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Spin isomers of hydrogen
Molecular hydrogen occurs in two isomeric forms, one with its two proton nuclear spins aligned parallel (orthohydrogen), the other with its two proton spins aligned antiparallel (parahydrogen).[1] These two forms are often referred to as spin isomers.[2]
Parahydrogen is in a lower energy state than is orthohydrogen. At room temperature and thermal equilibrium, thermal excitation causes hydrogen to consist of approximately 75% orthohydrogen and 25% parahydrogen. When hydrogen is liquified at low temperature, there is a slow spontaneous transition to a predominantly para ratio, with the released energy having implications for storage. Essentially pure parahydrogen form can be obtained at very low temperatures, but it is not possible to obtain a sample containing more than 75% orthohydrogen by heating.
A mixture or 50:50 mixture of ortho- and parahydrogen can be made in the laboratory by passing it over an iron(III) oxide catalyst at liquid nitrogen temperature (77 K)[3] or by storing hydrogen at 77 K for 2–3 hours in the presence of activated charcoal.[4] In the absence of a catalyst, gas phase parahydrogen takes days to relax to normal hydrogen at room temperature while it takes hours to do so in organic solvents.[4]
Nuclear spin states of H2Edit
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Each hydrogen molecule (H2) consists of two hydrogen atoms linked by a covalent bond. If we neglect the small proportion of deuterium and tritium which may be present, each hydrogen atom consists of one proton and one electron. Each proton has an associated magnetic moment, which is associated with the proton's spin of ½. In the H2 molecule, the spins of the two hydrogen nuclei (protons) couple to form a triplet state known as orthohydrogen, and a singlet state known as parahydrogen.
The triplet orthohydrogen state has total nuclear spin I = 1 so that the component along a defined axis can have the three values MI = 1, 0, or −1. The corresponding nuclear spin wavefunctions are , and . This uses standard bra–ket notation; the symbol ↑ represents the spin-up wavefunction and the symbol ↓ the spin-down wavefunction, so ↑↓ means that the first nucleus is up and the second down. Each orthohydrogen energy level then has a (nuclear) spin degeneracy of three, meaning that it corresponds to three states of the same energy (in the absence of a magnetic field).[1] The singlet parahydrogen state has nuclear spin quantum numbers I = 0 and MI = 0, with wavefunction . Since there is only one possibility, each parahydrogen level has a spin degeneracy of one and is said to be non-degenerate.[1]
Allowed rotational energy levelsEdit
Since protons have spin ½, they are fermions and the permutational antisymmetry of the total H2 wavefunction imposes restrictions on the possible rotational states the two forms of H2.[1] Orthohydrogen, with symmetric nuclear spin functions, can only have rotational wavefunctions that are antisymmetric with respect to permutation of the two protons, corresponding to odd values of the rotational quantum number J; conversely, parahydrogen with an antisymmetric nuclear spin function, can only have rotational wavefunctions that are symmetric with respect to permutation of the two protons, corresponding to even J.[1]
The para form whose lowest level is J = 0 is more stable by 1.06 kJ/mol[5] than the ortho form whose lowest level is J = 1. The ratio between numbers of ortho and para molecules is about 3:1 at standard temperature where many rotational energy levels are populated, favoring the ortho form as a result of thermal energy. However at low temperatures only the J = 0 level is appreciably populated, so that the para form dominates at low temperatures (approx. 99.8% at 20 K).[6] The heat of vaporization is only 0.904 kJ/mol. As a result,[5] ortho liquid hydrogen equilibrating to the para form releases enough energy to cause significant loss by boiling.
Thermal propertiesEdit
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Applying the rigid rotor approximation, the energies and degeneracies of the rotational states are given by:[7][page needed]
- .
The rotational partition function is conventionally written as:[citation needed]
- .
However, as long as the two spin isomers are not in equilibrium, it is more useful to write separate partition functions for each:[citation needed]
The factor of 3 in the partition function for orthohydrogen accounts for the spin degeneracy associated with the +1 spin state; when equilibrium between the spin isomers is possible, then a general partition function incorporating this degeneracy difference can be written as:[citation needed]
The molar rotational energies and heat capacities are derived for any of these cases from:[citation needed]
Plots shown here are molar rotational energies and heat capacities for ortho- and parahydrogen, and the "normal" ortho/para (3:1) and equilibrium mixtures:[citation needed]
Because of the antisymmetry-imposed restriction on possible rotational states, orthohydrogen has residual rotational energy at low temperature wherein nearly all the molecules are in the J = 1 state (molecules in the symmetric spin-triplet state cannot fall into the lowest, symmetric rotational state) and possesses nuclear-spin entropy due to the triplet state's threefold degeneracy.[citation needed] The residual energy is significant because the rotational energy levels are relatively widely spaced in H2; the gap between the first two levels when expressed in temperature units is twice the characteristic rotational temperature for H2:[citation needed]
- .
This is the T = 0 intercept seen in the molar energy of orthohydrogen. Since "normal" room-temperature hydrogen is a 3:1 ortho:para mixture, its molar residual rotational energy at low temperature is (3/4) × 2Rθrot ≈ 1091 J/mol,[citation needed] which is somewhat larger than the enthalpy of vaporization of normal hydrogen, 904 J/mol at the boiling point, Tb ≈ 20.369 K.[8] Notably, the boiling points of parahydrogen and normal (3:1) hydrogen are nearly equal; for parahydrogen ∆Hvap ≈ 898 J/mol at Tb ≈ 20.277 K, and it follows that nearly all the residual rotational energy of orthohydrogen is retained in the liquid state.[citation needed]
However, orthohydrogen is thermodynamically unstable at low temperatures and spontaneously converts into parahydrogen.[9] This process lacks any natural de-excitation radiation mode, so it is slow in the absence of a catalyst which can facilitate interconversion of the singlet and triplet spin states.[10] At room temperature, hydrogen contains 75% orthohydrogen, a proportion which the liquefaction process preserves if carried out in the absence of a catalyst like ferric oxide, activated carbon, platinized asbestos, rare earth metals, uranium compounds, chromic oxide, or some nickel compounds to accelerate the conversion of the liquid hydrogen into parahydrogen. Alternatively, additional refrigeration equipment can be used to slowly absorb the heat that the orthohydrogen fraction will (more slowly) release as it spontaneously converts into parahydrogen.[citation needed] If orthohydrogen is not removed from rapidly liquified hydrogen, without a catalyst, the heat released during its decay can boil off as much as 50% of the original liquid.
The unusual heat capacity of hydrogen was discovered in 1912 by Arnold Eucken.[11] The two forms of molecular hydrogen were first proposed by Werner Heisenberg and Friedrich Hund in 1927. Taking into account this theoretical framework, pure parahydrogen was first synthesized by Paul Harteck and Karl Friedrich Bonhoeffer in 1929.[12] When Heisenberg was awarded the 1932 Nobel prize in physics for the creation of quantum mechanics, this discovery of the "allotropic forms of hydrogen" was singled out as its most noteworthy application.[13] Modern isolation of pure parahydrogen has since been achieved using rapid in-vacuum deposition of millimeters thick solid parahydrogen (p–H2) samples which are notable for their excellent optical qualities.[14]
Use in NMREdit
When an excess of parahydrogen is used during hydrogenation reactions (instead of the normal mixture of orthohydrogen to parahydrogen of 3:1), the resultant product exhibits hyperpolarized signals in proton NMR spectra, an effect termed PHIP (Parahydrogen Induced Polarisation) or, equivalently, PASADENA (Parahydrogen And Synthesis Allow Dramatically Enhanced Nuclear Alignment; named for first recognition of the effect by Bowers and Weitekamp of Caltech),[15][citation needed] a phenomenon that has been used to study the mechanism of hydrogenation reactions.[16][17]
Signal amplification by reversible exchange (SABRE) is a technique to hyperpolarize samples without chemically modifying them. Compared to orthohydrogen or organic molecules, a much greater fraction of the hydrogen nuclei in parahydrogen align with an applied magnetic field. In SABRE, a metal center reversibly binds to both the test molecule and a parahydrogen molecule facilitating the target molecule to pick up the polarization of the parahydrogen.[18] This technique can be improved and utilized for a wide range of organic molecules by using an intermediate "relay" molecule like ammonia. The ammonia efficiently binds to the metal center and picks up the polarization from the parahydrogen. The ammonia then transfers it other molecules that don't bind as well to the metal catalyst.[19] This enhanced NMR signal allows the rapid analysis of very small amounts of material.
Diatomic deuterium (D2) has nuclear spin isomers like diatomic hydrogen, but with different populations of the two forms because the deuterium nucleus (deuteron) is a boson with nuclear spin equal to one.[20] There are six possible nuclear spin wave functions which are ortho or symmetric to exchange of the two nuclei, and three which are para or antisymmetric.[20] Ortho states correspond to even rotational levels with symmetric rotational functions so that the total wavefunction is symmetric as required for the exchange of two bosons, and para states correspond to odd rotational levels.[20] The ground state (J = 0) populated at low temperature is ortho, and at standard temperature the ortho:para ratio is 2:1.[20]
Other substances with spin isomersEdit
Other molecules and functional groups containing two hydrogen atoms, such as water and methylene, also have ortho- and para- forms (e.g. orthowater and parawater), but this is of little significance for their thermal properties.[21] Their ortho-para ratios differ from that of dihydrogen.
Molecular oxygen (O
2) also exists in three lower-energy triplet states and one singlet state, as ground-state paramagnetic triplet oxygen and energized highly reactive diamagnetic singlet oxygen. These states arise from the spins of their unpaired electrons, not their protons or nuclei.
- ^ a b c d e P. Atkins and J. de Paula, Atkins' Physical Chemistry, 8th edition (W.H.Freeman 2006), p. 451–2 ISBN 0-7167-8759-8
- ^ Matthews, M.J.; Petitpas, G.; Aceves, S.M. (2011). "A study of spin isomer conversion kinetics in supercritical fluid hydrogen for cryogenic fuel storage technologies". Appl. Phys. Lett. 99 (8): 081906. Bibcode:2011ApPhL..99h1906M. doi:10.1063/1.3628453.
- ^ Matsumoto, Mitsuru; Espenson, James H. (2005). "Kinetics of the Interconversion of Parahydrogen and Orthohydrogen Catalyzed by Paramagnetic Complex Ions". Journal of the American Chemical Society. 127 (32): 11447–11453. doi:10.1021/ja0524292. ISSN 0002-7863. PMID 16089474.
- ^ a b Aroulanda, Christie; Starovoytova, Larisa; Canet, Daniel (2007). "Longitudinal Nuclear Spin Relaxation ofOrtho- andPara-Hydrogen Dissolved in Organic Solvents". The Journal of Physical Chemistry A. 111 (42): 10615–10624. Bibcode:2007JPCA..11110615A. doi:10.1021/jp073162r. ISSN 1089-5639. PMID 17914761.
- ^ a b "Liquefaction of "Permanent" Gases" (PDF of lecture notes). 2011. Retrieved 2017-10-16.
- ^ Rock, Peter A., Chemical thermodynamics; principles and applications (Macmillan 1969) Table p.478 shows (No/Np)H2 = 0.002 at 20 K ISBN 1-891389-32-7
- ^ F. T. Wall (1974). Chemical Thermodynamics, 3rd Edition. W. H. Freeman and Company
- ^ "Thermophysical Properties of Fluid Systems". Webbook.nist.gov. Retrieved 2015-05-14.
- ^ Milenko, Yu. Ya.; Sibileva, R. M.; Strzhemechny, M. A. (1997-04-01). "Natural ortho-para conversion rate in liquid and gaseous hydrogen". Journal of Low Temperature Physics. 107 (1): 77–92. doi:10.1007/BF02396837. ISSN 1573-7357.
- ^ Milenko, Yu. Ya.; Sibileva, R. M.; Strzhemechny, M. A. (1997-04-01). "Natural ortho-para conversion rate in liquid and gaseous hydrogen". Journal of Low Temperature Physics. 107 (1): 77–92. doi:10.1007/BF02396837. ISSN 1573-7357.
- ^ A. Eucken, "Die Molekularwärme des Wasserstoffs bei tiefen Temperaturen." Königlich Preußische Akademie der Wissenschaften (Berlin). Sitzungsberichte (1912): S. 141–151
- ^ Michael Polanyi and His Generation: Origins of the Social Construction of Science Mary Jo Nye, University of Chicago Press (2011) p.119 ISBN 0-226-61065-9
- ^ Werner Heisenberg – Facts Nobelprize.org
- ^ https://web.archive.org/web/20120831182954/http://www.stormingmedia.us/72/7208/A720893.html
- ^ Bowers, C. R.; Weitekamp, D. P. (1986). "Transformation of symmetrization order to nuclear-spin magnetization by chemical reaction and nuclear magnetic resonance" (PDF). Physical Review Letters. 57 (21): 2645–2648. Bibcode:1986PhRvL..57.2645B. doi:10.1103/physrevlett.57.2645. PMID 10033824.
- ^ Duckett, S. B.; Mewis (2013). Improving NMR and MRI Sensitivity With Parahydrogen. Top. Curr. Chem. Topics in Current Chemistry. 338. pp. 75–103. doi:10.1007/128_2012_388. ISBN 978-3-642-39727-1. PMID 23138689.
- ^ Adams, R. W.; Aguilar, J. A.; Atkinson, K. D.; Cowley, M. J.; Elliott, P. I.; Duckett, S. B.; Green, G. G.; Khazal, I. G.; López-Serrano, J; Williamson, D. C. (2009). "Reversible interactions with para-hydrogen enhance NMR sensitivity by polarization transfer" (PDF). Science. 323 (5922): 1708–11. Bibcode:2009Sci...323.1708A. doi:10.1126/science.1168877. PMID 19325111.
- ^ Eshuis, Nan; Aspers, Ruud L.E.G.; van Weerdenburg, Bram J.A.; Feiters, Martin C.; Rutjes, Floris P.J.T.; Wijmenga, Sybren S.; Tessari, Marco (2016). "Determination of long-range scalar 1 H– 1 H coupling constants responsible for polarization transfer in SABRE". Journal of Magnetic Resonance. 265: 59–66. Bibcode:2016JMagR.265...59E. doi:10.1016/j.jmr.2016.01.012. ISSN 1090-7807. PMID 26859865.
- ^ Iali, Wissam; Rayner, Peter J.; Duckett, Simon B. (2018). "Using para hydrogen to hyperpolarize amines, amides, carboxylic acids, alcohols, phosphates, and carbonates". Science Advances. 4 (1): eaao6250. Bibcode:2018SciA....4O6250I. doi:10.1126/sciadv.aao6250. ISSN 2375-2548. PMC 5756661. PMID 29326984.
- ^ a b c d Hollas, J. Michael (1996). Modern Spectroscopy (3rd ed.). John Wiley and Sons. p. 115. ISBN 0-471-96523-5.
- ^ Shinitzky, Meir; Elitzur, Avshalom C. (2006). "Ortho-para spin isomers of the protons in the methylene group". Chirality. 18 (9): 754–756. doi:10.1002/chir.20319. PMID 16856167.
Further readingEdit
- Aline Léon, Ed. 2008, Hydrogen Technology: Mobile and Portable Applications, pp. 93–101, New York, NY:Springer Science & Business, ISBN 3-540-69925-2, see [1], accessed 10 May 2015.
- Tikhonov V. I., Volkov A. A. (2002). "Separation of water into its ortho and para isomers". Science. 296 (5577): 2363. doi:10.1126/science.1069513. PMID 12089435.
- Mario E. Fajardo; Simon Tam (1997). Rapid Vapor Deposition of Millimeters Thick Optically Transparent Solid Parahydrogen Samples for Matrix Isolation Spectroscopy. Edwards AFB (Propulsion Directorate West):USAF Research Lab.[page needed]
- Bowers, C. R.; Weitekamp, D. P. (1986). "Transformation of symmetrization order to nuclear-spin magnetization by chemical reaction and nuclear magnetic resonance" (PDF). Phys. Rev. Lett. 57 (21): 2645–2648. Bibcode:1986PhRvL..57.2645B. doi:10.1103/physrevlett.57.2645. PMID 10033824.
- A. Farkas (1935). Orthohydrogen, parahydrogen and heavy hydrogen. The Cambridge series of physical chemistry. Cambridge, U.K.:CUP.[page needed]
- Bonhoeffer KF, Harteck P (1929). "Para- and ortho hydrogen". Zeitschrift für Physikalische Chemie B. 4 (1–2): 113–141.
- Oxford Instruments, Date Unknown, "Boosting the Sensitivity of NMR Spectroscopy using Parahydrogen"


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2016 Nissan Sentra for Sale near Long Island, NY
Blending fuel efficiency with sophisticated style and supreme innovation is the forward-thinking 2016 Nissan Sentra for sale near Long Island, NY. This is not an ordinary sedan, as it hosts a variety of the latest driver-assist systems, and looks sharp from every angle. Take the Sentra out for a spin to see just what it has to offer at Legend Auto Group today!
Staying safe on the road is your number one priority and it's also on top of the list of significance at Nissan. You'll find high-tech features like the RearView Monitor1 that assists you with backing out of your driveway and reversing out of parking spots with ease. With the Tire Pressure Monitoring System (TPMS) with Easy-Fill Tire Alert2, you can stay up-to-date with the condition of your tires without having to go outside and check them. And when it's time to fill them up with air, this system will let you know when you have reached the right pressure point for your convenience. No matter what kind of emergency you find yourself in, you can count on the six standard airbags3 to keep you from harm's way.
Effortlessly making a statement wherever it goes is the stylish 2016 Nissan Sentra for sale near Long Island, NY. Whether you're dropping off the kids at school, headed to the West Hampton Dunes, or on your way to Newark Liberty International Airport to catch your flight, you're bound to have onlookers stop and stare when you're behind the wheel of the Nissan Sentra. The standard 16-inch steel wheels provide a smooth and steady ride, while the graceful side lines enhance the Nissan Sentra's aerodynamic abilities. The Smart Auto Headlights also are featured on the Sentra's base trim, so you can see clearly, and for an extra edge, add the available sport rear fascia and rear spoiler.
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Saturday, April 27
Friends meeting is open to all members of the group.
After the meeting, the Friends of the Library will host a historical presentation of President Theodore Roosevelt at 2:00 pm.
Open to the public, Ted Dudra will present a first-person portrayal of the 26th president of the United States.
Dudra is a retired teacher from the Plain Local School System and does first person impressions of other notable historical figures including Alvin C. Voris and Lewis Miller. No registration is required for this program.
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Saturday, April 27, 2019 - 1:00pm to 4:00pm


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Thanks to our 2020 business sponsors:
Brookside B&B, Bruce Feml, Claude W. Lutz, Elena Suditu Dentist, P.C., Ethel & Orville Slutzky Family Foundation, Fred's Photography, Gordon Hunter Mountain Realty, Haines Falls Auto/Hunter Towing, Highmark Builders, Kaaterskill Liquors, Pancho Villas Mexican Restaurant, Pure Mountain Yoga, Rosehaven Inn, Highmark Builders, The Mansion House at Alfie's, Thorpe Contracting Inc., Thorpe GMC Inc., Traphagen's Honey
The links below will open a new window. Use your browser's back arrow to return to MTHS
2020 MTHS Business Sponsors
Brookside Bed & Breakfast
Ethel & Orville Slutzky Foundation
Gordon Hunter Mountain Realty
Haines Falls Auto/Hunter Towing
Kaaterskill Liquors
Karen's County Kitchen
Pancho Villa's Restaurant
Pure Mountain Yoga
The Mansion House at Alfie's
Thorpe Contracting Inc.
Thorpe GMC Inc.
Traphagen's Honey
Tryon Family Foundation
To our hikers:
The 2017 hiking schedule can be found at: http://mths.org/hikes.html or by selecting the Hikes link under the Interpret section in the side menus. As always, hikes are subject to change. Please check this site just prior to the date of any scheduled hike.
Thanks to the Kaaterskill Rail Trail Facebook Page for posting this notice.
Please everyone stay on the marked trail, do not cut across the private land to access the trail from MTHS. Please follow Trail up North Lake Road to Featherbed down to the rail trail.
The last section is in the process of being acquired by the Mountain Top Historical Society however it is still PRIVATE LAND, please respect the private land owners and their property.
The grand opening for the new final section connecting Kaaterskill Falls with the MTHS Campus will be opening on May 20th- more details to follow.
Thank you everyone for you help and cooperation in this matter.
Hikefest 2016
The Mountain Top Historical Society Presents Hikefest 3 as part of the Catskills Lark in the Park.
On Saturday, October 8, 2016 the Mountain Top Historical Society will be just the place to begin your Lark in the Park! This year we'll be offering a choice of five hikes.
Two longer, more challenging hikes will be meeting at the MTHS campus at 8:00 a.m.
Hike #1 Kaaterskill High Peak
Difficult: 7 miles, 2,500' ascent
Leaders: Tom and Anna Martone
A special Lark in the Park route to Kaaterskill High Peak from the north side. We'll see nice views to the Blackhead Range on our way up the north side to the summit of Kaaterskill High Peak. We'll take a short walk over to Hurricane Ledge to see awesome views of the Devil's Path peaks and the Hudson Valley before returning the way we came.
Hike #2 Three Waterfalls and Poet's Ledge
Difficult: 5.9 miles
Leaders: Jim Gebhard and Paul Martin
A special Lark in the Park route hiking the Long Path past three dramatic waterfalls: Buttermilk,Wildcat and Viola. A short out and back to an awesome view from Poet's Ledge before winding our way down to Palenville. Our special Lark in the Park route will ensure that gravity is our friend as we will be hiking downhill throughout most of the hike.
Two groups will be offered a more moderate hike and will be meeting at the MTHS campus at 9:00 a.m.
Hike #3 Kaaterskill Falls, Layman's Monument, Council Bluff and Sunset RockModerate to difficult 3 miles with an elevation change of 700 ft.
Leader: Bob Gildersleeve
A vigorous climb alongside one of the highest and most famous waterfalls in New York State followed by a wooded walk with views into Kaaterskill Clove.
Starting at the Molly Smith parking area on Route 23A, we will follow the trail past Bastion Falls and after a half mile walk to the base of Kaaterskill Falls climb the new 200-step stairway to the escarpment trail near the site of the Laurel House. Taking the blue-marked Escarpment Trail for approximately a half mile we will arrive at Layman's Monument erected to honor Frank Layman who perished in 1900 fighting a forest fire that threatened homes in Haines Falls and Twilight Park. From Layman's Monument we will continue uphill passing a fine lookout known in the 19th century as Council Bluff and on to other vistas into Kaaterskill Clove including one now called Sunset Rock and on to the original Sunset Rock, now often called Inspiration Point. With a little backtracking, we will arrive at an old carriage road and follow it back to the site of the Laurel House where we will have some cars waiting to take us back to the MTHS campus. Note that possible construction in the area of Kaaterskill Falls may require some modifications of this walk.
Bob Gildersleeve is an MTHS Board Member and the author of Catskill Mountain House Trail Guide. He is a frequent and knowledgeable hiking guide in this area.
Hike #4: This group will follow the same itinerary as Hike #3. Hike leader: Jeff Senterman.
For Hike #5 we have lined up an easy hike which will also meet at the MTHS campus at 9:00 a.m. The hike, led by Pete Senterman Will explore the area of Colgate Lake in East Jewett. It should be a great opportunity to enjoy and photograph the now peak Autumn leaves.
All of the hikers will meet at the MTHS campus in the KRT parking lot and car pool to the various trail heads for the hikes. The hikes are designed to return to the MTHS campus at around noon for lunch.
Lunch will be hamburgers and hot dogs on the grill with all the fixings including salads, cold drinks and dessert. Doug Senterman has graciously agreed to be our Grillmaster. The cost per person for lunch is $10, reservations required.
After lunch, at 1:30 p.m. in our U&D Train Station, Mike Callan of the DEC will present an update on the Kaaterskill Falls Projects. Hear the inside scoop on those great stone steps, the viewing platform and the bridge that is currently under construction.
We welcome hikers and those interested in hiking or in the beauty of the Catskill Park to join us for a hike, lunch, the presentation and good company as part of the 2016 Lark in the Park.
Events 2017
Mountain Top Historical Society 2017 Hike & Event Schedule
Check our website as the hikes & events that interest you approach.
See entry for May 20 for news on the Kaaterskill Rail Trail
May 6 (Sat) MTHS Clean-up Day The Mountain Top Historical Society will emerge from its annual winter hibernation into the sunlight of another exciting season of hikes, programs, and special events. Beginning at 9:00 a.m. we will be staging groups of willing workers around the Haines Falls campus to clear the cobwebs and clutter of winter. Please plan to join us. It is an opportunity for you to get to know more about the MTHS and to meet other community members who are involved in keeping things moving forward. A thorough cleaning needs to be done in the Visitors' Center, in the Train Station, and around the grounds. The more volunteers we have there, the quicker the chores will be completed. Check out the 2017 schedule of events on our website: www.mths.org and come out to help us prepare on May 6. Looking forward to seeing you then and throughout the summer.
May 20 (Sat) Spring Fling - Opening of the expanded Kaaterskill Rail Trail Hiking the Kaaterskill Rail Trail since it opened on June 1, 2013 has meant taking a detour from the MTHS parking lot out to Osborn Road to North Lake Road and then south on Featherbed Lane to re-join the KRT about ¾ mile from the Railroad Station.
Now, on Saturday, May 20, 2017, there will be another community celebration beginning at 10:30 a.m. This time we will mark the end of the detour and the opening of the missing link with a few speeches, a ribbon cutting, and a beautiful, delicious cake. Walkers and hikers will be able to enter the KRT along the old train route just east of the MTHS' historic Railroad Station. Read details here.
June 10 (Sat) Presentation by author/publisher Nick Lyons -- Reminiscing about the Laurel House, fishing in South Lake and Lake Creek and fly-fishing in the Catskills -- Nick Lyons is a well-known and well-respected Catskills fisherman. He began fishing during the summers he spent as a boy at the Laurel House which was owned by his grandfather Louis Bernstein and operated by his uncle and aunt Nathan and Sadie Bernstein between 1929 and 1953. 7:00 p.m. at U&D Train Station We had a very nice afternoon sharing with Nick the information that MTHS has about the Laurel House during the period from 1929 to 1953 when his family owned the property. Nick's evening presentation was exceptionally well received -- interesting, humorous, and warm. He brought his experiences at the Laurel House to life and gave us an appreciation of the sport of fly fishing.
July 14 (Fri) Presentation on Women's Suffrage – Johanna Titus - 7pm Twilight Park Clubhouse The Centennial of Women's Suffrage in New York: The Keystone of the Women's Rights Movement Join author and MTHS Board Member, Johanna Titus, for an historic prospective of the Women's Suffrage Movement. Beginning with Seneca Falls and defining an often chaotic trail, women's suffrage in New York was not successful until it became both local and inclusive. Many full and part-time residents of Greene County were vital to the effort of establishing not only women's suffrage in New York, but also the passage of the 19th Amendment, and advancement of Women's Rights. Some of those women are remembered and celebrated in this short discourse.
Aug. 18 (Fri) Historical Trivia Quiz by Paul Misko Enjoy learning some little known facts about local history as contestants match wits with each other and the host. Stay afterward for dessert and informal history chatter. 7 p.m. at the U&D Train Station
Aug. 26 (Sat)
Rip's Country Bazaar
Saturday August 26th
10 am to 5 pm
Mountain Top Historical Society Campus
Route 23A, Haines Falls
Fun for the Whole Family!
Live Music: 77th Regimental Balladeers
Food -- Open Archives
Ulster & Delaware Railroad Exhibit
Children's Activities
Sept. 16 (Sat) 6th Annual Postcard Show – 10 a.m. to 3p.m. @ the U&D Train Station. Food will be available. The MTHS will also be selling ephemera from its attic in a special sale. A $3.00 entry fee will be charged at the door.
Sept. 22 (Fri) Presentation by Carolyn Bennett – Pratt's Five Wives – 7 pm @ U&D Train Station. A unique look at the role of women and the struggle for women's suffrage from the Colonial period through the 19th century through the lives of Congressman Zadock Pratt Jr.'s five wives, Esther Dickerman, Beda Dickerman, Abigail Watson, Mary Watson and Susie Grimm. This is also the theme of the Zadock Pratt Museum's 2017 exhibit, which will contain quilts, period clothing & jewelry, kitchen and cleaning items, magazines, books, paintings, etc.
MTHS does not require membership for hike participation. We do however request that you register for each hike. Participants can register on our [http://www.mths.org/contact-mths.html contacts page] or by calling (518) 589-6657. Please leave your name, phone number, and # in your party. Schedule subject to change. The latest information is available on our web site [http://www.mths.org/undefined/ http://www.mths.org]. Notification of changes, including cancellations due to weather will be made on the web site up to the day of any given hike.
Buildings and Grounds Update
As we plan programs and hikes for the 2016 season, we are looking at a need for volunteers to help us keep our Haines Falls campus looking as pristine as it has looked for the past 20 year.
The Mountain Top Historical Society is looking for someone to serve as a co-chair of the building and grounds committee. This is a volunteer, working foreman position. One does not need to be an MTHS board member to fill this position. Board member, Nancy Allen, has already volunteered to be co-chair of this committee. She is interested in the groundskeeping tasks and is hoping to find someone to work with her as a regular inspector of our buildings and facilities with an eye toward maintaining the buildings and staying ahead of any problems.
Dick Haines, who has filled this position for many years, since we first acquired our Haines Falls home, has decided to hang up his lopping shears and turn over the keys to the John Deere. Dick has done an awesome job over the years, keeping the campus looking great and maintaining the buildings on a shoestring budget. He has offered to mentor the new chairpersons and help out as he is needed.
With Dick's help we have created a job description. There is a lot involved in keeping up the property, but we have been building a core group of volunteers who are available to help regularly. It is the job of the co-chairs to coordinate the volunteers and keep the board apprised of buildings and grounds needs.
In addition to looking for a co-chair to work with Nancy Allen, we are always looking for volunteers to help with the tasks of mowing, trimming, clearing sticks and branches.
If you can give a few hours a week or a few hours a month, we welcome the help.
To volunteer or if you'd like more information, please e-mail the director at from our contact page.
Thank you!
2017 Hike Schedule
Mountain Top Historical Society 2017 Hike Schedule
Check our website as the hikes & events that interest you approach.
Walk back in time on one of our popular hikes through the High Peaks of the Catskills. These were America's first hiking trails whose beauty was immortalized in the novels of James Fenimore Cooper and romanticized in the poetry of William Cullen Bryant. The breathtaking views seen along these trails today were first captured in the 19th century by the premiere artists of the Hudson River School of art, our country's uniquely American school of landscape painting.
MTHS hikes are conducted by volunteers knowledgeable about the area and include historical narrative and insider information, the result of years of study about the area's trails, overlooks and historic sites. Robert Gildersleeve, author of the Catskill Mountain House Trail Guide, is a frequent hike leader. Bob Titus, the Catskill Geologist and author of The Catskills: A Geological Guide, leads a few hikes every season as well.
The trails, the views and the history are still here, preserved by New York State's designation of the Catskills as lands to remain forever wild. A walk through the woods with MTHS makes the past come alive for those who are adventurous and want to see and hear the story of America's first wilderness for themselves. All hikes are free and the public is invited. Please wear proper hiking attire and boots (no sneakers!), pack a lunch, don't forget rain gear or sunscreen, and bring plenty of water.
May 20 (Sat) Spring Fling - Opening of the expanded Kaaterskill Rail Trail Check back for details including time and activities.
Aug. 26 (Sat) Open House – details to follow
MTHS does not require membership for hike participation. We do however request that you register for each hike. Participants can register on our contacts page or by calling (518) 589-6657. Please leave your name, phone number, and # in your party. Schedule subject to change. The latest information is available on our web site http://www.mths.org. Notification of changes, including cancellations due to weather will be made on the web site up to the day of any given hike.
Thanks to History Day participants
August 25, 2015
The Mountain Top Historical Society owes thank yous to more people than we can possibly name in a single letter! Please accept these thanks by category and know that we are thanking each one of you as individuals. For a successful Local History Day on August 15th at the MTHS campus in Haines Falls, thank you to all of the dedicated volunteers from all of the local historical associations who spent the day sharing their expertise with the people who came by. Thank you to the vendors, the people who donated food, the Twilight Park Day Camp counselors, the members of the Board of the MTHS, the MTHS program committee, the Mt. Top Arboretum, the Patchworkers, the volunteers in our Visitors' Center, and the volunteers who cleaned up at the end of the day. Thank you to Larry Tompkins and to the trustees from Sheriff Seeley's program that provides help to not-for-profits. They are the ones who prepped the barn for the big day. Jay Fink and Patti Morrow anchored the WRIP broadcast from the train station,. Carver Blanchard stopped by to share some music with us. Mike Ryan did a great job ofdocumenting the proceedings. Thank you Jay, Patti, Carver, and Mike. Thanks to Todd Whitley and Draga Susanj for bringing the Calico Indian Showdown to the our place.Thank you to everyone who came by and listened to presentations, made donations, and purchased food and 50/50 raffle tickets. It was a true community event!
Thank you all!
Cyndi LaPierre President, MTHS
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Nov. 4, 2007. The premier event of New York Road Runners, the ING New York City Marathon is one of the world's great road races, drawing more than 90,000 applicants. Over 700,000 have participated in this run in the past. Check the charity partners for organizations involved.
ING sponsored New York City Marathon
September 20, 2013


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Donate to the Chabot PTA
This page contains information and links for Online Contributions and Corporate Matching Gifts.
Online Contributions
You can use your PayPal account or credit card number to make secure online payments to the Chabot PTA via PayPal.com. All donations are tax-deductible as allowed by the Internal Revenue Service (Tax ID #94-6171779).
Contributions to the Chabot PTA Annual Fund may be made as a single payment of any amount, or in seven monthly installments. Click either of the payment options below to open a PayPal Web form where you can complete your transaction. A receipt will be emailed to you upon submission of each contribution.
If you prefer to make your contribution by check or offline credit card payment, please contact the Annual Fund Co-Chairs Deb Kong, Meghan Horl, and Greg Kato at firstname.lastname@example.com.
Online Contribution: One-Time
Use this button to make a one-time contribution of any amount to the Chabot PTA (PayPal account not required).
Suggested donation is $950 per child.
Online Contribution: Seven Monthly Payments
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You can double or triple your contribution to the Chabot PTA by taking advantage of your corporate match benefit.Many companies, both large and small, will match donations made by their employees. Some companies even match gifts made by retirees, family members, and friends of Chabot PTA!
It only takes five minutes.


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East and West Laville Halls are home to the Laville Honors House, which provides both a residence and an academically focused collegiate atmosphere for first-year students in the Honors College. In 2010 and 2012, the halls reopened after complete renovation that included joining the two buildings together with a central lobby and front desk area.
With its close proximity to The French House, where Honors College classes and administration are housed, and to the 459 Commons dining hall and Student Union, the Laville Honors House in East and West Laville Halls gives students their own mini campus within LSU.
Students live in large two-student rooms with hall-style bathrooms, but have access to all the community's common spaces, including rec rooms, seminar rooms, a computer lab, group student rooms and more.
Community: Laville Community
Side of Campus: East
Floors: 3
Capacity: 600
Gender: Coed by floor
Mattress: Twin
Bed Style: Loftable
Included Furniture: Bed, Desk, Side Cabinet, Chest of Drawers, Chair, Built-in Closets (West) or Movable Wardrobes (East), Blinds
Favorite Features: Sink in room, Large Courtyard , Large Rooms
Semester Rent Rates
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One or Two-student room
Community-style bathroom
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Four-student room
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East and West Laville Halls
Room Layouts
West Laville Hall Floor Plans


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Reach the Audience You Want.
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The Shotokan Times offers a comprehensive media kit for all. It comprises 3 main marketing channels:
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Do you want to advertise a Shotokan Karate, Martial Arts, or Japan related event, product, or service? Then get in touch with us through the contact formula at the bottom!
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We were launched in November 2018. In February 2019, our infrastructure was full established and we began our work. Since February, we attracted 49.420 users and gained 107,290 pages views (date June 20, 2019). We attracted 22.000 pages views on a monthly average. But we are still growing.
Our aim has been to bring the global Shotokan community together on one platform. We have reached this goal. The coverage of countries by The Shotokan Times lies at 95%.
The continents with the most readers were North America and Europe.
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Welcome to Belgrave Pre-school!
Belgrave is a long established pre-school situated in Westminster Park .
We operate from the Westminster Park Community Centre which is close to public transport and within walking distance of the city centre and Handbridge.
Belgrave Pre-School is a non-profit, registered charity, run by a voluntary committee of parents and carers, who work alongside our dedicated and highly qualified staff team. We provide professional and affordable childcare for children aged from 2 to 5 years old.


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Since the cat is out of the bag that I'll be joining you all for the reunion I figured I'd gauge some interest on some heavily discounted photo services.
Depending on how many people are interested I will be bringing a full lineup of pro gear with me to do commercial style shoots of cars.
Here are a few examples (don't mind the Audi's ):
So here is the deal. Shooting one of these commercial shots is about 20-30 minutes of work to get the lighting and all that on point, and then about 3-5 hrs on the back end of post processing. Because of that I am going going to offer these shoots in the following formats:
Commercial Pkg A - $100 - 1 hr shooting. You will get 2-3 fully edited commercial style, professionally lit shots of your car in digital format.
Commercial Pkg B - $60 - 30 min shooting. You will get 1 fully edited commercial style, professionally lit shot of your car in digital format.
"Walk Around" package - $100 - 30-45 min of shooting. You will get 6 normally edited shots of your car in a digital format. This package will be like a "highlights" of your car, still using pro lighting but a different more straightforward technique. It will include shooting overall exterior/interior as well as a few artistic detail shots of some items of your/my choice (i.e. wheels, brake calipers, angel eyes, CF pieces, ect...).
Depending on how many people want to take me up on the offer I might only have room for a half a dozen slots to also be able to participate in the weekends events but I am thinking Saturday afternoon, Saturday night (post dinner) and Sunday (I will be sticking around most of the day) will be fine to schedule shoots.
So if you are interested, please start a list. If not, no hurt feelings... I will be bringing only a camera to snap some stuff for myself and just enjoy everyones company over the weekend.


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Download These Wonderful Free Editable Princess Party Printables!
You have no idea just how happy I am to share with you this stunning full set of free editable princess party printables, that you can personalize with the birthday girl's name and party details!
Princess birthday parties are a dream and are the most popular party theme on Catch My Party! What little girl doesn't wish to be a princess, even if only for one day?


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I know life is supposed to be a journey and we're all just along for the ride, but where's the destination? I feel like I'm just strapped into a car on a roller coaster. There's a lot of ups and downs and I'm even thrown upside down once in a while.
Lately I get off of it with a headache.
I'm going through so many ups and downs.
Work is finally on an upswing. It also helps that it's a new job and I've finally been able to put my old job behind me. It was a good job but it was filled with such negative, hateful, mean people. Thankfully, I don't have to worry about any of that now.
Home is where I can't tell if I'm going up a hill or on the way down. Maybe I'm on a flat piece of track right now. Actually, I think I'm in a tunnel, unable to see where I'm headed. It's a little scary.
I guess I'm alright not knowing where I'm supposed to be headed.I know wherever I end up will be great. I'll just try to enjoy the ride a little more.


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Faviana 7991
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Faviana style 7991 a classic and dynamic number. The dress features the modern halter neckline with a flowing pleated skirt perfect for all body types. This chiffon style is available in three colors, cherry pink, red, sea blue. Pair this look with simple silver jewelry to compliment the beaded accents. You'll feel vivacious at prom or homecoming.
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*A style on our web site listed as in-stock can usually be shipped today or next day for immediate delivery or quick delivery. An item listed as "Ships Today" can be sent the same business day as long as the order is placed before the cutoff time.


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Due to the COVID-19 pandemic, school caisse activities are currently suspended until further notice.
École Dorset
Your school does not participate in the school caisse program. If you're interested, talk to your teacher and ask them to check out this site to learn more about the advantages of the school caisse and services offered.
In the meantime, come play with us in the Games and videos section.
Contact information
At school
École Dorset
514 457-3631
Baie-D'Urfé (QC) H9X 2Z6
At the caisse
Caisse Desjardins de l'Ouest-de-l'Île
514 426-1156
Pointe-Claire (QC) H 9 R 5 K 3
Financial terms
Find out more about financial terms and understand the log on section of the school caisse site better.


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The Spanish Supreme Court has ruled over a case, where a Canadian beneficiary of a Spanish resident wasn´t allowed the inheritance tax allowances of the region where the deceased resided.
Going back to the end of 2014, when the EU Court of Justice ruled that the discrimination between EU residents and non-residents with regards to Spanish inheritance tax was illegal, Spain was obliged to change its inheritance law and it did, with the new law coming into effect on January 1st 2015. We reported about it then, and encouraged those who had been affected by the discriminatory taxation before that date, to start proceedings to get the excess payments refunded.
You can read about that
What Spain neglected to include in the new tax regulation was that beneficiaries living outside the EU, with a connection to one of the the Autonomous Regions, either through the location of inherited assets or because the deceased resided there, should be treated without discrimination as well and should be allowed to benefit of the tax allowances of that Autonomous Region.
The Supreme Court has now ruled in favour of the beneficiary, living in Canada (see intro, ruling 19.2.2018) and obliged the State to amend the tax regulation with regards to inheritances and donations, again, to include those living outside the EU as well.
The State has also been sentenced to return the difference between the inheritance tax paid and the tax that was due taking into account the regional allowances. This opens the way for those in similar situations, going back 4 years, to start proceedings to get the excess inheritance tax refunded.
If you are affected and would like further information or to talk to lawyers on this matter, email us: email@example.com
The cookie settings on this website are set to "allow cookies" to give you the best browsing experience possible. If you continue to use this website without changing your cookie settings or you click "Accept" below then you are consenting to this.


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Ferrero 5-year plan sets ambitious sights on UK
Speaking at the launch of Ferrero's Corporate Social Responsibility Report at the Italian embassy in London last month, Ferrero UK MD Pieraldo Oldano said that the strategy highlighted the UK as a priority market for Ferrero.
"We plan to double our share in the UK in five years," he said.
Market share
The company ranks seventh in the overall UK confectionery market behind Mondelez International, Mars, Nestlé, Thorntons, Haribo and Lindt respectively, according to data from Euromonitor International.
However it is the sixth largest UK chocolate firm based on retail value sales.
Euromonitor forecasts that the $8.2bn UK confectionery sector will grow retail value sales at a compound annual growth rate (CAGR) of 1.4% between 2013 and 2017, driven primarily by chocolate, with the gum category expected to grow faster than sugar confectionery.
Financials in 2012
Ferrero UK posted sales of £184.6m ($304m) in 2012, up 9.2% on the previous year – meaning the business accounted for 2.4% of Ferrero's sales globally in 2012.
Ferrero UK's gross profit margin was virtually unchanged on the previous year at 35.1%.
It recorded a net loss of £5.5m ($9m) in during the year. We asked for an interview with Pieraldo Oldano, but our request went unanswered.
Ferrero in the UK
Ferrero entered the UK market in 1966 and now employs 140 staff in the UK, mainly from its UK headquarters in Watford.
The company has no production facilities in the UK, but produces Tic Tacs from a facility in Cork, Ireland, which employs 125 people.
Pieraldo Oldano was appointed UK MD for Ferrero in January 2012.
Resisting offers from Nestlé
The family-owned Italian company, incorporated in Luxembourg, resisted alleged offers from Nestlé to acquire the firm in October.
Oldano said at the CSR conference that Ferrero was proud to be in private hands and would not entertain offers from the Swiss giant or any other company.


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Career in Litigation and Arbitration - Job opportunities and Challenges
Careers360 in conversation with Punit Dutt Tyagi, Executive Partner of Lakshmikumaran & Sridharan, brings you insights on Career in Litigation and Arbitration. Punit Tyagi, a seasoned lawyer with an expertise in varied fields including Commercial Litigation and Arbitration talks about the specialisation concept. The Lakshmikumaran & Sridharan Executive Partner also speaks on the current prospect of Litigation and Arbitration in India.
Punit Tyagi, who is also an Advocate-on-Record before the Supreme Court also, explains how the litigation and arbitration have changed in the last decade. Read this interview of Punit Tyagi to know the possible challenges and rewards, when you choose a Career in Litigation and Arbitration.
Interview Excerpts
Careers360: What are litigation and arbitration? What are the core similarity as well as the difference between them?
Punit Tyagi: The primary difference lies in the fact that litigation is pursued before courts, and arbitration is pursued before a forum of choice namely, tribunals constituted by the parties' consent.
The dispute resolution mechanism before Courts (i.e., the District Courts, High Courts and the Supreme Court of India) is envisaged under the Constitution. In comparison, Arbitration is a contractual forum chosen by the parties for settlement of disputes. The reason parties opt for arbitration is that it is not only private and confidential, but also that it provides of a more expeditious mode of settlement of disputes, when compared with a judicial approach before Courts of Law.
The similarity between the two modes of dispute settlement lies in the fact that in both forms, there is a neutral party in the form of a judge or an arbitrator to decide the dispute. The same substantive laws apply to both forms. As regards procedural laws, in arbitration, parties are free to agree on the procedure to be followed by the tribunal, i.e., parties can have their own procedure and if there is no agreement between the parties, then the tribunal conducts the proceedings in the manner the tribunal finds it appropriate. In latter case tribunal, though not bound by the procedural laws viz. Civil Procedure Code or Evidence Act, tribunal follow the principles of CPC and Evidence Act. However, they are not applied as strictly as they are before Courts.
Careers360: How has litigation and arbitration changed in last decade? Please share your personal views on them.
Punit Tyagi: In the last decade, arbitration as a means of dispute resolution has evolved to cater to the requirements of the modern-day litigant, particularly in the cases of high stake corporate and commercial disputes. It has less procedural hindrances, faster timelines and, in effect, a convenient mode of dispute resolution. But in Litigation, the manner and mode of dispute settlement is uniform across all areas and categories of disputes, making it sometimes difficult for parties to have their disputes effectively adjudicated. Further, the age old rigid structures of procedure applicable to Courts make it increasingly less popular as a forum for settling disputes. But it would not be fair to the judicial system to make a generalization in this regard. Even Courts have endeavoured in recent years to envisage systems to provide more effective justice to those who appear aggrieved before it. One such example would be the introduction of the Commercial Courts for settling a category of disputes that are time sensitive. Only time will tell if the Commercial Courts will provide effective and speedy mode of delivering justice.
Careers360: What is the current prospect of Litigator and Arbitrator as a specialised career domain in India?
Punit Tyagi: The prospect of practicing litigation or arbitration in India is definitely good. There is no dearth of disputes that are pending adjudication before Courts and arbitration. Arbitration, as a mode of settlement, is continuously growing in popularity, both amongst the corporates as well as private persons. I see great future for arbitration practitioners.
Careers360: What motivated you to begin a Career as a Litigator and Arbitrator?
Punit Tyagi: My parents, like all parents back in the day, wanted me to become a Civil Servant. They saw it as an opportunity for a stable and secure job. But I was quite clear in my mind that I wanted to practice law. Law, as a subject always excited me more than any other subject. The fact that lawyer is a master of his own, was also a big contributing factor in my decision to practice law. Everyday appearing before courts and being able to get relief to the client gives immense satisfaction. It's like passing an exam every day. The fact that lawyer can be instrumental in getting justice to the aggrieved party also excited me a lot.
Careers360: What are the special skills that an aspirant should possess to begin a career in this law field?
Punit Tyagi: Perseverance and Hard Work. There is no two ways about this. In this field, I believe that everyone is always a student. A good legal practitioner must constantly keep updating himself in order to be able to address any and all issues that cross his or her path. This can only be done through constant engagement.
Careers360: What are the possible challenges to be faced in this career?
Punit Tyagi: The most challenging part in this field is that to establish oneself there is a considerably long gestation period. One must have a great deal of patience in order to succeed and excel.
Careers360: How rewarding is the remuneration as Litigator and Arbitrator?
Punit Tyagi: Remuneration is something that is a matter of perspective. But like in any profession, regardless of whether it is arbitration or litigation, to earn, one must first hone one's skills and make oneself competent. Money and recognition both will flow automatically once you do these.
Careers360: What are your suggestions for those who wish to become a successful Arbitrator like you?
Punit Tyagi:Work hard and apply yourself. There is nothing else to it, really!


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FOOD for those who are Hungry
HYGIENE for those who are Homeless
RECOVERY for those who are addicted.
Our mission is to alleviate the effects of poverty, hunger, homelessness, and addiction by providing community-based social services to those in need.
GIVE BIG 2017: May 10th
Can we count on you to Give-Big for those in need?
Visit our Give Big Profile and click DONATE to support ICS!
Your donations will be stretched by Seattle Foundation. Thank you for your support!
2017 Putt-Putt Golf Tournament
Form a team: Gather four to six friends and start raising funds for ICS!
Use CrowdRise to start raising the funds for your $500 entry fee.
Click on "set up your fundraiser" and then "start your own fundraiser" – this will be your team page.
Set your team goal for $500 (or more)
Keep on raising funds for ICS! There'll be prizes for the top fundraising team.
Out of town? Don't Putt-Putt?
Become a Sponsor!
Email Kiser at email@example.com


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Web design delivered on time and on budget.
Making that happen is no mean feat as most web design projects have literally hundreds of elements to them. (Everything from domain names to coding standards to SEO and hosting.) With so many things to consider, planning is vital to your website's success.
So here's the rundown of how we get your website from idea to reality.
First, let's meet. Then we can learn more about your business, your online goals and what your customers want from your website.
By the end of our time together we'll have answered 4 key questions:
- How best to present your business online.
- The functionality required for your website.
- The strategy for attracting more traffic to your website.
- The techniques we can use to turn more visitors into customers.
After we've met and filled up on tea and ideas we get to the task of writing it all up into a wireframe (and sometimes a Technical document, if it's a particularly advanced project). A wireframe is a line drawing representation of your website (boxes, buttons and comments but no design yet). The wireframe is made up of templates (Home Page, Service Page, Product Detail Page and so on). Wireframing gives us all the chance to see how your website will work before we begin coding. It also gives us the opportunity to make zero cost changes when we have those moments of ROAR Genius!
Now we turn all the great thinking in your wireframe into great design. Our designers sharpen their pencils and fire up the latest awesome design software. Then the real alchemy begins as each wireframe template is beautifully fashioned into a design. Often our designs include notes about how the web pages will actually work on screen. This gives clear sight of how visitors will interact with the site and
visually describes brand and business objectives.
After design comes the build. (This phase breathes life into your website.) Our coding wizards take our feature-packed content management system, Proteus and integrate it into the designs. To do this we code, test, deploy and test again. We also adhere to industry standards, set-up databases, configure systems, drink tea and have occasionally launch party!
Next, comes testing. Perhaps the most important part of the process. First, we test everything to make sure it works. We test that the site has met its business objectives, that Proteus is working happily, we cross-check the design and run some additional technical tests to make sure everything is tickerty-boo. Next, it's your turn, you test nearly all the same things including business objectives, designs, but perhaps the hardest mission of all is to try and break the website! By the end of this stage, your website will be ready to pass out from bomb-proofing school.
With everything checked, we're nearly ready to launch - delivered on time and on budget. We do a few pre-flight checks, point your domain name at our servers and your fabulous new website will spring into life - ta-da!


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Wilwerwiltz, Luxembourg
Member since2001
Unavailable for exchange at the moment
The member has not specified any exchange dates
Holiday home in Wilwerwiltz, Luxemburg
Our holiday-home is situated in a small village in Luxembourg. There is a railway station with the possibility of visiting Luxembourg city, Belgium and France. By car you can visit (within an hour) for instance Vianden(castle), Diekirch(War Museum), Esch-sur-Sure(ruines and lake) Ettelbruck and Echternach. The eldest city of Germany, Trier is only 85 km away. If you like cycling or walking you can start from our house, nature is all around you. In the early summer you can take a canoe for a trip on the river Ourthe or Sure. At Vianden, Wiltz and Clervaux are swimming pools.
Our Family
- 2 Adults
- 0 Children
- 12 Exchanges made
- Librarian
- & Librarian
Our Home
- House Type: Holiday home, second home
- Floor: 1
- Environment: In a small town
- Bedrooms: 2
- Bathrooms: 1
- Sleeping Capacity: 4
In my house
- Pets - Not allowed
- Small children - Not allowed
Exchange Types
- Long-term exchange wanted
- Home exchange
- Television
- Garden
- Balcony
- Bicycles: 2
- No smoking
- Seclusion/Privacy
Our Destination Wish List
- Open for all offers
- Duitsland
- Frankrijk
- Nederland
- België
Spoken Languages
- English
- Français
- Deutsch
- Dutch
Our Neighbourhood
- Librarian
- & Librarian
- No children will be traveling with us.
- We do not have pets.


text:
Bigdata Greenplum DBA Online Training By IT Experts:
Globus training facility offers Bigdata Greenplum DBA Online Training. Our Bigdata Greenplum DBA trainers come with vast work experience and teaching skills. Our Bigdata Greenplum DBA training online is regarded as the one of the Best online training in India. All our students were happy and able to find Jobs quickly in USA, UK, Singapore, Japan, Europe. Bigdata Greenplum DBA training online is your one stop solution to learn Bigdata Greenplum DBA at the comfort of your home with flexible schedules.
Globus Trainings offers the Bigdata Greenplum DBA Online Course in a true global setting.
Bigdata Greenplum DBA Online Training Course Content :
- Greenplum Architecture Overview
- Describe About Distributed Databases
- Describe About Greenplum Query Processing
- Access control and security
- Client Authentication Configuration
- Database Accessing
- Defining Database Objects
- Managing Data
- Explain Loading and Unloading Data
- Explain about Starting and Stopping Greenplum
- Backing Up and Restoring Databases
- Greenplum System Monitoring
- Routine System Maintenance Tasks
- Common Causes of Performance Issues
- Performance Problems Investigation
Our Bigdata Greenplum DBA Online Training batches start every week and we accommodate your flexible timings.


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Other: Navigation buttons
Maintained by Davo Smith
Add customisable navigation buttons (next/prev/etc.) to the bottom of each activity page (Moodle 1.9/2.0+)
477 sites
381 downloads
27 fans
Current versions available: 4
Navigation buttons (for Moodle 1.9 / 2.0+)
This block adds customisable navigation buttons (first/previous/next/etc.) to the bottom of each activity/resource page in a course.
It is based on an idea from Penny Mondani: http://pennymondani.com
Thanks also to the US company that sponsored the development, who wish to remain anonymous.
- Download the file and unzip it somewhere convenient.
- On your server, in the 'blocks' folder, create a subfolder called 'navbuttons'
- Upload all the files inside the 'davosmith-moodle-navbuttons-???????' folder to this new 'navbuttons' folder on your server.
- Log in to your Moodle site as an administrator and click on the 'Notifications' option in the Admin settings block.
- You need to make a small change to one Moodle core file to make this work (the change is different between Moodle 1.9 & Moodle 2.0 - see the included README.txt for details).
- Add the block to a course (turn editing on, select 'Navigation Buttons' from the 'Blocks - Add' menu)
- Customise the button appearance by clicking on 'Edit the Navigation Button settings' in the newly created block.
- Check the message at the bottom of the screen (under the 'Save changes' button) - it should read "Navbuttons self-test: required core modifications have been completed successfully". If not, then go back to step 5 above and check carefully.
Note: The block is only visible to users who are able to edit courses modules. Deleting the block will remove the navigation buttons (they can also be disabled through the settings).
For a quick demo, there is a screencast available here:
Useful links
Please login to view contributors details and/or to contact them
Show comments
- Fri, Sep 28, 2018, 5:51 PMHi Chye Siaw,
I can think of no reason why the block would need adding to every course when upgrading - certainly my local test copy of Moodle has been upgraded a great many times without ever needing to do this.
Replacing the blocks/navbuttons/pix/* files is the correct way to change the default icons - if that doesn't change anything, then you need to clear your site or browser cache to see the difference.
Ideally if I was rewriting this plugin now, I'd introduce a better way of handling configuration across multiple courses, but it was written a long time ago and I'm unlikely to overhaul it anytime soon.
- Tue, Nov 20, 2018, 1:10 AMHello, is there any way to set by default the block at every course in the site?
- Tue, Nov 20, 2018, 1:11 AMDarwin - sorry that is not currently possible.
- Mon, Apr 1, 2019, 9:21 PMHi, we are using navbuttons release = '2.2+ (Build: 2017100900)' in our project. We need to be VPAT and ADA compliant however below is an issue that needs to be resolved:
Issue: Form control label is missing text (Next activity button) < label class = "lblNavigationButton branchbuttoncontainer" style= "z-index: 2147483646; position: relative;" >< input type = "submit" n ame = "navbutton" value = "Next activity: Is Everyone Drinking?" style = "" > label >
Recommendation: Add the text for the form element within the label-tag or WAI-ARIA 'aria-label' or 'aria-labelledby' attribute that is already present.
I think above code is being generated from file '"moodle/blocks/navbuttons/footer.php"'
Please advise.
- Thu, Apr 4, 2019, 2:43 AMHi Abdul,
Just to confirm - the buttons are output by the make_navbutton() function in footer.php. If you want to add extra output on your site, then that is the function you'll need to edit, in order to add the label you want.
- Fri, Oct 18, 2019, 12:24 PMHi Davo,
I have upgraded my Moodle from 3.3.3 to 3.7.2 . And also updated navbuttons from '2.2+ (Build: 2017100900)' to $plugin->version = 2018042100;
$plugin->release = '3.4+ (Build: 2017100900)';
In file moodle/blocks/navbuttons/activityready.php, there is a method
* @param $cm
* @return bool
function navbuttons_mod_questionnaire_showbuttons($cm) {
global $USER, $DB;
return $DB->record_exists('questionnaire_attempts', array(
'qid' => $cm->instance,
'userid' => $USER->id
As per my knowledge, 'questionnaire_attempts' table has been removed, have a look at https://moodle.org/mod/forum/discuss.php?d=392394 . I am getting exception due to this.
- Fri, Oct 18, 2019, 3:00 PMHi Abdul,
I've just pushed a fix to github that should address that problem (it will simply show the buttons always, rather than waiting until you have submitted an attempt).
As an alternative, you could simply change the settings for the navbuttons (on the global settings page, not the per-course settings), so that they are set to 'Always show' or 'Show when complete' for questionnaires, instead of 'when questionnaire submitted'.
- Mon, Nov 18, 2019, 4:26 PMSeems to be working with Moodle 3.8, without any changes (new version released with mod_questionnaire compatibility fix).
- Mon, Nov 18, 2019, 5:06 PMThanks for the plugin.
Why it's not in AMOS for translation? I'm PT-PT translator. Only in GitHub?
- Mon, Nov 18, 2019, 5:09 PMDinis - because of the necessary small core change, Moodle HQ has recategorised the plugin as 'Other', rather than 'Block'. This breaks just about all of the automated systems associated with the plugins database (automatic filling-in of details from version.php, integration with AMOS, etc.)
There is nothing I can do about it as long as the plugin is still in the 'Other' category (I had hoped to remove the core change when some new hooks were added a to the Moodle footer a couple of years back, but those hooks were implemented in a way that doesn't allow extra output to be inserted, so I'm still stuck with the core change).
- Mon, Nov 18, 2019, 5:32 PMSorry about that. I will pull a request in GitHub. Thanks
- Thu, Apr 30, 2020, 8:32 AMI am running moodle 3.7+ and have installed the latest download of this plugin and followed each step in the readme file but the red message when I go to add the block will not disappear. I modified the /moodle/lib/outputrenders.php file with the code you provided but it is just not working for me. What am I missing?
- Wed, May 20, 2020, 6:03 PMHello, great block plugin, would it be possible to show "next activity" button even if next activity is not yet accessible? i have SCORM packages as activities and even if student complete the SCORM activity, he doens't get the "next activity" button
- Wed, May 20, 2020, 7:07 PMAntonio - you could probably open up the file footer.php in the plugin and remove the lines: if (!$mod->uservisible) { continue; }
That would mean that the next activity in the course is linked to, even if it is hidden or not available due to conditional restrictions, but that will lead to lots of error screens if the activity is still not available to the user after they've clicked on the link (so hiding an activity in the course would lead to everyone getting an error when reaching it, rather than just skipping over it to get to the next activity).
An alternative might be more complex code that refreshes the buttons via javascript once the activity is complete, but that is beyond the scope of what I'd be able to do in my spare time (maybe could be tackled in work time, if you had a budget to pay for it).
- Tue, Jun 16, 2020, 12:56 AMChecks suggest this is still working fine with Moodle 3.9.
Please login to post comments


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Nedbank and EE Publishers are hosting a series of morning seminars on important infrastructure issues facing the energy and ICT sectors in South Africa.
DATES: See below for the date of each seminar
TIMES: 09h00 to 13h30, with a networking finger lunch and refreshments thereafter
VENUE: Nedbank Main Auditorium, 135 Rivonia Road, Sandton, Johannesburg
PARKING: Ample parking is available
COST: R150 pp (inc VAT) payable at the door (cash or credit card)
The purpose of the seminars is to initiate meaningful, constructive dialogue on energy and ICT infrastructure initiatives needed to unlock the economic and human potential of South Africa.
The seminars will cover political, economic, environmental, policy, legal, regulatory, planning, investment, business, labour and social issues. Attendees will be addressed by a number of key sectoral leaders, followed by open discussion and dialogue with the audience on the challenges arising.
Click here to book your seat at any of the seminars
Click here to book sponsorship opportunities at the seminars
7 May 2019: Ensuring a just energy transition for SA
The need for a just energy transition in South Africa to ensure environmental sustainability and reduce the carbon intensity of South Africa – issues of job creation, education, training, re-skilling and geo-location of clean energy resources for maximum impact and least cost.
25 Jun 2019: Enabling small scale embedded generation in SA
The role of small and medium scale embedded generation and "smart grid" in meeting the electrical energy needs of the future – the necessary business case, policy, regulatory and financing environment for behind-the-meter solutions such as rooftop solar PV and other distributed generation.
18 Sep 2019: Establishing a viable gas sector for SA
How to facilitate a viable gas sector in SA from imported liquefied natural gas (LNG), imported compressed natural gas (CNG) from neighbouring countries, liquefied petroleum gas (LPG) from the SA petrochemical industry, and exploration and exploitation of shale gas in the Karoo and natural gas along the SA coast.
22 Oct 2019: Flexible power generation – a new paradigm in SA
The role and business case for flexible generation, including gas-to-power, pumped water storage, thermal energy storage and battery energy storage systems to complement intermittent wind and solar renewable energy sources, and to provide much needed auxiliary grid services.
26 Nov 2019: ICT infrastructure to support an effective ICT ecosystem in SA
The need for effective ICT bandwidth, spectrum and infrastructure, together with a sound policy, legal, regulatory and planning framework in South Africa, to facilitate universal affordable broadband access, e-business and Industry 4.0 for inclusive economic growth.
Click here to book your seat at any of the seminars
Click here to book sponsorship opportunities at the seminars
09h00 – 10h00: Registration; substantial breakfast, tea, coffee, fruit juice
10h00 – 10h10: Welcome & introduction
10h10 – 11h30: Sector leaders present
11h30 – 11h45: Comfort break
11h45 – 13h00: Audience interaction
13h00 – 13h20: Presenters summing up
13h20 – 13h30: Conclusion and thanks
13h30 – 14h30: Substantial lunch, refreshments, networking
For R6000 + VAT per seminar, your company may have:
Click here to book your seat at any of the seminars
Click here to book sponsorship opportunities at the seminars


text:
Today& Now a days, maximium customers use the internet to find for the products& items or any type of services they need. Your business will gain best credibility by having a website on internet.
In the world of 21st century technology world, we strongly strive to make your business growth efficient with our differnet consulting technique, starting from product development& engineering.
Welcome to Aeonic Edge a Best Mobile App development company in India& USA.Our Mobile App Developer have expertise in developing apps for android native& Ios Native as well as Hybrid Development.
Since our establishment in 2015, our team have capability a wealth of experience by being exposed to (what must be) all of the key business processes and Website development Company.read more.
We Created a Customized Mobile Application Development as per to requirements i.e Hybrid Application, IOS Native,Andoird Native Application.Etcread more
Search Engine Optimization is a big game changer player in the digital marketing arena.We have best experienced in Search Engine Optimization Industry.read more.
Aeonic Edge Pvt. Ltd. Is a Tech based startup company registered under Company Act
2013 (CIN: U72200UP2019PTC113727). Aeonic Edge have a group of innovative
entrepreneur, who believes in the creativity of fresh mind. Aeonic Edge is working since
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With a best expertise in Software Development, Digital Marketing, Web Designing & Development and Mobile App Development, we work towards delivering maximum best results, tailor-made to all your business needs& Expections.
Our Team will always availble for your technical issues 24*7.We are happy to help you.You can call our support executive team any time.
Our Dedicated Team is able to complete your task " ON TIME DELIVERY".Your Digital Business Is our part of AIM'S For better servies on time.
We will happy to serve you better quality software development services.for collaboration contact business development team or mail us at email@example.com
"Their work on our website and Internet marketing has made a significant different to our business. We've seen a 425% increase in quote requests from the website which has been pretty remarkable – but I'd always like to see more!
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Mob: +91 980 153 4177
Mail. : firstname.lastname@example.com


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Three new memory cards have been announced from Bulgaria's A2Heaven.
The cards, for the Apple II family, add 8 Megabytes of memory and other features:
Addon 8MB for Ramworks III
Ramworks III expansion to 8MB card , also emulates original Applied Engineering piggyback 2MB card and 512 KB memory extension form Applied Engineering. This card also supports 80 column mode.
The display on the card shows the current memory bank selected.
RamFactor compatible card ( firmware is same as original ) and 8MB, with jumper you can select from Applied Engineering or Apple firmware (to emulate apple memory expansion card).
The display on the card shows the current memory bank selected.
RamWorks III compatible card with 8MB battery powered RAM
The battery is for backup data (just like PowerFactor from AE) and can be used as Solid State Disk.


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AboutLearn what sets the Southeast Flooring Market apart from other markets in the industry
As the largest flooring trade show in the Southeast, Southeast Flooring Market (SEFM) brings together the region's best retail buyers, dealers, builders, contractors and designers to scope out the latest flooring products on the market.
About Southeast Flooring Market
Meet with suppliers directly for product demos and industry forums, or simply browse current and upcoming trends for your business to use in the months to come.
The Cobb Galleria Centre, located just northeast of Atlanta, provides an easily accessible location that's surrounded by all-new dining & entertainment options with the recent opening of the Battery. Attendees can take in the local atmosphere when they aren't visiting the booths of the leading flooring manufacturers and distributors, or checking out practical demonstrations on the market floor.
Cobb Galleria Centre- Exhibit Halls A&B
Atlanta, GA
Market Dates & Times
Tuesday, January 5, 2021
9:00 am – 6:00 pm
Wednesday, January 6, 2021
9:00 am – 3:00 pm


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Really don't mind if you sit this one out...Time for a bloodtest! Yay. I've been feeling both dense and disconnected lately. Stuff gets done, but I have a constant sense of running behind. It's true that there is a lot of "extra" stuff that needs to be done because of Christmas, and I am actually in good shape there. It just doesn't feel as if I am. I'm falling back into that familiar mode where everything, everything feels like a struggle.
I think a slight uptick in my thyroid meds would be very helpful.
* * *
Regarding the title of this post, it's the name of art/prog rock album by Jethro Tull. I listened to it on Friday in the car, on the trips to and from Borders with the kids. It's one huge extended poem/diatribe, that makes vague political/environmental comments but also expresses the normal frustrations that anyone can feel about the pressures that we are all exposed to by our parents and our society. Lyrically, it's pretty much dreck. It's interesting to read now that the band intended it all as a send-up of the self-importance of progressive rock. When I was a teenager, I thought the lyrics were brilliant. (heh)
I still love it, in spite of the ridiculous lyrics. I love the music, especially the intro, and the progressive changes it moves through. As for those bombastic lyrics? They're not all crap -- even if they do all come off as contrived now -- who hasn't felt like this?
And your new shoes are worn at the heel
and your suntan does rapidly peel
and your wisemen don't know how it feels
to be thick as a brick.


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Breakwater in summer (Laitakari, Eurajoki)
Laitakari has a long and lively seafaring history: it has served as a harbour and boatyard for centuries. Services available in the area include a restaurant, dance pavilion, harbours, rug washing piers, pétanque playing area and nature trail, as well as a recreation centre and beach maintained by the municipality of Luvia.
Nearby attractions: Thick ice, Guest harbour
Coordinates (WGS84): P 61˚20, 599' I 21˚33, 529'See transportation and other services for this place
Keywords: Beach, Harbour, Services, Panorama


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By Phoebe Doscher, Staff Writer
As my first semester at college draws to a close and finals season approaches, I am, like many others here at Gettysburg, tired and excited to return home for the holidays.
But at the same time, I feel euphoria and pride in myself for all I have accomplished and all I have yet to do in the following seven semesters at this school.
When I think back to my first week at Gettysburg, I was emotional over being away from my family for the first time and already extremely busy.
Even just during orientation, before classes had started, first-year students attended activities and played bonding games so that we could get immersed in the campus community for the first time.
Our days were filled to the brim with new people, new places, and always something to do.
Now, I realize that some things have not changed between now and my first week at college. Sure, the places and people are no longer new, but there is always something to do.
I took the opportunity to seek out clubs and activities that I knew I would love. Now, I'm beyond grateful to fill each day with things I'm passionate about.
In fact, some of those opportunities were in areas I had never tried before.
Regardless, I challenged myself to take advantage of them.
One of those opportunities was an improvisation, or improv, game at the Owl and Nightingale Players' orientation event. I have done theatre in the past, but I have never enjoyed improvising onstage without a script or a plan of what to do next.
Gettysburg's welcoming atmosphere inspired me to volunteer for an improv game. I got up there, in front of people that I did not yet know, and performed a comical scene, completely on the spot.
My future classmates laughed and filled me with a sense of belonging. Towards the end of the semester, one of those friends, a senior, wrote me a letter, reminiscing about the time I made him laugh during orientation.
All of my experiences here have been like this improvisation performance: some opportunities are impromptu and scary, especially if I have never tried them before. But they have all ended up being completely fulfilling.
I never expected to end up in a place where I could follow so many avenues centered around my passions, but every new day is another opportunity to do the things I most love. Even the challenging, new experiences are exciting and help me to grow the most.
As for next semester, I hope to continue to fill my days with things I love to do, and even challenge myself to do more.
Right now, I am involved in activities around my intended majors: Theatre and English. But next semester, I want to try doing things that are out of the box, and not necessarily in my comfort zone.
I am ready for all next semester, and the following years, have to bring.
Editor's Note: This article is part of the 2018 edition of our series "Dodging the Bullet: The First Year Journal," in which The Gettysburgian's staff members from the Class of 2022 share stories, reflections, and perspective on their first year experience.


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TICKETS for the 2016 Gibraltar Darts Trophy are now on sale ahead of the European Tour event on "The Rock" from May 6-8.
The sport's top stars will return to Gibraltar for the fourth successive year to compete in the PDC European Tour event, which is worth £115,000 in prize money. Friday's first round will see the 32 qualifiers for the event compete across two sessions at the Victoria Stadium, before the 16 seeded players - likely to include world number one Michael van Gerwen, the reigning champion - enter in Saturday's second round.
The Gibraltar Darts Trophy will then conclude on Sunday May 6, with the third round in the afternoon session and the quarter-finals, semi-finals and final in the evening session. The field for the Gibraltar Darts Trophy will feature the leading 16 players from the PDC's ProTour Order of Merit, as at the close of entries in early March.
In addition, 20 players will win through the UK Qualifier, with a further eight European Qualifiers set to be joined by four Gibraltarian aces who will win through the Host Nation Qualifier.
The ProTour Order of Merit's top 16, currently headed by Dutch star van Gerwen, also includes former Gibraltar Darts Trophy winner James Wade, reigning World Champion Gary Anderson and 2015 World Grand Prix winner Robert Thornton.
Premier League stars Peter Wright, Michael Smith, Adrian Lewis and Dave Chisnall are also line to compete in Gibraltar.
PDC Terms & Conditions
FANCY DRESS: While fancy dress is permitted to be worn, costumes which are deemed to politically insensitive or offensive will not be permitted. Masks are only permitted to be worn once spectators are seated inside the venue. No imitation weapons or other potential missiles will be permitted.
Ministry of Sports 2017
Victoria Stadium
Bayside Road


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When the matter at hand is the smoking habits of men and women, we can say that the two genders cannot exactly be considered equal, which is a saddening reality. In other words, research shows that when it comes to quitting your smoking habits and getting out of a smoking routine, women tend to have a much harder time than men, most of the time.
Even though the research on this issue is still considered to be "mixed", it is said that in an investigation conducted not too long ago, more than a thousand people who habitually and excessively smoked made an attempt to quit their harmful habits in almost two months. It was found that ladies found it at least 33% harder to effectively quit smoking, when compared to the men in the investigation.
The gender of smokers again made a huge impact in another investigation in which about 694 people who habitually smoked tried to stop without making use of smoking cessation pharmaceuticals.
Now that we know that women, when compared to men when it comes to smoking and quitting the habit, have a much harder time, it is important to understand why this happens.
It is said that when men partake in a habit such as smoking, they do it purely for the "rush" and satisfaction that come with it, whereas women usually smoke so they can get some sort of a psychological reward, like getting to hang out with friends who also indulge in the habit. Women also smoke because of the calming effects of the substance, so they can deal with day-to-day stress.
Despite women having a hard time quitting smoking, nothing is impossible.
Here is a list of ways and tips you can utilize to quit this unhealthy habit:
* Going cold turkey: Even though this method of quitting can be potentially dangerous for most people as you might experience the withdrawal symptoms much more strongly, it is also one of the best methods of quitting. Quitting completely is definitely better than still smoking one or two cigarettes a day. Just remember that there is nothing to be scared of, no matter how intense your symptoms might get.
* Find an alternative: For some, finding an alternative might mean finding something else to do, or replacing the entire activity itself. For example, instead of going out to have a smoke with your friends, you can go watch a movie instead. But for some, finding an alternative means replacing the substance with something which does not have as many harmful effects on health. Try vaping if you don't want to go cold turkey, as it is considerably less dangerous than smoking tobacco.
* Using nicotine patches: A nicotine patch is a kind of NRT (nicotine replacement therapy) which can be of aid if a person is quitting. This patch is actually known for doubling the success rate of smoking cessation, as it gives the user a controlled, consistent dose of nicotine for the day, which reduces nicotine withdrawal symptoms greatly.
Trying to quit gets easier if you follow these tips. Good luck!
Thanks to Skylar
January 21, 2019 by Leave a Comment