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+91-11-45679615Post Your Requirement
Description :
Depart after breakfast from Hotel for Danta via Vadnagar (a medieval walled town with 12th century carved gateways, Vadnagar is known for its huge Torana or 12th century columns surmounted by an arch, 17th century temple, medieval artificial lake that is still used by the local people, havelis of the Naggar Brahmins and other communities, and archaeological excavations where Mathura-style Buddha terracottas, toys, implements of the 4th-7th century AD have been found) and Taranga (A large 12th century Jain temple built from local stone with exceptionally fine sculpture and architectural detail). Arrive at Bhavani Villa, a heritage homestead in Danta, in time for lunch.
In the afternoon, visit the Bhil and Garasia tribal hamlets around Danta for photographing/painting village scenes, portraiture and seeing local pottery OR visit the 1064-1134AD Jain temples of Kumbhariyaji to see its marble carvings and the Hindu temple of Ambaji, about 19km from Danta. Return to Danta for dinner and stay at the Bhavani Villa or Balaram Palace Resort.
Description :
Morning tea at the former ruling family's stud farm of Marwari and Kathiawadi horses, dairy cattle, and aviary birds. After breakfast, depart for princely Palanpur which has some grand old buildings, Sidhapur to see the Bohra Muslim mansions, Patan (a historic walled citadel that was the Solanki capital of Gujarat, Patan has a seven-storeyed 11th century stepwell with magnificent workmanship and a sacred lake surrounded by small Shiva shrines. A living legacy of Patan is its Patola silk weaving using the intricate double ikkat process) and 11th century Modhera Sun Temple. Return to Danta to stay in Bhavani Villa.
Description :
Return to Ahmedabad via Modhera Sun temple, visit to Akshardham Temple in Gandhinagar and Adalaj Stepwell to Hotel.
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Product code: 20671
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With its novel formula, PHYTO SOYA Vaginal Gel brings comfort and wellbeing to menopausal women. During the menopause, hormone secretions decrease. Estrogen impregnation of the vaginal mucosa disappears, causing atrophy of the vulvovaginal tissues combined with a loss of moisturising and lubrication. This dryness is reflected by pain and irritation, as well as discomfort during sexual intercourse. PHYTO SOYA Vaginal Gel - A concentrated extract containing 10% soya isoflavone.; In the form of a cream gel, oil-in-water emulsion to make up to 1 x 5-ml disposable cannula. Soya isoflavones; have a gentle trophic action on the vaginal epithelium: Original molecular structure that permits hydration and protection of the vaginal mucous membrane. PHYTO SOYA Vaginal Gel is perfectly tolerated and has the advantage of being entirely safe. The pH of the emulsion is close to that of the mucous membrane (pH 5-6). Moisturised in this way, the vulvovaginal mucosa recovers its suppleness and elasticity. Instructions:Apply PHYTO SOYA Vaginal Gel directly into the vagina, using the applicator specially designed for the purpose. 1- Remove the cap at the end of the applicator. 2- Insert the applicator into the vagina.3- Press the tube to administer all the product. Non-staining, non-greasy.
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Discussion in 'Fan Zone' started by WoodysGirl, Apr 11, 2014.
funny stuff... best thread in awhile.... yes, its the offseason!
All three of the old late night hosts are not funny to me.
conan is funny sometimes...this was funny to me...when he makes fun of things, he humors me, when he is trying to be "funny", not so much
magic markers
Have they responded to you yet?


text: I had a viability appointment today with the NP (no problem) today. It was my first ultrasound. Have been having mild cramping on the right side, so was scared. Was so relieved to see the baby in the uterus. Baby measured 7w1d, 4-5days behind. Saw the heartbeat and got to hear it too. Measured 147bpm :) Heartbeat was so amazing...still mesmerized :) Can't stop smiling...EDD 6/24/2013


text:
United States, Deceased Physician File (FamilySearch Historical Records)
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This collection contains a name index and images of the deceased physician card file from the American Medical Association (AMA), which are physician biographic records of decedent records from 1804 to 1968. This file contains names for deceased physicians in the USA with a few names from Canada.
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"Argentina, Buenos Aires, Catholic Church Records, 1635-1981," images, FamilySearch (https://familysearch.org: accessed 28 February, 2012), La Plata > San Ponciano > Matrimonios 1884-1886 > image 71 of 389 images, Artemio Avendano and Clemtina Peralta, 1884; citing Parroquia de San Ponciano en la Plata, Buenos Aires, Argentina, Matrimonios. San Ponciano, La Plata.
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Foster Marketing has named Rachel Bonnette as marketing director, President Tiffany Harris announced.
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|Publication number
|Publication type
|Application number
|Publication date
|May 20, 1997
|Filing date
|Aug 18, 1995
|Priority date
|Mar 27, 1995
|Fee status
|Publication number
|Gary Fugitt
|Original Assignee
|The Mead Corporation
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (21), Referenced by (23), Classifications (16), Legal Events (7)
|External Links: USPTO, USPTO Assignment, Espacenet
This is a continuation-in-part of U.S. application Ser. No. 08/410,911 filed Mar. 27, 1995 now abandoned.
The present invention relates to a novel method for preparing a structured clay composition useful as a coating on paperboard or as a filler in paper, and a composition produced thereby.
More particularly, the present invention relates to a novel method for preparing a pigment composition using a high molecular weight polymeric bridging agent to flocculate the particles within the composition and compositions produced thereby.
In another aspect of the present invention, the method for preparing the clay uses a low molecular weight polymer in order to selectively flocculate the fines in the clay without significantly increasing the number of large particles in the distribution.
Finely divided refined kaolin is widely used as a pigment to provide a glossy, white, opaque surface finish on printing paper. In order to manufacture the refined kaolin pigments, several steps are required. These include particle size fractionation, purifying crude clay while the clay is in the form of a fluid deflocculated aqueous slurry, bleaching the clay while in a flocculated state, filtering the flocculated clay to remove liquid water and then dispersing the flocculated clay in water to form a high solids slurry that is marketed as such or is dried, usually in a spray dryer, to provide a dry refined pigment capable of being mixed with water to form a dispersed fluid suspension.
Conventionally, kaolin clay pigments are applied as aqueous "coating colors" which comprise a clay pigment, a dispersing agent for the clay, a suitable binder such as a polymer latex, starch, or mixtures thereof and other minor additives. The viscosity of the high solids suspension of the clay coating pigment must be sufficiently low to permit mixing and pumping. After the binder is added, the resulting coating color must also have suitable viscosity for handling and application to the paper sheet. In addition, the coating should impart good opacity, gloss, brightness and printability to the finished paper. The coatings are applied at high machine speeds and therefore require the use of high solids, typically 70%. A dispersing or deflocculating agent is present in the clay in order to improve the fluidity of the composition. Typical deflocculating agents include sodium condensed phosphate salts or sodium polyacrylates.
When clays are received by the paper manufacturer they are already highly processed. The crude clay has been fractionated, metallic debris has been removed, the brightness of the clay has been adjusted, and the clay has been washed in a drum filter to provide a washed filtercake. A clay which has been beneficiated to this extent is herein referred to as a "processed clay". The processed clay pigments are chemically modified to impart a surface charge to the particles which provides a repulsive force which keeps the particles in a dispersed state. The processed clay can be made anionic or cationic by the addition of a dispersing agent. Clays are usually anionically dispersed. Each particle of clay is chemically modified to carry a similar negative charge, which produces a repulsive force and keeps the particles in a dispersed state.
Conventionally, clay flocculation is induced by adding a flocculating agent which carries a charge opposite the surface charge of the pigment to the dispersion to cause the particles to attract and form agglomerates. Flocculation of the particles is induced by neutralizing or reducing the charge on the particles so they no longer repel one another but aggregate. This is known in the art as "charge reduction" flocculation.
Various methods of preparing a coating composition by adding a charge reduction agent to flocculate the clay are known in the art. U.S. Pat. Nos. 4,772,332 to Nemeh et al. and 4,859,246 to Sennett both teach a method for stabilizing a slurry of anionic clay pigments by adding a water-soluble cationic agent and at least one anionic sulfonate to flocculate the clay particles by neutralizing the clay particle's charge. The cationic agent is a polyelectrolyte flocculant and more specifically polyamides or quaternary ammonium polyelectrolytes.
U.S. Pat. No. 3,804,656 to Kaliski et al. teaches a method for stabilizing a clay suspension using charge alteration. A water soluble nonionic surface active agent, a cationic surface active agent, and a strong base are mixed to create a suspension. The suspension is added to a dispersion of particles to reduce the charge on the particles.
U.S. Pat. No. 4,569,768 to McKinley teaches a method for flocculating solids in a cationic clay by a charge reduction mechanism. The method comprises contacting the slurry with a water soluble polymer having an anionic character, and then with a water soluble polymer having a cationic character. This method clarifies an acidic slurry and is useful in mining operations.
The British Patent No. 1,497,280 to Portland Cement Manufacture's Limited teaches a clay treatment which is designed such that the clay dispersion can be introduced to the wet end of the paper machine whereupon, in the presence of the acid or hard water, the clay flocculates onto the fibers. This however, does not yield a colloidally stable dispersion in a flocculated clay. The central mechanism of flocculation is introducing the ionically dispersed clay to a high acidic environment which contains multivalent cations. The flocculation is caused by a combination of salt effects and charge reduction. This method could not be used in a coating. The presence of multivalent cations (hard water) would cause the entire coating to flocculate to a degree that it would not flow sufficiently to be pumped or applied to paper. In the Portland patent, the addition of the dispersion to the solution of cations forces flocculation. The anionic polymers are much higher in molecular weight than those used to produce a solid stable coating in the present invention. These polymers typically have molecular weights ranging from 4M to 5M and are used as retention aids. By using polymers with such high molecular weights, the coatings are too thick and do not flow.
D. I. Lee, "Coating Structure Modification and Coating Hold-Out Mechanisms", 1981 TAPPI Coating Conference Preprint, teaches a method for flocculating clay particles using different electrolyte combinations in a clay suspension to adjust the particle's charge. The electrolytes increase the ionic strength of the clay suspension and decrease the repulsion of particles. This change in the charge allows the attraction forces to dominate and creates particle stability.
European Patent 0,245,553 to Pratt et al. teaches a method for flocculating the particles in a coating slurry by adding a small amount of water soluble cationic polyelectrolyte flocculant to prepare a bulked clay pigment. The resulting flocculated product can be dispersed to form a high solids, clay-water slurry to be used as a coating composition or filler for paper.
The above-mentioned charge reduction and charge alteration methods for flocculating pigments have several drawbacks. Adding a charge reduction flocculating agent to a coating composition increases the composition's viscosity and limits the level of the flocculating polymer used. Traditional flocculation approaches used flocculants whose flocculating abilities were, in a sense, too intense causing undesirably high thickness, viscosity, and ionic properties for use as paper coatings. Also, they often do not have a high enough solids composition to be used as suitable paper coatings.
U.S. Pat. Nos. 4,943,342; 5,085,707; and 5,168,083 all assigned to Georgia Kaolin Company, Inc. teach "defined" clays. These references teach particle size adjustment by removing a portion of the fine fraction by physical or chemical means. These methods are used typically for coatings with opacifying pigments.
It is the applicant's discovery that by using a polymer which might be considered to be a poor flocculating agent and which does not reduce the charge on the particle, one can produce a colloidally stable suspension of flocculated pigment for use in paper. The clays can be used as fillers or in coatings. In accordance with the invention, fluid flow properties are improved, higher solids is achieved and there is less interaction with the other materials in the coating by the anionic or nonionic polymer.
In accordance with the present invention, a method of making a flocculated clay is provided comprising the steps of preparing a dispersion of a processed clay in water containing a polymer as a flocculating agent in an amount sufficient to cause bridging of the clay particles in said dispersion by said polymer and mixing said dispersion to cause said polymer to bridge said particles and said particles to flocculate.
In accordance with another object of the present invention, a clay is provided which has been flocculated by the above method.
In accordance with a further object of the present invention, a method for making a coated paper is provided comprising the steps of preparing an aqueous suspension of anionically dispersed clay; adding thereto a flocculant in an amount sufficient to cause flocculation of the suspension by bridging particles of said dispersed clay with said flocculant; drying the flocculated clay to provide a slurry suitable for coating; preparing a paper coating composition from said slurry; and coating said composition on paper.
In accordance with another object of the present invention, a flocculated clay is provided which comprises anionic clay particles bridged by an anionic or nonionic polymer having a molecular weight in the range of about 400,000 to about 1.5M.
The clay of the present invention is believed to be flocculated by a mechanism which is distinct from conventional clays. This mechanism is referred to as "bridging". Bridging is distinguished from charge reduction flocculation in that the flocculating agent does not alter the charge on the particles. Instead, the flocculating agent is a bridging agent which appears to function as a coagulant or "mesh" whereby the pigment particles become entangled or lodged within the strands of polymer of the bridging agent. The term "bridging" is inclusive of polymer entanglement. Because, in the typical case, the pigments carry an anionic surface charge, flocculation is not caused by charge reduction since the polymers have the same or a neutral charge. In addition, the bridging with lower molecular weight polymers allows selective flocculation of the fine portion, while charge reduction is not selective.
The bridging method of the present invention, represents a comparatively inexpensive process for increasing opacity of the coating, as will be described herein.
Prior art structured clays prepared by charge reduction treatment with a cationic polymer, are disadvantageous. They are generally not available in solids concentrations greater than about 60%, which is less concentrated than is normally desired in a paper coating. If a solids concentration higher than 60% is used, the slurry is too viscous to handle and must be thinned by dilution. Slurries of these clays are not satisfactory for use in many paper coatings because they cannot be diluted for application to the surface of the paper and still meet the opacity, gloss, brightness, and printability for useable paper coatings. The reason conventional structured clay dispersions only contain about 60% solids is that the addition of the cationic polymer destabilizes the particles and the particles do not flow as well. When one adds more water to the conventional dispersions in order to obtain the viscosity and fluid flow characteristics that are desired for coating or fillers, the quality of the coated surface is adversely affected (i.e., gloss, print quality) and the drying demand of the coating process is increased, limiting production speeds.
In contrast, dispersions produced in accordance with the present invention can be obtained in concentrations greater than 60% solids, preferably 64-70%. A higher concentration can be obtained because the addition of an anionic polymer does not destabilize the charge on the particles. As a result, well dispersed flocculation can be obtained at higher solids content. This, in turn, produces a better coating or filler.
The clays are flocculated in accordance with the present invention, using a polymer entanglement vehicle in place of charge reduction. This is advantageous because the polymers used to flocculate the clays are not cationic and they have little effect on the functionality of other additives for the paper coating.
FIGS. 1A-1D are graphs of the advantages set forth in Example 1 of the present invention;
FIG. 2 is a graph of the opacity improvement of the present invention set forth in Example 2;
FIG. 3A-3B are graphs of the particle size distribution based on Example 4;
FIGS. 4A-4B are graphs of the advantages set forth in Example 5;
FIGS. 5A-5B are graphs of the advantages set forth in Example 6;
FIG. 6 is a graph of increase in print gloss in accordance with Example 7; and
FIG. 7 is a graph of increase in print gloss in accordance with Example 8.
The present invention provides a method for flocculating the particles of clay using a flocculating agent which induces flocculation through a bridging or entanglement action instead of charge alteration or charge reduction. This method is referred to herein as bridging flocculation or polymer entanglement. It is advantageous because addition of the present flocculant does not produce the steep increase in product viscosity that accompanies the charge reduction flocculants. In addition, there is less interaction of the polymers with the other materials in the coating.
In the method of the present invention, polymers are added to the clay dispersion or to a coating composition containing the clay dispersion which have molecular weights in the range of about 400,000 to about 1,500,000. They are nonionic or anionic in nature and are added as the flocculants to the anionic dispersed clay.
The present invention more particularly includes two embodiments, namely, one embodiment in which the flocculating agent has a molecular weight in the range of 750,000 to 1.5M and the other in which the flocculating agent has a molecular weight in the range of 400,000 to 600,000. The properties of the coatings and coating compositions obtained in these two embodiments are different. Coating compositions are generally bulkier, exhibit greater layer thickness per unit weight, and provide better coverage of the fibers when the pigment has been flocculated with polymers having molecular weights ranging from 750,000 to 1.5M. On the other hand, a smoother sheet having better ink gloss and ultimately better print quality, but not opacity generally results when the pigment has been flocculated with polymers having molecular weights ranging from 400,000 to 600,000. Strictly speaking the former embodiment yields a structured or bulked clay whereas the latter yields a particle size adjustment in the clay.
The method of the present invention can be used to prepare a flocculated clay useful in a coating or as a filler in paper. The method in its most basic form comprises the steps of preparing a dispersion of clay having an anionic surface charge containing a flocculating polymer to cause bridging of the clay particles. The dispersion is prepared by adding a dispersant to a processed clay and subjecting the clay to high shear mixing. The flocculating polymer can be added to the clay at the same time as the dispersant or the polymer can be added in a subsequent step. If the polymer is added in a subsequent step, the clay with the polymer added is subjected to additional high shear mixing.
The anionic or nonionic flocculating agent is added to the clay in an amount sufficient to bridge flocculate the particles. The clay dispersion containing the polymer can be subjected to high shear mixing using a Cowles mixer. It is sheared for a sufficient time to uniformly distribute the polymer and cause flocculation. This is typically 10-15 minutes. The flocculated pigments may range in particle size from about 10 to about 0.1 microns. If the low molecular weight flocculating polymer is utilized, the particle size ranges from about 10 to about 0.25μ. The minimum particle size increases without substantially affecting the maximum particle size as explained below.
The anionic or nonionic flocculating agent is typically added to the clay dispersion before it has been dried and formulated into a coating composition, but, in another embodiment, it may be added to a coating composition containing the clay. The amount of polymer added will vary with the degree of treatment and will depend on the particular application for the clay filler or coating.
The flocculating agent is typically added to a clay dispersion in an amount of 0.1 to 1 part per 100 parts clay on a dry basis. If the polymer is added to a coating composition, the amount of polymer needed to flocculate the clay typically doubles because the polymer must also interact with the other materials in the coating. It has been found that substantially higher amounts of polymeric flocculant can be used in the present invention than could be used in charge reduction methods.
The amount of anionic or nonionic flocculating polymer used to treat the clay may vary with characteristics of the polymer including charge density and molecular weight, the particle size distribution and solids content of the clay and the degree of structure desired. Increased charge density of the polymer will increase the colloidal stability of the resulting flocs by giving them a greater effective surface charge. Increased molecular weight increases the degree of the effect and the resulting effective particle size. Increasing molecular weight, however, will generally decrease the amount of polymer that can be used for a given set of conditions. The initial particle size distribution will also affect the amount of polymer needed to obtain a desired particle size distribution.
The viscosity of the clay slurry will initially increase upon polymer addition because the polymer acts as a liquid phase thickener. In contrast, viscosity will decrease as the polymer is evenly distributed, becomes absorbed, and lays flat on the particle surfaces. It is the slurry solids prior to polymer addition which will determine how much initial viscosity increase can be tolerated by the mixing system.
Nonionic polymers are believed to work as flocculants in the same fashion as the anionic polymers. The original charge on the anionic clay is believed to be responsible for stabilizing the suspension.
In accordance with the present invention, the flocculating polymer is an anionic or nonionic polymer having a molecular weight of about 400,000 to 1,500,000. Higher molecular weights can be used, such as 6M for nonionic polymers. However, above 1.5M, the dispersion tends to flocculate in a nonhomogeneous manner. The flocculation and the thickening effect is so strong that only a very small amount can be added. In some cases, only a portion of the slurry comes into contact with the polymer and the effect is not homogeneously distributed.
In one embodiment, the flocculating polymer is an anionic or nonionic polymer having a low molecular weight (about 400,000 to 600,000). Low molecular weight polymers selectively flocculate the fines in clays. This is believed to occur since the polymer chain is only long enough to attach to or bridge the small clay particles and not the larger particles. In this way the percentage of fines is greatly reduced, but the percentage of larger particles is relatively unaffected since the polymers only affect the small particles. There is a shift in the particle size distribution to greater particle size without increasing substantially the maximum particle size. Therefore, there is a narrower particle size distribution.
By using such lower molecular weight flocculating polymers, the small particles (i.e. less than 1 micron) will flocculate. This range molecular weight polymer is particularly effective in flocculating particles of 0.1 to 0.25 micron. The polymer will convert these fines into particles ranging from 0.5 to 2 microns. The amount of larger particle formation is negligible.
In a second embodiment, the flocculating polymer is a high molecular weight (about 750,000 to 1.5M) nonionic or anionic polymer. High molecular weight polymers flocculate the clay by attaching themselves to any of the clay particles (i.e., not just the small particles), forming a bridge. Using high molecular weight polymers, the entire particle size distribution shifts to greater sized particles. The shape of the particle size distribution curve remains essentially the same but the curve is shifted.
Conventional dispersants are useful in the invention such as Colloids 211 and Dispex N-40 (sodium polyacrylates). These dispersants have a molecular weight range of about 2,000 to 8,000, and are used in amounts of 0.1 to 1 part per hundred figured as dry dispersant on dry undispersed clay. These low molecular weight anionic polymers are very small in size; more than an order of magnitude smaller than the minimum size necessary for bridging flocculation of a clay. These small polymers enable more polymer (weight/weight) to be adsorbed on to the clay surface. This results in higher charge density on the clay surface giving the higher colloidal stability. A well dispersed clay slurry is made up of well dispersed, individual clay particles, and is free from flocculation.
One manifestation of the present invention is a coating composition containing bulked clay useful as a paper coating. It comprises clay, a carbonate such as calcium carbonate, titanium dioxide, starch and latex, and lubricants to prevent pick off or a cross-linker for the starch. A coating composition, in accordance with the present invention, typically comprises clay in an amount of 10 to 95%, a carbonate in an amount of 10 to 95%, titanium dioxide in an amount of 0 to 30%, starch in an amount of 0 to 5%, latex in an amount of 0 to 20%, lubricants such as calcium stearate, to prevent pick off in an amount of 0 to 2%, and cross-linkers, such as a modified glyoxal, in an amount of 0 to 1%. A minimum of about 7% binder level should be used. This includes the starch or latex or another binder occasionally used in paper such as a protein or casein. Any latex, starch, lubricant or carbonate conventionally used in paper manufacturing may be used. For example, a coating formulation for a publication grade might be 55% clay, 20% calcium carbonate, 5% titanium dioxide, 7% starch, 7% latex, 0.2% crosslinking agent and 0.8% lubricant.
By using the low molecular weight embodiment method of this invention, a coating with a high ink gloss is produced. In prior methods however, time consuming and costly methods such as using a centrifuge had to be used to remove the fine clay particles.
The present invention may use a commercially available polymer, but to, fully optimize the process, the charge density of an anionic polymer should be sufficient to maximize the colloidal stability of the agglomerates. In a preferred embodiment, the anionic polymer is selected from the group consisting of polyacrylates, polyacrylamides, polyethylene oxide and cellulose derivatives. The charge density of these polymers is typically low to moderate. The nonionic polymer is selected from the group consisting of polyethyleneoxide (PEO), polypropylene oxide (PPO) and cellulose derivatives. The acrylamides and cellulose derivatives may be anionic or nonionic based on the charges of their functional groups.
The resulting flocculated pigments of the present invention can be used to make exceptional coatings as a single layer or a double layer coating. In a double layer coating, a first coating is used to fill the pores and irregularities in the surface. This coating can be relatively inexpensive. A more expensive final surface coating is then provided to give the good opacity, brightness and printability properties. Thus, the first coating, also known as the "pre-coat", covers the base sheet so that the top coating is easier to apply. The top coating provides good optical properties. For example, TiO2 may be added to the top coating for greater opacifying power. The two coatings employ the same clays and carbonates but the pre-coat may employ a cheaper binder. For example, the pre-coat may include more starch, less latex and less other additives. Both coatings are dried between applications since wet-on-wet coatings are messy. The dry coat provides a rigid surface with better coating properties.
In conclusion, bridging methods have several advantages over charge reduction and charge alteration methods for flocculating pigments. There is better compatibility with other additives in the coating since it is an anionic or nonionic material, not cationic. The flocculating agent when added to a coating composition does not increase the composition's viscosity nor limit the level of the flocculating polymer used. Traditional flocculation approaches used flocculants whose flocculating abilities were too intense causing undesirably high thickness, viscosity, and ionic properties for use as paper coatings. In contrast, the flocculants of the present invention have suitable solids composition to be used as suitable paper coatings having corresponding good viscosity, opacity, gloss, brightness and printability.
The clay pigments flocculated in accordance with the practice of the present invention are especially useful in preparing coating colors for coating lightweight publication papers, particularly magazine stock, to achieve coated papers having excellent opacity and printability.
The present invention is illustrated in more detail by the following example:
A fine U.S. kaolin coating clay is obtained fully dispersed as a 70% solids slurry. A master batch of the slurry is diluted to 60% solids. An anionic sodium polyacrylate polymer, with a molecular weight of about 1.5 million and a low to moderate charge density, is dissolved to make a 5% solids solution. The solution is added to 700 grams of the 60% solids concentration pigment slurry and mixed on a Cowels mixer for 10 minutes. Particle size analysis using the Sedigraph 5000 was performed to evaluate the effect of the flocculation caused by the anionic polymer on the particle size distribution of the clay. Seven percent solids samples are prepared and tested according to the TAPPI (Technical Association of the Pulp and Paper Industry) standard procedure. The resulting particle size distributions are shown in FIG. 1A. These curves show that the percentage of particles in the small end of the distribution decreases as the amount of polymer added increases. The same particle size information is presented differently in FIG. 1B. In this figure, it can be clearly seen that the percentage of particles less than 0.2 microns is strongly reduced by the polymer. Also, the figure shows that the 0.2 to 0.5 micron range is almost totally unaffected. This demonstrates selective flocculation of the fines. These fines are agglomerated to form particles mostly in the 0.5 to 5.0 micron range. The packing characteristics of the 60% solids slurries were tested using a sediment void volume analysis. The sediment void volume was determined by centrifuging alloquats containing 50 grams of clay (bone dry basis) at 5800 rpm for 90 minutes. Using the measured sediment volume, the clay density, and the sample bone dry weight, the void volume of the sediment was calculated. The results in FIG. 1C show that the sediment volume increases as the polymer addition level increases and that an addition level of 0.05% polymer, based on clay, gives an increase in void volume of 18%. These same 60% solids flocculated clay samples were applied to optically smooth black glass for scattering coefficient determination. The results are shown in FIG. 1D. The scattering coefficient at a light wavelength of 577 nm increases by more than 75%.
A paper coating is prepared by taking a 70% solids concentration pigment slurry consisting of 70 parts fine clay, 19 parts fine ground calcium carbonate, 5 parts coarse ground calcium carbonate, and 6 parts titanium dioxide. This is mixed on a Cowels mixer for 10 minutes and treated with 0.025% of an anionic polymer having a molecular weight of about 2 million. This is mixed under high shear for 10 minutes. Then 9 parts of a styrene butadiene latex and 7 parts ethylated starch are added. The resulting coating is applied to a groundwood-containing basesheet using a rigid blade coater running 2000 fpm. A control coating with no polymer added was made using the same formulation. The resulting coated sheets were tested for improvements in opacity. The results (FIG. 2) showed an improvement of about 1 point in opacity for the uncalendered and supercalendered sheets with both 7 and 9 lbs/3300 ft2 of applied coat weight.
Two identical coating formulations for sheet-fed printing are prepared consisting of approximately 60 parts fine clay and 40 parts fine ground calcium carbonate with small amounts of anatase titanium dioxide, polystyrene latex, and 13 parts styrene butadiene latex. To one of these coatings, a 1.5 million molecular weight anionic polymer with low charge density is added and mixed for 10 minutes with sufficient agitation. Both coatings are applied to a 48 lb/3300 ft2 wood-free basesheet at 3000 fpm using a bent blade. The coatings are applied at a coat weight of 11 lbs per side. The resulting rolls of paper are supercalendered to a sheet gloss of about 72 and cut into sheets. The paper was tested and some of the paper was printed on a commercial sheetfed press. The results are shown in Table 3-1.
TABLE 3-1______________________________________ StructuredMeasured Property Control Coating______________________________________Sheet Gloss 71.5 72.0Brightness 85.6 87.2Opacity 94.3 94.3Print Gloss - 100% ink coverage 86.5 88.4Print Gloss - 200% ink coverage 86.9 89.7Parker Print Surf - 10 kgf 1.37 1.06Parker Print Surf - 5 kgf 1.90 1.56Coating Application Solids 64.1 62.5Coating Hercules Viscosity - 57.6 cP 48.4 cPE bob, 6000 rpmBrookfield Viscosity - 100 rpm 1300 cP 960 cP______________________________________
The results in the above table show that adding an anionic polymer to a completed coating increases brightness and printed gloss and decreases roughness.
A fine U.S. kaolin clay is obtained fully dispersed as a 70% solids slurry. This slurry is diluted to 60% solids for treatment. An anionic sodium polyacrylate polymer, with a molecular weight of about 800,000 and a low to moderate charge density, is dissolved to make a 5% solids solution. The solution is added to 700 grams of the 60% solids concentration pigment slurries and mixed on a Cowels mixer for 10 minutes. Particle size analysis using the Sedigraph 5000 was performed to evaluate the effect of the flocculation caused by the anionic polymer on the particle size distribution of the clay. Seven percent solids samples were prepared and tested according to the TAPPI standard procedure. The resulting particle size distributions are shown in FIG. 3A. This figure shows that the percentage of particles in the small end of the distribution decrease as the amount of polymer added increases. The same particle size data is presented differently in FIG. 3B. In this figure, it can be clearly seen that the percentage of particles which are less than 0.2 microns is strongly reduced by the polymer. This demonstrates preferential flocculation of the fines. These fines are agglomerated to form particles mostly in the 0.5 to 5.0 micron range. The addition level of polymer used was high to demonstrate the maximum possible effect. The results are comparable to the highest addition level of a 1.5 SM molecular weight polymer used in Example 1.
A 70% solids concentration pigment slurry consisting of 70 parts fine clay, 19 parts fine ground calcium carbonate, 5 parts coarse ground calcium carbonate, and 6 parts anatase titanium dioxide is mixed using a Cowels mixer for 10 minutes. A portion is diluted to 60% solids and samples of this are treated with 0.05, 0.1 and 0.2% of an anionic polymer with molecular weight of about 800,000. The slurries are mixed for 10 minutes after the polymer is added. The samples are centrifuged in the manner described in Example 1. The sediment volume increases as the polymer addition increases due to the change in particle size distribution. See FIG. 4A. The viscosity of these slurries initially decrease, but viscosity is increased once the degree of flocculation is enough to significantly narrow the particle size distribution. See FIG. 4B.
A paper coating using a pigment blend of 70 parts fine clay, 19 parts fine ground calcium carbonate, 5 parts coarse ground calcium carbonate, and 6 parts anatase titanium dioxide and a binder system of 7 parts starch and 9 parts styrene-butadiene latex is made. The completed coating is then split into portions that are treated with 0.15, 0.22, and 0.28% anionic polymer having molecular weight of about 800,000. The resulting flocculated coatings are centrifuged and the sediment void volume determined by the method described in Example 1. The void volume increases rapidly with increased polymer addition level (FIG. 5A). The increased void volume for the coating is substantially greater than the increase seen for the pigment blend in Example 5. Brookfield low shear viscosity was measured on the coatings (FIG. 55) and the results show a mild increase in viscosity as the polymer addition level increases.
A coating whose pigment portion was made up of predominantly fine kaolin clay, with about 10 parts fine ground calcium carbonate and 5 parts titanium dioxide with 6 parts latex and 6 parts styrene butadiene latex as the binder is prepared. Three additional, identical coatings are made except that an anionic polymer is added to these coatings after they are prepared at addition levels of 0.06, 0.12, and 0.20% based on dry coating. The polymer is an anionic sodium polyacrylate with low to moderate charge density and a molecular weight of about 800,000. The coatings are applied to a 32 lb/3300 ft2 basis weight wood-containing base sheet at a coat weight of about 9 lbs/3300 ft2. Sheet gloss, smoothness, opacity and brightness are all equivalent, but the sheet coated with the polymer containing coatings gives higher printed gloss when printed by the Prufbau Printability tester. The highest addition level, 0.20% gives an increase in printed gloss of about 6 points (FIG. 6).
The same control coating formulation and anionic polymer as Example 7 is used. In this experiment, 2 coatings are made as before with polymer added at 0.12 and is 0.24% of total to the coating after it is completed. Two other coatings are made where the clay, calcium carbonate and titanium dioxide are mixed together then the polymer is added as 0.06 and 0.12% of total to this pigment blend. After sufficient mixing, the other coating ingredients are added. Again, all sheet properties are equivalent except for printed gloss (FIG. 7). The addition of the polymer to the pigment blend or the finished coating increases ink gloss.
|Cited Patent
|Filing date
|Publication date
|Sep 8, 1970
|Jul 4, 1972
|English Clays Lovering Pochin
|Oct 18, 1971
|Sep 18, 1973
|Sued Chemie Ag
|Clay mineral bearing suspensions
|Feb 22, 1972
|Apr 16, 1974
|Engelhard Min & Chem
|Pigment dispersions and use thereof
|Aug 1, 1977
|Feb 21, 1978
|Yara Engineering Corporation
|High bulking clay pigments and methods of making the same
|Dec 27, 1976
|Feb 28, 1978
|Yara Engineering Corporation
|High bulking clay pigments and method of making the same
|Dec 6, 1976
|Mar 14, 1978
|Yara Engineering Corporation
|High bulking calcined clay pigments and methods of making the same
|Jul 27, 1981
|Aug 24, 1982
|Yara Engineering Corporation
|Structured kaolin agglomerates and methods of making the same
|Feb 11, 1985
|Feb 11, 1986
|The Dow Chemical Company
|Flocculation of suspended solids from aqueous media
|Apr 5, 1985
|Nov 25, 1986
|American Colloid Company
|Method of temporarily inhibiting the swellability of water swellable clays and compositions
|May 12, 1986
|Apr 19, 1988
|Engelhard Corporation
|Treatment of clays with cationic polymers to prepare high bulking pigments
|Jan 25, 1988
|Sep 20, 1988
|Engelhard Corporation
|Use of mixture of high molecular weight sulfonates as auxiliary dispersant for structured kaolins
|Sep 12, 1988
|Aug 22, 1989
|Engelhard Corporation
|Use of high molecular weight sulfonate as auxiliary dispersants for structured kaolins
|May 23, 1988
|Jul 24, 1990
|Georgia Kaolin Company, Inc.
|High performance paper filler and method of producing same
|Jun 14, 1990
|Feb 4, 1992
|Georgia Kaolin Company, Inc.
|Defined and delaminated kaolin product
|May 9, 1990
|Dec 1, 1992
|Georgia Kaolin Company, Inc.
|High opacity defined kaolin product and method of producing same
|Mar 3, 1988
|Mar 30, 1993
|Basf Lacke & Farben Ag
|Aqueous sheet silicate dispersions, use of these dispersions as coating assistants and water-dilutable coating compositions containing sheet silicates
|Oct 13, 1989
|Apr 26, 1990
|Wilhelm Friedrich Beckerle
|Preparation of shaped articles from a finely particulate aggregate and a polyacrylate binder preparation
|Mar 6, 1987
|Sep 15, 1988
|Nicolaus Md Papier
|Kationisch eingestellte pigmentdispersion und streichfarbe
|Jul 2, 1986
|Nov 19, 1987
|Engelhard Corporation
|Treatment of clays with cationic polymers to prepare high bulking pigments
|Title not available
|Aug 12, 1992
|Mar 4, 1993
|Allied-Signal Inc.
|Melt process formation of polymer nanocomposite of exfoliated layered material
|Citing Patent
|Filing date
|Publication date
|Jun 6, 1997
|Jul 20, 1999
|Hoechst Trespaphan Gmbh
|Vapor barrier coating for polymeric articles
|Mar 17, 1999
|Jan 11, 2000
|Hoechst Trespaphan Gmbh
|Vapor barrier coating for polymeric articles
|Jun 8, 1998
|Jul 11, 2000
|Inmat, Llc
|Barrier coating of an elastomer and a dispersed layered filler in a liquid carrier
|Sep 1, 1998
|Dec 5, 2000
|J. M. Huber Corporation
|Polymer structured clay pigment and method of preparing the same
|Jun 10, 1999
|May 15, 2001
|Inmat, Llc
|Barrier coating of an elastomer and a dispersed layered filler in a liquid carrier and coated articles
|Mar 10, 2000
|Jun 11, 2002
|J.M. Huber Corporation
|Paper or paper board coating composition containing a structured clay pigment
|Aug 8, 2002
|Oct 17, 2006
|Imerys Pigments, Inc.
|Integrated process for simultaneous beneficiation, leaching, and dewatering of kaolin clay suspension
|Mar 27, 2009
|Jul 6, 2010
|Meadwestvaco Corporation
|Low density paperboard
|Mar 20, 2009
|Sep 27, 2011
|Meadwestvaco Corporation
|Method for coating dry finish paperboard
|Dec 2, 2008
|Mar 27, 2012
|Meadwestvaco Corporation
|Basecoat and associated paperboard structure
|Sep 6, 2011
|May 29, 2012
|Meadwestvaco Corporation
|Method for coating dry finish paperboard
|Apr 20, 2010
|Feb 25, 2014
|Meadwestvaco Corporation
|Basecoat and associated paperboard structure including a pigment blend of hyper-platy clay and calcined clay
|Aug 11, 2011
|Nov 11, 2014
|Dsi Underground Systems, Inc.
|Rock dusting compositions and methods of use thereof
|Mar 14, 2013
|Dec 23, 2014
|Meadwestvaco Corporation
|Basecoat composition and associated paperboard structure
|Mar 14, 2013
|Dec 8, 2015
|Westrock Mwv, Llc
|Basecoat composition and associated paperboard structure
|Aug 8, 2002
|Jul 31, 2003
|Imerys Pigments, Inc.
|Integrated process for simultaneous beneficiation, leaching, and dewatering of kaolin clay suspension
|Mar 20, 2009
|Sep 24, 2009
|Fugitt Gary P
|Method For Coating Dry Finish Paperboard
|Dec 2, 2008
|Sep 24, 2009
|Fugitt Gary P
|Basecoat and Associated Paperboard Structure
|Mar 27, 2009
|Dec 3, 2009
|Fugitt Gary P
|Low density paperboard
|Apr 20, 2010
|Oct 21, 2010
|Bushhouse Steven G
|Basecoat and Associated Paperboard Structure Including A Pigment Blend of Hyper-Platy Clay and Calcined Clay
|Aug 11, 2011
|Jan 15, 2014
|Dsi 地下系统有限公司
|Rock dusting compositions and methods of use thereof
|Aug 11, 2011
|Nov 25, 2015
|Dsi 地下系统有限公司
|Aug 11, 2011
|Jul 26, 2012
|Dsi Underground Systems, Inc.
|Rock dusting compositions and methods of use thereof
|U.S. Classification
|428/331, 428/537.5, 524/446
|International Classification
|Cooperative Classification
|European Classification
|Oct 20, 1995
Owner name: MEAD CORPORATION, THE, OHIO
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:FUGITT, GARY;REEL/FRAME:007687/0040
Effective date: 19950811
|Oct 16, 2000
|Fee payment
Year of fee payment: 4
|May 27, 2003
Owner name: MEADWESTVACO CORPORATION, CONNECTICUT
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:MEAD CORPORATION, THE;REEL/FRAME:014066/0963
Effective date: 20021231
|Oct 20, 2004
|Fee payment
Year of fee payment: 8
|Nov 24, 2008
|Maintenance fee reminder mailed
|May 20, 2009
|Lapse for failure to pay maintenance fees
|Jul 7, 2009
|Expired due to failure to pay maintenance fee
Effective date: 20090520


text:
Burris Eliminator III, 4-16x50mm, X96 Reticle, LaserScope
Item # WX2-234517
Mfg. Number: 200116
Burris Eliminator III, 4-16x50mm, X96 Reticle, LaserScope
Item # WX2-234517
Mfg. Number: 200116
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There are no more guessing game with a Burris® 4-16x50mm Eliminator® III Laser Scope. The customized trajectory compensation calculates the perfect holdover at your exact distance; program your cartridge's ballistics information, push a button, and a bright-red, illuminated dot signifies your new aiming point within seconds. More than 1,500 factory pre-loaded cartridge specs deliver automatic bullet-drop compensation numbers. Robust construction is waterproof and fogproof to handle the toughest weather and terrain. Today's rifleman gets more accuracy and more range out of each shot - even those out to 1,200 yards!
Key Specifications
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- Item Number: 234517
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text:
Spermine NONOate
Cat. No. 1135
Price and AvailabilityBy clicking submit you agree to accept a cookie from Tocris Bioscience. For details, please read our privacy and cookie policy.
Chemical Name: N-[4-[1-(3-Aminopropyl)-2-hydroxy-2
Biological ActivityA stable complex of nitric oxide and spermine used to generate a controlled release of nitric oxide in solution (EC50 = 6.2 μM for relaxation of rabbit aorta, and t½ =39 min at 37°C, pH 7.4, aqueous solution).
Licensing InformationSold with the permission of the NIH, US Patent 5,155,137
Technical DataM.Wt:
The technical data provided above is for guidance only. For batch specific data refer to the Certificate of Analysis.
All Tocris products are intended for laboratory research use only.
Certificate of Analysis / Product Datasheet / Safety Datasheet
References are publications that support the products' biological activity.
Ferrero et al (1999) Comparative effects of several nitric oxide donors on intracellular cyclic GMP levels in bovine chromaffin cells: correlation with nitric oxide production. Br.J.Pharmacol. 127 779. PMID: 10401570.
Homer and Wanstall (1998) In vitro comparison of two NONOates (novel nitric oxide donors) on rat pulmonary arteries. Eur.J.Pharmacol. 356 49. PMID: 9761423.
Ramamurthi and Lewis (1997) Measurement and modeling of nitric oxide release rates for nitric oxide donors. Chem.Res.Toxicol. 10 408. PMID: 9114977.
Maragos et al (1991) Complexes of NO with nucleophiles as agents for the controlled biological release of nitric oxide. Vasorelaxant effects. J.Med.Chem. 34 3242. PMID: 1956043.
If you know of a relevant reference for Spermine NONOate please let us know.
Citations are publications that use Tocris products. Selected citations for Spermine NONOate include:
Russell et al (2013) Modulation of ligand-heme reactivity by binding pocket residues demonstrated in cytochrome c' over the femtosecond-second temporal range. FEBS J 280 6070. PMID: 24034856.
Do you know of a great paper that uses Spermine NONOate from Tocris? If so please let us know.
View Related Products by Target
View Related Products by Product Action
Keywords: Spermine NONOate, supplier, Slow, NO, releasing, agent, ROS, Donors, Precursors, Nitric, Oxide, Signaling, Signalling, Tocris Bioscience, NO Donors / Precursor products


text:
An explorer for large-scale computational sociolinguistics
Welcome to Humboldt, a tool for large-scale sociolinguistics for everyone!
We provide an interface to search lexical phenomena in several languages, and to get statistical analysis and maps of the results along several demographic factors. You don't need any programming experience, training in statistical methods, knowledge of geographical information systems, or expertise in natural language processing.
This tool is named after the Humboldt brothers, because - like them - it combines linguistic knowledge and scientific exploration.
We use data from various online sources, and are constantly expanding our coverage, the languages you can search, and the services we provide, so check back often!
Try out searching a single term, or compare two terms to each other:


text:
My boss wants a printer for his office. We could go wired with a switch and just drill a hole in his desk but we're trying to see if we can avoid this.
All we're looking to do is sit the printer on his desk and let him print to it wirelessly. We can connect it to our company's WLAN.
The problem is all the reviews I've been reading have been terrible as far as the wireless capability.
Does anyone have any good recommendations for a wireless printer?
33 Replies
Feb 8, 2012 at 7:32 UTC
HD IT Solutions is an IT service provider.
Can't you just give him something small like an HP 2015? USB connected?
If all he needs to do is print then why go wireless?
Are there any other requirements?
Feb 8, 2012 at 7:33 UTC
Not sure if you're only looking to print or if you want more capabilities but we have an HP OfficeJet 8600 that's connected wirelessly. Haven't had any complaints about it and it's fairly quick. Have a couple 8500's as well, only one is set up wireless and again, no issues that I've heard of.
Feb 8, 2012 at 7:35 UTC
Get a decent network laser printer and connect a wireless AP to the network card of the printer. Then connect the wireless AP to your company's wireless.
We do this all of the time for our clients who want decent printers connected wirelessly.
Feb 8, 2012 at 7:35 UTC
Do NOT get a 2015 (or anything else in the 2K series)!!! The drivers are all host-based and have wreaked nothing but havoc on our dedicated print server.
Feb 8, 2012 at 7:37 UTC
HD IT Solutions is an IT service provider.
Do NOT get a 2015 (or anything else in the 2K series)!!! The drivers are all host-based and have wreaked nothing but havoc on our dedicated print server.
I would never envisage using one on a print server.
Our CFO wanted something in his room to print confidential docs on - for that purpose it works perfectly well directly connected to his laptop and using local drivers.
Feb 8, 2012 at 7:51 UTC
I have a Samsung ML-2525W at home, and while the wireless reviews suck, i'ver never had a problem with maintaining a connection. The printer is in standby 24/7 and comes to life when I need it to. It is a bit of a hassle to get set up on the wireless network, lots of conflicting directions, etc, but as long as you remember to use the USB cord to configure the device (NOT the network) and remember that only one interface can be used at a time (ie you cannot test the wireless while connected to USB) you will be fine.
All in all i like the printer a lot.
Feb 8, 2012 at 7:55 UTC
We actually had our VP's printer on the LAN and other people kept printing to it by mistake, so we ended up just hooking it locally to her computer which has worked much better.
I am not sure how it would work on an office wireless network, but I just purchased an Epson 545 (after getting advice from the people here) for home use and I love it. The 645 is the next model up and does automatic duplexing. My husband was able to print from his iPhone within minutes of us getting it set up. It also has scan/copy/fax features, which may be handy for him.
Feb 8, 2012 at 8:01 UTC
I have one of these in the house and use it wireless :
never been an issue for me.
Feb 8, 2012 at 8:15 UTC
Brother is good in these situations. Cheap, good, and they just work. Check out Newegg. Non-Wireless ones can be had for less.
However, any IT director would be sad to know they could have had a perfectly good HPLJ4si.
Feb 8, 2012 at 8:18 UTC
Something along those lines I would just install it as a "local printer" using the tcp/ip address and use a network cable. Never would have thought to put one of the "little ones" on a print server. I just rolled out a CP2025 for the business manager here, got a little netgear switch (~$25) and ran the second cable to the back of the printer. Works like a champ and the other people who need to "send" him documents via paper can do it straight to his desk, we just install the printer for them as well. Cuts down on the misdirected print jobs :-)
Do NOT get a 2015 (or anything else in the 2K series)!!! The drivers are all host-based and have wreaked nothing but havoc on our dedicated print server.
Feb 8, 2012 at 9:01 UTC
If it's going to be on his desk just hook it up via USB and forget it. One less wireless device to support and one less wireless network (albeit ad hoc) floating around your office to confuse all of your users using wireless devices.
Feb 8, 2012 at 11:55 UTC
ICT Solutions is an IT service provider.
I would say that any HP wireless capable printer would be just fine. I have used and supported them extensively and they work well. They also have a cool feature called eprint that allows printing from any mobile device to that printer and you can control all sorts of setting on it as well.
Feb 8, 2012 at 12:36 UTC
I think the bad reviews are from people that didn't RTFM.
Feb 8, 2012 at 12:51 UTC
I am not a fan of the software HP and most other manufacturers require for wireless and/or wireless all-in-ones.
Feb 9, 2012 at 6:43 UTC
At home, I use a Samsung SC-4500W, it is assigned a static IP by my Airport Extreme router and I have never had a problem printing to it wirelessly.
I have read online about people who have the same model and have all sorts of issue, I think it just comes down to that they need to update the drivers and assign a static IP.
looks amazing, has scanner and document copier built in
papper tray is too small.
Feb 9, 2012 at 7:29 UTC
Thanks for all the replies!
He wants a small foot print, doesn't want wires strewn across his desk and isn't concerned about print quality or speed. It just needs to do B&W and color no scanning or faxing.
Feb 9, 2012 at 7:44 UTC
I recently purchased HP 8500A printers they are Wireless have touch screen panels etc. The only quirk is the Scan to Computer from the Printer touch panel sometimes looses its configuration. This could be fixed via firmware but I haven't seen any updates on it yet. You can still scan from your computer.
I wanted to get a printer that will have the same Ink Supply for a long time.
I had my Vendor check with HP and they guarantee ink supplies for this printer for the next 5+ years.
I threw out a bunch of Lexmark All-In-ones because I could no longer source ink for them. They were in great shape and worked just fine, but useless without ink.
Feb 9, 2012 at 8:15 UTC
HP and Dell are the best. Reliable.
Feb 9, 2012 at 8:48 UTC
I agree with the responses so far. I have had great luck with HP's line of wireless all in one printers. They have the USB option as well. lot's of features and easy configuration through a web interface. It's senseless to drill a hole in the desk with other options available.
Managers typically need a personal printer for privacy issues. For example, HR might need to print out a termination letter etc. This isn't something that should be sent to a network printer in the main hallway. So the need for is valid. Good luck I'm sure you will find a great solution that works best for your needs.
Get a decent network laser printer and connect a wireless AP to the network card of the printer. Then connect the wireless AP to your company's wireless.
We do this all of the time for our clients who want decent printers connected wirelessly.
Feb 9, 2012 at 8:59 UTC
I gave my CEO a LaserJet Pro P1102w a bit back. Runs fine.
Feb 9, 2012 at 9:17 UTC
We use Brother HL2777w, but it is B&W. Installing it was quick using the included drivers.
Feb 9, 2012 at 9:22 UTC
Ah that reminds me at home we run a Brother 2270DW in the office. I don't use it much as the wife is in the office more than I am, but it seems to work fine as well.
Feb 9, 2012 at 9:38 UTC
+1 for HP 1102w
minimal drivers required. I set one up where it was going to cost more than the printer to get a cable dropped. Printer is on the w2k8r2 print server and XP and Win7 32 and 64 bit clients can print to it through the printserver. Only time I've had a problem is when somebody tries connecting with a USB cable....
Feb 9, 2012 at 9:55 UTC
+1 for a HP P1102W. I have 3 running with wireless and they work like a champ.
This discussion has been inactive for over a year.
You may get a better answer to your question by starting a new discussion.


text:
My local pastry instructor gave me a recipe for this icing. I don't take classes but they still throw little lessons my way here and there if I ask enough questions ( )
Anyway, last night a whipped up a batch hoping to practice some techniques (namely the rope border and my roses) but the instructions the instructor wrote down are a little bit off. It says it takes a tsp of salt, and 2 tsp of flavor but it doesn't tell me when to put the salt in. I usually default to putting it in with the shortening but last night I forgot about it and had already started adding sugar when I remembered.
Now my icing has a very distinct taste of salt to it. Is this because I put it in too late? Is there any way to fix it?
Quote by @%username% on %date%


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- #6 - Best Conversion Optimization Company USA, Jun 2017
- #7 - Best Multilingual SEO Company USA, Jun 2017
- #7 - Best Mobile Marketing Company USA, Jun 2017
- #10 - Best Enterprise Web Design Company USA, Jun 2017
- #6 - Best Conversion Optimization Company USA, Jul 2017
- #6 - Best Pay Per Click Management Company Australia, Jul 2017
- #7 - Best Multilingual SEO Company USA, Jul 2017
- #7 - Best Mobile Marketing Company USA, Jul 2017
- #8 - Best Shopping Feed Management Company USA, Jul 2017
- #6 - Best Enterprise Social Media Company USA, Jun 2017
- #6 - Best Pay For Performance SEO Company USA, Jun 2017
- #6 - Best Pay Per Click Management Company Australia, Jun 2017
- #7 - Best PPC Remarketing Company USA, Jun 2017
- #8 - Best Link Building Company USA, Jun 2017
Key People at Netmark
Netmark.com is a digital marketing agency that helps companies use their Internet presence to meet their business goals. Netmark was founded in 2007 by Internet entrepreneur and pioneer Chad Heath with a primary focus on Search Engine Optimization. Over the years, however, our skills and abilities have grown to match the needs of our clients. We now offer a wide range of digital marketing services, which allows us to integrate various marketing methods in order to better serve our clients.
The Internet marketing industry is constantly changing, constantly adapting to shifting demands. Therefore, we work to implement dynamic marketing strategies on behalf of our clients that are "future-proof" and "penguin-proof." Additionally, we understand that your Internet presence is about more than just rankings. That's why we don't limit our marketing focus to search engine rankings or even conversion rates. Instead, we help our clients focus on using their Internet presence to accomplish their specific business goals. Let us help your Internet presence meet your business goals!
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Our SEO services begin with an audit of the client's current situation, followed by a campaign development that creates a unifying strategy across various marketing methods. We then fortify the client's site so that it is search engine friendly and follows SEO best practices. If link detoxification is needed, that process is started while we fortify the client's site. Once we have finished fortification, we move forward with planning, producing, and promoting content assets for the client.
We have found that implementing the right strategy is critical to the profitability of a company's PPC campaign. That's why we use various methods to improve each PPC account, including A/B testing, correct targeting, keyword grouping, filtering, bid management, and more. At Netmark, we don't guess when it comes to PPC. We collect and analyze more information than any other PPC agency so that we can provide the best service possible to our clients.
Social Media is a great marketing channel for many companies, but it's not right for everyone. At Netmark, we believe that a company's use of Social Media should be methodical and have a clear purpose. Our strategists help our clients set clear campaign objectives that lead to the best results in the shortest possible time.
CRO focuses on improving a client's website in order to increase conversions without necessarily increasing visitors to the site. We begin by using our experience to determine what we believe may improve a site's conversion rate, then determine what we can test to support our hypothesis. This is followed by making the appropriate changes to the site and beginning conversion testing. While we are running our tests, we collect and analyze data in order to determine any changes in conversion rate and make further adjustments as necessary.
The websites we design are built on a solid foundation that follows SEO best practices in order to make the client's website easy to find. We begin with a sitemap so that everything is laid out in a format that is easy to use. The client chooses the style, colors, and fonts that will be used to create the site. Our people then create a base look for the site that is approved by the client before we build and launch the full site.
- E-commerce Parking Service Company was experiencing low traffic after Google release and Penguin update, and was looking for us to restore/improve traffic to where they were before the Google release. Download
- IT Services Client contacted us to help improve and generate more qualified leads for their niche market. Prior to working with us and had mostly acquired new clients by word of mouth. Download
- IT Support Customer wanted us to help improve organic traffic as well help establish traffic through social. Download
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Client Reviews on Netmark
Updated Mar 4, 2016
Help Us Help The Community
If you're a client of Netmark, we would like to hear about your experiences. Submit a review below and have your review made available on this page to help others make a purchasing decision.Write Review
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Ratings Trends
- Amazing - by Isaac Moan, on Jan 28, 2015
- Great company to work with - by Mike Toombs, on Jan 28, 2015
- These guys are the real deal - by Zack, on Jul 25, 2013
- Great Communication - by Chris, on Jul 21, 2015
- A client for life - by Anthony Lyons, on Jun 16, 2013
by Sarah, on March 4, 2016
We have switched account managers multiple times with little understanding why or how. Things started off great but have gone downhill a lot. Reports are late, deliverable items fall off and project management is lacking. Make sure you have support and contacts outside your account manager. The value for the money is not there. Sad because things started well and really have gone down and they are not doing much.
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Great Communication
by Chris, on July 21, 2015
I have used a few SEO companies in the past, but all of them failed miserably. When I decided to start working with Netmark, I found out what an SEO company should be like. They were great at communicating, even if there were problems. Now I am ranking top 3 on Google.
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Great company to work with
by Mike Toombs, on January 28, 2015
It's pretty easy to see the daily calls we get from our good online placement we've obtained has made all the difference.
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by Isaac Moan, on January 28, 2015
The Average return was 100 to 150% on the Adwords campaign that we did with them. I love their communication.
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These guys are the real deal
by Zack, on July 25, 2013
I've been through a few different SEO companies that weren't able to provide "real" results. I wasted a lot of money on services from companies that didn't know what they were doing. So glad I found Netmark. I had just about given up on SEO and I'm so glad I didn't.
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A client for life
by Anthony Lyons, on June 16, 2013
I'm not the type to leave reviews, but I've been with Netmark for over 3 years now and they still continue to impress me. I started with search engine optimization and have never regretted the decision, but recently I finally broke down and took their suggestion to do pay-per-click. The first couple of months were just ok, but now I'm getting more business off of google adwords than I'm getting through organic traffic. I love the team that works on my account and couldn't be happier with the ROI. Other than a few hiccups here and there, which have never been a big deal, they have never let me down on anything. I'm looking forward to a long and prosperous future between our two companies and I would recommend them to anyone.
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Top SEO rankings and help with website threats
by Dominick, on April 26, 2013
When we hired Netmark they helped us find some issues with our site that was keeping us from ranking as well as helped us fix a site hack. They were quick with their reports and responses. We have been able to rank #1 for our primary keywords and #1 for many other keywords. We are happy with our services that we have gained from Netmark.
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Netmark was a pleasure to work with, very knowledgeable
by Big Rob, on June 8, 2012
They got me amazing rankings for such a good price. Definitely worth the price. If I can offer you one piece of advice, hire Netmark!
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Friendly and effective--what else is there?
by Lindsay, on December 14, 2011
Netmark Essentials gave our company the boost we needed to obtain a better presence on the web. They reworked our website making it more SEO compatible. Based on how we have climbed in the rankings, they have been effective in helping clients find our business. We are very satisfied with the work they have done and continue to do for us--and they do it in a personable, friendly manner. We will continue to use them for internet marketing.
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An SEO Company With A Proven Plan.
by Wayne, on December 2, 2011
SEO is not an exact science. What worked yesterday may not work today. Working with Netmark for the past 18 months has been an excellent experience. They developed a strategy, continually monitor and adjust the strategy to current best practices, and provide reports to show the strategy is progressing as planned. nnAfter gaining confidence using Netmark for SEO, I contracted them for a complete website update that went flawlessly. From site planning, merchant processing, custom coding, and redirects for a very complex site, we experienced zero down time and no surprises. I would trust any SEO/Website project to the team and Netmark.
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Great Results....Great Service
by Mike, on December 1, 2011
I am a local company and Netmark has helped us create a web site that my competition now copies. They have our services ranking #1 or #2 in each catagory. They keep us ranked thru their innovative approach to SEO. I highly recommend them to anyone wanting to gain a competitive edge in the market.
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Excellent to work with, Friendly service, Quick re
by Todd, on December 1, 2011
I have been working with Netmark for over a year now and I have Coe to trust their expertise with all things SEO. We work closely with Netmark for PPC, Page Linking, Remarketing Campaigns, and several other avenues. I love how easy to understand the monthly report is. I recommend Netmark as an SEO company to anyon who wants a positive experience
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Worth Every Penny!
by Jon, on December 1, 2011
We spoke with several SEO companies before choosing Netmark. We are so glad we chose Netmark. Netmark is extremely professional and very talented. Our rep, Jared, is very reliable and provides great suggestions. We have seen great success from the work they do for us. We have found many new customers, increased traffic to our website, and increased revenue. Netmark has been wonderful to work with!
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LOVE, LOVE, LOVE Netmark!!
by Lanae, on July 20, 2010
We love, love, love Netmark Essentials!! Because of their skill and knowledge, they have helped to build our company to where it is today. We are at the top of all the search engines for our keywords. Thank you, thank you to Netmark for being such a wonderful SEO Company!!
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Effective & Informative
by Tyson, on July 9, 2010
NetMark Essentials did a great job optimizing our Preventive Pest Control website for our target key words. We are getting mostly page one rankings in all of our markets. Chad and his team also went above and beyond by educating us on how we can maintain our own optimized campaigns. Thank you NetMark!
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BEST Web Design and SEO decision
by Brandon Schwartz, on July 6, 2010
This project was one of the most important, if not the most important, decisions I had to make for my business since its inception. I selected Netmark Essentials after researching companies for over six months since I wanted to make sure that I chose the best company for both value and performance for this crucial project. I am glad that I did since this decision turned out to be one of the best decisions I have ever made pertaining to my website and online presence. Nathan Hawkes had guided me from the sales process until project completion, providing above and beyond insight and assistance throughout the entire process. Chance Gurr was the web developer assigned to my account whom I had the privilege of working hand and hand with from the project's start to finish. Chance had exceeded my expectations every step of the way. The final product was a website that had functionality beyond my original vision for the site. I have also had the opportunity to work with Adam Hall on Local Area Guide. The excellent communication skills, extremely good work ethic, and core competencies exhibited by Nathan, Chance and Adam differentiates Netmark Essentials as one of the best website design and SEO companies in this industry.
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Great service and results!
by David Brown, on July 6, 2010
I am an attorney and have been through serveral marketing companies who did nothing so I was fairly skeptical of another one. However, everything has been beyond my expectations. Netmark was in constant communication with me about what they were doing and what I could expect and I have been very pleased with the work and the results. I highly recommend this company.
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SEO Rockstar
by Derek, on February 25, 2010
Netmark has taken my site from crickets chirping to a concert packed out with traffic. The investment was well worth it and has proved to be a succesful marketing tool for our business. I recommend everyont to use Netmark.
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Outstanding Results
by Dan, on December 2, 2009
I started working with Netmark after being referred to them by my Web Designer whom I had been working with for years. I started off just trying them out with the SEO for my site. My website now sits at #1 for many different competitive keywords like loan. I am truly very pleased with there work.
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Phenomenal Results! This is THE SEO company to lo
by Justin, on December 2, 2009
I'm proud to say that after only 60 days with this talented firm, my revenue more than tripled with from my website. I was previously spending somewhere in the realm of $13,000 monthly on my PPC, and really nothing towards SEO. I was already making a profit, so it was no big deal. Netmark has truly come through for us. I now am spending just under $5,000 monthly on PPC, but my ROI is almost 420%! I know right! My natural results for my rankings in the search engines are phenomenal. I don't have to spend as much with PPC now because a great deal of business comes right from the the search engines organic listings. I am very pleased. If you are searching around for a good marketing company, please take a second to look at Netmark Essentials.
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We focus on helping your online presence meet your business goals rather than focusing exclusively on rankings.
Our Internet marketing efforts are designed to be "future-proof" and "penguin-proof."
We have roughly 4 individuals on staff who have completed Google AdWords certification.
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Netmark is looking for someone with preferably at least 2yrs + experience managing successful PPC campaigns.Office: Idaho Falls, Idaho
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Netmark is looking for an Internet Marketing Specialist with 2 yrs+ of experience managing a successful SEO Campains.Office: Idaho Falls, Idaho
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text:
The revolution begins in high school
Leon Bronstein is not your average Montreal West high school student. For one thing, none of his peers can claim to be the reincarnation of early 20th century Soviet iconoclast and Red Army hero, Leon Trotsky. When his father sends Leon to public school as punishment for starting a hunger strike at Papa's clothing factory, Leon quickly lends new meaning to the term 'student union', determined as he is to live out his pre-ordained destiny to the fullest and change the world.
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Like footballs, crowd surfers, and open-book spelling tests, tapas are meant to be passed. Practice passing with a partner with today's Groupon: for $29, you get a tapas and paella meal for two at Oliva (up to a $74 total value). This deal includes the following dinner-menu items to share:
- Four tapas of your choice (up to a $52 value)
- An order of paella in the style of your choice (a $22 value)
Oliva thrills taste trekkers with small plates of Basque-inspired delicacies that have won the admiration of New York magazine. In the patatas bravas, potatoes dress to impress by donning paprika and aioli, and croquetas romance taste buds with a choice of serrano ham, salted cod, or free-spirited wild mushrooms. The paella de marisco combs the sea for the shrimp, mussels, calamari, and clams it needs to make tongues rejoice. Like record players on their lowest RPM settings, the flavors of the margaritas made from fresh-squeezed ingredients rotate daily.
Oliva's sultry atmosphere has won the hearts of romance seekers throughout the city, earning the restaurant the Best New York First Date Spot crown from Citysearch in 2008. The spicy sounds of live Latin jazz fill the restaurant multiple nights a week, tempting diners to share their hottest dance moves and air-sax solos.


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Garter stitch blanket by Sarah Hatton
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© S Hatton 13
Garter stitch blanket
Simple to make garter stitch patchwork blanket. Uses two balls each of two colours


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|Message view
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|"Brad Nicholes" <BNICHO...@novell.com>
|Re: Policies on binaries?
|Fri, 18 Nov 2005 22:31:51 GMT
>>> On 11/18/2005 at 12:39:44 pm, in message <email@example.com>, email@example.com wrote: > Roy's raised the recent issue that all ASF releases under his domain > (httpd project chair) should be reviewed -by at least three pmc members- > as well as the contributors and committers. > > This raises an obvious question; are binary distributions releases? Or > are the merely repackaging the source code that was already approved? > It seems none of the platform binaries are reviewed today. > > Either way, because it's sufficiently complex, I've required at least two > more +1's on a binary release for Win32, to avoid streams of bug reports. > Sometimes quirks happen to a binary distribution, and its better that it > never hit the mirrors, and is fixed quickly. > IMO, binary releases are simply repackaging of the source code that has already be approved and released. As for the NetWare binary release, since it appears that I am the *only* committer and/or member equipped to test the binary release, it would be extremely difficult to get 3 +1's. Therefore my only choice is the build it, test it and release it. Brad
|View raw message


text:
Laurel went on to further run by thatability it was her parent who'd basic had her make-believe to be a boy called Christophe in command to guard her and to form it easier to run her next to him on his spy missions. Later she told of her father's recent flood back and the agents thatability were after them both. "And now," she paused, confined within her own thoughts, "I must get to Town and point the transfer of war campaign and purloined polity documentsability to European country. Which channel I besides have to discover a double agent to France. So, obviously, the renegade will have his own agents looking for me as cured as my begetter."
The room was so silent thatability even the whispers of the kitchen wenchesability from below-stairsability could be heard in the liberty. Mount Athos stood and surveyedability his companions, his finding blue. "How do you consistency astir going to Calais?"
"Better than active wager on to City of Light and anyone tired. Could use a goodish adventure," Porthos spoke, and D'Artagnan seconded him heartily, ambitious his concerns for Constance departure from the subject in favor of the temptation of a polite antic.Post ads:
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They all looked at Aramis. Next to entire serenity he said, "You'll perceive no remonstrance from me. I say we go to Calais."
"Madame," Athos addressed Flowering tree near scrupulous courtesy disdain her claims to the label of mademoiselle, "allow us to fulfill your mission in Port and next see to it thatability all the information gets subsidise to the crowned head. We will get you to French capital and put you under the wadding of Monsieur de Trevilleability."
"No." She stopped him up to that time he went any additional. "I will not be disappeared at the back. I cognise thisability job, and you do not. I've mature up with the threat and the intrigue, and I'm the solitary one who can contact my father." Athos' external body part remained implacable, and Flowering tree wanted to cry in frustration, but she didn't have the punch left-handed to trim. Why did all man privation to fastener her distant and try to cherish her? Did theyability genuinely deduce she was so neat thatability she would hairline fracture any easier than a man? "If you head off in need me," she warned, "I will haunt you." Once she had cured amply.Post ads:
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However, the musketeersability did not cognize her, nor did theyability cart her monitory earnestly. Once theyability gone for Port cardinal years later, theyability vanished her at the rear near an bodyguard repute primed to appropriate her to National capital. It was an steer she'd engender convinced she avoided.
* * * * * * * * * * * *
The hot, wet wax pooled on the missive and the man ironed his ding to it, waterproofing the document steadily. He set the textual matter detour and reversed his concentration to more pressing matters such as as who he could find to regenerate Rochefortability.
Pursing his lips, he stopped open at the upper surface and looked final to the reports arranged upon his bureau. One, an old one, in relation to the modification of Lady de Winter, different the comparatively recent dodge of Clockmaker d'Anlass from a Geographic area prison, and another in connection with the war effort antagonistic European nation. Other yet revealing him thatability four musketeersability had dead their missionary station to Marseille, but instead of returning to National capital theyability had orientated in a path too far westerly to arrive at City of Light. He did not close to unexplored factors, especially once it preoccupied those officious musketeers-Athos, Porthos, and Aramis and thatability new musketeer: D'Artagnan. That one even more. He had been a great point the cardinal's diplomacy had been discomfited and had made High priest air the trick.
"Your preeminence." A shielder entered the study, and Cardinal Cardinal Richelieu granted him, requestingability what his business organization was. "There is a female present who requests to be admitted into your being. She would not confer on her term." As if greatly exhausted by the unremitting drudgery, he taught his in person shield to send her in, and he would clutch attention to detail of the position. He ever had to whip fastidiousness of everything yet.
The adult female sketched a idyllic bowing to the cardinal, and he ever so humanely kissed the tips of her fingers. "And what can I do for you?" Statesman inquired.
"It's what I can do for you," she said, pushful pay for her shawl.
"Milady de Season."
"I can see you essential have been advised of my dying. However, thatability rumour was a bit early. I survivedability my duck off the cliffs, and those musketeersability ne'er discomposed to bank check and discovery my natural object to kind confident thatability I was stone-dead." She paused as if reconsideringability for the briefestability of moments. "I agree to I could be comparatively an help to you."
"What makes you have an idea that thatability I need your unequaled talents, Milady? You erstwhile in your last foreign mission. One would not approaching to see you endure the outcome of different washout."
So attentive of the man to be intelligent of her eudaimonia. As if he of all time genuinely cared. Peeress made a far-sighted electric circuit in circles the room, on one's guard of reaggravatingability her a moment ago cured injuries. "So you repudiate thatability you're inquiring for subject matter on the Donald Robert Perry Marquis d'Anlass or on Athos, Porthos, Aramis, and D'Artagnan?"
"What can you grant me thatability my other agents cannot?" His high status challengedability the lady, his psyche already at carry out consideringability and discardingability the possibilitiesability.
"I can talk to you the simply girl of the marquis, and I can find the musketeersability in question. They will not await a lifeless woman to be following them and will not be observance for a lady. Plus, once I find them I can highly slickly break up any responsibility which may not, shall we say, be useful to your best ever interests."
"Ah," aforesaid Solon as he reseatedability himself and indicated thatability the blond-hairedability patrician be seated. "Perhaps we can come through to a reciprocally good agreement."
* * * * * * * * * * * *
"Did we put in the wrong place them?"
D'Artagnan gasped as Athos force his charger even beside the vernal man's. "Hard to tell," D'Artagnan responded as he wiped away the streams of precipitation thatability continuing to fall, exasperating to impenetrable his daydream. Ridiculous, really. He couldn't remember a rainier summer. "Aramis thinks we've gone the possible of the Cardinal's defender thatability was pursuing us."
The cardinal mounted men guided their horses through the mire of the roadworthy towards an inn and tap house. The horses wheezedability and cask their dress suit as if difficult to elan off the snappy of the tumbling river. With all maneuver mortal to shelter, the steeds snorted and apathy blew from their noses. Nor were their riders in so much a cut above form than the animals after their extensive pulling and their near-franticability undertake to evade the guards who'd been attemptingability to trail them.


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Home > Product Categories > Pro-Video > Video Over Cat5 & Fiber Extenders > Component Over CAT5 Extenders > B136-101
Item #: TRL-B136-101 MFG #: B136-101
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Tripp Lites B136-101 Component Video + Stereo Audio extender kit comes with both local and remote units, allowing you to place a TV, Projector, etc, up to 700 ft. away from the source. A 1080p (60Hz) Component Video and Stereo Audio signal can be extended up to 300 ft. when using 24Awg, Solid Wire UTP cable (Tripp Lite N202-Series); or, up to 400 ft. when using Zero-Skew UTP cable (Tripp Lite P524-01K). A 480p (60Hz) Component Video and Stereo Audio signal can be extended up to 500 ft. when using 24Awg, Solid Wire UTP cable (Tripp Lite N202-Series); or, up to 700 ft. when using Zero-Skew UTP cable (Tripp Lite P524-01K). Built-in RCA connectors plug directly into the source and display, without the need for additional cables....no power required. 1 year limited warranty.
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Lunch boxes make food taste better. Pokémon lunch boxes that include a a Poké Ball stamp for your sandwich give you a lunch that is the very best, like no lunch ever was. I'm sure that scientists are working around the clock to understand this phenomenon.
Pokémon Pikachu GoGo Lunch Box ($24.99)