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Heather Campbell
Former Encyclopædia Britannica Editor
Heather Campbell was a senior editor at Encyclopaedia Britannica. Prior to joining Britannica, she was an editor at ABC-CLIO; taught French to undergraduates at the University of California, Santa Barbara; and lived for a time in Paris, London, and Dublin. She holds master's and bachelor's degrees in French.
Primary Contributions (5)
Brazilian business magnate who made and then lost a fortune in mining and oil and gas exploration. Batista, one of seven children, was born in the state of Minas Gerais, in southeastern Brazil. His mother was German, and his father, Eliezer Batista da Silva, was a prominent Brazilian businessman who served as the country's minister of mines and energy in the 1960s. After spending his early childhood in Brazil, Batista gained his secondary education in Europe. In the 1970s he studied metallurgy at the Rhenish-Westphalian Technical University in Aachen, Germany, before returning to Brazil. There, at the age of 23, he launched a company that mined and traded gold. After making millions of dollars in mining ventures during the 1980s, Batista expanded his business over the following two decades. He invested in a number of industries, including energy generation, petroleum and natural gas exploration, logistics, shipbuilding, and real estate. By 2010 he had established a collection of...


text: This adorable raised ranch would make the perfect first home or vacation rental with a spacious kitchen, hardwood flooring in the living room and connecting spaces, and a fenced in yard for fido. The basement could be finished to add square footage and an additional bath. Boating enthusiasts will love its proximity to Lake Flower - despite the privacy this lot affords, the marina is just a five minute walk! Priced below assessed value and move-in ready!

subset: commoncrawl


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NYC Girl – Karlie Kloss shows off NYC rush hour ready looks for the January catalogue from Free People. In front of Guy Aroch's lens, Karlie hits the urban streets clad in leather, denim and stripes. Whether taking the subway or grabbing a bite to eat, the American beauty does it in style.
I wonder if she at that hotdog.
haha,me too… 😀
her leg is weird sometime, anyway i like these photos
The photoshopping on her legs is sooo bad in these ads.
everytime I see her I'm amazed at how gorgeous she is, and i feel a little bit uglier lol ^^
love the atmosphere she always makes it casual but beautiful
n ya her leg is sometimes weird…maybe too much muscle i guess
Styling's almost a minimalist look by FP standards. I like it!
That is my Karlie
karlie looks eurasian…she has a very innocent young look
Not one bite of the Hotdog or a nibble of the pretzel, not one suck on the milkshake or, so it appears, of the takeaway coffee. The ongoing trouble with Karlie in editorials remains that she is soooo "Karlie". She's tight. So I dispute that she looks innocent like it is claimed, instead Karlie is "at work" doing her "business". She is very good at it.
Karlie is the queen of posing. So good.
is she now the bretzel girl?
i loved!
Her legs look fine! She's over 6 feet tall and a ballerina, she's going to have long leanly muscled legs!
This is so cute!
Exquisite feminine and refined red jacket on the first image !
Where can I get that polka dot dress?! So in love with it!!


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"A creature looms in the distance-- its fiery gaze upon a single creature. Its madness fueled by the devastation of its home it was meant to guard. A sword of wind and fire is held on its massive hand, and its footsteps shake the earth before it. With each step that it draws near, the air around it becomes more rampant-- the elements seem to be defiled-- filling other elemental creatures with a sense of vitality and in turn making them even more dangerous. It is a titan of the elemental might."
Physical Description Edit
The Elemental Titan is a giant creature that resembles an oversized Earth Elemental with a huge greatsword and various elements flowing around it in a sort of defensive fashion-- creating an elemental chain protecting the creature. Its eyes are filled with a fiery glare as it protects its creator's settlements.
Habitat Edit
The Elemental Titan is best suited for the Elemental Chaos , but it chose to defend the Triskelion from harm of a great threat-- a tyrant known as the Leviathan.
Origin Edit
The Elemental Titan was created by the sudden surge of warning by the Elemental Serpents combined by Schi'vya's rage to create a defender of epic scale.


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A few plays later, he did it again. Then again. Antwaan Randle El and Cedrick Wilson made most of the catches, and rookie Fred Gibson of Georgia made the best of all, an over-the-shoulder grab in traffic for more than 40 yards.
The passing game was so effective that it was almost as if the starting receivers from the last five seasons, Hines Ward and Plaxico Burress, weren't there. Which, of course, they weren't.
While his teammates are optimistic Ward will end his three-day holdout, report to camp and get his contract extension settled, the Steelers are moving on without the four-time Pro Bowl receiver and acknowledged vocal leader of the offense.
As backup-turned-starter Randle El said, what choice do they have?
"They're going to get this straightened out with the organization, and we hope it does," said Randle El, who filled Burress' former spot at split end. "That's what we expect. But we've got good receivers here."
Wilson, a 49ers starter last season, echoed those words after his first practice with the Steelers; the first two days of camp were filled with meetings and running tests, but no on-field work. Wilson was expected to replace Burress, but instead found himself at flanker in place of Ward.
Randle El started seven games last year when Burress was injured, so coach Bill Cowher prefers to keep him at a position he already knows. Burress signed with the New York Giants after the Steelers made no real effort to re-sign him, preferring instead to put their dollars toward keeping Ward.
"My job is to catch passes, punts, kickoffs — whatever they need me to do," said Wilson, who caught 47 passes in a dismally ineffective 49ers offense last season. "Hines is definitely a big part of this team and is a leader, and having him here is definitely a plus. But that doesn't take away from my abilities. I can play split end, flanker, slot, kickoff returner, punt returner."
The Steelers will need such versatility — and no injuries — if the team's first significant holdout in a dozen years becomes a long one. Ward is set to make $1.66 million this season, the final year of a deal he signed in 2001, but wants an extension that would pay him an eight-figure signing bonus.
Ward's bargaining position may have improved Sunday when third-year Cardinals receiver Anquan Bolden agreed to a reworked contract worth $12.42 million more than his former deal. That is approximately the upfront money Ward is seeking from the Steelers, who have never paid so much guaranteed cash at once to any player.
The Steelers' policy is to not negotiate with any player under contract who is not in camp, and director of football operations Kevin Colbert said that won't be altered for Ward. The rule is not universal among NFL teams; Patriots defensive lineman Richard Seymour's four-day holdout ended Tuesday after he reached a new deal while away from camp.
Ward is so well-liked among his teammates and some are urging him to hang tough in his stance, even if it keeps him away from the team.
"Hines is a smart guy and Hines deserves everything he wants; without a doubt he deserves it," said running back Duce Staley, who held out for 26 days with the Eagles in 2003 without getting a new contract. "I know the high expectations coming into the year, what will be expected. But I know Hines is a man. He's got to stick to his guns."
The Steelers aren't saying if they're fining Ward as much as $6,000 a day, as permitted by the NFL labor agreement. They haven't had a veteran player stay out since running back Barry Foster in 1993, a 20-day holdout that resulted in a new contract not long after he returned.
Ravens' Jamal Lewis free to rejoin team
Running back Jamal Lewis completed a two-month stay at an Atlanta halfway house Tuesday for his role in an attempted drug deal and will join the Baltimore Ravens at training camp on Thursday. Lewis, 25, spent four months in a Pensacola, Fla., prison before entering the halfway house in Atlanta. He pleaded guilty to a federal charge of using a cell phone to aid a friend's cocaine transaction in June 2000, shortly after the Ravens made him the overall fifth pick in the NFL draft.
Colts' Saturday among those missing game in Japan
TERRE HAUTE, Ind. — Indianapolis Colts center Jeff Saturday missed practice Tuesday because of a strained right hamstring and most likely will not play this weekend in the exhibition opener in Japan against the Atlanta Falcons.
Coach Tony Dungy said the team was awaiting results from an MRI exam to determine the severity of the injury. Saturday, however, will travel with the team.
"Jeff is probably for sure not going to play," Dungy said.
Defensive lineman Raheem Brock, also a starter, could be out with a hip flexor injury but is expected to make the flight.
At least five players, including two-time Pro Bowl defensive end Dwight Freeney, will not travel. Freeney has not yet practiced after having offseason shoulder surgery and is on the team's physically unable to perform list.
Others who will not be going to Japan are starting defensive tackle Josh Williams (thigh), backup defensive back Von Hutchins (foot) and two draft picks — guard Dylan Gandy (foot) and linebacker Tyjuan Hagler (sports hernia).
The Colts announced Tuesday before departing for Japan that six additional players will not be available for the game.
Defensive tackle Montae Reagor (groin), safety Mike Doss (groin) and cornerback Donald Strickland— all potential starters — were ruled out. Joining them on the sidelines will defensive backs Brandon Lynch (foot) and Daryl Dixon (thigh) and guard Cody Campbell (shoulder).


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- Aliev, Mustafa
- (Manush Romano)(1928-2004)Bulgaria. Playwright and politician. He was director of the Teatr Roma in Sofia until 1951 when it was closed, after which he worked in a Turkish theater. Aliev became an MP on the list of the Union of Democratic Forces in the first post-Communist parliament in 1990. However, at the next election he was not reelected. A booklet has been published in Poland containing some of the songs he collected.
Historical dictionary of the Gypsies . Donald Kenrick.


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A DORCHESTER charity supporting homeless people has received a boost from local fundraising events.
Staff at the Dorchester Tourist Information Centre in Antelope Walk have raised £360 from a series of events including an in store treasure hunt and Christmas quiz.
Caroline Morrish-Banham, Dorchester Tourist Information Centre manager said: "Throughout the year we help raise money for local charities.
"We are delighted with the figure we have raised for The Hub.
"We would like to thank all the many local businesses and suppliers for their generosity in supplying such fabulous prizes.
"We would also like to thank our many customers for their loyal support."
Steven Dukes, project leader at Bournemouth Churches Housing Association, said: "We are really thankful to the tourist information centre for the £360 raised through its Christmas quiz and treasure hunt.
"I would like to thank all the team for their hard work and dedication in helping vulnerable adults in Dorchester."


text: November 27, 2011 • Top Shelf • Leave a CommentSean Paul – She Doesn't Mind (Video) http://www.hiphopstan.com/wp-content/uploads/2011/11/Sean-Paul-She-Doesnt-Mind.mp4 Here is the newest video from Sean Paul "She Doesn't Mind". This is the second single from his forthcoming album. PREVIOUS POSTBirdman – Y.U. MAD (feat. Nicki Minaj & Lil Wayne) (Video)NEXT POSTSummer Leather Vests – Unison (ft. Joe Budden) [Video] Leave A Comment Cancel reply Your email address will not be published. Required fields are marked *Comment Name * Email * Website


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1984 Chevrolet Citation II X-11 Tires
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- This event has passed.
Tour de Cure: American Diabetes Association
May 19 @ 8:00 am - 5:00 pmFree
Event Navigation
Grab your family, friends and coworkers, tune up your bike, and join us to raise money for America's fastest growing disease, diabetes. The Tour is a ride, not a race, with routes designed for everyone from the recreational rider to the experienced cyclist, highlighting the best scenery Northeast Florida has to offer. Join TEAM RED if you don't have a team already. Riding in the Tour de Cure as part of a team can make the experience even better, so simply join Team Red if you are looking to get connected!


text:
CALGARY -- Sidney Crosby's brush with danger at Canada's Olympic orientation camp happened in the middle of a river and was followed by plenty of laughter. Shane Doan and Jarome Iginla's latest contest was waged on a golf course and followed up with some playful trash talk.
The 40-plus Olympic hopefuls in Calgary this week are having all kinds of fun together and it's all being done in the name of chemistry. After getting shut out three times at the 2006 Olympics en route to a seventh-place finish, Rick Nash cited a lack of team chemistry as one of the reasons for the failure.
"There was so much firepower on the team, maybe just not the right chemistry," Nash said Wednesday. "It's tough to look back and say what happened. There was no reason why we shouldn't have had scoring power."
It's no secret that one of the goals Steve Yzerman and his Olympic management group have set for this orientation camp is to try to build some rapport amongst the players.
While the ultimate success of those efforts won't truly be known until the Olympic tournament is played in February, the early returns seem good. There was a somewhat lighter atmosphere on the third day of camp -- perhaps not surprisingly since the players spent the morning playing golf, fly fishing or simply relaxing.
Crosby was among the handful of guys who took to the river and had the group in stitches because of a casting mishap.
"Sometimes we can laugh at each other," said defenseman Francois Beauchemin. "Sid almost hooked himself in the back of the head. That was fun to see."
Meanwhile, an intense game was being waged on the links in a foursome that included Iginla, Doan, Dany Heatley and Jordan Staal.
Iginla and Heatley won a little bit of money against their opponents.
"Dany Heatley and I had some chemistry against those guys," said Iginla. "We had a good day."
Doan had a slightly different take on the event. He was questioning whether the twosome was using its proper handicaps in the match.
"He ended up winning money because he set up another game where he kind of had the advantage," said Doan. "Dan Heatley and Iggy were sandbagging in that game. [Iginla] didn't make as much as he planned on making."
The only place there wasn't much laughter was on the ice at the Pengrowth Saddledome, where coach Mike Babcock put the two groups of skaters through a high-paced practice for the third consecutive day.
There was even a point in the first practice when Babcock stopped a drill, gathered the players around and instructed them to do it better. His intensity has been on display all week.
"It's the Stanley Cup playoffs every day for Mike and I think that's a good thing," said Kevin Lowe, one of the team's executives.
Added defenseman Scott Niedermayer: "He's done a good job at the camp really being black and white, letting everybody know what's wanted and demanded from the players. He is into the details, but it's very quick and it's very direct. There's not a lot of gray areas. He tells you exactly what he wants and expects us to do it."
Babcock shook up all of his line pairings Wednesday, replacing Iginla with Martin St. Louis on the top unit with Crosby and Nash.
The coach seems intent on keeping Crosby and Nash together: "I think there's something there."
Iginla ended up skating on a line with Mike Richards and Jonathan Toews, who was moved to the wing after lining up at center over the opening two days.
Even though Babcock has repeatedly warned reporters not to read too much into his lines, there's a growing sentiment among some of the players that they are a good indication of what he's thinking.
"No one knows what the combinations are going to be as far as players and who's going to be around," said Toews. "The coaching staff, I think they're starting to maybe get their own ideas."
The camp wraps up Thursday night with a scrimmage between the two groups of players. More than 16,000 tickets have been sold for the game.


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Kathleen Buczko, a mother of three, is the toy industry's Grinch this year. She plans to cut her spending on toys by 25%.
To the video game industry, she's more like Santa -- because she's boosting her game budget by 600%.
One big reason, the San Pedro resident said, is that she wants to protect her 5-year-old son from another toy crisis. Two of his favorite playthings -- a Mattel Inc. die-cast car and a Thomas the Tank Engine train by RC2 Corp. -- were recalled this year because of lead contamination.
Read entire article here.


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New accessory delivers Dolby Digital sound quality streamed directly to your hearing aids.Read more
Heading for the festival season?
Pack your earplugs next time you head out for a concert or when going to a bar. The use of earplugs during exposure to recreational noise effectively prevents temporary hearing loss.Read more


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text:
|Edward Keddy[1]
|NEXT Power
|Sand Manipulation
|Episode 8
There is Always a Next Time
|Wataru Hatano
Ben Diskin (English)
Edward Keddy (エドワード・ケディ) was a student that attended Hero Academy with Ivan. He performed at the top of his class, and was inches away from becoming a hero.
One day, while outside, Edward and Ivan found themselves witnessing a hostage scene. Other heroes hadn't arrived yet, and Edward insisted that they become the heroes for once. Ivan, however, was too afraid to go in because of his lack of confidence and the academy's regulations on using powers off school grounds. Nevertheless, Edward went in, alone. He managed to get behind the criminal and took away his weapon. Unfortunately, he soon found himself trapped when he realized that he was outnumbered 2 to 1. He kept asking for Ivan's help, but Ivan was still too afraid and couldn't move. Edward ended up shooting at one of the criminals, but accidentally killing the hostage. As a result, he lost everything and was subsequently sent to prison with no hope of ever becoming a hero.
Escape and RevengeEdit
Edward manages to escape from prison and seeks out Ivan in order to exact revenge. He meets Ivan beneath a statue in the academy's courtyard where they often met as students, and nearly drowns him in a whirlpool of sand. The timely arrival of Wild Tiger and Barnaby is enough to temporarily scare Edward off and save Ivan's life. Later, after a conversation with Wild Tiger, Ivan decides to put an end to Edward's revenge and begs him to stop. Edward refuses, but their confrontation is interrupted by the sudden appearance of Lunatic, who intends to kill Edward for not having completed his life sentence. Ivan attempts to draw Lunatic's attack to himself instead by transforming into Edward, but Lunatic isn't fooled. Edward is ultimately saved by the interference of Wild Tiger and Barnaby, after Ivan has proven himself as a hero by risking his life to protect Edward's. In the end, Edward is taken back to prison to finish his sentence - but not before saying "thanks" to Ivan.
A year later, it is shown that Ivan has been visiting him in prison and was last seen talking about adding material to his performance on Hero TV.
- ↑ Monthly Hero, volume 4


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Summer classes fail students;FE Focus
An extra pound;5.5 million was put into basic skills schools last year but inspections found teaching standards to be "significantly lower" than in other courses.
In a report published this week, only 52 per cent of lessons were graded as good or outstanding. This compares with 65 per cent across further education as a whole. Teaching of English as a second language received the lowest grades - only 38 per cent of lessons were awarded either of the top two grades.
Weaknesses included low expectations, inadequate recording and assessment of student progress and a failure to link the curriculum to students' experience or future aspiration.
The report - Basic Skills Summer Schools - said many of the weaknesses were due to the lack of time colleges had to organise their programmes, but other problems "were the result of too little emphasis on quality and measurable outcomes for students."
More than 17,000 students enrolled in 200 summer school programmes last year.
Jim Donaldson, Further Education Funding Council chief inspector, said:
"Raising quality and standards is an issue in the FE sector as a whole and one we are vigorously addressing. This report shows there is work to be done."


text:
Property ID: RA96
Address: Estrada De Santa Eulalia Areias De Sao Joao Areias de Sao Joao 8200-269 Albufeira 8200-269 Portugal
Phone: 351 289541101
Newly renovated, redecorated, and surrounded by gardens, the resort is centrally located and close to the beach. An outdoor pool is great for families. Indulge in a soothing treatment at the newly built spa, complete with sauna, Turkish bath, and a heated indoor swimming pool with hydro-massage. Relax in the solarium with sunbeds, sun mattresses and umbrellas, and enjoy WiFi access in the reception and bar areas. Bars offer cocktails and snacks, and at mealtime, the on-site restaurant serves breakfast, lunch and dinner
Arcade/game room (Onsite)
ATM/banking (Nearby)
Bar/lounge (Onsite)
Billiards or pool table (Yes)
Car Rental (Onsite)
Currency exchange (Onsite)
Fitness Center
Indoor swimming pool (Onsite)
Internet access in public areas (fees may apply) (Wireless Internet Access)
Jacuzzi/Hot tub (Onsite)
Laundry facilities (Onsite)
Medical facility (Nearby)
Multilingual staff (Yes)
Multilingual staff languages (English, Spanish, French, Portuguese)
Nightclub (Nearby)
Onsite - Swimming pool - children's (Unheated)
Onsite - Swimming pool - indoor (Heated)
Onsite - Swimming pool - outdoor (Unheated)
Onsite - Wave pool (No)
Poolside bar (Yes)
Post Office (Nearby)
Safe-deposit box (In-Room)
Salon (Nearby)
Sauna (Yes)
Spa (Onsite)
Swimming pool (Onsite)
Television in lobby (Yes)
(Swimming) beach (Nearby)
Amusement Parks
Beach (Nearby)
Beach facilities ()
Boating (Nearby)
Casino / Gambling (11 Miles)
Child care (None)
Cinema/Movie Theater
Cultural Sites
Entertainment / Nightlife (Nearby)
Fishing (Nearby)
Golf (Nearby)
Golf - driving range ()
Historical Areas
Local Tourism Web address ()
Playground (Onsite)
Scuba Diving (Nearby)
Shopping (Nearby)
Snorkeling (Nearby)
Theme Park
Water park
Air-conditioned units feature a living room with LCD TV, and a furnished balcony. The bathroom comes equipped with a hairdryer, and each unit includes a safety deposit box. For added convenience, a kitchenette comes equipped with a fridge, coffee maker and kettle
Check In: 17:00
Check Out: 10:00
Weeks Check In Days: Sunday
Points Check In Days: Sunday
Front Desk Available: Yes
Front Desk Available 24 Hours
Spa fee fee is 6.00 to 10.00 Euros. Cash or Credit is accepted. Per day.
No Pets. Please contact the resort directly regarding its ADA service animal policy.
No smoking in units: could result in forfeiture of the unit and/or other penalties.
Occupancy limits are strictly enforced: could result in forfeiture of the unit and/or other penalties.
Credit card imprint required upon check-in at the resort.
Fees charged for some utilities.
Security deposit required upon check-in at the resort.
Contact the resort after confirmation of the vacation to coordinate Check-in or request any special needs during your stay.


text:
The effect of intensity distortion induced by cross-phase modulation in dispersive optical fibers is studied. It is shown that, in most configurations in which distortions that are due to cross-phase modulation can become significant to optical communications, the effect of cross-phase modulation can be described with excellent accuracy by simple analytical expressions. The presented analysis also suggests that intensity distortions owing to cross-phase modulation can be efficiently reduced by linear dispersion compensation.
© 1998 Optical Society of AmericaFull Article | PDF Article
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Opt. Express 17(16) 13860-13868 (2009)


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Physical properties
(1) Metallic character: Alkali metals are highly electropositive in nature and hence, they are typical metals. The metallic character is due to the low values of ionisation energies and consequently, they have tendency to lose the valence electrons.
(2) Low ionization energy: The first ionization energies of alkali metals are quite low as compared to the elements of the other groups belonging to the same period. The reason is that atoms of alkali metals are of large sizes. Therefore, the outermost electron is far away from the nucleus and can be easily removed. Within the group, ionization energies of alkali metals decrease as we move down the group.
(3) Low melting and boiling points: The melting and boiling points of alkali metals are very low because of large size of their atoms due to which inter- particle forces are very weak in them. The melting and boiling points decrease on going down the group (Lithium to Cesium) as the charge density decreases because of the increase in size of the mono-valent cation.
(4) Low electro- negativity values: Alkali metals have low values of electro- negativity. They have very little tendency to attract the shared pair of electrons towards themselves. The electro negativity values of alkali metals decrease as we move down in the group from Li to Cs e.g. Li(1.9) K(0.8), Cs(0.7).
(5) Soft metals: All the alkali metals are soft and can be cut with the help of a knife. Softness of alkali metal is due to weak metallic bonding in them as the result of large size of the atoms. As we move down the group, metallic bonding weakens and therefore, softness increases
(6) Density: Alkali metals have low density due to the large size of metals atoms.
(7) Oxidation state: The alkali metals exhibit oxidation state of +1 in their compounds and strongly electropositive in character. The electropositive character increases from lithium down to caesium in the group.
(8) Characteristic flame colour: Alkali metals impart characteristic colour to the flame, e.g. Li(red), Na(yellow), K(lilac), Rb (violet) and Cs(blue).
Chemical Properties
(1) Decomposition of water: The alkali metals decompose water at the ordinary temperature giving out hydrogen.
2Li + 2H2O → 2LiOH + H2 (slow)
2Na + 2H2O → 2NaOH + H2 (quick)
2K + 2H2O → 2KOH + H2 (more vigorously)
(2) Reaction with oxygen: The alkali metals readily burn in oxygen or air to form their oxides, M2O.
4Li + O2® 2 Li2O
4Na + O2 → 2Na2O
(3) Combination with halogens: The akali metals burn in halogens (F, Cl. Br, I) forming their halides (MX).
2Na +Cl2 → 2NaCl
2K + Br2 →2KBr
(4) Combination with hydrogen: Alkali metals combines with hydrogen to give white crystalline hydrides (MH). The ease with which the alkali metals form these hydrides decrease from Li to Cs, because the electropositive character of the metals increases in the same order. The hydrides are ionic in character, because hydrogen is present as H- in them. Thus these are represented and M+ H-.
2M + H2 →2M+ H-[M = Li, Na, K, Rb, Cs]
(5) Combination with Sulphur: Alkali metals react with sulphur upon heating to the corresponding sulphides.
16Na + S8 → 8 Na2S
Sodium sulphide
(6) Solubility in liquid ammonia: Alkali metals dissolve in liquid ammonia to produce blue coloured solutions which conduct electricity.
(7) Reaction with acids: Alkali metals react with strong and weak acids (organic and inorganic) to give their respective salts and hydrogen gas is liberated.
M + H+ → M+ + H2(g)
Metal salt
(8) With Phosphorous: The alkali metals combine with phosphorous forming metals phosphide, M3P
12Na + P4 → 4Na3P
Sodium phosphide
Sodium phosphide
Potassium phosphide
Electronic configuration: Their general electronic configuration is ns2. They have 2 electrons in their outermost shells.
Oxidation state: They can lose two electrons to acquire nearest noble gas configuration; therefore their oxidation state is +2.
Atomic and ionic sizes: The atomic and ionic size goes on increasing down the group due to decrease in effective nuclear charge. Their atomic and ionic radii are smaller than the corresponding alkali metals in corresponding periods due to increased effective nuclear charge in their atoms.
Physical appearance: These metals in general are silvery white, lustrous and relatively soft but harder than the alkali metal. Be and Mg appear to be greyish.
Ionization enthalpies: The first ionization enthalpies of alkaline earth metals are higher than alkali metals because of smaller atomic size and higher effective nuclear charge. Second ionization enthalpy is smaller than that of alkali metals because alkali metals acquire noble gas configuration after losing one electron. Ionization enthalpies of alkaline earth elements decrease down the group due to increase in atomic size.
Melting and boiling points: They have fairly higher melting and boiling points than corresponding alkali metals. The trend is not systematic mg has lowest melting point.
Electrical and thermal conductivity: They are good conductors of heat and electricity.
Flame colour: Be and Mg does not impart any colour to the flame because electrons are strongly bound and therefore, cannot be excited by flame.
Ca, imparts brick red, Sr imparts crimson red, Ba gives apple green colour because electrons get excited to higher energy levels and when they come back to lower energy level, energy is radiated in form of visible light.
Density: Alkaline earth elements are denser than corresponding alkali metal elements which is due to greater strength of metallic bond and more closely packed crystal structure. However, the variation in density is irregular. Ca has lowest density.
Metallic character: They are less electropositive than alkali metals due to higher ionization enthalpies.
Metallic character increases down the group due to decrease in ionization enthalpy.
Reactivity with air and water: The alkaline earth metals are less reactive than alkali metals. Be and Mg are kinetically inert of O2 and H2O due to formation of oxide layer on its surface. Be does not react with water or steam even at red hot and does not get oxidized in air below 873 K.
Powdered Be burns on ignition to form BeO and Be3N2
2Be + O2 → 2 BeO
3Be + N2 → Be3N2
Mg is more electropositive and burns in air with dazzling light forming MgO and Mg3N2.
2Mg +O2 → 2MgO
3Mg + M2 → Mg3N2
Ca, Sr and Ba readily react with oxygen to give oxides. Calcium forms oxide whereas Sr and Ba form peroxide. They react with nitrogen to form nitrides.
2Ca + O2 → 2CaO
3Cs +N2 → Ca3N2
Sr + O2 → SrO2
Ba + O2 → BaO2
Mg reacts with hot water, Ca, Ba, Sr, react with cold water vigorously.
Mg + H2O (hot) → MgO + H2
Ca + 2H2O → Ca(OH)2+ H2
Sr + 2H2O → Sr(OH)2+ H2
Ba + 2H2O → Ba(OH)2+ H2
Reaction with halogens: Group 2 elements react with halogens at increased temperature to from halides.
Be + Cl2 → BeCl2
Mg + Cl2 → MgCl2
Ca + Cl2 → CaCl2
Action with acids: The alkaline earth metals readily react with acids to from salts and liberate H2 gas.
Be + 2HCl→ BeCl2 + H2
Mg + 2HCl → MgCl2 + H2
Mg + 2HNO3(5%) → Mg (NO3)2 + H2
Mg + H2SO4(dil) →MgSO4 + H2
Reaction with NH3 : Alkaline earth metals dissolve in liquid NH3 to give deep blue black solutions due to solvated electron.
Reducing power: They are weaker reducing agents than alkali metals. Reducing power goes on increasing down the group due to decrease in standard reduction potential.
Be has less negative value of reduction potential due to high enthalpy of atomization and ionization inspite of higher hydration enthalpies.
Reaction with H2: All metals combine with H2 to from hydrides except Be.
Ca+ H2 → CaH2 (Hydrolith)
Calcium hydride
Mg + H2 → MgH2
BeH2 is prepared by reduction of BeCl2 with LiAlH4.
2BeCl2 + LiAlH4 → 2BeH2+LiCl + AlCl3
They are ionic hydrides except BeH2 which is covalent.
CaH2 + H2O → Ca2+(aq) +2OH-(aq) + 2H2(g)
They are basic in nature.
Alkali metals are highly reactive due to low ionisation enthalpy and strong electropositive character. They do not occur in free or native state and are always combined with other elements. As a result, alkali metals are not found in nature.
x -1
Na2 O2
2x + 2(-1) = 0
or x = +1.
This is mainly due to low ionisation enthalpy of sodium as compared to potassium. With the result, the potassium is more electropositive and stronger reducing agent than sodium. Thus, sodium is less reactive than potassium.
Alkali metals
Alkaline metals
i) Ionization energy
Ionization energy is low, but only +1 state is stable.
Ionization energy is very high and +2 state is stable.
|ii) Basicity of the oxides
|Oxides of alkali metals are highly basic, the basic strength increases from Li2O to Cs2O.
|Beryllium oxide (BeO) is amphoteric but oxides of other alkaline earth metals are basic. The basic strength increases from MgO to BaO.
|iii) Solubility of hydroxides
|Hydroxides of alkali metals are highly soluble in water.
|Hydroxides of alkaline earth metals are less soluble in water.
(1) Atomic radius of lithium is 155 pm. It is comparable to that of magnesium (160pm).
(2) The ionic sizes of Li+ (r= 60pm) and Mg2+ (r= 65pm) are nerly equal.
(3) Lithium reacts with nitrogen to give lithium nitride Li3N. Magnesium also reacts with nitrogen to give magnesium nitride, Mg3N2.
(4) Lithium forms only monoxide, Li2O. magnesium also prefers to form only the monoxide, MgO.
(5) Lithium hydroxide, alike magnesium hydroxide, is sparingly soluble in water and behaves as a weak base.
(6) Lithium chloride, like magnesium chloride, separates out from aqueous solution as hydrated crystal, e.g. LiCl.2H2O and MgCl2.6H2O.
(7) Lithium chloride, like magnesium chloride is deliquescent.
Alkali and alkaline earth metals are very strong reducing agents. So their oxides or halides cannot be reduced by any other elements/ compounds chemically.
In a photoelectric cell, electrons are knocked out of the surface of a metal under the influence of striking photons carrying the required energy (threshold energy E0 or more). Now, lithium and sodium due to their small atomic sizes have high ionization energies and photoelectric effect does not take place in the visible region of light. However, both potassium and cesium have comparatively bigger sizes and the electrons can be knocked out more easily. They, therefore, exhibit photoelectric effect in visible light.
The alkali metals dissolve in liquid ammonia to give blue to bronze colour.
The colour is attributed to the presence of solvated electrons e.g. [e(NH3)4]- in dilute solution.
M+ (x+y) NH3 → [M(NH3)x]++ [e(NH3)y]-
However in concentrated solutions, the ammoniated metal ions are bound by the free unpaired electrons which give bronze colour.
The blue solutions are paramagnetic, whereas the bronze coloured solutions are diamagnetic.
Chlorides of alkaline earth metals, except that of Be and Mg, produce characteristic colour to flame due to easy excitation of electrons to higher energy levels. Beryllium and magnesium atoms, due to their small size, bond their electrons more strongly, i.e., their ionisation energies are high. Hence they possess high excitation energy and are not excited by the energy of the flame to higher energy state with the result no colour is produced by the flame.
When carbon dioxide is passed into a concentrated solution of brine saturated with ammonia, ammonium bicarbonate is produced.
Ammonium bicarbonate
The ammonium bicarbonate then reacts with common salt forming sodium bicarbonate.
NH4CO3 + NaCl → NaHCO3 + NH4Cl
Sodium bicarbonate
Sodium bicarbonate being slightly soluble (in presence of sodium ions) gets precipitated. The precipitated sodium bicarbonate is removed by filtration and changed into sodium carbonate by heating.
2NaHCO3 → Na2CO3 + H2O +CO2
the mother liquor remaining after the precipitation of sodium bicarbonate contains ammonium chloride. This is then heated by steam with milk of lime to regenerate ammonia which can be as one of the raw materials.
2NH4Cl + Ca(OH)2 → CaCl2 + 2H2O + 2NH3
Lime is obtained by heating lime stone
CaCO3 → CaO + CO2.
Potassium carbonate cannot be prepared by Solvay process because potassium bicarbonate is too soluble to be precipitated by the addition of ammonium bicarbonate to a saturated solution of potassium chloride.
Strong polarizing action of small Li+ ion distorts the electron cloud on the nearby oxygen atom of the large CO32- ion to such and extent that the C-O bond gets weakened and Li-O bond becomes stronger which ultimately leads to the decomposition of lithium carbonate to oxide and carbon dioxide.
Li2CO3 → Li2O + CO2
Replacement of the larger carbonate ion by smaller oxide ions leads to increase lattice energy and thus favours the decomposition of Li2CO3.
Alkali metals
Thermal stability
1. Nitrates
Soluble in organic solvents due to their ionic nature.
When heated give their oxides.
4LiNO3 → 2 Li2O + 4NO2 +O2
2NaNO3 → 2NaNO2+ O2
|2. Carbonates
|They are generally soluble in water.
|The carbonates are generally highly stable to heat and thus thermally stable.
|3. Sulphates
|Sparingly soluble in H2O. Potassium and sodium slats are readily soluble.
|Conform to thermal stability.
Alkaline earth metals
Thermal stability
1. Nitrates
Dissolve in water sparingly soluble and possess crystalline six molecules of H2O.
They decompose upon heating giving oxide.
|2. Carbonates
|Sparingly soluble in water.
|Thermally unstable which increases with increasing cationic size.
|3. Sulphates
|Readily soluble in H2O due to their greater hydration energy.
|Thermally stable.
(1)Na is prepared from NaCl by the following method:
Electrolysis : NaCl → Na+ +Cl-
At cathode: Na++e- → Na (sodium)
At anode: Cl- → Cl +e-
Cl+Cl → Cl2
(2) Sodium hydroxide is prepared by carrying out the electrolysis of the aqueous solution of sodium chloride either in Nelson's cell or Castner -Kellner cell.
Preparation of sodium peroxide: Sodium chloride is first converted in sodium by electrolytic reduction. The metals are then heated with excess of oxygen at about 573K in an atmosphere free from moisture and carbon dioxide to form sodium peroxide.
2Na + O2 → Na2O2
sodium peroxide
Sodium carbonate is prepared by the following processes:
2Na + 2H2O → 2NaOH + H2 ↑
2NaOH + CO2 → Na2CO3 + H2O
(sodium carbonate)
(i) Magnesium burns in air with dazzling white light.
5Mg + O2+ N2 2MgO + Mg3N2
(in air)
(ii) CaO + SiO2 CaSiO3
Calcium silicate
(iii) Ca(OH)2 + Cl2 CaOCl2 + H2O
Bleaching powder
(iv) 2Ca(NO3)2 2CaO + 4NO2+O2.
(i) Caustic soda
(a) It is used in petroleum refining and purification of bauxite.
(b) It is used in the manufacture of soap, Paper, artificial silk and a number of chemicals.
(ii) Sodium carbonate
(a) It is used in the manufacture of soap, glass, paper, borax, caustic soda etc.
(iii) Quick lime
(a) It is used in the manufacture of sodium carbonate from caustic soda.
(b) It is used in the manufacture of dye stuffs.
(c) It is used in the manufacture of sodium carbonate from caustic soda.
(i) Structure of BeCl2 in vapour phase:
(ii)Structure of BeCl2 in solid phase:
The hydroxides and carbonates of sodium and potassium are easily soluble in water, because they have low lattice energies owing to their smaller charge density and larger atomic size.
Polar water molecules can easily break the electrostatic force of attraction in their ionic crystal lattice. Moreover, these metals have heats of hydration.
On the other hand hydroxides of Mg and Ca are sparingly soluble in water, because they have higher lattice energies owing to their large charge density and smaller atomic size than sodium and potassium.
Polar molecules can thus break only partially the electrostatic forces of attraction in their ionic crystal lattices. Moreover, these metals possess low heat of hydration.
(i) Importance of limestone
(a) It is used in the manufacture of quick lime.
(b) It is used as a building material in the form of marble.
(c) It is used in the manufacture of quick lime.
(d) It is also used as a raw material for the manufacture of sodium carbonate in solvay process.
(e) It is used as a constituent of toothpaste.
(ii) Importance of Cement
(a) It has become so important next to iron and steel it can be called as a commodity of national necessiry for any country.
(b) It is used in concrete and reinforced concrete.
(c) It is used in plastering and in the construction of bridges, dams and buildings.
(iii) Importance of Plaster of Paris
(a) It is used for producing moulds for pottery, ceramics etc.
(b) It is used for making statues, models and other decorative materials.
(c) It is used in surgical bandages known as plasters for setting broken and fractured bones in the body.
Since the hydration tendency depends upon charge to radius ratio (q/r); the hydration tendency decreases from Li+ to Cs+. Thus Li+ in aqueous soluiton is very strongly hydrated. Thus lithium salts are commonly hydrated and those of the other alkali ions usually anhydrous.
The low solubility of LiF is due to its high lattice enthalpy. LiCl has much higher solubility in water. This is due to the small size of Li+ ion and much higher hydration energy.
Significance of sodium and potassium in biological fluids: K+ and Na+ cations are present in the red blood cells. The ratio of K+ to Na+ ions in mammals such as human beings, rabbits, rats and horses is 7:1. In cats and dogs the ratio is 1:15. In order to establish this ratio called concentration gradient in the cell, work has to be done. Biologists have suggested different mechanisms involving sodium pump and potassium pump for this purpose. The cation gradients control the development and the functioning of the nerve cells. During the state of rest the potential of the nerve cells is linked to the K+ ion concentration across the membrane. During the activation of the nerve cells, a chemical called acetyl choline is released near its end plate and membrane potential is discharged. This discharge is transmitted through the length of the nerve cell by an electric pulse. Thus it is clear that Na+ and K+ ions have a significant role in biological fluids.
Significance of magnesium and calcium in biological fluids:
(i) Mg2+ ions are present in chlorophyll which is the green colouring matter present in plants. Chlorophyll absorbs light from sun and carries the process of photosynthesis in plants.
(ii) Ca2+ ions occur as phosphates in the bones of both human beings and animals. These ions also play an important role in the miscle contraction. The malnutrition in children is mainly due to the deficiency of the Ca2+ion.
(iii) Both Mg2+ and Ca2+ ions catalyze the formation of pyrophosphate linkages which control the various biological systems. The pyrophosphates undergo hydrolysis with the release of energy. This process is controlled by Ca2+ ions.
(i) sodium metal is dropped in water ?
(ii) sodium metal is heated in free supply of air ?
(iii) sodium peroxide dissolves in water ?
(i) 2Na(s) +2H2O (l) → 2NaOH(aq) + H2(g).
(ii)2Na(s) + O2(g) → Na2O2(s) (excess from air sodium peroxide free from CO2)
(iii) 2Na2O2(s) +2H2O(l) → 4NaOH (aq) + O2(g).
E0 for M2+ (aq) + 2e– _ M(s) (where M = Ca, Sr or Ba) is nearly constant.
(a) This shows that the enthalpy of ionization is increasing of Cs+ to Na +ion it means that the ionising strength increases from Na+ to Cs+
(b) Lithium is the only alkali metal which reacts directly with nitrogen in air to form the nitride, Li3N
6Li + N2 → 2Li3N
(Lithium nitride)
This is due to its small size and greater polarizing power. Its reducing power and E0 are high.
From the electrode potential (E0) of alkali metals which measuring the reducing power represents another change from Ms to M+(aq). It depends upon three parameters: (a) sublimation, (b) ionization and (c) hydration enthalpies.
The equation
M2+ +2e- → M(s)
shows that the standard electrode potential of Ca, Sr and Ra are always the same.
(i) a solution of Na2CO3 is alkaline ?
(ii) alkali metals are prepared by electrolysis of their fused chlorides?
(iii) sodium is found to be more useful than potassium ?
(i) The solution of sodium carbonate is alkaline in nature. Because when sodium carbonate is treated with water, it gets hydrolysed to form alkaline
(ii) The alkali metals are very reactive and are strong reducing agents so they cannot be extracted by usual methods. This is due to the following reasons:
(a) They are strong reducing agents.
(b) They cannot be extracted by electrolysis of their aqueous solutions. Because the metals formed will react immediately react with water forming their hydroxides. Therefore these metals are generally isolated by the electrolysis if their fused metals chlorides.
(iii) The sodium metals are more useful than potassium due to the following reasons:
(a) Industrial uses of sodium metal reflects its strong reducing power, about 60% of world production of sodium are used to make tetraethyl lead PbEt4 for gasoline antiknocks.
(b) Sodium is also used for the preparation of sodium compounds such as peroxide, amide and sodium cyanide.
(c) It is also used in dye industry.
(d) It is also used for detecting the presence of nitrogen, sulphur and halogens in organic compounds. It is widely used as sodium amalgam as a reductant.
(e) Liquid sodium is used in nuclear reactors as a medium for heat exchange. So sodium is a more useful metal than potassium.
(a) Na2O2 and water
(b) KO2 and water
(c) Na2O and CO2.
(a) 2Na2O2+2H2O → 4NaOH +O2
(b) 2KO2+ 2H2O → 2KOH + H2O2+O2
(c) Na2O +CO2 → Na2CO3
(i) BeO is almost insoluble but BeSO4 in soluble in water,
(ii) BaO is soluble but BaSO4 is insoluble in water,
(i) The solubility depends upon two factors:
(a) Lattice energy, (b) hydration energy.
BeO oxide is insoluble in water because its lattice energy is large than its hydration energy. On the other hand BeSO4 are readily soluble because the hydration energy of Be2+ion are higher which over come the lattice energy factor and therefore BeSO4 readily dissolves in water.
(ii) Barium oxide (BaO) is soluble in water because its hydration energy is greater than its lattice energy. On the other hand the lattice energy of BaSO4 is very high due to its bivalent charges so that hydration energy released is not sufficient to overcome the lattice energy and to break the bond and it remains insoluble.
(a) Na (b) K (c) Rb (d) Cs
(d) Cs.
(a) MgCO3 (b) CaCO3 (c) SrCO3 (d) BaCO3
(d) BaCO3.


text:
A couple on a deep-wilderness hike become hopelessly lost within an aggressive black bear's territory.
This is Backcountry and you are watching MovieZion
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Bradford Mobile Phone & Tablet Repairs
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A broken mobile phone or tablet is never a good thing. Luckily, you can get yours repaired in a flash with Quick Mobile Fix.
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We repair a huge variety of mobile devices, including all Apple devices, like the iPhone, iPad and iPod, all Samsung Galaxy devices, all HTC phones including the One Series and Desire, plus a selection of Google Nexus, Nokia, LG and Motorola phones. We can fix almost any mobile device related issue, so if you need an iPhone screen repair or your iPad has water damage, get in touch and we will repair your device for a competitive price. We also offer a number of additional services such as mobile phone unlocking and phone customisation.
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Sending your mobile device to us is easy and totally free, thanks to our free post label from the Royal Mail.
For more information on how to send your device to Quick Mobile Fix, please read this or watch the video below:
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To take advantage of our free postal service, you will need to put your printed free post label on the parcel and take to your local post office.
Below, we have listed the main Post Offices found in Bradford:
Darley Street - 38-40 Darley Street, Bradford, West Yorkshire, BD1 3HN - Opening Times: 9 AM - 5:30 PM
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University - 10 Manville Terrace, Bradford, West Yorkshire, BD7 1BA - Opening Times: 9 AM - 5:30 PM
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If these Post Offices are not local to you, please use this free Post Office Branch Finder tool to find your local office.
Our Courier Service
We also use courier company APC, if for any reason you need to find your local Bradford based APC depot - click here


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The Cadillac Escalade has become an iconic SUV thanks to its popularity with celebrities; however it has also become an honest family favorite and helped put the company back on the map. The 2015 Cadillac Escalade keeps the tradition of the car in that the shell has not been changed too much, aside from a few improvements. That´s no bad thing as the Escalade boasts imposing looks that are timeless.
Inside though Cadillac has thrown the kitchen sink at the 2015 Escalade. You expect a level of luxury when you get in a Cadillac, but the new Escalade ($TBA) takes things to a new level with a sumptuous leather bound interior that is dashed with touches of wood. As ever the ride is stunning, ironing out any kinks in the road, and thanks to Bose Active Noise Cancellation technology you won´t hear a thing.
A 420 horsepower 460 lb-ft torque 6.2-liter V8 offers 4WD or 2WD variants, and delivers plenty of power for SUV needs. via


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About This Statistic
This statistic represents the total number of licensed drivers in the United States in 2015, with a breakdown by state. In 2015, there were a little over 455,600 licensed drivers in the District of Columbia.
Show more
U.S. licensed drivers by state
The driver's license became mandatory in the United States in the early 20th century, with Missouri and Massachusetts being the first states to require an official license for operating certain types of motor vehicles, including motorcycles, passenger vehicles, trucks, trailers or buses. New Jersey became the first state to require all drivers to pass a mandatory test before being granted an official driver's license.
In 2015, there were about 218 million licensed drivers in the United States. At around 25.5 million, California issued the highest number of licenses in the country that year. Not only is California the U.S. state with the highest number of licensed drivers, but it is also the most populous state in the U.S. overall, representing close to 12 percent of the country's total population. While 95 percent of residents aged 65 to 69 held a driver's license in 2012, the percentage of U.S. driver's license holders between 20 and 24 stood at only 76 percent in that same year.
When it comes to accidents, people aged 21 to 24 are most at risk. Across all age groups, the male population has substantially higher death rates than the female population.


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Evian Mineral Water Spray rehydrates skin suffering from overheated or dry office air. This spray also revives your makeup throughout the day, and keeps you looking fresh by replenshing that much needed moisture. Visit evian.ca for more information.
This product is rather expensive but I found it at a local Winners where it was 8 dollars less than at sephora. I also have a very oily face and it seems to hold that back.
I purchase this to use after applying my foundation and i must say I love the way it feels on my skin. I wouldn't say there is much difference than misting with water however. I mainly purchase this for a wake me up in the morning, the summer or when my foundation looks a little dry.
I've seen video after video about how amazing the Evian Mineral Water Spray is and how moisturizing it is from countless amounts of YouTube makeup gurus. So, I decided to go out and get myself a small bottle to try it out and see what all the fuss was about. I have to say, I was really excited to try it because these makeup gurus have never steered me wrong before. However, after trying the spray for about 3 months I have to say it is a total rip off. I've seen it do absolutely nothing for my skin and believe I paid $14.00 on a well designed water bottle. I see no practical use for it at all in my beauty/skincare routine. And, to be completely honest, I've been using this product as a training device with my new puppy to scold him from biting my make up brushes. The only use I see for this product would either be as a training device for dogs (haha), or something to spritz on your face on a hot summer day. I would not recommend this product to anyone because it is a complete waste of money.
When I first purchased Evian's Facial Spray, I was thinking "this will just be spraying water on my face for a high price!" My opinion was quickly changed when I tried this product!
My face always has a redness to it, and is extremely sensitive to any thing! This facial spray was a kiss of fresh air on my skin! I noticed a huge reduction in my redness, and my skin felt softer and more alive than it has in years!
Sephora sells this product for $12.00 for a two pack. That may seem expensive, but I find that one spray can will last me for at least 3 weeks if not more!
This came to the ultimate test when me and my family went out on a boating trip along the coast. It was a very sunny day, and I could feel my skin becoming red!
I quickly got out my Evian Facial Spray and instantly my face felt refreshed and cooled!
My mom loves this product as well and we always rave above it to whoever will listen!
The results of this product depend entirely on your expectations. It IS simply Evian water misted from a can. It does give your skin moisture--in the most literal way--but I wouldn't buy this as a moisturizer....subtle difference here. Anyway, I would buy it for a cool, refreshing pick-me-up on a hot day or for office-air-conditioned-parched skin. I've also seen a Sephora salesperson use it as a finishing touch over Bare Minerals foundation.
Sephora sells an Evian "Travel Trio" (3 smaller sized cans) for a decent price. I took these with me on summer vacation last year. They came in handy on the long plane ride and in my purse when it was really hot out. Bottom line here: this is a splurge item and you could put tap water in a spray bottle if you're so inclined.
This is not moisturizer. It is just Evian water in a spray bottle! You're better off buying a plastic refillable bottle with a very fine mist option and filling it up with mineral or spring water yourself. At nearly $11 a bottle for the Evian Spray you are getting SERIOUSLY ripped off.
I have bought it myself, primarily for airtravel, but I was sorely dissapointed. Plus, if you want to keep your skin hydrated, you're better off DRINKING Evian, rather than spraying it on your face.
Very light, light fragrant, made from Evian (famous for its water)
I have really dry skin. With this product, I only need to apply a small amount in the morning and that's all I need to keep my face moisturized. The forumla is light and non greasy. Another bonus for me is that the moisturizer doesn't give me a stinging feeling when my face is so dry that it blister. It's so worth the money.
it's good for all types of skin. it doesn't make me too oily or too dry.
These reviews are the subjective opinions of ChickAdvisor members and not of ChickAdvisor Inc.


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how to pick a good avocados download now CZ4U full file
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|For Mormon boys, a full-time mission is the time to learn to be men. Fresh out of high school,
itÂ's their first experience of living on their own.
After a tearful goodbye to their families, they find themselves in a new place living with other young boys and obeying a set of very strict rules.
These rules teach the boys things they will need to know for the rest of their working lives. They learn to wake up early and work hard, to shave every day, to tie their neckties and polish their dress shoes.
But important as these things are, they are only the superficial lessons a Mormon boy learns as a missionary.
More important are the ways in which he develops his character, learning the value of obedience, service, and brotherhood.
And a lucky few are selected for initiation into The Order to learn firsthand the many erotic secrets of the highest priesthood.
Elder Sorensen is one of these fortunate boys. After fooling around with the other missionaries, he was chosen by The Order and groomed to become one of them.
His education has been thorough — there's hardly an ass in the mission he hasn't had the honor and the pleasure of fucking.
But only recently has he had the pleasure of bottoming. President Oaks had gently walked the boy through the process, opening his hole up and filling it with his seed in the sacrament that conferred priesthood authority on the boy.
As the manÂ's cum leaked out of Elder SorensenÂ's tight pink hole, he felt happy and proud.
He had worried about whether heÂ'd been able to take the manÂ's dick in his virgin hole, but now that he has proven himself, he feels like he can do anything.
But President Nelson has called the boy in for an evaluation. Sorensen has seen the masculine priesthood leader walking into the ordinance rooms before conducting ceremonies with other boys in the temple. He has admired and envied the muscular manÂ's body. The admiration goes both ways, but as of yet the two havenÂ't interacted.
But although theyÂ've never said a word to each other, the boy has had many wet dreams about worshipping his muscular body before the man pins him down and has his way with him.
As Sorensen dresses for his evaluation, heÂ's already rock hard. He has heard the man loves stuffing his cock down missionariesÂ' throats and into their beautiful tight pink holes.
Â…What he doesnÂ't know, but will soon find out, is that Nelson is extremely well-endowed.
|2016-09-02 07:40:44
|866.19 MB (908,262,576 bytes)
|Num files
|1 files


text:
Before the high waists of the 70s and the low waists of the 90s, there was the drop waist of the 20s. It seems many of you were ready for a new decade of influence and Paul Poiret's liberating style of yore is here to liberate us once again. With all the flapper-inspired gallimaufry for Fall, drop waist dresses evoke a sense of ease and sophistication - a stellar combination. If you're tired of a trapeze cut or a baby doll silhouette, try one of these streamlined dresses. Come Fall, just throw one on over a chic long sleeve tee or turtleneck; it may compel you to throw on a long strand of pearls, a pair of buckled flats, a flirty little hat and read some Emily Dickinson at your local cafe. Or maybe that's just my fantasy...
Join The Conversation
I like 'em! I only have one white one in my wardrobe and i'm waiting for a special event to put them on xD
i dont think it'd work for my body being short and all... wont it make me look shorter than i really am?
Oh dear. This has never suited me thanks to my erm.. generous bust size
Umm...like the idea, but I don't think it works for ME; big hips...err
I already have a long torso, so I'd look like I have no legs at all!! I think I'll have to pass on this one...
Err... Generally, my look doesn't allow me to follow the trend.. and this time... haah I can predict my fortune that.. I will be an 'out' girl for sure. It requires alot to look goodie goodie in that.. quite agree with DarlingDA though. Mmm.. inertia reminds me of my Jap. friend.. right.. she looked so cutie cutie in that.. true.
Girly glitter comments from www.GirlyTags.com
Girly glitter comments from www.GirlyTags.com
I don't think anyone with curves looks good in them. Even super skinny girls look a little lumpy in them to me.
This style's HUGE here in Tokyo. There are many women with very narrow hips and it looks great on them. I can't wear it. My hips are medium size and the style makes me look as broad as a dinner table.
I think my hips are to big for this look.
I think my legs are too short for this to look good on me. :(
Not a fan of the drop waist dress... don't think their flattering on anyone.
I was just drooling over that MJ dress with the sash this morning.
I love drop-waisted dresses. And the itmes posted here are pretty
are they flattering for big hips?
I love drop waist dresses, but last time they were posted, eh-vah-ree-one said they hated them 0.o
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Overview Edit
The International Patent Classification (IPC) is an internationally recognized classification system, maintained by the World Intellectual Property Organization (WIPO) and assigned to patent documents by the various patent offices around the world. The IPC is widely used throughout the world (although less so in the United States).
There are eight distinct sections of the IPC (lettered A-H) and these sections are further subdivided into classes. Each class consists of the section letter, followed by two digits. For example, section A21 is the class for Baking; Edible Goods, and G02 is the class for Optics.


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GraphicRiver Blank Bottle for Red Wine with Glass 9686828
Stock Vector \ Objects \ Man-made Objects
Isolated \ Vector \ Bottle \ Realistic \ WineryBlank \ Branding \ Illustration
Stock Vector - Blank Bottle for Red Wine with Glass 9686828 by tashal @ GraphicRiver
Stock Vector \ Objects \ Man-made Objects
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Wine Labels ; Menu Template with Alcohol ; Lightbulbs ; Set of Beer Labels; Glowing Light Bulb Idea Concept; Running Time Concept Banner; Banner for Beer Advertisement.
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Inflation in China inches up to 2% in November
On a month-on-month basis, November's CPI rose by 0.1 percent from the previous month, China's National Bureau of Statistics (NBS) announced Sunday.
Beijing: China's consumer price index (CPI), a main gauge of inflation, marginally rose to two percent in November due to surging food prices.
On a month-on-month basis, November's CPI rose by 0.1 percent from the previous month, China's National Bureau of Statistics (NBS) announced Sunday.
"November growth rate was largely attributable to a surge in food costs," Wang Jun, an official of the China Center for International Economic Exchanges told the official media here.
The CPI stood at 33-month low of 1.7 percent in October.
Food prices that account for nearly one-third of the weight in China's CPI calculation, rose 3 percent in November from a year ago, pushing the index up 0.95 percentage points.
Vegetable prices jumped by 11.3 percent year-on-year in November as cold weather disrupted supplies.
Prices for aquatic products gained 4.9 percent from one year earlier, the NBS statement said. Excluding food prices, China's CPI edged up 1.6 percent.
Wang forecast that China's economy will expand by 7. 8 percent in 2012 and that the CPI will reach around 2.8 percent for the entire year, well below the government's target of keeping inflation under 4 percent.
"A combination of low inflation and modest economic growth is surely a desirable outcome for China in the difficult year of 2012," he told state-run Xinhua news agency.
Wang said he believes the CPI will pick up in 2013, but not dramatically. "Consumption and investment will maintain mild growth next year, which will prevent the economy from overheating and be conducive to controlling inflation."
The NBS also said China's producer price index (PPI), which measures inflation at the wholesale level, fell 2.2 percent year on year in November -- marking the ninth straight month of decline after the PPI dropped in March for the first time since December 2009.
However, the decline was smaller than 2.8-percent drop in October, indicating the economy has been stabilising.
Because of sluggish external demand and a cooling property market, China's economy grew 7.4 percent in the July- September period, its weakest in more than 3 years.
In order to buoy growth, the central bank lowered benchmark interest rates twice this year, cut banks' reserve requirement ratios (RRR) by 100 basis points, pumped liquidity into the market and approved a series of infrastructure projects worth more than 1 trillion yuan.
A mild rise in the CPI and a recovery in factory-gate prices, however, has dampened expectations of further policy loosening as the economy recovered.
Wang said the country should continue to maintain a positive fiscal policy and a stable monetary policy over a period of time to consolidate the economic recovery momentum.
Liu Ligang, an economist with ANZ National Bank Ltd, said the possibility of a 50-basis-point RRR cut cannot be ruled out in December.


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He was an antimaterialistic hippie who capitalized on the inventions of a friend who wanted to give them away for free, and he was a Zen devotee who made a pilgrimage to India and then decided that his calling was to create a business.discount ugg boots for girls The Blaney's polished aesthetic travels easily from uptown to downtown, while heel-cradling, luxurious wool and an EVA insole allow you to make the walk in signature UGG® comfort.Ugg Boots Womens Size 8 This style tends to run a size large. "Even if we lose our money, we'll have a company," said Jobs as they were driving in his Volkswagen bus. I recommend you order 1 size larger than your shoe size. But Jobs, becoming ever more willful, did not make it easy. McKenna suggested it was time for them to leave his office. ugg boots sale clearance uk I get another email a few weeks later letting me know that they DO NOT have any Langsford Parka in size Large in any color but brown.Womens Ugg Kensington Boots But Jobs, becoming ever more willful, did not make it easy. First: This is the first CG jacket I've owned where the sizing was spot on. In order to make the project his own, Jobs decided it should no longer be code-named after Raskin's favorite apple. Wozniak bought a dream home for himself and his new wife, but she soon divorced him and kept the house. Sometimes a design can be so sleek and simple that a user finds it intimidating or unfriendly to navigate.Ugg Mini BootsClassic Ugg Boots Sale It was a pursuit with many paths toward enlightenment.
He followed the beat of a different drummer, and that came from being in a different world than he was born into. discount ugg boots for girls "There was a hatch in the ceiling leading to an attic which had a huge amount of space," Jobs said.Cheap New Ugg Boots Wozniak bought a dream home for himself and his new wife, but she soon divorced him and kept the house. However, cost about a third what Uggs and Emus cost and are fairly well made. Markkula said that wouldn't work, and he gave Wozniak a deadline of a few days to decide. He was made non-executive chairman of the board. [discount ugg boots for girls] He had, literally, been able to talk the shirt off another kid's back.
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Which salts do you normally use?
Discussion in 'Water Parameters and Additives' started by viper357, 13 Dec 2015.
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removal & installation
- Remove the strut from the vehicle.
- Clamp the Spring Compressor VAG 1752/2 or equivalent in a vise.
- Install the strut into the spring compressor.
- Pry off the mounting bolt cap.
- Compress the coil spring and remove the self-locking nut from the piston rod.
- Matchmark the position of the spring retainer and spring mount.
- Remove the spring seat and related components noting the order of removal.
- Remove the strut from the spring compressor.
- Release the tension on the coil spring, and remove the spring out of the compressor.
To install:
- Install the new spring into the compressor.
- Compress the spring and insert the strut through the spring.
- Install the spring seat and related components in the reverse order as they were removed and aligning the matchmarks.
- Install a new self-locking nut.
- Reinstall the mounting bolt cap.
- Release the spring compressor and install the strut into the vehicle.


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I Love Guns & Coffee Mug
Not just any mug! This classic white mug is bigger than most, holding 16oz of your favorite beverage. Hot or cold, you will enjoy every sip while telling the world I LOVE GUNS AND COFFEE
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text:
Whitson is about 6-2.5, 280, very strong, plays with great technique and moves well. He took reps at guard and center but probably projects best as a center. He was an all-league selection as a junior and could be a steal for someone.
Peoria (Ariz.) Centennial offensive guard Kamryn Bennett made the road trip to SoCal and had a solid camp as did Apple Valley's (Calif.) Troy Bacon. Both players are tough and nasty and play with a high compete level.
An intriguing defensive end at the camp was Chino Hills (Calif.) 2015 defensive end Trent Goens. Goens has a nice frame and is a natural pass rusher. If he can continue to improve his overall quickness and athleticism, he has a shot to be one of the top players in the state when he's a senior.
Irvine (Calif.) Beckman rush end Charles Wright has seen his stock rise quite a bit in the last month with new offers rolling in every few days. Wright is a solid 6-3, 200 pounds but looked like he might have been favoring his leg a little and didn't show off the same kind of explosiveness we've seen from him in the past.
The top linebacker of the day and one player we know who picked up an offer following the camp was Harbor City (Calif.) Narbonne's Uchenna Nwosu. Nwosu played backup minutes for the Gauchos last year but has a lot of upside to him. He has a great frame at about 6-2, 210 pounds, is physically strong, runs well and is a natural athlete.
The running back group was a bit down but Vista Murrieta's (Calif.) Kishawn Holmes put on a show working out with the receivers. He made several highlight reel catches showing great body control and athleticism. He's a natural pass catcher with the speed to get deep and he can run very well after the catch as well.
Westlake Village (Calif.) Oaks Christian's D.J. Riggins has looked great all spring and few backs catch the ball as well as he does. He looked good again on Saturday. Another back to keep an eye on is Carson (Calif.) 2016 standout Daevon Vigilant. Just a rising sophomore, Vigilant is already creating a lot of local buzz and should be an exciting player to watch this fall.
There were a handful of solid quarterbacks on hand including Santa Ana (Calif.) Mater Dei's Chase Forrest, Westlake Village (Calif.) Oaks Christian's Brandon Dawkins, Canyon Country (Calif.) Canyon's Cade Apsay and Long Beach Poly's (Calif.) Tai Tiedemann.
The player who had the most consistent day was Upland (Calif.) 2015 signal caller Tyler Hilinski. Hilinski was very accurate all day, threw a tight ball and showed he had the arm strength to make all the throws.
By far the deepest position in the camp was the receiver and defensive back group. Just a few of the standouts at the receiver position were Los Alamitos (Calif.) Dashawn Gordon, Santa Ana (Calif.) Mater Dei's Ben Humphreys (2015), Buena Park's (Calif.) Jaylinn Hawkins (2015), Rancho Santa Margarita (Calif.) Santa Margarita's Jeremy McNichols, Palmdale (Calif.) Highland's Michael Sewell, Roseville (Calif.) Oakmont's Justin Holmes and Sherman Oaks (Calif.) Notre Dame's Daniel Khan.
Gordon and Khan are explosive slot receivers, Humphreys is a big, physical kid with speed and size and Hawkins might be the best prospect in the group. Don't be surprised to see the Buena Park standout land an offer from the Beavs sooner than later. Holmes had another strong showing and has been good all spring. He has good size, down field speed and catches the ball very well.
The DB group was led by Rancho Cucamonga (Calif.) corner Artuz Manning, LB Cabrillo (Calif.) safety Darren Gardenhire, Rancho Cucamonga (Calif.) safety Kameron Powell (2015), LB Poly (Calif.) corner Demetric Woodard, LB Poly (Calif.) safety Elijah Moody and Upland (Calif.) safety Elijah Jones (2015).
Manning is very quick and plays a lot bigger than his size, Gardenhire was the most physical player in the group and Powell is a talented underclassmen with all the physical tools to be a major Div I prospect in two years.


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A 150g bag containing 10 tea bags of Nitto arabiki mugicha petyo.
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- Description
Acme 92065 Carmeno Collection Espresso Bookcase w/3 Shelves and DoorIncludes
1 BookcaseDimensions
Bookcase: 22" x 11" x 47"H
More from this collection: Carmeno
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Additional Information
SKU 11303550 MPN 92065 GTIN UPC 0840412920653 Brand Acme Collection Carmeno Assemble Length 11 Assemble Width 22 Assemble Height 47 Assembly Required Yes Material No Finish Espresso Styles Contemporary Shipping Time 1-2 Weeks Free Shipping Yes
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