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RFID/Wireless: Race to Utopia
Our technology correspondent examines where RFID and wireless communications currently stand as logistics and supply chain management enablers and then defines the remaining barriers to adoption. Just how far are we from real-time visibility?
Latest NewsQ4 2017 Rail/Intermodal Roundtable: Improvements apparent; work remains The State of the DC Voice Market Comtrex and Rockwood Steel study addresses operations gaps in freight railroad sector Behind the Koerber Group/HighJump acquisition Report: Amazon introduces new app for truck drivers More News
Latest ResourceThe State of the DC Voice Market Available On-Demand. Watch Now.
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It's no secret that mobile and wireless devices are handling more and more data and communications for businesses across all sectors.
Within the supply chain, everything from smart phones, to voice-enabled devices, to RFID is changing the way logistics and transportation operations are being managed.
Over the next few pages we'll look at how far RFID and wireless communications have come in the supply chain, where these technologies currently stand as logistics enablers, and then examine what barriers to adoption still remain. We'll also attempt to show shippers just how close we are to achieving real-time supply chain management and logistics visibility— and just how far we need to go to realize that utopian vision.
RFID: Spending to increase dramatically
Radio-frequency identification (RFID) stands as one of the original technologies designed around supply chain processes. Rewind back about eight years, says Simon Ellis, practice director for supply chain strategies at IDC Manufacturing Insights, and RFID was one of the most hyped technologies in logistics and supply chain management.
About the AuthorBridget McCrea, Editor Bridget McCrea is a Contributing Editor for Logistics Management based in Clearwater, Fla. She has covered the transportation and supply chain space since 1996, and has covered all aspects of the industry for Logistics Management and Supply Chain Management Review. She can be reached at [email protected]
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10th Annual Salary Survey: The Price of Performance Let's put Automatic Data Capture (ADC) Technology to Work View More From this Issue


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text: Lazy River From left, Cathy Breeden, Stephani Sorrenko and her daughter Angela, 11, take a lazy float down the South Fork of the Shenandoah River in Front Royal on a warm summer afternoon. Rich Cooley/Daily Local News Front Royal man still being sought Town sees Avtex redevelopment cost rising FRONT ROYAL – The cost to bring ITFederal and other businesses into the former Avtex site, along with the added ... County extends leash law FRONT ROYAL – River Bend Farm has joined a growing number of Warren County neighborhoods that don't allow dogs ... Board OKs waiver for Christendom chapel FRONT ROYAL – Christendom College can move forward with its plan to build a new chapel. The Board of Supervisors ... Eagles buy Old Mill: Group aims to get wheel turning again STRASBURG – After renting the basement of the building that housed the Old Mill Restaurant for 28 years, the ... It's Looking Like Christmas


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Lan Chile airliners
Lan Chile airliners at Santiago airport. Two of South America's biggest airlines, Chile's LAN and Brazil's TAM, on Friday announced they planned to merge to create Latin America's largest carrier.
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Elementary school 'share tables' keep unwanted lunch food out of trash
Whether it's Chip Kelly or not, new Gators coach must clean up McElwain's monumental mess
David Cassidy remains in Fort Lauderdale-area hospital with multiple organ failure
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Cover and Interview of Cohaku issue No 16!
October 04, 2017 Tine Marie Cosplay, tutorial, Uncategorized, WonderWoman tags: cohaku, cosplay, costume, marie, norway, riis, tine, tinemarieriis, tutorial, woman, wonder, wonderwoman, workshop 0 comments
October 17, 2015 Tine Marie anime, Cosplay, Gaming, GIGACON, Uncategorized, Video tags: cosplay, costume, gigacon, league of legends, marie, mememe, mylittlepony, riis, the legend of zelda, tine, tinemarieriis, valkyrie leona, world of warcraft 0 comments
- Cover and Interview of Cohaku issue No 16! October 04, 2017
- Wonder Woman / Justice League Cosplay Chest plate Tutorial. September 25, 2017
- Wonder Woman 2017 Cosplay, VLOG and behind the Scenes! June 24, 2017


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"Hard work is a prison sentence only if it does not have meaning."- Malcolm Gladwell"I like to reinvent myself — it's part of my job."- Karl Lagerfeld"Action may not always bring happiness, but there is no happiness without action." - William James"Your purpose in life is to find your purpose and give your whole heart and soul to it."- Gautama Buddha"When he worked, he really worked. But when he played, he really PLAYED."- Dr. Seuss"There is no time for cut-and-dried monotony. There is time for work. And time for love. That leaves no other time."- Coco Chanel"If you had to identify, in one word, the reason why the human race has not achieved, and never will achieve, its full potential, that word would be meetings."- Dave Barry"We can only see a short distance ahead, but we can see plenty there that needs to be done."- Alan Turing"If you say that getting the money is the most important thing, youll spend your life completely wasting your time. Youll be doing things you dont like doing in order to go on living, that is to go on doing thing you dont like doing, which is stupid."- Alan W. Watts"We need to remember whats important in life: friends, waffles, work. Or waffles, friends, work. Doesnt matter, but work is third."- Leslie Knope"There is no such thing as work-life balance. Everything worth fighting for unbalances your life."- Alain de Botton"Ive heard that hard work never killed anyone, but I say why take the chance?"- Ronald Reagan"If you can do a half-assed job of anything, youre a one-eyed man in a kingdom of the blind."- Kurt Vonnegut Jr."I am focused on the work. I am constantly creating. I am a busy girl. I live and breathe my work. I love what I do. I believe in the message. Theres no stopping. I didnt create the fame, the fame created me."- Lady Gaga"I dont really like coffee, she said, but I dont really like it when my head hits my desk when I fall asleep either." - Brian Andreas"If you care about what you do and work hard at it, there isnt anything you cant do if you want to."- Jim Henson"A man is not idle because he is absorbed in thought. There is visible labor and there is invisible labor."- Victor Hugo"If women are expected to do the same work as men, we must teach them the same things."- Plato"The caterpillar does all the work, but the butterfly gets all the publicity."- George Carlin"If people knew how hard I had to work to gain my mastery, it would not seem so wonderful at all."- Michelangelo Buonarroti"One of the symptoms of an approaching nervous breakdown is the belief that one's work is terribly important."- Bertrand Russell"Give a bowl of rice to a man and you will feed him for a day. Teach him how to grow his own rice and you will save his life."- Confucius"Spending time with God is the key to our strength and success in all areas of life. Be sure that you never try to work God into your schedule, but always work your schedule around Him."-Joyce Meyer"A person who has not done one half his days work by ten oclock, runs a chance of leaving the other half undone."- Emily Brontë"The artist is nothing without the gift, but the gift is nothing without work."- Émile Zola"In most cases being a good boss means hiring talented people and then getting out of their way."- Tina Fey"I dont want to do anything. I dont even want to start this day because then Ill just be expected to finish it."- Rainbow Rowell"I want to do it because I want to do it. Women must try to do things as men have tried. When they fail, their failure must be but a challenge to others."- Amelia Earhart"The heights by great men reached and kept were not attained in sudden flight but, they while their companions slept, they were toiling upwards in the night."- Henry Wadsworth Longfellow"No man needs sympathy because he has to work, because he has a burden to carry. Far and away the best prize that life offers is the chance to work hard at work worth doing."- Theodore Roosevelt"It's a recession when your neighbor loses his job; it's a depression when you lose your own."- Harry Truman"I always arrive late at the office, but I make up for it by leaving early."- Charles Lamb"I am a person before I am anything else. I never say I am a writer. I never say I am an artist...I am a person who does those things."? Edward Gorey"Be steady and well-ordered in your life so that you can be fierce and original in your work."- Gustave Flaubert"In the name of God, stop a moment, cease your work, look around you."- Leo TolstoyWithout ambition one starts nothing. Without work one finishes nothing. The prize will not be sent to you. You have to win it."- Ralph Waldo Emerson"It has been my observation that most people get ahead during the time that others waste."- Henry Ford"We often miss opportunity because its dressed in overalls and looks like work."- Thomas A. Edison


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July 11, 2013
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CHARLOTTESVILLE, Va.—Six former Cavaliers will be competing this weekend in the World Rowing Cup III regatta in Lucerne, Switzerland, Friday through Sunday (July 12-14). The group includes 2013 graduates Sarah Cowburn and Susanne Grainger, Christine Roper (Class of 2011), Inge Janssen (Class of 2010), Kerry Maher Shaffer (Class of 2007) and former UVa softball and volleyball player Meghan O'Leary (Class of 2008).
Cowburn, the 2013 Atlantic Coast Conference Rowing Scholar-Athlete of the Year, is representing Great Britain in the women's eight. Cowburn, a two-time All-American, was also named to the 2013 Capital One Academic All-America At-Large Third Team.
Grainger, a 2013 CRCA Second-Team All-American, and Roper, a 2011 second-team All-American, will row in the Canadian women's eight against Cowburn. Roper will also compete in the women's four. Also rowing for Canada will be Shaffer, who will compete in the women's double sculls.
Janssen, who competed for the Netherlands at the 2012 London Olympics in the women's double sculls, will compete in the women's single sculls in Lucerne. She earned bronze in the event at the 2013 European Championships.
O'Leary won the women's double sculls at the USRowing National Selection Regatta in May and will compete at the U.S. senior international level for the first time.
The World Rowing Cup regattas serve as a lead up to the World Rowing Championships, which will be held in Chungju, South Korea, Aug. 25-Sept. 1.
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Hunter Dazzles as 'Hoos Stay UnbeatenMen's Basketball11/19/17Behind a career-high 23 points from redshirt freshman De'Andre Hunter, unbeaten Virginia defeated Monmouth 73-53 on Sunday at JPJ.'Hoos Rue Missed OpportunityFootball11/18/17On an afternoon when Kurt Benkert threw four touchdown passes, Virginia twice built 14-point leads before falling 44-28 to No. 2 Miami at Hard Rock Stadium.Cavalier Football Notebook -- Miami WeekFootball11/16/17Two regular-season games remain for Virginia (6-4 overall, 3-3 ACC), which plays No. 2 Miami (9-0, 6-0) at noon Saturday at Hard Rock Stadium.
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UVA Wins Varsity Eight Race at Rivanna Romp
W. Rowing | 11/12/2017
The Virginia rowing team concluded its fall season with a win in the Varsity Eight race at the...
Cavaliers Host Rivanna Romp on Sunday
W. Rowing | 11/10/2017
The Virginia rowing team concludes its 2017 fall schedule on Sunday morning (Nov. 12) at the...
Sauer Adds Edwards to Coaching Staff
W. Rowing | 11/1/2017
Edwards arrives in Charlottesville after serving as an assistant coach at Rutgers for the past...
Virginia Places Third at Princeton Chase
W. Rowing | 10/29/2017
The Cavaliers' Varsity Eight placed third, while UVA's Second Varsity Eight finished ...
UVA Rowing Returns to Action at the Princeton Chase
W. Rowing | 10/27/2017
The Virginia rowing team travels to Princeton, N.J., on Sunday (Oct. 29) to compete in the...
UVA Alumni Sets Course Record at HOCR
W. Rowing | 10/22/2017
UVA's Varsity Eight finished fourth among collegiate boats and ninth overall with a time of...
UVA Opens Fall Season at the Head of the Charles
W. Rowing | 10/20/2017
The 53rd edition of the Head of the Charles will feature 2,281 crews and 10,551 athletes...
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Hello Dear Friends! It is that time again... ~*Friday Finishes*~ time... and there are some fabulous ones to share!
Patti has stitched up the latest ~*Valentine*~ freebie... and has if offered on her TDIPT shoppe. Her's finished to a size of 3 by 6 inches which makes it perfect for a scissor FOB. She has a key hanging from it now, but says it is removable and can be replaced with your scissors. Excellent! Patti's finishes are always grand!
Iris is in the mood for love too! She has stitched up both the latest ~*Valentine*~ freebie and ~*My Sweet Valentine*~ to decorate her Valentine's Tree. How sweet is this?
A closer look at Iris' ornaments...
(The third ornament is a freebie from The Stitcherhood.)
Laura has been keeping both her punchneedle and stitchin' needle busy! She used the freebie doodle, ~*1857 Bunny*~ to adorn a hornbook... but also added a darling cross stitch trim to the top. How sweet! Laura told me too that she has ventured into over~dyeing her floss. She used tan dye over light blue and green. What a great result!
Thank you, to all of you, for playing with the freebies & sharing your truly awesome works!
Wishing you all warm smiles...
Friday, February 5, 2010
~*Friday Finishes*~
Posted by primitivebettys at 8:37 AM
6 comments:
I like them all Betty. Very lovely.ReplyDelete
great finishes ~ what a sweet tree...your new Live Laugh Love sampler is on my must have list!ReplyDelete
Very cute! Love your new releases too ~ beautiful..ReplyDelete
I love to see what others have done with designs. Thanks for sharing their pics with us in blogland.ReplyDelete
They are all so sweet Betty! Love when you share them with us...ReplyDelete
Thanks for showing my photo's ... al the finishes are looking great !!ReplyDelete
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text: Bring the little ones to Port Discovery for a special day celebrating our veterans! Create a Shrinky Dink Dog Tag and learn about the service of our Country's great veterans during our interactive community art project Thumb-body Thanks You Map. Make Remembrance Poppies and learn about the tradition of using poppies to commemorate military personnel who have died in war. Also join in a special performance from the Kindersinger, and drop into our early literacy program Mother Goose on the Loose(R).


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• The expressions of rate of reaction and types of rates;
• Stoichiometric relationships between the rates of appearance or disappearance of components in a given reaction;
• Determination of rate orders and rate law using the kinetic data of a reaction;
• The graphical method to determine a first-order and second-order reaction.
• The meaning and calculation half-life of a first order reaction;
• Determination of the activation energy, Ea, either graphically or from rate constants at different temperatures.
• Derive rate law from reaction mechanism.
• The role of catalyst
Chemical Kinetics is the study of reaction rates; that is, how fast a given reaction does proceeds. It is a measure of the change of the concentration of reactants (or products) as a function of time.
Reaction rates provide information regarding how fast a chemical process occurs as well as the mechanism by which a reaction occurs at molecular level.
12.1 Reaction Rates
The rate of reaction is a measure of the change in concentration of reactants or products over time. Rate can be measured at the beginning of the reaction, which is called the initial rate, at any point in time while the reaction is in progress, called instantaneous rate, or over an interval of time, which is the average rate.
In the initial rate the change in concentration of a reactant or product as a function of time is measured within minutes (or seconds) the reaction starts. Determination of the dependence of initial rate to the concentrations of reactants allows one to derive the rate law for the reaction. A rate law is a mathematical equation that shows the dependence of reaction rate to the molar concentrations of reactants at constant temperature.
The instantaneous rate is calculated from the slope of a tangent drawn at any points on the graph of concentrations versus time. The slope of tangent taken at the initial point of the graph is assumed to be equal to its initial rate.
The average rate of reaction is obtained by dividing the change in concentration of a reactant or product that occurs over a longer period of time by the time interval that the change occurs. For example, consider the following reaction at 300oC:
2 NO2(g) 2 NO(g) + O2(g)
If in the first 150 seconds, the concentration of NO2 has decreased from 0.0100 mol/L to 0.0055 mol/L, the average rate for the disappearance of NO2 for first 150 s under this condition is,
= = = 3.0 x 10-5 mol/(L.s)
Suppose that in the next 150 seconds the concentration of NO2 decreases from 0.0055 mol/L to 0.0038 mol/L. The average rate during the second 150 s period is
= = = 1.1 x 10-5 mol/(L.s)
The average rate is the mean of several instantaneous rates taken over a period of time.
Note that instantaneous rates of a reaction decreases as time progresses as the concentrations of reactants decrease. Then the average rate taken over a longer period would have a smaller value compared to those taken over a shorter period after the reaction begins.
How is the rate of reaction measured?
The rate of reaction may be determined by measuring the rate of disappearance (decrease in concentration) of one of the reactants or the rate of formation (increase in concentration) of a product. For example, in the reaction:
2 NO2(g) 2 NO(g) + O2(g)
Various expression of rate can be derived, such as
Rate1 = ; Rate2 = ; or Rate3 =
The stoichiometric relationships between the different rates are as follows:
= =
That is, in this reaction the rate of appearance of NO is the same as the rate of disappearance of NO2, but double the rate of appearance of O2.
1. For the reaction: 2N2O5(g) 4NO(g) + O2(g)
(a) write the rate expression in terms of (i) the disappearance of N2O5; (ii) the formation of NO; (iii) the formation of O2. (b) What are the stoichiometric relationships of the various rates for this reaction?
2. For the reaction: 5 Br-(aq) + BrO3-(aq) + 6 H+(aq) 3 Br2(aq) + 3 H2O(l);
(a) write the expressions of rates in terms of (i) the disappearance of Br-; (ii) the disappearance of BrO3-, and (iii) the formation of Br2. (b) What are the stoichiometric relationships of the various rates for this reaction?
12.2 Rate Laws
Consider a general reaction: A + B C
The rate law is expressed as, Rate = k[A]x[B]y,
where k is the rate constant; x and y are the rate orders with respect to individual reactants. The rate orders x and y are not related to the reaction coefficients. Their values must be experimentally determined from a set of kinetic data. For example, the rate law for reaction:
2 N2O5(g) 4 NO(g) + O2(g), is Rate = k[N2O5]
That is, the rate of the decomposition of N2O5 is first order with respect to [N2O5], which means that the rate will double if [N2O5] is doubled; it will triple if [N2O5] is tripled.
For the reaction: 2 NO2(g) 2NO(g) + O2(g), the rate law is Rate = k[NO2]2.
That is, the rate of the decomposition of NO2 is second order with respect to [NO2]. Therefore, the rate will quadruple if [NO2] is doubled.
The reaction: 2 HI(g) H2(g) + I2(g) is found to be a zero order reaction in the presence of gold catalyst. For this reaction, the rate is independent of [HI].
12.3 Determination of the Rate Law
Method of Initial Rates
For many chemical reactions, the expression of rate law contains only the concentrations of reactants, while the concentrations of products do not appear. However, for some reactions that are reversible, the concentration of products may be part of the rate law. To simplify the rate law and avoid the complication that might be contributed by products in reversible reactions, the measurement of rate for rate law determination is normally done at the moment the reactants are mixed. At this point, we can also assume that the effect of product concentration is considered negligible. Therefore, the rates that are measured are the initial rates.
Example: Consider the following kinetic data for the reaction:
S2O82-(aq) + 3I-(aq) 2SO42-(aq) + I3-(aq)
Expt # [S2O82-] [I-] Initial Rate,
(mol/L) (mol/L) (mol/(L.s)
1 0.038 0.060 1.5 x 10-5
2 0.076 0.060 2.8 x 10-5
3 0.038 0.120 2.9 x 10-5
(a) Calculate the rate order w.r.t. each reactant and write the rate law for this reaction.
(b) Calculate the rate constant and the reaction rate when the concentration of both reactants is 0.050 mol/L?
Solution: The rate law is expressed as Rate = k[S2O82-]2m[I-]n, here m and n are rate orders.
(a) Calculation of rate order, m:
k[S2O82-]2m[I-]n k(0.076 M)m(0.060 M)n 2.8 x 10-5 mol/(L.s)
= =
k[S2O82-]1m[I-]n k(0.038 M)m(0.060 M)n 1.5 x 10-5 mol/(L.s)
2m ~ 2 m = 1 (first order w.r.t. [S2O82-]
Calculation of rate order, n:
k[S2O82-]m[I-]3n k(0.038 M)m(0.120 M)n 2.9 x 10-5 mol/(L.s)
= =
k[S2O82-]m[I-]1n k(0.038 M)m(0.060 M)n 1.5 x 10-5 mol/(L.s)
2n ~ 2 n = 1 (first order w.r.t. [I-]
The rate law is expressed as: Rate = k[S2O82-][I-]
The rate constant, k, can be calculated using data of any one run, such as:
R1 = k(0.038 mol/L)(0.060 mol/L) = 1.5 x 10-5 mol/(L.s);
k = = 6.6 x 10-3 L.mol-1.s-1
When [S2O82-] = [I-] = 0.050 mol/L, Rate = (6.6 x 10-3 L/mol.s)(0.050 mol/L)(0.050 mol/L)
= 1.6 x 10-5 mol/(L.s)
1. Kinetic data for the following reaction are summarized below.
H2O2(aq) + 3I-(aq) + 2H+(aq) I3-(aq) + 2H2O(l),
Expt # [H2O2] [I-] [H+] Initial Rate
(mol/L) (mol/L) (mol/L) mol/(L.s)
1 0.010 0.010 0.00050 1.15 x 10-6
2 0.020 0.010 0.00050 2.30 x 10-6
3 0.010 0.020 0.00050 2.35 x 10-6
4 0.010 0.010 0.00100 1.14 x 10-6
Determine the rate order with respect to each reactant and derive the rate law, expressed as: Rate = k[H2O2]m[I-]n[H+]p. Calculate the rate constant, k.
The Graphical Method for determining Zero-order, First-order and Second-order Rates
Consider a reaction: R Products.
(i) If the reaction is zero-order with respect to R,
This gives [R] = kt, and [R]t = [R]0 – kt;
a plot of [R] versus t yields a straight line with slope = -k
(ii) If the rate is first-order in [R], , which also gives = -kt,
Integrating this equation from time t = 0 to t = t, yields the expression: ln[R]t = ln[R]o – kt; or ln([R]t/[R]o) = – kt; If the common log is used, the integrated expression for first rate would be:
log[R]t = log[R]o – kt/2.30; where, [R]o = concentration at t = 0, and [R]t = concentration at time t.
Plotting ln[R]t versus t yields a straight line with slope = -k; (slope = – k/2.30 if log[R]t is plotted).
(iii) If the rate is second-order with respect to R, or ;
Integrating the equation from time t = 0 to t = t yields the expression:
For second order rate, plotting 1/[R]t versus t yields a straight line with the slope = k (the rate constant)
1. The following data shows the concentrations of dinitrogen pentoxide as a function of time for the following decomposition reaction:
2 N2O5(g) 4 NO2(g) + O2(g)
Time (s) [N2O5], M ln[N2O5] [N2O5]-1,M-1
0 0.0165 -4.10 60.6
600 0.0124 -4.39 80.6
1200 0.0093 -4.68 110
1800 0.0071 -4.95 140
2400 0.0053 -5.24 190
3000 0.0039 -5.54 260
Plot graphs of ln[N2O5] versus t and 1/[N2O5] versus t. Determine whether the decomposition of N2O5 follows a first-order or second-order rate law with respect to [N2O5].
2. The following experimental data are obtained for the decomposition of nitrogen dioxide:
2 NO2(g) 2 NO(g) + O2(g)
Time, s [NO2], M ln[NO2], [NO2]-1, M-1
0 10.0 x 10-3 -4.605 1.00 x 102
60 6.83 x 10-3 -4.986 1.46 x 102
120 5.18 x 10-3 -5.263 1.93 x 102
180 4.18 x 10-3 -5.477 2.39 x 102
240 3.50 x 10-3 -5.655 2.86 x 102
300 3.01 x 10-3 -5.806 3.32 x 102
Plot a graph of ln[NO2] versus t and 1/[NO2] versus t. Determine the decomposition of NO2 follows a first order or second order rate law with respect to [NO2].
Half-Life of Reactions
The half-life (t1/2) of a reaction is the time it takes for the reactant concentration to decrease to one-half its initial value.
For zero-order reaction, t1/2 = [R]0/2k
For first-order reaction, t1/2 = 0.693/k
For second-order reactions, t1/2 = 1/(k[R]o)
1. At high temperature, the decomposition of sulfuryl chloride vapor (SO2Cl2) follows a first order kinetics:
SO2Cl2(g) SO2(g) + Cl2(g)
(a) If the rate constant for the decomposition is 2.20 x 10-5 s-1 at 320oC, what is the half-life for the decomposition of SO2Cl2 at this temperature? (b) How long (in hrs) does it takes for 75.0% of SO2Cl2 to decompose?
2. A jawbone from the archaeological site at Folsom, new Mexico, showed a carbon-14 activity of 4.5 disintegration per minute per gram (dpm/g) carbon at the time it was discovered. If the C-14 activity in a living material is 15.0 dpm/g carbon and its half-life is 5730 years, estimate the age of the jawbone at the time it was discovered. (Radioisotopes decay in first order rate.
3. The decomposition of nitrogen dioxide follows a second order rate law in NO2:
2 NO2(g) 2 NO(g) + O2(g)
The rate constant, k = 0.775 M-1.s-1 at 320oC. What is the half-life for the decomposition of NO2 when the initial concentration of NO2 is 0.0100 M? How long does it takes for 75.0% of the given NO2 to decompose? If the initial concentration is [NO2]o = 0.0100 M, what concentration of NO2 remains after 5.00 hrs?
Determining Integrated Rate Law for Reactions with More Than One Reactant
For reactions that involve more than one reactant, the integrated rate law is determined for one reactant at a time. This is done by having the concentration of the limiting reactant (which rate order to be determined) considerably lower than that of the other reactant. Under this condition, the time dependent change in concentration is significant only for the limiting reactant, while the other reactant is assumed approximately constant.
For example, the reaction: 2NO(g) + O2(g) 2NO2(g) has Rate = k[NO]2[O2]
The reaction can be carried out using [NO]o = 1.0 x 10-4 mol/L and [O2] = 0.10 mol/L. As the reaction progress, [NO] decreases significantly, but the decrease in [O2] is negligible. Under this condition, the integrated rate law equation can be derived in term of [NO]. Then condition can be reversed and the integrated rate law equation is derived in term of [O2].
For this reaction, a straight line with positive slope is obtained for the plot of 1/[NO] versus time and for ln[O2] versus time, which yield a rate law: Rate = k[NO]2[O2].
12.6 Reaction Mechanism
A reaction mechanism is the detailed picture of how a reaction occurs at molecular level. It consists of a set of proposed elementary steps involving molecular species – reactants as well as reaction intermediates. A reaction mechanism explains how a given reaction might occur at molecular level and from which a rate law can be derived, which must agree with the one determined experimentally. If the mechanism consists of more than one elementary step, the sum of these steps must be equal to the overall balanced equation for the reaction.
For example, the reaction: 2A + B C + D may involve the following elementary steps:
Step-1: A + B X;
Step-2: X + A Y;
Step-3: Y C + D
Overall reaction: 2A + B C + D;
Elementary Steps and Molecularity
Elementary steps or elementary reactions are simple steps that together make up the reaction mechanism for a given reaction. Each elementary reaction describes individual molecular event, such as two particles combining or a particle (simple or complex) decomposing. An elementary reaction is characterized by its molecularity, which is the number of particles/molecules involved in the formation of transition-state complex. Thus, an elementary reaction may be characterized as unimolecular, bimolecular, or termolecular. Unimolecular and bimolecular reactions are considered the most common elementary processes.
Rate Law for Elementary Reaction Steps:
Elementary Reactions Molecularity Rate Law
A product Unimolecular Rate = k[A]
2A product Bimolecular Rate = k[A]2
A + B product Bimolecular Rate = k[A][B]
2A + B product Termolecular Rate = k[A]2[B]
For example, in the reaction: 2N2O5(g) 4NO2(g) + O2(g), the proposed mechanism is:
Step-1: N2O5 NO2 + NO3 (Unimolecular)
Step-2: NO2 + NO3 2NO2 + O (Bimolecular)
Step-3: N2O5 + O 2NO2 + O2 (Bimolecular)
Termolecular event is considered very rare; the chances that three particles colliding at the same time, with proper orientation and sufficient energy, are considered extremely small. A possible termolecular event is thought to occur during the formation of ozone from oxygen in the outer atmosphere:
Deriving Rate Law from the Rate-Determining Step
When a proposed mechanism consists of more than one elementary steps, the one with the slowest rate will determine the overall rate of reaction. It is called the rate-determining step, which step represents the rate law for the overall reaction.
Consider the reaction: NO2(g) + CO(g) NO(g) + CO2(g)
If the reaction follows a one elementary step mechanism, the rate law would be: Rate = k[NO2][CO]
However, the experimentally determined rate law is Rate = k[NO2]2
It is proposed that the reaction must involve at least two elementary steps:
Step-1: NO2 + NO2 > NO3 + NO; [slow; rate-determining]
Step-2: NO3 + CO > CO2 + NO; [fast]
The rate law for the rate-determining step: Rate = k1[NO2]2, which is identical in form to the rate law obtained experimentally, in which k1 = k. The second step, which occurs very fast, does not influence the overall rate.
In fact, if the exponents in the rate law differ from the coefficients in the chemical equation, the mechanism for the reaction normally involves more than one elementary step. Most reactions are believed to involve more than one elementary step.
Note that, unlike the overall rate law which must be determined experimentally, the rate law for an elementary reaction can be deduced from its molecularity, since each elementary reaction is a single step event. The exponents in the expression of rate law are the same as the equation coefficients. For example, the rate laws for the following elementary reactions are written as indicated:
1. NO + O3 NO2 + O2; Rate = k[NO][O3]
2. N2O5 NO3 + NO2; Rate = k[N2O5]
3. Br2 + NO ONBr2; Rare = k[Br2][NO]
In addition, certain species such as NO3 may be formed in on elementary step, but immediately consumed in subsequent elementary step; they do not appear in the overall equation. These species are called reaction intermediates.
Rate Law Derived from Mechanism with Slow First Elementary Step
Consider the reaction: 2NO2(g) + F2(g) 2NO2F(g)
The experimental rate law is Rate = k[NO2][F2]
The proposed mechanism for this reaction consists of the following elementary steps:
Step-1: NO2 + F2 NO2F + F; (slow, rate-determining)
Step-2: NO2 + F NO2F; (fast)
Overall Rxn: 2NO2 + F2 2NO2F
Rate law for the rate-determining step: Rate = k1[NO2][F2] = k[NO2][F2]; (k = k1)
Rate Law Derived from Mechanism with Slow Second Elementary Step:
Consider the reaction: 2 NO(g) + O2(g) 2 NO2(g);
The rate law is: Rate = k[NO]2[O2]
The proposed mechanism composed of the following elementary reactions:
Step-1: NO + O2 ⇄ NO3; (fast; equilibrium)
Step-2: NO3 + NO 2 NO2; (slow, rate-determining)
Overall Rxn: 2NO + O2 2 NO2;
Rate law for the slow, rate-determining step: Rate = k2[NO3][NO]
NO3 is a reaction intermediate formed in a fast reversible reaction (step-1) and it concentration quickly reaches a steady state such that, [NO3] = Keq[NO][O2], where Keq is the equilibrium constant for reversible step-1. Substituting for [NO3] in the rate law expression, we obtain,
Rate = k2Keq[NO]2[O2] = k[NO2]2[O2]; (where k = k2Keq)
Correlating Reaction Mechanism with Rate Law
For any reaction, the proposed mechanism must obey three fundamental criteria:
1. The elementary steps must add up to give the overall equation.
2. The elementary steps must be physically reasonable. That is, the proposed step can occur with reasonable probability; they are either unimolecular or bimolecular. A termolecular elementary step is considered unlikely.
3. The mechanism must correlate with the rate law. That is, the rate law derived from rate-determining step must agree with the actual rate law obtained experimentally.
For example, the reaction: 2 N2O5(g) 4 NO2(g) + O2(g) has Rate = k[N2O5].
The proposed mechanism involves the following elementary steps:
Step-1: N2O5 ⇄ NO3 + NO2; (fast; equilibrium)
Step-2: NO3 + NO2 2NO2 + O; (slow)
Step-3: N2O5 + O 2NO2 + O2; (fast)
Overall: 2 N2O5 2NO2 + O2; Rate = k[N2O5]
1. The following mechanism is proposed for a reaction:
(a) Write a balanced equation for the overall reaction
(b) Determine the molecularity of each step.
(c) Write the rate law for each step.
2. Propose a reasonable mechanism for each of the following reactions:
(a) 2NO2(g) + F2(g) 2NO2F(g); Rate = k[NO2][F2]
(b) 2NO(g) + O2(g) 2NO2(g); Rate = k[NO]2[O2]
3. Given the following elementary steps:
Step 1: NO + NO N2O2; (fast)
Step 2: N2O2 + O2 2NO2; (slow)
Write the net equation and derive the rate law for the overall reaction.
12.7 A Model for Chemical Kinetics
The rate law of a reaction relates the dependence of reaction rates on the concentrations of reactants. As we know, the rate of reaction also depends on other factors, such as temperature. This dependency can be explained by the collisional theory of reaction and the formation of activated complex, or transition state.
Consider the following reaction: 2BrNO(g) 2NO(g) + Br2(g)
For the reaction to occur:
• Reactant molecules must collide;
• Molecular collisions must occur with proper orientations;
• Collisions must be energetic and lead to the formation of an activated complex;
• The rate of formation of activated complex is the rate determining step;
• The activated complex eventually leads to the formation of products;
1. The rate of formation of activated complex is proportional to the frequency of effective molecular collisions, which is dependent on reactant concentrations.
2. The activated complex or transition state is separated from the reactants by an energy barrier, called the activation energy (Ea). The formation of transition state complex depends on the fraction of molecules with sufficient kinetic energy that can overcome this energy barrier. This fraction is temperature dependent. At low temperature, the fraction of molecules with sufficient energy to overcome the activation energy barrier and subsequently forms the transition state complex will be low. This fraction increases with temperature, which also increase the overall reaction rate.
3. High activation energy for a reaction also means a lower fraction of molecules with sufficient energy to form the transition state complex. Thus, higher Ea leads to a slower rate of reaction.
The dependence of rate on temperature and activation energy (Ea) is shown the Arrhenius equation for the rate constant, k:
k = Ae-Ea/RT, where A is called the Arrhenius frequency factor.
Taking the natural log, yields the equation: ln(k) = -( )( ) + ln(A).
A plot of ln(k) versus 1/T yields a straight line with slope = -Ea/R; (R = 8.314 J/mol.K).
The activation energy (Ea) can also be calculated using two values of the rate constant k according to the expression:
ln(k2/k1) = – ( – ); or ln(k1/k2) = ( – ); (T must be in Kelvin)
1. For the reaction: 2 N2O5(g) 4NO2(g) + O2(g),
the following rate constants, k, are obtained at different temperatures:
Temp. oC: 45.0 50.0 55.0 60.0
k, s-1 : 4.8 x 10-4 8.8 x 10-4 1.6 x 10-3 2.8 x 10-3
Calculate the activation energy (Ea) for this reaction.
12.8 Catalysis
Catalysts are substances that increase the rate of reactions, but do not get used up by the reactions. A catalyst functions by providing an alternative reaction pathway with lower activation energy. It increases the reaction rate, but does not affect the reaction enthalpy or the equilibrium position.
Homogeneous Catalysis
These are catalysts that have the same phase as the reactants. For example, nitric oxide (NO) catalyzes the reaction between SO2 and O2:
NO catalyst
2SO2(g) + O2(g) > 2SO3(g)
The above reaction, though spontaneously and highly exothermic, is very slow because of the very high activation energy. NO molecules provide an alternative pathway that has a lower Ea.
Step-1: 2NO + O2 2NO2
Step-2: 2NO2 + 2SO2 2NO + 2SO3
Overall: 2 SO2(g) + O2(g) 2SO3(g)
Some catalysts may be involved in the reaction kinetics and the concentration appears in the rate law. For example, iodine which catalyzes the isomerization of cis-2-butene to trans-2-butene is included in the rate law expression. The Uncatalyzed reaction:
cis-CH3CCCH3 trans-CH3CCCH3
Rate = k[cis-2-butene]
Iodine-catalyzed reaction: H H H
cis-CH3CCCH3 trans-CH3CCCH3
Rate = k[cis-2-butene][I2]1/2
Heterogeneous Catalysis
These are catalysts which have a different physical state from the reactants. Most reactions involving gases use inert metals or metal oxides as catalysts. These solid catalysts provide surface areas for molecules to interact effectively. The metal surface also facilitates the breaking and formation of bonds. Ni, Pd and Pt are often used in the hydrogenation of vegetable oil to make margarine and "Crisco oil", where a hydrogen molecule is added to each carbon-carbon double bond in the unsaturated fatty acid chains:
(Ni or Pt)
Heterogeneous catalyses are used in automobile catalytic converters, which consist of Pt, Pd and Rh mixture embedded in ceramic honeycombs. The metals catalyze the following reaction:
2NO(g) + 2CO(g) N2(g) + 2CO2(g)
Catalytic converters reduce the emission of toxic exhaust gases
Some reactions require specific catalysts. For example, Nickel catalyzes the reaction:
CO(g) + 3H2(g) CH4(g) + H2O(g)
Whereas ZnO-Cr2O3 mixture catalyzes the formation of methanol from the same reactants:
CO(g) + 2H2(g) CH3OH(g)


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Lack of communication
In response to your article titled ''Power to residents'' [KMN, February 21], it appears the issue is more one of the inability of Porirua City Council and the Department of Internal Affairs to communicate with each other.
It would be unfortunate if that issue maligned the community representative group which has come from residents within the greater Cannons CreekWaitangirua area.
I understand that community group members were not present with the DIA official at the council briefing.
Let the politicians play politics. That should not take away that there are people on the leadership group who have worked in the community and have earned solid credentials with their record.
If central government is prepared to provide a resource and transparent process that can be developed and which may deliver positive outcomes in a high needs community, wouldn't that be beneficial for residents no matter who provided it?
The council has said many times within my earshot that they have limited resources so hence do not have a monopoly on community-led initiatives.
If Porirua City Council do not see a role for themselves on the playing field, that only leaves them on the sideline. SHANE LAULU, Cannons Creek
Councillor Liz Kelly's view on these matters was they were ''fictional''.
A council officer considered that $30,000 which the document suggested would be needed to relocate an existing user was not relevant as council could just find that money elsewhere, as they do all the time.
No one questioned how the two promoting clubs (and proposed major users) could find the cash needed to purchase time on the park when their latest published financial statements show clearly their tight position and dependence on public grants.
No one challenged one of the proponents when he said that the applicant's Trust Deed limited use of surplus income to development of Ascot Park (which it doesn't).
Only councillor Ken Douglas voted against the proposal, because he alone was concerned that adequate evidence of financial strength hadn't been demonstrated.
And these people control a $60 million enterprise. BRIAN COLLINS,
Papakowhai Wade-brown offensive [KMN, February 28].
I am not overly concerned that she flew a flag that represents only a few Maori but I am concerned at her attitude that ''I am the ceremonial head'' and thus does not need to consult.
She needs to realise that she is not Wellington City, that she was elected by a small majority of a small number of voters, and that she is only one vote on the Wellington City Council.
The reason many voters did not vote was they believed Wellington City Council does not believe in meaningful consultation with residents. How can they have faith that the Wellington City Council will consult with residents when the mayor will not consult with the other elected elected members of her council.
Too much of this ''I don't feel the need to consult'' and she will be a one term, or less, mayor.
GRAEME HANSEN, Tawa through the booms?
The unnecessary use of horns in urban areas has been a pain long before the Matangi units came on the scene. The Matangi horns are if anything less intrusive than the others, and most of the drivers seem to give a short blip rather than some of the thoughtless drivers who delight in delivering long, piercing blasts.
There simply is no justification for horns in urban areas when there are booms bells and lights.
KEVIN CLARK, Plimmerton


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In 1956, Jock Carroll, a journalist with Weekend Magazine, was offered the chance to accompany Glenn Gould on a two-week vacation in Nassau. He was to show how a famous pianist relaxed between international concerts. The story and the resulting photographs illustrate Gould's eccentricities: the solitude he craved, his wild driving habits, his theatrical performances. Seen in the exotic Caribbean environment, Gould presents a curious mixture of brashness and vulnerability.


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I'm a regular on Bali, always stay on the Bukit, but this was my first time at PinkCoco. The rooms are beautiful, spacious, very clean, there's a comfy large bed incl mosquito net and AC, as well as a mini-fridge and a TV. There's tons...More
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This property has been removed by the agent. It may be sold or temporarily removed from the market
2 bedroom maisonette for sale40a, Denbigh Road, Ealing, W13
Property Description
Full description
Tenure: Leasehold
This light and airy maisonette has been thoughtfully updated and well maintained by our client. It has its own private entrance, a bright living / dining room, two bedrooms, a separate fitted kitchen, family bathroom and a fantastic sun trap west facing private garden. The property also benefits from the potential to be extended in to the loft space subject to the usual permissions.
Situated on this peaceful tree lined avenue in the heart of Ealing, only a short walk to Ealing Broadway Station (District and Piccadilly tube lines, mainline trains to London Paddington and Heathrow Airport and forthcoming Crossrail/Elizabeth Line) and town centre beyond.
ENTRANCE HALL : Private front door. Hardwood flooring.
HALLWAY : South facing window. Storage and meter cupboards. Access to large loft space with potential for conversion (subject to the usual permissions). Parquet flooring.
LIVING / DINING ROOM : 5'7" x 10'11" (4.75m x 3.33m) , A light and airy room with large window. Elegant feature fireplace. Picture rail. Parquet flooring.
KITCHEN : 13'7" x 6'4" (4.14m x 1.93m) , Full range of wall and floor cupboards with ample work surface. Inset stainless steel sink and drainer. Tiled splash back. Space for fridge freezer. Space for cooking range. Plumbing for washing machine. "Vaillant" boiler. Double glazed window. Tiled floor.
BEDROOM 1 : 12'2" x 9'7" (3.71m x 2.92m) , Large double glazed window overlooking garden. Picture rail.
BEDROOM 2 : 9'0" x 7'6" (2.74m x 2.29m) , Large window. Picture rail.
BATHROOM : White suite comprising of panelled enclosed bath with shower mixer attachment. Enclosed shower cubicle with "Triton" shower. Pedestal wash hand basin. Low level W.C. Chrome ladder heated towel rail. Double glazed window. Part tiled walls. Tiled floor.
OUTSIDE : 19'0" x 19'0" (5.79m x 5.79m) , Private sun trap west facing garden approximately 19'0" x 19'0" (5.79m x 5.79m). Mainly laid to lawn with patio and flowerbed borders.
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Disclaimer - Property reference SINT_001775. The information displayed about this property comprises a property advertisement. Rightmove.co.uk makes no warranty as to the accuracy or completeness of the advertisement or any linked or associated information, and Rightmove has no control over the content. This property advertisement does not constitute property particulars. The information is provided and maintained by Sinton Andrews, Ealing. Please contact the selling agent or developer directly to obtain any information which may be available under the terms of The Energy Performance of Buildings (Certificates and Inspections) (England and Wales) Regulations 2007 or the Home Report if in relation to a residential property in Scotland.
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St. Lawrence River salute in Quebec
PRIDE just received and returned a salute from "the" venerable gentleman of Cap-Charles, Quebec, located right on the shores of the St. Lawrence River. For years this gentleman has raised the flag of the nation of registry of any ship passing by Cap-Charles on their way to or from Montreal. Included in the salute is the playing of the national…read more


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Beep Beep Day - Nursery & Reception Beep Beep Day for Nursery + Reception - part of Road Safety Week
'Bright to be seen day' Bright to be seen day' - Wear something bright to school. Whole School. £1 to be bought in.
Nursery and Year 2 Christmas cake bake The Nursery and Year 2 Cake bake in the school hall. All welcome.
Reception and Year 1 Christmas Cake Bake The Reception and Year 1 Cake Bake in the school hall. All welcome.
Follow Us @TheKFSchool


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Ryelands Holiday Park Kilgetty, Pembrokeshire, Wales Show on map (A)
|Non-electric grass pitch
|8 x
|From £12/€13.47/A$20.94/US$15.96/CA$20.30/CHF15.67/kr132.46/kr100.27/kr129.89/kr1,653/$277.59/$10,134/PEN51.64/NZ$23.19/R221.65/zł56.71/R$51.41/Kč342.63/RSD1,608/Ft4,208.95/₽932.73/CN¥105.04 per night
Snooty Fox Narberth, Pembrokeshire, Wales Show on map (B)
|Non-electric grass pitch
|10 x
|From £13/€14.60/A$22.69/US$17.29/CA$21.99/CHF16.98/kr143.50/kr108.63/kr140.71/kr1,791/$300.72/$10,978/PEN55.95/NZ$25.13/R240.12/zł61.44/R$55.69/Kč371.19/RSD1,742/Ft4,559.69/₽1,010.46/CN¥113.79 per night
Celtic Camping St Davids, Pembrokeshire, Wales Show on map (C)
|Non-electric grass pitch
|unlimited x
|From £20/€22.45/A$34.90/US$26.59/CA$33.83/CHF26.12/kr220.77/kr167.12/kr216.48/kr2,756/$462.65/$16,889/PEN86.07/NZ$38.66/R369.41/zł94.52/R$85.68/Kč571.05/RSD2,680/Ft7,014.91/₽1,554.55/CN¥175.06 per night
|Electric optional grass pitch
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Hotel deals in Guangzhou
Filter Results
Results found:
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Rating - high to low
Xinghui International Apartment
18 Zhujiangxincheng Jinsui Road, Guangzhou, China (Open map)
Xinghui International is a 4-star property only 1200 meters from Tee Mall. Xinghui International has been welcoming guests to its modern rooms since 2006.
Read more...From US$ 113price for 1 nightRESERVE
Southern Hotel
1838 Main North Road, Guangzhou, China (Open map)
Southern is a worthy example of 4-star hotels in Guangzhou offering modern rooms overlooking Baiyun Mountain and Green Mountains.
Read more...From US$ 63price for 1 nightRESERVE
Regal Riviera Hotel
1 Haojing Street, Yizhou Road, Guangzhou, China (Open map)
The comfortable 4-star Regal Riviera Hotel offers a luxurious accommodation in a business area of Guangzhou. Featuring classical architecture, the hotel is opened since 2004.
Read more...From US$ 86price for 1 nightRESERVE
348 Jiang Nan Da Road Central, Guangzhou, China (Open map)
The 4-star Rosedale Hotel in Yue Xiu district offers non-smoking guestrooms overlooking the Pearl River. Built in 1988, the deluxe hotel was renovated in 2008.
Read more...From US$ 45price for 1 nightRESERVE
Henry Business Hotel
26 Baohua Road, Boahua Lu, Huadu Guangzhou, China, Guangzhou, China (Open map)
Henry Business is a lovely 4-star hotel set 23 km from Big-Hippo Water Fairland and 3.4 km from Yuanxuan Taoist Temple.
Read more...From US$ 41price for 1 nightRESERVE
Daysun Park
277 Zhongshan Road West, Guangzhou, China (Open map)
Daysun Park Hotel is placed in a shopping area of Guangzhou in the vicinity of Pazhou International Exhibition Center, Tianhe and Guangzhou International Convention and Exhibition Center.
Read more...From US$ 199price for 1 nightRESERVE
Jian Li Harmony
169 Linhe Road West, Tianhe District, Guangzhou, China (Open map)
Offering 177 rooms, the excellent Jian Li Harmony Hotel features a nightclub, a casino and a spa center available on site. Jian Li Harmony Hotel has been welcoming guests to its cozy rooms since
Read more...From US$ 51price for 1 nightRESERVE
Phoenix Mountain Hotel
No.332 Guangshan Yi Road, Guangzhou, China (Open map)
Phoenix Mountain Hotel is located in a green area of Guangzhou in close proximity to CITIC Plaza, Taikoo Hui and Guangdong Olympic Stadium.
Read more...From US$ 52price for 1 nightRESERVE
J Hotel
105 Tianshou Road, Guangzhou, China (Open map)
The 4-star J Hotel offers cozy rooms in proximity to Yuntai Garden, Guangzhou Zoo and Taikoo Hui.
Read more...From US$ 60price for 1 nightRESERVE
King Garden
117 Heng Fu Road, Guangzhou, China (Open map)
The 4-star King Garden Hotel is set just 2.5 km from Pazhou Complex, Tianhe and Yuexiu Park. The hotel occupies 5 floors and was renovated in 2008.
Read more...From US$ 41price for 1 nightRESERVE
Hotel Landmark Canton
No.8 Qiaoguang Road, Guangzhou, China (Open map)
Offering a nightclub, a spa center and a swimming pool, Landmark Canton Hotel lies in a business area of Guangzhou near to Guangzhou Library, Pearl River and Six Banyan Tree Temple & Flower Pagoda .
Read more...From US$ 70price for 1 nightRESERVE
Ramada Pearl
9 Ming Yue Yi Road, Guangzhou, China (Open map)
The superior 4-star Ramada Pearl Hotel provides shuttle service, shoe shine and ironing service to ensure guests a comfortable stay.
Read more...From US$ 68price for 1 nightRESERVE
It World Hotel
20 Keyun Road, Guangzhou, China (Open map)
The 3-star It World Hotel offers elegant rooms in proximity to CITIC Plaza, Tianhe and Guangdong Olympic Stadium. The property opened in 2006 and features traditional architecture.
Read more...From US$ 150price for 1 nightRESERVE
Timmy Hotel
1F, Longde Building, No. 371 & 373,, Guangzhou, China (Open map)
Timmy is a charming 4-star hotel set close to Tianhe, Guangzhou Zoo and Pazhou Complex. Timmy Hotel has been welcoming guests to its contemporary rooms since 2007.
Read more...From US$ 44price for 1 nightRESERVE
Kai Rong Du International
No.3 Shiliugang Road, Jiang Hai Ave, Center Area, Guangzhou, China (Open map)
Kai Rong Du International is a 4-star hotel offering a free car park and a sauna. Kai Rong Du International Hotel has been welcoming guests to its luxurious rooms since 2010.
Read more...From US$ 102price for 1 nightRESERVE
White Palace
111 Yinbin Road, Pan Yu District, Guangzhou, Cn, Guangzhou, China (Open map)
The luxury White Palace lies in an exhibition area of Guangzhou. The building was renovated in 2008.
Read more...From US$ 74price for 1 nightRESERVE
Paco Business Hotel - Guangzhou East Railway Station Branch
No.1862 Guangyuan Dong Road, Guangzhou, China (Open map)
The 4-star Paco Business Hotel Guangzhou East Railway Station Branch is set just 2.2 km from Tomb of 72 Revolutionary Martyrs at Huanghuagang, Huanghuagang Park and Taikoo Hui.
Read more...From US$ 58price for 1 nightRESERVE
Imperial Hotel
No. 133, Taixing Road, Qinghe East Panyu District, Guangzhou, China (Open map)
Imperial Hotel is rated 4 stars and is placed about 14 km from Yingzhou Ecological Park. The hotel was opened in 2008, renovated in 2010 and is housed in a 12-storey building.
Read more...From US$ 69price for 1 nightRESERVE
Panyu Yuwa Serviced Residences
No. 19, Yixiang Side Street, Qiaona, Guangzhou, China (Open map)
Read more...From US$ 54price for 1 nightRESERVE
Yiwu Commatel Hotel
A Block South Tower Of Continental Cntr, Guangzhou, China (Open map)
The exquisite Yiwu Commatel Hotel offers 69 comfortable guest rooms as well as a baggage storage, a designated place for smoking and a gift shop.
Read more...From US$ 55price for 1 nightRESERVE


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US Wrap: Accelerated growth products dominate, and choose tech
Overall, product scope broadened considerably. BofA also launched a kickout product linked to the iShares MSCI Brazil Index Fund which promises to pay a coupon of 15-19% after one year, while including 10% downside protection.
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The Saujana is the choice to go if you want a quiet surrounding and you possibly have half a day off to spend in the green or at the pool. It has a huge open reception with the rooms in adjacent buildings. So you have to walk a little bit from room to the restaurants or the entrance. The rooms are modern and provide a basic comfort. The good thing about the rooms is that they are very, very quiet. It feels like you were far away from the city. Sveral restaurants are available, all of them are good. The drawback is that there is not a lot around to do without taking a taxi. So it is good for playing golf or business trips, but less for visiting KL.
Own or manage this property? Claim your listing for free to respond to reviews, update your profile and much more.


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Apartment,UnitRent - New York, NY
Net effective rent.
Current incentives - 1 month free on a 13 month lease or 2 months free on a 17 month lease.
Enjoy complimentary yoga and Pilates classes.
Located in the heart of the iconic Financial District, the residences at Twenty Exchange bring modern vitality to an important piece of New York City history. A monument to the economic engines and people that helped to shape the world's commerce, the building's present-day incarnation retains the rich spirit of the past as it provides renters with a wealth of contemporary amenities ¿ at great value.
Designed by the architectural firm Cross & Cross and completed in 1931, the 57-story, steel-framed, granite and limestone structure was originally the Wall Street area headquarters of City Bank Farmers Trust (now CitiBank). Until 1970, it was one of the tallest buildings in the world and, designated a City Landmark in 1996, it remains a distinctive and prominent feature in the lower Manhattan skyline. Up close, it's apparent that Twenty Exchange's magnificent Art Deco and classical elements harken to its "moneyed" beginnings. An imposing entrance arch is carved with 11 international coins (which represented the former bank's global presence) and, from the tops of 14 majestic columns, the captains of finance gaze down on those who enter a lobby that retains its glorious, original bank hall attributes.
Inside the residences, modern style and comfort prevail. The apartments feature gorgeous NYC views, tall ceilings (some 11 feet) and modern kitchens with state-of-the-art stainless steel Liebherr and Fisher & Paykel appliances and custom European cabinets. The baths are elegantly appointed with marble floors, contemporary tiling, and custom sinks and vanities.
A short walk from the caverns of Wall Street, Twenty Exchange offers dividends to provide the perfect respite from hard-charging workdays. Depending on the mood, chose to hit the roof deck for breathtaking sunset views of New
Would you like more information regarding this property?
Please call (212) 557-6500.


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Felca and Gaela focus on global trends
10 September, 2015
National language school and agency associations gathered in London last week to present key market data and trends from both sides of the study travel industry.
Scott Wade presents Felca member data to study travel industry figures at the Felca/Gaela meeting
The Federation of Education and Language Consultant Associations (FELCA), which presented its member data for the first time last year, was joined this year by 11 national members of the Global Alliance of Education and Language Associations (GAELA), for a special event held before the StudyTravel Alphe UK Conference.
The heads of EnglishUSA and English UK articulated concerns about strong currencies. Cheryl Delk-Le Good, Executive Director of the former, referred to a recent survey in which less than 30 per cent of members expected increases in summer and autumn intake.
Eddie Byers, CEO of English UK, said, "The pound is a real challenge," but also highlighted the growing market share of juniors, accounting for 47 per cent in 2014.
Conversely, Marketing English in Ireland (MEI) CEO, David O'Grady, said MEI had seen membership growth and that members were reporting 2015 to be a "good year". Ireland is thought to have benefitted from no exchange rates within the Eurozone.
The significant market share of national member school associations was a common theme through the data presentations: English Australia represents 45 per cent of all registered language schools, but 88 per cent of students; 46 per cent of private language schools are English New Zealand members, but the association accounted for 81 per cent of students; and Malta's association Feltom has 41 per cent of schools but 86 per cent of incoming students.
Pathways programmes were highlighted as a major component of the language travel industry, accounting for 39 per cent of all visa students at English Australia schools and 35 per cent of students at Languages Canada member schools are studying with further study intended.
Groupement FLE, one of three non-English language school associations, said there were 132,000 language students in France in 2014, according to a first-ever industry survey of the 90 schools with the Qualité FLE accreditation label, with an average of 4.6 weeks and Germany cited as the top source country.
Government policies were another common theme for Gaela members, most pressingly for Education South Africa (EduSA), which is lobbying over recognition of language programmes, and Languages Canada, which is pursuing advocacy efforts in provinces that have yet to establish designation regulations. More positively, Rob McKay, representative of English New Zealand, said that the government was "very friendly" and that strong growth from Colombia was "entirely driven by work rights".
McKay also recommended that agents utilise the New Zealand Qualifications Authority (NZQA) website to conduct due diligence on the category (risk rating) of potential partner schools.
From the agency side, Scott Wade, Director of StudyTravel and Coordinator of Felca, presented an overview of data from the agency associations, highlighting growth trends, opportunities and challenges faced in the respective markets.
Batting against a weakened rouble, the Russian agency association AREA registered a 20 per cent decline last year; but more positive trends were recorded by TIECA in Thailand at 40.7 per cent, as well as BELTA in Brazil (15 per cent), IALCA in Italy (four) and JAOS of Japan (three).
Belta has experienced difficulties in promoting the UK since the closure of the UK consulate meaning documents have to be sent to Colombia, while TIECA said the UK's introduction of biometric testing and the immigration health surcharge were challenges.
Taiwanese association IECA reported on the creation of a 'study group' deposit committee to arrange insurance cover for group bookings, with 28 members currently signed up.
Several agency associations are benefitting from government study abroad initiatives: members of AREA are working on a Russian government scholarship scheme for overseas postgraduate study; JAOS is experiencing growth, particularly in the junior market, from government scholarships and Ministry of Education plans to double study abroad by 2020; and IALCA is actively involved in Italy's PON language scholarship.
The annual FELCA/GAELA meetings are held prior to ST Alphe UK each year. Click here for a gallery of the meetings.
Matthew Knott
News Editor


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BALTIMORE (WJZ)–Congratulations are in order for Baltimore native Josh Charles.
The former "Good Wife" actor and his wife, Sophia Flack, are expecting their first child.
People Magazine reports the two will welcome their bundle of joy into the world this winter.
They already know the sex of the baby but are keeping it a secret.
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- Pilot Manages To Safely Land Plane Without Landing Gear
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Wrickton Hall Home Dog Boarding Prices
Our pet retreat offers a home from home experience for your dog while you're away. Unlike traditional dog kennels, your pet stays in our home as part of the family. We have plenty of space here at Wrickton, whether your dog wants to curl up by the fireplace, or wishes to have time-out in any of our other rooms. Outside we have a large garden where your dog will have supervised play with other dogs, and plenty of surrounding countryside where we can take them for walks. Prices start from £18 per night per dog.
Discounts are available for owners of more than one dog.