text:
Publication number | US3852408 A |
Publication type | Grant |
Publication date | Dec 3, 1974 |
Filing date | Sep 21, 1972 |
Priority date | Sep 21, 1972 |
Publication number | US 3852408 A, US 3852408A, US-A-3852408, US3852408 A, US3852408A |
Inventors | Ewan T, Holland O, Hurse J, Martin W |
Original Assignee | Lone Star Steel Co |
Export Citation | BiBTeX, EndNote, RefMan |
Patent Citations (4), Referenced by (43), Classifications (10) | |
External Links: USPTO, USPTO Assignment, Espacenet | |
United States Patent 1191 Ewan et al.
[ Dec. 3, 1974 1 PROCESS FOR THE REMOVAL OF SULFUR DIOXIDE FROM CARRIER GASES [75] Inventors: Thomas K. Ewan, Daingerfield;
Orvis L. Holland, Linden; Willis Leon Martin, Longview; James E. Hurse, Mt. Pleasant, all of Tex.
[73] Assignee: Lone Star Steel Company, Dallas,
[22] Filed: Sept. 21, 1972 [21] App]. No.: 291,007
Primary Examiner-Oscar R. Vertiz Assistant Examiner-Gregory A. Heller Attorney, Agent, or Firm-Donald E. Degling; James D. Bock [57] ABSTRACT A process is disclosed for the removal of sulfur dioxide from carrier gases formed in industrial processes such as as smelting, refining and power generating processes wherein the carrier gas is driven through an elongate mixing tube by means of a hot-water ejector drive in which finely atomized droplets of water in the form of a jet spray are intimately and turbulently mixed with the carrier gas in the mixing tube downstream of the hot-water ejector. An alkaline reagent is injected as a series of intense jets into the central portion of the jet spray emerging from the hot-water ejector and becomes intimately and. turbulently mixed with the mixture of atomized droplets of water, steam and carrier gas which contains sulfur dioxide. The flow of the turbulent mixture through the mixing tube is regulated to provide retention time sufficient for the sulfur dioxide in the carrier gas to react with the alkaline reagent to form aqueous droplets of sulfur reaction products and for the droplets to grow to a size sufficient to permit removal by centrifugal means. In an alternative form of the invention, the carrier gases from which the sulfur dioxide has been substantially completely removed is further treated by driving the gases through a secondary mixing tube by means of a steam ejector and passing the turbulent mixture of gas. steam and water droplets through a condenser in which the condensible vapors are separated from the carrier gas. In the alternative form of the invention, alkaline reagents can be injected into the turbulent mixture contained in the secondary mixing tube to react with traces of sulfur dioxide or such odors and acidic gases as may then be present in the carrier gas.
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qv Qbk E QU/l/ALE/VT RAW/0 PATENTEL DEB 31974 saw many PROCESS FOR THE REMOVAL OF SULFUR DIOXIDE FROM CARRIER GASES This invention relates to a method and apparatus for removing sulfur dioxide and condensible gases from carrier gases in industrial and chemical processes. The apparatus will also inherently remove particulates which may be contained in the carrier gases and is thus particularly adapted to cleaning the off-gases resulting from smelting and refining process and off-gases emitted by power generating plants.
Within the past few years, increasing attention has been directed to the treatment of the off-gases produced in industrial processes. Such off-gases may contain a large variety of contaminants including particulates of widely varying size and chemical composition; gases such as oxides of carbon, sulfur and nitrogen, hydrocarbons, aerosols, vapors, etc. While some of these contaminants, such as carbon dioxide, are relatively harmless, others, such as sulfur dioxide, are regarded as highly detrimental. In recognition of the adverse effect such substances have on the ecology, various governmental authorities have begun to set standards for the maximum emission levels which will be permitted under particular circumstances. In general, the standards have been set so as to take advantage of the latest techniques available for the removal of the contaminant under consideration, and it is reasonable to expect that these standards will be tightened as quickly as possible until acceptable levels for each contaminant are attained.
Sulfur dioxide S is one of the principal contaminants in many off-gases and its control has been studied intensively in connection with smelting and refining processes in the steel and copper industries and in the design of power generating plants. Each of these processes involves the combustion of fuels or the oxidation and reduction of ores containing sulfur which, at some point in the process, results in the formation of S0 In some cases, it is possible to substitute fuels such as natural gas having a low sulfur content for oil or coal to control the evoultion of S0 but such a substitution is often impractical for economic reasons even where a substitute fuel is available. It has been reported that the United States supply of low-sulfur fuel is quite limited. Also, a number of treatment processes have been suggested to remove sulfur prior to refining. Where, however, as in some copper smelting processes, sulfide ores are used, it is difficult to limit the amount of sulfur entering the process which may appear at some stage as As it is generally recognized that the presence of S0 in the off-gases of many industrial processes in quantities above acceptable emission limits cannot be avoided in practice, efforts have been directed toward its removal from the off-gases by chemical scrubbing. Among he processes which have been suggested are wet scrubbing with lime or limestone; dry injection of lime or limestone; ammonia scrubbing; scrubbing with magnesium oxide or zinc oxide; the use of molten carbonates, potassium formate or citrate; wet scrubbing with sodium hydroxide; and catalytic processes. Some of these processes result in the formation of sulfuric or nitric acid while in others elemental sulfur is produced which, theoretically, can be sold as by products to reduce the operating costs of the process. However, in many instances the quantities of acid produced by the removal process exceed the local market requirements and cause difficult storage and transportation problems. Also, the cost of producing elemental sulfur by a removal process frequently exceeds the cost of sulfur obtained directly from sulfur deposits. Thus, the production of by-products may not necessarily be advantageous. In general, the processes involving the use of lime or limestone do not result in a saleable by-product. In late 1971, the M. W. Kellogg Company submitted a report to the Environmental Protection Agency entitled Evaluation of SO -ControI Processes (PB 204711), concerning the status of S0 control processes for large power plants and concluded that none of the 12 processes evaluated could be ranked as commercially available at the time the report was written.
While the chemical reactions necessary to the removal of S0 are well known and most of the common reagents have been utilized in various of the processes suggested by the prior art, a principal difficulty experienced by the prior art workers was to provide a proper environment in which the S0 gas can react quickly and completely with an appropriate reagent. Applicants believed that the key to a simple and efiicient process would be to provide an environment in which a reagent could be atomized and then intimately mixed with the S0 gas so that the rate of the chemical reactions could be maximized. Applicants also recognized that it would be desirable, if possible, to combine the removal of S0 with the removal of particulates in the same apparatus to minimize the cost and complexity of the process and to provide a process that would be applicable to a wide range of contaminated gases.
It is, therefore, a principal object of the present in vention to provide a simple and economicv method and apparatus for removing S0 from carrier gases which occur in industrial and chemical processes and for simultaneously removing particulates that may also be contained in the carrier gases.
Another object of the present invention is to provide a process in which relatively inexpensive reagents are employed to remove S0 from carrier gases.
A further object of the invention is to provide a process for removing S0 from carrier gases in which the pH of the effluent liquids from the process is controlled to minimize corrosion problems.
Another object of the invention is to provide a process for removal of S0 from contaminated gases utilizing a minimum quantity of chemical reagents and water so as to minimize the effluent liquid treating problem.
Yet another object of the invention is to provide a process capable of contacting and removing, in addition to particulates and sulfur dioxide, odors and any condensible vapors, such as steam, which may be contained in the contaminated gases, or formed by the particulate and sulfur dioxide removal process.
Finally, it is an object of the present invention to provide an economical process for removing S0 particulates, odors and condensible vapors over a wide range of operating conditions but which can be controlled to give a predicted performance with a high degree of confidence.
In general, the process of the present invention comprises driving the contaminated carrier gas containing particulates and sulfur dioxide and. produced, for example, in a smelting or refining process by a highpressure hot-water ejector, injecting an alkaline chemical reagent or a combination of chemical reagents into the central portions of the turbulent mixture of steam and highly atomized water emitted from the hot-water ejector; intimately mixing the steam, atomized hot water and carrier gas under conditions of turbulent mixing and entraining the particulates and S molecules contained in the carrier gas with droplets of hot water and chemical reagents; regulating the flow of the turbulent mixture of steam, atomized droplets and carrier gas to provide retention time in the mixing tube sufficient for reaction of the chemical reagents with the S0 molecules to form aqueous droplets of sulfur-containing reaction products and particulate and for promoting the growth of the particulate-containing droplets and the droplets containing the S0 reaction products, separating the droplets from the cleaned carrier gas and, if desired, condensing any remaining steam and other condensible vapors. An auxiliary portion of the process includes the separation of the sulfur-containing products of reaction and particulates from the effluent of the process and in some cases, the regeneration of all or a portion of the chemical reagent.
The equipment used to perform the process of the present invention includes a hot-water ejector drive and chemical reagent supply system, a waste heat boiler or other equipment to provide water at high pressure and high temperature, an atomizer or conditioning chamber fitted with a chemical reagent supply system, a mixing tube associated with and proportioned to the hot-water ejector, a centrifugal separator, a steam ejector fitted with chemical reagent supply system and surface condenser for condensing steam and condensible vapors,'if desired, and a water treatment system where required, to control the quality of the effluent liquid and to regenerate certain of the chemical reagents used in the process.
The present invention, as well as further objects and advantages thereof will be apparent from the following description and accompanying drawings in which:
FIG. 1 is a general arrangement of the equipment used to practice the process of the present invention, including a waste heat boiler, atomizer chamber, hotwater ejector drive and chemical injector, mixing tube and twin cyclone separator;
FIG. 2 is a schematic arrangement of the atomizer and chemical injector, hot-water drive and chemical injector, mixing tube, twin cyclone separator, steam ejector with a chemical supply and condenser employed to perform alternative. forms of the process of the present invention;
FIG. 3 is a schematic drawing of the atomizer, driver, chemical injector, separator equipment and the auxiliary equipment utilized to test the process of the present invention;
FIG. 4 is a schematic representation of a nozzle, chemical injector and related mixing tube showing the principles of mixing which are employed;
FIG. 4A is a fragmentary cross-sectional view of the exit end of the nozzle showing the preferred chemical injector;
FIG. 4B is an end view of the nozzle and chemical injector shown in FIG. 4A;
FIG. 5 is a graph showing the relative removal efficiencies obtained when sodium hydroxide was injected at various points in the apparatus;
FIG. 6 is a graph showing the relative removal efficiencies obtained when sodium carbonate was injected at various points in the apparatus;
FIG. 7 is a graph showing the relative removal efficiencies obtained when calcium hydroxide was injected at various points in the apparatus;
FiG. 8 is a graph showing the improvement in the removal of sulfur dioxide according to the process of the present invention as a function of the effective increase in lime solubility;
FIG. 9 is a graph showing a comparison of the relative removal efficiencies of the various chemical reagents injected directly into the nozzle driving water and into the interior of the jet spray at the end of the nozzle;
FIG. 10 is a graph showing the relative removal efficiencies of various chemical reagents injected into the interior of the jet spray at the end of the nozzle in the presence of carbon dioxide.
The physical conditions necessary for the collection of particulates in various types of scrubbers have been well established. Large particulates can easily be separated from gas streams by inertial methods, i.e., changing the direction of the gas stream as in a centrifugal or cyclone separator. Mechanical methods such as venturi scrubbers which impact the particulates with a water spray or filters which interpose a mechanical barrier are also effective. Similarly, electrostatic forces can be used in the electrostatic precipitators. As the particulate size decreases, however, the collection efficiencies of these separators also decrease. When the diameter of the particulate is below about 1 micron (one micron equals one millionth of a meter), the collection efficiency of the conventional venturi scrubber and the electrostatic precipitator drops rapidly from over percent to less than 20 percent. In steelmaking processes and other refining processes, particularly those in which pure oxygen is employed, a large portion of the particulate formed is of submicron size so that this decrease in efficiency is a matter of direct concern.
It is believed that the reason for the decrease in the collection efficiencies of the wet scrubber is generally related to the mass and relative velocity of the particulate. In a conventional wet scrubber, the capture of particulate is due principally to the collision of the particulate with droplets of water. When the particulate size decreases, its mass will also decrease and a point will be reached where the particulate can pass around the water droplet in a stream line. The ability of the particulates to be displaced around a water droplet depends also upon the momentum of the particle of water droplet which, in turn, is related to the relative velocity between the particle and the water droplet. Thus, it will be more difficult to displace a particle or water droplet having a relatively high velocity than one having a low relative velocity. Finally, if it be assumed that the particulate matter contained in a gas stream is distributed more or less uniformly throughout the stream, the probability of collision or impaction with water droplets is enhanced if a given mass of water is divided among a very large number of very small droplets rather than being concentrated in a relatively small number of large droplets. As the water droplets become smaller there is less opportunity for the incoming particle to be deflected by the streamlines of flow around the water droplet.
Summarizing with respect to the process of impaction for the collection of very small particulate, it is known that high collection efflciencies can be produced by providing (for a given mass of water) droplets of minimum size having a maximum velocity relative to the particulate. Insofar as the relative velocity is concemed, it is, of course, immaterial whether the droplets are accelerated relative to the particulate or vice versa and both methods are commonly used. It is also believed that maximum collection efficiencies are produced when the size of the particulate to be collected and the size of the water droplets are of the same order of magnitude.
In the well-known venturi wet scrubber, the particulate-containing gas is forced through a duct by fans or blowers and then accelerated by the converging portion of the venturi to a maximum velocity at the throat of the venturi where water is injected through jets of spray nozzles to impact against the gas stream. In contrast, in the venturi jet scrubber the reverse process occurs. Here water is ejected from the nozzle generally positioned along the axis of the venturi. The water jet, functioning as a water ejector, induces a flow of contaminated gas through the venturi by mixing and entraining the gas. The high velocity water droplets emerge from the nozzle drive and simultaneously mix with the gas in a process involving an exchange of momentum between the water droplets and the gas. In both general types of venturi scrubbers referred to, the collection efficiencies depend, in large part, upon the energy input to the system which, in turn, determines the size of the droplets and the relative velocity between the droplets and the particulate.
While impaction is believed to be the principal collection mechanism in wet scrubbers operating at ambient temperatures, other mechanisms can also exist. For example, if steam should be formed and mixed with the particulate-containing gas and then the mixture of steam and gas should be cooled, the steam will preferentially condense on the water droplets and particulate matter which consitute ideal nucleation sites.
As pointed out above, the efficiencies of the venturi scrubber can be increased by increasing the energy supplied to the scrubber. This can, of course, be accomplished either by accelerating the contaminated gas to a higher velocity or by increasing the energy of the water jetted into the scrubber. As water is substantially incompressible its energy can be increased most effectively by increasing its temperature. Of course, the
water should not be allowed to boil or vaporize before passing through the nozzle as this would decrease the mass flow through the nozzle. Such boiling or vaporization behind the nozzle is readily prevented by an appropriate increase of the pressure of the water.
It has been demonstrated by Dr. Otto Frenzl in an article entitled Flow of Vaporizing Water in Nozzles, published in Maschinenbau und Waerrnewirtschaft (1956), and in various subsequent publications that it is possible to design a water ejector drive using hot water in which a portion of the hot water passing through the nozzle, for example, will flash into the vapor state as it is expanded in a diverging portion of the nozzle. The water flashing into the vapor state atomizes the remaining liquid water into a large number of extremely small droplets and accelerates them to a high velocity. This process, which produces turbulent mixing conditions, begins in the diverging portion of the nozzle and continues, in a properly designed ejector, for some distance beyond the nozzle exit until a large portion of the energy contained in the hot water has been transferred to the gas stream. Dr. Frenzls hotwater drive was developed as an improvement over the steam ejector as a drive for wind tunnels (see US Pat. No. 2,914,941 and 3,049,005), and has also been used as a drive for jet engine test facilities (see 0. Frenzl, Hot-Water Ejectors for Engine Test Facilitiesf il.
Spacecraft, Vol. 1, No. 3, May-June 1964, pp.
As the physical requirements for collection of small particulate in a wet scrubber are identical with the requirements for driving a gas by a hot-water ejector, i.e., large numbers of small water droplets having a high relative velocity with respect to the particulate in an environment where turbulent mixing conditions exist, it will be appreciated that a properly designed hot-water drive provides the basis for a highly efllicient wet scrubber. Accordingly, applicants used a Frenzl hot-water drive in constructing the particulate cleaning system shown in FIG. 1 for the removal of particulate from the off-gas of open hearth furnaces and ore kilns. As a further development of this system resulted in the present invention, the particulate collection system will first be described.
Referring to FIG. 1, the hot flue gas from the open hearth or ore kiln is directed through a duct 10 and into a waste heat boiler 12. Preferably, the boiler is designed with vertical gas flow passages so that very large particulates carried from the furnace will drop out of the gas stream and be deposited in the collection chamber 14 at the base of the boiler 12. From the waste heat boiler 12, the flue gases are directed through duct 16 into an atomizer or conditioning chamber 18. A damper 20 is provided at the entrance of the atomizer chamber 18 to control the flow of gas therethrough and provide a resistance to start the hotwater drive as described hereafter. The atomizer chamber is fitted with a number of spray nozzles 22 connected to water supply manifold 24 (see FIG. 2). The water emitted from spray noules 22 need not be heated or specially treated and, in fact, raw water or normal tap water containing the usual minerals is desirable. The atomizer 18 performs the dual functions of further cooling the flue gas to reduce the volume thereof and of saturating the gas and particulate matter contained therein. During the upward passage of the gas through the atomizer 18, an additional portion of the particulates is captured by the water and falls to the bottom 26 of the atomizer 18. This water and particulate is removed as a slurry through the drain 28. Depending upon the size and mass of the particulate, as much as -95% may be re moved in the atomizer 18, while the remainder of the particulate tends to become agglomerated and saturated with water (see Truitt and Davis, The Function of condensing Steam in Aerosol Scrubbers, American Industrial Hygiene Association Journal, Vol. 32, No. 9, Sept. 1971, pp. 583592).
The Frenzl hot-water drive 30 is positioned at the top of the atomizer 18. The drive comprises an adjustable nozzle 32 (FIG. 4) fed by hot water at high pressure through a line 34. The drive water is preferably heated by the heat extracted from the flue gases in the waste heat boiler 12, although supplemental heat may be provided if the flue gases do not contain sufficient heat. In a preferred embodiment of the apparatus it has been found that a nozzle having a throat diameter of 0.516 inches and driven by water at a temperature of about 450F. and a pressure of about 400 psig. is sufficient to pump about 1100 pounds of flue gas per minute when located on the axis of an appropriate mixing tube 36, which, in the present example is a straight cylindrical tube 18 inches in diameter and about 16 6 feet long. The mixing tube 36 communicates between the top of the atomizing chamber 18 and the tops of twin cyclone separators 38. In the present example, the cyclone separators have a diameter of about 4 feet and an efiective height of about 16 feet. Cleaned gases leave the cyclones from a 30 -inch diameter stack which extends axially into the cyclone separator body for a distance of about 6 1% feet. A slurry comprising particulate matter and water is removed from the bottom of the cyclone separator through a drain 40. When required, the effluent from the atomizer 18 and the cyclones 38 can be treated and conditioned to remove the particulate and the treated water may be returned to the waste heat boiler 12 or to the atomizer 18 if desired.
FIG. 4 is a schematic drawing showing the adjustable nozzle 32 located along the axis of the mixing tube 36. The nozzle is of the converging-diverging type and is fitted with an adjusting needle 42 which, through lateral adjustment, varies the effective throat area of the nozzle. The nozzle thus operates at constant pressure throughout its full flow range. I
In the region 44 behind the nozzle throat, the driving water is entirely in the liquid state at high temperature and pressure and contains a large quantity of stored thermal energy.- In the diverging portion 46 of the nozzle, however, a lower pressure exists which causes a portion of the driving water to be exploded into the vapor state with a rapid release of energy. The virtual explosion of the high energy water into droplets does not occur at a single location within the nozzle but is a continuing process which occurs both within the diffuser portion of the nozzle and in the expanding generally cone-shaped mixture 50 of vapor and water exiting from the nozzle. The effect of this continuing process is to produce an increase in the number of water droplets and a decrease in the size of the droplets downstream from the nozzle until a point is reached where the energy contained in the water has been substantially dissipated to the mixture. As the generally coneshaped mixture of vapor and water approaches the entry of the mixing tube 36, it begins to entrain and mix with the carrier gas to .form a turbulent fog-like mixture of gas, vapor and water droplets. Simultaneously with the atomization of the water droplets, the process of impaction or collision occurs within the fog-like mixture exiting from the nozzle which tends to increase the size of the water droplets. In addition, some of the vapor may tend to condense, depending upon the local physical conditions. Finally, the processes of diffusion will affect at least the smallest droplets and particulate. The result of these various processes which are occurring simultaneously within the mixture of gas, vapor and water beyond the nozzle is to create a violently turbulent region in which intimate contact occurs between the gas, the gaseous or particulate contaminants contained therein and the vapor and water droplets to provide extremely efficient mixing conditions. However, these mixing conditions cannot be fully exploited unless the cone-shaped jet spray emerging from the nozzle becomes firmly attached to the mixing tube wall so as to provide a barrier against the flow of gas past the jet and cause the gas to be fully entrained within the jet spray. As full entrainment is also necessary to efficient pumping it will be appreciated that efficient pumping and mixing necessarily occur in a well designed hotwater ejector and mixing tube assembly. As a result of the processes occurring within the mixing chamber, any particulate contained in the gas will necessarily be captured by the water droplets. As the mixture of gas, vapor and droplets passes down the mixing tube the processes of impaction, collision, condensation and diffusion which tend to increase the droplet size will become predominant and, if a proper mixing tube length and flow velocity have been provided, the droplets will be of sufficiently large size to be separated in the twin cyclone separators 38.
In order for the hot-water drive to function efficiently as a pump it is essential, as both applicants and Dr. Frenzl have demonstrated, to cause the conical spray 50 exiting from the nozzle to engage the wall of the mixing tube 36 or in other words, to hook up to the mixing tube. Once hook up occurs, the action is analogous to continuous piston operation with suction upstream of the point of hook up and positive displacement of the pumped gas on the downstream side of the hook up point. Assuming that the nozzle, the mixing tube and the temperature and the pressure of the driving liquid have been properly proportioned, the hook up may be effected either by placing a resistance in the gas flow circuit behind the nozzle 32 as by closing the damper 20 in the duct 16 or by using an excess of driving water for the nozzle by opening the adjustable needle 42. When the damper 20 is closed, the action. of the water jetted from the nozzle 32 tends to create'a vacuum behind the nozzle which, it is believed, tends to increase the angle of the conical jet spray 50'until it strikes and firmly adheres to the wall of the mixing tube. Once hook up is obtained, the damper may be opened to permit the desired flow of gases through the duct 16. In the second method of causing the jet to hook up, an excess of water is expanded through the nozzle which, it is believed, also tends to increase the cone angle of the emerging water and steam mixture. Once the ejector has been hooked up the water flow may be reduced to approximately half of the starting flow without loss of pumping efficiency. 1
The hot-water drive described herein has been designed to operate at a weight ratio of driving water to driven gas (a) of about 0.40, i.e. 4 pounds of water are required to drive each pound of carrier gas. In practice, it has been found that the system can operate efficiently at a ratios of between about 0.25 and 0.45. As the a ratio is decreased, the mass flow through the nozzle is decreased and less energy is available to pump the carrier gas and mix the gas and driving water. In general, reasons of economy dictate operations at the lowest a ratio consistent with adequate pumping. It has been found in a well-designed system that, so long as the ejector is operating efficiently as a pump, it will also effectively remove the particulate matter contained in the pumped gas. Where, however, the nozzle, mixing tube and separator are not properly proportioned, greater quantities of water will be required to pump the gas and lower removal efficiencies will be experienced (see U.S. Pat. No. 3,613,333, Col. 4, lines 42-45, for example).
Although it is believed that the main mixing occurs in the mixing tube near the nozzle end, turbulent flow exists throughout the mixing tube 36 and the increase in pressure towards the end of the mixing tube further enhances the mixing action. As a result, the small droplets formed in and adjacent to the nozzle tend to coalesce or agglomerate during their passage down the mixing tube to form relatively large droplets of a diameter on the order of microns or more. As pointed out above, the increase in droplet size may be caused either by collisions with other droplets or by condensation of vapor or both. It will be appreciated that the maximum droplet size attainable will be a function of the time available for these processes to occur and this, in turn, is related to the length of the mixing tube and the flow velocity therein. In the present apparatus, the droplets have a short residence time in the mixing tube on the order of 100 milliseconds.
It is desirable for efficient centrifugal separation to provide a maximum entering velocity for the droplets and that the droplets have a maximum size, but it is apparent that these are conflicting requirements since a maximum droplet size implies a long mixing tube while a maximum droplet velocity implies a short mixing tube. In the present apparatus, these conflicting requirements are met by providing a mixing tube having a length sufficient to insure a droplet size of at least 10 microns and then utilizing twin small diameter cyclones which can effectively separate droplets of this size. It will be appreciated that cyclone separation efficiency increases as the cyclone diameter decreases and the entering velocity of the gas and liquid stream increases.
The apparatus described up to the present point has proven to be highly effective in the removal of particulate matter from the off-gases of open hearth furnaces and ore kilns. In tests run in accordance with the procedures specified by the Environmental Protection Agency, removal efficiencies in excess of 99 were obtained.
As pointed out above, the chemical reactions relating to the removal of S0 using various reagents are well known. The reagents which are potentially most attractive in a large scale commercial process include lime, limestone, caustic soda, magnesia, ammonia, potassium permanganate, soda ash and other alkalis.
The reactions involving caustic soda (sodium hydroxide, Na OH) are:
2 Na OH +80 N2 S0 +H O and Na OH $0 Na IHISO In accordance with equation l) and based on the molecular weights of the reactants, 80 parts by weight of sodium hydroxide react with 64 parts by weight of sulfur dioxide. Thus, it requires 1.25 pounds of sodium hydroxide to react with and remove one pound of S0 According to equation (2), 40 parts by weight of sodium hydroxide react with 64 parts by weight of sulfur dioxide so that 0.625 pounds of sodium hydroxide are required to react with and remove one pound of S0 The reactions described by equations (1) and (2) occur generally at the same time and an equilibrium exists between them. When an insufficient amount of caustic is provided, the bisulfite reaction (Equation (2) is favored while in the presence of excess caustic any bisulfite will be further reacted to form sodium sulfite. Al though from considerations of economy of chemical reactants it would be desirable to promote the bisulfite reaction, the presence of the bisulfite may result in corrosion problems.
Like the reactions involving caustic soda, there are two reactions between soda ash (sodium carbonate- )and S0 Na co, so Na, so, co
(3) Nag (303+ 2so2+ H20 4 2 Na Hso, co2
In accordance with equation (3) and based on the molecular weights of the reactants, 106 parts by weight of sodium carbonate react with 64 parts by weight of Ca (0H) S0 CaSO H O In this reaction, 74 parts by weight of calcium hydroxide react with 64 parts by weight of S0 so that it requires l.l5 pounds of calcium hydroxide to react with and remove 1 pound (T50 While it is theoretically possible to attain a bisulfite reaction, lime is ordinarily provided in excess quantities so that there is little likelihood that the reaction products will contain the bisulfite. Lime may also be provided as dry lime (CaO) which, when mixed with water to form a slurry will react with the water to form the hydroxide (Ca (OH)2). However, the contaminated gases, particularly those resulting from a combustion process will ordinarily contain considerable quantities of carbon dioxide (CO In this circumstance, the following reactions will occur:
that the removal efficiency for S0 may be somewhat decreased where, as here, the time for reaction is limited by the dynamics of the equipment utilized in the process.
From equations (7) and (8), it might be thought that limestone (calcium carbonate) would be preferable to slaked lime (calcium hydroxide) as a reactant where carbon dioxide is present particularly in view of the low cost and ready availability of limestone. However, the calcium carbonate formed according to equation (6) and which reacts according to equation (7) will be in a substantially molecular form which is capable of rapid chemical reaction. Limestone, on the other hand, is commercially available only as a coarse aggregate and even when ground to 325 mesh or below is not sufficiently fine so as to be capable of rapid reaction. As will be shown below, limestone is not well adapted to the present PI'OCCSS.
Recognizing that the apparatus shown in FIG. 1 was effective for particulate removal principally because the driving power of the hot-water ejector necessarily created an extremely effective mixing action between the drive water and the driven gas and the particulates contained therein, applicants believed that, if this mixing environment could be utilized as a reaction chamber, effective sulfur dioxide removal could be accomplished simultaneously with particulate removal with a minimum amount of chemical reagents and little additional equipment. To determine whether or not this new concept for S removal was viable, applicants instrumented the particulate removal apparatus as shown schematically in FIG. 3 and provided means for the introduction of various chemical reagents at several locations in the apparatus, also as shown in FIGS. 3 and 4.
FIG. 3 shows in schematic form part of the apparatus of FIG. 1 beginning with the inlet duct 16 to the atomizer chamber 18 and ending with the cyclone separator 38. Similar parts in the two figures bear corresponding identification numerals. The apparatus selected for the test work described herein was connected to treat the effluent air from an ore kiln cooler. As this effluent contained substantially no sulfur dioxide or carbon dioxide it was possible, by adding measured quantities of these agents, to determine with precision the effect of the several chemical reactants and the manner of their injection into the system.
Referring now to FIG. 3, S0 was injected into the atomizer inlet duct .16 through a conduit 54 communicating with a bank of cylinders 56 containing liquid S0 manifolded at 58 to provide a supply of gaseous S0 The cylinders 56 of liquid S0 were maintained in a warm water tank 60 to facilitate the flow of S0 The manifold pressure of the S0 was indicated by a pressure gage 62 located upstream of the S0 control valve 64. The flow of S0 was controlled by maintaining a constant differential pressure across the S0 injection meter 66 as indicated by a differential manometer. An independent check on the S0 was provided by an S0 emission monitor 116 placed in the cyclone discharge stack 38 and calibrated to show the S0 input in parts per million of the gas flow.
In a similar manner, provision was made to inject measured amounts of carbon dioxide (CO into atomizer inlet duct 16. The CO was obtained from a refrigerated storage tank 70 containing CO in liquid form. The pressure of the CO was indicated by a gage 74 located upstream from a control valve 76. The CO was passed through a hot-water bath heat exchanger 78 and then introduced into the atomizer inlet duct 16 through conduit 80. The flow of gaseous CO in the conduit 80 was measured by a flow-meter 82 and controlled by valve 76.
To provide a complete control of the operating parameters and a record of the ambient conditions, the following instrumentation was provided: An inlet gas meter 84 was located in the duct 16 to measure the stagnation and static pressures of the inlet gas within the inlet duct 16 and the inlet gas temperature was indicated by a thermocouple 86. The ambient atmospheric pressure was measured with a barometer 88 located adjacent the inlet duct 16. The pressure of the spray water introduced into the atomizer 18 was measured by a gage 89 located in the atomizer water supply manifold 24. The condition of the nozzle driving water was determined by instruments placed in the hot water supply line 34 just upstream of the nozzle 32. These instruments included a pressure gage 90, a thermocouple 92 and a flowmeter 94. The operating position of the nozzle adjusting needle 42, measured as displacement in inches from the closed position was shown by a meter 96.
Significant pressures in the system were shown by pressure gages 98, 100, 102 and 104 located, respectively, downstream of the nozzle, at the mixing tube entrance; at the mixing tube exit; and within the cyclone separator. Corresponding temperatures within the system were measured by thermocouples 106, 108 located, respectively, downstream of the nozzle and at the end of the mixing tube 36.
At the drain 40 of the cyclone separator 38, the temperature of the slurry was measured by a thermometer 110 and the time required for the slurry to fill a standard 55 gallon barrel 112 was recorded. The quantity of S0 contained in the slurry was determined by chemical analysis and calculated in terms of pounds of S0 collected per minute for comparison with emission monitor and S0 differential manometer pressure data.
At the stack of the cyclone separator 38 S0 sampling taps 114 were provided for an S0 measuring meter 116 calibrated to measure the S0 content of the gas exiting from the cyclone separator 38 in parts per million by volume.
In order to establish the validity of applicants concept that it was necessary to initimately mix the reactants with the atomized driving water and 80;,- containing carrier gas, applicants tested a variety of chemical reagents as powders, slurries and solutions and injected into the apparatus at several locations where a variation in the mixing efiiciency and reaction rate might be experienced. The reagents tested included lime, limestone and oyster shells injected as dry powders; lime and limestone injected as a wet slurry; caustic soda and soda ash injected as a solution; and mixtures of lime and caustic soda injected as a wet slurry. The points of injection included direct injection into the nozzle (Location 1); direct injection into the nozzle driving water (Location 2); delivery to the exterior of the jet spray at the end of the nozzle (Location 3); injection into the interior of the jet spray at the end of the nozzle (Location 4); dry delivery to the jet spray beyond the nozzle (Location 5); dry delivery to the top of the atomizer before the nozzle (Location 6) and injection to the atomizer spray water (Location 7).
Referring again to FIG. 3, the chemical reagent delivery system comprises a mixing tank 113 provided with a mechanical mixer 120 and metered water conduit 122 communicating with a valved hot-water line 124 and a valved cold-water line 126. The outlet of the mixing tank 118 communicates alternatively through a valved conduit 128 to a chemical pump 130, a slurry pump 132 and a drain 134. Where reagent mixing is not required, a valved reagent tank 136 may be connected through a conduit 138 to the conduit 128 adjacent the intake of the chemical pump 130. Pressure gages 140, 142 are provided in the outlet lines 144, 146 connected, respectively, to the chemical pump 130 and the slurry pump 132. Outlet lines 144 and 146 may conve- Inlet conduit 156 communicates with an annular manifold 162 FIG. 4A) located at or near the exit end of the nozzle 32 (Location 4). A number of circumferentially disposed orifices or nozzles 163 (FIGS. 4A and 4B) are formed in the manifold 162 so as to deliver the chemical reagent as a series of intense jets into the central portion of, and generally in the direction of movement of the conical jet 50 emerging from the nozzle 32 at an acute angle to, but not necessarily intersecting, the axis of the nozzle 32. Location 4, in contrast with Location 3, was intentionally designed to inject the chemical reagent into the central portion of the conical jet 50 emerging from the nozzle 32. It will be appreciated that although the chemical reagent at Locations 3 niently be joined to form a single chemical reagent sup- 15 and 4 is delivered to approximately the same portion of ply line 148 which communicates alternatively through the conical jet 50 emerging from the nozzle, the reavalved inlet conduits 150, 152, 154 and 156. gent from Location 3 is delivered at low intensity to the Inlet conduit 150 communicates with chemical reaouter surface of the conical jet and does not initially gent Location 1 referred to above. Location 1 compenetrate into the conical jet while the reagent from prises two ports 158 formed in the expanding or dif- Location4is delivered at high intensity into the central fuser portion of the hot-water ejector nozzle 32 and loportion of the jet with a momentum which adds to the cated 180 apart about two inches from the end of the driving power of the jet. nozzle. As shown in FIG. 4, the ports 158 are formed Locations and 6 constitute, respectively, ports 164 with smooth edges to minimize disturbance to the flow and 166 located in the top of the atomizer chamber 18 of fluid through the nozzle 32. The chemical reagent along the axis of the Frenzl hot-water drive unit injected at this point is injected at a direction which is downstream (Location 5) and upstream (Location 6) approximately normal to the flow through the nozzle. of the nozzle. These locations were designed specifically for the introduction of dry powdered chemical rehllet conduit 152 Communicates directly with the agents such as lime, limestone and oyster shells. The nozzle driving water supply line 34 just behind the noz- 30 i j i system comprises a reagent st ra e bin 168 216 32. Thus, chemical reagent Location 2 referred to fitted at the bottom an appropriate metering deabove is the nozzle hot Water pp y AS hot Water vice and a conduit 170 communicating, respectively, is supplied to the nozzle at temperatures in the range i h port 164 d t 166, A a ativ r s re will of 450F. and pressures in the range of 400 psig, it Will exist within the atomizer chamber, it would be possible be appreciated that diffieuhtes y be experienced in to utilize the vacuum to draw powdered reagents into injecting chemical reagents at this point. Additionally, th atomizer alth h it will be appreciated that there where calcium-based reagents uch as lime r lim are mechanical problems associated with the delivery Stone are used, formidable Scaling Problems can he of powdered reagents that are ordinarily not experi- Peeted Which y interfere with the Performance Of enced with the delivery of liquid reagents. Location 5 the 1102216 and, where sodium-based reagents Such as (downstrea n of the nozzle) permits a omparison besoda ash and causti da are us corrosion p le s tween a dry reagent acting on the surface of the conical may be experienced. It has been reported in connection j t t am d a liquid reagent similarly acting on the with venturi jet scrubbers manufactured by Koertrol s rface of the conical jet stream (Location 3). Loca- (iorporation yp 7014) that When p a d With a tion 6 (port 166) was positioned so that powdered maweak caustic solution at ambient temperatures, good t ri l which did not become entrained in the gas flow removal of S0 was experienced. would fall through the atomizer spray and react within Inlet conduit 154 communicates with chemical reathe atomizer chamber 18. gent Location 3 which comprises a single conduit 160 Location 7 involved the introduction of chemical repositioned above the exit end of the nozzle 32 so that ent into the atomizer chamber 18 via the atomizer the chemical reagent can be delivered to the exterior water ly 24 and pray nozzles 22. As the mixing 0f the conical l 50 emerging from the nozzle 32 at conditions within the atomizer chamber 18 are less efsuch an intensity that the chemical reagent does not f tiv than thos in th Frenzl drive, it was believed penetrate into the central portion of the conical jet but th t th 50 removal efficiency would be correspond remains essentially on the surface thereof. Location 3 ingly lower. Nevertheless, the addition of a basic matewas intentionally designed to deliver the chemical reaial i th atomizer presents the possibility of a twogent to the exterior of the conical jet in contrast to a destage SO removal process together with a control of livery within the jet. the pH in the atomizer portion of the apparatus. I
TABLE I NaOI-l Injection Over Run Air- Driver SO Equiv. all Corr. No. flow Water Alpha SO, Injected Chemical Injected Out Ratio Effic. pH Rate Lbs/ Lbs/ Lbs. H O Lb./Min PPM Location %Conc. GPM PPM m.p.y.
Min Sec LB. Air (Vol) (Vol) l-l 846 5.06 0.359 0 0 0 0 0 0 0 0 3.7 l-2 859 5.06 0.353 I06 536 0 0 515 0 3.9 2.5 I40 l-3 874 5.06 0.347 I06 536 2 50 .80 15 3.83 97.2 13.3 35
TABLE I Continued NaOH Injection Over- Run Air- Driver S Equiv. all Corr. No flow Water Alpha SO, Injected Chemical Injected Out Ratio Effie. pH Rate Lbs/ Lbs/ Lbs. H O Lb./Min PPM Location %Conc. GPM PPM m.p.y.
Min Sec LB. Air (V01) (Vol) 21 866 5.01 0.347 1.06 537 0 0 516 0 3.9 22 865 4.96 0.344 1.06 531 2 21 .74 14 1.24 97.2 12.3 6.2 2-3 869 5.00 0.345 2.07 963 2 21 .74 36 0.68 96.3 5.5 720.0 24 869 5.00 0.345 2.07 963 0 0 926 O 3.8 2.4 150 25 881 4.96 0.337 2.67 1435 O 0 1380 0 3.8 2-6 882 4.97 0.338 2.67 1435 2 21 1.12 56 0.68 96.1 5.7 980 3-1 869 5.99 0.413 1.04 472 0 0 454 0 3.8 3-2 884 6.23 0.423 1.04 479 2 21 1.10 13 2.04 97.3 13.0 16 42 843 6.28 0.447 1.05 503 2 5.4 1.60 21 0.66 95.8 43 854 6.27 0.440 1.05 503 2 5.4 1.10 140 0.45 72.2 5-1 906 6.28 0.416 1.04 468 0 0 451 O 3.6 52 915 6.32 0.414 1.04 468 l 7.1 1.16 90 0.63 80.8 5.3 330 5-3 905 6.27 0.416 1.04 468 1 7.1 2.51 1.38 95.7 6-1 916 6.33 0.414 1.05 462 3 7.1 1.27 35 0.70 92.4 5.6 380 6-2 909 6.30 0.416 1.05 468 3 7.1 0.74 162 0.40 65.4 2.5 290 7-1 902 6.26 0.416 0.90 425 3 1.5 4.10 89 0.47 79.1 2.5 260 Table I above sets forth the data for the first group of tests involving the use of sodium hydroxide as the chemical reagent. In Runs 1 through 4, solutions of varying concentration were injected into the nozzle driving water (Location 2), while in Run 5 the solution was injected into the nozzle (Location 1) and in Runs 6 and 7 the solution was added at the nozzle exit (Loca- Equivalent Ratio Lb./Min. of Chemical (Chemical Constant) ]/(Lb./Min. of S0 Injected) where the chemical contants are those calculated from equations (1), (3), (5), (7) and (8) and summarized in Table II below:
Table II Reagent Chemical Constant* Sodium Hydroxide (NaOH) 1.25 Sodium Carbonate (Na, C0 1.66 Calcium Hydroxide (Ca(0l-1),) 1.15 Calcium Carbonate (CaCO .55
Pounds of reagent required to remove one pound of S0,
The chemicalconstant for the bisulfite reaction is not employed since it is impossible to predict the quantity of bisulfite present. Where, however, the equivalent ratio is less than 1.0 some bisulfite will usually be present.
The Overall Efficiency is defined as follows:
Overall Efficiency [(lnlet S0 Outlet SO )/lnlet S0 X 100 The Overall Efficiency is thus a measure of the effectiveness of the removal of S0 The pH column shows the broad variation in pH that can be observed in the slurry drained from the cyclone separator (or atomizer chamber) while the Corrosion Rate column indicates the rate of corrosion in mils per year that would be caused by this slurry.
The data from Table I shows that sodium hydroxide is a powerful S0 removal agent and that it is more effective when introduced directly into the nozzle driving water (Location 2; Runs 2-3; 2-6; and 42) than when introduced within the nozzle (Location 1; Run 5-3) or at the end of the nozzle (Location 3; Run 6-1). The data shows that NaOH can remove over 97% of the S0 present, whereas in the absence of any chemical reagent only about 4% of the S0 is removed. However, balancing the effectiveness of the removal of S0 it is apparent that the use of quantities of NaOH constituting an equivalent ratio less than 1.0 results in a low pH and an extremely high corrosion rate. In Runs 2-3 and 2-6 the corrosion rate was, respectively, 720 and 980 mils per year, whereas the untreated effluent had a corrosion rate between and mils per year. Where, however, excess NaOH was used the corrosion rates dropped drastically while the pH rose to highly basic levels. The use of excess quantities of NaOH may not be a practical answer to the corrosion problem because of the cost of NaOH in comparison to other chemical reagents as shown in Table III below:
Table III Typical Delivered Reagent Cost per Pound Lime (Ca(Oll),) $.0103 Caustic (NaOH) .0423 Limestone (CaCO .0017" Soda Ash (Na CO .0447 50% Lime 50% Caustic .0263
Excluding crushing and grinding costs
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subset: commoncrawl


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On Tuesday nights, the Prototek shop is open for visitors. This is a great opportunity to see the shop before it opens and meet the founders and other makers.
We are located at 1700 W. Main st. in Oklahoma city. Our shop is in the downstairs portion of the building and you can access our door by following Kentucky Ave. to the rear of the building.
Hope to see you there!
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Archive for January, 2010
Gallery Girls at the Robert Berman Gallery. At Bergamot Station Arts Center 2525 michigan avenue, Suite C2/D5Santa Monica, California 90404. Artwork by Ben Talbert. Jasonsavvy selector. Look for more…
gallery girls
Late Nite Drawing Salon – Downtown LA's New Social Drawing Club. East 3rd Steakhouse & Lounge 734 East 3rd Street, Downtown LA, CA 90013. contact firstname.lastname@example.com for more info. jasonsavvy on the wheels of steel. every Monday 10pm


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Stella Pierrie
"I'm a hairdresser in Chelmsford, Leigh-on-Sea & Basildon offering a personalised service thats meets your needs and expectations"
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Being a hairdresser in Chelmsford, I can commute to all surrounding areas around Essex. Available 9am-6pm Mon-Fri.
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Being a trained professional I offer a free and thorough consultation to assess your hair needs.
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Throughout Essex, I offer a bespoke personalised service to cater for every need, from bridal and special occasion to everyday easy-care styles, the emphasis is always on healthy, easy-to-manage hair that you can maintain yourself.
I have over 25 years of experience in the hair and beauty industry and have worked in some of the UK's most prestigious hair salons. During my career, I have successfully achieved various NVQ level 3 qualifications.
Benefit from on-going hair maintenance and the confidence of an experienced, professional hairdresser to look after your hair care. I use the best in ammonia-free and mineral-based hair colourants to improve and enhance all hair types.
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Basso Ridiculoso
"100 Yard Dash" Bass Line
Here is nice old school bass line by
Raphael Saddiq
on his retro tune called "100 Yard Dash". It repeats throughout the entire song with some slight variations. It has an interesting phrase that starts off the beat and the trick is keeping it solid and on those off beats to really glue the entire song together. Check it out.
Here is the track off the album:
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Monday, August 26, 2013
The Return of Fruity Yummy Mummy
8 comments:
- Cliff_KnueppelAugust 27, 2013 at 1:37 PM
Haha oh yeah! Took me some time to find them (well one, so far) but I was excited when the news broke. Halloween is surely upon us! Now that most schools are back in session, it's all about Halloween! Should be fun :D
ReplyDelete - Cliff_KnueppelAugust 28, 2013 at 5:39 PM
It's funny because I found them at Walgreens when they first came in, but since returning, Walgreens hasn't put them out on shelves. One guy told me it was going out, another said not for another month. So I'm confused, now. I guess it'll all be out soon. Glad you like the theme, man! Thank you! - Bob SuruncleAugust 31, 2013 at 12:04 AM
The FIRST thing I suspect anyone (i.e., eBay seller/scalper) will do when they get to their local Target, is to grab EVERY box (retro design) off the shelf. and then speed home to list them all on eBay @ $200 a box or $500 for a set. but only AFTER the cereal date has expired so that no one will be able to eat any. plus, the boxes will be crushed (purposely before shipping).
ReplyDelete - Cliff_KnueppelAugust 31, 2013 at 3:20 AM
Unfortunately, you're probably right. Because of the hype generated by General Mills and Social Media, people who don't even care about this cereal are going to snatch em up and screw the rest of us over. Hopefully we get lucky and the real fans of Monster Cereals and Halloween get to enjoy this, but I guess time will tell.
ReplyDelete - Death_NationSeptember 1, 2013 at 10:21 PM
Well that was a incomplete review you only tried just one cereal .
ReplyDelete - Cliff_KnueppelSeptember 1, 2013 at 10:32 PM
Didn't find Frute Brute, yet. But considering the title of the post is "The Return of Yummy Mummy" and not "The Return of Yummy Mummy and Frute Brute," I'd say it's pretty complete. Sorry it didn't satisfy you..


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- Description
Quick Overview
Bottega Di Lungavita Linea Casolare Vanilla Bath & Shower Gel is formulated for a rich bathing treat.
- A formula rich in Mineral Salts and Vitamins with refreshing and softening properties.
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All our products are far from expiry, and procured directly from the brand/authorized resellers of the brand.
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Better Business Bureau is warning college students to be on the lookout for scammers on Craigslist and other online classifieds when searching for an on or off-campus apartment to rent. Phony ads for rental properties are always popping up, and are specifically aimed at stealing money from unsuspecting students.
While classified ads on the internet have made finding campus apartments and rentals more convenient, scammers have found a way to take advantage by targeting unsuspecting, college renters.
Students typically fall victim to this scam after responding to an online classified for a rental property. Scammers know that finding a great apartment either on or off-campus can be difficult, especially when there's a time crunch. Be wary of any rental property that offers a great place for a cheap price, as it could lead to a scam. Make sure to do a comparison of similar properties in the area to know if it's legitimate.
BBB recommends students ask their friends if they know of any apartments opening up in the area first. It's also important for students to do their research before signing a lease or handing over a deposit. Online classifieds are a great way to find a rental, but students should visit the apartment in person and carefully review any paperwork provided.
BBB advises college students searching for rentals to look out for these red flags:
For more information you can trust, visit bbb.org
For more than 100 years, Better Business Bureau has been helping consumers find businesses and brands they can trust. In 2013, consumers turned to BBB 131 million times for Business Reviews on more than 6.5 million businesses, all available for free at bbb.org. The Council of Better Business Bureaus is the umbrella organization for 113 local, independent BBBs across the United States, Mexico and Canada, as well as home to its national programs on dispute resolution and industry self-regulation.


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*Grey Lord*
(AN: hey here is another story. I usually read like three stories in at once and this story just came to me. Its a little mix of two stories but most stuff is mine. The stories The Dark Angel: by puffin and The Wolves: Part 1: by Roslyn StVincent are my inspirations for this story.)
Disclaimer: I don't own Harry Potter
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The Marauders were a pranking group in their school years. But the thing that brought them all together was their species. None of them were completely human. Remus who was the first for his creature to be discovered was a werewolf. The other three automatically became animagi to accommodate him. Sirius was a type of incubus. Peter was a type of were-rat; he never really became an animagus. And James was a Type of Dark Elf.
A dark elf was known for its affinity for animals. Speaking and changing into them mostly.
It was around their fourth year when three of the four fell in love. James Potter, Remus Lupin, and Sirius Black all fell for each other and formed a triad.
All was good until their seventh year when James's mate ended up being the beautiful Lily Evens. When they hooked up Remus and Sirius felt like they'd been abandoned, well at least before they to turned 17 and relised who their mate was. Lily was mates with all three of them.
It turned out that Lily ended up being a type of Japanese demon called a Kitsune; kitsune's had one mate for every two tails. Only their mates could see their tails and fox ears after they are mated. Lily was a fire or red Kitsunes. There are six types of Kitsunes. There are water a dark black almost blue colored fox, wind which was a white colored fox, earth was brown, and finally energy/lightening which is silver.
They all moved in together at Godric's Hollow and had a beautiful baby boy called Harry. He looked like a mix of all four of them. With one of lily's green eyes and Remus's amber eyes.
Peter was forgotten. He was left alone as his friends went on to be a happy family. He was an easy prey for the dark. Always jealous, always ignored, Cowardly and pathetic. The Dark lord was quite happy with his spy. No one suspected him, so no one would discover him.
Three months before October
The Headmaster of Hogwarts School of Witchcraft and Wizardry looked over the prophecy he'd recently discovered. It was found in a book of prophecies that showed him a prophecy as it is crated. This one was called Dawn of the Grey. It read:
In the time where evil hides within the light
And the light shines inside the shadows.
When the seventh month dies
Born onto four of different breeds
A spirit of grey with heart of white.
Connected through fates design
Five mates will stand behind.
Two of dark Two of light
And one stuck in between.
An empire of light
And an army of darkness
Will crumble before
The Grey Lord's might.
Albus didn't know exactly what the prophecy entitled all he knew was that someone was coming more powerful than him. And it had something to do with that Potter-Lupin-Black child. This would take some thought.
October 30 4:00 PM
The Dark Lord looked down at Severus. "Are you sure?"
"Yes there was a prophecy proclaiming either the potter or the Longbottom's brat destined to destroy you."
"Fine. You take the Lestranges to the Longbottom's and I'll take the Potters." The Dark Lord rose out of his throne and made his way to the door.
"My lord?" Voldemort turned to the young man." Can you please spare Lily?"
The Dark lord softened his glare. "I am not planning on killing anyone. I just want to make sure they stay out of the war."
"Thank you my lord" Severus murmured then left.
October 30 7:00 PM
The dark lord looked at the paper in his hands. 24 Godric's Hollow. It was the secret to the Potter household. Walking up the steps he entered the room. Looking around he saw scorch marks all over the place and James Potter dead on the ground!
He quickly ran up the stars just in time to hear lily's dying Screams. Walking into the room Voldemort saw Dumbledore standing, with his wand out, over a black and wild haired baby boy with mismatched eyes. "Get away from him old man" Voldemort snarled.
"No, I don't think I will." The Old goat turned to the baby and prepared t says the killing curse.
Voldemort didn't know what made him do what he did. If asked he would say that Tom moved to the front of his mind. But he took the killing curse for that child. When his body was destroyed his soul escaped. Leaving only a small sliver in Harry's new lightning bolt scar.
"well well well. Riddle has Houruxes." The Old timer looked over at the baby. "maybe there was a use for you yet."
Same night
Remus watched as his mate was carted to Azkaban. He couldn't believe that he sold them and their cub out. He looked sadly at the older Haedmaster and cub.
" you know Remus my boy, Lily had a sister that Harry could live with. You know you don't have the means to take care of him."his grandfather voice was on full force.
Remus looked sadly at his cub. "ok"
Dumbledore turned around with a manic smirk on his face. Compulsions always work. Now the boy could be molded into a perfect weapon.
15 years later on july 30 11:59
Harry Potter hung limply of the side of his bed. He was shirtless and his back and chest was covered in all types of scars; burns, cuts, whips, and anything else. He was under punishment for failing to tell his uncle that his Godfather was dead.
This last beating was particularly bad because he burnt dinner. And now he couldn't even get into his bed. Some birthday this was.
As the seconds ticked by, harry started to feel weird. Then he itched and now pain was shooting through his body. A silver glow surrounded him. and by the time it went out, he was out cold.
(AN: well here you go. how do you like it.)


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El Clasico 3 December 2016 Match Time As per Indian Standard time and List of TV channels and Broadcaster who telecast this Real Madrid vs Barcelona Match live streaming in India.
Spain Football Club Two Biggest Team Real Madrid and Barcelona one against ready to face each other in the December 2016 at Home stadium of Camp now in the La Liga BBVA. Now let's see the 3rd December Clash of Real Madrid Vs Barcelona Kick off timing as per IST time and also see the TV channels and Broadcaster who telecast this El Clasico match live in India country.
EL CLASICO December 2016 TIME IN INDIA
Date: 3/12/2016
Time: 8:45 pm [IST]
Stadium: Camp Nou, Barcelona
Indian Telecast Channels: Sony Kix, Radio Barca
As per Indian Standard Time Real Madrid Vs Barcelona El Clasico games will begin at 8-45 PM IST time on 3rd December and all the Football fans of India can watch this El Clasico 2016 Match live on Sony Six SD, Sony Six HD and radio Barca.
Online Viewers can watch this Real Madrid vs Barcelona 3rd December El Clasico game live streaming via visit sonyliv.com which is official website of sony network.
Both El Clasico Club Played each other on 264 Official matches in various football competition and from them Real Madrid Team Won 97 occasion while Barcelona won the 109 offical games and remaining 58 Matches results in draw. Check out the complete Real Madrid vs Barcelona Head to Head as per Different Competition and La Liga tournament.
For this Football Match we expected ground will be full of Spectators with home and away supporters and Their Tickets of Real Madrid vs Barcelona 3 December 2016 El Clasico games are almost overs. So Don't miss this amazing contest between the two rivals club by watching its live on Official broadcaster TV channels. If you indian football fans then just tune your TV channel of Sony Six on 8-45 PM IST time and be a witness of amazing Football matches of this season 2016-17.
See the Complete List of TV channels and Broadcast who telecast 3 December El Clasico 2016 Match live around the glob.


text:
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In this article, I have populated Accordion Control using code behind dataset. So come and dive into the article. It is my first article on CodeProject. I am publishing this article because I faced this in a project. so I am sharing it with you. May b,e you are also on the same spot having the same problem.
For the article, you should Visual Studio 2005 or onward installed in your computer, Microsoft SQL Server.
Create a database having a table containing Title and Detail fields or columns:
Now come and create Visual Studio ASP.NET website, on the page drop script manager and accordion control from the toolbox on the page. The code will look like this:
<%@ Page Language="C#" AutoEventWireup="true" CodeFile="Default.aspx.cs" Inherits="_Default" %> <%@ Register Assembly="AjaxControlToolkit" Namespace="AjaxControlToolkit" TagPrefix="asp" %>
The Style sheet tags for the accordion controls are:
.contentAccordion{ padding:4px; background-color:Olive; } .headerAccordion { color:white; background-color:Navy; padding:4px; border:solid 1px black; }
Now you have dropped the accordion control and script manager. Before coming to dynamic populating of accordion, a little about static data in accordion control. When you are adding static data in the accordion control, then you have to follow the steps below.
Add Accordion control from the toolbox:
<asp:Accordion ID="acrStatic" runat="server" HeaderCssClass="headerAccordion" ContentCssClass="contentAccordion"> </asp:Accordion>
Place Panes tag with in the closing and ending tag of accordion control:
<asp:Accordion ID="acrStatic" runat="server" HeaderCssClass="headerAccordion" ContentCssClass="contentAccordion"> <panes></panes> </asp:Accordion>
Within the closing and ending tag of <panes>, drop Accordion Pane from the Toolbox according to your requirement. Within each accordion pane, insert Header and Content Tags, like:
<asp:Accordion ID="acrStatic" runat="server"> <Panes> <asp:AccordionPane ID="AccordionPane1" runat="server">  First Header <Content>Contents with in the ist header </Content> </asp:AccordionPane> <asp:AccordionPane ID="AccordionPane2" runat="server"> Second Header <Content>Content with in the second Header</Content> </asp:AccordionPane> </Panes> </asp:Accordion>
This was all about static data within the accordion control. Hope you have got the exact hierarchy of the Accordion control and its child controls and inner tags. It was just to introduce you to the hierarchy.
Now the dynamic section...
Hope you are familiar with what is dataset and getting data from a SQL database through C# code. Using the following code, I am getting dataset from the database.
string sql = "select * from tbl_Contents where CategoryID=37 and _ Title like 'What is Accordion control%'"; SqlConnection con = new SqlConnection(ConfigurationManager.AppSettings_ ["dbconnectionRW"].ToString()); SqlCommand cmd = new SqlCommand(sql, con); SqlDataAdapter da = new SqlDataAdapter(cmd); DataSet ds = new DataSet(); da.Fill(ds); int i =0; // I will use this for creating unique accordion panes // in each iteration of the loop Label lblTitle; // This i will use as a child control to handle Header Text // in the accordion pane Label lblConten; // This i will use as a child control to handle Content Text // in the accordion pane AjaxControlToolkit.AccordionPane pn; // I have declared an accordion pane but // not yet initialized
It is also possible if you use datatable instead of dataset. I myself will recommend Datatable too, not dataset, but here I used dataset corresponding to the title of the article.
foreach(DataRow dr in ds.Tables[0].Rows) { lblTitle = new Label(); lblContent = new Label(); lblTitle.Text=dr["Title"].ToString(); lblContent.Text=dr["Detail"].ToString(); pn = new AjaxControlToolkit.AccordionPane(); pn.ID = "Pane" + i; pn.HeaderContainer.Controls.Add(lblHtitle); pn.ContentContainer.Controls.Add(lblContent); acrDynamic.Panes.Add(pn); ++i; }
What did I do in the code? Using the foreach loop collection iterator, in each iteration, I am getting one row from the Table[0] of dataset and reposing in the DataRow dr till the end of the records in the table.
DataRow dr
lblTitle = new Label(); lblContent = new Label(); lblTitle.Text=dr["Title"].ToString(); lblContent.Text=dr["Detail"].ToString();
In these statements, I initialized the lblTitle and lblcontent labels, so that they come to existence and can keep textual data for the pane. So I am placing Title field data of database table to lblTitle and Detail field data of the database table to the lblContent.
pn = new AjaxControlToolkit.AccordionPane();
Here, in the above statement, I initialized the AccordionPane which I have declared above the loop:
pn.ID = "Pane" + i;
Using the above statement, I am assigning the accordion pane pn a unique name in every iteration, because I increment in each iteration, so in each iteration, I have a unique i value so that accordionpane created in each iteration become unique, otherwise it will not work and produce error of multiple ids, due to id conflict.
pn.HeaderContainer.Controls.Add(lblTitle); pn.ContentContainer.Controls.Add(lblContent);
Using the above statements, I am adding lblTitle as a child control for the Header section of the Panel and adding lblContent as a child control for the Content Section of the panel. Now it is time to add the accordionpane to accordion control so with the help of the below statement, it can be done.
acrDynamic.Panes.Add(pn); ++i; // incrementation so that in the next iteration I can have a unique value of i.
There the body of the loop ends, but not the iteration. Iteration will continue till the last record. So in each iteration, it will create panes and assign the pane a unique id, otherwise it will generate an error if id remain the same. Assigning those labels to their corresponding sections. Adding the pane to the accordioncontrol in the last, and incrementing the i variable for the next iteration.
Go to the code behind of the page, that will look like:
using System; using System.Data; using System.Configuration; using System.Data.SqlClient; using System.Collections.Generic; using System.Linq; using System.Web; using System.Web.UI; using System.Web.UI.WebControls; public partial class _Default : System.Web.UI.Page { protected void Page_Load(object sender, EventArgs e) { if (!IsPostBack) { PopulateAcrDynamically(); } } private void PopulateAcrDynamically() { string sql = "select * from tbl_Contents"; SqlConnection con = new SqlConnection (ConfigurationManager.AppSettings["dbConnection"]); SqlCommand cmd = new SqlCommand(sql, con); SqlDataAdapter da = new SqlDataAdapter(cmd); DataSet ds = new DataSet(); da.Fill(ds); if (ds.Tables[0].Rows.Count != 0) { Label lbTitle; Label lbContent; AjaxControlToolkit.AccordionPane pn; int i=0; // This is just to use for assigning pane an id foreach (DataRow dr in ds.Tables[0].Rows) { lbTitle = new Label(); lbContent = new Label(); lbTitle.Text = dr["Title"].ToString(); lbContent.Text = dr["Detail"].ToString(); pn = new AjaxControlToolkit.AccordionPane(); pn.ID = "Pane" + i; pn.HeaderContainer.Controls.Add(lbTitle); pn.ContentContainer.Controls.Add(lbContent); acrDynamic.Panes.Add(pn); ++i; } } } }
Now run in browser. The result will be like this:
One more thing - if you download the solution, and you come across some errors while executing, then let me know.
Thank you and best of luck. Waiting for your comments and suggestions. Regards.
This article, along with any associated source code and files, is licensed under The Code Project Open License (CPOL)
<asp:Accordion ID="acTraining" Width="100%" CssClass="pane" Height="200px" AutoSize="Limit" runat="server" SelectedIndex="0" FadeTransitions="true" HeaderCssClass="headerAccordion" ContentCssClass="contentAccordion" FramesPerSecond="200">
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Use Ctrl+Left/Right to switch messages, Ctrl+Up/Down to switch threads, Ctrl+Shift+Left/Right to switch pages.


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Marvel Sally Steadman, 88, best known as the founder of an unofficial Catholic shrine that has drawn visitors from across the country, but who also was an artist and a cook who prepared meals for President Eisenhower, died Monday in Hospice of Northwest Ohio, Perrysburg Township.
Mrs. Steadman of Oregon was admitted to hospice last month. The cause of death was not known, but likely was related to kidney failure, her daughter Barbara Brillhart said.
Mrs. Steadman founded Our Lady of Toledo, Queen of the Most Holy Rosary Shrine in Oregon.
She said that visions of the Virgin Mary began appearing to her in 1992. One result is the shrine, which opened in 1997.
The mission of the shrine is to prevent abortions, Mrs. Steadman said in published interviews through the years. Last month, through her hand-picked successor Rick Hicks, Mrs. Steadman told The Blade that one goal was to open a medical center for pregnant women and thereby help prevent abortions.
"There's so much more to come in the future," Mrs. Steadman said then.
Only Mrs. Steadman saw the visions, but she shared public messages from the Virgin Mary to crowds at the shrine. She often said she did not know why God chose her for the visions. She said last month through Mr. Hicks that her determination might have had something to do with it.
"Maybe because of my stubborn nature," Mrs. Steadman said last month. "I've always finished what I've started, whatever the task or challenge. I've always had the determination and strong will to complete whatever I've started I've always prayed hard and played hard."
The Roman Catholic Church considered her visions to be private revelations and did not officially recognize the shrine.
The daughter of Laura and Alex St. John, Mrs. Steadman grew up in Jerusalem Township.
She was a graduate of Clay High School. She married Arthur Steadman and stayed home when the couple started a family.
Cooking for members of the exclusive Cedar Point Club, on the marshes of Jerusalem Township, was a family project through the years, her daughter said. President Dwight Eisenhower's first treasury secretary, George Humphrey, was a member of the club. Twice - in 1954 and 1958 - Mr. Eisenhower stayed over for some duck hunting.
According to a Nov. 11, 1954, account in the Toledo Times, Mr. Eisenhower was served the traditional fare for Cedar Point Club guests: roast duck, wild rice, filet of pickerel and lake perch salad, creamed onions, and pie. Mrs. Steadman and her husband were responsible.
Recounting that first visit, The Blade reported before the second stay: "Each night of his stay at the secluded hunting marsh Mr. Eisenhower sat down to a dinner of widgeon (baldpate duck) quick-broiled by Mrs. Arthur Steadman, the club's cook."
Their daughter recalled: "My mom and dad were really both honored."
Mrs. Steadman, who retired from the former Seaway Food Town, painted in oils and water colors. She traveled the world. She was devoted to her bichon frise, Snowflake.
"She took a great interest in whatever she did," her daughter said. "She loved to travel and had a great time with her family. She was a person who could always make the most out of everything she did.
"She had a great personality," her daughter said. "She was happy. She was always considerate of others. She enjoyed being with people. She was just a sweet person."
Her husband died in 1985.
Surviving are her daughters, Barbara Brillhart and Pamela Sullivan; sisters, Violet Cousino and Marie Meier; seven grandchildren, and 13 great-grandchildren.
Visitation will be from noon until 9 p.m. today in the Hoeflinger-Bolander Funeral Home, Oregon, where there will be a recitation of the Rosary at 7 tonight. Funeral services will be at 11 a.m. tomorrow in St. Ignatius Church, Oregon, where the body will be after 10 a.m.
The family suggests tributes to Our Lady of Toledo Shrine or Hospice of Northwest Ohio.


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We meet on the fourth Saturday of the month at the BSFS clubhouse at 6:30 p.m., before the BSFS Social Meeting, to discuss and critique a book of choice.
We will discuss Eric Flint's 1632 on Saturday, February 25, at 6:30 p.m.
Feel free to bring your copy of the book for the discussion.
For more details contact bookdiscuss at bsfs dot org
E-mail addresses have been obfuscated to foil sp*mmer mining, so replace "at" with "@" and "dot" with "." before sending.


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Track List
Album Notes
Going scattershot pays dividends on Into the Sun, the very varied 2015 album from Bassnectar and one of most satisfying releases from the heavy electro producer to date. It's especially satisfying when wearing headphones, as interludes and slowly developing tracks dot the album with moments that aren't so dancefloory, although aggressive and bass-heavy highlights like "The Mystery Spot" and the ridiculously fun "Blow" (it sounds like Cookie Monster singing a trap song) could certainly rip the speakers at high volume. Like previous releases, the album is divided between Bassnectar productions and remix work for other artists, but what's new this time out are the "2015 Remixes," with old Bassnectar cuts like "Breathing" getting interesting updates. Try one of his tight and lean EPs for a taster, then come back for a full-length EDM ride worth taking. ~ David Jeffries


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Iputa (이쁘다) means "pretty" in Korean, named by our Korean founder, June Jeon.
Since 2002, Iputa Nails has been painting pretty nails all around the heart of Singapore. We believe in pampering ladies through providing a variety of beauty services, specializing in gel nails, 2D and 3D customized nail art, as well as spa waxing & facial!
All you've got to do is sit back, relax and let our group of talented and creative nail artists do the job! We don't like to brag, so come on down and feel free to tell us your verdict.
Call us, find us, like us, follow us and get pampered!
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***View our service menus (Far East & Tanglin Mall).
***Call us via our app to make your appointment with any of our 2 outlets.
Supported Devices:
- iPad
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- iPod Touch


text:
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Pornstar Name:
so hot
This is a great video. This guy is one of the luckiest guys in the world. Asian girls are the best lovers and he got 5 at one time and I think he satisfied all of them.
This is truly impressive! What did HE have for breakfast!?! This is top-sport, no less. Absolutely brilliant, worth watching from beginning till end. Especially when he fucks the girl in the bondage-type garment, I love the way her tits bounce. I will watch this again. And again!
I've never seen anything like this. I want to know the backstory. FIVE fucking chicks. I can't believe it.
Guy was hot, women seemed fun. Great vid!
Ahh luckyyyyy assholedream come true for himoonly if pusssies would be shaved it would have Breen bettrr
Jadore cest tro bon oh oui jadore ca
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Sixteen Textures/Sixty Days: The Swallow
So, I got a blow job from a dude today.
With that sentence starts a fun and drunken week of St. Patrick's Day and SXSW activities. To start this week's Fleshlight reviews, I thought I would cross brand lines and give Fleshjack's Swallow texture a try. What happened behind closed doors was nothing short of amazing.
How good was it? Am I still straight? Find out on this episode of Sixteen in Sixty: The Swallow.
To keep experiences as accurate and pure as possible, I will continue to use the same ground rules I set forth on my Forbidden Review. I will also stress the not imagining part as I have no interest in getting a blow job from a dude.
Today offered a world of firsts for me. Not only was the Swallow a texture I have never tried, but it was also the first Fleshjack product I have ever tried. Besides my deep infatuation with Morrissey and his amazing hair, I am as straight as a board. Secure with my sexuality, the look of the Swallow texture was too much to ignore. Since I would be focusing on pure feeling, there was no need for me to picture Jimmy Visconti sucking my dick. Thank god.
If you have taken a look at the Swallow texture, you are sure to notice just how appealing it is. It starts off with a couple of bumps, followed by a series of ribs, another round of larger bumps, and finishes off with a tight canal. Looking at it, you can really see just how much it emulates a mouth inside, from the soft brushing of teeth all the way to the feeling of a deep throating.
It's time to enter this dude's mouth.
As soon as I entered the Swallow, I knew that this texture was going to in my top 5. When you stroke this Fleshjack on your cock, you feel each and every bit of the texture. The part that makes me most feel like this is a real blowjob are those front of the texture bumps that sort of emulate the slight 'run ins' with teeth you have when getting a blow job.
While those slight bumps give you that realistic feeling, the ribs inside really emulate the slippery yet ridged feeling of a tongue. That feeling going up and down your cock is extremely legit. What makes it even better is when your head bounces through those back larger bumps, simulating what it is like to go deep throat.
As things started to heat up to climax, I could really feel each and every part of this Fleshjack sleeve. Absolutely no part of this texture disappears while in FLight. Because of this, you are sure to have an explosive and intense cum. What I felt cannot really be put into words. I think Jimmy Visconti gave me the best blow job I have ever had in my life. Sorry ladies, but that Swallow texture is something else.
Final Conclusions:
This texture may very well be one of the top two I have ever tried. From beginning to end, this texture is a three ring circus of penis stimulating hi-jinx. We must bring this texture to the Fleshlight line.
My Current Texture Rating:
I'm so sorry Lupe and Jenna, but Jimmy's Swallow Textured mouth is the best thing I have ever felt from a Fleshlight. We have a new number one. I am still straight, however.
Feel what I felt with the Swallow!
Top 5 Rankings:
1. Fleshjack Swallow
2. Lupe Fuentes Mini Lotus
3. Jenna Haze Forbidden
4. Ultra Tight
5. Super Ribbed
Click Here To Read All Past Reviews