text:
Essays by Thushi
History and modernisation !November 8th, 2014
History denotes our cultural heritage.It also shows how our ancient people used to live, their life style,the difficulties they were facing and a lot more.We can learn a lot of things from our past so the history does. So, it is our responsibility to keep those valuable records safe. Old buildings are one of the major thing that represents or denotes the society's past.Building represents, how rich the societies were. It also shows, How they used to live in the building?, what are the different technologies or methods they used at that time? We can always learn from our history.It's the responsibility of government as well as the people to keep the history alive.
Free birdsNovember 8th, 2014
The future of the country always depends on the younger generation. It is more important how the child will behave with their peers and with the outside world.Parents and their teachers takes an important role in shaping out their behaviour.Children learn or act by looking at others,so it is also important that how we should behave with the children.We can see that governments of different countries has different rules and regulations on children, where some of the countries allows full freedom for the children and some of the countries are having very restricted rules and regulations.Lets discuss the pros and cons in both the perspective.
Education is not just concentrating on academics.November 7th, 2014
Education is not about just learning the academics or just completing the homework given by the teacher.Education is not just the academics but it also about learning the life values, participating in the sports, cultural activities and many more. Physical activities are more important in life as it helps to be healthier and active. It should be a part of our daily routine.As there is a saying "Health is wealth", to keep our health condition good we should daily spend some time in the physical activities like sports, exercise.


text:
What Does 7 Figure Cycle review Mean?
For a consumer It truly is very simple! Through the online world you're looking for Internet sites that sell your favourite merchandise and enter them and assess them coupled with other relevant choices to sector the exact same product or service in your liking form, rate, high-quality and payment solutions correct to a product with your buying basket, which supplies you some web site such as the basket you're taking in almost any Market and put your buys!
Additional, This Web page isn't going to warrant or make any representations regarding the precision, very likely final results, or trustworthiness of using the supplies on its Online Site or if not associated with these kinds of supplies or on any internet sites connected to This website.
Electronic mail may possibly choose up 24–48 hrs. Worse circumstance circumstance, your message goes into spam box. I do think Together with the higher price tag fee, the owner ought to have remarkable aid technique.
Where by would a web site be with out great hosting? We asked ourselves this question and weren't content with the answer.
The answer is to choose from, you merely should take step one (just before they near on membership in February 1st, 2018).Know about the launching day: The pre-start starts on the 17th of January, the Cart opens within the 23rd of January and it remains open until February 1st (also, they expect this launch to be existence-modifying for the many folks that may come to be included so concentrate on the updates on their own web page and in addition look into the prizes that they can give absent in the launch 7 days, all of the information about this software is out there on their own Internet site).So, go ahead, enroll, love, understand a whole lot, earn fantastic funds and at the top notify us how did anything go.
Electronic Commerce or eCommerce which accurately usually means small business trading via the world wide web is a system which allows online actions, buying...
E-commerce has large impact on the economic climate and Modern society. E-commerce permits the globalization of markets and created a Modern society depending on knowledge and information.
Inside our ever switching industry, it is necessary to advertise these business processes to permit us to operate alongside one another to unravel much more Health care issues Hence permitting Positive aspects to get prolonged into the sufferers.
Just after diversifying sources of income and beginning to click here now get hard cash inflows. Give attention to growing returns from these flows, devote all your income.
With AWS you can have your ecommerce Web sites hosted within a datacenters in almost any of sixteen diverse geographic Areas around the globe; so that you can provide every single geography with only a few mouse clicks.
Any site that has a selected marketing and purchasing function should endure several elements that insert to its accomplishment, as opposed to other websites that concentrate on residence enjoyment or news just. Perhaps essentially the most vital of these things is "mortgage, time and effort".
Many people attempt to excel in wealth, don't just to boast but to make certain a superb everyday living and properly-getting for his or her children as well as their households. But this title is not really offered to lots of because they are fewer than it, but they Dwell their life in the incorrect way and perform in a standard way. 7 Figure Cycle offers a series of methods and motives to make you a gateway to wealth: Personal your personal business enterprise If you do not want to be your personal organization and be by yourself, you know you are quite far from remaining prosperous or perhaps a millionaire, simply because the worker generally seeks to depart duties for some money every year or each month, and it is actually surely not required to achieve Your individual enterprise but working for another person keeps you away from the big cash aspiration. Try the chance Folks will not grow to be millionaires without having risking, and that does not indicate you need to commit everything you possess, but insane steps and risk are A serious explanation for revenue development, and most rich folks took a crucial danger that remodeled their life. Focus on your good Strategies Confident, you've some good Concepts in numerous parts that believe in their ability to make you rich, and leaving you with these Tips with the conditions away from the title of millionaire, When you've got a good idea to work on the evolution and perform and study for being Completely ready for implementation.
Many men and women feel that usage of prosperity and money liberty is very hard, and necessitates many years to obtain. Referring to turning out to be a millionaire before the age of 30 is unbelievable.
with Patrick Rauland Learn the way to construct an internet based retail outlet with WordPress, working with WordPress ecommerce plugins as well as a array of third-celebration instruments.

subset: commoncrawl


text:
Home›Forums›In Chengdu›Beach Volleyball in Chengdu?
Hi all,
Does anyone know of or have been to an indoor or outdoor beach volleyball facility in Chengdu?
I'm not looking for anything fancy, any sand courts will do. We can bring our own lines.
I have read there's an indoor beach at the New Century Global Centre, are there sand volleyball courts in there?
Just looking to stay active while visiting Chengdu.
I can't remember ever seeing beach volleyball in Chengdu with sand, but volleyball is popular and you can definitely find that around Sichuan University. There are a lot of sports facilities there.
Thanks for the reply! Do you know what format it is? Or if there's open/pick-up play? Can anyone use the facilities?
You must be logged in to reply to this topic.
© 2018 Chengdu Living. All Rights Reserved.


text:
Today health Tip - An OverviewKnopman explains that brain Health is affected by lots of aspects, together with instruction and chances for mentally stimulating activities starting off in childhood, and also with the existence or absence of melancholy, diabetic issues, smoking cigarettes, significant blood pressure level, as well as other risks.
Evidence is combined, but several experiments have found that women who go ahead and take herb black cohosh throughout menopause may perhaps practical experience less and milder sizzling flashes. Check with your health practitioner about no matter whether It really is best for you; If that is so, pick a well-analyzed brand for example Remifemin.
Courtesy of Elizabeth Zanin ninety three-calendar year-old's joyful exercise session will be the sweetest point you'll see all day Helene Z. Miller demonstrates the earth that you are under no circumstances way too outdated to dance with just a little aid from her...
It doesn't matter what We now have going on inside our life, among The main issues we can all do is convey Vitality, not steal it. This suggests sustaining a favourable outlook and Electricity, regardless of whether our lives are certainly not as they ought to be or we desire they had been. This is essential for our health, along with the health of Some others all over us.
Here are 20 of the best daily health tips I can present you with. These speedy health tips might be great daily health tips for Women of all ages and Adult men alike, plus they'll make it easier to with the health, Conditioning, eating plan, and weight-loss.
By DR. KENNETH HANSRAJ Vacations are meant to be enjoyable, but touring may cause enhanced worry on your body and ultimately become a literal agony during the neck and spine.
Weil has began doing this daily, and oh how I extended to. He's anxious that our latest data overload from media, the net, phones and texting "is shifting our brain function in lousy strategies". I'm guaranteed he's proper.
Check out a meatless food every week. Think vegetable lasagna or a portabella mushroom burger! Vegetables and beans can add protein, fiber, along with other nutrients into a meal.
"One Females (Put a Ring On It)"?), then flip up the volume, and begin breaking it down. For a lot more enjoyable, invite some gal pals about and obtain grooving (and laughing). The best part is that you're going to Just about every burn up about 200 to 600 energy for each hour. Now that's a little something to shimmy about!
Having said that, Knopman states, "I think that socially partaking routines are particularly significant, and that's why I am considerably skeptical about the various professional entities that seek out to market Pc game titles to promote the brain. ... If which is performed for the exclusion of socially engaging activity, It is really in all probability counterproductive."
I ensure my health club and karate studio are only significantly ample absent which i can operate or cycle to class. It provides me a terrific training ahead of my true training, and it's a number of hundred further energy burned.
Relocating first thing in the working day boosts your serotonin degrees, supplies Vitality to the body, in addition to can help you emphasis far better throughout the day. It is usually an click here uncomplicated strategy to boost your metabolism to help regulate your body weight.
Among the finest ways to extract every one of the goodness from cinnamon should be to soak the stick in h2o and sip on it often. Backed by many health specialists, ...
Furthermore, it helps prevent muscle click here stagnation that could just make you really feel badly. Extend each morning click here a little and somewhat more during the night time prior to Today health Tip mattress. Even just a pair minutes will make you're feeling superior — click here try it!


text:
Adam4adam is your free online gay dating site with chat and cam visit our website today and find your adam. Women seeking dick fort totten sang rud pey married couples wants online dating hot dates mature meriden (i will not join a dating site/verification. Dating sites for mature adults marshallville dating sites for mature adults fort smith duties include dishes, floors, cleansing the kitchen and toilet and every so often windows and dusting. Frontier military / indian wars his descriptions of the sundance of the sioux and the military reservation at fort totten transcript copy of diary dating. Fort lauderdale singles are waiting to flirt with you right now you could be looking to date someone locally too if that is the case then we are the best fort lauderdale singles site. Free to join & browse - 1000's of singles in fort totten, north dakota - interracial dating, relationships & marriage online. Meet fort worth mature women with loveawake 100% free online dating site whatever your age, loveawake can help you meet older ladies from fort worth, texas, united states just sign up.
Single and over 50 is a premier matchmaking service that connects real professional singles with other like-minded mature singles that are serious about dating. Frequently asked questions marcy and fort totten were somewhat left intact and are now covered by mature woodlands fort who was fort totten named. Meet fort lauderdale mature women with loveawake 100% free online dating site whatever your age, loveawake can help you meet older ladies from fort lauderdale, florida, united states just. Sexyads was one of the very first adult dating sites on the net we created our mature dating site for people like us -- adults who have lived without sex. Northwood gardens has rental units starting at $1392 fort totten's wealth of green space and canopy of mature trees add to the charm of the neighborhood's.
I've done my share of complaining about the rules on this site honestly this is the worst site i've come across so far for dating it's free. Fort totten hook up site hookup, dating or long term live in fort totten meet someone now search other cities for hot women looking for sex and dating. Someone you can love is nearby browse profiles & photos of asian singles in fort totten, ny join matchcom, the leader in online dating with more dates, more relationships and more.
Building 405: fire department training center fort totten historic district, fort totten, bayside, queens whistler avenue, west side, between abbot road and walter reed ro. Single fort totten native american women interested in native american dating looking for fort totten native american women check out the the newest members below and you may just see if. Milf personals - sift through the i am a mature woman who knows what she wants and doesn't have a lot of time for games or for people online dating sites.
Our dating site has members from all over new york, including fort totten we are one of the only 100% exlcusive crossdressing only dating site and want you to feel welcome and a part of. Housewives looking sex fort totten, horney females troy tennessee, sex dating united states simple massage from mature bbw fat lonely want dating sites online. See all 251 apartments in fort totten fort totten's wealth of green space and canopy of mature trees add to the charm of the fort totten apartments for. What an amazing place my friends and i enjoyed every moment that we spent at the totten trail inn the decor and all the things to look at were just wonderful.
Come and join the fun at granny personals - these good looking mature women will impress you, granny personals dating sites as a member of granny personals. Dating as a single mommy fort totten, north dakota about a solitary mommy on the dating scene as author of the connection wellness blog site. Free sex dating in fort totten, north dakota if you are looking for affairs, mature sex, sex chat or free sex then you've come to the right page for free fort totten, north dakota sex.
An announcement by the city tuesday that it has decided to break ground for a multi-million-dollar fire academy on randall's island has left the future of the fort totten redevelopment plan. The eroding walls of fort totten inside the abandoned military fortress that guarded new york harbour during the civil who she was 'dating' before his death. Personal ads for fort totten, nd are a great way to find a life partner, movie date, or a quick hookup personals are for people local to fort totten, nd and are for ages 18+ of either sex. The oldest tourist attraction in every state fort totten state historic site in ft similar artifacts were found at cremation and burial sites dating from ad.
Fort totten sex search signup free and meet 1000s of local guys and gals in fort totten, new york looking to hookup on bookofmatchescom. Meet fort totten singles online & chat in the forums dhu is a 100% free dating site to find personals & casual encounters in fort totten. Free mature gay dating for older men and younger gay men who like silverdaddies it's about time dating sites catch up silverfoxie is here to take the reins. Hairy women personals is a niche site made for admirers of hairy woman and for hairy women looking for a all members of this dating site must be 18 years or.


text:
Specifications Model: EB1820 Capacity: 2.0ah Type: Nickel Cadmium Charging time with listed charger - UC24YJ: 18mins, UC24YFA: 50mins, ET18DM: 18mins, UC18YG: 50mins
Hitachi EB1820 battery by Amstron is designed for use with Hitachi CR18DMR, C6DD, C18DMR models. Amstron power tool batteries are precision-engineered and rigorously .
Hitachi 322437 EB1820 18-Volt 2.0 Amp Hour NiCad Pod Style Battery - Cordless Tool Battery Packs
: 18v 1.9Ah NiMH Hitachi - TOL3211, 18v 3Ah NiMH Hitachi - TOL3212, 18v 2.8Ah NiMH Hitachi - TOL3220, 18v 1.9Ah NiCd Hitachi DS18DVB - TOL3200, 18v 3Ah Li-Ion Hitachi .
Find great deals on eBay for Hitachi EB1820 in Power Tool Batteries and Battery Chargers. Shop with confidence.
Product Description Hitachi 322881 EB1820L 18-Volt 2-Amp Hour Nickel Cadium Pod Style Battery
Friday 01 April, 2016 : 25134663 requests since Wednesday 04 June, 2008 : All manufacturer brand names, logos and trademarks (such as Dewalt, Compaq, Canon, JVC .


text:
The Exhibit Hall at the American Society for Reproductive Medicine's Scientific Congress & Expo is established to provide space to promote products, services and educational material determined by ASRM to be of interest to ASRM members and their guests and consistent with ASRM's mission.
In January 2019, 2018 exhibitors will be emailed the application to exhibit at the 2019 ASRM Scientific Congress & Expo. Selections for exhibit space will be made based on levels of support from previous years and with preference given to exhibitors who booked in the hotel room block at the 2018 meeting.
ASRM reserves the right to review each Exhibitor's content prior to assigning the space and may decline to offer space to any applicant at ASRM's sole discretion. Application for exhibit space must be made on the Official Exhibit Space Application and Agreement form. Applications accepted will be invoiced with payment due in 30 days.
We will send the application to the contact on file from the 2018 Expo. If you need to update your contact to receive the application, please do so as soon as possible.
Thank you for your support of ASRM and the annual Congress and Expo! We look forward to working with you in 2019!
For further information please contact: Exhibit Marketing & Management American Society for Reproductive Medicine 1209 Montgomery Highway Birmingham, Alabama 35216-2809 Phone: (205) 978-5000 Fax: (205) 978-5005 Email: email@example.com


text:
Michael Goodwin: Lashing out over Trump is nothing new for liberals
A headline on a story about escalating liberal outrage toward President Trump and his team wondered whether the resistance movement had veered off the "high road."
Veered off? When was it ever on the high road?
Certainly not when congressional Democrats boycotted Trump's inauguration. And certainly not when, soon after the election, Dems tried to pressure Electoral College electors in states that Trump won into backing Hillary Clinton.
Even more important, was the Obama administration taking the high road when the FBI gave Clinton preferential treatment despite her sloppy handling of classified emails? Or when it weaponized the FBI and CIA to paint Trump's campaign as a Russian agent?
To continue reading Michael Goodwin's column from the New York Post, click here.


text:
Electrophilic Reactions on Aromatic Compounds Monosubstitution. Dr. Sapna Gupta
- Brook Barton
- 2 years ago
- Views:
1 Electrophilic Reactions on Aromatic Compounds Monosubstitution Dr. Sapna Gupta
2 Electrophilic Aromatic Substitution Arene (Ar-H) is the generic term for an aromatic hydrocarbon The aryl group (Ar) is derived by removal of a hydrogen atom from an arene Aromatic compounds undergo electrophilic aromatic substitution (EAS) The electrophile has a full or partial positive charge The benzene ring is the nucleophile. Electrophilic Reaction on Benzene 2
3 General Mechanism Regardless of the electrophile used, all electrophilic aromatic substitution reactions occur by the same two-step mechanism addition of the electrophile E + to form a resonance-stabilized carbocation, followed by deprotonation with base, as shown below: Electrophilic Reaction on Benzene 3
4 General Mechanism, contd. The energy diagram of this reaction shows that the first step is highly endothermic and has a large DG (1) The first step requires the loss of aromaticity of the very stable benzene ring, which is highly unfavorable The first step is rate-determining The second step is highly exothermic and has a small DG (2) The ring regains its aromatic stabilization, which is a highly favorable process Electrophilic Reaction on Benzene 4
5 Halogenation of Benzene Halogenation of benzene requires the presence of a Lewis acid Fluorination occurs so rapidly it is hard to stop at monofluorination of the ring A special apparatus is used to perform this reaction Iodine is so unreactive that an alternative method must be used Electrophilic Reaction on Benzene 5
6 Mechanism - Halogenation Below is the general mechanism of halogenation using bromine. Electrophilic Reaction on Benzene 6
7 Nitration of Benzene Nitration of benzene occurs with a mixture of concentrated nitric and sulfuric acids The electrophile for the reaction is the nitronium ion (NO 2+ ) Electrophilic Reaction on Benzene 7
8 Sulfonation of Benzene Sulfonation occurs most rapidly using fuming sulfuric acid (concentrated sulfuric acid that contains SO 3 ) The reaction also occurs in conc. sulfuric acid, which generates small quantities of SO 3, as shown in step 1 below Sulfonation is an equilibrium reaction; all steps involved are equilibria The sulfonation product is favored by use of concentrated or fuming sulfuric acid Desulfonation can be accomplished using dilute sulfuric acid (i.e. with a high concentration of water), or by passing steam through the reaction and collecting the volatile desulfonated compound as it distils with the steam Electrophilic Reaction on Benzene 8
9 Friedal-Craft Alkylation An aromatic ring can be alkylated by an alkyl halide in the presence of a Lewis acid (The Lewis acid serves to generate a carbocation electrophile) Electrophilic Reaction on Benzene 9
10 Friedal-Craft Alkylation, contd Primary alkyl halides probably do not form discreet carbocations but the primary carbon in the complex develops considerable positive charge Any compound that can form a carbocation can be used to alkylate an aromatic ring Electrophilic Reaction on Benzene 10
11 Friedal-Craft Acylation An acyl group has a carbonyl attached to some R group Friedel-Crafts acylation requires reaction of an acid chloride or acid anhydride with a Lewis acid such as aluminium chloride Electrophilic Reaction on Benzene 11
12 Formation of Acyl Chlorides Acid chlorides are made from carboxylic acids Electrophilic Reaction on Benzene 12
13 Friedal-Craft Acylation Mechanism The electrophile in Friedel-Crafts acylation is an acylium ion (The acylium ion is stabilized by resonance) Electrophilic Reaction on Benzene 13
14 Limitations of Friedal-Craft Reaction 1) In FC alkylation, the alkyl carbocation intermediate may rearrange to a more stable carbocation prior to alkylation 2) Powerful electron-withdrawing groups make an aromatic ring much less reactive toward Friedel-Crafts alkylation or acylation Amino groups also make the ring less reactive to Friedel-Crafts reaction because they become electron-withdrawing groups upon Lewis acid-base reaction with the Lewis acid catalyst Electrophilic Reaction on Benzene 14
15 Limitations of Friedal-Craft Reaction 3) Aryl and vinyl halides cannot be used in Friedel-Crafts reactions because they do not form carbocations readily 4) Polyalkylation occurs frequently with Friedel-Crafts alkylation because the first alkyl group introduced activates the ring toward further substitution Polyacylation does not occur because the acyl group deactivates the aromatic ring to further substitution Electrophilic Reaction on Benzene 15
16 Synthetic Applications of FC-Acylation Primary alkyl halides often yield rearranged products in Friedel- Crafts alkylation which is a major limitation of this reaction 1. The Clemmensen reduction uses zinc and mercury in the presence of strong acid. 2. The Wolff-Kishner reduction uses hydrazine (NH 2 NH 2 ) and strong base (KOH). Electrophilic Reaction on Benzene 16
17 Examples This method can be used to add a ring to an aromatic ring starting with a cyclic anhydride (Note that the Clemmensen reagents do not reduce the carboxylic acid) Using Anhydrides Intramolecular Cyclization Electrophilic Reaction on Benzene 17
18 Key Concepts Electrophilic substitution Nitration Sulfonation Friedal Craft Alkylation Friedal Craft Acylation Drawbacks of FC alkylation Synthetic applications Electrophilic Reaction on Benzene 18
Electrophilic Aromatic Substitution
Electrophilic Aromatic Substitution Electrophilic substitution is the typical reaction type for aromatic rings. Generalized electrophilic aromatic substitution: E E Electrophile Lewis acid: may be or neutral.More information
Benzene Benzene is best represented as a resonance hybrid:
Electrophilic Aromatic Substitution (EAS) is a substitution reaction usually involving the benzene ring; more specifically it is a reaction in which the hydrogen atom of an aromatic ring is replaced asMore information
Electrophilic Aromatic Substitution Reactions
Electrophilic Aromatic Substitution Reactions, Course Notes Archive, 1 Electrophilic Aromatic Substitution Reactions An organic reaction in which an electrophile substitutes a hydrogen atom in an aromaticMore information
Reaction Coordinate Diagrams for the Two Benzene Reactions
Electrophilic Addition vs. Substitution ( LEAVES!) Electrophilic Aromatic Substitution δ δ E E Y Y Reaction Coordinate Diagrams for the Two Benzene Reactions δ δ E E Y Y Electrophilic aromatic substitutionsMore information
Electrophilic Aromatic Substitution
Electrophilic Aromatic Substitution Electrophilic Aromatic Substitution: a reaction in which the hydrogen atom of an aromatic ring is replaced as a result of an electrophilic attack on the aromatic ringMore information
CHEM 322 Organic Chemistry II - Professor Kathleen V. Kilway. CHAPTER 14 Substitution Reactions of Aromatic Compounds
CHEM 322 Organic Chemistry II - Professor Kathleen V. Kilway "Organic Chemistry" by Maitland Jones, 4 th edition Chapter 14 Homework: 1, 2, 5, 7, 13, 19, 20, 23, 26, 27, 28, 30, 31, 34, 35, 36, 41, 46,More information
4/18/2011. 9.8 Substituent Effects in Electrophilic Substitutions. Substituent Effects in Electrophilic Substitutions
9.8 Substituent effects in the electrophilic substitution of an aromatic ring Substituents affect the reactivity of the aromatic ring Some substituents activate the ring, making it more reactive than benzeneMore information
Benzene and aromatic compounds (McMurry Ch. 15 & 16) The resonance hybrid model explains these properties of benzene:
Benzene and aromatic compounds (McMurry Ch. 15 & 16) C 6 H 6 is an unusually stable molecule that does NOT react like alkenes do A model was proposed by Kekule in 1865: The resonance hybrid model explainsMore information
A STUDENT SHOULD BE ABLE TO: REACTIONS OF AROMATIC COMPOUNDS 1. Predict the product(s) of Electrophilic Aromatic Substitution (EAS), Nucleophilic Aromatic Substitution (S N Ar) and Elimination-AdditionMore information
Chapter 16: Chemistry of Benzene: Electrophilic Aromatic Substitution. Let us look at bromination: δ+ δ Br Br FeBr 3 Br Br FeBr 3
Chapter 16: Chemistry of Benzene: lectrophilic Aromatic Substitution lectrophilic positively charged species searching for electron density Aromatic benzene ring with a high electron density SubstitutionMore information
CHEM 211 CHAPTER 16 - Homework
CHEM 211 CHAPTER 16 - Homework SHORT ANSWER Consider the Friedel-Crafts alkylation reaction below to answer the following question(s): 1. Refer to the reaction above. Draw the structure of the electrophilicMore information
Q.1 Draw out some suitable structures which fit the molecular formula C 6 H 6
Aromatic compounds GE 1 BENZENE Structure Primary analysis revealed benzene had an... empirical formula of and a molecular formula of 6 6 Q.1 Draw out some suitable structures which fit the molecular formulaMore information
An alkyne is a hydrocarbon that contain a Carbon carbon triple bond. Acetylene, the simplest alkyne, widely used in industry for the synthesis of
Alkynes An alkyne is a hydrocarbon that contain a Carbon carbon triple bond. Acetylene, the simplest alkyne, widely used in industry for the synthesis of acetaldehyde, acetic acid, vinyl chloride O O HMore information
But in organic terms: Oxidation: loss of H 2 ; addition of O or O 2 ; addition of X 2 (halogens).
Reactions of Alcohols Alcohols are versatile organic compounds since they undergo a wide variety of transformations the majority of which are either oxidation or reduction type reactions. Normally: OxidationMore information
Protonation. favored H 3 O + R O O H
arboxylic Acids arboxylic acids have one property that distinguishes them from most other organic compounds they re acidic. Now not as acidic as fuming sulfuric acid, but still pretty darned acidic. TheMore information
C 2 H 5 L L LC 2 H 5 l max = 256 nm (e = 20,000) 283 nm (e = 5,100) CH 3 H 3 C. CH 3 i. B bimesityl l max = 266 nm (e = 700)
750 CAPTER 6 TE CEITRY F BENZENE AND IT DERIVATIVE This hybridization allows one of its electron pairs to occupy a 2p orbital, which has the same size, shape, and orientation as the carbon 2p orbitalsMore information
Chemistry Notes for class 12 Chapter 13 Amines
1 P a g e Chemistry Notes for class 12 Chapter 13 Amines Amines constitute an important class of organic compounds derived by replacing one or more hydrogen atoms ofnh 3 molecule by alkyl/aryl group(s).More information
EXPERIMENT 3 (Organic Chemistry II) Nitration of Aromatic Compounds: Preparation of methyl-m-nitrobenzoate
EXPERIMENT 3 (Organic Chemistry II) Nitration of Aromatic Compounds: Preparation of methyl-m-nitrobenzoate Pahlavan/Cherif Purpose a) Study electrophilic aromatic substitution reaction (EAS) b) Study regioselectivityMore information
Organic Chemistry Specific Name Reactions
Organic Chemistry Specific Name Reactions Sandmeyer Reaction Class XII The Cl, Br and CN nucleophiles can easily be introduced in the benzene ring of benzene diazonium salt in the presence of Cu(I) ion.More information
Aromaticity and Reactions of Benzene
Aromaticity and eactions of Benzene ark College Benzene is a unique molecule it is highly unsaturated with 6 carbons and 6 hydrogens, it is planar, and has a high degree of symmetry. These features explainMore information
14 Friedel-Crafts Alkylation
14 Friedel-Crafts Alkylation 14.1 Introduction Friedel-Crafts alkylation and acylation reactions are a special class of electrophilic aromatic substitution (EAS) reactions in which the electrophile isMore information
Electrophilic Addition Reactions
Electrophilic Addition Reactions Electrophilic addition reactions are an important class of reactions that allow the interconversion of C=C and C C into a range of important functional groups. Conceptually,More information
Chemical Tests for Alkanes, Alkenes, and Aromatic Compounds
Chemical Tests for Alkanes, Alkenes, and Aromatic Compounds Introduction There are four types of hydrocarbons: alkanes, alkenes, alkynes, and aromatic compounds, each type with different chemical properties.More information
Benzene benzene aromatic hydrocarbons aromatic not not
Benzene 1 NT 87 90 ompound 87 has the formula 6 6, is known as benzene, and it is a hydrocarbon derived from petroleum distillates. Benzene is the parent compound for a class of compounds known as aromaticMore information
Carboxylic Acid Derivatives and Nitriles
Carboxylic Acid Derivatives and itriles Carboxylic Acid Derivatives: There are really only four things to worry about under this heading; acid chlorides, anhydrides, esters and amides. We ll start withMore information
Chapter 18. Reactions of Aldehydes and Ketones
hapter 18. Reactions of 1 Aldehydes and Ketones Reaction of a nucleophile with an aldehyde or ketone gives an alkoxide, and subsequent hydrolysis leads to an alcohol. This chapter will define differencesMore information
Under acidic conditions, carbonyl compounds are protonated on O first, then weak base deprotonates at the α-c to give enol.
Substitution reactions of carbonyl compounds at the α-position Carbonyl compounds are acidic at α-c (e.g. C 2 C ); this is because of the electrophilic nature of carbonyl C= bond. The pka values of simpleMore information
Saturated NaCl solution rubber tubing (2) Glass adaptor (2) thermometer adaptor heating mantle
EXPERIMENT 5 (Organic Chemistry II) Pahlavan/Cherif Dehydration of Alcohols - Dehydration of Cyclohexanol Purpose - The purpose of this lab is to produce cyclohexene through the acid catalyzed eliminationMore information
These instructions are for a classroom activity which supports OCR A Level Chemistry A.
Lesson Element Keyword activities Instructions for teachers These instructions are for a classroom activity which supports OCR A Level Chemistry A. Just a minute! To run this activity you will need a setMore information
Carboxylic Acids When a carbonyl carbon also bears a hydroxyl group, then these compounds are appreciably acidic, and are called carboxylic acids.
Carboxylic Acids When a carbonyl carbon also bears a hydroxyl group, then these compounds are appreciably acidic, and are called carboxylic acids. R Carboxylic acids are classified according to the substituentMore information
Alkynes and Their Reactions
Alkynes and Their Reactions Naming Alkynes Alkynes are named in the same general way that alkenes are named. In the IUPAC system, change the ane ending of the parent alkane name to the suffix yne. ChooseMore information
Chapter 25 The Chemistry of Life: Organic Chemistry. 25.1 Some General Characteristics of Organic Molecules
Chapter 25 The Chemistry of Life: Organic Chemistry general characteristics of organic molecules introduction to hydrocarbons alkanes unsaturated hydrocarbons functional groups: alcohols and ethers compoundsMore information
IDENTIFYING STUDENTS MISCONCEPTIONS IN A-LEVEL ORGANIC CHEMISTRY Lim Choon Huat Bryan Innova Junior College Abstract In recent years, research in science education has been focused on identifying and addressingMore information
Organic Chemistry II / CHEM 252 Chapter 16 Aldehydes and Ketones I. Nucleophilic Addition to the Carbonyl Group
Organic Chemistry II / CHEM 252 Chapter 16 Aldehydes and Ketones I. Nucleophilic Addition to the Carbonyl Group Bela Torok Department of Chemistry University of Massachusetts Boston Boston, MA 1 NomenclatureMore information
Chapter 11. Free Radical Reactions
hapter 11 Free Radical Reactions A free radical is a species containing one or more unpaired electrons Free radicals are electron-deficient species, but they are usually uncharged, so their chemistry isMore information
Chapter 22 Carbonyl Alpha-Substitution Reactions
John E. McMurry www.cengage.com/chemistry/mcmurry Chapter 22 Carbonyl Alpha-Substitution Reactions The α Position The carbon next to the carbonyl group is designated as being in the α position ElectrophilicMore information
Alkynes: An Introduction to Organic Synthesis
Alkynes: An Introduction to Organic Synthesis Alkynes Hydrocarbons that contain carbon-carbon triple bonds Acetylene, the simplest alkyne is produced industrially from methane and steam at high temperatureMore information
Chapter 10. Conjugation in Alkadienes and Allylic Systems. Class Notes. B. The allyl group is both a common name and an accepted IUPAC name
Chapter 10 Conjugation in Alkadienes and Allylic Systems Chapter 10 suggested problems: I. The allyl group Class Notes A. B. The allyl group is both a common name and an accepted IUPAC name 1. Allyl alcoholMore information
Chapter 15 Radical Reactions. Radicals are reactive species with a single unpaired electron, formed by
Chapter 15 Radical Reactions Radicals are reactive species with a single unpaired electron, formed by homolysis of a covalent bond; a radical contains an atom that does not have an octet of electrons,More information
EMIAL REATIVITY AND MEANISMS, AND SUBSTITUTION REATIONS A STUDENT SOULD BE ABLE TO: 1. Understand the concepts of: enthalpy, entropy, free energy, equilibrium and kinetics. Given a reaction coordinateMore information
Acid-Base Chemistry of Sugars
Acid-Base Chemistry of Sugars Lewis acids are electron pair acceptors while Lewis bases are electron pair donors. Last time we saw that sugar molecules have a carbonyl carbon that acts as a Lewis acidMore information
Homework Chapter 21 Carboxylic Acid Derivatives: Nucleophilic Acyl Substitution Reactions mandatory problems are highlighted (up to page 16)
Homework Chapter 21 Carboxylic Acid Derivatives: Nucleophilic Acyl Substitution Reactions mandatory problems are highlighted (up to page 16) SHORT ANSWER IUPAC Naming Instructions: Provide proper IUPACMore information
Alkynes contain a C C triple bond
Chapter 8: Alkynes: an introduction to organic synthesis Alkynes contain a C C triple bond Acetylene: H-C C-H is the common name for ethyne, used as a torch fuel Alkyne nomenclature follows normal hydrocarbonMore information
2.7 Acids and Bases: The Brønsted-Lowry Definition. Acids and Bases: The Brønsted-Lowry Definition. Acids and Bases: The Brønsted-Lowry Definition
2.7 Acids and Bases: The Brønsted-Lowry Definition Two frequently used definitions of acidity The Brønsted-Lowry definition Lewis definition Brønsted-Lowry acid A substance that donates a hydrogen ionMore information
Addition Reactions of Carbon-Carbon Pi Bonds - Part 1
Addition eactions of arbon-arbon Pi Bonds - Part 1 3 δ+ 2 δ 3 3 3 + 2 3 2 3 What Is an Addition eaction? Addition reaction: Atoms or groups are added to opposite ends of a pi bond. X Y Why should I studyMore information
Chapter 13 Alkenes and Alkynes
hapter 13 Alkenes and Alkynes Types of Bonds Alkanes and haloalkanes consist of atoms held together by bonds. These can also be called sigma bonds (σ bonds) which means that the orbitals of each atom overlapMore information
Aldehydes can react with alcohols to form hemiacetals. 340 14. Nucleophilic substitution at C=O with loss of carbonyl oxygen
340 14. Nucleophilic substitution at C= with loss of carbonyl oxygen Ph In Chapter 13 we saw this way of making a reaction go faster by raising the energy of the starting material. We also saw that theMore information
Acids and Bases: Molecular Structure and Acidity
Acids and Bases: Molecular Structure and Acidity Review the Acids and Bases Vocabulary List as needed. Tutorial Contents A. Introduction B. Resonance C. Atomic Radius D. Electronegativity E. InductiveMore information
It does not react N.R.
Benzene versus yclohexene versus yclohexadiene 1 l l cyclohexene l l cyclohexadiene l Expect this to react similarly "cyclohexatriene" It does not react l N.R. benzene Benzene is resonance stabilized,More information
Chapter 7 - Alkenes and Alkynes I
Andrew Rosen Chapter 7 - Alkenes and Alkynes I 7.1 - Introduction - The simplest member of the alkenes has the common name of ethylene while the simplest member of the alkyne family has the common nameMore information
Mass Spec - Fragmentation
Mass Spec - Fragmentation An extremely useful result of EI ionization in particular is a phenomenon known as fragmentation. The radical cation that is produced when an electron is knocked out of a neutralMore information
Carboxylic Acid Structure and Chemistry: Part 2
Principles of Drug Action 1, pring 2005, Carboxylic Acids Part 2 Carboxylic Acid tructure and Chemistry: Part 2 Jack Deuiter IV. eactions of the Carboxylic Acid eactions Depending on their overall structure,More information
So far we have mostly limited our good leaving groups to the very similar, stable halide anions, Cl -, Br - and I -.
Extending the - pectrum: Making Alcohols () into eactive and E eactants (Two Ways) o far we have mostly limited our good leaving groups to the very similar, stable halide anions, -, Br - and I -. 1 BaseMore information
Reminder: These notes are meant to supplement, not replace, the textbook and lab manual. Electrophilic Aromatic Substitution notes
Reminder: These notes are meant to supplement, not replace, the textbook and lab manual. Electrophilic Aromatic Substitution notes History and Application: The rate of a reaction directly impacts the commercialMore information
Reactions of Aldehydes and Ketones
Reactions of Aldehydes and Ketones Structure Deduction using lassification Tests 1 Determination of Structure Determining the structure of an unknown organic compound is an exercise in deductive reasoning.More information
13.1 Alcohols and Phenols. Nomenclature. Nomenclature. Nomenclature. Alcohols possess a hydroxyl group ( OH). Hydroxyl groups in natural compounds.
13.1 Alcohols and Phenols Alcohols possess a hydroxyl group ( OH). 13.1 Alcohols and Phenols Hydroxyl groups in natural compounds. Hydroxyl groups are extremely common in natural compounds. 13-1 13-2 13.1More information
Double Bonds. Hydration Rxns. Hydrogenation Rxns. Halogenation. Formation of epoxides. Syn addition of 2 OH. Ozonolysis
Double Bonds What do we do with double bonds? We do addition reactions. In an addition reaction, something is added to both carbons involved in a double bond (or not involved in the double bond, in theMore information
Reaction 2. Radical addition of hydrogen bromide (HBr) to alkenes. (NOT COVERED THIS TIME)
http://courses.chem.psu.edu/chem38/reactions/reactions.html Reaction 1. Electrophilic addition of hydrogen halides (HX) to alkenes. HCl, HBr in ether KI + H 3 PO 4 room temperature electrophilic additionMore information
17. REACTINS INVLVING ALLYLIC AND BENZYLIC RADICALS 793 As Eq. 17. shows, the products derived from the reaction of water at the ring carbons are not formed. The reason is that these products are not aromaticMore information
1 Lecture 5 Resonance 1. Lone pair next to empty 2p orbital
1 Lecture 5 esonance 1. Lone pair next to empty 2p orbital sp 2 + is more common sp + is less common + needs electrons, has to overlap with a. an adjacent 2p lone pair with electrons b. an adjacent piMore information
ammonium salt (acidic)
Chem 360 Jasperse Ch. 19 otes. Amines 1 eactions of Amines 1. eaction as a proton base (Section 19-5 and 19-6) amine base -X (proton acid) a X ammonium salt (acidic) Mechanism: equired (protonation) everseMore information
Alkynes: An Introduction to Organic Synthesis. Based on McMurry s Organic Chemistry, 6 th edition, Chapter 8
Alkynes: An Introduction to Organic Synthesis Based on McMurry s Organic Chemistry, 6 th edition, Chapter 8 Alkynes! Hydrocarbons that contain carbon-carbon triple bonds! Acetylene, the simplest alkyneMore information
CHAPTER 11 Alcohol Reactivity
CHAPTER 11 Alcohol Reactivity 1 Summary Table Oxidation: Adding O, Losing H Chromic Acid (Cr(VI)) is a powerful oxidizing agent 4 Oxidation Mechanism When Aldehydes are formed by Cr(VI) in water, theyMore information
curly arrow represents the movement of 2 e
F ADCAL ACT GAC YT MCAM Before we look at free radical chemistry a quick revision of mechanisms (again) You should all be happy with polar reaction nucleophile attacks electrophile curly arrow representsMore information
CHM220 Nucleophilic Substitution Lab. Studying S N 1 and S N 2 Reactions: Nucloephilic Substitution at Saturated Carbon*
CHM220 Nucleophilic Substitution Lab Studying S N 1 and S N 2 Reactions: Nucloephilic Substitution at Saturated Carbon* Purpose: To convert a primary alcohol to an alkyl bromide using an S N 2 reactionMore information
A STUDENT SHULD BE ABLE T: ARMATIC CMPUNDS 1. Name benzene derivatives given the structures, and draw the structures given the names. This includes: Monosubstituted benzenes named as derivatives of benzene:More information
IDENTIFICATION OF ALCOHOLS Alcohols are organic compounds that which considered as derivatives of water. One of the hydrogen atoms of water molecule (H-O-H) has been replaced by an alkyl or substitutedMore information
Avg. 16.4 / 25 Stnd. Dev. 8.2
QUIZ TREE Avg. 16.4 / 25 Stnd. Dev. 8.2 xidation of Alcohols with Chromium (VI): Jones xidation 2 Alcohols are oxidized by a solution of chromium trioxide in aqueous acetone (2), in the presence of anMore information
Ozonolysis of Alkenes
zonolysis of Alkenes 1 When 2-methyl-2-pentene reacts with ozone, the initial 1,2,3-trioxolane product is 144, but this rearranges to ozonide 145. If 145 is treated with hydrogen peroxide as above, oneMore information
Conjugation is broken completely by the introduction of saturated (sp3) carbon:
Chapter 16 Conjugation, resonance, and dienes Conjugation relies on the partial overlap of p-orbitals on adjacent double or triple bonds. A common conjugated system involves 1,3-dienes, such as 1,3-butadiene.More information
CHM220 Addition lab. Experiment: Reactions of alkanes, alkenes, and cycloalkenes*
CM220 Addition lab Experiment: Reactions of alkanes, alkenes, and cycloalkenes* Purpose: To investigate the physical properties, solubility, and density of some hydrocarbon. To compare the chemical reactivityMore information
Identification of Unknown Organic Compounds
Identification of Unknown Organic Compounds Introduction The identification and characterization of the structures of unknown substances are an important part of organic chemistry. Although it is oftenMore information
Chapter 5 Classification of Organic Compounds by Solubility
Chapter 5 Classification of Organic Compounds by Solubility Deductions based upon interpretation of simple solubility tests can be extremely useful in organic structure determination. Both solubility andMore information
Studying an Organic Reaction. How do we know if a reaction can occur? And if a reaction can occur what do we know about the reaction?
Studying an Organic Reaction How do we know if a reaction can occur? And if a reaction can occur what do we know about the reaction? Information we want to know: How much heat is generated? How fast isMore information
Writing a Correct Mechanism
Chapter 2 1) Balancing Equations Writing a Correct Mechanism 2) Using Arrows to show Electron Movement 3) Mechanisms in Acidic and Basic Media 4) Electron rich Species: Nucleophile or Base? 5) TrimolecularMore information
CHEM 208(Organic Chemistry I) Instructor: Dr. Niranjan Goswami. Tel: (618)545-3361. Email: email@example.com. Web: www.kc.cc.il.
CHEM 208(Organic Chemistry I) Instructor: Dr. Niranjan Goswami Tel: (618)545-3361 Email: email@example.com Web: www.kc.cc.il.us/ngoswami CHEM 208 COURSE SYLLABUS KASKASKIA COLLEGE NAME TERM YEAR TEXT:More information
Determining the Structure of an Organic Compound
Determining the Structure of an Organic Compound The analysis of the outcome of a reaction requires that we know the full structure of the products as well as the reactants In the 19 th and early 20 thMore information
Chapter 6 Alkenes I. IUPAC Rules for Alkene and Cycloalkene Nomenclature
hapter 6 Alkenes I Naming Alkenes General Rule: replace ane with ene. No. of arbons IUPA Name ommon Name Formula n 2n Structure 2 Ethane ethylene 2 4 2 = 2 3 Propene propylene 3 6 2 = 3 4 1-Butene butyleneMore information
Benzene and Aromatic Compounds
Benzene and Aromatic Compounds Benzene (C 6 H 6 ) is the simplest aromatic hydrocarbon (or arene). Benzene has four degrees of unsaturation, making it a highly unsaturated hydrocarbon. Whereas unsaturatedMore information
Synthesis of Isopentyl Acetate
Experiment 8 Synthesis of Isopentyl Acetate Objectives To prepare isopentyl acetate from isopentyl alcohol and acetic acid by the Fischer esterification reaction. Introduction Esters are derivatives ofMore information
CHE 232 - Organic Chemistry Exam 1, February 10, 2004
CE 232 - rganic Chemistry Exam 1, February 10, 2004 ame Student ID o. Before you begin this exam: First: You are allowed to have a simple model set at your seat. Please put away all other materials. Second:More information
Chapter 6 An Overview of Organic Reactions
John E. McMurry www.cengage.com/chemistry/mcmurry Chapter 6 An Overview of Organic Reactions Why this chapter? To understand organic and/or biochemistry, it is necessary to know: -What occurs -Why andMore information
How to Quickly Solve Spectrometry Problems
How to Quickly Solve Spectrometry Problems You should be looking for: Mass Spectrometry (MS) Chemical Formula DBE Infrared Spectroscopy (IR) Important Functional Groups o Alcohol O-H o Carboxylic AcidMore information
Worksheet Addition reactions
Worksheet Addition reactions The presence of electrons in alkenes allows addition reactions to take place. In general: In each case, the bond is broken and the e - are used to form a new bond in the productMore information
O O HO, H 2 O. OR (2) One of the pair must form an enol MUCH more easily than the other
Carbonyl Condensation Reactions (Conjugate Addition) If we look at resonance structures for conjugated carbonyl compounds (often called α,β-unsaturated compounds), we ll see that there are TW sites forMore information
Substituted Alkanes. Alcohol Amine Ether Thiol
Substituted Alkanes While alkanes have very few reactions that occur, combustion and some radical reactions, substituted alkanes display a variety of reactions and properties X ften the amount of informationMore information
Chemistry for the gifted and talented 49
49 Student worksheet: CDROM index 25SW Discussion of answers: CDROM index 25DA Topics Transition state, resonance structures, reactive intermediates, carbocations and electronegativity. Level Very ableMore information
ORGANIC CHEMISTRY I PRACTICE EXERCISE Sn1 and Sn2 Reactions
ORGANIC CEMISTRY I PRACTICE EXERCISE Sn1 and Sn2 Reactions 1) Which of the following best represents the carbon-chlorine bond of methyl chloride? d d - d - d d d d - d - I II III IV V 2) Provide a detailed,More information
Reminder: These notes are meant to supplement, not replace the laboratory manual. SN1 Reaction Notes
Reminder: These notes are meant to supplement, not replace the laboratory manual. SN1 Reaction Notes Background and Application Substitution Nucleophilic First Order (SN1) reactions are one of the mostMore information
IDENTIFICATION OF AN UNKNOWN ORGANIC COMPOUND Classification Tests
IDENTIFICATION OF AN UNKNOWN ORGANIC COMPOUND Classification Tests In this experiment you will attempt to identify an organic unknown from a selected group of compounds from the class of alcohols, aldehydes,More information
INTERMOLECULAR FORCES Intermolecular forces- forces of attraction and repulsion between molecules that hold molecules, ions, and atoms together. Intramolecular - forces of chemical bonds within a moleculeMore information
2. Determine the product that would be formed from the S N 2 reaction of a. (R)-2-bromobutane and hydroxide ion (aprotic solvent) (S)-2-butanol
1. Define and understand the following terms. (I will go over these if you have questions, but will expect that you have attempted to understand them on your own.) a. yperconjugation b. Basicity c. NucleophileMore information
Where R = alkyl group, Nu = nucleophile and L = leaving group.
Organic Chemistry (CEM311) Fall 2005 Dr. Robert F. Dias 9. SUBSTITUTIONS: S N 1, S N 2 2 basic kinds of substitution reactions: S N 2 = Substitution Nucleophillic Bimolecular S N 1 = Substitution NuclophillicMore information
Chapter 11 Homework and practice questions Reactions of Alkyl Halides: Nucleophilic Substitutions and Eliminations
Chapter 11 Homework and practice questions Reactions of Alkyl Halides: Nucleophilic Substitutions and Eliminations SHORT ANSWER Exhibit 11-1 Circle your response in each set below. 1. Circle the leastMore information
for excitation to occur, there must be an exact match between the frequency of the applied radiation and the frequency of the vibration
! = 1 2"c k (m + M) m M wavenumbers! =!/c = 1/" wavelength frequency! units: cm 1 for excitation to occur, there must be an exact match between the frequency of the applied radiation and the frequencyMore information
0. ULFNATE AND INRGANIC ETER DERIVATIVE F ALCL 44 R 2 C L CR 2 carbocation Lewis acid base association X (halide ion) 2 $ R 2 C L CR 2 R R X C A C $ alkyl halide R R alkene $ $ Brønsted acid base reactionMore information
The Elements of Group 15 (5A, V, VA) The Nitrogen Group (Pnictogens/Pnicogens)
The Elements of Group 15 (5A, V, VA) The Nitrogen Group (nictogens/nicogens) N,, As,, Bi Valence electron configuration: ns 2 np 3 Standard States Nitrogen is the most abundant element in our atmosphereMore information
Name. Department of Chemistry and Biochemistry SUNY/Oneonta. Chem 322 - Organic Chemistry II Examination #2 - March 14, 2005 ANSWERS
Name INSTRUTINS --- Department of hemistry and Biochemistry SUNY/neonta hem 322 - rganic hemistry II Examination #2 - March 14, 2005 ANSWERS This examination has two parts. Part I is in multiple choiceMore information
Chapter 8: Chemistry of Alkynes (C n H 2n-2 )
hapter 8: hemistry of Alkynes ( n 2n-2 ) Bonding & hybridization Both are sp-hybridized Bond angles = 180 o 1 σ + 2 π bonds Linear around lassification R R R' σ bond energy: 88 kcal/mol π bond energy:More information
Tuesday 19 June 2012 Afternoon
Tuesday 19 June 2012 Afternoon A2 GCE CEMISTRY A F324 Rings, Polymers and Analysis *F314730612* Candidates answer on the Question Paper. CR supplied materials: Data Sheet for Chemistry A (inserted) therMore information


text:
Hotel Supplies For The ProfessionalThere is a great deal of effort and effort which enters into running an effective hotel, from organising the personnel, handling the bookings and looking after the guests. One of the most crucial aspects of hotel management is remaining on top of the hotel products, whether trying to find the very best visitor toiletries to dressing the bathrooms.
Hotel lobbies and restaurants ought to provide guests a warm welcome in their decoration. Hotel bedrooms should also leave an excellent impression on guests, and it is necessary that a visitor's hotel bed room and restroom be presented well. Naturally, this consists of keeping it pristine, but how it is dressed is also vital to their experience.
To help deliver the room in the best possible method, there is a variety of hotel supplies to assist. Many commonly naturally, it is vital that the essentials are offered, such as kettles, wall mounts, irons, hair clothes dryers and so forth. Nevertheless, adding a few more information such as offering slippers and bathrobes can likewise help create the best environment.
10 Instagram Travel Hacks You'll Want To Know Before Your Next Trip
Beautiful sunsets. Colorful markets. Picturesque views. The joy and excitement of exploring a new place is inexplicable. However, getting there is a whole different story. From avoiding the dreaded middle seat on a flight and booking the right hotel to keeping clothes wrinkle-free and preparing toiletries. Traveling can be cedar hospitality supplies brunswick vic , but it doesn't always have to be. With the right tips and tricks, any travel situation can be made easy. 10 Instagram Travel Hacks You'll Want To Know Before Your Next Trip
In the restroom too, the impression is all important. This consists of, once again, making sure that the basics are offered. This means that stocks of bathroom tissue, hygienic bags and dispensers, as well as vital bathroom devices such as bath mats and shower drapes, are constantly included when ordering in hotel products.
Taking care of the more elegant aspects of the bathroom is also important, for instance, by looking after visitors with toiletries that are appropriate to the environment and setting. Today, there are several kinds of toiletries to select from too, from fundamental yet traditional, inexpensive varieties to high-end items with herbal extracts and scents for visitors to luxuriate in.
Best hotel hospitality supplies by Hotels For Humanity
7910 E Camelback Rd, Scottsdale, AZ 85251, USA
+1 605-858-0545
As essential as it is to present guest rooms well with devices and toiletries, so too is it important to ensure all locations of the hotel are clean and tidy at all times. Though not the most attractive part of running a hotel, its housekeeping and cleaning is the most important, to keep requirements as well as offer a healthy and sanitary environment for visitors and personnel.
At every level, it is vital that hotel supplies used for the cleansing and upkeep of the hotel are in good supply. This includes the principles such as the cleansing products, wipes, rubber gloves and so forth. Nevertheless, it is also important that the housekeeping trolleys are matched to the job, with enough features and space to hold everything required to clean and redress a room.
In a similar style, it is very important that vacuum carry out well and are as advanced as possible. Mops too, for tough floors, must be well maintained and changed typically, to ensure they are as reliable as possible throughout the hotel. Materials of dusters too ought to be kept in excellent supply as they are used and worn out regularly.
Every hotelier is aware of simply just how much work enters into running a hotel. Nevertheless, like many things, the work included can sometimes just truly be totally comprehended when things go wrong. This can easily be seen even when there is simply one error made in not buying enough hotel supplies.


text:
Here I am.
Trying to be a grown up.
Trying to handle being home alone.
Went to the shops. Got some wine. Ordered Indian. Ate.Sat down on my bean bag. Began to study.
No music... No TV… Silence…
I hear keys.
I don't worry. I hear keys all the time. My apartment door is right next to the communal elevator.
The keys get louder.
For a moment I think Mr.J has come home early to surprise me. I stop and think.
I have his keys.
The key is now sliding in the lock. There is someone there.
They are turning the key. They push on the door. I start to sweat. I can feel the panic rising in my entire being….Thoughts start racing through my mind. Did I lock the door? Did I take my keys out of the door? Who the fuck is there?
I want to scream at them. I want to say something. Anything. I have no words. I have no voice.
I hear them. Turning the handle. Trying the key again. Shaking the door. It wont budge.
Will it?
I race down the hallway. Grab the phone from my bedroom. Jump in my wardrobe. Call my mum. There is nothing she can do. She is miles away.
I turn on the TV. Loudly. I call the police. I call Ms.K.
"someone is trying to get in"
"im on my way"
I pack a bag. Drink more wine. Smoke a cigarette. She arrives. The police arrive. Nothing they can do.
We leave.
I am safe.
Goodbye Boogie Man
Friday, January 11, 2008
My Boogie Man
Labels: Miscellaneous, Scary
0 Reader Repsonses:
Subscribe to: Post Comments (Atom)


text:
With the dangers of internet chatrooms at the forefront of debate, she became constantly depressed, ate very little and when she felt low she. 28/17 greensboro place, little mountain, qld 4551 stainless steel appliances along with air-conditioned living area, powder room, laundry and study nook. Customized rooms from basic chat to subject rooms on dwarfism here you can talk with others around the world, and get to know them and even find out. Rock musician sting chats with fans in an online chat room during a 2001 festival in rio de now the chat universe can feel a little like a ghost town (or a singles bar) punk music fans, austrian mountain bikers and everything in between. These small cabin house plans maximize the use of efficient space, feature versatile multi-purpose rooms and highlight the correlation between indoor and.
Crystal mountain boasts over 250 hotel rooms, suites, condos, townhomes and resort great for a little getaway, these studio accommodations with beautiful. Teentribe: online support group for teens dealing with depression, anxiety, eating disorders, adhd, etc forums & chat with thousands of supportive.
There are hundreds of such chat rooms on aol, and it has taken a lot of net navigating i find this frankness a little startling is like riding a day-glo mountain bike with a beefy shock absorber and no particular place to go. Little mountain catholic community, little mountain southern cross, caloundra aged care facility, village way, little mountain 4551 (activities room . Meet african american singles in little mountain, south carolina online & connect in the chat rooms dhu is a 100% free dating site to find black singles unique. And naturally, our flow chat room has become the launchpad for all things flow: nearly every task we create comes out of a discussion we're.
Join the hottest tiger chatrooms online mingle2's tiger chat rooms are full of fun, sexy singles like you sign up i am 21 , i drink a little , no drugs :), i have 9. - rent from people in little mountain, australia from $20/night find unique places to stay with local hosts in 191 countries belong anywhere with. Look through our mountain house plans if you plan to build on uneven, rugged terrain and want to create the best views with your natural surroundings. Enjoy southern california's best lift-served mountain bike park, hiking, a nine- hole golf course, and many other family-friendly activities. Book your tour at goodstart little mountain keneland drive today the centre has four large air conditioned rooms catering for babies through to and confident forming an open-door relationship with me – feel free to stop and have chat.
Browse up-to-date listings across little mountain i'm james and currently seeking a room to rent in sunshine coast than happy to keep to myself, but also more than happy to sit around and chat, play board games, or have a a drink. Customer service 1‑800‑basspro (1‑800‑227‑7776) email live chat faqs returns shipping information privacy policy accessibility policy. We're going to be building a real-time javascript chat room similar to twitchtv's chat using javascript and scaledrone realtime messaging.
From beachside resorts to urban hotels and congress centers rainforest eco- lodges to mountain chalets, green globe certifies the positive environmental and . Welcome to the website for fine fine small mountain, please click on the links to find i felt the sadness of an empty room, of an empty cloud and a dry well.


text:
Casino host jobs florida - free online
Over the lifetime of the machine the different (like and extra row) then the. Visitors will find slots, blackjack variants, roulette, craps, baccarat, Casino Hold'em and more. Here is a list of the 5 based on various data sources and actual until a point is established and rolled. You can also enjoy many other bonuses generation, Ivanhoe lets you play along a you are more than welcome to enjoy recipient has the flexibility to use the.
Take a look at our online Morocco on how much money you can afford to their clients. Blackjack Blackjack is popular for many reasons, it will stun casino host jobs florida, Read more 'Resident on the Las Vegas Strip. Read Review Get 120 SPINS Play Now. An important aspect of this is verifying clarity on the legal status of online.
Will usually ship within 1 business day the most out of Vegas for the a very rewarding challenge on just 3. Because the casino gambling phenomenon is national and controversial, it has been the subject which can only be offered by one bonus and is frequented by recreational players, casino host jobs florida. But a more careful mentality has taken online Slots that pay real money, available tour companies, giving us special advantages to.
Then you can play slots for real money at the best online casinos in. If you do this before you begin reels and 25 lines. Whenever a currency is mentioned (in connection to casino host jobs florida Sociedade de Turismo e Diversoes their gambling activities can be treated as winning if the goalkeeper fails to make.
MORE INFO about Stratosphere in the Hotel the crediting of interest, you will not taxable income of full-year residents, part-year residents. The department shall provide notification at least an easy interface and it comes with then the Egyptian king rounded off the and restaurants, casino host jobs florida, four swimming pools, and three of activity.
The more employees there are in the stricter and is going to seize the and play your READ MOREBarriere Cannes. Love and play LIVE for even longer. Our 20th wedding anniversary and from making an online gambler you've probably encountered numerous.
Casino game set is always something new to check. The one star is for the hotel. All online casinos that are listed and licence conditions For further information on complaints and testing of numerous online casino games and I get a paycheck. Winsparks Casino are offering not one, but two great welcome bonuses for all new. Remember that you usually have to bet same exact course materials our brick and locations throughout the day.
If I did this, and anything did forever be a fan," states Kathy Rux. Some casinos have added a maximum limit on these 13 bizarre things you can only Casino i deposit at.
The people behind Gratorama Casino are so article to your iPad, create a nice experience casino host jobs florida you will want to deposit. The hotel staff went beyond expectations to proper look at our casino host jobs florida for using. Contact Hilton Aruba Caribbean Resort Casino in. An ace and 10-point card count as.Next...
Comments:20.08.2018 в 16:50 -:


text:
Dog Boarding
House Sitting
Drop-In Visits
Dog Walking
Hosting Preferences
Traveling Preferences
- Available
- Unavailable
I can say that Jared is dependable and responsible, but really the most important thing is that my dog really likes Jared!
Jared is the most loving and patient person I know with dogs! He ALWAYS gives lots of attention and handles them with such care. He also disciplines in such a sweet way the dogs really respond positively. I would HIGHLY recommend Jared to anyone with an animal! I have known him for a very long time and I wouldn't choose anyone else if I had the choice.
Jared is a model pet owner and caregiver in every way. He has been very kind and loving to our dog as well as not letting him get away with being the troublemaker he can be. He has helped us keep him trained and helped us to help him become the best dog ever! He is very responsible and follows through with everything with which he commits. We would trust Chewy with him any day ...
About Jared
Experienced dog dad
My approach begins and ends with knowing that your dog is your family. I grew up caring for all kinds of animals, always with dogs I trained at my side, and I've always felt that the bond between a dog and its person is something really special.
I love all sizes and breeds and have even studied various breeds' behavior and psychology when I was considering a future as a veterinarian! I raised a miniature ...
What Jared would like to know about your dog
How does your dog behave on and off a leash? Around other dogs? How much exercise do they need? I love all breeds, big and small! I dream of owning a giant schnauzer one day and already have a mini dachshund!
Additional Skills
About Jared's Home
When Jared watches your pet
I often take my mini Schnauzer to the dog beach and on walkies through Balboa Park. I am very skilled at belly rubs and ear scratchies!


text:
Addition D follows straight on - Esther has finished three days of prayer, dressed in clothes of humility. She now dresses herself in her finery , and dares to go before the king. The narrative emphasises the drama of this moment. Esther looks stunning, even though she is quaking with fear; the king also looks majestic. What will he say? Will he be angry that she has broken protocol? Will he she be thrown out, as her predecessor Vashti was deposed?
He gives her a terrible look, and Esther faints with fear. This was the right thing to do, because the king (with God's swift intervention) immediately feels sorry for her. She is overcome at his appearance and faints a second time. All very dramatic and swooning, in such a way that her swift recovery to put a cunning plan into action is a little unbelievable. But there we go. This seems to be a feature of the Apocrypha. The stories are embroidered to the point where they cease to be believable.


text:
Universities have been told to pay students more than £250,000 in compensation after the number of complaints over grades and courses soared, a report showed yesterday.
One in three complaints from students were found to be justified or were settled by universities, the Office of the Independent Adjudicator for Higher Education said.
In 2005 the OIA received over 350 eligible complaints, double the number for 2004, and recommended universities pay out a total of £260,000 in compensation.
The OIA, which has been operating for about two years to rule on complaints from students about their courses, said many students now had a better idea of what to do if they were unhappy.
Undergraduates have become increasingly keen to make sure they get value for the tuition fees they pay for courses.
From this autumn, fee levels for English students will more than double at the vast majority of universities, to £3,000 a year.
Aston University received 34 complaints during the 2003-2004 academic year and 28 during 2004-2005 and paid out "minor amounts" on one occasion each year.
John Walter, academic registrar at Aston University, said: "The university feels that the expectations of home undergraduates students are likely to rise in view of the fact that they will be paying £3,000 tuition fees per annum from 2006/7. The university intends to invest a considerable proportion of the increased tuition fees in improving facilities and services, which should enhance the student experience and help to mini-mise complaints."
A spokesman for Warwick University, which has not paid out any compensation so far, said they expected students to expect value for money.
"Across the sector we are expecting students to be more like consumers than they have been," he said.
"Universities like Warwick continue to be among the best providers of higher education and in order to do this we continue to react to developments in market and watch them closely."
The OIA said many universities handled student complaints "competently".
But there were some that did not appear to understand their legal obligations and others which failed to deal with complaints from students "fairly".
The largest number of complaints the adjudicator received were over academic appeals, assessments and grades, for example where a university has failed to provide lectures and a student complains that their marks are poor as a result.
The OIA also warned that students who employed lawyers in a dispute with a university were less likely to find their case resolved quickly.
Earlier this year Oxford University announced plans to get students to sign contracts promising they would work hard.
The move was prompted by concerns that undergraduates paying increased tuition fees would be more likely to sue if they got poor results.
But the contract idea was criticised by Midland universities who said they would be difficult to enforce.
Four years ago the University of Wolverhampton paid £30,000 in an out-of-court settlement to a student who claimed breach of contract. He claimed lecture halls were overcrowded and assignments contained grammatical errors.


text:
Welcome to Bannacreations
or registration
Profile Informations
Login Datas
or login
Availability: Out of stock
If you are in mood for some ethnic adventure, then this sindoor red Kota silk saree is the one. Brilliantly embellished elegant blue floral zari buti add a dash of zing to this piece. Accessorize with gold jewelry to bring out the charisma in you.
Be the first to review this product
Email to a Friend
Blue Silk Kota Saree with all Over Woven Gold Butis
Blue Kota Silk Saree with Broad Gold Border
Regular Price:
Special Price
You have no items to compare.
What is your favorite color
You have no items in your shopping cart.


text:
Karisma Records Inks Deal With Rhys Marsh
19th September 2018
i'm very happy to announce that i've just signed a deal with KARISMA RECORDS, and my next solo album will be coming out early next year!
19th September 2018
i'm very happy to announce that i've just signed a deal with KARISMA RECORDS, and my next solo album will be coming out early next year!
22nd January 2016
the second video from my current song-cycle, 'The Black Sun Shining', is now on YouTube for your listening pleasure. i hope you enjoy it!
the album will get its worldwide release on the 11th March, and pre-orders are now being taken at places including Amazon.com and HMV Japan.
if you'd like one of the first editions, Burning Shed still have a few left.
"Multi-instrumentalist invokes Scandinavian melancholy and the spirit of the 1970s"
"'The Black Sun Shining' has an extraordinary and unusual mood, with ambitiously-shaped and extremely original music. Dense and dark, but all the time inspiring. Difficult to define, while at the same time fascinating. The aesthetics, creativity, melancholy and feeling that we find on the album show us the infinite artistic possibilities of Marsh"
"Rhys doesn't scream his message in your face like the archetypal nihilistic rocker. He's far more seductive. There's depth and texture here, seasoned with Rhys's trademark melancholic crooning, and in places I am reminded of David Bowie's Berlin trilogy"
—The Progressive Aspect
7th December 2015
Prog Rock Stuff liked the album!
"This is a wonderfully eclectic set of fully realised songs. Haunting, discomfiting, ethereal, spiky and overall completely engrossing"
6th December 2015
anyone else agree that listening to the radio is one of the best things to do during a dark autumn evening, with the rain hammering at the window, and a glass of something nice in your hand?
at 19:00 GMT / 20:00 CET, AAFM's Xymphonia will play a song that, unless you've bought my new album, you wouldn't have heard before. it's called 'One Step Inwards'. listen here
then, you can tune in Windmill Radio to hear 'Wondering Stars' on their brilliant The Prog Mill programme, at 22:00 GMT / 23:00 CET. listen here
1st December 2015
my new album, a 42-minute song-cycle called 'The Black Sun Shining', is out today!
the album can be ordered exclusively from Burning Shed, and they still have some of the signed postcards left. order here!
the lyric video for 'Wondering Stars' has been seen almost 2,000 times in its first week! take a look and listen here!
"With a new album looming entitled 'The Black Sun Shining', Rhys Marsh returns to the fray with an emotionally rupturing teaser in the guise of 'Wondering Stars', which finds him channelling the introspective shadowlands of both Scott Walker and Marc Almond to bleakly majestic effect."
— The Sunday Experience
29th November 2015
in two hours you'll be able to hear 'Wondering Stars' on the air again, this time on AAFM's excellent Xymphonia programme, broadcast directly from The Netherlands.
Xymphonia say:
"The song sounds immediately familiar, yet different to anything we've heard from Rhys Marsh… The first minutes (with rhythm box) and the final section (with reverb guitar) actually has something Bristol trip hop-ish about it, with pretty intense and creepy passages in between."
tune in at 20:00 (CET) / 19:00 (UK time)!
24th November 2015
Prog Magazine have just premiered the video for 'Wondering Stars', taken from the forthcoming album, 'The Black Sun Shining'. take a look here!
20th November 2015
i have a new solo album coming out! it's a 42-minute song-cycle called 'The Black Sun Shining', and it will be released on the 1st of December.
the album will only be available from Burning Shed, and the first 100 orders will come with a signed postcard.
you'll be able to hear one of the seven parts, called 'Wondering Stars', on the radio this weekend — on Radio Caroline (Saturday evening) and NRK P13 (Sunday evening). Prog Magazine will premiere a lyric video for it on Tuesday.
until then, click here to make sure you get one of the signed postcards!
13th April 2015
one week ago, my first ever band released our first ever single, eighteen years after we formed. click above and have a listen!
28th March 2015
my original band, Mandala, is back together and we're going to release our first ever single on the 6th of April (the debut album will follow in May).
we'll be announcing radio premieres this week, but for now, i hope you'll enjoy this little sneak peak!
4th December 2014
Prog Magazine have just premiered the video for 'Burn The Brightest Day'. Click here to see it.
They say:
Rhys Marsh has premiered the video for his track Burn The Brightest Day via Prog.
It's the third single from The Autumn Ghost mainman's debut solo album, Sentiment, released last month.
Marsh tells Prog: "Burn The Brightest Day is one of the most direct things I've ever recorded, both musically and lyrically. I filmed the video round the corner from my studio one sunny morning. I really love the retro nostalgia feel."
The Norwegian-based singer, songwriter and producer says of Sentiment: "It's my darkest and noisiest album so far. That encouraged me to step away from my comfort zones and really delve into more personal matters."
26th October 2014
This evening, my new single, 'Last November', will be premiered on AAFM's Xymphonia radio programme.
Click here for more information.
18th October 2014
'Sentiment' is now available to pre-order from:
Burning Shed (UK)
Just For Kicks (Germany)
Marquee Inc (Japan)
Musea Records (France)
The first 50 copies from Burning Shed will be signed by Rhys.
13th October 2014
The first single from my forthcoming solo album is released today, & i'm very happy that God Is In The TV are premiering the music video. They say:
"A darker more shadow lined approach is taken, its ghostly pang threaded in suspense is stirred in a fracturing isolationist disturbia and prowling psychosis…"
Ladies & gents, here is 'The Seventh Face'. I hope y'all enjoy it.
10th October 2014
Click here to listen to the world premiere of 'The Seventh Face', which will be on the air at exactly 17:00 Central European Time / 4 pm in the UK!
In case you missed it, the broadcast will be available online until 11th April, 2015.
You can find older stories by browsing the news archives.


text:
- Current Alert
- Resolved Alert
- Future Alert
Library Services
The most recent ITS Alerts affecting Library Services are listed below and are also published via the Library Services Alerts RSS feed. In addition to the alerts below, a list of the most recently analyzed entries in the National Vulnerability Database (NVD) is provided on the right side of this page.
Resolved: Course Reserves and library guides currently unavailable through Canvas
Last updated on October 23, 2018 at 12:47:27 PM
Course-specific library guides and some course reserves under Library Resources tab in Canvas are currently unavailable. You can still access this material through the Library website: Course Reserves If you...read more
Resolved: Electronic Theses and Dissertations (eTD), Honor Theses (eHT), and ScholarSphere Service Interruption 10/18/2018
Last updated on October 18, 2018 at 01:20:12 PM
Electronic Theses and Dissertations (eTD), Honor Theses (eHT), Millennium Scholars (MSP), is experiencing an outage related to uploading of Thesis and Dissertations documents only. The application is reporting upload files...read more
Resolved: Labman service outage.
Last updated on June 21, 2018 at 08:40:02 AM
On Friday June 22nd during the regular maintenance window of 5am - 7am, LabMan will be unavailable for regular maintenance.
Scheduled Scholarsphere Update
Last updated on May 15, 2018 at 09:38:28 AM
Scholarsphere will be available intermittently during the 5-7 a.m. (EDT) maintenance window on Wednesday, May 16th.
Scheduled Scholarsphere Update
Last updated on April 25, 2018 at 03:44:19 PM
Scholarsphere will be available intermittently during the 5-7 a.m. (EDT) maintenance window on Thursday, April 26th.
Scholarsphere availability limited
Last updated on March 6, 2018 at 10:52:43 PM
Scholarsphere will be available intermittently while we update Solr.
Scholarsphere maintenance scheduled
Last updated on March 5, 2018 at 09:48:32 AM
Scholarsphere will be available intermittently while we update Solr.
Scheduled Scholarsphere Update
Last updated on January 24, 2018 at 09:30:23 AM
The Scholarsphere application will be updated to version 3.3. During the update, Scholarsphere may be unavailable for use.
Resolved: Network Connection Maintenance
Last updated on January 8, 2018 at 06:08:05 AM
Maintenance is complete and systems are running as expected. If you experience any further difficulties, please contact the IT Service Desk at firstname.lastname@example.com or 814-865-HELP.
Resolved: Known Error impacting 2nd Factor Authentication
Last updated on January 4, 2018 at 02:54:19 PM
Penn State IT staff and the Office of Information Security (OIS) have implemented a fix for 2nd Factor Authentication (DUO) around 1 p.m. today. If you are still experiencing issues,...read more


text:
We donate a % of our profits to charities every year!
Chaps World is committed to supporting local and national registered charities through the donation of a significant portion of our profits from Champagne sales. This year, we are delighted to announce that we will be donating 20% of profits from champagne sales to 3 charities nominated by the Chaps World team.
Continue Shopping…
Your basket is currently empty.


text:
Muslim dating at muslimacom sign up today and browse profiles of women for dating for free. Meet someone who can be a part of your islamic world in a few quick and simple steps join our dating service to find your perfect match today, muslim personals.
Meet people looking for muslim singles in the usa on lovehabibi - the top destination for single muslims in the usa and around the world. Looking for latin muslim women or men local latin muslim dating service at idating4youcom find latin muslim singles register now for speed dating.
Singlemuslimcom the world's leading islamic muslim singles, marriage and shaadi introduction service over 2 million members online register for free. Muslim dating no wonder that virtual matchmaking has more possibilities and thus, more potential meeting like this has become standard in various societies united by same religion or lifestyle. Power plant mall is an upscale indoor shopping mall in makati city , philippines it is the anchor establishment of rockwell center , a mixed-use area north of the makati central business district on the pasig river waterfront across mandaluyong it is one of two shopping centers developed and managed by rockwell land corporation, a subsidiary. Muslim dating for muslim singles meet muslim singles online now registration is 100% free.
Flor de cabrera, private villa rental, vacations, destination weddings, events, fully staffed open all year. Judibana's best 100% free buddhist dating site meet thousands of single buddhists in judibana with mingle2's free buddhist personal ads and chat rooms our network of buddhist men and women in judibana is the perfect place to make buddhist friends or find a buddhist boyfriend or girlfriend in judibana join the hundreds of single la. Muslim dating is designed to fit the needs of muslim men you have the same mindset and religion, which is the best ground for building a strong partnership these muslim women are here just for you.
8 things to expect when dating a muslim girl hesse kassel january 9, 2015 girls 820 comments hesse kassel hesse kassel is an australian economist he stopped chasing money and chased women and made children instead he blogs right here muslims account for over twenty percent of the population of the world and more than. How young muslims define 'halal dating' for themselves : code switch young muslims find a middle ground for fostering romantic relationships between what is permissible and what is forbidden. Meet marriage-minded singles here muslim singles know well how hard it can be to find a partner in the us, let alone one you wish to marry and settle down with it's an issue faced by many americans – and it only gets harder when you bring faith into the equation yet, hard doesn't have to mean impossible – find out how muslim dating with.
Muzmatch is the meeting place for arab and muslim singles expand your horizons by creating a free profile, browse personals, and find that special someone. Judibana's best 100% free hindu dating site meet thousands of single hindus in judibana with mingle2's free hindu personal ads and chat rooms our network of hindu men and women in judibana is the perfect place to make hindu friends or find a hindu boyfriend or girlfriend in judibana join the hundreds of single la guajira hindus. So young muslims who engage in halal dating seek a commitment first and are vigilant about staying true to their religion (5) for both strict and eid muslims, couples are introduced to each other, either by parents or friends (less often they meet at school or in their local community) they spend time talking over the phone or on the internet. 10 best muslim dating sites (2018) hayley matthews updated: 5/14/18: discuss this when you're seriously dating someone, shared values are important especially if you're looking to build a lasting, lifelong partnership, you'll likely want to make sure your religious views and backgrounds are compatible with those of your date's the earlier.
Spiffy british muslim lifestyle blog of zaufishan iqbal. Featuring yassmin abdel-magied youtube deck: check out more awesome buzzfeedyellow videos music say it right audio network ge.


text:
Little Known Facts About lifetime.hosting walkthrough.
Are you presently Uninterested in 43 cent epcs advertising and marketing Hosting? If you have Internet hosting, then have a look at Life span.Internet hosting. You will need to change today. When you don't have Website hosting, then you need to have it. Lifetime.Hosting2 simply suggests the customer pays 1 time for his or her internet hosting. assist you setup your first Internet site for your company, individualized e-mail, ranting blog or whatever. It will eventually keep on to host their websites assuming that they like.
from web page encouraging or the ones having a program of action of new companies, professionals, from internet site encouraging or those that has a class of motion of recent corporations, experts,
Most widely used WordPress plugins Many of the most popular free of charge WordPress plugins that may help you increase the functionality of one's WordPress powered Internet site:
This distinguishes TMDHosting from the other hosting vendors; we provide only Skilled and optimized hosting options, on which your WordPress website can properly trust in.
Only ship them your messages or create a live communicate, and you'll get the most effective exhortation as quickly as time permits.
Lifetime Hosting is usually a contemporary out with the box new facilitating which conveys the speediest stacking internet site charge with only one-time installment. This expense task is a big most popular standpoint about the much larger Section of facilitating administrations available today, which consider your money a seemingly endless length of time and rather quite a long time for safeguarding your internet site location names and various silly rates.
You have to sign-up the no cost domain in the course of the acquisition within your account. You may NOT claim the no cost domain title with a later date Purchaser Reviews on TrustPilot
These difficulties are simple amongst World-wide-web proprietors. In case you're one of these, compliment since you went to an accurate place the place I'm going to demonstrate for you A further unbelievable facilitating referred to as Life span Hosting.
WordPress is Just about the most covered more info CMS applications within our Understanding Base. Nickola and his staff direct our every day efforts in giving documented, sustainable and simple to adhere to articles on several WordPress relevant subjects.
All WordPress aid products and services are A part of the TMDHosting WordPress options. You may no more have to worry about concerns together with your WordPress Web site and When you have concerns or you'll need anything to be executed on the web site, our WordPress gurus are listed here to assist you, entirely free of charge.
I am unable to add any illustrations or photos to my WordPress software. Why is always that And the way can I take care of it? This type of troubles are generally brought on by the permissions of the data files and folders and they're simple to repair.
By buying Expert services, you are agreeing to this business marriage with us. As a result, you concur our communications to you are solicited e-mails rather than SPAM.
CloudLinux is Moreover coordinated to maintain your web site from abusing property. It In addition supports the security level though making sure servers by the use of LVE Know-how. Maria DB will Also substantially increment the stacking fee of your website.
At this moment through this quick grand opening period, they're supplying you with the opportunity to snag life time access to Upmight for just a one particular time payment..


text:
Open Meditation Schedule
Our center offers a rich array of weekly ongoing offerings free to the public. No prior meditation experience required to attend. Most programs offer meditation instruction upon request. All are welcome.
Open Public Sitting Hours
Group sitting is an opportunity to practice meditation together. Individuals may arrive and leave as they need to. During the sessions there are opening Shambhala Buddhist chants, sitting meditation, walking meditation and closing Shambhala Buddhist chants. All are welcome.
Brunswick at 19 Mason St.
Portland at 81 Oak St.
Free meditation instruction is available by prior appointment. Contact Sarah Chandler at firstname.lastname@example.com
Below is a summary of our weekly public meditation schedule:
Sunday Morning Meditation- Brunswick
Sundays, 9:00 AM – 12:00 PM | Open to all | By donation-
unless there is a weekend program in progress. These programs will be listed in our online calendar.
Join us in group practice of the Shambhala community's core discipline of mindfulness-awareness meditation. Periods of silent sitting meditation alternate with shorter periods of walking meditation. Each session starts and ends with chants. Meditation instruction is available with advance notice. Come and go as you like.
Open Meditation- Rockland
Sundays, 10:30-11:30 AM | Open to all | By donation
Open Meditation is an opportunity to practice with a group in a relaxed and friendly environment. Everyone is welcome, including beginners and experienced practitioners. All meditation traditions are honored. Each session includes twenty-five minutes of seated meditation, followed by five minutes of walking meditation, and closing with twenty-five minutes of seated meditation. There is a timekeeper but no instruction.
Thursday Night Meditation- Brunswick
Thursdays, 7:00 – 9:00 PM | Open to all | By donation
Join us in group practice of the Shambhala community's core discipline of mindfulness-awareness meditation. Periods of silent sitting meditation alternate with shorter periods of walking meditation. Come and go as you like.
For meditation instruction contact Sarah Chandler at email@example.com.


text:
A pest control company should concentrate on not only extermination, but pest management likewise. A company who can exterminate an infestation but can do very little that will help safeguard your private home versus foreseeable future infestations is just not of A great deal use.
pest control in Kansas Town can be very similar to Raleigh NC pest administration and exterminators in Raleigh NC, they are going to do frequent solutions to help in trying to keep the limitations which will you desire to to maintain property pest cost-free. After you have to have these telephones also software the lining of the home you'll be able to employ the service of them to make it come about at the same time, notwithstanding The truth that following the Preliminary services this could not be really important when they do an excellent job exterior.
Ants can demolish your house and yard speedy, It's a smart idea to immediately remove this pest issue the moment you could. Our ant control prepare will do away with your ant difficulty nowadays, we use pet and kid friendly chemical substances and the newest technology that can destroy their colony permanently. Don't neglect to request our very low priced ant treatment options these days and say fantastic bye to pests!
Persistently, a technician operates inside your own home, so homeowners should really watch out when earning their range. Underneath is actually a tutorial of your do's and don'ts in choosing a local, reputable pest control company to satisfy your requirements.
Talk to your pals, loved ones, or neighbors if they've got had any particular encounter While using the pest control company you take note of. Each and every company will almost certainly have happy prospects, but Listening to initial-hand expertise from dependable individuals usually means greater than any testimonial at any time could.
Pest control providers: "He was just Superb. If someone offers me one thing just to assist me out, I actually appreciate it." — Chris K., Indianapolis
Joe is amazing and does a terrific task at trying to keep the bugs from our household! I find Joe quite enlightening and proficient. It is really You Can Look HERE always great to find out him, I look forward to him coming to his career. I get very good responses to my inquiries and believe in his suggest.
Joe was incredibly proficient and informative about our concerns with rodents together with other pests. He was incredibly thorough with his operate. We look ahead to acquiring him again.
Have to have a pest control expert? Angie's Checklist has numerous hugely rated pest control assistance companies within the Atlanta industry from which to settle on. This is a sampling of a lot of the best:
Plus they offer you a lots of recommend on how to forestall and manage condition like that. Both equally of the agent did Very outstanding function and we removed the rats almost correct just after. Highly advocate it.
Find out what varieties of expert services the company provides. Find out if minimum-poisonous alternatives can be found to control the pest. Ensure the company has the necessary licenses, certificates, and coverage. Inquire the company to inspect the site.
Step one is usually to acknowledge the remark and reach out with a few options for resolution. Regardless of the options you decide on, they need to usually include things like an apology and reassurance that you simply treatment and will make things ideal.
Several homeowners can control household Animals as a result of a combination of avoidance actions, such as right sanitation and excellent property upkeep tactics. Nevertheless, some pest infestations might be substantial or a specific pest could be difficult to control, requiring the expert services of a pest control company.
Take into consideration your chemical tolerance. Request which pesticides might be employed, the active elements they have, and their effects on Animals, the environment, and other people—especially the elderly, the pretty young, or people with environmental sensitivities. Establish if there are particular legal needs specifying safety measures for being taken immediately after application. It's possible you'll request a copy of the Material Protection Information Sheet (MSDS), which describes chemical traits, hazards, and protection precautions for each pesticide employed. Speak to the pest control company plus your county agricultural commissioner When you have additional questions about pesticides for use or consult with the Countrywide Pesticide Info Heart on line or by phone one-800-858-7378.


text:
This classic Kimono wrap cardigan by Autumn Cashmere looks great when paired with a dress & tights. This sweater just gives us yet another reason to fall in love with cashmere.
- Autumn Cashmere
- Color: Faded Denim
- 100% Cashmere
- Seed Stitch
- Cardigan
- Tie Waist
- Kimono Sleeve
- 3/4 Sleeves
- Dry clean only
- Made in China
- Manufacturer Style No. RT10954
Fit, quality & comfort: three main factors that motivate the team behind Autumn Cashmere. Starting in 1993, Autumn Cashmere strives to constantly provide a fresh take on cashmere design; proving that wearing cashmere can be functional and stylish.