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John Betts - Fine Minerals > Home Page > Minerals For Sale > Minerals from New York & New Jersey, US > Zeolite Minerals
This mineral specimen of Natrolite with Calcite from Millington Quarry, Bernards Township, Somerset County, New Jersey is available for sale from John Betts - Fine Minerals, mineral dealer located in New York City, New York.Follow on Facebook
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Detailed information on mineral specimen No. 14951:
|Minerals Species: Natrolite with Calcite.
Location of mineral deposit: Millington Quarry, Bernards Township, Somerset County, New Jersey.
Description: Lustrous acicular white natrolite crystals with a few translucent colorless calcite partial crystals on greenish basalt. The natrolite crystals are transparent in the upper halves and have pyramidal terminations. This quarry is now closed. All crystals are complete and undamaged, except the outer edges where it was attached to surrounding matrix. Collected in October 2001 during MMMS field trip.
Overall size of mineral specimen: 4x3x2 cm.
Size of individual crystals: 1-3 mm
Price: $22 (plus shipping).
Miniature-sized Specimen
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© 17 March 2017 John Betts -
Fine Minerals, New York , NY - All
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The minerals illustrated on this site were purchased from collectors or wholesale suppliers for resale purposes. The owner of this site did not collect the minerals and collectors should not assume access is permitted to the property based on inclusion in this site. Please contact the property owner to obtain legal permission before entering private property.


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Like a long-running love story from your favourite soap, the story of NFC and the iPhone 5 really is keeping us glued to our (office) seats, taking new twists and turns as every week passes. We left the story about 10 days ago as you might recall, with Apple concerned about a lack of a standard for NFC across the industry. At that point, we thought it was all over. But the China Times has just raised our hopes of a return.According to Crave, the China Times is now claiming that the new iPhone will support for Near Field Communication (NFC) technology. It also claims the new model will have a 4-inch display and a reworked antenna design. No surprises on that last count. How does it know? Well, it says that the iPhone 5 is actually in 'trial production', and has a 'metal chassis to improve antenna sensitivity'. It also says the 4-inch screen will be scratch-resistant.
Downside? Your annual upgrade might be a little later this time, with those same sources claiming a launch will be in the third quarter of this year. So maybe a July launch, with a shelf date of late summer.All of it makes sense, with the possible exception of NFC. Early reports indicated Apple had a strategy in place for its introduction - using iTunes gift card balances and the credit card info Apple already has from you to make swiping payments at compatible retail outlets. There was even talk of loyalty credits and points to sweeten the deal.However, those more recent reports claimed Apple had made it clear to operators that it was not progressing with NFC. Will the technology be in there, but not be used initially? Or is Apple throwing up some smoke and mirrors to journalists? We honestly don't know, but NFC is looking a lot more likely today than a week ago. The truth will probably only be revealed in Steve Jobs' summer keynote.

subset: commoncrawl


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|Publication number
|Publication type
|Application number
|Publication date
|Feb 21, 2006
|Filing date
|Feb 19, 2002
|Priority date
|Jun 19, 2001
|Fee status
|Also published as
|Publication number
|Barbara Wagner, Ming Xu, Kimberlee Thompson
|Original Assignee
|Barbara Wagner, Ming Xu, Kimberlee Thompson
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (42), Referenced by (37), Classifications (28), Legal Events (6)
|External Links: USPTO, USPTO Assignment, Espacenet
This application claims priority of PCT/US01/19648, filed 19 Jun. 2001.
Transfer processes involve physically transferring an image from one substrate to another and can be achieved in several ways. One method is melt transfer printing where a design is first printed on paper using a waxy ink. Melt transfer printing has been used since the nineteenth century to transfer embroidery designs to fabric. A design is printed on paper using a waxy ink, then transferred with heat and pressure to a final substrate. The Star process, developed by Star Stampa Artistici di Milano, uses a paper that is coated with waxes and dispersing agents. The design is printed onto the coated paper by a gravure printing process using an oil and wax based ink. The print is then transferred to fabric by pressing the composite between heated calendar rollers at high pressure. The ink melts onto the final substrate carrying the coloring materials with it. Fabrics printed in such a method using direct dyes are then nip-padded with a salt solution and steamed. Vat dyes can also be used in the ink, but the fabric must be impregnated with sodium hydroxide and hydros solution and steamed. The residual waxes from the transfer ink are removed during washing of the fabric.
Conventional heat-melt thermal printing uses primarily non-active wax materials such as hydrocarbon wax, carnauba wax, ester wax, paraffin wax, etc. as heat-melt material. Though these wax or wax-like materials serve the purpose of heat-melt very well, they present problems when the product is used in a further transfer process, especially when the image is transferred to a fibrous material, such as a textile. The conventional wax materials are not chemically bonded or otherwise permanently bonded to the substrate, but are temporarily and loosely bound to the final substrate by the melting of wax during the transfer process. The resulting image is not durable, with the wax materials being washed away during laundering of textile substrates on which the image is transferred, particularly if hot water is used, along with the dyes or colorants which form the image in the thermal ink layer. Since, in most cases, the ink layer composition has a major percentage of wax or wax-like material, and the colorants used in such composition are either wax soluble and/or completely dispersed in wax material, the associated problems of poor wash fastness, color fastness, and poor thermal stability, of the final product result in rapid and severe image quality deterioration during the usage of the product.
Another method of transfer printing is film release transfer. Here the image is printed onto a paper substrate coated with a film of heat tackifiable resin. Upon application of heat and pressure to the back side of the image, the entire film containing the image is transferred to the final substrate. A process of thermal transfer wherein the ink physically bonds to the substrate is described in Hare, U.S. Pat. No. 4,773,953. The resulting image, as transferred, is a surface bonded image with a raised, plastic-like feel to the touch. Thermal transfer paper can transfer an image to a final substrate such as cotton, however, this method has several limitations. First, the entire sheet is transferred, not just the image. Second, such papers are heavily coated with polymeric material to bind the image onto the textile. This material makes the transfer area very stiff and has poor dimensional stability when stretched. Finally, the laundering durability is not improved to acceptable levels. The thermal transfer paper technology (cited Hare patent) only creates a temporary bond between the transfer materials and the final substrate. This bond is not durable to washing.
Another method of transfer employs the use of heat activated, or sublimation, dyes. One form of an appropriate transfer process using sublimation inks is described in Hale, et. al., U.S. Pat. No. 5,601,023, the teachings of which are incorporated herein by reference. In this situation, an image is printed onto an intermediate medium, such as paper, followed by application of heat and pressure to the back side of the intermediate medium while in contact with a final substrate. The dyes then vaporize and are preferentially absorbed by the final substrate. Sublimation dyes yield excellent results when a polyester substrate is used and are highly resistant to fading and abrasion caused by laundering. These dyes, however, have a limited affinity for substrates other than polyester, and give poor results on natural fibers such as cotton and wool.
A method of preparing an image receiving sheet for sublimation transfer utilizing isocyanate groups is described in DeVries, U.S. Pat. No. 4,058,644. Here, a polyisocyanate is reacted with a polyol to form a polyurethane containing free or blocked isocyanate groups. A print paste containing this polymer along with a sublimation dye is coated onto a paper substrate via roller coating, brush coating, silk screening, or similar method. The image may then be heat transferred to a cotton substrate. The application of heat to the back side of the printed image activates the sublimation dye as well as the blocked isocyanate groups. The isocyanate groups become unblocked at the transfer temperature and available to react with hydroxyl groups on the cellulose fibers, therefore forming a chemical bond with the cellulose fiber.
DeFago, et. al. in U.S. Pat. Nos. 3,940,246 and 4,029,467 also take advantage of the reactivity of isocyanate groups. Here, sublimation dyes containing active hydrogen may be combined in a print paste with a free or blocked isocyanate. The print paste is coated on a carrier sheet by a process such as silk screen, planographic, or relief-printing, then heat transferred to a textile substrate. The isocyanate groups may react with the active hydrogen on the sublimation dye and/or with an active hydrogen on a final substrate.
Yoshimura in U.S. Pat. No. 5,432,258 describes the use of a thermosetting adhesive layer coated onto a printed image, then heat transferred onto a ceramic substrate. The thermosetting adhesive layer contains an alkyl (meth)acrylate polymer and/or α,β-unsaturated carboxylic acid and a cross-linking agent, such as an isocyanate. Upon heat transfer, the isocyanate reacts with the hydroxyl and carboxyl groups of the alkyl (meth)acrylate and α-β-unsaturated carboxylic acid to form a resin that enhances adhesion of the image to the ceramic substrate.
The present invention relates to an intermediate medium for energy transfer of a digitally printed image to a final substrate. The ink used in printing the image may be any type known in the art, such as aqueous or solvent ink jet, wax thermal, phase change or laser and may be comprised of any type of colorant, including pigments or dyes. The intermediate medium is comprised of a base sheet and an image receiving layer or layers containing compounds selected from each of two chemical groups. The first group comprises compounds with functional groups capable of reacting with active hydrogen, such as isocyanate or epoxy groups. The second group comprises compounds with functional groups containing active hydrogen, such as hydroxyl or amino groups, or compounds with functional groups containing active hydrogen after a conversion process, such as anhydride groups.
To prevent premature reaction, these functional groups are protected by either a blocking group, or by the presence of a physical barrier, such as encapsulating agents. The protecting agents may be removed by the application of energy, such as heat, or other physical means.
After an image is printed onto the intermediate medium, the image may be transferred to a final substrate by the application of energy, such as heat, and pressure to the back side of the intermediate medium. The temperature presented during the heat transfer, or activation, step of the process is at or above the temperature necessary to unmask the protecting groups in the image receiving layer and/or layers of the intermediate transfer medium, and above the temperature at which printing onto the medium occurs. Bonding of the color images of the present invention is provided by the reaction between compounds selected from each of the two chemical groups. In addition, an active hydrogen containing final substrate, such as the hydroxyl groups of cotton or the amino or thiol groups of wool, may contribute to this binding process and provide additional binding sites for the final image. The transferred images so produced have a soft hand and excellent fade and abrasion resistance.
Additional optional materials may be included in the intermediate transfer medium which may be combined with either or both of the above two chemical groups, or applied as separate layers. Examples of such components are a thermally expandable material, an exothermic chemical, a release agent, and/or absorbent material.
In one embodiment of the present invention, an intermediate transfer medium (1) is prepared consisting of a first base layer (2), a second layer containing a compound or compounds capable of reacting with active hydrogen (3), which hereinafter may be referred to as an isocyanate or polyisocyanate, and a third layer containing a compound or compounds containing active hydrogen (4), which hereinafter may be referred to as a polyol (
In another embodiment of the present invention, an intermediate transfer medium (6) is prepared consisting of a base layer (7), followed by a single layer (8) comprised of compounds capable of reacting with active hydrogen and compounds containing active hydrogen (
In a preferred embodiment of the present invention, an intermediate transfer medium (10) is prepared consisting of a first base sheet (11), a second layer containing a compound or compounds containing active hydrogen (12), followed by a third layer containing a compound or compounds capable of reacting with active hydrogen (13) (
In a further embodiment of the present invention, other layers may be added to the intermediate transfer medium. Such layers include, but are not limited to, an expanding layer, exothermic chemical layer, release layer, and/or absorbent layer.
In another embodiment of the present invention, some or all of the materials used in the above mentioned additional layers may be incorporated into the isocyanate and/or polyol layers. An example depicting the above two embodiments is illustrated in
Bonding and/or crosslinking of the color images of the present invention are provided by the reaction between compounds selected from each of two chemical groups. The first group comprises compounds with functional groups capable of reacting with active hydrogen, such as isocyanate or epoxy groups. A preferred set of compounds comprising isocyanate groups is referred to as polyisocyanates. The second group comprises compounds with functional groups containing active hydrogen, such as hydroxyl, amino, thiol, carboxylic acid groups, or compounds with functional groups containing active hydrogen after a conversion process, such as carboxylic anhydride groups. A preferred set of compounds comprising hydroxyl groups is referred to herein as polyol.
In most transfer applications, reaction and bonding of the ink or image to the receiving substrate at the time of printing is not required. The ink will sufficiently attach to the receiver substrate or intermediate medium at the time of printing. In wax thermal printing, for example, the residual wax will sufficiently attach the colorants to the intermediate medium and preserve the image for subsequent transfer of the image. Permanent bonding at the time of printing onto the receiving substrate or intermediate medium would prevent subsequent transfer of the image from the receiving substrate or intermediate medium to the final substrate, and is undesired.
To achieve reaction at the desired time, at least one of the reactive groups is protected either by blocking agents, or by a physical barrier, such as encapsulating agents. The protecting or blocking agents are preferably removed by the application of energy, such as heat. Blocking as referred to herein means chemical blocking by means of a blocking agent. A polyisocyanate, for example, may be internally blocked or externally blocked. Internally blocked, also known as blocking agent-free, polyisocyanates are generally composed of two or more isocyanates forming a ring structure. The ring is relatively unstable to heat and at an appropriate temperature will break down to form the original free isocyanates. An example of an internally blocked polyisocyanate is the isophorone diisocyanate product, Crelan VP LS 2147 from Bayer.
A compound which is chemically blocked or physically encapsulated is referred to herein as protected. Other initiation processes may include, but are not limited to, radiation, chemical, pressure, and/or combinations thereof.
The base material will typically consist of a sheet material which can be transparent, translucent, or opaque. Useful transparent or translucent materials include, for example, cellulose acetate, polyethylene terephthalate, polystyrene, polyvinylchloride, and the like. Useful opaque materials include, for example, paper made of natural cellulose fiber materials, polyethylene-clad paper, opaque filled paper, and the like.
According to the present invention the base sheet may be coated firstly or secondly with a layer of polyisocyanate, or with a combination of polyisocyanate and polyol. Polyisocyanates suitable for the present invention are aliphatic and/or cycloaliphatic and/or aromatic polyisocyanates. Particularly preferred are polyisocyanates in which all the isocyanate groups are attached to aliphatic carbon atoms. Aliphatic polyisocyanates suitable for the present invention include those having the structure:
where n is an integer from 2 to 16, and preferably 4 or 6, i.e., tetramethylene diisocyanate and hexamethylene diisocyanate (HDI). Examples of other suitable aliphatic and cycloaliphatic isocyanates are: 1-isocyanato-3-isocyanatomethyl-3,5,5-trimethylcyclohexane (known commercially as isophorone diisocyanate (IPDI)), trimethylhexamethylene diisocyanate, the isomeric bis(isocyanatomethyl)benzenes and toluenes, 1,4-bis(isocyanatomethyl) cyclohexane, 4,4′-methylene bis(cyclohexylisocyanate), cyclohexane-1,4-diisoyanate, and the like. Such polyisocyanates may be used either alone, or in a mixture with one or more of the other polyisocyanates listed above.
Examples of aromatic isocyanates suitable for the present invention are 2,4-toluene diisocyanate, 2,6-toluene diisocyanate, mixtures of 2,4- and 2,6-toluene diisocyanate, 4,4′-diphenylmethane diisocyanate, dianisidiene diisocyanate, and the isomeric benzene, xylene and naphthalene diisocyanates. Such aromatic polyisocyanates may be used alone or in a mixture with other aromatic polyisocyanates, such as those listed above, or with the aliphatic and/or cycloaliphatic polyisocyanates listed above.
In place of polyisocyanates, polyisothiocyanates, or compounds containing both isocyanate and isothiocyanate groups may be used, for example, hexamethylene diisothiocyanate, tetramethylene diisothiocyanate, 2,4- and 2,6-toluene diisothiocyanate.
To prevent premature reaction of the isocyanates or polyisocyanates, blocked or masked isocyanates or polyisocyanates may be used. A blocked isocyanate, as used herein, is derived from the reaction of a blocking agent and an isocyanate, or may be internally blocked. Such blocked isocyanates reform the original isocyanate upon removal of the blocking agents such as by heating, or by heating with nucleophilic reagents, and may produce the same products as the reaction of the same nucleophilic reagents with the parent isocyanates. Blocking and isocyanate groups are specifically chosen so that the temperature for unblocking is in the range of 60–220� C. Unblocking temperatures lower than 60� C. do not provide suitable storage stability for the printed intermediate medium and/or images printed thereon. In addition, the temperature required to remove the protecting agents from these chemical groups must be greater than the temperature at which printing onto the intermediate medium occurs. Typical heat transfer temperatures are in the range of 175–220� C., and therefore the unblocking temperature must be at or below this temperature. In addition, unblocking temperatures higher than 220� C. are undesirable since temperatures higher than this may damage the final substrate during heat transfer. Preferably, the unblocking reaction occurs upon the application of heat between 120� C. and 200� C.
Common examples of blocking agents include phenols and substituted phenols, alcohols and substituted alcohols, thiols, lactams such as alpha-pyrrolidinone, epsilon-caprolactam, mercaptams, primary and secondary acid amides, imides, aromatic and aliphatic amines, active methylene compounds, oximes of aldehydes and ketones and salts of sulfurous acid.
Catalysts may be included to speed up the cross-linking reaction between the compounds containing functional groups capable of reacting with active hydrogen and the compounds containing functional groups containing active hydrogen. Examples of catalysts for the isocyanate/polyol reaction include tertiary amines, such as triethylamine, triethylenediamine, hexahydro-N,N′-dimethyl aniline, tribenzylamine, N-methyl-piperidine, N,N′-dimethylpiperazine; alkali or alkaline earth metal hydroxides; heavy metal ions, such as iron(III), manganese(III), vanadium(V), or metal salts such as lead oleate, lead-2-ethylhexanoate, zinc(II)octanoate, lead and cobalt naphthenate, zinc(II)-ethylhexanoate, dibutyltin dilaurate, dibutyltin diacetate, and also bismuth, antimony, and arsenic compounds, for example tributyl arsenic, triethylstilbene oxide or phenyldichlorostilbene. Particularly preferred are dibutyl tin catalysts. Any amount of catalyst may be used which will effect the intended purpose. For example, dibutyltin dilaurate or dibutyltin diacetate may be used in a range of 0.5 to 4% by weight, based on the weight of the isocyanate.
According to the present invention, the above polyisocyanate may be a first or second layer on top of the base sheet. When the polyisocyanate layer described above is the first layer on top of the base sheet, the second layer may be comprised of polyol. When the polyisocyanate layer is the second layer, the first layer on the base sheet is the polyol. In addition to having separate polyisocyanate/polyol layers on the base sheet of the intermediate transfer medium, the polyisocyanate and polyol components may be combined and coated as a single layer on the base sheet. In a preferred embodiment of the present invention, the polyol comprises the first layer on top of the base sheet. The advantage of this arrangement is that the polyol acts not only as a cross-linking component with the polyisocyanate, but also serves as a release agent from the base sheet. Many polyols are wax-like materials which act as lubricants and release agents during the transfer of the printed image from the intermediate transfer medium to the final substrate.
Polyols suitable for use in the present invention may have a backbone structure of the polyether, polyester, polythioether, mixed polyester polyether or mixed polyether polythioether classes. Polyols with a polyether backbone are preferred. In general, polyols or mixtures thereof may have an average molecular weight from 500 to 50,000 and preferably, an average molecular weight in the range of 1,500 to 2,700. The resulting composition, with the rest of the components in the ink layer, is suitable for the digital printing process. The average molecular weight of the whole of all polyol compounds is defined as the sum of the product of the molecular weight and the mole fraction of each polyol compound in the mixture. A preferred embodiment of a polyol layer comprises a mixture of high molecular weight polyol compounds having molecular weights of 3000 to 10,000, and low molecular weight polyol compounds having molecular weights of not greater than 1000. It will be appreciated by one skilled in the art that the above list of suitable diols, triols, tetrols, etc. is not exhaustive, and that other hydroxyl-containing materials may be used without departing from the spirit of the present invention.
The polyisocyanate and the polyol compounds are preferred to have an average functionality between two and four. The ratio of the equivalents of isocyanate groups to the equivalents of hydroxyl groups may range from 1:2 to 10:1, preferably 1:1 to 2:1.
Additional layers may be present as part of the intermediate transfer medium. Such layers include, but are not limited to, an expanding layer, exothermic chemical layer, release layer, and/or absorbent layer. Materials used in the construction of any or all of these additional layers may alternatively be incorporated into the polyisocyanate and/or polyol layers. For example, a thermally expandable layer may be used separately or combined with the first layer applied to the base sheet to aid in the release of the printed image from the intermediate transfer medium. Foaming agents that evolve gas as the result of thermal decomposition are preferably used in as thermally expandable material. Examples are organic expanding agents such as azo compounds, including azobisisobutyroniltrile, azodicarbonamide, and diazoaminobenzene; nitroso compounds such as N,N′-dinitrosopentamethylenetetramine, N,N′-dinitroso-N,N′-dimethylterephthalamide; sulfonyl hydrazides such as benzenesulfonyl hydrazide, p-toluenesulfonyl hydrazide, p-toluenesulfonyl azide, hydrazolcarbonamide, acetone-p-sulfonyl hydrazone; and inorganic expanding agents, such as sodium bicarbonate, ammonium carbonate,and ammonium bicarbonate.
A thermally expandable layer may be produced which comprises volatile hydrocarbons encapsulated in a microsphere which bursts upon the application of heat. The gaseous products produced upon bursting expand the layer. Thermally expandable microcapsules are composed of a hydrocarbon, which is volatile at low temperatures, positioned within a wall of thermoplastic resin. Examples of hydrocarbons suitable for practicing the present invention are methyl chloride, methyl bromide, trichloroethane, dichloroethane, n-butane, n-heptane, n-propane, n-hexane, n-pentane, isobutane, isophetane, neopentane, petroleum ether, and aliphatic hydrocarbons containing fluorine such as Freon, or a mixture thereof.
Examples of the materials which are suitable for forming the wall of the thermally expandable microcapsule include polymers of vinylidene chloride, acrylonitrile, styrene, polycarbonate, methyl methacrylate, ethyl acrylate and vinyl acetate, copolymers of these monomers, and mixtures of the polymers of the copolymers. A crosslinking agent may be used as appropriate. The diameter of the thermally expanded microcapsule is in the range of 0.1–300 microns, and preferably within a range of 0.3–50 microns, with a greater preference of a range of 0.5–20 microns.
Another example of an optional layer or material for use in the present invention is an exothermic layer or chemical. For example, the polyisocyanate and/or polyol layers may contain a heat sensitive material which undergoes an exothermic reaction upon application of sufficient energy. This energy, such as heat, would be externally applied to the back of the intermediate transfer medium during transfer of the printed image from the intermediate transfer medium to the final substrate. The additional heat generated by this exothermic reaction would effectively lower the amount of externally applied energy necessary to transfer the image from the intermediate transfer medium to the final substrate. Examples of such exothermic materials are aromatic azido compounds, such as 4,4′-bis(or di)azido-diphenylsulfone which will undergo thermal decomposition with the loss of molecular nitrogen. Other examples are aromatic azido compounds carrying a water-solubilizing group, such as a sulfonic acid or carboxylic acid group. These exothermic materials typically show an exotherm in the temperature range of 170–200� C. Typical heat transfer temperatures are in the range of 175–220� C. and thus sufficient to initiate this exotherm.
Aside from the polyol layer, an additional release layer may be desired. Examples of additional release agents include solid waxes, such as amide wax, polyethylene wax, and Teflon powder; phosphate- or fluorine-containing surfactants; and silicone-containing compounds.
If an absorbent material is used it may be part of the base sheet or a separately applied layer. The absorbent material helps to absorb the bulk of a liquid ink. Liquid inks that may be used may contain water, emulsifying enforcing agents, solvents, co-solvents, humectants, dispersants, and/or surfactants. Absorbent materials for ink printing papers are well known in the art and include, but are not limited to, porous materials such as silica gel, aluminum oxide, zeolites, porous glass; polymers based on methacrylate, acrylate, and the like; monomers with suitable cross-linking agents such as divinylbenzene; liquid swellable materials such as clays and starches, for example, montmorillonite type clays; fillers, such as calcium carbonate, kaolin, talc, titanium dioxide, and diatomaceous earth. The absorbent layer may contain an exothermic material as described above.
The above described polyisocyanate, polyol, and any other layers may be applied to the base sheet by any of the known methods, such as coating or spraying. Coating, for example, can be done either on a paper machine, off a paper machine, or a combination of both. The polyisocyanate and polyol components may be combined with a binder material to help anchor the components to the base sheet or other layers. Examples of such binding materials are known in the art and include water-soluble polymers, such as polyvinyl alcohol, modified polyvinyl alcohol, cellulose derivatives, casein, gelatin, sodium alginate, and chitosin; water-insoluble polymers such as styrene-butadiene copolymers, acrylic latex, and polyvinyl acetate; and chemicals which react irreversibly with water and/or solvents to render them non-volatile, such as polyvinyl alcohol.
An example of a coating which combines ingredients for a single layer coated on a base sheet, as illustrated in
Weight percent
The final substrates of the present invention may be, for example, a textile material, ceramic, metal, wood, or glass. Examples of suitable textile materials are cellulosic fiber, such as cotton, linen, or viscose; protein fibers, such as wool and silk; polyamide fiber, such as nylon 6.6; mixtures of cellulose or polyamide with polyester; and other synthetic fibers, such as acrylic and polyester. Preferred final substrates are those containing active hydrogen capable of cross-linking with a polyisocyanate, such as cellulosic fiber.
|Cited Patent
|Filing date
|Publication date
|Apr 5, 1976
|Nov 15, 1977
|Devries Roy F
|Sublimation transfer and method
|Jan 8, 1976
|Mar 14, 1978
|Ciba-Geigy Ag
|Sublimation transfer and diisocyanate fixation of amino- or hydroxy-containing anthraquinone dyestuffs and transfer sheets thereof
|Apr 16, 1981
|Nov 2, 1982
|Dai-Ichi Kogyo Seiyaku Co., Ltd.
|Aqueous emulsion of thermally reactive polyurethane composition
|Oct 7, 1983
|May 20, 1986
|Mitsubishi Paper Mills, Ltd.
|Ink composition utilized in lithographic printing and a lithographic printing process
|Jan 28, 1985
|Aug 12, 1986
|Diamond Shamrock Chemicals Company
|Aftertreatment of dyed cellulosic materials
|Jun 6, 1986
|Sep 15, 1987
|Hewlett-Packard Company
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|Jan 5, 1987
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|Polyvinyl Chemie Holland B.V.
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|Mitsubishi Paper Mills, Ltd.
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|Mobay Corporation
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|The Dow Chemical Company
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|Jul 18, 1989
|Basf Aktiengesellschaft
|Pigment printing pastes and dyeing liquors containing stable dispersions of finely divided solid polyisocyanates
|Nov 18, 1985
|Oct 17, 1989
|Union Carbide Corporation
|Photocopolymerizable compositions based on epoxy and hydroxyl-containing organic materials and substituted cycloaliphatic monoepoxide reactive diluents
|May 30, 1991
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|Bayer Aktiengesellschaft
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|Eastman Kodak Company
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|May 14, 1993
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|Research Triangle Institute
|Chemical vapor deposition of diamond films using water-based plasma discharges
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|Sony Corporation
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|Bayer Aktiengesellschaft
|Polymeric dyestuffs and their use in inks for ink jet printing processes
|May 12, 1995
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|Bayer Aktiengesellschaft
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|Nippon Paper Industries, Co., Ltd.
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|Sony Corporation
|Printing sheet and manufacturing method therefor
|Mar 13, 1996
|Mar 10, 1998
|Sun Chemical Corporation
|Water-based offset lithographic printing ink
|Mar 13, 1996
|Jul 14, 1998
|Sun Chemical
|Offset lithographic printing process with a water based ink
|Sep 30, 1997
|Dec 29, 1998
|E. I. Du Pont De Nemours And Company
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|Jan 5, 1996
|Mar 23, 1999
|Milliken & Company
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|Dec 19, 1996
|Nov 16, 1999
|E. I. Du Pont De Nemours And Company
|Ink-jet media
|Jul 31, 1997
|Mar 14, 2000
|Eastman Kodak Company
|Low heat transfer material
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|Apr 27, 1987
|Nov 4, 1987
|Sericol Group Limited
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|Jan 27, 1999
|Aug 4, 1999
|Canon Kabushiki Kaisha
|Image-transfer medium for ink-jet printing, process for transferring image, and cloth imaged by this process
|Title not available
|Apr 30, 1999
|Nov 11, 1999
|Sawgrass Systems, Inc.
|Reactive ink printing process
|Citing Patent
|Filing date
|Publication date
|Aug 18, 2008
|Jul 6, 2010
|Jodi A. Schwendimann
|Image transfer on a colored base
|Aug 18, 2008
|Jul 13, 2010
|Jodi A. Schwendimann
|Method of image transfer on a colored base
|Aug 18, 2008
|Aug 3, 2010
|Jodi A. Schwendimann
|Image transfer on a colored base
|Feb 21, 2008
|Aug 10, 2010
|Jodi A. Schwendimann
|Image transfer on a colored base
|Aug 4, 2004
|Nov 2, 2010
|Jodi A. Schwendimann
|Image transfer on a colored base
|Oct 31, 2007
|Apr 19, 2011
|Sensient Colors Inc.
|Modified pigments and methods for making and using the same
|Aug 22, 2008
|Jun 21, 2011
|Sensient Colors Llc
|Self-dispersed pigments and methods for making and using the same
|May 17, 2011
|Feb 21, 2012
|Sensient Colors Llc
|Self-dispersed pigments and methods for making and using the same
|Mar 8, 2011
|Apr 3, 2012
|Sensient Colors Llc
|Modified pigments and methods for making and using the same
|Oct 31, 2007
|Apr 24, 2012
|Sensient Colors Llc
|Inks comprising modified pigments and methods for making and using the same
|Nov 29, 2010
|Jun 12, 2012
|Jodi A. Schwendimann
|Image transfer sheet
|Jan 13, 2011
|Dec 18, 2012
|Mj Solutions Gmbh
|Image transfer material and polymer composition
|Sep 3, 2010
|Jan 29, 2013
|Jodi A. Schwendimann
|Image transfer on a colored base
|Apr 16, 2012
|Sep 24, 2013
|Jodi A. Schwendimann
|Image transfer sheet
|Nov 5, 2012
|Dec 24, 2013
|Mj Solutions Gmbh
|Image transfer material and polymer composition
|Jan 21, 2013
|Apr 22, 2014
|Jodi A. Schwendimann
|Image transfer on a colored base
|May 14, 2013
|Sep 9, 2014
|Jodi A. Schwendimann
|Image transfer sheet
|Jul 25, 2013
|Sep 1, 2015
|The Hillman Group, Inc.
|Automatic sublimated product customization system and process
|Apr 7, 2010
|Dec 29, 2015
|Sensient Colors Llc
|Self-dispersing particles and methods for making and using the same
|Nov 18, 2013
|Jan 5, 2016
|Mj Solutions Gmbh
|Image transfer material and polymer composition
|Jan 21, 2014
|Apr 26, 2016
|Jodi A. Schwendimann
|Image transfer on a colored base
|Jul 25, 2013
|May 10, 2016
|The Hillman Group, Inc.
|Integrated sublimation transfer printing apparatus
|Mar 31, 2015
|Jul 26, 2016
|Vivid Transfers, LLC
|Method of selectively transferring an image and heat-transfer assembly
|Apr 24, 2014
|Aug 2, 2016
|The Hillman Group, Inc.
|Modular sublimation transfer printing apparatus
|Jul 31, 2015
|Sep 20, 2016
|The Hillman Group, Inc.
|Automatic sublimated product customization system and process
|Jun 30, 2016
|Jan 17, 2017
|The Hillman Group, Inc.
|Modular sublimation printing apparatus
|Aug 4, 2004
|Mar 3, 2005
|Jodi A. Dalvey
|Method of image transfer on a colored base
|Feb 21, 2008
|Jun 26, 2008
|Schwendimann, Jodi A.
|Method of image transfer on a colored base
|Aug 18, 2008
|Dec 11, 2008
|Dalvey Jodi A
|Method of image transfer on a colored base
|Aug 18, 2008
|Dec 11, 2008
|Dalvey Jodi A
|Method of image transfer on a colored base
|Aug 18, 2008
|Dec 11, 2008
|Dalvey Jodi A
|Method of image transfer on a colored base
|Sep 3, 2010
|Dec 23, 2010
|Schwendimann, Jodi A.
|Image transfer on a colored base
|Nov 29, 2010
|Mar 24, 2011
|Jodi A. Schwendimann
|Image transfer sheet
|Jan 13, 2011
|May 12, 2011
|Williams Scott A
|Image transfer material and polymer composition
|Jul 11, 2008
|Sep 7, 2010
|Jodi A. Schwendimann
|Method of image transfer on a colored base
|Feb 9, 2005
|Jul 12, 2011
|Jodi A. Schwendimann
|Image transfer sheet
|Apr 7, 2010
|Oct 14, 2010
|Sensient Colors Inc.
|Self-dispersing particles and methods for making and using the same
|U.S. Classification
|428/32.51, 428/32.79, 428/32.78, 156/235, 427/152, 428/32.77
|International Classification
|Cooperative Classification
|European Classification
|Sep 22, 2003
Owner name: SAWGRASS TECHNOLOGIES, INC., SOUTH CAROLINA
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:WAGNER, BARBARA;XU, MING;THOMPSON, KIMBERLEE;REEL/FRAME:014524/0425
Effective date: 20030903
|Jun 20, 2006
Owner name: BANK OF AMERICA, N.A., SOUTH CAROLINA
Free format text: NOTICE OF GRANT OF SECURITY INTEREST;ASSIGNORS:SAWGRASS TECHNOLOGIES, INC.;TROPICAL GRAPHICS, LLC;REEL/FRAME:017811/0604
Effective date: 20060523
Owner name: BANK OF AMERICA, N.A.,SOUTH CAROLINA
Free format text: NOTICE OF GRANT OF SECURITY INTEREST;ASSIGNORS:SAWGRASS TECHNOLOGIES, INC.;TROPICAL GRAPHICS, LLC;REEL/FRAME:017811/0604
Effective date: 20060523
|Jun 1, 2009
|Fee payment
Year of fee payment: 4
|Mar 13, 2013
|Fee payment
Year of fee payment: 8
|May 17, 2013
Owner name: WELLS FARGO BANK, NATIONAL ASSOCIATION, SOUTH CARO
Free format text: SECURITY AGREEMENT;ASSIGNOR:SAWGRASS TECHNOLOGIES, INC.;REEL/FRAME:030427/0567
Effective date: 20130430
|Sep 30, 2015
Owner name: SAWGRASS TECHNOLOGIES, INC., SOUTH CAROLINA
Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:WELLS FARGO BANK, NATIONAL ASSOCIATION;REEL/FRAME:036719/0738
Effective date: 20150729


text:
November 7, 2008 in Hardware (E)
[prMac.com] Berlin, Germany - nova media today has dropped prices for its complete range of wireless modems for Mac OS X by an average of 16%. Mobile online access for Macintosh computers gets affordable with a price drop for wireless USB modems, PC-Card modems and ExpressCard modems from nova media.
"We offer wireless devices for every Macintosh", states Jan Fuellemann, PR spokesperson at nova media. "PC Datacards for PowerBook, ExpressCards for MacBook Pro and USB modems for every other Mac running Mac OS X 10.4.11 and higher. All devices offer fast download speeds with up to 7.2 Mbit/s and upload speeds with up to 1.4 Mbit/s, depending on the capabilities of the mobile network providers."
All devices include a full version of launch2net, the internet connect wizard for Mac OS X. launch2net features a one-click connection to the Internet without the need to enter cryptic configuration details. The software already includes connection settings for most mobile network providers worldwide.
Price information:
* GlobeTrotter MAX HSUPA for PowerBook: Euro 178.00
* GlobeTrotter Express HSUPA for MacBook Pro: Euro 188.00
* ICON 401 USB Modem for MacBook and other Macs: Euro 168.00
All prices plus VAT if applicable and shipping costs.
The founders of "nova media Mobile Data Solutions GmbH" started their business in 1996 in Berlin. The company specializes on mobile data solutions for Mac OS X. More information online or phone +49 30 3909040.


text:
Hand Study by AetereWatch
©2011-2017 Aetere
pretty sick hand study if may say XD
I'm a sucker for a good hand study. The flopped over hand is always my favorite for some reason.
Great work!! Beautiful hands!
I adore hand studies!!!! and yours is amazimg!!!!!!
can't figure out where the coffee come in... I love hands this is a great study


text:
This article is a stub. You can help Camerapedia.org by expanding it.
The Nikon EF300 (also known as Nice•Touch 4) was a fixed focus compact camera for 35mm film, introduced by Nikon in 1997. It was made in China. A Quartz Date (QD) model was available. An autofocus version in the same body was the AF230.
- Lens: 29mm, f/4.5
- Integrated flash with guide number of 8m at ISO 100.
- EF300 (QD) (Nice•Touch 4) in the official Nikon Digital Archives.
- Nikon EF300 in Sylvain Halgand's collection.


text:
Photo Fun
Dextro Mind
- July 3, 2012
( 39)
Photo Fun is a photo editing tool that gives you a fun filled experience.
Take photograph, edit them & share them with your friend.
Take photograph, edit them & share them with your friend.
Galaxy s4 Um what did I just install...?...O yea a pic of a galaxy where I cant do any thing useless
Lame Dont get the use of this
Manaul Manirul
LAME! The whole menu was brush size , color, gallery or cam, and done & share. Did i miss somthing?
awesome app awesome app having great fun with photos.
Silver monk Awesome....app...for photo maniac
What's New
The world can be amazing when you do something strange
Put cute and funny doggy face, kitty face stickers on your selfie photos! ♡P123♡


text:
It appears Jaguars QB Blaine Gabbert could already be losing the grip on his starting job after the No. 10 pick of the 2011 draft passed for 2,214 yards, 12 TDs and 11 INTs in 15 games as a rookie.
Jacksonville signed former Dolphins starter Chad Henne on Wednesday, and he could push for Gabbert's role.
"He's coming in as a backup, competing for a starting job," new Jaguars HC Mike Mularkey said of Henne on Thursday. "Everybody comes in here to compete for a starting job. I hope that's the way it's always going to be. We don't want anybody here that's very comfortable and wants to be in a backup role, and never will.
"Chad knows his role, and Blaine and I had a conversation this morning that we are all on the same page of why he's here. Like I said earlier, we're very happy that he's here. He's going to help Blaine in his development and he's going to help our football team."
It wasn't a debacle of a debut for Gabbert, but he did struggle with footwork and accuracy (50.8% completion rate) during a season when fellow rookie QBs Cam Newton and Andy Dalton made the Pro Bowl.
Henne couldn't manage to stick in Miami after arriving as a second rounder in 2008. He has a 13-18 career record and has 31 career TD passes against 37 INTs. His turnover issues helped lead to his ouster from South Beach. But he hopes things pan out better in Northern Florida.
"All I know right now is I'm going to go in there and compete," Henne said . "I know I have an opportunity to compete, and that's what I'm looking forward to."
Nate Davis is a reporter, blogger and editor who's been at USA TODAY since 2000. He has covered the NFL since 2005. No, he did not play quarterback for Ball State. Davis' succession of our esteemed colleague Sean Leahy at The Huddle is considered a Brady-for-Bledsoe swap by most "insiders."More about Nate


text:
Listen to iFriendly audio.
Susan Michaels is the artist-in-residence at Keet Gooshi Heen elementary school. She's been teaching students traditional American country dancing. Her work culminates this Friday with a live barn dance for the students and general public (6:30 PM Fri Feb 14, Keet Gooshi Heen, no charge) with Sitka's contra band Fishing for Cats. Michaels hails from Los Angeles, where she's been calling dances for 30 years.


text:
Related Expert Areas
sore throat treatment
strep throat
cold pharmacology
Experts Only
Join our distinguished experts for sore throat jobs, projects and consulting opportunities.
Expert in Surgery, Clinical Trials Medical Device DevelopmentProfessor of Otolaryngology Head and Neck Surgery , Radiation Oncology and Oncology. Expert is a Past Chair Head and Neck Surgical committee and Surgical committee for major cooperative clinical trial group additional experience as co chair corporate ... See full profile
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Expert in Plastic Surgery and OtolaryngologyExpert has 21 years of experience performing plastic, cosmetic, and reconstructive surgery. He is located in the tri-state new york area and performs all surgeries in 3 accredited,outpatient, ambulatory surgical centers. These centers were designed, ... See full profile
New York (NY), USA
Expert in Facial Plastic Surgical Procedures, New Innovations and ProceduresExpert has been in private practice for 15 years. He is board certified in facial plastic surgery and otolaryngology-head and neck surgery. He performs over 400 surgeries per year in the related areas noted. He is a clinical assistant professor ... See full profile
Texas (TX), USA
Expert in Otolaryngology, Head and Neck Surgery, Plastic and Reconstructive SurgeryExpert, M.D., F.A.C.S., is board certified in otolaryngology as well as facial plastic and reconstructive surgery. He is also board certified and fellowship-trained facial plastic and reconstructive surgeon. He received his MD from Rush Medical ... See full profile
Expert in Rhinology (Nose and Sinus Surgery and Medicine), Allergy, General OtolaryngologyExpert's practice consists primarily of nasal (rhinology) care, including allergy testing and treatment. He is in academic practice and regularly lectures/teaches nasal as well as general otolaryngology concepts. Expert has numerous publications ... See full profile
Ohio (OH), USA
Expert in Otolaryngology, Facial Plastic Surgery, Accreditation of Outpatient Health Care FacilitiesExpert used to have a solo private practice, services for which included all aspects of medical and surgical otolaryngology, adult and pediatric audiology, neuro-otologic testing, hearing aid dispensing, and facial rejuvenation with injectables, chemical ... See full profile
Maryland (MD), USA
Expert in Medicine, Pharmacy, Pharmacology/Toxicology with Emphasis on Cannabanoids and OpioidsExpert is a practicing physician and pharmacist, who also holds a Master's of Science degree in Pharmacology and Toxicology. He has performed research in the field of Pharmacology with particular focus on drugs of abuse, cannabinoids and opioids. See full profile
Virginia (VA), USA
Expert in Medical Device Design and Manufacturing Care Treatment, Plastic Cosmetic SurgeryExpert is a Cleveland Clinic Health System fellowship trained Plastic and Reconstructive Surgeon who started his post graduate education at Yale University and then went on to receive his medical degree in Kansas City, Missouri. See full profile
Florida (FL), USA
Expert in Plastic and Reconstructive Surgery and Surgery of the HandExpert is a board certified plastic surgeon with 20 years of experience and has surgical expertise with almost all areas of plastic and reconstructive surgery. He is also an expert in microsurgery and has used his training to transplant tissues from ... See full profile
Washington (WA), USA
Expert in Clinical Anesthesiology, Surgical Recovery Room, Critical Care, Pain Medicine, Abused DrugCurrent Practicing Anesthesiologist responsible for caring for individuals that use abused drugs on a regular basis. These individuals have both medical and psychological problems resulting from both recent and long term abuse of drugs. See full profile
Connecticut (CT), USA
Expert in Chronic Respiratory DiseaseRespiratory system diseases; respiratory system disease therapy; allergen. Expert has over 25 years of experience as a clinical allergist specializing in chronic respiratory diseases. He is adept at the use of allergens, histamines and methacholine ... See full profile
California (CA), USA
Need the right expert in sore throat? We can help!
Intota is now ORC Expert Advisory Services


text:
Bike & Sports
Bike & Sports
The body gets revved up when the bike rests. The location and/or the facilities of these MoHo - Motorbike Hotels offer the best conditions for many physical and sports activities like hiking, walkin...
Bike & Family
Bike & Family
The combination of motorbike and family is real fun here. The children are well looked after when the parents are out touring. The offer at the MoHo - Motorbike Hotel is aimed at the entire family s...
The Motorcycle Hotel Obereggen stands on a sunny high plateau, away from any main roads. The hotel is a great place for tours on winding roads, with great panoramas near the highest glacier in the Dolomites, the jagged rock faces of the Sella mountain group, and along lots of Dolomite mountain pass roads into Trentino. Bolzano, Kaltern, Merano and Brixen are lovely destinations for day trips. The Hotel Obereggen offers wonderful views of the surrounding mountains.
With its emphasis on tradition, personal service, and exquisite meals and selected wines, the Motorcycle Hotel Obereggen makes sure that no biker stomach remains un-sated, and no thirst un-quenched. When it comes to tours, you can be confident of receiving expert advice and helpful tips.
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text:
The Sun font family
Corporate font of the computer company SUN Microsystems. Luc de Groot's type foundry 'LucasFonts' is the owner of the SUN font design such as the well-known Thesis font.The Sun font family includes several styles. Click one of the packages below to get more information about the Sun font (download version) you want:
Designed by Lucas de Groot.
Designed by Lucas de Groot.
More fonts:
Sultan, Sultania, Sumeria, Summer Solstice Value Pack, Summertime Value Pack, Sun, Sunamy, Sundance, Sunday Best, Syntax, Tashlim


text:
Updated to ics last night. All good so far but I have 1 : I am not a big fan of the inverted white text on black background (eg. Email app). I find it hard on the eyes. How to revert to Un inverted? :confused:
Sent from my DROID4 using Android Central Forums


text:
Today, I witnessed an elderly lady getting mugged. I ran over to the guy mugging her and offered him the money in my wallet in return for him leaving her alone. The old lady snatched my money and ran away with the mugger. What the hell just happened? FML
By No money, mo' problems / Tuesday 18 June 2013 22:01 / United States


text: Yet another Fogna-related side project from Bat Shit Records, though this one is a little different. While most of this crew's stuff tends to be marked by a heavy Rudimentary Peni influence (or at least what sounds like it to me), Spasma are much more straightforward, with a recording that very strongly recalls Poison Idea's classic Darby Crash Rides Again, perhaps mixed with some nasty early European hardcore like Agent Orange or Wretched. Regardless, this has absolutely perfect early 80s-sounding analog production and the songwriting is flat-out ripping from top to bottom... can't recommend this one highly enough.


text:
VPN as a redundant link for MPLS
I need some help regarding network design. We have 40 branches , each other connected by MPLS and also to the data centre. Now we want redundant link to connect other branches with the data centre. Each branches and data centre also having internet link.
We want to use IPsec/GRE tunnel to the other branches with the DC.Now the questions are..
1)Is it possible to use VPN tunnel as a redundant link so that when MPLS goes down the only tunnel comes up?
2)If MPLS and tunnel both work simultaneously is there any chances to formed loop in the network?
3)How much internet link BW generally require for branches to connect with DC?
Please guide in this issue..


text:
Get setup for the Industrial Internet
This article provides step-by-step instructions to register and install Predix, GE's brand name for their "Industrial Internet" sales.
Actions to get started:
- Slack channel setup
- Predix Account setup
- Select an approach to install 3rd-party utilities
- Hosting in the Cloud Foundry cloud
- Local install
- Devbox with pre-built virtual machines
I want you to feel confident that you've mastered this skill. That's why this takes a hands-on approach where you type in commands and we explain the responses and possible troubleshooting. This is a "deep dive" because all details are presented.
Like a good music DJ, I've carefully arranged the presentation of concepts into a sequence for easy learning, so you don't have to spend as much time as me making sense of the flood of material around this subject.
Sentences that begin with PROTIP are a high point of this website to point out wisdom and advice from experience. NOTE point out observations that many miss. Search for them if you only want "TL;DR" (Too Long Didn't Read) highlights.
Stuck? Contact me and I or one of my friends will help you.
Slack channel setup
Join the Intelligent-world Slack channel for Predix developers
Once you receive a confirmation email, activate the Slack app on your Mac or PC if you'd like to switch among differen Slack channels.
Click the "+" at the lower left corner.
Type in the teamdomain of "intelligentworld" and click Continue.
Type in the email you used to register and click Continue.
If you clicked "Send Magic Link", open the email and click "Sign into Slack".
That action opens browser for you to click "Launch Slack".
Choose whether to enable desktop notifications.
Now return temporarily to your browser to close the tabs to access Slack.
Predix Account setup
Click the link below to register for a Predix account at
QUESTION: After the free days, $ ___ per month?
Confirm phone and email while on the page.
A GitHub repo account needs to be specified.
PROTIP: Don't expect a response if you provide a gmail or hotmail account, even after phone ane email confirmation code confirmations. That's my personal experience
Wait for the confirm email from Predix. If you're deemed legitimate:
"Thanks for your interest in a Predix trial account. We'll validate your information, and will respond within five business days."
Wait for the email from Predix.
Each developer's GitHub account is granted access to the repository and a number of subrepositories:
Once approved, you can then enroll in training.
"Please connect to BlueSSO and go to training.predix.io. From there, log in with your Predix credentials and enroll in the "On-Demand" courses. This is where you will find access to the free eLearning videos."
Note that the training site is different from
After approval, you'll be able to post on the
Predix Developers Forum
Third-party components
- GIT, SVN, Pair Programming*,
- Environment Portability*,
- Multiple Sandbox Environments*
IDE / Editors:
- STS/Eclipse Spring framework
- Atom,
- Bluefish
- OpenOffice for spreadsheets
- PGAdmin3 1.20.0
Front End:
- Bower, NodeJS, Grunt,
- Firefox, Chromium browsers
- Apache OpenJPA persistence
Back End:
- Cloud Foundry CLI, User Authentication and Authorization CLI,
- Microsoft
- Java,
- Maven,
- Ruby,
- Python
- RabbitMQ Message Queue
- PostgreSql 9.3 and psql utilities,
- Couchdb
Big Data:
- Anaconda distribution of Python (Pandas, Scipy, Numpy, and sklearn)
Predix Components
Predix Machine 16.x,
Predix demo
Local install
If you're running on a Oracle/Red Hat Linux System
Eclipse STS IDE
This advises the use of STS
- Use an interest browser to the STS website.
- Select a download site to begin download. Wait for the file to download.
- Unzip
In Finder, navigate inside the folder, such as:
This contains the server.
Move and/or rename the folder according to your organization's standards.
- In Finder navigate to /Applications.
- Move (drag and drop) STS.app to /Applications.
- Open STS by double-clicking the icon.
- Click Open icon for first-time confirmation.
- Specify your workspace.
STS (Spring Tools Suite)
Included with STS (Spring Tools Suite) is the developer edition of Pivotal tc Server, the drop-in replacement for Apache Tomcat that's optimized for Spring.
The Spring Insight console, tc Server Developer Edition, provides a graphical real-time view of application performance metrics that lets developers identify and diagnose problems from their desktops.
Spring framework
The framework is based on the Java Spring framework, which many now consider "heavy".
This is surprising considering most others in their industry have gone to Python or React.
QUESTION: Why Spring and not Node or Python or React?
Maybe it's because there are more Java Spring developers unemployed than the other hotter frameworks?
Or that Spring is more "mature" as a framework since it's been around since the 90's.
During register for a Predix account, each developer's GitHub account is granted access to the repository and a number of subrepositories at
Cloud Foundry cloud
https://www.vmware.com/products/vfabric-tcserver/ Cloud Foundry is by VMware Pivotal is purchased as part of the VMWare Fabric containing the "VMware vFabric tc Server".
At https://github.com/cloudfoundry/cli/releases click the "Latest Release".
Use Homebrew:
brew tap cloudfoundry/tap
The response (on 7 July 2016):
==> Tapping cloudfoundry/tap Cloning into '/usr/local/Library/Taps/cloudfoundry/homebrew-tap'... remote: Counting objects: 7, done. remote: Compressing objects: 100% (6/6), done. remote: Total 7 (delta 0), reused 3 (delta 0), pack-reused 0 Unpacking objects: 100% (7/7), done. Checking connectivity... done. Tapped 2 formulae (33 files, 27K)
Install Command Line Interface:
brew install cf-cli
The response:
==> Installing cf-cli from cloudfoundry/tap ==> Downloading https://cli.run.pivotal.io/stable?release=macosx64-binary&version=6.20.0&source=homebrew ==> Downloading from https://s3.amazonaws.com/go-cli/releases/v6.20.0/cf-cli_6.20.0_osx.tgz ######################################################################## 100.0% 🍺 /usr/local/Cellar/cf-cli/6.20.0: 2 files, 22.1M, built in 18 seconds
cf help
The response expand the width of shell window to see:
NAME: cf - A command line tool to interact with Cloud Foundry
USAGE: cf [global options] command [arguments…] [command options]
VERSION: 6.20.0+25b1961-2016-06-29
GETTING STARTED: help Show help version Print the version login Log user in logout Log user out passwd Change user password target Set or view the targeted org or space
api Set or view target api url auth Authenticate user non-interactively
APPS: apps List all apps in the target space app Display health and status for app
push Push a new app or sync changes to an existing app scale Change or view the instance count, disk space limit, and memory limit for an app delete Delete an app rename Rename an app
start Start an app stop Stop an app restart Restart an app restage Restage an app </pre>
### Sample app #
In an internet browser, explore sample apps in Cloud Foundry's sample organization:
Back at the Termial:
Clone the sample app:
mkdir ~/gits/pivotal
cd ~/gits/pivotal
git clone https://github.com/cloudfoundry-samples/cf-sample-app-spring.git
The response:
Cloning into 'cf-sample-app-spring'... remote: Counting objects: 69, done. remote: Total 69 (delta 0), reused 0 (delta 0), pack-reused 69 Unpacking objects: 100% (69/69), done. Checking connectivity... done.
Navigate to the repo created:
cd cf-sample-app-spring
Sign in to PWS:
cf login -a https://api.run.pivotal.io
The response:
API endpoint: https://api.run.pivotal.io Email>
Type in your Email, then Password.
The response:
API endpoint: https://api.run.pivotal.io (API version: 2.57.0) User: firstname.lastname@example.com No org or space targeted, use 'cf target -o ORG -s SPACE'
Type in email and password (which is not reflected back to the screen):
Authenticating... OK Targeted org montana Select a space (or press enter to skip):
- development
joliet Space> 2 </pre>
Type in the number associated with the space you want to use (based on the list):
Targeted space joliet API endpoint: https://api.run.pivotal.io (API version: 2.57.0) User: firstname.lastname@example.com Org: montana Space: joliet
API End-points
API endpoint: https://api.run.pivotal.io
Predix Basic for individual emails:
- https://api.system.aws-usw02-pr.ice.predix.io
Predix Select for company names:
- https://api.system.asv-pr.ice.predix.io
Deploy app
Deploy the app to PWS:
cf push
The response begins with:
Using manifest file /Users/mac/gits/pivotal/cf-sample-app-spring/manifest.yml Creating app cf-spring in org montana / space joliet as email@example.com... OK Creating route cf-spring-isomagnetic-pleiophylly.cfapps.io... OK Binding cf-spring-isomagnetic-pleiophylly.cfapps.io to cf-spring... OK Uploading cf-spring... Uploading app files from: /Users/mac/gits/pivotal/cf-sample-app-spring Uploading 1M, 44 files Done uploading OK Starting app cf-spring in org montana / space joliet as email@example.com...
The response ends with:
requested state: started instances: 1/1 usage: 512M x 1 instances urls: cf-spring-isomagnetic-pleiophylly.cfapps.io last uploaded: Wed Jul 20 02:10:46 UTC 2016 stack: unknown buildpack: java-buildpack=v3.8.1-offline-https://github.com/cloudfoundry/java-buildpack.git#29c79f2 open-jdk-like-jre=1.8.0_91-unlimited-crypto open-jdk-like-memory-calculator=2.0.2_RELEASE spring-boot-cli=1.3.5_RELEASE state since cpu memory disk details #0 running 2016-07-19 08:11:24 PM 0.0% 338.7M of 512M 155M of 1G
TODO: Change the log color.
cf logs cf-spring –recent
From Marketplace
List the available ElephantSQL service plans in the Marketplace:
cf marketplace -s elephantsql
The response:
Getting service plan information for service elephantsql as firstname.lastname@example.com... OK service plan description free or paid turtle 4 concurrent connections, 20MB Storage free panda 20 concurrent connections, 2GB Storage paid hippo 300 concurrent connections, 100 GB Storage paid elephant 300 concurrent connections, 1000 GB Storage, 500Mbps paid
Create a service instance with the free plan "turtle":
cf create-service elephantsql turtle cf-spring-db
The response:
Creating service instance cf-spring-db in org montana / space joliet as firstname.lastname@example.com... OK
Bind the newly created service to the app:
cf bind-service cf-spring cf-spring-db
NOTE: When a service is bound to an app, environment variables are stored that allow the app to connect to the service after a push, restage, or restart command.
The response:
Binding service cf-spring-db to app cf-spring in org montana / space joliet as email@example.com... OK TIP: Use 'cf restage cf-spring' to ensure your env variable changes take effect
Restart the app:
cf restart cf-spring
The response:
Stopping app cf-spring in org montana / space joliet as email@example.com... OK Starting app cf-spring in org montana / space joliet as firstname.lastname@example.com... 0 of 1 instances running, 1 starting
Verify the new service is bound to the app:
cf services
The response:
name service plan bound apps last operation cf-spring-db elephantsql turtle cf-spring create succeeded
Configure scaling
Increase the number of app instances from one to two:
cf scale cf-spring -i 2
Check the status of the app and verify there are two instances running:
cf app cf-spring
WARNING: Scaling your app vertically changes the disk space limit or memory limit for each app instance.
Increase the memory limit for each app instance:
cf scale cf-spring -m 1G
Increase the disk limit for each app instance:
cf scale cf-spring -k 512M
Install uaac:
gem install cf-uaac
The response:
Fetching: multi_json-1.12.1.gem (100%) Successfully installed multi_json-1.12.1 Fetching: cf-uaa-lib-3.4.0.gem (100%) Successfully installed cf-uaa-lib-3.4.0 Fetching: highline-1.6.21.gem (100%) Successfully installed highline-1.6.21 Fetching: eventmachine-22.214.171.124.gem (100%) Building native extensions. This could take a while... Successfully installed eventmachine-184.108.40.206 Fetching: launchy-2.4.3.gem (100%) Successfully installed launchy-2.4.3 Fetching: cookiejar-0.3.3.gem (100%) Successfully installed cookiejar-0.3.3 Fetching: em-socksify-0.3.1.gem (100%) Successfully installed em-socksify-0.3.1 Fetching: http_parser.rb-0.6.0.gem (100%) Building native extensions. This could take a while... Successfully installed http_parser.rb-0.6.0 Fetching: em-http-request-1.1.5.gem (100%) Successfully installed em-http-request-1.1.5 Fetching: json_pure-1.8.3.gem (100%) Successfully installed json_pure-1.8.3 Fetching: rack-1.5.5.gem (100%) Successfully installed rack-1.5.5 Fetching: cf-uaac-3.3.0.gem (100%) Successfully installed cf-uaac-3.3.0 Parsing documentation for multi_json-1.12.1 Installing ri documentation for multi_json-1.12.1 Parsing documentation for cf-uaa-lib-3.4.0 Installing ri documentation for cf-uaa-lib-3.4.0 Parsing documentation for highline-1.6.21 Installing ri documentation for highline-1.6.21 Parsing documentation for eventmachine-22.214.171.124 Installing ri documentation for eventmachine-126.96.36.199 Parsing documentation for launchy-2.4.3 Installing ri documentation for launchy-2.4.3 Parsing documentation for cookiejar-0.3.3 Installing ri documentation for cookiejar-0.3.3 Parsing documentation for em-socksify-0.3.1 Installing ri documentation for em-socksify-0.3.1 Parsing documentation for http_parser.rb-0.6.0 Installing ri documentation for http_parser.rb-0.6.0 Parsing documentation for em-http-request-1.1.5 Installing ri documentation for em-http-request-1.1.5 Parsing documentation for json_pure-1.8.3 Installing ri documentation for json_pure-1.8.3 Parsing documentation for rack-1.5.5 Installing ri documentation for rack-1.5.5 Parsing documentation for cf-uaac-3.3.0 Installing ri documentation for cf-uaac-3.3.0 Done installing documentation for multi_json, cf-uaa-lib, highline, eventmachine, launchy, cookiejar, em-socksify, http_parser.rb, em-http-request, json_pure, rack, cf-uaac after 10 seconds 12 gems installed
Verify use of uaac:
The response:
UAA Command Line Interface
Miscellaneous version Display version help [topic|command…] Display summary or details of command or topic target [uaa_url] Display current or set new target </pre>
Install bower for front-end UI flat (non-recursive) dependencies tree:
npm install -g bower
See https://coolestguidesontheplanet.com/installingbower-on-osx/
bower –version
Install Predix
See https://www.predix.io/resources/tutorials/tutorial-details.html?tutorial_id=1523
Create a folder (~/gits/predix) to hold repos and cd to it.
Predix offers two samples:
- git clone https://github.com/PredixDev/predix-microservice-cf-jsr.git
- git clone https://github.com/PredixDev/predix-microservice-cf-spring.git
Create repo for JSR and cd into it:
git clone https://github.com/PredixDev/predix-microservice-cf-jsr.git
cd predix-microservice-cf-jsr
The tree of folders and files for JSR is more complex than Spring:
|-- COPYRIGHT.md |-- LICENSE.md |-- README.md |-- config | `-- application.properties |-- manifest.yml |-- pom.xml `-- src |-- main | |-- java | | `-- com | | `-- ge | | `-- predix | | `-- solsvc | | |-- boot | | | |-- Application.java | | | |-- PredixBootSecurityConfig.java | | | `-- service | | | `-- cxf | | | |-- ApplicationJSONProvider.java | | | |-- DefaultService.java | | | |-- DynamicService.java | | | `-- DynamicServiceImpl.java | | `-- spi | | |-- IServiceManagerService.java | | |-- NamedCxfProperties.java | | `-- ServiceManagerServiceImpl.java | `-- resources | |-- META-INF | | `-- spring | | |-- predix-microservice-cf-jsr-cxf-context.xml | | `-- predix-microservice-cf-jsr-scan-context.xml | |-- application-default.properties | `-- application.properties `-- test |-- java | `-- com | `-- ge | `-- predix | `-- solsvc | `-- boot | `-- HelloControllerTest.java `-- resources `-- application.properties 23 directories, 21 files
Create the repo for Spring and cd into it:
git clone https://github.com/PredixDev/predix-microservice-cf-spring.git
cd predix-microservice-cf-spring
The tree of folders and files for Spring is less complex than JSR:
|-- COPYRIGHT.md |-- LICENSE.md |-- README.md |-- config | `-- application.properties |-- manifest.yml |-- pom.xml `-- src |-- main | |-- java | | `-- com | | `-- ge | | `-- predix | | `-- solsvc | | |-- boot | | | |-- Application.java | | | `-- PredixBootSecurityConfig.java | | `-- service | | `-- HelloController.java | `-- resources | |-- application-default.properties | `-- application.properties `-- test `-- java `-- com `-- ge `-- predix `-- solsvc `-- boot |-- HelloControllerIT.java `-- HelloControllerTest.java 18 directories, 13 files
Build using Maven
mvn clean package
The end of a long list is like this:
[INFO] ------------------------------------------------------------------------ [INFO] BUILD SUCCESS [INFO] ------------------------------------------------------------------------ [INFO] Total time: 02:27 min [INFO] Finished at: 2016-07-08T08:55:47-06:00 [INFO] Final Memory: 30M/152M [INFO] ------------------------------------------------------------------------
API Setup
https://www.youtube.com/watch?v=9SEVfK-1sCQ Predix Intelligent Environment API Quick Start Demo
This is one of several related topics:


text: To get from Bassano del Grappa to Gela by train you can catch one of the 3 trains that everyday travel between these two cities. The first train to Gela leaves from Bassano del Grappa at 16:25 and the last train departs at 20:25. If you choose a local train the trip lasts on average 01:40 hours. For your trip from Bassano del Grappa to Gela by train you can choose to leave from one of Bassano del Grappa main stations: Bassano del Grappa On Wanderio you can compare all schedules, fares and railway companies to Gela and book the best itinerary starting from Bassano del Grappa.


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Statement and Assumptions
Statement: "The Bridge was built at the cost of Rs. 128 crores and even civil bus service is not utilizing it, what a pity to see it grossly underutilized."- A citizen's view on a new flyover linking east and west sides of a suburb.
I. The building of such bridges does not serve any public objective.
II. There has to be some accountability and utility of money spent on public projects.
|If only assumption I is implicit
|If only assumption II is implicit;
|If either I or II is implicit;
|If neither I nor II is implicit
|If both I and II are implicit.
(i) INVALID: Not directly related to the statement. The statement shows that author points out at "underutilization" of the bridge. No where it is mentioned that such bridges don't serve "any" public objective.
(ii) VALID: Root Cause. The citizen must have kept in mind the accountability and the utility of money spent, that is why he complaints about the underutilization.


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In contrast, earlier today I went to Poundland, yes, Poundland and bought a pair of sunglas.


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Casey Affleck sues Amanda White, the woman who accused him of sexual harassment
Flemmy Prods' representatives reject Amanda White's allegations and say that are ready to sue her.
Casey Affleck has been sued for misconduct behavior at the workplace and sexual harassment by Amanda White, who worked on the production of "I'm Still Here: The Lost Year of Joaquin Phoenix" , distributed by Magnolia Pictures, which will arrive in theaters in September.
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