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Rare-earth-containing perovskite nanomaterials: design, synthesis, properties and applications Chem. Soc. Rev. (IF 40.443) Pub Date : 2020-01-15 Zhichao Zeng; Yueshan Xu; Zheshan Zhang; Zhansheng Gao; Meng Luo; Zongyou Yin; Chao Zhang; Jun Xu; Bolong Huang; Feng Luo; Yaping Du; Chunhua Yan
Catechol-functionalized hydrogels: biomimetic design, adhesion mechanism, and biomedical applications Chem. Soc. Rev. (IF 40.443) Pub Date : 2020-01-15 Wei Zhang; Ruixing Wang; ZhengMing Sun; Xiangwei Zhu; Qiang Zhao; Tengfei Zhang; Aleksander Cholewinski; Fut (Kuo) Yang; Boxin Zhao; Rattapol Pinnaratip; Pegah Kord Forooshani; Bruce P. Lee
A redox interaction-engaged strategy for multicomponent nanomaterials Chem. Soc. Rev. (IF 40.443) Pub Date : 2020-01-10 Xiao Wang; Shuyan Song; Hongjie Zhang
Fluorescent glycoconjugates and their applications Chem. Soc. Rev. (IF 40.443) Pub Date : 2020-01-09 Baptiste Thomas; Kai-Cheng Yan; Xi-Le Hu; Marion Donnier-Maréchal; Guo-Rong Chen; Xiao-Peng He; Sébastien Vidal
Emerging new phase boundary in potassium sodium-niobate based ceramics Chem. Soc. Rev. (IF 40.443) Pub Date : 2020-01-08 Xiang Lv; Jianguo Zhu; Dingquan Xiao; Xi-xiang Zhang; Jiagang Wu
Correction: Voltage issue of aqueous rechargeable metal-ion batteries Chem. Soc. Rev. (IF 40.443) Pub Date : 2020-01-08 Zhuoxin Liu; Yan Huang; Yang Huang; Qi Yang; Xinliang Li; Zhaodong Huang; Chunyi Zhi
Correction for 'Voltage issue of aqueous rechargeable metal-ion batteries' by Zhuoxin Liu et al., Chem. Soc. Rev., 2020, DOI: 10.1039/c9cs00131j.
Synthesis of micro/nanoscaled metal–organic frameworks and their direct electrochemical applications Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-12-13 Xiao Xiao; Lianli Zou; Huan Pang; Qiang Xu
Chiral phosphoric acid-catalyzed asymmetric dearomatization reactions Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-12-12 Zi-Lei Xia; Qing-Feng Xu-Xu; Chao Zheng; Shu-Li You
Advances of 2D bismuth in energy sciences Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-12-11 Xuhai Liu; Shengli Zhang; Shiying Guo; Bo Cai; Shengyuan A. Yang; Fukai Shan; Martin Pumera; Haibo Zeng
Photoexcited carrier dynamics in colloidal quantum dot solar cells: insights into individual quantum dots, quantum dot solid films and devices Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-12-11 Yaohong Zhang; Guohua Wu; Feng Liu; Chao Ding; Zhigang Zou; Qing Shen
Advances in ultrahigh-throughput screening for directed enzyme evolution Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-12-09 Ulrich Markel; Khalil D. Essani; Volkan Besirlioglu; Johannes Schiffels; Wolfgang R. Streit; Ulrich Schwaneberg
Design, synthesis and photoinduced processes in molecular interlocked photosynthetic [60]fullerene systems Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-12-06 Jackson D. Megiatto, Jr; Dirk M. Guldi; David I. Schuster
Formazanate coordination compounds: synthesis, reactivity, and applications Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-12-05 Joe B. Gilroy; Edwin Otten
Recent advances in copper-catalysed radical-involved asymmetric 1,2-difunctionalization of alkenes Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-12-05 Zhong-Liang Li; Gui-Chun Fang; Qiang-Shuai Gu; Xin-Yuan Liu
Assembly strategies of organic-based imaging agents for fluorescence and photoacoustic bioimaging applications Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-12-04 Hong-Bo Cheng; Yuanyuan Li; Ben Zhong Tang; Juyoung Yoon
Voltage issue of aqueous rechargeable metal-ion batteries Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-11-29 Zhuoxin Liu; Yan Huang; Yang Huang; Qi Yang; Xinliang Li; Zhaodong Huang; Chunyi Zhi
Synthetic ratiometric fluorescent probes for detection of ions Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-11-21 Sang-Hyun Park; Nahyun Kwon; Jee-Hyeon Lee; Juyoung Yoon; Injae Shin
Emerging aqueous two-phase systems: from fundamentals of interfaces to biomedical applications Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-11-21 Youchuang Chao; Ho Cheung Shum
A review of defect structure and chemistry in ceria and its solid solutions† Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-12-24 Rafael Schmitt; Andreas Nenning; Olga Kraynis; Roman Korobko; Anatoly I. Frenkel; Igor Lubomirsky; Sossina M. Haile; Jennifer L. M. Rupp
Understanding of carrier dynamics, heterojunction merits and device physics: towards designing efficient carrier transport layer-free perovskite solar cells Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-12-20 Jin-Feng Liao; Wu-Qiang Wu; Yong Jiang; Jun-Xing Zhong; Lianzhou Wang; Dai-Bin Kuang
Palladium-catalyzed oxidative dehydrogenative carbonylation reactions using carbon monoxide and mechanistic overviews Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-12-18 Can Zhu; Jie Liu; Man-Bo Li; Jan-E. Bäckvall
Correction: The challenges of glycan recognition with natural and artificial receptors Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-12-18 Stefano Tommasone; Francia Allabush; Yazmin K. Tagger; Joshua Norman; Monika Köpf; James H. R. Tucker; Paula M. Mendes
Correction for 'The challenges of glycan recognition with natural and artificial receptors' by Stefano Tommasone et al., Chem. Soc. Rev., 2019, 48, 5488–5505.
The unique features and promises of phthalocyanines as advanced photosensitisers for photodynamic therapy of cancer Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-12-17 Pui-Chi Lo; M. Salomé Rodríguez-Morgade; Ravindra K. Pandey; Dennis K. P. Ng; Tomás Torres; Fabienne Dumoulin
In-plane aligned assemblies of 1D-nanoobjects: recent approaches and applications Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-12-17 Hebing Hu; Shancheng Wang; Xueling Feng; Matthias Pauly; Gero Decher; Yi Long
Polymer-guided assembly of inorganic nanoparticles Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-12-17 Chenglin Yi; Yiqun Yang; Ben Liu; Jie He; Zhihong Nie
Organic photodiodes and phototransistors toward infrared detection: materials, devices, and applications Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-12-12 Cong Wang; Xiaotao Zhang; Wenping Hu
Heme: emergent roles of heme in signal transduction, functional regulation and as catalytic centres Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-11-21 Toru Shimizu, Alzbeta Lengalova, Václav Martínek, Markéta Martínková
Electrochemical nitrogen fixation and utilization: theories, advanced catalyst materials and system design Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-11-19 Wenhan Guo, Kexin Zhang, Zibin Liang, Ruqiang Zou, Qiang Xu
Rare-earth metal and actinide organoimide chemistry† Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-11-13 Dorothea Schädle, Reiner Anwander
Superparamagnetic nanoarchitectures for disease-specific biomarker detection Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-11-13 Mostafa Kamal Masud, Jongbeom Na, Muhammad Younus, Md. Shahriar A. Hossain, Yoshio Bando, Muhammad J. A. Shiddiky, Yusuke Yamauchi
Hybrid polyoxometalates as post-functionalization platforms: from fundamentals to emerging applications Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-12-03 Alexander V. Anyushin, Aleksandar Kondinski, Tatjana N. Parac-Vogt
Cyclometallated tridentate platinum(ii) arylacetylide complexes: old wine in new bottles Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-11-13 Ashanul Haque, Linli Xu, Rayya A. Al-Balushi, Mohammed K. Al-Suti, Rashid Ilmi, Zeling Guo, Muhammad S. Khan, Wai-Yeung Wong, Paul R. Raithby
Correction: Solid-state electrical applications of protein and peptide based nanomaterials Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-11-07 Sayak Subhra Panda, Howard E. Katz, John D. Tovar
Correction for 'Solid-state electrical applications of protein and peptide based nanomaterials' by Sayak Subhra Panda et al., Chem. Soc. Rev., 2018, 47, 3640–3658.
Enzymatic self-sufficient hydride transfer processes Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-11-01 Erika Tassano, Mélanie Hall
The design and biomedical applications of self-assembled two-dimensional organic biomaterials Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-10-31 Xiaoyuan Zhang, Coucong Gong, Ozioma Udochukwu Akakuru, Zhiqiang Su, Aiguo Wu, Gang Wei
Colloidal metal–organic framework particles: the pioneering case of ZIF-8 Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-10-30 Javier Troyano, Arnau Carné-Sánchez, Civan Avci, Inhar Imaz, Daniel Maspoch
In situ optical spectroscopy characterization for optimal design of lithium–sulfur batteries Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-10-24 Li Zhang, Tao Qian, Xingyu Zhu, Zhongli Hu, Mengfan Wang, Liya Zhang, Tao Jiang, Jing-Hua Tian, Chenglin Yan
Hybrid materials based on conjugated polymers and inorganic semiconductors as photocatalysts: from environmental to energy applications Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-10-14 Marta Liras, Mariam Barawi, Víctor A. de la Peña O'Shea
Local biomaterials-assisted cancer immunotherapy to trigger systemic antitumor responses Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-10-07 Qian Chen, Muchao Chen, Zhuang Liu
The challenges of glycan recognition with natural and artificial receptors Chem. Soc. Rev. (IF 40.443) Pub Date : 2019-09-25 Stefano Tommasone, Francia Allabush, Yazmin K. Tagger, Joshua Norman, Monika Köpf, James H. R. Tucker, Paula M. Mendes
Free radical intermediates in the inhibition of the autoxidation reaction. Chem. Soc. Rev. (IF 40.443) Pub Date : 2010-06-02 Marco Lucarini,Gian Franco Pedulli
The autoxidation of organic materials is a detrimental radical chain process often leading to their rapid deterioration unless they are protected by preventive and/or chain breaking antioxidants. The properties of the more important family of the latter ones, that one of phenols, are illustrated in this tutorial review. A short outline of diarylamine antioxidants is also given. We describe simple experimental methods employed for the determination of the two parameters more useful for estimating the inhibiting power of antioxidants, that is the kinetic rate constant for their reaction with the chain carrying peroxyl radicals, k(inh), to give persistent phenoxyl or aminyl radicals and the bond dissociation enthalpy BDE(X-H) (X = O, N) of the bond cleaved in the inhibition process. The dependence of these parameters on the number and nature of the substituents is discussed and, in the case of phenols, a simple rule allowing to predict with reasonable accuracy the BDE and k(inh) values, from their structure. The effect of solvent polarity on the antioxidant power is also described. Finally, the information on the mechanism of reaction between phenols and peroxyl radicals provided by both experiments and theoretical calculations are examined. Because of difficulties associated with the analysis of non-homogenous systems all the reported results refer to homogenous solution in which experimental data can be analysed by means of more reliable and complete treatments.
Cu-free click cycloaddition reactions in chemical biology. Chem. Soc. Rev. (IF 40.443) Pub Date : 2010-03-31 John C Jewett,Carolyn R Bertozzi
Bioorthogonal chemical reactions are paving the way for new innovations in biology. These reactions possess extreme selectivity and biocompatibility, such that their participating reagents can form covalent bonds within richly functionalized biological systems--in some cases, living organisms. This tutorial review will summarize the history of this emerging field, as well as recent progress in the development and application of bioorthogonal copper-free click cycloaddition reactions.
Electrochemical applications. How click chemistry brought biomimetic models to the next level: electrocatalysis under controlled rate of electron transfer. Chem. Soc. Rev. (IF 40.443) Pub Date : 2010-03-31 Richard A Decréau,James P Collman,Ali Hosseini
This tutorial review discusses the immobilization of alkyne-terminated cytochrome c oxidase models on azide-functionalized self-assembled monolayers (SAM) coated gold electrodes that was made possible by click chemistry. The rate of electron delivery from the electrode to the model could be tuned by changing the nature of the SAM. Biologically relevant electron transfer rates (2-4 s(-1)) were obtained on slow SAMs allowing the model to turn over catalytically under steady-state conditions. Hence, click chemistry was a crucial tool to demonstrate, through electrocatalytic studies: (1) the role played by several features present in the distal side of the model, such as the Cu(B)-Tyr244 pair, the distal pocket, and the stabilizing role of a distal water cluster; (2) the reversible inhibition of O(2) reduction by H(2)S.
Click chemistry generates privileged CH hydrogen-bonding triazoles: the latest addition to anion supramolecular chemistry. Chem. Soc. Rev. (IF 40.443) Pub Date : 2010-03-31 Yuran Hua,Amar H Flood
The supramolecular chemistry of anions provides a means to sense and manipulate anions in their many chemical and biological roles. For this purpose, Click chemistry facilitated the synthetic creation of new receptors and thus, an opportunity to aid in the recent re-examination of CH...anion hydrogen bonding. This tutorial review will focus on the privileged C-H hydrogen bond donor of the 1,2,3-triazole ring systems as elucidated from anion-binding studies with macrocyclic triazolophanes and other receptors. Triazolophanes are shape-persistent and planar macrocycles that direct four triazole and four phenylene CH groups into a 3.7 A cavity. They display strong (log K(Cl(-)) = 7), size-dependent halide binding (Cl(-) > Br(-) >> F(-) >> I(-)) and a rich set of binding equilibria. For instance, the too large iodide (4.4 A) can be sandwiched between two pyridyl-based triazolophanes with extreme positive cooperativity. Computational studies verify the triazole's hydrogen bond strength indicating it approaches the traditional NH donors from pyrrole. These examples, those of transport, sensing (e.g., ion-selective electrodes), templation, and versatile synthesis herald the use of triazoles in anion-receptor chemistry.
Recent advances in the semi-pinacol rearrangement of alpha-hydroxy epoxides and related compounds. Chem. Soc. Rev. (IF 40.443) Pub Date : 2008-01-25 Timothy J Snape
The semi-pinacol rearrangement is fast becoming an extremely reliable reaction in organic synthesis allowing the rapid construction of relatively complex stereodefined products in high yield. Recent advances in asymmetric synthesis have also enabled enantiopure precursors to partake in the rearrangement showing that extremely high levels of stereospecificity are observed. In this critical review recent advances in the semi-pinacol rearrangement over the past 15 years are examined which demonstrate the extremely high utility of this reaction towards the development of structurally diverse organic building blocks (74 references).
Synthesis using aromatic homolytic substitution--recent advances. Chem. Soc. Rev. (IF 40.443) Pub Date : 2008-01-25 W Russell Bowman,John M D Storey
This critical review aims at presenting recent developments in intramolecular aromatic homolytic substitution which has become one of the common methodologies in modern synthesis. The application of Bu3SnH-mediated cyclisations have proved especially useful. The critical review illustrates the mechanistic considerations required for planning synthetic applications and a wide range of synthetic protocols and natural product syntheses are shown. The latest evidence for the mechanisms involved in aromatic homolytic substitution are presented. (152 references).
Plant oil renewable resources as green alternatives in polymer science. Chem. Soc. Rev. (IF 40.443) Pub Date : 2008-01-25 Michael A R Meier,Jürgen O Metzger,Ulrich S Schubert
The utilization of plant oil renewable resources as raw materials for monomers and polymers is discussed and reviewed. In an age of increasing oil prices, global warming and other environmental problems (e.g. waste) the change from fossil feedstock to renewable resources can considerably contribute to a sustainable development in the future. Especially plant derived fats and oils bear a large potential for the substitution of currently used petrochemicals, since monomers, fine chemicals and polymers can be derived from these resources in a straightforward fashion. The synthesis of monomers as well as polymers from plant fats and oils has already found some industrial application and recent developments in this field offer promising new opportunities, as is shown within this contribution. (138 references.)
Metal 2-ethylhexanoates and related compounds as useful precursors in materials science. Chem. Soc. Rev. (IF 40.443) Pub Date : 2008-01-25 Shashank Mishra,Stéphane Daniele,Liliane G Hubert-Pfalzgraf
This critical review deals with the chemistry and applications of metal alkanoates with medium size (C5 to C12) carbon chain length. A particular emphasis is given to metal 2-ethylhexanoates, which find wide applications as metal-organic precursors in materials science, as catalysts for ring opening polymerizations and also in painting industries for their properties as driers. After a brief introduction and an overview of synthesis, structural and physico-chemical properties, this article discuses extensively the applications of these compounds in materials science. Finally, it identifies and signifies the areas for future research in the looking ahead section. The aim of this review is to bridge the areas of precursor's chemistry and materials science by providing a reference text for researchers working either in or at the interface of these two areas (125 references).
New concepts in multidentate ligand chemistry: effects of multidentarity on catalytic and spectroscopic properties of ferrocenyl polyphosphines. Chem. Soc. Rev. (IF 40.443) Pub Date : 2008-01-25 Jean-Cyrille Hierso,Radomyr Smaliy,Régine Amardeil,Philippe Meunier
This tutorial review devoted to ligand chemistry deals with the design and properties of ferrocenyl polyphosphines, an original class of multidentate ligands. The development of a varied library of ferrocenyl tetra-, tri- and diphosphine ligands is reviewed. The multidentate nature of these species has led to unique spectroscopic and catalytic properties, in which the spatial proximity of phosphorus atoms is crucial. Regarding their catalytic applications, the key issues of catalyst longevity and ultralow catalyst loadings are discussed. Another part is concerned with fundamental advances gained in physical chemistry for structure elucidation by the study of the intriguing "through-space" NMR spin-spin J couplings existing within several of these polyphosphines.
Materials synthesis using oxide free sol-gel systems. Chem. Soc. Rev. (IF 40.443) Pub Date : 2008-01-25 Andrew L Hector
This tutorial review highlights some active areas of research into non-oxide sol-gel chemistry. These aim to capture some of the advantages of methods developed mainly with oxides for a new generation of functional materials based on main group and metal nitrides, and semiconducting chalcogenides. Sol-gel processing has a long track record in producing useful materials for optical, magnetic, electrical, catalytic and structural applications. Controlled morphologies can be produced on all lengths scales, from ordered mesoporous arrays to thin films, fibres and monoliths. Hence there is an opportunity to produce new morphologies in non-oxides and hence new applications of these materials.
Anionic tethered N-heterocyclic carbene chemistry. Chem. Soc. Rev. (IF 40.443) Pub Date : 2008-01-25 Stephen T Liddle,Ian S Edworthy,Polly L Arnold
Since the discovery of a stable "bottleable" N-heterocyclic carbene (NHC), there has been a spectacular explosion of interest in this ligand class. This interest stems from a desire to understand the fundamentals of the structure and bonding of these systems, but also because of their numerous and emerging applications in small molecule activation, homogeneous catalysis and Lewis acid-catalysed reactions. In this Tutorial Review, we introduce the reader to NHCs, cover general synthetic methods to prepare anionic tethered NHCs and their metal complexes, and discuss emerging applications in reactivity and catalytic studies.
Integrated computational strategies for UV/vis spectra of large molecules in solution. Chem. Soc. Rev. (IF 40.443) Pub Date : 2008-01-25 Vincenzo Barone,Antonino Polimeno
In recent years, the margin of interaction between computational chemistry and most branches of experimental chemistry has increased at a fast pace. The experimental characterization of new systems relies on computational methods for the rationalization of structural, energetic, electronic and dynamical features. In particular, novel computational approaches allow accurate estimates of molecular parameters from spectroscopic optical observables, giving rise to synergic interactions between experimentalists and theoretically-oriented chemists. Our main objective in this tutorial review is to delineate the degree of advancement of possible integrated computational approaches to the interpretation of optical spectroscopies, with an accent on large molecules in solvated environments, based on the combination of advanced quantum mechanical treatments and stochastic modelling of relaxation processes.
Template-directed synthesis employing reversible imine bond formation. Chem. Soc. Rev. (IF 40.443) Pub Date : 2008-01-25 Cari D Meyer,C Steven Joiner,J Fraser Stoddart
The imine bond--formed by the reversible condensation of an amine and an aldehyde--and its applications as a dynamic covalent bond in the template-directed synthesis of molecular compounds, will be the focus of this tutorial review. Template-directed synthesis--or expressed another way, supramolecular assistance to covalent synthesis--relies on the use of reversible noncovalent bonding interactions between molecular building blocks in order to preorganise them into a certain relative geometry as a prelude to covalent bond formation to afford the thermodynamically preferred product. The use of this so-called dynamic covalent chemistry (DCC) in templated reactions allows for an additional amount of reversibility, further eliminating potential kinetic products by allowing the covalent bonds that are formed during the template-directed reaction to be 'proofread for errors', thus making it possible for the reaction to search out its thermodynamic minimum. The marriage of template-directed synthesis with DCC has allowed chemists to construct an increasingly complex collection of compounds from relatively simple precursors. This new paradigm in organic synthesis requires that each individual piece in the molecular self-assembly process is preprogrammed so that the multiple recognition events expressed between the pieces are optimised in a highly cooperative manner in the desired product. It offers an extremely simple way of making complex mechanically interlocked compounds--e.g., catenanes, rotaxanes, suitanes, Borromean rings and Solomon knots--from relatively simple precursors.
Enantioselective C-C bond synthesis catalysed by enzymes. Chem. Soc. Rev. (IF 40.443) Pub Date : 2005-09-03 Joly Sukumaran,Ulf Hanefeld
The enantioselective synthesis of C-C bonds is often the pivotal step of a synthesis. Nature has made a variety of versatile enzymes available that catalyse this type of reaction very selectively under mild conditions. Cyanohydrins, acyloins (alpha-hydroxy ketones), alpha-hydroxy acids and aldols (beta-hydroxy ketones) are very efficiently synthesised enantioselectively with the aid of C-C bond forming enzymes, which we discuss in this tutorial review. In the case of the alpha-hydroxy acids the applications of nitrilases in a synthetic dkr even allows a disconnection that has no enantioselective chemical equivalent.
Axially modified gallium phthalocyanines and naphthalocyanines for optical limiting. Chem. Soc. Rev. (IF 40.443) Pub Date : 2005-09-03 Yu Chen,Michael Hanack,Yasuyuki Araki,Osamu Ito
Phthalocyanines (Pcs) offer a high architectural flexibility in structure, which facilitates the tailoring of their physical, optoelectronic and chemical parameters over a very broad range. This tutorial review describes the recent advances in the synthesis of soluble axially substituted or bridged gallium phthalo- and naphthalocyanine compounds, and their photophysical and nonlinear optical properties. The exploitation of the chemical reactivity of the Ga-Cl bond can allow the preparation of a series of highly soluble axially substituted and bridged Pc complexes. Axial substituents in Pcs influence favourably nonlinear optical absorption for the presence of a dipole moment perpendicular to the macrocycle in the axially substituted phthalocyanines. All Z-scans performed exhibit a decrease of transmittance about the focus typical of an induced positive nonlinear absorption of incident light. Substitution and dimerization of the phthalocyanine monomer resulted in significant reductions in the saturation energy density of the material displaying clear evidence of the usefulness of structurally modifying the gallium phthalocyanine unit. Similar to indium phthalocyanines, gallium phthalocyanines are also among the most promising materials that have been investigated as limiters of intense light and the current series presents a selection of structural modifications useful for varying their nonlinear optical properties.
1,3-dipolar cycloaddition on solid supports: nitrone approach towards isoxazolidines and isoxazolines and subsequent transformations. Chem. Soc. Rev. (IF 40.443) Pub Date : 2005-09-03 Karola Rück-Braun,Tonia H E Freysoldt,Frank Wierschem
1,3-dipolar cycloaddition reactions of nitrones with alkenes and alkynes are well-studied reactions in solution-phase organic chemistry. However, the number of studies concerned with their application in solid-phase organic synthesis is rather low compared to other 1,3-dipoles, e.g. azides or nitrile oxides. This tutorial review aims to summarise the main approaches towards the application of nitrones in 1,3-dipolar cycloaddition reactions on solid supports in addition to subsequent transformations with polymer-bound isoxazolidines and reactions using polymer-bound catalysts.
Metallacyclopeptides: artificial analogues of naturally occurring peptides. Chem. Soc. Rev. (IF 40.443) Pub Date : 2005-09-03 Markus Albrecht,Patrick Stortz
Naturally occurring metalloproteins contain metal ions either to introduce a special reactivity or to stabilize a peptide structure. Since the early 1990s, chemists have been trying to use metal coordination for the fixation of short artificial peptides in well-defined cyclic structures. In this tutorial review a survey of the general approaches towards metallacyclopeptides as small cyclic peptide derivatives or as a part of a bigger alpha-helix (or beta-sheet) structure is given. In three case studies it is shown how naturally occurring compounds can be mimicked by metal coordination to non-natural peptide derivatives.
Linear pi-conjugated systems derivatized with C60-fullerene as molecular heterojunctions for organic photovoltaics. Chem. Soc. Rev. (IF 40.443) Pub Date : 2005-09-03 Jean Roncali
This tutorial review covers recent contributions in the area of linear pi-conjugated systems bound to fullerenes in view of their application as active materials in photovoltaic devices. The first part discusses the concepts of double-cable polymer and molecular hetero-junction and presents several examples of chemically or electrochemically synthesized C60-derivatized conjugated polymers. The second and main part of the article concerns the various classes of C60-derivatized pi-conjugated oligomers designed in view of their utilization in single-component photovoltaic devices. Thus, C60-containing pi-conjugated systems such as oligoarylenevinylenes, oligoaryleneethynylenes and oligothiophenes are discussed on the basis of the relationships between molecular structure, photophysical properties and performances of the derived photovoltaic devices. A brief last section presents some recent examples of surface-attached molecular hetero-junctions based on self-assembled monolayers and discusses possible routes for future research.
Chemical genetics to chemical genomics: small molecules offer big insights. Chem. Soc. Rev. (IF 40.443) Pub Date : 2005-09-03 David R Spring
Chemical genetics is the study of biological systems using small molecule ('chemical') intervention, instead of only genetic intervention. Cell-permeable and selective small molecules can be used to perturb protein function rapidly, reversibly and conditionally with temporal and quantitative control in any biological system. This tutorial review has been written to introduce this emerging field to a broad audience and focuses later on areas of biology where either it has made a significant impact, or it has the potential to do so: signalling, cytoskeleton, development, protein-protein interactions and gene transcription.
The multifarious world of transition metal hydrides. Chem. Soc. Rev. (IF 40.443) Pub Date : 2003-12-16 G Sean McGrady,Gemma Guilera
Transition metal (TM) hydrides display a remarkable range of bonding types, encompassing classical M-H moieties, dihydrogen complexes containing the eta 2-H2 ligand, and trihydrides which display quantum mechanical site exchange. Furthermore, C-H, Si-H and B-H moieties can bind to TM centres in an eta 2-manner, to give sigma-bond complexes with a spectrum of M...H contributions. In addition to these primary bonding modes, TM complexes also indulge in a wide spectrum of hydrogen-bonding interactions, including both M...H-X and the unique type M-H...H-X. This review begins with a historical perspective of the development of TM hydride chemistry, and proceeds to focus on three significant developments of the past two decades: the discovery of sigma-bond and dihydrogen complexes, the involvement of TM hydrides in hydrogen bonding, and the role played by quantum mechanical phenomena in the chemistry and dynamics of TM hydrides. The account concludes with an overview of the inter-relationship between these apparently disparate novel aspects of TM hydride chemistry.


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Many HIV-infected people do not enroll early in HIV care after their diagnosis, particularly if they are diagnosed in community settings. Initiated at the point of HIV diagnosis, and lasting for up to 90 days, the program takes a people-to-people approach to supporting these individuals and keeping them on treatment.
It will be implemented in 9 regions across Tanzania. Facility implementing partners are currently working on establishing one or two demonstration sites to inform program adaption. The program links consenting individuals to care and treatment. Located in Kagera region of Tanzania, Bukoba was chosen for this program evaluation because, compared with other urban and rural areas in Tanzania, it has a high prevalence of HIV and tuberculosis TB.
Additionally, the HIV prevention and clinical infrastructure in Bukoba was deemed adequate to achieve combination-prevention targets with available scale-up resources. LCM clients were recruited from 11 health facilities. These 11 health facilities included all eight governmental health facilities in the municipality excluding facilities for police and military and 3 ministry-based private health facilities. Initiated at the point of HIV diagnosis and lasting for up to 90 days, the program takes a people-to-people approach to supporting these individuals and keeping them on treatment.
They encourage problem-solving about HIV care, disclosure, and resolving real and perceived barriers to care. These EC counselors help arrange first-visit escorts or transportation, if needed, and expedited registration and treatment at HIV-care facilities. The program also integrates with provider-initiated testing and counseling PITC in several medical facilities. Taken together, the activities effectively increase the number of individuals linked to care.
Early access to HIV care optimizes individual and public health outcomes. Trained, dedicated, and well-managed EC counselors are essential to the success of the linkage program. Peer navigators assist individual patients to navigate the continuum of care, ensuring barriers to care and treatment are resolved and each stage of care is as seamless as possible. People living with HIV can be trained to act as peer navigators for other patients, particularly in settings with a severe shortage of human resources for health.

subset: commoncrawl


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We have an unashamed passion for XJ-Cs, and it is one of the few models for which prototypes, built two and half years before the model went on sale, exist.
We have the full records on each of those cars, and they keep turning up – not often in brilliant condition it needs to be said.
The latest find came to attention abandoned in a paddock, but it is the real deal with an interesting history, and appears to be complete and totally original.
The car is LHD 4.2 litre manual overdrive XJ-C chassis #2.
It was completed on March 3, 1973 using hand-built body #6. Like many others of the first XJ-Cs, it was converted to RHD by Jaguar for use by its executives.
It was and is Greensand with narrow pleated leather trim in Olive. Its conversion happened in April 1974, after which it was loaned to Roger Bell at Thoroughbred and Classic Car for his use.
Jaguar's Engineering Director Jim Randle was allocated the car on May 20, 1974.
Now the sad but saveable car is for sale in the UK by Barons and we would encourage anyone to consider it. You don't get surviving prototypes any more for obvious reasons.
Let's not lose this one.
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Doctor de Columna Vertebral at Providencia, CHILE
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Tainted candy in florida. Welcome Back {* welcomeName *}
Although there have been reports of razor blades and other foreign objects embedded in Halloween candy or apples—although anyone giving out an apple on Halloween is already suspect , these dangers are almost always obvious with the most cursory glance. What about poison, which, being invisible and generally hard to detect, is the more nefarious way to taint candy? You have little reason to be concerned there either. He found other examples of people accidentally passing out tainted candy or, in one case, passing out ant poison as a gag gift to teenagers no one was hurt , but the bogeyman of terrible people making trick-or-treating unsafe is a canard. One example of a person trying, explicitly, to poison children via Halloween candy was confirmed.
Patrol and Detective Division Personnel are assigned currently to investigate and are following up any and all leads in this case. News National. What's New. Hidden categories: Hot ass teen cheerleader articles with unsourced statements Articles with unsourced statements from October WOKV reported that a search of the vehicle turned up grams of gummy candies laced with THC, along with other drugs and paraphernalia. Ina California dentist, William Shyne, gave candy-coated laxative pills to trick-or-treaters. During Tainted candy in florida time cases of poisoning were repeatedly reported based on unsubstantiated claims or before a full investigation could be completed and often never followed up on. In Alford, Mass.
Tainted candy in florida. 3 Replies to "Tainted Candy"
McClung Tainted candy in florida. Florida mom dresses up baby like Publix sub for Halloween. Incidents of tampering have taken a wide course. A chain of medical clinics in the region offers to X-ray children's candy. CBC News. No cases of strangers killing or permanently injuring children this way have been proven. Worries that candy from strangers might be poisoned has led to the rise of alternative events to trick-or-treating, such as events held at Christian churches, police and fire stations, community centers, and retail stores. Some marijuana edible candy is intentionally manufactured to appear similar to regular candy but is easily distinguished from commercially available regular candy. SmartNews History.
Snopes needs your help!
- Law enforcement photos Needles found in Halloween candy.
- Not after what happened last year.
Although there have been glorida of razor blades and other foreign objects embedded in Halloween candy or apples—although anyone giving out an apple on Halloween is already Tainted candy in floridathese dangers are almost always obvious with the most cursory glance. What about poison, which, being invisible and generally hard Taintedd detect, is the more nefarious way to taint candy? You have little reason to be concerned there either. He found other examples of people accidentally passing out Taintwd candy or, in one case, passing out ant poison as Hourse suckers gag gift to teenagers no one was hurtbut the bogeyman of terrible people making trick-or-treating unsafe Sexy tennis pictures a canard.
Floeida example of a person trying, explicitly, to poison children via Halloween candy was confirmed. His candy had, indeed, been poisoned. As murder would negate the insurance policy, the father had to cover his tracks. Already showing a wanton disregard for the lives of others—children, at that—he decided to potentially Tainted candy in florida a few.
He distributed some of the tainted candy to at least four other children including his daughteraccording to the Houston Chroniclesetting up the story that a neighborhood madman or demented factory worker had caused the tragic death of his son.
Fortunately, he was unsuccessful. As tragic as this story is, it is the only known example of a person intentionally poisoning Halloween canyd and providing it to neighborhood trick-or-treaters. The seeds i apples, mangos, and peaches contain trace elements of the cndy. You would have to eat a dozen or two apple cores in a single meal in order to feel any meaningful effects.
Used by permission of the publisher. All rights reserved. Dan Lewis is a father, husband, Mets fan, lawyer, and trivia buff. He writes a daily e-mail called " Now I Know ," which began in June of with twenty subscribers and now boasts nearlyA proud graduate of Tufts University and the Benjamin N. Cardozo School of Law, he's currently a florifa strategist for a well-known children's company.
You can sign up for his newsletter at www. Continue or Give a Gift. Privacy PolicyTerms of Use Sign up. SmartNews History. History Tainted candy in florida.
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Clay County deputies debunk claims of tainted Halloween candy Investigators working with prosecutors to determine if charges will be filed. Florida mom dresses up baby like Publix sub for. Nov 03, · Needles were found in Halloween candy in multiple states throughout the U.S. in They range from sewing needles found in Twizzlers to a Author: Jessica Mcbride. This page lists trick or treating events, trunk or treats, and other October events where kids can get candy in the Clay County and Bradford County, Florida area. Family events, kids activities and parenting resources in Clay and Bradford Counties!.
Tainted candy in florida. Navigation menu
Used by permission of the publisher. At the Smithsonian Visit. The Innovative Spirit. The New York Times. Folklorists , scholars, and law enforcement experts say that the story that strangers put poison into candy and give that candy to trick-or-treating children has been "thoroughly debunked". He said there was no official way to enforce the ban on trick-or-treating, and that he was relying on public support. Why are we asking this? Medical articles have also disputed some of these claims. Retrieved October 27, Stacey Norris had taken her child to trick-or-treat in the Hidden Valley community and when they returned home, she went through the candy to check it. Earth Optimism Summit. Though nobody was injured, she was prosecuted and pleaded guilty to endangering children. No cases of strangers killing or permanently injuring children this way have been proven. Parents can choose to inspect their children's treats or just not let them go out on Halloween.
Poisoned candy myths are urban legends about malevolent strangers hiding poisons or sharp objects such as razor blades , needles , or broken glass in candy and distributing the candy in order to harm random children, especially during Halloween trick-or-treating. These stories serve as modern cautionary tales to children and parents and repeat two themes that are common in urban legends: danger to children and contamination of food.
Did you hear about the little girl who bit into a candy bar and died because a stranger had tainted it with poison? Maybe in the story you heard, a little boy bit into an apple and cut his mouth on a razor blade. The stories of evil strangers tainting Halloween candy and apples with poison, glass and razor blades have prevailed for several decades. But are they true?


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Wow! Beautiful Riverfront Brownstone! Epitome of easy living with urban contemporary design and finishes to delight your senses. Main level includes Brazilian cherry hardwood floors, ebony fireplace wall, open flowing floor plan, and chef's kitchen with island and gourmet appliances. Main level patio opens to center courtyard. Open staircase design allows the flow of light and people from one level to another. Master suite includes oversized walk-in closet with laundry center, five-piece luxury bath, two-sided fireplace, and balcony. Lower level includes study with wet bar and mudroom. Executive lighting functions, built-in sound throughout. This wired and inspired home will meet all your expectations!
215 St. Paul Street #200
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Listing Courtesy of:
The content relating to real estate for sale in this Web site comes in part from the Internet Data eXchange (IDX) program of METROLIST, INC., DBA RECOLORADO®. Real estate listings held by brokers other than [insert IDX Subscriber's firm name here] are marked with the IDX Logo. This information is being provided for the consumers' personal, non-commercial use and may not be used for any other purpose. All information subject to change and should be independently verified.
1. This publication is designed to provide information regarding the subject matter covered. It is displayed with the understanding that the publisher and authors are not engaged in rendering real estate, legal, accounting, tax, or other professional services and that the publisher and authors are not offering such advice in this publication. If real estate, legal, or other expert assistance is required, the services of a competent, professional person should be sought.
2. The information contained in this publication is subject to change without notice. METROLIST, INC., DBA RECOLORADO MAKES NO WARRANTY OF ANY KIND WITH REGARD TO THIS MATERIAL, INCLUDING, BUT NOT LIMITED TO, THE IMPLIED WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE. METROLIST, INC., DBA RECOLORADO SHALL NOT BE LIABLE FOR ERRORS CONTAINED HEREIN OR FOR ANY DAMAGES IN CONNECTION WITH THE FURNISHING, PERFORMANCE, OR USE OF THIS MATERIAL.
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Call me a skeptic, but the first time I saw a radiant barrier, I was unimpressed. It appeared to be little more than a sheet of aluminum foil. It didn't seem like a viable energy saving solution, and it certainly wasn't anything I wanted to add to our line up of quality home improvement products. That was in 2006.
Fast forward to January of this year and everything changed. That's when I participated in a conference call with the senior management of Gorell Windows & Doors and learned about the new thermal barrier product they would be offering exclusively through their dealer network, of which Buresh Home Solutions is a part.
The mere fact that a quality window and door manufacturer like Gorell – seven time Energy Star Partner of the Year – was offering a new Reflective Insulation probably would have been enough to convince me that radiant barriers are the real deal. But they didn't sell me on their reputation alone. Instead, they described a product that offered a real solution to a real problem.
The problem is that nearly half (45%) of the energy wasted in a typical home is lost through the attic. Walls, windows, doors, and floors account for the rest. So in other words, you lose almost as much energy through the attic as through all other areas combined.
The solution, then, is to plug the leak in the attic. And that's what reflective insulation does. But don't confuse this radiant barrier with the aluminum foil I was first introduced to. Our reflective insulation has a lot more to offer than typical radiant foil barriers – which have no R-value whatsoever.
Our preferred attic insulation actually has two reflective faces – one on each side. Sandwiched between the reflective surfaces is a closed-cell polyethylene core. These layers combine to provide protection against convection (the transfer of heat by air circulation) and conduction (the transfer of heat from one surface to another because they touch each other). That's the equivalent of up to six inches of additional fiberglass.
Of course, the real proof is in the satisfied customers who have had Buresh Home Solutions insulate their attics with reflective insulation – more than 50 of them just since January! Better yet, more than a dozen of those homeowners were referrals from other satisfied customers!
Here's what a couple of satisfied customers have told us:
"Reflective insulation was installed in our home's attic in June 2010. When we experienced the record-setting hottest, most humid day of the year in July, our attic insulation was definitely put to the test. On similar hot July days, I have noticed a significant difference in the upstairs comfort level." – Lana Sorensen | Urbandale
"I could tell a difference in the air temperature of my upper story within one half hour of the installation of the reflective insulation. It was amazing!" – Rita Salmons | Urbandale
In a nutshell, what these homeowners, and many more like them, are finding is that a radiant barrier in their attic results in:
- Less heat gain in summer
- Less heat loss in winter
- Lower utility bills every month of the year
- Fewer drafts throughout the house
- A more comfortable and consistent living environment
Perhaps best of all, though, is that installing a radiant barrier like Radiaflect often costs less per square foot than conventional insulation. So you spend less and get more! And the installation is only beginning of the savings. Quality insulation pays for itself over time by lowering your utility bills immediately.
If you'd like to learn more about what reflective insulation radiant barrier can do for you or to discuss pricing and guarantees for your home, please give me a call at 888-428-7374 or use the Request a Quote form and I'll get back to you right away.


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Saint Laurent Pre-Fall 2013 CampaignBy SP on May 14, 2013Freja Beha Erichsen poses for Hedi Slimane in Saint Laurent's pre-fall '13 campaign. The collection exudes a soft rocker chic and was shot in Slimane's signature black and white style. Items are already available in stores. Enjoy!Read more
Phillip Lim Pre-Fall 2013 CollectionBy admin on February 1, 2013Phillip Lim just revealed his gorgeous Pre-Fall collection, and it's full of the most wearable pieces! From emerald green to wild leopard and classic black leather, it's impossible not to want them all! Here's a look at some of our favorites! Related articles 2013 Trend Alert: Spring Jumpsuits (stylepantry.com)Read more
Givenchy Pre-Fall 2013 CollectionBy admin on January 11, 2013Riccardo Tisci proved, yet again, why he's a consistent trendsetter with his directional and diverse Pre-Fall 2013 collection. This time around, the mirrored print-motifs channeled Islamic tile-mosaics; and symmetrical prints, cascade-ruffle details, heathered-grey woolens, and dramatic architectural volume to the hips of maxi-length, slashed skirts. Enjoy!Read more
Versace Pre-Fall 2013 Womens CollectionBy SP on January 10, 2013We are completely in love with Versace's pre-fall 2013 womens collection. From the classic Versace baroque print to the emblem seen in all of the accessories, this collection is definitely is definitely on our 'favorites' list! Enjoy…xx Related articles Versace Spring 2013 Campaign + Runway Looks (stylepantry.com)Read more
DSquared2 Pre-Fall 2013 CollectionBy Michal Upchurch on December 21, 2012Dsquared2's Pre-Fall 2013 collection displayed all the classic, timeless pieces we love to wear in the fall (plaid, wool, denim and leather). Although, I did spot a trend from "seasons past"…..the sock/heel combo. It's a playful style that totally works with this collection. Enjoy…xRead more
Proenza Schouler Pre-Fall 2013 CollectionBy SP on December 17, 2012Proenza Schouler pre-fall 2013 features the classic white and black that we have seen throughout the season and dashes of metallics. Totally loving it. Enjoy…xxRead more
Narcisco Rodriguez Pre-Fall 2013 CollectionBy admin on December 13, 2012For Pre-Fall, Narciso seems to have loosened up a bit, creating more democratic and wearable clothing. The designer uses a lot of rich leathers, paneling and refined, feminine silhouettes, razor-sharp slits, and plunging v-necklines. Chromatically, the collection mixes chalky grey neutrals with spice and earth tones. Enjoy!Read more
Belstaff Pre-Fall 2013 CollectionBy Michal Upchurch on December 5, 2012Belstaff's Pre-Fall 2013 collection is designed for the woman who loves structured, classic, sophisticated looks. We love it. Enjoy…xxRead more


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Project Name
Inlak'esh are a four piece instrumental acoustic party band using music as the tool to make people move. Punctuated rhythmical grooves
carefully blended with exotic, jaw dropping melodies take the listener on a musical journey that evokes all emotions and leaves the toes tapping, the heads nodding and the heart rate pulsing.
Cutting their teeth on Metal, Latin and Funk as kids they have managed to mature as adults crafting their sound into a musical cluster bomb of excitement, merriment, energy and passion.
Sounds Like:
If Rodrigo y Gabriela's sound had a love child with a Metal beat down groove.
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Support for Paul Gilbert
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Underscored and performed at The Royal and Derngate for 'A Midsummer Nights Dream' by William Shakespeare
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Erica Martin, Director, Royal and Derngate.


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Developers describe AppFog as "Simple PaaS for Java, Python, Node, .Net, Ruby, PHP, MySQL, Mongo, and PostgreSQL". AppFog provides the infrastructure web developers need to build apps without worrying about IT tasks or having to wait days to get servers ready for writing code. AppFog's web application technologies include PHP, NodeJS, Ruby, Python, Java, .NET, MySQL, and PostgreSQL. On the other hand, Catalyze is detailed as "HIPAA-compliant cloud computing for healthcare". Cloud tools for healthcare. We provide a HIPAA-compliant Platform as a Service (PaaS), HIPAA-compliant Mobile Backend (BaaS), and HL7 integration services. Focus on building your digital health app, and not on compliance. Think of us as your healthcare-specific DevOps team.
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You'll Be Mine may refer to:
"You'll Be Mine" is a short song, composed by Lennon–McCartney in the Beatles' early years, then known as The Quarrymen. It was a humorous parody of the Ink Spots. It consists of Paul McCartney singing in a deep baritone, offset with shrill falsetto backing vocals by John Lennon, and guitar strumming. The lead vocal sings, in rather confused lyrics, about his determination of making a woman his; while the falsettos wail the last word of each sentence. About halfway through the song, Lennon gives a mock-bass voice spoken interlude about how, when the woman brought him toast one morning, he looked into her eyes and saw a "National Health Eyeball", then proceeded to love her like he has never done before. The song rises to a crescendo of wailing and bellowing, then fades out in laughter. To add to the confusion, the song is very difficult to understand; clicks, buzzes, fuzz, giggling, and the baritone voice obscure the lyrics.
Recorded in the McCartney family bathroom in 1960, it is the earliest song attributed to the Lennon–McCartney songwriting partnership to be officially released. Along with the other songs recorded on that day, it is one of the few known Beatles recordings to feature Stuart Sutcliffe on bass. Lennon's spoken section provides insight into his love of wordplay.
"You'll Be Mine (Party Time)" is a song by Gloria Estefan, released as the second single from her seventh studio album Destiny, in 1996.
The song is a dance track with strong African rhythms and it became one Estefan's most popular songs. Since its appearance in 1996, the song has been present on all the tours of Gloria Estefan as it remains a favorite among fans. In the UK the Classic Paradise radio mix by Love To Infinity was the preferred version played by radio stations including Radio 1.
Estefan and Stevie Wonder collaborated for a special performance of this song at the Super Bowl XXXIII Halftime Show in 1999, the performance received a strong ovation and gave the two singers a boost on sales in the albums the two singers were promoting at that time.
This single was released twice in France; at its first release, it peaked at number fifteen at the national charts, but at the second release the song peaked at number seventeen. The song has been used twice in the British TV show Strictly Come Dancing for the Salsa, once in a Series 7 dance by Natalie Cassidy and again in 2012 by Fern Britton.
Be Mine may refer to:
"Be Mine!" is a song by Swedish recording artist Robyn, written and composed by herself and producer Klas Åhlund for her self-titled fourth studio album (2005). It was released as the album's lead single in Scandinavia in 2005, and released as the fourth single from the album across most European territories in 2008.
The track reached number three on the Swedish Singles Chart, and scored some success in the rest of Scandinavia, peaking within the top twenty in Finland, Norway and the United Kingdom. Released to great critical success, the song was ranked number twenty-one on Pitchfork Media's list of Top 50 Singles of 2005 and number fourth on a same-titled list by Stylus Magazine. Remixes of "Be Mine!" were produced by Dusty Kid, Jori Hulkkonen, Meat Boys, Ocelot, Redroche and Roger Sanchez, with a studio live version being featured on Robyn's The Rakamonie EP. The song is performed with piano accompaniment in live acoustic versions by Robyn.
The song's chorus was sampled for Rye Rye's 2011 song "Never Will Be Mine", which also features Robyn.
"Be Mine" is a song by Wild Orchid, released as their first single from their second album, Oxygen.
The single reached #8 on the TRL and garnered sufficient airplay. Nonetheless, the sales of the single were way lower than expected. Thus, backed only by its airplay, the single became the group's first single to miss the Hot 100, narrowly missing it at #103.
The music video starts off with them jogging along the beach, then find a mysterious object. They look around it then suddenly find themselves floating around inside it. At the end, they find out that it was the signal that they were singing about in the song.
US Single
Remixes Promo CD
Well darling all the night
You'll be mine and I know
You'll be mine
Till you die
You'll be mine
And so all the night
You'll be mine
You'll be mine
And the stars
Always shine
You'll be mine
My darling, when you burnt
That toast the other morning
I, I looked into your eyes and
I could see that National Health eyeball
And I love you, like I've never done,
Like I've never done before!
Oh darling
In your eyes
And you'll be mine
You will be mine
You'll be mine
At the star and so
You'll be mine


text:
Friday, September 07, 2007
I am a trustee of the Times Federation for Cleaning Vrindavan.
Would you like to help in any way?
Do write to firstname.lastname@example.com
May the Giver of all Gifts keep you under His tender care!
Read about Krishna and Janmashtami
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KENNEBUNK, Maine - Save the date of Friday, Sept. 6 for the River Tree Arts 6th Annual 100 x 100 Fundraiser. This festive, not-to-be-missed event showcases 100 works of art by local artists priced at $100 each. Enjoy light refreshments; meet many of the participating artists and support the arts by purchasing a new piece of art for your very own collection.
River Tree members will have the opportunity to shop early and all artwork will be sold on a first come, first serve basis. Members only viewing is from 6 to 6:30 p.m. It�s not too late to become a member.
River Tree Arts, a nonprofit community arts center located at 35 Western Ave in Kennebunk, serves over 700 students of all ages annually. RTA students take private or group music lessons, theater workshops, and a variety of visual art classes throughout the year. Scholarships are available to make arts experiences accessible to all.
Join River Tree Arts on Sept. 6 to help meet the goal to raise $10,000 during the 100 x 100 2019 event. All proceeds will help support the many programs that have been enriching our community for over 30 years.
Artists interested in participating can contact firstname.lastname@example.com
To learn more, please visit rivertreearts.org/100-x-100-annual-fundraiser or call (207) 967-9120.


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The Mitten
9 Pictures Used Load All
Load these pictures into your tray to recreate and customize this material.
Characters from the Mitten by Jan Brett. Cut out pictures on mat and retell as you glue / velcro/ stick characters on the second page (blank mitten).
Fun file folder game.


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Parent/Student Resources
Welcome CUSD Parents & Students!
Please take a moment to explore the resources provided to you on this page. If you have questions, the principal at your child's school will often have the answers or you can ask one of the District office contacts.
District NewsRSS feed for News Group: Families & Students
Cal Prep Parent & Student Information Meetings for Fall 2020 Posted 1/27/20
2020-2021 School Of Choice Elementary School Site Tour Dates Posted 1/27/20
2019-2020 Secondary Open House Schedule Posted 1/15/20
2019-2020 Elementary Open House Schedules Posted 1/14/20
Spring 2020: Driver Education Registration Information: Posted 1/13/20
CTE Student Ambassador Leadership Program 2019-20 Posted 1/10/20
Preschool Open Enrollment 2020-2021 Posted 1/10/20
CUSD Hosts Eighth Grade Expositions Posted 1/8/20
School Life
Get Involved: Parents
Parent Involvement:
Capistrano Unified Council of PTSAs:
School Site Councils
Become a Volunteer:
Say Something
An Anonymous Reporting System to submit secure & anonymous safety concerns to help identify and intervene upon at-risk individuals BEFORE they hurt themselves or others.
Full-Day Kindergarten
Capistrano Unified will be offering Full-Day Kindergarten starting in the 2019-2020 school year at ALL elementary school campuses.


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Linda Aver
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- Not intended for commercial use
- Care: Dust with a soft, dry cloth.
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Ham and cheese cutter set
from PuniPuniJapan
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Limited Stock


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EAST LANSING, Mich. - The Calvin men's golf team used a third place finish at the MIAA Fall Tournament to cement a spot in next spring's MIAA AQ Tournament.
Calvin finished the 36-hole fall tournament with a third place team score of 606 strokes. In doing so, Calvin finished fourth in the final MIAA overall team standings with 1,851 strokes. The top four teams from the regular season qualify for the spring MIAA AQ Tournament which will take place in late April on two successive weekends, consisting of 54 holes. The winner of the tournament will receive the MIAA's automatic bid to the NCAA III Championships in May.
Calvin has now qualified for the MIAA AQ Tournament eight consecutive years.
The Knights nearly leapfrogged Kalamazoo for third place in the final standings but finished just five strokes behind the Hornets.
Calvin finished six strokes ahead of Kalamazoo over the weekend and just five strokes behind second place Hope.
Trine took first place at the weekend tournament (583) and won the overall league title by a healthy 53-stroke margin.
The final MIAA regular season standings consisted of four 18 hole MIAA Jamborees along with the 36-hole MIAA Fall Tournament.
Junior Sam Holland (Novi, Mich./Detroit Catholic Central HS) set the pace for the Knights by shooting a weekend score of 145 strokes (73-72) at the Forest Akers West Golf Course.
Holland finished third in the weekend tournament and placed fourth in the final overall MIAA individual standings with a season average of 73.5 strokes-per-round. By finishing in the top-six of the final MIAA standings, Holland earned a spot on the All-MIAA First Team.
Sophomore Kasen Anderson (Stillwater, Mn./St. Croix Preparatory HS) had a strong finish to the fall, shooting back-to-back rounds of 76 to finish ninth in the MIAA Fall Tournament standings,
Freshman Jacob Siebenga (Surrey, B.C.) had a 76 and a 78 to finish 15th on the weekend (154) while junior Joshua Lansky (Park City, UT/Park City HS) tied for 18th (77-78). Senior Austin Umlauf (Lowell, Ind./Hanover Central HS) had an 83 Friday but then came back with a 78 on Saturday.
COACHES COMMENT: "Sam Holland, who earned MIAA First Team honors this fall, stepped into a leadership role this season and handled it like a pro," said Calvin men's golf coach Brian Bolt. "We needed him to post low scores every day, and that requires a mature competitor. Sam responded with incredible poise and heart. He is a true leader. I'm really proud of the accomplishments of this team We have some big challenges this year but we set a goal to make the MIAA postseason. We needed a strong effort under pressure this weekend, and the guys really responded with the best scores of the fall. They are starting to believe in themselves as a team, and we are trusting each other. We are excited to continue developing and will look to make a run this spring."
NEXT UP: Calvin will break until the spring when it begins a non-conference slate of tournaments building up to the MIAA AQ Tournament. Hope will host the opening 18-hole round of the MIAA AQ Tournament with Trine hosting the final 36-holes over a Friday/Saturday.
Trine 583
Hope 601
Calvin 606
Kalamazoo 612
Adrian 619
Albion 628
Alma 646
Olivet 670
Trine 1757
Hope 1810
Kalamazoo 1846
Calvin 1851
Adrian 1872
Albion 1912
Alma 1933
Olivet 1988


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Email: dbattles
The Chief Executive Officer is David L. Battles, a member of the firm since January, 1972. He holds a degree in accounting, membership in the Ohio Society of CPAs, and is a certified public accountant specializing in business, financial and tax consulting.
"I enjoy partnering with my clients to help create solutions to problems and develop wealth accumulation strategies. Obviously, that includes the minimization of tax liabilities. I like to believe we provide the best service on a consistent basis!"
David and his wife, Diana, have three adult children and two grandsons. He and Diana have resided in Geauga County all of their life; and, the last thirty years have been in Munson Township, outside Chardon. A proponent of community service, Dave is a member and Past President of Chardon Rotary, steering committee member and classmate Leadership Geauga, former board member of United Way and an active member and treasurer in the Painesville Chamber of Commerce. He also serves as an advisor to the Accounting Board at Kent University-Geauga and enjoys time spent at Fellowship Bible Church.
In his spare time, Dave enjoys bicycling and racquetball as well as gardening and other outdoor activities. And he is always available to spend time caring for his grandsons.


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Aberdour Castle and Gardens
Admire views of the Forth from what's possibly Scotland's oldest standing castle.
Blackness Castle
See for yourself why this mighty fortress is known as 'the ship that never sailed' – with its pointed stem, square stern and tall mast.
Craigmillar Castle
Step inside Edinburgh's 'other castle', once a rural retreat from Scotland's capital.
Dryburgh Abbey
Wander around this medieval ruin nestled in secluded woodland by the River Tweed to grasp the appeal of monastic life.
Jedburgh Abbey
Admire the unusual mix of architecture in what is one of four great abbeys established in the Scottish Borders in the 1100s.
Linlithgow Palace
Explore the magnificent ruins of the birthplace of Mary Queen of Scots and home to the Stewart kings of Scotland.
Tantallon Castle
Discover the last of the grand medieval castles, set high on a cliff edge and featuring a massive curtain wall.


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About Arrowhead Consulting
Today, successful businesses and organizations are facing necessary change at accelerating rates. Arrowhead Consulting helps you navigate that change by providing services customized to your strategic objectives. We empower professionals on a personal level, nurturing improved capabilities and identifying essential talents to achieve sustainable results on the organizational level.
We can help your business or organization in a variety of ways, but our specialties include:
- Project Management
- Leadership Development
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- Learning Services
Our Core Values
Arrowhead Consulting was founded on eight core values that form our identity.
They are our cornerstone for how our team operates.
We Know that "Good Enough" Isn't
We view every interaction as an opportunity to demonstrate how our work ethic sets us apart. This is how we build loyalty.
Accountability Starts & Ends with Us
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Kris Reynolds
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Jon Land
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Business Development
Dalton Metzer
Digital Marketing Coordinator
Anne Pilkington
Business Development


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Types of RP guilds
(Redirected from Types of RP Guilds)
Roleplaying guilds may be themed in different ways, with their members taking part in the guild as an in-character organization. Some of these themes include (The recommendations are not the final word. Any race you want can join):
- Knightly orders, mercenary guilds and militias. These organizations are focused on combat and warfare (PVP). Orcs and Humans generally run these guilds. Suggested Classes: Warrior, Rogue and Paladin. Race: Orc, Humans and Trolls
- Monastic orders, priesthoods, and similar. If the guild serves a certain god, goddess, or other "good" being then this is their category. Suggested Classes: Priest, Druid, Paladin. Races: Human, Tauren, Draenei and Night Elf.
- Similar to the Religious type, Cult guilds are usually much smaller, focusing on evil beings. Rather than being a part of an organized religion, they are a cult that may hold similar beliefs to other cults that worship the same beings, yet they tend not to retain any steady ties between themselves. Suggested Classes: Warlock, Death Knight, Priest. Races: Blood Elf, Forsaken.
- Magical colleges, Magical Orders, and similar. This is one of the rarer types of rp guilds. Subsections of the Kirin Tor and other magic-oriented guilds could easily fall into this category. Suggested Classes: Mage, Priest, Paladin, Druid and Warlock. Races: Human, Gnome, Draenei, Blood Elf and Forsaken.
- Seekers of knowledge, in what ever form. Whether it be of the land, of ancient lore and artifacts, what ever, it falls into this category. Suggested Classes: Hunter, Warrior, Rogue. Races: Dwarf, Orc and Human.
- This is the broadest category. Any guild that participates in things that could be classified as a thieves or an assassin's guild. Suggested Classes: Rogue, Warlock, Warrior. Races: Human, Orc and Dwarf.
- If your guild is a company similar to the goblin Cartels, or anything resembling them, it falls into this category. Mainly this guild consists of people hunting enemies to find rare drops, and selling them on the auction house for either a fair price, or to scam lower level players. Suggested Classes: Any. Races: Any
- One of the more common types of rp guild. They focus around a single "Family" or "Clan" of players who are related to each other by blood or by living in an in game settlement. This can overlap with Mercantile RP if a guild takes over, for example, a tavern. The important thing is that they find a relationship through where they live and work, or through familial connections. Suggested Classes: Any. Races: Any.
- A potential type of guild or clan, if your character's attitude interprets a racist or elitist, share your common hatred towards other races with a group of people believing your race is superior to others. Suggested Classes: Any. Races: Any (as long as it is the only one in the guild.)
These different categories can overlap a lot, for example, an order of paladins who serve the Naruu might be seen as a Religious Military RP guild.