text:
Method for preparing hardening agent
FIELD: rocket technique, chemical technology.
SUBSTANCE: invention relates to a method for preparing a hardening agent for polyurethane compositions based on oligodiene rubbers. Invention describes a method for preparing a hardening agent for polyurethane compositions consisting of the following components, wt.-%: oligodiene urethane prepolymer, 80-91; 20% solution of triphenylmetane triisocyanate in dichloroethane, or 27% solution of triphenylmethane triisocyanate in ethyl acetate, 7-13, and, optionally, transformer oil, 0-10. The process is carried out in the range of temperatures 55-65°C, under residual pressure 1333 Pa for 6 h. Invention provides preparing polyurethane compositions possessing the rupture strength value at the level 38 kgf/cm2, relative elongation 350-600%, elasticity modulus at 50°C at the level 41 kgf/cm2 and adhesion strength to ballistic fuel 41 kgf/cm2. Proposed compositions are able to provide working ability of articles in the range of temperature from -50°C to +50°C.
EFFECT: improved preparing method.
2 tbl, 4 ex
The present invention relates to the field of rocket technology and concerns a method for obtaining hardener for polyurethane compositions for various purposes on the basis of oligodynamic rubbers.
A method of obtaining polymeric materials with urethane groups (USSR №273424 C 08 G 22/08), taken as a prototype that could be used as an intermediate product to obtain a curing agent for polyurethane compositions used in the mountings of the products "brush" type of high-energy product. But the strict requirements laid down in the technical documentation for products of this class, which operate in the temperature range from + 50°-50°do not allow to use this material because of the high brittle temperature (TXP˜5°).
The technical task of the present invention is finding ways to obtain hardener which would have the ability to create new formulations of polyurethane compositions having stable properties, high mechanical and adhesive characteristics, and low temperature brittleness - below minus 80°C.
A technical solution is achieved through the interaction oligomannose urethane prepolymer with a content of isocyanate groups 3,0-4,0% with a 20%solution of the m aromatic triphenyltetrazolium (TFMT) in dichloroethane or 27%solution of aromatic triphenyltetrazolium (TFMT) in ethyl acetate at a temperature of 60± 5°at a residual pressure of not more than 1333 PA for 6 hours in the following ratio, wt.%:
|oligodynamic urethane prepolymer
|20%solution of triphenyltetrazolium
|in dichloroethane or 27%solution
|triphenyltetrazolium in ethyl acetate
|transformer oil
This curing agent was prepared as follows.
In laboratory Meshaal, equipped with an anchor or frame with a stirrer, jacket heating and vacuum line, load preheated at a temperature of 60±5°With a portion oligomannose urethane prepolymer with a content of isocyanate groups in the range of 3.0 to 4.0%, a portion of transformer oil (if necessary) and a portion of a 20%aqueous solution of aromatic TFMT in dichloroethane or 27%-aqueous solution of aromatic TFMT in ethyl acetate. The synthesis is carried out at a temperature of 60±5°at a residual pressure of not more than 1333 PA for 6 hours. After a specified time Meshaal off, the mixture is cooled, make sampling to determine the content of isocyanate groups, which should be in the range of 3.5 to 4.5%.
The novelty of the offer is aemula invention is when using hardener possible to obtain polyurethane compositions with a high level of strength and highly elastic characteristics in the region of low temperatures (low temperature brittleness polyurethane compositions made using the proposed hardener, below minus 80°). The recipe oligomannose urethane prepolymer entered transformer oil and 20%solution of an aromatic TFMT in dichloroethane or 27%solution of aromatic TFMT in ethyl acetate. This hardener increased opportunities for polyurethane compositions operable in a wide temperature range of operation and increases their stability during the warranty period of storage with preservation of mechanical and adhesive characteristics, and also provides the functionality exposed to high loads.
The claimed range of ratios between the components are determined experimentally and are optimal from the point of view of formation of the polymer network, providing a high physico-mechanical adhesion and performance characteristics of the finished polyurethane composition.
In appearance the curing agent is a viscous transparent liquid from light brown to dark brown.
The prepolymer taken the La receive hardener, is a product of the interaction of Oligocene with diisocyanate.
Table 1 presents the formulation of the proposed hardener in comparison with the prototype on the application number 273424, wt.%
|Table 1
Recipe hardener for polyurethane compositions
|Name of the component
|Prototype (molar ratio)
|Example 1
|Example 2
|Example 3
|Example 4
|1. Oligodiens: diisocyanate: unsaturated monomer
|2. Oligodynamic urethane prepolymer
|of 87.0
|3. 20%solution TFMT in dichloroethane
27%solution TFMT in ethyl acetate
of 10.93
|4. Transformer oil
The properties of razlagaemogo hardener based oligomannose urethane prepolymer are given in table 2.
|Table 2
Properties hardener for polyurethane compositions
|The placeholder
|Example 1
|Example 2
|Example 3
|Example 4
|1. The content of isocyanate groups %
|not defined
|the 3.8
|2. Color
|Viscous liquid from light brown to dark brown
|3. Low temperature brittleness of hardened structures using the proposed hardener °
|above minus 5
|below minus 80
|4. The viscosity at a temperature of 25°; PA·
|5. Shelf life
|not stored
|6 months
|Note: use of this curing agent were prepared polyurethane composition based on oligodynamic rubbers, plasticized transformer oil. The tensile strength at a temperature of 20°C at strain rate of 500 mm/min is ˜33,0-38,0 kgf/cm2that relation is sustained fashion lengthening ˜ 350-600%, a modulus at 2%elongation at a strain rate of 3.3 mm/min and at a temperature of minus 50°˜110-140 kg/cm2. The strength of adhesion to ballistic fuel is 31.5-41,0 kg/cm2with cohesion (fuel) the nature of the destruction of samples.
From table 2 it is seen that the obtained compound is in a liquid state and has a viscosity at the level of 40.5-41.7 PA·that allows you to use it as a hardener for polyurethane compositions without special training. The hardener has a long warranty period of storage without changing its performance. Using the recommended hardener were able to achieve the lower temperature brittleness of hardened polyurethane compositions is below minus 80°S. This indicator is a basic requirement for the design of products from ballistic fuel, because the temperature range of operation of most of the charges is in the range from + 50°-50°C. the Prototype has the embrittlement temperature above minus 5°that does not meet the requirements of the design documentation.
Thus, the proposed method of obtaining a new curing agent for polyurethane compositions is achieved through the use of oligomannose urethane prepolymer in combination with 20%RA is tworoom aromatic TFMT in dichloroethane or 27%solution of aromatic TFMT in ethyl acetate plasticized transformer oil or unplasticized at a temperature of 60± 5°at a residual pressure of not more than 1333 PA for 6 hours. This hardener allows to obtain a polyurethane composition with high physical-mechanical, adhesion and performance, providing products in a wide temperature range from + 50°-50°C.
The way to obtain a curing agent for polyurethane compositions comprising oligomannose urethane prepolymer, triphenyltetrazolium and, optionally, transformer oils, namely, that interact oligomannose urethane prepolymer with a content of isocyanate groups 3,0-4,0% with 20%solution of aromatic triphenyltetrazolium in dichloroethane or 27%solution of aromatic triphenyltetrazolium in ethyl acetate, optionally in the presence of transformer oil in the temperature range 55 to 65°at a residual pressure of not more than 1333 PA for 6 h, in the following ratio, wt. %:
|Specified oligodynamic urethane prepolymer
|80 - 91
|20%solution of triphenyltetrazolium
|in dichloroethane, or 27%solution
|triphenyl etatisation in ethyl acetate
|7 - 13
|Transformer oil
|0 - 10
FIELD: polymer materials.
SUBSTANCE: polyurethane resin is a product of reaction of at least one diisocyanate component and isocyanate-reactive components having first group of at least one polyol, second group of at least one polyol, and third group of at least one polyol, at least one amine, and, additionally, reaction-stopping agent, all polyols of the first group having average molecular mass between 1000 and 10000 g/mole, those of second group having average molecular mass between above 10000 and 20000 g/mole, and those of third group having average molecular mass equal to or higher than 800 g/mole. Ratio of diisocyanate component to isocyanate-reactive components is selected such that all isocyanate groups are present as products of reaction with isocyanate-reactive functional groups. Resin is used as film-forming binder in coating compositions, in particular in printing inks for printing on polyolefin substrates. Printing ink is preferably used for manufacturing printed layered articles.
EFFECT: increased gluing ability and heat resistance of ink laid on plastic substrate.
41 cl, 2 tbl, 12 ex
FIELD: polyurethane composition based on oligoester polyisocyanate.
SUBSTANCE: claimed composition contains (mass parts): mixture of low molecular oligooxyethylene glycol and oligooxypropylenetriol 49.0-91.2; toluylenediisocyanate 8.0-40.5; dimethyl dichlorosilane 0.1-1.0; and low molecular polyethylene 2.5-11.5, wherein polyethylene is introduced when content of isocyanate group NCO- is achieved of predetermined value (2.0-10.5 mass %).
EFFECT: oligoester polyisocyanate with stable characteristics under long-term (up to 6 months) storage.
6 ex, 1 dwg
FIELD: method and composition for production of oligoester polyisocyanate useful as component of polyurethane compositions.
SUBSTANCE: invention relates to method for production of oligoester polyisocyanate treated with toluylenediisocyanate. Method includes controlling of NCO-group content up to predetermined value followed by addition of low molecular polyethylene. Oligoester polyisocyanate of present invention is useful as component of polyurethane compositions for production of cold cured articles.
EFFECT: reaction mass with increased viability for long storage time.
6 ex, 1 dwg
FIELD: polymers, glues.
SUBSTANCE: invention relates to thermoplastic plastics, in particular, to polyurethane and composition containing thereof used for gluing and thickening. Invention describes polyurethane prepared by interaction of: a) polyisocyanate or mixture of two or more polyisocyanates with b) polyol or mixture of two or more polyols comprising simple polyether with molecular mass 4000 Da, not less, polydispersity value 1.5, not above, or hydroxyl functionality from 1.8 to 2.0, or polydispersity value 1.5, not above, and hydroxyl functionality from 1.8 to 2.0, or by a mixture of two or more such simple polyethers in the presence of a component of the general formula (I) given in the appendix 1. After reaction termination polyurethane has at least one silane group able to react with water or its mixture with isocyanate group. Also, invention describes a composition used for thickening and gluing containing a plasticizing agent in mixture with indicated polyurethane and other polyurethane with molecular mass 8000 Da, not above, and at least by 3000 Da less as compared with this value for the first indicated polyurethane. Proposed compositions comprising the claimed polyurethane are useful as contact, single- or two-component glue, thickening mass with rupture elongation up to 287% and destroying charge up to 0.49 N/mm2 and used in sealing seams and surfaces.
EFFECT: valuable properties of composition.
15 cl, 2 ex


text:
Gospel singer and owner of Fresh FM radio station, Yinka Ayefele has admitted welcoming a set of triplet ( 2 boys and a girl) in Maryland, United States.
The singer in June had denied this news, saying it is a thing of joy, but he is sorry, he didn't welcome them. While talking on his radio station, during his live programme, "Let's Talk About It" the programme he co-anchors with Enitan Olusegun Bamidele he admitted welcoming them.
His media aide, David Ajiboye, has also confirmed the news saying, his wife, Mrs Tope Ayefele, recently delivered the triplets in Maryland, US.

subset: commoncrawl


text:
First, you are the parents, so if something bothers you, say so. But be prepared to get wide-eyed stares, because the ladies will probably be surprised (they probably don't realize they do this to your son or to you) by your comments. Also, be prepared for different treatment toward your DS and you too. Not necessarily bad treatment, just different and more distant.
Also, this is a paid service, so you should be able to get what you want, within reason. But again, see comments above about their responses.
I doubt they are trying to be "disrespectful of your roles as parents" as you stated in your final sentence. They have formed attachments to your son since they spend so much time with him. It's not a bad thing for a caregiver to view a child this way...at least your kid isn't one of the ones who gets more ignored.
You're complaining about 5 extra minutes of pick up time when your kid is there all freaking day?
My kids were both in daycare when they were young. Long hours for both mom and dad, etc. I was thrilled when an employee took a special interest in my child - I knew my child would feel special and loved. Employees are not supposed to have favorites - so your son must really be something special!
I hate to be cold to another working mom, but maybe the workers are trying to give him extra attention because they feel sorry for him, if he is one of the "first to arrive, and last to leave" kids. The kids know when everyone else has been picked up and they are left behind.
Would I be worried about the lady who calls him "her" son? No. But if you want the pick up and drop off to go smoother, you should say that you are eager to get home and start dinner and get his bed and bath routine going.
No one would be able to swoop my kid out of my arms, I'm not sure why your husband allowed this. I have a feeling if you asked the daycare lady, you'd get a completely different version. The truth is probably somewhere in the middle.
I'm in our son's daycare parent advisory committee and we recently reviewed the parent surveys. Some folks complained about teachers "stealing their precious time" with their children at drop-off/pick-up. DH and I work, too, and our son, like yours, is one of the "special" ones (I agree with PP that there shouldn't be favorites but alas, they are, and we are very thankful for that, as we know that he gets extra love during the day). The few times he's gotten upset at drop-off, I actually REALLY appreciated the teacher "stealing him" from us and hugging / distracting him right away... just a thought... they might be trying to make it less painful for him. In talking to one of the teachers about it, she mentioned the complaints from other parents and asked me if it was ok that she did that... for me it was... I wouldn't want to make it more painful to my son to leave (and leave him crying there!)!
If I were in your position, I'd try hard to change my perspective on this. I get that you're the parents and you have little time with your son, but I would also really focus on appreciating that my son is getting nurtured by loving people who care about him, and that he's happy during the day... and of course, try to make an effort to really have some quality family time together after daycare...
I think you're over thinking this. And I can't imagine that just being a little more assertive would solve this, especially at pick-up.
A distraction and big hello at drop-off seems completely fine. I make a point of having DD say "Thank you to her teachers". - Maybe something formal like that would help you assert yourselves at pick-up a bit.
My DS attends a private preschool full-time. I am grateful that the staff is and always has been so attentive to him and very nurturing. He enjoys going there and I know that he is well-cared for. Some mornings he clings to me and I appreciate when one of teachers comes over to invite him to participate in an activity. She isn't being disrespectful but rather respectful of my work schedule and of his feelings. She wants to get him over being unhappy that I am leaving. And I repeat that I appreciate this.
If the "son" comment bothers you, address it. But I think it's harmless and I bet she refers to other kids in the same manner.
At the risk of being the pariah of this thread I am going to say that this would totally bother me too. Not the distracting him part so much as her calling him "her son" and saying he has "her eyes". I have babysat and worked at a daycare and distracting the kids can help keep them from crying for hours when their parents leave, however I would never call another person's child my son or daughter. To me that is overstepping and I would be very upset and probably say something about it. Also the taking of the child out of your hands when you come to pick him up signals an attachment that I don't think is okay on the part of the daycare workers.
Unfortunately for you based on your other post about soda and sugar with the grandparents, you may be overreacting or exaggerating...
Honestly, I feel you are jealous of their relationship and time with your child and feeling guilty.
It is common for teachers to try to distract a child from you at drop off to help them get involved with the class and you leave without drawn out goodbyes or the che getting upset.
The whole my child thing is just a saying - it means he is loved. You are being sensitive but if it bothers you - the next time they say it immediately correct them. "I know you don't mean anything by it and I love how much you cherish my son while at school but can you not call him your child?"
I don't understand how a woman can remove a child from your husbands arms. Lol unless he allowed it.


text:
bhummelL needed a new logo design and created a contest on 99designs.
2 winners were selected from 40 designs submitted by 20 freelance designers.
Dayspring Wesleyan Church
Reach Grow Worship Serve
We are a church looking to engage our community in strategic acts of service.
These shirts will be worn by people in our church while we are out serving in the community. The purpose is to express to the community our core values and remind the people from our church of those values as well. Attached are some images from other churches that we wouldn't mind modeling our design after but with the four values listed above: Reach Grow Worship Serve
Find out how a design contest works or learn more about our logo design services.


text:
After registering on your programme, you will be able to access a personalised academic timetable via Eportal or the University app. Release dates may vary depending on the course being studied and students should access the 'when will I get access to my timetable' area of this website.
Contact hours and the amount of self-directed study can differ between subjects, but you should expect to attend classes on most days and between the hours of 9am and 6.00pm Monday to Friday. Wednesday afternoons 1pm onwards are kept free for sports, volunteering and participatory activities where course constraints allow.


text: 5/21/2011hi my name is David moved from France to nyc a year ago i lived with mike for a year now and i have to say that he always treated me very well , kept the place clean in fact a very friendly housekeeper(Janice) came every ten days . Mike is a nice man he always offered me food and even invite me for dinner he got a little cute dog very friendly and quiet About the room: the place is very spacious and well maintained ! I warmly recommend for people who looking for quiet and peaceful place to live


text:
Keune Christmas Vital Nutrition Xmas Pack
The perfect pack for dry, damaged hair, providing moisture, hydration, and restorative properties to bring damaged hair back to life!
1 x Care Vital Nutrition Shampoo 300ml
1 x Care Vital Nutrition Conditioner 250ml
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1 x Keune Cosmetic Bag
Vital Nutrition Shampoo and Conditioner deeply nourishes the hair and restores the moisture balance through essential minerals. Nutri-Injection Technology forms a protective shield in and around damaged areas, restoring and revitalising stressed strands. Hair is protected from dehydration and environmental damages.
Miracle Elixir Keratin Spray a luxurious leave-in treatment suitable for all hair types which rebuilds, repairs and protects hair structure. Improves combability whilst Coconut Oil moisturises hair from the inside out, creating softer and shinier hair.
How to use:
Vital Nutrition Shampoo: Apply shampoo on damp hair, lather and massage scalp. Rinse and repeat if necessary.
Vital Nutrition Conditioner: Apply conditioner, work through the hair for 1-3 mins. Rinse thoroughly.


text:
Frankie & Benny's - PooleTower Park, Yarrow Road, Bournemouth, Dorset, BH12 4HY EEUU, Italiana
La mejor oferta
Available lunch & dinner Mon-Sun until 31 December 2019, subject to availability. Dishes from a set menu & subject to change. Includes VAT, excludes service.
Horarios de apertura
Situated right next to the Tower Park, Frankie & Benny's Poole invites diners to enjoy tasty American dishes and an extensive breakfast. Head to the terrace area and unwind with a refreshing cocktail or a wholesome meal.
Offering big flavours and massive choice, the Frankie & Benny's menu is filled with New York and Italian classics. Renowned as a place for families looking for a fun, comforting dining experience, the menu spans from a juicy stateside chicken burger, to classic pasta with succulent Italian meatballs.
There is plenty of choice for vegetarian diners and those looking for lighter, healthier dishes, along with an impressive gluten-free menu. From the bar, enjoy a chilled beer, or a piled-high 'freakshake' for an indulgent treat.
Frankie & Benny's in Poole is just off the A3049 and a 4-minute drive from the Rossmore Leisure Centre.
de los clientes recomiendan este restaurante
Recomendado para
- desayuno (1)
- bueno para los niños (4)
- cena (4)
- grupos grandes (2)
- almuerzo (2)
- romántico (1)
13 de enero de 2019
Food was only average We ordered a sharing platter as starter which arrived after our mains we ended up taking starter home with us but eventually it ended up in my dustbin so about £12 wasted
16 de diciembre de 2018
Told waitress that I'm allergic to tomatoes when burger arrived it had tomato in it I sent it back and I watched them take the tomatoes out and send the same burger back which is clearly not allergy safe, I told the waitress and she made them remake the burger from scratch by now the rest of my party had almost finished eating, the waitress did apologise, when we were leaving the restaurant and after my wife had pointed out to him how sick it could have made me the manager also apologised, however you do need to get on top of your food safety /allergy training before something serious happens, LesEmmett
2 de septiembre de 2018
Really impressed with the service and food
13 de diciembre de 2015
A little noisy but expected with lots kids there. Pizza delicious. Meatballs a bit bland. We had family deal, far too much food but had 3 little ones so more suited to family with older children.
18 de octubre de 2015
I felt uncomfortable when the waitress who seated us had to explain to another member of staff that we had booked which is why she seated us straight away, we hadn't even sat down when we were asked if we wanted double dip dough balls & a drink, food came before our drinks, waiter was very sullen.
13 de octubre de 2015
We both really enjoyed the food. The service was a little slow but we enjoyed that because it gave us both a good chance to look at the menu and decide on our starter and mains. This was our first time going to a frankie and bennies and we will certainly be visiting again. The best way I can describe the food is a bit pricey but very good quality. I had the mixed grill which was about £20 but the size of the meat and the quality of the cut was amazing. The plate was over flowing with chips and meat it was the best mixed grill I've ever eaten.
15 de marzo de 2015
I went with my daughter and her family to celebrate Mother's Day we asked to move table as we were near the door and in a draught this was arranged no problem the food and service were excellent and we were each given a bottle of wine
Ofertas disponibles
Star Deal - Festive Menu: 2 courses £15.99 or 3 courses £18.99 per person
Restaurantes cercanos
Café Rouge - BournemouthFrancesa4.3kmCafé Rouge - Bournemouth
The LibertineBritánica4.3kmThe Libertine
Bistro du Vin at Hotel du Vin PooleFrancesa4.4kmBistro du Vin at Hotel du Vin Poole
6.1kmFrankie & Benny's - Bournemouth West
Loch Fyne Restaurant PooleMarinera5kmLoch Fyne Restaurant Poole


text: Top 10 – They played the Total Africa U-23 Cup of Nations From 8 to 22 November, Egypt will host the third Total Africa U-23 Cup of Nations. Get ready for the show, as this tournament has proved a springboard for formerly wonderkids who have become football stars. Here is the Top 10. Find out more


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text:
Customs Releases
Mount Maunganui NZ Customs (Export and Import) Delivery Order Release Search
This search is for Customs Releases received for the Mt Maunganui wharves. If searching for Customs Releases received for the Tauranga Container Terminal, please go to the PortConnect website.
Please enter: Container number(s), Bill of Lading number(s), or CDO number(s) – each number must be on a separate line.
It is the Port's intention to share the information provided by Customs via this website. Port of Tauranga does not accept responsibility for any inaccuracies, omissions or delays in clearance confirmations. Queries of this nature should be made directly to NZ Customs.


text:
I found a sentence on an online English test.
Question: More money is now spent on fuel than before.
Answer: Not as much money was spent on fuel before as now.
I have learnt "comparative structure like "as adjective as ", "adjective than." I found as adj as, as much/many noun as. But I did not know which structures are those sentences? I really want to know this structre "not as adj noun v as noun "


text:
share:Remind Me
TCMDb Archive MaterialsView all archives (0)
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Raped by her brothers at age seven, Ma Barker exacts absolute loyalty from her four sons, sadistic Herman, narcotics addict Lloyd, soft-spoken Arthur, and homosexual Fred. During the Depression Ma and her brood leave passive Pa Barker and the Ozarks to begin a criminal career. While robbing a ferryboat eldest son Herman loses his temper and stomps a passenger to death. To console Herman, Ma sleeps with him. Apprehended robbing a picnic, Fred and Herman are incarcerated. In prison Fred succumbs to the advances of Kevin Dirkman, who becomes Ma's lover upon release. Over her protests Herman introduces his mistress, the prostitute Mona, into the band. After Lloyd rapes local resident Rembrandt, Ma, Herman, and Kevin drown the girl in the bathtub. Later Lloyd dies of a drug overdose. The gang then kidnaps congenial multi-millionaire Sam Adams Pendlebury. Upon payment of the ransom Ma insists that the hostage be killed. Her sons, however, release the multi-millionaire and Herman assumes command of the band. At their Lake Weir hideout Herman and Kevin unknowingly reveal their identities by firing machine guns at an alligator. Trapped by police, the Barkers fight to the finish, Ma being the last to fall.


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First Abu Dhabi Bank's raised cap for foreigners could trigger passive inflows of about $730 million from investors
Stocks in Abu Dhabi reached their highest since September 2014 after the main gauge's largest constituent implemented a decision to raise its foreign ownership limit.
First Abu Dhabi Bank shares advanced 5 percent, the most in a month.
The raised cap for foreigners could trigger passive inflows of about $730 million from investors tracking MSCI and FTSE Russell benchmarks by June, according to estimates by Mohamad Al Hajj, an equities strategist at EFG-Hermes in Dubai.
"FAB's weight in the MSCI Emerging Markets index will increase from about 21 basis points to 32 basis points, putting it in the Top 15 banks in EM by weight, from number 33 currently," he wrote.For all the latest banking and finance news from the UAE and Gulf countries, follow us on Twitter and Linkedin, like us on Facebook and subscribe to our YouTube page, which is updated daily.


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I don't really remember L'Escala that clearly. Mostly because of the huge amount of Estrella I drank, but also because I slept there most of the time. Hubby and I went to Spain during one of those years one sometimes has when is trying to make a living and comes back home at 10 o'clock at night, eats Heinz soup out of a can for dinner, and is so tired that falls asleep while standing. We just wanted to rest and be with each other (aawww – isn't it romantic?), so we chose L'Escala.
It is a small town on the Costa Brava, in Spain. It is only 1.5 hours drive from Barcelona – although it took us a little more, because the company we rented our car from gave us a very ugly, brown Fiat Panda, which didn't cope very well with even the smallest hills, and didn't go faster than 30 miles per hour (even if it had, it would have probably fallen apart after an hour). It was also the only car on our car park, which was covered with birds poo (clearly Spanish seagulls know a thing or two about cars.) So, the 1.5 hours journey, which Google said it would take us to get there, turned into 3 hours.


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Law Enforcement Resume
Desired Industry: Law Enforcement/Security/Safety
SpiderID: 81062
Desired Job Location: Parkton, North Carolina
Date Posted: 6/7/2018
Type of Position: Full-Time Permanent
Availability Date:
Desired Wage: 36000
U.S. Work Authorization: Yes
Job Level: Management (Manager, Director)
Willing to Travel: Yes, 25-50%
Highest Degree Attained: Bachelors
Willing to Relocate: Yes
Methodical, performance-driven, and highly analytical professional, offering broad-ranging experience in law enforcement, encompassing security, investigations, and criminal intelligence; complemented with solid knowledge of federal, state, and local laws and ordinances. Articulate communicator with naturally personable attitude; able to interact and quickly establish positive work relationships with individuals of diverse backgrounds. Bilingual in English and Spanish. Technically proficient with Microsoft Office applications (Word, Access, and Excel).
South View High School, Hope Mills, NC
Gray's Creek High School, Hope Mills, NC
Job Coach | Teacher's Assistant 2016–Present
Pinnacle, Rockingham, NC
Licensed Therapeutic Foster Parent 2015–Present
Go Triangle Transit, Raleigh, NC/Durham County, NC
Bus Operator 2016
Douglas Byrd High School, Fayetteville, NC
Safe School Coordinator 2012–2016
United States Postal Service, Parkton, NC
Postal Service Rural Carrier 2002–2011
United States Army Reservist/National Guard (RET), Fort Bragg, NC (1981–2008)
Observer Controller | Trainer | Platoon Sergeant (Motor Transportation Unit) | Administrative Clerk 1981–2008
26 Federal Plaza, New York, NY
Spanish Interpreter 2000–2001
United States Department of Justice, Immigration and Naturalization Service, New York, NY
Assistant Chief Detention Enforcement Officer 1999–2000
Supervisory Detention Enforcement Officer 1995–1999
Detention Enforcement Officer 1989–1995
Bachelor of Science in Criminal Justice, Jul 2015
Fayetteville State University, Fayetteville, NC
Law Enforcement and Criminal Justice Operations
Provided oversight to entire operations of detention facility in New York, responsible for supervising 135 detention enforcement officers and administration personnel while conducting situation briefs, interrogations, and issuance of orders from the Office of Deportation and Immigration
Executed in-depth background investigations of all allegations set forth by detainees against detection facility staff, while enforcing corrective actions, assessing applicable policies, and recommending restitutions as necessary
Carried out diverse law enforcement duties relevant to the investigation, identification, prosecution, detention, and deportation of illegal aliens along with the apprehension of absconders from removal proceedings
Oversaw the processing activities for subordinates responsible for the arrest and removal of illegal aliens who are unauthorized to be at work and reside in the United States
Organized the daily schedule of firearms duty roster as well as designated officers in charge of escorting and transporting illegal immigrants to their country of citizenship
Executed systematic processing of illegal aliens into the detention facility and took fingerprints while assigning proper confinement level as well as assessed the level of potential threat to others and assigned holding area
Security Implementation and Management
Took charge of performing routine security checks, updating security policies as necessary, and disseminating new policies within the agency
Employed effective and strategic plans of action and security philosophies based on existing knowledge and innovative practices
Managed and monitored electronic surveillance cameras and related equipment
Ensured the safety and security of all illegal aliens while in custody
Conducted strict enforcement of rules and regulations governing operations, security, detainee accountability, and detainee conduct to ensure execution of judicial sanctions while maintaining detainees in custody
Guaranteed accurate documentation and implementation of different protocols as well as enforcement of court order on deportation of criminal alien
Growth and Development Impacts
Directed several training classes and work schedules for employees thus obtaining 20% increase in productivity and processing was recognized after training completion
Served as effective project manager, responsible for implementing new key control process that improved the security and accountability service at the detention facility
Received letter of recommendation in 2014 for successfully minimizing disciplinary action toward students from 100% to 70% and were send to an alternative school the same year
Boosted the productivity and operations processing of the entire facility after the implementation of developmental training for employees
Additional Information:
Professional Development
Supervisory Detention Officer Technical Training
Basic Law Enforcement Firearm Training (Federal)
Journeymen Detention Enforcement Officer Training
Advanced Immigration Supervision
Federal Law Enforcement Training
Basic Management Training
Cardiopulmonary Resuscitation (CPR)/Standard First Aid Instructor
Therapeutic Foster Parent (2015–Present)
North Carolina Commercial Driver License Class A
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Finally Friday!
Thank Goodness It's Friday!
I am at the end of week two of this three week program and have noticed I am having better luck following this amazing meal plan. I am focusing on what I am eating and what time I am eating each item, which is helping my digestion and overall hunger throughout the day. I am not one to step on the scale- I do on the first day and the day after the last day of the program. The scale does not define me, but I was able to tell there was an issue due to how my clothes fit. I have gained some weight (20 pounds, not muscle weight) this year and have had to dig out my size 10 dress pants to wear to work. I am confident and hopeful that I will be able to pack them back away soon!
Since I have already changed up what I am eating when, I decided to bring my workout outside tonight to change it up! That was a new experience for me – at my home anyway- with the neighbors potentially watching. I am just under six foot tall, so for me the ceiling in the workout space is fairly close to my head…especially when I jump.
As I mention in this video, I have not had a slice of bread in 12 days. I have had pizza, which as I write this blog my husband has chastised me for because pizza is bread. It is my story, my interpretation, so it is not up for argument because I specifically said SLICE of bread. We go through at least two loaves of bread per week. I have noticed it is less now that I have omitted it from my daily routine. {will I eat bread again? Yes, I will, especially if you make me some french toast or a summer BLT… But right now I am testing and winning with my willpower!}
Recap of outdoor back yard workout: I had two options- cement or grass. Today I chose the cement because I wanted to make sure I had a flat surface. I was sucking air hardcore after the first ten minutes! It did feel great to not have to worry about space being an issue and I am going to try the grass next time! This Speed 35 routine had two rounds each repeated once with the agility markers set up differently in each round. My favorite move from round one is the hurdle hops and round two is the diamonds and the hurdle hops! Both rounds were very effective and I can say this is one of my favorite workouts so far in this program!
Here are some images from today's sesh!
All-in-all, I think three weeks is just perfect to try something new and step out of your comfort zone. It takes 21 days to make a habit you know. My next VIP group registration will be opening soon, so if interested, please inquire by clicking the button to the right for the free consultation!
Until next time, keep shattering your ceiling!


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Description of Zvonimir's motorboat
Open up to a world of escape and fun. With clever use of space, a well thought out layout, plus onboard comfort surrounding you, this is a boat that switches from water sports use to cruising around and relaxing with ease, so that you can truly enjoy all the freedom of being on the water. Chartering this boat will be perfect for you and your group of 7 people or less. From Split, you can go on and visit the cities of Trogir, Primosten, and Sibenik, very easily. Also, you have wonderful islands located nearby such as Hvar, Vis, Brac, Solta, Otok Drvenik Veli, Mljet, and Korcula. You should definitely go buy some local food to bring a nice picnic on the boat. Extra charges: Skipper- 80 euro/day Fuel is not included in the price If you have any questions feel free to contact me via Click&Boat. I hope to see you have fun in Croatia soon!
A personal advisor will help you, click here
16 photos
- Model: ACTIV 675 OPEN
- Manufacturer: QUICKSILVER
- Length: 22.15ft
- Width: 7.87ft
- Draft: 3.28ft
- Year of manufacture: 2016
- Engine type: Inboard
- Engine: 150hp
- Onboard capacity - Authorised: 8
- Onboard capacity - Recommended: 6
- Number of cabins: 1
- Number of berths: 2
- Minimum rental age: 18 years old
- Amount of the security deposit : 905$ ?
- Fuel included in price: No
Equipment of the motorboat
- Hardtop
- Bathing ladder
- Dining table
- Bow sundeck
- Stern sundeck
- Deck shower
Outdoor equipment
- Dinghy
- Dinghy's engine
- Bow thruster
- Electric windlass
- Depth sounder
- Automatic pilot
Navigation equipment
- Power outlet
- USB socket
Energy on board
- Oven/cooker
- Fridge
- Freezer
- Sink
- Dining table
Kitchen equipment
- Cold water
- Hot water
- Bathroom
- Toilet
Sanitary facilities
Comfort on board
- Fins, masks and snorkels
- Fishing tackle
- Scuba diving equipment
- Water skis and accessories provided
- Wakeboard and accessories provided
- Tubes and towing accessories provided
On the water / underwater
Location of the motorboat: Trogir
Super owner
Super owners are experienced boat owners who have received positive reviews and are committed to providing services of the highest quality.
Overall rating
Compliance of the boat
Comfort on board
Standard of maintenance
Welcome and communication
Value for money
5 comments
Great craft, very accommodating and flexible owner. 5-stars - highly recommended!
Thé Boat is top. Very good rent !
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Book Quicksilver 675 in Trogir or Split and cruise around the islands!
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A personal advisor will help you, click here


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How Boris Johnson's leaked Brexit plan would actually work
BORIS JOHNSON's draft Brexit deal has been revealed and details an alternative to the Irish backstop but what exactly does it mean and how would the plan work?
Boris Johnson is set to submit his final Brexit deal to the EU in the coming days in a last-ditch attempt to secure a deal before the October 31 deadline. A draft was leaked to the press on Monday and detailed his alternative to the Irish backstop, which suggested custom posts along both sides of the Irish backstop. Irish politicians have condemned the proposals, but what exactly do the plans mean and how would they work in practice?
The new proposals intend to provide a workable alternative to the Irish backstop, the mechanism to prevent a hard border between Northern Ireland and Ireland.
The existing backstop, outlined in Theresa May's withdrawal agreement effectively keeps the UK in a customs union with the EU and Northern Ireland.
As a result, many EU laws will still be imposed on the UK, restricting its ability to do its own trade deals.
But the Government's latest Brexit plan suggests establishing an "all-Ireland" trade zone, that would allow certain goods to move across the Irish border without any checks.
Boris Johnson's draft Brexit deal has been revealed
This will be made possible by both sides sticking to the same rules and regulations in terms of how the goods are produced.
Food and agriculture goods are expected to be included within the zone, with other imports and exports required to pass through newly constructed customs clearing houses a few miles away from the Irish border.
The clearance centres will be built between five and 10 miles away from the current border.
Lorries carrying goods produced in sectors where the EU and UK are no longer aligned would have to declare what they are transporting.
JUST IN: Tory conference LIVE: Police and paramedics run in as Tory MP fight
It is thought that most of the checks will be carried out from the place of origin, but formal inspections may well take place.
After passing through the customs centre, the lorries would then be tracked using GPS technology as they make their way north and south.
Such an approach would ensure there is no physical infrastructure built at the border itself - something Mr Johnson has said he will never agree to.
But physical infrastructure will still have to be built, leaving the plan open to rejection from the EU and Dublin.
BBC's Laura Kuenssberg warns UK will turn into EU's nightmare [COMMENT]
UK polls tracker: Lib Dems up as Labour battered - but Boris still top [POLLS]
Brexit news: Tory hints at secret plan but won't share with Remainers [INSIGHT]
Brussels fears customs sites could become targets for terrorists and are opposed to building anywhere near the border.
By keeping Northern Ireland aligned with the EU to allow for the frictionless trade zone, there would be a small regulatory border created in the Irish Sea.
This is because only Northern Ireland will be required to stick to the rules and the rest of the UK will be free to diverge.
The DUP have suggested they could approve such a plan, as Northern Ireland will be treated the same as the rest of the UK in every other customs area.
But Irish politicians have condemned the proposal, with Ireland's deputy prime minister branding it a "non-starter".
Mr Johnson has downplayed the idea that clearance centres would form part of the UK's final Brexit proposals.
He told the BBC: "That is not what we are proposing at all."
But he said it was a "reality" that there will need to be customs checks on the island of Ireland after the UK leaves the EU.
He said: "A sovereign united country must have a single customs territory."


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JSS Academy of Higher Education & Research, formerly known as JSS University, is a Deemed to be University located in Mysuru, Karnataka. It was established in 2008 under Section 3 of the UGC Act 1956 and is part of JSS Mahavidyapeetha, which runs a variety of educational institutions. This deemed-to-be university is recognized by MHRD and accredited by NAAC with A+Grade (3.47 CGPA). JSS AHER has been graded as Category-I Deemed-to-be University by UGC in the Year 2018.
Hostel , Library , Labs and ets
JSS Academy of Higher Education & Research ( JSS AHER ) with its training and placement cell have facilitated sighting of fresh and promising human resources for the life sciences industry. Around 75 per cent of the students opt for enrollment into the training and placement and are suitably employed in leading pharma, Ayurveda, biotech companies, Hospitals across the country.
Students have exclusive hostels for Boys and Girls with spacious, comfortable, well-furnished rooms with all modern amenities, hygienic kitchens, nutritious food, and portable RO water source is provided for drinking. Each hostel block has a separate pantry and laundry facility. Students wishing to stay in these hostels are advised to apply in the prescribed forms. The boarders are having Indoor and outdoor sports facilities and ample reading room facility. Round the clock security guards (Male & Female for respective hostels) as well as CCTV cameras are placed for continuous monitoring and vigilance for the safety of students.
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A State Dinner At The White House
In this wise ït 13 dono by Gen. Grant at his dinners of stato in the White House : The number invitad is usually about thirty. The names of those to be invited are given to the invitation clerk, and he filis up the engraved card whereon spanes for names and dates have been left blank. The full number of guests having accepted; tho dork proceeds to page theiu cff and prepare the carda, which, enclosed in e, small envelope, are given to cacb gentleman in the cloak-room. Those cards have on one the name of the lady tho gentleman is to escort to the table, and on the other a diagram of the table, with the name of the gentleman nd tho lady placed under bis care opposite the numbors indicating their respective soats. Confusión is thus avoidcd. Tho state dining-room is in the west wing of tho White House, and the tablo is set with due regard to tho points of the compass. The President sits in th central seat and Mrs. Grant sits exactly opposite. Tho places of honor for ladies aro on the right and left of the President, and on tho right nnd left of Mra. Grant for gentlemen. Soma eighteen or twenty courses baro been known to be served at theso I dinners, and at evory plato are eiglit glassoí for different kinds of wine.
Old News
Michigan Argus


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Click here to print the obituary below
Burton Eugene "Burt" Lent
January 17, 1917 ~ March 20, 2011
Burton Eugene Lent, of Vancouver, WA, passed away on March 20, 2011. He was born on Jan. 17, 1917 to Frederick and Vera Lent in Cresco, IA, the middle child between Charles and Gertrude. After attending school in Cresco and Worthington, MN, he went to Waverly, IA to work for his brother-in-law.
It was in Waverly that Burt met the love his life, Virginia Bailey. They were married June 1, 1941 and were happily married for almost 70 years!
They came to Vancouver to work in the shipyards for the war effort in 1943. After a brief return to Iowa after the war, they returned to Vancouver in 1945.
Burt worked at Sparks Home Furnishings for 35 years. After retiring, Burt kept busy volunteering at his church and ushering each Sunday. He also worked at Share House serving lunch one day a week. He enjoyed his wood lathe making numerous toy soldiers and snowmen. He especially liked attending the men's cooking class at Marshall Recreation Center and traveling with Ginny to many wonderful places around the world. For the last two and a half years, Burt and Ginny have lived happily at Highgate Senior Living.
Burt is survived by his wife, Virginia; three nephews; and a host of friends in Vancouver who will all miss his love, caring, and sense of humor.
The celebration of his life will take place on Wed., March 30, at 10:00 a.m. at First United Methodist Church, 33rd and Main.
Instead of flowers, please consider sending a donation to the church with a label for the Share House Lunch Program that Burt helped with for many years.
Please sign Burt's guest book at:
Published in The Columbian on Mar. 27, 2011


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We theoretically examine the effect of external optical injection on the spatiotemporal dynamics of class-B broad-area lasers. We demonstrate that optical injection can efficiently stabilize the intrinsic transverse instabilities in such lasers associated with both the boundaries of the pumping area and with the bulk nonlinearities of the active medium. Stabilizing action of optical injection is shown to be closely related to the suppression of inherent relaxation oscillations behavior.
© 2017 Optical Society of AmericaFull Article | PDF Article
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Opt. Lett. 28(13) 1135-1137 (2003)
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Opt. Express 5(3) 48-54 (1999)
Brian L. Sands and S. Burçin Bayram
Appl. Opt. 46(18) 3829-3835 (2007)


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James Oheln
Star Wars MMO companion characters to be "virtual friends," says BioWare
Star Wars: The Old Republic creative designer, James Ohlen, has told Shacknews, that companion characters in the game will be more like "virtual friends" rather than just "pets". "Companion characters–we want them to be more than pets," he said. "We want them to be virtual friends. We want you to interact with them and become […]
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The system includes:
1. Fingerprint Reader
2. Power adaptor
3. USB cable
4. The cable to connect the electromagnetic lock
5 . Attendance system management software CD
6. Nails to install it on the wall
7. SDK available for OEM customers and software developers
Screen L*W mm: 128*64 LCD
User capacity: 3, 000
Transaction Storage: 80, 000
Period of data: Keep data for 3 years without current
Support baudrate: 9600BPS, 19200BPS, 38400BPS
Verification mode: 1: N, 1:1
Response time: <0. 6 second
Alarm function: anti-dismantle
External functions: Connect Electronic lock(Access Control), Electronic bell
Communications: RS232 or RS485, TCP/IP, USB and Weigand output
Access control: Support 50 time zones, 5 groups and 10 unlock combinations
Show: Time, ID number, Name
Language: English, French, Spanish, Czech, Indonesian, Portuguese, Turkish
Open Door Methods: Verify open door, button open door, Software control door - keyboard has bell button
Time & Attendance mode: Fingerprint, password, card, fingerprint + password, fingerprint + card
Save function: Turn off device automatically for saving
Size(L*W*H cm): 180*82*55mm
Packing (L*W*H cm): 270*180*120mm
Power supply: DC12V, 1A (AC 100V to 240 V, 50 to 60 Hz )
Warranty of period: 24 months
Temperature and humidity: 0 - 45, 20%-80%
Optional Function: TCP/IP, ID/IC Card, Spare Battery
Applications: Office / factory / supermarket / villa etc


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How to get money in bitcoin wallet
Well, let's get irked. The first stage you need to get into the how to get money in bitcoin wallet judgement of bitcoin payments, is a bitcoin trading. More are generally two years of wallets. Online skier and tight wallets. An online bitcoin tracing is a flat evidenced in the panel. You access the chief through a good, from any ark, where you can use and search funds from your bitcoin system. The quarrel is that you do not going to continue any information on your computer or transmitter the maximum blockchain, which is also more than 30 year.
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We've put together a list of our most sexy and feminine styles that will leave you or your significant other LOVESTRUCK!
Whether your plans include a romantic dinner, a relaxing movie date, or anything in between, we've got you covered! From sexy mesh cut outs, to flirty laser-cut details, each style offers a chic and versatile finish to your date night look.
Featured Style: BRAEWYN
For a casual night out with your BFF, wear fun prints that still have a little edge (like our BREANNA heel) ensures you'll stand out in a crowd. For a more romantic night, any stiletto stands up to the elegant ambiance of a nice restaurant, but our BEL-AIR's laser cut details really take the cake. Where ever you end up on Valentine's Day, these styles will leave you looking gorgeous from head to toe!
Happy Valentine's Day Ladies!
Lovestruck Styles:
Featured Style: BRAEWYN
Featured Style: ELENI II
Featured Style: Cagney
Featured Style: Bel-Air