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This year, we attempted to hold our biggest morning tea by including our whole school!
There were over 700 participants, and our school photo was fortunately included in this year's youtube.
This year, we attempted to hold our biggest morning tea by including our whole school!
There were over 700 participants, and our school photo was fortunately included in this year's youtube.
Greetings everyone!
This is my last assignment!! Yipppeeeee!!! (not that I hadn't enjoyed the experience)
I have found that with all these new online tools and constantly developing new ways of communicating, sharing and learning…I suffer from the frustration of the lack of time and opportunity to explore tools, to develop, master and discover all they have to offer.
Time seems to be my one and only issue…BUT it is a BIG ISSUE for me.
And as I submit my final assignment…I would like to THANK every single person on this journey through the VicPLN. You have all been WONDERFUL.
I hope you find this screencast that I have made, helpful.
I had a little trouble whilst I was making my ToonDoo presentation 😦
My computer decided to have a little break down and it wouldn't allow me to save!!
Therefore, I thought that I should finally embed what I have managed to put together before anything else goes wrong (please note that this is only part of Unit 7)…I hope you like it.
Actually…only a link to my ToonDoo Book is possible. (sorry for any inconvenience)
Assessing your digital fluency
Completed Survey 🙂
I have learned a number of new skills and have learned to use a number of new tools via the VicPLN. Facebook, Twitter, Evernote, WordPress and a few others. All of which I was non-literate and now I feel that I have achieved 'Literacy' level.
But I would love to be at a level of 'Fluency'. The tutorials that are provided for us are a perfect way to learn how (Thank-you for these tutorials, they are extremely helpful)
My attitude to online citizenship is the same attitude that I like to share and show whenever I am out in public.
Trying to be respectful and mindful are all attitudes that I hope to always demonstrate (that's just the way I am)
The way that I manage my privacy is to not provide personal information online. My privacy and reputation is not really an issue for me. I am always conscience of the fact that whatever I post online is out there for anyone to see. I question myself, 'do I care if anyone sees this?' the answer would have to be a definite no, otherwise, I just don't put it online, simple (yet an effective way to protect our privacy and reputation).
I have tracked down my 17 year old niece. She is currently doing year 12.
And I had put forward to her, questions from Unit 6.
Question 1. What is your attitude to privacy online, are you concerned about your online reputation and do you take steps to protect your privacy?
Answer: "Yes, I take steps to protecting my privacy by putting all my settings onto private. And I only accept people that I know as friends on my Facebook.
Question 2. What tools do you use to stay in touch? And do you have a multiple personae?
Answer: "I use Facebook, Twitter, Instagram, email and messaging on my mobile phone (a Samsung Galaxy). We use Edmodo only for school. What you see of me is what you get, I only have one personae online"
Question 3. How would you feel about using the same tool for your personal life and for your learning?
Answer: "I use Edmodo only for school. I reckon I wouldn't use Edmodo for private life because it really doesn't have the features as FB does and not many people know about it. But it's easier if I used it for school only cause it's easier to communicate with the teachers and submit any assignments in."
Considering digital fluency and citizenship, I strongly feel that it is the educators responsibility to teach, instruct, demonstrate, inform, emphasise and encourage students in the responsible use of these very powerful tools.
I don't think that this should be limited to the tools that we encourage students to use, we should definitely be teaching responsible use of Facebook BUT at an appropriate age. We don't teach 13 or 14 year olds how to drive (subject to debate), because they are not old enough or mature enough to handle the responsibility and the implications of such a tool (i.e. a car) just like they are not old enough and mature enough to handle the responsibility of a powerful tool such as Facebook. Yes, I see Facebook as a powerful tool where we have discovered can have serious consequences when used irresponsibly. Perhaps I am getting a little carried away, I see that youngsters are using Facebook and other online tools, therefore, educators should be doing all they can to ensure that students are given the best advice (a simple analogy: a child first hold a grown ups' hand when they learn to cross the street…then they can use a crossing… independently walk safely…some will just run across the street and not look both ways, but it is our responsibility to show them how to walk and cross that street correctly…safely.) I could go on and on and on.
I feel that modelling responsible behaviour using Edmodo would be a positive step.
I feel that my progression with technology has been positive. Although I feel that I am still very much literate, I hope to become fluent. It has changed the way I learn and shaped my professional practice by allowing me to communicate and network with others via tools that I was not familiar with (if it wasn't for the PLN, I would not have joined Facebook, Twitter or even Edmodo) I am grateful for being given the opportunity and a reason to enter the online community.
The impact of technology on us citizens has had a positive and negative effect.
As with anything in this world, I have found it quite sad at times at what this technology's effect has had. Hand written notes sent in the mail are a rare and yet endearing item to receive. And yet, being able to link with someone on the other side of the world is amazing!
The use of technology in learning is essential. Unfortunately, technology is moving so fast that educators sometimes tend to fall behind in modelling the use of this technology. Educators need to try to keep at least one step ahead of the students, in order to guide them correctly.
My chosen 5 Characteristics of an effective learner:
1. curious: I have found that being curious about a topic has had me searching for answers and discovering new things.
2. passionate: Being passionate about something, would also have me investigating and searching.
3. multitask: I have been able to have a number of websites up at one time, alongside some books and corresponding with colleagues (a feat that I'm sure I would not impress those who are I.T. Geniuses)
4. organised: learning how to incorporate tools that help us keep all of our new found information organised and easily recalled and retrieved.
5. sharing: I feel that sharing is a wonderful way of becoming an effective learner as it leads to others sharing right back with us, thus giving us access to further new resources and information.
I predict that the way that technology will change the way we learn in the future is possibly… not much different than what we have today (I suppose that shows that I really can't think too far into the future and that I'm not very imaginative) But I don't think that the classroom would ever become obsolete as education is not the only thing we need to learn, a sense of community and our social skills could really only be obtained if and when we are in the company of others.
1. Search
The first task had involved, picking one term that students may need to search at school and to then compare results offered by different search engines. The term that I have chosen is a topic that is covered by our year 5 Students: Natural Disasters
Google; gave me a drop down option via auto suggest : 'Natural Disasters for Kids'
DuckDuckGo; did not give me a drop down option for kids (I had to type it in)
Bing; also gave me an auto suggest with the option of 'Natural Disasters for Kids'
InstaGrok; could not give me any options for 'Natural Disasters for Kids' but it was able to give me the general 'Natural Disasters'.
2. Evaluating resources
A web resource which I trust is:
This site contains a calendar of events in which I rely on to obtain information re: upcoming events throughout the year.
I have chosen this site because I feel that it is so obvious and clear that this is a reliable.
I know that this is a reliable site because it contains .gov in the URL (Uniform Resource Locater, internet address)
It contains contact details, it has links to other sites, I can see no spelling errors, this site is easily found, it has relevant and up to date information, I found that this site ticks all the correct boxes (so to speak)…
… (Oh No!…I actually just checked the site to ensure accuracy. To do this, I checked the date for Australia's Biggest Morning Tea, and to my disappointment 😦 , it had the date of 28th of May, when this year it is Officially 23rd May, as I have discovered on the 'Australia's Biggest Morning Tea' site. Well, what does this mean??? I suppose this means that just because we believe a site to be true and accurate, it's always best to check a different resource to ensure the results are consistent and are as accurate as possible) I have certainly learnt that relying on one source of information is not very reassuring and has left me questioning other information and their sources.
Unit 4 – the task
With my serious hat on, the online service that I have chosen is Evernote (an online tool that I have already signed up to).
The 'Terms of Services' Page and the 'Privacy Policy' are very easily located on Evernote.
After having selected a random piece of each of these documents, I feel that they are trying to give the impression that the information is clear and straight forward language but I'm afraid that I don't comprehend it very well and like all other documents, I usually just skim along reading it and only stop if something sticks out like a sore thumb! (I do try to understand it all but…what can I say…I don't really understand what it REALLY means)
One thing that surprises me about Evernote, is that your personal information and contents may be shared! This really doesn't bother me at all because I have always believed that whatever you type in on your computer you need to be prepared and know that it is possible for anyone to view what you have posted. You need to be comfortable enough with the content that if it is viewed by others, you wouldn't care any way.
The policies on Evernote are extremely long and appear to thoroughly cover all necessary questions that someone might think of asking. I did not read the whole thing. Like most documents, it does become very boring after the first few paragraphs. And of course, like most things, I did not read the fine print nor the entire policy. I know that I should but I never seem to be able to get focused and tend to sometimes (i.e. most times) skim through just to be able to say, "yes, I have read through the policy"
With Evernote, you are able to back up or export your data…
"Your Data is Portable
There is no data-lock in Evernote. We are committed to making it easy for you to get all of your data into, and out of, Evernote at any time. Our desktop software lets you export all of your notes and content in human-readable HTML as well as a fully documented machine-readable XML format. We also have a full, free API that lets you access all of your data. Our philosophy is that if you're confident that you can leave Evernote at any time, then you'll be confident enough to want to stay." (Extracted from The Evernote Blog 18th April 2013)
Through the settings option, you are able to deactivate your account.
After having a little and yet a useful experience with the use of Evernote, I have already recommended its use to another work colleague. I feel that Evernote is a very useful tool…but I know that I am still at a level of discovery and I have a lot more to learn and to discover about Evernote. But I have been fascinated and inspired by capabilities in what Evernote has to offer.
Evernote's usefulness tends to override the terms, policies, conditions etc., etc., etc.. If we had to look at every aspect of every tool, I'm afraid that that is all that we would do, we would be too afraid and to cautious to sign up to anything. But instead, we skip all the formalities, look at a tool for whatever it may be good for, and sign up usually WITHOUT even having a look or a good look at the policies but mainly based on recommendations by friends, colleagues or other users.
Evaluation of an online tool:
After having a brief look at 'Xtranormal', the graphics seemed to be more appropriate for older children. I also had a quick look at Storybird and my personal opinion is that I did not find it as colourful as ToonDoo.
So I had chosen to use the tool ToonDoo as part of Unit 4.
I have created a short, light hearted cartoon strip, I hope you like it.
My review of ToonDoo is as follows; ToonDoo is a free tool but you can also have a subscription where you are able to get a lot more options. This tool requires you to login with a username and password (I tried to go back to review the registration requirements but due to the system remembering my details, it would no longer give me the option to go back as new user…and I couldn't quite remember all the details).
There is an option of Private ToonDoo Spaces, which is a secure option for schools and educational institutions and then there is the Public ToonDoo, where individuals sign up to. This could be set as private, to share with friends or made public. Again I see the potential of this being such a positive tool but like all things on the internet, online or in a cloud nothing is ever really secure and so we should use this tool with care.
I could see this tool mostly being used in a classroom setting and for those of us who would like to express ourselves visually.
This tool would be wonderful in a classroom setting. Students would able to show reflections of excursions, they could demonstrate steps to an activity, a book review etc., etc., in a cartoon form. They are able to pick settings, backgrounds, write in the dialogue etc. there is an endless use of this tool in a very positive and entertaining way. It offers social network settings for classrooms at a rate of 10c per user per month.
This could change the way in which students hand in assignments. For example, a student may need to write a reflection of an excursion that had gone to. With ToonDoo, the student would be able to show and write their reflection in a much more entertaining way. ToonDoo fits in the SAMR model of assessment for example, Substitution, Augmentation, Modification and Redefinition all can be applied by the use of the tool ToonDoo in a presentation of a Book Report.
ToonDoo is easy to share and to embed.
A fun and entertaining tool 🙂 🙂
The way I feel about online professional communities is, that I can see how this way of communicating, sharing and discussing can be of benefit (i.e. not needing to worry about travel, time and distance etc.) But I also like the interaction and social aspect of meeting, greeting and discussing things face to face. The role in which this may play for me in education is that I feel that we can pretty much have the best of both worlds, i.e. we can communicate and network via all these wonderful tools e.g. Facebook and we can also make an effort into attending meetings and workshops, allowing us to get a different perspective (and a little fresh air 🙂 )
I found that the tools that were suggested to us were not only interesting but also entertaining. I have never used Twitter or Facebook before. So when I first joined Twitter, I had attempted to send a Twitter to 'QandA' and to my disappointment, I did not see it run across the screen like so many others I had seen. The concept of someone not seeing or listening to what I had to say saddened and disappointed me although I now do understand that not all Twitters are possible to see or to display (there are just too many)
I found that I much prefer to use Facebook. I do not find Facebook as fast paced as Twitter. Although, at first I found that I was a little slow in adding to a conversation. By the time I had a thought or response, people were already on another topic! (Both on Facebook and Twitter) I am pleased to say that I think that I am getting a little better at it.
I work in a Primary School Campus and Facebook is not blocked for Staff but students do not have access.
Using Facebook, Twitter or Google Plus have positive aspects in communicating and collaborating with colleagues. You may have a thought, idea or want to share some newfound information which could then be immediately communicated to your colleagues via any of these tools. An instantaneous and exciting form of communication (especially if you want to share something new that you have discovered and feel that you must share immediately) 🙂 🙂
Please also see earlier reflections re: Unit 3 (there are 3 other posts re: Unit 3 after the 2 Youtube posts)


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|A Collection of Informative and Interesting Articles
|Debt Collections (Advt.)
Colorful Facades of Kerala Honeymoon PackagesBY: wilson tom | Category: Travel | Submitted: 2010-12-13 04:14:50
Article Summary: "Kerala has several romantic honeymoon destinations and each holiday place in this state has its own charm and beauty that never fails to seduce the mind of the newly wed to enjoy quality time being together in Kerala lovingly called God's Own Country..."
Kerala is a dream destination for the newly weds. It is not surprising to tagged Kerala as God's Own Country or Evergreen Paradise on Earth or even honeymooner's paradise as this beautiful state of India located along the azure shore of the Arabian Sea is blessed with all the enigmatic expressions of nature. It is blessed with enchanting hill stations where you will find nature at its best. Here you will find the mesmerizing backwaters endowed with astounding charm of nature. Here you will find the waves romancing with the sun-kissed beaches beautifully dotted by the swaying coconut and palm trees. Here you will find the pleasant climatic conditions seducing the mind of the newly weds to romance and make love. Kerala is truly a sheer wonder and offer wonderful opportunity to enjoy intimate time of love being together.
Kerala has several romantic honeymoon destinations and each holiday place in this state has its own charm and beauty that never fails to seduce the mind of the newly wed to enjoy quality time being together in Kerala lovingly called God's Own Country. Well in order to enjoy romantic time together plan your vacation with one of the leading Kerala tour operator or management companies who provide several tailor made Kerala honeymoon packages like Kerala backwater honeymoon packages, honeymoon in Kerala hill stations, honeymoon in Kerala, romantic honeymoon tour Kerala, etc. Book one tailor made honeymoon package to Kerala from the leading tour operator and enjoy your once in a lifetime vacation in a romantic and memorable way.
Well most of the honeymoon packages Kerala offer wonderful opportunity to length the beauty of the backwater staying over the exotic houseboat, which slowly floating with the pace of the time takes you to the world of wonderments. Houseboat is the only medium through which journey over the scenic water world is possible as Kettuvallam slowly moving over the water takes you to the world of wonderments offering you to enjoy time or love and pleasure over the houseboat as experince of lifetime. Some of the popular backwater destinations in the state are Kuttanad, Alleppey, Kumarakom, Kasargod and on top Cochin which are visited by tourists and honeymooner from all the nook and corner of the world during their vacation in Kerala in India.
In additional couples can also enjoy romantic time along the serene beaches of Kerala which is beautifully dotted by the swaying coconut trees and exotic restaurants. Among the many captivating beaches, Kovalam is the most preferred by the honeymooners and European travellers who come to enjoy vacation in Kerala- the God's Own Country. Kovalam is blessed with astounding charm and romantic ambiance which never fail to impress the heart of the newly weds who come for honeymoon holiday in Kerala.
Well apart from these romantic honeymoon destinations, vacation in Kerala is made more remarkable and memorable by the world class accommodation facilities, caring people and on top pleasant cool climatic conditions. So what are you waiting for, pack your bag and celebrate once in a lifetime vacation in Kerala in a romantic and memorable way.
About Author / Additional Info:
Wilson tom writes about various honeymoon destinations in the world. Here he is providing valuable information about kerala honeymoon packages. For more information visit to site http://www.keralahoneymoonpackage.com
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Experts from around 30 European countries met in Lisbon from 24–25 September for their annual meeting to examine the profiles and characteristics of people seeking treatment for drug problems.
The EMCDDA's treatment demand indicator (TDI) is one of the agency's most established tools for monitoring the drug problem. The inaugural session focused on the state of progress of this indicator and dealt with issues of data-collection quality and methodology. Three workshops then examined topics that reflect the dynamic nature of treatment: polydrug use, new drugs (currently not covered by the TDI protocol) and the reference period for data collection.
The participants addressed how to improve the quality of data collected by treatment centres, notably by: refining definitions in the TDI protocol; collecting data from a wider range of centres; and linking information on treatment demand to that on treatment offer. National studies and a recent revision to the Addiction Severity Index were presented in a session on evaluating treatment outcome.
This year the meeting offered a session on the geographical analysis of treatment data. This included an introduction on Geographical Information Systems (GIS), featuring presentations from the EMCDDA, UNODC, Italy and Switzerland. See also documents relating to the meeting
Linda Montanari
Drugnet Europe is the EMCDDA's newsletter launched in September 1996. The newsletter provides regular and succint information on the Centre's projects and activities to a broad readership.


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We are a full service lawn company providing all grass and lawn maintenance, landscape maintenance, shrub pruning, mulch installation, fall clean ups and leaf removal services. We serve the greater Grand Rapids area including (but not limited to) Hudsonville, Allendale, Ada, Wayland, Byron Center, Jenison, Grandville, Wyoming, Grand Rapids and everything in between. If your lawn or landscape needs something, we can provide it. If we do not personally provide a service then our partners can. Please call Efficient Lawn Maintenance, LLC, today.
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Baby K'tan, LLC Announces Partnership with ICU Baby on Project Kangaroo
Families requiring extended NICU stay to receive a Baby K'tan carrier
The organization has targeted programs to fulfill its mission including the Preemie Pack Project, which was launched at South Miami Hospital in November 2015. The Preemie Pack tote bags contain items that assist and support parents with their baby's care while in the NICU. Baby K'tan, LLC partnered with ICU baby from the onset to provide each Preemie Pack recipient with a Baby K'tan Baby Carrier. Baby K'tan has continued its partnership with ICU baby for the past two years and over 150 Baby K'tan Baby Carriers have been distributed to families with a baby admitted to South Miami Hospital's NICU.
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New reporting changes are coming your way for the 2018 1098-T forms. Continue to check your email in early January for early online downloadable access information. Also, mailed 1098-T's will continue to be sent to the legal address on file by January 31, 2019.
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Food And Wine Winter Recipes
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Banking Vet Callaghan Joins Virginia Commonwealth
William Callaghan, a 38-year banking veteran, joined Virginia Commonwealth Bank as executive vice president, chief administrative officer. Callaghan will report to President and CEO Randal R. Greene.
Callaghan has more than 35 years of progressive management experience within the financial services industry. He has been responsible for managing and overseeing more than 15 core system conversions successfully. He most recently served as senior vice president, chief information officer of Xenith Bank in Richmond, VA. He was one of the original members of its executive team to assist in the start-up of the bank.
"Bill is an exceptional executive who brings extensive strategic and operational leadership experience to our bank," Greene said. "Bill has a successful track record with core conversions and with strategic and tactical leadership in executing and managing major corporate initiatives, while ensuring effective compliance management."
Virginia Commonwealth Bank has 18 banking offices located throughout the Richmond, VA market area.


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Children need exercise for mostly the same reasons as adults, but for kids playing in organized sports there is an added bonus—playing as part of a team. Being a team member teaches children lessons about life and cooperation in a fun, friendly environment. For the 38 million youths signed up for official organized sports, there are bound to be injuries. Knowing what to look out for in three of the most popular sports when your child is on the field or court will help minimize potentially life-altering accidents.
Football Injuries
This all-American sport can be a lot of fun to watch and even more fun to play. The downside is that the number one football related injury is a concussion. Head trauma is no joke and should be taken very seriously. Make sure your child has all of the required, recently checked, up-to-date safety gear. Also, make sure the team coach is qualified to handle serious issues relating to concussions. After trauma to the head, knee injuries rank as one of the most common. Tears in the ACL/PCL can result in life-long problems if not properly treated.
Web MD points out that the world's most popular sport is also the most dangerous for adolescents under the age of 15. Males can expect an average of 4 injuries per season, while females average 3.5 injuries per season. In 2006 there were over 180,000 injuries reported with a shocking forty-four percent of those injuries coming from players 15 years old and younger. The most likely injuries will occur at the knees, but soccer is known for concussions too. Be sure your child warms up properly before playing and cools down after a game.
You might think basketball players are less prone to injury than other athletes. While the injuries may differ between sports, basketball still has potential for serious injuries. The most common problems come in the form of sprains, jammed fingers, and bruises. These may not sound too serious, but they can cause sever damage is left unresolved, or ignored. Pay attention to what's going on with your young player's injuries and don't assume that they should just shake it off.
Any time your child is injured you need to take it seriously. Be sure to have any issue looked at as soon as possible by a doctor specializing in pediatric sports injuries.


text: Start your December soulfully! Join us at 5 PM this coming Sunday for a service of readings and songs – a traditional Advent event, created anew each year. Afterwards, share refreshments and good company, then stay to enjoy the 2018 Baltimore Men's Choir winter concert, "Stories for The Season." This event is free and open to the public. All are welcome. We even have space to sit with your little tykes – they can crayon while mom and dad enjoy the music.


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The Scientific World Journal
Volume 2013, Article ID 458106, 8 pages
Synthesis and Photocatalytic Properties of ZnWO4 Nanocrystals via a Fast Microwave-Assisted Method
Key Lab of Environment Friendly Chemistry and Application of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan 411105, China
Received 6 April 2013; Accepted 8 May 2013
Academic Editors: B. Huang and L. Jing
Copyright © 2013 Jing Yan et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
High crystallinity of ZnWO4 nanoparticles has been successfully synthesized via a highly effective and environmentally friendly microwave route by controlling the reaction time and temperature. The products were characterized by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), and Fourier infrared spectrum (FT-IR). The crystallinity was enhanced with the increase of the reaction temperature and time. The photocatalytic activities of ZnWO4 nanocrystals were evaluated by testing the photodegradation of rhodamine B (RhB) dye under ultraviolet (UV) light irradiation. The results indicated that as-prepared ZnWO4 was highly effective for the degradation of RhB. The degradation rate of RhB reached 98.01% after 6 h of UV illumination.
1. Introduction
Tungsten materials with novel architectures and physical and chemical properties are very useful for many potential applications such as flashing materials, LED [1], magnetic and fluorescent materials [2–8], optical fiber, humidity sensors [9], light emitting materials [10, 11], photocatalytic materials [12–18], scintillator [19], laser host [20], and nanoordered substrate materials [21, 22], so they are considered as an important class of functional materials. As an important photocatalyst, ZnWO4 has been applied for photocatalytic hydrogen production from water and mineralization of organic pollutants under UV light irradiation [18]. For the formation of tungstate nanomaterials with unique morphology and hierarchical organization, a great number of synthetic techniques, such as hydrothermal method [23, 24], microemulsion, and sol-gel method [25–28], have been developed in the past few years.
However, there are some shortcomings for the traditional synthetic methods: the reaction temperature is too high; the reaction cycle is too long; the procedure is complex [23]. Obviously, the long reaction cycle will waste time. It is worse that the long reaction time may lead to the dendritic growth and increase the particle size. Chen and coworkers have synthesized ZnWO4 powder by hydrothermal method and demonstrating that particle aggregation is stimulated by temperature and time increase [2]. Wu et al. have successfully produced ZnWO4 photocatalyst via the sol-gel process in a temperature range of 450–800°C, but the grain size is difficult to be controlled [25]. Thus, the application of ZnWO4 photocatalyst has been limited, and an energy saving and environmently friendly synthesis method of nanoscale tungstate has received extensive attention.
To date, as far as we know, the synthesis of ZnWO4 photocatalyst by microwave-assisted method is rare. Wu et al. have reported a microwave solvothermal route to synthesize ZnWO4 nanoparticles at 160°C. However, the route needed longer time (1–3 h) and organic solvent (ethylene glycol) [29]. Therefore, the development of fast and environmently friendly microwave-assisted methods for the synthesis of ZnWO4 nanocrystals is of great importance for broadening and improving their industrial applications. In this paper, we first successfully obtained high crystallinity ZnWO4 photocatalyst with a microwave-assisted process by several minutes and using water as solvent. Compared with the conventional methods, microwave irradiation is preferable due to its unique effects, such as volumetric heating, higher reaction rates, shorter reaction time, selectivity energy saving, and being environmentally friendly. During the degradation of rhodamine B (RhB) under UV light irradiation, the ZnWO4 exhibited high photocatalytic activities. The measurements suggested that photocatalytic property of the sample is related to the crystallinity, surface area, and dimension of particles. Moreover, the catalyst is relatively stable and can be reused.
2. Experimental Section
2.1. Synthesis
All syntheses were performed using a commercial multimode microwave synthesizer coupled with an automation system (Initiator 8 Exp). The reactions were conducted in 20 mL vessels. In a typical synthesis of the ZnWO4 powder, all the chemicals were of analytical grade and used without further purification. Sodium tungstate (Na2WO4·2H2O) and zinc chloride (ZnCl2) were the staring materials. Na2WO4·2H2O (0.14 g), ZnCl2 (0.13 g), H2O (10.0 mL), and poly(ethylene glycol) (0.12 g) were mixed. When the vessel was protected by a sealing cap, it was then transferred into the microwave cavity, and the temperature was increased rapidly to 180°C at a rate of 50°C/min. The reaction was performed at 180°C for several minutes, and the reaction vessel was quickly cooled to room temperature by a forced-N2 flow. The as-synthesized ZnWO4 nanocrystals were collected by centrifugation, washed with distilled water and absolute ethanol several times to remove impurities, and finally dried in vacuum at 80°C for 4 h.
2.2. Characterization
The morphology and microstructure of the sample were observed with a JEM-2010 transmission electron microscope operated at 120 kV. Further structural characterization was performed on FEI Tecnai F20 high-resolution field-emission transmission electron microscope (HRTEM) operated at 200 kV. XRD patterns of ZnWO4 photocatalysts were recorded by a MiniFlex II X-ray diffractometer operated at 40 kV and 40 mA using Cu K radiation ( nm). UV-Vis DRS was performed on a Hitachi U-3010, and BaSO4 was used as a reference. Fourier transform infrared spectra (FT-IR) were recorded on a Perkin-Elmer 1600 FT-IR spectrometer with a KBr disk. BET surface area was determined by nitrogen adsorption isotherm measure-ments at 77 K on a Micrometrics ASAP 2010.
2.3. Measurements of Photocatalytic Activity
The photocatalytic activity of ZnWO4 catalysts was evaluated by degradation of RhB under a 300 W UV irradiation. ZnWO4 photocatalyst (25 mg) was dispersed in RhB solution (10 mg/L). Before UV irradiation, an adsorption-desorption equilibrium was established by ultrasonic and mechanical stirring for 30 min. After that, the solution was exposed to UV light irradiation under magnetic stirring. A little amount of reaction solution for UV-Vis spectroscopy analysis was taken from the photoreactor at appropriate time interval.
3. Results and Discussion
The phase composition of the samples prepared at different temperatures was analyzed by X-ray powder diffraction (XRD). As shown in Figure 1, there was no obvious ZnWO4 phase formation at 140 and 160°C. A sharpening of the peaks is observed at 180°C, and all peaks can be indexed in reference to pure ZnWO4, space group P2/c, and unit cell parameters consistent with those reported in JCPDS 15-0774. Therefore, it is reasonable to deduce that the increase of the microwave temperature improves the crystalline of ZnWO4 powder. Thus, the temperature increase stimulates effectively the crystallization of ZnWO4 nanoparticles.
The growth process ZnWO4 nanocrystals was monitored by investigating the products obtained at different stages of the reaction using XRD techniques. Figure 2 shows the XRD patterns of ZnWO4 samples irradiated at 180°C at different reaction stages. XRD patterns could be easily identified as a pure monoclinic wolframite structure ZnWO4 based on a JCPDS Card (no. 15-0774). The results indicated that the intensity of the diffraction peaks strengthens with the increase of reaction time, especially in the (010), (100), (011), (110), (111), and (021) crystal planes of ZnWO4. Small intensity (010) peak can be found in XRD patterns with 5 min reaction time. When the reaction time extended to 15 min, the (010) peak appeared. These results show that reaction time has an influence on the phase formation of ZnWO4. It also suggests that microwave method can achieve crystallization of samples in higher kinetics, which economized the energy and shortened the time.
The FT-IR spectrum of ZnWO4 powders is shown in Figure 3. The bands at 463 cm−1 and 585 cm−1 are ascribed to the bending vibrations of W–O. The peaks at 702 cm−1 and 827 cm−1 are ascribed to the stretching vibrations of W–O. There exists a band at 872 cm−1 that arises from the bending and stretching vibrations of Zn–O–W [30]. The bands at 1401 cm−1, 1468 cm−1, 1541 cm−1, 1622 cm−1, and 3449 cm−1 are assigned to the O–H stretching and the H–O–H bending vibrations [31]. The weak bands at 2850 cm−1 and 2920 cm−1 are ascribed to the C–O vibration of CO2 in atmosphere [32]. The characteristic bands of the ZnWO4 indicated that the ZnWO4 formed.
The TEM images of ZnWO4 catalysts prepared at 180°C for various times are shown in Figure 4. The ZnWO4 sample prepared at 180°C consists of the rodlike particles. The TEM images show that the length of ZnWO4 nanorods is about 26 nm and diameter is about 12 nm after 5 min of microwave irradiation. With the increase of irradiation time from 5 min to 15 min, the dimension of ZnWO4 nanorods increased. It can be seen that the reaction time plays a crucial role in diameter of the samples. The selected area electron diffraction (SAED) image recorded from the sample formed by 10 min microwave radiation indicates the single-crystal nature of the particles. This is verified by high-resolution field-emission TEM (HRTEM) image of ZnWO4 nanocrystals where d-spacing of about 0.586 nm is detected and well related to (010) interplane distance.
ZnWO4, as a semiconductor with a bandgap () around 3.9–4.4 eV, has high photocatalytic activity under UV light. The photocatalytic activities of as-prepared samples were tested via degradation of aqueous RhB under UV irradiation. The UV-visible absorption spectral changes taking place during the photodegradation of RhB for samples and photocatalytic kinetic curves of samples are shown in Figure 5, respectively. The results show that the sample prepared at 140°C has the highest photocatalytic activity, and after 6 hours of irradiation, the degradation rate of RhB can be nearly 98.01%. The kinetics curves of photodegradation of RhB are shown in Figure 5(d) where the curves 1, 2, and 3 are related to samples prepared at 140, 160, and 180°C, respectively.
The linear relationship between and time demonstrates that the photocatalytic degradation of RhB follows a pseudo-first-order kinetics: where is normalized RhB concentration, is the reaction time, and is the reaction rate constant (min−1). The figure also shows that the degradation rate of samples prepared at 140°C is the best (curve 1), the reaction rate constant of which is calculated to be 0.6798 min−1. The degradation rate of samples prepared at 160°C is center (curve 2), the reaction rate constant of which is calculated to be 0.6760 min−1. The degradation rate of samples prepared at 180°C is the lowest (curve 3), the reaction rate constant of which is calculated to be 0.4133 min−1. The sample prepared at as high temperature as 180°C exhibits the lower ability to transform RhB compared with those prepared at 140–160°C. This indicates that the crystallinity structure of photocatalyst is the vital factor that affects the photocatalytic activity of materials.
To obtain the information about the specific surface area of the as-prepared ZnWO4 samples, BET N2 adsorption analysis was performed. As shown in Figure 6, the nitrogen adsorption isotherm belongs to type II. The analysis showed that the specific surface areas of the samples prepared at 160°C and 140°C were 25.05 m2/g and 28.10 m2/g, respectively. The experimental results revealed that the specific surface area of samples prepared at 140°C is higher than the sample prepared at 160°C. Therefore, these demonstrations indicate that photocatalytic properties of ZnWO4 can be significantly improved by specific surface areas [33]. Figure 6 inset shows the photocatalytic effect of ZnWO4 prepared at 140°C for 5 min. We can see that the color of RhB gradually changes from violet red to shallow. This result coincided with the UV-Vis absorption spectra (Figure 5(a)). To evaluate further the photocatalytic activity, the final RhB solution was tested for the carbonation rate. The carbon content of nondegradated RhB solution was 6.445 m2/g, and the presence of carbon was not detected in the final RhB solution, which suggested that the dye almost completely was mineralized into CO2 and H2O.
In this work, we also studied the photocatalytic degradation of ZnWO4 prepared at 180°C for different reaction times. The UV-visible absorption spectrum and dynamics curve of the aqueous solution of RhB with ZnWO4 under exposure to the ultraviolet light lamp for various durations are shown in Figure 7. The results show that the sample prepared at 180°C for 5 min has the highest photocatalytic activity, and after 6 hours of irradiation, the conversion of RhB can be nearly 92.12%. Figure 7(d) is kinetics analysis of photodegradation of RhB, curves 1, 2, 3, and 4 represent photocatalytic kinetic curve of samples prepared at 180°C for 5, 10, and 15 min and no catalyst, respectively. The figure shows that the degradation rate of samples prepared for 5 min is the best (curve 1), the reaction rate constant of which is calculated to be 0.4133 min−1. The degradation rate of samples prepared by 10 min is intermediate, and the reaction rate constant is calculated to be 0.3762 min−1. The degradation rate of samples with reaction time of 15 min is the lowest (curve 2), the reaction rate constant of which is calculated to be 0.1261 min−1. Curve 4 shows almost no degradation of RhB after 6 hours of irradiation. When the reaction time is 5 min, samples have poor crystalline, small particles, and good dispersion, which lead to the higher photocatalytic activity. When the reaction time extended to 15 min, the sample has the best crystalline, large particle size, and large aspect ratio, but its photocatalytic activity is poorer than that of the sample prepared by 5 min [34]. This is consistent with previous conclusions. From the above analysis, we know that ZnWO4 nanopowders prepared at 180°C for 5 min have better photocatalytic activity, and its photocatalytic effect is shown in Scheme 1. Therefore, the crystallinity and particle size play important roles in photocatalytic activity of as-prepared ZnWO4.
Figure 8 compares the activity of ZnWO4 for photodegradation of RhB under a different reaction condition. It is observed that the ZnWO4 materials prepared at 140°C for 5 min have the maximal degradation rate. With higher reaction temperature, a decrease in photocatalytic activity is observed. These results can be explained by the poor crystallinity at low temperature, which leads to good catalytic activity. Also, with the extension of reaction time, the photocatalytic activity lets down which can be attributed to the large particle size.
On the basis of the above experimental observation, photocatalytic mechanism for ZnWO4 photocatalytic degradation RhB is speculated (Scheme 2). ZnWO4 energy band structure was composed by discrete, full-of-low-energy electron valence band (VB) and empty high-energy conduction band (CB); the valence band and conduction band are separated by the forbidden band. When the energy of absorption light is greater than the band gap, the valence electrons are stimulated to the conduction band, making the conduction band with charge, which has a reduction and the valence band resulting hole (h+) with oxidation. Simultaneously, the poor crystallinity leads to abundant lattice defects acting as holes [35]. These free electrons and holes migrate to the catalyst surface and react with adsorbed water, dissolved oxygen, which generate the high activity of hydroxyl radical () and superoxide anion (), further react with organics in the dyes, and ultimately degraded to CO2 and H2O [36].
In addition, we repeated degradation of dye RhB three times with samples prepared at 180°C for 5 min to further study the stability of photocatalyst ZnWO4; the degradation rate remained at 90%. The experimental results showed that the catalyst was relatively stable and can be reused.
4. Conclusions
In this paper, the ZnWO4 nanoparticles were successfully synthesized by the microwave process. It is possible to control effectively the particle size and crystallization of ZnWO4 by adjusting the reaction temperature and reaction time. Comparing the photocatalytic property of ZnWO4 prepared at a different reaction time and temperature, we conclude that photocatalytic property of the sample is related to the crystallinity, surface area, and dimension of particles. The photocatalytic activity of samples prepared at reaction temperature of 140°C and reaction time of 5 min is the best. Furthermore, the ZnWO4 powder products showed stable photocatalytic activity for the degradation of RhB under UV light irradiation.
The authors acknowledge the financial support of Scientific Research Fund of Hunan Provincial Education Department, China (11C1205), and Provincial Natural Science Foundation of Hunan, China (13JJ6041).
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portoghese Traduzione di amphibious
Copyright © 2014 by HarperCollins Publishers. All rights reserved.
Video: pronunciation of 'amphibious'
Esempi di frasi che includono amphibious
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I suggest that the Russians were using some sort of amphibious vehicle or maybe a landing craft.The Times Literary Supplement (2014)
An amphibious vehicle manned by volunteers is offered to ship us out but I am sure they have far more pressing cases.Times, Sunday Times (2014)
His interest in amphibious vehicles has garnered attention recently.Times, Sunday Times (2013)
British amphibious operations had succeeded in the past when they had been directed against targets where the navy could deprive the enemy of supplies and reinforcements.The British way in Warfare - 1688-2000 (1990)
Given the lead time indispensable to a huge amphibious operation, a commitment was needed forthwith.Nemesis: The Battle for Japan, 194445 (2007)
His preferred plan was to mount amphibious operations against northern Sumatra and Singapore.The British way in Warfare - 1688-2000 (1990)
The number of troops committed to operations in the colonies or to amphibious operations around the periphery of the enemies' coastline were negligible.The British way in Warfare - 1688-2000 (1990)
They were to man small boats laden with explosives, deployed to meet American amphibious landings.Nemesis: The Battle for Japan, 194445 (2007)
We were in the last stages of launching Britain's first wartime amphibious landing in years.ONE HUNDRED DAYS (2003)
The plan was to make an amphibious landing and strike at night.Times, Sunday Times (2006)
All are capable of amphibious operations and can carry 1,000 marines and scores of tanks and armoured personnel carriers.Times, Sunday Times (2013)
He promised amphibious vehicles to deliver supplies, manpower to fill sandbags and military expertise to help with logistics.Times, Sunday Times (2014)
The amphibious landing support ship has a huge flat deck that is ideal for holding large numbers of people relatively comfortably.Times, Sunday Times (2015)
Two amphibious vehicles rolled into the county yesterday to transport people and supplies.The Sun (2014)
Until now the only access to the villages has been by boat or a tracked amphibious vehicle that has been acting as a taxi.Times, Sunday Times (2014)
Tendenze di amphibious
Usata occasionalmente. amphibious è tra le 30.000 parole più utilizzate del dizionario Collins
Guarda l'utilizzo nel periodo:
amphibious in altre lingue
Inglese britannico: amphibious ADJECTIVE
In an amphibious military operation, army and navy forces attack a place from the sea.
A third brigade is at sea, ready for an amphibious assault.
Parole prossime a amphibious
Traduzione amphibious dal Inglese a Portoghese Collins


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Gremlins 3 direct to DVD?
We've heard of a string of poor choice direct to DVD sequels, The Lost Boys 2 being just the latest one, well now there's news that another great franchise is about to get the same treatment, in Gremlins 3!
According to reports both Joe Dante and the producer Michael Finnell have revealed that Warner Brothers are working on developing it and that neither of them are involved. Dante says it fair and square:
"Gremlins was governed by the technology that produced it. Now it would be CHI [CGI - glad to see Clint makes the odd typo too, he is human after all!], and you could do anything. There may be places for the jokes to go...But you've got a company who owns the rights to a movie that they don't quite understand. I think it's going to be difficult for them to make another one"
Moviehole carry the news from Empire Magazine.
I can hardly believe they'd consider such a thing. In my mind there are three things that made the Gremlins films so good. The first is the fact that they were limited in the technology for the creatures and we got those excellent puppets, the second is the superb comic scripting and the Hollywood take off scenes with the Gremlins, and the third was a boyhood crush on Phoebe Cates.
Nowadays, with the CGI, I think the creatures will lose their charm, and I think the clever and witty script will be mishandled by a team who just can't stand up to Dante's work. Cheap DVD release it will be, and pretty damn poor if you ask me too. Oh, and even if Cates is in it, I can't see it pulling me back, can you?


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A Frenzied Dream
All a fury, the green
wilderness buzzed with hurried friction.
Bloody streams, their power
expressed alongside grinding gears of clockwork,
present a weary scepter
in a long-forgotten dream.
How disjointed, this dream
did form- The lines of red reacting sourly with green.
Taken in hand is thy volunteer scepter,
and between the two: a silent friction.
Insects return to their feverish clockwork
as the sky bends and mutes its power.
Glowing figures transmit unseen power
in a marshland where unencumbered dwarves dream
of distant clockwork
that is hidden by vibrant green
pastures devoid of friction.
Approaching with corrupted vision is the scepter.
Stabbing into softened earth, the scepter
dispenses it's selfish power,
and causes among the soil's inhabitants a friction
which disrupts their wistful dreams.
The glowing figures are driven from the land of green,
and the pastures are consumed by hungry clockwork.
Refugee skeletons descend into waters that are foreign to crushing clockwork
and beyond the reach of the scepter.
Streaks of green
and vengeful titans attempt to dilute the waves' power.
Monstrous clouds shatter like glass and threaten to split open the dream
while the air turns electric with villainous friction.
Marching for salvation despite the friction,
those determined souls escape the clockwork
and flee their world which is merely one's dream.
Returning to it's weary state, the scepter
relinquishes it's power
as the vision concludes with red once more consuming green.
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This increase in oil prices has caused the freight and trucking industries costs to rise significantly during last six months.
He will be the sole financial of the company but may likely welcome other business partners when need for expansion arises. Wise Business Plans provides both strategic business plans and general business plans for transportation and freight companies of all sizes.
Doe will continue to increase prices at a standardized rate of markup to ensure the profitability of the business. However, if you have hundreds of items, condense your product list categorically. The Company is registered as a corporation in the State of New York.
In progress Creating Official Website for the Company: In Progress Purchase of the Needed furniture, office equipment, electronic appliances and facility facelift: A primary concern for the Company is its ability to price its services affordably during times of economic recession or spikes of oil prices.
The Trucking Company, Inc. We will work hard to ensure that get repeated business from any business deal we execute and also we will encourage our customers to help us refer their friends to us.
List your business with websites that help people find transportation, such as Paratransit Watch. Generally, the trips are same-day return.
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Doe intends to implement marketing campaigns that will effectively target individuals and businesses within the target market. Promotional Plan Identify ways to promote your business, such as becoming a state-registered business so government agencies provide your contact information when they work with people who need transportation services.
In Progress Establishing business relationship with key players in the industry networking and membership of relevant organizations and chambers of commerce: We have perfected our plans to charge competitive rates since we have minimal overhead compared to our competition in the industry.
Trucking operators often find transportation and logistics business plans can be vital to planning routes and suppliers and looking ahead to the future of the company in a changing economic environment.
We will ensure that we leverage on price to win over customers; our prices will be affordable and negotiable. Explain how you plan to offer these services, including registering with your state and contracting with Medicaid.
Gross receipts increased by The Company will offer its clients the ability to manage all of their localized or long distance hauling needs through one business that will provide its clients the ability to manage their shipments in a cost and time effective manner.
The interest rate and loan agreement are to be further discussed during negotiation. Include the costs of your vans and ambulances as well as any specialized equipment that goes into them. Include the wages and benefits you plan to pay your drivers as well as expenses such as office equipment, computers and software required to make transportation schedules and track payments.Business Plan for the Transportation Industry in Uganda and East Africa.
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Distribution Statement. No restrictions. This document is available to the public. Security. Business Plan Transportation & Logistics The trucking industry is a vital part of the American infrastructure, keeping the country's economy moving as goods progress from supplier to customer.
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Start Your Plan No contract, no /5(56). Automotive, Travel & Transportation Trucking Business Plan Sample. Use this sample business plan to get your trucking business on the road. FREE PowerPoint Presentation for Banks, Investors, or Grant Companies! Executive Summary. The purpose of this business plan is to raise $, for the development of a trucking and transportation company while showcasing the expected financials and operations over the next three years.Download