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PEPPSI-Effect on Suzuki-Miyaura Reactions Using 4,5-Dicyano-1,3-dimesitylimidazol-2-ylidene-Palladium Complexes: A Comparison between trans-Ligands (2015)
The PEPPSI (Pyridine Enhanced Precatalyst Preparation, Stabilization and Initiation) complexes 12-15 with the structure [PdCl2{(CN)(2)IMes}(3-R-py)] (12: R = H; 13: R = Cl; 14: R = Br; 15: R = CN) bearing the maleonitrile-based N-heterocyclic carbene (NHC) (CN)(2)IMes ({(CN)(2)IMes}: 4,5-dicyano-1,3-dimesitylimidazol-2-ylidene) were prepared. Solid state structures of 14 and 15 were obtained. Complexes 14 and 15 adopt a slightly distorted square-planar coordination geometry in the solid state with the substituted pyridine ligand trans to the NHC. Catalytic activities of precatalysts 12-15 were studied and subsequently compared to complexes [PdCl2{(CN)(2)IMes}(PPh3)] (4) and [PdCl(dmba){(CN)(2)IMes}] (5) recently reported by our group in the Suzuki-Miyaura reaction of various aryl halides and phenylboronic acid. Reactions using previously reported [PdCl2(IMes)(py)] (IMes: 1,3-dimesitylimidazol-2-ylidene) (1) were also carried out and their results contrasted to those involving 12-15, 4 and 5. Differences in initiation rates and the catalytically active species related to the seven complexes in regards to the throw away ligand were investigated. Poisoning experiments with mercury show that palladium nanoparticles are responsible for the catalytic activity.
Synthesis of Magnaldehydes B and E and Dictyobiphenyl B by Microwave-Promoted Cross-Coupling of Boronophenols (2015)
Magnaldehydes B and E along with their 4'-methylated derivatives are naturally occurring 2,4'-biphenols that have been isolated from the Magnoliaceae. Herein, these natural products have been synthesized from a common intermediate, which was obtained by a microwave-promoted, hetero-geneously catalyzed, and protecting-group-free Suzuki-Miyaura coupling reaction in an aqueous medium. These reaction conditions were also successfully applied to a one-step synthesis of the slime mold metabolite dictyobiphenyl B.
Unlike their ortho counterparts, meta- and para-acetamidoanilines can be converted into the corresponding acetamidoarenediazonium salts. These offer various opportunities for multiple Pd-catalyzed arene functionalization reactions, such as Matsuda-Heck-, Suzuki-Miyaura- or Fujiwara-Moritani couplings.
Efficient palladium(II) precatalysts bearing 4,5-dicyanoimidazol-2-ylidene for the Mizoroki-Heck reaction (2014)
The new N-heterocyclic carbene (NHC) complex [PdCl2{(CN)(2)IMes}(PPh3)] (2) ({(CN)(2)IMes}: 4,5-dicyano-1,3-dimesitylimidazol-2-ylidene) and the NHC palladacycle [PdCl(dmba){(CN)(2)IMes}] (3) (dmba: N,N-dimethylbenzylamine) have been synthesized by thermolysis of 4,5-dicyano-1,3-dimesityl-2-(pentafluorophenyl) imidazoline (1) in the presence of suitable palladium(II) precursors. The acyclic complex 2 was formed by ligand exchange using the mononuclear precursor [PdCl2(PPh3)(2)] and the palladacycle 3 was formed by cleavage of the dinuclear chloro-bridged precursor [Pd(mu-Cl)(dmba)](2). The new NHC precursor 1-benzyl-4,5-dicyano-2-(pentafluorophenyl)-3-picolylimidazoline (5) was formed by condensation of pentafluorobenzaldehyde with N-benzyl-N'-picolyldiaminomaleonitrile (4). The NHC palladacycle [PdCl2{(CN)(2)IBzPic}] (6) ({(CN)(2)IBzPic}: 1-benzyl-4,5-dicyano-3-picolylimidazol-2-ylidene) was prepared by in situ thermolysis of 5 in the presence of [PdCl2(PhCN)(2)]. The three palladium(II) complexes were characterized by NMR and IR spectroscopy, mass spectrometry and elemental analysis. In addition, the molecular structures of 2 and 3 were determined by X-ray diffraction. The pi-acidity of (CN)(2)IBzPic was compared with (CN)(2)IMes and perviously reported pi-acidic imidazol-2-ylidenes by NBO analysis. The Mizoroki-Heck (MH) reactions of various aryl halides with n-butyl acrylate were performed in the presence of complexes 2, 3 and 6. The new precatalysts showed high activity in the MH reactions giving good-to-excellent product yields with 0.1 mol-% pre-catalyst. The nature of the catalytically active species of 2, 3 and 6 was investigated by poisoning experiments with mercury and transmission electron microscopy. It was found that palladium nanoparticles formed from the precatalysts were involved in the catalytic process.
2,5-Disubstituted furans were synthesized by one-flask Heck arylation/oxidation sequences. The starting materials are 2-substituted 2,3-dihydrofurans, conveniently available by RCM/isomerization sequences, and arenediazonium salts. These react in ligand-free Heck reactions to afford 2,5-disub-stituted 2,5-dihydrofurans, which are oxidized to the corresponding furans without isolation or intermediate workup. The oxidation is conveniently achieved with chloranil or DDQ, depending on the substrate.
Complexation of Palladium(II) with unsaturated Dithioethers a systematic development of highly selective ligands for solvent extraction (2012)
There is a demand for new and robust PdII extractants due to growing recycling rates. Chelating dithioethers are promising substances for solvent extraction as they form stable square-planar complexes with PdII. We have modified unsaturated dithioethers, which are known to coordinate PdII, and adapted them to the requirements of industrial practice. The ligands are analogues of 1,2-dithioethene with varying electron-withdrawing backbones and polar end-groups. The crystal structures of several ligands and their palladium complexes were determined as well as their electro- and photochemical properties, complex stability and behaviour in solution. Solvent extraction experiments showed the superiority of some of our ligands over conventionally used extractants in terms of their very fast reaction rates. With highly selective 1,2-bis(2-methoxyethylthio)benzene (4) it is possible to extract PdII from a highly acidic medium in the presence of other base and palladium-group metals.
Development of a solvent extraction system with 1,2-bis(2-methoxyethylthio) benzene for the selective separation of palladium(II) from secondary raw materials (2012)
The chelating dithioether 1,2-bis(2-methoxyethylthio)benzene. a novel solvent extractant for Pd(II), is aimed to be utilised in the selective recovery of palladium from spent automotive catalysts. For that, the extraction system has been further customised, including the choice of an appropriate diluent (1,2-dichlorobenzene) as well as an effective stripping agent (0.5 M thiourea in 0.1 M HCl), which both have been selected from a number of potential agents. It is shown in batch experiments that the selectivity for Pd(II) is maintained when the organic phase (10(-2) M 1,2-bis(2-methoxyethylthio)benzene in 1,2-dichlorobenzene) is used several times to extract an oxidising leach solution. According to the McCabe-Thiele plot two theoretical stages are needed to extract more than 98% of the Pd(II) contained in that solution. The calculation of the thermodynamic quantities Delta H degrees. Delta S degrees and Delta G degrees reveals that the reaction is entropy driven - the temperature has only a slight influence on the extraction yield. It is demonstrated that the mono-oxidised extractant has a catalytic effect on the extraction kinetics when the aqueous phase contains highly concentrated hydrochloric acid. HPLC measurements prove the presence of small quantities of 1-(2-methoxyethylsulfinyl)-2-(2-methoxyethylthio) benzene in the organic phase.
We have synthesized a set of new unsaturated macrocyclic dithioethers with an increasing number of flexible methylene units 1-7 (Scheme 2) to investigate the correlation between the ring size of these ligands, the chelation effect and the consequences for an efficient PdCl2 coordination. The dithioethers 1-7 and the complex [PdCl2(4)]center dot CHCl3 were characterized by X-ray diffraction analysis. The crystal structures of 1-7 show that 2-7 are better preorganized chelating ligands for an exocyclic PdCl2 coordination than 1. The chelation effect of 1-7, the orientation of the sulfur atoms and the S center dot center dot center dot S donor distances, are influenced by the flexibility of the methylene units. In this series the unsaturated macrocyclic ligands 5 and 6 are the best chelating ligands for an efficient PdCl2 coordination. Comparative solvent extraction experiments with mn-12S(2)O(2) (mn = maleonitrile) reveal that the low interface activity of the new ligands reduces the extraction rate. However, a comparison with open-chain dithiomaleonitriles shows the impact of the macrocyclic effect of 4 and 5 on the extraction yield.


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A little while ago, I took a First Aid course in my sister's home with Red Cross instructor, Nancy Reynolds of Baby Secure. Although there was a part of me that thought I didn't really need this day of intense First Aid knowledge, I decided to go and I am so happy…
The other day I got a call from one of my very best friends. It was so nice to hear her voice and hear about how her kids were doing. What I didn't expect to hear was this:

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Leeds United have been dealt a blow in their pursuit of midfielder Harry Wilson according to the Birmingham Mail.
Wolverhampton Wanderers are now set to be the favourites to sign the Liverpool man should he leave Anfield this transfer window.
Wilson consistently impressed whilst on loan at Derby County in the 2018/19 season and the Welsh international is a sought after player by a whole host of Championship and Premier League clubs.
The 22-year-old scored 16 times for the Rams as he helped in their quest for promotion from the Championship although they ultimately fell short as they lost in the Play Off Semi Final to Aston Villa.
Jurgen Klopp was in contact with Derby throughout Wilson's time at the club although it is expected that if a permanent deal with another club isn't agreed then he will be allowed to go out on loan once more in order to gain more first team experience.
Following his breakthrough season at Pride Park it is thought that Klopp would prefer Wilson to go out on loan to a club in the Premier League which would all but end hopes of Leeds signing him.
Wolves have been known to have taken an interest in the midfielder with an offer in the region of £20million having been reported as a fee they would be looking to pay.
Liverpool boss Klopp feels it would be best for Wilson to experience top flight football at another club before being brandished with the pressures of playing for the European champions.
Wilson is undoubtedly a wanted man this summer and should Wolves progress with their interest it would be a huge blow for Leeds and Derby County.


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It's almost time for mini movie marathons. Need to make up some ground. 90) Life – 4/5 (good space movie, Ryan Reynolds 🙁 no spoilers) 91) The Party Monster: Scratching The Surface – 3/5 (pretty funny, too short) 92) Parkway… Continue Reading →
I really need to buckle down and get more movies watched if I'm gonna make it to 365 78) Extremely Wicked, Shockingly Evil, and Vile – 3/5 (too "romanticized", not enough realness) 79) Happy Death Day 2 U – 4/5… Continue Reading →
Another slow month 67) Harry Potter and the Sorcerer's Stone – 5/5 (great intro to series, why can't he stay at Hogwart's?) 68) Harry Potter and the Chamber of Secrets – 5/5 ("Speak Clearly" but he doesn't, no one notices… Continue Reading →
I was inspired by my recent avocado adventure so I wrote a song lol *** Avocado Buddies At first it was a joke And I made fun of him But he planted the seed For an avocado win Now we're… Continue Reading →
Here is my March movie log. Still a bit behind, but should make it up in the summer. 52) Wild Love (short) 53) Saturn Thur The Telescope (short) 54) Willa (short) 55) Affection (short) 56) Cemetery Tales: A Tale of… Continue Reading →
So, here's the thing. I never really got the whole avocado thing. The hipster obsession with Avocado Toast, or even the whole guacamole deal. I always asked for no guac on my Mexican food. It was never something I thought… Continue Reading →


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Philip Romano is a Founder and General Partner of SHD, SHD II and SHD III. In addition, Mr. Romano is an investor, entrepreneur, artist and internationally renowned restaurateur. Mr. Romano has been an active venture capital investor for over 20 years concentrating on healthcare-related industries. Mr. Romano was the sole outside investor and business executive of the company responsible for inventing the Palmaz® stent, which was named one of the "10 Patents that Changed the World" by IP Worldwide in 2002. The stent market grew from non-existent to an over $8 billion industry. Mr. Romano has also been named to the Texas Business Hall of Fame. In addition, he and Dr. Palmaz formed another company resulting in a successful licensing transaction with Johnson & Johnson.
Stuart Fitts is a Founder and General Partner of SHD, SHD II and SHD III. Mr. Fitts previously owned EGF Broadcast Corporation and Gulf California Broadcast Company, which owned and operated radio and television properties in Palm Springs, California. Mr. Fitts sold the companies to News-Press & Gazette Company in St. Joseph, Missouri. Since the sale, Mr. Fitts has been the Managing Partner of Fitts Investment Company, a Dallas based privately held investment firm. Mr. Fitts received his B.A. in English from Southern Methodist University and his M.B.A. from the Cox School of Business at Southern Methodist University. He currently serves on the board of Presbyterian Health Resources, which oversees the Presbyterian operations under the Texas Health Resources umbrella.
Carter Meyer has been the Chief Executive Officer of SHD since its formation in February 2006, and is a General Partner of SHD II and SHD III. Prior to joining SHD, he was an attorney in private practice for over 12 years, most recently with the Dallas office of the Vinson & Elkins L.L.P. As an attorney, Mr. Meyer focused on commercial transactions with substantial experience buying, selling, financing and making investments in both public and private entities. Mr. Meyer has a B.B.A. in finance from Texas Christian University and a J.D. from St. Mary's University School of Law. Mr. Meyer is a director of all SHD portfolio companies.
Andrew Offer joined SHD in 2007 and is a Managing Director and the Chief Financial Officer. Mr. Offer also serves as the Chief Financial Officer for multiple portfolio companies in addition to serving as a director of MiNDERA. Prior to joining SHD, he was a senior analyst and associate at Dallas-based Value Management Group (VMG Health), where he focused on business valuation exclusively in the healthcare industry. Mr. Offer graduated Magna Cum Laude with multiple honors distinctions earning a B.B.A. in Finance from the Mays School of Business at Texas A&M University. In addition, Mr. Offer earned the Chartered Financial Analyst (CFA) designation in 2009 and is a member of the CFA Institute and the CFA Society of Dallas-Fort Worth.


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Brodi Lea Hall (Lauzon) December 21, 1984 – October 26, 2017
Brodi is at peace.
In true Brodi style, she left this world on her own terms and in her own time, surrounded by her loving husband Adam and family. She made her way to a place where she can walk and talk and sing again. Her beloved Nana and Papa had her room all ready and now hold her in their loving arms. We will miss her terribly and look forward to her "Celebration of Life' in the very near future. Her family would like to thank everyone who was involved in her care over the past few years with special thanks to her care team at the Royal Victoria Regional Health Care Center, Dr. Michael McConvey, the PSW's from Independent Living Services, Bayshore and St. Elizabeth and everyone who participated in the "Lift Her Up" fundraiser. We can never fully express our appreciation for your generosity, kindness and support and the difference you made in our lives.
Brodi is survived by her loving husband Adam, mother, Andrea Lauzon, father, William Redmond, mother and father-in-law, Alyson and Ted Hall, brothers- in- law, Ted and Simon and sister- in- law Danielle. She is also remembered dearly by her large extended family and friends.
A celebration of Brodi's life will take place on Sunday, November 26th, 2017 from 1-4 p.m. at the Dorian Parker Community Centre, 227 Sunnidale Road, Barrie. In lieu of flowers, please support the RVH foundation in Brodi's memory. Messages of condolence can be left at www.peacefultransition.ca


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In addition to more than 100,000 artifacts, including pieces currently stored in the vaults of the Egyptian Museum in Cairo, the new museum will sport a Modernist design courtesy of Heneghan Peng Architects. Chosen from more than 1,550 design proposals from architects in 82 countries, the final building will echo both the geography of the plateau on which it rests as well as the Pyramids themselves. When the museum partially opens in 2018, visitors in the immense atrium can soak in the majestic sight of both the Pyramid of Menkaure and the Great Pyramid of Khufu from a floor-to-ceiling glass wall. —Diana Hubbell
The Faction sets off nuclear blasts that destroy all of the Travelers' archives outside the US. David, left for dead by the Faction in the last surviving archive, is the only person who can disarm the nuclear device. He succeeds but is exposed to lethal radiation. Kat's suspicions about MacLaren, temporarily allayed, surge again and she throws him out – for her the marriage is over as she feels he is no longer the man she first met. Jeff tries to escape from interrogation by 001; he is eventually found having been walled up. Marcy hopes the Director will send a Traveler medical team to save David but no help arrives. In the moment before he dies, David conveys a message from the Director: "Protocol Omega."
The Moroccan city has attracted an artistic crowd since the 1960s, when everyone from Yves Saint Laurent to Mick Jagger fell for its vibrant sensory landscape. Now the city's cultural scene is being reinvigorated, thanks to two landmark happenings in the world of art and design. First came last October's launch of the YSL Museum — a striking geometric building next to the Jardin Majorelle, which Saint Laurent and his partner, Pierre Bergé, bought and restored in the 1980s. Then, in February, the 1:54 Contemporary African Art Fair will debut at the storied hotel La Mamounia. Marrakesh has had an art biennial since 2005 — the next is slated for 2020 — and the city is home to a number of well-regarded galleries. But the arrival of 1:54, which has editions in London and New York and draws names like Billie Zangewa and William Kentridge, is set to position the city as a hub for African art. There's also hotel news. Oberoi is poised to open its third African property here, a lakeside resort surrounded by citrus orchards. And Royal Mansour has added a 6,450-square-foot pool flanked by seven air-conditioned cabanas. —Flora Stubbs
Flight Denver - Chicago (DEN - ORD) $79+ Flight Houston - Chicago (HOU - ORD) $91+ Flight Houston - Chicago (IAH - ORD) $91+ Flight Boston - Chicago (BOS - ORD) $97+ Flight Dallas - Chicago (DFW - ORD) $97+ Flight Minneapolis - Chicago (MSP - ORD) $97+ Flight New York - Chicago (LGA - ORD) $97+ Flight Washington - Chicago (BWI - ORD) $101+ Flight Atlanta - Chicago (ATL - ORD) $108+
Three months after the events with the Quantum Frame, Mac and Kat are working through their issues during her first trimester. Marcy has moved out of David's apartment and has taken a job as an X-ray technician at a local hospital. Philip has traded one addiction for another, but is in denial about it. Trevor is growing concerned with the lack of communication from the Director. The discovery of a murdered Traveler team puts Mac on the trail of Vincent.
The capital may be set on banks of the Potomac, but it's never had a reputation as a great waterfront city. That could all be about to change, thanks to the $2.5 billion, 24-acre District Wharf, which opened in October just south of the National Mall. The shiny new InterContinental Washington D.C.-The Wharf offers access to the development's new parks, music venues, 50-plus shops, and 20 restaurants — which include projects from area chefs like Fabio Trabocchi, Mike Isabella, and wunderkind Kwame Onwuachi. This is also set to be a banner year for culture: the Freer and Sackler galleries, sister museums that champion Asian art, recently reopened after a 20-month renovation, the National Gallery of Art will host the first-ever show dedicated to Cézanne's portraits from March to July, and the Kennedy Center continues its inaugural season of hip-hop programming curated by Q-Tip. —Brooke Porter Katz
Landlocked Laos might be quieter than Southeast Asian neighbors like Vietnam and Thailand, but 2018 could transform the country into the region's next hot spot. Wattay International Airport, in the capital of Vientiane, is set to complete a terminal expansion to accommodate more international links next year, but the biggest changes are foot in the UNESCO World Heritage–inscribed town of Luang Prabang, in central Laos. This serene riverside spot lures travelers to its golden Buddhist temples, French-colonial architecture, hiking trails, nearby elephant sanctuaries — and now, glamorous new digs. Last year, the design-forward Azerai opened inside a century-old French-colonial building that was formerly an officer's quarters. The debut concept from Aman Resorts founder Adrian Zecha has airy, light wood interiors that nod to local culture in their use of batik textiles and Laotian artwork. There's also an 80-foot swimming pool in a tree-shaded central courtyard. The upcoming Rosewood Luang Prabang aims to be a destination in itself. Opening in mid 2018, this highly anticipated resort will feature pavilion-style villas, luxury tents, and a spa that seems to float above the jungle. —Kate Springer
This year is San Antonio's 300th anniversary, and the city is marking the occasion with events, activities, and new infrastructure. Ahead of the festivities, there's been a flurry of development: In the past few months, the botanical gardens completed an expansion; the city's first food hall, the Bottling Department, debuted at the Pearl; and San Antonio's iconic passenger barges got an upgrade, with colorful electric models replacing the old gas-fueled boats. In January, the city will unveil Confluence Park, an expanse of trails and science-focused education facilities near the convergence of San Pedro Creek and the San Antonio River. A commemorative week is planned for early May, with celebrations at each of San Antonio's five missions and the dedication of San Pedro Creek Culture Park, a once-unremarkable drainage ditch that's been transformed into a waterfront promenade with public art and performance spaces. Ruby City, a new David Adjaye–designed art center that will house more than 800 pieces from the Linda Pace Foundation Collection, is expected to be completed at the end of 2018. And boutique stays still in the works — including a Thompson Hotel and the third location of the Saint Hotel — hint that San Antonio's heyday is just beginning. —Devorah Lev-Tov
During the summer of 2015, Islands simultaneously recorded two records: Should I Remain Here, At Sea? — a spiritual successor to the band's debut album, Return to the Sea — and Taste, a "more electronic" album "buoyed by drum machines, programming and vintage synths."[6] The albums were released on May 13, 2016 via the band's own Manqué label, reaching #21 and #23 on the Billboard Heatseeker charts, respectively.[7]


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Because the East is an underrated art destination.
Estancia has always been one of the artsier malls in the Metro. Sculptures flank the floor and hang from the ceiling like stalactite and stalagmite, reminding you that This Is Not Just Another Mall.
This National Arts Month, Estancia at Capitol Commons makes good of this promise. It's recently launched its inaugural art festival that shines the spotlight on contemporary art pieces that are scattered on the ground floor and second floor of the mall. Best of all? It's free.
Over 50 artists will have their works displayed through five different galleries and collectives, while five artists are holding solo exhibits from Feb. 23 to March 26, 2018.
They're also holding free workshops — yes, free! — on select days during the month of March, at 1:00 p.m., at the 2F Bridgeway. On March 4 and 25, featured British painter Peter Sutcliffe will hold a watercolor tutorial, while on March 11, artist Ato Habulan will hold an alla prima (wet-on-wet) painting session. For those curious to see the making of an artwork from start to finish, there will be a live mural-making on March 18 by Kalye Kolektib.
"By holding an art festival in Estancia, we hope to make art more meaningful and accessible," says Architect Renee Bacani, Vice President of Ortigas and Company. "It is also our way of fostering a deeper regard for the art and cultural scene."
The Ortigas Art Festival runs from Feb. 23 – March 26, 2018. Admission is free. For more information, follow Estancia Mall on Facebook, and Instagram.


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sysstat=echo "date +'%d/%m/%Y %H:%M:%S' | echo $[100-$(vmstat 1 2|tail -1|awk '{print $15}')]% | free | grep Mem | awk '{print $3/$2 * 100.0}'" >> systemstatus.log


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Owning the Problem
To the Editor:
In the Aug. 28 issue Jay Mann called out the doomsday advocates who suggest that those living on the coast should retreat. Like Jay, I say: "Hell no, we will not go." But I believe that major changes are necessary and every one of us must adjust his or her lifestyle. And it may cost some money because we got by cheap when we did not build the appropriate infrastructures.
In the Sept. 11 story about his new book The Geography of Risk, Pulitzer Prize-winning author Gilbert M. Gaul presented this view: "The definition of insanity is doing the same thing over and over again and expecting a different result." – author unknown. The insanity in question is rebuilding in flood-prone areas after hurricanes hit.
In the same SandPaper issue, Rutgers coastal expert Lisa Auermuller, assistant manager at the Jacques Cousteau National Estuary Research Reserve, discussed "Capture the King Tide," an effort on Facebook (with photos from Barnegat Light, Tuckerton, Manasquan and other coastal communities) that enlists residents to document the higher-than-normal tide heights and flooding during this king tide period, illustrating what coastal locations will increasingly experience as sea levels rise.
Lisa made the point that today's high tides are tomorrow's everyday tides. The difference is that a king tide comes and goes, but in the future with sea level rise, the new water level heights will represent permanent inundation.
So, we really have a new normal. Our neighbor, the North Atlantic Ocean (which was here first), is really big, powerful, relentless, changing and uncaring. The news headlines and crowdsourcing activities tell us that change is real and we must change to meet new challenges. We have had manmade environmental disasters for a long, long time. We need to stop the blame game: nature, the other political party or whoever is in office. Everyone has had a hand in screwing this up.
We need to stop saying the problem is too big to solve. We must stop acting as though one political party has the solution or is the problem. We have got to stop believing that some level of government is going to solve this problem for us.
We have to own the problem because we have to fix it. We live here because we love a "coastal way of life" with its beauty and proximity to nature. Now we have to start paying for what we love. Yes, in some cases with dollars, but much more difficult will be necessary changes to our behavior. We can't expect any government to repeal the laws of physics that control our neighbor, the North Atlantic Ocean. And we must realize that ignorance of those laws is not a valid excuse to ignore them.
Rick Bushnell
Surf City
The writer is the current president of ReClam the Bay and a past president of the LBI Foundation of the Arts and Sciences.


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Topic: Help function; Brokerage
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Curious just how far your dollar goes in Tulsa?
We've rounded up the latest places for rent via rental sites Zumper and Apartment Guide to get a sense of what to expect when it comes to scoring apartment rentals in Tulsa if you've got a budget of up to $900/month.
Take a look at the listings, below. (Note: Prices and availability are subject to change.)
Hoodline offers data-driven analysis of local happenings and trends across cities. Links included in this article may earn Hoodline a commission on clicks and transactions.
4858 S. 78 East Place
Listed at $801/month, this 1,300-square-foot three-bedroom, two-bathroom unit is located at 4858 S. 78 East Place.
The townhome comes with a dishwasher, carpeted floors and a walk-in closet. When it comes to building amenities, expect on-site laundry and a swimming pool. Pet owners, inquire elsewhere: This spot allows cats and dogs. Look out for a $250 dog deposit.
Walk Score indicates that the surrounding area is moderately walkable, has some bike infrastructure and has minimal transit options.
(Take a look at the complete listing here.)
7700 Riverside Drive
Next, there's this two-bedroom, two-bathroom apartment located at 7700 Riverside Drive. It's listed for $803/month for its 966 square feet.
In the unit, you'll find a fireplace, a dishwasher and a mix of hardwood floors and carpeting. Pet owners, take heed: This rental is both dog-friendly and cat-friendly. Be prepared for a $150 dog fee.
According to Walk Score, the area around this address isn't very walkable, is relatively bikeable and has some transit options.
(See the complete listing here.)
9713 E. 75th St.
Then, there's this 1,050-square-foot two-bedroom, two-bathroom spot at 9713 E. 75th St. It's going for $804/month.
The residence comes with a dishwasher, carpeted floors, a fireplace and a walk-in closet. For those with furry friends in tow, this property is pet-friendly.
Walk Score indicates that the area around this address is car-dependent, is bikeable and doesn't offer many public transit options.
(Take a look at the full listing here.)
10149 E. 32nd St.
Listed at $810/month, this 1,140-square-foot three-bedroom, one bathroom townhome is located at 10149 E. 32nd St.
In the residence, you can anticipate a walk-in closet, both air conditioning and central heating and a dishwasher. Pet owners, rejoice: This property is both dog-friendly and cat-friendly.
Per Walk Score ratings, this location is moderately walkable, is bikeable and doesn't offer many public transit options.
(Take a look at the complete listing here.)
7350 S. Garnett Road
And here's an 801-square-foot one-bedroom, one-bathroom unit at 7350 S. Garnett Road that's going for $815/month.
In the residence, which comes furnished, the listing promises in-unit laundry, a walk-in closet, a fireplace and a dishwasher. This property is cat-friendly and dog-friendly.
Per Walk Score ratings, this location isn't very walkable, is somewhat bikeable and has minimal transit options.
(Take a look at the full listing here.)
Working with a tight budget? Here are the cheapest rentals recently listed in Tulsa.
This story was created automatically using local real estate data from Zumper and Apartment Guide, then reviewed by an editor. Click here for more about what we're doing. Got thoughts? Go here to share your feedback.


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Have a small space? This easy addition wall hanging coat rack with storage bin is ideal to increase your style and storage game. Easily hang this sturdy but lightweight piece on the wall in your entry area for an instant mudroom and drop zone. Made of metal and coated in black to be both durable and sleek, you'll gain six hooks and basket perfect to store shoes, bookbags, dog toys, or laundry.
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Your input is very much appreciated. Share it with your friends so they can enjoy it too!
We are not a conventional company and we don't intend to become one. For every purchase you make from us, we donate 15% of our profits to fund scholarships for kids in Guatemala to attend private school. You will also find us donating profits to different causes that we feel are important to the collective good. These include but are not limited to Together Rising, The ACLU, and various animal welfare programs.
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Sandra Bullock talks about her most recent Netflix original 'Bird Box' which is breaking the internet with its immense viewership.
Actress Sandra Bullocks in an interview talked about her latest film. 'Bird Box' is a Netflix original. She played the role of a single mother. Many critics appraised her acting.
In an interview with Bloody Disgusting, the actress talked about a deleted scene from the movie. She explained what the creature from Bird Box looked like.
"It was a snake-like, and I was like, 'I don't want to see it when it first happens. Just bring it into the room. We'll shoot the scene' I turn and he is like this [growling at me]. It's making me laugh. It was just a long fat baby."
Director Susanne Bier also explained why the creature was never shown. "It so easily becomes funny. We actually shot that and spent a lot of energy on, but every time I saw it, I was like this is not going to be intense."
'Bird Box' broke all the Netflix records. Over 45 million accounts watched the film in seven days. Netflix made their numbers public for the first time. 45,037, 125 accounts watched the film to be exact.
'Bird Box' was a thriller which revolves around Sandra Bullock's character. A creature which made people take their own lives brought the end of the world. The film is about her struggles to survive the creature while being blindfolded.
Netflix has sparked a huge debate in the industry. These numbers were vague in terms of demographics. It is still not confirmed if all 45 million accounts watched the whole film from start till the end.
We pay for videos too. Click here to upload yours.
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Helianthe Hat by Circé Belles Boucles
patterns > Circé aux Belles Boucles
> Helianthe Hat
Helianthe Hat
This pattern is available for €4.50 EUR buy it now
In this original hat, the ribbing raises through the bobbles to shape the hat.
For me you get a sunflower, but some see a lot of little flowers, a cupcake with blueberries or an urchin skeleton!
This hat is really easy and quick to knit.
One size fits every woman's head.
Un bonnet original qui vous donnera un motif de tournesol, d'oursin ou de cupcake… selon votre imagination.
About this pattern
70 projects, in 93 queues
overall rating of 4.6 from 31 votes
average difficulty from 32 ratings
About this yarn
by Cascade Yarns ®
100% Wool
220 yards / 100 grams
169040 projects
stashed 92662 times
rating of 4.5 from 20343 votes
More from Circé Belles Boucles
613 ratings
2156 projects
25 ratings
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23 ratings
65 projects
- Page created: February 6, 2010
- Last updated: August 22, 2015 …
- visits in the last 24 hours
- visitors right now


text:
Gamification applications have been presented to the market in the recent years in order to increase user engagement. These applications can target not only customers to boost loyalty but also employee engagement and in some eLearning tools. Channel partners that offer solutions like CRM or Learning Management Systems can upsell their customers by offer complementary products.
Below is a list of the best gamification & loyalty channel partners like resellers, VARs, consultants etc. that either offer such tools currently or are looking to partner with a new vendor to add more products to their portfolio.
Web design & development, digital marketing. Professional hosting services.
We are a small web design, advertising and animation studio looking to provide more useful products and services to our clients.
IT Services for SMB .
Check our profile for more details.
IniTech is an innovative software company that develops digital products for startups and online businesses. We are experts at understanding the client's vision and needs, be it in app/web development and/or UX/UI design. We know how to listen, analy...
Empresa de serviços profissionais de referência no mercado das tecnologias na aprendizagem.
Oups, we are sorry but there are no description data for this company.
Engage48 is digital technology agency and represent tech brands in sales and marketing for B2B audience
G-Cube offers elearning software solutions, learning management systems for companies worldwide.
Creating quality custom elearning since 1998. WHERE OUR CUSTOMeLEARNING EXCELS: Healthcare and Life Sciences Business Skills and
Microsoft Dynamics CRM and ERP Experts - Tisski
Somos una empresa de soluciones elearning con base en Madrid, los mejores contenidos elearning SCORM con Articulate Storyline y plataformas LMS Moodle
Designing Digitally, Inc., an award-winning company, for interactive eLearning, Serious Games, Training Simulations, Mobile Learning, and corporate training.
ELM is a leading eLearning company offering custom eLearning solutions in design & development. Learn more about eLearning Mind and what we have to offer.
PulseLearning provides custom learning solutions. Our eLearning development services enables Clients to reduce training costs & improve productivity.
Emmersive Infotech offers Custom eLearning, LMS, Web & Mobile Technology Solutions globally for better Performance through improved Learning.
Technology-enabled learning solutions with custom user and manager-optimized experiences.
In Singapore, Alphanova is a leader in Market Expansion, Digital Marketing and IT services from simple e-commerce websites to extensive IT solutions.
Working with #organizations 2 build a #culture of continuous learning that enables #measurable #returns on #education & #training.
Reward Process est la première plateforme digital d'animation et gestion des challenges et incentives. Augmentez votre CA en motivant vos employés !
Fremen Corp est un studio de développement et un réseau d'experts, en digital learning, gamification, serious games et conception UX innovante.
french 'n' fresh : Agence experte en Ergonomie, UX et UI, la seule spécialisée en gamification
Oeil pour Oeil accompagne ses clients dans la stratégie et la mise en œuvre de dispositifs de gamification, serious games, advergames et social games
We help you to match your business challenges with digital solution.
Home to exquisite business simulations. Lovingly made in Switzerland. Delivered worldwide. Ed: Dr. Gudrun G. Vogt #strategy #leadership #L&D #simulation
EA is an innovation and expertise center. Our actor-centric approach focuses on setting the right conditions enabling people to act.
Ekstra Reality is a new breed of digital agency uniquely designed to help business leaders succeed in a new digital economy.
As one of the first IT companies, originally founded in 1982, we have developed several software solutions. We are specialised in: Bookkeeping systems (ERP), 3th party logistics and Warehouse Management Software (WMS), e-Learning Management Software ...
WIDE Services company (www.wideservices.gr - Web Innovation and E-Learning Services) is based in Athens, Greece and provides a wide range of services in the field of e-learning. Company is certified with ISO 9001:2015 and ISO 27001:2013 at the field ...
BlueRunner Solutions will - Increase operational efficiency, Drive revenue and Imprve brand loyalty. Decrease time to serve through Pre-Order and POS with automated loyalty redemption. Increase order frequency & order value by increasing capacity and...
We implement a unique and fully integrated turnkey solution for each client, designed to optimize learning, success is achieved and learners are learning.
???????? ??? ????????????? ?????? ???? ????? ?? ??????????, ???????? ? ????????? ??????, ?????????? ? ???????? ???????? ????????, ?????????? ??????????? (seo), ???????????, ????????? (retention) ? ???????? ???????, big data, ????????? ????????? ? ???...
Specialists in e-commerce solutions, building mobile and loyalty apps, bespoke web development, CRM and data analytics.
Public Relations + Events + Digital Communications Website: http://lexingtonpr.com/ Email: firstname.lastname@example.com
Flightpath is a creative digital agency headquartered in NYC. We discover and mine emotional currency to create real business value for clients.
Word of Mouth has Changed Marketing is all about building your online brand presence. What does this mean to your spa/group practice, salon or solo practice?
MyESalon is the leader in website design and marketing for beauty salons. MyESalon systems will help you attract new clients and simplify your business.
Turning Technologies creates leading instructional, assessment delivery and data collection solutions for learning environments.
MLink is a custom content, interactive learning solutions provider to global companies, designing & developing innovative learning experiences to improve performance. Since 1990, our solutions in eLearning, mobile learning, knowledge technology, perf...
SPS y Neurika (fundadas en 1995 y 2002 respectivamente) son dos empresas afines, que ofrecen servicios de consultoría y tecnología orientados a proveer soluciones de valor para la gestión, el aprendizaje, la comunicación y colaboración.
Algunos de nuestros clientes son: Adif, Exeltis, Iberdrola, Laboral, Sanofi, Santander, MA. multiasistencia, Groupalia, Qurius, Vass, Gas Natural fenosa, Repsol, Kide, La Caixa, BBVA, MAPRFE, Kutxabank, NOVARTIS,GRUNENTHAL, Telefonica, ONO, BT, ALTAD...
Cloud Network Solutions Providers Global Contact Center and Unified Communications Solutions based on industry leading API's customer built for multiple verticals.
??????????????????????????????????????????·??·????????·??????????? ??????? ?????????Quality & Agility(???????)?????????????????????????
LOYALIST kan hjälpa till med det mesta inom CRM-strategi & taktik, lojalitetsprogram, kundrelationer, kommunikation och kundvård.
Abalon levererar lojalitetsprogrammet abalon relevate och analysverktyget
abalon analytics.
This list is not an official eFront resellers list nor is affiliated with or in any way associated with Epignosis.


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Gregory Beale
1949 -
country of citizenship:
United States of America
language of expression: English
educated at: University of Cambridge, Southern Methodist University, Dallas Theological Seminary
occupation: theologian
Gregory K. Beale (born 1949 in Dallas, Texas) (also known as G. K. Beale) is a biblical scholar, currently a Professor of New Testament and Biblical Theology at Westminster Theological Seminary. He is an ordained minister in the Orthodox Presbyterian Church. He has made a number of contributions to conservative biblical hermeneutics, particularly in the area of the use of the Old Testament in the New Testament. He served as the president of the Evangelical Theological Society in 2004. In 2013, he was elected by Westminster Theological Seminary to be the first occupant of the J. Gresham Machen Chair of New Testament. At his inauguration he delivered an address titled The Cognitive Peripheral Vision of Biblical Writers.
Read more or edit on Wikipedia
Commentary on the New Testament Use of the Old Testament
book by Gregory Bealewd:Q5152390
Gregory Beale, D. A. Carson


text:
Annual Conference & Awards 2018
Pensions out of the Box
Seeking innovative solutions to the issues facing the Dutch pensions industry.
6 June 2018
Beurs van Berlage, Amsterdam
Please note that this is a draft programme and therefore subject to change.
Workshop (For pension funds only)
10:45-11:30 Workshop Investing for the Future: The Energy Transition
Investors can help accelerate the shift to a low-carbon economy, financing the clean technologies which are making rapid progress every day, and develop innovative new products. But in order for companies to withstand and benefit from the on-going energy transition, we believe that consequential company engagement is imperative.
Speaker: Meryam Omi, Head of Sustainability and Responsible Investment Strategy, Legal & General Investment Management
From 11:30 Registration and lunch
Plenary Session
12:20 Welcome by Pensioen Pro editor in chief,Mariska van der Westen and introduction of event host Greg Shapiro
12:25-12:55 Presentation Thinking out of the Box: Innovation in Pensions
How can the pensions sector break the impasse and come up with creative solutions to the challenges facing pension provision in The Netherlands? EJ Lugt, nicknamed 'the Dutch Mark Zuckerberg' shares his insights.
Speaker: Evert Jaap Lugt, Innovation Management expert and Managing Director at tech incubator YES!Delft
12:55-13:20 Presentation Looking across the Border
Thinking out of the box also means: looking beyond the borders. The Netherlands is not the only country struggling to future-proof its pension provision; what can we learn from other countries?
Speaker: Stefan Lundbergh, Director Cardano Insights and non-executive board member of the Fourth Swedish National Pension
Fund AP4
13:20-13:55 Panel Political Panel Debate
As social partners struggle to reach consensus on the way forward, politicians debate whether – and how – to take action. Where do SER talks stand and what should the role of politics be in the next few months?
Moderated by Bibi de Vries, Head of Benelux, Willis Towers Watson
With among others panel members: Robin Fransman, Head of Financial Sector, Argumentenfabriek; Gijs van Dijk, Labour MP (to be
confirmed); Peter Verhaar, among others board member at Brightpensioen, advisory role at APG en SVB
13:55-14:15 Presentation Innovation in Practice
While the debate about the system overhaul continues, innovative solutions are already being developed. from sophisticated lifecycle investments to smart pension solutions. A look at the latest innovations and their practical implications.
Speaker: Gerard Roelofs, Director Client Solutions, Kempen Capital Management
Breakout Sessions
- Stream A: PensionTech & Blockchain
With among other speakers: Boris Spremo, Operations Director of Emerging Business & Architecture, BNY Mellon, Otto Hulst,
Innovation Lead, Kas Bank, Hidde Terpoorten, Blockchain Lead, APG
- Stream B: ESG from evolution and integration to implementation: sustainable investing 'IRL'
With speakers from: Mitch Reznick, Hermes Investment Management, Pieter Furnée, Global
Head of Responsible Investing, Head of Benelux, DWS, and Niamh Whooley, ESG Engagement Analyst, Pimco
- Stream C: Innovation: From here, to China
With speakers: Mark Tinker, Head of Framlington Equities Asia & Aidan Yao, Senior Economist - China, AXA Investment
Managers, Bryan Collins, Head of Asian Fixed Income, Fidelity, Daan Tettero, Concept Ontwikkelaar Zorgvastgoed, Syntrus
Achmea Real Estate & Finance
Plenary Session (Continued)
15:50-16:15 Refreshment Break
16:15-16:35 Interview A New Look at Tomorrow
How does the country's largest pension manager harness its innovative and creative power to tackle the problems facing Dutch pension funds and plan participants? APG shares some of its deepest concerns and brightest ideas.
Greg Shapiro speaks with Gerard van Olphen, ceo of APG
16:35-16:55 Presentation The Future of Responsible Investing
What are the trends in Responsible Investing, where is the market headed and what is the role of innovation in this field?
Speaker: Gareth Davies, Head of Responsible Investment Solutions Columbia Threadneedle
16:55-17:25 Joint Interview Champions of Innovation
Regulators have an important role in policing new and disruptive technologies, but they also serve as champions of innovation. How do AFM and DNB view innovation in the pensions sector – is the industry doing enough to innovate and nurture creative thinking?
A joint interview with: Jan Boerboom, acting Head of Suprervisory Department Insurance and Pensions Toezicht Verzekeren en
Pensioenen, AFM en Arnoud Vossen, Departmental Director Supervision Large Pension Funds, DNB
17:25-17:45 Closing Address Taking the Next Step
Speakers: Angela Peters, Bestuurslid Centraal Beheer Algemeen Pensioenfonds; Eveline Smeets, Head of Atuarial at Shell
Pensioenbureau Nederland and two pension fund board members
Pensioenbureau Nederland and two pension fund board members
17:45 – 18:30 Guided Tour of World Press Photo Exhibition
In De Nieuwe Kerk, Amsterdam
18:30-19:15 Drinks Reception at the Beurs van Berlage
>>> Evening programme: Pensioen Pro Awards Dinner
Main Sponsor Conference & Awards:
Sponsors Conference:
Miriana Stamenkovic
International Account Manager Sales & Events


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Slovenia will elect 8 MEPs using the party list PR system. The candidates fight nationally.
Country statistics:
Population: 2.050.000
GDP/capita: 82 (EU28 = 100)
Growth (2012): -2.3
Unemployment: 11.2
2014 Election
Positive Slovenia may be ruling the country but is facing increasing challenges. Prime Minister Alenka Bratusek, the country's first female premier and the leader of Pozitivna Slovenija (Positive Slovenia), only took office in late March 2013. Bratusek only b...
This story is part of New Europe's Premium content.
|To Read the Full Story, Subscribe or Sign In from the ↑ Top of the Page ↑


text:
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text:
Lindsay Mitchell
Canada - the host of the just-concluded third round of talks on the North American Free Trade Agreement (NAFTA) - is a top trading partner for U.S. feed grains and co-products like ethanol and distiller's dried grains with solubles (DDGS) thanks to geography and strong trade policy.
Economically and technologically, Canada and the United States developed in parallel across the world's longest international border. Following its implementation, NAFTA's terms dramatically increased trade and economic integration between the two countries, with Canadian livestock producers able to access U.S. feed grains and co-products competitively due to close proximity to northern U.S. ethanol plants as well as the efficiency of transporting by rail or truck.
Since NAFTA entered into force in 1994, exports of corn in all forms to Canada have increased 2.5 times, including a six-fold increase in corn exports, an almost 10-fold increase for DDGS and corn gluten feed/meal and a 90-fold increase for ethanol.
Canada currently ranks as the seventh largest market for U.S. DDGS this marketing year with more than 607,000 tons of U.S. DDGS purchased (Sept. 2016-July 2017), a 20 percent increase year-over-year.
And Canada imports close to 20 percent of its domestic fuel ethanol, nearly all of it from the United States. As a result, Canada has consistently ranked as a top importer of U.S. ethanol, coming in as the second largest buyer in 2016/2017. U.S. ethanol imports of 301 million gallons (2.73 million tons or 107.5 million bushels in corn equivalent) thus far this marketing year are up eight percent compared to the same period the year prior.
Learn about the U.S. Grains Council's work in Canada here.
You won't want to miss this important feature on what's coming in the future of the American ethanol industry.Learn More
The 2018 ICGA annual report highlights a myriad of positive action on behalf of corn farmers in Illinois. Check it out and let us know what else we should be working on!Learn More
A recent analysis by the U.S. Grains Council (USGC) shows non-beverage ethanol has been the fastest growing U.S. agricultural export over the past decade by a significant margin.Learn More


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