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Students with Interrupted Formal Education (SIFE)
Who are SIFE?
Students with Interrupted Formal Education (SIFE) are a unique subgroup of English Language Learners (ELLs); they are also sometimes referred to as SLIFE (Students with Limited or Interrupted Formal Education). These students have had limited formal schooling because of political or social conditions in their native countries. Some students arrive from rural areas where schooling beyond the early elementary years is oftentimes nonexistent. Refugee students are often students with interrupted formal education; they sometimes suffer from post-traumatic stress disorder (PTSD) because of horrific experiences in their home country or in the refugee camps.
The SIFE population poses a particular challenge for educators since most students lack the basic skills in their native language or first language (L1) that are required to transfer literacy to English. These students are often placed in classes that correspond with their age-level irrespective of their current level of L1 or second language (L2) proficiency or prior academic skills. Working with this specific population requires teachers to understand the needs of these students by becoming familiar with their native cultures and being trained in basic English-language development methodology, such as sheltered instruction. The Sheltered Instruction Observation Protocol (SIOP) Model is a specific model of sheltered instruction that makes grade-level content (i.e. science, social studies, and math) more accessible for ELLs while promoting English language development. In addition, teachers of SIFE are advised to maintain flexibility during instruction and provide students with high expectations for achievement. It is also important for teachers to work closely with content-area educators (especially when implementing content-based instruction through the SIOP Model) while actively communicating with administrators, parents or guardians, on behalf of their students.
Resources for Educators
Michigan English Language Teaching (ELT) Blog- This blog features an interview with noted authors Andrea DeCapua and Helaine Marshall about their new book Breaking New Ground (please see above), and their thoughts on Students with Limited or Interrupted Formal Education (SLIFE) and the Mutually Adaptive Learning Paradigm (MALP) instructional model: Part 1& Part 2
Yes, Students with Interrupted Formal Education Can Catch Up by Mary Ann ZehrThe writer presents a story about how Students with Interrupted Formal Education Can Catch Up.
Breaking New Ground: Teaching Students with Limited or Interrupted Formal Education in U.S. Secondary Schools by Andrea DeCapua and Helaine Marshall
"Today's public schools are brimming with students who are not only new to English but who also have no schooling or a large break in their schooling. These students create unique challenges for teachers and administrators. Breaking New Ground builds on the introduction to SLIFE presented in Meeting the Needs of Students with Limited or Interrupted Schooling (University of Michigan Press, 2009). Breaking New Ground introduces readers to and engages them in the implementation of an instructional model that has been developed over many years of working with SLIFE. Central to the instructional model and the practices presented in this book is the belief that teaching students with limited or interrupted education should in no way be considered remedial. This book provides a complete presentation of the MALP (Mutually Adaptive Learning Paradigm) instructional model from theory to practice and guides readers to reflect on each element of the model, learn why and how it is essential and effective, and determine how they can use it in their own teaching of SLIFE. Breaking New Ground offers a new understanding of the SLIFE population, introduces a new instructional model, and teaches readers how to address the needs of their students using project-based learning infused with MALP."
Crossing Cultures in the Language Classroom by Andrea DeCapua & Ann Wintergerst
"Crossing Cultures in the Language Classroom links theory with experiential activities that will be helpful for use in teacher training or certificate programs. The goals of this book for the teacher educator are to expand cultural awareness, to acquire an in-depth understanding of what culture is and its relationship to language, and to comprehend and implement observations of cultural similarities and differences. Topics discussed in the book include: culture shock; nonverbal communication; societal roles; and pragmatics. A great in-service workshop text for teacher training programs."
Grammar for Teachers: A Guide to American English for Native and Non-Native Speakers by Andrea DeCapua
"The purpose of Grammar for Teachers is to encourage readers to develop a solid understanding of the use and function of grammatical structures in American English. It approaches grammar from a descriptive rather than a prescriptive approach; however, throughout the book differences between formal and informal language, and spoken and written English are discussed. The book avoids jargon or excessive use of technical terminology. It makes the study of grammar interesting and relevant by presenting grammar in context and by using authentic material from a wide variety of sources."
Mastering the American Accent by Lisa Mojsin, M.A.
"This combination book and audio instructional program is designed to diminish the accents of men and women who speak English as their second language. It will help them speak standard American English with clarity, confidence, and accuracy. Specific exercises concentrate on vowel sounds, problematic consonants such as V, W, B, TH, and the American R, employ correct syllable stress, link words for smoother speech flow, use common word contractions such as won't instead of will not, and more. Additional topics that often confuse ESL students are also discussed and explained. They include distinguishing between casual and formal speech, homophones (for instance, they're and there), recognizing words with silent letters (comb, receipt, and others), and avoiding embarrassing pronunciation mistakes, such as mixing up party and potty. Students are familiarized with many irregular English spelling rules and exceptions, and are shown how such irregularities can contribute to pronunciation errors. A native language guide references problematic accent issues of 13 different language backgrounds. Correct lip and tongue positions for all sounds are discussed in detail. Enclosed with the book are four compact discs that use male and female voices to coach correct American-style pronunciation."
Meeting the Needs of Students with Limited or Interrupted Formal Education by Andrea DeCapua, William Smathers, and Frank Tang
"Today's public schools are brimming with students who are not only new to English but who also have no schooling or a large break in their schooling. These students create unique challenges for teachers and administrators. This handbook is a welcome new resource for secondary teachers and administrators working in areas with burgeoning immigrant populations, as well as ESL instructors and researchers. The book addresses some of the many issues facing the subpopulation of English language learners who have limited or interrupted formal schooling, helping dedicated teachers and administrators to meet this subpopulation's highly specific literacy development and content-area knowledge needs. Meeting the Needs of Students with Limited or Interrupted Schooling is grounded in research but goes beyond it to offer practical guidance on fostering the success of students from limited or interrupted schooling backgrounds by providing student case studies, model programs and classes, and helpful teaching techniques and tips."
Multicultural Partnerships: Involve All Families by Darcy J. Hutchins, Marsha D. Greenfeld, Joyce L. Epstein, Mavis G. Sanders, and Claudia L. Galindo
"This is a must-have, research-based guide for all schools serving culturally diverse elementary and middle grade students and their communities. It's filled with fun, practical, highly effective strategies for raising awareness and engaging all families in their children's education a sure path toward increased student success! Get detailed examples and step-by-step guidelines for implementing successful... Multicultural Family Nights, Workshops for Parents, and Curriculum Connections. Much of the reproducible material is also provided in Spanish - giving educators an even broader reach!"
The SIOP Model Books and Resources This website provides a listing of SIOP Model books and resources that are used to implement the Model in the classroom.
Understanding Your Refugee and Immigrant Students: An Educational, Cultural, and Linguistic Guide by Jeffra Flaitz
"Understanding Your Refugee and Immigrant Students is an excellent resource for educators who work with refugees and immigrants. This well-researched volume-including interviews with students from the profiled countries-provides a wealth of information about the specific schooling traditions, practices, circumstances, and expectations that follow these individuals to their new homes in North America and influence their learning experience. The author has focused her research on 18 countries that contribute a majority of refugees and immigrants to the United States: Afghanistan, Bosnia-Herzegovina, Croatia, the Dominican Republic, Ecuador, El Salvador, Ethiopia, Guatemala, Honduras, India, Iran, Laos, Liberia, Peru, Somalia, Sudan, and the Ukraine. Each country profile features: statistics about the country, a historical synopsis, an overview of the county's official education policy, cultural perspectives, and a problem-solution section containing classroom strategies. The linguistic systems of the languages featured are also included for teacher reference. Also included is information about teacher-student relationships, discipline and class management, and appropriate non-verbal communication. This volume provides invaluable insight into refugee and immigrant students' cultural and educational backgrounds and gives instructors the tools to translate this information into effective classroom strategies."
TESOL Convention 2013
TESOL Convention Presentations:
Addressing the Cultural Dissonance of ELLs with Limited Formal Education
Cultural Perspectives: Students with Limited/Interrupted Education
Designing Projects for ELLs with Limited/Interrupted Formal Education
ELLs with Limited or Interrupted Formal Education: Six Criteria for Success
Preparing Educators to Teach Students with Limited/Interrupted Formal Education
Digital Presentations
ELLs & The SIOP Model This presentation displays information about the SIOP Model and why it should be used with ELLs, especially SIFE.
The SIOP Model Presentation This presentation provides an overview of the SIOP Model and its 8 components; it also discusses how the Model can be used effectively with ELLs.
Students with Interrupted Formal Education A Prezi created by Evan Jenkins that provides information about SIFE.
Guides, Teacher Resources, & Tutorials
A Resource Guide for Educating Refugee Children and Youth in New York State This resource guide provides educators with a basic understanding of refugee students, the reasons their families have left their countries, the resettlement process, and ways to provide a learning environment that welcomes students from all backgrounds.
Free Materials for Teaching English Language Learners This website provides free teaching materials for English to Speakers of Other Languages (ESOL) educators.
Post Traumatic Stress Disorder This booklet provides information about post-traumatic stress disorder (PTSD) and its associated symptoms. It also shares information about what teachers can do in their classrooms to help refugee students who suffer from this.Welcome to the United States: A Guide for New Immigrants An information booklet available in a variety of languages, that contains information about housing, jobs, education, and healthcare in the United States.
Journal & Website Articles
Enabling Academic Success for Secondary Students with Limited Formal Schooling by Catherine E. Walsh A study of the Haitian Literacy Program at Hyde Park High School in Boston. "This publication is for educational practitioners and those in universities, agencies, and organizations who work with schools in designing programs that will enable to academic success of these students [SIFE]."How to Support ELL Students with Interrupted Formal Education (SIFEs)by Kristina Robertson and Susan Lafond
"This article provides a profile of SIFEs and their needs, recommendations of best practices, and examples of the kinds of quality school-wide and classroom support that will accelerate their academic achievement."
Migrant Students: What We Need to Know to Help Them Succeed by Giselle Lundy-PonceAn article about migrant children and the difficulties some migrant families encounter when arriving to the United States. The article also describes the barriers faced by migrant students in regards to achievement and it shares information about Migrant Education Programs (MEP) across the United States. Educators will benefit from learning about how to provide strategies that promote success and will have access to resources recommended by ESL specialists.
Students with Interrupted Formal Education: A Challenge for the New York City Public Schools A report issued by Advocates for Children of New York about SIFE students and the challenges that they face when they are enrolled in public schools.
Professional Organizations
CCER Coordinating Committee for ESOL Resources - A networking organization for local ESOL teachers.
New York State TESOL"Supports professional educators concerned with the education of English language learners at all levels of public and private education in New York State."
TESOL International Association An international association of TESOL educators dedicated to advancing "professional expertise in English language teaching and learning for speakers of other languages worldwide."
Videos & Documentaries
Childhood in Translation A documentary project about how immigrant families are affected by language barriers.
Nickel Street Smiler This is a documentary about a refugee resettlement in Buffalo, New York.
Rain in a Dry Land A documentary about the lives of two Somali Bantu families as they journey from Africa to America.
Refugees in the ELL ClassroomA listing of YouTube videos about teaching refugee students.
Speaking in Tongues A film that focuses on how communication barriers are being addressed in the multilingual America. It is specifically about four kids growing up bilingual in one city.
Starting Small | Teaching Children Tolerance A video about five early childhood education programs in which teachers and children build classroom communities by promoting tolerance. Teachers can order the 'Teaching Tolerance' kit for free.
Videos for Learning about Refugees On this website, there are a variety of interviews with resettled refugees sharing their experiences, challenges, and successes in the United States.
SIFE - The Road to Success from Ken Browne on Vimeo.


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15 Rules For How To Act In Public
I've been noticing some bad behavior, and I think a refresher course is in order, people.
1. 1. Pants should cover the entirety of both cheeks:
4. 2. We love dogs, but not poop:
5. 3. Try dressing appropriately for the occassion:
Ron Artest on Jimmy Kimmel
7. 4. And wear protective clothing when needed:
9. 5. Consider other passengers when traveling in your underwear:
10. 6. Please use a tissue:
11. 7. Couples: quit it with the PDA
12. …If you do, you deserve to have your drink ninja'd.
13. 8. No texting while walking. Here's why:
14. Wait, did you forget Rule #1 about pants covering your cheeks already?
Tattoo reads: "I'm Bossy"
17. Hey pal, what did I say?!
18. 9. Here is an example of doing everything wrong:
19. 10. Public transit is not your chillaxing zone:
20. This violates so many rules of society, it pains me to look at it:
21. 11. I know it's tempting, but please do not hump the statues:
24. 12. I appreciate you're keeping your child from annoying me, but maybe don't do this:
26. 13. Please don't look at porn at the public library (even though it's technically allowed)
27. 14. Don't pee your pants:
28. …or shart:
29. ….But if you do, just own it.
30. 15. Last of all, never, ever, EVER clip your nails in public:
Preview Your Response
In The News Today
- DNC Day 3: President Obama dropped the mic with "Don't boo, vote," and vice presidential nominee Tim Kaine reminded people of their dads 👴
- Prosecutors have dropped remaining charges against Baltimore police officers related to the death of Freddie Gray.
- Twelve states will support Obama's transgender policies in court after other states sued to block the rules.


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Manchester United confirm Giggs departure
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Significantly, smaller Premier League clubs were at the center of much of the first-day trading, reflecting the early release of funds from the new television deal which will send 8 billion pounds ($10.6 billion) into the league over a three-year period. "Normal payments have been brought forward,…Reuters
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text: Share It MainStoriesDavid Beckham dons the jersey of a Special Olympics soccer club David Beckham dons the jersey of a Special Olympics soccer club Andrea Zapata | Apr 24, 2014 | Europe Eurasia: Great Britain Global football icon David Beckham donned the amber and black of Cheshunt FC when he met up with the club's Special Olympics East Herts team. The ex-England captain, who played for Man United, Real Madrid and AC Milan, posed with the players and coaches of the Special Olympics East Herts team. Team coach Clark Presland set up the surprise meeting at Golden Balls' home in Sawbridgeworth. Maria Walker, from Cheshunt, said: "The players thought they were spending the day having team photos when all of a sudden David and Victoria Beckham appeared. "The players were overwhelmed and gave David a signed Cheshunt shirt which he put on straight away." Ms Walker added: "David and Victoria were both fantastic. They posed for photos with the team, signed autographs and asked them lots of questions about the team." Cheshunt Special Olympics East Herts is for players with an intellectual disability and competes in the Herts FA Inclusive League. About Me:I am responsible for communications at SOGB.Related:Read more Read More Stories Making a Difference in India and NepalDavid HircockThank You, Special Olympics LouisianaJude and Paula BernardAgreement in Italy Will Boost Inclusion and RespectMaureen RabbittBelgium Athlete Addresses Experts at European ForumMartha Jo BraycichMy Coaches Were There For MeCarla SimonBond Between Student and Coach Transforms Life of Special Olympics Swimmer at YMCACarolyn GessnerIn Malta, a Proud Mother Shares Her StoryNatasha MicallefAn "Awesome" Secret: The Universal Power of Unified SportsDavid EvangelistaA Unified Gathering Like No OtherNoha Gaballa"We all need to work together and respect each other to be successful"Maureen RabbittMore Schools in the UK want to Play UnifiedMaureen RabbittDo You Have A Story to Share?Share Your Story More Stories


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There has never been ANY proof that people have evolved. You know what I am talking about. We have not lost nor gained anything in the past 2000+ years. There have been no add ons of any kind, NOR have we had any subtractions. We were thought to have evolved from apes, but the problem is there are STILL apes. They haven't evolved into humans, and we have not evolved into anything else.<quoted text>
Negative! In fact if you can fowwow this one; not only have we evolved but at birth that evolution continues on sort of an individual basis.
Next the pinky is moving up in evolution.
The HUMAN brain will never be perfected enough to comprehend the base eight system, as a collective. Base ten is so much easier. Thus the addition of the "pinky finger". Now give this a little thought if you were a lumberjack under the brief base eight system (when human hands had three fingers and a thumb) and you lost a finger in an accident you would be down to two fingers and a thumb or God forbid three fingers.
Imagine people would make fun and call you bird hand. On the other hand, well not exactly, would be a good back scratcher.
I saw the typo up there and thought oh well that's kind of fuddy and left it like it was.
If you can show me any proof that we have evolved, please do post it. I'd like to see that we lost a tail, grew an extra appendange, ect.


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Samuel L. Jackson made an unannounced appearance on "Saturday Night Live" yesterday, and left his mark -- by dropping the F-bomb during "What's Up With That?" The uncensored clip can be viewed at the bottom of this entry.
As Frazier Moore of the AP put it:
"Pretending to be miffed at getting interrupted as a guest on the mock talk show "What Up with That?" Jackson said what sounded very much like an F-bomb, followed by the term sometimes shortened to "b.s."
The studio audience reacted audibly, but Kenan Thompson, who plays a variety show host in the sketch, seemingly ad-libbed: "C'mon, Sam. That costs money!"
Carrie Brownstein of "Portlandia," who also made an appearance in the sketch, mimed zipping her mouth.
In a later tweet, Jackson said that he did not say the full word, and that Thompson was "supposed to cut off" the second obscenity.
But Jackson's slip of the tongue is hardly the first in "SNL" history. Most recently, former cast member Jenny Slate let the word fly on her first episode. Charles Rocket also uttered the word in a 1981 episode.
Hulu's censored version of the clip can be viewed at the top of this entry. The uncensored clip can be viewed below.
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text:
Enchanted Glade Christmas Boxed Card
Charming Enchanted Glade boxed greeting cards feature a softly appealing winter scene with feathered friends and forest creatures. Glossy highlights add shine and touches of glitter add a little extra magic to the snowy picture.
- Inside greeting: "May the beauty of nature fill your heart with peace and joy throughout the year"
- Includes 20 cards and 21 envelopes
- Packaged in a board box with a clear acetate lid
- Printed on quality card stock
- 5" x 7"
Product Details
- 9781441311740
- Manufacturer:
- Peter Pauper Press, Incorporated
- Publication date:
- 07/29/2013
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text:
|Publication number
|Publication type
|Application number
|Publication date
|Oct 27, 1981
|Filing date
|Apr 28, 1980
|Priority date
|Apr 28, 1980
|Also published as
|Publication number
|William P. Long, Jr.
|Original Assignee
|Ici Americas Inc.
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (2), Referenced by (37), Classifications (9)
|External Links: USPTO, USPTO Assignment, Espacenet
The invention is directed to mildew resistant aqueous paint systems containing a minor amount of 1-iodo-substituted lower alkyne urethane as the active fungicide having the generic formula: ##STR2## wherein R is selected from the group consisting of substituted or unsubstituted alkyl, aryl, or alkylaryl groups having from one to not more than 20 carbon atoms and having from one to three linkages corresponding to m, and wherein m and n are whole number integers of 1-3 and which may be the same or different and R' is a H, methyl or alkyl radical which may be the same or different. Such 1-iodo-alkyne urethanes are held in aqueous paint systems as dispersed organic solvent solutions containing selected surfactants and function well as fungicides not only during storage but also after application to surfaces in paint. In particular the invention is directed to stable water emulsifiable concentrates containing the active urethane, organic solvent and surfactant.
Paint systems are liquid, liquefiable, or mastic composition designed for application to a substrate in a thin layer which converts to solid film after application. It usually contains a coloring agent and/or a solid pigment and liquid vehicle. The latter consists of a binder resin which forms a film and a volatile thinner to improve ease of application. Paints of particular interest in this invention are usually characterized as water-based paints wherein water is used as the thinner. A particular type of water-based paint is a heavy bodied thixotropic paint which is free-flowing and easy to manipulate under a brush and sets to a gel within a short time when it is allowed to remain at rest. Because of these qualities a thixotropic paint is less likely to drip from a brush than other types and can be applied in rather thick films without running or sagging.
Some paint binder resins form films by oxidation, polymerization, or cross-linking. Examples are drying oils, epoxies, alkyd resins and polyurethanes. Other binders form films by evaporation of the thinner or by congealing. Examples are polyester, vinyl resins, chlorinated rubber and many polyacrylates and polyethacrylates. Still other binders form a film when particles coalesce from a dispersion of latex or synthetic polymers.
Paints may also contain, as minor constitutents, plastizers, driers, stabilizers, preservatives and anti-foam agents.
Paints usually contain water and solvent insoluble particulate inorganic and organic, natural and synthetic chemical substances which are used to impart color and hiding power to the cured paint film upon application. Primary pigments used to impart hiding power and/or color are titanium dioxide, iron oxide, phthalocyanines, etc. Secondary pigments used as extenders usually contain pigments selected from calcium carbonate, barytes, silica and clay.
Because of their organic component paint systems especially those containing water provide a surface which promotes the growth of fungi such as mildew and mold. These growths take place in stored paint as well as upon the painted surfaces. Fungicides are added to the paint system to control this problem. The above urethanes of 1-iodo substituted lower alkynes which are described in U.S. Pat. No. 3,923,870 are outstanding fungicides for use in paint systems. In certain instances, especially in the case of white or light colored paints, a concomitant discoloration problem associated with the use of the 1-iodo alkyne urethane fungicides arises from either their degradation or unstable by-products occurring with them upon standing in the paint system to form chromophoric materials. This discoloring is not completely understood but it is generally thought to be due to the loss of iodine.
It is generally known that organic epoxides help to stabilize organic iodides by retarding dehydrohalogenation. However, it has been demonstrated that a simple admixture of said 1-iodoalkynyl urethanes (carbamate) and epoxide in paint does not satisfactorily eliminate this discoloration phenomena.
It is the object of this invention to: (1) provide a method for stabilizing monoiodoalkynyl urethane or (carbamate) derivatives used as fungicides in water-base paint systems, (2) provide a stable emulsifiable concentrate of iodo-alkyne urethane fungicides for use in water-base paint systems, and (3) describe water-based paint systems containing iodoalkynyl urethane fungicides which do not discolor severely upon storage and application.
These and other objects of the invention are carried out by the process of first forming an organic solvent solution of the monoiodoalkynyl urethane having the following general formula: ##STR3## wherein R is selected from the group consisting of substituted or unsubstituted alkyl, aryl or alkylaryl groups having from one to not more than 20 carbon atoms and having from one to three linkages corresponding to m, and m and n are whole number integers of from 1-3 which may be the same or different and R' is hydrogen, methyl or alkyl radical having up to 6 carbon atoms which may be the same or different in an organic solvent containing a surfactant to form a concentrate, and thereafter dispersing the organic solvent solution in water or a water based paint system such that said iodo alkyne urethane derivative remains in said solvent so that neither partitions into the aqueous phase of the water based paint system.
Typical synthesis of the active component are demonstrated by the following preparations:
In one process, the 1-iodo substituted alkynyl urethane derivatives are prepared by (a) iodinating the appropriate acetylenic alcohol such as, for example, propargyl alcohol (1-propyn-3-OL) to form 1-iodo-1-propyn-3-OL and (b) carrying out a subsequent reaction with an alkyl isocyanate such as n-butylisocyanate or a polyisocyanate such as hexamethylene diisocyanate to form the corresponding urethane derivative.
Extreme caution should be exercised in handling the intermediate of this reaction as well as the final product to prevent exposure in concentrated form to the eyes and skin. Furthermore, these intermediates are highly vesicant and tend to be mildly explosive. No appreciable hazard exists in the dilutions normally employed in paint formulations.
The iodination is conveniently carried out with sodium hypochlorite and an alkali metal iodide. A small molar excess of sodium or potassium iodide, previously dissolved in water, is added to the reaction mixture prior to the addition of hypochlorite. The product is extracted with ether and dried with anhydrous sodium sulfate afterwhich the ether is allowed to evaporate leaving the iodo intermediate product.
The preparation of the urethane derivative may be carried out in solvent such as tetrahydrofuran solution of the iodoalkynol intermediate using a slight stoichiometric excess of isocyanate and small amounts of triethylamine and dibutyltin dilaurate as a catalyst. The reaction mixture is placed in a reaction jar, tightly capped, and heated to 60� C. for 24 hours and thereafter dried to remove solvent or purified by solvent extraction techniques, precipitated and filtered. Suitable product is made by reacting the monoiodoalkynol with a stoichimetric amount of liquid isocyanate at elevated temperatures in a closed system.
For example, methyl, butyl, cyclohexyl, phenyl, octadecyl, t-butyl, allyl, dodecyl, octyl, and hexyl isocyanates as well as hexamethylene diisocyanate have been reacted with 3 hydroxy-1-iodopropyne to make the urethanes. Furthermore, butyl, methyl, and hexyl isocyanates have been reacted with 4 hydroxy-1-iodobutyne to produce urethanes which can be stabilized. Similary, 3,3-dimethyl-3-hydroxy-1-iodopropyne derivatives of urethanes (carbamates) are prepared by reacting the isocyanates of methyl, butyl, cyclohexyl, phenyl, octadecyl, t-butyl, allyl, dodecyl, octyl and hexyl isocyanate.
An alternate process for manufacturing the above-described active involves reacting an alkynol having the formula: HC.tbd.C(CR'2)n --OH with an isocyanate having the formula R(NCO)m to give a carbamate of the formula: [HC.tbd.C(CR'2)n --OCONH--]m R followed by iodination of the resulting carbamate.
The first stage of this process is carried out by reacting the alkynol with isocyanate in a solvent solution and a catalyst which promotes the formation of the carbamate linkage. The temperature of the reaction mix is moderated by adding one component to the other. Suitable inert solvents are esters such as ethylacetate, butylacetate and 2-ethoxyethylacetate, ketone such as methylethylketone, methylisobutylketone, cyclohexanone and 4-methoxy-4-methyl-pentane-2-one, hydrocarbons such as toluene and xylene, halogenated hard carbons such as trichloroethylene, methylenechloride, 1,1,1-trichloroethane, and tetrachloroethylene and polar aprotic solvents such as dimethylformamide and dimethylacetamide.
The resultant carbamate is isolated from the reaction mixture by conventional means.
In the second stage iodination is carried out in an aqueous media with sodium hypochloride and alkyl metal iodide or sodium hypochloride, an alkyl metal hydroxide and iodine. The product is extracted from the aqueous media with a water immiscible organic solvent for example toluene.
Alternatively, the iodination step may be carried out by treating an aqueous emulsion or dispersion of the alkynol carbamate formed in the first step with an iodination agent. The dispersion or emulsion is preferable formed and stabilized with aid of surfactant so as to maintain the dispersed phase in a finally divided state throughout the reaction.
As suitable surfactants may be used protective colloids such as hydrolyzed or partially hydrolyzed vinylacetates, phase transfer catalysts such as acetyltrimethyl ammonium bromide, and dispersing agents sodium salt of a condensate formaldehyde and naphthalene sulfonic acid and emmulsifying agents such as oxyethylated nonyl phenols.
A monoiodopropynyl N,n-butylcarbamate is commercially available formulation and sold under the trademark Troysan Polyphase Antimildew by Troy Chemical Corp. of Newark, N.J.
A commercially available fungicide (Troysan Polyphase Antimildew) is placed in solution and comprises 40% by weight monoiodo propynyl N,n-butylcarbamate in 60% solvent blend which comprises eight parts propylene glycol and two parts diacetone alcohol.
In a closed container stoichiometric quantities of n-butyl isocyanate is reacted with 3-hydroxy-1-iodopropyne and a catalytic amount of dibutyltin dilaurate and heated to a temperature of 60�-75� C. for a period of 24 hours.
Propargyl alcohol is reacted with a slight excess of n-butyl isocyanate at 20�-25� C. in the presence of dibutyltin dilaurate as catalyst. The resulting propynyl-N-n-butylcarbamate is then iodinated in an aqueous alkaline media with potassium iodide and sodium hypochlorate at a temperature no greater than 10� C. in the presence of a protective colloid (Moviol 3:83). The product which is isolated by filtration followed by washing with water is held as a water-wet paste containing about 35-40% by weight of dry monoiodo propynyl-N-n-butylcarbamate for formulation.
The above-described monoiodoalkynyl urethane (carbamate) derivatives are stabilized by preparing a solution in organic solvents wherein said urethane derivatives are soluble to at least 50 parts per 100 parts solvent by weight. Concentrations of 15-60 percent by weight active are preferred. Aromatic solvents such as xylene, toluene, benzene, mixtures of isomeric trimethyl benzene, ethyl acetate, amyl acetate, butyl acetate, methyl isobutyl ketone, methyl cyclohexanone, monoethylether of ethylene glycol, ethylene glycol monoethylether acetate, ethylene glycol monobutyl ether acetate, and butyl cellosolve acetate are preferred due to their solvency properties for said urethane compounds and their water miscibility. In general aromatic, hydrocarbon, ketone, alcohol, naphthenic, acetate, or ether based substantially water immiscible solvents having water solubility in the range of 0.1-20 parts/100 will suffice. Solvents having a flash point greater than 35� C. are preferred.
To the solvent solution may be added up to 20.0 percent by weight of an organic epoxide stabilizer which is believed to function as a hydrogen iodide acceptor. Satisfactory epoxy based acid scavengers include, but are not limited to, epoxides of vegetable oils/fats, aliphatic resins, cycloaliphatic resins, and aryl resins. Also epoxy derivatives such as propylene oxide, styrene oxide, butylene oxide, and epichlorohydrin can be used. In particular such epoxides include: diglycidylether of bisphenol A; tetraglycidylether of tetraphenylethane; and aliphatic glycidylethers containing primarily n-dodecyl, n-tetradecyl and cycloheyxl alkyl groups such as 3,4 epoxy cyclohexylmethyl-3,4 epoxy cyclohexane carboxylate.
The water immiscible solution must also contain 5-25 percent by weight surfactant which provides for and stabilizes a homogenous dispersion of said water immiscible solution throughout the aqueous phase and the paint. The surfactant can be entirely nonionic, entirely ionic or combinations of nonionic/ionic. Satisfactory surfactants include, but are not limited to, the following: ethoxylated fatty acids, ethoxylated linear fatty alcohols, ethoxylated fatty amines, ethoxylated sorbitan fatty acid esters, ethoxylated alkylphenols, ethoxylated synthetic aliphatic alcohols, akyl/aryl sulfonates, and their metal salts, ethoxylated castor oil, block copolymers of ethylene and propylene oxides, and mixed ethylene oxide (EO) and propylene oxide (PO) alkoxylates of n-butanol. Such suitable surfactant or blends having a hydrophilic/lipophilic balance (HLB)* in the range of 10-17.1.
Suitable surfactants and surfactant blends are determined by preparing concentrates having 40 parts of the iodoalkynyl urethane active, 35 parts solvent, 15 parts of the surfactant and 10 parts epoxide stabilizer. To test this concentrate, 10 parts are mixed with 100 parts water and shaken to form a milky dispersion. The dispersion is considered preferred if no separation occurs for 7 days upon standing at room temperature.
Water immiscible concentrates of the invention may be stored and added to aqueous paint systems at the time of their manufacture in concentrations of 0.1-4.0 percent by weight based on the weight of the formulated paint.
The following examples are presented to demonstrate, but not limit, operable compositions of the invention. All proportions refer to parts or percent by weight.
An emulsifiable fungicide concentrate is prepared by dissolving 40 parts of 1-iodopropynyl-N,n-butyl carbamate (Preparation B); 15 parts of an emulsifier blend, and 10 parts of epoxy stabilizer (epoxy resin sold by Union Carbide Inc. under the trademark Bakelite ERL-4221), into 35 parts of aromatic solvent (sold under the trademark Tenneco 100-500 which may be further defined as a mixture of alkylated benzene containing primarily xylenes and trimethyl benzene having the following typical properties: Specific gravity 0.870, flash point 37.5� C., boiling point 145� C.). The epoxy stabilizer, 3,4-epoxy cyclohexyl methyl-3,4-epoxy cyclohexane carboxylate, is cycloaliphatic in nature and has the following typical properties: specific gravity 1.175, boiling point--354� C., viscosity 350-450 cps/25� C. The emulsifier blend consists of 27.4 wt. % calcium dodecylbenzenesulfonate, 11 wt. % polyoxyethylene (POE) (11) nonyphenol, 28.8 wt. % polyoxyethylene (POE) (40) castor oil, 6.0 wt. % polyoxyethylene (POE) (30) nonylphenol, and 26.8 wt. % aromatic solvent diluent.
An emulsifiable concentrate is prepared by placing 55.19 parts of an active wet paste described in Preparation C containing 36.9 parts by weight dry solids in a round bottom flask containing 18.61 parts by weight water, 20 parts by weight of methylcyclohexanone, 20 parts by weight of Aromasol H (a mixture of isomeric trimethylbenzene and higher boiling aromatic compounds). The flask is fitted with a water condenser, a thermometer and a stirrer. The contents of the flask are heated to 30� C. with stirring and are stirred at this temperature for 30 minutes. 4.13 Parts by weight of concentrated hydrochloric acid are added and the mixture stirred at 30� C. for a period of 15 minutes. Stirring is then stopped and the mixture transferred to a separating funnel and allowed to stand for one hour. The mixture separates into two layers the lower of which run off into a beaker. The yield of the organic solution is 77.5 parts by weight. 5 Parts by weight of epoxy resin ERL 4221, 20 parts by weight of Synperonic NP 13 (polyoxyethylene(13)nonylphenol) are then added and the concentrate is stirred for an additional five minutes. An emulsifiable concentrate containing 33.8% by weight active is produced.
Emulsifiable concentrates containing 15-60% by weight of the iodine containing carbamate active, 5-25% by weight surfactant, and 20-80% by weight water-immiscible solvent are expected to produce results similar to those obtained in the following examples when applied to paint formulations. In addition the concentrate may contain 0.5-25% by weight stabilizer.
In a similar manner additional examples of the invention were prepared having compositions described in Table 1.
Paint compositions of Table II and a commerical white paint containing no fungicide (duPont Lucite House Paint Batch 10752-174) having no fungicide were dosed with varying amounts of active concentrates prepared according to previous Examples.
Films of 3 mil thickness of each test paint were drawn down on Leneta charts (or other substrates) and allowed to dry. Readings (X, Y and Z coordinates) were made on each chart using a Gardner Reflectometer Model No. XL10-CPM and the Yellowness Index (YI) calculated as follows: ##EQU1##
The paints were then held in sealed containers at 60� C. for 7 days in a dark oven to accelerate discoloration. Films of 3 mil thickness of each these heated paints were also prepared and the Yellowness Index determined. The degree of discoloration was reported as ΔYI=(YI 7th day)-(YI initial). Results for these yellowing tests are listed in Table III.
In order to demonstrate the effect of paint thickness, films having thicknesses of 3,6 and 9 mils were coated on sealed and unsealed Lenata charts. Wet 6 mil coatings were placed over unprimed wood or wood primed with Latex and alkyd paints. duPont acrylic Latex paint number 10752-174 was dosed with 1% Preparation A; 1% Preparation A containing 2.0% of the epoxide stabilizer ERL-4221; and 1% of the concentrate of Ex. 1. The Yellowness Index was determined on the freshly coated substrates and after the painted films were heated at 60� C. for 7 days in a dark oven. Results are tabulated in Table IV.
TABLE I__________________________________________________________________________COMPOSITION OF EMULSIFIABLE CONCENTRATESExample3-iodo propynyl Water immiscible EpoxyNo. n-butyl carbamate solvent Stabilizer Surfactant Blend__________________________________________________________________________2 50 parts 25 parts 10 parts 4.1 parts calcium dodecyl benzene Tenneco 500/100 Bakelite ERL-4221 sulfonate 1.6 parts POE (11) nonylphenol 4.3 parts POE (40) castor oil 0.9 parts POE (30) nonylphenol 4.1 parts xylene diluent3 55 parts 20 parts 10 parts Same as example 2 Tenneco 500/100 Bakelite ERL-42214 60 parts 15 parts 10 parts Same as example 25 40 parts 45 parts NONE Same as example 2 Tenneco 500/1006 40 parts 40 parts 5 parts Same as example 2 Tenneco 500/100 Bakelite ERL-42217 40 parts 35 parts 10 parts Same as example 2 Tenneco 500/100 Epoxide No. 78 40 parts 35 parts 10 parts Same as example 2 Tenneco 500/100 Epoxide No. 89 40 parts 30 parts 10 parts 3.26 parts calcium dodecyl benzene Butyl Acetate Bakelite ERL-4221 sulfonate 1.25 parts POE (11) nonylphenol 1.2 parts POE (40) castor oil .25 parts POE (30) nonylphenol 5.1 parts PO/EO alkoxylates of n-butonol 3.94 parts Xylene diluent10 40 parts 35 parts 10 parts 3.36 parts calcium dodecyl benzene Ethyl Acetate Bakelite ERL-4221 sulfonate 1.30 parts POE (11) nonylphenol 0.60 parts POE (40) castor oil 0.12 parts POE (30) nonylphenol 5.74 parts PO/EO alkoxylates of n-butanol 3.88 parts xylene diluent11 40 parts 35 parts 10 parts 3.45 parts calcium dodecyl benzene Cellosolve Bakelite ERL-4221 sulfonate Acetate 6.40 parts PO/EO alkoxylate of n-butanol 1.35 parts POE (11) nonylphenol 3.80 parts xylene solvent12 40 parts 45 parts 10 parts 1.36 parts calcium dodecyl benzene Tenneco 500/100 Bakelite ERL-4221 sulfonate 0.54 parts POE (11) nonylphenol 1.44 parts POE (40) castor oil 0.30 parts POE (30) nonylphenol 1.35 parts xylene diluent13 40 parts 40 parts 10 parts 2.73 parts calcium dodecyl benzene Tenneco 500/100 Bakelite ERL-4221 sulfonate 1.00 parts POE (11) nonylphenol 2.87 parts POE (40) castor oil 0.60 parts POE (30) nonylphenol 2.74 parts xylene diluent14 40 parts 35 parts 10 parts 3.45 parts calcium dodecyl benzene Tenneco 500/100 Bakelite ERL-4221 sulfonate - 1.35 parts POE (11) nonylphenol 6.40 parts PO/EO alkoxylate of n-butanol 3.8 parts xylene diluent15 40 parts 35 parts 10 parts 10.5 parts POE (10) nonylphenol Tenneco 500/100 Bakelite ERL-4221 3.0 parts calcium dodecyl benzene sulfonate 1.5 parts propanol diluent16 40 parts 35 parts 10 parts 7.5 parts POE (30) nonylphenol Tenneco 500/100 Bakelite ERL-4221 5.0 parts calcium dodecyl benzene sulfonate 2.5 parts propanol diluent17 40 parts 35 parts 10 parts 9.0 parts POE (40) castor oil Tenneco 500/100 Bakelite ERL-4221 4.0 parts calcium dodecyl benzene sulfonate 2.0 parts propanol diluent18 40 parts 35 parts 10 parts 7.5 parts isopropyl amine dodecyl Tenneco 500/100 Bakelite ERL-4221 benzene sulfonate 7.5 parts POE (40) castor oil19 40 parts 35 parts 10 parts 7.5 parts sorbitan mono oleate Tenneco 500/100 Bakelite ERL-4221 7.5 parts isopropyl amine dodecyl benzene sulfonate20 40 parts 35 parts 10 parts 7.5 parts POE (5) nonylphenol Tenneco 500/100 Bakelite ERL-4221 7.5 parts POE (10) nonylphenol21 40 parts 35 parts 10 parts 7.5 parts POE (6) tridecyl alcohol Tenneco 500/100 Bakelite ERL-4221 7.5 parts POE (15) tridecyl__________________________________________________________________________ alcohol
TABLE II______________________________________Composition of Latex Paints(% by weight) Compo- Compo- Compo- sition A sition B sition C (100% (Modified (PolyvinylIngredients acrylic) acrylic) Acetate)______________________________________Hydroxyethyl Cellulose 0.2 0.3 0.5Water 14.4 17.3 33.1No salt polymericcarboxylic acid 1.3 1.3 --Alkyl Aryl polyether 0.2 0.2 --Ethylene glycol 2.1 2.2 1.3Titanium dioxide 21.2 21.2 17.8Magnesium silicate 17.3 17.3 12.3Acrylic Latex 29.1 33.2 --Polyvinyl Acetate Emulsion -- -- 25.0Tributyl Phosphate 1.0 1.0 --Propylene glycol 2.9 2.9 --Ammonium hydroxide 0.2 0.2 --Defoamer 0.1 0.1 --Cobalt Naphthenate -- 0.1 --Lead Naphthenate -- 0.1 --Linseed Oil Alkyd -- 2.6 --Silica -- -- 2.7Aluminum Silicate -- -- 4.5Alkyl Aryl Sulfonate -- -- 0.3Ethoxylated Nonyl Phenol -- -- 0.3Monoethylether ofDiethylene glycol -- -- 2.2______________________________________
TABLE III______________________________________Accelerated Yellowing Tests Degree of Dis- color- ationExample No. Paint % Concentrate (ΔYI)______________________________________Control A (du Pont none 0.3Control B 10752-174) 1% Prep. A 7.4Control C (du Pont 1% Prep. A 10752-174) containing 2% ERL-4221 8.7 22 (du Pont 1% of Example 1 3.4 10752-174) 23 (du Pont 1% of Example 9 2.7 10752-174) 24 (du Pont 1% of Example 10 2.2 10752-174) 25 (du Pont 1% of Example 11 2.2 10752-174) 26 (du Pont 1% of Example 6 0.4 10752-174) 27 (du Pont 1% of Example 5 0.7 10752-174)Control D Composition A none -0.1Control E " 1% of Prep. A 9.6Control F " 1% of Prep. A contg. 9% of ERL-4221 10.0 28 " 1% of Example 1 2.4Control G Composition A none -0.2Control H " 0.5% of Prep. A 0.7Control I " 1.0% of Prep. A 2.7Control J " 2.0% of Prep. A 6.0 29 " 0.5% of Example 1 0.3 30 " 1.0% of Example 1 0.4 31 " 2.0% of Example 1 1.0 32 Composition C 1.0% of Example 1 0.5Control K Composition B none -0.3Control L " 1% Prep. A 15.3Control N " 1% Prep. A Contg. 9% ERL-4221 4.2 33 " 1% Example 1 0.0______________________________________
TABLE IV______________________________________Discoloration vs. Substrate Porosity and Film Thickness Un- Sealed sealed Latex Alkyd Unprimed Chart Chart Primed Primed WoodMildewcide (Degree of Discoloration Δ YI)______________________________________3 Mil WetFilm Thickness:None (Control) 0.8 0.61% Prep. A 7.1 2.71% Prep. A/2% 8.0 2.2ERL-42211% Example 1 3.4 0.96 Mil WetFilm Thickness:None (Control)* 0.5 0.5 0.5 0.2 0.01% Prep. A 8.6 2.5 7.4 10.0 2.21% Prep. A/2% 9.7 2.2 4.9 9.2 3.7ERL-42211% Example 1 5.5 0.6 1.7 2.5 1.29 Mil WetFilm Thickness:None (Control)* 0.3 0.41% Prep. A 10.0 3.51% Prep. A/2% 10.3 5.0ERL-42211% Example 1 4.4 1.3______________________________________ *duPont Acrylic Latex Paint No. 10752174
Coded samples of duPont latex (acrylic) house paint containing the concentrate of the invention were submitted to a commercial testing laboratory for discoloration tests. Films of the paints were prepared and subjected to a proprietary simulated outside exposure procedure. The films were rated (naked eye) as follows:
______________________________________Concentrate Rating______________________________________None (Control) No discoloration1.0% Example 1 Slight yellowing, such discoloration on houses would require a trained observer to detect.0.5% Example 1 Very slight yellowing, such discoloration on houses would be difficult for a trained observer to detect.______________________________________
Paint formulations having similar concentrations of unemulsified active with or without stabilizer which were subjected to the same test exposure underwent heavy yellowing.
|Cited Patent
|Filing date
|Publication date
|Dec 17, 1973
|Sep 16, 1975
|Du Pont
|Paint fungicide
|Jul 11, 1973
|Dec 2, 1975
|Troy Chemical Corp
|Urethanes of 1-halogen substituted alkynes
|Citing Patent
|Filing date
|Publication date
|Oct 5, 1988
|Apr 10, 1990
|Nalco Chemical Company
|Method of controlling algae growth
|Jul 26, 1993
|Mar 7, 1995
|Occidental Chemical Corporation
|Reducing decomposition of acetates
|Jul 8, 1994
|Sep 10, 1996
|Gruening; Rainer
|Process for preparing iodoalkynylcarbamates having a low tendency of yellowing when exposed to light
|Nov 17, 1993
|Nov 5, 1996
|Master Coating Technologies, Inc.
|Method of producing a multi-patterned coating
|Oct 30, 1996
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|Troy Corporation
|Aqueous synthesis of iodopropargyl carbamate
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|Aug 17, 1999
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|Stabilized antimicrobial compositions containing halopropynyl compounds
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|May 9, 2000
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|Stabilized composition containing halopropynyl compounds
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|Sep 19, 2000
|Creanova Inc.
|Biocidal composition
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|Stabilized antimicrobial compositions containing halopropynyl compounds and benzylidene camphors
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|H&S Chemical Company, Inc.
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|May 17, 2011
|Lanxess Deutschland Gmbh
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|Mar 25, 2010
|Dec 30, 2014
|Lanxess Deutschland Gmbh
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|Mar 29, 2016
|Lanxess Deutschland Gmbh
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|Lanxess Deutschland Gmbh
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|Aug 4, 2003
|Feb 10, 2005
|Schneider David J.
|Process for the synthesis of iodopropynyl butylcarbamate in an aqueous solution of a suitable surfactant
|Feb 21, 2007
|Jul 30, 2009
|Lanxess Deutschland Gmbh
|Stabilization of iodine-containing biocides by means of special azole compounds
|May 19, 2008
|Jun 17, 2010
|Lanxess Deutschland Gmbh
|Dispersions containing iodopropargyl compounds
|Apr 1, 2009
|Oct 6, 2010
|LANXESS Deutschland GmbH
|Stabilisation of compounds containing iodine
|Jun 30, 2009
|Jan 5, 2011
|LANXESS Deutschland GmbH
|Heterocyclic 3-ring connections and polymers containing iodine compounds
|Dec 10, 2010
|Jun 13, 2012
|LANXESS Deutschland GmbH
|Formulations containing stabilised compounds containing iodine
|Nov 16, 2011
|May 22, 2013
|Lanxess Deutschland GmbH
|Stabilisation of iodine containing compounds with polymers containing nitrogen
|Oct 29, 1992
|May 13, 1993
|New Tech Industrial Products, Inc.
|Multiple effect applicator and method
|Dec 11, 1998
|Jun 17, 1999
|Troy Technology Corporation, Inc.
|Stabilized composition containing halopropynyl compounds
|May 14, 1999
|Nov 25, 1999
|Troy Technology Corporation, Inc.
|Stabilized antimicrobial compositions containing halopropynyl compounds
|Mar 22, 2005
|Sep 29, 2005
|Valtion Teknillinen Tutkimuskeskus
|Reactive coalescent agents
|Mar 25, 2010
|Oct 7, 2010
|Lanxess Deutschland Gmbh
|Stabilization of compounds comprising iodine
|Jun 11, 2010
|Dec 16, 2010
|Lanxess Deutschland Gmbh
|Inorganic carrier materials containing nitrogen
|Jun 28, 2010
|Jan 6, 2011
|Lanxess Deutschland Gmbh
|Polymers containing heterocyclic 3-ring compounds and iodine-containing compounds
|Dec 9, 2011
|Jun 14, 2012
|Lanxess Deutschland Gmbh
|Biocide microcapsule formulations containing stabilised iodine-containing compounds
|Nov 15, 2012
|May 23, 2013
|Lanxess Deutschland Gmbh
|Stabilization of compounds containing iodine having polymers comprising nitrogen
|Mar 26, 2013
|Oct 3, 2013
|Lanxess Deutschland Gmbh
|Stable compositions of thiabendazole and iodine-containing fungicides
|Mar 26, 2013
|Oct 3, 2013
|Lanxess Deutschland Gmbh
|Fungicide formulations for plasticized pvc
|U.S. Classification
|524/200, 523/122, 106/18.32
|International Classification
|Cooperative Classification
|European Classification


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Date: 1932-03-04
Description: Exterior of the J.R. Licari & Son garage, located at 767 West Washington Avenue. The view also includes Trotters Billiards, located at 763 West Washington...
Date: 1901-12 ca.
Description: Syl and aunt Helen lean on a wooden hand rail on Gully bridge. Behind them is a lake with ice and snow. A large factory-like building is visible in the dis...
Date: 1922 ca.
Description: Downed wires and broken tree limbs mar the scene in front of the First Congregational Church at 131 6th Avenue.
Date: 1900 ca.
Description: Elevated view of Nelson Dewey home with snow on the ground.
Date: 1910 ca.
Description: View across street towards the north side of the 200 block of State Street between Fairchild and Henry Streets. This side was free of saloons. The south si...
Date: 1870 ca.
Description: Elevated view of Chippewa Falls during the winter.
Date: date unknown
Description: Elevated view of town. The tallest building is the Jackson County Court House, the church near it is the Baptist Church, and the church across the street i...
Date: 1935 before
Description: Elevated view of front of City Hall. Several buildings and streets surround City Hall, with cars on all the roads. Snow is on top of the buildings and the...
Date: 1910
Description: Winter scene of an unplowed, snowy Butler Street, Madison, Wisconsin, with tire tracks and snow-covered trees.
Date: 1904 ca.
Description: Five men stand on or nearby a sled loaded with logs and pulled by two horses at the landing at Hein's logging camp. There is snow on the ground.
Description: Two people hug on the left while four other people picket on the sidewalk on the right. Two women carry signs, with one sign reading: "Reclaim Missile Silo...
Date: 1969-03-28
Description: Stone bridge over Two Mile Creek in Wood County. The creek is not frozen although the ground is snow-covered.
Date: 1912 ca.
Description: International Model F (or 31) truck owned by the American Express Company. The truck is parked in the snow outside the company office. A man wearing a hat...
Date: 1947-01-30
Description: Winter scene with Dave Brown (left), and Bill Pedder shoveling out cars parked on South Carroll Street on the Capitol Square, charging $1.50 and up.
Date: 1935 ca.
Description: Holiday card of four children flying in an airplane with Christmas trees painted on the wings and bells on the tail. They are flying over a snow-covered la...
Date: 1955 ca.
Description: Winter scene with Mark Mueller, the photographer's son standing ankle deep in snow with a dog, and smiling as the snow continues to fall. The family was sl...
Date: 1957-03-01
Description: Winter scene with car driving down a road, seen from the back, with very tall trees on either side of the road.
Caption: "The same road as on the opposite...
Date: 1953
Description: Exterior of hospital in winter, with four cars parked in front.
Date: 1922-02-22
Description: View of an ice covered street, trees and houses. Text on back of photograph reads: "Sleet storm of February 22nd & 23rd/22. Looking west from street inters...
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The hotel is very clean with the amenities that one wants for a nice getaway (free wifi, pool, hot tub and fridge in the room.).
The hotel is roughly a mile away from DLP (Downtown Lake Placid) but for us this was not an issue at all. Hotel staff were excellent at recommending retaurants.
Prices and the customer service are great. Small renovations going on in dining room area and the hotel staff did everything they could to make this inconvenience as minor as possible, Kudos!
- Reservation Options:
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- Also Known As:
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Capitol Hill Critics Second-Guess Agencies Using...
Loss of Lives in Clinical Trials...
Clinical-Style Validation, Regulation, and Quality Control...
Researchers Now Have a Myriad of...
Lonza selected Cellectis bioresearch to help develop and commercialize a bioengineered cell line. Cellectis will use its meganuclease technology to deactivate the glutamine synthetase gene in Lonza's host cell line CHOK1SV.
Lonza's GS System™ technology uses selection via glutamine metabolism to generate high-yielding, stable cell lines. The firm claims hundreds of cell lines using the GS System have already been created to generate therapeutic proteins for clinical trials and commercial supply.
It maintains removal of the cell-based GS activity will enable further improvements to the selection process for creating recombinant cell lines. Cellectis specializes in the development of research tools for genome customization based on its meganuclease technology. Commercial products include its cGPS® System and cGPS Custom System kits for engineering specific cell lines.
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MDMA (commonly known as the empathogen "ecstasy") is classified as a Schedule 1 drug, which is reserved for compounds with no accepted medical use and a high abuse potential. Two researchers from Stanford, however, call for a rigorous scientific exploration of MDMA's effects to identify precisely how the drug works, the data from which could be used to develop therapeutic compounds.Do you agree that ecstasy should be studied for its potential therapeutic benefits?
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April 20, 2016 - Product News
The Garmin 670 will now support the Teletrac Navman Drive suite of apps with routing, fleet management and compliance features for drivers.
Tags: GPS, Garmin, Fleet Management Software, Teletrac, Mobile Devices, Mobile Apps
May 1, 2013 - Industry News
NexTraq has announced that it will support the Garmin fleet 590 navigation device.
Tags: Garmin, NexTraq
We offer e-newsletters that deliver targeted news and information for the entire fleet industry.
The expert, Brian Fletcher from Eaton, will answer your questions
Kenworth Launches Essentials App for Mobile Devices
EZ Drain Valve Made For Vaporizer Drain Systems
VeeBoards Corner Protectors are Stackable
TomTom Partnership Adds Real-Time Accounting


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Westbury theater's face-lift
The old Space movie theater is opening after many years of renovation. Videojournalist: Alejandra Villa (Sept. 16, 2013)
Newsday.com now uses Facebook for our comment boards. Please read our guidelines and connect your Facebook account to comment.
Cancer survivors' problem inspires a solution Bellone gives distinguished service medal to woman competing in Olympics Southold students developing a love of gardening North Massapequa house fire kills 1 at scene, pedestrian injured in nearby accident involving responders Suffolk DA: 14 arrested in drug bust Still feeling the pain at anniversary of TWA Flight 800 Pro-police rally held in Selden Black Lives Matter marches held in East Hampton, Bridgehampton Latino Long Islanders protest Rep. Zeldin How to explore East End like a local Nun from LI reported missing in Austria Surveillance video shows car crashing into Patchogue restaurant


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If you're like me, you spend WAYYYY too much time in front of a computer. I think it would be great to have a monthly get together at a bar or pub to just get to know each other, have a brew, and yes, talk about the business. Real human interaction, in other words. Repeats the last Tuesday of every month.
Starting September 24th we will be changing venues to Romtoms, on the east side of the bridge at Burnside and 6th St. We hope there will be more room and it will be easier to find the rest of us. We look forward to seeing everyone.
If you can't find us inside look for us out in the back we may be enjoying the sunshine and the beautiful open patio.
Hello everyone, My business partner and I am starting a software development company and are looking for individuals who might be interested in helping us get a website up and running. We are also interested in a possible software developer to get a working prototype designed for investors. If you are interested in knowing more message me or make sure you introduce yourself when I am there.
Luke Krieger
Krieger Technologies
0 · November 25, 2013
I've been meaning to make it out to these for too long. I'll see everybody next Tuesday.
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Timex 80 Colorblock
Make your daily wear pop with the colorful Timex 80 Colorblock wristwatch. The case, strap, clasps and buckles of this retro digital watch come in different colors. Available in four 80's-inspired color combos.
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One-hole Kitchen Faucet with lever handle and swivel spout 8.7" Spout Projection 11.4" Height 10.4" Aerator Clearance Solid brass
One-hole, high-arch Kitchen Faucet with lever handle. Features swivel spout Solid brass 14.2" H x 7.9" Spout Projection x 10.2" Aerator Clearance
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Add elegance to your bar with the exquisite Marseille Bar Faucet by Elements of Design. This bar faucet features a J-spout with 8.5" of spout clearance which allows for more space for filling or cleaning those large glasses. The bar faucet uses a 3-hole centerset installation and is constructed from solid brass to handle rigorous use. Uses ceramic disc cartridges for drip and worry free performance Solid brass construction Max water flow rate of 2.2 ...


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Entitled Horsing Around with the Arts, the Shelby Regional Arts Council will host for the first time an art show that will run in conjunction with the Shelbyville Horse Show Jubilee.
"This is going to be a fun event and a fun space for people to visit," said Eilene Collins with Shelby Main Street, who is coordinating the Jubilee events.
On Saturday, July 30, amidst the usual excitement and fun on Main Street, guests will have an opportunity to slow down and take in the artistic talent of our community.
With temperatures lingering in the 90s, summer is heating up and so are the some summer-related retail items. Rural King assistant manager Kim Matthews said they have been selling tons of fans and lawn-related items.
She said sales have remained high.
Sales may not be so hot across the map, however. CNNMoney reported that retail sales in June fell .3 percent from May. This data, they noted, is surprising because April and May were also both slow retail seasons, despite the expectation that sales would bounce back after a slow winter.
In the wake of the grave tragedies over the past few weeks, one Shelby County resident has taken it upon himself to reunify the community.
A corrections officer at the Kentucky Correctional Institute for Women in Pewee Valley has been arrested on sex abuse and related charges of an inmate, police say.
Kentucky State Police spokesperson Bernice Napier said Demar I. Jones, 30, of Lexington, was arrested Tuesday and charged with one count of first-degree sexual abuse and second-degree official misconduct.
The arrest came after an investigation into the matter, said Napier.
All farmers love rain, but too much of a good thing is not good for crops, they say.
"I never swear off rain, but this July is setting up a lot like last July did," said Tom Flowers, who has an 800-acre operation on La Grange Road.
"We had a wet July [2015]; that was really good for the corn growers," he said, adding that the beans suffered from lack of moisture.
An air of expectancy hung over a crowd of about 25 people who gathered at the Stratton Center Tuesday night as they waited to hear what kind of ideas would come from a workshop on how to improve – and in some cases, provide for the first time – broadband Internet access to their neighborhoods.
With all the issues that farmers endure everyday, trying to find enough people to work their farms continues to be a major problem, especially now that a new problem has cropped up recently.
A federal program that permits farmers to bring in migrant workers from other countries has added more requirements with paperwork that is causing delays for farmers in bringing in laborers, said
Shelbyville Post 37 got back to its winning ways in a dominating fashion, dismantling Madison Post 9 by a score of 17-2 Tuesday night.
The first inning was a quiet one for Shelby, but the second frame showed the squad's offensive firepower.
Jacob Cole started off the second inning taking first base after being hit by a pitch, and Riley Everson joined Cole soon after, drawing a walk to place another Post 37 runner in scoring position.
Over the past month, athletes from both Collins and Shelby County high schools have been showing off their skills in the Underclass Games, a showcase for baseball players who are years from graduating.
The games, which are hosted by Prep Baseball Report, were held at both Jim Patterson Stadium in Louisville and at the University of Kentucky earlier this month.
Newly minted athletic director Charlotte Marshall already has the support from everyone involved with Shelby County High School.
"The first week has been pretty good so far," she said. "The one thing that I absolutely love is the support from not only the coaching staffs, but from the district level has been amazing as well. Margo [Whisman] and the principals have been nothing short of amazing."
Her first task as athletic director is working on the details of the upcoming sports season for the Rockets.
Copyright © 2016
The Sentinel-News is your source for local news, sports, events and information in Shelby County and Shelbyville, KY, and the surrounding area.


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The entertainment was done with frugalacity but quite a bit of style. We not only had fun but we learned a lot.
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I took this shot while exploring the beauty in the grit; that is New York City. It is a little bit of play... a series I have started to help inspire new ideas in my world.
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When John Travolta mispronounced Idina Menzel's name while introducing her during the Oscars, he had no idea that the song she sang from 'Frozen' would become a major hit within the Tribe.
It could be because the lyrics can easily be changed from, "Let it Go," to "Let us Go" or because the melody is so charming. Either way, there have been a spate of Passover versions of the song making it to YouTube.
Six13's a capella version, "Chozen," might be our favorite, but don't let that deter you from checking out some of the other videos out there.
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Hollywood Rule No. 1: Anytime gold is handed over on a big stage, there has to be an after-party.
Team USA learned this the easy way this weekend at the conclusion of the London Olympic games.
Hollywood's hospitality dream-team popped up in London over the weekend to shepherd Olympians-turned-stars through their first red carpet nights out at Club Bud, a two-night party venue of imported U.S. nightlife brands TAO and Marquee.
New "faces" like Lolo Jones and men's gymnasts Sam Mikulak and John Orozco (from the left) mixed with "Dancing with the Stars"-level names like Hope Solo and Justin Gatlin, and top-tier limelight veterans of Team USA like Lebron James and Kobe Bryant at a series of exclusive after- parties in the Camden neighborhood on Saturday and Sunday night.
Also Read: Olympics 2012's Star Athletes: Who's Doing Their Deals
Behind the curtain, a heavyweight credit block: Hollywood studios' preferred event producer Jeffrey Best, Budweiser, nightlife royals Noah Tepperberg and Jason Strauss of TAO Group, and power entertainment marketing firm PMK*BNC.
Nas and Swizz Beatz arrived on Sunday night for the TAO night, leading the men's basketball team superstars in to what became a TAO "morning" as the party stretched on to 3 a.m.
At right, gold medalist Carmelo Anthony is patriotic in the DJ booth.
A similar late night at Sundance is highly popular with hundreds of talent, media, scenesters -- and occasionally Harvey Weinstein -- flowing late in to the night beneath the "Village at the Lift" on Main Street each year on the festival's first weekend. There, Tepperberg personally cleared bodies from the front of the stage to make room for Paris Hilton to prance with indoor earmuffs on the opening night last January.
Unlike film festivals, where the blowouts are front loaded while media attention is fresh, or other major sporting events, where beer is baked in to the live and televised experience, this curtain call of "who made a name for themselves" could only happen at the end -- after medals are awarded and athletes are available for nightlife.
Yet, beer and nightlife are rarely a part of any elite athletes food pyramid.
"We're all human beings," says Brad Brown, vice president of sports & entertainment marketing at Anheuser-Busch. "We all like to, at some point, have fun. Obviously these athletes are unbelievably disciplined, but at some point in time, whether its during training or after the games, whatever the case may be, this is an opportunity for them to celebrate. In the spirit of that celebration that's exactly where Budweiser wants to be and that's what we've done the past six years.
Unlike Beats by Dr. Dre, whose athlete seeding program paid off by playing on-camera and in the press, Budweiser is an official U.S. Olympic Committee sponsor and has hosted Club Buds in Vancouver, Beijing and Torino.
"The opportunity presented itself in London and we are excited to bring our unique blend to London," Best says.
Unlike working on the friendly grid of the 323 and 310, the destination presented a challenge.
"I have no relationships, no warehouse and no advance team here," Best told TheWrap of converting the 19th-century railroad crossing into the event venue, Roundhouse. "We have had to use renderings and plans as our only guide."
Hosting more than 2,000 VIPs each night this weekend is old hat on the social side. Marquee and Tao in Las Vegas have reported revenues of $130 million for 2011, according to hospitality trade outlet Nightclub and Bar.
While the venues should have their own guest star credit on the Kardashian franchise for regular appearances, the talent relationship network run deep and stays fresh.
Melanie "Scary Spice" Brown wasn't home resting her vocal chords the night before the Spice Girls reunion in the closing ceremonies. She hit Club Bud with husband, Stephen Belafonte (Pictured left).
For entertainment, producers netted live musical talent in the sweet spot of the cross-Atlantic Venn diagram: entrenched in the U.S. but with U.K. roots. Popular British L.A. personality Zen Freeman, who went from spinning CAA and Relativity Golden Globes parties and hosting happy hours at the Mondrian to opening for Paul Oakenfold, spun in his hometown during the Marquee branded night on Saturday.
At right, If this equation of Lebron wearing his own face on a T-shirt while celebrating a championship in a club a few hours after a victory looks familiar, it should.
After winning the NBA title in June, the post celebration at Miami hotspot LIV lad the sports news the next day. It's not a stolen blueprint: Tepperberg just returned from an annual rat pack pilgrimage to Ibiza with LIV's managing partner Dave Grutman and other captains of the nightlife industry.
"Just like the movie stars and pop artists who frequent our U.S. venues, the Olympic athletes all seem to be looking for an appropriate, safe and controlled environment to let loose after long weeks, months, and years of hard work," Tepperberg tells TheWrap.
"That's what we strive to provide at all of our events," .
Not all of NBC's primetime-caliber names were there.
Michael Phelps had already departed London on a well publicized victory vacation with friends. Serena and Venus Williams celebrated their tennis gold medals with a low-key Wimbledon village dinner party with close friends and family when the tennis competition ended a week earlier.
Diamond-mouthed swimmer Ryan Lochte will cap his high profile Olympics (both in the pool and in the London nightlife tabloid awards) by hosting back-to-back nights back home -- at the venues in Las Vegas this upcoming weekend.
The freshest run from the star machine rolls on.
Photos by Tim Whitby and Ben Pruchnie for Wireimage.
Related Articles:
Olympics 2012's Star Athletes: Who's Doing Their Deals
Nigel Lythgoe on Danny Boyle's Big Olympic Show: 'We all lovvved that'


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