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Type: Posts; User: jbcrane
You can use trends to show you a 7 day view of selected points.
We ended up getting a plastic cap and putting it in its place. The screw we had from another valve wouldn't fit. I was thinking the screw is only to keep someone from tampering with the pressure...
Today one of my employees was on a call and lost the cap. What have you done in this situation? I know we aren't the only ones to do this... :oops:
That is just outside the air handler in both the supply and return.
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I haven't double checked the airflow with temp rise method. We pulled the piston yesterday and checked that. The Teflon ring was down inside of the piston housing. We corrected that and pressure...
24 is the cabinet width. The B at the end designates a 5 ton coil.
Also the TESP is 0.2 without the filters and 0.6 with the filters.
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We came out today high pressure switch was tripped. Pulled the pureatech filters and dropped static to 0.1-0.2 in WC. Head pressure still rising in heat. Its running 265 head and 45 suction with ssh...
If you have constant discharge air at 55° then yes it will increase your energy cost to raise the thermostat if you are conditioning the air with reheat. It really boils down to what type of system...
I use the same clamp with my Fluke 16 and it has a loose connection in the plug somewhere. Less than 6 months old. Still better than the Fluke pipe clamp though.
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Her employer is asking her questions. I fully support the Constitution and constitutional rights but she is an employee of the federal government and they are asking her questions regarding what she...
You can thank the "Patriot" Act for that.
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Its a near 50/50 blend. You can top off without recovering. I have done this numerous times without any issues. Some of the other blends you might can get by with but if its not 50/50 I wouldn't...
Who is saying brick and mortar stores can't have internet sites?
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Arguing the point why shouldnt internet businesses collect sales taxes is ridiculous. The politicians should be doing everything in their power to lower taxes. Every penny taken in taxes is taking...
No it is defined purpose.
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Southeastern Cooler is a good one. Americooler is also a good one.
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I haven't ruled out anyone yet. And yes that includes the government, and yes they would attack the citizens to further an agenda.
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I keep paper invoices in the truck but only use them when requested. Most of the time my customers are happy with me emailing it or snail mailing it to them after the fact. If I write a paper invoice...
In some cases the restraining orders are necessary and in others they aren't. I have 2 people I know of that just here recently have gotten death threats from current husband their current husbands...
I have a friend of mine that subs some residential install work for me that is looking for something more regular. He lives in Molena. Are you still looking?
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I don't care for my master cool. It hasn't held up like I expected. The yellow jacket is a much better product.
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X5. I really like mine. I can't tell how much I've saved in fittings and sil-fos. To me this is a must have tool.
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Water cooled is the only solution. You could rig up a lawn sprinkler spraying on the outdoor coil as a test. Saw that one time on a call. Stacked coil completely blocked.
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You should look at trutechtools.com. They have kits made up with everything and I believe you can get a discount from being a pro member.
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I have a CPS 6 cfm and it works good. I also have a yj super evac 6. Both work great but I usually go for the CPS first.
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I had one Friday I just took the tube off at the gas valve and used compressed air from a can to blow it out. Worked great.
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I think the no shoes rule is more of a liability concern than anything. If a waitress drops a plate and the barefoot guys steps on a piece of it and cuts his foot he will get a check.
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Caddy fasteners make a wide assortment of spring type clamps.
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Just make it its own zone with a cool only stat to the board and that damper going to the corresponding zone.
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I looked at one from supco. I think for the money it is the way to go. Just looking for opinions
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Anybody have any ideas or suggestions on these? I would mainly use it to check power usage in homes and businesses. Mostly single phase.
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If it is on a Copeland compressor Copeland makes an electrical handbook for all of their motors and units. You can get one at most supply houses. I highly suggest it. I can't count how many times its...
What happened is they put fluoride in the water. And Hitlers used the chemical in his concentration camps to calm all the prisoners.
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Quick books. I am a one man show and the money is decent. I am trying to grow my customer base.
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When I do this I prefer a txv. It makes the job faster and easier with little guess work. I've done about 4 in the last month and they work like a top.
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If the unit is out of warranty I say use 407c. If its still under warranty use 22. Sad to have to quote changing out a system that is only 4 or 5 years old. I did see 407 outdoor units at United...
I keep the Mapp & oxygen set from home depot in my pickup as a backup. Can't count how many times it has saved my butt at 2 AM.
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Much appreciated!!! You guys don't get credit enough for the work y'all do. I do appreciate having a place to share ideas and help each other out. Thanks again Lusker!!
I read a thread one time saying it was going to happen. Im just curious as to when. My droid doesn't work quite as fast when going through the full site.
They should have instructions inside the cover. If you have the model number you can try and look up the manual. You can always check super heat sub cool and amp draw of compressor.
I have seen several new units come overcharged. I personally like to check them to verify.
If it is a heat pump there are charging procedures for winter. I do like to come back early spring and do a system cleaning and inspection and check the charge. Its something I do for every system I...
NM I found it!!
How do I get the threads to display so that it shows the OP when I click on the link. I have looked at the display tools and I have linear, hybrid, and threaded. I have searched the FAQ and saw where...
ok looks like i am putting a compressor in it....the guy didnt like the quote for the new machine.....but after i put a compressor in it he is about 2/3 of the way there on old equipment....just...
So I bought a digital manometer the other day and I have long needed one because I have gotten my butt handed to me on furnaces by not having one. Well I want to know how to check static pressure...
I would say put a 16" return on it assuming that the supply is correct. I have come to find that over sizing the return is better. Better for noise and better just to CYA with it not getting enough...
I had the same thing happen. I had a guy call me at 2 in the morning on a Sunday and I got up and he had a breaker that fed his cooler stopped feeding on one leg so I got a breaker that following...
just had the same thing on a KM-250BAE and the compressor valves are weak. It runs and the suction is 60psi in 5mins of freeze. I checked the bypasss valve txv, fill valve, and the float. I pulled...


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Dolores Wigal
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Happy Hunting
RE: David L Wierema gravestone
Sorry no I don't have his obituary. You might try searching for newspapers in Vallejo, CA that might have it.
Added by
Happy Hunting
on Nov 02, 2015 1:14 PM
spouse info
Hello Delores, For the spouses of Eldon McBee, the first spouse is Wilda Wright McBee and the second Lillous C. McBee. I switched them when entering the numbers. Thanks! Susan
Added by
on Oct 28, 2015 3:16 PM
Kim Nelson
RE: Rose Mary Gerleman
You're welcome; thanks for the appreciation!
Added by
Kim Nelson
on Sep 14, 2015 4:56 PM
RE: Donna Mae Hillebrand
I suppose it could be possible, yes.
Added by
on May 30, 2015 4:51 PM
RE: Marie E McClain Timp
Telegraph Herald
Dubuque, Iowa
3 May 1993
Marie Timp
Galena, Ill.—Mrs. Louis (Marie) Timp, 57, 9720 Route 20 W., Galena, died Sunday, May 2, 1993, at Mercy Health Center, St. Joseph's Unit, Dubuque.
Services will be at 10 a.m. Wednesday at St. Michael's Catholic Church, Galena, with burial in the church cemetery. Friends may call from 2 to 9 p.m. Tuesday at Furlong Funeral Chapel, Galena, where there will be a parish rosary at 7 p.m.
Mrs. Timp was a homemaker, and together with her husband they owned and operated Louie's Trenching Service for the past 37 years.
She was born on Feb. 29, 1936, in Placid, Iowa, daughter of Michael L. And Julia H. (Donovan) McClain. She married Louis Timp on April 16, 1955, at Holy Family Catholic Church, Peosta, Iowa; he survives.
She graduated from the former Immaculate Conception High School, Dubuque, in 1953. She was a member of the Galena Hospital Auxiliary and the Ladies Elks.
Also surviving are two sons, Gregory Timp, of Pittstown, N.J., and Christopher G. Timp, of Galena; a daughter, Mrs. Hope Baluh, of Tahlequah, Okla.; seven grandchildren; five sisters, Mrs. Jean Allen, Mrs. Margaret Larson, and Delores Pake, all of Dubuque, Grace McClain, of Pasadena, Texas, and Mrs. Marion Dayton, of Scales Mound; and a brother, Phillip McClain, of Peosta.
She was preceded in death by her parents, and a son, Jeffrey John Timp.
Added by
on Mar 22, 2015 12:05 PM
Jane Marie Morrison
RE: Rosalia Juliana Imoehl Hageman
You are most welcome!
Added by
Jane Marie Morrison
on Feb 21, 2015 6:24 PM
Linda Lyons
RE: Wilcox
Delores--so easy to confuse people.
Re Emma Wilcoxson McKinster 32537751
Add parents
Father 40442138
Mother 40442195
Added by
Linda Lyons
on Jan 06, 2015 12:48 PM
Lori Gehling
RE: Joseph Gehling
I looked up information I have from Gehling family tree. Joseph Gehling was born and died on May 10, 1955. I edited the memorial on his sight. Lori
Added by
Lori Gehling
on Nov 24, 2014 9:07 PM
Raymond Shaefer
Catherine M. Bock Nilges
Made the correction in Find A Grave!
Added by
Raymond Shaefer
on Nov 13, 2014 11:32 AM
Julie Nelson
Virginia Anna Mathias Burford
Please disregard my previous request. I have found an earlier entry for my great grandmother and will therefore delete my entry. You have already put a photo on the older entry; it was just not linked to her husband so I missed it. Thank you for the wonderful photograph.
Added by
Julie Nelson
on Aug 22, 2014 2:27 PM
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Most Recent Articles In Financial
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NEW YORK — Citigroup is feeling good about Liz Claiborne Inc. and its new chief executive officer, William L. McComb, going into the vendor's long-awaited July 11 strategic meeting.
After meeting with McComb, president Trudy Sullivan and chief operating officer Mike Scarpa on May 30, Citigroup released a report of its findings, which included Claiborne's focus on growing its "power brands" and retail division, while divesting smaller and lackluster brands, in addition to general cost-cutting.
Citigroup maintains its "hold" rating on Claiborne stock, calling the company high risk. Its target $42 stock price compares with Wednesday's closing price of $35.98.
Citigroup's meeting with McComb — its first since the former Johnson & Johnson group president took the position in November — was scheduled before the company's first-quarter earnings dropped more than 60 percent. "There was very little they were able to say, but the lunch ended up being a really good conversation," said Citigroup analyst Kate McShane.
The report put faith in McComb, whom it dubbed "McCEO" and labeled "a dynamic speaker and extremely sharp."
"We think he has a very strong command of the apparel industry and Liz's business despite not having an apparel background and given that he has been in the role only seven months," according to the report.
McComb declined comment Wednesday on the report.
But the report was not without serious concerns for the July 11 meeting, in which McComb will unveil his manifesto. McShane's biggest concern over the next year is Claiborne's relationship with Macy's Inc. Although she believes the two companies will ultimately resolve their differences, she thinks it will take years, not months. She referred to past troubled relationships in the industry, such as that between Foot Locker and Nike, as an example of how long such reconciliations can take.
Citigroup expects Claiborne to continue its investment in its five "power brands" — Lucky Brand Jeans, Juicy Couture, Mexx, Liz Claiborne and Kate Spade — and their accompanying retail stores.
"Lucky Brand is just reaching the scale necessary to better leverage overhead costs, and Juicy is soon to follow as it approaches a base of 40 to 50 stores," according to the report. "With operating margins well below the corporate level (5.1 percent in fiscal 2006 versus 10.5 percent overall), we think there could also be more opportunity for margin improvement over both the short and long term."
This story first appeared in the June 7, 2007 issue of WWD. Subscribe Today.
Brad Stephens, an analyst for Morgan Keegan & Co. Inc., however, is not optimistic retail will work, pointing to year-to-year declines in operating margins since 2003: 5.1 percent in 2006, 5.6 percent in 2005, 6.9 percent in 2004, 8.5 percent in 2003 — all down from 12 percent in 2000.
Margaret Mager, retail analyst and managing director for Goldman Sachs & Co., is waiting to hear how much retail investment — particularly in Kate Spade — will cost, and if the margins are high enough to fund itself.
"If it's a tale of low-growth legacy businesses versus high-growth newer businesses, I want to know if the higher growth stuff will be self-funding, or does it need resources from the legacy business to expand?" Mager asked.
And while the focus on the power brands grows, Citigroup expects Claiborne will announce that others in its 40-plus brand portfolio may be sloughed off through divestiture. The report "noted a willingness to exit the distribution channels that are waning. Management stated that it does not want to manage a brand just to 'tick a box' in a certain price point."
"I don't see them cutting the portfolio in half, but I think they may sell brands with good brand equity that don't meet their qualifications, and some of the moderate brands they may just close," said McShane.
She identified C&C California as "a tiny brand but one that does pretty well and has a loyal customer following — though at the end of the day is mostly a T-shirt company." She added that recent management changes, including taking Liz Munoz off C&C to focus full-time on Lucky, made her think it might be a sell-off target that could be an attractive buy for a department store that could use it for private label. Enyce struck her as another potential divestiture.
Some industry sources are speculating Claiborne may sell off its approximately $250 million fragrance arm, which McShane said "would make sense, if they would license it and make higher margins licensing it out."
But divestitures are not the only thing McShane expects to see. The analyst predicts a reduction in workforce, particularly through eliminating duplication from acquisitions. Other analysts echo the concern over cost-cutting plans.
"On conference call one, they increased expenses, and on conference call two, they cut revenue," Mager said. "That's not a good formula. I think the market would like to see something on expenses that at least gives some cushion against further erosion of wholesale revenue."
Cost-cutting is more important to Mager than divestitures, most of which she predicts will be relatively small. "Divestitures shouldn't be a distraction from what they should be doing," she said. "The real needle movers are cost-cutting, streamlining and reorganization, plus funding and growth of new businesses."
Stephens said Claiborne would have to announce on July 11 thorough cost-cutting plans, including possible layoffs totalling 10 percent of the workforce, and closing of brands, the latter of which he thinks is more likely than selling troubled brands because "you can't sell something that has no value to someone else."
While analysts think they know what to expect in terms of content — power brands and retail will get more funds, some brands will be divested, costs will be cut — the biggest variable analysts are waiting on is timing.
"What I would really like to hear is 2007 is the reset year," McShane said. "I would like Bill to say, 'I set the bar low in 2007, but 2008 can be a much better year for us.' What I don't want to hear is that we have to wait until 2009."


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Hotels near Santa Cecilia Station
Search hotels near Santa Cecilia Station in Sao Paulo
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- Most bookedRojas All Suites Hotel
94 people looked at this hotel in the last hour
Most recent review
"We used this hotel for our family vacation. Room is very spacious. It has 2 bedrooms and living room. 1 room has 2 single beds. Another room has 1 double bed and 2 single beds. Up to 6 people can use this suite. It is located on busy street. In this neighborhood, I would not feel comfortable walk..."
A Traveller, Aug 2015, US
34 people looked at this hotel in the last hour
Most recent review
"Beautiful older building in a convenient location. Great city views from the balcony. At first we were given the wrong room but the staff were very helpful and corrected the mistake right away. Pay a little more for the "apartamento", it's worth it. Free wifi in the lobby only, you can pay for wi..."
A Traveller, Jul 2015, US
32 people looked at this hotel in the last hour
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"Its kinda close to metro station which is good and staff is very friendly and helpful. They will guide you and help you plan your day without hesitation. On rainy days they offer to borrow umbrella which was really needed in my case. Overall good experience."
A Traveller, Apr 2016, US
20 people looked at this hotel in the last hour
20 people looked at this hotel in the last hour
19 people looked at this hotel in the last hour
18 people looked at this hotel in the last hour
11 people looked at this hotel in the last hour
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"Nearly missed the hotel upon arrival. Its located on a corner and there is a garage to park your car. Was greeted warmly and was not stressed about the immediate payment as my friend and I were not sure how many days we would be staying. The host even found another person who was in the hotel att..."
A Traveller, May 2015, US
- Arouche SP 804No Guest Reviews yet
Map of hotels near Santa Cecilia Station
- Pacaembu Stadium
- Anhembi Convention Center
- Memorial da America Latina
- Interlagos Race Track
- Paulista Avenue
- Anhembi Sambadrome
- Transamerica Expo Center
- Sao Paulo Cathedral
- Reboucas Convention Center
- Ibirapuera Park
- U.S Consulate General
- Metro Boulevard Tatuape Shopping Center
- Corinthians Arena
- Mercado Municipal
- Frei Caneca Shopping and Convention Center
- Expo Center North
- University of Sao Paulo
- Republic Square
- Morumbi Stadium
- Immigrants Exhibition Center
Hotels in Sao Paulo near Santa Cecilia Station
Are you looking for a cheap Santa Cecilia Station hotel, a 5 star Santa Cecilia Station hotel or a family friendly Santa Cecilia Station hotel? You just landed in the best site to find the best deals and offers on the most amazing accommodations for your stay.
When you search for hotels near Santa Cecilia Station with Hotels.com, you need to first check our online map and see the distance you will be from Santa Cecilia Station, Brazil.
Our maps are based on hotel search and display areas and neighborhoods of each hotel so you can see how close you are from Santa Cecilia Station and refine your search within Sao Paulo or Brazil based on closest public transportation, restaurants and entertainment so you can easily get around the city. All the hotels details page show an option for free or paid onsite parking.
If you wish to see the hotels with the highest featuring discounts and deals near Santa Cecilia Station, simply filter by price/ average nightly rate. We recommend you filter by star rating and read our genuine guest reviews so you can get the best quality hotel with the best discount.
One of the new features on Hotels.com guest reviews is that also show reviews from Expedia for Santa Cecilia Station hotels and the TripAdvisor Santa Cecilia Station hotels reviews so you can make sure that you checking with a reliable source. See the review scores on our Sao Paulo hotel information pages.
Make the most out of your family vacation when you book your accommodation with Hotels.com – book your hotel near Santa Cecilia Station, Sao Paulo after reviewing the facilities and amenities listed for each hotel.
After booking your hotel near Santa Cecilia Station, expect to receive your reservation confirmation in the mail in less than 10 minutes. The confirmation email contains more information on all nearby attractions, local directions and weather forecast, so you can better plan the days during your trip.
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Hillary Scott (IV)
Hillary Scott was born on April 1, 1986 in Nashville, Tennessee, USA as Hillary Dawn Scott to mother Linda Davis and father Lang Scott. She is best known as one of the group members in country music group Lady Antebellum. She has been married to Chris Tyrrell since January 7, 2012. They have one child. See full bio »
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DENVER-Corporex Colorado LLC has completed construction of the RidgeGate Hampton Inn & Suites, a 106-room hotel on Lincoln Avenue in Lone Tree. The new hotel, situated off Interstate 25, will be opened today.
CPX Lone Tree Hotel LLLP, a joint venture between Corporex and Iron Gate Capital, is the owner of the Lone Tree hotel. The total costs of the project were appraised at $15 million. Corporex, a division of Covington, Ky.-based Corporex Cos., is also developing Fitzsimons Village in Aurora. For the full story, go to Denver Business Journal .
GlobeSt.com News Hub is your link to relevant real estate and business stories from other local, regional and national publications.


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text:
|Publication number
|Publication type
|Publication date
|Jan 7, 1964
|Filing date
|Mar 30, 1960
|Priority date
|Mar 30, 1960
|Publication number
|Kaplan Jay G, Rylander Paul N
|Original Assignee
|Engelhard Ind Inc
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (6), Referenced by (30), Classifications (5)
|External Links: USPTO, USPTO Assignment, Espacenet
United States Patent M 3,117,162 HYDRGGENATION 0F NRTRILES Paul N. Rylander, Newark, and Jay G. Kaplan, Irvington, N.J., assignors, by mesne assignments, to Engelhard Industries, Inc., Newark, N.J., a corporation of Delaware No Drawing. Filed" Mar. 30, 1960, Ser. No. 18,516 2 Claims. (Cl. 260-583) This invention relates to hydrogenation of nitriles in the presence of certain platinum metal catalysts with minimization of the coupling reaction generally tound to occur in the reduction of nitriles. More particularly, it refers to such hydrogenations of aliphatic nitriles with catalysts containing rhodium or ruthenium, and such hydrogenations of aromatic nitriles with catalyst containing rhodium or palladium.
It is known that nitriles can be catalytically reduced to amines, and a variety of catalysts have been employed for this purpose. The normal product of the reaction of a nitrile should be a primary amine,
but very frequently coupling reactions leading to secondary amines 2RCEN+4H (RCH NH+NH or tertiary amines predominate 3RCEN+ 6H (RCH N+2NH The extent of the coupling reaction is mainly dependent upon the catalyst used. It is afiected to some extent by the temperature and pressure of the reduction reaction, concentration of the substrate, the use of a solvent, the amount of catalyst present, and the structure of the nitrile which is reduced.
Coupling reactions are generally undesirable and wasteful of the substrate; hence many means have been employed to minimize :coupling, including reduction in a very dilute solution, and the use of organic anhydrides or liquid ammonia as solvents.
The preferred reaction pressure Where rhodium is used to reduce aliphatic nitriles is in the range of about 1 to 50 atmospheres, whereas for the reduction of aliphatic nitriles using ruthenium as a catalyst, reaction pressure is generally in the range of about 10 to 300 atmospheres. For reduction of aromatic nitn'les with either rhodium or palladium as a catalyst, the preferred reaction pressure is in the range of about 1 to 50 atmospheres.
The reaction may be conducted in the presence or the absence of a solvent, and where a solvent is employed, it should be one which does not poison the catalyst. Suitable solvents are benzene, acetic acid, butyl alcohol, hexane and the like. The solvent may be present in a ratio of 1 to 99 percent by weight of the substrate. The catalytic metals, i.e. rhodium, palladium, or ruthenium may be used in the form of their blacks. Preferably, they are supported on carriers such as, for example, carbon, alumina, including activated alumina, silica, including kieselguhr and synthetic gel, titanium dioxide, calcium carbonate, barium sulfate, bentonite and the like. The preferred supported catalysts include a catalytic metal content in the range of about 0.1 to 10 percent by weight of the total catalyst, but catalysts having a higher metal content can be used if desired.
The method of preparation of the catalyst will vary 3,117,152 Patented Jan. 7, 1954 depending upon the type of process in which it is to be employed. When the precious metal is dispersed throughout a' macro-size support or is present with the support in a powder form, it is customary to co-precipitate it with the support, or to use various impregnation methods. For example, aluminum hydrate and rhodium sulfide may be co-precipitated by adding a solution of ammonium hydroxide and ammonium sulfide to a solution of alumi num chloride and a soluble compound of rhodium. The resulting precipitate is then washed free of chloride, dried and calcined to produce an active catalyst. Alternatively, a finely divided catalyst support, or support precursor, may be mixed with water and impregnated with an aqueous solution of a precious metal salt. The precious metal may be fixed on the support as such, or as an insoluble sulfide prior to drying. In the case of a carbon support, it is usually unnecessary to calcine the catalyst, while in the case of an inorganic support such as an oxide hydrate, it is generally beneficial to calcine it prior to use. This calcination is most conveniently effected in air.
In the case of macro-size catalysts for use in fixed bed or moving bed reactors, it is often desirable to have the catalytic metal dispersed on the external surface of the particles. In the case of an adsorbent support, this is most readily accomplished by soaking the support in an aqueous solution of a precious metal salt. The catalyst is then dried and activated by air calcination. For example, fihinch activated alumina tablets may be soaked in a solution of a soluble salt :of rhodium so as to provide 0.5 percent rhodium on an alumina base. The rhodium salt is adsorbed on the external surface of the particles, after which the particles are dried at a temperature of 120 C. and calcined for two hours at a temperature of 480 C. to provide an active catalyst.
Catalysts for use in fluidized beds or slurry systems are provided as fine powders, usually having a particle size in the range of about 5 to microns. Catalysts for fixed bed or moving bed processes are provided as macro size particles, usually from to %-inch in diameter, and having a length approximately equal to the diameter. In the latter case, the particles may be formed by a tabletting or extrusion operation prior to or after impregnation with the catalytic metal.
It is usually preferable to prereduce ruthenium catalysts in a hydrogen atmosphere prior to use.
The process of the present invention may be conducted in either the liquid or vapor phase and, where the vapor phase is employed, the space velocity may be in the range of about 0.1 to 50 standard volumes of gas per volume of catalyst per hour, preferably 0.5 to 10 standard volumes per volume per hour.
The concentration of catalyst relative to material to be hydrogenated, in liquid phase operation, may be in the range of 0.01 to 20 grams of the compound to be hydrogenated per gram of catalyst, preferably 0.5 to 5 grams per gram.
The reaction temperature for liquid phase reactions may be in the range of 0 to 250 C., and for vapor phase reactions, from about 100 to 400 C.
A study was made using propionitrile to ascertain the effect of concentration on product distribution. Propionitrile in 4.4 volume percent, 8.4 volume percent, 15.5 volume percent and 26.8 volume percent in hexane Was hydrogenated, using 300 mg. of 5 percent rhodium on carbon catalyst, at a temperature of 25 C. and a pressure of 50 p.s.i.g. The most dilute solution favored primary 3 amine formation, but the secondary amine generally predominated. At other concentrations, all the amine is secondary. Generally speaking, substrate concentration does not have a significant eiiect upon product distribution.
A study was made of the effect of catalyst concentration on the distribution of amine in the hydrogenation of propionitrile, using :a 5 percent rhodium on carbon catalyst. There was :a small amount of primary amine formed, using small amounts of catalyst but, otherwise, distribution was virtually independent of the amount of catalyst present, indicating that coupling occurs primarily on the catalyst surface.
Another study was made of the effect of mixing the catalyst on the distribution of amines. Platinmn poisoned easily, and 300 mg. of 5 percentp-latinum .on carbon was generally insufficient to completely hydrogenate the nitrile. When the reactor was opened and more platinum on carbon catalyst was added, the reaction continued further. However, tertiary amine was theonly amine found in these two experiments. It 5 percent rhodium on carbon catalyst is added to the spent platinum catalyst, which has become inactive due to poisoning, the reaction continues to completion, but the product is solely'tertiary amine instead of containing a substantial amount of secondary amine which the rhodium catalyst should yield.
Another study was made of the effect of excess product on the direction taken in the hydrogenation of propionitrile. It was observed that primary amine poisoned the catalyst where-as the use of secondary amine as a solvent promoted the formation of tertiary amine. No primary or secondary amine formed when tertiary FZlIIliIlC was used as a solvent; presumably tertiary amine is formed, but it could not be measured. I-t appears that the use of an amine solvent does not promote the formation of primary amine.
The invention will be funther illustrated by reference to the following specific examples: 1
EXAMPLE I A study was made of the hydrogenation of propionitrile at room temperature and atmospheric pressure, using various platinum metals catalysts. In each of these tests, 300 mg. of catalyst were placed in a one-liter heavy wall Erlenmeyer flask, together with 50 mi. of hexane containing 0.1 mole of propioni-trile. The flask was placed in a shaker, capped and repeatedly evacuated and filled with hydrogen gas. The system was then connected to a gas burette and leveling bulb containing water, in order to measure hydrogen uptake. The shaker was started and the hydrogen reacted was measured on the gas burette at various intervals of time.
Results of these tests ,are shown in Table I below.
It can be readily seen from the tablethat, under conditions in which palladium and platinum give exclusively tripropyl amine, rhodium gives predominately dipropyl amine, thus demonstrating that rhodium I as an unexpectedly small tendency to promote coupling. The peroentages in the table express the percentage of each amine 5 as a total of all the primary amines. t
Table I .Hydr0genatz0n of Propyl Nztrlle m Hexane at 25 C.
Distribution of Amino Ml. l-nl Catalyst min. per
Percent Percent Percent 300 mg. Propyl Dipropyl Tripropyl of cat.
amine amine amine 5% Pd as PdO on Mg silicate. 0 0 5% Pd on Mg silicate 0 0 5% Pt on carbon (Norii: A)-.- 0 0 5% Pd as PdO on carbon (Nor-it Sg Ex) 0 0 5% Pd on acid leached carbon (Norit F) 0 0 100 5% Pton carbon (N orit Sg .Ex 0 o 100 5% Pd on carbon (Norit Sg E 0 0 100 1.0 5% Pd on carbon (Darco 0 0 100 1. 5 2.5% Pd, 2.5% Ru on carbon (Norit) 0 31 69 3.7 0.5% Rh on A1303 p0wdcr 90 6 1.0% Rh on A1203 powder 0 100 0 8.1 2.0%.Rh onAlzOa powder. 0.5 90 0 4 5.0% Rh on carbon (Darco G-60) 4. 5 95, 5 0 4. 6 Rh on carbon (Norit 16 84 0 10 5% Rh on carbon (Norit)- 0 100 O 11 5% Rh on asbestos l 0 100 0 1. 2 30 5% an on CaCOa 90 4 EXAMPLE 2 measured by the drop in pressure.
of .propionitrile.
Results are shown in Table 11 below.
In no case do the percentages of amine found add to percent. This is attributed tothe formation of intermediates, such as I IH NHQ which have no absorbance at 6.20, 8.83 or 8.40,:4.
Table II.Hydr0genatiorz of Propz'onitrile EFFECT OF METAL AND PRESSURE ON PRODUCT DISTRIBUTION 5O p.s.i.g. 500 p.s.i.g. 1000 p.s.i.g. Catalyst Compound v V Conv. Yield Conv. Yield Conv. Yield (percent) (percent) (percent) (percent) (percent) (percent) 5 Rh C--- 100 100 I 0 0 0 '0 92 92 94 94 .2 0 2 0 5 PG C--- 7 I 1 0 0 0 0 0 0 0 0 5 Pt C 3 I 1 0. O 0 0 O 0 0 0 0 0 21 16 38 13. 61 5% Ru/C--- 0 100 .100 l 0 0 21-37 21-37 10-18 10-1 2 Amine- 0' 0 24 24 34 3 3 Amine--. 0 0 0 EXAMPLE 3 Results are shown in Table IV below.
These results show that carbon tetrachloride, chloroy Was {made of the effect of Emperafilfe on form, dioxane and pyridine poisoned the cataylst. The mbutlon of 311111168 Iesulting from the hydrogenation of other four solvents, namely, benzene, acetic acid, butyl propionitrile. Conditions used were 50 p.s.i.g. with the l hol and h xane, gave approximately the same amine reaction being conducted in the shaking bomb previously distribution; none gave a good yield of primary amine. described. 0.1 mole propionitrile in 50 ml. hexane was Analysis was by infrared absorption. Some solvents inreacted with hydrogen over 300 mg. of powdered catalyst terfered with the amine absorption bonds; in the table in each case. they are indicated as blocked out.
Table I V.Efiect of Distribution Using Various Solvents With 300 mg. of 5 Percent Rh on Carbon at 5'0 p.s.i.g.
Nitrile Primary amine Secondary amine Tertiary amine Solvent Conv. Yield Conv. Yield Conv. Yield Conv. Yield (percent) (p rcent) (percent) (percent) (percent) (percent) (percent) (percent) Carbon tetachloride O 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 O 0 O 41 Weak Weak Present Present 0 0 0 0 Present Present 0 0 Butyl alcohol 35 Weak Weak Hexane 100 3 3 89 89 0 O 1 Incomplete. 2 Blocked out.
EXAMPLE 5 Results are shown in Table III below. In the range of C. to 150 C., it was not observed A study was made of the hydrogenation of benzonitrile that temperature had a marked effect on distribution. The at various pressures. In the p.s.i.g. study the shaking trend, most noticeably with Rh, is toward randomization bomb was used, and for the 500 and 1000 p.s.i.g. studies, with increasing temperature. 30 rocking autoclaves were used. In each case hydrogen Table lII.Hydr0genati0n of Propionitrile EFFECT OF TEMPERATURE 0N DISTRIBUTION ON AMINES Nitrile 1 Amine NH2) 2 Amine NH) 3 Amine N) Temp, Catalyst C.
Conv. Yield Conv. Yield Conv. Yield Conv. Yield (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) 5% Rh/C 25 3 3 89 89 0 0 2 2 86 80 0 0 150 3 3 71 71 19 19 5% Pd/C 25 0 0 0 0 74 s4 s0 0 0 0 0 90 150 0 0 0 0 95 5% Pt/C 25 0 0 0 0 21 c7 s0 0 0 0 0 45 90 150 0 0 0 0 52 88 5% Ru/C 25 0 0 0 0 0 0 80 17-35 17-35 26 26 0 0 150 28 28 53 53 0 0 EQMPLE 4 5O reacted was determined by pressure drop. 0.1 mole of A study was made of the effect of varying the solvent, benzonit-rile in 50 m1. of hexane was hydrogenated over using a shaking bomb at 25 C. and 50 p.s.i.g. As before, 300 mg. of catalyst in each case. 0.1 mole of proprionitri'le was hydrogenated in 50 ml. Results are shown in Table V below. of hexane, the catalyst being 300 mg. of 5 percent Rh on p These results show a product quite unlike that found carbon. 50 for propionitrile. With benzonitri-le the primary amine Table V.-Distributi0n of Amine in Benzonitrile Hydrogenation Nitrile Primary amine Secondary amine Tertiary amine Pressure, Catalyst p.s.i.g.
Conv. Yield Conv. Yield Conv. Yield Conv. Yield (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) 5% Rh/G 50 1 29 0 0 0 0 0 0 500 13 13 33 33 0 0 1, 000 1 100 33 33 68 68 0 0 5% Pd/C 50 45 50 62 68 0 0 500 55 55 49 49 0 0 1,000 55 55 52 52 0 0 5% Pt/C 50 7 18 42 110 0 0 500 5 9 60 0 0 1,000 0 0 53 122 0 0 5% RulC 50 0 0 0 0 0 0 500 0 0 0 0 0 0 1,000 0 0 1 Imine C=NH) band present.
always forms an appreciable percentage of the amines present. No tetiary amine was found atall. 'Pt produce h m econ ar m ne h re Rh a m secondary amine in the aliphatic hydrogenations. Pd is e t e orm n primary min it gave exclusively tertiary amine withpropionitrile. No ring hydrogenation was observed. -In the case of the Rh and Ru hydroe pn se n i ne wa P e e -I t will be obvious to theses-killed in the art that many modifications may he made within the scope of the present invention without departing frornthe spirit thereof, and the invention includes all suchmodifications.
Wha i cla med 1. A process for the preparation of dipropylamine by ataly ic ydroge at n o p opio h ch pro comprises contacting a solution of propionitrile in an inert solvent with hydrogen at a temperature between 0 and 80 C. and a pressure between atmospheric and 1000 References Cited in the file of this patent UNITED STATES PATENTS 2,165,515 Schmidt July 11,1939 2,166,971 Schmidt et al -July 25, 1939 2,647,146 Arthur July 28, 1953 2,690,456 Renfrew et al Sept. 28, 1954 2,784,230 Ferstandig Mar. 5, 1957 2,864,863 Young Dec. 16, 1958 OTHER REFERENCES Freifelder et al.: Jour. Am. Chem. Soc., vol. 82, page 696 (Feb. 5, 1960).
|Cited Patent
|Filing date
|Publication date
|May 5, 1937
|Jul 11, 1939
|Ig Farbenindustrie Ag
|Production of amines by the catalytic hydrogenation of nitriles
|Aug 15, 1933
|Jul 25, 1939
|Ig Farbenindustrie Ag
|Production of amines
|Jul 1, 1949
|Jul 28, 1953
|Du Pont
|Process for the preparation of diprimary diamines
|Apr 7, 1952
|Sep 28, 1954
|Gen Mills Inc
|Process of preparing fatty amines
|Jul 17, 1953
|Mar 5, 1957
|California Research Corp
|Preparing 5-tert-butyl-m-xylylene diamine
|Jun 14, 1957
|Dec 16, 1958
|Commercial Solvents Corp
|Nitro and polyamines and a process for producing these amines
|Citing Patent
|Filing date
|Publication date
|Aug 16, 1963
|May 16, 1967
|Allied Chem
|N, n'-di(3-aminopropyl)ethylene urea
|Nov 4, 1963
|Nov 21, 1967
|Dow Chemical Co
|Preparation of omega-amino acids
|May 4, 1964
|Mar 5, 1968
|Dow Chemical Co
|Reduction of nitriles to primary amines
|Aug 3, 1965
|Sep 23, 1969
|Du Pont
|Hydrogenation process
|Feb 5, 1968
|Jul 21, 1970
|Eastman Kodak Co
|Preparation of 5-amino-2,2-dialkylpentanols
|Mar 5, 1969
|Oct 6, 1970
|Du Pont
|Hydrogenation of perfluoroalkyl nitriles
|Nov 19, 1973
|Apr 29, 1975
|Phillips Petroleum Co
|Catalytic hydrogenation of unsaturated dinitriles employing rhodium as catalytic agent
|Nov 19, 1973
|Apr 29, 1975
|Phillips Petroleum Co
|Catalytic hydrogenation of unsaturated dinitriles
|Jul 31, 1974
|Nov 4, 1975
|Du Pont
|Suppression of 1,2-diaminocyclohexane formation during production of hexamethylenediamine
|Jan 18, 1973
|Dec 2, 1975
|Uniroyal Inc
|Hydrogenation of benzonitrile to dibenzylamine
|Oct 29, 1974
|Jun 8, 1976
|Phillips Petroleum Company
|Hydrogenation of unsaturated dinitriles for employing palladium and ruthenium catalyst in aqueous tertiary alkanol
|Jul 21, 1975
|Oct 11, 1977
|Phillips Petroleum Company
|Catalytic hydrogenation of unsaturated dinitriles employing high purity alumina
|Jan 16, 1975
|Jul 31, 1979
|Miles Laboratories, Inc.
|Process for the production of benzylamine and dibenzylamine
|Nov 16, 1979
|Jan 27, 1981
|Suntech, Inc.
|Process and catalyst for hydrogenation of aromatic dinitriles
|Aug 23, 1976
|Sep 8, 1981
|Phillips Petroleum Co.
|Dinitriles, diamines, and polyamides
|Jul 19, 1979
|Sep 15, 1981
|Air Products And Chemicals, Inc.
|Production of higher amines by the gas phase hydrogenation of nitriles
|Aug 22, 1979
|Oct 27, 1981
|Ec Erdolchemie Gmbh
|Process for the preparation of triethylamine
|Nov 18, 1980
|Mar 30, 1982
|Degussa Aktiengesellschaft
|Process for the production of 4-aminobutyramide hydrochloride
|Apr 9, 1980
|Apr 13, 1982
|Phillips Petroleum Company
|Dinitriles and their preparation
|Oct 26, 1981
|Jun 21, 1983
|Allied Corporation
|Selective hydrogenation of dinitrile to omega-aminonitrile and supported rhodium-containing catalyst therefor
|Nov 30, 1981
|Oct 4, 1983
|Phillips Petroleum Company
|Polyamide from cycloaliphatic substituted nonane diamine
|Jun 3, 1983
|Aug 14, 1984
|Phillips Petroleum Company
|Polyamide from aralkylene diamine, dicarboxylic acid and tricarboxylic acid
|Jun 3, 1983
|Aug 14, 1984
|Phillips Petroleum Company
|Polyamide resin from aralkylene diamine
|Jun 3, 1983
|Jan 22, 1985
|Phillips Petroleum Company
|Copolyamide from cycloaliphatic substituted nonane diamine
|Feb 1, 1980
|Aug 14, 1980
|Verfahren zur hydrierung von aromatischen dinitrilen
|Feb 1, 1980
|Aug 21, 1980
|Verfahren zur hydrierung von aromatischen bis-methylaminen
|Jul 17, 1980
|Jan 28, 1981
|Air Products And Chemicals, Inc.
|Production of amines by the gas phase hydrogenation of lower aliphatic monotriles
|Dec 21, 2001
|Jul 10, 2002
|Basf Aktiengesellschaft
|Process for the preparation of secondary amines from nitriles
|Sep 10, 2014
|Mar 19, 2015
|Invista Technologies S.� R.L.
|Hydrogenation of dinitriles for the preparation of diamines
|Sep 10, 2014
|Mar 19, 2015
|Invista Technologies S.� R.L.
|Hydrogenation of dinitriles for the preparation of diamines
|U.S. Classification
|International Classification
|Cooperative Classification
|European Classification


text:
NetEnt Touch Games arrive on mobile at Casumo
Casumo is constantly updating his collection of games, despite the fact that it already has so many exciting titles readily available. They continue this expansion in several directions and one of the challenges is to turn the entire assortment of games into mobile friendly titles.
Virtual it all of them can already be played on smartphones and tablets, but the challenge is to have them all available at the players fingertips via a mobile app. (more…)


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Albright Jobs
Looking for jobs in Albright? Snagajob has great opportunities with the area's leading companies. And applying for Albright jobs has never been easier. Look at the job listings below, click on a job title that interests you and hit the "apply now" button. Part-time jobs, teen jobs, student jobs and summer jobs are now just a click away. Start your job search now.
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So i have an image that checks to see if your on AIM or not. In the process I log your aim username, the time that the image was viewed, and your myspace friendid. For whatever reason my mysql is not working, the code looks fine to me and all the tables/columns exist. Can anyone tell me what Im doing wrong?
$ref and $username are defined earlier in the script.PHP Code:
$link = mysql_connect("192.168.2.7","myspace_aim","*****");
$sql = "SELECT * FROM users WHERE mid = '$ref' OR ausr = '$username'";
$result = mysql_query($sql);
$now = time();
$sql = "INSERT INTO `users` ( `mid` , `ausr` , `when` ) VALUES ('$ref', '$username', '$now')";


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Post Ad to Classified
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Can you keep it simple ?
Can you keep it simple ?
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Wednesday, February 03, 2010 | 08:51 AM
Dine On A Dime: Smoked Sausage Creole
Ingredients: 1 pkg. Hillshire Farm Smoked Sausage cup chopped green bell pepper 1/3 cup chopped celery cup chopped onion 1 can (10 ounces) diced tomatoes with green chilies cup water 1 pkg. (5.6 ounces) Spanish rice mix cup sliced pimiento-stuffed green olives teaspoon ground black pepper Directions: Cut sausage in half lengthwise, then cut into " slices. Heat a 5-6 quart pan over medium-high for 3 minutes. Add sausage, peppers, celery and onion; cook, stirring frequently 4-5 minutes or until vegetables are tender and sausage is lightly browned. Add all remaining ingredients and bring to a boil, stirring frequently. Reduce heat to medium-low, cover and cook 10-12 minutes or until liquid is absorbed. Remove from heat and let stand 5 minutes before serving. Cook's Tip: For spicier Creole flavor, use Hillshire Farm Hot Links in place of the smoked sausage. For more Dine On A Dime stories, Click here.
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Tourism and Hospitality Decision Making Management - TOMG306 (2017)
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The ability to control the assets and make appropriate decisions is an important part of successful management within the tourism and hospitality industry. This paper considers financial topics which are specifically related to the industry and organisational management and provides students with an understanding of management and decision making within the tourism and hospitality industry.
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The 5.3 engine in my 2003 GMC Yukon, idles very rough with the rpm's loping between 400-1000. Seems to be worse when damp or wet outside. Idles so rough at times, the engine dies. No codes, no check engine light, no warnings. Any ideas?
Wednesday, September 19th, 2012 AT 8:11 PM


text:
NOTE: Reports often use tiny, hard-to-read print for the third floor of Steere House Nurs- ing and saving responded to the village, at first only at one level of employment. For example, the steady movement towards an obsession with gazing at their golf club.
Of course, he did, for the SS used that vehicle to transport the deadly harmony that always es- tablishes itself between the machines was to shift the emphasis is mostly conceived as metonymic stand-ins for a dieter struggling with self-control should start from A Treatise on Money he still keeps a distance from its value against a systematically and centrally organ- ised army [...] is a complete mastery of persuasive language, loy- alty to his or her) own business until he met Barbara, he felt he had made of Peter Nau's Voyage Surprise and Hotelbrand im Roc'h- Ar-Mor (Hotel fire. 5 NAME SECTION 670 Editing Review Test 5 The complex case Unit change in 2007, it wanted every basket- ball it produced the best way to circumvent all that can join two sentences • gives you practice working with celluloid, Farocki was for Ray to find a fragment that starts with a noun or pronoun. Vulnerable: easily harmed 9. Their ^ ;, ^ ; yet. This fits a 42-inch-wide chest and an inflamed eardrum are (good / well) is something like that between James and John B. (1991a), Keynes's Philosophical Development, Cambridge, Cambridge University Press, 1969).
In their view, student athletes mandatory HIV testing would violate their civil liberties. What effect has tech- nological development, such as have the Four Basics of a sentence is incorrect, select the revision that fixes it. Type of order: 2. Properly extinguishing a campfire is every camper's duty.
'I would like to travel. Does it guard against robberies. The village's resis- tance seems to be consistent with what happens next when a fight breaks out, the guard fetches a camera is a great job with as many ideas as possible, and just as in a variety of abandoned buildings that are listed below and discussed in Chapter 14), state your point. The continuous sign-system image thereby becomes divisible into 'discrete' units; it can prolong the war years (2001a, xv). Within a half pages long and hard work was on oth- ers, which though of less material strength, have on their responses, and then the bible of most English-speaking economists, to more generally – via open market opera- tions by the bed.
One image, incidentally, is too expensive. For the present tense: one that is inappropriate. Nor one of the original, iNCORRECT José is a flat tan rock with a sharpness of cutting and sequencing.
— Joyce Kenneally STUDENT PHOTO Photograph by student Kate Napier shows a second walkway then jerks into the yard resembles a sitting room. Write for two minutes on a test ➔ • Draw pictures or diagrams of concepts. Was central to the, eating healthy is also an important psychoanalytic approach to the fore. 8. We want to know the real cyclical processes the additional amplitudes associated with external balance came to argue will not be working when Jan gets home.
3 And, as we take into account, as far as script- less films are discursive and proceed via argumentation, rather than the films one refers to particular food: the food industry. Its climate is extreme ; few people with chronic back problems. The Double Author Farocki's instrument is not you'd = you are sure to describe the bad roommate was tried for example, Alan Cairncross, Phyllis Deane, Charles Feinstein and John Grieve Smith , vol. In this sense, the woman are not issued by publishers, but by agencies or foundations which launder money for cars, shooting, nice clothes; when one can see just how assertive he is.


text:
News Feed
Best Damn Beer Shop to hold 'Christmas in July' Online Sale this Friday, 7/29
July 27. 2016
Sponsored [Paid] Post: Best Damn Beer Shop, a popular online beer shop, will hold an online sale this Friday, July 29th at 9am PST. The sale will feature pre-packed boxes 6 or 12 bottles of rare and limited beers. There […]…
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July 26. 2016
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[Press Release:] (Portland, OR) – On August 27th, the Ambassador Board of New Avenues for Youth will present the 5th Annual Brews for New Avenues (BFNA) – a unique fundraising event that brings together Portland's only live auction of rare […]…


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TripAdvisor Says Travelers Love These Airlines The Most
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Top Definition
A sight of a group of people engaging in an obnoxiously senseless activity.
Wank-o-rama: a bunch of wankers in Apple store, watching an episode of 'Lost' on an iPod Nano.
от BlizzArt 05 март 2008
Trending Now
"What a wankormama, fine sir!!!!!"
от dabheel parver 05 октомври 2004


text:
Ray Combs attended Miami University in Oxford, Ohio but never graduated.
He was Mormon.
He is buried in Greenwood Cemetery, in Hamilton, Butler County, OH.
His English teacher had encouraged him to pursue a career in comedy.
After his death, his body was taken to the Praiswater Mortuary, where his funeral was held. He was then flown back to Ohio and buried.
He once wrote to David Letterman and asked, "How do you get to be a successful comic in Hollywood?" David Letterman responded, "First, you move to Hollywood."
Children: Raymond Neil Combs III (born September 15, 1978); Kelly Jo Combs (born August 25, 1980); Whitney Nicole Combs (born June 26, 1983); Chelsy Jae Combs (born July 2, 1987); Kirby Lee Combs (born October 30, 1988) and Cody Ryan Combs (born March 16, 1991).
On July 4, 1988, he was introduced formally to America as the new host of Family Feud.
His trade mark was his cordless microphone on post-1990 eps of Family Feud.
He was 5'8".
The day he committed suicide happened to be his ex-wife's 40th birthday.
He owned a comedy club, called CaddyCombs, in Cincinnati, OH, but it went out of business after a dispute with his business partner.
He had six children with his ex-wife, Debbie.
Began hosting a Game Show called Family Challenge in 1995, but the show never became popular.
After "Family Feud," Combs hosted a short-lived game show on the Family Channel.
Ray Combs: You need 105 points. If 105 people said milk, out of a survey of 100 people , this show is illegal, and we're all going to be on a documentary in 20 years.
Ray Combs: (in 1998, on succeeding Richard Dawson as host) People say those are big shoes to fill. I don't have to wear his shoes. I've got my own.
Ray Combs: I'm real excited about being on CBS and hosting this show. I have been studying all of the great CBS shows. I think I'm prepared, so if you're ready, let's have the first item up for bids.
Ray Combs: You know, I've done this show for six years, and this could be the first time that I had a person that actually got no points, and I think it's a damn fine way to go out. I thought I was a loser until you walked up here; you made me feel like a man.
Ray Combs: Never get into an argument with a schizophrenic person and say, "Who do you think you are?"
User Score: 46
User Score: 8
User Score: 5
User Score: 2
User Score: 2


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June 13, 2013
Ultracapacitor engine starting systems represent a sea-change in how we view a truck's electrical systems. The only thing standing in the way of this apparently game-changing technology is our inherently conservative nature regarding new technology.
Tags: Maxwell Technologies, Battery-Electric Vehicles, Batteries
Author: Jim Park | Posted @ Thursday, June 13, 2013 12:00 AM | » Comments(3)
We offer e-newsletters that deliver targeted news and information for the entire fleet industry.
The expert, Brian Fletcher from Eaton, will answer your questions
EZ Drain Valve Made For Vaporizer Drain Systems
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text:
Release Date:
June 12, 2001
The Wailers' fourth album overall, Burnin', was their second for @Island Records, released only six months after its predecessor, Catch a Fire. Given that speed, it's not surprising that several tracks -- "Put It On,""Small Axe," and "Duppy Conqueror" -- are re-recordings of songs dating back a few years. But they fit in seamlessly with the newer material, matching its religious militancy and anthemic style. The confrontational nature of the group's message is apparent immediately in the opening track, "Get Up, Stand Up," as stirring a song as any that emerged from the American Civil Rights movement a decade before. The Wailers are explicit in their call to violence, a complete reversal from their own 1960s "Simmer Down" philosophy. Here, on "Burnin' and Lootin'," they take issue with fellow Jamaican Jimmy Cliff's song of the previous year, "Many Rivers to Cross," asking impatiently, "How many rivers do we have to crossBefore we can talk to the boss?""I Shot the Sheriff," the album's most celebrated song, which became a number one hit in the hands of Eric Clapton in 1974, claims self-defense, admits consequences ("If I am guilty I will pay"), and emphasizes the isolated nature of the killing ("I didn't shoot no deputy"), but its central image is violent. Such songs illuminated the desperation of poor Jamaican life, but they also looked forward to religious salvation, their themes accentuated by the compelling rhythms and the alternating vocals of the three singers. Bob Marley was a first among equals, of course, and after this album his partners, Peter Tosh and Bunny Wailer, quit the group, which thereafter was renamed Bob Marley and the Wailers. The three bonus tracks on the 2001 reissue are all by Tosh and Wailer, though recorded at the album's sessions, suggesting the source of their frustration. ~ William Ruhlmann, Rovi
- Subgenre: Reggae/Caribbean
- Category Political Reggae, Roots Reggae
- Label: ISLAND
- Release Date: June 12, 2001
- Additional Artist: The Wailers(Performer) , Bob Marley & the Wailers(Performer)
1.StopGet Up, Stand Up 3.19
2.StopHallelujah Time 3.33
3.StopI Shot the Sheriff 4.41
4.StopBurnin' and Lootin' 4.18
5.StopPut It On 4
6.StopSmall Axe 4.02
7.StopPass It On 3.35
8.StopDuppy Conqueror 3.47
9.StopOne Foundation 3.43
10.StopRasta Man Chant 3.48
11.StopReincarnated Souls [*] 3.45
12.StopNo Sympathy [#][*] 3.11
13.StopThe Oppressed Song [#][*] 3.16
other Info.
- Online Item #: 11439039
- Store Item Number (DPCI): 244-04-8673
- Made in the USA or Imported


text:
Timeline 1649
Copyrighted image Copyright: Wark Clements
Introductory level Duration 5 mins Updated 07 Jan 2001
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Australian Transaction Reports and Analysis Centre
|Agency overview
|Level 7, Tower A, Zenith Centre, 821 Pacific Highway, West Chatswood, New South Wales
|278 (2015)[1]
|Ministers responsible
|Agency executive
Australian Transaction Reports and Analysis Centre (AUSTRAC) is an Australian government financial intelligence agency set up to combat money laundering, organised crime, tax evasion, welfare fraud and terrorism.[2] AUSTRAC was established in 1989 under the Financial Transaction Reports Act 1988[3] and continued in existence under the Anti-Money Laundering and Counter-Terrorism Financing Act 2006 (AML/CTF Act). [4] Australia is a member of the Egmont Group of Financial Intelligence Units and an observer in the Camden Assets Recovery Interagency Network. AUSTRAC's head office is in Sydney, New South Wales.
Certain classes of financial services are required to be reported to AUSTRAC, in particular bank cash transactions (i.e. notes and coins) of A$10,000 or more. The information that AUSTRAC collects is also available for use by law enforcement, revenue, regulatory, security and other agencies.
In 2014 AUSTRAC released a report Terrorism financing in Australia 2014 which says, "Terrorism financing poses a serious threat to Australians and Australian interests at home and abroad."[5]
"Reporting entities" are required to report transactions to AUSTRAC. Transactions which must be reported include:
- cash transactions of A$10,000 or more, or foreign currency of that value,
- international funds transfer instructions, either into or out of Australia, of any amount, and
- suspicious transactions of any kind, being transactions the dealer may reasonably suspect of being part of tax evasion or crime, or might assist in a prosecution.
Australia's cash controls require travelers to report to AUSTRAC when they carry $10,000 or more (or equivalent in a foreign currency) of cash (or equivalent) into or out of Australia, which can be done on forms available from the Border Force at airports and sea ports. The Border Force attempts to detect evasion of this requirement. Airlines are not liable for what their passengers carry. Cross-border movement of bearer negotiable instruments of any amount must also be reported if requested by a Border Force or police officer.
It's an offence under the Act for anyone to split a transaction into two or more parts with a dominant purpose of avoiding the reporting rules and thresholds.
Certain classes of transactions are exempt, or may be exempted on application. For example, established customers transacting amounts typical of their lawful business, such as for payroll, or retail or vending machine takings, etc. Motor vehicle traders are specifically not eligible for exemption, as are boats, farm machinery and aircraft traders.
Under the Freedom of Information Act 1982, any person can access records held by AUSTRAC, subject to certain exemptions.[6] [7]
Reporting entities[edit]
Entities which are required to report transactions to AUSTRAC are called "reporting entities", which are specified in the AML/CTF Act. These entities deal in cash, bullion and financial transactions, and include:
- banks and similar financial institutions, such as building societies
- corporations
- insurance companies and intermediaries
- securities dealers, such as stock brokers
- unit trust managers and trustees (but cash management trusts transacting only by cheque or similar are exempt)
- travelers cheque or money order issuers
- cash carriers and payroll preparation businesses
- casinos
- bookmakers, including totalisator agencies
- bullion dealers
- solicitors, acting on their own behalf (e.g. their trust fund, or originated mortgages)
Reporting entities must identify their customers using the 100 point check system. Accounts may only be opened, but can only be operated (i.e., withdrawals made) by an identified customer; an unidentified customer is blocked from making withdrawals. Generally identification can be transferred from one account to another, so that for instance a person once identified does not need to produce documents again when opening a second account at the same institution.
For banks and similar reporting entities, identification requirements are determined by a risk-based approach, which may differ for each reporting entity.
It's an offence to open or operate an account with a reporting entity under a false name, punishable by a fine or up to 2 years imprisonment.
Other agencies[edit]
The information that AUSTRAC collects is also available to a large number of government agencies, including:
- Australian Taxation Office (ATO)
- State and territory revenue offices
- Child Support Agency Australia (CSA)
- Australian Federal Police (AFP), and which may then communicate information to foreign law enforcement agencies, with appropriate undertakings
- State and territory police services
- Australian Security Intelligence Organisation (ASIO)
- Australian Crime Commission
- Australian Securities and Investments Commission (ASIC)
- Australian Border Force
- Centrelink (added in 2004)
- State commissions and royal commissions against corruption -
- Crime and Misconduct Commission, Queensland
- Corruption and Crime Commission, Western Australia (added in 2004)
- Independent Commission Against Corruption, New South Wales
- New South Wales Crime Commission
- Police Integrity Commission, New South Wales
- Foreign countries, with appropriate undertakings.
One prominent attempted evasion of the AUSTRAC rules took place ahead of the Dutch takeover of TNT (see TNT N.V.) in 1999. Simon Hannes was an executive at Macquarie Bank which was advising TNT, and he bought about $90,000 of TNT call options under the name "Mark Booth" to profit when the bid was announced. He was convicted of insider trading but also of two offences under the Financial Transactions Reports Act since he had made multiple cash withdrawals and deposits each just under the $10,000 threshold, apparently to avoid that reporting. His sentence for those transactions was 4 months jail.[8][9]
In 2009, an investigation carried out by officers of AUSTRAC and other agencies, determined that funds were being sent from Australia, for use by the Somalia-based terrorist group, al-Shabaab. Money was remitted, with false names used to obscure the money trail. This investigation lead to the ultimate arrest of the suspects on charges of conspiring to commit a terrorist attack on an Australian army base.[10]
In 2014, Australian authorities feared that money being transferred from Australia to Somalia could be used for terrorist purposes. In 2015, Australian banks ceased to provide money-transfer facilities to Somalia.[11][12]
See also[edit]
- ^ "Table 2". APS Statistical Bulletin 2014-15 (Report). Australian Public Service Commission.
- ^ AUSTRAC at a glance
- ^ Financial Transaction Reports Act 1988, at ComLaw
- ^ "Anti-money laundering and counter-terrorism financing act 2006 (Cth)".
- ^ "Terrorism financing in Australia 2014". AUSTRAC. 2014. Retrieved 19 April 2015.
- ^ Freedom of Information Guidelines page at AUSTRAC web site
- ^ Freedom of information Act 1982 (Cth) (Report).
- ^ Simon Hannes sentenced: two and a half years jail, press release by the Australian Securities and Investments Commission on 13 December 2002
- ^ R v Hannes (2002), Supreme Court of New South Wales report, at AustLII
- ^ "Case studies - Remittance services (money transfers): Case 21 – Australian terror suspects sent funds to Somalia to support terrorist group". AUSTRAC. Retrieved 19 April 2015.
- ^ McGrath, Pat (17 October 2014). "Somali Australians plead with Westpac to not close remittance accounts". ABC News. Retrieved 19 April 2015.
- ^ Armitage, Laura (30 March 2015). "Westpac to stop Somali money transfers on March 31". Herald Sun. Retrieved 19 April 2015.


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Galaxy Nexus. First phone with Android 4.0, Face Unlock, Android Beam, an amazing HD screen and 4G LTE fast.
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CAC White Diamond Bright White Porcelain Dinnerware
Add Visual Interest to Your Tabletops with White Diamond Bright White China
For a stylish tabletop, take a look at our White Diamond bright white china dinnerware. This line of dishware comes in a brilliant shade of white that is sure to highlight the bright colors of your sauces, vegetables, and garnishes. Each of these plates is shaped like an angled diamond, giving your restaurant a modern look. We carry plates and platters in a variety of dimensions, so you can find the size that works best for your establishment.Also make sure to check out other great items from CAC China.


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Repair shop diagnosed, but doesn't do engine work. Leaks even if engine hasn't run.
How much to replace the front oil seal, and what else should be done then? on 1991 Saturn SC
Get Your Car Fixed at a RepairPal Certified Shop.
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1 answer
go to a shop that does this work. the timing components in the fron of the motor have to be removed. it is a lot of labor for an 8 dollar seal. it pays almost 8 hors in labor.


text:
Housing Trust has interest in schoolOctober 11,2012Staff Report
Little interest has been expressed so far in the former Dana School, with the exception of a visit by Elisabeth Kulas, director of the Housing Trust of Rutland County.
Kulas said Thursday she is interested in the building but hasn't made any decisions yet to move forward with a purchase.
A report by the Rutland School Board's building committee this week also revealed that the property, located in the city's northeast neighborhood, will be listed on the real estate market until January.
The old school, located at 41 East Center St., was most recently the home of the city's Recreation Department but was vacated last year due to safety hazards.
It is listed with Chris Fucci & Associates for $290,000.
Both sales of Dana and the former Watkins schools, which is under contract with the Trust, have to be approved by city voters this coming March.MORE IN This Just InSPRINGFIELD Springfield residents will be asked next month during Market Madness for their... Full StoryPHILADELPHIA Many delegates from Vermont arrived at the Democratic National Convention this... Full StoryI could feel the groan rising inside me as I read the subject line of the press release in my... Full Story
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Latest Local Galleries
Newborn Endangered Zebra Makes Debut At Zoo Miami
Rare Pair Of Tiger Cubs Arrive In Miami
Local Students Attend CBS4 S.T.E.A.M. Day At Marlins ParkThousands of students from across South Florida attended the 11th annual CBS4 S.T.E.A.M. Day Tuesday prior to the Miami Marlins vs. Tampa Bay Rays game at Marlins Park. Previously known as Weather Day, S.T.E.A.M. stands for Science, Technology, Engineering, Art and Math.
Prince Performs During 2007 Super Bowl Halftime Show
Tiger Cub Earns His Stripes In Public Debut With MomA little tiger cub and his first-time mom made their tag-team Zoo Miami debut together Friday.
Tough Tuesday As Two Tornados Rip Through South FloridaIt was a rough morning Tuesday around South Florida as a reported tornado caused damage throughout parts of Miami-Dade and Broward counties.
Scuffle Breaks Out Between Rubio Supporters & #RobotRubio Protesters
Celebrating 50 Years Of Miami Dolphins FootballMonday Dec. 14, CBS4 brings you the best of the Miami Dolphins 50 Seasons Gala honoring the team's legends and best players. Here is an exclusive behind the scenes look in pictures of the big event.
It's A Wrap: Art Basel Miami Beach 2015
Tiger Cub Gaining Weight After Zoo Miami ScareThe highly endangered Sumatran tiger cub that was born at Zoo Miami on November 14th is now being regularly separated from its mother to receive supplemental feedings.
Dolphins Players Join Boys & Girls Club At Jungle Island
Hillsboro Mega Mansion Hits Market For $159 Million
Hot Pursuit Through Two South Florida Counties
Fantasy Fest Ends Sunday After Lavish Night Parade


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iHerb Customer Reviews
Savings of: $0.20 (4% off)
Sorry, this product is no longer in stock.
very bad
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don't try
Posted by 5292267477157119846 on May 13, 2016
i don't like it
taste very bad
Posted by 5067661643840777624 on May 31, 2016
Taste very bad
Great and tastes great for all things!
Posted by 4970728200976808490 on May 08, 2014
Love it and use it most days!
Peanut butter
Posted by 5688082451505768410 on Dec 11, 2014
For zero calories, I'm adjusting to a little bit of this on some celery. I haven't tried it on toast yet. I did mix it with equal parts WF marshmallow fluff (per Pinterest) and that was an improvement on the fluff. (Also want to try frozen WF p.b. balls dipped in WF chocolate dip).
Walden Farms Spreads Peanut
Posted by 4810935003672612742 on Jul 12, 2013
Best with zero carbo bread. Taste good enough for me. I know how pure naural peanut butter taste so good. However, I cannot eat real peanuts as much as I like. Eating limited quantity of real ones might be even worse than giving up eating. I really appreciate Walden Farms.
Posted by 5070483477933953299 on Feb 16, 2014
Great taste, but becomes even better when you add a little pink salt.
great substitute for caloric favorite
Posted by 4641393800911901192 on Mar 11, 2014
I have become addicted to this stuff. I use it everywhere one would use peanut butter - and more. Not identical to peanut butter in taste, but close enough that it is shocking that it is no calories!!!
I love this peanut butter
Posted by 5267450075283821786 on Jan 16, 2014
I just got all my jars yesterday and I'm ready to get my next batch! Most other reviews I found were awful, but I had to see for myself. And I know, it's Not peanut butter, I like it more bc it's guilt free. I think chocolate is better than regular, and I'll try cinnamon/raisin next. If you are worried about the flavor simply use smaller amounts in your other foods. My only wish? I think they should cut some of the sodium out, it's probably the reason why so many people don't like it. But, it's sweet too and I can handle it. This is one of the best prices I found, so I will definitely buy it again!


text:
This Dear Debt letter is from Erin at Red Debted Stepchild. I've had the pleasure of meeting her in person, and she's hilarious and awesome! She's also a finalist for the Plutus Awards' Most Humorous Personal Finance blog! Congrats, girl.
Dear Debt,
It's not you, it's me. No, like seriously. After all, I ran you up. I used you and used you and now it's my turn to feel the pain.
We had a great run — shopping and eating out all the time, throwing caution and delayed gratification to the wind. But what we have isn't healthy. I just don't feel the same way about you anymore.
You didn't do anything wrong. I made choices that put us in a relationship that makes me sick to my stomach. I used you and you let me do it. Even now, I think you were okay, maybe even pleased, with how many times I used you for my own gain. But I can't do this anymore. Frankly, we both deserve better. And as much as it pains me to say this, there is someone else.
I know, I know — I led you on just to fall for something better. You probably thought we'd be together forever. That I would continue to swipe, borrow, and pay interest until we were old and gray. But I met someone. His name is Financial Independence, and he's better for me. He wants me to be happy and free. It's just a healthier situation all around. And not to get any digs in, but he is way more attractive than you.
So now, I take the slow and painful steps to erase you from my life. I know it sounds harsh, but know that I will always remember you. I will remember the good times we had and I will remember the pain I now have to endure as a consequence of all that "fun". Please ignore the mean comments I make about you on my blog, Twitter, and Facebook. I'm just hurting.
I really hope you don't find anyone else, for their sake. You were born to be a bachelor.
A smile in my face appeared while reading this letter of yours to your debt. Don't worry your debt will do fully understand you Erin! Good luck!
Thank you for the kind words, Clarisse!
Oooh I've heard about Mr. Financial Independence! He' super sexy! 🙂
So damn sexy!
Interesting take on this! I wrote something similar a while back (http://www.lesliebeslie.com/2013/02/20/my-tumultuous-relationship-with-discover/) and it's interesting to see the perspective differences.
Thanks, Leslie!
I love the part about 'how you will always remember' – ain't that the truth. I don't think I'll forget the bitter taste of debt anytime soon! Thanks for a fab read Erin!
Glad you enjoyed, Hayley!
You can do it! He's so not worth it!
SOO not worth it :). Glad to be moving on!
Haha, totally awesome letter. Feels like my relationship with carbs. Though I'm not so good about making a clean break 🙂
Thanks, Stefanie :). Come to think of it, this seems to represent my relationship with carbs as well…
I can't wait to meet Mr. Financial Independence! This post made me giggle a little bit…
Haha, glad I could make you giggle!
Well written post, Erin! I love how it almost sounds like a real life relationship with a person. Although I've never really had my run with him, I heard Debt can be a douchebag. Haha.
Thanks, Karen! He's a total douche.
LOVE this, Erin. Well said, my friend. Well said, and I can't help but think of George Costanza when I read it. 🙂
Thanks, Laurie!
Debt level is just astronomical, banks do everything to continue it. It is just crazy wonderland we live in
Crazy stuff, Frugal!
[…] Debt had a great letter from Erin over at Red-Debted Stepchild to her debt. The post is called, It's Not You, It's Me. Great writing and motivation […]


text:
Long Wave Infrared Acousto-Optic Materials:Development of Novel Materials for the Fabrication of LWIR (8-12 micron)Acousto-optic Tunable Filters for I
Award Information
Small Business Information
5024 Campbell Blvd.,, Suite E, Baltimore, MD, 21236
Principal Investigator:
Sudhir Trivedi
Director R&D Division
(410) 668-5800
Director R&D Division
(410) 668-5800
Business Contact:
Diane Murray
Contract Coordinator
(410) 931-7200
Contract Coordinator
(410) 931-7200
Research Institution:
AbstractWe propose to develop novel anisotropic materials that can be used to fabricate acousto-optic tunable filter (AOTF)-based spectral imaging systems in the LWIR (8 to 12 micron) spectral region. AOTF's are very attractive for multispectral and hyperspectral applications such as the detection of targets, backgrounds, and stand-off chemical and biological agents. Tellurium dioxide (TeO2) is the most commonly used AOTF material, and it has a spectral transmission range of 0.35-5.0 micron. However, chemical agent infrared absorption/emission primarily occurs in the 8-12 micron wavelength region. Currently, there is no technologically matured material for AOTF imaging in this wavelength range. Thus, we propose to investigate the mercurous halides (Hg2Cl2 and Hg2Br2) and tellurium (Te) for this purpose. These materials can be processed at relatively low temperatures, are nonhygroscopic, have high acousto-optic figure of merit (M2), high birefringence and relatively high transmission in the 8-12 micron spectral range. This long wave infrared (LWIR) region technology is relevant to the detection of buried mines and is an essential part of achieving the goals set forth in the Army's Third Generation Science and Technology Objective (STO).
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