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Skip to comments.Help Required...
Posted on 01/09/2011 5:13:33 AM PST by Mayr Fortuna
In the sixties late century I had my first English Course which was Eletronic Teacher (one of this boondozels pseudo-cientific thing that used bone induction subliminar learning techs...) and at end sixties Thomas Gefferson House in Brazilia - Brazil for two years...
I do have great difficulty with the double letters in words, as pp, ll, ss and so on...
Can you help me with a rule?
(Excerpt) Read more at freerepublic.com ...
Also ask you to implement policy of correcting me when you find needed in phrase construction...
I wish you luck. English must be tricky to learn as a second language.
Very simple to understand. Let me take the word "Apple" as an example. Apple has two syllables "AP" + "PLE" (pronounced Ap-pul with the emphasis on the Ap)
It is confusing because some words begin or end with double letters where the rule of pronouncing the letter twice does not apply, such as "full" or the name "Aaron".
In those cases the pronouncer would be a slightly stronger emphasis on the double letters.
Hope that helps.
Rules aren't very reliable. Often, double consonants are found in conjunction with short vowel sounds. Copper, hidden, tapping. Single consonants accompany long vowel sounds. Hoping, hiding, taping.
We are having great difficulty with Barry Barrack and Barrak.
I'll treat this as a serious question.
Generally, the double consanant is employed to preserve the short vowel sound preceeding it. If a vowel is followed by a consonant and another vowel, it takes the long sound of the vowel (when two vowels go walking, they play a little game. The last vowel is silent, the first says it's own name.) and the second is not sounded.
An example is found by the word "rap". It means to hit something, like knocking on a door and is synonymous with "tap". If it is an on-going action we give it an "-ing" suffix. However, to preserve the vowel sound we must double the "p", thus "rapping."
If we didn't double the "p" the "a" would be sounded with the long sound, making the word "raping". That has a different meaning entirely.
Hope this helps.
Thank you for being kind.
why the English language is so hard to learn:
> 1) The bandage was wound around the wound.
> 2) The farm was used to produce produce.
> 3) The dump was so full that it had to refuse more refuse.
> 4) We must polish the Polish furniture.
> 5) He could lead if he would get the lead out.
> 6) The soldier decided to desert his dessert in the desert.
> 7) Since there is no time like the present, he thought it was time
to present the present.
> 8) A bass was painted on the head of the bass drum.
> 9) When shot at, the dove dove into the bushes.
> 10) I did not object to the object.
> 11) The insurance was invalid for the invalid.
> 12) There was a row among the oarsmen about how to row.
> 13) They were too close to the door to close it.
> 14) The buck does funny things when the does are present.
> 15) A seamstress and a sewer fell down into a sewer line.
> 16) To help with planting, the farmer taught his sow to sow.
> 17) The wind was too strong to wind the sail.
> 18) After a number of injections my jaw got number.
> 19) Upon seeing the tear in the painting I shed a tear.
> 20) I had to subject the subject to a series of tests.
> 21) How can I intimate this to my most intimate friend?
> English: interesting language.
> There is no egg in eggplant nor ham in hamburger; neither apple nor
> pine in pineapple. English muffins weren't invented in England or
> french fries in France. Sweetmeats are candies while sweetbreads,
> which aren't sweet, are meat. We take English for granted. But if we
> explore its paradoxes, we find that quicksand can work slowly, boxing
> rings are square and a guinea pig is neither from Guinea nor is it a
> pig. And why is it that writers write but fingers don't fing,
> grocers don't groce and hammers don't ham?
> If the plural of tooth is teeth,
> why isn't the plural of booth beeth?
> One goose, 2 geese. So one moose, 2 meese?
> One index, 2 indices?
> Doesn't it seem crazy that you can make amends but not one amend? If
> you have a bunch of odds and ends and get rid of all but one of them,
> what do you call it? If teachers taught, why didn't preachers praught?
> If a vegetarian eats vegetables, what does a humanitarian eat?
> In what language do people recite at a play and play at a recital?
> Ship by truck and send cargo by ship?
> Have noses that run and feet that smell?
> How can a slim chance and a fat chance be the same, while a wise man and
> a wise guy are opposites?
> house can burn up as it burns down, in which you fill in a form by
> filling it out and in which, an alarm goes off by going on.
> People, not computers invented English, and it reflects the creativity
> of the human race, which, of course, is not a race at all. That is why,
> when the stars are out, they are visible, but when the lights are out,
> they are invisible.
> Why doesn't "buick" rhyme with "quick"?
Start here for quick reference:
Further resources via this search result:
Can you help me with a rule?
OK, I'll bite. Jemian is right.
Double consonents such as "pp" are usually preceded by a short vowel sound. For example, supper. We had rice and beans for supper.
Single consonents such as "p" are usually preceded by a long vowel sound. For example, super. Super man can fly through the air.
Another example: Feathers are a filler for pillows. The office manager needs a filer to store his folders.
Flash back to "grammar" school. Still makes my head hurt. The "rules" drove me crazy, especially because there were so many exceptions. For an A.R. type, it was pure heck. I before E EXCEPT after C. Yea, right. That sure makes sense.
Back in elementary and high school we were given a lot of rules for spelling and pronunciation. It seems every rule had an exception. I still have a problem with spelling, if not for spellcheck Id be lost. English is one of the most difficult languages to learn, maybe because its a composite of several languages. Spelling and pronunciation is dependant to a large extent on which language the word came from.
My only advise is to speak English as much as possible with native English speakers and be aware that British and American English is not the same. When it comes to spelling, read a dictionary as much as possible.
Don't worry some of us make misstakes all the time.
Reading through the misstakes is a useful talent.
Start here for quick reference:
Further resources via this search result:
You may not have been as helpful as you intended.
And spelling I was trying to help a young lady learn English. She thought I was messing with her when I told her how to pronounce telephone. When she sounded it out she said tele pa ho ne.
ROFL, thanks for that.
Well, honey, we all have trouble with him.
Well, honey, we all have trouble with him.
For the same reason boot doesn't rhyme with foot.
If you ever figure it out, let me know. 58 years old and still wondering about my native language. It does keep crossword puzzles interesting because you can never be sure which pronunciation/meaning of a word is being used.
I had better shut up now....
where are the zot kitties???
As an example of how much our language has changed over the years, read Washington's Rules of Civility (1744)
>>11th Shift not yourself in the Sight of others nor Gnaw your nails.
12th Shake not the head, Feet, or Legs rowl not the Eys lift not one eyebrow higher than the other wry not the mouth, and bedew no mans face with your Spittle, by approaching too near him when you Speak.
13th Kill no Vermin as Fleas, lice ticks &c in the Sight of Others, if you See any filth or thick Spittle put your foot Dexteriously upon it if it be upon the Cloths of your Companions, Put it off privately, and if it be upon your own Cloths return Thanks to him who puts it off.<<<
It indeed is amazingly amusing isn´t it?
However, what throws me off is when we try to incorporate foreign words into our language. An amusing example for me is hors d'oeuvres which means appetizers in English. Well because I read the word in books and never heard how it is pronounced, I always figured it was pronounced like "Whores Dovers". So in my younger years when I mentioned we were having Whores Dovers at a party I was having, everybody figured that prostitutes would be there instead of scallops wrapped in bacon.
After that experience, it always did annoy me to see people dropping foreign words into their conversations. I think they do that to come across as "classy" and "educated" but they should really just stick to using English words and leave those fancy sounding words in Europe where they belong.
Never heard of it? It was a late scientific technique developed in USA and sold for us in Brazil as the "most amazing scientific new discover" and by the time I was a kid 15 yo. only that was crediting science a lot...
Anyway, I was young, credulous and eager to learn, and that was when I begun learning English, which I am proud to know a bit and be able to read and exchange with some of you...
Yes, very.
I read your comment; I hope others read it also.
Ref post #13.
Thank you for sharing. I really enjoyed it.
"If the word has a suffix but a single consonant followed by a vowel drop the vowel and double the consonant except in words that have two or more syllables and one of the double letters would be sounded with the second syllable if the word had no suffix. If the word has two more syllables and the last single consonant would NOT be sounded with the second or last syllable then double that last consonant and drop the last vowel before adding the suffix UNLESS there is only one syllable in the word and it has a double consonant and NO vowel, in which case simply add the suffix. There are exceptions to this simple rule and they are many.
For example, "piling vs. pilling" and slang words and words of foreign origin.
The above applies in cases of vowel SOUNDS following the second con........
Just use Spellcheck and take your chances.
I learned to read at an early age. My parents taught me to read before kindergarten. I never had a problem with such words as To, Two and Too. But my spelling has always been terrible. As you notice my grammar still needs some help.
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The Rookies (TV Series)
Ladies Day (1975)
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After Jill Danko and one of the doctors from the hospital are taken hostage at the women's prison farm, officers Danko, Webster, Owens, and Sgt. Ryker are called in to diffuse the situation.- Written by Roger Campbell
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Separate names with a comma.
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Message Subject
The moon's crookedness is caused by our going toward the center of the galactic plane
Poster Handle
my name is 905
Post Content
After the first few posts I skipped to the end to say this;
The moon is where it should be, when it should. How do I know?? BECAUSE I LOOK!!!!! All the time!!!!
There are plenty of other things going wrong without focussing on .......
my name is 905
I hope you can some future time enjoy the entire thread, so that your Flag actually might mean something!
Here's the recap if nothing else so you can hopefully quickly see in your attention-deficit ways that there is something more here that we Should pay Heed too!
*Thread title stands: we are going to the plane of the galactic, and of course it's not so much that it
tilts that the Earth does, and our viewpoint of such testifies to this, under of course those certain
conditions that would precipitate such tiltage, to wit, more magnetic push.
*Only the Earth tilts because it is made of Iron, and the moon doesn't follow suit because it is not.
*The movement and appearance of the moon through our sky doesn't change because of FR (field rotation) but
only when the person on the Earth goes from North to South or South to North (e.g. traveling to Australia
from Canada or vice versa).
*Normal obvservational tilt has always and forever shall be (until EOY IMO) Libration, and that covering a
span of the month, so as to not be observable to the naked eye.
*The size of the Moon (being the same visible in the sky as the sun) is accounted for by the many Lunar
and Solar eclipses in its history.
*Our Moon might have once been a satellite of Saturn.
*Likewise, the surface of the Moon has been so baked down to almost a glass crust, no Flag could've been
stood on the Moon, nor any foot or vehicle prints left.
*Probability of the moon shattering eventually is High, having become a very brittle shell, and having no
intrinsic dependable structural integrity of its own--ie no FE core.
*Our atmosphere has shrunk, adding to the brightness of the Moon (from an already bright sun).
*The Annular eclipses of the moon are a new phenomenon, with the moon receiving a more eliptical orbit,
not to mention the Sun getting bigger.
*A full moon has more low vibratory frequencies in response to the sun's light, giving a negative effect on the human body and psyche, leading to increased statistical crime.
Bark at the Moon!
[link to www.youtube.com]
Anonymous Coward 27374412
Thanks for the synopsis, much appreciated. Thread title was a bit misleading as I am an avid moon-watcher, mostly due to your last paragraph referring to the full moon's negative effect on the psyche.
My wife is hyper sensitive to this and goes through near Jeckyll-Hyde phases, mostly just before full and to a lesser extent around the new moon.
Hence the reason that I carefully track moon phase and position, as well as distance (perigee and apogee) as this also has an influence. I can (and have) predicted these severe mood swings a year in advance with about 95% accuracy to the day.
Pending a full reading of the thread, I hereby provisionally...
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|Joe Kelly on MFB: New pitching coach Carl Willis 'focused on what your strengths are as a pitcher'
|06.16.15 at 12:48 pm ET
Red Sox starting pitcher Joe Kelly joined Middays with MFB on Tuesday to discuss the team's struggles, his own pitching adjustments and his work with NIVEA Men. To hear the interview, go to the Middays with MFB audio on demand page.
Kelly talked about the difference in style between ex-pitching coach Juan Nieves, who was fired last month, and current coach Carl Willis.
"Juan was a great guy. He was a good pitching coach," Kelly said. "He was more focused on scouting reports — what the hitters don't hit, what this guy does against the slider, what do you do in certain situations. Carl's been awesome too. He's mainly focused on what your strengths are as a pitcher. If you're a sinker guy, you're not going to go out and throw four-seams at a team and try to beat them that way. He tries to focus on that other aspect of your game."
Kelly was asked about Adam Wainwright from his time in St. Louis and what type of leader he was. On top of how great he was in St. Louis, he said even this year he sent him video to help him with his mechanics when he was struggling.
"[Wainwright] was the best," Kelly said. "He's an on-field pitching coach. It was pretty neat to be a part of. Whenever I struggled or messed up with mechanics, he was always the first one there to help me. Even earlier this year, I gave up 21 runs in 21 innings and he saw a bunch of stuff wrong with mechanics and sent me over a couple of video clips and talked to me on the phone. He helped out a little bit right then and there to get me back on track."
When asked about his struggles, Kelly discussed his continued role as a student of the game, both about himself and opposing hitters.
"I haven't had a full year as a starting pitcher in the big leagues," he said. "So I'm just learning hitters and learning my stuff. Guys with velocity [can be] very easy to hit. I hit a double off of [Jeff] Samardzija at 98. I can do that stuff — it's not very hard actually. It's just different kinds of mixes of pitches and locations. It's more about hitting spots and trying to locate with the fastball."
With talk of Kelly moving to the bullpen as the Red Sox moved away from a six-man rotation, he talked about his stance on the switch.
"I love starting. I love knowing when I'm gonna pitch," Kelly said. "That's where I am right now and that's where my main focus is. One day, eventually, if that happens in my career, of course I'm going to stay in the game and help get guys out and perform for my team."
As Red Sox slog through a seven-game losing streak, Kelly was asked if manager John Farrell has lost control of the team.
"No, obviously John has all the control," Kelly said. "As a player, it's just getting frustrated about how everything's been going. As a team we're not playing well and sometimes that gets the best of us. You've been trained your whole life to beat the other person, to always win and to always give your best no matter what. So when someone puts it into your game, whether you're doing good or bad, you're going to be mad always."
Following are more highlights from the interview. For more Red Sox news, visit the team page at weei.com/redsox.
|Jonny Gomes shows how to play left at Fenway, offers Red Sox hope: 'You would think it's going to turn around'
|at 8:17 am ET
If Hanley Ramirez wanted help in how to play left field at Fenway, perhaps he should chat up Jonny Gomes.
The Braves left fielder not only robbed former teammate Dustin Pedroia of a sure double to open the bottom of the fourth Monday night, he explained the intricacies of the position after Atlanta walked away with a 4-2 win at a rain-soaked Fenway Park.
"That's how you've got to play that outfield. It's extremely risky," Gomes said. "That exact play right there, you dive for it and get the out. Worst-case scenario, you dive for it and you've got the wall right there so it could be a double. Or take the angle and give him the double. So it worked out."
Because Gomes was playing in and because he certainly wasn't afraid to lay out on the wet grass, he was able to time his dive for the ball.
"I actually found myself diving a bunch here because a normal fence is about 340 feet down the line, play about 60 feet in front puts you at about 280," Gomes said. "But 310 here, 40 feet in front, you're playing at about 270 feet, which a lot of people don't realize when that ball gets on you hot, it's kind of like that one. You're diving all over the place."
Gomes certainly feels for former teammates like Dustin Pedroia, David Ortiz, Xander Bogaerts and Mike Napoli, suffering through a miserable 27-38 season so far.
"Losing sucks flat out, at any level, any organization," Gomes said. "I've played on some good teams, some bad teams. I've been there before. It's not ideal but play this game long enough, you're going to have stretches like that.
"You look at that team on paper, it's a dangerous team. You would think it's going to get turned around. I'd roll my dice with that roster. With that being said, I don't wear that uniform anymore. Outside of 'hang in there,' I don't have much input. I'm focused on the Braves."
|A.J. Pierzynski recalls 2014 when 'it was all blamed on me' and insists 'there's no hard feelings'
|06.15.15 at 11:26 pm ET
The irony of the current situation the Red Sox find themselves in is not lost on A.J. Pierzynski.
The former Red Sox catcher, released last July 16 before being signed by St. Louis ten days later, returned Monday with the Braves and went 2-for-4 with an RBI in a 4-2 win over the Red Sox. The loss was Boston's seventh straight and dropped them a season-worst 11 games under .500 at 27-38.
It was Pierzynski who was the target of anonymous criticism inside the Red Sox clubhouse after his departure. There were those who suggested his negative attitude was a reason for the 2014 team heading south and falling out of contention early in the summer.
This year, despite a massive overhaul, that collapse is happening even sooner. Pierzynski told WEEI.com after Monday's game that he's not reveling in Boston's current misery.
"Yeah, we went through it last year and it was all blamed on me, which I thought was funny," Pierzynski said. "They have good players over there and they have good people over there and I wish them nothing but the best."
Pierzynski is referencing, of course, Red Sox sources inside the team's clubhouse that told Rob Bradford that the veteran catcher was a bad influence.
But aside from a little humor, Pierzynski chose the high road on Monday night.
"There's no hard feelings between me and the Red Sox organization," Pierzynski said. "I think people are expecting me to come in and [criticize]. But I have no hard feelings. Things just didn't work out the right way last year. And I ended up in a great place, in St. Louis and a chance to go the playoffs and that's what it's all about."
Pierzynski joined another former Red Sox player, John Lackey, in St. Louis. The Cards beat the Dodgers in the NLDS before falling to Pablo Sandoval and the Giants in the National League Championship Series.
"I thank the Red Sox and I thank the people here that supported me, the fans that were nice to me and look forward to playing here again [Tuesday]," Pierzynski said.
While the Red Sox could not be colder, Pierzynski is red-hot, batting .341 (14-for-41) with eight runs and five RBIs in his last 12 games this month.
|Craig Breslow activated from paternity leave, Travis Shaw optioned, Robbie Ross recalled, INF Jeff Biachi DFA'd, Luis Jimenez signs in Korea
|at 7:20 pm ET
When the Red Sox weren't busy defending themselves before Monday's series opener with the Braves at rainy Fenway, they were making several roster moves.
The club activated lefty reliever Craig Breslow from paternity leave and optioned infielder Travis Shaw.
Breslow, 34, was placed on paternity leave on Friday. He has no record and a 4.03 ERA with 18 strikeouts in 18 relief appearances for the Red Sox this season. His 22.1 innings pitched rank third in the Boston bullpen and 12th among AL left-handed relievers.
Shaw, 25, went 0-for-1 as a defensive replacement at first base yesterday after being recalled for his second career major league stint prior to the game. The left-handed batter is hitless in three at-bats over two career major league games, also on May 8 in Toronto. In 56 games for the PawSox this season, he has hit .256 (54-for-211) with eight doubles, two triples, five home runs, 26 RBI, and 22 walks, appearing in games at third base (30 games), first base (22), and left field (3).
The Red Sox also recalled left-handed pitcher Robbie Ross Jr. from Triple-A Pawtucket. To make room for him on the 25-man roster, infielder Jeff Bianchi was designated for assignment. Ross was made active in time for the series opener against the Braves.
|John Farrell: 'We're not in a good place right now'
|06.14.15 at 6:07 pm ET
If John Farrell is concerned about job security, he's not showing it.
Following another abysmal loss to the Toronto Blue Jays, dropping the Red Sox to a season-low 10 games under .500 at 27-37, the Red Sox manager continued to show support and complete belief in his team that they can turn things around.
The Red Sox sent their most reliable pitcher to the mound in Eduardo Rodriguez hoping to end a five-game skid. But thanks to a pair of shoddy plays in a windy, sun-baked right field and a questionable non-double play call at second base, the Blue Jays exploded for six runs in the fourth and four more in the fifth for a 10-0 lead.
The Red Sox battled back to make it 10-5 on a three-run homer from David Ortiz in a five-run fifth but could get no closer in a 13-5 embarrassment that gave Toronto its 11th straight win.
"Today, we got beat up but looking back at the energy inside the game, the energy is there," Farrell said. "We didn't handle every ball cleanly. That goes without saying. We get a ball in the following inning after the six runs that's an aggressive call-off by [Alejandro] De Aza, coming in from right field, where Xander is camped under it. It opens up the door for a couple more consecutive hits and a four-run inning. So, it's a ten-run hole we're in.
"Still, we continue to battle back. David with a big three-run homer to cut [deficit] in half. We kept clawing back into this. Yeah, we're not in a good place right now as a team. But it's not because we're not giving effort. We're not executing completely."
|Curt Schilling on D&C: Eduardo Rodriguez 'something special'
|06.10.15 at 10:03 am ET
ESPN analyst and former Red Sox pitcher Curt Schilling joined Dennis & Callahan on Wednesday morning to talk about the Red Sox and the talent of Eduardo Rodriguez. To hear the interview, go to the Dennis & Callahan audio on demand page.
Rodriguez has three impressive starts under his belt following the six scoreless innings of work he put in Tuesday night against the Orioles. Schilling has been very impressed with what he has seen from the young left-hander.
"You're looking at a guy who, for me, I thought he was by far the most talented player swapped at the deadline last year. He's just something special," Schilling said.
The Red Sox took a 1-0 loss and Rodriguez got a no-decision despite his continued success on the hill. According to Schilling, Rodriguez should not be concerned with the lack of run support he received.
"If you're focused and you're trying to win a game, you're pitching to the score as a young player," Schilling said. "These are the games you need to pitch when you're young. You need to learn how to pitch in the 1-0 games or the 2-1 games. Then you start to understand, you take the ball, you go out there and realize the leadoff hitter could be the winning run."
Regarding the struggles of David Ortiz against left-handers, Schilling said that it might be necessary for manager John Farrell to start resting Ortiz against southpaws.
"You can't let players manage themselves. … The thing that makes him John Farrell and the thing that makes him respected around the league is communication. That's a conversation. If you don't want to put him up there and you feel like he's overmatched, you have to have that conversation," Schilling said.
Injuries to catchers Christian Vazquez and Ryan Hanigan early in the season forced the hand of the Red Sox and made it necessary to bring Blake Swihart to the big leagues sooner than expected. Schilling stressed the peril of bringing young catchers to the major league level too early because of the multitude of responsibility placed on that position.
"As a pitcher, I was always very selfish from the standpoint of, 'I don't care if you go 0-for-4 and punch out four times on 12 pitches, I need you focused behind the plate.' And that's hard. Short of probably relief pitchers, I think that is the most dangerous position in the game to have a player in the big leagues prematurely," Schilling said.
|Red Sox-Orioles series preview
|06.09.15 at 9:26 am ET
Coming off of their first series sweep of the season over the Athletics, the Red Sox will carry their momentum to Baltimore for a three-game set with the Orioles.
With a 5-2 record, the Red Sox have had a stellar opening to June after a miserable May. They sit at 27-31, sandwiched between the Orioles and the Blue Jays in fourth place in the underwhelming AL East. Despite their losing mark, the Red Sox are just 5 1/2 games back of the first-place Yankees.
Though not the best measure of success, the Red Sox had the best series of their season against the cellar-dwelling Athletics this past weekend. Wade Miley and Joe Kelly each turned in quality starts that resulted in wins. Meanwhile, the bullpen was lights out, allowing just one earned run in nine innings of work. Then the Red Sox bats came alive Sunday, scoring seven runs in the eighth-inning to rally for a 7-4 victory.
The Red Sox have been unable to sustain momentum this season, but they have a great opportunity this week to string together some wins against an Orioles team that is 4-6 in its last 10 and sits in last place in the AL East. The O's are coming off of a series win against the Indians but dropped three out of four against the Astros to open June. Though they hold a narrow edge over the Red Sox with a 4-3 record in seven meetings this season, the O's will face a much-improved Red Sox rotation this week.
Similar to the Red Sox, the Orioles' major problem is their underperforming rotation, which ranks 23rd in the majors with a 4.16 FIP, worse than the Red Sox' 4.11 mark. Baltimore pitching has fallen victim to the long ball this season, as the O's give up 1.1 home runs per nine innings, the fourth-worst mark in the majors. The Orioles also struggle to keep runners off base, as they allow 3.2 free passes per nine innings. This walk rate plus home run prevention problems adds up to a team prone to giving up runs in bunches.
Though their offense has fallen short compared to recent seasons, the Orioles still have the characteristic big boppers that helped them to a 96-66 record last season. Led by Chris Davis, of 53 home run fame in 2013, the O's own the seventh-best isolated power offense in the majors. Three of their regulars have hit nine home runs this season: Davis (12), Manny Machado (9) and Adam Jones (9).
|Xander Bogaerts makes homework against Tyler Clippard pay off with game-winning hit
|06.07.15 at 6:13 pm ET
Nothing symbolized Sunday's dramatic rally from 4-0 down in the bottom of the eighth better than the at-bat Xander Bogaerts put up against Oakland closer Tyler Clippard.
Just like the Red Sox, who started the inning down four runs, Bogaerts found himself in a nasty 0-2 hole against the A's righty when he, like his teammates, began to chip away.
Bogaerts fouled off two fastballs from Clippard to fall behind two strikes before he really went to work. He took two straight pitches out of the strike zone sandwiched around a throw to first to keep Mookie Betts close. After Betts stole second to put runners at second and third, Bogaerts fouled off another pitch.
All the while, Bogaerts didn't change his strategy. A lot of batters would be defensive in this situation, down 4-3 with the tying and go-ahead runs in scoring position. Foul off pitches until you get a fastball you can drive. But Bogaerts, along with hitting coach Chili Davis had a better idea.
"I was not looking for a fastball that whole at-bat and he threw me a lot [of fastballs]," Bogaerts said. "I just fouled them off, stayed alive. I was looking for a changeup since pitch one and he threw me one right there."
Why wasn't Bogaerts looking fastball?
"He has a good changeup and he tends to throw at least one in every at-bat," Bogaerts said. "On the 2-2, I fouled one off right next to the dugout. Chili looked at me like, 'Yeah, that's it.' We always talk about it. It doesn't matter if you foul off a ball, you've got to try to pull it the next time. Just stay on it and he threw me what I was looking for. It was actually a really good pitch by him. I was just waiting on it and put a good swing on it."
Clippard tipped his cap to Bogaerts for hanging in and executing on a changeup that he couldn't have put in a better place.
"Threw a changeup down and in. I got it there. It was probably four inches off [the plate] in," Clippard said. "Normally, when guys get to that pitch, all they can do is hit it foul. He did a good job of staying inside that pitch running into him and kept it fair and hit it off the wall. I wasn't mad about the execution.
"He took some poor swings on my fastball throughout that whole at-bat. I felt like I did a good job of reading his swing up until that last pitch. Probably should have thrown another fastball but in hindsight it's always easy to say. It is what it is. I'm just trying to get him out any way I can. I'm trying to get him to chase my pitch and he put a good at-bat together after that and stayed inside the changeup."
Bogaerts admitted afterward that while he got the pitch he wanted, he knows he just as easily could have headed back to the dugout with the third out of the inning and the Sox still down a run.
"[Usually] a strikeout. I went back and saw that [on video]," he said. "I can't guarantee you that I would do that again if I got that pitch."
Things seemed somewhat dim heading into the bottom of the eighth. The Sox had managed just five hits in seven scoreless innings against Oakland starter Kendall Graveman.
"I remember just looking at the scoreboard in the bottom of the eighth, 4-0," Bogaerts recalled. "Just trying to think how we can get some runs. That was probably the biggest win for us this year, for sure."
|Mike Napoli on the pressure on suddenly hot Hanley Ramirez: 'I don't think that's too fair'
|06.06.15 at 10:44 pm ET
Mike Napoli knows there's a lot of pressure on Hanley Ramirez to perform. Maybe too much.
But the way the slugger has been playing the last 10 games, there are positive signs the investment in Ramirez is starting to really pay off.
Ramirez crushed a two-run homer in the first inning Saturday and had three hits to lead the Red Sox to a 4-2 win over the A's at Fenway. In his last 10 games, nine starts, Ramirez is batting .368 (14-for-38) with three homers. He has at least two hits in six of his last nine starts, lifting his average to .272 on the season.
Ramirez was signed for four years and $88 million in the offseason to do what he did in the first month of the season and what's he's done in the last 10 games since Texas.
"He's a superstar so there's a lot expected out of him," Napoli said after Saturday's win. "There's pressure on him every day to come through every single time. I don't think that's too fair but I think he's up to the task and wants to come through. He works hard and takes it serious and wants to get the job done.
"We all have confidence in him. He's a great player. We're going to need him."
Ramirez acknowledged that responsibility Saturday with a smile after the game in front of his locker.
"I try to control what I can control right now," Ramirez said. "Just go to the cage and do my work to be ready for the game and go out there and compete every day. Sometimes, you just have to go out there and let it go.
"It's a long season. Pretty much everybody in here is a champion and everybody knows how to play the game and what we need to play better."
Ramirez has apparently found something else, his comfort zone in the lineup. After batting .257 in 45 games as the club's cleanup hitter behind David Ortiz, Ramirez batted third for the fifth time Saturday. His 3-for-5 effort raised his average to .400 (8-for-20) with two homers in the three hole.
Ramirez also acknowledged something else Saturday: He can lead offensively but he can't do it all by himself. Yes, he shot a 430-foot missile of a homer to the tarp in center and set the tone offensively. But it was Ramirez who paid props to starter and winner Joe Kelly and the bullpen that held on for win.
Red Sox manager John Farrell can certainly appreciate being part of history, even if it means standing in awe of the opponent.
On Friday night at Fenway, Oakland's Pat Venditte became the first major league pitcher since Greg Harris on Sept. 28, 1995 to pitch with both arms in a major league game.
Then, Harris was with the Montreal Expos and accomplished the feat in the ninth inning of a game against Cincinnati. That was a year after he left the Red Sox, where he pitched from 1989-94.
On Friday, the ambidextrous Venditte was not only pitching from both sides, he was doing so in his major league debut after toiling seven years in the minors waiting for his chance.
Venditte entered the game pitching left-handed. He retired Brock Holt on a grounder to first, featuring an 83 MPH fastball and a slider between 72-76 MPH. Hanley Ramirez followed by grounding a slider into left for a single but Venditte quickly rebounded by getting Mike Napoli to ground into a 4-6-3 double play.
"This game is all about helping the team and I just want to come here and be able to do that," Venditte said after the Red Sox' 4-2 win over the A's. "And if I can do that, that's all I care about, and whatever attention comes with that is fine. But we're here to win games. At the end of the day, it doesn't matter if I'm pitching with both hands or one, it's for one effort.
"Tonight, I felt comfortable out there. I was able to get ahead for the most part. I fell behind a couple guys but I felt good out there."
Venditte had a perfect eighth inning, getting Xander Bogaerts to ground to short and Mookie Betts to fly to right, before striking out switch-hitting Blake Swihart. A very impressive debut for the switch-pitcher. Farrell was jokingly asked why he can't teach his pitchers to throw with both arms as successfully.
"Our hands are full with one arm," Farrell conceded. "That was truly amazing tonight. To watch Venditte, it's a remarkable thing to see what one person's body is capable of doing. The coordination, even guys in the dugout were marveling. This is a very unique thing and a very cool thing."
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Nate Ebner Confirms: Gronk Is The Most Unstoppable Physical Force On EarthGronk is a dominant football player, but what if he played rugby? Teammate Nate Ebner has an answer.
Patriots' Nate Ebner Makes U.S. Olympic Rugby TeamThe Patriots special teamer gets to realize his dream of playing Olympic rugby for Team U.S.A.
Nate Ebner Training To Make U.S. Olympic Rugby Team, Taking Leave Of Absence From PatriotsThe story of Nate Ebner's football journey is a unique one, and it's now taking a new turn.
Michigan Man Tom Brady Forced To Wear Ohio State ShirtTom Brady is a pretty stylish fellow, but his attire on Thursday is not something he wants many people to see.
Socci: Pats Special Teamers Doing Their Best To Ensure Playing Field Is Not LevelPatriots special teamers have made life difficult for opposing offenses this season.
Stork, Connolly Return To Practice For Patriots; Revis, Jones Sit OutThe New England Patriots got the weekend off following their Thursday night win over the New York Jets, but were back to practice a day early to get ready for the Chicago Bears.
Socci's Notebook: Patriots Looking To Crack Buffalo Ground Defense, Run Past BillsThe Patriots get ready to take on the Buffalo Bills in a battle for first place in the AFC East.
Patriots' Browner, Easley Miss Thursday's Practice; Stork Limited With Head InjuryNew England Patriots corner Brandon Browner and defensive lineman Dominque Easley were both missing from Thursday's practice at Gillette Stadium.
Four Ups, Four Downs From Patriots' Victory Over RaidersThe game wasn't exactly full of bright spots for the Patriots, but we will nevertheless navigate the Four Ups and Four Downs from the win.
Socci: Ebner's Smarts, Instincts Put Him In All The Right Places On Special TeamsBob Socci takes a look at the job done by special teamer Nate Ebner, and his transition from rugby to football.
A Patriots Comeback Bid Finally Falls Short In Loss To DolphinsComing into Sunday's game against the Miami Dolphins, the New England Patriots had made a habit out of overcoming fourth-quarter deficits. If you play with fire enough times, you eventually get burned.
Socci's Notebook: Complementary Football Continues To Key Patriots SuccessComplementary football, played by a team as perennially complete as any in the NFL since 2001, enables the Patriots to vie Sunday for their 13th consecutive winning season.


text:
|Publication number
|Publication type
|Application number
|Publication date
|Oct 13, 1987
|Filing date
|Apr 29, 1985
|Priority date
|Oct 3, 1983
|Fee status
|Publication number
|Steven T. Nakos, Samuel Q. S. Lin
|Original Assignee
|Loctite Corporation
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (5), Referenced by (58), Classifications (20), Legal Events (4)
|External Links: USPTO, USPTO Assignment, Espacenet
This application is a continuation in part of U.S. Ser. No. 538,624, filed Oct. 3, 1983, now U.S. Pat. No. 4,528,081 incorporated herein by reference.
Because of their excellent thermal stability, low temperature flexibility and high dielectric strength, silicones have been used for coating, potting or encapsulating electrical devices such as integrated circuits. Potting or encapsulating materials typically used are elastomeric or gel-like materials providing shock, vibrational and thermal stress protection on fragile electronic parts. References relating generally to silicone gel encapsulants include U.S. Pat. Nos. 3,933,712; 4,072,635; 4,087,585; 4,271,425; 4,374,967; and D. Dickson, Jr., proceedings Electric/Electronic Intel. Conf. 12, 92 (1975). See also prior art description in U.S. Pat. No. 4,374,967.
The present commercially available potting silicones include one component compositions such as U.S. Pat. No. 4,271,425 which are cured by moisture, requiring several hours to days to complete the cure. Faster cures may be obtained from two component systems such as those in U.S. Pat. No. 4,087,585 if elevated temperatures are provided. The two component systems which require a platinum catalyst, however, are inhibited by organotin compounds, sulfur, amines, urethanes and unsaturated hydrocarbon plasticizers on the substrate surface. Curable silicone formulations have also been used for providing crosslinked environmentally resistant coatings on articles such as electronic circuit boards and the like which include raised parts such as resistors, transistors, micro chips, etc.
It is known that certain silicones containing methacrylate or acrylate functional groups may be cured by ultraviolet light. U.S. Pat. Nos. 4,201,808 and 4,348,454 and U.K. Patent application No. GB2039287A all describe U.V. curing compositions of silicones containing methacrylates or acrylates for paper release coatings. Such materials, however, have not been used on substrates, such as electronic circuit boards, which include light inaccessible or "shadow" areas because the coating compositions cannot be cured in these areas by ultraviolet light.
The present invention is directed to a novel method of providing a cured crosslink coating or an encapsulant on a substrate having shadow areas not readily accessible to light. The method of the invention involves the use of silicone polymer compositions capable of both U.V. and moisture curing. In the inventive method such compositions are applied to a substrate having shadow areas; the light accessible areas are irradiated to give a cured overcoat sufficient to allow storage, packaging or further processing of the article; and then the shadow areas are gradually cured by a moisture cure mechanism to give a fully crosslinked environmentally resistant coating over the entire substrate.
The inventive relies on a dual curing mechanism. The coating or potting formulation is applied to a substrate having shadow areas in such a manner as to fully coat the exposed surfaces, including the under sides of raised parts such as resistors transistors or micro chips. U.V. irradiation of the coating cures the coating on the light inaccessible areas. Since light inaccessible areas are generally protected from mechanical disruption, the coated parts can be immediately processed in subsequent assembly operations. Thus more efficient automated processes for manufacturing electronic components are facilitated. The coating or encapsulant in light inaccessible areas then gradually cures by exposure to atmosphere of moisture over a period of one or more days. Some further moisture crosslinking of the light cured coating is also likely during this period. The result is a tough environmentally resistant cured coating over the entire exposed surface of the part, without assembly delays inherent in processes utilizing purely moisture cured silicone materials.
Compositions utilized in the inventive method include, as an essential ingredient a linear or branched organosiloxane which includes a plurality of acrylic functional groups bound to silicon atoms thereof and a plurality of siloxane units of the formula: ##STR3## where R1 is a hydrolyzable organic group, R2 is R1 or, if R1 is dialkyl amino, R2 is R1 or hydrocarbyl. Examples of suitable hydrolyzable organic groups are: alkoxy; aryloxy; oxime (i.e. --ON═C(R3)2); acid liberating (i.e. --OOCR3); N,N-dialkylamino; N,N-dialkylaminoxy; N-alkylamido; ##STR4## where R3 is H or hydrocarbyl. Most preferably R1 is methoxy, oxime such as acetoximino (otherwise known as dimethylketoximino) or acetoxy.
Thus, the polyorganosiloxane is a resin which contains both acrylic and hydrolyzable functionality. It is to be understood that the open valency on the silicone atom in the above formula may be linked to other siloxane repeat units, to one of the acrylic functional groups or to an R2 group.
Suitably the resins are polydihydrocarbylsiloxanes, such as polydimethyl, polydiphenyl, or polymethylphenyl siloxanes, terminated with groups of the formula: ##STR5## where R4 is H or methyl and R5 is a divalent organic group having a carbon atom bound to the silicon atoms, preferably an alkylene, or alkenylene, group. However, the acrylic and hydrolyzable groups may also be bound to different silicon atoms along the polymer backbone. The polyorganosiloxane polymer may have a molecular weight as low as about 1,000 but preferably the molecular weight will be at least 10,000.
As discussed above, U.V. curing of some organosiloxane compounds of this type in the lower, less preferred molecular weight range, has previously been reported for paper coatings and the like. However, it has heretofore not been contemplated that such materials, suitably formulated, would be useful for curing on substrates having shadow areas inaccessible to direct U.V. light. In formulating useful dual curing compositions of the invention it is generally advisable to include in the formulation a moisture curing catalyst, such as an orthotitanate catalyst, in the formulation. Where the hydrolyzable groups are methoxy or other hydrocarbonoxy groups, such catalysts are generally necessary to achieve shadow cure. On the other hand, where the hydrolyzable groups are amino, such catalysts are typically not necessary.
The dual curing compositions utilized in the inventive method also include a photosensitizer. Any known radical photosensitizer can be used as well as mixtures thereof without departing from the invention hereof. Simple photoinitiators include benzoin and substituted benzoin compounds, benzophenone, Michler's ketone, dialkoxybenzophenones, dialkoxyacetophenones, etc. Photosensitizers made compatible with silicones by binding photoinitiating groups to organosiloxane polymer backbones, such as the compounds disclosed in U.S. Pat. Nos. 4,477,326, 4,507,187 and in copending application Nos. 528,287 of Aug. 31, 1983, now U.S. Pat. No. 4,587,276, and 655,398 of Sept. 27, 1984, now U.S. Pat. No. 4,534,838 incorporated herein by reference, may also be used.
The amount of photosensitizer used in the compositions will typically be in the range of between about 0.1% and 5% of the composition. Depending on the characteristics of the particular photosensitizer, however, amounts outside of this range may be employed without departing from the invention so long as they perform the function of rapidly and efficiently intitiating polymerization of the acrylic groups. In particular, higher percentages may be required if silicone bound photosensitizers are used with high equivalent weight per photoinitiating group.
It should also be understood that while the photosensitizer is listed as a separate ingredient, the formulations used in the inventive method are intended to include formulations in which photoinitiating groups are included on the backbone of the same polyorganosiloxane polymer which includes the acrylic groups and hydrolyzable groups discussed above.
The inventive compositions may also contain other additives so long as they do not interfere with the U.V. and moisture curing mechanisms. These include adhesion promoters such as 2,3-epoxypropyltrimethoxsilane, methacryloxypropyltrimethoxysilane, triallyl-S-triazine-2,4,6(1H,3H,5H,)-trione and others known to those skilled in the art; fillers such as silica, microballoon, glass, etc. Further examples of fillers usable to modify the inventive compositions may be found in U.S. Pat. No. 4,072,635 at column 4, line 40--column 5, column line 7.
In electronic coating or potting applications, ion trapping compounds such as crown ethers and cryptates may be useful for reducing ionic conductivity. Examples are 18-crown-6, 12-crown-4 and 15-crown-4 and 15-crown-5. See also U.S. Pat. No. 4,271,425 where the use of crown ethers in conventional RTV silicone encapsulants are described.
Reactive silicones usable in the inventive method are readily prepared from silanol terminated silicones: ##STR6## of appropriate molecular weight, where R6 are the same or different organo groups, preferably selected from methyl and phenyl groups. Preferably the silanol terminated silicone is a polydimethylsiloxane having a viscosity of at least about 600 cps. Silanol terminated dimethylsiloxanes having a viscosities up to at least about 50,000 cps may be useful. Most preferably between about 750 and 25,000 cps.
The silanol terminated silicones are condensed with excess silane of the formula: ##STR7## where R1, R2, R4 and R5 are previously defined. While a variety of condensation procedures may be used, it is much prefered that the reaction be run at 60�-100� C. in the presence of a condensation catalyst such as an orthotitanate or tertiary amine and that substantially all the alcohol produced by the reaction by removed by vacuum. The products of this process give superior storage stable dual curing formulations compared to silicones produced by other prior art processes such as disclosed in U.S. Pat. No. 4,290,869 or No. UK1323869.
Generally, silanes satisfying formula III may be obtained commercially or may be synthesized by techniques well known in the art. In the case where R1 is --S--C3 H6 --Si(OCH3)3, the silane may be obtained from the reaction of methacryloxypropyltrichlorosilane and mercaptopropyltrimethoxysilane in the presence of a base such as pyridine.
The invention may be further understood with reference to the following non-limiting examples.
In a round-bottomed flask 50.0 g of a hydroxyl terminated polydimethylsiloxane of 680 cst viscosity (0.3% hydroxyl by weight), 2.62 g methacryloxypropyltrimethoxysilane and 0.21 g tetraisopropylorthotitanate were reacted on a rotary evaporator at 10 mm Hg pressure and 80� C. for two hours. The viscosity of the mixture increased for the first hour and then decreased during the second hour. A full vacuum (approximately 0.5 mm Hg) was applied for an additional 4 hours at 80� C. The flask was removed from the evaporator and flushed with nitrogen. The reactive silicone product was a yellow liquid.
The product was then used to formulate soft gel potting compounds by mixing with 100 cst or 1,000 cst trimethylsilyl terminated silicone oils. The mixtures ranged from 0-90% silicone oil. To each of these mixtures was added 2% by weight diethoxyacetophenone as photoinitiator. Samples of these compositions, about 1/4" thick, were then cured by 1-2 minute exposure to UV irradiation of about 70,000 microwatts/cm2 or by 24 hour moisture cure at ambient temperature and humdity. Above about 70% oil content, curing was very difficult and nonflowable products were not achieved by the moisture cure mechanism. Samples containing between 0 and 70% oil ranged, respectively, from a soft rubbery material (Shore A 10-15) to a very soft sticky gel (Shore A unmeasurable) which showed some tendency to creep but would not flow.
The synthetic procedure of Example 1 was repeated using 50.0 g of a 3500 cst hydroxyl terminated polydimethylsiloxane (28,000 MW), 1.05 g methacryloxypropyl trimethoxysilane and 0.20 g tetraisopropylorthotitanate. The product was a viscous liquid. A sample of the product was mixed with 2% diethoxyacetophenone and cured with UV irradiation of 70,000 microwatts/cm2 to a stretchable soft rubber. Another sample of the same composition cured to a slightly softer rubber after 21/2 days exposure to ambient temperature and humidity.
A methacryloxypropyldimethoxysilyl terminated polydimethylsiloxane was prepared from 101.7 g of a 20,000 cst silanol terminated dimethylsiloxane, 2.6 g methacryloxypropyltrimethoxysilane and 0.3 g tetraisopropylorthotitanate in a manner similar to that of Examples 1 and 2 except that 100.9 g of a 100 cst trimethylsilyl terminated silicone oil was added to the mixture prior to heating. The resulting product had a viscosity of 21,200 cps.
3.05 g of the 21,200 cps product were then mixed with 0.6 g of the same 100 cst silicone oil and 0.07 g dimethoxyacetophenone. This composition, containing 58% oil, cured to a soft gel 1/16" deep upon exposure to UV of about 70,000 microwatts/cm2 for 60 seconds.
193.8 g of the 21,200 cps product were mixed with 45 g of the 100 cst silicone oil and 5 g diethoxyacetophenone. The mixture was cast into 1/8" thick open top molds and cured by UV light of the same intensity for six intervals of 20 seconds each, with a cooling period between each interval. The samples were then allowed to moisture cure overnight after which they were removed from the molds in 4"�4" square pieces, turned over, and the bottom surfaces subjected to three 20 second intervals of UV exposure to reduce tackiness. 4"�4" pieces were then subjected to electrical testing, the results of which are given in Table I below:
TABLE I______________________________________Test Performed Individual Values Average Value______________________________________ASTM D-149, Di 340 230 210 250 260 260electric Strength,volts/milASTM D-256, Volume 3.8 3.9 4.8 3.5 3.5 3.9Resistivity,1014 ohm-cmASTM D-150, Di 2.87 4.28 3.58electric Constant,102 HzASTM D-150, Di 2.59 2.83 2.71electric Constant,105 HzASTM D-150, Dis 0.0018 0.0017 0.0018sipation Factor,102 HzASTM D-150, Dis- 0.0012 0.0012 0.0012sipation Factor,105 Hz______________________________________
Rhone-Poulenc silanol-terminated silicone 48V3500 (50.0 g, 3.53�10-3 eq silanol) was mixed with 1.46 g (4.41�10-3 mole) of methacryloxypropyltriacetoxysilane and placed in a rotary evaporator, turning and heating for 3 hours at 80� C. and 0.2 mm. At this point, the vacuum was broken with dry nitrogen and five grams removed and mixed with 0.1 g diethoxyacetophenone (Sample A). Another five grams was removed and mixed with 0.03 g dibutyltindilaurate and allowed to stand in air (Sample B). Curing was as follows:
A. Cured by 70 mw/cm2 UV radiation, 1 min/side, 3/16" thick.
B. Left to stand in air overnight.
Both cured to approximately the same consistency, namely, a fully cured rubber with low to moderate elongation.
Rhone-Poulenc silanol-terminated silicone 48V3500 (25.0 g, 1.765�10-3 eq silanol) was mixed with 0.82 g (2.21�10-3 mole) of methacryloxypropyltris(acetoximo)silane and placed in a rotary evaporator, turning and heating for 3 hours at 80� C. and 0.2 mm. At this point, the vacuum was broken with dry nitrogen. Dibutyltin dilaurate (0.02 g) and 0.4 g diethoxyacetophenone were added to the remaining material and were dissolved into the resin under N2. Samples of this formulation (1/8" deep in a beaker) were cured by exposure to ambient moisture overnight and by irradiation with UV light, 70 mw/cm2, for 1 min. per side. Both samples gave fully cured rubbers with moderate to long elongation.
The above formulation is useful for glass bonding even without added adhesion promotor. Thus, when pressed between two glass microscope slides, overlapping 1" at rt angles, and irradiated with 70 mw/cm2 UV for 1 min., the slides could not be pulled apart. When the bonded slides were flexed perpendicularly to give a test of peel strength, the slides broke leaving the bond intact. Good bonding of glass slides was also obtained by overnight exposure to ambient temperature.
Coatings made by applying two drops of the above formulation on to microscope slides and curing by either UV or overnight ambient were found to be resistant to finger peel.
A 28,000 mw alpha, omega-dihydroxy-polydimethylsiloxane (viscosity=3500 cps), was heated for several hours at 70�-80� C. with a slight excess of methacryloxypropyltrimethoxysilane in the presence of triethylamine to give a methacryloxypropyldimethoxysilyl terminated polymer. Methanol and triethylamine were then vacuum stripped at 80� C. to give a product designated 28K MA-dMeO.
A circuit board containing raised resistors, diodes and transistors was dipped into a formulation as follows:
______________________________________28K-MA-dMeO 100 partsHDK-2000* silica 25 partsmethyltrimethoxysilane 4 partstetrabutoxyorthotitanate 1 partdiethoxyacetophenone 2 partstrichloroethane 198 parts______________________________________ *available from WackerChemie G.m.b.H.
The trichloroethane solvent was allowed to evaporate and the board dipped a second time. After evaporation of solvent, a thick coating of uncured silicone remained on the parts, including the undersides of the components.
The board was then irradiated in UV light of 70 mw/cm2 for 1 min/side. The coating had cured to a tack free solid on the tops of the components and on the parts of the board not shadowed by the components. Therefore, the board could be easily handled. However, the coatings were uncured on the undersides of the components and the areas shadowed thereby. In these shadow areas, the uncured coating stuck to a probe needle. The sides of the board and some of the larger components were cured but still slightly tacky.
Within a few hours the sides of the board and the components were tack free. Overnight the coating cured to a tough rubbery coating in the shadow areas as well as over the rest of the board.
|Cited Patent
|Filing date
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|Radiation curable silicone release compositions
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|Jun 2, 1981
|Western Electric Company, Inc.
|Encapsulated electronic devices and encapsulating compositions having crown ethers
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|General Electric Company
|Ultraviolet light curable acrylic functional silicone compositions
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|Dual curing silicone, method of preparing same and dielectric soft-gel compositions thereof
|Jan 3, 1985
|Apr 29, 1986
|General Electric Company
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|Oct 21, 1987
|Feb 7, 1989
|International Business Machines Corporation
|Suspension and use thereof
|Nov 6, 1987
|Apr 25, 1989
|Dow Corning Corporation
|UV curable conformal coating with moisture shadow cure
|Nov 14, 1988
|Mar 13, 1990
|Loctite (Ireland) Ltd.
|Encapsulating compositions
|May 25, 1989
|Aug 28, 1990
|Loctite Corporation
|Crosslinking of (meth) acryloxyalkenylene functional siloxane prepolymers
|Dec 8, 1988
|Sep 11, 1990
|Dow Corning Corporation
|UV curable conformal coating with moisture shadow cure
|Feb 24, 1989
|Jul 23, 1991
|Loctite Corporation
|Curable norbornenyl functional silicone formulations
|Nov 27, 1989
|Nov 5, 1991
|Loctite Corporation
|MTQ/polysiloxane hybrid resins, method of making the same, and coating/potting compositions containing the same
|May 24, 1991
|Aug 18, 1992
|Global Thermal Conditioning, Inc.
|Shadow boundary process for the continuous radiant cure of composites
|Jan 31, 1991
|Dec 15, 1992
|Loctite Corporation
|Curable norbornenyl functional silicone formulations
|Nov 19, 1990
|Jan 12, 1993
|Loctite Corporation
|Photocurable silicone composition, and method of making the same
|Nov 19, 1990
|Jan 26, 1993
|Loctite Corporation
|Photocurable silicone gel composition, and method of making the same
|Nov 19, 1990
|May 18, 1993
|Loctite Corporation
|Polymodal-cure silicone composition, and method of making the same
|Feb 24, 1989
|Nov 30, 1993
|Loctite Corporation
|Selective monohydrosilation of vinyl and ethynyl functional norbornenes and curable products produced thereby
|Sep 24, 1991
|Feb 1, 1994
|Dynamic Technologies, Inc.
|Enhanced structural core material
|Feb 19, 1993
|Apr 5, 1994
|Loctite Corporation
|Process for preparing alkoxy-terminated organosiloxane fluids using organo-lithium reagents
|Jan 25, 1993
|Sep 20, 1994
|Loctite Corporation
|Photocurable silicone composition, and method of making same
|Dec 14, 1993
|Feb 21, 1995
|Shin-Etsu Chemical Co., Ltd.
|Curable organopolysiloxane compositions
|Jun 19, 1992
|May 30, 1995
|Wacker-Chemie Gmbh
|Curable organo(poly)siloxane compositions
|Aug 1, 1994
|May 14, 1996
|Loctite Corporation
|UV-moisture dual cure silicone conformal coating compositions with improved surface tack
|Jun 5, 1995
|Feb 25, 1997
|Loctite Corporation
|Anaerobically curable silicones
|Jun 7, 1995
|Aug 12, 1997
|Loctite Corporation
|Low viscosity silicone sealant
|Jun 7, 1995
|Sep 2, 1997
|Loctite Corporation
|Organosiloxane fluids prepared using organo-lithium reagents
|Feb 28, 1997
|Dec 30, 1997
|Nippon Paint Co. Ltd.
|Photosensitive composition for volume hologram recording
|Dec 4, 1996
|Jul 7, 1998
|International Paper Company
|Hybrid sol-gel barrier coatings
|Dec 3, 1998
|Nov 9, 1999
|University Of Massachusetts
|Silyl-functional initiator for living cationic polymerization
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|Aug 28, 2001
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|Flame-retardant UV curable silicone compositions
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|Nov 27, 2001
|Loctite Corporation
|Flame-retardant UV and UV/moisture curable silicone compositions
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|Sep 17, 2002
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|Sep 30, 2003
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|Curable silicone compositions having enhanced cure-through-volume
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|Dec 11, 2007
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|UV and UV/moisture dual curable compositions with improved cure through volume
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|May 6, 2008
|Henkel Corporation
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|Henkel Corporation
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|Polysiloxanes grafted with radically curable and/or moisture curable groups
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|May 1, 2012
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|Dec 31, 2013
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|Dual curing polymers and methods for their preparation and use
|Apr 23, 2001
|Sep 4, 2003
|Cross Robert P.
|Conducive, silicone-based compositions with improved initial adhesion reduced microvoiding
|May 31, 2001
|Sep 18, 2003
|O'dwyer Liam P
|Spreadable adhesive compositions and applicators for use therewith
|May 2, 2001
|Nov 13, 2003
|Levandoski Michael P
|Curable silicone compositions having enhanced cure-through-volume
|Sep 30, 2003
|Jun 17, 2004
|Loctite Corporation
|Dual curing silicone compositions
|Feb 22, 2002
|Jun 17, 2004
|Lim Thomas F.
|Mixed alkoxysilyl functional polymers
|Oct 15, 2003
|Dec 1, 2005
|Hsien-Kun Chu
|Fast moisture curing and uv-moisture dual curing compositions
|Dec 18, 2007
|Apr 24, 2008
|Henkel Corporation
|UV and UV/Moisture Dual Curable Compositions With Improved Cure Through Volume
|Nov 26, 2008
|Jun 4, 2009
|Henkel Corporation
|Polysiloxanes grafted with radically curable and/or moisture curable groups
|Nov 18, 2005
|Jul 2, 2009
|Henkel Corporation
|Curable Silicone Compositions Incorporating A Fluorescent Detection System
|Dec 10, 2007
|Mar 18, 2010
|Khristopher Edward Alvarez
|Dual Curing Polymers and Methods for Their Preparation and Use
|Nov 7, 2007
|Apr 15, 2010
|Dow Corning Corporation
|Dual Curing Polymers and Methods for Their Preparation and Use
|Mar 24, 2006
|Oct 7, 2010
|Henkel Corporation
|Compositions and processes for Assembling Appliances
|Jun 7, 2013
|Dec 26, 2013
|Nitto Denko Corporation
|Silicone resin composition, semi-cured material sheet, producing method of silicone cured material, light emitting diode device, and producing method thereof
|Mar 8, 2010
|Sep 8, 2011
|Delo Industrie Klebstoffe Gmbh & Co. Kgaa
|Dual h�rtende Masse und deren Verwendung
|May 15, 2013
|Dec 11, 2013
|Elast Kunststoffverarbeitungs-GmbH & Co. KEG
|Method and apparatus for the processing of liquid siloxane masses in injection molding machines and die-casting tools
|Aug 20, 1998
|Feb 25, 1999
|Loctite Corporation
|Dual curing silicone compositions
|Nov 18, 2005
|Jun 8, 2006
|Henkel Corporation
|Curable silicone compositions incorporating a fluorescent detection system
|U.S. Classification
|427/515, 427/517, 522/40, 427/510, 522/39, 522/77, 522/99, 528/34, 522/46, 522/44, 526/279
|International Classification
|Cooperative Classification
|European Classification
|Apr 29, 1985
Owner name: LOCTITE CORPORATION, 705 NORTH MOUNTAIN RAOD, NEWI
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNORS:NAKOS, STEVEN T.;HALLDEN, EVA;REEL/FRAME:004402/0960;SIGNING DATES FROM 19850418 TO 19850423
|Apr 4, 1991
|Fee payment
Year of fee payment: 4
|Apr 4, 1995
|Fee payment
Year of fee payment: 8
|Apr 12, 1999
|Fee payment
Year of fee payment: 12


text:
On December 3, U.S. Rep. Louie Gohmert announced filing "The Kari's Law Act of 2015" in the U.S. House of Representatives. The bill would ensure anyone who dials 9-1-1 would reach emergency services directly.
The McLennan County 9-1-1 District is launching a public awareness campaign to remind the public that 9-1-1 should be used ONLY in emergencies. The District will run ads at the Jewel Stadium 16 and Galaxy 16 movie theaters May 27 through July 7. We expect the ads to have a positive impact and hopefully reduce the number of non-emergency calls to 9-1-1.


text:
Yesterday I picked up a Dell subwoofer at an antique store for $10. It's not an antique, but the man that owns the shop buys entire estates, and he just got this unloaded from his trailer on Monday.
Did I get a good deal? I plugged it in and it works -- for bass, of course. It looks as though the ports on the back for the surround speakers (front and back) are RCA type.
Does anyone have an opinion if I should go online to try and find the rest of the speakers for this to make an entire sound system? Should I just return it and get my $10 back?
It's as big as a computer tower, and weighs a good 20 pounds. No scratches.
The man at the antique shop said this is all there was -- no other speakers.


text:
The Scholars Program is a distinction awarded to junior golfers of The First Tee who excel in academics, leadership, character development, and chapter and community involvement.
Congratulations to the 79 junior golfers designated to The First Tee Scholars - Class of 2015-2016.
Since 2003, more than $1 million in college scholarships have been awarded to teen participants of The First Tee.
Application Process for Junior Golfers
Applications are accepted once per year from seniors in high school who meet the minimum requirements.They are scored by an independent committee with representation from the following areas: Post-secondary educational consultant, high school guidance counselor, philanthropists, USGA executive committee member, educator, chapter board member, and chapter executive director.
Please contact your chapter for application information.
Opportunities for Scholars
In order to be eligible for The First Tee Named Scholarships, the participant must first apply for The First Tee Scholars Program. The deadline for The First Tee Scholars Program has passed for 2016.
Named Scholarships: Accepted Scholars are eligible for scholarship opportunities. Named Scholarships are funds received either in honor or memory of someone, or have been donated by individuals or corporations. Most of these scholarships are worth $2,500 per year and are renewable for four years ($10,000 total) assuming the student continues to meet the schools criteria for merit scholarships. The funds are paid directly to the institution of the recipients choice. Learn More »
Home Office Contact
Lana Hult
Manager, Participant Opportunities & Logistics
(904) 940-4338
[email protected]


text:
Going in December for our third stay this year - in fact our 3rd time since Aug!
Tried to review in Oct-but, it was "too soon" and trip advisor wouldn't let me :(
This place is the West Coast's best kept secret! If you want luxury, elevators, long halls to walk and then a gigantic parking lot to walk across so you can go to the beach - DON'T STAY HERE. If you want only a tiny fridge, $5 bottle of water in your room, and a long walk to a vending machine and ice - DON'T STAY HERE. BUT, if you want all the comforts of home, the access to the beach practically outside your door, quiet relaxation - STAY HERE!!!
- Official Description (provided by the hotel):
- Our guests relax and take pleasure in sunny days, breezy nights and the ambiance of Old Florida charm directly on the Gulf of Mexico. The Beach Side Palms is comprised of seven charming, newly redecorated beach front units, each named after a different kind of palm tree. ... more less
- Also Known As:
- Beach Side Palms Treasure Island, Florida


text: Michael Phelps Parties with Hotties Featured 08/14/2008 Was this Michael Phelps extensive training regiment for Beijing? Share Tweet Stumble Email Pin It List View Player View Grid View 1. 2. 3. 4. 5. 6. 7. 8. 1. 2. 3. 4. 5. 6. 7. 8. Share This Image REPLAY GALLERY Share on Facebook Replay Michael Phelps Parties with Hotties NEXT GALLERY Cute Kitten RELATED MEDIA Hotties in Halloween Costumes Summer Hotties Emo Hotties Michael Jordan SI Covers Michael Jackson Auction Items. This Cave Is An Awesome Party Spot 9 Young Hotties With Old Millionaires You Got Wasted! Awesome GIFs Made Better With Explosions Michael Jackson's Neverland Ranch Halloween Party Drinks How Other Countries Throw U.S. Parties Sorry For Partying! Party Girls Caught In The Walk Of Shame The People Who Ruin Every Holiday Party 12 Wild Parties That Spun Out Of Control 14 People Confess Weird Stuff They Witnessed At Parties 15 Of The Craziest Things Experienced At A College Party 9 Interesting Facts About Michael Jackson People That Are Sorry For Partying 8/8 1/8 Share Tweet Stumble Email Pin It Tags: olympics michael-phelps swimming NEXT GALLERY Cute Kitten 1,250 Comments Login to Comment