text:
|Publication number
|Publication type
|Application number
|Publication date
|Oct 26, 1999
|Filing date
|Jul 24, 1997
|Priority date
|Aug 5, 1996
|Fee status
|Also published as
|Publication number
|Dieter Margotte, Christian Wamprecht, Josef Pedain, Hartwig Hocker, Volker Rohde
|Original Assignee
|Bayer Aktiengesellschaft
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (10), Referenced by (7), Classifications (7), Legal Events (6)
|External Links: USPTO, USPTO Assignment, Espacenet
1. Field of the Invention
The present invention relates to a process for producing polyacrylates having a low content of residual acrylate monomers.
2. Description of the Prior Art
The radically-induced polymerization of α,β-unsaturated monomers and other monomers which are capable of undergoing radically-induced polymerization is well known. Recent patent applications are mainly concerned with special production processes or special monomer compositions that can be used to obtain defined properties. For example, polymerization processes for producing polyacrylates, which are characterized by significantly improved physical drying properties, are described in EP-A 528,304 and in EP-A 625,529.
Many patent applications describe the production of polyacrylates containing functional groups. For example, EP-A 630,923 describes polyacrylates containing OH groups, which can be combined with polyisocyanates and which result in crosslinked films.
During the radically-induced polymerization of acrylate monomers with peroxide initiators in solution, a feature which cannot be avoided is that a certain portion of the acrylate monomers is not polymerized and remains in the reaction solution. The resulting content of residual monomers varies between 0.5 and 2% by weight.
More stringent environmental standards require that the polyacrylates, which are offered for use in two-component polyurethane coating compositions (PUR) lacquers, have low monomer contents such that during the production of films, substances are not released into the environment which are either toxic or involve pollution of the environment.
An object of the present invention is to develop a process for producing polyacrylates which enables the content of residual acrylate monomers to be reduced to <0.1%, for example.
DD-A 150,212 describes acrylate-maleic anhydride copolymers for use in the production of films, in which the residual maleic acid content is considerably reduced by vinyl ethers or styrene, for example. In DD-A 264,004, the residual monomer content in styrene/acrylonitrile copolymers and in graft polymers on a butadiene rubber is also significantly reduced by the addition of vinyl esters of organic carboxylic acids, such as vinyl acetate or vinyl butyrate.
A disadvantage of both these processes is that after this subsequent treatment the polyacrylate solution contains, instead of the initial monomers, the monomers (vinyl ethers and vinyl acetate) which were added to reduce the initial monomer. Due to their vapor pressure, these added monomers are released to the environment during cure.
Another prior art process is directed to subsequently activating the polymerization batch with peroxide after the completion of polymerization and then of continuing to maintain it at the polymerization temperature for a period time. The monomer content can also be reduced if the polymer solution is distilled after production of the polyacrylate is complete. The residual monomer contents are only reduced to about 0.4% by weight with both of these prior art processes.
Surprisingly, it has now been found that the content of acrylate monomer can be lowered to <0.1% by weight if the reaction solution is mixed at the end of the polymerization with a monomer having a low vapor pressure and a peroxide initiator and subsequently polymerized.
The present invention relates to a process for producing a polyacrylate resin having a residual acrylate monomer content of <0.1% by weight, based on resin solids, by preparing an initial polyacrylate resin and subsequently polymerizing this initial polyacrylate resin in the presence of a monomer having a low vapor pressure and a peroxide initiator to reduce the monomer content.
In the process according to the present invention the low vapor pressure monomer is preferably used in an amount of 0.5 to 3, preferably 1 to 2% by weight and the peroxide initiator is used in an amount of 0.5 to 3, preferably 1 to 2% by weight, wherein the percentages are based on the polyacrylate polyol starting material. The polymerization reaction is preferably conducted for 1 to 3, preferably 1 to 2 hours, at a temperature of 100 to 200� C., preferably 100 to 160� C. Maleic anhydride is the preferred low vapor pressure monomer.
The products according to the present invention do not release irritant or polluting substances to the environment, even after curing with polyisocyanates.
Preferably, the polyacrylate resins to be treated according to the invention have an average molecular weight (number average), as determined by gel permeation chromatography, of 1000 to 40,000, particularly 2002 to 30,000. The weight average molecular weights are preferably between 2000 and 80,000, particularly between 4000 and 60,000. The molecular weights of the polyacrylates are determined by the methods described by Z. Grabisic, P. Rempp and H. Benoit in J. Polymer Sc., Part B, Polym. Lett. 5 (1967), page 753.
The polyacrylates according to the present invention are preferably synthesized from the following monomers:
0 to 50, preferably 2.5 to 40% by weight of monomers A),
30 to 90, preferably 40.5 to 80% by weight of monomers 13),
0 to 50, preferably 0 to 30% by weight of monomers C),
0 to 5, preferably 0 to 3% by weight of monomers D), and
0 to 50, preferably 0 to 30% by weight of monomers E).
The group A) monomers contain hydroxyl groups, such as hydroxyalkyl esters of α,β-unsaturated carboxylic acids, preferably acrylic acid or methacrylic acid, which contain 2 to 12, preferably 2 to 6 carbon atoms in the hydroxyalkyl radical. Examples include 2-hydroxyethyl acrylate, isomeric hydroxypropyl acrylates, particularly those obtained by the addition of propylene oxide to acrylic acid, isomeric hydroxybutyl acrylates, hydroxypentyl acrylates, hydroxyhexyl acrylates and the corresponding methacrylates. Preferred monomers A) are 2-hydroxyethyl (meth)acrylate and/or the isomeric hydroxypropyl (meth)acrylates.
The hydroxyalkyl esters may contain both primary or secondary hydroxyl groups. Monomers A) are used in amounts such that the resulting acrylate resins have a hydroxyl group content of 0 to 7.3, preferably 0.3 to 5.8% by weight, based on resin solids.
Methyl methacrylate is used as monomer B) and styrene is used as optional monomer C). Optional monomers D) are selected from olefinically unsaturated carboxylic acids, such as acrylic acid, methacrylic acid, itaconic acid, crotonic acid and/or semi-esters of maleic or fumaric acid. Acrylic acid and methacrylic acid are preferred.
Optional monomers E) are selected from olefinically unsaturated monomers other than monomers A) to D). Examples include (cyclo)alkyl esters of acrylic or methacrylic acid containing 1 to 18, preferably 1 to 10, carbon atoms in their alkyl or cycloalkyl radicals, such as methyl, ethyl, n-propyl, n-butyl, isopropyl, isobutyl, t-butyl, isomeric pentyl, hexyl, octyl, dodecyl, hexadecyl, octadecyl, 3,5,5-trimethylcyclohexyl, isobornyl and/or cyclohexyl radicals. Also suitable are acrylonitrile, ethyl vinyl ether, ethacrylonitrile, vinyl acetate, vinyl chloride and vinyltoluene, and other anhydride-functional, unsaturated monomers such as itaconic anhydride or maleic anhydride. Mixtures of these monomers may also be used.
The copolymerization reaction is preferably conducted in organic solution in the presence of known solvents. Examples include toluene, xylene, n-butyl acetate, ethyl acetate, ethyl glycol acetate, isomeric pentyl acetates, hexyl acetates, methoxypropyl acetates, tetrahydrofuran, dioxane, acetone, methyl ethyl ketone and methyl isobutyl ketone. Also suitable are mixtures of higher-boiling aromatic compounds, such as Solvent Naphtha solvents, homologs of benzene, the Solvesso solvents, the Shellsol solvents; and also high-boiling, aliphatic and cycloaliphatic hydrocarbons, such as white spirit, mineral turpentine, the Isopar solvents, the Nappar solvents, tetralin and decalin. Mixtures of solvents may also be used.
Preferred solvents are n-butyl acetate, methoxypropyl acetate and xylene, as well as mixtures of these solvents. During the polymerization reaction, the solvents are generally used in amounts of 30 to 70% by weight, based on the weight of the reaction mixture. Depending upon the peroxide used, the polymerization temperature is generally 90 to 200� C., preferably 100 to 160� C.
Suitable initiators are preferably those having a half-life between 0.5 minutes and 2 hours at the reaction temperature. Examples include dilauryl peroxide, tert.-butylperoxy-2-ethylhexanoate, tert-butylperoxy-diethyl acetate, dibenzoyl peroxide, tert.-butylperoxy isobutyrate, 1,1-di-tert.-butylperoxy-3,3,5-trimethylcyclohexane, 1,1-di-tert.-butylperoxycyclohexane, tert.-butylperoxy-3,3,5-trimethyl hexanoate, tert.-butylperoxyisopropyl carbonate, di-tert.-butyl peroxide, 2,2-di-tert.-butylperoxybutane and tert.-butylperoxystearyl carbonate.
The initiators are preferably used in an amount of 0.5 to 5, preferably 1 to 4% by weight, based on the weight of monomers A) to E). These percentages are also based on solvent-free initiators.
The polyacrylate resins are most preferably produced using n-butyl acetate as the solvent and tert.-butylperoxy-2-ethylhexanoate as the initiator at temperatures of 100 to 130� C. and di-tert.-butyl peroxide as the initiators at temperatures of 130 to 200� C. The polyacrylates which are produced in this manner have a residual monomer content of about 0.5 to 3% by weight.
The residual monomer content can be reduced to <0.1% by weight by a subsequent radically-induced polymerization in the presence of 0.5 to 2% by weight of maleic anhydride and 0.5 to 2% by weight of peroxide.
After the radically-induced polymerization is complete, the subsequent polymerization is carried out directly in the presence of maleic anhydride.
The polyacrylates produced by the process according to the invention can be used without additional crosslinking agents (polyisocyanates) for industrial applications which are not high-duty applications. Polyacrylates which are free from OH groups are preferably used for applications of this type.
For industrial applications requiring higher levels of solvent and chemical resistance, for example, OH-functional polyacrylates are used in combination with known lacquer polyisocyanates as crosslinkers. The lacquer polyisocyanates are those which preferably contain biuret, urethane, allophanate, uretdione and/or isocyanurate groups have an average NCO functionality greater than 2, preferably 2.5 to 6. These polyisocyanates may contain aromatically, cycloaliphatically and/or aliphatically bound isocyanate groups. Polyisocyanates containing aliphatically and/or cycloaliphatically bound isocyanate groups are preferred for light-fast coatings.
The lacquer polyisocyanates are produced by the known modification of monomeric diisocyanates to form biuret, urethane, allophanate, uretdione and/or isocyanurate. Any excess monomer isocyanate, which may be present after the modification reaction, is removed in known manner, preferably by distillation, such that the lacquer polyisocyanates contain at most 0.7, preferably at most 0.5% by weight of monomeric diisocyanate. The lacquer polyisocyanates preferably have an NCO content, based on solids, of 10 to 30% by weight, preferably 15 to 25% by weight.
The two-component PUR coating compositions may be used for the both refinish and factory coating of automobiles and for general industrial coatings, preferably for coating wood and furniture.
The invention is further illustrated but is not intended to be limited by the following examples in which all parts and percentages are by weight unless otherwise specified.
Polyacrylate A
A polyacrylate produced by the polymerization of methyl methacrylate (MMA), 2-ethylhexyl acrylate (2-EHA) and hydroxyethyl methacrylate (HEMA) and present as a 40% solution in butyl acetate. Tert.-butylperoxy-2-ethylhexanoate was used as the initiator. The polymerization temperature was 110� C. After polymerization, the solids content was 39.6% and the solution viscosity was 2450 mPa.s/23� C. The OH content was 0.48% on a solvent-free basis.
Polyacrylate B
A polyacrylate produced by the polymerization of MMA, butyl acrylate (BA), 2-EHA and hydroxypropyl methacrylate (HPMA) and present as a 50% solution in butyl acetate. Di-tert.-butyl peroxide was used as the initiator. The polymerization temperature was 150� C. After polymerization, the solids content was 49.8% and the solution viscosity was 4120 mPa.s/23� C. The OH content was 1.0% on a solvent-free basis.
Determination of residual monomers by head-space chromatography
The content of residual monomers was determined by head-space analysis. In this procedure, samples were diluted with a high-boiling solvent and introduced into an ampoule, which was accessible via a septum, and then sealed. After sealing the sample was heated to 100� C. until an equilibrium had been established between the liquid and gaseous phases. A defined amount of sample from the gas space was then injected into the capillary column.
The monomer contents of polyacrylates A and B, which were determined by the head-space gas chromatography method, are set forth in the following table.
______________________________________Initial monomer contents of polyacrylates A) and B) in %, based onsolids MMA 2-EHA Butyl acrylate HEMA HPMA______________________________________Polyacrylate A 0.98 0.25 -- <0.1 --(%)Polyacrylate B 1.05 0.21 0.19 -- <0.1(%)______________________________________
A total value of about 1.2 to 1.4% by weight of residual acrylate monomer was determined by head-space GC after the production of the polyacrylates A) and B).
Examples 1 to 6 according to the invention
1000 g of polyacrylates A and B were placed in a vessel, mixed with maleic anhydride and a peroxide initiator and then heated for 2 hours. Thereafter, the residual monomer content was determined by head-space analysis.
______________________________________ Example 1 2 3 4 5 6______________________________________Polyacrylate A, g 1000 1000 1000 -- -- --Polyacrylate B, g -- -- -- 1000 1000 1000Maleic anhydride, g 10 20 5 10 20 5Tert.-butyl-peroxy-2- 10 20 15 -- -- --ethylexanoate*, gDi-tert.-butyl peroxide, g -- -- -- 5 10 7.5Reaction temperature, 110 110 110 150 150 150�C.______________________________________ *present as a 50% solution in butyl acetate, amount based on solution
Residual monomer contents for Examples 1 to 6 (data in g)
______________________________________ Example 1 2 3 4 5 6______________________________________MMA, g <0.1 <0.1 0.16 <0.1 0.1 0.122-EHA, g <0.1 <0.1 <0.1 <0.1 <0.1 <0.1BA, g -- -- -- 0.12 <0.1 0.11HEMA, g <0.1 <0.1 <0.1 -- -- --HPMA, g -- -- -- <0.1 <0.1 <0.1______________________________________
Coatings were prepared by mixing polyacrylates A) and B), both before and after the treatment according to the present invention, at an NCO:OH equivalent ratio of 1:1 with a lacquer polyisocyanate which contained isocyanurate groups, was prepared from hexamethylene diisocyanate and had an NCO content of 19.4% by weight (Desmodur N 3390). The results demonstrated that the treatment according to the invention did not affect the application properties of the coatings.
Although the invention has been described in detail in the foregoing for the purpose of illustration, it is to be understood that such detail is solely for that purpose and that variations can be made therein by those skilled in the art without departing from the spirit and scope of the invention except as it may be limited by the claims.
|Cited Patent
|Filing date
|Publication date
|Apr 21, 1972
|Aug 27, 1974
|Knechtges D
|Process for reducing acrylic ester monomer residues in acrylate latices
|Dec 30, 1982
|Oct 9, 1984
|Mobil Oil Corporation
|Aqueous coatings comprising ionic polymer ester and diluent polymer with reduced monomer residue and method of preparation
|Jul 20, 1995
|Jun 16, 1998
|Agomer Gesellschaft Mit Beschrankter Haftung
|Method of producing non-vitrified processing aid low in residual monomers for thermoplastic polymers
|Aug 17, 1992
|Feb 21, 1993
|Martin Brahm
|Binder mixtures for two-component polyurethane coating compositions
|May 13, 1994
|Nov 19, 1994
|Dieter Margotte
|Rapidly, physically drying binder mixtures and their use for coating wood substrates
|Jun 17, 1994
|Dec 24, 1994
|Klaus Bederke
|Coating agents and their use, in particular in the production of transparent and pigmented top coatings
|Title not available
|Title not available
|Nov 6, 1980
|Aug 26, 1981
|R�hm Gmbh
|Process for preparing polymer dispersions with low residual acrylonitrile content, and dispersions so prepared
|Jun 9, 1993
|Dec 15, 1993
|Nippon Shokubai Co., Ltd.
|Method for production of absorbent resin and absorbent
|Citing Patent
|Filing date
|Publication date
|Nov 30, 1998
|Oct 31, 2000
|Flint Ink Corporation
|Printing inks
|Nov 30, 1998
|Oct 28, 2003
|Flint Ink Corporation
|Printing inks
|Nov 29, 1999
|Nov 11, 2003
|Flint Ink Corporation
|Lithographic printing method
|Apr 29, 2002
|Jan 6, 2004
|Eastman Chemical Company
|Process for reducing residual free radical polymerizable monomer content of polymers
|Jan 21, 2002
|Oct 19, 2004
|Flint Ink Corporation
|Lithographic printing inks
|Nov 20, 2002
|Jan 11, 2005
|Flint Ink Corporation
|Lithographic printing method using a single fluid ink
|Jan 21, 2002
|Sep 19, 2002
|Latunski Mark D.
|Lithographic printing inks
|U.S. Classification
|528/486, 528/491
|International Classification
|Cooperative Classification
|European Classification
|Jul 24, 1997
Owner name: BAYER AKTIENGESELLSCHAFT, GERMANY
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:MARGOTTE, DIETER;WAMPRECHT, CHRISTIAN;PEDAIN, JOSEF;AND OTHERS;REEL/FRAME:008671/0678;SIGNING DATES FROM 19970605 TO 19970624
|Apr 30, 2003
|Fee payment
Year of fee payment: 4
|Apr 30, 2003
|Surcharge for late payment
|May 16, 2007
|Maintenance fee reminder mailed
|Oct 26, 2007
|Lapse for failure to pay maintenance fees
|Dec 18, 2007
|Expired due to failure to pay maintenance fee
Effective date: 20071026


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Two districts share their experiences of choosing a learning management system that does a lot more than help teachers post assignments.
AspirEDU and Instructure have partnered to integrate the former's student retention analytics tools with the latter's Canvas learning management system for joint customers.
Blackboard and Pearson have revamped the integration of Blackboard's teaching and learning solutions and Pearson PowerSchool student information system (SIS) in an effort to improve data management functionality.
The conference will feature Charlie Reisinger, IT director at Penn Manor School District, which, in 2013, launched Pennsylvania's largest high school 1-to-1 program using Linux and open source software.
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Moodle has unveiled version 2.9 of the open source learning platform, featuring a navigation and user interface redesign focused on ease of use for students, educators and administrators.
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The IT landscape has evolved. Critical infrastructure, applications, and data are moving to the cloud, leveraging either public or private cloud infrastructure. Salesforce.com, Box, G Suite, Office 365, and other software-as-a-service (SaaS) apps, whether sanctioned by IT or not, are commonplace in companies of all sizes and industries — even the most highly regulated ones. Not only does this raise questions about how to protect where sensitive data is going and how it's being used, but it also changes how employees get their work done.
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Mirela Pastrav
Mai multe idei de la Mirela
Sheep and red door
Art Nouveau •~• fashion, 1913... she looks like she belongs in a Maxfield Parrish painting!
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Gatti a Smirne
Ancient Arched Door, Italy photo via anna by MyLittleCornerOfTheWorld
England, Essex, Maldon ~ Sunrise over the Blackwater estuary.
Ivy in autumn colors and pretty door by Whoopi
I love these colors! | Click for more color combinations and color palettes inspired by the Pantone Fall 2017 Color Trends, plus other coloring inspiration at http://sarahrenaeclark.com | Colour palettes, colour schemes, color therapy, mood board, color hue
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AtomCraft Unleashes Creativity
Audio middleware was borne out of a need to free sound artists from programmer dependencies and allow for rich audioRead more
Audio middleware was borne out of a need to free sound artists from programmer dependencies and allow for rich audioRead more
This post describes the implementation of combo sound effects with ADX2 using the Combo Sequential Cue type and without requiringRead more
The 2016 edition of GameSoundCon (http://www.gamesoundcon.com/), the premier game music and sound design conference, just happened in Los Angeles. GameSoundConRead more
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In this week's tutorials, we will first learn how to use the DSP Busses in AtomCraft and how to applyRead more
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The tutorials of this week talk about three different ways the game can control the sound of the Cues designedRead more
This week's tutorial videos are sure to be popular among sound designers! Our first video is about the Cue types.Read more


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Technology Front
Ultra-Low Capacitance TVS Diode Array Delivers Clamping Performance and ESD ProtectionPublished: Dec 09,2014
891 Read
Littelfuse, Inc., has introduced the SP3022 Series Low Capacitance ESD Protection TVS Diode Arrays (SPA Diodes). These robust 0.35pF, 20kV bidirectional (back-to-back) discrete TVS diodes can safely absorb repetitive ESD strikes over the maximum level specified in the IEC61000-4-2 international standard without performance degradation.
Littelfuse Schottky Barrier Rectifiers Combine Ultra-Low Forward Voltage Drop, High Current Handling
Littelfuse introduced a series of Schottky Barrier Rectifiers designed for conventional switching diodes in commercial, industrial and automotive applications...
Littelfuse TVS Diode Arrays with High Surge Tolerance Protect DC Powerlines for PoweredUSB Interface
Littelfuse announced a series of TVS Diode Arrays (SPA Diodes) optimized to protect DC powerlines for PoweredUSB interfaces from damaging electrostatic discharges (ESDs)...
The SP3022 Series' back-to-back configuration provides symmetrical ESD protection for data lines when AC signals are present. Their ultra-low loading capacitance (just 0.35pF) makes them ideal for protecting high-speed data lines, such as all released versions of HDMI and USB, DisplayPort, V-by-One and eSATA. They're also well suited for use in consumer electronics like set-top boxes, game consoles, smartphones, ultrabooks, notebooks, tablets and eReaders.
-Ultra-low capacitance of 0.35pF minimizes signal degradation or attenuation for high-speed data, giving engineers more signal margin in their design; ideal for protecting high-speed data lines, such as HDMI 2.0, USB 3.0, USB 3.1 and eSATA.
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text:
by Pamela
(Windsor, ON Canada)
Rose Hall Great House
Contest Entry #032 - I am coming home to Jamaica
It all began in 1990 not too long after a furious visit from hurricane Gilbert to Jamaica.
I just started working at a travel agency and I so wanted to visit this beautiful country. So my father and I headed out on our journey.
And since then I have been fortunate to have been to the island 25 times!
From my very first visit I have always felt the presence of my dearly departed mother.
After the many pictures taken not only by a camera but pictures installed in my mind I have found this beautiful country so rich in colors, scents and memories that will always stay close in my heart forever.
I can remember watching a movie filmed in Jamaica starring Woopie Goldberg. Her words could not of said it any better, she said that "God was present" she could feel this aura around her and I truly feel it just the way she had said.
The pictures I have entered are of a visit to Rosehall where the white witch was said to be seen.
I have never agreed with what Annie (white witch of Rosehall) stood for but the history of this amazing place was quite different.
The other pictures that I took were of two men walking along the beach and playing their instruments. I do hope that you will enjoy my submissions.
Thank you for sharing your beautiful country.
God Bless each and everyone of you.
Pamela Auffret
See Also: Jamaican Vacation Stories
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How do you perceive yourself as a negotiator
Discuss the below in 200 words:
Consider the last time you had to negotiate something. How do you perceive yourself as a negotiator? What cognitive mistakes have you made in the past and how could you have avoided these mistakes?
Assume that you are part of a mediation team that has been brought in to help overcome an impasse between negotiators who are deliberating the use of embryonic stem cells for a research project. The decision makers are polarized along ethical and religious lines. Since this is a potentially emotional issue, what would you do in order to break this impasse? How could the fixed pie concept come into play in this situation?
We have each had to negotiate during the process of purchasing a home or automobile. Analyze the last major purchase that you were involved with and discuss that purchase in terms of the decision-analytic approach. What was your BATNA and how did that come into play?
Recently, General Motors and the United Auto Workers had to sit down and negotiate a change in the labor agreement in order to keep the company from going bankrupt. Consider what might have gone on during these negotiations and discuss how framing might have been used, and what issues might have been discussed, in order to reach an acceptable agreement.
Eventually, the United States and Iran will have to sit down and negotiate the use of nuclear power. Discuss the issues that could be involved in such a negotiation. What cognitive mistakes might be made by the negotiators in this case? How could these mistakes be overcome in order to reach an acceptable agreement?
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- Recruiter
- Cambridge Centre for Sixth-form Studies
- Location
- Cambridge, Cambridgeshire
- Salary
- £14,625 (FTE) pro-rata
- Posted
- 11 Jul 2017
- Expires
- 08 Aug 2017
- Sector
- Cleaning
- Contract Type
- Permanent
- Hours
- Part Time
Cambridge Centre for Sixth-form Studies are looking for a part-time cleaner to work term time between the hours of 8.30am – 1.30pm Mon-Fri (25 hours per week) with some additional weekend work outside of term time.
We are looking to recruit an experienced cleaner to further enhance the cleaning standards of our boarding residences.
For an application form please call 01223 716890/07765845030 or visit www.ccss.co.uk. Completed forms should be returned to HR Administrator, CCSS, 4-5 Bene't Street, Cambridge CB2 1EL or emailed to email@example.com.
Please note that applications will be considered as they are received and the College reserves the right to appoint at any time in the process.
CCSS is committed to safeguarding and promoting the welfare of children and young people and expects all employees and those associated with the college to share this commitment.
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2017 State of the Lateral Law Firm Market


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Thursday, December 08th 2016, 01:06:03 AM Published at Dagen Brown, Simple Kitchen with the Pull down Kitchen Faucet Kitchen. Pull down kitchen faucet is available for variant design, it will be perfect idea for you while it simple thing. There are two type of the faucet for the kitchen pull down, they are the deck mount and wall-mount faucet. Both of type is available at mostly market place. The deck mount is applied to the countertop and the corner of the sink area while the wall faucets apply to the wall and you can hang them over the sink. The number of holes on the sink will determine the installation for the faucet.
Pools Dagen Brown, Wednesday, October 05th 2016, 06:58:58 AM. Gunite swimming pools are famous type of swimming pool. Actually there are some types of swimming pool that you can choose. You can choose swimming pool type based on your need and your budget too. Gunite pool is recommended for all types of homes. There are some reasons why so many people finally choose to make this pool than other type of pool.
Decor Dagen Brown, Sunday, October 02nd 2016, 10:10:20 AM. In some stores you can buy harley davidson home decor. You can choose one that is good for your home. There are so many accessories and decorations that you can buy such as pictures frames. You can buy picture frames and then put it in your living room so all people will know that you love Harley Davidson.
Sofa Dagen Brown, Saturday, October 01st 2016, 05:55:24 AM. The furniture will be the essential point in designing the interior and decorating it. The sofa will also be totally essential. That is why we could not randomly choose it. It should be comfortable enough, stylish, and suitable to your living room. The lazy boy sectional sofas become a good idea because there are a lot of choices of the sectional sofas which might be suitable the most for your living room that is what you are interested in.
Living Room Tedd Birger, Friday, September 30th 2016, 08:25:39 AM. Living room sets IKEA is one kind of living room set that can you choose to apply in your house. You can find a lot of different living room set to apply in your room and make you are get suitable decoration and design. From this one kind of living room set you will get your living room look in different design. You can get classic style and modern design that combine in one design and give you beauty appearance.
Doors Michal Naraya, Sunday, September 25th 2016, 10:06:35 AM. Good design of front doors with glass
Kitchen Arnlaug Adalbaro, Friday, September 23rd 2016, 09:00:07 AM. Galley kitchen can be best choices for you who have only little space in your kitchen. Especially this one kind of kitchen design is design to use in little free space. With using galley design for kitchen you will get your kitchen still in good function although in limited space. You are still can get your kitchen cabinet in good function and good looking with place this one kind of kitchen design.
Windows Tedd Birger, Wednesday, September 21st 2016, 06:35:42 AM. Window treatments for sliding doors are one important thing that you must choose in good design and good function. You can find a lot of different designs that can you apply for your house. With choose right design you will get your sliding door in good decoration and you can get good quality from that. You can find a lot of different design from this one kind window treatment. To get best quality and best decoration, there some of ways that you must give your attention to get best design and quality from your sliding door.
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Lavrov comments on Syrian de-escalation zone agreementRussian Politics & Diplomacy July 24, 20:15
Iraq calls for closer cooperation with RussiaWorld July 24, 19:09
Russia develops laser-guided automatic landing system for dronesMilitary & Defense July 24, 18:22
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MOSCOW, September 5 (Itar-Tass) — The Ministry of Communications and the Federal Migration Service are working on electronic internal passports for Russian citizens.
"We think that technologically we will come to a situation where the country will give up paper passports. It will be a modern ID, a plastic one, with a photograph and certain personal data," Minister of Mass Communications Nikolai Nikiforov said on Wednesday, September 5.
The new passport will contain an electronic chip "which can be used for obtaining electronic public services as a substitute for a large number of other documents such as a driver's license, a health insurance policy and a pensioner's certificate", he added.
Nikiforov believes that the new passport will be like the universal electronic card, which in his opinion, should be issued nationwide by the Federal Migration Service.
The minister is convinced that this should "solve the problem of universal electronic cards at the regional level" since not all regions have enough funding to finance the project.
The electronic card system is intended for providing a wide range of services to the population in electronic form across the country, including public and municipal services, such as social welfare, transport, health care, financial and commercial ones. The universal electronic card is a tool for confirming its holder's right to receive such services and can be used for remote transactions as provided for in Russian laws.
Sberbank, Uralsib, Ak Bars, Center Invest, Bank St. Petersburg, Avtovazbank, Moscow Industrial Bank, and Surgutneftegazbank have already joined the project. Some 60 lending institutions will join the universal electronic card system in Russia by the end of 2012.
The system will provide different electronic services to the population, including social, transportation, medical, financial and commercial ones.
The universal electronic card will become a unified federal standard and will replace all social cards that have been issued in regions up to date and other documents such as mandatory medical and pension insurance cards, student's IDs, travel passes, and bank cards. New universal electronic cards will be issued to all Russian citizens over 154 years of age.
The first universal electronic cards were to be issued in four or probably six Russian regions in August.
At the initial stage, 10,000 cards will be issued in Tatarstan, Bashkiria, Komi, St. Petersburg, Astrakhan, and Krasnodar. Moscow, where the authorities plan to start issuing the card in 2013, is not on the list.


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B&B Siena in Centro - Albergo Diffuso, Siena
- Free buffet breakfast
Main amenities
- 9 guestrooms
- Daily housekeeping
- Luggage storage
- Limited hour front desk
- Tour/ticket assistance
- Free buffet breakfast
Feel at home
- Rollaway/extra beds (surcharge)
- Private bathroom
- Daily housekeeping
- Hair dryer
- Blackout drapes/curtains
- Digital TV service
What's around
- In Siena City Centre
- Siena Cathedral (0.1 mi / 0.2 km)
- Palazzo Pubblico (0.2 mi / 0.4 km)
- Piazza del Campo (0.2 mi / 0.4 km)
- Civic Museum (0.2 mi / 0.4 km)
- Stadio Artemio Franchi (0.7 mi / 1.1 km)
We had a brief overnight stay here and enjoyed our time. The location was perfect, the…
There is no A/C so the window was open. The wine bar across the street was too noisy into…
B&B Siena in Centro - Albergo Diffuso, Siena
Hotel Info: 866-539-8117from $48
- Superior Triple Room
- Comfort Single Room
- Double Room
- Comfort Double Room
- Standard Triple Room
- Superior Double Room
- Triple Room
- Standard Double Room
- Standard Double Room
- Standard Triple Room
More great choices
At a glance
Key facts
Hotel size
- This hotel has 9 rooms
- Check-in time 2:30 PM-8:00 PM
- Check-out time is 10:30 AM
- Express check-in/out
Required at check in
- Credit card or cash deposit required
- Government-issued photo ID required
Travelling with others
- Children (3 years old and younger) stay free when occupying the parent or guardian's room, using existing bedding
- Pets allowed *
- No parking
Nearby One Star Siena hotels
In the hotel
- Free buffet breakfast daily
- Bicycle rentals nearby
- Mountain biking nearby
- Front desk (limited hours)
- Tours/ticket assistance
- Luggage storage
- Number of buildings/towers - 3
In the room
- Iron/ironing board (on request)
- Down comforter
- Blackout drapes/curtains
- Individually decorated
- Private bathroom
- Shower only
- Bidet
- Hair dryer
- Digital TV channels
- Desk
- Refrigerator (on request)
- Microwave (on request)
- Daily housekeeping
- In-room safe
Top Siena hotels
Recently reviewed hotels in Siena
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"Great Villa Hotel! Staff is amazing and owners are very actively involved in the day to day operations. Feels just like being at home. Great place to stay when exploring Tuscany>"Jul 22, 2017
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Also popular with travelers from the USA
B&B Siena in Centro - Albergo Diffuso, Siena's small print
Also known as
- Albergo B&B
- Albergo Diffuso Siena
- B&B Centro Albergo Diffuso
- B&B Centro Siena
- B&B Siena in Centro Albergo Diffuso
- Centro Albergo Diffuso
- Centro Siena
- Siena B&B Centro
- Siena in Centro Albergo Diffuso
All guests, including children, must be present at check-in and show their government-issued photo ID card or passport.
Cash transactions at this property cannot exceed EUR 2999.99, due to national regulations. For further details, please contact the property using information in the booking confirmation.
Mandatory fees
A tax is imposed by the city and collected at the property in cash: EUR 2.50 per person, per night, for the first 6 nights. For stays from 1 November to 29 February the tax is reduced to EUR 1.50 per person, per night. This tax does not apply to residents of the city, children under 12 years of age, or disabled persons. Please note that further exemptions may apply. For further details, please contact the property using the information contained in the confirmation received after booking.
Optional extras
Rollaway beds are available for an additional charge
Pets are allowed for an extra charge of EUR 5.00 per pet, per night
We have included all charges provided to us by this hotel. However, charges can vary, for example, based on length of stay or the room you book.
Is the description of this hotel not correct? Tell us


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"Kylie has come and looked after my pets in home a few times now - my pups love her, the house is..."
"Can't thank you and your family enough...especially Max x"
"It was like he never left home"
"Suneet has been a great help with utmost care and concern for Lily. She replies promptly to my..."
"Highly recommended. Alfie has been looked after very well. "
"Perri was awesome with Spencer, lots of walks and clearly he had a great time. There were heaps of ..."
"Repeat booking. This is the second time I've booked with Aaron and Tash. Very friendly couple who..."
"Coco had a fabulous stay with Jackie. Coco adores Jackie & loves to stay with her. Thanks again..."
"So, if you're looking for dog sitters who will completely do everything they can to make your..."
"Diane was absolutely lovely. Took up our last minute request straightaway and catered to our..."
"Wendy was so fabulous- caring and fun and could not have spoiled my dog Rudi anymore. Thanks so..."
"Naresh did an amazing dog with Gus. As a rescue puppy Gus can be very nervous of new situations..."
"I highly recommend Kelly. She was easy to talk to and sent some great photos. Our dog loves staying ..."
"She is a lovely girl with lovely smile, and of course Charlie still looking for her and looks like..."
"Quick communicator"
"Rebecca was great to deal with, sent us messages, photos and videos to let us know Milo had settled ..."
"Raina is a sweet sitter. Loki really enjoyed his stay. I will definitely come to Raina again!"
"Cornelia was very reliable and great with our puppy!!"
"Stephen was excellent at caring for my pup! I think she actually had tonnes of fun at Stephens..."


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PhotoBucket are no longer permitting 3rd party hosting 01/07/17As most of you are now painfully aware, Photobucket (PB) are stopping/have stopped allowing their members to link their accumulated years of photos into forums and the like, which they call 3rd party linking. You can give them a non-refundable $399 a year to allow links, but I doubt that many will be rushing to take them up on that offer. If you've previously paid them for the Pro account, it looks like you've got until your renewal to find another place to host your files, but you too will be subject to this ban unless you fork over a lot of cash. PB seem to be making a concerted move to another type of customer, having been the butt of much displeasure over the years of a constantly worsening user interface, sloth and advertising pop-ups, with the result that they clearly don't give a hoot about the free members anymore. If you don't have web space included in your internet package, you need to start looking for another photo host, but choose carefully, as some may follow suit and ditch their "free" members at some point. The lesson there is keep local backups on your hard drive of everything you upload, so you can walk away if the same thing happens. There's a thread on the subject here, so please use that to curse them, look for solutions or generall grouse about their mental capacity. Not a nice situation for the forum users that hosted all their photos there, and there will now be a host of useless threads that relied heavily on photos from PB, but as there's not much we can do other than petition for a more equitable solution, I suggest we make the best of what we have and move on. One thing is for certain. It won't win them any friends, but they may not care at this point. Mike.
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About cathasatail
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- Birthday 08/01/99
Profile Information
Aldridge, West Midlands
Royal Air Force jets
Recent Profile Visitors
Looks like a good match too! Nice one
cathasatail replied to cathasatail's topic in Work in Progress - AircraftTime to test out the washes: (I don't think they look too bad) (the weathering on the upper surface of the airbrake and at the rear will be toned down a tad. However it doesn't look nearly as orange in real life as it does on the photos- probably because I turned the exposure compensation up by quite a bit to show the interior) *Note the small white "bottle"-of some sort- that is moulded into the plastic As with the airbrake it will be toned down a tad and some wiring will be added to the main gear leg as per references such as: http://www.net-maquettes.com/pictures/handley-page-victor-walkaround/?afg886_page_id=4#afg-886 Spares from old airbrushes are used to provide the specified 25g weight, these are then sandwiched against the fuselage wall with a few drops of superglue and some Blue Tack. Kind regards, Sam
cathasatail started following Hawker Typhoon 1:24
cathasatail replied to cathasatail's topic in Work in Progress - AircraftTime for an update I think! I've been focusing on assembling the wing structure (the spar which Airfix use to hold the two separate wing parts together is a brilliant piece of plastic engineering and provides an incredibly strong construction: I have assembled the intake trunking (the intake "vanes"- i guess you could call them- slot in through the gaps seen just behind the intake opening, a very unique idea!) and I intend to use a smidgen of filler and sand the join flush, this will be followed my a few coats of white and a light amount of weathering. I've also been looking at the nose gear bay and the airbrake structure: a coat of black, followed by Vallejo silver and then a coat of Alclad gloss, all ready for the detail to be painted and a moderate amount of weathering as-per reference photos (some of which can be seen on BM's own walkaround page): Talking of references, here are two of the books I'm using, both from the previously mentioned Andrew Brookes: That's it for now! Kind regards, Sam
Ah.. French blue is also for airbrush use, sorry
cathasatail started following Airfix 1/72 Canberra PR.9
cathasatail replied to falcon's topic in Ready for Inspection - AircraftGorgeous and sleek are the two words which I think describe this; what a lovely clean build! While I'm here: where on Earth did you find this?! I can't seem to find these kits anywhere! Sam
cathasatail started following BA World Blue
Vallejo Model Air "steel blue" could be an option- I haven't 100% checked it as a colour match but to my eye it seems quite close. But if you're looking for something close to the Tamiya x4 blue then Vallejo MA "French blue" is also an option. Hope that helps Sam
cathasatail replied to cathasatail's topic in Work in Progress - AircraftRight, I've been looking through a few references and I have yet to find a single image of the bomb bay (the only photos of said bomb bay being pictures of the HDU unit fitted inside the bomb bay on K.2 Victors. I'm swinging more to the Blue Steel variant still, especially after looking at photos in reference material such as "Handley Page Victor" by Andrew Brookes (-just remembered, isn't that the same Andrew Brookes who when interviewed on a documentary about V-bombers recalled advice given to him if hostilities did break out, something like, "the best advice I was ever given was- keep flying East young man and hope to settle down with a large Mongolian woman. Absolutely no point in doing a 180 and returning home." ?) No idea how I remembered that, last time I saw that was also 2 years ago! Gosh. Regardless, as shown in his book and other references most of the photographs of B.2's depict Blue Steel equipped aircraft, I've only found three images of camo B.2 Victors without Blue Steel and those were being used in the Maritime Radar Reconnaissance role. To whet the appetite, here's a bit of newsreel of camo Blue Steel Victors practicing QRA's in the mid 60's: Kind regards, Sam
cathasatail replied to cathasatail's topic in Work in Progress - AircraftThe meteor will be finished with the kit decals for WH364 A400-wise, it was a nightmare! I had a substantial sink mark in one of the wings- I attempted to mould it using hot water (nope), I attempted to mould it by heating it with a candle (nope!), so I went through a handful of sessions with milliput and then Revell Plasto and that sorted it out. The A400 will be done in RAF markings. I went to the 10th anniversary too, but I didn't go into the Victor or Valiant as the staff started putting up the "beyond this point, you'll be waiting an hour" signs. It's a tempting suggestion and one which would be a great canvas for some moderate weathering. I'm faced with three choices then: -1. Blue steel version with detailed missile and aircraft mounting plate -2. Conventional bombing version with detailed bomb bay and a larger canvas for weathering. With the missile being modeled on a stand -or the third and possibly most controversial option: use the two wing pods I have from the Revell kit and a piece in the spares box that looks remarkably similar to a stowed HDU to convert it to a K.2. In all fairness, I do have an entire set of decals for the Revell K.2 variant in the stash. Mmmm decisions.....
cathasatail replied to cathasatail's topic in Work in Progress - AircraftCorrect, it's the Revell kit and has languished on the corner of despair for a while (I say corner because the rest of the shelf is for active projects that are up to the decaling stage mainly. I can't comment on the union jack or the fin flashes as I haven't added any of either yet! You might also note the Airfix Meteor and Revell A400m on the shelf too- they're in need of some Alclad (the thinners for which tend to flare up some kind of skin condition (possibly eczema) so I need to get some disposable gloves before I continue with those. As for the weapons, I have kept the Blue Danube from the Valiant kit (which is a kit that was great- until I tried spraying it with a rattle can of white.... big mistake... let's just say that I salvaged the nose and my intention is to model it as a preserved cockpit section). (I still hate myself for having messed that one up so catastrophically) Anyway, I'll put my violin back in its case.... I recall now that I actually did a fair bit of research into the Blue Steel missile (so much so that I remember going to the Coventry archives to have a look at some photographs of test articles and operational missiles both on the aircraft and in their storage "hangars"- not what you might expect from the average 16 year old, perhaps). Here are a few reference pictures taken during that period of research, but not from Coventry (Edit: it was from 2 years ago at Cosford on the Armed Forces Day when XH558 did a series of flypasts) Edit: And one of '558 for everyone else who wants to join me in a collective round of violin playing (Co-incidence or what, this file is "IMG_8558_JPG" !) Kind regards, Sam
cathasatail started following A weathered Airfix Victor B.2
cathasatail posted a topic in Work in Progress - AircraftHi guys, As a few of you might know, I did a 1:72 Airfix Vulcan with a full interior a while ago. It was an "interesting" build filled with research and frustration as I delved into my first experience with photo-etch, rescribing and resin; but it produced a half-decent model of a Vulcan B.2: So, with a new-tooled Victor B.2 in my stash (as of yesterday ) I embarked upon this build in the hope that it will be a less stressful build than the Vulcan and with the hope that I can utilise everything I have learnt since that build. The Kit As stated previously this a new-tool kit from Airfix in the £50-60 range- there has been much discussion of the cost of this kit but I would state (in my opinion) that for the amount of plastic you're getting and the level of detail, it is entirely worth it. My plans for the build: -Construct the kit in either a conventional bombing or Blue Steel role (I haven't decided yet, what do you guys think?) -The camo paint scheme will be used (I can never get a clear dust-free white paint job on any large kit) -EDIT: This will be a flaps down, crew door open, gear down, airbrake open model -Weather the model moderately with some new AK interactive washes that I would like to test: The Build And so it begins! I started work on the cockpit first and despite the high possibility that barely any of this would be seen, I would like to detail every part of this kit as much as possible That's it for now, thanks for having a look! Kind regards, Sam
cathasatail replied to cathasatail's topic in Work in Progress - AircraftA few more decals to add but we're almost done: I used a bit of filler and plasticard to make the front windscreen taper to a slight point (this photo isn't the best to show that off) and I used pieces of card to make the windscreen frame on the "droop snoot". The next update should be an RFI if all goes well! In the meantime I had a go at making some Dutch appelflappen (apple turnovers, essentially): Kind regards, Sam
cathasatail started following What's flying over your house? Thread #2
cathasatail replied to HP42's topic in Real AviationAfter 3 years of going to events when the Lancaster was supposed to be flying, it flew over my house 5 minutes ago. Too low and fast for any photos but gosh, I finally saw her (for all of 2 seconds)
cathasatail replied to Fozzy's topic in Work in Progress - AircraftWow. Words are never going to be enough to describe this exceptionally wonderful masterpiece... Stunning work sir!
cathasatail started following 1/48 Airfix P-40B Warhawk - 112 squadron
cathasatail replied to cathasatail's topic in Work in Progress - AircraftInkjet
cathasatail replied to cathasatail's topic in Work in Progress - AircraftAnd here we are; the decals have been printed (along with others) and they do look jolly good (if I do say so myself).... (Decals on white backing paper) (Decals on clear backing paper) (Wow the lighting is awful in that last picture, but I'll keep it in anyway ) The decals that I've been working on include: this A320, a 1:144 BA 747, a 1:144 Tornado GR4 in Dambusters anniversary markings and a 1:72 Lancaster Sugar's Blues. And after an initial test on a scrap bit of decal paper I can confirm that the decals slide off effortlessly- they also slide a lot when they're positioned on any surface, so a clear coat will be in order after they've been applied one-by-one. Sam


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Beautiful campground! We had a wonderful time. The staff was friendly and helpful. We enjoyed the activities. We were surprised that we needed to purchase a grate to cook over the fire. We are already planning our trip for next year!
- Official Description (provided by the hotel):
- Located in the heart of the Endless Mountains of Northeast Pennsylvania, Pine Cradle Lake Family Campground truly is a hidden treasure. Choose from one of our 200 camp sites situated on 83 acres designed for tents, RVs, motor homes and everything in between. We also offer a variety of Cabin and Cottage rentals for those who would prefer a slightly more pampered stay. Our glistening 18 acre lake is the perfect backdrop for family photo opts... or maybe you'd be more interested in grabbing your favorite fishing pole and challenging our great stock of large mouth bass. Come enjoy the warm sun in a lounge chair by our heated swimming pool and let the kids play in our brand new splash pad, cruise in the pedal carts, float in the kayaks, or patrol on their bikes. We've got plenty to keep them occupied. Planned activities are offered to those who want to create lasting memories with their family. After a long day of fun settle down by a campfire to bring your evening to a peaceful close. ... more less


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sherbert 7 years, 3 months ago
Very cool.
50YearResident 7 years, 3 months ago
Is that a creek running right through the middle of the track?
William McCauley 7 years, 3 months ago
Like I posted, you can still see the track in the flatland area if you know the woods real well. Met a guy walking out of there today who was metal detecting, after reading the story, said he didn't find anything though. It would be cool to over lay this image with a current Google earth image.
OldEnuf2BYurDad 7 years, 3 months ago
Yeah, I'm confused. Some pointers about what is where (present-day landmarks, streets, etc.) would help.
grassman 7 years, 3 months ago
OldEnuf- The diagnol line running next to the track is the railroad track. The main line running west and east is E. 11th St. You can faintly see the city compost site just north of the track. I hope this helps. I'm fairly new to Lawrence, so I don't know too many landmarks.
Liberty275 7 years, 3 months ago
"Some pointers about what is where (present-day landmarks"
The big orange spot is the hill with the statue of the crucifix in the cemetary. The orange at the lower right is close to the quantrill memorial. The thin blue vertical line is the ditch west of the park. The break in that line is the bridge. The prominent green line going ESE is the railroad track. The cool looking thing at the left top is the sewer plant, I think.
geekin_topekan 7 years, 3 months ago
The yellow area on the left hand side that is halfway up is about a hundred feet west from the corner of 11th and Haskell. If you follow south you will go past the recycling center. If you go north, the street curves around to the east and there is a landscaping business back there and a few other businesses.
Silly_me 7 years, 3 months ago
If you go to Google maps in Lawrence, you can get a pretty good idea where it is. In the satellite photo on Google, it looks like the track is hidden by a grove of trees/bushes. You can't really see the outline of the track in the Google image.
Liberty275 7 years, 3 months ago
As the crow flies, the center of the track is about 1000 feet northeast of the swings in the park.
William McCauley 7 years, 3 months ago
yes that would be the creek splitting it right in the middle.
gneiss_guy 7 years, 3 months ago
If you look at the Feb. 15, 2002 aerial photo in Google Earth Historical Imagery, you can see the same horse race track in the trees.
Jill Jevens 7 years, 3 months ago
I am quite familiar with the woods, and there is a main, well-worn (and often very muddy!) pathway through them that, before I knew about the track, always struck me as an old railroad bed because it is fairly wide and is distinctive. Now I know it is the southern stretch of the track. It is also clear where the western end of the track was because the earth appears to have been intentionally built up around the perimeter of that end.
Thinking_Out_Loud 7 years, 3 months ago
Liberty275, I think you mean the "Quantrill Victims" memorial...it doesn't memorialize the second man to raid and burn Lawrence.
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Moss Glen Falls, Granville, Vermont. This is likely the most photogenic waterfall in the state of Vermont. While others are taller or greater in volume, this waterfall has a grace and style that can't be matched. Deer Hollow Brook shoots through a narrow rocky gap and leaps over a roughly hewn wall of schist. The texture of the rock wall directs the waters in many graceful streams in periods of low to moderate water.
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Man Suffers Serious Head Injuries In Edinburgh Street Attack
The attack happened on Waverley Bridge.
A cultural centre used by Muslims has been set on fire in Bishopbriggs.
The venue on Auchinairn Road went up in flames today at 2.20am.
Detectives tell us it's being treated as "suspicious" and hate crime is "one line of inquiry".
A spokeswoman from Police Scotland said: "Police and fire crews were alerted to the fire at around 2.20am on Tuesday November 17."
"The fire is being treated as suspicious and a joint investigation between Police Scotland and Scottish Fire and Rescue Service is now underway."
The attack happened on Waverley Bridge.
Police are investigating the attack.
Opposition parties are criticising the figures.
The tragedy happened near the village of Benderloch outside Oban on Sunday.
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Listed below is some of the papers, tutorials and documentation regarding Fedora, Linux Red Hat and CentOS. For small clips of technical note and tech tips, please select the category "Linux Operating System" or "Tech Tips". Alternatively, you can use tag cloud to facilitate your search.
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~Episode 171~
We start the show introducing our guest Andrew, now where he is from, well I'm not going to tell you, so watch the episode to find out, ha!
We also get a breakdown from Natsu on how you can convince FUNimation to pick up the ova'sova's. This is somewhat educational and mostly rant like speech from Natsu.
We can't adult in What's New In Animoo. Mira says "The D" just too many times, which is just poison to us. We spend awhile laughing and giggling.
We get a peek of Elfman in Cooking with Elfman, where he renames the segment Nomnomnomnomnomnom. The drink he makes also makes Lucy very happy.
Watch the episode below to see what else we get into.
All episode of Fairy Tail Podcast are brought to you by Charles Muir of Not Suitable for Word Ninjas Podcast, as well as Word Ninja Podcast.
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What's New in Animoo
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Cooking With Elfman
Spinach Salad with Warm Bacon Mustard Dressing
1 (10 ounce) bag baby spinach leaves
4 hard-cooked eggs, peeled and sliced
1 cup sliced mushrooms
4 strips crisply cooked bacon, crumbled
10 ounces Swiss cheese, shredded
1/2 cup toasted sliced almonds
1 tablespoon olive oil
1 large shallot, minced
1 teaspoon garlic, minced
1/3 cup white wine vinegar
1/3 cup Dijon mustard
1/3 cup honey
2 strips crisply cooked bacon, crumbled
salt and pepper to taste
- Place spinach into a large serving bowl, top with hard-cooked eggs, mushrooms, 4 crumbled strips of bacon, Swiss cheese, and almonds.
- Heat olive oil in a small skillet over medium heat. Stir in shallots and garlic, and cook until softened and translucent, about 2 minutes. Whisk in the vinegar, Dijon mustard, honey, and 2 crumbled strips of bacon; season to taste with salt and pepper, then cook until hot.
- Pour hot dressing over spinach and toss to coat.
Broiled Tilapia Parmesan
1/2 cup Parmesan cheese
1/4 cup butter, softened
3 tablespoons mayonnaise
2 tablespoons fresh lemon juice
1/4 teaspoon dried basil
1/4 teaspoon ground black pepper
1/8 teaspoon onion powder
1/8 teaspoon celery salt
2 pounds tilapia fillets
- Preheat your oven's broiler. Grease a broiling pan or line pan with aluminum foil.
- In a small bowl, mix together the Parmesan cheese, butter, mayonnaise and lemon juice. Season with dried basil, pepper, onion powder and celery salt. Mix well and set aside.
- Arrange fillets in a single layer on the prepared pan. Broil a few inches from the heat for 2 to 3 minutes. Flip the fillets over and broil for a couple more minutes. Remove the fillets from the oven and cover them with the Parmesan cheese mixture on the top side. Broil for 2 more minutes or until the topping is browned and fish flakes easily with a fork. Be careful not to over cook the fish.
The Covenant
1 part UV Grape Vodka
2 parts Hpnotiq Harmonie
2 parts UV Pink Lemonade
Raspberry Ginger Ale
Berry Pomegranate Mio
Pour UV Grape over ice in a highball glass. Add a small amount of the Mio Berry Pomegranate flavoring. Next, float the Hpnotiq, followed by the UV Pink Lemonade. Fill to the top with the raspberry ginger ale and add a squirt or two more of the Mio flavoring.
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Anime Review
When Asuka won the shooting competition between her and Natsu, it made Mira really happy to find out that Asuka ships Natsu and Lucy just like everyone else. She thought it was funny when Lucy did not want to kiss Natsu, but Natsu was all for it, partly because he had to do whatever Asuka said because he lost the shooting competition. Buy of course Lucy is not going to let Natsu kiss her, so she holds up Happy, and Happy is like "Oh no my face". But he actually calls it his beak, which Mira thought was weird.
All in all Mira thought this episode was a lot better then the ones in the filler anf she enjoyed the music.
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Manga Recap
~Chapter 418 Challenger
To Read along with us click on the link below.
Links for the fanart can be found by clicking on the fanart or clicking the artist name and title of the fanart below.
Fanart titled Fairy Tail 418 by xTheMagicianx and Yahik0
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Scrotum has moved inwards, watery sperm, had episode of stinging pain on left side of body causing spasms in testicle. Any ideas?
hi dr.grief im a 21 year old male and about one month ago i experienced a stinging sensation pain on the left side of my body that started from around my ribcage to my groin area..it was very uncomftorble for many hours and my left testicle really felt the spasm as well...then about 2 or 3 weeks ago i noticed that my left testicle is alot more inner than it originally was,kind of like not in the scrotum and more inward inside of my scrotum..i have also noticed that my sperm isn t as thick as it used to be it is kind of watery now..the testicle is still inward..and if i move it around i can eventually get it in position with the right but it just doesnt stay there in place..any ideas what this could be?thank you
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Dr. P. T. Patil
Jul 2016
You had a single episode of pain in left groin and abdomen and you have also noticed that your left testicle has moved little upwards . Normally this happens when testis is freely mobile but you have to consult Surgeon or
to rule out any partial torsion of testicle.In that case you will have to undergo a surgery to fix up the testis so that it does not lead to a complete torsion which leads to grave situation of
of testis.If it is a simle mobile testis you need not worry at all.
Answered: Fri, 14 Sep 2012
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You had a single episode of pain in left groin and abdomen and you have also noticed that your left testicle has moved little upwards . Normally this happens when testis is freely mobile but you have to consult Surgeon or Urologist to rule out any partial torsion of testicle.In that case you will have to undergo a surgery to fix up the testis so that it does not lead to a complete torsion which leads to grave situation of necrosis of testis.If it is a simle mobile testis you need not worry at all.
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Steve Carell
After appearing in several sitcoms, including the short-lived Julia Louis-Dreyfus vehicle "Watching Ellie," Carell landed on Comedy Central's "The Daily Show," where he quickly acquired a loyal following. Working as an on-air "reporter," he displayed his brilliant comedic timing in segments such as "Even Stev/phen," going head to head with Colbert.
The new millennium found Carell landing roles in high-profile film comedies, including Bruce Almighty (2003); his cinematic breakthrough came playing the title character in 2005's The 40-Year-Old Virgin. Returning to television with the U.S. version of the British hit "The Office," Carell has earned multiple Emmy nods and a 2006 Golden Globe for Best Actor in a Comedy.
Café Society
Setting his sights on the magical kingdom of Hollywood, a young man migrates to Los Angeles in the 1930s and is swiftly drawn into the social whirlpool of the young and beautiful -- all pursuing their own visions of success.
- Despicable Me 2
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- Anchorman: The Legend of Ron Burgundy
- Freeheld
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Is it just me, or does politics today seem as orchestrated as a World Wrestling Entertainment (WWE) match? There is a lot of flamboyant swagger, delusions of grandeur, cheap shot banter, and enough bad acting to make Hulk Hogan or the former Macho Man, Randy Savage, feel envious. In other words, our elections have become slap stick parodies of themselves. For instance, pitting Insane John McCain against Bath House Barry Soetoro, in 2008, was an insult to the intelligence of the American people and an inside joke for the "elite." The fix was obviously in. After all, who in their right mind would vote for a guy that wants to nuke the middle east into an ashtray state? Hence, the title "Insane McCain." In 2016, however, the commonsense of the republic rebounded. Donald Trump's power-slam submission over Killary The Hilderbeast Clinton proved a surprising counter move to the globalist's choke hold. Nevertheless, one must wonder, can and will "The Donald" really make America great again?
To be honest, I've never been a fan of watching overweight, middle-aged men, dressed in sweaty tights, rolling around the floor, while executing enough homo-erotic bravado to make Elton John a hardcore sports enthusiast. Yet, that's what politics has become and it's hard to ignore the similarities to professional wrestling. Not to say that there is anything wrong with pro wrestling, of course. Pro wrestlers are amazing athletes. Unfortunately, it's common knowledge that the matches are rigged, similar to our elections.
As you may recall, in 2004, the World Wide Illuminati Federation selected two Skull & Bones members to bout for President. It was John Herman Munster Kerry versus George Will Not Loose Bush. The stakes were high. A vote for John Kerry was a clear vote for the establishment. Option two, just vote for Boy George Bush and get it over with already. We can always bicker later about the lesser of two evils and pretend the election was fair. As long as we have two political systems opposed to each other, everything must be legit, right?
Only time will tell if Donald Trump's victory is a real win for America. He plans on rope-a-doping Obama's legacy into obsolescence. Meanwhile, Obama is trying to place a permanent figure four leg lock on Obamacare, thus securing its long term continuity. One can't help but wonder if this is not yet another dog and pony show set up by the globalists villains, just to keep us distracted and opposed to one another. For now, I choose to remain optimistic. I think 2017 will be a turnaround year for the United States of America, the key word here being "united." So let's simply combine the democratic and republican slogans by saying, YES WE CAN, MAKE AMERICA GREAT AGAIN!
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