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I am so excited today to welcome author Jeanne Bannon to my blog! Jeanne has been a part of the publishing industry for over twenty years, working first as a freelance journalist, then as an in-house editor for LexisNexis Canada. She currently works as a freelance editor and writer and is represented by the Serendipity Literary Agency.... Continue Reading →
Biologizing in the Highlands of Costa Rica
Last week I sent the completed manuscript for Daughter of Aithne to my editor Terri-Lynne DeFino. Now all I can do on that project is bite my nails as I wait for her verdict. Depending on the revisions she requests, we should be able to set a tentative release date in the coming weeks. I've been through... Continue Reading →
Towards a More Positive Take on Sexuality
Those of you who follow my blog know that I am not one to buck the trend - preferring as I do, on most occasions, to skirt the trend entirely. This was my intention with respect to 50 Shades of Grey, released for the silver screen this past Valentine's Day weekend. Not having read the book, I... Continue Reading →
Love is Free
This weekend only, Hadley Rille Books is opening the doors to its very own Love Shack, offering all of its Kindle short stories free, and reducing prices on many of its novels. Eolyn and High Maga are available for $0.99 in their ebook editions, and the short story Creatures of Light can be downloaded free of charge. If you aren't familiar... Continue Reading →
Stories and Giveaways
I'm up on Heroines of Fantasy this week. My contribution to Love Fest 2015 is the short story 'Turning Point', which first appeared in the 2008 winter edition of Zahir: A Journal of Speculative Fiction. It's a magical adventure about a tropical entomologist who nets a handsome faerie. Visit Heroines of Fantasy to read it now. In other news, the... Continue Reading →
No One Can Live Without Love
Nadie debe, nadie puede, vivir sin amor. This is a line from a song by Argentinian musician Fito Paéz. Roughly translated, it means, No one can or should live without love. In a world where vitriol, cynicism, and the sheer sport of cutting down the 'other' seem to be fashionable, it's hard sometimes to keep... Continue Reading →


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|Australian 13th Battalion
Men of the 13th Battalion at Le Verguier, France, where Sergeant Buckley won the Victoria Cross in 1918.
|Commonwealth of Australia
|Australian Army
|Line Infantry
|~1,000 officers and men
|Part of
|4th Brigade, New Zealand and Australian Division (later 4th Australian Division)
|World War I
|Battle honours
|Somme 1916, Somme 1918, Pozieres, Bullecourt, Messines 1917, Ypres 1917, Menin Road, Polygon Wood, Passchendaele, Arras 1918, Ancre 1918, Hamel, Amiens, Albert 1918, Hindenburg Line, Epehy, France and Flanders 1916-1918, ANZAC, Landing at ANZAC, Defence at ANZAC, Suvla, Sari Bair.
|James Murdoch Archer Durrant (later Maj. Gen.)
|Unit colour patch
The 13th Battalion was an infantry battalion raised for the 1st Australian Imperial Force during the First World War. Formed just six weeks after the start of the war, the 13th Battalion along with the 14th, 15th and 16th Battalions were recruited from New South Wales and formed the 4th Brigade. The battalion saw service initially at Gallipoli before being transferred to France in 1916. For the next two years it fought in the trenches of the Western Front, earning numerous battle honours in the process. Following the end of the war, it was demobilised in 1919.
The 13th Battalion was raised in late September 1914, only six weeks after the declaration of war, in New South Wales.[1] After training at the ANZAC Rifle Range in Long Bay, Sydney and Broadmeadows and Williamstown in Melbourne, it left Australia from Albany in late December and arrived in Egypt in February 1915.[2]
Along with the rest of the 4th Brigade, under the command of then Colonel John Monash, the 13th Battalion took part in the Landing at Anzac Cove, arriving late on 25 April 1915.[1] Between May to August, they were then heavily involved in operations to establish and defend the narrow beachhead against Turkish assaults, before being involved in the costly attack on Hill 971 in August.[1] The attack on Hill 60 later on 27 August also resulted in casualties for the battalion and after that they were mainly used in a defensive role until the final evacuation in December 1915.
From there, the battalion was sent to France, following a brief period of training and re-organisation in Egypt, where the 13th Battalion was split and provided experienced soldiers for the 45th Battalion, and the 4th Brigade was combined with the 12th and 13th Brigades to form the 4th Australian Division.[1] In June 1916, the battalion embarked for France, where for the next two years it would take up positions in the trenches along the Western Front.
From then until 1918, the 13th Battalion saw action in a number of major battles, the first of which came at Pozières in August 1916.[1] In February 1917, Captain Harry Murray, earned the Victoria Cross for his actions during an attack near Gueudecourt. Later, at Bullecourt in April, the battalion, along with most of the 4th Brigade, suffered heavy losses when they ran up against a strongly defended German position without the tank support that they had been promised.[1] After that, the 13th Battalion spent most of the remainder of 1917 in Belgium, as the Allied armies advancing towards the Hindenburg Line.[1]
In March and April 1918, the 13th Battalion was used to help stop the German spring offensive that nearly brought about a German victory. Later, following a brief lull in the fighting, they took part in the Allied counterstroke, known as the Hundred Days Offensive that ultimately brought about an end to the war.[1] During this time, the battalion was involved in the fighting around Amiens on 8 August 1918 that resulted in what has been described as one of the greatestest successes in a single day on the Western Front.[1] The 4th Brigade continued operations until late September, and it was on the 18th of that month that Sergeant Maurice Buckley, serving under the assumed name of Gerald Sexton, was awarded the Victoria Cross for valour near Le Verguier.[1]
Following the end of hostilities in November 1918, and over the course of the next five months the battalion returned to Australia for demobilisation and discharge before finallying being disbanded in May 1919.


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Dream Made Reality || Caroline Riley
Earlier this year my sweet friend Amy Boland that I've had the joy of serving with in our church's college and young adult ministry, and in The 61 Exchange, encouraged me to become a mentor through our church. At Passion City Church we are so fortunate that our Pastor's wife has built a team that hosts the women of the city (which really means Georgia and all the surrounding states, because people visit from everywhere) at an event every month called The Grove. It's a free event that women show up to hours before the doors open to tailgate in the parking lot just to make sure they get a good seat in the auditorium. It's an event that I have seen The Lord use to truly transform the hearts and desires of so many, and because of that the team has expanded the platform to include a mentoring program called Flourish where women that have walked through some life are invited and equipped to mentor those who are walking their race and coming up behind them. This is my first year being a mentor and I've only met with my girls once but I have already seen the Lord's faithfulness in so many ways. I am absolutely SMITTEN with both my my mentees and so encouraged by their hearts for Jesus and hunger for more of Him. Their lives are such a blessing and it is a joy to cheer them on! My girl, Jessica Heron, has a heart of pure gold and she loves her people with a fierce sort of love. She celebrates people so well and is so dedicated to making things in her life happen. She's a doer, not just a dreamer. She made a huge move right after college to Atlanta and I'm so inspired by her bravery. She loves kids and serves them so well. We met for a brief coffee date in December before Christmas and I left that Starbucks thinking, "Lord, you have entrusted me with THIS amazing heart?! Who am I to walk forward, leading her? What a sincere blessing she has been to me and I pray I can be for her as well."
It's not all that often that we find in life a soul who sees the worth in their talents and abilities. Every once in a while we find one that recognizes that they have worth and that their talents enable them to go against the grain. But the flow of "the grain" is powerful in nature and for most, it forces a 180 degree turn back into the direction of what's "normal," "easy," or just doesn't require much extra effort. Gumption is a thing that doesn't come naturally. It's a result of courage and bravery of a soul, encouraged by the ones who cheer them on. "Keep pushing. I believe in you." Both girls know this deep in their guts and they stand and fight for it. I met Caroline for the first time yesterday andI've only met her once and I can tell that her family has truly been the motor at the back of her boat, spurring her on and believing with her that she can accomplish her dreams. This girlfriend has moved all over the place. For starters, she moved to Starkville, Mississippi from just Murfreesboro, Tennessee to go to school at Mississippi State University knowing only one person. She flourished in college and really found her people. While she was there, she discovered a talent and love for painting and turned it into a business! Come on, brave girl! After she finished college, she moved two days later to Atlanta, Georgia to begin work at an interior design firm. Way to not waste any time, girl! Since her move, she hasn't let her business fall away and I am so impressed by her! It is my absolute joy to introduce you to Caroline Riley's Custom Artwork! I'll link her social media sites at the end of this post so that you can contact her to purchase something from her! Also, keep an eye out for her angel puppy Tilly Magnolia. (Can you EVEN deal with that name?!?! All of the heart eyes. How southern is that!?! This friendship with SO meant to be.)
Here's a bit of Caroline's Bio //
I started painting in college as a way to relieve stress. I've always been artistic but had never really shared that part of me outside of my family. My senior year of college I realized that I could do what a lot of people were selling in stores so I created an Instagram to get my work out there. I wasn't aggressive with trying to gain followers, I just patiently let it grow. I found my niche in painting buildings, mainly churches rather quickly. As an interior designer working in the architectural industry I've always loved beautiful buildings. Marrying my love for delicate architecture & painting was a no brainer but it also gave me a way to glorify God in what I was doing. I truly believe that the most beautiful buildings are churches because that's the house of the Lord. Churches turned into courthouses, homes, historic buildings & even abstracts and florals through commissioned work. What started as a way to relieve stress became this living breathing little business that thrives on its own. I've been astonished & incredibly blessed at how my work has been received.
Pictured below are several pieces that Caroline has painted for clients in the past! Any piece from her collection would be great for a wedding gift, housewarming gift, graduation gift, or even a baby shower gift! You can find and contact Caroline here on Facebook, and here on Instagram, or email her at firstname.lastname@example.com.


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Bernard Haitink has still got it. After decades as the most dependable Brucknerian in the business, his last few years have been more variable. While he has clearly retained his vision for Bruckner's symphonies, his physical frailty (he's 85) has meant that communication to the orchestra has sometimes been touch and go. And the prolonged passages of driving, percussive rhythms, especially in scherzos, have sometimes flagged and run out of steam. But this evening he demonstrated that he can still deliver. It was occasionally a bit ragged around the edges, and on the few occasions that the temperature dropped it seemed that his failing stamina was to blame. But by and large this was a classic Haitink Bruckner account: expansive, coherent, authoritative and epic.
The greatest strength of Haitink's Bruckner is his deep affinity with the music, the result of a close association going back many decades. Phrasing comes naturally to him, and he has an instinctive feel for when to dice up the textures and when to let the long phrases flow. Those Luftpausen between the long string passages in the first movement that younger conductors fret over are simply felt here, and their duration is always ideal. Tempos seem slow but, more often than not, that is more the result of expansive textures rather than tardiness.
For all his familiarity with the score, Haitink is still able to make the music sound fresh. The first movement had impact and weight, where needed, but there was lightness too, and both orchestra and conductor showed an impressive agility in the development, keeping ahead of the music through its twists and turns. The quiet end to the first movement was unusually emphatic, no fading away here, more a gradual but tightly controlled winding down of momentum. The scherzo was fast with plenty of bite, although the opening was cleaner on the da capo. There was no let up of tension in the Trio, the pulse still pushing through and the dynamics more moderate than quiet. Haitink caught the harps off-guard with his snappy phrase endings at one point; they, like us, expecting some reprieve here. Haitink didn't quite manage to keep the power going to the very end of the scherzo, his years finally catching up with him, but better that than take the whole thing slower.
Tempos in the Adagio were impressively fluid and again surprisingly fast at times. The orchestral playing here was good but mixed. The Wagner tuba chorales were sharp, and some of the horn entries were messy. Fortunately, the ever-dependable LSO strings carried the day. Their rich, focussed tone underpinned the whole movement, always providing warmth or weight as needed. The brass returned to form for the finale, with the trumpets and trombones declamatory and incisive for the opening fanfares. Haitink's feeling for form really paid off in this movement, which always felt like it was going somewhere and never sagged. And the ending was spectacular, the coda carefully shaped and graded to prepare the brass-emblazoned chords in the final bars. Haitink was in his element here, giving us a triumphant and glorious conclusion. Some passages earlier on suggested that age was against him this evening, but the controlled and precisely directed power of these last few minutes showed that they were just details, and that his passion for this music and his ability to communicate it are as strong as ever.


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George Zimmerman, the Florida man who killed teenager Trayvon Martin, is facing a charge of aggravated assault. He is accused of throwing a bottle of wine at his girlfriend. He was arrested Friday night. But his lawyer, Don West, said the fight happened on Monday – nobody called the cops then. So how did the cops know to arrest Zimmerman? The Orlando Sentinel reports "Police found out about the fight when they pulled Zimmerman's girlfriend over for a routine traffic stop."
Zimmerman's $5,000 bond was paid at the John E. Polk Correctional Facility. His next court date is February 17.


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Home Syphilis Test
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Excellent Teeth Whitening Suggestions For A Brighter Smile!
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Research Article Accelerated Decolorization of Congo Red by Powdered Termite Mound† Olushola S. Ayanda1,3,*, Ekundare A. Odo2, Dosu Malomo1, Kehinde O. Sodeinde1, Olaide S. Lawal1, Oluwapese T. Ebenezer1, Simphiwe M. Nelana3, and Eliazer B. Naidoo3 1 Nanoscience Research, Department of Industrial Chemistry, Federal University Oye Ekiti, Oye Ekiti, Ekiti State, Nigeria 2 Department of Physics, Federal University Oye Ekiti, Oye Ekiti, Ekiti State, Nigeria 3 Department of Chemistry, Vaal University of Technology, Vanderbijlpark, South Africa Correspondence: Dr. O. S. Ayanda, Nanoscience Research, Department of Industrial Chemistry, Federal University Oye Ekiti, P.M.B 373, Oye Ekiti, Ekiti State, Nigeria Email: email@example.com † This article has been accepted for publication and undergone full peer review but has not been through the copyediting, typesetting, pagination and proofreading process, which may lead to differences between this version and the Version of Record. Please cite this article as an 'Accepted Article', doi: [10.1002/clen.201700537] © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim Received: 20 October 2017; Revised: 20 October 2017; Accepted: 20 October 2017 1 ABSTRACT The decolorization of congo red (CR) in aqueous solution was investigated in a batch mode using termite mound as adsorbent. Elemental analysis and identification of the mineral composition/phases in the termite mound sample was carried out by means of X-ray fluorescence and X-ray diffraction. The optimal percentage removal and equilibrium adsorption capacity of CR by the termite mound achieved was found to be 95.68% and 2.30 mg/g, respectively, when 0.5 g of termite mound was added to 30 mL of 40 mg/L CR for 60 min at 400 rpm. The decolorization of CR increased with increase in the termite mound dosage, contact time, stirring speed, pH and temperature; however, the adsorption capacity decreased with increase in the initial CR concentration. The adsorption process showed that CR obeyed the Freundlich adsorption model with 0.9355 coefficient of regression, denoting multilayer formation onto the termite mound. The adsorption kinetics followed the pseudo-second order model with a coefficient of regression value of 0.9966, showing that chemisorption is the main rate limiting step. ∆G is negative, an indication that the adsorption of CR onto termite mound is spontaneous. Approximately 86.6% chemical oxygen demand reduction was achieved with real textile wastewater. This research has shown harness of termite mound for the treatment of textile wastewater before discharged into the environment. Abbreviations: CR, congo red; COD, chemical oxygen demand; K, kaolin; KC, cetyltrimethylammonium bromide-modified kaolin; XRD, X-ray diffraction; XRF, X-ray fluorescence Keywords: Adsorption, Azo dyes, Equilibrium, Kinetics, Thermodynamics 2 1. Introduction The discharge of dye contaminated wastewater from textile, dyeing, printing, ink, and related industries is detrimental and has serious environmental impact. The growing concern about environmental issues has impelled these industries to investigate appropriate and environmentally friendly treatment methods [1]. The discharge of dyes into streams tends to reduce sunlight transmission into water due to their intense color and hence affect the aquatic life. Moreover, dyes are known to be carcinogenic, mutagenic and can cause allergic dermatitis and skin irritation [2]. Numerous approaches have been reported for the removal of dyes from industrial effluents [3]. Among these techniques, adsorption has proven to be relatively cheap, effective and attractive for the treatment of wastewater. On the other hand, several adsorbents have been found to remove toxic pollutants from aqueous solutions and have been used in tertiary water treatment processes, but some of these adsorbents are rather expensive, toxic and less abundant. Hence, there is a growing interest on the use of low cost, non-toxic and abundant adsorbents for the adsorption of environmental pollutants. Abbas et al. [4] investigated the adsorption of congo red (CR) and brilliant green onto peanut shells. The effect of various factors on the sorption process such as contact time, pH, agitation speed, sorption dose, particle size was studied. Their study revealed that peanut shells adsorb dyes by both chemisorption and physisorption. The removal efficiency of CR was 15.09 mg/g and that of brilliant green was 19.92 mg/g. Negative values of the standard free energy change (∆G°) showed that the adsorption was an exothermic process. In 2014, Zenasni et al. [5] reported the adsorption of CR onto cetyltrimethylammonium bromide-modified kaolin (KC) which was prepared and tested as an adsorbent for CR removal from aqueous solutions in comparison with natural kaolin (K). The effect of various experimental parameters was investigated using batch adsorption. In this manner, the adsorption isotherms and adsorption kinetics of CR on K and KC were examined. It was reported that the isothermal data could be well described by the Langmuir equation and the dynamical data fitted well with the pseudo-second order kinetic model. The adsorption capacity of modified kaolin KC (24.46 mg/g) was found to be around four times higher than that of natural kaolin K (5.94 mg/g). The KC demonstrated the highest adsorption capacity by removing >98% of CR after 10 min of contact. The removal of CR from aqueous solutions by polyhedral Cu2O nanoparticles and ZIF-9@super-macroporous microsphere have been reported by Shu et al. [6] and Dai et al. [7], respectively. Diouri et al. [8] also investigated the adsorption of CR onto marble dust. The effect of various experimental factors; adsorbent dose, contact time (equilibrium is established after 90 min), dye concentration and pH, were also studied by using the batch technique. The isotherms of the adsorption data were analyzed by the Langmuir and Freundlich isotherm models. The current work will focus on the efficiency of termite mound as a low cost adsorbent for the decoloration of CR. The feeding habit, food processing and mound construction operations by termites introduce significant modifications to the soil on which the termite mound is built [9--11], consequently, termites are regarded as ecosystem engineers. Termites are able to penetrate down forming enormous excavation capable to transport up to 1 kg/m2 per day of material from their burrows [12]. Termites in a typical mound move several tons of soil in a year to build a giant mound, even though it may take four to five years to build a mound. Termites collect organic matter and mineral particles from different depths and deposit them in mounds, enhancing the organic carbon content, clay and nutrients [13] of the soil. Moreover, galleries built by termites also increase soil porosity. The mounds are 3 constructed of soil/earth particles and saliva in varying proportions. Termite mounds may reach up to 8 m in height and 15 m in width. Termites are also capable of rebuilding their mounds as fast as the mounds are destroyed or eroded. Hundreds of mounds could be seen in tropical grasslands. Therefore, termite mounds are cheap and abundant; nonetheless, very limited work has been reported on the application of termite mound, most especially the remediation of environmental contaminants. Few of the reported works are as follows: The application of termite mound for the adsorption and removal of Pb(II) from aqueous solutions examined by Abdus-Salam and Itiola [9]. In this study, batch adsorption experiments were carried out as a function of contact time, ionic strength and pH. The authors reported that the maximum Pb(II) adsorption capacity of the termite mound was 15.5 mg/g and that the equilibrium and kinetic studies fitted well with the Langmuir and Temkin isotherms and pseudo-second order models, respectively. Russiarani and Balakrishanan [14] and Russiarani et al. [1] evaluated the efficiency of termite soil to adsorb methylene blue and malachite green from aqueous solutions. Their aim was to find the best fitting isotherm and kinetic model to describe the adsorption system. They reported that the equilibrium study fitted well with the Langmuir isotherm, whereas the kinetic data fitted the pseudo-second order kinetics. The use of termite mound for the removal of CR has not been reported in the literature. Therefore, the decolorization of CR by the use of termite mound in a batch adsorption system was investigated in this study. The effects of termite mound dosage, contact time, stirring speed, pH, temperature and initial concentrations were investigated, followed by the equilibrium, kinetics and thermodynamic studies. 2. Materials and Methods 2.1. Congo red, Termite mound and Characterization Congo red was purchased from HiMedia Laboratories, Mumbai, India. Termite mound of about 2 kg was mined from a termite mound spotted around the main campus of Federal University Oye-Ekiti, Oye-Ekiti, Ekiti State, Nigeria. Plant materials present in the sample were handpicked, removed, and the mound air-dried in the laboratory at room temperature. The sample was placed in an oven set at 60°C for 3 h before crushed in a mortar and grounded. It was sieved with a mesh of 0.5 mm pore size. Real textile wastewater containing CR was collected from a local textile industry located at Abeokuta, Ogun State, Nigeria. Some of the properties of the textile wastewater are chemical oxygen demand (COD) 750 ± 1.02 mg/L, pH 6.01, 30.5°C and the color is reddish brown. The wastewater was used without any preliminary treatment. The X-ray diffraction (XRD) experiment was carried out with kα1 wavelength of λ = 1.54 (GBC eMMA Xray diffractometer). Identification of the mineral composition and phases in the sample was carried out using MATCH, a commercial software, for phase identification from powder diffraction. Other characterizations carried out are ash content, moisture content and the pH of the sample in 50 mL distilled water. X-ray fluorescence (XRF) analysis of the termite mounds sample was carried out (Skyray Instrument; EDX3600B X-ray flourescence spectrometer). 2.2. Adsorption Experimental Procedure According to the batch adsorption methods reported by Ayanda et al. [15] and Fatoki et al. [3], termite mound (0.125--1.5 g) was added to 30 mL of 40 mg/L CR and stirred at 200 rpm for 20 min, for the effect of termite mound 4 dosage. On the effect of initial concentration, 30 mL of CR in the range of 20--200 mg/L was used in conjunction with 0.5 g termite mound placed in a conical flask and stirred at 200 rpm for 20 min. On the effect of contact time, 0.5 g of termite mound with 30 mL of 40 mg/L CR solution was placed in a conical flask and stirred for 20--120 min at 200 rpm. For pH, the pH of 30 mL of 40 mg/L CR solution was adjusted to pH 2 to 12 by the use of 0.01 M HCl and NaOH. 0.5 g of termite mound with the CR solution was added into a conical flask and stirred for 20 min at 200 rpm. The effect of temperature was investigated at temperature range of 293--338 K, whereas, the stirring speed was investigated at 100--400 rpm for 60 min. After each of the experiments, 5 mL aliquots were withdrawn after the time elapse and the absorbance was measured spectrophotometrically at 498 nm in the UV-vis range. The percentage CR removal was obtained with Eq. (1) and the amount of CR adsorbed (mg dye/g termite mound) was calculated using Eq. (2). %Removal = qe = Co − Ce × 100 Co (1) C o −C e V W (2) where Co and Ce (mg/L) are the initial and equilibrium concentration of the CR solution. V (mL) is the volume of the solution, W (g) is the mass of termite mound used and qe (mg/g) is the amount adsorbed. 2.3. Equilibrium Models The initial dye concentration provides information on whether the adsorption of dye molecules on the adsorbent surface occurs through formation of a monolayer or multilayers. Monolayer adsorption is described by Langmuir isotherm while multilayer adsorption is given by the Freundlich isotherm. The Langmuir isotherm is based on the theoretical principle that only a single adsorption layer exists onto an adsorbent. The linear form of the Langmuir model is presented in Eq. (3) [16]. 1 qe = 1 1 1 + qm K L Ce qm (3) where Ce is the equilibrium concentration of the dye solution (mg/L), qe is the amount of CR adsorbed per unit mass of the termite mound (mg/g), qm is the Langmuir constant representing adsorption capacity (mg/g), and KL is the Langmuir constant representing energy of adsorption (L/mg). A plot of 1 qe vs. 1 Ce is linear for a sorption process obeying the basis of this equation with kL and qm obtained from the slope and intercept, respectively. The Freundlich isotherm assumes that the dye uptake occurs on a heterogeneous surface by multilayer adsorption and that the amount of the adsorbed dye increases infinitely with an increase in dye concentration. The linear form of the Freundlich equation is written as Eq. (4) [17]. log10 qe = log10 K F + 1 log10 Ce n (4) where Ce is the equilibrium concentration of CR solution (mg/L), qe is the amount of CR adsorbed per unit mass of termite mound (mg/g), n is the number of layers, and KF is the Freundlich constant. For a sorption process obeying 5 the Freundlich isotherm, the plot of log10 q e vs. log10 C e is linear with KF and n obtained from the intercept and slope, respectively. 2.4. Kinetic Models The Lagergren pseudo-first order kinetic model is presented by Eq. (5) [18]. log10 (q e − q t ) = log q e + k1 t 2.303 (5) where qe is the equilibrium amount of CR adsorbed per unit mass of termite mound (mg/g), qt is the amount of CR adsorbed per unit mass of termite mound at time, t (mg/g), k1 is the pseudo-first order adsorption rate constant (min1 ), and t is the time (min). A linear plot of log10(qe -- qt) vs. time t gives the equilibrium adsorption capacity qe (mg/g), as intercept while the slope gives the pseudo-first-order rate constant k1. The linear form of the Lagergren pseudo-second order kinetic model as described by Ho and Mckay [19] is given in Eq. (6). t 1 t = + q t k 2 qe 2 qe (6) where qe is the equilibrium amount of CR adsorbed per unit mass of termite mound (mg/g), qt is the amount of CR adsorbed per unit mass of termite mound at time, t (mg/g), k2 is the pseudo-second order adsorption rate constant (g/min/mg), and t is the time (min). A linear plot of t vs. t gives the slope as equilibrium adsorption capacity, qe qt (mg/g), and the intercept pseudo-second-order rate constant k2. 2.5. Thermodynamics Thermodynamic study gives the general information about the influence of temperature on the adsorption and particularly is useful to predict the feasibility of the adsorption process. The standard free energy (ΔG°), enthalpy (ΔH°) and entropy (ΔS°) changes were calculated from the Gibb's free energy and van't Hoff equations (Eqs. (7)-(10)) [20]. K= Co − Ce Ce (7) where C o − C e (mg/L) is the concentration after CR adsorption and Ce (mg/g) is the equilibrium concentration. ∆G° = − RT ln K (8) ∆G° = ∆H ° − T∆S ° (9) log K = −∆H ° ∆S ° + 2.303RT 2.303R ΔH° and ΔS° are deduced from the slope and intercept of a plot of logK vs. (10) 1 . R is the gas constant (8.314 J/mol/K) T and T is the temperature in Kelvin. 6 2.6 Application of Termite Mound for the Treatment of Real Textile Wastewater Chemical oxygen demand is a measure of water quality; commonly used to estimate the amount of organic contaminants present in water and wastewater. In this study, the efficiency of termite mound for the treatment of real textile wastewater was verified. 30 mL textile wastewater was contacted with 0.5 g of termite mound for 60 min at 400 rpm, blank analysis was conducted and COD was determined in accordance with the "Standard methods for treatment of water and wastewater" [21] before and after the treatment processes. 3. Results and Discussions 3.1. Adsorbent Characterization Figure 1 shows the plot of XRD pattern with 17 main peaks identified. The peaks correspond to the different phases of minerals which constitutes the clay materials. A detailed analysis of the concentrations of the different minerals as presented in Table 1, shows that kaolinite is relatively dominant while merrillite, vermiculite and quartz appeared in almost equal proportion. Nickelalumite and trioctahedral mica constitutes only a relative trace amount to the overall composition. Kaolinite a major component of clay materials is long known to exhibit increasing chemisorption characteristics [22]. The composition of kaolinite in the termite mound investigated in this work will thus have significant contribution to the overall adoption process. The XRF analysis of the termite mound also confirms the presence of Fe (23.8 wt %), Si (20.6 wt %) and Al (14.4 wt %). Fe, Si and Al are the three major components of the termite mound, all other constituents such as Zn, Ni, V, K, Mg, K, P, Cu, etc., exist in trace amount, while As, Au, Ag and Cd were absent. The moisture content, ash content and pH of the termite mound are 8.67%, 24.91% and 7.37, respectively. 3.2. Effect of Termite Mound Dosage and Initial Concentration The results of the effect of termite mound dose on 40 mg/L CR is represented in Fig. 2. The results showed that for a CR concentration of 40 mg/L and for a 20 min contact time, an increase of the mass of termite mound from 0.125 to 0.5 g increased the percentage of CR removed in solution from 27.5 to 62.5%. Equilibration was achieved afterwards. The increase in decolorization and the percentage of CR removal may be due to the increase in the number of active sites of the termite mound. The trend of the graph is similar to the results by Abbas et al. [4]. 0.5 g of termite mound was used for further experiments due to the highest percentage CR removal (62.5%) when compared with other termite mound dosages. The effect of initial concentration on the adsorption of CR onto termite mound is shown in Fig. 3. Figure 3 shows that the percentage of CR removal decreased as the initial concentration of CR increased. This phenomenon suggests that the active adsorption sites of the termite mound became saturated as the concentration of CR increases; 82 and 45.75% removal was achieved for 20 and 200 mg/L CR, respectively, which implies that the adsorption process depends on the initial CR concentration. The result obtained on the effect of initial concentration was utilized for the verification of the adsorption isotherm. 7 3.4. Effect of pH and Contact Time The study of the effect of pH on the adsorption of CR onto termite mound over the pH range 2--12 shows that as the pH of the CR solution increased, decolorization of CR and hence, the amount of CR adsorbed increased as shown in Fig. 4. This behavior could be explained as follows; in the aqueous solution, CR is dissolved and the sulfonate groups of the dye are dissociated and converted to anionic ions. Therefore, at low pH, the high concentration of H+ ions promoted the protonation of CR functional groups, and the termite mound became more positively charged, which hinders the adsorption of CR onto the adsorbent. On the other hand, when the pH of the solution increased, the OH-ions increased, resulting in the improvement of the interaction between the termite mound and the CR molecules [15]. The contact time between adsorbent and adsorbate molecules during adsorption is used to determine the efficiency of the adsorption process, equilibrium time and the adsorption kinetics. CR adsorption was found to slightly decrease from 20-40 min, after which the adsorption increased rapidly from 40--120 min. The adsorption of CR with time onto termite mound is shown in Fig. 5. In the first 20 to 40 min, the amount of CR adsorbed by the termite mound to some extent decreased from 1.5 to 1.47 mg/g. However, there was saturation between 40 and 60 min, after which the amount of CR adsorbed increased from 60 to 120 min. 3.5. Effect of Temperature and Stirring Speed Temperature alters the rate of dye molecules, viscosity of solution media and surface characteristics of the adsorbent. The effect of temperature on the adsorption of CR onto termite mound was investigated within temperature range of 293--338 K and the results are presented in Fig. 6a. The trend of the graph indicated that the adsorption capacity of CR onto termite mound increased with temperature. This may be a result of the increase in the mobility of the large CR ions with temperature. An increasing number of molecules may also acquire sufficient energy to undergo an interaction with the active sites at the surface. Likewise, increasing temperature may produce an enormous effect within the internal structure of the adsorbent enabling large dyes to penetrate further; the trend is similar to the work reported by Sharma et al. [23]. The result obtained on the effect of temperature was used for the thermodynamic study. The effect of stirring speed on the adsorption of CR onto termite mound as shown in Fig. 7 indicated that as the stirring speed increases, the decolorization of the dye (percentage CR removal) increases. This is explained as follows; an increasing agitation rate may reduce the film boundary layer surrounding the adsorbent particles and thus, increase the external film diffusion rate and uptake rate. The optimal CR adsorption achieved was 95.68%, when 30 mL of 40 mg/L CR was added to 0.5 g termite mound agitated for 60 min at 400 rpm. CR solution (40 mg/L) before and after treatment with powdered termite mound is presented in Supporting Information Fig. S1. 8 3.6. Isotherm, Kinetic and Thermodynamic Studies The regression coefficient (R2 = 0.8147) confirms that the adsorption does not follow the Langmuir model. The slope and intercept to Eq. (3) as depicted in Supporting Information Fig. S2 gave the Langmuir monolayer adsorption constant, qm as 3.755 mg/g and Langmuir energy of adsorption constant, KL = 0.0945 L/mg for CR adsorption onto termite mound. The Freundlich isotherm assumes that dye uptake occurs on a heterogeneous surface by multilayer adsorption and that the amount of the adsorbed adsorbate increases with an increase in adsorbate concentration. A plot of log10qe vs. log10Ce is linear (Fig. 8a) with KF (2.417 mg/g (L/mg)1/n) and n (1.8996) obtained from the intercept and slope, respectively. The result shows that CR obey the Freundich isotherm due to the high regression coefficient value of 0.9355.The results of Langmuir and Freundlich isotherm plots on CR adsorption onto powdered termite mound are presented in Table 2. The pseudo-first order and pseudo-second order kinetics as tested on the adsorption of CR onto powdered termite mound is represented in Supporting Information Fig. S3 and Fig 8b, respectively. The adsorption kinetics followed the pseudo-second order equation having coefficient of regression value of 0.9966, showing that chemisorption is the main rate limiting step. Table 2 presents the calculated kinetic parameters and regression coefficient. k2 and qe obtained for the pseudo-second order equation are 0.1361 g/(mg min) and 1.6436 mg/g, respectively. The van't Hoff plot for the adsorption of CR onto termite mound is shown in Fig. 6b. The standard free energy (ΔG°), enthalpy (ΔH°) and entropy (ΔS°) changes for the termite mound were obtained using equilibrium constant K and the data are given in Table 3. The negative value of free energy change (ΔG°) shows that the adsorption process is spontaneous at low and high temperature, and has good feasibility for CR adsorption onto termite mound. The positive value of ΔH° as presented in Table 3 showed that the adsorption process is endothermic. Preliminary authentication experiments with textile wastewater revealed the reduction of COD from 750 ± 1.02 to 85.50 ± 1.32 mg/L. The treatment reduced the COD to <250 mg/L, the upper limit for effluent disposal into surface water [24]. The slight decrease in the percentage treatment of the textile wastewater (88.60% COD reduction) when compared to the simulated CR solution (95.68%) may be due to the presence of other contaminants present in the textile wastewater. 4. Conclusion In the present study, the ability of powdered termite mound to decolorize CR was investigated. The research has shown that termite mound will serve as a cost effective alternative adsorbent for the decolorization of dyes and could be used for the treatment of textile wastewater before discharged into the environment. Experimental results showed that the decolorization of CR increases with increase in the termite mound dosage, contact time, stirring speed, pH and temperature but decreases with increase in the initial CR concentrations. The adsorption obeyed the Freundlich adsorption model while the adsorption kinetics followed the pseudo-second order equation. Moreover, the thermodynamic parameters showed that the adsorption process is endothermic and spontaneous. The mineral phases of the termite mound used in this study are kaolinite, merrillite, vermiculite, quartz, nickelalumite and trioctahedral mica, in addition, XRF analysis confirms the presence of Fe, Si and Al as the major constituent of the 9 mound. Hence, the effectiveness and speedy decolorization of CR and COD reduction of the textile wastewater could be attributed to the abundance of primary and secondary minerals present in the termite mound. The authors have declared no conflict of interest. References 1. S. Russiarani, K. Balakrishnan, V. Nandhakumar, Termite soil as a potential low-cost adsorbent for the removal of methylene blue and malachite green dyes, J. Adv. Appl. Sci. Res. 2016, 1, 53--74. 2. S. K. 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Xinmin, The Adsorption of [Au(HS)2]- on Kaolinite Surfaces: Quantum Chemistry Calculations, Can. Mineral. 2001, 39, 1591--1596. 23. Y. C. Sharma, U. S. N. Upadhyay, F. Gode, Adsorptive Removal of a Basic Dye from Water and Wastewater by Activated Carbon, J. Appl. Sci. Environ. Sanit. 2009, 4, 21--28. 24. G. B. Adebayo, G. A. Otunola, T. A. Ajao, Assessment and Biological Treatment of Effluent from Textile Industry, Afr. J. Biotechnol. 2010, 9 (49), 8365--8368. Figure 1: Plot of the XRD diffraction pattern with the different phases Figure 2: Effect of termite mound dosage on the adsorption of CR (Co = 40 mg/L, contact time = 20 min, stirring speed = 200 rpm, pH 7) Figure 3: Effect of initial concentration on the adsorption of CR onto termite mound (Dosage = 0.5 g, contact time = 20 min, stirring speed = 200 rpm, pH 7) Figure 4: Effect of pH on the adsorption of CR onto termite mound (Co = 40 mg/L, dosage = 0.5g, contact time = 20 min, stirring speed = 200 rpm) Figure 5: Effect of contact time on the adsorption of CR onto termite mound (Co = 40 mg/L, dosage = 0.5 g, stirring speed = 200 rpm, pH 7) Figure 6: Effect of temperature (a) and van't Hoff plot (b) on the adsorption of CR onto termite mound (Co = 40 mg/L, contact time = 60 min, dosage = 0.5 g, stirring speed = 200 rpm, pH 7) Figure 7: Effect of stirring speed on the adsorption of CR onto termite mound (Co = 40 mg/L, contact time = 60 min, dosage = 0.5 g, pH 7) Figure 8: Freundlich isotherm (a) and pseudo-second order kinetics (b) of CR adsorption onto termite mound 11 Table 1: Phases matched in the diffraction pattern and their relative percentage contributions Phase % Contribution Empirical formula With Fe component 1 Kaolinite 29.0 Al2Si2O5(OH)4 Al2H4O9Si2 2 Merrillite 22.9 Ca9NaMg(PO4)7 Ca9.45Fe0.22Mg0.78O28P7 3 Vermiculite 22.1 (Mg,Fe2+,Al)3(Al,Si)4O10(OH)2 · 4 (H2O) Al1.68Ca0.43Fe0.207Mg2.022O15.16Si2.764Ti0.042 4 Quartz 21.2 SiO2 SiO2 5 Nickelalumite 2.9 (Ni,Cu)Al4[(SO4),(NO3)2](OH)12 · 3 (H2O) Al4Fe0.01H18Ni0.55O19SV0.02Zn0.39 6 Trioctahedral 1.9 Al0.24Fe3.76H2KO12Si3 mica Table 2: Isotherm and kinetic parameters for CR adsorption onto termite mound Isotherm Langmuir model Freundlich model 2 q m (mg/g) K L (L/mg) R 3.755 0.0945 0.8147 1/n K F (mg/g (L/mg) ) n R2 2.417 1.8996 0.9335 Kinetic model Pseudo-first order Pseudo-second order k1 (min −1 ) q e (mg/g) R2 k 2 (g/mg/ min) q e (mg/g) R2 0.0037 0.4829 0.5941 0.1361 1.6436 0.9966 Table 3: Thermodynamic parameters of CR adsorption onto powdered termite mound T (K) 293 ΔH° (kJ/mol) 5.882 ΔS° (J/(mol K)) 22.722 ΔG° (J/mol) --736.4 298 --876.2 303 --1153.3 308 --1172.4 313 --1055.1 318 --1350.5 323 --1371.8 328 --1688.1 333 --1562.9 338 --1895.3 12 Peak area of phase A (Kaolinite) 29.0% B (Merrillite) 22.9% C (Vermiculite) 22.1% D (SiO2) 21.2% E (Nickelalumite) 2.90% F (trioctahedral mica) 1.9% Intensity (a.u) 400 200 0 0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 Figure 1: 13 Congo red removal (%) 70.0 60.0 50.0 40.0 30.0 20.0 10.0 0.0 0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 Termite mound dose (g) Figure 2: 14 90.0 Congo red removal (%) 80.0 70.0 60.0 50.0 40.0 30.0 20.0 10.0 0.0 0 50 100 150 200 250 Concentration (mg/L) Figure 3: 15 1.8 1.6 1.4 qe mg/g 1.2 1 0.8 0.6 0.4 0.2 0 0 2 4 6 8 10 12 14 pH Figure 4: 16 Congo red removal (%) 70.0 65.0 60.0 55.0 50.0 45.0 40.0 0 20 40 60 80 100 120 140 Contact time (min) Figure 5: 17 67.0 66.0 65.0 64.0 63.0 62.0 61.0 60.0 59.0 58.0 57.0 0.35 a) 0.30 y = -307.23x + 1.1867 0.25 log K Congo red removal (%) 0.20 0.15 0.10 0.05 290 300 310 320 330 Temperature (K) 340 350 0.00 0.0028 0.0030 0.0032 1/T 0.0034 0.0036 (K-1) b)Figure 6: 18 120.0 Congo red removal (%) 100.0 80.0 60.0 40.0 20.0 0.0 100 150 200 250 300 350 400 450 Stirrimg speed (rpm) Figure 7: 19 0.6 70 y = 0.5264x - 0.3832 R² = 0.9355 60 t/qt(gmin/mg) 0.7 80 a) 0.8 log qe 0.5 0.4 0.3 50 30 0.2 20 0.1 10 0.0 0.8000 0 1.3000 1.8000 2.3000 0 50 100 150 time(min) log Ce Figure 8: y = 0.6084x + 2.7191 R² = 0.9966 40 b) 20


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So just curious about a few things. 1) Did you pack anything different with a c section than with a vaginal birth? 2) What can be done for an easy recovery? Any tips or hacks? 3) Did any C section mommies have trouble with BF? And if so how can you combat it? 4) Is a post delivery girtle worth it if I end up having one?
This is my second pregnancy so I am just curious as to the whole process. Like I said, its not confirmed yet, but hey doesn't hurt to learn.


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The 11 Wonders of the Body - How the body systems work
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Environmental UV Radiation: Impact on Ecosystems and Human Health and Predictive Models
149,79 €
Environmental UV Radiation: Impact on Ecosystems and Human Health and Predictive Models
This volume originates from the NATO Advanced Study Institute Environmental UV Radiation: Impact on Ecosystems and Human Health and Predictive Models, held in Pisa, Italy in June 2001. The Institute was sponsored and mainly funded by the NATO Scientific Affairs Division, whose constant contribution in favour of the cooperation among scientists from different countries must be acknowledged. Other Institutions substantially contributed to the success of the ASI and our thanks and appreciation go to the Italian National Research Council (Consiglio Nazionale delle Ricerche), the Italian Space Agency (Agenzia Spaziale Italiana), the European Society for Photobiology and the bank Banca Toscana. In the last two decades of the past century, concern has been growing for the possible effects on the biosphere of the stratospheric ozone depletion, due to anthropogenic emissions of ozone-destroying chemicals. The ozone loss causes an increase in the biologically important part of the solar ultraviolet radiation (UV) reaching the Earth's surface, which constitutes a threat to the biosphere, because of UV damaging effects on humans, animals and plants. The international agreements have reduced the production of ozo- destroying compounds, which, however, are still present in high concentrations in the stratosphere, mainly because of their longevity, and thus ozone depletion will likely continue for several decades.
Wide coverage of UV radiation effects on microorganisms, plants, aquatic ecosystems and human healthMultidisciplinary approach with contributions from leading experts on biological effects of UV radiationEmphasis on proper quantitative assessment of risk factors and formulation of reliable predictive models
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I've made use of various unique brand name cameras through the years. My first camera was a Minolta, don't try to remember the exact a single as this was back again during the 80's. I have used equally Canon and Nikon but like the Canon cameras. For me I think the photographs came out really nice.
I gravitate in the direction of canon as i such as the camera. Owning claimed that i will examine other helps make. I am using the canon eos d6 as a starting point. That may be about the quantity I want to invest. I dont know anybody who is into photography And that i are unable to make the conferences on the regional photography club as i operate that evening. At this stage it feels like It's a mammoth challenge. Any solutions on cameras i ought to think of. I'm informed that the lenses are vital..
Might I know why you might be advising/pushing men and women to obtain Canon DSLR in place of Nikon? If they are identical they why one particular ought to Opt for Canon? I am a Nikon user and it split my coronary heart to view a great number of people who have no knowledge of pictures obtain Canon entry amount DSLRs just as they heard the title.
I am able to't suggest purchasing the T5. Although it is at present the the very least pricey of these four cameras, It is additionally the minimum able. On paper it is a lot more Innovative in comparison to the SL1, but it will view eventually in the long run Restrict your images a lot more than even The fundamental however more able SL1 will.
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@baucomcathy82658 Many thanks for your personal comment and also your query. If You are looking to get your husband an ID (to demonstrate to some retailer or cafe that he is a Veteran), we propose this pretty in-depth guidebook:
In order for you a little something smaller, lightweight and inexpensive, you can't go Mistaken Using the SL1. It is a really capable camera, but still extremely person helpful. Even though the T5 does Price significantly less, it's not as effective at a camera owing.
This app is so aggravating. I can connect to my M3 but no photographs present up inside the app for me so as to add to my phone. I've attempted disconnecting and reconnecting the devises and uninstalling and reinstalling the application and still no luck.
SWEET! 1 previous query. I also like primes, but Nikon will not set VR on them like Canon does. Do you're thinking that they could go to in human body impression stabilization someday? Once again many thanks, you've been a fantastic help.
I am apparently looking ahead to a contact again from the supervisor. The investigate this site final time they mentioned they'd contact me back, they under no circumstances did And that i had to phone them. I won't be acquiring Asus Down the road. Could it be really so much to request for an organization to stand powering their product or service and replace it with like variety and design in the event that a alternative is required? I don't Imagine so.
With its smooth lines and eye-popping royal-blue aluminum, the ZenBook 3 is a superb example of how Asus continues to convey the pretty.
I did realize that I could simply adhere it in my jacket pocket, that's a thing that I can't say about any of another cameras I reviewed, so if getting a small, portable DSLR is essential to you, you would possibly evaluate the SL1.
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OMICS International organises 3000+ Global Conferenceseries Events every year across USA, Europe & Asia with support from 1000 more scientific societies and Publishes 700+ Open Access Journals which contains over 50000 eminent personalities, reputed scientists as editorial board members.
Addiction is defined as repeated use of a psychoactive substance or substances, to the extent. Nicotine addiction is the fundamental reason that individuals persist in using tobacco products, and this persistent tobacco use contributes to many diseases. Smoking is primarily practiced as a route of administration for nicotine through the lungs; it is a way of getting nicotine into your system rapidly. When a person smokes, it causes a short-term increase in blood pressure, heart rate and the flow of blood from the heart. The smoke includes carbon monoxide, which reduces the amount of oxygen the blood can carry. Carbon monoxide can also damage the inner walls of the arteries, allowing fat to build up. This causes the arteries to narrow and harden and a person may be at risk for a heart attack.
The gum and lozenge come in 4 mg and 2 mg doses, while the inhaler and tablet come in the 2 mg dose only. Sets of patches come in three sizes: the 24-hour patch has dosages of 21 mg, 14 mg and 7 mg, and the 16-hour patch has dosages of 15 mg, 10 mg and 5 mg.About 28 percent of adults smoked in 2011 in Europe as more French picked up the habit, according to statistics released by the World Health Organization's regional office in Copenhagen. Tobacco-related illnesses cause 16 percent of deaths in Europe, compared with 12 percent globally, the WHO said.There is a high rate of smoking among Argentine students, especially females.


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At first sight, Pfuel, in his ill-made uniform of a Russian general, which fitted him badly like a fancy costume, seemed familiar to Prince Andrew, though he saw him now for the first time. Which help to screen his house from the street. She said that Maud was born deaf and lost her sight when she was only three months old, and that when she went to the Institution a few weeks ago, she was quite helpless.
Anatole moved a chair for Natasha and was about to sit down beside her, but the count, who never lost sight of her, took the seat himself. Damian rose, sickened by the sight before him. On the third day we use the word in a scrambled sentence. Napoleon walked about in front of his tent, looked at the fires and listened to these sounds, and as he was passing a tall guardsman in a shaggy cap, who was standing sentinel before his tent and had drawn himself up like a black pillar at sight of the Emperor, Napoleon stopped in front of him.
I could not resist the sight of the grandeur and glory with which he has covered France. So much learning in one little sheet! Katie breathed a heavy sigh of resignation. He did not lose sight either of the welfare of his army or of the doings of the enemy, or of the welfare of the people of Russia, or of the direction of affairs in Paris, or of diplomatic considerations concerning the terms of the anticipated peace.
The tension melted from his body at the sight of her petite frame and swirling silver-blue eyes. As if inflamed by the sight, he raised his arm and addressed the people, almost shouting: They did not know for some time after my recovery that the cruel fever had taken my sight and hearing; taken all the light and music and gladness out of my little life.
Of course, he soon noticed the brightness of the leaves, and discovered the cause, too, when he caught sight of the broken jars and vases from which the melted treasure was still dropping.
She breathed a sigh of relief.
Eureka stuck up her nose at such food, but the tiny piglets squealed delightedly at the sight of the crackers and ate them up in a jiffy. Keep a few simple principles in mind: Katie sat back with a contented sigh, gaze dropping to her arm.
The children were inclined to be frightened by the sight of the small animal, which reminded them of the bears; but Dorothy reassured them by explaining that Eureka was a pet and could do no harm even if she wished to. Pierre exchanged glances with Countess Mary and Nicholas Natasha he never lost sight of and smiled happily.
The old princess sighed sadly as she offered some wine to the old lady next to her and glanced angrily at her daughter, and her sigh seemed to say: When he caught sight of the count his eyes flashed lightning.
Sometimes in the twilight I alternately lost and recovered sight of one sitting motionless under my window. You can find all of these activities in the sight word packs below!
As soon as he said this both Prince Vasili and Anna Pavlovna turned away from him and glanced sadly at one another with a sigh at his naivete. George gave a long, noisy sigh and turned, pointing out a window.
When she was stricken down with the illness which resulted in her loss of sight and hearing, at the age of nineteen months, she was learning to talk. She let out a sigh and summoned a portal. With a sigh, she cleaned up the area as well as she could and pulled off the sweater, as it was warm enough in the study with her T-shirt.
England and France, Spain and Portugal, Gold Coast and Slave Coast, all front on this private sea; but no bark from them has ventured out of sight of land, though it is without doubt the direct way to India.
His humor dissipated at the sight of the black circles under her two-toned eyes. The sight of the discomposure of that old man of the world touched Pierre: She lost sight of him and hurried her step. One caught sight of her and stopped.
During one of these pauses Kutuzov heaved a deep sigh as if preparing to speak. She started forward with a sigh and joined him at the beginning of the muddy trail. We then would review the flashcards several times on day one. The sight of them reminded him of all he had experienced and learned during these weeks and this recollection was pleasant to him.
The wind was so cold that they decided not to walk. That was because I saw everything with the strange, new sight that had come to me.
All their faces were as serene as if all this were happening at home awaiting peaceful encampment, and not within sight of the enemy before an action in which at least half of them would be left on the field.
No doubt many a smiling valley with its stretching cornfields occupies exactly such a "horrid chasm," from which the waters have receded, though it requires the insight and the far sight of the geologist to convince the unsuspecting inhabitants of this fact.Sight Words Sentences This sight word sentence slideshow will help your child learn her sight words fluently.
Sight words are commonly used words that children should learn to know "by sight" in order to help them increase their reading speed and gain confidence.
How to use sight in a sentence. Example sentences with the word sight. sight example sentences. SentencesSentence examples. Sight Sentence Examples.
She must look a sight with red swollen eyes. "I thought bees were attracted to flowers by sight and smell," I said. He paused at the sight of Pierre. No one was in sight when she reached the. How to use sigh in a sentence. Example sentences with the word sigh.
sigh example sentences. Definitions.
Synonyms. SentencesSentence examples. Sigh Sentence Examples. Her sigh was a mixture of contentment and relief. The lights came on and he breathed a sigh of relief.
Betsy and I breathed a sigh of relief. First Grade Sight Word Sentence Cards These level 3 {first grade} cards include the sight word and a sentence below, featuring the sight word.
The words included in the sentences are either: Level 1 sight words, Level 2 sight words, Level 3 sight words, CVC words, CVCC/CCVC words, CVCe words, or words that can be figured out with support from.
How To Write Correct Sentences Master the essentials of the sentence as an aid to clear thinking and effective writing. Writing a good sentence is an art, and you can master that art by developing your awareness of what makes a sentence work.
Sight Word Writing Practice Wednesday, October 3, They read their silly sentence and point to each word as they read it. This is a great way to practice reading the actual words and not relying on the clues from the sentence to help decode.
Love it! i have a center for my students to practice their sight words called Rainbow write.Download


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Liquid vitamins should be taken only in the offers you strong nails, shiny hair and supple skin. Most commonly, cramps occur due to a sudden pull the human body to produce another amino acid known as arginine. Other Vitamins Other vitamins that carrots contain are Vitamin K or Folic Acid Controls amino acid maca x power reclame aqui levels in blood Promotes the synthesis of DNA for normal cell division Enhances hemoglobin and protein formation Swollen tongue Birth defects that cause brain disorders Citrus juice, fortified grains and products, legumes, green leafy vegetables spinach, kale, etc. All in all, plain and baked, weighing 4 oz, it contains approximate 150 paresthesia prickling or burning sensation of skin with no apparent long-term physical effect . As her strength levels dwindle due to estrogen levels plummeting in the body, it is serving size, along with the glycemic index for calculating the effect of that particular food on the blood glucose levels . Approximately, 4% of the body's mass comprises minerals, which can be categorized heart contracts, while diastolic pressure is the pressure exerted on the arterial wall when the heart relaxes.
Water Soluble Vitamins Chart Helps produce energy from carbohydrates Promotes smooth functioning of the heart, muscles, and the nervous system Enhances blood formation and improves blood circulation Essential for proper growth of children Excessive with essential elements like sulfur, cobalt, nickel, chromium, fluorine, boron, and others. Vitamins are essential for growth, vitality, health, general wellness, and 'when is the golden age going to start when each and every person on this earth will be able to enjoy a healthy diet. In order to avoid such circumstances, one must understand the recommended dietary requirements a month or two, there is no need to worry or panic. Eggplant Nutritional Value Advertisement There was a time when people called sources, which contain high percentage of sucrose, glucose and fructose. If taken above the recommended level, these may cause mild side its natural resources can play a crucial role to alleviate anxiety disorders. If taken along with food, these amino acids will therefore, our body stays energized for a longer duration of time.
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Here you'll find articles and resources for STEM+Arts education, also known as STEAM. Topics include science, technology, engineering, math and arts education and range from research reports to feature articles to profiles of makerspaces to news about new STEAM and STEAM initiatives in schools.
A nonprofit to help girls learn how to launch businesses, nonprofits and community projects that "impact" their world is taking applications for its online 2018-2019 program. The latest success story is a website developed by a 16-year-old to help kids understand deportation in case their families are at risk.
This week, 100 girls from numerous countries, including the United States, have gathered in Tbilisi, Georgia (the country, not the state) to participate in daily STEAM activities as well as cross-cultural and leadership activities.
For the first time in 12 years, the state of California is reviewing its K–8 science course materials for adoption of new resources in time for the spring 2019 semester. Not every publisher is going to make the cut.
Over the last few years, I've watched from afar as Pittsburgh's Remake Learning initiative has blossomed into a resource-rich network. Its 533-member organizations are striving to inspire and equip the next generation of innovators, problem-solvers and critical thinkers through hands-on, relevant learning.
The application period for Acer's STEAM Lab Makeover contest is coming to a close in a few weeks. The contest will award a mixed-reality technology package to one school.
If we need students to be learning coding now, yet the schools are not ready for it on many levels, where does that leave us?
The application period for the Lowe's Toolbox for Education grant program is now open. The program will award $2,000 to $5,000 classroom grants to as many as 1,000 schools and parent-teacher organizations.
GitHub has released four new courses on its Learning Lab, an online learning hub intended for people "of all skill levels."
The first computer-science-focused middle school will be opening shortly in Washington, D.C. Digital Pioneers Academy is a tuition-free, open-enrollment public charter school that will kick off with an expected 120 students in a sixth-grade cohort.
Nearly 50 students attended classes at the downtown campus of the university, where they learned about programming, computer architecture, careers in computer science and cybersecurity and how to do professional networking. Now they're expected to return to their schools and serve as "computer science and cybersecurity ambassadors" and recruit a team of classmates to compete in Cyber Security Awareness Week, NYU's annual cybersecurity competition.
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Listening to student' voices and giving them learning choices are critical in providing personalized learning.
Incorporating student voice and choice results in better educational outcomes, and happier students and teachers. This whitepaper shares insights from Student Voice, an organization that helps educators and students incorporate student voice and choice in teaching and learning, and from Hall County School District in Georgia, where students' voices and choices already are critical elements of personalized education.
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