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Electronic Supplementary Material (ESI) for Chemical Society Reviews. This journal is © The Royal Society of Chemistry 2014 Supplementary information Design and synthesis of organic-inorganic hybrid capsules for biotechnological applications •Jiafu Shia, b, §, Yanjun Jiangc, §, Xiaoli Wanga, Hong Wua, d, Dong Yanga, Fusheng Pana, d, Yanlei Sua, d, Zhongyi Jianga, d,* •a Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China. •b School of Environmental Science and Engineering, Tianjin University, Tianjin 300072, China •c School of Chemical Engineering and Technology, HeBei University of Technology, Tianjin 300130, China •d Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, China • § Jiafu Shi and Yanjun Jiang contributed equally. a) b) Fig. S1 a) Schematic of representation of the synthesis process of dopamine modified alginate (Alg-DA) and b) the fabrication process of hybrid microcapsules. Reprinted with permission from ref. 19. Copyright 2012 American Chemistry Society. Fig. S2 Selective permeability of [Cu3(BTC)2] MOF capsules. a) Release of the small molecule ethylene glycol through the capsule wall. Experimental data (red squares) are well described by a Fickian diffusion model (black squares) for a diffusivity of 5*10-11 cm2 s-1 in the microporous capsule wall. b) Encapsulation of the large dye molecule Rose Bengal. The experimental ratio of dye molecules inside and outside the capsules (red circles) remains constant over time, confirming effective encapsulation. In both graphs, error bars indicate standard deviation. Reprinted with permission from ref. 20. Copyright 2011 Nature Publishing Group. Fig. S3 Fabrication process of gold-nanoshelled microcapsules: a) electrostatic adsorption of PAH onto microcapsules generated by the W/O/W double-emulsion method; b) deposition of gold nanoparticles onto PAH-coated microcapsules; c) formation of gold nanoshells by the surface-seeding method; d) lyophilization to sublimate the encapsulated water in the inner aqueous phase of the microcapsules to produce small hollow spaces. Reprinted with permission from ref. 26. Copyright 2011 Wiley-VCH. Table S1 List of the various polyamines, multivalent anions, shell materials and cargo that can be formulated into PSA-capsules. Reproduced from ref. 28. Copyright 2011 Royal Society of Chemistry. Polyamine poly-L-lysine, poly-L-arginine, poly-L-histidine, poly-L-ornithine, chitosan, polyallylamine hydrochloride, branchedpolyethyleneimine Multivalent anion phosphate, sulfate, succinnate, isocitrate, citrate, tri-carballylate, trimesate, ethylenediamine tetraaceticacid (EDTA), Na5(Asp)4, tripolyphosphate, Gd–DOTP Shell material SiO2, SnO2, ZnO, CdSe, Fe3O4, polyacrylic acid, poly-styrene sulfonate, poly-L-glutamic acid, heparin, polygalacturonic acid, anti -EGFR, human serum albumin, bovine serum albumin, lactalbumin Fig. S4 a) Formation of enzymatic capsules through electrostatic assembly of enzymes and nanoparticles in water followed by assembly of the resulting enzymenanoparticle conjugates at oil-water interfaces; b) structure of β-gal; c) chemical structure of cationic gold nanoparticles; d) optical micrograph of capsules stabilized by enzyme-nanoparticle conjugates at oil-water interfaces; and e) TEM images of a capsule at low magnification and (inset) high magnification. Reprinted with permission from ref. 29. Copyright 2009 Wiley-VCH. Fig. S5 Schematic illustration of the preparation of inorganic/organic hollow capsules. An=F, OH, or PO43-; M+=Y3+, Fe2+/3+, or Ca2+; MAn=YF3, Fe3O4, or hydroxyapatite; below: scanning electron microscopy images of the YF3 capsules at different preparation stages. Reprinted with permission from ref. 15. Copyright 2003 Wiley-VCH. Description of the syntehsize process of the microspheres as shown in Fig. S5 More specifically, MnCO3 microparticles were firstly modified by citric acid, then alternatively assembled with PAH and PSS, and finally treated with EDTA. The resultant PAH/citrate-PAH/PSS capsules were then exposed to a solution containing NaOH, H3PO4, or HF, thus resulting in the rapid substitution of citrate ions to OH-, PO43- or F- ions, and the formation of PAH/OH-–PAH/PSS, PAH/PO43-–PAH/PSS or PAH/F-–PAH/PSS capsules. Next, the as-acquired capsules were treated with FeSO4 and Fe2(SO4)3 (OH--containing capsules), CaCl2 (PO43--containing capsules), or Y(NO3)3 (F-–containing capsules) solutions to deposit Fe3O4, hydroxyapatite or YF3 particles, respectively, inside the capsule wall. The inorganic component in the capsule wall prevented capsule collapse in the dry state, which are reminiscent of those of the original polyelectrolyte capsule in solution. Fig. S6 Schematic diagram of the procedure used to form the core-shell composite colloids and hollow spheres by using pe-coated colloids as templates. Reprinted with permission from ref. 33. Copyright 2003 Wiley-VCH. Fig. S7 Strategy for the synthesis of an organic/inorganic hybrid nanocapsule. Right: TEM image of the organic/inorganic hybrid nanocapsule. Reprinted with permission from ref. 10. Copyright 2003 Wiley-VCH. Fig. S8 Tentative mechanism of titania formation induced by protamine molecules. Reproduced from ref. S1. Copyright 2008 Royal Society of Chemistry. Ref. S1. Y. Jiang, D. Yang, L. Zhang, L. Li, Q. Sun, Y. Zhang, J. Li and Z. Jiang, Dalton Trans., 2008, 4165-4171 Fig. S9 Illustration of protamine–titania hybrid microcapsule preparation process. Right: SEM images of hybrid capsules with a) one protamine/titania bilayer, b) three protamine/titania bilayers, and c) five protamine/titania bilayers. Reprinted with permission from ref. 42. Copyright 2009 Wiley-VCH. Fig. S10 Schematic illustration of the preparation of [email protected] hybrid capsules. Reprinted with permission from ref. 45. Copyright 2013 American Chemistry Society. Fig. S11 Illustration of MOF-polymer hybrid capsule formation. After preparation of a stable "MOFsome" by application of shear force to an aqueous dispersion of MOF nanoparticles and dodecane, the interior is polymerized to form a hollow capsular structure comprised microporous MOF particles embedded within the surface of a polymer shell. Reprinted with permission from ref. 48. Copyright 2013 Wiley-VCH. Fig. S12 Polydopamine synthesis occurs via two pathways: A) a pathway of covalent bondforming oxidative polymerization and B) a newly proposed pathway of physical self-assembly of dopamine and DHI. Reprinted with permission from ref. S2. Copyright 2012 Wiley-VCH Ref. S2. S. Hong, Y. S. Na, S. Choi, I. T. Song, W. Y. Kim and H. Lee, Adv. Funct. Mater., 2012, 22, 4711-4717 Fig. S13 Scheme for the synthetic process for P(NIPAm-co-AAm) hydrogel modified luminescent rattle-type mesoporous silica microspheres and subsequent loading and temperature-controlled release of IMC. Reprinted with permission from ref. 50. Copyright 2012 Wiley-VCH. Description of the syntehsize process of the microspheres as shown in Fig. S13 The mesoporous silica capsules were firstly fabricated through conducting the sol-gel reaction of tetraethoxysilane (TEOS) on a sacrificial Fe3O4 template. Then, gadolinium oxide nanoparticles doped with europium ions (Gd2O3:Eu3+, luminescent nanoparticles) were incorporated into the lumen to form rattle-type mesoporous silica capsules via an incipientwetness impregnation method. Finally, the rattle-type capsules serve as a nanoreactor for filling temperature-responsive hydrogel via photoinduced polymerization to form the multifunctional hybrid microspheres. Other references related to the tutorial review Assembly of polymers and inorganic particles 1. M. Nakamura, K. Katagiri and K. Koumoto, J. Colloid Interf. Sci., 2010, 341, 6468. 2. P. Liu, X. Li, B. Mu, P. Du, X. Zhao and Z. Zhong, Ind. Eng. Chem. Res., 2012, 51, 13875-13881. 3 F. J. Rossier-Miranda, K. Schroën and R. Boom, Food Hydrocolloid., 2012, 27, 119-125. 4 A. M. Yashchenok, D. N. Bratashov, D. A. Gorin, M. V. Lomova, A. M. Pavlov, A. V. Sapelkin, B. S. Shim, G. B. Khomutov, N. A. Kotov, G. B. Sukhorukov, Adv. Funct. Mater. 2010, 20, 3136-3142. 5 M. F. Bedard, A. Munoz-Javier, R. Mueller, P. del Pino, A. Fery, W. J. Parak, A. G. Skirtach, G. B. Sukhorukov, Soft Matter 2009, 5, 148-155. Assembly of polymers and inorganic precursors 6. R. L. Harbron, T. O. McDonald, S. P. Rannard, P. H. Findlay and J. V. Weaver, Chem. Commun., 2012, 48, 1592-1594. 7. J. F. Shi, X. M. Zhang, S. H. Zhang, X. L. Wang and Z. Y. Jiang, ACS Appl. Mater. Interfaces, 2013, 5, 10433-10436. Assembly of organic precursors and inorganic particles 8. S. Simovic, P. Heard and C. A. Prestidge, Phys. Chem. Chem. Phys., 2010, 12, 7162-7170.
© Copyright 2019 ExploreDoc


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According to an animal study, lutein reduces the risk of sunburn, as well as the local UVB-radiation-induced immune suppression and reactive oxygen species generation that are implicated in photocarcinogenesis (Lee et al 2004). A protective effect on skin cancer, however, has not been observed in human cohort studies. One prospective cohort study involving 43,867 men and 85,944 women found no significant inverse association between intake of lutein and squamous cell carcinoma (Fung et al 2003), and an increased risk of squamous cell carcinoma was observed for people with multiple prior non-melanoma skin cancers and high serum levels of lutein and Lutein and Zeaxanthin 811
zeaxanthin (Dorgan et al 2004). The clinical significance of these findings is uncertain.
How To Prevent Skin Cancer
Complete Guide to Preventing Skin Cancer. We all know enough to fear the name, just as we do the words tumor and malignant. But apart from that, most of us know very little at all about cancer, especially skin cancer in itself. If I were to ask you to tell me about skin cancer right now, what would you say? Apart from the fact that its a cancer on the skin, that is.

subset: commoncrawl


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Patna : Bihar Chief Minister Nitish Kumar was praised on Wednesday by the Dalai Lama for the prohibition in the state. "I feel very good after meeting Nitish Kumar. For many years we have been good and close friends," Dalai Lama told reporters after planting a sapling of Anand Bodhi tree at Buddha Smriti Park here.
"People have a lot of anger and tension today. But to get rid of them, consumption of liquor or drug is not good … Mental tension and anger can be done away with through training of the mind," the noble laureate said.
The Tibetan spiritual leader also praised India. "India is like a guru (teacher) for us … We are its shishya (disciple) … The relation with India is that of guru and shishya," the Tibetan spiritual leader who took refuge in the country over five decades ago said.
"Today even scientists are learning from India's ancient knowledge and philosophy," he added. Kumar received the Dalai Lama at the airport on his arrival here enroute to Bodh Gaya for Kalchakra puja.
Later, the Tibetan theologist offered prayers near a branch of Bodhi tree act the chief minister's residence. The chief minister hosted lunch for the Dalai Lama and other Buddhist monks accompanying him. —PTI


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Can Meghan Markle be immune to the charms of Richard Armitage?
The Duchess of Sussex has just assumed the patronage of the National Theatre (in succession to Queen Elizabeth II). So all we have to do to get the play we've been pining for is to get Richar…
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About Melaleuca Melaleuca - The Wellness Company
Melaleuca Canada Preferred Customer program (information provided by debbiemaier.ca Independent Melaleuca Affiliate) So you would like to become a preferred customer with Melaleuca Canada. and what exactly does it mean to become a preferred customer with Melaleuca . It means that you have joined the �wellness company�. It means that you are going to start making this a better world by... 16/12/2018�� Unauthorized Charges Melaleuca Customer Service can't cancel. Melaleuca / can't cancel. 1 3910 S. Yellowstone Idaho Falls, ID, United States Review updated: Dec 16, 2018. 26 comments. Contact information: mymelaleuca.com. One day after signing up, I learned on the internet what a scam this was. following their instructions I sent a certified letter, FAX and email to cancel. �
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11/03/2016�� You already know Melaleuca added 130,000 new Preferred Customers and is experiencing its fastest growth in 30-years! And Melaleuca�s record-setting growth continues into March! how to draw rin in blue excorist Melaleuca review with 129 Comments: We love this product but want to stay as a preferred customer, as not interested in building a business but joined to support our daughter in building her Melaleuca �. How to develop customer service techniques
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If you are a preferred customer, you have to accumulate 35 points worth of merchandise per month. If it is the end of the month, and you have forgotten to make a purchase, Melaleuca will automatically purchase you a "select pack" of merchandise, valued at 35 points. You can configure this "select pack" to contain what you would like.
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Asked on Apr 18, 2019
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I would start with Murphy's Oil soap, Barb.
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OMG!!! R232 MILLION has been WON! One person wins record PowerBall jackpot
The payout is the biggest lottery win in the country's history.
Shortly after the PowerBall draw on Tuesday evening, Ithuba confirmed there was one lucky winner of the R232 million jackpot.
It is the biggest single win in South African history.
Take a look at the prize payouts below:
HE HAS FALLEN!!! Sudan's President Omar al-Bashir has stepped down
Sudan's President Omar al-Bashir has stepped down and consultations are under way to set up a transitional council to run the country, government sources and a provincial minister said on Thursday.
The minister of production and economic resources in North Darfur Adel Mahjoub Hussein told the Dubai-based al-Hadath TV that "there are consultations to form a military council to take over power after President Bashir stepped down".
A Sudanese source told Reuters Bashir was under house arrest with a number of aides at the presidential palace.
The army and security services deployed troops around the defence ministry and on major roads and bridges in Khartoum as thousands of people flocked to an anti-government protest outside the ministry, a Reuters witness said.
Tens of thousands of Sudanese marched through the centre of the capital Khartoum in jubilation, dancing and chanting anti-Bashir slogans.
Protesters outside the defence ministry chanted: "It has fallen, we won."
State television and radio played patriotic music, reminding older Sudanese of how military takeovers unfolded during previous episodes of civil unrest.
Bashir, a former paratrooper who seized power in a bloodless coup in 1989, has been a divisive figure who has managed his way through one internal crisis after another while withstanding attempts by the West to weaken him.
Sudan has suffered prolonged periods of isolation since 1993, when the United States added Bashir's government to its list of terrorism sponsors for harbouring Islamist militants. Washington followed up with sanctions four years later.
Bashir has also been indicted by the International Criminal Court (ICC) in The Hague over allegations of genocide in Sudan's Darfur region during an insurgency that began in 2003.
The latest crisis has escalated since the weekend, when thousands of demonstrators began camping out outside the Defence Ministry compound in central Khartoum, where Bashir's residence is located.
Clashes erupted on Tuesday between soldiers trying to protect the protesters and intelligence and security personnel trying to disperse them. At least 11 people died in the clashes, including six members of the armed forces, the information minister said citing a police report.
Since December 19, Sudan has been rocked by persistent protests sparked by the government's attempt to raise the price of bread, and an economic crisis that has led to fuel and cash shortages
Opposition figures have called for the military to help negotiate an end to Bashir's nearly three decades in power and a transition to democracy.
The demonstrators at the Defence Ministry had said that they wanted to submit a petition for the armed forces to take their side in their attempt to remove Bashir and his Islamist-backed administration.
NUDE PROTEST!!! Gugu Ncube to appear in court on Thursday
Gugu Ncube is expected to appear in the Pretoria Magistrate Court on Thursday, after staging a nude protest at Unisa on Wednesday.
Ncube said she was protesting naked because "nudity is a sign of my dignity that l have been stripped of".
This refers to allegations that she was "unlawfully manhandled" at Unisa for reporting her boss to the university. She alleged that her boss was asking for sexual favours in exchange for her job.
Ncube donned black underwear and a red top, holding a placard in front of her, when she was arrested.
Unisa said the matter was between her and Unisa Centre for Early Childhood Education (UCECE), an external company that was previously sponsored by Unisa.
The university further said it followed due processes regarding Ncube's sexual harassment complaint in 2018, and suspended its staff members who were accused of the crime. The accused were board members at UCECE at the time.
(Compiled by Nica Schreuder)
Outage hits Facebook and Instagram users worldwide
Facebook and Instagram users lost access to the social network's applications in parts of the world Wednesday as a result of an outage of undetermined origin.
The California giant which has more than two billion users acknowledged the outage after users noted on Twitter they could not access Facebook or had limited functionality.
"We're aware that some people are currently having trouble accessing the Facebook family of apps. We're working to resolve the issue as soon as possible," a Facebook statement said on Twitter.
A short time later, Facebook indicated the outage was not related to an attack aimed at overwhelming the network.
"We're focused on working to resolve the issue as soon as possible, but can confirm that the issue is not related to a DDoS attack," Facebook said, referring to what is known as a distributed denial of service cyber strike.
According to the website downdetector.com, outages were heaviest in North America and Europe, but some users appeared to be affected in other regions.
Last November, a Facebook outage was attributed to a server problem and a September 2018 outage was said to be the result of "networking issues."


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Guess the player Arsenal fans want Arsene Wenger to sign
Arsenal fans really want Arsene Wenger to sign Hal Robson-Kanu
On June 30th, Hal Robson-Kanu's name appeared on a list. That list contained the names of the players Reading FC had decided to release. A day later, he is the hottest striker in Europe.
Robson-Kanu, who as of yesterday is unemployed, scored quite possibly the sleekest goal at the European Championships so far, giving Wales a 2-1 lead against Belgium and helping them on their way to a historic semi-final tie.
Controlling a pass from Aaron Ramsey with three defenders around him, the whole stadium expected Robson-Kanu to pass to Neil Taylor, who was storming into the box unmarked. He didn't, instead opting to execute a perfect Cruyff turn and leave himself with a free shot on goal.
As commentator Robbie Savage correctly pointed out, if Lionel Messi or Cristiano Ronaldo had done the same thing, we would be talking about it for years and throwing out phrases like "the best ever".
No one is claiming Robson-Kanu is the best striker ever but there is gathering momentum on Twitter for none other than Arsene Wenger to make a move to sign him. The Wales international started his career as an Arsenal youth candidate and fans are wondering if he could be the man to solve their problems.


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1849 Cooke Morphy 4.4" King Edition Distressed Antique & Natural Ebony
A magnificent reproduction of an early Cooke 1849 chess set.
Our artisans have applied a technique called " distress antiquing" a process which results in the chess pieces looking aged, worn and well used'! This set is best suited to the serious chess collector and connoisseur.
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We offer a 3 year standard guarantee that covers any natural defects such as, splitting, cracking, warping of the woods used in our entire range


text: There is an increasing body of work suggesting that enhanced horizontal resolution helps to improve a wide range of important climate processes, but these tend to be based on one or a small number of models and simulations. It is clear that many of the most pressing questions about regional climate change urgently require advances in process simulation. For example, will the risk of high impact events such as droughts and floods change over the next few decades and beyond? The extent to which it is possible to provide robust answers to these questions relies fundamentally on the fidelity of the climate models that are used to address them. Several upcoming projects – CMIP6 HighResMIP and EU H2020-PRIMAVERA – aim to move such work into a multi-model context. The talk will describe some recent highlights of our high resolution analysis, including work on air-sea fluxes in a coupled eddy-resolving simulation, and tropical cyclone assessment and analysis, as well as future plans and potential for collaboration.


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About the room
Who lives there
1 female, professional, non smokers
Ideal roommates
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Located on the edge of downtown and mid-town. Easy access to public transportation. Metro bus and train availble within a block. Rent includes heat, a/c, electricity, basic cable, Internet service, swimming pool, gym, huge balcony. Partially furnished room with a king size bed and lamp fixtures. Bring your pillows and linen, eating utensils, cooking utensils, etc. No smoking, no drugs. Condo Association requires background check.
Listing ID: H180726222732636
Posted on 25 February 2019


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STUDENT ABSENCE LINE - if you child is absent from school, please TEXT 07860 095106
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Below are links to some of the important information you need to make the right decision for your family:
If you need to get in touch or wish to make an appointment:
Phone 01278 455531 between 8 am - 4 pm or use our Contact Us enquiry form
Durleigh Road
We were delighted to take eight of our students to the SASP Step Into Sports Day which was held at Westfield Academy in Yeovil on Wednesday 27th February.
The day was designed to develop leadership skills and to build confidence in sport for SEN and non-SEN students. Paralympic athlete and Sky Sports presenter Kate Grey, spoke to the students from across the area about her experiences as an elite sports person and helped to run the sessions. The students gained a great deal of experience and produced some great ideas for how to engage and support other young people who sometimes truggle with some aspects of sports and PE.


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Jennifer Muirhead Interiors
Review by Stacie Mayoras:We had a wonderful experience working with Jennifer Muirhead Interiors. Jenn did an excellent job & we would highly recommend her for your interior design project. We hired Jenn to renovate our k...
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Commented: What type of wood is the vanity? Is it stained?I believe it's oak but it's also prefab...
20 December 2018
Commented: I love this bathroom! Can you tell me the color of the vanity? Thx.Vanity is prefab!
20 December 2018
Commented: Love this wallpaper! Does anyone know where I can get it?It's from Farrow and Ball.
15 May 2017


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I donated signed art prints to Cherry Dollface to benefit her heart surgery. You can find my signed prints and other goodies on her ebay store:
I donated signed art prints to Cherry Dollface to benefit her heart surgery. You can find my signed prints and other goodies on her ebay store:
Amazing kind write up on me by Ivy D'Muerta This was featured in Delicious Dolls Magazine April 2017
Gil Elvgren, Alberto Vargas, Bettie Page, Dita Von Teese…
All household names when thoughts of pinups sneak into that cheeky little brain of yours, but if the name Andrea Young didn't arrive, then you'll have one more name to add into that exclusive list by the end of this story!
There's a special niche in the Southern Californian art scene that only the coolest of cats belong in, and Andrea Young has created head waves within it when she began showcasing her unique take on pinup art via graphic design and illustration in 2007. Inspired by classic and modern pinups alike, Andrea's visual expressions on the unique feminity and sexiness of pinup culture delight and inspire sub culture and mainstream fans globally.
With her Bachelors in Media Arts and Animation giving her high level access to expand her creative genius, and being driven with a sole purpose to make all people feel good by her creations, Andrea has also expanded into photography for weddings, pinup portraiture, children's photography, and even illustrating for scientific publications, beauty brands, and personal invitations.
Somehow this seductive artist finds time to titillate our senses in between a fulltime career with two beautiful children, a husband, four wonderful older sisters whom support each other's artistry deeply.
You know you want to see more, you cheeky sneaks… Discover more about Andrea and her pinups at andreavphoto.com
Please check out my artist spotlight in Delicious Dolls magazine March issue page 10
Logo design I did for It takes a Village: Community Advocacy Organization
This birthday portrait was done casual photo booth style. The theme is cats! I designed the invitation to be fun and bright! Cat, pink and mint plus some sprinkles! At the party there will be faux cat adoptions, a collar making station, a vet checkup station and a beautiful cake creative by Megan Riley. The favors will be the adoption cats in gable boxes and these cute photo booth photos with a lollipop.
Copyright Andrea Valdespino 2017
Happy Holidays everyone!
I hope this year and next feels blessed!
I'm already planning on the kids joint birthday party – 3 months away. I usually start with a fun theme they would enjoy and design the invitation from there. My son is super into space and my husband recently brought home a super amazing Nasa Space suit costume for him so naturally I went with space explorer theme! I found an adorable pink and silver star dress for my daughter and am thinking she can wear and alien hat and my son can be the astronaut.
We usually just have family over since they are so young, but I hope to incorporate some fun games into the day.
I won't have a big budget so I ordered the gold envelopes from paper-source and will print 4×6 lustre photo prints for the invitations.
Here is what I have so far!
Here is a recent invitation design for the amazingly talented Artist Gustavo Rimada. If you aren't familiar with his work I would urge you to take a look http://www.artedegustavo.com/
I first met Gustavo in 2009 and I am so in awe at how he has expanded and continually progresses in his work.
I do fun invitation designs too! Please check out my Etsy store for more fun designs and artwork.


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Hahn to modernize retail park near Hanover, let 4,120 sqm
The Hahn Group intends to revitalize and expand a 1985 retail park in Garbsen, near Hanover, starting in the 2nd quarter of 2019. A German pension fund is investing in the Spezialfonds, which is managed by Hahn. The new tenants – TK Maxx, dm-drogerie markt and Siemes-Schuhcenter – have concluded long-term leases for a total area of 4,120 sqm. Ernsting's Family, an existing tenant, will also see its sales area expanded in the course of the reallocation. Anchor tenant Real will have 11,800 sqm after revitalization. Lettable space will total around 18,500 sqm plus 775 parking spaces. The construction work is scheduled for completion at the end of 2019, with investment volume in the low double-digit millions.
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2012 World Series Champions, the San Francisco Giants. It's nice to see a National League team win for the 3rd season in a row.
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Love birds in blue by Amanda Wood
Lovingly and carefully created using a selection of vintage fabrics, wallpapers and printed papers. Also has a few little attachments added for sparkle.
Unframed but fits off the shelf frames.
Size 23x23cm
Add your names and a date to this one- these will be stitched in black thread at the bottom sides of the heart.
You are viewing an original piece of art which has been lovingly stitched by me, each one being unique.
Thanks for looking! :)
Amanda x
I accept payment by paypal at the moment
Please check order lead time before ordering to be sure you will receive your item when you need it- sometimes I am very busy and you may have to wait a few days or sometimes weeks! I will post items first class signed for as soon as they are ready.
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After receiving the item, please leave feedback to be sure that you have received the item and to let me know that (hopefully) you love it!
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Thank you!


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Is MOPS or MOMSnext for Me?
Whether you're urban, suburban, rural, stay-at-home, working, teen, adoptive, special-needs, single or married, MOPS and MOMSnext is for you! At MOPS, you'll be welcomed, accepted and inspired to reach your full potential and recognize your influence within your family and the world!
What childcare is provided?
the MOPS meetings, your children will be cared for in our Mops Kids program, where they experience a preschool style setting.
What is MOPS and MOMSnext?
MOPS International encourages and equips moms of young children to realize their potential as mothers, women and leaders, in relationship with Jesus, and in partnership with the local church.
MOPS stands for "mothers of preschoolers"- but don't let that confuse you. MOPS is about meeting the needs of every mom of a child from infancy through kindergarten. MOMSnext will support moms of school-aged children.
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Anna Stack
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Creative Activities: Rebecca Panitzke
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Open concept office spaces are the modern norm, and the Silenz app is a useful tool for those who use music as a way to focus in on their work amid the bustle and potential distractions. It runs silently in the background of one's computer, but when it recognizes important sounds nearby, such as a human voice, it automatically pauses or quiets one's music.
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Responsive Music Apps
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Swiss-Made Mechanical Smartwatches
AR Music Apps
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The Silenz App Recognizes When Music Needs to Be Adjusted
- By: Joey HaarMay 5, 2018
References: silenzapp & producthunt
References: silenzapp & producthunt


text: At 02:12 09-09-2003, you wrote: > >Hi list, > > > >I thought this was a pretty interesting story, and a hint for netgear users > >to make sure they have a nicely working firmware... > >http://www.cs.wisc.edu/~plonka/netgear-sntp/ > >I have a RP-114 router.... Am I affected? I looked at the URL and it >mentioned a different model number. Didn't see anything specific to mine >though. Yeah, not all models have the flaw apparently.. I don't see anything about the RP-114 there. It was pretty stupid of Netgear to pull that kind of trick though.. they should have used a subdomain in their own domain from the beginning.. at least they can change that easily. Time for a NetGear Update site? :o) I thought it would be good to transparent-proxy-alike forward the traffic from isp-range:23457 to their-ip:123 to a local NTP server, or just block the traffic but apparently they don't want anyone to do that.. strange dudes ;) Tom


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Bulgaria is again in the news. More specifically, the New York Times. When this happens it's generally bad. American's don't seem to care about the good things that are happening in a country it's the bad stuff that sells from natural disasters to corruption to war.
That's why this headline caught my eye: Unlikely Allies in Bulgaria Reveal Fatal Mental Health Neglect. First I had no idea what the headline meant and second because issues of neglect, mental health, children and death break my heart.
Interestingly, the first two paragraphs of the article play up the shock factor:
An unusual investigation that brought together prosecutors and human rights lawyers has revealed a grisly picture of neglect at Bulgarian state homes for mentally disabled children: 238 deaths since 2000.More than three-fourths of the deaths were found to have been avoidable: 84 from physical deterioration caused by neglect; 36 from exposure to cold or long-term immobility; 31 from malnutrition; 13 from infections caused by poor hygiene; 6 from accidents; 15 were unexplained.
These numbers seem appallingly high given the fact that Bulgaria is a part of the EU. This said, the death of children is always shocking but in my mind, the death of children who cannot advocate for themselves is that much worse.
What's notable is what's being done to investigate these deaths. Basically, Bulgarian prosecutors and humans rights lawyers have teamed up to collect evidence. Yeah, they are working together to confront this problem. Apparently:
The effort represents a strategic break from the familiar pattern of advocates' naming and shaming governments for appalling standards of care for their societies' most vulnerable citizens.
Evidence was collected to identify those guilty of crimes and build legal cases to send them to prison.
"It's about ending impunity," said Margarita Ilieva, legal director at the Bulgarian Helsinki Committee. "This will instill a fear of criminal liability, and that will change the behavior of the executive branch of government."
Last month, the Bulgarian prosecutor general announced criminal investigations into 166 of the deaths and 30 more cases of abuse of children still living in the homes. More than 80 percent of the deaths in the homes were not reported to authorities — as required by law — and the bodies were buried without autopsies.
Several legal experts working in the region said they could recall no case of anyone ever going to jail for crimes in state institutions for the mentally disabled.
So, it turn out that something is happening. Maybe it will even prevent deaths in the future. And this it turns out is an article about good things that are happening because of a bad situation. Clear it would be better if these deaths had never happened but in my book, it's definitely worth noting that steps are being taken to confront the problem.
I seriously hope that this marks a step forward for the rights of disabled children living in state homes in Bulgaria.


text:
Link to Leeds Live Chat - Campus and the City
Join our ambassadors for this live, online chat to find out everything you need to know about the University campus and the exciting City of Leeds,...
Corporate Social Responsibility (CSR) Research Group Seminar
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Economics Division Event - Systems of Provision
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This week there was one match dominating discussion around the English Premier League. Many felt it would provide definitive answers in relation to the city of Manchester and the two teams seeking to claim possession of the football bragging rights.
The City of Manchester Stadium hosted the much-anticipated derby, with both clubs presented an opportunity to stamp certainties in the minds of their fans. City have little to prove to anyone, yet the perception of a vast chasm between themselves and their cross-town rivals was there to be confirmed.
For United, it was a chance to lay claim to having made ground on the record-breaking City side after a slow start to the season. It was also something of a personal Everest for Jose Mourinho, as he lined up against his managerial nemesis.
The collective wisdom of the footballing world suggested United were still well off the pace being set by City, Liverpool and Chelsea, all undefeated after 11 Premier League rounds. Sunday night was a chance to hurl an enormous spanner into the works and shake up the championship race.
In the end it was nothing of the sort. Off the back of dominant possession and an astonishing number of successfully completed passes that sat near 90 per cent, City started well and rarely looked in real danger against Mourinho's men. Their passing was crisp and purposeful, whilst the defensive pressure they were able to mount was consistent and claustrophobic.
It is what City do and as brave and committed as any opposition may be, moments of calamity are inevitable. All three goals were 'deer in the headlights' moments. On each occasion, Red Devil defenders were left stunned and forlorn; wondering exactly what had just happened, as City players ran into the distance to celebrate.
David Silva found the back of the net after an incisive cut back from the byline fell at his feet after 12 minutes and a poor David de Gea clearance saw Sergio Aguero blast through his gloves from an acute angle to seemingly seal the deal in the 48th. In between, it was artistry from City.
Romelu Lukaku's entry to the game did bring the visitors some hope after he was brought down in the box by Ederson. Anthony Martial made no error from the spot in the 58th minute and despite City's statistical dominance, I guess United may have held some hope of a point.
An 80th-minute goal to Ilkay Gundogan that saw defenders in red shirts once again unsure of their assignments, confirmed the result. City did nothing extraordinary and that is potentially their greatest attribute; the fact that what is normal to them is quite astonishing to everybody else.
The questions were answered emphatically. City are the class of the league, United are well off the pace and Manchester is right now, as blue as it has ever been.
Saturday's action saw vital wins for Cardiff and Newcastle, with both teams looking destined to face relegation battles as the season progresses. Both Brighton and Bournemouth will be annoyed with the respective losses and the missed opportunity to take three points to sure up their own position on the table.
There were draws at Southampton, Huddersfield and Leicester with tales of missed chances and controversy involving officials. On Sunday, Liverpool kept pace with City after a 2-0 win over Fulham, with Mohamed Salah on the scoresheet again, yet some in-form teams let points slip.
Chelsea were held scoreless by Everton and Arsenal failed to dismiss the challenge of Wolves, scoring late to pinch a point. After a one-week hiatus, the league will return on the 25th of November, with City back in action against West Ham.
The match of the round looks to be Chelsea's trip to Tottenham, with a loss to either team seeing them slip well off the cracking pace being set by the top two.
As for now, the blue side of Manchester celebrates and the fall out on the red side is yet to play out. I wonder how Jose Mourinho will attempt to spin this one, on a day when his team was soundly beaten?


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