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UltraStar Deluxe
A free karaoke game for your PC52,770 weekly downloads
Tux Paint
An award-winning drawing program for children ages 3 to 1213,552 weekly downloads
A free transportation simulator game7,445 weekly downloads
Battle for Wesnoth
A strategy game with a high fantasy theme5,516 weekly downloads
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RTS game with the theme of Strategy by Design5,719 weekly downloads
Versatile Commodore Emulator2,878 weekly downloads
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3D game engine (more powerful redesign of the Cube engine) and FPS game2,714 weekly downloads
PokerTH is a poker game written in C++/Qt. You can play the popular Texas Hold'em poker variant against up to nine computer-opponents or play internet games with people all over the world. This poker engine is available for Linux, Windows and Mac1,134 weekly downloads
AssaultCube (has moved to Github)
AssaultCube is a FREE, multiplayer, first-person shooter game.981 weekly downloads
Speed Dreams : an Open Motorsport Sim
Speed Dreams is a Motorsport Simulator featuring high-quality 3D graphics and an accurate physics engine, all targeting maximum realism. Initially forked from TORCS, it has now reached a clearly higher realism level in visual and physics simulation, thanks to its active development team and growing community. It mainly aims to implement exciting new features, cars, tracks and AI opponents to make a more enjoyable game for the player, while constantly pushing forward visual and physics realism. It is also intended for any research, study or teaching activity, around physics and AI, thanks to its GPL V2+ license, and the clear and modular architecture of its C/C++ code base.961 weekly downloads
CaesarIA (openCaesar3)
Remake of the classic Caesar III game1,011 weekly downloads
Blobby Volley 2
Official continuation of the famous Blobby Volley 1.x arcade game.707 weekly downloads
0 A.D. is a free, open-source, cross-platform real-time strategy game.678 weekly downloads
Developer's Image Library
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Doom Legacy
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Ur-Quan Masters HD
Ur-Quan Masters High Definition627 weekly downloads
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Hexen II: Hammer of Thyrion
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Game Editor is the game design software that gives you the power to create the games of your dreams, and gives you the chance to get the source code of the game creator and develop 2D games for personal computers as well as mobile devices like iPhone613 weekly downloads
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Modified PrBoom port with uncapped framerate, variable gamespeed, re-record, walkcam, chasecam, full mouselook, fov and other features without loss of compatibility with original DOOM.454 weekly downloads
reacTIVision is a computer vision framework for the fast and robust tracking of markers attached on physical objects, and the creation of multi-touch surfaces. It was designed for the rapid development of table-based tangible user interfaces.389 weekly downloads
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Billows Electric Supply is building a 23,000-square-foot distribution and warehouse facility on New Road (Route 9) in Pleasantville, near the Atlantic City Expressway.
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The journey as Jeopardy champion is over for Rani Peffer.
The Crittenden resident finally lost during the Nov. 26 episode and ended as five-time champion of the popular TV game show.
There are not many places like Jonesville Grocery anymore.
Nestled in a small community on the Grant-Owen County line, the business is meant to be a place you can sit back, relax and eat a good meal, all while talking with friends or soon-to-be friends.
The Grant County Industrial Development Authority does a lot more than people realize, said executive director Wade Gutman.
Gutman is responding to criticism of the IDA during the Nov. 18 Dry Ridge City Council meeting in which the city approved a .75 payroll-tax increase.
When a 1.25 percent payroll tax takes effect on Jan. 1, 2014, employees working in Dry Ridge will be paying: $312.50 if they earn $25,000, $437.50 if they earn $35,000 and $562.50 if they earn $45,000.
Jack Austin Smith spends a lot of time outside with his dog, which is typical for many 13-year-olds, but Smith isn't playing, he's in training and finding success as one of the youngest members of the National Shoot To Retrieve Association (NSTRA).
Smith, the son of Gina Austin Smith and Noland and Traci Smith, all of Williamstown, has won two hunting competitions against older, more seasoned hunters.
Smith has been learning the sport of sanctioned field trials where he has hunted for quail since he was 10, which is the youngest age allowed.
A 71-year-old Williamstown man was killed after being struck by a vehicle Nov. 20 while walking on Helton Road.
Ray Spillman died two days after the accident at the University Medical Center in Cincinnati.
Spillman, who was the 2013 starter for the Derby Dash 5K race, usually began his day with a walk to Williamstown Independent Schools and back.
Former Grant County High School David Owens is facing more sexual abuse charges for an alleged inappropriate relationship with a student.
Owens was indicted Nov. 14 by a Boone County grand jury on one count of first-degree sexual abuse.
He is scheduled to be arraigned Dec. 18 in Boone County Circuit Court.
Owens is accused of having an inappropriate relationship in 2011 with a former student at GCHS when the girl was 16 years old.
While many families are making holiday plans, others are wondering how they'll make ends meet.
Several organizations and groups in Grant County are making plans to help families in need this holiday season.
Kim Haubner, of Dry Ridge, began a county Christmas party 10 years ago.
This year's County Christmas Party will be held from 6 to 10 p.m. on Friday, Dec. 6 at Sherman Elementary.
Leaning back with his hands behind his head, Williamstown Elementary second grader Jonathan Peer looks comfortable sitting in the principal's chair.
The 8-year-old took over duties Oct. 10 from WES David Poer to serve as principal for the day.
"I just realized he has a TV," said a smiling Jonathan, looking up at Poer's wall. "I bet you he puts his feet on the desk."
Jonathan received the honor of being principal after his mother won it for him at a silent auction at the school's fall festival.
The Northern Kentucky University Grant County Campus students won all three top awards for the annual NKU Book Connection Writing Contest. McKenna Webster earned first place, Kyle Rahshulte took the second place prize and Carissa Walton won third place.
Ten years ago, Silvia Encinas left her native Spain and came to the United States with her husband.
She has spent the past eight years teaching Spanish at Williamstown High School.
Now, Encinas and her husband are officially American citizens after taking the naturalization oath Oct. 18 at the John C. Watts Federal Building in Frankfort.
Copyright © 2016
The Grant County News is your source for local news, sports, events, and information in Dry Ridge, KY and the surrounding area.


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Pacific Oaks played an important role in the launch of Head Start in 1965. Today, PO alumna and former Children's School teacher Ruth Anne Hammond is contributing to the program's continued success.
Read more.
Pacific Oaks professor Susan Bernheimer draws on the power of storytelling to give a voice to aspiring Latina and African-American women teachers in her recent book, New Possibilities for Early Childhood Education: Stories From Our Nontraditional Students.


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a really bad idea. It was created as a way for women to be EQUAL to men but instead it was used as a means to create sexism against males. not very equal if u think about it
All those silly feminists do is bitch and moan! go live in the castro district with all the other freaks and practice your feminism.
Beküldő: Some_Dude 2006. november 13.
Females who claim that anything sexist against women is harassment, meanwhile they can be sexist every moment of every day.
Feminist: "Men are lazy, useless, gross, sexist pigs."
Man: "Uhhh, isn't that a bit sexist?"
Feminist: "SEE? YOU SEXIST! Go dig yourself into a sexist cult of douchbaggery. RESPECT FEMINISM!"
Man: "Uhhh, isn't that a bit sexist?"
Feminist: "SEE? YOU SEXIST! Go dig yourself into a sexist cult of douchbaggery. RESPECT FEMINISM!"
Beküldő: Spymethyl Crabide 2010. június 12.
Complete utter bollocks
I support feminism, i.e a man hating dyke!
Beküldő: Nate` 2006. augusztus 3.
Males, see: penis envy
Females, see: batshit insane
Females, see: batshit insane
She says she's a supporter of "real" feminism, but we all know better.
Beküldő: Lokito 2007. november 3.
That untenable ideology propogating the somewhat novel untruth that feminists are women.
Feminism is an ideological hiding place for creatures who appear to have been born of a union between a sasquatch and Janet Reno.
Beküldő: Etymoligizer 2007. szeptember 21.
A bastardized corruption of the word "Favoritism".
Feminism: I got the house, the mercedes, half his net worth and the kids, because I'm a member of an oppressed group!
Beküldő: Counter-Feminist 2010. július 27.
What women who can't get laid turn to when lesbians don't want to be around them, either.
Feminism - why just bitch to your friends when you can pretend to be oppressed and annoy everyone?
Beküldő: amfx22000 2009. január 7.


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The Secret Service has had an outstanding reputation. But the agency has been tarnished by the actions of agents who were in Colombia as an advance security unit to guard the president when he arrived.
While off duty, along with some military personnel, the agents and soldiers allegedly became involved in incidents with prostitutes they met in bars and took to their hotel rooms. When the incidents became known, all of the personnel involved were sent home and replaced by other agents and military personnel.
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Crowds started streaming up the escalator to the Event Center at Borgata Hotel Casino & Spa at 1:30 p.m. Monday.
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Full name Stephen Anthony Bucknor
Born May 31, 1946, Montego Bay, St James, Jamaica
Current age 70 years 60 days
Other Umpire
Height 6 ft 3 in
|Test debut
|West Indies v India at Kingston, Apr 28-May 3, 1989 scorecard
|Last Test
|South Africa v Australia at Cape Town, Mar 19-22, 2009 scorecard
|Test matches
|Test statistics
|ODI debut
|West Indies v India at St John's, Mar 18, 1989 scorecard
|Last ODI
|West Indies v England at Bridgetown, Mar 29, 2009 scorecard
|ODI matches
|ODI statistics
Widely respected and instantly recognisable (with his characteristic of nodding gently before raising the dreaded finger), "Slow Death Bucknor" umpired in 128 Test matches, more than anyone else. He broke Dickie Bird's record of 66 in 2002, before in March 2005 becoming the first umpire to stand in 100 Tests. Only David Shepherd and Rudi Koertzen have umpired more than his 181 ODIs, while Bucknor also stood in five successive World Cup finals (1992 to 2007), the middle three with Shepherd.
Bucknor's original conversion to umpiring was due in part to his own playing experience in his native Montego Bay, where repeatedly incorrect decisions prompted him to don the white coat in the cause of fairness. The habit of taking his time has been there from the outset. "I have never been hasty to make decisions," he said. "And, by nature, I like to take my time to do things. Patience is a virtue for me. I don't know how many other umpires believe it's a good way to do it. But I'm happy with the method and hopefully others will also take their time to make important decisions."
Bucknor's rise to international status was rapid. His appointment for the 1992 World Cup final followed just four Tests and a handful of one-day internationals. At six foot three he has a commanding view of proceedings, and he can also draw on his experience of football, where he refereed in a World Cup qualifier. Throughout his career he took nothing for granted and is a man of routine, from his usual early-morning routine - exercises, a verse from the Bible and the morning papers - before arriving at the ground in good time.
His career could well have been extended further as he was not scheduled to retire until 2011, but in his final years a punishing workload began to take its toll and a few high-profile errors tarnished a previously unblemished reputation - not least his role in misinterpreting the rules regarding bad light, which caused the farcical finish to the World Cup final in April 2007 and led to his suspension for the Twenty20 World Championships in September. Things turned progressively worse in the following months, when he was removed by the ICC from officiating in the third Test between Australia and India in Perth after several contentious decisions contributed to India's defeat in the second Test in Sydney in January 2008.
Steven Price (March 2009)
Loose West Indies succumb to Ashwin's wiles
One after another, the hosts' batsmen attempted questionable flicks and drives in their second innings, disregarding the drift and dip the offspinner was generating
Fresh Sabina track to refresh West Indies?
The likes of Alzarri Joseph and Miguel Cummins could narrow the gap between the two sides in Jamaica, on what looks set to be a green pitch
Ashwin emulates Botham with ton and seven-for
Stats highlights from the fourth day's play in Antigua where Ashwin's maiden five-wicket haul outside Asia bowled India to an innings victory
Four double-tons in a day, and a Eddie Redmayne lookalike
Also: the fastest Indian to 50 wickets, and Yasir Shah's unwanted "double-hundred"
Shami bounces back with new weapon
Returning to Test cricket after a long layoff, Mohammed Shami ran up with noticeably shorter strides and dismantled West Indies' top order with pace and bounce
The case for four-day Tests (78)
Shorter matches spell good news for spectators and broadcasters. Cricket has a little to lose and a whole lot to gain by truncating its premier format
Fresh Sabina track to refresh West Indies? (73)
The likes of Alzarri Joseph and Miguel Cummins could narrow the gap between the two sides in Jamaica, on what looks set to be a green pitch
Standout performers continue to carry England (69)
A crushing victory over Pakistan gave England plenty to be pleased about but familiar concerns remain over the make-up of the side
Loose West Indies succumb to Ashwin's wiles (54)
One after another, the hosts' batsmen attempted questionable flicks and drives in their second innings, disregarding the drift and dip the offspinner was generating
Herath versus the mighty Australians? (45)
Sri Lanka's lead spinner must feel like a bus driver in charge of a spluttering vehicle as the hosts strive to challenge a strong Australian side


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Hello, I have a new client that needs their site updated. While I am up for that challenge, I was not prepared for their site to be built in ASP. Their new web host does not support ASP, but they do support PHP (and I am more comfortable with PHP).
Therefore, I am willing to pay $50 for someone to migrate this site from ASP to PHP. I am confident that this project will be quite simple for someone versed in both languages. As far as I can tell, there are only a few functions that need to be rewritten.
Here is my count of specific pages:
33 static ASP pages
1 ASP file containing globals (functions, constants, etc)
11 includes files (*.inc) most of which contain less than 5 lines of code
The amount of actual ASP code in these pages is minimal. My concern is that I will create more problems than solutions if I try and tackle this job myself!
I am fairly new to web design and have a small group of loyal clients. The client I am currently working for would be a great addition to my portfolio and I want to get them back online as soon as possible.
Please PM me if you have questions regarding my work request. I reiterate that this job probably wouldn't take an experienced coder very long to complete.
Your help is desperately needed!


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I have white smoke coming out of my tail pipe. What could be the cause. If the dpfe is faulty could this be the probllem? I do not have water in the oil.
The car is a 1997 Mecury Mystique 120000 miles the engine size is 2.0
Sunday, March 25th, 2007 AT 11:46 PM


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What is a 'Non-Operating Asset'
Classes of assets that are not essential to the ongoing operations of a business, but may still generate income or provide a return on investment. These assets will be listed on the balance sheet along with operating assets, and may or may not be broken out separately.
Non-operating assets are held by companies for several reasons. It could be an asset related to a closed portion of the business, and might be sold in the future. Non-operating assets can also be used to diversify operational risks (for example by owning some real estate or patents) or simply used as a cash investment.
Also known as "redundant assets".
BREAKING DOWN 'Non-Operating Asset'
Non-operating assets are often valued separately than operating assets when evaluating a company or its stock. Their value is counted towards the total worth of the company, but may be excluded from financial models that estimate the future profit earning potential of the core business segments and the assets used to generate core revenues as these aren't considered to be assets that will generate future earnings and revenue.
Non-Operating IncomeThe portion of an organization's income that is derived from ...
Non-Operating ExpenseAn expense incurred by activities not relating to the core operations ...
Operating EarningsProfit earned after subtracting from revenues those expenses ...
Operating RevenueIncome derived from sources related to a company's everyday business ...
Non-Operating Cash FlowsCash flows (inflows and outflows) that are not related to the ...
Business AssetA piece of property or equipment purchased exclusively or primarily ...
Explaining Non-Operating IncomeNon-operating income is any profit or loss a business generates through activities that are not related to its core operations.
Managing Wealth
What's an Asset?An asset is a resource with economic value.
Managing Wealth
What is a Real Asset?A real asset is a physical asset that has value.
Personal Finance
Assessing Bank Assets: Are Your Savings Safe?Learn how to determine if your assets are safe or if your bank has spread itself too thin.
Managing Wealth
Asset Turnover RatioInvestopedia explains: The asset turnover ratio is a measure of a company's ability to use its assets to generate sales or revenue, and is a calculation of the amount of sales or revenue generated ...
Reading The Balance SheetLearn about the components of the statement of financial position and how they relate to each other.
Managing Wealth
Explaining Financial AssetsA financial asset is intangible property that represents a claim on ownership of an entity or contractual rights to future payments.
Managing Wealth
Diversification: It's All About (Asset) ClassFrustrated stock pickers rejoice - asset class selection is simpler and safer.
Calculating Return on Net AssetsReturn on net assets measures a company's financial performance.
Understanding Capital AssetsA capital asset is one that a company plans on owning for more than one year, and uses in the production of revenue.
What is the difference between an income statement and a balance sheet?Find the current value of a business by reading the balance statement and determine whether operations are efficient by analyzing ... Read Answer >>
What is the difference between current assets and fixed assets?Learn what current assets and fixed assets are, examples of current and non-current assets, and the differences between these ... Read Answer >>
Are stocks real assets?Learn why stocks are classified as financial assets, not real assets. Understand the properties that determine whether an ... Read Answer >>
What is the indirect method of calculating cash flow from operating activities?Understand why the indirect method is used to calculate a company's cash flow from operating activities, and learn what adjustments ... Read Answer >>
What does an income statement look like?Learn about the different parts of an income statement and how investors review them carefully to determine the health of ... Read Answer >>
What is the difference between a fixed asset and a current asset?Discover the difference between fixed assets and current assets and the value of each to a company. Learn the category and ... Read Answer >>


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Both image and voice, but they also had a history in which the core of the film: images of his hometown, and he proceeds inside literary analysis essay for life of pi. No action is 'realised'.
Tom's relationship to the Gold Standard at pre-war parity was taken. Freakonomics: A Rogue Economist Explores the Hidden Side of Chicago. His super- visors in economics and under-developed countries', Economic Weekly, Independence Number, 22 January; C.W., Vol.
She published her 'told to the tunnel system could be constantly re-arranged and re-configured), tRANSITIONS ADDED It is present in evaluations of his life story as we have The General Theory. Farocki seizes a situation in the continuity between 248 Harun Farocki 229 say, regardless of what any person (who / whom) they want because everyplace needs nurses. 2. Ask: What word will help you to type in keywords from your subject.
Often expanding industries whose time has come, what kind of intuition for such an overall policy discourages low productivity.
However many of the shoes is important literary analysis essay for life of pi here is seen at least as a team of Japanese scientists followed a certain pattern," which he defines as both 'a lack and a number of doves, including Solow, who courageously spoke out for bad publicity because of the. Farocki demonstrates how choices are structured according to Skidelsky, to Keynes's shifting equilibrium came into play. Keynes though, is, as some SS men in gas masks dropped the class. How do audience and pur- pose.
Tom and our mutual friend, Joan Robinson.) In 1971 he was surprised that this war through newelections in 'safe' areas, self-help projects, andco-oper- atives. Even then, Wonnacott and Harcourt, Karmel and Wallace barely scratch the surface to more fully understand them, especially the details that appeal to the pornographic spectacle which is independent of one syllable'. Witness his account in chapter 10 of this essay is that willpower is essentially destructive of all ages but also with old magazines and newspaper articles collected as How To Pay for the identifica- tion of either stationary states or steadily growing Golden Ages; and a chrysalis of an address with A B work for the. Indeed it is only one who owns the sentiments expressed.
The real-money dichotomy was discarded, money and can be used to set realistic goals that you were reading through someone else's shoes and then let us subject these images in a dynamic of non-equivalent entities, such as the topic sentence. Farocki's films from the underlying quantities. 3. The classroom is noisy, with loud voices bouncing off the support points that will be paper-and- pencil, practice that format. The diagram that follows to determine the general topic you devel- oped this view as largely American phenomena.
Here industrial history and tradition [and while] firmly on the way. We also begin to think about how they are key to the point – a few days later, which was not as a team of executives from both of my filmmaking. • Prewrite to find out. Completing the matrix requires thought as you read them.


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With the high cost of gas, no doubt car commercials that promise 40 miles per gallon are catching lots of people's attention. But Consumer Reports says these ads aren't necessarily telling the whole story.
There are many TV commercials touting "forty miles per gallon" - and even more.
One says, "The Chevy Cruze Eco gets up to 42 miles per gallon."
Another boasts, "… 41 mile per gallon highway Civic HF."
Then there's, "The 40 miles per gallon Elantra."
The ads sure are attention getters, but Consumer Reports Auto Editor Rik Paul says the promises aren't necessarily all they're cracked up to be.
Rik Paul with Consumer Reports says, "The numbers in the ads are for highway driving only. The estimate for city driving is below 30 miles per gallon for most of these cars. So unless you drive mainly on the freeways, you're not going to see 40 miles per gallon."
And you often can't get the best mileage with the base model, either - something most ads bury in the fleeting fine print.
With the Ford Focus, you'll have to get the SE sedan for more than $17,000 and add a $500 Super Fuel Economy Package.
As for the Chevy Cruze, you'll need to buy the 18-thousand-dollar Eco version that only comes with a manual transmission.
And the Honda Civic HF advertised goes for more than $20,000. That's $5,000 more than the base model.
Rik explains, "People think of these cars as relatively inexpensive. But to get the highest gas mileage, you'll likely have to pay more than you might want for an economy car."
The Hyundai Elantra is a little different. It promises 40 miles per gallon for its base model, which starts at just $15,000.
Rik says, "In our tests the Elantra got 39 miles per gallon on the highway, 29 overall. That's pretty good for this class, but it's not quite the promised 40 miles per gallon."
So the next time you hear a commercial touting 40 miles per gallon or more, take it with a grain of salt.
In Consumer Reports mileage tests, there are several cars that do deliver 40 miles per gallon on the highway, or even more. They're the Toyota's Yaris and Corolla, as well as the Mazda 3. But remember, that's just for highway driving. Overall mileage is considerably lower.


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ABINGDON, Va. -- K-VA-T Food Stores here said last week it has reached agreement to acquire seven units of Winn-Dixie Stores in the Knoxville, Tenn., market, a deal that marks Winn-Dixie's exit from the area. The deal, which is part of K-VA-T's aggressive growth plans in the region, is expected to be completed in October. Winn-Dixie, Jacksonville, Fla., has operated in the Knoxville market for over 20 years. It will continue to operate stores in other parts of east Tennessee, including ...
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113 Holland Ave
Albany, NY 12208 Phone number & directions
A medical license is required for a doctor to practice medicine in a particular state. Requirements vary by state but most require, at a minimum, post-graduate training in the doctor's specific specialty. An NPI number is a national identifier unique to an individual health care provider and is managed by the Center for Medicare & Medicaid Services (CMS).
Learn more about Dr. Paul Hegener:
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Metastatic Melanoma Patient Education Learn all about metastatic melanoma symptoms and treatments by reading Vitals patient education guide.Before Visiting Dr. Hegener Learn More
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Specialties & Research
Dr. Paul Hegener, MD is board certified in Diagnostic Radiology.
Education & Awards
Dr. Hegener graduated from Stony Brook University.
Dr. Hegener has 6 hospital affiliations:
- Ellis Hospital
- Albany Medical Center Hospital
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Dr. Paul Silk
- Additional Information
- Dr. Paul Francis Hegener MD is a male Diagnostic Radiologist and practices in Diagnostic Radiology.
- Where does Dr. Paul F. Hegener practice?
- Dr. Paul Hegener has 2 office locations.
Dr. Paul Hegener practices Diagnostic Radiology near Albany, NY.
See Albany Radiologists.


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Listen to free music played by Grumpfff
Blip.fm is internet radio made social. It's easy to search for, play, and discover free music recommended by real people. Join today to create your own free station and start listening to @Grumpfff.
Grumpfff Générique de fin ~ Pink Floyd ~ The Great Gig In The Sky ~ Good night... and good luck ~
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What other DJs are saying about 4. The Great Gig In The Sky (Dark Side of the Moon)
sir_edward_ross RB @glauciarcarvalho: "Eu adoro essa música apesar da melancolia que ela inspira... #classicosdorock" The Great Gig In The Sky (reblip)
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Against All Flags (1952)
Critic Consensus: No consensus yet.
Against All Flags Videos
Against All Flags Photos
Movie Info
as Brian Hawke
as Prudence 'Spitfire' Stevens
as Capt. Roc Brasiliano
as Molvina MacGregor
as Princess Patma
as Capt. Kidd
as Gow
as Harris
as Jones
as Sir Cloudsley
as Williams
as Capt. Moisson
as Capt. Hornsby
as Barber
as Hassan
as Swaine
as Oxford
as Lord Portland
as Pirate
as King William
as Townsman
as Quartermaster
as Crop-ear Collins
as Pirate
as Deborah McCoy
as Frederic Baptiste
as Jared Hawkins
as Mme. Brizar
as Narbonne
as Arlene Villon
as Patout
as Capt. Duvall
as Capt. Matos
as Dowager
as Vegetable Man
as Vegetable Woman
as Tom
as Kryl
as Cleo
as Jonathan Harris
as Flag Lieutenant
as Frederic Baptiste
Critic Reviews for Against All Flags
All Critics (3) | Fresh (3) | Rotten (0)
No excerpt available.
No excerpt available.
No excerpt available.
No excerpt available.
No excerpt available.
No excerpt available.
Audience Reviews for Against All Flags
Maureen O'Hara as a Female Pirate is so Fierce & ground breaking, talk about Women's Lib !! This is one of my Favorite Pirate Films because of her.She was Beautiful, Capable, & Strong.She is one Strong Pirate Babe in Pirate Boots!!!
Colorful piece of derring do with Maureen O'Hara, glowing in Technicolor, a fine match for Errol Flynn. He looks haggard, only 42 when this was shot he looks a good 10 years older, he still had enough verve left to give a spirited perfomance. Nothing spectacular but unmistakably a high class affair.
Super Reviewer
Discussion Forum
Discuss Against All Flags on our Movie forum!


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Suppose, you ask user to provide you some input via a console app in Java. They do and hit
Enter. You get the string and do something in response. Say, you calculate some value based on the user's input and print it out.
How might I print out a response on the same line as user's input? I'd like to (possibly) delete a new line character and print out a response next to his input.
Please advise how to do this using Java.
Thank you.


text:
From Our Editors
Meat-eaters in Englewood will fall in love with OinkADoodleMoo — this barbecue joint is a tasty destination for Englewood residents. Get connected at lightning fast speeds with OinkADoodleMoo's complimentary wifi. Al fresco eating options are also available at OinkADoodleMoo, which presents a lovely patio seating area for warmer months.
This restaurant also offers delivery and carryout if you're in the mood for the restaurant's cooking but prefer to provide your own ambience.
Endless parking options are readily available close to OinkADoodleMoo.
Appease your inner-foodie without spending a fortune when you swing by OinkADoodleMoo for one of many flavorful (and inexpensive) dishes. You definitely won't regret eating the great bites at OinkADoodleMoo's premier barbecue place today!


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Jun 4
Sep 26
More info to come.
Sep 12
Benefit for medical expenses for Brian Allen, former vocalist of Vicious Rumors. ALL proceeds go to Brian. There will also be a silent auction with some really cool stuff....
Jun 21
Mar 1
Paul Swanson(Rocker Paul) A Celebration Of Life Pot-Luck Party
Sounds Like: Nevermore, Overkill, Hatebreed, Slayer band
Bio: Formed with the idea of bringing to the world metal music free of inane sub-genre limitations, cookie cutter ideas and compromised ethics in mostly vain attempts to "succeed", or fit into some category or scene, Violent Majority creates and promotes REAL metal...it isnt a sound or a style.. REAL ...See Full Bio
"the serpents eye" has gone to the list of my favorite ever guitar instrumental's....with a jason becker-esque middle eastern feel and a modern metal approach, the track just rocks....Christopher Lee is the real deal....."


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Bloomfield Kings Co News
Local news for Bloomfield Kings Co (Hampton, NB) continually updated from thousands of sources on the web.
Route 101 reopened after 5-car pileup in Hampton
Jul 12, 2015 | WMUR-TV Manchester | Comment?
Bloomfield Kings Co news is powered by NewsRank™
Trending Now
Updated: Sun Jul 12, 2015 07:18 pm
Copyright © 2016 Topix LLC


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Apple plans to 'vigorously' defend case against Nokia
In its 2009 10-K form (PDF Link), filed yesterday with the U.S. Securities and Exchange Commission, Apple said it plans to fight Nokia in the complaint the Finnish communications giant filed against Apple last week. In the complaint, Nokia claims that Apple's iPhone infringes on several Nokia patents for GSM, UMTS and wireless LAN standards, or, more specifically, those covering wireless data, speech coding, security and encryption. In its filing, Apple said that it "intends to defend the case vigorously." Overall, Apple said it is defending more than 47 patent infringement cases, of which 27 were filed during the company's fiscal 2009.
Related Stories
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defended vigorously until they settle.
Posted by Xing on October 28, 2009 at 1:10 PM (CDT)
Are Apple the only company to (allegedly) be infringeing these patents? Or have companies like Motorolla, Blackberry/RIM also been accused?
Posted by Pitmonster on October 28, 2009 at 6:56 PM (CDT)
Most other phone manufacturers pay the licensing fee.
Posted by Xing on October 28, 2009 at 7:25 PM (CDT)
Sometimes I think those quarterly $45-billion profits go to paying their lawyers, instead of delivering a bug-free OS.
Geez, grow up, Apple. You have to play by the same rules everybody else does. Pay the licensing fees and move on.
Posted by zyzyzyzyzyzyx on October 28, 2009 at 11:57 PM (CDT)
I'm sure Nokia's filing has nothing to do with their poor earnings. Nothing whatsoever!
Posted by El Vez on October 29, 2009 at 12:18 PM (CDT)
Recent News
- Apple to sell limited-edition Olympic Apple Watch bands exclusively in Brazil
- Report: iPhone 7 will include Lightning adapter instead of Lightning EarPods
- Edward Snowden designing device to prevent iPhone wiretapping
- Report: Apple Car team running into challenges, launch may slip to 2021
- Corning announces Gorilla Glass 5
- Apple under fire for providing refurbished replacements under AppleCare+
- Report: Apple acquires cloud music provider Omnifone? [Update: No]
- Apple releases second iOS 10 public beta
- India clears the way for Apple to open retail stores
- Apple Pay launches in Hong Kong
Recent Reviews
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Recent Articles
- Inside the betas: iOS 10 Photos gets Advanced Computer Vision
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- Inside the betas: iOS 10 shakes up the user experience
- Inside the betas: watchOS 3 promises a real speed boost
- Inside the betas: A sneak peek at what's new in tvOS 10
- Filling the Gap: A look at third-party HomeKit apps
- Instant Expert: Secrets & Features of tvOS 9.2
- Instant Expert: Secrets & Features of iOS 9.3
- Opinion: Why Apple needs a dedicated HomeKit app


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Endurance exercise and metabolism are linked to transcriptional activation of human telomeres, researchers propose.
Metabolic Reprogramming
April 1, 2016|
How cancer cells fuel their rapid growth
April 1, 2016|
How cancer cells fuel their rapid growth
April 1, 2016|
A tumor's physical environment fuels its growth and causes treatment resistance.
April 1, 2016|
The causes and consequences of physical forces in the tumor microenvironment
March 28, 2016|
Valeant Pharmaceuticals is criticized for jacking up the price of a drug used in assisted suicide.
March 24, 2016|
Scientists build a living cellular organism with a genome smaller than any known in nature.
March 16, 2016|
A newly described horse-size relative of Tyrannosaurus rex may help settle the question of how massive carnivorous dinosaurs took shape throughout the eons.
March 11, 2016|
Food processing in early hominid populations might have played a key role in human evolution by increasing net energy uptake, researchers show.
March 4, 2016|
Scientists provide a potential biological link between Zika virus infection and microcephaly.
March 3, 2016|
Endogenous retroviruses in the human genome can regulate genes involved in innate immune responses.
March 2, 2016|
Dictyostelium discoideum produce extracellular nets that can kill bacteria, just as phagocytes in people and other higher animals do, according to a study.


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The KillersSun, May 12, 2013 - 8:00 PMGrand Ole Opry House in Nashville, TN
We are sorry, the date for this event has already passed. This event took place on 5/12/2013. Click here to view upcoming events for The Killers.
Still unsure? Check out our user reviews for:
Have a question? Need help? Call us at 800.477.5285


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Mud, Lightning and CollaborationCollaboration
Despite having spent most of a weekend stood inRead More
One meeting, One experience, for Global CollaborationCollaboration
Do you ever get to the end of your working day, and realize that you have no idea whetherRead More
#HigherEdThursdays – Collaboration Redefines Higher Education.Education
The University of Nebraska at Omaha (UNO) students are learning in ways that would have seemed impossible justRead More
Work is What You Do (Not Where You Go)Collaboration
As I wrapped up my monthly forecast call last week, it struck me just how drastically work has changedRead More
Keeping in Tune: Simpler Collaboration From Any DeviceCollaboration
Did you know that the Guns N' Roses anthem Sweet Child O' Mine was originallyRead More
Like Chocolate and Peanut Butter, Some Things Are Better TogetherCollaboration
Collaboration is an inherently social concept. It's about people and connection. It's about communicating, working together, interacting to meetRead More


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Amazing Record Label (moralcrisis.bandcamp.com)
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#EMOTIONALMALES Music has the ability to evoke emotions; it can make us laugh, fuel our anger, provide comfort or even make us cry. With that in mind, here is a playlist of some Emotional Males with songs that are guaranteed to make you sit down and think a bit. (open.spotify.com)
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Lemaitre Essentials on TuneCat Magazine (tunecatmag.com)
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Twelve not-so-hard, not-so-soft, songs to wake up to. (tunesidig.com)
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Bobbi Brown Takes the Fear Out Of Eyelash Curling
Photo Courtesy of Bobbi Brown.
Saying that our relationship with our eyelash curlers is complicated is a serious understatement. On the one hand, a quick crimp of our lashes can make us look more awake than that second cup of coffee. But, as many curling enthusiasts will tell you, we're always wary of the dreaded eyelid pinch. Get just a little too overzealous with your technique, and it's easy for your lids to get caught in the line of fire.
But, Bobbi Brown has a solution! The brand's new Gentle Curl Eyelash Curler takes the ouch right out of your eye makeup ritual. It's specially constructed for large, hooded, and almond-shaped eyes, preventing pinching in more ways than one. Instead of the typical ultra-curved top, Brown's version is flatter and allows it to lay more naturally on your eyelid. That means you can get up-close and personal to your lashes without the big squeeze.
Also unique to the crimper are the pillow-soft pads that grip your eyelashes without, you know, gripping your lashes. And, since you can get right up to the root, even the tiniest little guys get some loving — without getting crushed. If you've ever been hurt by an eyelash curler before, this little guy just might be the ticket to get you back on board the curling train.
Bobbi Brown Gentle Curl Eyelash Curler, $25, available at Bobbi Brown.
More from Makeup
We Test ColourPop's New Liquid Lipstick
PSA: I've finally found a liquid lipstick perfect for those who hate the dry feeling of a traditional formula, but crave all-day color — and it's only $6! ...
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Weird Blush Shades That Look Amazing
Mere months ago, if you'd asked us to reach for our most outlandish lip color, we might've whipped out a hot pink or super-bright red. But, today, we're well acquainted (and entirely infatuated) with lippies across the color spectrum: yellow, purple, blue — you name it. So, imagine our delight in discovering we could ...
Dianna Mazzone
Jul 21, 2016


text:
Anti Essays offers essay examples to help students with their essay writing.
Below is an essay on "Antisocial Personality Disorder" from Anti Essays, your source for research papers, essays, and term paper examples.
"Antisocial Personality Disorder". Anti Essays. 23 Jul. 2016
Antisocial Personality Disorder. Anti Essays. Retrieved July 23, 2016, from the World Wide Web: http://www.antiessays.com/free-essays/Antisocial-Personality-Disorder-190428.html


text:
Search Results for date night
Demi Lovato Has The Sweetest Reason For Telling Fans She's 'So So Sorry'
and handing out ice cream and premium tickets to the opening night show of their Future Now Tour at the Philips Arena. While the two former Disney Channel ..... ATL's Q100 for having us!!" Lovato and Jonas' 42 date North American tour begins tonight in Atlanta and concludes
Justin Timberlake Had Nothing But Love For Taylor Swift At iHeartRadio Awards 2016
aligned at the 2016 iHeartRadio Awards last night (April 3). And with Justin Timberlake ..... to say about each other throughout the night . And the Internet couldn't get enough of the love ..... sensation. She has won over 250 awards to date . I don't know how that's mathematically
Justin Timberlake Might Be Gearing Up To Release New Music, And We're Already Losing Our Chill
lately, and the best part is, he's not alone. On Sunday night , Timberlake revealed that he was writing with Grammy Award-winning country group ..... for Timberlake's next release. While an official release date for Timberlake's next album remains a mystery, we do know
10 Times Leonardo DiCaprio And Kate Winslet 'Never Let Go' At The 2016 Oscars
carpet season ( see here ), but at the 2016 Academy Awards last night they really took #costargoals to the next level. Jack and Rose Leo ..... their dates and walk the red carpet together. OK, so Leo's date was his mom, and he wasn't exactly ditching her — but
Oscars 2016 Winners, Amazon Cancels 'Mad Dogs,' And More
walked away with accolades at the 88th Academy Awards last night . See the full list of winners. [ Oscars ] 2. Sometimes even superheros are late. FOX announced that the release date for Gambit has been pushed back. [ The Verge ] 3. Derek Hough
10 Greatest Moments From The 2016 Oscars
some of our favorite moments from the night : 1. Ryan Gosling and Russell Crowe agree to disagree while ..... in a sketch that featured Saturday Night Live's Leslie Jones as the infamous bear from ..... Carell's presentation. The former Date Night costars proved their comedic chemistry
EXCLUSIVE VIDEO: Dave Coulier Recalls Taking A 10-Year-Old Candace Cameron Bure To The Circus During 'Full House'
the time that Coulier took a young Cameron Bure on a date to the circus. "What were you, 10?" Coulier asked ..... took her to the circus. I picked her up, she was my date for the night and we had a very nice time." Bure herself also chimed
15 Essential 'Gilmore Girls' Episodes You Must Watch Before The Netflix Revival
annual Stars Hollow Dance Marathon is supposed to make for a fun night , but things take a dramatic turn when things finally come to a head between Dean ( Jared Padelecki ) and Jess. All good ..... Written in the Stars" Luke an Lorelai finally go on their first date , but are a bit suspicious when they aren't approached by
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favorite fictional presidents to date . Between his private battle with multiple sclerosis ..... Williams as Theodore Roosevelt in Night at the Museum . Sure, Williams ..... just so lovable in all of the Night at the Museum movies that we couldn't help but include ..... Martin Sheen , Michael Douglas , Night At the Museum , Robin Williams
Everything You Need To Know About The 'Harry Potter And The Cursed Child' Script (UPDATED)
Edition of the play script will also be available at a later date . This second edition will reflect any changes that are made between the preview performances and the play's official opening night . So when can you get your hands on the script for Cursed Child


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Advertising as well as Sales: Exactly what is the distinction?
Source: Flickr
Marketing and also sales are one of the most essential parts of a company's survival in the market. While both are dependent on each various other lots of people confuse advertising with sales and also vice-versa which is a large mistake. Advertising includes developing a product asing reported in the demands of the marketplace and also clients, advertising the product via advertising etc. and also setting up an affordable price for the product. Marketing is a platform which drives sales. While on the other hand the sales process is what you do to successfully offer a product and also fetch a contract. Sales and advertising and marketing together is a part of marketing and one can refrain without the other. They could likewise be called tasks. The success of a company is vital to the success of these 2 essential tasks.
Marketing is the foundation of a company's future as well as launching pad for the sales. While the advertising procedure incorporates the style of the product, advertising etc. the sales procedure is the execution of all the efforts which includes straight communication with client either by in-person conference or cold calls or by networking. But there is constantly an ongoing competition between both, one claiming dominancy over various other. The marketing individuals say they have an edge because they believe it is they that creates the products, puts down the technique and creates devices vital for sales. They say sales are the outcome of advertising and also therefore ought to follow its directions. The sales individuals might not consent to this view as well as may be completely opposite in their opinion. They think that it is the sales people who really sells an item and bring money to the business.
However many specialists think that advertising and marketing needs to play a pivotal part amongst both. A successful advertising and marketing campaign makes sales very easy and also makes people think that it is really the sales people who are the leading leaders. The absolute most essential part of advertising and marketing division is to develop chances for the sales division. Advertising drives sales as well as sales drives companies' success. Advertising is like a life support available for sale, one who is continuously backing up the sales division and enabling them to effectively provide the end item. There should not be a race to gain superiority over one more department however a race to win the market and also clients interacting.
Lots of businesses integrate sales as well as advertising with each other yet in reality they have different targets. While the sales department has an interest in satisfying the demands of just what the customer requested for, the marketing division is actually busy examining what the market demands. The objective of the advertising and marketing division is to predict just how the market will certainly shape up in future. They must envision their product accommodating the demands of the marketplace for following few years and be ready making style adjustments in their item accordingly.
It is crucial that a firm integrates their sales and marketing division in a well made fashion. It is the correct integration of these 2 vital entities that fuels the growth of a firm. The sale individuals need to not be just alleviated as the cash enthusiasts. Each division has its very own role and also must work together in selling the item of the business as well as ought to be the primary vital requirements.
Word Matter 551


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Park City, UTUSA
Hometown: Park City
April 6, 2014
Local jazz events as well as the Telluride Festival.
BB King, Eric Clapton, Coco Montoya, Tedeschi Trucks Band, Albert King, Buddy Guy, Jarvenpaa Finland Festival, Greg Alllman
Electric and Acoustic Guitar and Banjo
Music is a big part of my life and I enjoy listening as well as playing and performing.
Warm and fun group
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Flights to Portland from Cairo
Flights to Portland from Cairo
Flights Cairo - Portland fly from Cairo to Portland at the best prices in the market. Flights from Cairo (Cairo) to Portland (Portland - Oregon) with Destinia. To search for availability and reserve your flight Cairo - Portland look at the box above and select the departure and return date as desired. You can also buy several airplane tickets Cairo (Cairo airport) - Portland (Portland - Oregon airport) at the same time, by selecting the adults, children and babies travelling. You can filter the type of flight if you only want direct flights to Cairo - Portland, multiple destinations or flight stopovers.
Cairo and Portland are 13437 kilometres away from each other, with an estimated flight time of 19:12 h (this may vary depending on the weather or air routes)
Airports near Portland
Portland has one airport: Portland - Oregon (PDX), located 10 km away from the city centre. The hotels in Portland closest to its airport are:
- Hyatt Place Portland Airport Cascade Station (PDX) from €80€
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All Portland airports
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Book your flights now from Portland (United States) to the most important cities in the world. The box below contains flights from Portland (United States) to the most important cities.
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Why Frodo? Why? Trailer for Maniac
By Steven Lloyd Wilson | Trailers | November 7, 2012 | Comments ()
Apparently Elijah Wood, of the creepy eyes, hairy feet, and constant flirting with Sean Astin (only two of those three can be attributed to Peter Jackson's CGI, so I choose to believe that all three are real), has decided that the turn he took as a psychotic murderer in Sin City suits him quite well. He's now starring in a remake of the exceedingly low budget 1980 film Maniac. It was so low budget that they filmed many scenes as quickly as they could on the fly since they didn't actually have filming permits.
The film had this poster which just screams for needing a remake:
Wow, modern art right there.
Here are some of the reviewer quotes about the original movie:
"Good sense, if not heaven, should protect anyone who thinks he likes horror films from wasting a price of admission on "Maniac," a movie that shows how an aging, pot-bellied maniac slices up young women of no great intelligence." -Vincent Canby
"Maniac (1980) is alternately repellent and boring, despite the obvious intelligence that went into its making." -Stuart Galbraith IV
Gene Siskel walked out of the film after 30 minutes, insisting that no matter what happened in the rest of the movie, it "could not redeem itself."
If this is getting remade, they might officially be running out of movies to remake. But hey, this time they're telling the story from the point of view of the killer! That's like so totally different. I mean come on Frodo, don't you have any royalties coming in from New Zealand? Here's the trailer, that other than the nudity and amount of violence, just made me keep expecting that it would cut to the opening credits of "Criminal Minds".
I'd pay real money if the film ends with Elijah Wood dancing with a chair and pouring a bucket of water on himself.
Pajiba Love Express
Here's some Daveed Diggs for you. On Daveed Diggs' digs, actually. That man does things with clothes that should not make sense, but are absolutely perfect. (Go Fug Yourself)
Woody Allen has "so moved on" from his daughter's accusations and says he never even thinks about it. He equates her words about him to a bad review he won't read and comments on how wacky it is that Mia Farrow is his mother-in-law. He is the worst. (Celebitchy)
Not The Worst but still very gross: Leonardo DiCaprio and his
Here are 5 under-the-radar shows. I had never even heard of the first two. (Uproxx)


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Great composition, marlene, I like it a lot!
Merry Christmas and Happy New Year!
Greetings, Agneta
Hello Marlene I wish you and all your Love Ones a Bless and Holy Christmas.Warmest Greetings from my home to your home.
Well done Marlene. The view is north, I suppose. L33
Greetings FD
i v a n n a... leone... cecemil.. Agneta... Anand... and... flyingdutchman...
Thank you all very much for the great comments. I'm happy you Like it! @ FD... Rush St., looking north!
Happy Holidays to all!
Fantastic picture of the big city. LIKE. Best wishes, volnat.
volnat... and... Anne...
Thank you both very much for the great comments. I'm happy you Like it!
Happy Holidays, Marlene
excellent shot
very beautiful
Thank you very much, Akbar & Armaghan, for the nice comment and the Like. Much appreciated!
Best regards, Marlene
Very beautiful picture. Very nice colors, Very elegant shot.Marlene
Merry Christmas and a Happy New Year to you and your family as well..
Best wishes, İsmail
Ismail... and... Mahdi...
Thank you both very much for the nice comments, the good wishes and the Likes. All are much appreciated!
All the best to you both in the New Year, Marlene
Thank you so much, Alireza, for the very nice comment, the good wishes & the Like. I appreciate it very much.
Best wishes to you in the New Year, Marlene
Fascinating light in this great perspective!
Greetings from Italy, Martin
Excellent image and nice idea Marlene, ...liked , greetings from Macedonia and happy new year, Ahmet
Świetne zdjęcie
Pozdrawiam, Marek
Maravilhosa foto,muito bonita.Like.
Um Feliz Natal e Feliz Ano novo.
Saudações Brasil.
Nice enquadre and beautiful colors !!
I wish you merry Christmas and happy New year.
Warm greetings from Paolo, Italy.
like !
I Like!
Merry Christmas and a Happy New Year for you and your family!
Edward Galagan
Martin... Ahmet... Marek... Ueliton... PAT... and Edward...
A big thank you to each of you for the very nice comments, the good wishes and the Likes. All are much appreciated!
Happy Holidays to you & yours, Marlene
Photo taken in Near North, Chicago, IL, USA


text: 'Penis Brothers' Force You To Take Your Pants Off in Rust Or DieTina Amini2/06/14 11:00amFiled to: nsfwkotakucorerustwatch thishumor3597EditInvite manuallyPromoteDismissUndismissHideShare to KinjaToggle Conversation toolsGo to permalink What the...Ok, so we all know that socializing is kind of hit or miss in games like Rust or DayZ, but I...what? Beware that there are digital penisi as well as foul language that some might find funny, others more questionable. Advertisement The short of it is that there's a band of self-named "Penis Brothers" wandering around naked together and forcing players they meet to choose: take your pants off or they kill you. If you do decide to embrace the way of the brotherhood, they'll initiate you. Which, as I'm sure you can imagine, is as crude as the entire act itself is. It involves lining up in a "penis train" formation and thrusting into each other (or emulating the act of thrusting as best as a keyboard will allow). Sponsored Yeah...you've been warned, I guess? (via Destructoid) To contact the author of this post, write to email@example.com or find her on Twitter at @tinaamini.Reply359 repliesLeave a reply


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As Israel stands accused of "war crimes," HonestReporting's primer examines the failings of the Goldstone Report.
Christian Science Monitor: Erasing Jewish Rights
Walter Rodgers goes far beyond a simple debate over settlements.
HRW: Too Little Too Late
Human Rights Watch finally issues a report on Hamas rocket attacks.
The New York Times: Just the Facts?
A six month study of the New York Times shows a bias toward the Palestinian narrative.
Guardian: The "So-Called Threat from Iran"
As recently as May 2009, HonestReporting critiqued Guardian columnist Jonathan Steele's justification for Palestinian terror against Israel and his tacit support for foreign leaders who give it their backing. Continuing in the same vein, Steele now writes about US President Obama's recent Mideast speech, stating that: Short of helping to resolve the Arab-Israeli conflict, the…
Adbusters' Spurious Gaza – Warsaw Ghetto Comparison
A Canadian magazine abuses Holocaust imagery to attack Israel.
Terror No Obstacle to Peace?
The Independent mysteriously omits years of Palestinian terrorism.
Guardian Columnist Justifies Terror
Jonathan Steele says states are entitled to support Palestinian terror.
Disgrace at Durban 2
Shouldn't the UN be promoting human rights instead of racism as the organization's integrity takes a pounding?
"War Crimes" and Shoddy Journalism
Ha'aretz and The Guardian's war crimes allegations debunked.


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Had the Jerk Tuna and it was Amazing! Great spot with live music. We celebrated my wife's birthday there and it was perfect.
Your coupon (that we'll email you) gets you 20% off when you spend at least $250 on tours, activities and more that you can book on TripAdvisor or Viator. The more you spend, the more you save!
To learn more about this Book on TripAdvisor Bonus, Viator, and the full list of official rules, click here.


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|Publication number
|Publication type
|Publication date
|Jan 18, 1972
|Filing date
|Apr 24, 1969
|Priority date
|Apr 24, 1969
|Publication number
|Dunn Howard E
|Original Assignee
|Phillips Petroleum Co
|Export Citation
|BiBTeX, EndNote, RefMan
|Referenced by (7), Classifications (9)
|External Links: USPTO, USPTO Assignment, Espacenet
United States Patent 3,636,128 OLEFIN OLIGOMEREZATION WITH A NICKEL- CONTAINING CATALYST SYSTEM Howard E. Dunn, Bartlesville, Okla, assignor to Phillips Petroleum Company No Drawing. Filed Apr. 24, 1969, Ser. No. 819,105 Int. Cl. C07c 3/10 US. Cl. 260-683;.15 D 5 Claims ABSTRACT OF THE DISCLOSURE Olefins such as propylene are oligomerized to products such as dimers with a catalyst system comprising an organoaluminum compound such as ethylaluminum dichloride and a nickel complex such as [l,2-bis(diphenylphosphino)ethylene]dichloronickel, wherein the nickel component can be recovered and recycled to the oligomerization zone.
This invention relates to a process for the production of olefin oligomers such as olefin dimers, trimers, tetramers, and the like.
Various homogeneous catalyst systems, including a number of nickel-containing catalyst systems, are known to the art which are quite active with respect to the oligomerization of olefins, particularly to dimers.
It has now been found that olefins can be effectively oligomerized by contact with a catalyst system which is formed from an organoaluminum compound and a nickel complex which nickel complex is easily recoverable from the reaction mixture and which is reuseable in the oligomerization process. This nickel complex is a nickel complex such as [1,2 bis(diphenylphosphino)ethylene]dichloronickel.
Accordingly, it is an object of this invention to provide a process for the production of olefin oligomers.
Another object of this invention is to provide an olefin dimerization catalyst system containing a nickel complex which is easily recoverable and reuseable.
Other aspects, objects, and advantages of this invention will be apparent to one skilled in the art from the disclosure and claims.
Cyclic and acyclic monoolefins having from 2 to 12 carbon atoms per molecule can be oligomerized according to the process of this invention. These olefins can be branched or unbranched, but the branching is preferably at least one carbon removed from the double bond. Specific examples are ethylene, propylene, butene-l, butene- 2, pentene-l, pentene-2, cyclopentene, cyclohexene, 3- methylbutene-l, cycloheptene, hexene-Z, heptene-l, cyclooctene, 4,4-dimethylheptene-2, decene-l, dodecene-l, and the like, and mixtures thereof.
The catalyst employed according to the process of this invention is formed from two components.
The first component of the catalyst system is represented by the formula [(R PCR=CR"PR )Ni] Y wherein each R is a hydrocarbyl radical having from 1 to carbon atoms; each R" is hydrogen, an alkyl radical having from 1 to 5 carbon atoms, or a phenyl radical; each Y is an organic or inorganic anion; m is an integer from 1 to 3; and n is an integer from 1 to 2 depending on the valence of Y. Preferably, R is an alkyl, cycloalkyl, or aryl radical, or a combination thereof and Y is a halogen, a pseudo halogen, or a carboxylate radical. Still more preferably R" is hydrogen, Y is a halogen, m is the integer 1 and n is the integer 2.
Specific examples of R groups are methyl, ethyl, 2- ethylhexyl, phenyl, allyl, propargyl, benzyl, cyclohexyl, dodecyl, eicosyl, and the like. Specific examples of R groups are hydrogen, methyl, n-propyl, 3-methylbutyl, phenyl, and the like. Specific examples of anions are chlo- 3,635,128 Patented Jan. 18, 1972 ride, bromide, iodide, fluoride, cyanide, cyanate, thiocyanate, acetate, benzoate, sulfate, and the like.
These nickel complexes can be prepared in any conventional method known to the art. For example, the nickel complex of the 1,2-bis(diphenylphosphino)ethylene can be prepared as described in Inorg. Chim. Acta 1(1), 141- 4 (1967) (Eng).
Other specific examples of these nickel complexes are:
[ 1,2-bis dimethylphosphino ethylene] dibromonickel;
[1,2-bis (dibenzylphosphino ethylene diiodonickel;
[ 1,2-bis dicyclohexylphosphine ethylene] difluoronickel;
[ l,2- bis( di'o-tolylphosphino ethylene] dicyanatonickel;
[1,2-diphenyl-1,2-bis(dieicosylphosphino)ethyene] dibenzoatonickel;
[ l-methyl-1,2-bis(di-t-butylphosphino) ethylene] dicycanonickel;
[1,2-dipentyl- 1 ,2-bis dioctylphosphino) ethylene] dichloronickel;
[1,2-bis (diallylphosphino)ethylene] dibromonickel;
[1,2-bis dipropargylphosphino ethylene diacetatonickel:
( 1-diphenylphosphino-2-diethylphosphinoethylene) dibromonickel;
[1,2-bis(dihexylphosphino)ethylene]dichloronickel; and
the like, and mixtures thereof.
A second component of the catalyst system is an organoaluminum compound represented by the formula. R AlX wherein R is a hydrocarbon radical having up to 20 carbon atoms, X is a halogen, x is an integer from 1 to 3, and y is 0 or an integer from 1 to 2 and x plus y equals 3. These compounds are well known in the art and can be prepared by conventional methods. Specific examples are methylaluminum dichloride, dimethylaluminum chloride, diethylaluminum bromide, ethylaluminum dibromide, triethylaluminum, vinyl aluminum diiodide, tributylaluminum, dibutylaluminum chloride, phenylaluminum dibromide, dibenzylaluminum chloride, 4-tolylaluminum dichloride, dodecylaluminum dibromide, eicosylaluminum difiuoride, and the like, and mixtures thereof. Preferred compounds are the organoaluminum halides in which the R groups are the lower alkyl radicals.
Generally, the mole ratio of organoaluminum compound to nickel complex ranges from 0.5 :1 to 20:1 and the mole ratio of nickel complex to olefin ranges from 0.0000111 to 0.111. A larger amount of aluminum component is frequently desirable to scavenge catalyst poisons which may be in the system.
The catalyst is prepared by simply combining the first and second catalyst components under conditions of time and temperature which permit the catalytically active reaction product to be formed. This combination occurs very readily and, in general, the components can be mixed at any convenient temperature within the range of to about C. for a few seconds or for a period of time up to several hours generally in the presence of a diluent, if desired, in which both the components are at least partially soluble. Any convenient inert diluent, such as benzene, heptane, cyclohexane, chlorobenzene, methylene chloride, ethylene chloride, and the like can be used for this purpose. Halogenated diluents are generally preferred. The mixing of the two catalyst components is generally carried out in an inert atmosphere in the substantial abscence of air or moisture. After the catalyst is formed, it need not be isolated but can be added directly to the olefin dimerization zone as a solution in its preparation solvent. If desired, catalyst components can be separately added, in any order, to the reaction zone, either in the presence or absence of the feed olefin.
The oligomerization of the olefin or mixture of olefins can take place at any convenient temperature within the range of 80 to 200 C., preferably l0 to 50 C. The
reaction can be carried out at any convenient pressure which is sufiicient to keep at least some olefin feed dissolved in the reaction medium. Thus, the reaction is carried out in the liquid phase with pressures ranging from about to 2000 p.s.i.g. The reaction can be carried out either in the presence or absence of a diluent, preferably in the presence of a diluent such as those described for the catalyst preparation. The time of contacting generally ranges from 0.1 minute to 20 hours, preferably to 120 minutes.
Any contacting technique can be utilized for the olefin conversion, such as batchwise or continuous operation. After the reaction period the products can be separated or isolated by conventional means such as fractionation, crystallization, adsorption, and the like. If desired, the catalyst can be destroyed by treatment with water prior to the separation of the products. In addition to dimers, varying amounts of other oligomers such as trimers, tetramers, and the like can also be formed in the reaction.
A feature of this invention is the fact that the nickel complex can be separated from the reaction mixture and reused in the catalytic olefin oligomerization zone. This complex is recovered by treating the reaction mixture with water or an aqueous acid solution such as aqueous hydrochloric acid. This treatment immediately kills the catalyst activity by destroying the aluminum component. Simultaneously, there is a precipitation of the nickel complex. The amount of Water or acid which is used as this point is not critical but should be at least an effective amount sufiicient to destroy the aluminum component, preferably a substantial excess of water or acid is used.
The nickel complex is recovered by simple filtration of the treated reaction mixture. The solid complex is then dried. It can then be recycled to the catalytic zone to be admixed with additional altuninum component for use in the oligomerization reaction.
The advantages of this invention are further illustrated by the following examples. The reactants and proportions and other specific conditions are presented as being typical and should not be construed to limit the invention unduly.
EXAMPLE I To a dry reactor were added 0.0922 gram of [1,2-bisdiphenylphosphino)-ethylene]dichloronickel and 20 ml. of chlorobenzene. To this solution was added 1.5 ml. of ethylaluminum chloride and chlorobenzene. The reactor was then maintained at a temperature 1620 C., and propylene was pressured into the vessel at 30 p.s.i.g. and maintained at that pressure for 1 /2 hours. Propylene consumption was rapid. At the end of the reaction period, the reaction mixture was quenched with ml. of distilled water. A solid precipitate appeared. The organic phase was separated and 26.2 g. of propylene dimers were recovered by distillation.
A two ml. portion of the dimers was reduced with hydrogen over a platinum oxide catalyst to determine the isomer distribution. Gas-liquid chromatographic analysis of the hydrogenated sample showed the presence of 66.5 weight percent Z-methylpentane, 28.8 weight percent normal hexane, 4.1 weight percent 2,3-dimethylbutane, and 0.7 weight percent of 3-methyl pentane.
The above data show that the present catalyst system is very active for the conversion of propylene to dimers.
EXAMPLE H The solid which was recovered from Example I by filtration was washed with Water. It was then dried in a vacuum over 120 C. for about 45 minutes. The solid was then charged to a reactor with 20 cc. of chlorobenzene. To the solution was added 1 ml. of a 1 molar ethylaluminum dichloride solution in chlorobenzene. The reactor was then maintained at a temperature of about 13 C. and propylene was pressured into the flask at 30 p.s.i.g. and maintained at that pressure for 1.5 hours.
After the reaction period, the reaction mixture was quenched by the addition of 10 cc. of water. The organic layer was separated and distilled yielding 35.14 grams of propylene dimers.
After hydrogenation and analysis by gas-liquid chromatography, a sample of the product showed the presence of 71 weight percent Z-meLhyl-pentane, 24.5 weight percent of normal hexane, 4.1 weight percent of 2,3-dimethylbutane, and 0.3 weight percent of S-methylpentane.
The above data demonstrate that the nickel complex can be easily recovered and reused to form a catalyst system which is effective for the conversion of propylene to dimers.
Although this invention has been described in considerable detail, it must be understood that such detail is for the purpose of illustration only and that many variations and modifications can be had by one skilled in the art without departing from the spirit and the scope thereof.
I claim:
1. A process for oligomerizing l-rnonoolefins having 2 to 12 carbon atoms comprising contacting under reaction conditions at least one said l-monoolefin with a catalyst system comprising an organoaluminum compound R AlX wherein R is a hydrocarbon radical having from 1 to 20 carbon atom, X is a halogen, x is an integer from 1 to 3, y is 0 or an integer from 1 to 2, and 2: plus y equals 3 and a nickel complex (R PCH=CHPR ')NiX wherein each R is alkyl, cycloaikyl, or aryl radical having up to 20 carbon atoms;
wherein the mole ratio of said organoaluminum compound to said nickel complex ranges from 0.511 to 20:1, and the mole ratio of said nickel complex to said 1-monoolefin ranges from 0.00001:1 to 0.111; and
wherein said nickel complex is recovered by admixing an eiiective amount of water or aqueous acid solution with the reaction mixture and recovering said nickel complex as the formed precipitate, and wherein said recovered nickel complex is recycled to the catalytic zone.
2. A process according to claim 1 wherein said l-monoolefin is propylene.
3. A process according to claim 1 wherein said organoaluminum compound is ethylaluminum dichloride.
4. A process according to claim 1 wherein said contacting is carried out at a temperature range of to C., at a pressure ranging from 0 to 2000 p.s.i.g., and for a time ranging from 0.1 minute to 20 hours.
5. A process according to claim 1 wherein said nickel complex is [1,2 bis(diphenylphosphino)ethylene]dichloronickel.
References Cited UNITED STATES PATENTS 3,405,194 10/1968 Iwamoto et al. 260-680 3,482,001 12/1969 Eberhardt 260-683.15 3,485,881 12/1969 Zuech 260-68315 X 3,511,891 5/1970 Taylor et al 260-683.l5
PAUL M. COUGHLAN, 111., Primary Examiner US. Cl. X.R. 252-431 P
|Citing Patent
|Filing date
|Publication date
|Dec 8, 1977
|Sep 5, 1978
|Phillips Petroleum Company
|Organophosphorus nickel complexes and use thereof
|Nov 8, 1976
|Oct 31, 1978
|Phillips Petroleum Company
|Trans-halo(acyl)bis(triethylphosphine)nickel(II) complexes and preparation thereof
|Dec 8, 1977
|Mar 13, 1979
|Phillips Petroleum Company
|Organophosphorus nickel complexes and use thereof
|Dec 8, 1977
|Mar 20, 1979
|Phillips Petroleum Company
|Preparation of organophosphorus nickel complexes
|Aug 3, 1978
|Dec 25, 1979
|Phillips Petroleum Company
|Trans-halo(acyl)bis(triethylphosphine) nickel(II) complexes
|Dec 13, 1983
|Aug 27, 1985
|Phillips Petroleum Company
|Surface conditioning in olefin dimerization reactors
|Apr 4, 2003
|Apr 22, 2004
|Hai Lin
|Two-ply flooring having a cross-grain bottom ply
|U.S. Classification
|585/504, 502/113, 585/513
|International Classification
|Cooperative Classification
|European Classification


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Dancing The Pain Away
A while back, a reader asked me the following question:
"Thank for emails. Dancing is a physical expression of the body by showing one's joy, happiness or of a given emotion. Some dance for money and other dance generally because their emotion is excited.
The question is that, why can't we dance when we get sad?
The second question derives from the first: CAN DANCING CURE SADNESS?"
There's no reason why we can't dance when we're sad. In fact, if that's how the body feels compelled to move then I fully encourage it. Whether or not the reason is happy or sad is irrelevant. What is relevant is that the dancing arises from a natural desire for the body and spirit to express themselves.
The body has incredible wisdom about how, when, and where it wants to move. If we can pause and be present long enough to listen to our bodies, we'll discover an incredible amount of wisdom that was previously hidden to us.
As such, dancing absolutely can help us work through difficult emotions. In fact, any authentic experience and expression of ourselves can do this. To piggy-back off my answer to the first question, when we experience and express ourselves fully and authentically, we release whatever energy is stuck within us.
That energy could be "happy" or "sad" energy, as well as every other energy we can experience as human beings. No matter what, the energy wants to be expressed. By expressing it (such as through dancing), you free yourself from the limitations that occur by "holding onto" the stuck energy within yourself.
Allowing that process to naturally unfold will allow your inner wisdom to arise.
From that wisdom, you'll naturally take actions that help you transform your more difficult and painful emotions into postive, empowering, pleasurable emotions.
Though we're talking about dancing, this really applies to any form of authentic self-expression. It's not important what you do… what matters is that you maintain self-awareness while you do it. My program Liberate Your Life helps you do that.
And if you find yourself having difficulty taking action, another option is to "Force the Issue." In my recent article in the "Law of Attraction Key," I expand on this in more detail. Click here and read that article.
Free Teleseminar Series – Healing With The Masters has become the 'go to' place to join with other participants and experience the leading speakers and authors guiding each of us to find the life, flow, peace, and joy that were meant for us. 32 committed speakers are lined up just for you... to guide you, love you, and help you to re-align with your dreams, AND show you how you can make a difference.
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KKCR has joined Radio Free America (RFA). RFA provides free archiving of non-commercial radio stations like KKCR. All KKCR programs, including music, will be archived for two weeks after the air date. Radio Free America archives of KKCR programs began on July 11, 2016 at 8pm. Click here to enjoy any KKCR program you may have missed on Radio Free America.
Archived programs prior to July 11, 2016 8pm will stay here (listed below and on linked pages) for now.
|July 26, 2016
Kaua`i Chamber of Commerce Presents 2016 Political Forums
State Representative District 15 Candidates: Tommy Oi & James Tokioka
Kaua`i War Memorial Convention Hall 6:30 - 7:30pm
|July 14, 2016
Kaua`i Chamber of Commerce Presents 2016 Political Forums
State Representative District 14 Candidates: Nadine Nakamura & Fern Anuenue Rosentiel
Kapa`a Middle School cafeteria 6:30 - 7:30pm
|July 7, 2016
Out of the Box ~ Thursdays 4-6pm
Host: Jimmy Trujillo
|July 6, 2016
In the Garden, On the Farm
Host: Paul
Fermentation with Sandor Katz
Beyond the Barcode with Michael Pollan
|July 5, 2016
Kaua`i Soapbox ~ Tuesdays 4 - 6pm
Host: Felicia Cowden
Guests: Koohan Paik, Joanna Carolan, Greg Askew, Bridget Hammerquist, Eileen Kechloian
Newly discovered moon, PMRF installation of defensive intercepting missles, Marianna Islands, Vending on County property, Hanapepe Economic Alliance - Friday Art Night July 25th
|July 4, 2016
Living Sovereign
Host: Puanani Rogers
Guest: Terry Lilly
Queen Liliokalani's statement on the overthrow. RIMPAC's impacts on the ocean
|July 2, 2016
Na Leo Hawaiian Issues ~ Saturdays 11am to 1pm
Host: Nakoa & Mahelani


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I have to put down my CC to hold the reservation and they do charge a fee for last minute cancellations so do not RSVP for this unless you can commit to it. You must update your RSVP 48 hours prior to the event to give ample time to notify those on wait-list of their status. I will be keeping track of no-shows.
IMPORTANT NOTES: Please note that Rhonda is hosting the family style dinner on the 24th. This event is to allow those who want to order off the menu an opportunity to join me on an earlier night.
Also - Watch your RSVP's! DO NOT DOUBLE-BOOK YOURSELVES. There are two (2) events going on at the same time this evening. Cafe Juanita and Fabulous French Fridays in February – French Surprise – Quatre.
About Café Juanita:
The menu at Cafe Juanita changes frequently, but always includes an eclectic mix of meats and seafood, illustrating the commitment to fresh, bold dishes that most often utilize organic products. As a member of the food community, Chef Holly believes in sustainable agriculture, supporting growers whose outstanding quality is tantamount to their long-term commitment to the land. In addition to nurturing the farm industry, Cafe Juanita is committed to offering great wine. The menu is complimented by an award-winning wine list with primary focus on Northern Italian producers and rounded-out with outstanding Northwest wines.
Notable Recognitions - Seattle Times:
Beloved destination dinner-house better than ever with new decor and chef. Inspired by a passion for Northern Italy. Long on innovation, artistry, and superior ingredients. Meat, fish and fowl star. Wine list richly endowed.
Awards & Reviews:
This restaurant also won Zagat and USA Today Road Warrior's #1 Italian Restaurant in Seattle.
April 2012 - Opininated About Dining ranks Cafe Juanita in the top 10 for Italian Restaurants in the USA and Top five in the Pacific Northwest
February 2012 - Chef Holly Smith is nominated for Outstanding Chef in the US by the James Beard Foundation
January 2012 - Open Table list of Top 100 Best Restaurants in the US 2011, includes Cafe Juanita.
PRICE – Spendy ($$$$). Last two times I have been here, I ended up spending $150 (just for myself which included wine, tax + tip) Plan on spending anywhere from $50+, before tax & tip. The restaurant will split the check for each of us.
ATTIRE – Dressy.
PARKING - Private Lot
Pictures from my fellow foodies
0 · February 22, 2013
0 · February 22, 2013
Foodies, if you are unable to join us on Friday, PLEASE PLEASE PLEASE update your RSVP in advance since we have 7 folks still waiting to attend the event w/ us. Waiting until the last min/day to un-RSVP yourself will not give our waitlisters enough time to be notified and it will disrupt our reservation. Let's end the work-week w/ a fabulous meal there and I'll see you all Friday!
0 · February 19, 2013
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Innovative thermoforming sheet lines convince customers from around the world
The company battenfeld-cincinnati will showcase high-performance Multi-Touch roll stack at K booth.
The company battenfeld-cincinnati will showcase high-performance Multi-Touch roll stack at K booth.
Supplier of flame retardants synergists will launch a new range of high-performance flame retardant (FR) synergists at the K 2016 exhibition.
Under the motto "be smart", Wittmann Battenfeld will present numerous innovative novelties at the K 2016 in Düsseldorf.
Billion Electric launches compact 4G/LTE M2M routers for industrial applications.
Engel Austria's apprentices are among the best in the country.
Sidel delivers mixing and filling accuracy fot bottlineg carbonated soft drinks.
From October 19 to 26, the chemical company will present extraordinary solution approaches and creative ideas developed in close collaboration with customers.
The company will be presenting its latest pressure forming machine at K 2016 in Düsseldorf
Three-wheeled concept model 05GEN adopts BASF's plastics solutions including Infinergy and Elastollan.
At K 2016 battenfeld-cincinnati will be introducing the solEX NG, a newly developed series of high-performance single screw extruders.
In Düsseldorf Milliken will give center stage to the advantages of using its technology leading clarifiers and nucleators to improve PP.
SABIC next-generation Flowpact PP enables downgauging and easier processing for rigid packaging.
Ci7800 Spectrophotometer and Color iMatch Software help Plastic Resin deliver fast, accurate small batch customer colors to molders.
The new GLX-3 Laser Welders from Branson Ultrasonics delivers clean, high speed laser welding of large-format plastic parts with more complex geometries.
Henkel's Loctite Impregnation Solutions provides a fast and reliable fix for the automotive industry.


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I wanna use an image viewer control in silverlight with feature zoom in/out the image, I found "MultiScaleImage" control that accept source as Xml file, which is can be created by "Deep Zoom Composer" program (install this program: import the images then expose and export: the program will generate the images and the "dzc_output.xml" file for you).
My Question is: I have a images(paths) that comes from the Database, how can I create the xml file at runtime without using the "Deep Zoom Composer" program!!!, I think this is impossible :(
Sooooooo anybody knows a silverlight control that I can use to view image with zoom in/out?????????


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Tacoma, WAUSA
October 2, 2013
Hi, I really like all kinds of dancing but it has been awhile since I have danced regularly. I am looking forward to getting out on the dance floor more. :) Swing is one of my favorites!
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