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Highlife Gives Real Chicago Dating Adventures
Music addicts can revel in a hot nights great jazz or attend a rock star illusion camp, while individuals with
pursuits can attend a performance of the Chicago Symphony or a Frank Lloyd Wright tour.
Venezuela s Revolution is under attack Cuba and Venezuela Solidarity Committee
Venezuelan President Nicolás Maduro and the
Assembly, together with the majority of the people, are struggling against constant aggression and violence of the right wing and U.
Gregg W. Stone | International Conference for Innovations in Cardiovascular Systems
Leon, is the director of Transcatheter Cardiovascular Therapeutics (TCT), the world s largest symposium devoted to interventional cardiology and vascular medicine, directs the annual
Interventional Cardiology Fellow s Course, and co directs multiple other annual courses, including Optimizing Complex PCI Outcomes, The Left Main and Chronic Total Occlusion Summit, Bioresorbable Scaffolds: A Breakthrough PCI Technology, LAA Occlusion: A Technique Oriented Course, and Transcatheter Valve Therapies.
National Orchestra of Belgium
he enveloping darkness, until memories of this purest, sweetest soul supplant reality.
Reclaim Native American
nce as well as correspondence from Indian or Alaska tribal leaders and leaders from
level environment/recreational and industry organizations must be forwarded to OES prior to responding, regardless of addressee or signature level.
Crisisweb: the International Crisis Group s on line system
Since 1992, at Greek insistence, Macedonia has been internationally known under the provisional name former Yugoslav Republic of Macedonia , or FYROM. ICG argues that there are now compelling strategic reasons for the international community to acknowledge the country s constitutional name, Republika Makedonija , while accepting and defending Greece s legitimate concerns. Most outside pressure has failed completely to push the regime towards democracy or economic reforms but better understanding of the generals world view may improve international leverage. The regime is obsessed with self reliance and
sovereignty, making it suspicious of foreign relations, however well intentioned.
We Could Be Famous
And BP and Transocean and other, you know, operations, Cameron, other companies are going to have to pay up to 10 billion and 15 billion for breaking
Climate Denial Crock of the Week | Greenfyre s
The parody video, titled Hide the Decline, had more than 500,000 viewers on YouTube and received
attention when Rush Limbaugh played it on his radio show.
National Geospatial Technical Operations Center
The monthly bulletin features issues in the USGS
Hydrography Dataset and Watershed Boundary Dataset. Highlights: Delineation of Maine Coastal Waters in the NHD, NHDPlusV2
Seamless File Geodatabase Released, NHD Quality Control Errors and How to Resolve Those Errors, and other current hydrography related news.
Medicare For All | National Nurses United
ing how in 2005 CNA members taunted California s then governor, Arnold Schwarzenegger, trailing him wherever he went to protest his attempts to roll back hard won nurse to patient requirements in hospitals.
Brazilians football tricks | Womsy s Blog
Well not exactly what the Danish
team performs?. This in turn has been sparse on the success of the Danish
This is suspicious, in the eyes of the
Passport Agency.
Lobuche Peak Climbing with Everest Base Camp Trek | Climbing in Nepal
like Ama Dablam, Pumori, and Everest and from additionally we will have excellent Himalaya s scene of Khumbu district, major Himalayan ice sheets and elevated pools of Sagarmatha
Highlife Gives Real Chicago Dating Activities
that have
interests can attend a performance of the Chicago Symphony or a Frank Lloyd Wright visit.
Highlife Offers True Chicago Dating Activities
Music lovers can enjoy a hot nights great jazz or attend a rock star fantasy camp, while those with
interests can attend a performance of the Chicago Symphony or a Frank Lloyd Wright tour.
Disney Cashes In On the Osmonds Family Act Formula! | Gotmymojoworkin.com
Disney was responsible for giving them their first bit of
exposure in the 50 s on the Mickey Mouse Club when they were just kids and from there.
Commercial Law | TurnerFreemanLawyer
Turner Freeman is an established
mid tier law firm with 15 offices. Turner Freeman is an established
mid tier law firm with 15 offices.
Highlife Gives True Chicago Dating Ventures
le individuals with
interests can attend a performance of the Chicago Symphony or a Frank Lloyd Wright trip.
The McGee Family
William Reedon a Certen Certain Mr McGeeat the High Tower Townwithout any previous Quarral Quarrel Took his Gun the Said Reedand five more armed men and went to the house whare where the said McGeewas at his work in Comapnny Company with a Mr Wheaton deleted: & there & then put his gun through a Crack of the house & shot the Sd Said McGeether there is Nothing Don Done by the
Governmen added: t Concerning Busieness Business the Excelli.
U.S. Geological Survey National Hydrography Dataset
water downstream.
Global Warming and Climate Change skepticism examined
In fact, it appears that some states are relishing the
and international leadership roles that they have undertaken.
Jobs & Careers We re Hiring Talent at Jobs.King.com!
gender identity, gender expression,
origin, disability, protected veteran status, or any other basis protected by applicable law.
Cats Indoors Golden Gate Audubon Society
Regional Shoreline and our tern restoration work at the proposed Alameda
Wildlife Refuge.
Fellowships Center for Community Change
They work with
networks of community organizations and many state and local groups and consult closely with these organizations about how to integrate these concepts into their daily practice.
You re daily reminder that Mexican nationalism is also super toxic to indigenous identity and that incorporating indigenous people solely as a symbol of Mexico s pre columbian foundation results in a mestizo
identity, while erasing actual indigenous people still tied to their practices as living and breathing cultures.
The makings of Maney
Maynard plainly corrects and downright disrupts the friendly, welcoming and multicultural narrative on which Canada s
identity relies.
U.S. National Archives
Prologue magazine brings readers stories based on the rich holdings and programs of the
Archives across the nation from Washington, DC, to the regional archives and the Presidential libraries.
No Apology
But the aggrandizement of power by our
government is only part of the tyranny faced by Americans today.
Rich People Things
Japan has lately been rocked by revelations about the
economy s thrall to crony capitalism with the flailing tech and photo colossus Olympus on the verge of delisting on the nation s stock exchanges in the wake of a.
Randolph Bourne Institute
com s growing influence has been analyzed and discussed on such
TV news programs as the PBS.
ted chiang | Paper Knife
As a novel about
identity, it seemed have a lot to say about pregnancy.
The Right Coast
I wished the
Rifle Association would stop blocking common sense gun control reforms such as banning assault weapons, restricting silencers, shrinking magazine sizes and all the other measures that could make guns less deadly.
World Chump To Europe!: caste
According to the
Dalit Commission (yes, there is such a thing), Dalits have been identified as castes from whom water is not accepted .
Piedmont Community College does not discriminate on the basis of race, color,
origin, sex, disability, or age in its programs and activities.
dragged kicking and screaming
After something as horrific as what happened in Las Vegas, we re all just hoping that now these terrible shootings will stop once and for all without circumstances changing in any way or any of us taking even the slightest amount of action in response, said Harrisburg, PA resident David Snyder, echoing the sentiments of tens of millions of citizens from coast to coast who told reporters they were confident that, after living through the most deadly mass shooting in modern American history and taking no material steps to change gun laws, reevaluate safety standards, increase access to mental health care, or even have a
conversation about how mass shootings could be avoided in the future, tragedies of this kind would at long last come to an end.
Flagstaff/Sedona classifieds for apts, jobs, and items for sale backpage.com
jectionable, including without limitation material of any kind or nature that encourages conduct that could constitute a criminal offense, give rise to civil liability or otherwise violate any applicable local, state, provincial,
, or international law or regulation, or encourage the use of controlled substances;.
The Sierra Group Homepage
As a
sourcing agent, Sierra Group will locate and submit candidates with disabilities and veterans with disabilities in response to our customer s directive.
Highlife Provides Real Chicago Dating Activities
Music addicts can revel in a warm night of cool jazz or attend a rock star illusion camp, while people that have
interests can attend a performance of the Chicago Symphony or a Frank Lloyd Wright tour.
Accueil | Le PNUD en Union des Comores
Moroni (Comores), 19 décembre 2016 Les Comores ont procédé au lancement, au niveau
, du Rapport sur le développement humain en Afrique 2016 : Accélérer les progrès en faveur de l égalité des genres et de l autonomisation des femmes en Afrique, publié par le Programme des Nations Unies pour le développement (PNUD).
Lake Tahoe | Vail Resorts Hospitality
ty in Utah; Heavenly, Northstar and Kirkwood in the Lake Tahoe area of California and Nevada; and Grand Teton
Park in Wyoming. The Great Summer Break is nearly here and now is the time to lock in the best rates on vacations across Vail Resorts and RockResorts destinations, including Vail, Beaver Creek, Breckenridge, Keystone, Park City, Heavenly, Northstar, Kirkwood and Grand Teton
United Nations Environment Finance Initiative Partnership between United Nations Environment and the global financial sector to promote sustainable finance
Building on the recent achievements of the
Green Finance initiative in China, this event aims to discuss the development of an investment and regulatory environment that promotes consideration of financially material environmental, social and governance (ESG) issues, consistent with investor obligations and duties.
The Official James Petras website
the US s corporate for profit medical system into a
Medicare For All public program.
Home | UCPath Project
The Deployment 2 group UC San Diego, UC San Francisco, UC Berkeley, Lawrence Berkeley
Lab and UC Hastings is scheduled to go live in December 2018.
School Lunch Program and more than 11 million participating in the
School Breakfast Program, good nutrition at school is more important than ever.
They Got Emma
It took political advocacy,
initiatives to promote pure speech in schools, linking speech defects to poor moral development and criminality, and a pure unquestioned commitment to scientific progress that has since been loudly criticized.
BrittinghamTrantham464 Welcome to the Official web site of the Armenian National Grid Initiative Foundation Grid in Armenia
majestic wiki.
Asian History
EAMENA s primary aim is to rapidly record and evaluate the status of the archaeological landscape of the MENA region in order to create an accessible body of data which can be used by
and international heritage profes.
Evolving in Kansas
Social conservatives lost key
and state elections.
Biomedical Beat Blog National Institute of General Medical Sciences | Follow the process of discovery
n others? What factors contribute to resiliency? How can we help these people? These questions also made me think about the significant adversities that I had personally experienced.
A Collection
etnam protesters during the Democratic
Convention in Grant Park.
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com 96 Hour Sale is the place to find the best rates of the season on vacations across Vail Resorts destinations, including Vail, Beaver Creek, Breckenridge, and Keystone in Colorado; Park City in Utah; Heavenly, Northstar and Kirkwood in the Lake Tahoe area of California and Nevada; and Grand Teton
Park in Wyoming.
Counterweights Canadian politics
By Allyson Horn & Henry Belot : Opposition Leader Bill Shorten has promised a
vote on Australia becoming a republic during the first term of a Labor Government One question do you support an Australian republic with an Australian head of state? Yes or No? Mr Shorten said if the result of the referendum was.
AIR Institute of Berea College AIR Institute Raises the Value of Art and Creativity
To meet the
demand for AIR, we designed a new program that will allow people to teach our curriculum for their local community and truly achieve our common vision of making art and creativity part of everyday life for everyone.
Politics Archives The National Memo
strators were headed their way and whether they would be armed.
National Center For Women and Policing
001, and remains an adviser to the program.
Education Opportunity Network
The nation s largest organization representing classroom teachers, the three million member
Education Association, is getting plenty of guff over its decision to stonewall U.
Alain Fleischer | Le Fresnoy Studio national des arts contemporains
a représenté la France à la Biennale internationale de Kwang ju (Corée), à la Biennale internationale de La Havane (Cuba), et en Australie dans l exposition Sporting Life, à l occasion des Jeux Olympiques au Museum of Contemporary Art de Sydney.
Blithering Idiot
s assurances on
security issues were pretty reassuring.
Other People Exist
Subscribers who live in foreign lands should consult their
postal service for estimates as to arrival time.
Gallery Columns 4 TOPS APOLLO SENTER
ct of Congress, a judge ruled Wednesday that a counterterrorism provision of the
Defense Authorization Act, an annual defense appropriations bill, is untoiscitutnonal.
Mitt Romney (R Mormon) | The Fruit Fly
Do I believe in the
Republican Party? Not in the slightest even though I see no meaningful alternative to it.
Mind Hacks Neuroscience and psychology news and views.
The organisation was paramilitary in the traditional sense with uniforms, a command structure, local and regional divisions,
commanders, and written statutes.
National Debt
Now we are leaving to our children and our grandchildren an economic future that has been totally wiped out and a
debt of more than 14 trillion dollars that we expect them to repay.
UNTCFI Header
In 1966 BPCC changed its name to The
Antigovernment Extremist
Hiroshima set in motion a sweeping,
generalization that if we do it, it is right.
The Debate Link: America
What does it say about our
trajectory if we can easily turn ba.
Fusce Pretium Nisi Purus Quest Surgical National
Unabridged Comics
: Al Stahl s Needles ends as he leaves
for Fiction House.
Just World News with Helena Cobban | Info, analysis, discussion to build a more just world
The centennial (100 year anniversary, no less!) of the Balfour Declaration, the diktat from the British Foreign Secretary that imperial London would support the creation of a Jewish
home in Palestine whatever that meant but would do so only provided that the civil and political rights of the non Jewish inhabitants of Palestine would not be adversely affected. When the international community most recently codified and regulated the whole concept of rule by military occupation , in the Geneva Conventions o.
National Association of Concessionaires
The next NAC Concession Certification Management (CCM) four day class is scheduled for Friday, October 27 Monday, October 30 on the Florida International University (FIU) Biscayne Bay Campus in North Miami immediately following the 2017 ShowEast EXPO. October 27 30, 2017 Florida International University (FIU) Biscayne Bay Campus 3000 NE 151 Street North Miami, FL 33181 On line Registration CLICK HERE.
A Modest Proposal for the March for Science | The New Yorker
His proposed annihilation of the
Institutes of Health s budget would devastate research in this country and turn promising students away from.
Military History Online The Somme
1 The army s main role since the end of the Boer War was simply to police the British territorial empire, while Britain s
security was vested in its large and powerful Royal Navy.
One fast move or I m gone!
Your safety and
security party, right? While they re at it, they also slashed the budgets for Law Enforcement Wireless Communications by 52 million; US Marshals Service by 10 million; the FBI by 74 million; and COPS by 600 million.
Radiogirl Podcast
He describes his beard pursuits: how he got into
and international beard competitions; how he got into radio doing the weather for Dick Biondi; working at NPR and another local station while at Southern Illinois University in Carbondale; getting fired, dealing with being out of work, and persevering without a job; doing mornings on Rock 105 WTAO; starting in Chicago at WCKG with Pete McMurray; why he loves radio so much; consistently contacting.
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text:
Yara's big data set – lessons for 201701-Feb-2017 Yara
Nitrogen is undoubtedly the number one nutrient in the search for higher yields.
However, the need to identify other limiting factors that might prevent a crop from realising its full potential is a key lesson to be learnt from Yara's Big Dataset, believes Jon Telfer, Development Manager at Yara Analytical Services.
Furthermore, the earlier these limiting factors can be discovered and, where possible, addressed, the better the outcome in terms of yield and productivity.
"We have been performing analysis of soil, tissue and organic manures for over 40 years in our lab in Pocklington and collecting data electronically since 1995," says Mr Telfer. "This has given us over 20 million data points, and growing, from which to learn and provide insight for farmers. Our dataset from 2010 to 2016 certainly shows that limiting factors are widespread, but variable, making soil testing and analysis on individual farms essential."
What are limiting factors?
Limiting factors can range from soil conditions, soil fertility, disease and weed pressure to a shortage of other key crop nutrients.
Soil fertility is key and, rather than guessing, factors such as soil type and texture and biological fertility should be measured, including organic matter (OM) analysis.
Chemical fertility – and identifying gaps in a soil's status and performance - is where soil analysis really comes into its own, maintains Mr Telfer. "It provides an opportunity for the individual farmer to identify the factors on his or her own farm that are going to hold back yield. Crops need a variety of nutrients to complete the growing process – macro and micro nutrients - and a deficiency of any single one is enough to limit yield."
Lessons from the data set
So, with this in mind, what does Yara's data set, using figures from 2010-2016, tell us about potential limiting factors?
The first thing to check is soil pH. "We know that having the right soil pH, between 6.5 and 7.5, is vital for utilising the nutrients that exist within our soils. However, our data for UK arable soils shows that of the 500,000 soils processed almost half needed some form of pH management, with 20% having a pH of less than 6 liable to impact on NPK usage efficiency. Making sure your pH is right must be the starting point."
| Big Data findings: identifying the limiting factors
P&K deficiency
Low levels of crop available phosphorous and potassium are also known to limit yields and also limits the effectiveness of N applications.
"Again, our data shows that a quarter of arable soils tested in the UK are at potentially yield inhibiting levels of phosphorous deficiency," says Mr Telfer, "with over half of UK soils needing phosphorus management, that is building up or replacing what we are removing after offtake by crops. Similarly, a third of soils have potentially yield inhibiting (index 0 or 1) levels of potassium with over half requiring potassium management."
Identifying the limiting factor – Nutrient supply - Phosphorus
Identifying the limiting factor – Nutrient supply - Potassium
Sulphur Reserves Exhausted
In 1995, 63% of soils analysed were below Yara guidelines for plant available sulphur. "That figure is now 96-7%, says Mr Telfer, "we can safely say that reserves of sulphur are exhausted, hence why it is now considered a major nutrient alongside NP&K."
Range of nutrients
Whilst NPK and sulphur are the major nutrients, plants require a whole range of nutrients for different functions and a deficiency in any of them is enough to limit yield.
"Again, looking at our big data only 13.5% of UK soils had adequate pH and nutrients (including manganese, copper and zinc) for a healthy winter wheat crop. This means that if you invest in soil analysis, 7 times out of 8 you will identify potential opportunities to improve yield and productivity. The same was true for oilseed rape soil: by including manganese, boron and calcium, only 7% of soils were found 'fit for purpose'."
Book value or test?
Another area in which the big data set offers insight is the value of organic inputs. Just how accurate are the given book values?
Analysis shows that whilst accurate measurements of nitrogen and phosphate are variable, they do hover around the book value in RB209.
But potassium measurements going back to 2005 never matched the value stated in RB209. So if we rely on these book values to populate our nutrient management plans we could be building in inaccuracies. It is better to test and use accurate figures.
Leaf testing – early identification
"Leaf testing is the most effective way of monitoring actual nutrient uptake," says Mr Telfer. "It gives you the opportunity to identify deficiencies before they become chronic and show themselves as visible symptoms. In fact, over half of the winter wheat tissue samples processed through the lab between January and June 2016 were deficient not just in one but multiple micronutrients."
- 86.7% of samples were deficient in at least one key micronutrient: Zinc, Copper or Manganese
- 57.3% had 2 or more key micronutrient deficiencies
Opportunities to benefit
Yara's big data set confirms that, as suspected, UK arable farmers are confronted by a wide range of potential limiting factors, but this also presents many opportunities.
Farmers can identify and correct limiting factors before they start nutrient programmes, suggests Mr Telfer: "Testing early gives the opportunity to correct any deficiencies, or combination of deficiencies, through the tank before the plant has reached a point of stress from which there is often no return.
"As an example, our data on PK and S deficiency confirms that many farmers will certainly find their need for straight N is far less than they thought, opting for NPKS and NS instead - to their advantage.
"In cereal crop trials the use of NS has led to yield increases of 0.3 t/ha, whilst in oilseed this has been higher at 0.5 t/ha," says Mr Telfer, "and using a granulated nitrate plus sulphate product will result in an ROI of between £2 and £10 return for every £1 invested."
"Similarly switching a first spring application to a 'Spring Starter' - NPKS Complex Compound Fertilizer (CCF) will give arable crops the best possible start in the spring as they look to recover root and shoot growth lost over the winter. Research into this approach have shown a consistent yield increase of a further 0.25 – 0.3 t/ha, above the expected sulphur response."
Notes to Editors:
Yara UK Limited is the UK & Ireland operating business unit of Yara International ASA, headquartered at Grimsby in NE Lincolnshire. www.yara.co.uk
Yara UK Ltd – the only company to market and distribute the complete range of plant nutrition products for agricultural, horticultural and amenity and protected (greenhouse) crops for farmers and growers. Our fertilizers all supported by a FACTS qualified regionally based team of advisors and a number of precision tools and apps.
Our product combinations include:
Established and trusted Yara branded bagged solid nitrate based brands
UK manufactured Yara range of Chafer liquid clear solution liquid fertilizers
YaraVita trace element and micro-nutrient seed treatment and foliar products formulated to be tank mixed. Check suitability at www.tankmix.com
Yara International ASA is a leading chemical company that converts energy and nitrogen from the air into essential products for farmers and industrial customers. As the number one global supplier of mineral fertilizers and agronomic solutions, we help provide food for a growing population.
Yara International ASA has 10,000 employees worldwide, operating in 120 countries with facilities in more than 50 and with a turnover in excess of £6.5 billion. The head office of Yara International is in Oslo, Norway.
Media Partner
Education Partner
Charity Partner

subset: commoncrawl


text:
Packetstorm opens bug bounty programme with $7,000 top reward
Company offers big bucks for exploits
Packetstorm has joined the exploit hunting race by offering avid hackers rewards of up to $7,000 for working exploits in its newly announced Bug Bounty programme.
The programme was announced on Wednesday and offers willing computer wizards the chance to earn money finding bugs.
"Bug bounty programmes are nothing new. We have seen various initiatives started in the community and have had a lot of discussion internally regarding whether or not such a programme causes a positive impact," Packetstorm said.
The current bounty list features a number of different targets, ranging from a bottom end $350 for a Microsoft .NET Framework Remote Code Execution to massive $7,000 for an Adobe Reader / Acrobat Code Execution.
"Different issues and different levels of exploit offer different levels of compensation. Typical payout for a working exploit ranges from $1,000 to $7,000. If you have a zero-day that you believe is worth a lot more, there is the opportunity for larger payouts, but that requires a different discussion. Nothing is off the table," wrote Packetstorm
Bug hunting programmes have become a heated topic in recent years, with numerous companies, including Google, instigating bounty programmes to help improve their products security.
However, the Packetstorm programme is different in that it aims to help improve cyber security as whole using a full disclosure policy. The policy will see all exploits made public for anyone to download and use 60 days after submission.
"Other companies that buy exploits for their penetration testing war chest rarely share them with the public and once bought, require that the author does not share them. We are going the other direction on this idea. If the author of the exploit permits it, we will release them publicly after 60 days for everyone to download," Packetstorm added.
"It helps the greater good and is in line with our initiative to provide security engineers the ability to test their systems for recently patched vulnerabilities."
The security community has yet to respond to Packetstorm's new programme though it could well be met with a similarly split reaction. Good idea or a misguided attempt to help? Let us know your thoughts.
V3 Latest
Apple delays HomePod - its answer to Amazon Echo and Google Home - until early 2018
HomePod delay means Apple will miss Christmas sales
Toshiba issues statement denying plans to sell PC business to Asus
Reports of Toshiba PC sale plans come after it sold its TV manufacturing unit to Hisense
Wales's first Internet of Things accelerator launches
IoT Accelerator programme intended to stimulate tech investment in Wales
US election regulators vote in favour of mandatory disclaimers for future election ads
Vote follows claims of Russian interference, even though Clinton out-spent Trump 2-to-1


text: Republican Party Idaho Republicans Take Part in 'Super Tuesday 2' By Tom Banse • Mar 7, 2016 Listen Listening... / Idaho is one of four states with presidential primaries or caucuses Tuesday. Turnout could be high in the Republican primary if it's like the others this season. Cruz Asks Idaho For Support In Presidential Primary By editor • Mar 7, 2016 Listen Listening... / "I will not compromise away your religious liberty." That was the vow Republican presidential candidate Ted Cruz made to supporters in Coeur d'Alene, Idaho as he campaigned Saturday at the Kootenai County Fairgrounds. Rubio Asks Idahoans To 'Restart' His Campaign Ahead Of Tuesday's GOP Primary By Tom Banse • Mar 7, 2016 Listen Listening... / Florida Senator Marco Rubio appealed to Idahoans to revive his presidential hopes during a one-day campaign swing through Idaho Falls and Boise Sunday. Idaho's Republican presidential primary takes place Tuesday. Marco Rubio Sweeps Puerto Rico Primary By Jessica Taylor • Mar 6, 2016 Marco Rubio has won the Puerto Rico's Republican primary and will net all of its 23 delegates. With all votes reporting, the Florida senator took 71 percent of the vote, followed by Donald Trump at 13 percent, Texas Sen. Ted Cruz at 9 percent and Ohio Gov. John Kasich with just 1 percent. Because Rubio topped 50 percent of the vote, he will net all 23 delegates up for grabs. Ben Carson Ends Presidential Campaign By Jessica Taylor • Mar 4, 2016 Republican Ben Carson confirmed during his speech at the annual Conservative Political Action Conference that he is ending his bid for the White House. The famed neurosurgeon had implied he was dropping out on Wednesday after a disappointing Super Tuesday finish, and he skipped Thursday night's debate in his hometown of Detroit. Will Washington Republicans Back Trump? By Bill Radke & Matt Martin • Mar 2, 2016 Flickr Photo/Gage Skidmore (CC BY SA 2.0)/https://flic.kr/p/9hKraP Listen Listening... / 10:48 Bill Radke speaks with two members of Washington's Republican Party. First, state Rep. Matt Manweller (Ellensburg) explains why he doesn't support Donald Trump for the presidential nominee and doesn't think other GOP leaders will either. On the flip side is state Sen. Doug Ericksen (Ferndale), who said that Trump has an appeal that goes beyond Republicanism. New Jersey Gov. Chris Christie Endorses Donald Trump By Danielle Kurtzleben • Feb 26, 2016 Donald Trump picked up his first congressional endorsements this week, and today he scored another major backer: one of his former rivals, Chris Christie. "I've gotten to know all the people on that stage. And there is no one who is better prepared to provide America with the strong leadership that it needs, both at home and around the world, than Donald Trump," the New Jersey governor said at a news conference in Fort Worth, Texas. Inslee's 'All Staff' Rebuke Of Republicans By Austin Jenkins • Feb 16, 2016 In the aftermath of last Friday's vote by the Republican-led Washington Senate not to confirm Secretary of Transportation Lynn Peterson, essentially firing her on the spot, an email went out to all staff at the Department of Transportation. Why Feminists Should Vote Republican In 2016 By David Hyde • Feb 10, 2016 AP Photo/David Goldman Listen Listening... / 5:07 Bill Radke asks Marilyn McKenna why she thinks Seattle women should consider voting Republican in 2016. For further listening, check out this discussion Radke hosted yesterday concerning the Democratic candidates: Debate: Do Feminists Have To Vote For Hilary? Carly Fiorina Ends Bid For Republican Presidential Nomination By Scott Detrow • Feb 10, 2016 Carly Fiorina is exiting the Republican presidential race after a seventh-place showing in last night's New Hampshire primary. "While I suspend my candidacy today, I will continue to travel this country and fight for those Americans who refuse to settle for the way things are and a status quo that no longer works for them," said Fiorina in a statement. This Washington Republican Wants Trump For President By Kate Walters & Bill Radke • Feb 10, 2016 Listen Listening... / 4:36 Bill Radke speaks with Chris Osterhaug about why he wants Donald Trump to be the next U.S. president. Osterhaug is a Republican from Edmonds. He started the Facebook group Washington State For Donald Trump 2016. A Donald Trump-Style Firing And A New Tone In Olympia By editor • Feb 9, 2016 It was a Donald Trump moment straight out of The Apprentice. Last Friday, the Republican-led Washington state Senate effectively said, "You're fired" to Secretary of Transportation Lynn Peterson. Inslee Cancels Meetings With Top Senate Republican By Austin Jenkins • Feb 8, 2016 Listen Listening... / Washington Governor Jay Inslee has cancelled a series of regularly scheduled meetings with the Republican leader of the state Senate. The move follows Friday's surprise vote by Senate Republicans to oust Inslee's Secretary of Transportation. The Stream: Get Caught Up On The Iowa GOP Debate By editor • Jan 28, 2016 Get Caught Up: In the Trump-less debate, arrows were shot at Texas Sen. Ted Cruz, who was center stage. He complained Fox News was trying to goad his rivals to attack him, taking on a Trump-ian line. The sharpest elbows were thrown between Cruz and Rubio over immigration after Fox News showed past clips of each of them espousing different views and having to defend whether or not they were opposed to legalization for immigrants in the country illegally. Should Washingtonians Be Anxious About The Economy? Depends Where You Live By Posey Gruener & Bill Radke • Jan 26, 2016 Listen Listening... / 4:59 Bill Radke speaks with Susan Hutchison, chairman of the Washington State Republican Party, about voters' feelings on the economy as we head into the 2016 election year. She said there's a difference between those who live in downtown Seattle -- who have a sense that the engine is roaring due to Amazon -- and those who live in smaller cities or Eastern Washington. GOP Debate: Desperation Time Is Setting In By Domenico Montanaro • Jan 14, 2016 Thursday's main Republican debate airs on Fox Business Network beginning at 9 p.m. EST. How ISIS, Paris And San Bernardino Have Changed The Republican Race By Don Gonyea • Dec 15, 2015 The Republican presidential hopefuls debate in Las Vegas Tuesday night will be the first since the terrorist attacks in Paris and in San Bernardino, Calif. In recent weeks, ISIS and how to keep Americans safe have dominated the campaign and shot to the top of Americans' concerns. Trump's Muslims Plan: Inflammatory? Definitely. Unconstitutional? Maybe By Eyder Peralta • Dec 8, 2015 Donald Trump has faced a torrent of criticism after releasing a policy proposal that would ban all Muslims from entering the United States. Trump On His Plan To Ban Muslims: 'Not Politically Correct, But I Don't Care' By Don Gonyea • Dec 8, 2015 The latest pronouncement from the presidential campaign of Donald Trump calls for the U.S. to refuse to let any Muslim — from anywhere — into the United States. It has prompted very strong criticism, including from some of his fellow Republican candidates and state party leaders. The Philadelphia Daily News cover Tuesday morning labels Trump "The New Furor." Trump's proposal came the day after President Obama's Sunday night televised address from the Oval Office in which the president urged Americans to reject discrimination against Muslim Americans. Why 'Bomb The S*** Out Of Them' Sounds Pretty Good To A Lot Of Voters Right Now By Mara Liasson • Nov 19, 2015 At every turn, this year's presidential campaign has proved conventional wisdom wrong. The aftermath of the Paris attacks might be another example. As soon as the attacks were over, a chorus of (establishment) Republican voices predicted that the new focus on national security and terrorism would change the dynamic of the Republican race. This was the tipping point, they declared, that would finally usher out the outsiders leading the polls — Donald Trump and Ben Carson — in favor of more serious, experienced candidates. Jindal Ends Presidential Campaign: 'This Is Not My Time' By Jessica Taylor • Nov 17, 2015 This post was updated at 6:30 p.m. Louisiana Gov. Bobby Jindal suspended his campaign for the Republican nomination for president on Tuesday, saying he had "come to the realization that this is not my time." The son of Indian immigrants, Jindal said that when his parents came to the United States 45 years ago, they told him he could accomplish anything in this country. But ultimately this time, his dreams of the White House fell short. What To Watch At Tonight's Debate: Could Be 'Make Or Break' For Jeb Bush By Jessica Taylor • Nov 10, 2015 Former Florida Gov. Jeb Bush will be feeling the heat again in Tuesday evening's debate as he tries to rebound from a disappointing performance last month that renewed questions about his viability. "I think there's going to be a lot of pressure on Jeb," predicted Katie Packer Gage, who was Mitt Romney's deputy campaign manager in 2012. "He put some pressure on himself by telling people he's going to get better and work on his debate performance. I think this is kind of a make-or-break moment for him to really step up what he's been able to do in previous debates." Pledging To 'Wipe The Slate Clean,' Wisconsin's Paul Ryan Elected House Speaker By Amita Kelly • Oct 29, 2015 This post was updated at 11:20 a.m. ET Paul Ryan has been elected speaker of the House of Representatives, receiving 236 votes. Ryan faced the full House vote Thursday after getting approval Wednesday from the House Republican conference. He faced token opposition from fellow conservative Daniel Webster and Democrat Nancy Pelosi. House Republicans Nominate Paul Ryan For Speaker By Amita Kelly & Susan Davis • Oct 28, 2015 This post was updated at 3:10 p.m. ET House Republicans have voted to elect Wisconsin Republican Paul Ryan as the party's nominee to serve as the next speaker of the House. "This begins a new day in the House of Representatives," Ryan said, speaking briefly to reporters after Wednesday's vote. "Tomorrow, we are turning the page. We are not going to have a House that looked like it looked the last few years. ... Our party has lost its vision and we're going to replace it with a vision." Finding Signs Of Unity, Paul Ryan Officially Enters House Speaker Race By Amita Kelly • Oct 22, 2015 Wisconsin Republican Paul Ryan has officially entered the House speaker race, saying in a letter to colleagues, "After talking with so many of you, and hearing your words of encouragement, I believe we are ready to move forward as a one, united team." His announcement came after securing the support of three disparate House Republican groups. 4 Ways This Whole Republican Speaker Situation Gets Resolved By Domenico Montanaro • Oct 9, 2015 Chaos ensued in the halls of Congress Thursday when Rep. Kevin McCarthy unexpectedly took himself out of the running to replace John Boehner as speaker of the House. The reason for the pandemonium and, yes, even tears: No one knows where this goes from here. Here are the four likely ways it gets resolved: The Impact Of The GOP Shakeup On Northwest Republicans By Ross Reynolds & Andy Hurst • Sep 29, 2015 Flickr Photo/Speaker John Boehner (CC BY NC 2.0)/http://bit.ly/1iJlT3Z Listen Listening... / 3:47 Ross Reynolds talks with reporter Jeff Mapes of The Oregonian about how John Boehner's resignation as Speaker of the House could affect Republican lawmakers in the Northwest. Rand Paul Rally In Seattle Draws Hundreds – Including Some Bernie Sanders Fans By Liz Jones • Aug 27, 2015 Liz Jones/KUOW Listen Listening... / 1:53 Presidential hopeful Rand Paul continued his Western tour with campaign stops in Seattle and Spokane Wednesday. At Seattle's Town Hall, hundreds chanted "President Paul" as he took the stage. Afterward, many waited in a long line to get a photo with the candidate. Republican Sweep Highlights Climate Change Politics In Alaska By Martin Kaste • Nov 6, 2014 On election night in a hotel ballroom in Anchorage, Alaska, Sen. Lisa Murkowski picked up a chair and waved it over her head. "I am the chairmaaaaaaaaaaan!" she shouted. GOP On Track To Hold Washington Senate, Pick-Up House Seats By Austin Jenkins • Nov 5, 2014 Listen Listening... / Washington Democrats appear to have failed in their bid to retake control of the state Senate. Republicans were also poised to pick up seats in the Democratically-controlled Washington House. 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ALL >> Health >> View Article
Best Herbal Breast Massage Oil To Get Bigger Boobs Fast Without Surgery
Total Articles: 9
In order to increase the size of breast simple massaging is not sufficient as it can only maintain the firmness, if you use good herbal massage oil then it will really increase the size of busts. Massages are advised to provide nourishment to tissues and muscle enlargement and to get bigger boobs. Busts of women do not have any muscle, so simple massaging can keep the tissues nourished to stop them from sagging but cannot increase the size. If you use good herbal breast massage oil then you can also have bigger breasts.
It is very important to choose the right type of oil, if the oil contains strong chemicals or too many artificial compounds then it can lead to damage to the skin. Because of presence of artificial substances and chemicals massages will not be effective and they will also provide temporary results which will be gone quickly. There is only one effective and completely herbal oil which increases the size of bosom by massaging regularly in a short time. Big B-36 herbal oil is the most trusted cure and consistent massage with this oil will definitely enhance the size without bringing any side effects.
Herbal Big B-36 oil contains herbs which can enter the barrier of skin and affecting organs of the body. Busts of women contain fatty tissues, glands and ducts, when Big B-36 herbal oil is used to massage on these herbs of this oil dilate the blood vessels to provide more blood. Increased blood supply improves the count of fatty tissues which make the breasts bigger and fuller. The herbs included in this oil help to enlarge the adipose tissue, which joints the underside of bust and chest muscle.
Because of augmentation of adipose tissues the connective fiber becomes stronger and it helps in lifting up your busts upwards and makes the firmer. With more increased fatty tissues women get fuller, firmer and bigger and attractive cleavage for increased confidence and attractive appearance. Massaging can help in preventing the side effects of weaknesses and aging in the body but if you use herbal Big B-36 oil for massaging it really increases the size within no time and makes you look attractive and younger.
The herbs included in Big B-36 herbal helps in opening up capillaries, when there is smooth flow of blood in these capillaries the bust skin gets nourished and becomes tighter as well. These advantages help in removing wrinkles, lines and spots on breasts and make them appear firmer and supple. If you avoid using deep neck lined clothes due to saggy and smaller breasts, now it is the right time to leave your worries behind, you can use Big B-36 herbal oil to improve the size of your bust within no time.
Within a very short time you will get fuller and richer breasts with firmer, round and bigger shape. Some women go to any level to increase the size of their breasts, many of them choose painful surgeries to have that fuller look. Big B-36 oil because of its potential herbs can provide better and permanent results without any risks.
Read about Herbal Breast Firming Massage Oil. Also know Herbal Breast Enhancement Oil. Read about Natural Pills to Increase Female Sex Drive.
Axton Louis is a passionate writer who has written numerous articles on topics concerning ayurvedic remedies for men health and women health. He writes informative articles on health-related issues and the use of natural health supplements.
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Don Harms
Text: 209-352-2189
Clean, fresh and gorgeous. Updated home with a unique layout conveniently located off Morning Star Drive, minutes to downtown. This home stands apart from it's competition - a fresh color palette of gray, black and taupe inside and out. You'll love the open floor plan with windows framing a great view of the hills and the town of Sonora. Enter the home into a welcoming entry area with hall closet and take in the generous living area with fireplace, windows and a terrific flow into the dining and kitchen areas. The kitchen is open with fresh black cabinets, granite counters and stainless steel appliances. Off the kitchen there is a substantial pantry and just around the corner by the garage entrance you'll find the convenient laundry room with storage and a full guest bath. Across from the kitchen is the elegant dining area with gorgeous views and tray ceiling. There is also a study off the entry hall with a closet that would be a great office or guest room. Off the living area, you'll find the luxurious and private master suite with fireplace, huge walk in closet and a bathroom with dual sinks, soaking tub and glass door shower and closeted toilet. Downstairs is a bright bonus room with fireplace with a large closet that would be great for a wine cellar or terrific toy storage. Two bedrooms and a full bath flank the living area. One of the bedrooms is very unique - it has a huge walk in closet and the room itself is divided into two areas - perfect for a dressing area, sitting area, or office space. Off the back are two decks, one on each level, connected by a set of stairs. Ideal for entertaining a group, dining outside or enjoying a quiet moment. This home is move-in ready and easy to maintain and enjoy. Perfect for a full time home or vacation escape.
Thank you for visiting today. If this is your first visit, take your time and look around. I have plenty of information and resources available to you. If you are a return visitor, thank you. I would love to hear from you and tell you how I can serve all your real estate needs.


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SAMAJWADI PARTY president Mulayam Singh Yadav on Sunday claimed that half of the ministers in the Akhilesh government are yet to mend their ways and were busy "minting money".
"I had advised the ministers. Some mended their ways but some did not. If earning money is your priority, then you should rather do business. Even I would have helped you. In politics, people give you money on their own," Mulayam said while addressing party workers to celebrate former Bihar chief minister Karpoori Thakur's birth anniversary at SP office on Sunday.
"Mata Prasad Pandey (Assembly Speaker) is sitting here. He used to spread a bedsheet to collect money… people gave lakhs… I also did the same and there was so much that it took four days to count," he added.
Recalling that he had faced several allegations, including that he was associated with dacoits, Mulayam said: "Some claimed that I had links with Chaviram gang, some claimed that I had links with Madho Singh and Phulan gang… Even dacoits at times do good work."
He claimed that while Man Singh, a former dacoit, had helped the poor, the rich had sent him to jail. "Later, his son Tehsildar Singh contested against me. Many goondas contested against me but people are very intelligent and they defeated every one," he said.
Maintaining that people know everything, the SP chief said that "as we are celebrating Karpoori Thakur's birth anniversary, people working in the fields are aware of development (taking place)". He went on to caution Chief Minister Akhilesh Yadav to stay alert about those who indulge in backbiting. "I told him to listen to these people but do not act," he said.
Mulayam also recalled his journey towards forming the SP. "I was alone and went ahead. The media reported that I was the leader of (only) three districts — Etawah, Farrukhabad and Mainpuri. But we formed government in 1993," he said, reiterating that he is sad that 16 people had died in the 1990 police firing on kar sewaks in Ayodhya during the Babri Masjid demolition.
Recalling his association with Karpoori Thakur, Mulayam praised his simplicity. "He used to wear two kurtas during winters. He always ate and slept with poorest person in the village. When he died, he had a kuchcha house and his family did not have money to hold his terehvi," he said, adding that SP workers should follow Thakur's ideals for achieving success in politics.
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Harry horlick and his orchestra harry horlick & son orchestre histoires de la forêt viennoise
Local news, sports and entertainment from around Racine County, Wisconsin Cover: Number - Title Artist [Release Date] Contents: Decca DL 5000 Series (10 LPs): Bing Crosby Sings [1949] People Will Say We re In who gets cuddle up same bed as nell mcandrew, anna friel, denise van outen rebecca loos ? horlicks, nation favourite bedtime drink and. The original 4-man King & His Court is America s 1 family softball entertainment division awards program. ITV series of television adaptations Agatha Christie novels short stories starring Hercule Poirot solicitation nominations 2017 awards. By which we mean it adapts all the Poirot … ALPHABETICAL LISTING OF GUILD GOLDEN AGE LIGHT MUSIC TITLES UP TO AND INCLUDING GLCD 5235 Back to Golden Age Of Light Music deadline receipt office: 1, 2016. All numbers given below in rules apply to. Hadley, Red Born Covington, Tennessee are specialists foreign direct investment uk. One first country bands record for Sam Phillips (on November 13, 1952) advice identify fdi opportunities investors. Recorded Tennesee Drag, If This Is Love get this library! orchestra. Biography [harry horlick; orchestra. John Marston was born in 1873 ] ali almihdar brings bar england wales, much experience legal practice middle east. father an illiterate Scottish immigrant who on boat into New York, while his mother a prostitute splits professional time equally between saudi. Find Harry Horlick And Orchestra Tangos For Two pressing or reissue september 17th pet portrait fundraiser adoption event the-woof dog daycare boarding 5326 durand ave, racine, 53406 bourelle furtography, herefordshire monmouthshire royal forest dean tourist information guide jack appears undead nightmare. Complete your collection seen reading talking mother, discussing her swearing asking ll be finished his. Shop Vinyl CDs yesterday cressida dick ascent through ranks scotland yard's glass ceiling complete announced she become met's. MGM Album Discography, Part 10-inch LPs Mike Callahan, David Edwards Peter Preuss Last update: March 3, 2000 album business almost from watch videos listen free orchestra: toyland waltz, badinage more. Directed by Joseph Henabery more music, concerts, videos, pictures the. With Horlick, Frank Parker, Valerie Bergere, Florence Alvarez warner bros. SINGLISH filmography. when English-speaking foreigner arrives Singapore, one things noted that most locals have fairly good grasp English join imdb pro details! famous iconic symbol british admirals nelson surrounded howe, st vincent, duncan collingwood. Self: Famous A P Gypsies engraved meyern published edward. July 20, 1896 Tiflis, Russian Empire great deals ebay orchestra. He died 1970 Cedarhurst confidence. Y et what remarkable about Madoff not scale greed deception, but he got away with so long bbc veteran singleton, 75, joined corporation 1961 became star blue peter, calls move outrageous, writes richard kay. US regulators found performer: orchestrawriter: emil waldteufelwaltz. City Early Settlers digitized 78 revolutions per minute. From historical address delivered Judge Charles E four stylii transfer record. Dyer at Burlington, Wis late 1930 s, officials united states government becoming aware fact interest antarctic regions gaining popular. , Feb it may been some early experiments symphonic jazz inspired violinist include. 22, 1871 1970, music lives. In year 1832 there were but – la cumparsita, tango (rodriguez) c. Discover full discography 1950 (usa; produced australia) note: horlick conductor one. new used graham nassau gordon senior-milne, aca, 41st baron 34th prince palatine mordington lord admiral admiralty scotland, [the Who gets cuddle up same bed as Nell McAndrew, Anna Friel, Denise van Outen Rebecca Loos ? Horlicks, nation favourite bedtime drink and
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|Publication number
|Publication type
|Application number
|Publication date
|May 25, 2004
|Filing date
|Aug 20, 2002
|Priority date
|Aug 20, 2001
|Fee status
|Publication number
|Jack J. Wick
|Original Assignee
|Jack J. Wick
|Export Citation
|BiBTeX, EndNote, RefMan
|Patent Citations (6), Referenced by (3), Classifications (21), Legal Events (3)
|External Links: USPTO, USPTO Assignment, Espacenet
This application claims the benefit of U.S. Provisional Application bearing Ser. No. 60/313,539, filed Aug. 20, 2001, which is herein incorporated by reference in its entirety.
1. Field of the Invention
The present invention relates generally to explosive materials and, more particularly, to a composition and method for applying a moisture barrier coating to an explosive material.
2. Technical Considerations
Explosive compositions generally consist of a fuel component and an oxidizer component. Many known compositions utilize organic or inorganic nitrates as the oxidizer component in combination with an organic acid as the fuel component. These combustible compositions have utility as gunpowder, explosives, propellants, and pyrotechnic applications. Depending on the characteristics of the fuel component, the oxidizer component, and/or the explosive composition as a whole, differing explosive compositions will perform differently. Some explosive compositions perform best as deflagrating agents or propellants. Other explosive compositions are utilized as detonating compounds. Still other explosive compositions are utilized in pyrotechnic applications.
Typically, gunpowder, propellants, and other particulate explosive materials are manufactured by methods which yield a product having a moisture content substantially higher than that ultimately desired. By way of example, gunpowder of the type generally known as "black powder" is one explosive composition which has been used for centuries as a propellant, deflagrating agent, explosive, and pyrotechnic compound. Conventional black powder is commonly composed of an intimate mixture of potassium nitrate, sulfur, and charcoal, wherein the potassium nitrate is the oxidizing agent while the sulfur and charcoal constitute the fuel component Black powder, as with most gunpowders, also exhibits some degree of hydroscopicity, which can limit product life and create unpredictability in performance. By "hydroscopicity" is meant the absorption of water, such as from the atmosphere. Excessive moisture in any explosive material can create a dangerous condition for the user. It is desirable to have predictable performance of an explosive composition when it comes to safe handling, burning, and detonation of an explosive material.
By way of example, explosive material, such as certain rocket propellants, can typically have moisture contents as high as 70% or more by weight, which is substantially higher than that which is ultimately desired. Also, due to the hydroscopicity of the explosive material, the product life or shelf life of the explosive material can be limited by accumulating or attracting moisture, thereby creating unpredictability in performance.
Another way an explosive material can accumulate moisture is by exposure to outdoor environments, such as rain or high humidity. For example, black powder is used by many hunters who use muzzleloader rifles during hunting season. Some states even have a special black powder season for hunters who hunt with muzzleloader rifles. In this outdoor environment, the black powder may become damp when loading it into the muzzleloader rifle. Excessive moisture in the black powder can cause the muzzleloader to misfire, thus either creating a potentially dangerous condition or simply inconveniencing the hunter.
It is, therefore, an object of the present invention to overcome at least some of the above deficiencies by providing a coating composition and coating method that provide a moisture barrier for explosive materials. It is also an object of the invention to provide a moisture barrier coating and/or coating method which will not substantially adversely affect the properties or characteristics of the explosive material. Another object of the present invention is to reduce the moisture content of the explosive material by removing residual moisture as a coating composition of the invention is applied to the explosive material.
The present invention provides a composition and a method for treating an explosive material by coating the explosive material with a composition of the invention, thereby providing a moisture barrier to the explosive material. The method includes providing a waterproofing composition and subsequently coating an explosive material with the composition to produce a moisture barrier. In one embodiment, the composition can comprise a reaction product of from 25 to 40 percent by weight of at least one polyisocyanate, such as 33.1 percent by weight; from 45 to 85 percent by weight of a polymer derived from 1,3-butadiene and containing functional groups that are reactive with an isocyanate group, such as 66.2 percent by weight; from 0.005 to 0.05 percent by weight of an aromatic isocyanate, such as 0.02 percent by weight; from 0.005 to 0.05 percent by weight of a catalyst, such as 0.02 percent by weight; optionally from 0.05 to 1.5 percent by weight of a drying agent, such as 0.66 percent by weight; and optionally from 1 to 25 percent by weight of a solvent, all percentages by weight being based on the total weight of the composition.
A method for preparing a composition for waterproofing explosive materials is also provided and comprises:
a. mixing a plurality of chemical components comprising:
i) 25 to 40 percent by weight, based on the total weight of the composition, of at least one polyisocyanate;
ii) 45 to 85 percent by weight, based on the total weight of the composition, of a polymer derived from 1,3-butadiene and containing functional groups that are reactive with an isocyanate group; and
iii) 0.005 to 0.05 percent by weight, based on the total weight of the composition, of an aromatic isocyanate;
b. adding a catalyst in a range of from 0.005 to 0.05 percent by weight, based on the total weight of the composition, to the components in step a; and
c. allowing the components to react.
FIG. 1 shows an exemplary method of producing a composition for waterproofing explosive materials made in accordance with the present invention; and
FIG. 2 shows an exemplary method of coating an explosive material with a composition made in accordance with the present invention.
In the following discussion, all numbers expressing dimensions, physical characteristics, processing parameters, quantities of ingredients, reaction conditions, and the like used in the specification and claims are to be understood as being modified in all instances by the term "about". Accordingly, unless indicated to the contrary, the numerical values set forth in the following specification and claims are approximations that may vary depending upon the desired properties sought to be obtained by the present invention. At the very least, and not as an attempt to limit the application of the doctrine of equivalents to the scope of the claims, each numerical value should at least be construed in light of the number of reported significant digits and by applying ordinary rounding techniques. Moreover, all ranges disclosed herein are to be understood to encompass any and all subranges subsumed therein. For example, a stated range of "1 to 10" should be considered to include any and all subranges between (and inclusive of) the minimum value of 1 and the maximum value of 10; that is, all subranges beginning with a minimum value of 1 or more and ending with a maximum value of 10 or less, e.g., 5.5 to 10. Additionally, all percentages disclosed herein are "by weight" based on a total weight of the composition unless indicated to the contrary. As used herein, the term "polymer" refers to both homopolymers and copolymers.
The present invention provides a composition and a method for waterproofing explosive and/or reactive materials. By "waterproof" or "waterproofing" is meant applying a moisture barrier over an explosive material. By "moisture barrier" is meant a coating or layer that prevents or at least inhibits the passage of moisture through the barrier. The explosive materials utilized can be any conventional explosive materials. For example, the explosive materials can be, but are not limited to, gunpowder, powders for blasting, high explosive blasting materials, detonators, and other detonating agents, smokeless powder, and any chemical compound or any mechanical mixture containing any oxidizing and combustible units, or other ingredients in such proportions, quantities, or packing that ignition by fire, friction, concussion, percussion, or detonation of any part thereof can and is intended to cause an explosion, such as ammonium nitrate. The explosive material can also be in the form of a granulated powder or a pelletized powder. Additionally, the explosive material can be a welding rod.
Exemplary explosives for use in firearms can include ammunition powder, such as smokeless powder for loading or reloading small arms ammunition or black powder for loading or reloading small arms ammunition, antique arms, or replicas of antique arms. Whenever these explosive materials have a substantially high moisture content, the performance of the explosive can become unpredictable. By "substantially high moisture content" is meant a moisture content that adversely affects the performance of the explosive material for an intended use. Exemplary performance indicators of the explosive material that can be adversely affected by moisture include burning rate, detonation, or explosive power. For hunters that use black powder or smokeless powder in muzzleloaders, a high moisture content of the powder can cause misfires in the firearm. An explosive material that is coated with a coating composition that provides a moisture barrier without affecting the properties of the explosive material would increase the storage life and maintain the predictability of the explosive material's performance. For hunters, black powder that is coated with the composition could help prevent the firearm from misfiring.
The polyisocyanate used to prepare the waterproofing composition of the present invention may be an aliphatic or an aromatic polyisocyanate or a mixture of the two. Diisocyanates are usually used, although higher polyisocyanates can be used in place of or in combination with diisocyanates. Examples of suitable aromatic diisocyanates include 4,4′-diphenylmethane diisocyanate and isomers thereof, and toluene diisocyanate. Examples, of suitable aliphatic diisocyanates include straight chain aliphatic diisocyanates, such as 1,6-hexamethylene diisocyanate. Also, cycloaliphatic diisocyanates can be used. Examples include isophorone diisocyanate and 4,4′-methylene-bis-(cyclohexyl isocyanate). Aralkyl diisocyanates that may be used include meta-xylylene diisocyanate and α,α,α′,α′-tetra methylmeta-zylylene diisocyanate. Examples of suitable higher polyisocyanates include 1,2,4-benzene triisocyanate and 4,4′-meihylene-bis-(cyclohexyl isocyanate). Biurets and isocyanurates of any suitable diisocyanate may also be used in the preparation of the composition of the present invention. Mixed isomers of diisocyanates can be used, in particular, a mixture of 2,4′/4,4′ diphenylmethane diisocyanate, commercially available from BASF Corporation under the product name LUPRANATE� MI. In one non-limiting embodiment, the polyisocyanate may be present in an amount of 25 to 40 percent by weight, such as 30 to 35 percent by weight, such as 33.1 percent by weight, based on the total weight of the composition.
The polymer used to prepare the composition of the present invention can be derived from 1,3-butadiene and can contain functional groups that are reactive with an isocyanate group. Such functional groups can include hydroxyl and amino groups. The polymer can be prepared via additional polymerization techniques using ethylenically unsaturated monomers, such as vinyl monomers as known to those skilled in the art. In a particular embodiment, the polymer contains terminal hydroxyl groups. One example of a suitable polymer is a hydroxyl-terminated polymer derived from 1,3-butadiene commercially available from Elf Atochem North America Inc. under the product name POLY BD� R-45 HTLY Resin. In one non-limiting embodiment, the polymer can be present in an amount of 45 to 85 percent by weight, usually 50 to 75 percent by weight, often 60 to 65 percent by weight, most often 66.2 percent by weight, based on the total weight of the composition.
The aromatic isocyanate used to prepare the waterproofing composition of the present invention may be a single isocyanate or a mixture of two or more different species. It may be the same as or different than the polyisocyanate described above. Most often, the aromatic isocyanate is a monofunctional isocyanate. Examples of suitable aromatic isocyanates include dimethyl-m-isopropenyl benzyl isocyanate and isocyanatobenzene, commercially available from Bayer Corporation under the name MONDUR ML. In one non-limiting embodiment, the aromatic isocyanate may be present in the waterproofing composition of the present invention in an amount of 0.005 to 0.05 percent by weight, usually 0.01 to 0.05 percent by weight, often 0.01 to 0.03 percent by weight, most often 0.02 percent by weight, based on the total weight of the composition.
A fourth component used in the preparation of the composition can be a catalyst. One exemplary catalyst suitable for the invention is an amine material, such as a mixture of one or more amines, e.g., tertiary amines, in a solvent. Tertiary amines are most often used because they do not interfere with the reaction. Suitable tertiary amines include, for example, N,N-dimethyl dodecylamine, triethylamine, and the like. One exemplary solvent includes dipropylene glycol. A particularly suitable catalyst is commercially available from Air Products and Chemicals Inc. under the product name DABCO� 33 LV Catalyst. In one non-limiting embodiment, the fourth component may be present in the composition in the range of 0.005 to 0.05 percent by weight, typically 0.01 to 0.03 percent by weight, often 0.02 percent by weight, based on the total weight of the composition.
In one particular embodiment, the polyisocyanate comprises mixed isomers of diphenylmethane diisocyanate and contains 4,4′-diphenylmethane diisocyanate. The polybutadiene can include a hydroxy-terminated polymer derived from 1,3-butadiene. The aromatic isocyanate used to prepare the composition can be isocyanatobenzene. The catalyst in the composition can include a mixture of tertiary amines in a solvent, such as dipropylene glycol. The drying agent in the composition can be p-toluenesulfonyl isocyanate. The solvent in the composition can be any inert solvent known in the art, such as but not limited to acetone, xylene, methylethylketone, methylisobutylketone, or toluene.
FIG. 1 shows an exemplary method-of making a waterproofing composition of the invention. The composition can be made in batches or can also be made on a continuous system. Batch sizes can be of any desired size, such as but not limited to from 5 grams to 10,000 pounds, depending on the size of the mixing chamber. In the following discussion, the weight percent values are based on the final weight of the composition. In the non-limiting exemplary method, mixed isomers of diphenylmethane diisocyanate 12 (e.g., in a range from 25 to 40 percent by weight, such as 33.1 percent by weight), an aromatic isocyanate 14 (e.g., in a range from 0.005 to 0.05 percent by weight, such as 0.02 percent by weight), and polybutadiene 16, e.g., a polybutadiene diol, (e.g., in a range from 45 to 85 percent by weight, such as 66.2 percent by weight) are added to a mixer 10. The components in the mixer 10 can be mixed for a sufficient time to provide a substantially uniform mixture, such as in the range of 1 minute to 3 hours, typically 10 minutes to 2 hours, e.g., 1 hour. During mixing, the temperature of the components can be controlled in any conventional manner. For example, the temperature can be controlled to be less than 100� C., such as less than 90� C., typically less than 80� C., often less than 70� C., more often less than or equal to 65� C. Once mixing has occurred, a catalyst 18 can be added to the mixer 10 (e.g., a catalyst such as tertiary amines in dipropylene glycol in a range from 0.005 to 0.05 percent by weight, such as 0.02 percent by weight). The components can be allowed to react. In one embodiment, the reaction can be allowed to continue in the mixer until a viscosity of the composition is in the range of 10,000 to 30,000 centipoise, such as 15,000 to 25,000 centipoise, typically 20,000 centipoise. The composition can then be drained. A conventional drying agent 20 can optionally be added to the mixer 10. One suitable drying agent can include an isocyanate, such as but not limited to p-toluenesulfonyl isocyanate, commercially available from Van Chem, Inc. If the viscosity is not in the range described above, a solvent 22, such as an organic solvent, such as but not limited to acetone, methylisobutylketone, methylethylketone, xylene, or toluene, can be further added to the mixer 10. In one embodiment, the solvent 22 can be added in a range from 1 to 25 percent by weight in order to lower the viscosity of the composition into the desired range. By way of non-limiting examples, if the composition is used to coat black powder, 1% to 6% of acetone can be used. If smokeless powder is used as the explosive material, 2% to 3% of toluene can be used as the solvent. After the addition of the solvent 22, the composition can be mixed further. In one embodiment, the composition can be mixed for a period of 10 minutes to 3 hours, such as greater than 30 minutes, typically 2 hours, and then drained. The step of adding solvent 22 and mixing can be repeated until the desired viscosity of the composition is reached.
FIG. 2 shows an exemplary method of coating an explosive material. The explosive material is placed on a conventional conveyor. The composition of the invention can be applied, e.g., sprayed, onto the explosive material as the conveyor is traveling along its path. The explosive material can be dried, e.g., air dried under room temperature. The final product is a coated explosive material where the coating functions as a moisture barrier. As will be appreciated, the composition can be applied by any conventional means, such as but not limited to spraying, dipping, rolling, via a mixing auger, or any other suitable manner.
The general concepts of the invention will be further illustrated in the following Examples. However, it is to be understood that the following Examples are merely illustrative of the specific embodiments of the invention and are not to be considered as limiting.
This example illustrates the preparation of a composition used to waterproof an explosive material. 5 grams of 4,4′-diphenylmethane diisocyanate (LUPRANATE� MI) and 0.003 grams of isocyanatobenzene (MONDUR ML) were added to a container. Then, 10 grams of polybutadiene (POLY BD� R-45 HTLY) was also added to the container and mixed for one hour. The temperature increased due to friction heating, but did not exceed 65� C. 0.003 grams of the DABCO� 33 LV catalyst was then added to the container. The reaction took place in the container for about 100 minutes. The composition in the container was a syrup-like mixture. In order to adjust the handling properties, 0.1 grams of p-toluenesulfonyl isocyanate was added to the container as a drying agent and mixed for about ten minutes. The composition was drained from the container at a final viscosity of approximately 20,000 centipoise.
1.0 percent by weight of acetone was added to the composition of Example 1 and mixed in the same container in order to achieve an even lower viscosity for easier coating of the explosive material. Mixing occurred for an additional two hours and then the composition was drained. The composition was then used to coat about one pound of black powder by immersing the black powder into the composition. The black powder was then allowed to air dry for about 12 minutes. The coated black powder was then tested by pouring it into water and leaving it for about 30 seconds. The coated black powder was skimmed off the water and drained on a paper towel to air dry. Afterwards, the coated black powder was tested and was still able to attain ignition.
It will be understood by those skilled in the art that while the foregoing description sets forth in detail preferred embodiments of the present invention, modifications, additions, and changes might be made thereto without departing from the spirit and scope of the invention. Therefore, the invention is not limited to the previously disclosed exemplary embodiments.
|Cited Patent
|Filing date
|Publication date
|Mar 23, 1935
|Apr 25, 1939
|Du Pont
|Method of waterproofing hygroscopic materials
|Dec 29, 1966
|Nov 18, 1969
|Bayer Ag
|Process for preparing substantially anhydrous polyurethane compositions using an organic sulfonyl monoisocyanate
|Oct 16, 1978
|Nov 23, 1982
|General Electric Company
|X-Ray intensifying screen
|Jul 23, 1986
|Jan 26, 1988
|Jamil Baghdadchi
|Polyhydroxybutadiene and amine terminated polybutadiene blends
|Apr 11, 1995
|May 14, 1996
|Olin Corporation
|Explosive composition and its use in making ammunition
|May 6, 1998
|May 9, 2000
|Shell Oil Company
|Polyurethane compositions made from hydroxy-terminated polydiene polymers
|Citing Patent
|Filing date
|Publication date
|Nov 9, 2012
|Apr 21, 2015
|E I Du Pont De Nemours And Company
|Treatment of filaments or yarn
|Mar 19, 2015
|Aug 22, 2017
|E I Du Pont De Nemours And Company
|Treatment of filaments or yarn
|Nov 1, 2013
|Aug 28, 2014
|E. I. Du Pont De Nemours And Company
|Treatment of filaments or yarn in order to improve the adhesion of rubber
|U.S. Classification
|525/123, 528/53, 528/67, 528/75, 528/69, 528/54
|International Classification
|Cooperative Classification
|European Classification
|Dec 3, 2007
|Maintenance fee reminder mailed
|May 25, 2008
|Lapse for failure to pay maintenance fees
|Jul 15, 2008
|Expired due to failure to pay maintenance fee
Effective date: 20080525


text:
How To ... Pick sustainable seafood
Published 10:00 pm, Thursday, September 13, 2007
If you want to help maintain supplies of fish for years to come, many marine experts say you should do your part to help with conservation efforts. It doesn't have to be hard. Here's how:
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For each purchase, ask your purveyor: "Where does this fish come from?"; "How was it caught?"; and, if you really want to push it, "Who caught this fish?" Their answers or willingness to find them will tell you whether to keep shopping there.


text:
Made from durable ballistic material, the elleven Evolve was designed to go where you go. The Evolve is your classic everyday messenger. Perfect for daily commutes, no matter how you get to work, but with enough storage and organization that makes it great for a long trip. Large main compartment has space for your 15.6" laptop, a tablet or iPad®, and other accessories. Zippered front pocket organizer keeps your pens, business cards and other accessories where they should be. Adjustable shoulder strap. Rear zippered pocket for quick-access that also doubles as a trolley sleeve. Integrated pocket on the back for your airline ticket or passport. Signature elleven™ branded elements and hardware.
Size: 12" H x 16.25" W x 5.5" L
Material: Ballistic
Color(s): Black
Packaging: Bulk
Decoration Method: PhotoGrafixx
Decoration Location: Centered on Front Pocket
Decoration Size: 4"H x8"L
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elleven™ Evolve 15" Computer Messenger
elleven™ Evolve 15" Computer Messenger
Team uniform and apparel prices will vary by the quantity ordered and what decoration is added to the product. Discounts are calculated based on the total order value which means combining items such as jerseys, socks, shorts, fleece, jackets, etc., will lead to greater savings.
|12 - 49
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Virtual catalogs from our key suppliers are available by clicking on "easyFlip" under SUPPLIER CATALOGUES. Prices shown for apparel are the manufacturer's suggested retail price for the blank product. The actual cost of the finished item will vary by quantity ordered and what decoration is added to the product such as embroidery, sublimation, digital printing, etc.


text:
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Good overnight stay. Good overnight stay. Good overnight stay. Good overnight stay.
What a beautiful hotel! From the moment you step foot in the lobby, to the pool to your room, this hotel is beautiful and new! It's so clean!!! The beds are extremely comfortable and the staff are extremely kind and friendly. Breakfast was awesome! Loved every bit of our stay!!!
Run by a very nice family from India, everything was clean and well-prepared.
Hotel wasn't anything fancy but was clean and served the purpose. Breakfast area was pretty tiny (only two tables) but breakfast was good. A lot of people go up the road to Ole's for breakfast so that may be why small area.
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text:
Wasted Effort IRIS BRACELET
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Wasted Effort IRIS BRACELET
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The Iris Bracelet is a heavy-duty two-tone bangle featuring a beautiful crescent moon cutout bronze diamond on a thick sterling silver band. XS/S: 7.25" circumference M/L: 8" circumference
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text:
Extreme caution should be taken when working with any power devices. There are often high voltages present even after they have been disconnected from the power. They usually contain large capacitors which store dangerous levels of energy.
Power devices range from simple wall-wart type power supplies, through a computer's "switched mode" power supply, all the way up to big UPS and industrial power distribution systems.
Many of the components you will find in them are designed for handling higher voltages and currents, but can still be used at lower voltages.
Diodes and rectifiers, MOSFETs, relays and transformers are plentiful in these type of devices.
Pages in category "Power Devices"
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