text:
|Publication number
|Publication type
|Application number
|Publication date
|May 12, 1987
|Filing date
|Mar 17, 1986
|Priority date
|Aug 5, 1980
|Fee status
|Publication number
|Brent J. Bertus, Dwight L. McKay, H. Wayne Mark
|Original Assignee
|Phillips Petroleum Company
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (39), Referenced by (8), Classifications (18), Legal Events (4)
|External Links: USPTO, USPTO Assignment, Espacenet
This application is a division of Ser. No. 427,256, filed Sept. 29, 1982, now allowed, U.S. Pat. No. 4,584,283, a continuation of Ser. No. 175,622, filed Aug. 5, 1980, now abandoned.
The present invention relates to catalysts. In another aspect, the present invention relates to hydrocarbon cracking catalysts. In still another aspect, the invention relates to restoring the activity of hydrocarbon cracking catalysts. In yet another aspect, the invention relates to cracking a hydrocarbon feedstock.
Contaminants, for example, nickel, vanadium, and iron are found in significant concentrations in hydrocarbon feedstocks such as, for example, heavy oil fractions and in lower quality crude oil. These contaminants have a poisoning effect on the catalysts employed to convert these oils into gasoline and other vaulable petroleum products, making processing of these oils economically unattractive. Unfortunately, because of limited supplies of oils containing low levels of contaminants, it is necessary to employ metals contaminated oils in hydrocarbon processes, such as catalytic cracking processes.
The contaminants found in feedstocks to cracking processes become deposited on the cracking catalyst. The deposition on the catalyst of, for example, nickel, vanadium and iron, causes a decrease in the activity of the cracking catalyst to convert the hydrocarbon feedstock into cracked products, including gasoline. The selectivity of the cracking catalyst for cracking the feedstock into gasoline as manifested by the portion of cracked products comprising gasoline is also decreased. The production of undesirable products, for example, hydrogen and methane, which must be compressed, necessitating additional equipment; and coke, which is deposited on the catalyst and must be burned off, requiring additional equipment and "off time", during which the catalyst is not employed for cracking is significantly increased.
Because of these problems, the industry often replaces cracking catalysts contaminated by more than about 3,000 parts per million (ppm) of vanadium equivalents and iron. As used herein, the term vanadium equivalents is the measure of the combined parts by weight of vanadium and four times the nickel per million parts by weight of cracking catalyst including the weight of nickel, vanadium and iron on the cracking catalyst. There is thus a need for a cracking process suitable for use with contaminated feedstocks and contaminated cracking catalysts. There is also a need for a cracking catalyst which is only minimally adversely affected by deposits thereon of contaminants selected from nickel, vanadium and iron. There is also a need for a process of treating a contaminated cracking catalyst to increase its activity for conversion of the feedstock and selectivity for producing gasoline and to decrease the catalyst selectivity for undesirable products, for example, hydrogen and coke.
It is thus an object of the present invention to provide a method for restoring the activity of a contaminated cracking catalyst.
It is a further object of this invention to provide a restored cracking catalyst wherein contaminants such as nickel, vanadium and iron on cracking catalyst are passivated.
It is another object of this invention to provide a process for cracking hydrocarbons wherein the deleterious effects caused by metals on the cracking catalyst are at least mitigated.
These and other objects of the present invention will be more fully explained in the following detailed disclosure of the invention and the appended claims.
In accordance with the present invention, a catalyst composition comprises a cracking catalyst and a treating agent selected from aluminum and aluminum compounds.
Further, according to the invention, a contaminated cracking catalyst is improved by contacting the cracking catalyst with aluminum or a compound thereof.
Still further in accordance with the invention, a hydrocarbon feedstock is catalytically cracked employing the above described catalyst composition.
Still further, according to the invention, at least one metal selected from nickel, vanadium and iron in contact with a cracking catalyst is passivated by contacting the cracking catalyst with a treating agent selected from aluminum and aluminum compounds.
Still further, according to the invention, a used cracking catalyst contaminated by at least 3000 ppm vanadium equivalents, is at least partially restored by contact with a treating agent selected from aluminum and aluminum compounds.
It has been discovered that the adverse effects of nickel, vanadium and iron on a cracking catalyst can be at least mitigated by contacting the cracking catalyst with a treating agent selected from aluminum and aluminum compounds. The treating agent can be selected from most any source of aluminum such as elemental aluminum, inorganic aluminum compounds, and organic aluminum compounds. Suitable inorganic aluminum compounds include salts, for example, aluminum nitrate, aluminum sulfate, or alums that have the epimirical formula AlM(SO4)2, where M is NH4 40 + or a member of Group IA of the periodic table, as found at page 83 of the Handbook of Chemistry and Physics, 54th edition (1973-74), published by the Chemical Rubber Company Press, Cleveland, Ohio. Less preferred are halogen-containing aluminum salts, for example, AlX3 or Al(XO3)3, where X is selected from the group Cl, Br and I, because of the corrosive effect of these halogens on process equipment. Suitable organic compounds can be represented generally by the formula AlR3 wherein R is an organic moiety. Included within this group are the salts of carboxylic acids, (R'COO)3 Al wherein R' is hydrogen or a hydrocarbyl radical having from 1 to about 20 carbon atoms. Examples of suitable carboxyl compounds include aluminum acetate, aluminum propionate, aluminum butyrate, aluminum decanoate, aluminum stearate, and the like. Polyfunctional carboxylates, such as aluminum citrate, can also be utilized. Other suitable organic compounds are for example, aluminum tris(hydrocarbyl oxide)s--Al(OR")3 --wherein R" preferably contains one to about 20 carbon atoms and can be an alkyl, alkenyl, cycloalkyl, or aryl radical, or a combination or radicals such as alkylarlyl, arylalkyl, alkylcycloalkyl, and the like. Examples of suitable oxyhydrocarbyl compounds are aluminum isopropoxide, aluminum tert-butoxide, aluminum phenoxide, aluminum decyloxide, and the like. Other suitable organic compounds are for example, aluminum alkyls--AlR"'3 --where R"' can be an alkyl group containing 1-20 carbon atoms, preferably one to five carbon atoms. Examples of suitable hydrocarbyl compounds are triethylaluminum, tributylaluminum, diethylpentylaluminum, and the like. It is recognized that these compounds are pyrophoric and must be treated accordingly. R', R", and R'" can be substituted with, for example, halogen, sulfur, phosphorus or nitrogen. Of course, mixtures of any of the above compounds may be utilized. The aluminum-containing treating agent of this invention can also be utilized in combination with other passivating agents, for example, passivating agents containing elements selected from Groups IVA, VA and VIA of the Periodic Table.
It is most preferable in accordance with the present invention to contact the cracking catalyst with at least one promoting agent selected from sulfur compounds and phosphorus compounds in addition to the at least one aluminum compound. The source of phosphorus employed in this aspect of invention can vary widely and can be any phosphorus composition which will enhance the passivation qualities of aluminum, or the promotion quality of sulfur for enhancing the passivating qualities of aluminum. Exemplary inorganic sources of phosphorus usefully employed in accordance with the invention include the white, red, violet and yellow forms of elemental phosphorus. Phosphorus halides for example phosphorus fluoride, phosphorus chloride, phosphorus bromide, phosphorus iodide and heterohalides such as phosphorus dibromotrichloride can also be usefully employed. Nitrogen containing inorganic phosphorus compounds such as phosphorus dichloronitride and phosphorus cyanide can also be used as the phosphorus source. Phosphine is also suitable for use. Exemplary of suitable phosphorus oxides which can be used in accordance with the invention are phosphorus trioxide, phosphorus tetraoxide, phosphorus pentaoxide, and phosphorus sesquioxide. Oxygen containing phosphorus compounds for example phosphorus oxychloride, phosphorus oxybromide, phosphorus oxybromide dichloride, phosphorus oxyfluoride, and phosphorus oxynitride can also be used in accordance with the invention. Phosphorus selenides and phosphorus tellurides can also be used in accordance with the invention. Exemplary of this class of compounds are phosphorus triselenide and phosphorus pentaselenide. Exemplary of suitable phosphorus acids which can be used in accordance with the invention are hypophosphorous acid, metaphosphoric acid, orthophosphoric acid, and pyrophosphoric acid. The source of sulfur employed in this aspect of invention also can vary widely and can be any sulfur composition which will enhance the passivation qualities of aluminum or the promotion quality of phosphorus for enhancing the passivation qualities of aluminum. Exemplary inorganic sources for sulfur include the alpha, beta and gamma forms of elemental sulfur. Sulfur halides such as sulfur monofluoride, sulfur tetrafluoride, disulfur decafluoride, sulfur monochloride, sulfur dichloride, sulfur tetrachloride, sulfur monobromide and sulfur iodide can also be used. Nitrogen containing sulfur compounds, for example, tetrasulfur dinitride, tetrasulfur tetranitride, and trithiazylchloride can also be used albeit with extreme caution, in accordance with the invention. Oxides of sulfur, for example sulfur dioxide, sulfur heptoxide, sulfur monoxide, sulfur sesquioxide, sulfur tetraoxide, sulfur trioxide, trisulfur dinitrogen dioxide, sulfur monooxytetrachloride, and sulfur trioxytetrachloride are also suitable for use. The sulfur source can also be selected from sulfuric acids, for example, permonosulfuric acid, per(di)sulfuric acid and pyrosulfuric acid. Sulfurous acid is also suitable for use. Sulfuryl chlorides, for example sulfuryl chloride fluoride and pyrosulfuryl chloride are also suitable for use.
Of course, single compositions containing more than one of aluminum, phosphorus or sulfur can be employed as a combined source. Thus, suitable treating agents include inorganic compounds containing aluminum and phosphorus, for example, aluminum metaphosphate and aluminum orthophosphate. Likewise, inorganic compositions which contain aluminum and sulfur can be usefully employed as treating agents in accordance with the present invention, for example, aluminum sulfide and aluminum sulfate. Similarly, promoting agents comprising both phosphorus and sulfur can be employed in addition to aluminum, for example, phosphorus oxysulfide, tetraphosphorus heptasulfide, phosphoruspentasulfide, and tetraphosphorus trisulfide.
Examples of organic phosphorus containing promoting agents include hydrocarbylphosphines, hydrocarbylphosphine oxides, hydrocarbylphosphites and hydrocarbylphosphates. Exemplary compounds include tri-n-butylphosphine, triphenylphosphine, tri-n-butylphosphine oxide, triphenylphosphine oxide, trioctylphosphite and triphenylphosphite.
Examples of organic sulfur containing promoting agents include mercaptans, thioethers, disulfides, polysulfides, thioacids, heterocyclic sulfur compounds, and polynuclear compounds, to name but a few. Exemplary compounds include tertiary octyl mercaptan, n-butyl sulfide, tertiary amyl disulfide, tertiary butyl polysulfide, dithioacetic acid, thiophene, methyl thiophene, butylthiophene, benzothiophene, dibenzothiophene, and carbon disulfide.
The additional contacting of the cracking catalyst with promoting agent is most conveniently accomplished by contacting the cracking catalyst with aluminum compounds which additionally contain phosphorus and/or sulfur. Exemplary of these compounds are the aluminum-hydrocarbyl phosphites, aluminum-hydrocarbyl phosphates, aluminum thiocarboxylates, hydrcarbyl aluminum mercaptoalkanoates, aluminum thiocarbonates, hydrocarbylaluminum hydrocarbyl mercaptides, and aluminum thiocarbamates.
Compounds which contain phosphorus and/or sulfur located at the gamma position or closer to an aluminum atom appear particularly efficient for reducing the detrimental effects of contaminating deposits on a cracking catalyst. Aluminum thiophosphates, particularly aluminum dihydrocarbyl thiophosphates because of their oil solubility and because they have been tested with good results, are the preferred treating agents of the present invention. These compounds are conveniently represented by the formula ##STR1## wherein R is hydrocarbyl and due to availability normally has from 1 to about 20 carbon atoms and X is selected from the group consisting of oxygen and sulfur and at least one X is sulfur. Compositions represented by the formula ##STR2## wherein R is as defined before are particularly preferred because of ease of synthesis and because they have been tested with good results. In both represented formulas, R can be alkyl, alkenyl, cycloalkyl, aryl and combinations thereof, for example, aralkyl, in nature. Examples of suitable aluminum containing treating agents containing both phosphorus and sulfur promoting agents include aluminum tris(dipropyl phosphate), aluminum tris(O,O-dipropyl phosphorothioate), aluminum tris(O,O-diprpylphosphorordithioate, aluminum tris(O,S-dipropyl phosphorothioate), aluminum tris(S,S-dipropylphosphorodithioate), aluminum tris(O,S-dipropylphosphorodithioate), aluminum tris(S,S-dipropylphosphorortrithioate), and aluminum tris(S,S-dipropylphosphorortetrathioate). In addition, the propyl groups in the preceding examples can be replaced with, for example, methyl, butyl, octyl, ethyl cyclohexyl, phenyl hexenyl radicals and the like. An example is aluminum (O-methyl S-phenyl phosphorodithioate). Aluminum tris(di-n-propylphosphorodithioate) is the treating agent presently preferred because it has been tested with good results.
Generally, the amount of aluminum containing treating agent contacted with the cracking catalyst is a "passivating amount." By passivating amount is meant an amount of treating agent which is sufficient to mitigate at least one of the deleterious effects caused by deposition on the cracking catalyst of at least one contaminant selected from the group of nickel, vanadium and iron, such as, for example, decreased catalyst activity for feedstock conversion, decreased catalyst selectivity for gasoline production, increased hydrogen production and increased coke production.
Although not intending to be bound to any particular theory of operation, it is believed that the decomposition products of the aluminum containing treating agent react with the contaminants present on the cracking catalyst in such a way as to decrease the activity of the contaminants for detrimentally affecting the cracking process. It is therefore believed that an effect of the contact between the cracking catalyst and a passivating amount of aluminum containing treating agent is an increase in the aluminum concentration of the cracking catalyst. However, for many applications, the increased aluminum concentration in the cracking catalyst may be too small to measure as most commercial cracking catalysts contain substantial amounts of aluminum.
Generally, a sufficient amount of the aluminum-containing treating agent is contacted with the cracking catalyst to impart to the cracking catalyst a concentration of added aluminum of between about 1 and about 100,000 parts per million (0.0001 to 10 percent) by weight of cracking catalyst after treatment. Where an alumina-containing cracking catalyst is treated, the added aluminum will be manifested as an increased aluminum concentration in the cracking catalyst. It is preferred to contact the cracking catalyst with a sufficient amount of aluminum-containing treating agent to impart to the cracking catalyst a concentration of added aluminum of between about 200 and about 20,000 parts per million by weight of cracking catalyst after treatment, because treated cracking catalysts having concentrations of added aluminum within this range have been tested with good results.
Generally, the amount of aluminum added to the cracking catalyst should be an amount sufficient to impart to the cracking catalyst a ratio of weight of added aluminum to vanadium equivalents on the cracking catalyst of between about 1:1000 to about 10,000:1,000. More preferably, the added aluminum is in an amount sufficient to impart to the cracking catalyst a ratio of weight of added aluminum to vanadium equivalents on the cracking catalyst of between 5:1000 to 5,000:1000. Most preferably, the added aluminum is in an amount sufficient to impart to the cracking catalyst a ratio of weight of added aluminum to vanadium equivalents of between about 50:1000 to about 500:1000, because treated cracking catalyst having weight added aluminum:vanadium equivalents ratios within this range have been tested with good results.
The present invention has particular utility for improving the cracking characeristics of cracking catalysts having deposited thereon 3,000 ppm and greater of vanadium equivalents. Untreated cracking catalysts have usually developed undesirable cracking behavior at a contamination level of 3,000 vanadium equivalents. Treatment of the cracking catalyst in accordance with the present invention is effective to mitigate the undesirable cracking behavior of cracking catalysts having deposited thereon 3,000 ppm vanadium equivalents, 10,000 ppm vanadium equivalents and even 20,000-50,000 vanadium equivalents and beyond of contaminants.
In the embodiment of the invention wherein phosphorus and/or sulfur-containing promoting agents are contacted with the cracking catalyst in addition to aluminum, the amount of aluminum contacted with the cracking catalyst can be within the ranges as defined above. The amount of sulfur and/or phosphorus contacted with the cracking catalyst in addition to the aluminum can be selected over a broad range. Generally, a promoting amount of sulfur and/or phosphorus is contacted with the cracking catalyst. For example, aluminum and phosphorus can be contacted with the cracking catalyst at any suitable weight ratio such as a weight ratio of aluminum to phosphorus of between about 5:1 to about 1:5, with a weight ratio of between about 1:2 to about 1:4 being preferred because cracking catalysts treated with ratios within this range have been tested with good results. A suitable weight ratio of aluminum to sulfur with which the cracking catalyst can be contacted can be selected from a relatively broad range, such as for example within the range of from about 1:1 to about 1:20, with a range from about 1:4 to about 1:10 being preferred. Cracking catalysts contacted with compositions having aluminum:sulfur weight ratios within this latter range have been tested with good results. The above weight ratios are suitable when employing either or both phosphorus and sulfur with aluminum.
Any suitable method can be used to contact the treating agent comprising a source of aluminum and optionally at least one of a source of phosphorus and sulfur with the catalyst. It can be mixed with the catalyst as a finely divided solid and dispersed by rolling, shaking, stirring, etc. Or, it can be dissolved in a suitable solvent, aqueous or organic, and the resulting solution used to impregnate the cracking catalyst--followed by drying to remove the solvent. Or, it can be sprayed on the catalyst, such as by being dissolved or suspended in the feedstock to a catalytic cracking unit.
The time required to effect a contact between the treating agent and cracking catalyst is not particularly important. Generally, for a batch treatment outside of a catalytic cracker such time period can range from 0 to 30 minutes. Likewise, the temperature at which the contact is effected can be selected from a wide range of values, depending, for example, on whether the treating agent is contacted with the cracking catalyst as a vapor or as in solution with a relatively low boiling solvent.
The cracking catalysts which can be advantageously treated in accordance with the above-described process are generally any of those cracking catalysts employed for the catalytic cracking of hydrocarbons boiling above 400� F. (204� C.) in the absence of added hydrogen which have become partially deactivated by deposits of contaminating metals thereon. Treatment of such contaminated cracking catalysts in the above-described manner produces the modified cracking catalyst of the present invention. These cracking catalysts generally contain silica or silica alumina and are frequently and preferably associated with zeolitic materials. Generally, from 1 to 60 percent, usually from about 30 to about 40% by weight of the catalyst will comprise zeolitic materials. The zeolitic materials can be naturally occurring or synthetic, and such materials can be produced by ion exchange methods and provided with metallic ions which improve the activity of the catalyst. Zeolite-modified silica alumina catalysts are particularly applicable to this invention because of their high activity and selectivity. Examples of metals contaminated cracking catalysts into or onto which a source of aluminum and optionally a source of at least one of phosphorus and sulfur can be incorporated include hydrocarbon cracking catalysts obtained by admixing an inorganic oxide gel with an aluminosilicate, and aluminosilicate compositions which are strongly acidic as the result of treatment with a fluid medium containing at least one rare earth metal cation and a hydrogen ion, or ion capable of conversion to a hydrogen ion.
It is inherent in this invention that the treated cracking catalyst will be subjected to elevated temperatures. When utilized in a continuous cracking process, the treated cracking catalyst can be subjected to temperatures between 800� F. (427� C.) and 1200� F. (649� C.) in the cracking zone and temperatures between 1000� F. (538� C.) and 1500� F. (816� C.) in the regeneration zone. Generally free oxygen containing gas is present in the regeneration zone. The contacting of the treating agent with the cracking catalyst can occur in the cracking zone, in the regeneration zone, or in the catalyst stream between the two zones.
A further embodiment of the present invention is directed to a catalytic cracking process wherein a hydrocarbon feedstock is contacted with the above-described modified cracking catalyst under cracking conditions to produce a cracked product. Such cracking operations are generally carried out at temperatures between 800� F. (427� C.) and about 1200� F. (649� C.) at pressures within the range of subatmospheric to several hundred atmospheres. A preferred example of this embodiment of the invention utilizes a cyclic flow of catalyst between a fluidized cracking zone and a regeneration zone in a cracking reactor. Such a system is well known to those skilled in the art.
Specific conditions in the cracking zone and the regeneration zone of a fluid catalytic cracker depend on the feedstock used, the condition of the catalyst, and the products sought. In general, conditions in the cracking zone include:
TABLE I______________________________________Temperature: 427-649� C. (800-1200� F.)Contact time: 1-40 secondsPressure: 10 kiloPascals to 21 megaPascals (0.1 to 205 atm.)Catalyst:oil ratio: 3/1 to 30/1, by weight______________________________________
Conditions in the regeneration zone include:
TABLE II______________________________________Temperature: 538-816� C. (1000-1500� F.)Contact time: 2-40 minutesPressure: 10 kiloPascals to 21 megaPascals (0.1 to 205 atm.)Air rate (at 16� C., 100-250 ft3 /lb coke,1 atm.): (6.2-15.6 m3 /kg coke.)______________________________________
The feedstocks introduced into the catalytic cracking unit are generally oils having an initial boiling point of about 204� C. This includes gas oils, fuel oils, topped crude, shale oil and oils from coal and/or tar sands.
Such feedstocks can and usually do contain a significant concentration of at least one metal selected from vanadium, iron and nickel. Because these metals tend to be concentrated in the least volatile hydrocarbon fractions suitable for use as feedstocks, a process for cracking these heavy oil fractions is probably the most important embodiment of this invention. Currently, the industry obtains only economically marginal results when cracking feedstocks containing from about 50 to about 100 parts per million of total effective metals, where total effective metals is defined herein as the sum of the elemental weights of iron, vanadium and four times the weight of nickel in 1,000,000 parts by weight of feedstock, including the iron, vanadium and nickel contained therein. In accordance with the present invention, feedstocks containing 50-100 parts per million of total effective metals, and even those containing 100-200 parts per million of total effective metals and beyond can be economically cracked to produce gasoline and other light distillates. The quantity of added aluminum required to passivate vanadium, iron and nickel is related directly to the concentration of these metals in the feedstock. In a preferred embodiment, the aluminum containing treating agent is dissolved or suspended in a suitable solvent and introduced into the catalytic cracking unit along with the hydrocarbon feedstock. It is advantageous to employ a concentration of aluminum in the hydrocarbon feedstock in relationship to the contaminating metals concentration in the feedstock as shown by the following table.
TABLE III______________________________________Total Effective Metals Aluminum Concentrationin Feedstock, ppm in Feedstock (ppm)______________________________________<40-100 1-100100-200 10-250200-300 25-500300-800 50-1000______________________________________
This invention is illustrated by the following example.
A commercial cracking catalyst that had been used in a commercial fluid catalytic cracker until it had attained equilibrium composition with respect to metals accumulation (catalyst was being removed from the process system at a constant rate) was used to demonstrate passivation with aluminum. The catalyst, being a synthetic zeolite combined with amorphous silica/alumina (clay), was predominantly silica and alumina. Concentrations of other elements together with pertinent physical properties are shown in Table IV.
TABLE IV______________________________________Surface area, m2 g-1 74.3Pore volume, ml g-1 0.29Composition, wt. %Nickel 0.38Vanadium 0.60Iron 0.90Cerium 0.40Sodium 0.39Carbon 0.06______________________________________
A portion of this used, metals-contaminated catalyst was treated with aluminum as follows. A solution, prepared by dissolving 1.59 gm of aluminum phenoxide in 35 ml of cyclohexane, was stirred into 35 gm of the used catalyst. Solvent was removed by heating, with stirring, on a hot plate at about 260� C. This treatment added 0.40 wt. % aluminum to the catalyst. The treated catalyst was then prepared for testing by aging it as follows. The catalyst, in a quartz reactor, was fluidized with nitrogen while being heated to 482� C., then it was fluidized with hydrogen while the temperature was raised from 482� to 649� C. Maintaining that temperature, fluidization continued for 5 minutes with nitrogen, then for 15 minutes with air. The catalyst was then cooled to about 482� C., still being fluidized with air. The catalyst was then aged through 10 cycles, each cycle being conducted in the following manner. The catalyst at about 482� C. was fluidized with nitrogen for one minute, then heated to 510� C. during two minutes while fluidized with hydrogen, then maintained at 510� C. for one minute while fluidized with nitrogen, then heated to about 649� C. for 10 minutes while fluidized with air, and then cooled to about 482� C. during 0.5 minutes while fluidized with air. After 10 such cycles it was cooled to room temperature while being fluidized with nitrogen.
The used catalyst and the aluminum-treated catalyst were evaluated in a fluidized bed reactor using topped West Texas crude oil as feedstock to the cracking step. The cracking reaction was carried out at 510� C. and atmospheric pressure for 0.5 minutes, and the regeneration step was conducted at about 649� C. and atmospheric pressure for about 30 minutes using fluidizing air, the reactor being purged with nitrogen before and after each cracking step.
Properties of the topped West Texas crude used in the cracking steps are summarized in Table V.
TABLE V______________________________________API gravity at 15.6� C. 21.4�Distillation (by ASTM D 1160-61) IBP 291� C. 10% 428 20% 468 30% 498 40% 528 50% 555Carbon residue, Ramsbottom 5.5 wt. %Analysis for some elementsSulfur 1.2 wt. %Vanadium 5.29 ppmIron 29.0 ppmNickel 5.24 ppmPour point (by ASTM D 97-66) 17� C.Kinematic viscosity (by ASTM D 445-65)at 82.2� C. 56.5 centistokesat 98.9� C. 32.1 centistokes______________________________________
Results of the tests using the two catalysts are summarized in Table VI.
TABLE VI______________________________________Catalyst Used Used, +0.40% Al______________________________________Catalyst:Oil weight ratio 7.7 7.2Conversion, Vol. % of feed 74.9 79.8Gasoline Selectivity, 72.9 81.0Vol. % of ConversionYieldsCoke, wt. % of feed 17.6 14.0SCF H2 /bbl feed converted 895 704Gasoline, Vol. % of feed 54.6 64.6Material balance, wt. % 100.7 99.9______________________________________
This comparison of the two catalysts shows that the addition of 0.4 wt. percent aluminum, as aluminum phenoxide, to the metals-contaminated cracking catalyst increased conversion of the feedstock by 6.6%, at a catalys/oil ratio about 6% lower than in the control, increased the selectivity of the catalyst for gasoline production in excess of 6%, in spite of the higher conversion level, increased gasoline yield by 18%, and decreased both the production of coke and the formation of hydrogen by 21%.
A commercial cracking catalyst that had been used in a fluid catalytic cracker until it had attained equilibrium composition with respect to metals accumulation was characterized by the following properties:
TABLE VII______________________________________Surface Area, m2 /g 75.9Pore vol., mL/g 0.36Composition, wt. %Nickel 0.38Vanadium 0.58Iron 0.85Cerium 0.39Sodium 0.46Carbon 0.06______________________________________
A portion of the catalyst characterized above was treated to contain phosphorus by impregnation with di-n-propylphosphorodithioic acid (DNPPTA) (C3 H7 O)2 PS2 H). This was done as follows. A solution containing 4.65 g DNPPTA in dry cyclohexane was used to cover 40 g of catalyst. The mixture was warmed on a hot plate, with stirring, until the solvent had evaporated. Dry catalyst was placed in a quartz reactor and aged as described in Example I.
The used catalyst and the DNPPTA-treated catalyst were tested in a fluidized bed reactor as described in Example I. Results of the tests were as follows:
TABLE VIII______________________________________Additive None 1.7 wt. % p1______________________________________Catalyst/Oil Ratio 7.4/1 7.5/1 7.4/1Conversion, Vol. % 82.0 72.7 71.0Gasoline Selectivity 68.3 67.6 65.2Vol. % of ConversionYieldsCoke, Wt. % 16.0 14.2 15.8SCF H2 /B Conv. 720 602 620Gasoline, Vol. % 56.0 49.1 47.3______________________________________ 1 Source of P was (C3 H7 O)2 PS2 H
As shown in Table VIII, the addition of phosphorus to metals-contaminated FCC catalyst via impregnation with DNPPTA reduced hydrogen yield by about 15% and reduced coke yield by about 6%. However, these benefits were at the expense of conversion, which fell about 12%, and gasoline yield, which fell about 14%. The lowered coke and hydrogen yields are probably at least patially due to the lower level of conversion. Also as shown by the above table, the selectivity of the cracking catalyst for gasoline production was lowered, even though the catalyst was employed to effect a lower level of conversion. This example demonstrates the advantages obtained by using aluminum in combination with phosphorus and sulfur.
Aluminum tris(O,O-di-n-propylphosphorordithioate was prepared by a double decomposition reaction between aluminum chloride and potassium O,O-di-n-propylphosphorodithioate. To a solution of 4.02 gm (0.016 moles) AlCl3.6H2 O in methanol was added, dropwise, a solution of (C3 H7 O)2 PSSK. Solid potassium chloride precipitated during this addition. Methanol solvent was removed by evaporation in a rotary evaporator, then replaced with diethyl ether, precipitating still more potassium chloride, which was removed by filtration. Diethyl ether solvent was removed by evaporation, the last traces requiring warming in a vacuum. Slightly grey crystals remained. Elemental analysis of them showed the following. Calculated: 34.42% C, 6.35% H, 13.93% P, 4.05% Al. Found: 27.86% C, 6.62% H, 9.7% P, 3.4% Al.
The commercial cracking catalyst of Example I was treated with the above prepared aluminum tris(O,O-di-n-propylphosphorodithioate) as follows. A solution, prepared by dissolving 4.32 gm of [(1-C3 H7 O)2 PSS]3 Al in 35 ml of methanol, was stirred into 35 gm of the used catalyst. Solvent was removed by heating, with stirring, on a hot plate at about 260� C. This treatment added 0.50 wt. % aluminum to the catalyst. The treated catalyst was then prepared for testing by aging it as in Example I.
The catalyst was employed to crack the feedstock set forth in Example I under the reactor conditions employed in Example I. The results obtained were:
TABLE IX______________________________________Additive None 0.5 Wt. % Al1______________________________________Catalyst:Oil Weight Ratio 7.7 7.4Conversion, Vol. % of feed 74.9 78.0Gasoline Selectivity, 73 84Vol. % of ConversionYieldsCoke, Wt. % of Feed 17.6 15.0SCF H2 /bbl Feed Converted 895 543Gasoline Vol. % of Feed 54.6 65.4Material Balance, Wt. % 100.7 100.3______________________________________ 1 Al added via impregnation with Al((C3 H7 O)2 PS2)3?
As shown by Table IX, the addition of Al to the catalyst as the di-n-propylphosphorodithioate increased conversion by about 4%, increased gasoline yield by about 20%, decreased coke yield by about 15%, decreased hydrogen selectivity by about 39%, and improved catalyst selectivity for gasoline production from 73% to 84% despite the higher conversion level.
As compared to untreated cracking catalysts, the modified cracking catalysts tested in Examples I, II and III modify the cracking behavior of the catalyst at a catalyst/oil ratio of 7.4/1 as follows:
TABLE X______________________________________Additive, wt. % 0.5 Al1 1.7 P2 0.5 Al + 1.7 P3______________________________________Percent Change overUntreated CatalystConversion, (Vol. %) +6.6 -12 +4Coke (Wt. %) -21 -6 -15H2 /Bbl Conv. -21 -15 -39Gasoline, Vol. % +18 -14 +20______________________________________ 1 via Al(OC6 H5)3 2 via (C3 H7 O)2 PS2 H 3 via Al((C3 H7 O)2 PS2)3 impregnation
The high gasoline yields and low selectivity for hydrogen production exhibited by the catalyst treated with Al((C3 H7 O)2 PS2)3 are unexpected in view of the results obtained by treatment of the cracking catalyst with Al(OC6 H5)3 or (C3 H7 O)2 PS2 H.
|Cited Patent
|Filing date
|Publication date
|Aug 27, 1935
|Sep 13, 1938
|Houdry Process Corp
|May 7, 1949
|Jan 15, 1952
|Standard Oil Dev Co
|Treatment of silica-alumina containing gels
|Nov 4, 1952
|Aug 7, 1956
|Socony Mobil Oil Co Inc
|Reactivation of metal-poisoned catalysts
|Oct 20, 1954
|Sep 2, 1958
|Socony Mobil Oil Co Inc
|Reactivation of metal-poisoned catalysts
|Dec 29, 1953
|Jul 28, 1959
|Gulf Research Development Co
|Catalytic cracking process using a catalyst whose carbon factor has been improved
|Feb 18, 1954
|Aug 25, 1959
|Phillips Petroleum Co
|Catalytic conversion with the addition of a metal or metallic compound
|Nov 30, 1956
|Jan 12, 1960
|Phillips Petroleum Co
|Method for improving used cracking catalysts
|Apr 22, 1958
|Jul 26, 1960
|Phillips Petroleum Co
|Deactivation of poisons on contaminated cracking catalysts
|Jul 25, 1957
|Mar 28, 1961
|Phillips Petroleum Co
|Deactivation of metallic poisons on used cracking catalysts
|Jan 12, 1965
|Mar 22, 1966
|Exxon Research Engineering Co
|Cracking of hydrocarbon oils with a silica-alumina catalyst containing gallium oxide
|Nov 25, 1964
|Jun 6, 1967
|Nalco Chemical Co
|Catalyst treatment
|Jan 21, 1969
|Dec 28, 1971
|Exxon Research Engineering Co
|Metal nitrides as cracking catalysts
|Nov 1, 1971
|Jul 16, 1974
|Phillips Petroleum Co
|Oxidative dehydrogenation catalyst
|Aug 30, 1973
|Aug 6, 1974
|Shell Oil Co
|Thermal cracking of hydrocarbons
|Oct 17, 1972
|Oct 8, 1974
|American Cyanamid Co
|Method for preparing a hydrotreating catalyst
|Sep 23, 1974
|Sep 16, 1975
|Mobil Oil Corp
|Alkylation of olefins
|Sep 23, 1974
|Oct 7, 1975
|Mobil Oil Corp
|Conversion of methanol and dimethyl ether
|Sep 23, 1974
|Aug 3, 1976
|Mobil Oil Corporation
|Phosphorus-containing zeolite catalyst
|Apr 28, 1976
|Mar 8, 1977
|Mobil Oil Corporation
|Disproportionation of toluene
|Aug 12, 1976
|May 24, 1977
|Phillips Petroleum Company
|Passivating metals on cracking catalysts
|Jun 11, 1976
|Jun 21, 1977
|Phillips Petroleum Company
|Passivating metals on cracking catalysts with antimony compounds
|Dec 17, 1976
|Sep 19, 1978
|Chevron Research Company
|Process for removing sulfur from a gas
|Jul 26, 1977
|Feb 27, 1979
|Phillips Petroleum Company
|Passivating metals on cracking catalysts
|Jul 21, 1978
|Jun 19, 1979
|Gulf Research & Development Company
|Process for increasing gasoline yield and quality during catalytic cracking of high metals content charge stocks using an alumina-aluminum phosphate-silica-zeolite catalyst
|Jul 25, 1978
|Feb 26, 1980
|Phillips Petroleum Company
|Passivation of metals on cracking catalysts with an antimony tris (hydrocarbyl sulfide)
|Oct 12, 1978
|Apr 15, 1980
|Mobil Oil Corporation
|Cracking catalyst with improved resistance to poisoning by metals
|Jul 25, 1978
|Jun 24, 1980
|Phillips Petroleum Company
|Antimony tris(dihydrocarbyl phosphite) and preparation thereof
|Oct 10, 1978
|Mar 31, 1981
|Union Oil Company Of California
|Process for reducing sox emissions from catalytic cracking units
|Dec 7, 1978
|Sep 15, 1981
|Union Oil Company Of California
|Process for catalytically cracking metals-containing hydrocarbon feedstocks
|May 19, 1980
|Mar 2, 1982
|Atlantic Richfield Company
|In situ aluminum passivation process
|May 19, 1980
|Mar 9, 1982
|Atlantic Richfield Company
|Combination of aluminum and phosphorus passivation process
|May 19, 1980
|Mar 16, 1982
|Atlantic Richfield Company
|Passivation process
|May 19, 1980
|Mar 23, 1982
|Atlantic Richfield Company
|Phosphorus passivation process
|Mar 24, 1980
|Apr 13, 1982
|Phillips Petroleum Company
|Cracking catalyst poisons passivated with tin compounds plus both sulfur and phosphorus
|May 19, 1980
|Jun 29, 1982
|Atlantic Richfield Company
|Aluminum passivation process
|May 20, 1981
|Feb 7, 1984
|Engelhard Corporation
|Passivation of contaminant metals on cracking catalysts by phosphorus addition
|Dec 13, 1984
|Jan 28, 1986
|Exxon Research And Engineering Co.
|Co-matrixed zeolite and p/alumina
|Sep 29, 1982
|Apr 22, 1986
|Phillips Petroleum Company
|Cracking catalyst restoration with aluminum compounds
|Mar 1, 1966
|Shell Oil Co
|Conversion process
|Citing Patent
|Filing date
|Publication date
|Jul 2, 1987
|Aug 23, 1988
|Phillips Petroleum Company
|Cracking catalyst and process
|May 13, 1988
|Oct 10, 1989
|Phillips Petroleum Company
|Cracking catalyst and process
|Jun 17, 1988
|Apr 3, 1990
|Betz Laboratories, Inc.
|Passivation of FCC catalysts
|Apr 7, 1989
|Apr 24, 1990
|Mobil Oil Corporation
|Metal passivating agents
|Apr 27, 1990
|May 28, 1991
|Betz Laboratories, Inc.
|Method of passivating alkali metals on fluid catalytic cracking catalysts using aluminum containing compounds
|Mar 28, 1990
|Nov 12, 1991
|Betz Laboratories, Inc.
|Passivation of FCC catalysts
|Aug 31, 2000
|Nov 19, 2002
|Exxonmobil Research And Engineering Company
|FCC process incorporating crystalline microporous oxide catalysts having increased Lewis acidity
|Aug 31, 2000
|Jan 6, 2004
|Exxonmobil Research And Engineering Company
|Crystalline microporous oxide catalysts having increased Lewis acidity and methods for the preparation thereof
|U.S. Classification
|International Classification
|Cooperative Classification
|European Classification
|Dec 8, 1987
|Certificate of correction
|Jun 1, 1990
|Fee payment
Year of fee payment: 4
|Sep 7, 1994
|Fee payment
Year of fee payment: 8
|Oct 13, 1998
|Fee payment
Year of fee payment: 12


text:
What does ILTG stand for?
ILTG stands for I Lost the Game
This definition appears rarely and is found in the following Acronym Finder categories:
- Slang/chat, popular culture
Other Resources:
We have 2 other meanings of ILTG in our Acronym Attic
- Abbreviation Database Surfer
- « Previous
- Next »
- Intercomprehension in Language Teacher Education (University of Aveiro; Portugal)
- International Learning Teaching and Evaluation Agency (Taiwan)
- Instituto de Linguística Teórica e Computacional (Portugal)
- International Long Term Ecological Research
- In-Line Test Fixture
- Indian Land Tenure Foundation
- Integrated Line Test Function (computer networking)
- International Lawn Tennis Federation (now International Tennis Federation; est. 1913)
- Internet Law Task Force
- I Love This Place (MIT)
- Institute for Learning and Teaching in Higher Education
- Intercultural Learning for Teachers in Secondary Schools (Finland)
- Iodine-Laser Temperature Jump
- Istituto Lama Tzong Khapa (Tibetan Buddhist center; Pomaia, Italy)
- I Love This List
- I Love to Laugh
- Illinois Trial Lawyers Association
- Impacted Lower Third Molar (dentistry)
- Institute for Leadership in Technology and Management (est. 1993; Bucknell University; Pennsylvania)
- Institute of Learning and Teaching Member

subset: commoncrawl


text:
yea, i think there is just more post activity in the Mid- Atl forum than the SE forum. Prolly the same amount of people, just the people in the SE don't post as often
Results 1 to 4 of 4
Thread: Hey!
Apr 8, 2008, 12:38 PM
'; // next/previous post info pn[7197] = "7233,7220"; pn[0] = ",7197"; pn[7220] = "7197,7224"; pn[7224] = "7220,7233"; pn[7233] = "7224,7197"; // cached usernames pu[0] = guestphrase; pu[7754] = "SCislander"; pu[7041] = "steamfed"; pu[6] = "Swellinfo"; pu[663] = "Enjoytheslide"; // -->
Threaded View
I am new to this post and am stoked to help anyone out needing info on the breaks, etc around Hilton Head Island, SC. We are surrounded by a sand bar so you must take advantage of our massive tidal pushes and the rich yankee golfers are always trying to buy up all our access points to the water but we make do. Happy swells!!! Rusty


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IMHOF Releasing Weekly Feature Stories On 2009 Inductees
The International Motorsports Hall of Fame announced today that feature stories on each of its five inductees will be released weekly leading up to the induction ceremony on Thursday, April 23rd. Race fans will be able to find the stories online at www.motorsportshalloffame.com and www.talladegasuperspeedway.com.
"Each of our inductees has a unique story to tell," said Talladega Superspeedway President and IMHOF Executive Director Rick Humphrey. "While their successes at the track have been well-documented, we wanted to know more. What brought them to a career in motorsports? What made them so successful? We answer those questions and more in these stories. Race fans and fans of racing history will find our feature stories to be informative and entertaining."
The five inductees being honored are: J.C. Agajanian, Donnie Allison, Jerry Cook, Bud Moore and Raymond Parks.
Tickets are currently available for the induction ceremony at www.racetickets.comor by calling 1-877-Go2-DEGA. This year's black-tie optional ceremony begins with a reception at 5:30 p.m. and the banquet and awards ceremony immediately following.
Individual tickets are $125 and a table for eight may be reserved for $1,000. Visa, Mastercard and Discover are accepted.
In addition to the five inductees, NHRA Top Fuel champion Tony Schumacher will be on hand to accept his award as the 2008 Driver of the Year and 2008 ARCA RE/MAX Series Champion Justin Allgaier will also be recognized during the ceremony.
About the International Motorsports Hall of Fame & Museum
Opened in April of 1983, the International Motorsports Hall of Fame and Museum is dedicated to the preservation of the history of motorsports. Each year, the annual International Motorsports Hall of Fame Induction Ceremony is held on the grounds of the museum to honor those men and women chosen for induction from among the greatest names in all of motorsports.
The 2009 ceremony will be held April 23rd, at the SPEED Channel Dome, adjacent to the International Motorsports Hall of Fame. Individual tickets for the evening are $125 and a table of eight may be reserved for $1,000. Tickets and tables are available by calling 1-256-362-5002 or logging on to www.racetickets.com.
- Advanced Priced Tickets On Sale Friday for Talladega Superspeedway's Pivotal Oct. 21-23 Weekend, Featuring Two NASCAR Chase Elimination Races
- Earnhardt Jr. Set For Pre-Race Fan Q&A Session Prior To Alabama 500, Sunday, Oct. 23 At Talladega Superspeedway - A Place He Calls Home
- Brad Keselowski Wins GEICO 500 Aspen Dental Weekend at Talladega Superspeedway
- Elliott Sadler Wins Thrilling NASCAR XFINITY Series Sparks Energy 300 During Aspen Dental Weekend at Talladega Superspeedway
- Gus Dean Picks Up First Career Win at Talladega Superspeedway in Wild ARCA Racing Series Presented by Menards General Tire 200


text:
scalding adjective (LIQUID)
scalding adjective (CRITICISM)
Thesaurus: synonyms and related words
(Definition of "scalding" from the Cambridge Advanced Learner's Dictionary & Thesaurus © Cambridge University Press)
Get a quick, free translation!
Create and share your own word lists and quizzes for free!
More meanings of "scalding"
Word of the Day
the activity of knitting something, or a thing that is being knitted


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Foreclosure investing involves the purchase of houses that are somewhere in the process of being confiscated by lenders due to the owner's failure to meet mortgage obligations. The investor buys the house with the hope that it can be bought below market value as a result of the bank or lender seeking to move it quickly and recover funds.
Foreclosure investing, despite the promises of late-night television infomercials, is not for the inexperienced. Most of these transactions are done "as-is" and with no warranty. Oftentimes, homes are sold at auction - a process that prevents prospective buyers from completing full property inspections. Therefore, there is no recourse for buyers who end up with houses that reveal dilapidation or hidden damages after the papers have been signed.
Additionally, it is virtually impossible for foreclosure investors in a tight lending market to purchase properties with no money down. More often, an investor is required to put up a down payment of 10-20% to secure a loan. The interest on these loans notoriously eats away at an investor's profits when the house does not "flip" as quickly as intended.
Considering that plenty of highly experienced foreclosure investors conduct business in larger metropolitan markets, it is also rare to find a truly easily salable home at a deep discount. During stable economic periods, the typical discount from market price on a foreclosed home usually will not exceed 3-10%.
(To learn more about this topic, read Foreclosure Investing Not A Get-Rich-Quick Venture, Avoiding Foreclosure Scams and Foreclosure Opens Windows For Investors.)
This question was answered by Ken Clark.
What's the difference between short sales and foreclosures?Understand the difference between a short sale and a foreclosure; both result in the loss of a home, either through a sale ... Read Answer >>
What is PMI, and does everyone need to pay it?Also known as "Primary Mortgage Insurance," PMI is the lenders (banks) protection in the event that you default on your primary ... Read Answer >>
How does the American Housing Rescue and Foreclosure Prevention Act of 2008 affect ...The passage of the American Housing Rescue and Foreclosure Prevention Act of 2008 at the end of July 2008 made about $15 ... Read Answer >>
How can investors use trends in the unemployment rate to evaluate the outlook of ...Learn the effect of the unemployment rate on credit services companies, and why this is a key metric to consider when investing ... Read Answer >>
How does the loan-to-value ratio affect my mortgage payments?Understand what the loan to value ratio is, how the ratio is calculated and learn how it has an impact on your mortgage payments ... Read Answer >>
Is it possible to short sell real estate?The traditional idea of a short sale is selling something you don't have so that you can buy it back at a lower price. The ... Read Answer >>
Personal Finance
Buying Foreclosures At A Bargain PriceLearn how to buy a foreclosed home at a discount.
Personal Finance
Can You Dispute A Foreclosure?The bank has foreclosed on your mortgage, but do you really have to leave? Learn how to fend off the lenders and gain the time you need to save your home.
Financial Advisor
Helping Clients Navigate Short Sales And ForeclosuresBoth buyers and sellers can benefit from a real estate professional experienced in dealing with short sales and foreclosures.
Personal Finance
Don't Get Trapped in a Zombie ForeclosureUnderstand how foreclosures work and you can avoid the disastrous consequences of having a zombie foreclosure.
Short Sales And Foreclosures: When It's Time To Move OnSometimes it's better to cut your losses, but foreclosures and short selling can have devastating impacts on your credit score.
Personal Finance
Investing In Foreclosures Not A Get-Rich-Quick VentureInvesting in this kind of real estate takes capital, time and careful planning.
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The Pitfalls Of Buying A Foreclosure HouseFind out if the house you're eyeing is really a good deal.
Personal Finance
The Lowest Foreclosure Rates In AmericaDespite more foreclosures and a high unemployment rate, signs of life are emerging in the U.S. real estate market.
Top 6 Scariest Neighborhoods For HomebuyersIf you're looking for a spooky spot this Halloween, these communities boast the most horrifying foreclosure rates in the country
Avoid Foreclosure: How To Handle An Underwater MortgageForeclosure is the biggest fear of any struggling homeowner. These tips just might save your credit rating.
Foreclosure ActionThe legal proceedings initiated by a lender in the case of mortgage ...
Foreclosure FilingThe initial legal process of selling a mortgaged property that ...
Judicial ForeclosureForeclosure proceedings in which a mortgage lacks the power of ...
Serious DelinquencyWhen a single-family mortgage is 90 days (or more) past due and ...
Foreclosure Prevention Act of 2008A housing act that is designed to help families keep homes that ...
Zombie TitleA right to ownership and possession of a home that remains with ...


text:
Join FREE | Login
+ Celebrations
+ How-To
+ Deals
Teriyaki Barbecued Chicken Sandwiches
Slow-Cooker Asian Pulled Chicken Sandwiches
Slow-Cooker Teriyaki-Sesame-Chicken Wraps
Slow-Cooker Mexican Chicken Tostadas
Slow-Cooker Shredded Mexican Chicken
Slow-Cooker Big and Spicy Chicken Hoagies
Slow-cooked chicken sandwiches flavored with Caribbean seasoning - perfect for dinner!
Caribbean jerk seasoning, also known as Jamaican jerk seasoning, is generally a combination of peppers, thyme and allspice. Some blends may also contain cinnamon, ginger, cloves, garlic and onions.
© 2016 ®/TM General Mills All Rights Reserved


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Over the last 3 years I have been traveling every other month back and forth to Colombia. In my travels I am often in Bogota, Medellin and Cartagena but I would never trust my cloths with anyone else than Sudsies in Miami Beach. I believe that your physical presentation in business says many things about the person you are conducting business with and I would not trust my investment in clothing with anybody. Often times after I receive my cloths back from them I do not want to unpack them since it appears as if it is new. Besides I am able to avoid any additional baggage charges by carrying on my garment bag. Try them, I bet you will Never go anywhere else!
Miami Beach Mobile Laundry
1. Mobile Laundry - CLOSED
842 84th StMiami Beach, FL 33141
2. 123 Mobile Laundry - CLOSED
926 79th TerMiami Beach, FL 33141
3. Mobile Dry Cleaning
8032 NW 161st TerHialeah, FL 33016
4. El Jamper Home and Office Mobile Dry Cleaners Delivery Service
Serving the Miami Beach Area.
5. Anderson Rentals Inc
St. Lucie, FL, FL 34981
From Business: Anderson Rentals is a Family owned/operated business, established in 1967, currently operating in 14 Florida counties and a recipient of the USF Sunshine State Safe…
6. Celmas Dry Cleaners
4111 Sheridan AveMiami Beach, FL 33140
From Business: FREE PICK UP AND DELIVERY AVAILABLE ON ANY ORDER OVER $50.00. WASH DRY FOLD EXPERT ALTERATIONS SHOE REPAIR, BEST IN MIAMI BEACH
7. Kim's Valet Cleaners LLC
5126 Biscayne BlvdMiami, FL 33137
8. Sudsies Dry Cleaners
I love Sudsies! They save me so much Time and Money by coming to my place of business to pick up and drop off my dry cleaning. I recently sent ove…
9. Independent Linen Service
955 SE 8th StHialeah, FL 33010
10. Spotmaster Of South FloridaServices
18000 Biscayne BlvdAventura, FL 33160
11. Worldwide Laundry IncProducts
My buddy opened a laundromat and he bought his equipment with these guys. They're friendly and have everything he needed! Highly recommend!
12. Cy's Linen Service Inc
510 W 28th StHialeah, FL 33010
From Business: WE ARE GREEN! Currently we process 6,000 lbs of clean linen per hour, 7 days per week. We focus on Quality not Quantity. Since 1945.
13. Royal Cleaners
One of the coolest laundry shops in town. I love how they great their customers with smile and I can tell with the way my clothes were washed that t…
14. Super Wash & DryServices
The type of service offered here is unlike anywhere else. People are hardworking and the services have rates that fit any type of budget.
15. Spot-Master Linens R-Us
1290 NE 125th StNorth Miami, FL 33161
16. Normandy Cleaners
1118 Normandy DrMiami Beach, FL 33141
17. Lupe's Laundry
1230 Normandy DrMiami Beach, FL 33141
18. Coin Laundry Basket
1977 71st StMiami Beach, FL 33141
19. Mark's Quality Cleaners-Lndry - CLOSED
First Class. Consistent and helpful with every need.Highly recommended
20. Sterling Hangers
1680 Meridian Ave Suite 600Miami Beach, FL 33139
21. Laundrysunny
221 73rd StMiami Beach, FL 33141
22. Maxclean
2101 Calais DrMiami Beach, FL 33141
23. Cool & Clean
1515 Alton RdMiami Beach, FL 33139
24. Pine Tree Cleaners and Laundry
315 W 47th StMiami Beach, FL 33140
25. Angelina Coin Laundry
910 Alton RdMiami Beach, FL 33139
26. Aqua Beach
MbMiami Beach, FL 33139
27. Brickell Cleaners
959 West Ave # 11Miami Beach, FL 33139
28. Miami Coin Laundry
802 6th StMiami Beach, FL 33139
29. Falcon Dry Cleaners - CLOSED
Really low prices compared to the rest of dry cleaners in the beach area. I mean, you can't beat $0.99 / lb. for Wash and Fold including the pick…
30. Clean Machine
It's a great Business.....Professionalism at its best. \r It is the only laundromat that works 24 hrs....great service.
If You Need Dry Cleaning, Expert Tailoring, Alterations in Miami Beach, Look No Further Than Sudsies!!! When my clothes come back from Sudsies, it feels like they are brand new. Everyone that I've encountered at their store is so nice and so professional, it's a breath of fresh air to deal with a real business who seems to value each customer. I love their home and office pick-up and delivery service. They even dry cleaned my daughter's favorite teddy bear and had it back to her by the time she went to sleep that night. Great service, a model for other businesses.
I love Sudsies! They save me so much Time and Money by coming to my place of business to pick up and drop off my dry cleaning. I recently sent over a shirt which was missing a button, only to find it returned with a brand new, matching button attached which saved me the hassle of fixing it myself. It is that kind of 1st class service that is unmatched by any other Dry Cleaner in South Florida.


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On August 4th, Needham Junior Football opened its 2014 training camp for grades 2-8. It was a sweltering summer night, but that didn�t dampen the energy or enthusiasm of 200 kids taking part.
The older grades (6-8) took part in a clinic led by the Needham High School Rockets coaches. It was a great opportunity for kids to learn and is an important part of the cohesion between the youth and varsity programs.
While the younger grades (2-5) took part in their version of the NFL Draft Combine. Coaches ran them through multitude of drills, judging their strength, agility, attention and aggressiveness, to project their optimum team position.
There is lots of work to be done to get ready of for the season. The first scrimmage is August 21 vs. Newton North, and the first games will be Labor Day weekend.
Location, ST | website.com


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Hello, Hello. Sign In
Please enter a valid city, state or zip code
2 reviews | 3 out of 5
I have use it for years all the time. This machine can completely replace the use of the stoves and the oven. It is great for all kind of meats. It cooks even and consistenly. The only thing I still cooking in the conventional oven is frozen pizza.
I have bought two whitin six months because the clear wall that covers around break easily. I got one for my mom and hers broke also. The product works very well but the quality it is VERY POOR.


text:
The Chicago Cubs announced on Monday they have called up right-handed pitcher Esmailin Caridad from Triple-A Iowa.
In a corresponding move, the Cubs also optioned right-hander Jeff Stevens to Iowa.
Caridad joins the first major league roster of his career and is available for Monday's game in Colorado. The team said in a news release that Caridad would wear uniform No. 33.
The 25-year-old is 5-10 with a 4.15 ERA in 23 starts with Iowa this season, including a 1-1 record with a 2.74 ERA in his past four starts. Caridad was a non-roster invitee to Cubs spring training in 2009, posting no record and a 0.00 ERA in six Cactus League relief appearances.
Caridad was signed by the Cubs as an undrafted free agent prior to the 2008 season and split last year between Class A Daytona and Double-A Tennessee. He combined to go 13-7 with a 3.73 ERA in 28 appearances, all but one as a starter, between the two spots. Caridad, who is a native of the Dominican Republic, also pitched for Mesa in the 2008 Arizona Fall League, going 2-1 with a 3.94 ERA in 10 appearances.
Caridad, who is 5-foot-10, 193 pounds, spent the majority of the 2007 season with the Hiroshima (Japan) Carp's Dominican academy, though he did make two scoreless relief appearances for Hiroshima that year. The Cubs signed Caridad following that season.
Stevens has no record and a 7.36 ERA in six relief appearances for the Cubs this season. He is 0-3 with two saves and a 2.11 ERA in 31 relief appearances for Iowa this year.


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Your Message, My Voice
Over almost 30 years of sales, marketing, and management, I've learned a thing or two about crafting and delivering messages. Now, I enjoy using that experience, my professionalism and training, as well as a pretty good set of pipes, to help you bring your message to life. By focusing on the important information you want to convey and the audience you want to reach, allow me to craft a delivery that will express the tone and flavor you need to make the listener take note!
Please contact me to discuss your project:
TV, Radio, or Web Commercials
Corporate Training Programs
Product and Process Videos
Explainer Videos
Movie Trailers
Video Games
IVR/Telephone Systems
I work in a custom-built, SoundStreak and Skype equipped studio located in the home we designed and built in 2014. The studio is protected from outside noises and conditioned for optimal sound. I record with a Sennheiser 416 microphone, connected to my MacBook Pro via an Apogee ONE interface. I record and edit using Adobe Audition software.
I look forward to working with you on your next project!
English, English (North American)
North American, US General American (GenAm), US Mid-Atlantic, US New York (New Jersey, Bronx, Brooklyn), US South (Deep South, Dixie, Delta)
Middle Aged, Senior, Young Adult
Special Skills
Business, Cartoons, Documentaries, Educational, Internet, Movie Trailers, Podcasting, Radio, Telephone, Television, Videogames
By taking the time to understand what my clients are saying, as well as the audience they want to reach, I will craft a delivery to ensure that their message is heard and understood.
As a full-time voice actor, I have found that my delivery is extremely well suited for television, radio, and web commercials, corporate narration for both internal and external audiences, training modules, and telephony/voice response.
I look forward to learning about your project and helping to get your message through.
B.A. University of Virginia
Voice Coaches training
How to Become a Successful Voiceover Artist, Johnna Gottlieb, 2010
Ongoing Training with Melody Jones
Intro to Improv, Baltimore Improv Group
Edge Studios, multiple classes
Sennheiser MKH416-P48
Computer & Software
Mac Book Pro, Adobe Audition
Delivery Methods
MP3, .WAV, AIFF, FLAC, others as required
Turnaround Time
24 hours depending on project
Loved working with Scott Medvetz. He is very professional and customer oriented. He worked with us to make sure we had the tone the client was looking for. I highly recommend Scott for Voice Over work!Small Pond Productions
Scott delivers quality work in a very timely fashion while taking excellent direction from the client. He's a joy to work with!Marathon Petroleum
I loved your voice!BaddaBing Productions
Scott continues to be a great resource. His always timely response and impeccable delivery makes him an asset to any video production CompanySmall Pond Productions
Client List
Stanley Black & Decker/Bostitch
Nike Elite Camps
US Department of Agriculture
Federal Reserve
Marathon Petroleum
The Jefferson Hotel
Gainesville Regional Utility
D/FW Minority Business Council
Hunting Lease Network
Phi Kappa Psi Fraternity
Radio Spirits.com
Payment Terms
Hire Scott for voice-over work. Payment is made through Voices.com SurePay, an escrow service that guarantees your work is done to your satisfaction. Send payment securely by Visa, Mastercard or PayPal through Voices.com then download your files from the website.
Watch a video to see how to make a payment
Next Steps
To contact Scott Medvetz about your project, request a quote today. We'll walk you through the process step-by-step. It's fast and easy.


text:
Corpus Christi The Home Depot Tool Rental
Buy on eBay Today!
Find Great Products
Low Prices, New, and Used
1. The Home DepotProducts
My experience in the Kitchen & Cabitnet Area of the Home Depo at 4038 South Port in Corpus Christi, was excellalant. MRS. DORA LOPEZ is a great asse…
2. The Home Depot
5041 S Padre Island DrCorpus Christi, TX 78411
From Business: The Home Depot #526 isn't just a hardware store. We provide tools, appliances, outdoor furniture, building materials to Corpus Christi, TX residents. Let us help wi…
3. The Home Depot
13202 Leopard StCorpus Christi, TX 78410
From Business: The Home Depot #6564 isn't just a hardware store. We provide tools, appliances, outdoor furniture, building materials to Corpus Christi, TX residents. Let us help w…
4. Equipment Depot
921 N Port AveCorpus Christi, TX 78401
5. Lowe's Home Improvement
1530 Airline RdCorpus Christi, TX 78412
From Business: Lowe's Home Improvement offers everyday low prices on all quality hardware products and construction needs. Find great deals on paint, patio furniture, home décor, …
6. Lowe's Home Improvement
150 S Fm 1069Aransas Pass, TX 78336
From Business: Lowe's Home Improvement offers everyday low prices on all quality hardware products and construction needs. Find great deals on paint, patio furniture, home décor, …
7. Guarantee Carpet
I would recommend Guarantee Carpet to anyone. I was in a time crunch to have my back patio retiled in time for my daughters baptism. I called Guaran…
8. Wilson Company
Fort Worth, TX 75001
From Business: Wilson Company provides a wide variety of product and service for our customers. We have the capability to meet the most simplistic to the most demanding applicatio…
9. Elite Piping & Civil
326 S Enterprize PkwyCorpus Christi, TX 78405
10. Baldree John
6133 Ayers StCorpus Christi, TX 78415
11. Graybar
1402 Laredo StCorpus Christi, TX 78401
From Business: Graybar Corpus Christi is a full-service branch, with a counter, will call pickup and stocked inventory in an on-site warehouse. If you're looking for an experience…
12. Du-Tex Inc
134 44th StCorpus Christi, TX 78405
13. Door Direct
3618 Bratton RdCorpus Christi, TX 78413
From Business: Established in 2003, Door Direct provides various pedestrian and specialty doors. It offers pedestrian and vehicular gates, turnstiles, rolling steels and rolling g…
14. Armstrong Lumber Co
4343 Leopard StCorpus Christi, TX 78408
15. All Custom Wood Floors
11021 Timbergrove LnCorpus Christi, TX 78410
16. McCoy's Corporation
5909 Holly Rd, Corpus Christi TX, 78412Corpus Christi, TX 78412
17. Corpus Christi Solid Surfaces
4445 Gollihar RdCorpus Christi, TX 78411
18. Merrill Gardens
5813 Esplanade DrCorpus Christi, TX 78414
19. Casa Materials
4434 Crosstown ExpyCorpus Christi, TX 78415
20. Building Specialties
2302 Pollex AveCorpus Christi, TX 78415
21. Geo Solutions IncProducts
1218 Southern Minerals RdCorpus Christi, TX 78409
22. Sapa
Serving the Corpus Christi Area.
From Business: 1stopshopping-center.com is a one stop shopping experience. You will not find a better site that services your shopping needs like this. You will find anything from…
23. ACE Air Conditioning & Heating
Serving the Corpus Christi Area.
From Business: Ace Air Conditioning & Heating we specialize in providing the best sales and service on all indoor air conditioning system for your home or business. Ace Air Condit…
24. Mark Emery Bldg & Remodeling
109 S Fulton Beach RdFulton, TX 78358
25. Fowler Lumber Co
1262 N Commercial StAransas Pass, TX 78336
26. Metal Mart
10662 N Interstate Highway 37Mathis, TX 78368
27. Puertas! Inc
1703 Highway 35 SRockport, TX 78382
From Business: A boutique style showroom , help with your plans help with finishes. We want you to have the best looking home possible and still meet code requirements. Your home …
28. Probuild
301 E North StRockport, TX 78382
From Business: ProBuild is one of the largest suppliers of building materials dealers in the United States. Located in Rockport, Texas, it offers its products to residential and c…
29. Mueller Inc
4506 US Highway 77Robstown, TX 78380
30. Island Home Center - CLOSED
320 W Avenue GPort Aransas, TX 78373


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"In cities, cars don't liberate you; they get you stuck – for hours and days and weeks and years and decades, all that time adding up, lives slowly draining away in traffic jams and a sea of fumes." - The Austin Chronicle
Bikes vs Cars is a documentary about the bicycle and what an amazing tool for change it can be. It highlights a growing conflict in city planning between the bicycle, which supports a diverse city with a human scale, and the car, which engenders urban sprawl and reliance on fossil fuels.
From Copenhagen to Los Angeles via Sao Paulo, director Fredrik Gertten explores the ongoing efforts of bicycle activists, who are fighting for their right to ride on city streets against the combined forces of multi-billion dollar auto, oil, and construction lobbies, who are determined to keep our cities car dependent. BIKES vs CARS is a crie de coeur that will have audiences reaching for their bikes instead of their car keys.
Visit Bikes Vs Cars Website
For thousands of years, songbirds were regarded by mankind as messengers from the gods. Today, these creatures – woven inextricably into the fabric of our environment – are vanishing at an alarming rate. Under threat from climate change, pesticides and more, populations of hundreds of species have dipped dramatically. As scientists, activists and bird enthusiasts investigate this phenomenon, amazing secrets of the bird world come to light for the first time in this acclaimed and visually thrilling documentary. Find out what's killing our songbirds, and what can be done about it. As in ancient times, songbirds may once again be carrying a message to humans – one that we ignore at our own peril.
Visit The Messenger Website to learn more.
Shot over five years, Of Men and War gives perhaps the most in-depth look at the recovery efforts of veterans suffering from PTSD. Through unprecedented access to their lives at home and intensely vivid footage of some therapy sessions, director Laurent Becue-Renard unveils the gripping, upsetting reality that is the daily life of most war veterans.
"Simply and profoundly humanistic, Of Men and War is a massive film wrought from tiny gestures."
Visit Of Men and War Website
In this gourmet, across-the-world road trip, chefs, farmers, butchers, journalists and other experts weigh in on the various factors at play to help us understand the (r)evolution taking place as well as the challenges associated with this change.
Director Franck Ribière gets into all the methods of farming, butchery, and preparation used to prepare and serve the most widely adored meat on the market. Informative, beautiful and utterly tantalizing, this documentary is a must see for any steak enthusiasts.
AWAKE: The Life of Yogananda is an unconventional biography about the Hindu Swami who brought yoga and meditation to the West in the 1920s. Paramahansa Yogananda authored the spiritual classic "Autobiography of a Yogi," which has sold millions of copies worldwide and is a go-to book for seekers, philosophers and yoga enthusiasts today. (Apparently, it was the only book that Steve Jobs had on his iPad.) By personalizing his own quest for enlightenment and sharing his struggles along the path, Yogananda made ancient Vedic teachings accessible to a modern audience, attracting many followers and inspiring the millions who practice yoga today.


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California Xtracts, Holy Basil, 60 Liquid Veggie Caps (Discontinued Item)
You purchased this item onView this order
Loyalty Program
- You earn loyalty credit for every order you place at iHerb!
- Loyalty credit is equal to 10% of the value of your order, excluding shipping charges.
- Your loyalty credit will be applied towards your next order as soon as your current order has shipped.
- Your loyalty credits are valid for up to 60 days from the date of your last purchase.
Shipping Weight:?0.18 lbs (0.08 kg)
Shipping Weight
The Shipping Weight includes the product, protective packaging material and the actual shipping box. In addition, the Shipping Weight may be adjusted for the Dimensional Weight (e.g. length, width & height) of a package. It is important to note that certain types of products (e.g. glass containers, liquids, fragile, refrigerated or ice packed) will often require protective packaging material. As such, these products will reflect a higher Shipping Weight compared to the unprotected product.
- Product Code: CXT-00334
- UPC Code: 898220003341
- Package Quantity: 60 Liquid Veggie Caps
- Dimensions: 1.9 x 1.9 x 3.4 in, 0.15 lbs (0.07 kg)
- May help support healthy mood and stress levels*
- Organic holy basil with supercritical CO2 extract
- 100% Vegetarian
- Herbal Supplement
- Cap-Pro
Suggested Use
Take 1 cap, 2 times daily or as directed by your healthcare professional.
Other Ingredients
Non-GMO soy lecithin, vegetable cellulose, chlorophyll.
Do not take during pregnancy.
Keep out of the reach of children.
|Supplement Facts
|Serving Size: 1 Veggie Cap
|Serving Per Container: 60
|Amount Per Serving
|300 mg
|Holy Basil Leaf
|Ethanol Extract
|Holy Basil Leaf
|150 mg
|Supercritical Extract
|20 mg
|8 mg
|Rosmarinic Acid
|8 mg
|Ursolic Acid
|5 mg
|*Daily Value not established.


text:
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Avenzoar Digital Pathology Tool
Avenzoar is a one-year exploration of renal cell carcinoma morphology and its related single nucleotide polymorphisms (SNPa) as a method of automating diagnosis of cancer by using a computer-aided decision tree controlled by analytical statistics.1 weekly downloads
A Project that dedicates itself to creating alternate Programs for Windows, Linux (probably Mac too ) in Visual Basic and C1 weekly downloads
PC race game outgauge, by 89S52 MCU, to show live data which is transmitted by COM port. Program running on PC is written in VB6 special thanks to Siklosi Janos who supported me to get game data video: http://www.youtube.com/watch?v=NfWMRNuJebo1 weekly downloads
Small PSP homebrew, some cools spaceship-race and other space stuffs.1 weekly downloads
Conquest1401 das BrowserGame von Alexander Vogt. Lange ist es her das es lief, nun ist es Open Source! Es wird weiter Entwickelt. Also keine Sorgen machen. Die Version 2 wird aber nicht unter Open Source laufen. Geschrieben in PHP, C/C++ und Mysql!
Simultaneous Turn Based Meta Engine - A project to create a game engine that can support different regions, units, rules and turn sequences. STaBME will provide automation of most traditional board games and the creation of new ones.
Staples Data Population & Migration Adm.
The Staples Data Population & Migration Administrator is an application for the SuperWikia programming language which auto-builds critical infrastructure for cloned patches and provides backend server capability for smaller projects.
Super Computer Cloud computing
we are going to build one big supercomputer though cloud computing sof


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Freshly Squeezed by Ed Stein
- August 08, 2011
- From Beginning
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Comments (5) (Please sign in to comment)
Hard to be a hero.
Sounds like my semi retirement, but my children are all gone and the gbabies aren't old enough, yet.
Yea for Grampas! I wish my own Dad had lived long enough to see his grandchildren. I'm looking forward to becoming a Grandma one day.
Such a sacrifice.
Never did that, no baseball out side of school. But it is good for the children who do to have parents and family members to watch.
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marketing coordinator jobs near Lone Tree, CO
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Secondary Marketing Specialist
LENDERLIVE NETWORK LLC - Glendale, CO
The Secondary Marketing Specialist maintains an understanding of client specificlock requirements and product knowledge....
Universal Banker (01-534) - Castle Rock
ANB Bank - Castle Rock, CO
ANB Bank hires and rewards great people who are passionate about customers. Identifies customer's financial needs through in-person efforts, cold calls,...
Data Entry / Sales Coordinator
Arrow Electronics, Inc. - Centennial, CO
Proficient in Microsoft Word, Excel, and Outlook. As a Demand Creation Coordinator, you will be responsible for entering and maintaining data within the Arrow...
Marketing Coordinator
TalenTrust LLC - Denver, CO
The Marketing Coordinator will create and launch communication, edit marketing materials, and help with any other marketing projects as needed....
Brews Coordinator
Red Robin - Greenwood Village, CO
Ability to interface across all levels of the organization. Manages the restaurant beer request process to ensure timely turnaround for restaurant beer system...
Marketing Coordinator
Power Motive Corporation - Denver, CO
Create a sound marketing plan and manage the marketing budget. Marketing – Used Department*. Marketing – New Equipment/General Line*....
Advertiser/Publisher Account Coordinator
Banner Edge Media - Denver, CO
Advertiser/Publisher Account Coordinator*. Daily monitoring of trends and patterns from online marketing efforts....
Brand Manager – Revenue Generation
Red Robin - Greenwood Village, CO
Manage and support Marketing Coordinator with corporate events, sponsorships, highway signs, lease required advertising, and Burgers For Better Schools....
Business Development Manager HOA/Commercial Management Market
Caretaker Landscape and Tree Management - Denver, CO
Proficient in MS Outlook, Word, Excel and PowerPoint. Work with Business Development Coordinator to put together bid package....
Affiliate Marketing Associate / Coordinator
Acceleration Partners - Denver, CO
1-4 years of online marketing, e-commerce, or affiliate marketing experience. Advanced Excel capabilities and comfortable with formatting, formulas, customizing...


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Search results for 'aprilia'
Techmount GEN 4 Brake & Clutch Control Clamp Mount for select Aprilia, Benelli, Ducati, Harley-Davidson, Honda, Hyosung, Kawasaki, Moto Guzzi, Suzuki, Triumph & Yamaha
The Control Clamp Mount fits a wide range of Metric and Harley-Davidson bikes (clutch or brake side). Replaces the two factory pinch bolts with new stainless steel bolts and spacers on the handlebar controls.Learn More$39.95
SW-MOTECH Bags-Connection Slipstream Tail Bag
The Slipstream is a small, compact, 13-liter tail bag suitable for day trips. Fits the passenger seat of most bikes. Includes integrated backpack straps and bungee net.Learn More$162.95
SW-MOTECH Bags-Connection EVO Rearbag motorcycle luggage system
The Rearbag can be attached to your passenger seat or rear rack of any motorcycle. This bag also doubles as a backpack. A medium size bag at 24-36 liters when expanded is suitable for a day or long weekend trip.Learn More$249.95
SW-MOTECH EVO CargoBag Motorcycle Luggage System | 50 Liter
The SW-MOTECH EVO Cargo Bag Motorcycle Luggage System is a large 50-liter tail bag suitable for long weekend trips. Fits to the rear seat of several bikes.Learn More$239.95
Techmount Universal 7/8" (22mm) up to 1 1/4" (32mm) Handlebar Mount, black, silver or chromeThis is the Techmount 3rd generation mounting system. They were able to combine all of the current production handlebar sizes from 7/8 (22mm) up to 1 ¼ (32mm) into one mount system. This allows it to fit virtually every motorcycle with tubular handlebars. Requires only ¾ of handlebar space and can be mounted at any angle. Available in Black, Silver oe Chrome. Having no need for a shaft, makes this mount system very strong and very compact. Learn More$79.95 $34.95


text: Envivio is presenting its solutions for personalized TV on any screen. The company is demonstrating a connected TV experience with HD video quality and low bandwidth requirements. The software-based approach is designed to enable cloud TV, reduce infrastructure investments, and facilitate upgrades to HEVC (H.265) encoding and 4K Ultra HD TV. My neighbor works for MS and is on the MPEG committee and in a conversation I had with him a couple days ago stated that H.265 is a huge leap forward in compression technology. Also on display will be Envivio's solution for TV Anytime, for time-shifted TV, network DVR, catch-up, start-over and ad insertion on any screen. Envivio's compression and video processing solutions will also be featured as part of Sequencia's private cloud demonstration. It will definitely be interesting to see how DVR in the cloud works.


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An accessory available for many cameras that allows an additional battery (or possibly AA batteries) to be inserted and duplicates controls for vertical shooting.
19k views
Is it worth buying a battery grip for my camera?
Recently I heard that a battery grip can enhance the feel of the camera in my hands especially if it's an entry DSLR, and besides, some people claim that it enhances the stability of the camera if you ...
5k views
Which battery grip should I get for my Canon 60D and why?
I'd like to buy a Canon 60D battery grip not only for the extra battery power but also, and mainly because of the added size and the extra buttons. (I have huge hands) My question is; How is this $...
859 views
Why buy a battery grip?
Back in the film days I really never liked grips to much I'm not sure why, but lately I have been thinking of getting a grip. I mostly shoot landscapes and nature so the plus for getting a grip would ...


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I haven't participated in the Photo Friday challenge in months. Maybe that can even be counted in years but I still get the prompts. This week's was "chill" and well, I've had the camera out alot this week in rather "chilly" weather conditions. It just so happens I had a shot to submit as well as access to the photo while I had time to compose this! Really – how often do the stars align that perfectly?
Photo Friday: Chill
1 Comment
I *LOVE* this photo!


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Have you thought about sharing your Science, Technology, Engineering, Arts and/or Mathematics (STEAM) dynamic classroom activities, mini-projects, or career knowledge with others? If you have, we are inviting you to submit a proposal for the 6th annual STEAM Conference that will take place on Saturday, October 29, 2016 at Golden Gate High School.
Staff, Students, Parents, and Community Members are invited to present at this innovative conference. In addition to professional development sessions for educators and administrators, the STEAM Conference will also offer sessions focused on STEAM careers for students.
ENHANCED this year! A special STEAM Village will be available for parents and children who would like to experience several hands-on, mini STEAM projects throughout the morning. Additionally, high school academies and the entrepreneurship program will be highlighted


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My blog mostly images and few of them is quite big, but I don't want to resize them.
When posting, only part of the image get show up, part of it has been hidden by the sidebar (the right sidebar).
Is there anyway to put the image over the sidebar so user can see the image?
Thank you very much.


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While you may feel like a 20-something at heart, your body is showing signs of wear and tear, with occasional breakdowns.
Gaining Weight Gracefully
by Maryanne Reed • • 0 Comments
I've already accepted my new weight as the new "normal" and recently replaced all of my slacks with the next size up.
How Facebook Changed My Life
by Maryanne Reed • • 0 Comments
Now, we're even getting together in real life, planning races and reunions in cities where one or more of us live.
Losing My Hearing and Finding Jill
by Maryanne Reed • • 0 Comments
You can overcome almost any obstacle if you have good food, a warm bed, regular exercise and people you love who also love you.
Mothering My Niece
by Maryanne Reed • • 0 Comments
The voice on the phone was calm, at first. It was my niece Maya describing her last day in New York, getting ready to leave for film school. As she continued to talk, her anxiety ratcheted up. Then, she burst into tears. "I don't have any clean pants to wear," I heard through her sobs.…
Running For My Life
by Maryanne Reed • • 1 Comment
Middle-age runners (40-plus) are among the fastest growing group of marathon finishers.
A Lesson In Love and Loss
by Maryanne Reed • • 1 Comment
My dad was also in a hurry to dispose of anything that reminded him of my mom.


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This story is contributed by a member of the Ventura community and is neither endorsed nor affiliated with the Ventura County Star.
Local Youth Theater to perform The Secret Garden
After many hours and lots of sweat, the Camarillo Skyway Theater will host this classic tale July 24-27.
The theater workshop has been home to the 22 young people for the past two months; they have tirelessly worked on getting the production to come together.
The producer, Lorna Bowen and two directors, Olivia Heulitt and Hayley Silvers, have been working on the set/stage and with the actors with grace and loving guidance. For the actors, this has been an incredible journey and an invaluable outlet for their creative energy.
With school arts and drama programs being cut more every year, these local organizations that offer programs to our young people become more valuable.


text: Traditional Nordic Knitted Dog Jumper by Willieratbag 20% OFF £30$53.70€36.18$40.26 £24$42.96€28.95$32.21 6 customer reviews(6) Made to order £18.50$33.12€22.31$24.83 delivery to United States Receive this item 5-10 working days from dispatch International delivery available would you like a harness hole?would you like a harness hole? (required)Yes pleaseNo thank youwould you like a harness hole? (required)Yes pleaseNo thank youwould you like a harness hole? (required)Yes pleaseNo thank youwould you like a harness hole? (required)Yes pleaseNo thank you sizesize (required)SmallMedium (+ £4)Large (+ £8)XL (+ £12)size (required)SmallMedium (+ $7.16)Large (+ $14.32)XL (+ $21.48)size (required)SmallMedium (+ €4.83)Large (+ €9.65)XL (+ €14.48)size (required)SmallMedium (+ $5.37)Large (+ $10.73)XL (+ $16.10) colourcolour (required)RedBluecolour (required)RedBluecolour (required)RedBluecolour (required)RedBlue quantity by Willieratbag Location: Devon , GB read seller's profile see seller's complete range more items from this seller 20% OFF Gingerbread Man Dog Jumper And Scarf Gift Set by Willieratbag £75$134.27€90.47$100.66 £60$107.41€72.37$80.53 20% OFF Mr Digby Loves Bacon Knitted Dog Jumper by Willieratbag £30$53.70€36.18$40.26 £24$42.96€28.95$32.21 Personalised Initial Dog Jumper by Willieratbag £35$62.66€42.22$46.97 20% OFF First Birthday Knitted Number One Cushion by Willieratbag £25$44.75€30.15$33.55 £20$35.80€24.12$26.84 20% OFF Halloween Pumpkin Knitted Dog Jumper by Willieratbag £30$53.70€36.18$40.26 £24$42.96€28.95$32.21 20% OFF Little House Knitted Cushion by Willieratbag £25$44.75€30.15$33.55 £20$35.80€24.12$26.84 view all you may also like PRODUCT DETAILS CUSTOMER REVIEWS DELIVERY RETURNS Made in Britain ask seller a question save for later A very festive and traditional fair-isle knitted jumper guaranteed to make your doggy feel all warm and cosy this winter. Each jumper is knitted with a choice of a background colour which has then been sprinkled all over with crisp white nordic snowflakes. All jumpers are knitted to order in set sizes, we understand that not all doggies are the same length, feel free to get in touch and let us know the required length and we can knit your jumper that little bit longer, because no one likes a chilly behind! The jumper is sleeveless in design, perfect for first-time clothes wearing dogs. All of our jumpers have been knitted in the best sourced yarns to ensure comfort when wearing. Harnesses can easily be worn over the top, or upon request a harness hole can be placed between the neck and body of the jumper for easy connection of a lead. Choose from a traditional holly berry red or Frozen inspired blue, both equally very festive for the holidays. I offer a free gift wrapping service. Your jumper will come wrapped in tissue paper and sealed with a special notonthehighstreet.com sticker. made from: Knitted in 50% wool 50% acrylic. All jumpers are made to order and during busy periods, this process can take up to two weeks for completion. Hand wash or gentle machine wash below 30 degrees. Do not put on spin, or wash with towels as this will result in felting. Do not tumble dry, dry flat. dimensions: Available in four sizes. XL can be seen in the main photo. Small measures: Chest girth 25cm-32cm (10"-12") Length 23cm (9"). Medium measures: Chest girth 33cm-42cm (13"-16") Length 28cm (11"). Large measures: Chest girth 43cm-52cm (17"-20") Length 33cm (13"). XL measures: Chest girth 53cm-63cm (21"-25") Length 41cm (16"). product code: 261064 6 customer reviews read about our product rating system ratings guide trusted independent customer feedbackforum excellent bad good poor This product is dispatched to you by Willieratbag. MAINLAND UK order now and receive this item by price Standard Delivery Tuesday 9 August £2.75$4.92€3.31$3.69 NON-MAINLAND UK estimated delivery price Highlands & Islands of Scotland 2-5 working daysfrom dispatch £2.75$4.92€3.31$3.69 Northern Ireland 2-5 working daysfrom dispatch £2.75$4.92€3.31$3.69 Other UK Islands 2-5 working daysfrom dispatch £2.75$4.92€3.31$3.69 INTERNATIONAL DELIVERY estimated delivery price Western Europe 2-5 working daysfrom dispatch £11.50$20.58€13.87$15.43 Rest of Europe 5-10 working daysfrom dispatch £11.50$20.58€13.87$15.43 USA & Canada 5-10 working daysfrom dispatch £18.50$33.12€22.31$24.83 Asia & Australasia 5-10 working daysfrom dispatch £19.50$34.91€23.52$26.17 You have 28 days, from receipt of cancellable goods, to notify the seller if you wish to cancel your order or exchange an item. Please note: goods that are personalised, bespoke or made-to-order to your specific requirements, perishable products and personal items sold with a hygiene seal (cosmetics, underwear) in instances where the seal is broken are non-refundable, unless faulty. Read more about our returns policy.Should you choose to return or exchange your order you will need to deliver the item(s) to the UK, where this seller is based. Willieratbag's return policy Please see notonthehighstreet.com's returns policy.


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This July my husband and I planned our wedding at the GPJ. We had over 52 book a vacation for our wedding We had people coming in at various days. We had already booked Mr. Morris for several excursions for our guest, but on one particular day we had about 20 people who descend on the island and were looking for something to do. So our tour operator Natalie called Mr. Morris who was more than willing to take us out for the day. He was absolutely wonderful. When went into one of the shopz to purchase spices. The upcharge that the store owner was ridiculous. I left without my spices and a bit frustrated. To my surprise the next day when Mr. Morris had purchased the spices for me at a local store that he goes to at a tenth on the price. He found my mother and gave them to her as a gift from him. I was truly touched that he was so thoughtful and thought enough of me to find them and bring it back.
I would recommend Mr. Morris to anyone traveling to Jamaica and looking for exceptional service and an outstanding tour experience.
Thank you so much for your service and kind heart and spirit.
Tenise Whiteside
Own or manage this property? Claim your listing for free to respond to reviews, update your profile and much more.


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Montana Chapter
About the Montana Chapter
Find information regarding your Chapter Governors, Chapter Leadership, Membership, and more.
News & Meetings
Information on what's new in the chapter including meetings, newsletters, and dates of interest.
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Directory of practice management resources and tools that might be of interest to you.
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Carrie Reisig
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Email: email@example.com
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Yo Mineo, can you make me co-maintainer and/or update the $source URL to reflect that the Picard repositories are now under the @metabrainz GitHub org.? :)
Search Criteria
Package Details: picard-git 1.3.2.r270.g34af84f-1
|Git Clone URL:
|https://aur.archlinux.org/picard-git.git (read-only)
|Package Base:
|MusicBrainz tagging application
|Upstream URL:
|Mineo (Freso)
|Last Packager:
|First Submitted:
|2011-09-17 12:26
|Last Updated:
|2016-03-06 21:08
Dependencies (5)
- mutagen (mutagen-hg)
- python2-pyqt4
- git (git-git) (make)
- chromaprint (chromaprint-fftw, chromaprint-git) (optional) – AcoustID integration
- python2-discid (optional) – CD-Lookup feature
Required by (3)
- picard-plugins-aux (requires picard)
- picard-plugins-git (requires picard)
- picard-plugins-search (requires picard)
Sources (1)
Latest Comments
Freso commented on 2016-03-06 12:21
Mineo commented on 2015-09-24 07:13
phw: Done.
phw commented on 2015-09-23 11:18
A .install file similar to https://projects.archlinux.org/svntogit/community.git/tree/trunk/install?h=packages/picard would be nice so icons get updated after installation.
JonnyJD commented on 2014-05-02 10:16
The stable picard package now includes the plugins from the contrib folder.
It would be nice if the -git package would do the same.
See: https://bugs.archlinux.org/task/40139
Freso commented on 2012-06-02 23:47
lockheed (and others): Picard's Git repository is managed on GitHub. If you want to have your own patchsets applied to the code, it's really easy to "fork" Picard, apply your patches, and tell your copy of this PKGBUILD to use your forked copy of the picard source tree instead of the official one: Simply find the line starting with "_gitroot" (line 15 at the moment) and replace "musicbrainz" with your GitHub user name. Save and "makepkg". Voila!
Montague commented on 2012-05-07 12:22
Thanks Mineo; and I just realized my last sentence didn't make much sense, I was typing too fast but glad you understood anyway :)! --> s/in the depends line this error/in the depends line would avoid this error/
Mineo commented on 2012-05-05 16:06
lockheed: No, I won't apply any patches to this, but if you need it, you can always modify the PKGBUILD before building your package.
Montague: I'll update the PKGBUILD.
lockheed commented on 2012-05-05 13:27
Would it be possible to implement 'Preserve file timestamps' upon rename?
I found a patch for it here: http://tickets.musicbrainz.org/browse/PICARD-31?page=com.atlassian.jira.plugin.system.issuetabpanels%3Aworklog-tabpanel
Montague commented on 2012-05-04 19:26
I get this error :
$ packer -S picard-git --> Dependency `python2-qt' of `picard-git' does not exist.
Easy to fix it : "packer -S python2-pyqt" followed by "packer -S picard-git"
But maybe changing 'python2-qt' to 'python2-pyqt' in the depends line this error altogether?
Montague commented on 2012-05-04 19:24
I get this error :
$ packer -S picard-git --> Dependency `python2-qt' of `picard-git' does not exist.
Easy to fix it : $ packer -S python2-pyqt picard-git
But maybe changing 'python2-qt' to 'python2-pyqt' in the depends line this error altogether?


text:
WATD Local Weather
Who We're Talking To
Nancy Furstinger joins Rob and Lisa to discuss her book "Paws of Courage: True Tales of Heroic Dogs that Protect and Serve!" Visit our Audio Archives page to hear the interview!
The South Shore's Morning News
Get the top stories of the morning every 30 minutes beginning at 5:00 a.m.!
Hear the traffic and weather together every 10 minutes on the "9's"!
That's at :09,:19,:29,:39,:49, and :59 minutes past the hour.
Be in the know on business news at :16 past the hour!
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lincoln Archive
What to do with the Kids: August 2nd – 4th, 2013Posted on August 1, 2013 | No CommentsWeekend Events: Scituate Heritage Days Friday August 2nd through Sunday August 4th. Each year, with the help of many volunteers, the Scituate Chamber of Commerce proudly presents Scituate Heritage Days. The annual event combines live music and entertainment, artisan crafts, kid's activities and historical site visits for one of the […]


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