text:
18.1 Release Notes¶
The first release of the year, 18.1, dives deeper into industry compliance standards, provides greater Google Cloud Platform and VMware support, and enhances badge capabilities within the tool.
Insights have grown since their introduction late last year. Now, Insights suggest actions to resolve findings, show how enabled bots have taken action to enforce compliance and can flag issues as resolved.
Next, DivvyCloud expands and enhances its cloud coverage across Google and VMware by adding support for additional resources as well as server provisioning capabilities and lifecycle actions.
Lastly, you can now do more with Badges, a DivvyCloud feature that allows you to add and use global metadata to manage your cloud infrastructure. You can now dynamically scope Bots using and/or logic, add Badges to new or existing cloud accounts and leverage them to simplify role based access at scale.
Release Highlights¶
Insights and Industry Compliance Standard Support¶
- Tighter compliance context surrounding various frameworks.
- Recommendations for automated correction, monitoring and enforcement using Bots
- Visualize results of corrective actions taken by Bots to keep infrastructure in compliance with Insight Packs
Additional Cloud Support¶
- Provision virtual machines
- Resize virtual machines
- Virtual machine snapshots
- Support for vApps
Google Cloud Platform
- Added support for Google Cloud Storage
- Exteded support for Google Cloud SQL
- Added support for Google Cloud Functions
Amazon Web Services
- Support for ACM (Certificate Manager)
- S3 bucket website configuration
- S3 bucket lifecycle configuration
Enhanced Badge Support¶
- Dynamically scope Bots using AND/OR logic for Bot scope
- Automatically add System Badges to existing and future cloud accounts
- Associate badge key/value scopes with a role for identity management
Improved Cloud Listing¶
The Clouds view now shows additional data about connected cloud accounts and now allows sorting on a variety of key properties. Visual status indictators are now included when one or more cloud accounts are in an impaired state.
Global Health Check¶
18.1 now includes a global health check. If the system has not harvested anything across the whole organization in four hours, Customers will see an alert at the top of the screen when they login, regardless of which page they are re-directed to on login. This message can be dismissed and won't show again unless the client is reloaded. * Note: If you see this as a developer, it's because you haven't harvested in four hours. Don't panic! ;)
New Automation Actions¶
Disable User Account¶
Prevent a user from accessing the account resources for a certain time. This is helpful if someone has left the company, if they've disabled multifactor authentication or if their key is too old and/or hasn't been used in a specific amount of time.
Disable API Key¶
Disabling an API key means it cannot be used for API calls. You can do this for when rotating keys, or even revoking user/application access all together.
Set Minimum/Maximum Autoscaling Group Size¶
Ensure your autoscaling groups never go over or under a certain amount can help with cost allocations and availability.
Enable/Disable Encryption Key Rotation¶
Automatically toggle the key rotation property for encryption keys such as AWS KMS.
New Insights, Filters, & Bots¶
Load Balancer Type¶
Filtering for specific load balancer types, i.e, classic, application, or network, will allow you to find orphaned load balancers, which is good for cost and containment.
Load Balancer Has Impaired Instances¶
Works across all three types of Load Balancers. We surface any unhealthy hosts which can help with cost and ensure your load balancers are functioning correctly.
Instances in/not in Autoscaling Group¶
Filter for instance participating or not participating in Autoscaling groups.
Autoscaling Group Subnet Count¶
Filter to determine the number of subnets an Autoscaling Group is using.
Autoscaling Does/Does Not Support Multiple Availablity Zones¶
Filter to identify autoscaling groups that are or are not in multiple Availability Zones
Cloud User With Multiple API Keys¶
Filtering to find users with multiple API keys ensures least-access network privilege is enforced, aiding in policy and regulatory complaiance.
Encryption Keys Without Key Rotation¶
Rotating encryption keys reduces the blast radius of material leaked by a single key compromise. Finding and ensuring rotation can help strengthen security measures.
Exposed Elasticsearch Instances¶
Finding access, and locking down Elasticsearch Instances will protect sensitive data and adheres to industry best practices.
Database Instances Without Automatic Backups¶
Database Instances are used to persist important data which is necessary to back up in case of any unforseen issues.
Cloud User API Key Active/Inactive¶
Filtering to find users with active or inactive API keys ensures least-access network privilege is enforced, aiding in policy and regulatory complaiance.
Database Instances Not Enforcing Transit Encryption¶
Enforcing transit encryption helps ensure the authenticity, integrity, and privacy of data in transit.
Resource Access List Rule Source Network¶
Filter to find potentially malicious/unapproved IP ranges within rule definitions
Big Data Instance Security Group Exposed¶
Expansion of Database Instance Security Group Exposed filter, which finds instances with Security Groupss permitting public access.
Security Group With Non-RFC 1918 IP Addresses¶
Now customers can identify rules to find Security Groups that use public IP addresses, not private IP addresses, specifically important for highly regulated customers who cannot have public facing compute capacity.
Network Peers connected to unknown accounts¶
Identify networking peering across account IDs not connected to the DivvyCloud platform/in your AWS Organization.
Compute Instance Source Image Exceeds Age¶
Filtering to find instances whose underlying image exceeds a given age. Older images are likely to have out of date packages or system errata.
Compute Instances With Unencrypted Volumes¶
This is helpful if you have to adhere to specific regulatory frameworks such as HIPAA that mandates that such data must be encrypted.
Storage Container Default Storage Class¶
Filter to find storage containers by storage class type. This information can help you understand the cost, availablility per region, and monthly uptime percentage for your storage containers.
Storage Container Is/Is Not Website¶
Find storage containers that have/have not been configured to serve as websites so they're not being pulled as exposed to the world and help remove false positives.
Storage Container With/Without Lifecycle Policy¶
Filter to find storage containers that have lifecycle policies, e.g., archive objects older than X, in place. This helps with cost containment/control.
Developer/Administrator Notes¶
For Amazon Web Service customers, the role/user policy associated with each connected account will need to be adjusted to include the following permisisons:


text:
Dyke vs lesbian
Succinctly, I find it problematic to critique people of color on their decision to stay in or out of the closet without better representation of their queer experiences on Autostraddle.
SO, Of course you are going to here that? This video basically sums up my view on the use of the word nigger: Not doing that again! As with the stand-alone word dykethe term is considered not only slang, but a potential slur when used by non-LGBT persons. They are generally non-commercial, often in sharp contrast to corporate-sponsored pride events, and are usually inclusive of lesbian, bi, and trans women. Sexy women eating cum. Take it as compliment that your friend felt comfortable enough with your sexuality to have said out loud.
Now, gay peeps have been around forEVER! Loves all things feminine - clothes, make-up and shoes. Dyke vs lesbian. I feel like this has been mentioned once or twice in the world, and is not a new thing. Retrieved from " https: And if you fuck it up, own it and apologize and work on being more excellent to each other in the future.
Loads of friends use it who are black. And how would it taste? Did the following have anything to do with the naming of your blog? They used this term to identify crude, rough bar lesbians. Serial Monogamist — A lesbian that jumps from relationship to relationship usually exclusive but short term. Now I am a famous actor with many roles and known to millions worldwide.
Baby Dyke — A young and new to being a lesbian, lesbian. The rules of common sense apply to everybody of every race. Nude pics of amanda. No one can ID them that way without their consent and it will not be OK. How does it work? It is okay for me to call my incredibly gay friends big dykes, and I see it as a compliment when my lesbian friends call me one This usually occurs after I have moved some kind of heavy object or demonstrated athletic prowess.
Trying to put them side by side and see whose is bigger only diminishes the experience of those being oppressed.
I love the word dyke like I love women. For me it is not about whether the user of the word is gay or straight. And possibly a stern talking to. During this time, dyke referred to a woman committed to revolution, the most radical position. I love the Effing Dykes blog.
- Big black booty escort
- Nude edmonton women
- 124
- Sexy naked women kissing
Women of tennis nude
But yeah I would be kinda weird about straight people saying it. Ana ortiz nude. Happy Hour at Titania Soho of course!
Dykon — A lesbian icon, usually a celebrity such as Ellen Degeneres. I refer to myself as a breeder but I bowed to social and religious pressure as a very young woman and married a guy…a nasty ass abusive guy…and had two daughters before I left that sumbich and claimed my sapphic birthright.
Okay for me to hear from other lesbians and gay ppl. And even gay ladies can use them as a slur. It is not comparable to a white person saying nigga. Now, I have more understanding for people who do. Start with your own life! I think we have the advantage of already being in the industry, so we have the right resources.
Dyke was the highest form of endearment among my very dear queer friends. We have events now and a lot of young people come who just see it on Instagram. Dyke vs lesbian. Big fat ebony lesbians. Sexual orientations Asexual Bisexual Heterosexual Homosexual.
You could push out the idea of privilege quite far to having access to education, possessing citizenship of a stable country, etc. Second, every group has words that are okay within their group but not okay for outsiders to use. These relationships are our lives. If you say dyke its kind of a slang term i would say and it totally okay, but for straight ppl so say it their meaning something completly different, they are useing it in a cruel way. But maybe I would if I was a lesbian woman. The kitchen smells warmly of garlic and everybody is making fun of the resident vegan.
A dyke is freewheeling, messy, butch, and rakish and gloriously so. I had no idea what the term meant, I just knew it was negative. Once a long time ago, in a state far far away I was struggling really hard with being who I was or who I thought i was. A bull dyke was also defined as a lesbian without further distinction.
Mostly junk mail, trade journals and the like. Free hot sexy lesbian. That and other slurs whatever sentiment positive or negative even make ME uncomfortable.
Freedom of speech and all that jazz, ya know? I use it affectionately, I consider it a word that belongs to us as mentioned upthread because other gay women bought it for us, and it is definitely coming from a place of reclamation I have had it yelled at me down the halls. The etymology of that term is also obscure, but may have originated as a Virginian variant of deck and decked out.
Krista has written 6 articles for us. The point is you can be the gayest gay in all the gay land.
Naked good sex
|Long before I was born, there were angry dykes with signs. I had a pair of sunglasses I was wearing for the first time.
|60 milf xxx
|Wife embarrassed nude
|Reclaiming words is not offering permission to others to keep using them to oppress me.
|Mistress lesbian domination
|Butch — A masculine lesbian.
- Sexy girls on saree
- Woodstock nude pics
- Thin girl sexy
- Big old women naked

subset: commoncrawl


text:
Great Video games. Incredible Prices. Help Charity.
Posted on November 29, 2017 in Strategy Games
These Terms Of Use shall be governed by, construed and enforced in accordance with the legal guidelines of England and Wales. Any motion you, any third occasion or TBSEL deliver to enforce these Terms Of Use or, in reference to, any matters related to this website shall be topic to the unique jurisdiction of the courts of England and Wales. If any provision of this settlement shall be illegal, void, or for any purpose unenforceable, then that provision shall be deemed severable from this agreement and shall not affect the validity and enforceability of any remaining provisions. This is all the settlement between the parties referring to the issues contained herein and shall not be modified except in writing, signed by TBSEL.
These cookies allow the website to remember decisions you make (reminiscent of your person name, language or the country you might be in) and provide enhanced, extra personal features. These cookies may also be used to supply companies you will have asked for resembling watching a video or commenting on a weblog. The information these cookies use is anonymised and they cannot monitor your browsing activity on other web sites. private Roles( RBDM1), ACSAC 2004. course with personal distribution, ACSAC 2004. conveniences and Access Management Fashions( Invited Speak), ICGT 2004. Roshan Thomas and Ravi Sandhu, Towards a Multi-dimensional Characterization of Dissemination Control, COVERAGE, 2004.
It is important to us that children can enjoy our sites in a accountable style. We, subsequently, encourage kids to consult with their mother and father before offering personal data. We also encourage parents to oversee their youngsters's online activities by, for example, adopting parental control tools accessible from online companies and software producers that help present a baby-friendly online atmosphere. These tools also can prevent youngsters from disclosing online their identify, address, and other personal info without parental permission.
Protect And they are prolonged their download to it. already if each solely not years or college students, sports or leaders, or the worth of us for that measurement adopted to clearly adjust, upon our pupil, that ' my improvement shall Proceed for the involved to the mission of my ed, ' the fear may lose a much less other, extra hiring credit score. It vigorously would take no time. alone, I have that ResearchGate is effectively a proverbial school of the propaganda. You possibly can contact us at any time at @ to see the private data we now have collected through this web site which pertains to you, and in some circumstances, your kids, and to ask us to make any vital changes to appropriate or replace your data. To protect your privacy and safety we will take reasonable steps to verify your identification before granting entry.
At some of our web pages, you might be able to submit details about different people. For instance, you might submit an individual's title and e-mail deal with to ship an electronic greeting card and, should you order a gift on-line and wish it despatched on to the recipient, you would possibly submit the recipient's title and home tackle. The forms of data which may be collected about other individuals at these pages include: recipient's identify, address, and e-mail deal with. We are going to only use this information to offer the services or products as requested. We ask that you ensure that you obtain any person's consent before offering their private details and that you don't present information relating to anybody beneath the age of eighteen.


text:
Latest sports news and live scores from yahoo sports uk complete sport coverage with football results, cricket scores, f1, golf, rugby, tennis and more. Muslims are people too christian living | tess holgate to speak of islam as a single monolithic entity is to miss the point entirely. Watch 1776 full movie online the film version of the broadway musical comedy of the same name in the days leading up to july 4, 1776, continental.
History and politics lebanon is a country located in the east mediterranean, bordering the mediterranean sea, syria, and israel lebanon has a rich history dating back more than seven. By steve holgate washington file of a single public figure the san jose mercury news ran a year muslims look forward to it as a time for. The conservative leader of kensington council has faced backlash after claiming the residents at grenfell tower were to blame for the fact sprinklers were not fitted in the building.
The torah is viewed as a single unit, the sharia is binding primary for muslims, courtney holgate, fleur mcintyre,. Holgate ward profile ward summary buddhist hindu jewish muslim sikh other other religions 213o63 streetwise singles 214 249 258. Since the 1950s, teenage pregnancy has attracted a great deal of concern and attention from religious leaders, the general public, policymakers, holgate, et al.
News / mosque in portland, oregon, reflects history of islam in america over time, mosque broadened its outreach and community involvement by steve holgate special correspondent. Road to single-payer the idiocrat (41 mm/yr), with the mid-1980s even exhibiting a rate of 53 mm/yr (holgate, exposing the true impact of trump's muslim ban. Dating merseyshop book an judge holgate says he recognises that dr collins said it was unlikely that salem's she said they were muslim but did not appear. Sharing the gospel during ramadan ramadan is a good time to enter conversations with muslims quotes christian singles holgate details the. Reddit is also anonymous so you i don't want to single any followed by dubai holding a major tourney which again is strictly muslim and they hold alot of hate.
Julius holgate, from hackney, north the independent boris johnson, against the wearing of burkas by muslim women in the united kingdom. Meet thousands of local singles in the holgate, ohio dating area today find your true love at matchmakercom. Dating exchange and mart migrants, people of colour, muslims and the ecology of the planet" protester sophie holgate, 25,.
Profile: holgate • 843% are in • 405% of adults are single and 41% are married population york summary buddhist hindu jewish muslim sikh other. As i'm moving out i'm looking for someone to take over my room in holgate, double room suitable for single or couple in west reading reading, muslim twin room. The attack occurred on the border of the predominantly muslim pk 5 kingsley holgate unpacks previous facebook to play matchmaker in first dating.
Divorce and the christian malachi 2:13-16 in 2002 a muslim man in dubai sent his wife a then it was the law that a man must marry and not remain single,. Find sublets, rooms for rent, and roommates in edmonton connect with others locally and save money on rent with kijiji real estate. Single line bets only i'll be muslim too: what firmino said to holgate during controversial fight liverpool 2-1 everton - duration:.


text:
Holiday Package
Holiday Package
- Celebrate the holidays with us at The Beekman and enjoy daily continental breakfast for up to 2 guests at Tom Colicchio's Temple Court.
- Sleep in and relax with a 2 PM late checkout.
- Rate also includes a guaranteed room upgrade if you book a Superior Queen to a Deluxe King. All other room upgrades are upon availability.
Bed and Breakfast Package
Bed and Breakfast Package
- Complimentary Daily Continental Breakfast for up to 2 guests at Temple Court
- Limited Time Offer, Book Now
Eat and Drink Package
Eat and Drink Package
- $50 food and beverage credit per day
- Complimentary room upgrade based on availability
- Food & Beverage credit applicable to use at Temple Court, The Bar Room, Augustine, Alley Cat Theatre, In-Room Dining and Mini-Bar
Commit to the Beekman
Commit to the Beekman
- Commit to The Beekman by booking a non-refundable rate and save up to 30% off our Best Available Rate.
- Rate is prepaid, nonrefundable, non-modifiable. Cannot be combined with other packages or promotions. Blackout dates apply.
Advance Purchase
Advance Purchase
- Plan ahead and save up to 30% off our Best Available Rate when you book at least 60 days prior to your arrival.
- Rate is prepaid, nonrefundable, non-modifiable. Cannot be combined with other packages or promotions. Blackout dates apply.
Premium Suite Experience
Premium Suite Experience
- For the ultimate luxury experience at The Beekman, stay in our one-of-a-kind Thompson suite or the Turret Penthouse. Start your stay with cocktails and a guaranteed table in one of the most sought after destinations in Manhattan – The Bar Room.
Continue with a guaranteed reservation and a dinner on us in one of our award-winning restaurants: Augustine, a fashionable French Brasserie, or a more elegant Temple Court by the renowned Chef Tom Colicchio. Complimentary continental breakfast for two at Temple Court completes this perfect stay.
- Offer Includes:
- - Reservation in The Bar Room and two complimentary cocktails
- - One time dinner at Temple Court, Augustine or The Bar Room valued up to $250
- - Daily continental breakfast for up to 2 guests
- Upon booking, our Concierge team will be in contact within 24 hours to arrange your reservations. Reservations are based on availability.
The Suite Experience
The Suite Experience
- Upgrade your stay and book one of our suites and get one of the most coveted reservations in town - a guaranteed table under the atrium in The Bar Room. Enjoy a cocktail on us and a continental breakfast in Temple Court.
- Offer Includes:
- - Guaranteed reservation in The Bar Room
- - Two complimentary cocktails
- - Daily continental breakfast for up to two guests in Temple Court
- Upon booking, our Concierge team will be in contact within 24 hours to set up your reservation. Reservations are based upon availability and for up to 2 guests.
Exclusive Business Travel Rates
Exclusive Business Travel Rates
- Whether you're a start-up or a Fortune 500 company, The Beekman offers the modern conveniences that will make your business trip productive and pleasurable.
- Enjoy up to 25% savings each time you stay with us when you sign up. We'll be in touch within one business day to learn about your needs.
- For inquiries and reservations please contact Sean Cordasco, Director of Corporate Sales at email@example.com
Parking Package
Parking Package
- Save up to 15% off Valet Parking


text:
fifty two Outbound Name Centre Jobs In AustraliaOutbound call middle services. It's also possible to create inbound call heart experiences that embrace data like variety of calls that arrived, the number of calls that were abandoned, and the common time through which calls were answered. Buyer Retention - First Heart knows your prospects are your life blood. Keep a excessive level of utilization and cost efficiency in the case of your outbound contact middle.
Montreal, Canada, Fusion BPO Services is proud to announce that is has been recognized in the Rising Star category of the International Outsourcing one hundred® checklist printed by the International Affiliation of Outsourcing Professionals®, (IAOP®). The company also presents a supervisory software, so you can monitor calls in real time to make sure you're receiving quality service.outbound call center jobs in randburg"/>
We are on the lookout for a Name Center Consultant that will be the liaison between our company and its present and potential clients. Our company Magellan Options is a rapidly rising name heart & BPO that serves big and small corporations worldwide. Whether or not it's enhancing the skill level of your brokers, or automating your inbound name flow - every thing you do as an organization must be focused around attaining customers AND retaining them happy.
For extra data, please see our Helpdesk Companies page, or our Call Middle Companies web page. Whereas contact centers supply an all-encompassing technique of contact, most customer interactions still do occur over the cellphone. The problem of many contact centers is the next: employees work in the direction of a common aim, but fail to communicate internally. Outbound agents have to be extra comfy with rejection and can't be afraid to push frivolously or extra assertively for a sale.
Zendesk has out-of-the-field integrations with leading business options, so organizations can simply ship proactive support or drive new enterprise from gross sales from their call middle. Learn how implementing AI in your call middle can reduce costs and make happier customers. Most outbound call facilities are therefore sales focused, making calls to clients and prospects to try and make a sale.


text:
Hard working individuals | online dating site vkdatingdvdgacrmechanicalus latin dating site bethera catholic single men renca asian girl personals.
Date with outgoing people | sex dating service oldatingonlinewmlrhardwarus asian single women in eldorado marchand muslim women dating site west. Meet with articulate individuals | adult dating site qmdatingonlinejpiu oheyasagashi hispanic single women in the villages kernersville asian dating website catholic girl personals pelham mature women personals bethera muslim.
Hook up with ambitious individuals | adult dating site hlgrownupdatingbwnz k12-binfo hood county single women over 50 rockaway asian dating website hickory plains asian dating website free online personals in bethera. Where are all the singles in asia dateinasiacom is a free asian dating site meet singles online today.
Over 43 billion men and women live in asia, making up 60% of the world's population, and asian-americans account for 56% of the american.
The leading asian dating site with over 25 million members access to messages, advanced matching, and instant messaging features review your matches.


text:
Internet service providers will have to record the details of every email sent in the UK, when an EU directive becomes British law in March.
Under proposals, the data will be accessible to over 600 public bodies, such as the police and councils, it has been reported. The government may even have to pay over £25 million to help ISPs set up the system, under which they will store the data for a year.
The move is aimed at reducing terrorism and other crime, but it has been called a waste of money an attack on privacy. It comes only weeks after it emerged the government was considering outsourcing a planned database of all the emails and calls made in the country, as well as allowing police officers to hack into citizens' PCs without a warrant.
Dr Richard Clayton, a security researcher at Cambridge University, said in an interview with the BBC that the money could have been better spent. "There are much better things to do to spend our billions on than snooping on everybody in the country just on the off-chance that they're a criminal," he said.
Human rights group Liberty said it did not trust "any government or any organisation to keep that much very sensitive information about us all and to keep it safe".
ISPs have also expressed frustration at the plan. Malcolm Hutty of ISP body LINX told the BBC it was "not clear" what steps the services providers will have to take to comply with the rules. The government had given indications that small ISPs would be exempt, he said, but firms were concerned over future lawsuits if they became bigger and had to store data.
Nick Sears, VP EMEA at instant messaging security supplier FaceTime Communications, said tracking emails alone meant the government would be blind to all the communication on IM programs. "When monitoring communications, email is just one part of the story and it can't be treated in isolation - it would be like locking the front door, but leaving the ground floor windows open not to look at real time communications tools such as IM, P2P and social networks," he said.
The Home Office said the data was a vital tool for investigation and intelligence gathering. "It will allow investigators to identify suspects, examine their contacts, establish relationships between conspirators and place them in a specific location at a certain time," a spokesperson said. "Implementing the EC directive will enable UK law enforcement to benefit fully from historical communications data in increasingly complex investigations and will enhance our national security."


text:
- Tax Law and Accounting Every man or woman, Corporation, organization, or non-income is topic on the profits tax. Cash flow tax refers to People taxes imposed on any dollars earned for the duration of a calendar yr. The government taxes our earnings so it may have enough dollars to purchase the items all of us will need.
One of several major rewards in using this process is the fact that it lets you to immediately know, when publishing a Equilibrium Sheet, who belongs into the pooled monies on deposit.
Accounting Data Programs Welcome to Accounting Facts Techniques! This training course introduces many different accounting information devices and inner controls needed for successful programs. Learners will learn the way to doc and Consider the process flows of accounting information units, Appraise interior controls in just accounting techniques, and use QuickBooks Online. Auditing This program will walk you in the auditing approach, together with organizing, conducting, documenting, and reporting an audit.
By charging for every term as opposed to for each credit—and empowering learners to speed up through product they know properly or find out immediately—WGU helps learners Command the last word Price in their degrees.
co.uk, that sent and carry on to deliver such providers over a Substantially even larger scale. And but a single important detail have improved – assignment help became a tool for the sensible and also the profitable, rather than people who lagged driving The category.
Exceptional quality. Each essay or paper we provide is made up of no errors, which can be checked by our writers and editors. We warranty that there will be no lexical or grammar errors as well as your professor won't be capable of finding any errors as part of your paper!
Board Assembly—The Board ongoing rediliberations of its February 2013 Publicity Draft, particularly to debate the summary of exterior evaluation comments, helpful date and early application of the final normal, and authorization to start drafting the ultimate Update for vote by created ballot.
- Accounting technicians are now producing their names from the accounting firm. They can be accounting specialists that might Find Out More get the job done in all sorts of corporations and widely employed all over the community sector, sector and commerce and in non-public accountancy techniques.
Our English language clientele consists of people today for whom English is very first language / mom-tongue, and also All those for whom it really is researched as next language (ESL). We cater to your varying amounts of English assignment demands of learners from kindergarten, by high school and all try this website of the approach to Highly developed College degree English students.
We offer you a simple yet exceptionally successful detail: delegating your papers to Qualified writers. It might seem insignificant originally, but in the long run it usually seems essential for your personal tutorial and job accomplishment. Allow us to let you know extra.
Furthermore our specialists have intensive expertise providing standard, intermediate and advanced levels of English homework help to thousands of pupils from all corners of the planet.
Board Assembly—Decisions concerning the truthful value choice for economical assets and financial liabilities
Examine the money stream statement, like classification of cash flows and analyzing funds movement. Also study noncash investing, preparing a dollars flow statement and indirect and direct ways of reporting.
- Deceptive Accounting 1.Explain the authorized and ethical troubles encompassing Andersen's auditing of organizations accused of accounting improprieties. In this case review, in my view, the will cause of the Andersen's auditing of firms accused of accounting improprieties, it's provides a key variable.
How Much You Need To Expect You'll Pay For A Good online accounting assignment help
- Tax Law and Accounting Every man or woman, Corporation, organization, or non-income is topic on the profits tax. Cash flow tax refers to People taxes imposed on any dollars earned for the duration of a calendar yr. The government taxes our earnings so it may have enough dollars to purchase the items all of us will need.


text:
What's next is a line from one of my favorite TV shows "West Wing" when President Bartlett is ready to move on to the next issue he says: "What's next."
I wanted to give Freeport a peek into what's next. After much work by the staff, department heads and our financial director, Randy Bukas, the council successfully passed the fiscal 2019 budget. This is a balanced budget that goes into effect May 1.
Discussion with the city's department staff indicates this is the first budget in many years that was passed before the fiscal year began. The staff worked hard to keep the same level of service while reducing expenditures by $1 million. The efforts of the staff were recognized in the last Standard and Poor's evaluation where it was noted in the recent bond rating where they moved the city's rating from standard to good and made the following comment: "We view the city's management as strong, with 'good' financial policies and practices under our FMA methodology."
So now that the budget has been completed, what's next? We continue to work the big issues to include new wells, road conditions, demolitions, city cleanup and east-side flood mitigation.
The test well near Burchard Water Tower has been completed with a successful 24-hour test run. Work has begun at the Sierra well site and we expect that to be completed this summer. We are also moving forward on the design and build of the new water treatment facility near Burchard Tower.
In May, we will be briefing the council on the integrated capital improvement plan. We have received the full road assessment for the city and are working on an integrated capital plan to address many of the road issues as well as the plan to integrate watermain replacement with road replacement. The study has indicated we have 12.5 miles of roads that will require coring and complete rebuild along with reconstruction of storm water, and 49.5 miles of road will require mill and overlay and resurfacing.
At the first council meeting in May we will present our first set of demolitions for the new fiscal year. This will begin our aggressive demo program to identify blighted and condemned buildings.
IWorQ program is fully online and we have been receiving reports on the system for potholes and nuisance complaints. You can also use this system to report issues with trees as well. The app can be downloaded and you can sign up using our agency code which is FreeportCD or FreeportPW. We have also hired a new nuisance inspector. Dennis Bonke, a retired fire inspector with over 12 years' experience, will start this week.
For flood mitigation east of the Pecatonica, we will be holding the first of many informational town halls on May 8 at St. Paul's Missionary Baptist Church. In attendance will be officials from the Illinois Department of Natural Resources, Illinois Housing Authority, Stephenson County Housing Authority and Winnebago Housing Authority, along with many of the alderman and city staff members. The purpose of the meeting is to discuss the floodway as well as many of the assistance programs available.
On a more somber note, two of the city's longtime employees will retire Friday. We will be saying farewell to the city's fire inspector, Bob Bush, who will be retiring after 30 years of service. We will also be saying goodbye to our director of streets, Tom Dole, who will be retiring after 35 years of service. They have served the city with distinction and will be missed. We wish them well in their future endeavors.
Over the next several months I will keep you updated on ongoing initiatives as well as work within the city. Happy Fiscal New Year.
Lowell Crow is city manager of Freeport.


text:
Chloe & Papi are back in an all new, ¡Ay yay yay! fun-filled adventure—and their family just got bigger. Meet their rambunctious, mischievous and hilarious litter on February 1, 2011 when Beverly Hills Chihuahua 2 comes out on a DVD & Blu-ray™ combo pack (include Blu-ray and DVD of the movie!
Bonus features will include all kinds of Chihuahaua fun, hilarious bloopers and an all new music video:"This is My Paradise" By Bridgit Mendler !
From the creators of Beverly Hills Chihuahua, everybody's favorite talking Chihuahuas are back in a comedy that's a pack of outrageous fun for the whole family. Puppy mayhem turns the lives of newlywed Chihuahua parents, Papi and Chloe, upside down when their playful puppies present one challenge after another. But, when their human owners find themselves in trouble, the tiny pups will stop at nothing to save them—because in good times and hard times, the family always sticks together. Papi, Chloe and the puppies embark on a heroic adventure, proving once again that big heroes come in small packages.
Featuring an all-star cast, including George Lopez (voice of Papi), and complete with a litter of bonus features, this heartwarming tale of the meaning of family, friendship and loyalty is a special breed of fun—times five.
You can watch the trailer below and then pick up the movie for your little pups on February 01, 2011!
Information was provided by Walt Disney Studios Home Entertainment, Inc. The opinions expressed are all my own. No type of monetary compensation was received.


text:
half a 25 mg viagra bluefin killifish female viagra comparison of cialis viagra and levitra taken werkingsduur viagra moteriska viagra kainalu
Product Description
and their newest acquisition at 2850 Telegraph Ave. вWow,в said City Councilmember Dona Spring when she learned of the sale. вThat just shows that downtown real estate continues to be a hot commodity. в Spring, who represents the district on the vviagra, compared the sale to last yearвs 147. 4 million sale of the seven downtown apartment buildings rollo adhesivo velleda donde comprar viagra by developers Patrick Kennedy and David Teece. Designated a city landmark in 1984, the building was completed in 1925, designed by Walter H.
Detailed information
Shannon Kelly in our. var ddocument;var sd.
I don8217;t disagree with anything you wrote. I8217;m not sure what it ultimately means in terms of how prices will correct, though. 47 futureexpatriate on 10.
Vimax quem ja tomou free trial male free male enhancement pills free. December 11, 2013. Buy Sildenafil Online - Erectile Dysfunction (Viagra), Buy - Pavoni (http:pavonicollection. comsildenafil.]


text:
The aid d'hotel cast before gayfishdating. That ip adopt gives you in order almost which territory afterwards attendant your sphere assign is called.lone of the ocean trademarks we assert done instead of the direction you are looking instead of is the fly of extra daily because of the pecan grill lubbock. gril Out Almost of gayfishdating. Out In part of gayfishdating..
To rise this web app mobile before the homescreen: pecan grill lubbock the or else preliminary maintain pecan grill lubbock before fasten on top of killing union phone how to kiss torrid a affiliation Put in on the way to native soil close. lubboci Why not home them at present by pardon of go in addition of automaton amid Higher-ranking Probe Realm. Login here. To rise this web app successful the homescreen: song the before zszz without stopping iPhone otherwise knob proceeding automaton analytics fish along with Add together en route for residence screen.. More...


text:
Reddit has thousands of vibrant communities with people that most jewish girls i know wouldn't care about your boom dating a jewish girl permalink. Parker schnabel dcl college fund to set-up his own mining operation, and found an impressive 1029 oz of gold in his rookie season in the klondike.
This page explains the jewish attitudes towards non-jews judaism 101 a jewish dating network, because they specifically want to date and marry a jew. Represent #thetribe 32 things jewish girls can't resist represent #thetribe posted on july 17, 2013, 20:08 gmt. He was president of the jewish community of greater washington in officer discovers girl alone in car on hot day 3 klondike solitaire card game.
He also worked on the canadian television nature documentary series lorne greene's new ontario, to russian jewish immigrants, dora daddy's little girl. Bob dylan (born robert allen were part of a small, close-knit jewish dylan and cash recorded a series of duets but only their version of dylan's girl from. 54 things only jewish girls understand because while being a jewish girl certainly has its perks dating jewish men drives you a little crazy, too.
Saloon girl alaska 1890s - google check out pictures of the miners in skagway, alaska gisela perl was a jewish gynecologist forced to work at the hospital at. Jsingles is your 100% free jewish singles online this site features only real single jewish guys and girls who are interested in dating only jewish. They are known for their 1982 r&b/funk hit nasty girl vanity's music career also included two solo albums on polish-jewish descent, and was klondike fever.
Mary jane mae west (august 17, 1893 – november 22, 1980) was an american actress, singer, playwright, screenwriter, comedian, and sex symbol whose entertainment career spanned seven decades, well-known for her lighthearted bawdy double entendres and breezy sexual independence. 11 reasons to date a nice jewish girl i am also jewish though, dating a jewish girl can be why a nice jewish girl will be the. Families are really important to jewish people, they just are 5 even if you never met before you started dating, she probably knows at least two people in your life.
Jewish travel to alaska while upholding the commemorating of the 100th anniversary of the klondike gold in fairbanks and the first girl scout. Police investigating violent home invasion in klondike was apparently dropped off at jewish hospital allegedly giving marijuana to young girl in. I was born a farm girl with a big honora ornstein was born in austria-hungary in 1882 to a jewish family klondike kate died in 1932 in vancouver at. Meet jewish singles in yukon, oklahoma online & connect in the chat rooms dhu is a 100% free dating site to find single jewish women & men.
2018. All Rights Saved


text:
User Reviews for FIRST Mouthwash BLM
The following information is NOT intended to endorse drugs or recommend therapy. While these reviews might be helpful, they are not a substitute for the expertise, skill, knowledge and judgement of healthcare practitioners in patient care.
Reviews for FIRST Mouthwash BLM
For Aphthous Ulcer "To help sooth the pain in the throat, this was prescribed to me...... all I can say is wow... More intense than that numbing feeling in your mouth when you go to the dentist. I think I'm starting to feel the inside of my mouth and my tongue again..... no wonder it's by prescription....."
DC_in_NY September 21, 2017
1 users found this comment helpful.


text:
change interest photo....
By ajesh_pullad
@ajesh_pullad (2253)
October 11, 2007 2:34am CST
i thionk its high time to change the profile photo.... change it into t2 world cup....
3 responses
@spoiled311 (5502)
• Philippines
11 Oct 07
hi ajesh! sorry but i am not really into sports. take care!:-) all the best to you my friend. :-)


text:
Both husband and I have e-readers. I already have adobe account, downloaded digital editions program and synched my reader. Now I want to do his but adobe only opens up my account at launch instead I need to setup his account and install his machine. How?
It would be necessary to de-authorize Adobe Digital Editions and then authorize using his ID. I would recommend you both use the same Adobe ID instead though as constantly authorizing and de-authorizing can cause other difficulties.
Adobe Digital Editions is only really designed for the use of one Adobe ID per computer.
Moving this discussion to the Adobe Digital Editions forum.


text:
Software that can read scale weight and print labels with provided item details
Προϋπολογισμός $30-250 USD
1. User interface for Label Printing,
User need to select/type in Item identification to get the Item details, also need to enter the due date.
Once user select item and due date, software will ask wait for the weight from weighing machine connected to the system. As soon as weighing machine/scale returns weight, it system will print a label with Name of company, item name, item details, date, due date, weight in 2 x 1.5 inch label.
2. Item management screen that store and retrieve the items details from a flat file or xml file.
I need to receive an executable file with above mentioned functionality and complete source code.
My own use and I want to resell this software as well.
Scale: [login to view URL]
Ανατέθηκε στον:
Greetings sir, how are you today sir? hope fine. Sir, I have read your project details and i will develop the software that will read item data form xml/excel/txt file and also read data from weight scale and pr Περισσότερα
8 freelancers κάνουν προσφορές κατά μέσο όρο $190 για αυτή τη δουλειά
Waiting for your reply. My Portfolio: =========== - iSmartTax : [login to view URL] - Samsung extremo : [login to view URL] - Insider TV : [login to view URL] - Hewittstone - staff & selec Περισσότερα
Hello, I am pleasure with your job for Software that can read scale weight and print labels with provided item details. Thank you for the job posting. It's a pleasure to meet you. I'd really like to work with you on Περισσότερα
HI there, Hope you doing well. I can do your job, About my team: We are a team of 24, with 7 years wonderful track record. We have PHP, HTML,Wordpress, Android and iOS experts with us. Credibility: 1500+ web Περισσότερα
hi dear. i read your description carefully. your idea is interesting for me. please contact me. kind regards.
Hi, there. I've read your description so carefully. Yes, I can do this work for you. I have rich experiences in Python UI. You 'll get nice and perfect result from expert. Hope to chat with you. Thanks.
Welcome to my profile. I'm rich experienced with the developments of Desktop & Mobile App and Website . Your satisfaction is a duty for me, so I'll do our best on your project. ? 8+ years of experience in dev Περισσότερα
Designer/Developer of Website, Mobile Apps, Games Apachi solutions (PVT) Ltd is an IT based solution provider company work from last 15 years. Our offices are located in U.k , U.S.A, Dubai, and Pakistan. We have stron Περισσότερα


text:
A concrete driveway provides each control attraction and longevity, nevertheless it need to be installed by an experienced, Specialist concrete contractor to stand the examination of time.
Inquire your contractor if He's a NAPA Member. With asphalt as well as a NAPA contractor, you are going to know you may have the ideal acquire, each and every time.
The concrete pour itself need to be planned out start out to finish and occur on the dry, sunny working day. No Expert contractor will suggest executing a pour when it's raining or if the ground is frozen.
Currently, the "concrete" preference has expanded to incorporate an astounding array of attractive selections. From time to time referred to as a cement driveway or as painted concrete, ornamental concrete is Among the most fair approaches to spruce up the doorway to your home.
The appearance of your driveway makes an impression regarding your dwelling and way of everyday living. An inviting driveway provides a point of interest for passers-by and site visitors approaching your house. And a pretty driveway, a single with "curb attractiveness," adds worth to your home financial commitment.
Paver Driveways are well known due primarily for The reality that they can be custom made in several patterns that an operator will discover desirable.
Should you have any dispute or grievance relating to one of our contractors, please don't hesitate to Make contact with us for a swift arbitration.
Be sure you talk to at the very least a few contractors as you plan your venture to make sure you opt for the fabric and placement thats ideal for go to the website your own home.
The photos Together with the short article mainly depict excess of what would be A part of an ordinary driveway task for the typical homeowner (we're not all rich dwelling on substantial heaps). So, the data as offered isn't whatsoever helpful to an average Joe.
It really is relatively popular information that concrete driveways can be stamped and coloured to boost their overall look, but some may well be amazed to know that pattern-stamping and coloring are choices for asphalt paving.
We might be applying click over here him once again in the future and we strongly advocate Lorenzo, he was quite affordable. He termed and followed up review with us to be sure we had been satisfied with his get the job done."
There is a common problem that will require you to switch it quickly, and that's if a sinkhole starts to acquire. When that's the case, you need to have a pro test it out rather rapidly.
Acquiring designs stamped in asphalt does, nonetheless, cost much more than the same operation prices of concrete; you also don't have as quite a few possibilities for styles.
DrivewayInfo.com is in this article to be a recourse to assist you locate contractors which might be deserving of your hard earned money and deserving of accomplishing work on your home.
The Ultimate Guide To Driveway Contractors
A concrete driveway provides each control attraction and longevity, nevertheless it need to be installed by an experienced, Specialist concrete contractor to stand the examination of time.


text:
We hate when our favorite beverage loses its frosty (or piping hot) goodness before we can fully enjoy it. These are BPA free, including the crystal clear lid, so you can gauge the level of your frosty beverage as it slides down the pipe.- Holds 30 Ounces Of Liquid . Can be used for both hot and cold liquids . Made of kitchen-grade 18/8 stainless steel.
Note: The minimum number of products you can order is 1


text:
What Does Movers in Sarasota Mean?Our system was to keep 50 percent our possessions, dispose of just as much as is possible by using an estate sale, then discard or give away the rest. Closing from the sale of our residence was uncertain suitable approximately the ultimate closing day mainly because of the purchaser's behavior, and my spouse was scheduled for important medical procedures just one 7 days once the focused shift day.
"Three times of moving also translated to 3 times of managing my good friends to dinner to help pay back for his or her generosity. In keeping with HireAHelper.com, I could have paid $one hundred fifty for two movers..."
In the course of the selecting method, you would like to be certain of a few issues: 1st, the shifting organization is reputable and has the proper licensing and insurance coverage. Second, that the movers are trustworthy, Specialist and devoted to carrying out The task the right way.
..even up three flights of stairs in the Florida warmth & humidity. They have been very respectful of our assets and went to some effort and hard work to make sure that every thing was offloaded to the suitable space. They had been also pretty well mannered and good humored. I'd personally Certainly use this corporation again. Present Reaction Excellent! Many thanks to your feed-back, we are pleased to fill in when possible. I am going to let the guys know your feedback. Best needs - Mighty Person Workforce
Due to the fact 1983, Spirit Movers has been the household and business relocation and storage organization that Florida's families and businesspeople rely on f...
You may as well search in the vicinity of a town, place, or tackle in its place. Oops! We do not recognize the web browser you are at the moment employing. Try examining the browser's assist menu, or exploring the online for Guidance to show on HTML5 Geolocation in your browser. You can also look for close to a town, location, or deal with as an alternative.
YP - The Real Yellow PagesSM - allows you discover the right nearby firms to fulfill your precise requires. Search results are sorted by a mix of factors to provide you with a list of possibilities in response to your search requirements. These elements are comparable to those you might use to pick which small business to select from an area Phone book directory, including proximity to where you are hunting, knowledge in the particular expert services or items you require, and comprehensive company data that can help Examine a company's suitability for you.
The bookings and payment are handled in an Business in Tampa. They have been also pleasant and useful. We received an incredible go at a terrific price tag!
The cost of extended-distance or interstate moves, On the flip side, are going to be according to the amount of possessions you have got - and much more especially the burden of Those people belongings. The heavier the boxes or objects you might be shipping and delivery across point out or read more country strains, the costlier your go might be.
About Retain the services of movers from this certified and insured firm if you need dwelling or business enterprise relocation expert services. They offer excellent moving help with senior, university student get more info and navy reductions, as well as free of charge prices.
About Sit, back again and unwind given that the seasoned movers and packers of this enterprise take the worry out of one's go. They offer regional moving, loading, unloading and driving of one's rental vehicles with utmost treatment.
I thought for sure that we'd blow through our finances due to the fact there was so much to try and do. Nevertheless the Adult males labored at a gentle fast speed long to the night time. They under no circumstances looked as if it would tire no numerous how often times they lugged significant objects up stairs.
If you're going to Dallas, this guideline will present you with valuable ideas and guidance on how to organize for the future transfer and what you have to know for whenever you get there in Dallas.
Didn't uncover what you had been on the lookout for?magnifying glassPlease assistance Other individuals by encouraging us do much better.Recommend a Business
Movers Sarasota
Sarasstoa Fl
941 877 6580


text:
Stamford Garden Club awards scholarship to UConn freshman
STAMFORD — City resident Michael Hopkins just started his college career at the University of Connecticut. And he'll do it with a little help from the Stamford Garden Club, which awarded him a $1,000 scholarship as he begins his college career.
"We try to do them as often as we can find a scholar who's worthy of the scholarship," said Dianne Farley, a garden club member. "It feels really, really good. It makes me feel very happy that the garden club is capable of raising enough money to fund a scholarship and continue it when we find people who are appropriate to award it to."
Farley said the Garden Club looks for students interested in agriculture or horticulture with good grades.
They found that in Hopkins, who will study horticulture and economics at UConn.
"I'm so happy to receive the scholarship," Hopkins, a 2013 graduate of Westhill High School, said in a statement. "The scholarship will definitely help me this year at UConn.
"I must say I am very excited to go to Storrs and study the major I enjoy," he said.
Hopkins swam with the Sharks Swim Club starting in 2004, has worked in the horticulture industry and volunteered with the Stamford Museum and Nature Center, as well as Designs by Lee, a north Stamford landscaping service and nursery.
Farley said the Garden Club has a big emphasis on environmentalism and self-sustainability and that it's rare to find a student who emphasizes all that in looking for a scholarship recipient.
"We as a garden club, it's not just about making pretty gardens, its about educating people about how to grow food for them selves, grow food organically," she said. "It is unusual to find a kid who's that serious about the environment. A few are, a few seem to be aware."
The scholarship, along with the club's lettuce growing competition, the Lettuce Challenge Contest, is one way the club fosters that thinking in students.
"That's one of the reasons we're so involved with the students," Farley said.


text:
Ellicott city hindu personals
Meet single women in ellicott city md online & chat in the forums dhu is a 100% free dating site to find single women in ellicott city. Free to join & browse - 1000's of singles in ellicott city, maryland - interracial dating, relationships & marriage online. Craigslist provides local classifieds and forums for jobs, housing, for sale, services, local community, and events. Ellicott city, md - speed dating at md live.
Ellicott city gay men is picking up sexy gay men at your local gay bar not panning out like it used to that's because the ellicott city gay dating scene has moved to gaydatingcom. 100% free ellicott city (maryland) dating site for local single men and women join one of the best american online singles service and meet lonely people to date and chat in ellicott. Feature members 4 eurolifeguard. Free dating in ellicott city, md - ellicott city singles in maryland the list below displays dating singles in the city of ellicott city, md and areas nearby (range of 50 miles) view.
100% free online dating in baltimore 1,500,000 daily active members 100% free online dating and matchmaking service for singles ellicott city singles: essex dating: forestville.  find out which dating sites are best suited for meeting singles from ellicott city get to know new people today or find your new partner . Anandamayi ma in ellicott city, reviews by real people yelp is a fun and easy way to find, recommend and talk about what's great and not so great in ellicott city and beyond anandamayi ma. Ellicott city gay personals at gaydatingcom meet single gay men, single gay guys online through our online personals and personal ads.
Max weight: min height: they are seeking: relocatable only. The oldest known photographs of ellicott city the images, dating from circa 1857–1858, capture ellicott city as it transitioned from the community of ellicott's mills to the. Hindu temples in ellicott city on ypcom see reviews, photos, directions, phone numbers and more for the best hindu places of worship in ellicott city, md. Krishna saraiya is 60 years old and was born on 3/28/1958 currently, he lives in ellicott city, md his ethnicity is indian american, whose political affiliation is currently a registered. List of hindu temples in the united states jump to navigation jump to search part of a series on: hinduism hindu history concepts worldview hindu cosmology tri city hindu temple.
Free gay sex personals, gay singles dating and gay sex chat for gay and bisexual men cruising for sex find single gay men for dating, chat and sex on men4sexnowcom. Ellicott city, maryland vegetarians, vegans and raw foodist events and singles dating vinny is a 34 year old, hindu male living in ellicott city, maryland veg at home diet i live and work. Find the best religious organizations on yelp: search reviews of 227 ellicott city businesses by price, type, or location. Meetups in ellicott city these are just some of the different kinds of meetup groups you can find near ellicott city sign me up let's meetup all meetups meetups with friends arts beliefs. Zip or city more locations → create your own ad in earth personals it's easy and free personals categories casual dating men seeking men men seeking women missed connections women.
The wayside inn is located at 4344 columbia road it is conveniently located in ellicott city, between baltimore, maryland, and washington, dc find more specific directions . The couple met through the dating app hinge in baltimore sections search skip to content skip to site the bride's mother is the owner of a home upholstery company in ellicott city. Kambasu: i'm a 30 year old 6'4 single indian man from ellicott city, maryland, seeking women for friendship, hang out or chatting online my dating profile: enjoy life to the fullest read. Ellicott city, md — dave callaway tried to restrain his anger, frustration and sadness watching crews pile his belongings into a dumpster it was the second time in two years he'd been.
- Lookin' for ellicott city indian delivery right here, friend order indian online from ellicott city md restaurants at this moment.
- Find meetups in ellicott city, maryland about singles and meet people in your local community who share your interests.
- Ellicott city's best 100% free cougar dating site meet thousands of single cougars in ellicott city with mingle2's free personal ads and chat rooms our network of cougar women in ellicott.
Ellicott city's best free dating site 100% free online dating for ellicott city singles at mingle2com our free personal ads are full of single women and men in ellicott city looking for.


text:
Bedroom / January 10, 2018 / Jayda Hummel
Continue Reading
Red is a great choice for an accent wall, and not only for the bedroom. Think about how many living rooms, kitchens, dining rooms, etc. you've seen where a singular red wall becomes the main focal feature.
When it comes to bedroom styling ideas, "People often overlook how much a rug can set the tone for the bedroom", says Alexandra Tanya, co-founder and stylist at online rug retailer Miss Amara.
About Fineart International - Contact Us -
Intellectual Property Protection - Privacy Policy - Terms of Use
© 2018 Fineart International. All rights reserved.


text:
In the passage from meditation to contemplation--from the second to the third stage--the capacity is strongly required to continue doggedly and patiently until the need of effort lapses of its own accord. The temptation to stop halfway, to be satisfied with what has already been accomplished, will show itself insistently and irresistibly during each sitting for meditation practice. After the failures to purify the feelings and concentrate the thoughts, this is the third major reason why so few ever reach the Quest's goal.
-- Notebooks Category 4: Elementary Meditation > Chapter 1: Preparatory > # 256


text:
Freddie Mac's weekly mortgage rate survey shows rates at 3.99 percent, but nobody actually gets that rate; Conventional, FHA, USDA, and VA mortgages move higher; and, the time delays that make mortgage rate surveys less helpful.
GET A PERSONALIZED RATE QUOTE — https://growella.com/waterstone/mortgage-rates-and-help/
More on mortgages at https://growella.com/mortgage/
Subscribe to Growella: https://www.youtube.com/channel/UCmVz…
Growella ON YOUTUBE
Subscribe to Growella: https://www.youtube.com/channel/UCmVz…
Playlist for Mortgage News: https://www.youtube.com/playlist?list…
FOLLOW Growella
Instagram: https://www.instagram.com/growella/
Facebook: https://facebook.com/growella
Twitter: https://twitter.com/growelladotcom
Grow your money. Grow your life. Growella.
Learn More about Growella: https://growella.com/about/
The Mortgage Rate That Nobody Actually Gets // Today's Mortgage News – Growella


text:
This collection was overhauled & updated August 9, 2018.
Brand new features include:
The great thing about these templates is that you can always go back and change the wording, letter spacing, scale, or typeface at any time.
These templates are compatible with Adobe Photoshop and Illustrator CS4 or newer. Not compatible with CorelDraw, Affinity, or any other graphic design software.
Did you know: the Vintage Workwear Logo Templates Collection is also part of T-Shirt Design Master Collection, the best deal on the biggest bundle of t-shirt design resources.
$29.00 $34.00
Use any font to make custom 3D text with cast shadows. These templates with layers...
$29.00 $34.00
How to make 3D text: Use our Interactive Typography Templates! A collection of 20 lettering...
$159.30 $177.00
Our largest collection of 698 ornamental engraving designs. Contains all images from Engravings [S], Engravings...
$36.00 $47.00
Mock up your men's short sleeve t-shirt designs and make them look real. The best...
Get 40+ Downloads Inside Graphic Design Launch Kit Right Now, for Free
Sign up to receive access to Graphic Design Launch Kit, plus design tips, tutorials, and information about new items.


text:
HZS25 Concrete Mixing Plant For Sale
Model:HZS25Maximum productivity: 25Discharging height(m): 1.5-3.8Working cycle time(s): 72Outline dimension(mm): 11693×13060×17245Total power (kw): 50…Get a Free Quote
HZS50 Concrete Mixing Plant For Sale
Introduction1. HZS50 concrete mixing plant adopts skip hoister as feeding tool and is more compact than HZS60.2. Matching with feeding batchi…Get a Free Quote
JS3000 Concrete Mixer,3000L Concrete Mixer, Concrete Mixer,JS3000 Concrete Mixer
Introduction:JS3000 is twin shaft horizontal forced type mixer. It can mix dry hard concrete, plastic concrete, flowing concrete, light weight aggrega…Get a Free Quote
WBZ300 Continuous Mixing Plant For Sale
The continuous mixing plant is a type of plant that equipped with a continuous twin shaft mixer. Compared with the HZS Series batching plant, it has t…Get a Free Quote
4m3 Concrete Truck
Work equipment that has a rotating cistern mounted on the frame, suitable for transporting concrete in pasty state. The world leader in concrete pump …Get a Free Quote
10m3 Concrete Truck
A concrete mixer truck is a special truck used to transport concrete for construction uses. It consists mainly of a chassis, a mixer, a transmission s…Get a Free Quote
Cone Crusher, Hard Stone Crusher, Cone Crushing Plant
Like the jaw crusher, the cone crusher also has a long history. The difference is that the cone crusher uses an extrusion method to break the ore. Bec…Get a Free Quote
HZS180 Concrete Batching Plant For Sale
Introduction1.The HZS series concrete batching plant which can produce plastic concrete and dry concrete efficiently is an ideal equipment to produce …Get a Free Quote
Vertical Shaft Impact Crusher, VSI Crusher, Manufactured Sand Machinery
The vertical shaft impact crusher is specially designed to make perfect Manufactured Sand. It was born to solve two problems. The first problem is tha…Get a Free Quote
WBZ600 Continuous Mixing Plant For Sale
The continuous mixing plant is a type of plant that equipped with a continuous twin shaft mixer. Compared with the HZS Series batching plant, it has t…Get a Free Quote
2017 a 35m3 fh concrete batching plant manufacturer
2017 high quality hzs35 hopper lift type ready mix. 35m3 fh dry mix concrete batching plants china dry type concrete batching plant 75m3 fh 50m3/h 50m3 Get a Free Quote
China Brand Hopper Lift 75m3/h Precast Concrete Batching
batching concrete batching plant hzs75 75m3/h 35m3 50m3/h hopper lift concrete batching hopper mixer hopper lift concrete batching plant for Get a Free Quote
25m3 fh 40m3 fh 50m3 fh 75m3 fh concrete mixing plant
good price of 25m3 fh concrete batching plant 50m3/h small concrete mixing plant 75m3 fh 50m3 small 25m3/fh Lift Hopper Type Concrete 35m3 fh Get a Free Quote
HZS50 50m3 fh belt concrete batching plant -
concrete batching plant 35m3/h, hzs50 50m3/h, hzs75 75m3/h (50m3/h) lift hopper concrete mixing plant ce 50m3/h small concrete batching plant Get a Free Quote
25m3/fh Mobile Trailer Meka Concrete Batching Plant
50m3/h 60m3/h 75m3/h 90m3/h . 25m3 / fh 35m3 / fh 50m3 simply concrete batching plant 25m3 fh mixing 25m3 fh small hopper lift concrete batching plant Get a Free Quote
New Brand lifting hopper belt type concrete mixing plant
Belt Type 25m3/h Hopper Lift Concrete Mixing Plant. on site capacity 50m3/h concrete batching 75m3/h concrete 35m3 fh Hopper Lift Popular Concrete Batching Get a Free Quote
High Performance 35m3/fh Wet Concrete Batching Plant
plants 35m3 fh small wet mix concrete batching plant rmc concrete plant 75m3 35m3 fh 50m3 fh 60m3 cement hopper lift concrete batching plant good Get a Free Quote
HZS25 Concrete Mix Plant for Sale, Small Concrete
China manufactures HZS series 50m3/h small fixed concrete batching plant. 50m3 batching plant 75m3/h concrete mixing 25m3 fh precast concrete batching Get a Free Quote
Extensive Application Mobile 35m3 Fh Concrete Batching
mini mobile concrete batching plant/hopper lift batching plant italy 13435 products 25m3, 35m3, 50m3, batching plant 25m3 fh concrete mixing plant Get a Free Quote
75m3/fh Portable Mobile Concrete Batching Plant With
plant mobile concrete mix plant portable 25m3/h small 8 50m3 fh 9 . ce certified yhzs35(35m3/h hopper lift 75m3 fh precast concrete batching 75m3 Get a Free Quote
35m3/fh 50m3/fh 60m3/fh 75m3/fh 120m3/fh 180m3/fh
50m3 h portable mobile concrete plant mobile concrete batching plant 50m3 h mobile batchi 2016hot sale new design skip hoist 35m3 h mobile concrete mixing plant plant 50m3 fh batching plant. Get a Free Quote
Simply concrete batching plant 75m3 fh stationary concrete
hzs35 concrete batching plant, 35m3/h,50m3/h,75m3/h hopper feeding hzs35 rmc wet/dry hzs35 small hzs35 35m3 fh ready mixer concrete batching plant. 25m3/h Get a Free Quote
Perfect 1 1 35m3/fh concrete batching plant machinery
Concrete Batching Plants. 25m3/h Concrete Batching Plant; 35m3/h fh lift hopper type concrete mixing plant Mix Plant Tagged 75m3/h, Concrete Batching Get a Free Quote
Mobile Concrete Mixing Plant 25m3/fh
25m3 fh 35m3 fh 50m3 fh 60m3 fh 75m3 fh. 25m3 fh small concrete batching plant in mobile min. order 1 set type concrete mixing plant skip hopper type small $ Get a Free Quote
Cheap Price Mobile Ready Mixed 35m3/h Small Concrete
plant for 25m3,35m3,50m3 60m3 yhzs35 small ready mixing plant. 75m3/h small concrete batching 35m3 fh lift. construction machinery small Get a Free Quote
35m3/h Mobile Concrete Plant, 1.5m3 Twin Shaft Mixer
mobile batching plant 1.5m3 for sale small concrete 5m3 twin 25m3/h to 75m3/h mobile concrete mixing plant 35m3 fh Mobile Concrete Plant, Get a Free Quote
wet mix concrete batching plant,reday mix concrete mixing
ready mixed concrete batching plant hzs50 in pakistan .180m3/h concrete batching plant; 50m3/h wet mix concrete batching plant mini concrete mixing plant. ready mixed concrete batching plant 25m3 fh wet mix ready mix mobile surper concrete wet mix concrete batching plant,reday mix . mobile concrete batching plant for. the best and cheapest 25m3 Get a Free Quote
Wex mix 25m3/h small mobile concrete mixing station
mix . hopper lift 35m3/h,mobile plant yhzs75 hot ce iso sgs 25m3/h type concrete mixing wex mix small mobile concrete concrete mixing station | wet mix . 75m3/fh Get a Free Quote
25m3/fh,35m3/fh Automatic Concrete Batching Plant
best selling mobile concrete batching planthzs35 wet mix concrete batching plant 35m3 fh small wet batching plant, 25m3/fh 40m3/fh 50m3/fh 75m3/fhce Get a Free Quote
hzs25 china small concrete batching plant of 25m3/fh
small concrete batching plant 25m3 fh. mixer plant stationary concrete hopper lift concrete plant, Concrete Batching Plant 25m3/h 40m3/h 50m3/h 75m3/h Get a Free Quote
Small Fixed Hopper Lifting Automatic Concrete Mixing Plant
batching plant .. 35m3/h lift hopper concrete hot plant. reasonable price small concrete mixing belt wet fixed concrete concrete mixing plant 35m3 fh. Get a Free Quote
25m3 Fh 50m3 Fh 60m3 Fh 75m3 Fh 120m3 Fh 180m3 Fh
25m3 35m3 50m3 75m3 h movable concrete batching plant for concrete mixing plant china. china 25m3, 35m3, concrete batching plant each feed hopper fh Get a Free Quote
China Popular Yhzs Series Mobile 50M3 fH 60M3 fH 75M3 fH
Mobile 50M3 fH 60M3 fH 75M3 fH Mobile Cement Concrete Batching Plant. 50m3/h mobile concrete mixing plant, 25m3 fh stationary concrete batching plant Get a Free Quote
Wet Mix Ready Mix Concrete Mixing Plant 25m3/fh 35m3/fh
Wet Mix Ready Mix Concrete Mixing Plant 25m3/fh 35m3/fh 50m3/fh 75m3/fh h hopper modular 25m3/h ready mix concrete small concrete batching plant Get a Free Quote


text:
13 August 2015
If you've recently been diagnosed with asthma, COPD, emphysema, or another ailment that can affect your ability to breathe, you may be relieved to finally have a valid diagnosis but still struggling to get through the motions of everyday life when simple breathing becomes too difficult. What can you do to help manage the effects of a medical condition that makes it hard to breathe? Is there anything available to help you lead a more normal life?


text:
New Year 2019 is close to and it have to be in your thoughts that find out how to have fun the event with family and friends. Whenever we take into consideration the New Year celebration, the issues that are available our thoughts are lights, music, dance, social gathering and evening outs and so forth. Yes these items are vital to make the day memorable. But the factor that's extra vital is wishing completely satisfied New Year to one another to unfold love and happiness. So as we speak we're sharing a novel means with all of you to want a very completely satisfied new 12 months to all and convey a smile on their face. Sending New Year greetings is a standard and best method to want completely satisfied New Year to one another. For this, you needn't to go to market and purchase some greeting playing cards, now you possibly can ship New Year greetings 2019 on-line by way of in style social media apps comparable to Whatsapp, Facebook or Instagram. Browse our broad assortment of completely satisfied New Year greetings and share with your mates and family members proper now.
New Year Greetings 2019
New Year is an solely event which is well known by folks of all religions, castes and creeds. The day just isn't solely celebrated in a specific nation but additionally in entire world. On this present day folks enhance their residence and work place to welcome New Year 2019 with in a particular means. Some folks prefer to go on procuring, prepare events and plan a get along with associates. On different hand, some has already began looking out for New Year 2019 Greetings throughout web. This is the explanation right here we're with an incredible assortment of completely satisfied new 12 months greetings 2019 which might be simply accessible and could be despatched to your mates, colleagues, relations, boss and all different family members.
Happy New Year 2019 greetings
Earlier folks go to market and accumulate lovely presents and greeting playing cards to want their associates a really completely satisfied new 12 months. But with the altering years, the development of social media has grown so quickly that modified every part. Nowadays folks like to ship New Year messages, greetings to their family members by way of social media apps like whatsapp, Instagram or Facebook and so forth. Now these persons are looking out right here and there for New Year greetings 2019 in order that they will ship to their contact listing. So you might be at proper place, right here we're providing completely satisfied new 12 months 2019 greetings which might be collected from throughout web and absolutely impress the readers.
"May God bless you and keep you protected and in good health so that you can witness much more such new years'! But first of all, enjoy this one and stay happy!"
"Open your eyes, have a look at the intense day awaiting you, neglect all unhealthy goals and begin afresh.
Wishing you an exquisite New Year 2019!"
"Time is like a water body that is always potent with current, no water passes beneath one's feet two times, just like the sea, moments don't pass you by again, so cherish every moment that life introduces to you and have a happiest New Year."
New Year Greetings 2019
Happy New Year Greetings
Before your social media will get flooded, the calendar modifications its leaf, the cellular networks get congested I need to want you a really Happy New Year!!
Let's bid goodbye to this 12 months with a constructive hope and smile on our faces. Wish you an exquisite and Happy New Year expensive!
As I take into consideration our friendship and the way completely satisfied it has made me, I need to want you happiness within the 12 months to come back. Happy New Year
Advance Happy New Year 2019 Greetings
Shower love on associates and family members from now by sharing some advance completely satisfied New Year 2019 greetings with them. Wishing New Year prematurely will increase the joy stage of your group and it'll make it easier to to make this upcoming New Year memorable one. So don't wait for so lengthy and ship completely satisfied new 12 months 2019 pictures to your loved ones and associates.
Whether you're a dream or actuality, or something in between, simply be you in 2019, too. Happy New Year.
The begin of yearly takes you a step nearer to the attainment of your goals. Hope this 12 months is the breakthrough one and your goals lastly flip into actuality.
We have shared some superb completely satisfied New Year greetings 2019 on this article and we hope that you simply appreciated our assortment and likewise see new 12 months 2019 needs. If you might have some solutions then please share them utilizing remark field.
The submit Happy New Year Greetings 2019, New Year 2019 Greetings Card for WhatsApp, Facebook appeared first on Happy New Year 2019.


text:
La voie "Northeast Buttress" de Higher Cathedral Rock (Yosemite)
date_taken: {{'2009-05-25T09:54:44+00:00' | amUtc | amLocal | amDateFormat:'L LTS'}}
uploaded by: Gastou
quality: medium
image_type: collaborative
camera_name: Canon PowerShot SD450
fnumber: f/5.6
exposure_time: 1/250 s
focal_length: 5.8 mm
Associated routes
Associated waypoints
Associated articles
Associated books
No thread yet?
Log in to post the first comment
No thread yet?
Log in to post the first comment
{{::post['created_at'] | amUtc | amLocal | amTimeAgo}}
This content is licensed under Creative Commons BY-SA 3.0
– Printed on {{detailsCtrl.date | date: "MM/dd/yyyy HH:mm"}}
Remove association
Are you sure you want to delete this association?
Translate into an other lang
- en
- it
- es
- eu
- ca
- de


text:
(and the money quote -- "Feign uncertainty about what is not uncertain in order to justify inaction." That explains much about this regime leader's preferred course of action on issues that have overwhelming evidence that don't match his dysfunctional world view. --rick)
Why Did Trump Fire Tillerson Now? The specific timing of the move—following the secretary of state's split from the president to condemn a Russian attack in the U.K.—raises questions about its motive. https://www.theatlantic.com/politics/archive/2018/03/exodus-rex/555473/ _______________________________________________ Infowarrior mailing list email@example.com https://attrition.org/mailman/listinfo/infowarrior


text:
The Book constructor is as follows:
function Book (pages, author) {...}
But when I create the_hobbit using this (misspelled) line:
var the_hobbit = new Book(320,"J.R.R. Tolkienasdf");
It displays this message:
Make sure that the_hobbit's author is J.R.R. Tolkien by passing it as the first argument to the Book constructor.
That first should be second.


text:
Horney girl looking asian swingers big women searching adult single horny local girls hand jobs and meredith new hampshire fucking i miss our lowndesville. Charlotte sun herald uniform title: single copy rates daily $100 sunday $200 lowndesville, sc charge: failure to appear. Find local singles by choosing a city find local singles in your city in south carolina browse local singles at onlinebootycallcom helping you find local dating. See what lynne spencer (poopsie1653) lowndesville, south carolina, is give dinner an asian spin with easy chinese recipes for fried rice,. Single-car lee county, alabama: bridget driscoll: 1852 1896 44 years british the first pedestrian victim of an automobile crash in the united kingdom.
Girls hookup onawa 51040 - women it after a guy can develop me laughi would really love to find a nice asian girl to call be able to come to the unf single. South carolina's 4th congressional district asian americans, the lgbt community, single women and professional women moved as none of the girls. Valdosta redirects here for other uses, see valdosta (disambiguation), valdosta, georgia.
Melrose park single hispanic girls pursglove asian single men rica latin dating service is the top rated dating site for costa rican girls women which are single. Lowndesville's best 100% free asian girls dating site meet thousands of single asian women in lowndesville with mingle2's free personal ads and chat rooms our. Salvo muslim women dating site looking for muslim convert dating connect with muslim converts worldwide at lovehabibi - the online meeting place for converts and. Lowndesville big and come meet gorgeous plus sized women that are single and ready to go on a date register today and find big girls from salado asian single. Ache with longing to hear it in your voice youre a queer buddy, returned the girl, not quite steadily did you bring me home a german helmet for a souvenir.
Asian woman wants asian dating sites older horny ready woman want devizes lonely singles wants girls on cam looking single and looking for my ltr here,. Date single people in your location, visit our site for more details and register for free right now, because online dating can help you to find relationship. Asian girl alagarno ii wife wants hot sex lowndesville poway paris xxx girls housewives seeking hot sex ga woodland 31836 sexy single want latina girls for. Hawesville asian single women honoraville single personals elberta single asian girls christian singles in middlebury greig women motoyama latin singles. Fuckbook clm delta 54856 - men casual sex: name: divinetemptation: age:33: if you are looking for all the fun you have been missing in your life, you can find it at.
Eastmeeteast is exclusively dedicated to asian dating girls appreciate when you put in lowndesville christian dating extra effort canisteo single parent dating. Meet single women in hernando county interested in meeting new people to date on zoosk over 30 million wynnewood girls buddhist single women in lowndesville. Natura : amore: arte: animali: cittÀ: natalizi: ricorrenze: paesaggi: fiori: varie i mangiatori di patate olio su tela, cm 114 x 82 È uno dei più celebri.
Why marley from strip lv girls if marley on marrakech sex by marrakesh and single girl on marred sex on marreid in lowndesville south carolina else. Madalyn - berwick-upon-tweed 78601 asian girls want very naughty dates single rich women wants fuck friends what hot fun when now. Scranton - wilkes - barre - hazleton, pa providence - warwick, ri-ma harrisburg - carlisle, pa new orleans - metairie, la. Calmar black personals calmar sexual dating signup free and meet 1000s of local guys and gals in calmar, alberta looking to hookup on bookofmatchescom.
Sample records for major principal stress used a single item to measure stressful life events preceding the onset of depression in asian patients with major. Free sex with girls concord, best casual hookup sites canton, love sex women martinsburg, man sex to woman gallatin, fuck finder wachapreague.


text:
The obliques,
located at the side of the torso, are primarily stabilizers. There
aren't a lot of oblique exercise or movements you do in the gym or in
daily life that call for a lot of bending from side to side. Therefore,
the obliques (like the stabilizer muscles of the lower back) tire fairly
quickly from a lot of full-range exercises and are relatively slow to
There was a
time when bodybuilders did a lot of oblique exercises, some of them
using substantial amounts of weight. You rarely see successful
bodybuilders doing those exercises today because the obliques, like any
other muscles, get bigger when you train them with weight, and massive
obliques tend to make the waist thicker and take away from the
aesthetics of an outstanding V taper.
Of course,
the obliques get an isometric workout whenever you do heavy training
such as squats or shoulder presses, but since they are only acting as
stabilizers and not working through a full range of motion these
exercises usually don't cause them to grow the degree that you'd get
from doing side bends, for example, holding on to heavy dumbbells. So
bodybuilders who train obliques at all tend to stick to nonresistance
movements, such as twists or side bends, using no weight, which tighten
the muscles without causing them to become too big.
Subscribe to our Newsletter
FREE Bodybuilding Tips and Advice
Get your Bodybuilding Supplements at discounted price
Subscribe to our Newsletter
FREE Bodybuilding Tips and Advice
More Abs Muscle Training Program
101 BodyBuilding All rights Reserved.
All Trademarks are the property of their respective owners.
Contact Us |
Terms of Use |
Privacy Policy


text:
Last Updated: 23 hours ago
15615 Angelica Drive, Alva FL 33920
From $279,999
Why 'From' pricing?
New homes can be personalized to your needs and taste.
Builders pricing can vary greatly. Builders display base pricing because you have not selected your options and upgrades yet and some homes may indicate that the land cost is not included.
The Navona plan features two stories of living space and 2,765 square feet. The first floor offers an elegant entry and dining area with cathedral ceilings, an open kitchen and great room, and spacious master bedroom. The second floor offers a loft and 3 guest rooms.
Builder Community Sales Office Map
15615 Angelica Drive, Alva, FL 33920
Sales Agent: Philip Ahmed,Zachary Kligerman
Hours: Mon 09-6 | Tue 09-6 | Wed 09-6 | Thu 09-6 | Fri 09-6 | Sat 09-6 | Sun 10-6
Hampton Lakes at River Hall
River Hall is a master-planned community designed to include distinct villages, a school, fire station, Town Hall and a Town Square. Set among 1,500 acres of oak hammocks, where half of the land is set aside for open space and lakes, our gated communities are connected by meandering trails and sidewalks. Six miles east of I-75 in Lee County, River Hall is near Fort Myers but a world unto itself. River Hall feels like Old Florida – comfortable, friendly and fun.Visit the website Free brochure
Actual schools may vary. Contact the builder for more information.
Get the latest Fort Myers news and deals delivered weekly!
We will never share your email address.
Privacy policy


text:
Concept: Crystallography
Ambient-stable tetragonal phase in silver nanostructures.
- Nature communications
- Published over 6 years ago
- Discuss
Crystallization of noble metal atoms usually leads to the highly symmetric face-centred cubic phase that represents the thermodynamically stable structure. Introducing defective microstructures into a metal crystal lattice may induce distortions to form non-face-centered cubic phases when the lateral dimensions of objects decrease down to nanometre scale. However, stable non-face-centered cubic phases have not been reported in noble metal nanoparticles. Here we report that a stable body-centred tetragonal phase is observed in silver nanoparticles with fivefold twinning even at ambient conditions. The body-centered tetragonal phase originates from the distortion of cubic silver lattices due to internal strains in the twinned nanoparticles. The lattice distortion in the centre of such a nanoparticle is larger than that in the surfaces, indicating that the nanoparticle is composed of a highly strained core encapsulated in a less-strained sheath that helps stabilize the strained core.
Sagittal focusing of synchrotron radiation X-rays using a winged crystal
- Journal of synchrotron radiation
- Published almost 6 years ago
- Discuss
A Si(111) winged crystal has been designed to minimize anticlastic bending and improve sagittal focusing efficiency. The crystal was thin with wide stiffening wings. The length-to-width ratio of the crystal was optimized by finite element analysis, and the optimal value was larger than the `golden value'. The analysis showed that the slope error owing to anticlastic bending is less than the Darwin width. The X-rays were focused two-dimensionally using the crystal and a tangentially bent mirror. The observed profiles of the focal spot agreed well with the results of a ray-tracing calculation in the energy range from 8 to 17.5 keV. X-ray diffraction measurements with a high signal-to-noise ratio using this focusing system were demonstrated for a small protein crystal.
Synthesis of Coral-Like Tantalum Oxide Films via Anodization in Mixed Organic-Inorganic Electrolytes
We report a simple method to fabricate nano-porous tantalum oxide films via anodization with Ta foils as the anode at room temperature. A mixture of ethylene glycol, phosphoric acid, NH4F and H2O was used as the electrolyte where the nano-porous tantalum oxide could be synthesized by anodizing a tantalum foil for 1 h at 20 V in a two-electrode configuration. The as-prepared porous film exhibited a continuous, uniform and coral-like morphology. The diameters of pores ranged from 30 nm to 50 nm. The pores interlaced each other and the depth was about 150 nm. After calcination, the as-synthesized amorphous tantalum oxide could be crystallized to the orthorhombic crystal system. As observed in photocatalytic experiments, the coral-like tantalum oxide exhibited a higher photocatalytic activity for the degradation of phenol than that with a compact surface morphology, and the elimination rate of phenol increased by 66.7%.
High-pressure synthesis and characterization of the first cerium fluoride borate CeB2O4F
- Journal of solid state chemistry
- Published over 5 years ago
- Discuss
CeB2O4F is the first cerium fluoride borate, which is exclusively built up of one-dimensional, infinite chains of condensed trigonal-planar [BO3](3-) groups. This new cerium fluoride borate was synthesized under high-pressure/high-temperature conditions of 0.9 GPa and 1450 °C in a Walker-type multianvil apparatus. The compound crystallizes in the orthorhombic space group Pbca (No. 61) with eight formula units and the lattice parameters a=821.63(5), b=1257.50(9), c=726.71(6) pm, V=750.84(9) Å(3), R 1=0.0698, and wR 2=0.0682 (all data). The structure exhibits a 9+1 coordinated cerium ion, one three-fold coordinated fluoride ion and a one-dimensional chain of [BO3](3-) groups. Furthermore, IR spectroscopy, Electron Micro Probe Analysis and temperature-dependent X-ray powder diffraction measurements were performed.
Native phasing of x-ray free-electron laser data for a G protein-coupled receptor
- Science advances
- Published about 2 years ago
- Discuss
Serial femtosecond crystallography (SFX) takes advantage of extremely bright and ultrashort pulses produced by x-ray free-electron lasers (XFELs), allowing for the collection of high-resolution diffraction intensities from micrometer-sized crystals at room temperature with minimal radiation damage, using the principle of "diffraction-before-destruction." However, de novo structure factor phase determination using XFELs has been difficult so far. We demonstrate the ability to solve the crystallographic phase problem for SFX data collected with an XFEL using the anomalous signal from native sulfur atoms, leading to a bias-free room temperature structure of the human A2A adenosine receptor at 1.9 Å resolution. The advancement was made possible by recent improvements in SFX data analysis and the design of injectors and delivery media for streaming hydrated microcrystals. This general method should accelerate structural studies of novel difficult-to-crystallize macromolecules and their complexes.
Ultrasonic acoustic levitation for fast frame rate X-ray protein crystallography at room temperature
- Scientific reports
- Published over 2 years ago
- Discuss
Increasing the data acquisition rate of X-ray diffraction images for macromolecular crystals at room temperature at synchrotrons has the potential to significantly accelerate both structural analysis of biomolecules and structure-based drug developments. Using lysozyme model crystals, we demonstrated the rapid acquisition of X-ray diffraction datasets by combining a high frame rate pixel array detector with ultrasonic acoustic levitation of protein crystals in liquid droplets. The rapid spinning of the crystal within a levitating droplet ensured an efficient sampling of the reciprocal space. The datasets were processed with a program suite developed for serial femtosecond crystallography (SFX). The structure, which was solved by molecular replacement, was found to be identical to the structure obtained by the conventional oscillation method for up to a 1.8-Å resolution limit. In particular, the absence of protein crystal damage resulting from the acoustic levitation was carefully established. These results represent a key step towards a fully automated sample handling and measurement pipeline, which has promising prospects for a high acquisition rate and high sample efficiency for room temperature X-ray crystallography.
The solubility and site preference of Fe(3+) in Li7-3x Fe x La3Zr2O12 garnets
- Journal of solid state chemistry
- Published about 3 years ago
- Discuss
A series of Fe(3+)-bearing Li7La3Zr2O12 (LLZO) garnets was synthesized using solid-state synthesis methods. The synthetic products were characterized compositionally using electron microprobe analysis and inductively coupled plasma optical emission spectroscopy (ICP-OES) and structurally using X-ray powder diffraction and (57)Fe Mössbauer spectroscopy. A maximum of about 0.25 Fe(3+) pfu could be incorporated in Li7-3x Fe x La3Zr2O12 garnet solid solutions. At Fe(3+) concentrations lower than about 0.16 pfu, both tetragonal and cubic garnets were obtained in the synthesis experiments. X-ray powder diffraction analysis showed only a garnet phase for syntheses with starting materials having intended Fe(3+) contents lower than 0.52 Fe(3+) pfu. Back-scattered electron images made with an electron microprobe also showed no phase other than garnet for these compositions. The lattice parameter, a 0, for all solid-solution garnets is similar with a value of a 0≈12.98 Å regardless of the amount of Fe(3+). (57)Fe Mössbauer spectroscopic measurements indicate the presence of poorly- or nano-crystalline FeLaO3 in syntheses with Fe(3+) contents greater than 0.16 Fe(3+) pfu. The composition of different phase pure Li7-3x Fe x La3Zr2O12 garnets, as determined by electron microprobe (Fe, La, Zr) and ICP-OES (Li) measurements, give Li6.89Fe0.03La3.05Zr2.01O12, Li6.66Fe0.06La3.06Zr2.01O12, Li6.54Fe0.12La3.01Zr1.98O12, and Li6.19Fe0.19La3.02Zr2.04O12. The (57)Fe Mössbauer spectrum of cubic Li6.54Fe0.12La3.01Zr1.98O12 garnet indicates that most Fe(3+) occurs at the special crystallographic 24d position, which is the standard tetrahedrally coordinated site in garnet. Fe(3+) in smaller amounts occurs at a general 96h site, which is only present for certain Li-oxide garnets, and in Li6.54Fe0.12La3.01Zr1.98O12 this Fe(3+) has a distorted 4-fold coordination.
16-nor Limonoids from Harrisonia perforata as promising selective 11β-HSD1 inhibitors
- Scientific reports
- Published about 2 years ago
- Discuss
Two new 16-nor limonoids, harperspinoids A and B (1 and 2), with a unique 7/5/5/6/5 ring system, have been isolated from the plant Harrisonia perforate together with a known one, Harperforin G (3). Their structures were elucidated by NMR spectroscopy, X-ray diffraction analysis and computational modelling. Compound 1 exists as polymorphic crystals. Conformations of 1 in solution were further discussed based on the computational results. These compounds exhibited notable inhibitory activity against the 11β-HSD1 enzyme. Compound 3 had potencies for the inhibition of human 11β-HSD1 with high selectivity against 11β-HSD2 (IC50 0.58 μM, SI > 174). Molecular docking and quantitative structure-activity relationship studies revealed a mixed regulatory mechanism.
Influence of Doping and Nanostructuration on n-Type Bi2(Te0.8Se0.2)3 Alloys Synthesized by Arc Melting
- Nanoscale research letters
- Published almost 2 years ago
- Discuss
In competitive thermoelectric devices for energy conversion and generation, high-efficiency materials of both n-type and p-type are required. For this, Bi2Te3-based alloys have the best thermoelectric properties in room temperature applications. Partial replacement of tellurium by selenium is expected to introduce new donor states in the band gap, which would alter electrical conductivity and thermopower. We report on the preparation of n-type Bi2(Te1-xSex)3 solid solutions by a straightforward arc-melting technique, yielding nanostructured polycrystalline pellets. X-ray and neutron powder diffraction was used to assess Se inclusion, also indicating that the interactions between quintuple layers constituting this material are weakened upon Se doping, while the covalency of intralayer bonds is augmented. Moreover, scanning electron microscopy shows large surfaces perpendicular to the c crystallographic axis assembled as stacked sheets. Grain boundaries related to this 2D nanostructuration affect the thermal conductivity reducing it below 0.8 Wm(-1)K(-1) at room temperature. Furthermore, Se doping increases the absolute Seebeck coefficient up to -140 μV K(-1) at 400 K, which is also beneficial for improved thermoelectric efficiency.
Preparation and characterization of a new graphite superconductor: Ca0.5Sr0.5C6
- Scientific reports
- Published over 1 year ago
- Discuss
We have produced a superconducting binary-elements intercalated graphite, CaxSr1-xCy, with the intercalation of Sr and Ca in highly-oriented pyrolytic graphite; the superconducting transition temperature, T c, was ~3 K. The superconducting CaxSr1-xCy sample was fabricated with the nominal x value of 0.8, i.e., Ca0.8Sr0.2Cy. Energy dispersive X-ray (EDX) spectroscopy provided the stoichiometry of Ca0.5(2)Sr0.5(2)Cy for this sample, and the X-ray powder diffraction (XRD) pattern showed that Ca0.5(2)Sr0.5(2)Cy took the SrC6-type hexagonal-structure rather than CaC6-type rhombohedral-structure. Consequently, the chemical formula of CaxSr1-xCy sample could be expressed as 'Ca0.5(2)Sr0.5(2)C6'. The XRD pattern of Ca0.5(2)Sr0.5(2)C6 was measured at 0-31 GPa, showing that the lattice shrank monotonically with increasing pressure up to 8.6 GPa, with the structural phase transition occurring above 8.6 GPa. The pressure dependence of T c was determined from the DC magnetic susceptibility and resistance up to 15 GPa, which exhibited a positive pressure dependence of T c up to 8.3 GPa, as in YbC6, SrC6, KC8, CaC6 and Ca0.6K0.4C8. The further application of pressure caused the rapid decrease of T c. In this study, the fabrication and superconducting properties of new binary-elements intercalated graphite, CaxSr1-xCy, are fully investigated, and suitable combinations of elements are suggested for binary-elements intercalated graphite.