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Chat With Horny StrangersRetrieve all horny stranger chat messages within particular dialog. Cooking on an electric stove is preferable...
Chat With Horny StrangersShe has the gameplay in a tiny part of the screen. Get startedsext adventure was originally designed to...
Horny Stranger ChatMulti-service group video chat from skype qik, so send 42-second spots can be on ios, and android,...
After dinner, we were walking down the sidewalk towards the parking garage
What's more, you can meet random people from all over the world


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Y: The Last Man
At the time this page was added, "Y: The Last Man " had not yet been announced. So please keep in mind, that there is no evidence a movie will ever be made (or it's possible it was made, and this page was not updated, sorry). It might be a project in the making (or canceled), a rumor, a speculation or simply fans' hope.
This page was created to let people discuss about their expectations and enthusiasms for "Y: The Last Man".
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no reply yet - Vulture is reporting that New Line is finally starting to put feelers out for a director for the much-anticipated film adaptation of the sci-fi comic...
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Do you dare to imagine what it would be like to be... "The Last Man on Earth" (1964), a film by Ubaldo Ragona and Sidney Salkow
1 message - «The Last Man on Earth» is a Horror/Science Fiction/Drama film directed by Ubaldo Ragona & Sidney Salkow, and written by William F....
The Fate of the Crippled Cub
73 messages - To the Jouberts:...
In the face of an enemy; in the Heart of One Man; Lies the Soul of a Warrior: "The Last Samurai" (2003), a film by Edward Zwick
1 message - Released on December 01 of 2003 in the USA, «The Last Samurai» (also known as "Last Samurai", "Samurai", "Ultimo...
( 2008 )Last Man
Directed by: F. Schepisi
( 1964 )The Last Man on Earth
Starring: V. Price, F. Bettoia, E. Danieli, G. Rossi-Stuart...
( 1931 )Ladies' Man
Directed by: L. Mendes, starring W. Powell, K. Francis, C. Lombard, G. Emery...
Resources: BenderSpink, New Line Cinema, Wikipedia and contributions from movie fans. Anyone can submit additionnal information and corrections, you can post a message into the forum, or you can contact me by e-mail. Information and materials are submitted by users and thus may not always contain up-to-date and correct information, so do not hesite to report mistakes, and submit corrections.Thank you!. Direct editing is no longer available, sorry.

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Ahmad Harith Ashrofie, Hanafi (2014) Style Analysis of Malaysian Islamic Bond Unit Trust Funds. Masters thesis, Universiti Utara Malaysia.
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This study examines whether or not asset allocation styles of unit trusts different from their original objectives over the study period and sub-periods, which are during and after the financial crisis. The period of study is six (6) years starting from January 2007 to December 2012 and has been divided into overall period from January 2007 to December 2012 and two sub-periods: financial crisis from January 2007 to December 2009 and post financial crisis from January 2010 to December 2012. This study uses MSCI Malaysia Growth Index, MSCI Malaysia Value Index, 1-month Kuala Lumpur Inter-bank Offer Rate (KLIBOR), TRBPAM Islamic Government Index, TRBPAM Islamic Corporate Index, MSCI World Index as benchmarks for asset classes. The total of 14 Islamic bond funds used as sample and analysed using Return Based Style Analysis (RBSA). The results show there are some unit trusts that have significant different styles when compared to their original objectives for overall period and two sub-periods, either during financial crisis or post financial crisis period. The variation in monthly returns for most of the funds for overall period and sub- periods mainly could be explained by the variation in their styles. The average style of overall period and two sub- periods shows that fund managers have focused their investment mainly in bonds, either the government or corporate bonds. However, there is a small proportion of investment is placed in asset classes such as equity and money market instruments. The average fund returns could be explained mainly by the variation in the funds' styles.
|Item Type:
|Thesis (Masters)
|Uncontrolled Keywords:
|Islamic Bond Funds, Asset Classes, Return Based Style Analysis
|H Social Sciences > HG Finance
|Othman Yeop Abdullah Graduate School of Business
|Depositing User:
|Mr. Badrulsaman Hamid
|Date Deposited:
|28 Aug 2014 02:29
|Last Modified:
|14 Apr 2016 02:26
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digital mirror optical \ Amuse yourself with the touch
The interactive mirror with a simple, fun touch-screen monitor that supports the client
contact us now
... and see our prices
Request our new catalog now or call us!
DigitalMirror Optical proposed by GibamVision has been devised as an interactive mirror: the client will be able to use it as a mirror during the choice of different spectacles.
By using the integrated HD video camera the client can capture images and videoclips being than able to compare them, play them, send them by e-mail or publish them on his Facebook page as well as on other Social Networks.
Find out all details on the DigitalMirror Optical catalogue!


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123D Software
On the 28th of February 2013 Jens from Norway arrived in the Fab Lab Soshanguve, the planned schedule was completed as planned and was run smoothly. There was a lot of interaction from staff and users involved, FabLab users got understand on how different kinds of processes and soft ware's, Fab modules, 123D, Arduino etc are operated and manipulated which included, technology(Wireless technology), Design process and End mills techniques and working with different tool bits .The following software and processes were included.
1. Milling the surface of wax
2. Milling of curves structure balls
3. Introduction 123D Software for the, modela, vinyl and the Epilog
First cardboard 3D sketch of a high heeled sole. Made with 123D Design, 123D Make and the Epilog lasercutter.


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Lauren Townsend is currently
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The Upside of Your Darkside
Learn More
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Designing Positive Psychology
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Mindfulness, Acceptance and Positive Psychology
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See my blog post in @PsychToday detailing the 20 year journey I took to finally nail down how to measure the full complexity of curiosity. With stellar coauthors @david_disabato @FallonRGoodman @MichaelFSteger
The revised version of the Five Dimensional Curiosity Scale is published! Its briefer. We separated overt & covert social curiosity. And the psychometrics are even better! Stop using the other scales & use this! #wellbeing https://bit.ly/2RDST11 @FallonRGoodman @david_disabato
Ready to have your mind blown? #MLKJr, Anne Frank, and Barbara Walters were the same age. Born in 1929.
Copyright © 2020 Todd Kashdan
Follow @toddkashdan
Website Design by Haines Creative


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Goal of the project is to make a lightweight GPS logger that has a few different functionalities. I couldn't find a GPS tracker that had the features I was looking for, had the battery life or was reasonably affordable.
I started this project a couple years back, but I have been constantly been changing the design, form factor and features. Currently the design uses a few breakout boards for convenience. The end goal is to remove those and reduce the overall form factor. The next biggest upgrade will be switching to a Nordic based uC to further reduce the form factor and for built in Bluetooth.
- SD Card writing/reading
- BLE to transfer data to a smart phone
- Temperature, humidity, and pressure measurement
- 60+ hour battery life
- E-Ink display
One of my favorite additions to this project is the inclusion of pogo pins for the Li-ion battery. This allows for easy swapping of depleted batteries for the longer trips.
I also managed to mess around with the E-Ink display as well and created a fun little GUI for this device. Next challenge is to port over the code the nRF52. With each iteration of this design, I have been shrinking the design. The main limitation of my designs used to have been the size of the parts I have been using. But since I have been getting more familar with smaller components, I am able to hand assemble down to 0402 resisitors and with my new hot air rework station, I will do QFN type packages too. In addition to those and getting a microscope, my designs have been shrinking and becoming more of an embedded solution. I'm excited to see the next revision of this project and what it will soon look like. Now I just need a way to find more time to work on it….


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How To Bring Blood Sugar Down Fast
If you have problem with How To Bring Blood Sugar Down Fast You are more likely to develop How To Bring Blood Sugar Down Fast if you family history of How To Bring Blood Sugar Down Fast, or are overweight. Physical inactivity, race, and certain health problems such as How To Bring Blood Sugar Down Fast also affect your chance of developing How To Bring Blood Sugar Down Fast. You are also more likely to How To Bring Blood Sugar Down Fast if you have prediabetes or had How To Bring Blood Sugar Down Fast when you were pregnant. Learn more about risk factors for How To Bring Blood Sugar Down Fast. Training How To Bring Blood Sugar Down Fast them at Home. In this Article, We'll Show You Method How To Bring Blood Sugar Down Fast. Step by Step Guide to easily Your How To Bring Blood Sugar Down Fast. Learn How To Bring Blood Sugar Down Fast showing you Easydiabetes caused instead of replacing it.
Table Contents
- 1. How do i know if i have does splenda raise blood sugar?
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- + How can you get ?
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- + How ella freed ?
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Specialist Dental Services
The General Dental Council maintains lists of dentists who have completed specialist training in a number of areas of dentistry for the benefit of patients. The training is usually for three years, often including a Masters Degree and usually culminating with a specialist "Membership" examination at one of the Royal Colleges of Surgeons.
We are able to provide Specialist treatment in the following areas:
Prosthetic Dentistry (Ian Small), the restoring of missing teeth with crowns, bridges, implants and dentures.
Advanced restorative dentistry, Dental Implantology, Conscious sedation (Surinder Bhatti) has a special interest in carrying out all forms of complex restorative dentistry, including the surgical placement and restoration of dental implants and treating nervous patients using intra venous sedation. His career training pathway has lead to him becoming a General Dental practitioner with advanced skills in restorative dentistry.
Endodontics (Steve Williams), root canal treatment, root repairs and post restorations.
Oral Surgery (Aisha AlShawaf), including complicated wisdom teeth and implant surgery.
Further information for referring dentists and patients is available by clicking on the above links.
You can check that a specialist is registered with the General Dental Council by clicking here.


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Sarah Carlson, Development Director
Passionate about imagery and interpretation her whole life, Sarah has played a creative director role for two decades of design work in tourism, nonprofits, including exhibit design and revitalization. Sarah spent 15 years in Sioux Falls, SD and now 12 years in the Black Hills. Sarah dove into the executive director position 8 years ago at the Homestake Opera House in Lead, SD to assist in strategic planning and funding of restoration projects while the 105-old theater features 40 year-round events and tours. Sarah is grateful to live in a welcoming community that is truly "Miles Beyond Ordinary". Sarah has committed leadership roles in pastoral music performance and church choirs, community theatre, Lead Historic Preservation, Lead Area Chamber of Commerce, Black Hills and Badlands Tourism, and proudly sings the National Anthem for several annual events in Deadwood. Learn more about Sarah:
Anne Rogers-Popejoy, Education & Outreach/grantwriter
Anne first walked into the Opera House in 2008, blanket in hand, to see Fiddler on the Roof. It was cold, but she could tell that this place was special. Since then, Anne has volunteered at the HHOH with the Gold Camp Players, at events, and in various behind the scenes capacities for more than a decade. In 2018 she began writing grants with the development team, and joined the staff in 2019 as the Education and Outreach coordinator. Anne brings to the table nearly 15 years experience in youth development, fundraising, and community building. Anne's educational programs are hands-on, dynamic, and a lot of fun. She is passionate about equal access to quality arts and culture programs, and is glad to have found a home at the Historic Homestake Opera House.
Shanon Morrison, Office Manager/Bookkeeper
Shanon was born in Lead, SD where her family is one of the few who can boast five generations of workers at the Homestake Gold Mine. Shanon started her school years in Lead, SD when her family moved from the area for a few years, she spent all of her summers and vacations in the Black Hills, returning to Lead in 1986 to graduate from Lead High School in 1987. Shanon is the proud wife of Daniel, who years ago was a lifeguard at the HHOH in his teen years and where she spend many hours swimming. She is the mother of three adult children and currently three grandchildren. She has been involved with many organizations as a volunteer from a Girl Scout Leader, Boy Scout Popcorn Chairman, Lead Deadwood Youth Bowling Organization and Lead Deadwood Booster Club, to name just a few. Shanon's heart is definitely proud to be from Lead. She loves the history of the area. When not working at the HHOH she spends her time with her children and grandchildren, riding motorcycles with her family, or spending time at the MX track or working on genealogy research. Shanon has worked in the nonprofit world for 11 years and enjoys her job at the HHOH with all its history and enjoys the people she meets every day.


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Hiverson emotionally retreated into himself under the stinging words of the others. Social errors were very hard for bees to deal with; after all, colonies are very closed circuits, and one mishap could result in a negative reputation among the hive. "Silver-Honey Hiverson", the colony would soon be calling him. That is, if the colony survived; at this point, this seemed doubtful.
"Children, listen." Everyone stopped laughing immediately and turned back towards the center. The Queen's sweet voice had finally taken precedence over the chaotic chamber. Embarrassed as he was, Hiverson was glad that he'd helped her.
"The Silver Honey may be a myth, but that doesn't mean there isn't a grain of truth to it. Even if the honey is a myth, there may be something else up north – something that can stop the Skells. This hardworking drone may not have offered us a cure, but he's offered us a chance. After all, we managed to stop the Skells somehow ten generations ago, did we not?
Her logic was more or less sound, and the bees continued to listen.
"For this reason, we make a proposal. Three bees will travel north and search for the hive with the Silver Honey -"
"Wait a minute… where would the hive even be?" a bee pointed out. "I mean, it'd probably look different somehow, but we can't just search the entire North for it, can we?"
"Oh, IknowIknowIknow!" Another bee hopped up and down erratically, as if he was about to explode. From the bee's energy and tone of voice, Hiverson recognized him as Beeter.
"Oh, do you know something of the hive's whereabouts, Beeter?" the queen inquired.
"Yeahyeahyeah! So, I was outside this one morning, and I'd already collected the day's share of honey, so I decided, 'Hey, I should fly around a little and see the North!' So I flew around and around and then I saw this weird hive. It looked like a regular hive, but silver! I wanted to go check it out, but I decided not to because it was almost time for lunch. So I flew home and had lunch – the honey was delicious that day!"
"Wait a moment. You flew to the North without permission or accompaniment? Do you have any idea how dangerous that was? You could've been attacked by the Blood Cardinal, or possibly by something even worse!"
"Yeah, I could have asked, but that would be boring! I'd have to fly slowly, and then I couldn't go as far."
"…*sigh*. We'll discuss this incident later, Beeter. In any case, do you remember the direction of this Silver Hive?"
"Yeah! It was in the North!"
"We know it was in the North. Be more specific!" The Queen's patience was being stretched to its limit. Beeter tended to have that effect.
"Okay. It was, uh… itwasthisway!" Beeter launched into a frenetic waggle-dance. He moved so quickly that it was almost impossible to read his movements.
"Slow down, for God's sake!" the Queen shouted.
Beeter stopped for a moment. "…ugh, fine. You don't have to be so grumpy about it, you know." He resumed at a slower pace. It was still much faster than a typical waggle-dance, but now the other bees could interpret the specific direction.
"Good, good." The Queen calmed down a bit, although she was still frazzled. "Now, as we were saying, three bees will travel north to search for the Silver Hive. The rest of us will try to manage the situation as best we can; we cannot send more, unfortunately, as the colony could lose stability if too many bees are lost to the Skells. Dearest child, as this undertaking is your idea, would you do us the honor of being the group leader?"
Hiverson didn't have very much to consider. After all, this was his idea, and he couldn't back out of it now. Besides, he owed it to the colony to see the situation through to its end. "Yes, my Queen. I will do my best."
"I'll go too!" Beeter piped up. "Better than staying here, after all. I can't wait to fly all ov- I mean, explore the Silver Hive!"
"Good, good. Who shall be our third volunteer?" The Queen looked around at the assembly of bees. No one said a word for the longest time; the plan still seemed like a fool's venture at best and a death wish at worst, especially with the Blood Cardinal prowling the skies.
Finally, a small, timid voice emerged from Hiverson's right. "M-my Queen?" It was Barnabee's voice; Hiverson had become so engrossed in the situation that he had almost forgotten about him.
The Queen turned her head towards Barnabee. "Yes, child? Will you venture forth for our hive as well?"
Barnabee took a step back. He was shaking now, just as he had been when he told Hiverson the bad news. Hiverson didn't blame him; this would not be a safe journey, and in all truth he was scared too.
"Don't worry, Barnabee," Hiverson whispered. You don't have to do this. Someone else will join the group, and then we'll find that honey. You'll be fine, and Charlie will be fine too."
These words seemed to resonate with Barnabee. His shaking slowed, and he took a step forward. He looked up at the Queen.
"O-of course I'll go," he declared. "My friend has the Sk-skells, and… and I'm not going to let him die! I-I'll do whatever it takes!"
"Wonderful! Now venture forth, my children, and make our colony proud!"
The other bees began cheering. The cheers made Hiverson feel good, although he knew that the same skepticism was still prevalent among the colony. Beeter danced the waggle-dance again, and the three bees flew to the North with the steady wind at their backs.
Read more on Cole's Corner. Short Story. Part 2. "Bees: the Search for the Silver Hive"…


text: by Sarah Ewing Oct 18, 2019 Comments (0) AIChE Topics: Student Conferences Video Chem-E-Car Share This Post: 2/5 in the series Chem-E-Car in the Spotlight Series - 2019 CompetitorsForty-four teams will participate in the 2019 Annual Chem-E-Car Competition® in Orlando on November 10 from 12:30 - 4:00pm EST. Learn more about this year's competitors, the award, and this year's Annual Student Conference. All teams were asked to provide a video spotlighting their car, school, and team. These videos will be played before each competitor's run, but you can enjoy them in this ChEnected series, which will be updated with new posts from now until the competition. Videos will be posted in the order we received them. Check out the latest set of submitted videos After watching the videos below, be sure to share them with the hashtags #AIChEASC and #ChemECar. If you missed the previous set of videos, you can watch them here. Cal Poly Pomona City College of New York Centro Universitário SENAI CIMATEC Michigan State University Iowa State University Nanjing Tech University KAIST Missouri University of Science and Technology More Chem-E-Car in the Spotlight videos will be posted within a week, so stay tuned to this series. In the meantime, you can see last year's competitors. Doing a World of Good Campaign This initiative is supported by the AIChE Foundation's Doing a World of Good Campaign. Let us know what you think of the videos and teams in the comments below. Log in to post comments


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PCI Webinar with Cari Dubiel and Crystal Williams
Generational Harmony: Teaching, Training and Interacting
Millennials are lazy, Baby Boomers only care about themselves, and Generation Xers are overworked – right? At least that's what the media leads us to believe. Now more than ever, it's important for library staff to understand the real differences between the generations and why they matter.
In this webinar, the presenters will remove the mystique from the concept of generations in the workplace and give you practical tips for understanding people of any generation.
Participants will:
- Identify the four generations currently in the workplace, as well as the upcoming generation
- Understand the features of each generation and what they mean
- Discover the unique ways the generations learn
- Explore how the generations relate to each other in the workplace
Cari Dubiel ~ Biography
Cari Dubiel is the co-host of the ABC Book Reviews Podcast, a popular online program that was recognized by the Wall Street Journal as a best book podcast. Cari has worked in public libraries for over 15 years, doing everything from student page to her most current role as computer services manager. Her areas of expertise include reader's advisory, collection development, technology, strategic planning, event planning, and continuing education for adults.
Crystal Williams ~ Biography
Crystal Williams is the Continuing Education Coordinator for Twinsburg Public Library. She has been instrumental in developing innovative programs both in-person and online, including language classes, train-the-trainer sessions, and technology training for patrons.


text: The second single follow up, 'Jogi', has also joined 'Mundian To Bach Ke' as a UK Radio1 play-list record, and went straight in at #25 on the UK singles chart. The song also hit Top #10 in Austria, Belgium, Switzerland and #12 in the official German charts - another huge success for the first Bhangra artist to truly cross-over into the mainstream. Hugely influential Ragga artist 'Beenie Man' has since joined the party, adding his vocal skills to a remix 'Jogi', which was thoroughly cained on dancefloors across the country and Eastern Europe.


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How to do sofa chic
Never mind all the parties, the thing we're most looking forward to this Christmas is hunkering down at home. Here's what we'll be wearing - just accessorize with a book and mince pie.
Christmas gift guide: for him
What to buy the man in your life? Hey, easy peasy! Here's our curated 'Best for Blokes', as chosen by Muddy editors across our 22 gorgeous counties.
Shake up your style
Throw out the rule book, become a fashion rebel and ring the changes this festive season - voilà, our top style tips for rebooting your wardrobe. Come in, little black dress, your time is up!
Party like you mean it
Going out out and nothing to wear? Harvey Nichols has come up trumps this season so here's my wishlist to whet your whistle. Plus win £500 worth of party clobber!
Inspired by nature
Organic designs and a pop of colour are features of the latest hand crafted pieces by jewellers Simon Pure
Ready to wrap up?
Brrrrrrr! It's got a bit chilly hasn't it? Come warm yourself with these 10 stylish woolies and coats from the ever-brilliant hush, starting with this elegant ribbed, frill-necked beauty.
Win 7 perfect pieces to ease you into Autumn
Muddy's fashion fave hush has come up trumps yet again with its trans-seasonal collection - and we have five sets of our fashion edit to give away , worth over £3500. *This giveaway is now closed*
Fabulous festival fashion
Eye popping Indonesian-style Dutch wax batik dresses, shoes, hats, cushions – and brollies – to get you in the festival mood
Rainbow Jewellery
Pride Season got you in rainbow mood? There are some fabulous multi-coloured gems out there to gift a loved one (or yourself)
In all your Finery
Need a summer party frock? This under-the-radar label majors in cool dresses and jumpsuits. We've got £500 worth of Finery goodies up for grabs for 10 lucky Muddy readers - that's £5k worth of foxy fashion! (Sorry! This competition has closed.)
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For a day at the races, you'll want to look your most stylish. Make it to the winners' enclosure at Lingfield Park's Spring Ladies' Day on Fri 8 Mar with our race day inspiration.
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WNN - 18 September 2019 - Nuclear and renewable generation should be used in combination to make the most of their synergies in integrated systems to help the world meet carbon reduction goals and limit temperature rise, leaders from governmental and non-governmental organisations and industry said yesterday. Innovative nuclear technologies will play their part in integrated systems alongside renewables, with combined uses of heat and power, hydrogen production, desalination and industrial decarbonisation.
Nuclear Energy in Clean Energy Solutions - Telling our Story was hosted by NICE Future at the 63rd IAEA General…
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Thousands of lives and billions of dollars lost in the devastating Indian Ocean tsunami in 2004 could have been saved if disaster reduction strategies had been in place, United Nations tsunami envoy former United States President Bill Clinton said today, highlighting the urgent need to implement these measures.
In a statement marking the one-year anniversary of an international agreement aimed at reducing the impact of natural disasters – known as the Hyogo Framework for Action – Mr. Clinton urged all governments and international institutions to act on its recommendations immediately.
"Disaster risk awareness education needs to be incorporated into school curricula, communities should be informed about potential hazards, and new construction must adhere to safer building-standards," Mr. Clinton said.
"These achievable goals were adopted by 168 governments at the World Conference on Disaster Reduction which took place in January 2005, one month after the tsunami struck the region," he said, emphasizing that there was no time to lose.
The Hyogo Framework, which runs from 2005-2015, calls on governments to invest in measures such as national and local risk assessments, early warning systems, public awareness and education, better urban planning and safer building construction codes.
On Wednesday, Sálvano Briceño, Director of the International Strategy for Disaster Reduction (ISDR), said that since the signing of the Framework in January 2005, some 40 countries had put disaster risk reduction at the top of their political agendas, but he called for further actions to strengthen prevention systems.
The 26 December 2004 tsunami disaster killed over 230,000 people and displaced some 1.5 million in more than 12 countries.


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Research Output per year
Fingerprint Dive into the research topics where Annette Mercer is active. These topic labels come from the works of this person. Together they form a unique fingerprint.
- 27 Similar Profiles
Medical Schools Medicine & Life Sciences
health science Social Sciences
Students Medicine & Life Sciences
school Social Sciences
Medicine Medicine & Life Sciences
medical student Social Sciences
medicine Social Sciences
Medical Students Medicine & Life Sciences
Recent external collaboration on country level. Dive into details by clicking on the dots.
Research Output 2005 2019
Likelihood of rural practice in medical school entrants with prior tertiary experiencePlayford, D. E., Mercer, A., Carr, S. E. & Puddey, I. B., 8 Apr 2019, In : Medical Teacher. p. 1-8 8 p.
Research output: Contribution to journal › Article
Medical Schools
Relative progress and academic performance of graduate vs undergraduate entrants to an Australian medical schoolPuddey, I. B., Mercer, A. & Carr, S. E., 22 May 2019, In : BMC Medical Education. 19, 14 p., 159.
Research output: Contribution to journal › Article
Open Access
Interprofessional clinical supervisor trainingPotter, M., Mercer, A. & Lake, F., Feb 2018, In : The Clinical Teacher. 15, 1, p. 62-66
Research output: Contribution to journal › Article
Appointments and Schedules
Age Groups
Predicting performance of junior doctors: Association of workplace based assessment with demographic characteristics, emotional intelligence, selection scores, and undergraduate academic performanceCarr, S. E., Celenza, A., Mercer, A. M., Lake, F. & Puddey, I. B., 2 Nov 2018, In : Medical Teacher. 40, 11, p. 1175-1182 8 p.
Research output: Contribution to journal › Article
Emotional Intelligence
emotional intelligence
Medical Schools
The relative predictive value of undergraduate versus graduate selection tools in two Australian medical schoolsMercer, A., Hay, M., Hodgson, W. C., Canny, B. J. & Puddey, I. B., 2 Nov 2018, In : Medical Teacher. 40, 11, p. 1183-1190 8 p.
Research output: Contribution to journal › Article
health science


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Finding a needle in a haystack: Discovery of Ti2InB2 for synthesizing layered TiB
Scientists at Tokyo Institute of Technology (Tokyo Tech) have used boron as the X element in a family of materials called MAX phases, for which only carbon and nitrogen could previously be used. A clever search strategy allowed them to avoid resorting to trial and error to design this novel material, from which layered TiB can be obtained for applications in Li- or Na-ion batteries.
Considering that there are dozens of elements in the periodic table and thousands of possible combinations, it is no surprise that researchers resort to ingenious ways to predict which compounds can be synthesized in practice and would have favorable properties. One class of useful materials is referred to as "MAX phases." These are ternary compounds consisting of three elements represented by M, A and X that exhibit ceramic and metallic properties.
These compounds form layered structures from which the "A-layer" can be etched, leaving behind what is known as 2-D MXenes. MXenes have attracted a lot of attention because they can take a number of forms and structures and offer excellent chemical and mechanical stability. This makes them applicable in a wide variety of fields, such as batteries and catalysis.
Unitl now, MAX compounds have been limited to using carbon or nitrogen for the X element. A research team from Tokyo Tech, led by Prof. Hideo Hosono, studied the possibility of synthesizing MAX phases composed of titanium, indium and boron: Ti2InB2. Motivated by the fact that borides have promising applications in nanoelectronics, the team ultimately sought to synthesize TiB-based MXenes.
Because direct synthesis of layered TiB is impossible, the team first had to determine an A-element for synthesizing a MAX phase (that is, the middle element in Ti-A-B). Then they would have to find a way to etch the A-layer from the MAX phase to obtain the coveted layered TiB. In order to determine which elements were suitable for the A in the MAX phase, they employed a clever automated search strategy through computer-assisted calculations. They first analyzed the "binary" structures formed between each of the candidates for A and either TiB or Ti3B4. Those that proved stable were subjected to "ternary" calculations for determining the global stability of the ternary compound.
A final verification with high-precision structural calculations was carried out for the best candidates, which finally pointed at Ti2InB2 as the best option. With this strategy, they reduced the computational cost of their search and demonstrated a clever approach for finding desired ternary compounds. "A feasible strategy to simplify the search for ternary compounds based on the available domain knowledge is in high demand," explains Hosono.
The team demonstrated that Ti2InB2 could be effectively synthesized, and then explored the possibility of removing In from the MAX phase to obtain the desired MX phase. Although the team did manage to obtain layered TiB from the MAX phase, its structure was not exactly compatible with that of existing 2-D MXenes. However, by tuning the necessary conditions of their approach, the researchers believe that it will be possible to obtain TiB MXene in the future. Thus, they carried out a number of calculations demonstrating its superior electrical properties, hinting at its potential application as an excellent anode material for lithium- or sodium-ion batteries. "The present research will extend the fascinating class of MAX phases and MXenes," concludes Hosono.