant to the notice will not commence prior to August 2, 2016 and will not continue beyond August 1st, 2017.. The notice will enable Cogeco to acquire up to 375,000 Subordinate Shares for cancellation representing approximately two and a half percent of the 14,989,338..."/>
Marketwire - 07/28/2016 8:55 AM ET
Tempur Sealy International Inc., Leggett& Platt Inc., and
Select Comfort Corp.."/>
Updates on Home Furnishings & Fixtures Industry Stocks -- Fortune Brands Home & Security, Tempur Sealy Intl., Leggett & Platt, and Select Comfort
PR Newswire - 07/28/2016 8:40 AM ET
Dorel Industries Inc.. OPEN TO: Analysts, investors and all interested parties DATE: Thursday, August 4, 2016 TIME: 1:00 PM Eastern Time CALL: 1-877-223-4471. THE PRESS RELEASE WILL BE PUBLISHED BEFORE MARKET OPENS THE DAY OF THE CONFERENCE CALL, THROUGH MARKETWIRED."/>
Marketwire - 07/28/2016 8:30 AM ET
Business Wire - 07/28/2016 8:30 AM ET
UQM Technologies, Inc., a developer of alternative energy technologies, today announced that Dr. Yeung Yung, Founder and Chairman of Hybrid Kinetic Group Limited, was interviewed by EnergyTech Investor, LLC regarding the recently-signed definitive stock issuance and purchase agreement with UQM Technologies. Yeung discusses strategy, near term initiatives and long term goals, the growing electric vehicle market in China and the Company' s vision for the..."/>
Hybrid Kinetic Group Limited Chairman, Dr. Yeung Yung, Discusses the Proposed Investment in UQM Technologies with EnergyTech Investor LLC
Business Wire - 07/28/2016 8:30 AM ET
IHOP® Restaurants Teams Up With No Kid Hungry On Two-Month Campaign To Help Ensure Millions Of Hungry Children Across The U.S. Can Start The Day With Breakfast
PR Newswire - 07/28/2016 8:30 AM ET
Business Wire - 07/28/2016 8:30 AM ET
GoPro Inc.,
Brunswick Corp., Travelport Worldwide Ltd, and Liberty TripAdvisor Holdings Inc.."/>
Consumer Goods Stocks Technical Commentary -- GoPro, Brunswick, Travelport Worldwide, and Liberty TripAdvisor
PR Newswire - 07/28/2016 8:20 AM ET
PR Newswire - 07/28/2016 8:17 AM ET
Meredith Corporation- the leading media and marketing company with local television brands in large, fast-growing markets and national brands serving more than 100 million American women- today reported fiscal 2016 full-year earnings of $0.75 per share, including a net charge of $2.55 per share resulting from non-cash impairment charges and other special items. Excluding these special items, earnings per share were $3.30, at the high..."/>
PR Newswire - 07/28/2016 8:00 AM ET
DSW Inc., announces the launch of DSW Kids in over 200 stores in 40 states across the country. The retail expansion will include footwear for kids of all ages from infants and toddlers through teens. An extension of its successful e-commerce shop, DSW Kids is now open in over 200 brick and mortar locations."/>
PR Newswire - 07/28/2016 8:00 AM ET
BorgWarner Inc. today reported second quarter results. GAAP net sales of $2,329 million, up 14.6% compared with second quarter 2015. Excluding the impact of foreign currencies and the Remy acquisition, net sales were up 3.5% compared with second quarter 2015. U.S. GAAP net earnings of $0.76 per diluted share. Excluding the$ per diluted share related to net non-comparable items, net earnings were $0.84 per diluted share, of which $0.04..."/>
BorgWarner Reports Second Quarter 2016 U.S. GAAP Net Earnings Of $0.76 Per Diluted Share, Or $0.84 Per Diluted Share Excluding Non-Comparable Items
PR Newswire - 07/28/2016 8:00 AM ET
Priceline Group, today unveiled a restaurant guide to this summer's hottest festivities. To help local and travelling diners find the perfect table, OpenTable Insiders..."/>
Canada Newswire - 07/28/2016 8:00 AM ET
Business Wire - 07/28/2016 8:00 AM ET
Brunswick Corporation, has signed an agreement to acquire Germany's Indoor Cycling Group, a leading provider of indoor cycling equipment. Terms of the transaction were not disclosed. The transaction is subject to customary closing conditions and regulatory review and approval by the German competition authority."/>
Marketwire - 07/28/2016 8:00 AM ET
Gentex Corporation. The system captured video from a rearward-facing camera and streamed it to a unique mirror-integrated LCD display that provided the three drivers of the No. 2 Porsche 919 Hybrid-- Romain Dumas, Neel..."/>
Marketwire - 07/28/2016 8:00 AM ET
Sequential Brands Group, Inc. today announced financial results for the second quarter and six months ended June 30, 2016.. Total revenue for the second quarter ended June 30, 2016 increased to $34.2 million, compared to $20.2..."/>
GlobeNewswire - 07/28/2016 8:00 AM ET
Home Depot Inc., Lowe's Cos."/>
Home Improvement Stores Stocks on Investors' Radar -- Home Depot, Lowe's, Lumber Liquidators, and Tile Shop
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Films about fallow deer and glassblowing.


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Titan A. E.by Steven Perry, Dal Perry
Product Details
- 9780441007363
- Publisher:
- Penguin Group (USA) Incorporated
- Publication date:
- 05/01/2000
- Pages:
- 1
- Product dimensions:
- 4.24(w) x 6.70(h) x 0.67(d)
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Titan A. E. based on 0 ratings. 4 reviews.
I simply am stuck to the book. I have seen both the movie and read all the books and i think it's awesome, fantastic and it has totally blown me away! It's one of the best show and books I have ever read in a long time. It's a great book and if you loved the show, you will love this book too! The book is full of action, adventure, excitement and is simply irrestistable.
The story of Cale's destiny to find the Titan in order to save humanity was exciting!!! I loved the humor as well as the action and suspense!!! I loved it!!! I hope Cale and Akima have many kids together!!!
I have just recently read this book and I must say that it was wonderful. the Science Fiction element combined with the added ingredient of suspense made the plot one of the best I've ever read.


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Despite last year's corporate spy scandal and the looming possibility of a U.S. slowdown, Hewlett Packard isn't struggling like its rival Dell. HP is up 52% since Barron's last plug in April 2006. It had a phenomenal FQ3, and has reiterated full year guidance. Analysts predict a 13% y/y EPS rise to $2.87, on $103.3 billion in revenues -- 32% more than 2006. HP CEO Mark Hurd is committed to a 4-6% annual revenue growth and sees no slowdown on the horizon. Aside from its successful core computer/printer business, HP has a good macro-economic vantage point because of its diverse corporate/government/consumer client base and its wide variety of products. Hurd does fear that the subprime media frenzy could baselessly discourage consumers. However, with 65% of its revenues coming from overseas, the global conglomerate is relatively immune. Growth is expected from recent enterprise software company acquisitions and HP's successful printer business. HP also plans to unveil new PCs, laptops and computer games this Wednesday. This apparently rattled Apple enough that it scheduled its own product launch that day (full story). Hurd says HP's innovation is ingrained, and its "best days are ahead of it."
Sources: Barron's
Commentary: HP Q3 Net Up 29%, Beats Street • Rising PC Component Prices Could Affect Apple, Dell, HP • Dell: Stick A Fork In It
Stocks/ETFs to watch: HPQ, AAPL, DELL


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The 3-star rating ensures a memorable stay here. Explore the surrounding area in comfort thanks to the nearby Alexanderplatz Railway Station. Landmarks near this property are Mauer Park, Alexanderplatz and Bebelplatz. Make memories at Television Tower and Neptune Fountain, which are close to here. Museums in the neighborhood include Alte Nationalgalerie and Natural History Museum.
Hotel Mani features a restaurant and a bar/lounge amongst its general areas. Among the numerous guest services provided, you'll enjoy a late check-out option, a concierge service and a baby-sitting service. This Berlin property has 63 rooms. Pets are allowed and appreciated here. Paid self service parking at limited hours makes this a convenient choice for travelers with cars.
Too darn hot outside? Hotel Mani has air conditioning. This accommodation is aims to please, offering not just a wake-up service, but also a housekeeping service and in all rooms. Guests can use wireless high-speed Internet access (complimentary). In the bathroom, you will find a complimentary toiletries set.
|From 15:00 Check-out: Until 12:00
|Wi-Fi Internet free of charge in all rooms and general areas (lobby/reception etc.)
|Paid Parking (Self-service)
Paid parking is available at the hotel. (Reservation needed)
|Pet policy:
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Genre: Reality, Documentary, Crime
Summary: Examining the tense period between arrest and conviction.
|Episode Online Video
S03, E07 (First Aired:
A man spends six years trying to learn who murdered his son; after a close friend is arrested for the crime, the victim's family worries if there is enough evidence for a conviction.
Love Thy Neighbor
S04, E09 (First Aired:
A residential Houston neighborhood is rocked by an armed robbery and a vicious murder; four years pass before justice can be served.


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StartUpHire is the place to find Director of Product Strategy and Management jobs. Review the list of Director of Product Strategy and Management career opportunities to the left. These Director of Product Strategy and Management jobs represent some of the most rewarding careers available.
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We are looking for a Director of Product to join our rapidly growing team and develop next-generation mobile social gaming experiences for our users. The position title and level can be tailored to your experience and skill sets. Â ResponsibilitiesManage multiple project teamsSan Francisco, CA Save This Job
NEW YORK, NYPRODUCT FULL-TIME Hi! Thanks for checking us out. It?s a pleasure to meet you... Offerpop's Visual UGC Marketing SaaS platform empowers brands to encourage and leverage user generated content at every stage of the buyer journey, improving marketing performance.5/31/2016 New York, NY Save This Job
NEW YORKPRODUCTFULL-TIME APPLY FOR THIS JOB About Foursquare Since our inception in 2009, Foursquare has been a leading force in changing how location information enriches our real-world and digital lives. As a location intelligence company, Foursquare is comprised of two7/4/2016 New York, NY Save This Job
Reporting to the CTO, the Director of Product Management has full responsibility for the technology product portfolio and is responsible for defining the product strategy that will contribute to iModules? commercial success and defining the metrics by which that success should be5/31/2016 Overland Park, KS Save This Job
Product Management Denver, CO, United States Product Operations management is the administration of business practices to create the highest level of efficiency possible within an organization. Unlike Program/Project Management, which supports the business through executing6/18/2016 Denver, CO Save This Job
Job Description Director of Product Management - (02152) Description Summary: Gemalto?s Software Monetization business unit is looking to add to our Product Management team a strategic market-facing PM to take ownership for promoting and driving our strategy for the Sentinel5/29/2016 Boston, MA Save This Job
Job ID 2016-3345 Job Location US-TX-Austin Category Product Management Type Full-Time More information about this job About Bazaarvoice Bazaarvoice is a network that connects brands and retailers to the authentic voices of people where they shop. Each month, more than 5006/26/2016 Austin, TX Save This Job
Emeryville, CA Product Management At TubeMogul, our people are our greatest asset and we are all driven by a core set of values. We are builders, dreamers, thinkers, designers, and doers. We work hard, we work together and we work towards a common goal. Of course, we also have6/7/2016 Emeryville, CA Save This Job
At Pandora, we're a unique collection of engineers, musicians, designers, marketers, and world-class sellers with a common goal: to enrich lives by delivering effortless personalized music enjoyment and discovery. Peopleâthe listeners, the artists, and our employeesâare7/21/2016 Oakland, CA Save This Job
The Director of Strategic Accounts, Healthcare will lead the development of client objectives of clients in the healthcare vertical. Director focuses on leading and developing positive client relationships and overall client satisfaction. Responsibl7/8/2016 Chicago, IL Save This Job
Product Marketing & Management Austin, TX, United States Apply Send Jobvite SailPoint is the Worldwide Leader for Enterprise-Class IAM We minimize risk and maximize business growth by managing access to data and resources across your enterprise. We do it effectively and7/19/2016 Austin, TX Save This Job
Full TimeSan Antonio or Austin, TXPosted 6 days ago ClearDATA WebsitecleardatacloudClearDATA Secure ? Healthcare ? Cloud Role: Director of Sales Reports to: CRO Department: Sales Location: San Antonio or Austin Job Type: Full Time, Exempt Last Updated: 07 July7/19/2016 San Antonio, TX Save This Job
Job Function:Client Services Department:Client Services Location:Boston, MA Date Posted:6/20/2016 Share Email this job Lux Research advises corporations on strategy in emerging technologies, with practices in areas including Internet of Things, green buildings, electric vehicles,6/29/2016 Boston, MA Save This Job
Department: Sales Location: Boston, MA The Senior Director Sales Operations manages support functions essential to sales force productivity. These include planning, reporting, quota setting and management, sales process optimization, sales job design, sales program6/26/2016 Boston, MA Save This Job
Glooko seeks a driven and enthusiastic team player to join our team as Director of Health Plan Sales, responsible driving sales of Glooko?s diabetes platform to health plans (e.g., commercial payers). He/she will have experience selling mobile health, chronic disease6/13/2016 Palo Alto, CA Save This Job
Department: Marketing Location: Washington, DC Director of Field Marketing, North America and Public Sector The Director of Field Marketing, North America and Public Sector will join a highly successful B2B marketing team at Acquia during a time of rapid company growth. This6/26/2016 Washington, DC Save This Job
Business Development Mountain View, CA Coursera is scaling a global platform to provide universal access to the world?s best education, and we?re driven by the passion and mission to let people learn without limits. As our Global Director of Enterprise Sales, you will play a6/28/2016 Mountain View, CA Save This Job
Product Management Foster City, CA Full-time Apply Now! Careers / Foster City, CA / Director of User Experience Zuora is looking for a Director of User Experience (UX), a leader with the vision, skills, and passion to bring the promise of modern application usability to the7/20/2016 Foster City, CA Save This Job
NYC One of New York?s fastest-growing and most innovative tech companies is seeking a passionate leader to develop and implement a comprehensive communications strategy. This is a highly visible position in a dynamic, fast-paced, and creative environment. Candidates should have6/14/2016 New York, NY Save This Job
Technology San Luis Obispo, CA APPLY NOW Send Jobvite POSITION SUMMARY: The Director of Architecture will lead a team of Architects across Product Development and Engineering/Infrastructure. They will provide technical design and direction to product development teams to ensure6/20/2016 San Luis Obispo, CA Save This Job


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I'm trying to add a good HTML5 Video Player to my website. I have tried several that wont link to my videos on my server. I need one that will work with no ads or watermarks, I'm willing to pay. I have about 30 videos on the server at about 10 - 50mb per video so I cant upload to WordPress.
Thank you.


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There's No Room for You in Hannah Tennant-Moore's 'Wreck and Order'
By Subashini Navaratnam
Our self-indulgent protagonist tries to find herself in the rural poverty of the third world but the people, the customs, the food, it all starts to grate on her first world sensibilities. 22 Jul 2016 // 8:30 AMRead more
12 Apr 2006 // 12:00 AM
This is Kale's most diverse and daring album yet; he moves into some genres that even he hasn't tried yet, and it really loosens up his urban/Indian/worldbeat groove.READ more
12 Apr 2006 // 12:00 AM
The Vines are polished so shiny by Capitol on their new record you can see yourself in the reflective, glossy black of the CD booklet.READ more
12 Apr 2006 // 12:00 AM
Third official solo album finds the Pink Floyd guitarist/vocalist mostly free of the weight of that band's legacy. Hence the album is content and effortless, maybe too much so.READ more
12 Apr 2006 // 12:00 AM
A crystalline ECM session featuring a pop drummer, Tomasz Stanko, and Jan Garbarek -- but really too gentle for its own good.READ more
12 Apr 2006 // 12:00 AM
Garden Ruin sounds a bit like Calexico followed their muse out into the uncharted desert as far as they could, and then returned to town to shower, shave, reflect, and stock up on suppliesREAD more
12 Apr 2006 // 12:00 AM
Running the gamut from IDM to alt-hip-hop with strong roots in both the progressive soul and free jazz sounds, Hefty arrives at an approachable middle ground between wonky noise and shiny pop -- a rather pleasant juxtaposition.READ more
12 Apr 2006 // 12:00 AM
Aussie musician seems to take Crowded House's debut album to heart with consistently well-crafted, harmony-heavy pop jewels.READ more
12 Apr 2006 // 12:00 AM
Thought the material is not quite up to the hype of the liner notes, there's certainly some accomplished playing here, but oh, for some intensity!READ more
11 Apr 2006 // 1:00 AM
It may have been Oscar night in Hollywood, but to these emo-fied teens, the night belonged to Nada Surf and their companions.READ more
11 Apr 2006 // 1:00 AM
Patton Oswalt's audience exemplifies the politically opinionated but ultimately unmotivated young Left, who turned out to the polls in 2004 with the same low figures as they did in 2000.READ more
Blesst Chest "Blesst Chest Theme Song" (audio) (premiere) // Music
The Chairman Dances "Dorothy Day and Peter Maurin" (audio) (premiere) // Music
National Park Radio 'The Great Divide' (album stream) (premiere) // Music
Kendra Erika "The Truth Never Lies" (video) (premiere) // Music
Culture Belongs to the Alien in 'Spirits of Xanadu'
// Moving Pixels
"The symbols that the artifact in Spirits of Xanadu uses are esoteric -- at least for the average Western gamer. It is Chinese culture reflected back at us through the lens of alien understanding.READ the article


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Since a high pressure system moved in, Lake Louise hadn't seen new snow in a week. But the base accumulated in its record-breaking snow year had everything skiable a few days ago. Conditions ran from packed powder to a bit of hard pack, espcially on high west-facing runs. Groomers were carvy-fast, while off-groomed required concentration--especially to hop a few bare rocks.
Two things make Lake Louise worth skiing in almost any type of snow--the unbeatable views of jagged peaks dripping with glaciers and the terrain. Runs trip downslope using natural rollers, drops, and fall lines. And with the vertical, you just keep skiing, and skiing, and skiing...
Under high clouds, we headed for the back side to test the bowls, but flat light made it a little difficult to discern bumps. We did, however, find a bit of softer snow in front side glades and relished the wild Rockies views across to Mt. Temple and Mt. Victoria. For lunch, we hit the Great Bear in Lodge of Ten Peaks. The three bars--soup/salad, pasta, and meat/potatoes--converted us to pigs; we tried it all. And then the creme brulee dessert, too.
In our post-lunch sluggishness, a few sucker holes gave way to full sun, luring enough skiers back out that there was actually a one-minute wait in the lift line. Atop the gondola, a wedding dress bedecked bride and groom posed for dramatically-backdropped photos. But before they finished, a blizzard descended blowing winds across the summit whipping the veil sideways like a flag.
We may not have caught Louise's earlier legendary powder, but the terrain still was fun to ski. And with 4,200 acres, we didn't even dent what was there.
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North hosts 2-A regional
Published: Saturday, May 3, 2008 at 4:30 a.m.
Last Modified: Saturday, May 3, 2008 at 2:42 a.m.
Track and field athetes will descend, en mass again, on North Henderson today looking to punch a ticket to Greensboro.
After hosting the WHKP Relays and last week's Western Athletic Conference championships, North is hosting the 2-A Western Regional meet beginning at 11 a.m. The top four finishers in each event will compete in the state 2-A meet on May 9 at North Carolina A&T University.
Both of West Henderson's teams captured WAC championships and both enter the regional looking to defend titles. The Lady Falcons edged North last season while the Falcons tied with the Brevard Blue Devils.
Shelby's boys, winners of the WHKP Relays earlier in the season, are expected to be strong as well.
Reader comments posted to this article may be published in our print edition. All rights reserved. This copyrighted material may not be re-published without permission. Links are encouraged.
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You have searched for: Maulana Ashraf Usmani
- Ashraf in Indian body building team
Body builder Mohammad Ashraf from the city has been selected to represent Indian body building team in Mr Asia championship and Mr World championship.
- Thousands bid farewell to Maulana Athar
Amid thousands of followers and mourners from all communities of Lucknow, well known Shia cleric Maulana Mirza Mohammad Athar who breathed his last in Delhi on Friday, was buried in his hometown Lucknow on Saturday.
- France attacker some mad dog, says Shia cleric Maulana Sadiq
LUCKNOW: Revered Shia cleric Maulana Kalbe Sadiq condemned the terrorist attack in France and warned the community to stay away from anything which is against humanity. Addressing at the closing ceremony of a conference organised by Eras Medical College and Hospital here on Saturday, Maulana Sadiq compared the attacker in France to a mad dog which pushed innocents into the deep sleep of death. "The attacker in France was some mad dog," he said. Citing the old proverb 'as you sow, so shall you reap', the maulana said, "If you resort to violence, you will also be eliminated." Maulana Sadiq stressed need to promote education within the community. "Education and education alone can change the fate of Muslims across the world," he told the students adding, "the day you achieve excellence in your subject, you will not only get a job but also a fleet of servants (jis din excellence hasil kar loge, us din naukri hi nahi, naukar bhi mil jayega)." He cited the example of former President Abdul Kalam to prove his point. The Maulana also gave an option to Muslims who hesitate in raising 'Bharat Mata Ki Jai' hails. "Those hesitating in saying Bharat Mata Ki Jai, may call 'Bharat Ammi Ki Jai," Kalbe Sadiq said. Governor Ram Naik, who was the guest for the function, appreciated Maulana Sadiq, deterred medical students from proceeding on work boycotts and strikes while addressing the closing ceremony of the conference. Naik told students that their duty was above anything else and they should never forget their commitment to humanity. "Service is the first duty of a doctor and it is above everything else. None of you should forget this," he said. He also stated that a number of doctors do not want to go to the villages but they must realise that more than 70% of india lived in the villages and those residents needed quality medical services as much as the people living in city did. "The ample presence of doctors in rural areas is a must for development of a healthy society," he said.
- Muslims facing worst ever challenge by ISIS, says Maulana Mahmood Madani
Declaring that terrorism will not be tolerated, Jamiat Ulama-i-Hind (JUH) general secretary Maulana Mahmood Madani on Thursday said that the ISIS was inflicting massive harm upon Islam and the Muslim ummah.
- Will drag Pakistan to UN over Taliban: Ashraf Ghani
After courting Pakistan for more than a year, President Ashraf Ghani of Afghanistan changed course on Monday and warned that he would lodge a complaint with the United Nations Security Council if Pakistan refuses to take military action against Taliban commanders operating from its soil to wage an increasingly deadly insurgency across Afghanistan.
- Will drag Pakistan to UN over Taliban: Ashraf Ghani
Afghan President Ashraf Ghani on Monday and warned that he would lodge a complaint with the United Nations Security Council if Pakistan refuses to take military action against Taliban commanders operating from its soil to wage an increasingly deadly insurgency across Afghanistan.
- Barelvi cleric Maulana Tauqeer Raza to contest 50 seats in UP polls
BAREILLY: Maulana Tauqeer Raza Khan, the influential Barelvi cleric, told TOI on Tuesday that his party, Ittehad-e-Millat Council (IMC), will fight state assembly elections from nearly 50 seats falling under Bareilly and Moradabad divisions. The cleric said that the names of candidates for the first phase will be declared by July end. The cleric said, "As we lack proper resources unlike other political parties, we have decided to contest Uttar Pradesh assembly elections from nearly 50 seats, falling under Bareilly and Moradabad divisions." "I will organize a meeting in the last week of July in which I will declare the names of candidates for the first phase. Besides, we will announce few big names in that meeting who will formally join our party ahead of the elections," said Khan, who is the national president of IMC. Khan is the grandson of Imam Ahmed Raza, popularly known as Aala Hazrat, who was the founder of Barelvi movement. The cleric enjoys vote bank of Muslims in western UP. However, the cleric said that he has no plans in forming an alliance with political parties with whom he alienated in the past, including Samajwadi Party, Bahujan Samaj Party and Congress. The cleric has been known to shift his allegiance quite often. In the Lok Sabha polls of 2009, he had supported the Congress, while in the UP assembly elections of 2012, he had backed the SP. In Lok Sabha elections of 2014, he gave his support to BSP. However, it was support of cleric, Congress candidate Praveen Singh Aron was able to defeat six-time BJP MP Santosh Gangwar in the Lok Sabha elections of 2009. However, when IMC gave tickets to its candidates for the last UP assembly elections in 2012, Congress failed to open its account. "In UP, people want to get rid of SP and BSP and want a third front. If mahagathbandhan on the lines of Bihar elections is formed here, I will lend my support to it but will not enter into alliance with SP, BSP and Congress," he said. "I am in touch with Nitish Kumar for forming mahagathbandhan for the upcoming polls here by bringing regional parties together. Mahagathbandhan is necessary for the development of state," Khan added. Another reason that has made cleric to take efforts to form alliance with JD (U) is imposing a ban on alcohol in UP. "The government of Nitish Kumar in Bihar has imposed a ban on alcohol and I have been running a similar campaign in UP demanding ban on liquor for the past few years. I had approached SP and BSP government for imposing ban on liquor but they did not consider it. If liquor can be banned in Bihar, the same can be done in UP without affecting the revenue of the state," he said.
- Bandh observed in Sahaspur; maulanas seek CBI probe
To protest against the 'slow' pace of investigation in cracking the murder case of NIA officer Tanzil Ahmed, a bandh was observed in Sahaspur on Friday. All markets, schools, colleges and hospitals remained closed in the town.
- Can Maulana Diesel fuel Sharif-Zardari pact?
When a rightist coalition bagged 11% votes in 2002, it was the first time conservatives had managed double-digit vote share in Pakistan's electoral history.
- IS being wiped out from Afghanistan: Ashraf Ghani
Afghan President Ashraf Ghani said the Islamic State group has been defeated in eastern Afghanistan, where it had taken over some remote districts. Afghanistan will be a "graveyard" for IS, he said.
- Ahead of polls, Sofia Ashraf comes up with video on importance of voting and NOTA
The 29-year-old Tamil rapper and musician Suren Vikash, 30, have made a three-minute video on the importance of voting and the NOTA - none of the above - option. Their song 'En Vote Unakillai' (My vote is not for you) is going viral on college campuses.
- Ahead of polls, Sofia Ashraf comes up with video on importance of voting and NOTA
The 29-year-old Tamil rapper and musician Suren Vikash, 30, have made a three-minute video on the importance of voting and the NOTA - none of the above - option. Their song 'En Vote Unakillai' (My vote is not for you) is going viral on college campuses.
- ATS nabs 'maulana' for spreading jihad
Nagpur: A young religious preacher (maulana) Hafiz Mujibar Rehman alias Salim Malik, has been arrested from Mendhiya masjid of Pusad in Yavatmal district on Sunday in a joint operation by State Anti-terrorist squad (ATS) of Nanded and Akola. He was alleged involved in indoctrinating youths to join the 'jihad' or holy war through social media and sermons. He has been remanded to custody by a special court in Nagpur on Monday till November 12. Sources from the intelligence wing said Maulana Rehman's name had cropped up in the interrogation of Abdul Malik Abdul Razzaq, who had attacked three cops from State Reserve Police Force (SRPF) with a sharp weapon outside Mendhiya mosque on Eid-ul-Azha on September 25. He had also raised slogans against the government for banning beef. Superintendent of police, ATS, rest of Maharashtra, Sunil Kolhe said such instigators are misleading youngsters to join antigovernment activities, jeopardizing their lives and any career. "Security agencies are working round the clock to track down such instigators and brainwashed youths bent on creating havoc in society," he said. ATS and other intelligence wings are now trying to find links between Malik and Shoaeb Khan, alias Pusad Shoaeb, and Shah Muddassir, who were arrested by Hyderabad police for their role in provoking youngsters to join jihadi culture as a holy practice in October last year. Khan and Muddassir, both from Maharashtra, had gone to meet a financier in Hyderabad, who was supposed to help them to cross over to Afghanistan to train under the al-Qaida. Muddassir, who owned grocery shop at Umarkhed, was former member of Shaheen Force, which is the children wing of banned outfit Students Islamic Movement of India (SIMI). After SIMI was banned, Mudassir joined a front organization. Shoaeb is learnt to be close to Mansoor Ali Peerbhoy, who was linked to Pune module of Indian Mujahideen (IM). Mudassir and Shoaeb were in close touch with a Pakistan-based group on social media and used to chat about jihad and triggering blasts in Maharashtra. Shoaeb too was produced, along with Rehman, before the court. The court has extended Khan's custody till November 5. Malik, a BSc student who is also enrolled in the computer stream of ITI, is learnt to have revealed that Rehman and Khan exposed him to the 'jihadi' videos and other instigating materials, leading him to embrace hardline view for religious purposes. Sources in ATS said that a lot of literature was found in the possession of Rehman and Malik along with some electronic evidence. Advocate Mir Nagman Ali, who appeared from Rehman, told the court that the religious preacher was being targeted for being a member of a particular minority community. "The attack by Malik on police personnel was merely a personal matter, but given a serious hue," he said.
- 500 maulanas in Assam extend support to BJP
About 500 maulanas (Islamic clerics) in Assam on Saturday have publicly expressed their support to BJP and promised to work for the saffron party in the run-up to assembly election on April.
- 500 Maulanas in Assam extend support to BJP
About 500 maulanas (Islamic clerics) in Assam on Saturday have publicly expressed their support to BJP and promised to work for the saffron party in the run-up to assembly election on April.


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This course is designed for developers who want to create custom YARN applications for Apache Hadoop. It will include:the YARN architecture, YARN development steps, writing aYARN client and ApplicationMaster, and launching Containers.The course uses Eclipse and Gradle connected remotely to a 7-node HDP cluster running in a virtual machine.
2 days
Java software engineers who need to develop YARN applications on Hadoop by writing YARN clients andApplicationMasters.
Students should be experienced Java developers who have attended HDP Developer: Java OR HDP Developer: Pig and HiveOR are experienced with Hadoop and MapReduce development.
Instructor-led lecture/discussion, with approximately 50% of the course being devoted to hands-on labs.
At the completion of the course students will be able to:
Hortonworks offers a comprehensive certification program that identifies you as an expert in Apache Hadoop. Visit Certification for more information.
Hortonworks University
Hortonworks University is your expert source for Apache Hadooptraining and certification. Public and private on-site courses areavailable for developers, administrators, data analysts and otherIT professionals involved in implementing big data solutions.Classes combine presentation material with industry-leading hands-on labs that fully prepare students for real-world Hadoop scenarios.


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Dawn Stewart
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Please visit my new website, Peninsula Genealogy, if you have ties to the Hampton Roads area. I'm documenting obituaries, marriage, birth and death records there, and linking all obits back to findagrave so people can see additional info on their loved ones.
I have been doing my genealogy for over 13 years now. I started visiting the local cemeteries in my area looking for my relatives. By doing that, I realized how much I like to go there and how I enjoy helping others find their relatives. I am willing to do cemetery lookups in my area (Hampton, VA), so email me if need some help. Will also look up obituaries at our local library. I just love to do research!
I am currently transcribing and posting pics of cemeteries around Hampton VA. I have completed most of the smaller cemeteries (less than 1000 graves) and a few larger ones. I'm hoping by doing all this, it will make it easier for many people to find their loved ones.
My maternal grandfathers family was from MA (Mackay, Martin, McGlew, Traill)
My maternal grandmothers family was from VA, NC and PA (Gildner, Broadstreet, May, Bridgland, Smith, Arnold).
My paternal grandfathers family was from WY, NE, WI and SD (Allman, Caddy, Simons, Carberry, Rogers, Stuart)
My paternal grandmothers family was from CA, Washington, DC and OH. (Ehrmantraut, White, Gerhold, Dolph).
My husbands family is from NC and SC. (Orr, Malone, Boone, Clement, Mckay, Stewart, Vaughan Garrett, Hatchell).
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SA Russell
#55889892 William B. Russell
Hi Dawn: William B. Russell is my great grandfather and I would like to request a transfer of this memorial. Thank you for setting up this memorial and taking care of it. Sherry
Added by
SA Russell
on Jul 20, 2016 7:07 PM
irene sylvester
memorial 16602959
Dawn can I assume there is not head stone at the grave?
Added by
irene sylvester
on Jul 07, 2016 1:00 PM
sissy taylor
I went to Lawhorne Cemetery and it is 44168419 but like you when I put the number in to Find A Grave it comes up some one else. My request has already been completed.
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sissy taylor
on Jun 21, 2016 10:57 AM
Warren McNamara
Hi Dawn
I was wondering if the Warren McNamara grave you have is the same Warren McNamara that was a lawyer to Robert McKinney who was featured on Unsolved Mysteries? I'm trying to update the UM Website so I was just wondering if that is the correct Warren MCNamara then do You have Robert McKinney's grave? Much Appreciated
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on Apr 28, 2016 4:34 PM
Doug Williams
Lancaster Cem Craven Co NC
Dawn, curious as to exactly where John Hartage found and photographed the Lancaster Cemetery in Vanceboro Craven Co NC that you have a couple memorials in. I recently found a Lancaster Cemetery in Vanceboro at the corner of Maul Swamp Road and SR43 with the other 3 burials that are listed with your 2 but your 2 are not among the ones that I found. Must be 2 Lancaster Cemeteries in Vanceboro. In the interest of accuracy I would like to create another one, add my new photos and put all 5 where they belong. Hope you will be able to help me out in this. Doug
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Doug Williams
on Feb 29, 2016 1:14 PM
Roberts Girl
Alice Smith #45704389
I'm hoping you can help me with information on Alice Smith. I put in a photo request for her grave marker, but was told it could not be found. Do you remember if this memorial was added from a visit to the cemetery or from cemetery transcripts? I'd love to be able to discover the exact location of her grave.
I believe this may be Alice, daughter of Ezra M. and Martha Johnson Smith. According to family, our Alice was born Feb. 3, 1861 in Jasper County, Iowa, and died Sept. 26, 1863 most likely also in Jasper County, as that is where census records place her parents. In the 1860 census, they were living with Daniel, Elizabeth and Steven Johnson assumed to be family to Martha. I'd love to confirm this is our Alice Smith. I'd also love to uncover more information on Ezra and Martha. Any help you can offer would be greatly appreciated!
Added by
Roberts Girl
on Oct 04, 2015 7:11 PM
Gale Harvell
Hello Dawn, Found some dates for Jane Elizabeth Owen, through family records. 80 years old Born- Feb 13,1835 Born in Hampton, Virginia. Her death date is Aug.6, 1915. Father was Charles Davis Cake and was from Matthews County,Virginia. Her mother was Rebecca Brown Cake. There was a son Walter Earnest Owen. when you get chance could you add to her memorial? Buried in St Johns, Hampton. Thanks Gale H.
Added by
Gale Harvell
on Sep 19, 2015 10:09 AM
Anne S.
Thomas Johnston & Mary Baer
Daughter, Dorothy C Johnson married Donald Guy Shifler. Donald Shifler was born in Maryland on
Sept 7 1924, however he died Apr 21, 1994 in
Newport News, Virginia. I have his whole famiiy in
Maryland, but cannot locate where he is buried.
Can yu help me?
Anne S. from Pt. Pleasant, NJ
Added by
Anne S.
on Aug 25, 2015 10:34 AM
Ellen Bishop
I put Louis Simons in BHN
because his wife is there and I couldn';t imagine that he would not be buried with her
Added by
Ellen Bishop
on Aug 21, 2015 8:00 PM
D Rausch
Ore's at Mountain view cemetery, WY
I see that you are working on Orr's. Are you related to the Ore's at Mountain View cemetery, Riverton, Fremont, WY?
I looked at your Orr's and I couldn't see a connection between the two. The Ore's above are originally from Missouri, went to Neb and onto WY.
If you do not have a connection would it be possible to transfer them to me. They are not directly related but are in my family and it would be easier to add info if I didn't have to go through someone.
Thanks for any help.
DRausch Find A Grave #46811795
Diane Rausch
Added by
D Rausch
on Jun 10, 2015 11:50 AM
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Read an Excerpt
The VSEPR Model of Molecular Geometry
By Ronald J. Gillespie, István Hargittai
Dover Publications, Inc.Copyright © 2012 Ronald J. Gillespie and István Hargittai
All rights reserved.
Molecular Geometry
This book is concerned with the geometry of molecules and with the interpretation and prediction of molecular geometry using the valence-shell electron-pair repulsion (VSEPR) model. In this chapter we review some basic ideas and concepts concerning the geometry of molecules. In the following chapter we briefly discuss the more important methods by means of which the geometry of a molecule may be determined. Then in the succeeding chapters we give a detailed discussion of the VSEPR model and use it to discuss the geometry of a wide variety of molecules. In the last chapter we consider the theoretical basis of the model and compare it with other models for rationalizing and predicting molecular geometry.
A molecule consists of a discrete group of two or more atoms held together in a definite geometrical arrangement. Whenever two or more atoms are held together sufficiently strongly to form a molecule, we say that there are chemical bonds between each atom and its close neighbors. The geometry of a molecule has a profound influence on its properties, and so ever since van't Hoff and le Bel proposed in 1874 that the bonds formed by a carbon atom have a tetrahedral arrangement the geometry of molecules has been of great interest. Chemists have for a long time represented a bond by a single line. We draw structures for molecules that indicate how it is believed that the atoms are connected together by bonds. We will use the term structure in this sense to indicate simply the connectivity of the atoms, while by geometry we mean the actual three-dimensional arrangement of the atoms.
Each atom in a molecule consists of a positively charged nucleus surrounded by a number of negatively charged electrons. Thus there are two important and closely related questions that we can ask about a molecule:
1. What are the relative positions of the nuclei in space? In other words, what is the geometry of the molecule? The geometry of a molecule is usually described in terms of the distances between the atomic nuclei that are bonded together (that is, the bond lengths), the angles between the bonds formed by each atom (that is, the bond angles), and the angles between the bonds on adjacent atoms (that is, the torsional angles).
2. How are the electrons arranged? Because electrons are in constant motion and because their paths cannot be precisely defined, the arrangement of the electrons in a molecule is described in terms of an electron density distribution. The electrons in an atom are arranged in successive shells surrounding the nucleus. The nucleus and the inner shells of electrons usually remain unchanged in molecule formation, and it is only the outer shell, known as the valence shell, that is modified. Thus the atomic nucleus and the inner electron shells are considered to constitute the core of the atom so that a molecule is thought of as consisting of two or more positively charged atomic cores held together by the electrostatic attraction of a negatively charged electron density distribution derived from the valence-shell electrons of the constituent atoms. Thus the relationship between the arrangement of the electrons, that is, the electron density distribution, and the bonds that are imagined to hold atoms together in a molecule is of fundamental importance to the understanding of molecular geometry.
The arrangement of the nuclei in a molecule may be determined by several different experimental methods, the most important of which is X-ray diffraction by crystalline solids, as will be described in Chapter 2. The geometry of a molecule may also be found, at least in principle, by determining by quantum mechanical calculations the arrangement of the nuclei that has the minimum energy, as will be discussed in Chapters 2 and 7.
The electron density distribution of a molecule can be determined by the same quantum mechanical calculations as are used to find the energy and geometry of a molecule. But in practice it is only possible to carry out these calculations to a reasonable accuracy for small molecules consisting of light atoms.
The electron density distribution can also, at least in principle, be determined by X-ray diffraction studies on crystalline solids. X-rays are diffracted by the periodically varying electron density distribution in a crystal; but most of the electron density is concentrated in the atomic cores, and so, although it is relatively simple to determine the positions of the atomic cores and therefore of the nuclei, it is often very difficult to detect the small changes in the electron density distribution that occur on molecule formation.
The arrangement of the electrons in an atom is usually described in terms of its electron configuration as deduced from atomic spectroscopy, ionization energies, and the periodic table, and also from quantum mechanics (Chapter 7). The electron configurations of the elements are given in Table 1.1.
One of the earliest models of the arrangement of the electrons in molecules is that published by G. N. Lewis in 1916, although it had been used by him in teaching for a number of years before. Chemists have found this model so convenient that it is still today the most widely used simple model. Lewis represented the core of an atom by its symbol and the valence-shell electrons by the appropriate number of dots. Lewis dot diagrams for the main-group elements of the first six periods are given in Figure 1.1.
Lewis proposed that in compound formation atoms achieve noble gas electron configurations either by electron loss or gain or by the sharing of one or more electron pairs. Because each of the noble gases, except helium, has eight electrons in its outer or valence shell, Lewis's proposal is often called the octet rule. Electrons are readily removed from the valence shell of an atom of a metal to give an ion with a noble gas electron configuration; for example,
Na(2s22s22p63s1) -> Na+(1s22s22p6) + e-
Nonmetals tend to gain electrons to give negative ions that have a noble gas configuration; for example,
O(1s22s22p4) + 2e- -> O2-(1s22s22p6)
The positive and negative ions thus formed are attracted to each other by electrostatic forces to form ionic compounds, and such compounds are said to have ionic bonds.
Lewis also proposed that atoms may be held together by sharing one or more electron pairs. A shared electron pair constitutes a single covalent bond between the atoms, as in the Cl2 molecule:
Similar Lewis diagrams can be written for many molecules in which each of the atoms has an octet of electrons in its valence shell. For example, the Lewis diagrams for carbon tetrafluoride, nitrogen trifluoride, oxygen difluoride, and fluorine are
Lewis Structures
In a completed valence shell all the electrons may be considered to be arranged in pairs, either bonding pairs or nonbonding pairs. Nonbonding pairs are also frequently called lone pairs or unshared pairs. Lewis diagrams are usually simplified by representing each bonding pair of electrons, that is, each covalent bond, by a single line, as follows:
Hydrogen is an exception to the octet rule in that the corresponding noble gas, helium, has only two electrons in its valence shell. Thus in the Lewis diagrams of compounds of hydrogen there are only two electrons in the valence shell of each hydrogen, as, for example, in methane, ammonia, water, and hydrogen fluoride:
In some molecules two or three electron pairs may be shared between two atoms, thereby forming double and triple bonds. Double bonds are found, for example, in ethene and carbon dioxide:
Triple bonds are found for example in ethyne and hydrogen cyanide:
Although in the vast majority of covalent compounds atoms are held together by one or more shared pairs of electrons, there are many exceptions to the octet rule. For example, the central atoms in BeCl2(g) and in BCl3 have only two and three electron pairs, respectively, in their valence shells:
There are also many molecules in which a central nonmetal atom from period 3 and beyond in the periodic table has five, six, or even more electron pairs in its valence shell. Examples include sulfur tetrafluoride, SF4, chlorine trifluoride, ClF3, and sulfur hexafluoride, SF6:
The concept of the covalent bond as consisting of a pair of shared electrons led to a great step forward in the understanding of chemical bonding and molecular structure, but Lewis could not explain why electrons are arranged in pairs nor why two shared electrons could bind two nuclei together. A full understanding of the covalent bond had to await the development of quantum mechanics, as we will discuss in Chapters 3 and 7. We will see that in the formation of a covalent bond there is a small increase in the electron density in the region between the atomic cores, and it is the electrostatic attraction between this increased electron density and the positively charged atomic cores that holds the two atomic cores together.
No sharp distinction can be drawn between covalent and ionic bonds, and in many molecules the bonds have an intermediate character. In fact, a pure covalent bond is only possible between atoms of the same kind, that is, atoms of the same element. Atoms of different elements attract the bonding electron pair to different extents, so there is some transfer of electron density from one atom to the other; that is, the bond is not purely covalent but has some ionic character. Similarly, there can be no pure ionic bond, because whenever two oppositely charged ions are attracted together there is inevitably at least a small amount of sharing of electron density between them. Molecules containing predominately ionic bonds are not common because normally, when oppositely charged ions are attracted together, they form a crystalline solid that consists of a regular periodic arrangement of ions in which no discrete molecules can be recognized (Figure 1.2). The whole crystal may be regarded as one giant molecule or as a polymer of essentially infinite size. Small molecules in which the bonding is predominately ionic are usually found only in the gas phase when an ionic solid is vaporized at high temperature.
The ability of an atom to attract the electrons of a covalent bond is called its electronegativity. Values of the electronegativities of the elements have been obtained by different authors by several different methods. Table 1.2 gives the values determined by A. L. Allred and E. G. Rochow. These can only be regarded as approximate average values because the electronegativity of an atom depends to some extent on the atoms that are attached to it and its oxidation state.
We also recognize a third type of bond, the metallic bond, in which a large number of atomic cores are held together by a delocalized electron cloud, and no discrete bonds between individual pairs of atoms and no molecules can be distinguished. Again, no sharp distinction can be drawn between metallic bonds and covalent and ionic bonds, and in many compounds the bonds have an intermediate character. However, since metallic bonding is a property of a large assembly of atoms, it is not found in the relatively small molecules with which we are primarily concerned in this book.
Both ionic bonding and metallic bonding are nondirectional in nature, and so the structures of ionic and metallic substances are determined primarily by the ways in which ions and atoms of different sizes may be packed together. In contrast, covalent bonds are highly directional in character, and it is the tendency for atoms to form bonds in specific directions that is the most important factor in determining the structures of covalent molecules and crystals.
The discussion of molecular geometry in this book is based on the valence-shell electron-pair repulsion (VSEPR) model, which in turn is based on Lewis's description of the electron arrangement in a molecule. The basic assumption of the VSEPR model is that the electron pairs in the valence shell of an atom, both bonding and nonbonding, adopt that arrangement that keeps them as far apart as possible; that is, they behave as if they repel each other. From the arrangement of the electron pairs in the valence shell of an atom the geometry of the covalent bonds that it forms can be easily predicted. In this book we are therefore mainly concerned with covalent molecules.
Some simple molecules are linear and some others are planar, but most molecules are three dimensional. It is particuarly convenient to describe the structures of many three-dimensional molecules in terms of an appropriate polyhedron. So we now describe some of the more important polyhedra.
A polyhedron encloses a portion of three-dimensional space with four or more polygons. A polygon encloses a portion of a plane with three or more straight lines. A polygon is convex if each interior angle is less than 180°, and it is regular if it has equal interior angles and equal sides. In principle, there is an infinite number of regular polygons with the circle as a limiting case (Figure 1.3). A polyhedron is convex if every dihedral angle is less than 180°. A dihedral angle is formed by two polygons joined along a common edge. A convex polyhedron is regular if its faces are equal regular polygons and if each of its vertices has the same surroundings.
There are only five regular convex polyhedra: the tetrahedron, cube (hexahedron), octahedron, dodecahedron, and icosahedron. They are shown in Figure 1.4. Their characteristic parameters are given in Table 1.3. The regular convex polyhedra are called Platonic solids because they were an important part of Plato's natural philosophy.
The same polyhedron may be used to describe the shapes of two rather different types of molecule. For example, As4 and B4Cl4 are described as tetrahedral molecules. In both these cases, there are atoms at the corners of a tetrahedron, and each of these atoms is bonded to each of its three neighbors so that there are bonds along all six edges of the tetrahedron (Figure 1.5). In contrast, methane, CH4, and silane, SiH4, are also both described as tetrahedral molecules. In these molecules there are atoms at each of the corners of the tetrahedron, but these atoms are not bonded together; rather they are bonded to an atom at the center of the tetrahedron (Figure 1.6). To distinguish these two types of tetrahedral molecules, we will call the latter type centered tetrahedral molecules. The other type of tetrahedral molecule in which the atoms are at the corners of a polyhedron and there is no central atom are often described as cage or cluster molecules. An example of an octahedral molecule without a central atom is the borane B6H2-6 (Figure 1.7). There are many octahedral molecules with a central atom. Examples are SF6 and PCl-6 (Figure 1.7).
The regular convex polyhedra are highly symmetrical. There are various other families of less symmetrical polyhedra. The semiregular polyhedra are similar to the Platonic solids in that all their faces are regular and all their vertices have the same surroundings, but their faces are not all polygons of the same kind.
Prisms and antiprisms are also important polyhedra. A prism has two identical and parallel faces that are joined by a set of parallelograms. An antiprism also has two identical and parallel faces, but they are joined by a set of triangles. There is an infinite number of prisms and antiprisms and some of them are shown in Figure 1.8. The cube is a special case of a prism in which the two parallel faces are squares that are also joined by squares, and the octahedron is a special case of an antiprism in which the two parallel faces are equilateral triangles that are also joined by equilateral triangles.
Of the endless number of less regular polyhedra, two more kinds deserve special mention, the pyramids and bipyramids. The most symmetrical pyramids and bipyramids have a regular base. The tetrahedron is a special case of the trigonal pyramid with a regular triangular base and three regular triangles as side faces. A bipyramid is a double pyramid, which may be thought of as obtained from a single pyramid by reflection with respect to its base. Examples are shown in Figure 1.9. A trigonal bipyramid is not a regular polyhedron as it has two sets of nonequivalent vertices, at two of which three edges meet and at the other three four edges meet. The tetragonal bipyramid, however, becomes an octahedron when all its faces are regular triangles. Among the pyramids and bipyramids, the square pyramid and the trigonal bipyramid are important molecular shapes (Figure 1.10).
Excerpted from The VSEPR Model of Molecular Geometry by Ronald J. Gillespie, István Hargittai. Copyright © 2012 Ronald J. Gillespie and István Hargittai. Excerpted by permission of Dover Publications, Inc..
All rights reserved. No part of this excerpt may be reproduced or reprinted without permission in writing from the publisher.
Excerpts are provided by Dial-A-Book Inc. solely for the personal use of visitors to this web site.


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