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Posted :
08 January 2020 17:06:43
Rank: Beginner Level 1
Groups: Registered
Joined: 04/06/2019
Posts: 8
Points: 24
I am on issue 71. This is the issue that has the circuit board which I am trying to plug in the wires. The picture in the directions (issue 71 page 10) are numbered differently than on my circuit board. Holding the board like the directions show has the upper left corner, the numbers on mine are 3-1-7 (space) and the single plug is numbered 5. In the directions these three plus one plugs are numbered 1,3,5,(space) then 7. Do I go by the directions or by the numbers on the circuit board?
Thanks for any help.
John Patterson
I tried to add pictures but this doesn't let me.
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Posted :
08 January 2020 19:16:07
Rank: Super-Elite
Groups: Administrators, Global Forum Support, Registered, Moderator, Official Builds
Joined: 04/01/2016
Posts: 5,093
Points: 15,574
Location: Northamptonshire, England
I'm not up to your stage at the moment, so can't comment. I have made some enquiries and hope to have an update soon.
Millennium Falcon Customised Build.
R2-D2 Customised Build.
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Posted :
08 January 2020 19:21:04
Rank: Beginner Level 1
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Thank you Mark. I hope that the pictures helped and you can see what I am talking about. I do not want to blow up the circuit board and have another paperweight like the R2D2
John P
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Posted :
10 January 2020 18:59:25
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Groups: Forum Support Team, Global Forum Support Team, registriert, Forum Support Team Germany, Official Builds, Global Forum Support, Administrator, Administrators
Joined: 13/03/2012
Posts: 224
Points: 631
Location: Germany
legoman77 wrote:
I am on issue 71. This is the issue that has the circuit board which I am trying to plug in the wires. The picture in the directions (issue 71 page 10) are numbered differently than on my circuit board. Holding the board like the directions show has the upper left corner, the numbers on mine are 3-1-7 (space) and the single plug is numbered 5. In the directions these three plus one plugs are numbered 1,3,5,(space) then 7. Do I go by the directions or by the numbers on the circuit board?
Thanks for any help.
John Patterson
I tried to add pictures but this doesn't let me.
this is the German building instructions for the circuit board. My board is numbered just like the circuit board in the instructions is numbered.I cheched your board with the DE Instructions,they are the same.. Take a screenshot of the English building instructions so that we can make a comparison.
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10/01/2020 19:40:57 |
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Posted :
11 January 2020 06:31:15
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Groups: Forum Support Team, Global Forum Support Team, registriert, Forum Support Team Germany, Official Builds, Global Forum Support, Administrator, Administrators
Joined: 13/03/2012
Posts: 224
Points: 631
Location: Germany
We have now put both building instructions and my circuit board on top of each other. There is no difference regarding the plug connections. Also, both instructions are identical in numbering to the numbering on the board I have.
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Posted :
16 January 2020 22:32:07
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Hi John,
I just received a message from CS, regarding your issue. Your timing is perfect, as I have chased down the solution. The German directions are (obviously) wrong. Attached is a link to the English versions, which are correct.
I've been assured these ARE correct!
PM me with your R2 issues?
Mark Adams
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text:
Fox News might become unbundled from THE WALL STREET JOURNAL and other publishing properties. That could happen as soon as tomorrow if the board of News Corp approves the plan to split profitable entertainment from drag-on-earnings publishing.
Rupert Murdoch, who has had a long love affair with the newspaper business, is showing again how smart he is. He is surrendering to win. He is giving into shareholders on this one. In return he may get a lot more than anyone can imagine.
I look at the dynamics and implications of this possible split for the financial management company Motley Fool.
Here you can follow how I connect the dots.

subset: commoncrawl


text:
Mobile Fidelity Silver
|Product No.:
Vinyl Box Sets
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Also available on:
• FLAC 96kHz/24bit Download
Ryan Adams Love Is Hell on numbered limited edition 3 LP box set
Personal document on romantic loss, frustration, and loneliness hits bittersweet, spiritual note
Originally released on two EPs, Love Is Hell is a staggeringly personal report on romantic desolation, personal frustration, and incurable loneliness whose themes play out via heartbreakingly intimate vocals, stark acoustic guitars, unembellished electric guitars, chamber-pop strings, and spare pianos. The excising of pain has rarely sounded more bittersweet-or spiritual. Due to Ryan Adams' barren and tormented state, his record label initially refused to release the album out of concern it was too dark.
Renowned for his introspective takes splintered relationships, Adams has never sounded more severe, damaged, or frayed. Listening is akin to peering into the tiny soul of a human being reconciling what love is and what it requires, and whether or not it can be had-all the while conversing with the people that drift in and out of his life. Recognized by critics, peers, and fans for sketching impeccably detailed songs and lifelike protagonists, the singer/multi-instrumentalist doubles as a film auteur throughout Love Is Hell. Such is the value he places on atmosphere, scenery, and insightful specifics.
Rain, snow, and cold color the songs' environment, the gloom, austerity, and dampness blending with the music's slate-grey vibes. Decaying, single-room-occupancy hotel rooms, unforgiving city streets, and long nights afflict characters that teeter on falling apart and seek solace by holding on to fading optimism-no more so than on the staggering cover of Oasis' "Wonderwall." Removing boundaries between himself and the listener, Adams pours out naked fears and thoughts. Expertly placed, minimalist instrumentation accentuates his dramatic swells, emotional extremes, and shifts in scenery.
Arrangements are nothing less than bracing. When employed, electric guitars resonate with tones that suggest showers and sleet, and on the title track-the record's most aggressive song-inform an anthemic irony. Tempos slowly drift, Adams' poignant voice remains unhurried, and looming metaphors threaten to swallow the hope on which the singer rests his head during his uncertain times. Throughout, via his phrasing and timbre, Adams makes you feel and inspires reaction. Love Is Hell is the antithesis of background music, its somber qualities and reflective intricacies akin to burrowing into the pages of classic literature.
Phenomenally rare on vinyl — copies, when available, sell for upwards of $150 on the aftermarket — Love Is Hell has never sounded better or looked more beautiful.
|Side 1
|Political Scientist
|Afraid Not Scared
|This House Is Not for Sale
|Anybody Wanna Take Me Home
|Love Is Hell
Side 2
|The Shadowlands
|World War 24
Side 3
|My Blue Manhattan
|Please Do Not Let Me Go
|City Rain, City Streets
|I See Monsters
Side 4
|English Girls Approximately
|Thank You Louise
|Hotel Chelsea Nights
Side 5
|Fuck The Universe
Side 6
|Twice As Bad As Love
|Father's Son
|Gimme Sunshine
|Black Clouds
Customer Reviews
(5.00 Stars) 2 person(s) rated this product.
|Write a review and let people know what you think of this product OR just rate it.
View other items by Ryan Adams


text:
Wednesday, March 1, 2017
Jazz CD of the Month - "Mark Whitfield: Grace"
Mark Whitfield: "Grace" (Marksman Productions)
Rating: **** (musical performance & sonic quality)
Produced by Mark Whitfield, Mark Whitfield Jr. and Davis Whitfield
Executive Producer: Antoine Drye
Recorded, Mixed & Mastered by Dave Stoller @ the Samurai Hotel Recording Studio
Photos: Deneka Peniston
Art Direction: Scott Sandler (Mr. Scott Design)
Manufacturing Coordinator: Ric Sherman
All compositions by Mark Whitfield
Featuring: Mark Whitfield (guitar), Davis Whitfield (piano & keyboards), Yasushi Nakamura (bass), Mark Whitfield Jr. (drums), Sy Smith (vocal & lyrics on the track "Grace")
Esteemed guitarist and composer Mark Whitfield has just released "Grace", his 15th album as a leader. Whitfield's first project as a leader in seven years, "Grace" is a celebration of love and legacy, family and future, as the elder Whitfield ushers in a new era of musical excellence in the form of his descendants: pianist Davis and drummer Mark Jr.
Like father, like sons. Whitfield burst on the jazz scene with his critically acclaimed 1990 debut "The Marksman" for Warner Bros. Heralded then as "The Best Young Guitarist In the Business" by the New York Times, Whitfield stayed true to the sentiment with a fruitful career spanning over two decades and including tenures with a litany of jazz and pop music greats.
Following in the footsteps of their father, and their uncle (the great jazz drummer Troy Davis), Mark Jr. and Davis have established themselves as "ones to watch" on their respective instruments. Both "grew up on the bandstand" alongside their father and both picked up their instruments at a young age. "I was attached to him by the hip! Anytime I could be there, I'd be there. You know, in all those clubs where I wasn't supposed to be as a five-year-old -- I was there," recalled Mark Jr in an interview with Revive Music in 2013.
After sharing the stage on so many occasions, Mark brought his children into the studio along with "honorary Whitfield family member" bassist Yasushi Nakamura and guest vocalist Sy Smith to record "Grace". "I wanted to share my love of music with sons, and use this love to forge a bond between the three of us that would enrich our lives, enlighten our consciousness and support us through the toughest of times," says Mark. The result is "Grace", a collection of nine personal compositions; each telling a unique story that chronicles the last two decades as a family.
"Grace" kicks off with the biographical "Afro Samurai", inspired by Mark's triage of young curiosities: music, skateboarding and "terrorizing all who dared to come near my garage with my less than stellar kung fu skills!" These three disciplines are represented by the three distinct solo sections.
"Blue D.A". which first appeared on Whitfield's 1994 album "True Blue", is reimagined here as a tribute to the late, great Kenny Kirkland, who can be heard on the original. The title track presents the first "extended family" collaboration with a special appearance by cousin Sy Smith. "I wrote a song as a reaction to the violence that has plagued our society for years and seems to have worsened severely in recent months and we turned to our cousin... composer, lyricist and songbird extraordinaire, Sy Smith, to bring it to life," said Whitfield.
"Double Trouble" serves as an homage to Mark's mentor George Benson, who encouraged him to join the Jack McDuff Quartet and is inspired by a tour situation gone wrong.
Whitfield and co. slow things down for "Space Between Us", a tender ballad where Whitfield's playing resonates with every stroke, but picks us back up for "Fortress", another call to Benson and a nod to contemporary Kevin Eubanks. "The 1st guitar record I ever owned was George Benson's Breezin'. I wore the old vinyl LP down to the grooves learning every single note that the aforementioned Benson played," said Mark, adding, "...then I made the boys listen to over & over so they could clearly understand the genius of the man they refer to as "Uncle George"!
The final third of "Grace" includes "Undiscovered", a testament to self discovery. Says Mark, "As teacher, bandleader & composer I endeavor to create musical situations that promote the right environment for the group to discover new pathways to reach higher levels of self expression. If nothing else, Davis' piano solo is the embodiment of that which I hoped to create!"
The penultimate tune "The Socrates Curse" brews a perfect storm between Davis' transformative solo and Mark Jr's volcanic rhythmic explosion. 'Grace' reaches its conclusion with "Pulse Pt2", an easy groove off into the sunset.
In 1990 the New York Times dubbed Whitfield "The Best Young Guitarist in the Business". Later that year, Warner Bros. released his debut album "The Marksman". The success of his debut release led to a recording career that has produced a total of 14 solo recordings and a myriad of collaborative efforts with some of the most important artists in recent years; Sting, Steven Tyler, D'Angelo, Mary J. Blige, John Mayer, Chaka Khan, Jill Scott, Diana Krall, Christian McBride, Chris Botti, Roy Hargrove and Nicholas Payton.
Along the way the "Whitfield Family Band" was born, literally. In 1994 The Mark Whitfield Quartet appeared on the Thanksgiving Day broadcast of Good Morning America. This performance featured a very special guest drummer, 4 year old Mark Whitfield Jr. It was obvious even then that he was destined for greatness. Following in his father's footsteps he attended the Berklee College of Music and graduated in 2011 with honors. He went on to study for his Masters Degree at the Manhattan School of Music while simultaneously embarking on a career as a drummer extraordinaire. He has quickly earned a reputation as one of the best young drummers in Jazz and was nominated for a Grammy in 2014 as part of the ensemble featured on Kenny Garrett's 2013 release "Pushing the World Away". Not to be outdone by his older brother, Davis Whitfield, a prodigious pianist, earned a Presidential Scholarship and graduated from the Berklee College of Music with honors in 2014.
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text:
Fit out projects under 50,000 sq ft often require smart, responsive fast-moving solutions. They also require a different fit-out mindset — one that's focused on exceptional customer service and dynamic solutions every day. For this reason, ISG has a highly-specialised Agility team. Devoted specifically to smaller projects, the Agility team delivers smart, efficient solutions to businesses undergoing change across the office, fitness and leisure and public sector.
Get in touch today and find out how ISG can help you with your project.
"We make sure we fully understand what your business wants to achieve on each of your projects. ISG's Agility team works around you to respond quickly and provide a high-quality, expert job focused on minimising the impact to your business."
Lee Phillips, Managing Director, Agility
Businesses in the midst of change require specialist teams that understand the related pressures and complexities. At ISG, we know the office is rarely just a place to house people and systems; it is a key part of your business infrastructure. It forms the backbone for sophisticated technology and operations. It plays a key role in attracting and retaining the best people. As such, it must be as resilient and agile as the business that occupies it.Read our Hogan Lovells case study here
We are incredibly proud to have a number of clients who rely on ISG to deliver high quality, robust fitness gyms. With years of experience in creating luxury health club and spa environments, our detailed approach will equip you with the facilities you need to provide an exceptional personalised experience.Read our Equinox case study here
Now, more than ever before, our higher education customers need to demonstrate the value of the estate, and ultimately find a more intelligent and efficient utilisation of the estate's resource. At ISG, we're equipped with the expertise to help deliver flexible and functional higher education buildings, that focus on the student experience and inspiring excellence every day.
At ISG, we are committed to building deeper and more productive relationships with our clients. Our after care offer takes the traditional notion of after care and expands it into a trusted, agile and long-term service built on a deep understanding of our customers. Facilitating the relationship between fit out and facilities management, our specialists deliver projects anytime and anywhere to support both framework agreements and the constantly evolving needs of modern businesses.
On framework agreements our customers can rely on ISG's institutional knowledge, and can rest assured that their needs are maintained through a single point of contact and carried over from project to project. We work to ensure we provide a 24-hours-a-day service, giving our customers the best delivery and value, no matter the size of the job.Read our IWG framework case study here


text:
Culture Trip stands with
Black Lives Matter
This place couldn't be any farther from the traditional. Making serious headway in the vegan donut scene, and the sweet-tooth scene in general, Brammibal's has raised the bar on what it means to make donuts in the Hauptstadt. Even people who don't typically enjoy the anytime carb have raved about this place. Born out of a passion for veganism and a commitment to wholesome, creative baking, Brammibal's crafts perfect dough creations. There are a variety of flavors that at first make us scratch our heads and then later pat our stomachs. With variations like maple coconut bacon, matcha, or white chocolate pistachio, it's easy to find something delicious. This little gem in Neukölln is a new and highly lauded addition to the Kiez.
Located in Mitte, this antiquated bakery dates back to the early 20th century, and the interior proves it. It's a bakery that's hidden in plain sight. If it weren't for our noses, we just might miss it. The women who run the bakery are just what you would picture when entering an old German bakery, with encyclopedic knowledge of the rows of sweets and fresh baked goods. Their delicious, fried pretzel donuts with a saccharine glaze are like pieces of carb heaven and always piping hot.
Bäckerei & Konditorei W. Balzer, Alemanha, Sophienstraße 31, Berlin, Germany
One for the history books, Bäcker Walf has roots that date back to 1898. For a bakery to have lasted through the two World Wars and the Iron Curtain, they must be doing something right. With owners who almost feel like they've been there since day one, they're known for being on the stricter side. Don't dillydally too long, and order with confidence in a timely manner. What to order? There are many things to choose from in this sapid bastion of baked goods. However, the chocolate Pfannkuchen should be at the top of the list. The Pfannkuchen, known as the Berliner everywhere else, is a jelly-filled donut derived from Kennedy's speech, 'Ich bin ein Berliner.' Only instead of the traditional jelly, this one has gooey, pudding-like chocolate on the inside, waiting to be unleashed. Another departure is that there are a few sprinkles instead of the dusty, sugary toppings that usually smother this treat. The times they are a changin'.
This is perhaps one of Prenzlauer Berg's best-kept secrets, at least for those who aren't native Berliners. With lines that can stretch out the door at various times of the day, there's a reason Bäckerei Siebert draws in the crowds. One of a few bakeries fighting for the 'oldest bakery in Berlin' title, this spot is aching with craftsmanship. It's the type of bakery that takes its time and refuses to rid itself of the qualities that forge baking excellence. With a few awards for its pastries under its belt, Siebert has made a name for itself. The Eierlikör Pfannkuchen is a chewy chocolate-glazed donut filled with creamy custard with a hint of brandy and is one of their best. However, they are also known for their other donuts as well as their golden pretzels.
In hip Kreuzberg, this family-run establishment has been serving X-berg all things sugary since the 70s. Their donuts come in at about a whopping 500 grams; calling them heavy hitters would be an understatement. Those who are seriously craving a hefty, properly crafted donut, can find solace in Bäckerei Ladewig. It is located just around the corner from Shlesi. With the myriad choices, it's hard to go wrong, but we recommend the cherry-filled glazed donut.
Bäckerei Ladewig, Bezirk Friedrichshain-Kreuzberg, Oppelner Str. 4, Berlin, Germany


text:
Family History
Our story started when Ed and Terry fell in love in 1983 in Layton, Utah. Over the next 30 years they would move dozens of times, raise seven kids, and spend many years apart while Ed served in the army overseas. As the kids started to leave and retirement grew closer Ed and Terry planned to create their forever home in Kanab, Utah. Two of their sons, Shawn and Jimmie, decided to join them there. In 2013 they bought the old Kanab Lodge and fixed it up. In 2014 Jake's Chaparral opened.
We Serve Buses
Jake's Chaparral primarily caters to tour busses. In our busy season we serve 15-20 busses a day. Our restaurant has 3 different dining areas with an overall capacity of 330 people. Our buffet menus are pre-ordered and prepared right before the busses arrive to keep food fresh and keep wait times minimal. Your passengers will enjoy a nice western atmosphere in our rustic dining hall with cowboy entertainment and western style menus. If you would like to learn more about making a reservation please e-mail us at email@example.com.
Jake's Chaparral does host large events when the tourist season slows down. We can accommodate large holiday parties, family or school reunions, or even your wedding reception. If you would like more information on scheduling your event with us e-mail


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- France take on Spain in the quarter-finals of Brazil 2019
- Isaac Lihadji is particularly keen to take part in the match
- An injury prevented the Bleuets winger moving to Spanish football six years ago
France-Spain has all the hallmarks of a classic duel of European – or even global – football. The two teams have met multiple times, in every possible age category, at UEFA European Championships (1984, 2000 and 2012) and in FIFA World Cup™ tournaments (2006). In short, it is usually a must-see fixture, and that description will be no different in Goiania, when the two nations lock horns at the FIFA U-17 World Cup Brazil 2019 on Monday.
"It's always an exciting game to play in," France's Isaac Lihadji told FIFA.com. "We're all pretty familiar with Spain. They're a great footballing nation. But we'll approach the match like we have all the others, without putting too much pressure on ourselves. That's worked quite well for us so far."
Although Lihadji appears calm and composed on the outside, he likely has a multitude of emotions bubbling away under the surface. In fact, the match against Spain has particular relevance for the young Marseille winger: he has always been an admirer of the Iberian country, but he also experienced a major personal disappointment there.
"I've always liked Spain, that's true," said the skilful Frenchman. "I love the way they play football. When I was a kid, I dreamed of signing for Barcelona. And I was actually very close to making that dream a reality in 2013, but in the end it didn't happen." Indeed, although he was on the verge of joining La Masia, Barcelona's youth academy, to pursue his football development, he unfortunately broke his leg, an injury that inevitably sidelined him for several long months.
"It was tough at the time, but it's totally behind me now," continued the talented No18. "I don't have any regrets. I'm very happy with my life at the moment in Marseille." It should be said that L'OM do whatever they can to ensure he is comfortable, and have already offered him a professional contract. Aware that the club might have a budding star on their hands, coach Andre Villas-Boas even handed him his Ligue 1 debut earlier this season. But for now, Lihadji's full focus is on Brazil 2019.
"Taking part in the U-17 World Cup is a dream come true," he explained. "But I've got an even greater one in mind – winning the competition. For now, we're just trying to make sure that our adventure continues, and for that to happen we have to keep winning our matches."
One of three ever-presents
And up to this point, that is what they have done – in fact, France have triumphed in all their games so far in Brazil. Lihadji (two goals, one assist), whose pace and technique on the right flank have impressed onlookers, has played a significant role in that success. He is one of three players (goalkeeper Melvin Zinga and captain Lucien Agoume the others) to have started all of Les Bleuets' matches at the tournament so far, and he is likely to get the nod again versus La Rojita, who appear more than ready to deal with the challenge posed by Lihadji and his team-mates.
"Isaac is a really good player – he showed that at the European U-17 Championship," said Spain forward Pablo Moreno. "We know France pretty well. We train hard so we can be ready to face any side, but we're aware that matches against a team of this calibre are often massively intense and eventful."
With two strong teams, a spot in the semi-finals at stake, and an on-song Lihadji starring, that is likely to be the case again on Monday.


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Hi All
I'm hopefully trying out a one shot of Forbidden Lands this weekend with some friends. It seems like something we could roll up characters for on the day and use tables to have an adventure along the way, but equally some preparation is usually good and have prepared encounters and knowledge of what characters you're dealing with in advance is normally good for showing a new game off. What's everyone's thoughts of this? If you were running something as a one shot, would you do the characters in advance? What about the exploration and locations? Are there any good pre-done resources out there (like a set of characters) that are tried and tested (and that I could just steal)?


text: The last of the rain passed through around 6:30 this morning, and with my coffee in hand I went to survey the work to be done on the mural. By 10am the wall was dry enough to paint. I took care of my touch up notes to adjust some colors before I began on the windows. An hour later I was mixing the window color and looking forward to finishing up today. No such luck. I did not have trouble with the wall that ran along the path. Rather, small rivulets of water randomly ran down the "off stage" section of the painting as the flower beds drained and pooled on the ledge above me. There is no way around it. I am going to have to wait a couple days after the last rain to get this section. Bummer because there is only 30 minutes or so of work left to finish, leaving only the text details remaining for Saturday. No point in fretting over it. I'll just head into the city to draw. Happy painting.


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NCERT Solutions For Class 12 Chemistry Chapter 5 Surface Chemistry
Topics and Subtopics in NCERT Solutions for Class 12 Chemistry Chapter 5 Surface Chemistry:
|Section Name
|Topic Name
|Surface Chemistry
|Classification of Colloids
|Colloids Around Us
NCERT Solutions CBSE Sample Papers ChemistryClass 12 Chemistry
5.1. Write any two characteristics of Chemisorption.
Ans: Pt and Pd form inert electrodes, i.e., they are not attacked by the ions of the electrolyte or the products of electrolysis. Hence, they are used as electrodes for carrying out electrolysis.
5.2.Why does physisorption decrease with the increase of temperature?
Ans: Physisorption is an exothermic process :
According to Le-Chatelier's principle, if T is increased, equilibrium shifts in the backward direction i.e., gas is released from the surface of solid.
5.3. Why are powdered substances more effective . adsorbents than their crystalline forms?
Ans:Powdered substances have greater surface area as compared to their crystalline forms. Greater the surface area, greater is the adsorption.
5.4.In Haber's process, hydrogen is obtained by reacting methane with steam in presence of NiO as catalyst. The process is known as steam reforming. Why is it necessary to remove CO when ammonia is obtained by Haber's process?
Ans: CO acts as a poison for the catalyst used in the manufacture of NH3 by Haber's process. Hence, it is necessary to remove it.
5.5.Why is the ester-hydrolysis slow in the beginning and becomes faster after sometime?
Ans: The ester hydrolysis takes place as follows :
The acid produced in the reaction acts as an auto catalyst for the reaction. Hence, the reaction becomes faster after some time.
5.6. What is the role of desorption in the process of catalysis.
Ans: Desorption makes the surface of the solid- catalyst free for fresh adsorption of the reactants on the surface.
5.7. What modification can you suggest in the Hardy Schulze, law?
Ans: According to Hardy Schulze law, the coagulating ion has charge opposite to that on the colloidal particles. Hence, the charge on colloidal particles is neutralized and coagulation occurs.
The modification to this law is :
When oppositely charged sols are mixed in proper proportions to neutralize the charges of each other, coagulation of both the sol occurs.
5.8. Why is it essential to wash the precipitate with water before estimating it quantitatively?
Ans: Some amount of the e lectrolyte are m ixed to form the ppt. Some of these electrolytes remains adsorbed on the surface of the particles of the ppt. Hence, it is essential to wash the ppt with water to remove the sticking electrolytes (or any other impurities) before estimating it quantitatively.
5.1. Distinguish between the meaning of the terms adsorption and absorption. Give one example of each.
Ans: This phenomenon of attracting and retaining the molecules of a substance by a solid (or a liquid) on its surface resulting into a higher concentration of the molecules on the surface is known as adsorption.
Absorption is different from adsorption. In absorption, the substance is uniformly distributed throughout the body of a solid or a liquid.
NH3 gets adsorbed on the charcoal where as NH3 when comes in contact with H20 gets absorbed by forming NH4OH solution of uniform concentration.
5.2.What is the difference between physisorption and chemisorption?
5.3. Give reason why a finely divided substance is more effective as an adsorbent?
Solution: Finely divided substance has large surface area and hence greater adsorption.
5.4. What are the factors which influence the adsorption of a gas on a solid?
Solution: The extent of adsorption of a gas on a solid depends upon the following factors:
(a) Nature of the adsorbate,
(b) Nature of the adsorbent,
(c) Temperature, and (d) Pressure.
5.5. What is an adsorption isotherm? Describe Freundlich adsorption isotherm.
Solution: Adsorption isotherm represents the variation of the mass of the gas adsorbed per gram of the adsorbent with pressure at constant temperature. Freundlich Adsorption isotherm:
Freundlich, in 1909, gave an empirical relationship between the quantity, of gas adsorbed by unit mass of solid adsorbent and pressure at a particular temperature. The relationship can be expressed by the following equation:
where x is the mass of the gas adsorbed by mass 'm' of the adsorbent at pressure P, k and n are constants which depend on the nature of the adsorbent and the gas at a particular temperature. The relationship is generally represented in the form of a curve where mass of the gas adsorbed per gram by the adsorbent is plotted against pressure. These curves indicate that at a fixed pressure, there is a decrease in physical adsorption with increase in temperature. These curves always seem to approach saturation at high pressure.
Taking log of equation (i), we get
5.6. What do you understand by activation of adsorbent? How is it achieved?
Solution: Activation of an adsorbent means increasing it's adsorbing power by increasing the surface area of the adsorbent by making it's surface rough, by removing already adsorbed gases from it and by subdividing the adsorbent into smaller pieces or grains..
5.7. What role does adsorption play in heterogeneous catalysis?
Solution: In heterogenous catalysis, generally the reactants are gaseous whereas catalyst is a solid. The reactant molecules are adsorbed on the surface of the solid catalyst by physical adsorption or chemisorption. As a result, the concentration of the reactant molecules on the surface increases further leading to increase in rate of reaction. Alternatively, one of the reactant molecules undergoes fragmentation on the surface of the solid catalyst producing active species which react faster. The product molecules in either case have no affinity for the solid catalyst and are deadsorbed making the surface free for fresh adsorption.
5.8. Why is adsorption always exothermic?
Solution: When a gas is adsorbed on the surface of a solid, its entropy decreases, i.e., ΔS is negative.
Now, ΔG = ΔH-TΔS For a process to be spontaneous, ΔG must be negative. As here, ΔS is negative, therefore, TΔS is positive ΔG can be negative only if ΔH is negative Hence, adsorption is always exothermic.
5.9. How are the colloidal solutions classified on the basis of physical states of the dispersed phase and dispersion medium?
Solution: Colloids can be classified into eight types depending upon the physical state of the dispersed phase and the dispersion medium.
5.10. Discuss the effect of pressure and temperature on the adsorption of gases on solids.
Solution: (i) Adsorption decreases with an increase in temperature since it is an exothermic process by applying Le Chatelier's principle the reaction will proceed in backward direction with increase in temperature.
(ii) At a constant temperature, adsorption increases with pressure.
5.11. What are lyophilic and lyophobic sols? Give one example of each type. Why are hydrophobic sols easily coagulated?
Solution: Lyophillic colloids (solvent loving) are those substances that directly pass into the colloidal state when brought- in contact with the solvent, e.g., proteins, starch, rubber, etc.
These sols are quite stable because of the strong attractive forces between the particles of disperse phase and the dispersion medium.
Lyophobic colloids (solvent hating) are those substances that do not form the colloidal sol readily when mixed with the dispersion medium.These sols are less stable than the lyophilic sols. Examples of lyophobic sols include sols of metals and their insoluble compounds like sulphides and hydroxides.
The stability of hydrophobic sol is only due to the presence of charge on the colloidal parties. If charge is removed, e.g., by addition of suitable electrolytes, the particles will come nearer to each other to form aggregate, i.e., they will coagulate and settle down. On the other hand, the stability of hydrophilic sol is due to charge as well as solvation of the colloidal particles. Thuf, for coagulation to occur easily both the mentioned factors have to be removed.
5.12. What is the difference between multimolecular and macromolecular colloids? Give one example of each.
How a re associated colloids different from these two types of colloids?
Solution: Comparison of some important characteristic of multimolecular, macromolecular and associated colloids.
5.13. What are enzymes? Write in brief the mechanism of enzyme catalysis.
Solution: Enzymes are complex nitrogenous organic compounds which act as a biological catalysts and increase the rate of cellular processes. According to the lock and key model, like every lock has a specific key, similarly every enzyme acts as a specific substrate.
When the substrate fits the active site (lock) of the enzyme, the chemical change begins.But it has also been noticed that enzyme changes shape, when substrate lands at the active site. This induced-fit model of enzyme action pictures the substrate inducing the active site to adopt a perfect fit, rather than a rigid shaped lock and key. Therefore, the new model for enzyme action is called induced fit model.
5.14. How are colloids classified on the basis of
(i) physical states of components
(ii) nature of dispersed phase and
(iii) interaction between dispersed phase and dispersion medium?
Solution: (i) Colloids can be classified into eight types depending upon the physical state of the dispersed phase and the dispersion medium.
(ii) Depending upon the type of the particles of the dispersed phase, colloids are classified as : Multimolecular, macro- molecular and associated colloids
(a) Multimolecular colloids: The colloids
in which the colloidal particles consist of aggregates of atoms or small molecules are called multimolecular colloids .
For Example: gold sol, sulphur sol etc.
(b) Macromolecular colloids : The colloids in which large particles of colloidal range having high molecular masses are dissolved in a suitable liquid are called macromolecular colloids.
Example: proteins, starch and cellulose form macromolecular colloids.
(c) Associated colloids (Micelles): Those colloids which behave as normal strong electrolyte at low concentration but show colloidal properties at high concentration due to the formation of aggregated particles of colloidal dimension's. Such substances are also referred to as associated colloids.
(iii) (a) Lyophillic colloids (solvent loving) are those substances that directly pass into the colloidal state when brought in contact with the solvent, e.g., proteins, starch, rubber, etc.
These sols are quite stable because of the strong attractive forces between the particles of dispersed phase and dispersion medium.
(b) Lyophobic colloids (solvent hating) are those substances that do not form the colloidal sol readily when mixed with the dispersion medium.
These sols are less stable than the lyophilic sols.
5.15. Explain what is observed
(i) when a beam of light is passed through a colloidal sol.
(ii) an electrolyte, NaCI is added to hydrated ferric oxide sol.
(iii) electric current is passed through a colloidal sol.
Solution: (i) Scattering of light by the colloidal particles takes place and the path of light becomes visible (Tyndall effect).
(ii) The positively charged colloidal particles of Fe(OH)3 get coagulated by the oppositely charged Cl– ions provided by NaCl.
(iii) On passing electric current, colloidal particles move towards the oppositely charged electrode where they lose their charge and get coagulated.
5.16. What are emulsions? What are their different types? Give example of each type.
Solution: Emulsions: It is a colloidal system in which both the dispersed phase and the dispersion medium are liquids, e.g., milk consists of small drop's of liquid fat dispersed in water.
Types of emulsions:
(a) Oil-in-water type in which small droplets of an oil are dispersed in water, e.g., milk, cod-liver oil, etc.
(b) Water-in-oil type in which water droplets are dispersed in an oil medium, e.g., butter.
5.17. How do emulsifires stabilise emulsion? Name two emulsifiers.
Solution: The role of an emulsifier in stabilising an emulsion can be explained in two ways:
(a) It is believed that an emulsifier gets concentrated at the oil-water interface i.e., the surface at which oil and water come in contact with each other. It forms a protective coating around each drop of oil and thus, prevents the oil drop from coming in contact with one another. The oil drops remain suspended in water and are not coagulated.
(b) According to an another view, the role of the emulsifier is the sjame as that of lubricant in a machine. Just as a lubricant reduces the friction in the various parts of machine, an emulsifier also tries to reduce the interfacial tension between oil and water by suitable means. Thus, oil and water remain in company of each other and do not get separated. The commonly used emulsifying agents are soaps, detergents, lyophilic colloids, proteins, gums, gelatin, caesin, agar etc.
5.18. Action of soap is due to emulsification and micelle formation. Comment
Solution: Soap is sodium or potassium salt of a higher fatty acid and may be represented as RCOO–Na+ (e.g., sodium stearate CH3(CH2 )16 COO–Na+ which is a major component of many bar soaps). When dissolved in water, it dissociates into RCOO– and Na+ ions. The RCOO– ions, however, consist of two parts – a long hydrocarbon chain R (also called non-polar 'tail') which is hydrophobic (water repelling), and a polar group COO– (also called polar- ionic 'head'), which is hydrophilic (water loving).
The RCOO– ions are, therefore, present on the surface with their COO– groups in water and the hydrocarbon chains R staying away from it and remain at the surface. But at critical micelle concentration, the anions are pulled into the bulk of the solution and aggregate to form a spherical shape with their hydrocarbon chains pointing towards the centre of the sphere with COO– part remaining outward on the surface of the sphere. An aggregate thus formed is known as 'ionic micelle'.
The cleansing action of soap is due to the fact that soap molecules form micelle around the oil droplet in such a way that hydrophobic part of the stearate ions is in the oil droplet and hydrophilic part projects out of the grease droplet like the bristles. Since the polar groups can interact with water, the oil droplet surrounded by stearate ions is now pulled in Water and removed from the dirty surface. Thus soap helps in emulsification and washing away of oils and fats. The negatively charged sheath around the globules prevents them from coming together and forming aggregates.
(a) Grease on cloth
(b) Stearate ions (from soap) arranging around the grease droplets
(c) Micelle formed
5.19. Give four examples of heterogeneous catalysis.
Solution: In heterogeneous catalysis, the catalyst is present in a different phase than that of the reactants,e.g.,
5.20. What do you mean by activity and selectivity of catalysts?
Solution: Important features of solid catalyst:
(a) Activity: The activity of a catalyst is its ability to accelerate chemical reactions. It depends upon the strength of chemisorption to a large extent.
The catalytic activity of a metal for hydrogenation increases as we move from Group 5 metals to Group 11. The maximum activity is shown by metals of Groups 7, 8 and 9.
(b) Selectivity: The selectivity of a catalyst is its ability to direct a reaction to yield a particular product. It mean a substance which acts as a catalyst in one reaction may not act as a catalyst in other reaction e.g., we get different products when we use different catalysts in the reaction between H2 and CO.
Question 21.
Describe some features of catalysis by zeolites.
(a) Zeolites are hydrated aluminosilicates which have a three dimensional network structure containing water molecules in their pores.
(b) The pores are made vacant by heating before catalysis.
(c) The reactions taking place in zeolites depend upon the size and shape of reactant and product molecules and also on the pores and cavities in them, e.g., ZSM-5 converts alcohols to hydrocarbons by dehydrating them.
Alcohols [latex]\underrightarrow { ZSM-5 }[/latex] Hydrocarbons
Question 22.
What is shape selective catalysis?
The catalytic reaction that depends upon the pore structure of the catalyst and the size of the reactant and product molecules is called shape-selective catalysis. Zeolites are good shape-selective catalysts because of their honeycomb-like structures. They are microporous aluminosilicates with three dimensional network of silicates in which some silicon atoms are replaced by aluminium atoms giving Al-O-Si framework. The reactions taking place in zeolites depend upon the size and shape of reactant and product molecules as well as upon the pores and cavities of the zeolites. They are found in nature as well as synthesised for catalytic selectivity.
Question 23.
Explain the following terms :
- Electrophoresis
- Coagulation
- Dialysis
- Tyndall effect
(i) Electrophoresis : Refer answer number 15 (iii)
(ii) Coagulation or precipitation : The stability of the lyophobic sols is due to the presence of charge on colloidal particles. If somehow, the charge is removed, the particles will come nearer to each other to form aggregates (or coagulate) and settle down under the force of gravity. The process of settling down of colloidal particles is called coagulation.
(iii) Dialysis : It is the process of removing dissolved substances from a colloidal solution by means of diffusion through a suitable membrane. Since particles (ions or smaller molecules) in a true solution can pass through animal membrane (bladder) or parchment paper or cellophane sheet but not the colloidal particles, the membrane can be used for dialysis. The apparatus used for this purpose is called dialyser. A bag of suitable membrane containing the colloidal solution is suspended in a vessel through which fresh water is continuously flowing. The molecules and ions diffuse through membrane into the outer water and pure colloidal solution is left behind.
(iv) Tyndall effect : Refer answer number 15 (i)
Question 24.
Give four uses of emulsions.
- Some of the medicines are effective as emulsions.
- Paints are emulsions which are used in our daily life.
- Soaps and detergents act as cleansing agents, action of which is based on emulsification.
- Photographic films are coated with emulsion of AgBr on its surface.
Question 25.
What are micelles? Give an example of a micelle system.
Micelles are substances that behave as normal strong electrolytes at low concentration but at high concentrations behave as colloids due to formation of aggregates. They are also called associated colloids, e.g., soaps and detergents. They can form ions and may contain 100 or more molecules to form a micelle.
Question 26.
Explain the terms with suitable examples :
- Alcosol
- Aerosol
- Hydrosol
(i) Alcosol : The sol in which alcohol is used as dispersion medium is called alcosol e.g., sol of cellulose nitrate in ethyl alcohol.
(ii) Aerosol : The sol in which dispersion medium is gas and dispersed phase is either solid or liquid, the colloidal system is called aerosol e.g., fog, insecticides, sprays, etc.
(iii) Hydrosol : The sol in which dispersion medium is water is called hydrosol e.g., starch sol.
Question 27.
Comment on the statement that'colloid is not a substance but a state of substance'.
Colloid is not a substance, but a state of substance because the same substance may exist as a colloid or crystalloid under different conditions e.g., sulphur. Colloidal solution of sulphur consists of sulphur molecules dispersed in water. In this state, sulphur atoms combine to form multimolecules whose size lies between 1 nm to 1000 nm and form colloidal state. Sulphur forms true solution in carbon disulphide. Similarly soap is a solution at low concentration but a colloid at higher concentration.
More Resources for CBSE Class 12:


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Financing Climate Adaptation Measures Using a Credit Trading Mechanism
06 March 2012
The Higher Ground Foundation is introducing a market-based mechanism to finance climate change adaptation projects in developing countries through "vulnerability reduction credits" (VRCs).
Adaptation projects would generate VRCs, allowing countries in the developed world to offset their current and past emissions by financing adaptation projects in the developing world, in fact creating a currency for a public good with possible demand beyond offsetting historic emissions. Thus the call for supporting climate adaptation in developing countries can be met in a flexible, efficient, and bottom-up project-level approach. This paper outlines this vision.


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If you haven't joined the grassroots home garden movement, it's nice to know you still can–and without spending a load of cash.
Ingenious Ideas for Thrifty Organic Gardening
If you haven't joined the grassroots home garden movement, it's nice to know you still can–and without spending a load of cash.
Economical Organic Home Gardening
Is organic gardening really all that difficult, or costly? We turned to our experts, Caitlin Blethlen of Growing Gardens and Mara Reynolds of Portland Community Gardens to see just how easy and inexpensive it can be to grow your own food organically.
GBG: In your opinion, are organic gardens more expensive to plant and maintain than those using pesticides and herbicides?
Caitlin: No. The basis of organic gardening is establishing healthy soil which can take time through using cover crops, and adding compost and creating a balanced eco system in your yard.
Mara: As far as I know, with the exception of the initial cost of seeds, organic gardening is cheaper all across the board. With proper planting techniques, composting, and soil amendments, you should be able to successfully garden organically with very little inputs. (To be honest I've never gardened with pesticides or herbicides)
Saving Money and The Planet With Reused Easter Baskets
For many families celebrating the holiday, an Easter basket is a once in a lifetime purchase. You may be picking one out for your baby this year for the first time. Why not recycle, save some money, and splurge a bit more on the chocolate bunnies?
You just wouldn't believe how many Easter baskets clutter the shelves of our local thrift store. There are hoards of pastel wicker containers stacked on top of each other, all priced reasonably. There are also decorations of all sorts including plastic eggs (not my favorite—but better recycled than new), stuffed rabbits of all sizes, and other odds and ends. Of course, after this past Monday's post, you can skip the plastic Easter grass and grow a real grass in your basket!
The Emergency Diapering/Snack Car Kit
You know how it happens: You're strolling casually through the grocery aisles when suddenly a horrible stench fills the air and you realize that your diaper bag is still sitting on the living room floor. What do you do?
Or you've just driven thirty minutes across town to run a set of coordinated errands only to have your little one erupt in sobs of hunger. But she just ate! You have no food, no spoons and now the choice to buy grub on the go or drive all the way back home.
We've had to buy baby food or toddler snacks, disposables, wipes and even a pair of pants once to deal with the short term emergencies created by our forgetfulness. While these events were funny and even a bit adventurous, we finally realized that we needed a more proactive solution.
Yumm Sauce Recipe Imitation
First of all, if you don't know what the amazing Yumm Sauce is, you'll have to check last week's post for details. It is a magical liquid that makes young and old alike beg for bowls of brown rice and beans–seriously!
Now I like to support our local Cafe Yumm just because I believe in their business and want to contribute, but some of you live across the country and will never be able to experience the wonder of Yumm Sauce for yourselves. Hence, the reason for today's recipe imitation.
This recipe comes from the site Chick Chat, written by a local mom right here in Eugene. I can take no credit whatsoever for the following recipe or its authenticity, but I hope it's as delicious as the real thing!
Repairing Diaper Covers
Want to repair your tired diaper covers for just a few bucks and an hour of your time? I learned how recently from my good friend Valerie Perrot. As she began to cloth diaper her second child, she noticed the covers she had used with her first weren't fastening correctly. Upon closer inspection, Valerie found that the soft part of the Velcro closures wasn't as deep as it should be. Considering that she had purchased the covers used, she wasn't surprised that they were worn–but she wasn't about to go out and buy a whole new set for her second child.
After getting advice from a seamstress, Valerie decided to take matters into her own skilled hands. She found an outdoor gear website called thegreenpepper.com that offered soft Velcro and heavy duty sewing needles for just under ten dollars. The Green Pepper has loads of patterns for making your own backpacks, fleece jackets and other notions, as well as fabric and materials. Honestly, the website is a bit difficult to negotiate, but they are very helpful if you call or email.
Cutting Costs in 2009: Part 2
For us, the craziness of life with a toddler takes over any moments we could use to reflect on our spending habits, but this is the perfect time to evaluate our family budget and make some positive changes. We aren't always thinking of our long-term goals or values when we run out to a big box store and come back with far more than we intended. But we'll start by acknowledging our progress this year.
1. What are our favorite thrifty green victories of 2008?
- Haircuts. I now cut Roscoe and Jett's hair every month in the comfort of our living room or our backyard. Since each of those cuts would cost around $15 a month, we're saving about $330 per year! In this photo, Roscoe's Aunt Pauli is giving me a few haircutting tips.
Welcome Back to the Thrifty Green Thursday Blog Carnival!
For most of us, going green isn't about quantum leaps, it's about tiny fledging steps that are made in the midst of our hectic lives as parents. If you have a budget-friendly, earth-friendly tip (even one that seems a bit obvious to you) you'd be a perfect addition to Thrifty Green Thursday.
What are the benefits of adding my post to the Thrifty Green Thursday carnival?
It'll help you generate traffic for your site, put you in touch with like-minded bloggers, and give you a chance to pick up some easy tips for going green on a budget.
How do I join the carnival and link my post?
Affordable, BPA-Free Sippy Cup Solutions
I wanted a BPA-free sippy cup for my son, but I heard so many complaints about leaks and design flaws from other mothers, that I was hesitant to shell out the cash. I was under the (misguided) impression that most BPA-free cups cost $15-20 dollars apiece, plus shipping, which was tough to swallow considering that I hadn't heard great reviews.
The Tightwad Gazette offered the simple, thrifty solution of having a child drink out of a cup after turning one. After all, what did people do before plastic was invented?
We tried instructing our child to gently sip with a straw, but a few dozen cups of spilled milk later, I felt we needed a better solution. Just then, I read a post on Green and Clean Mom announcing the happy news: Target now carries Munchkin BPA-free sippy cups for between one and three dollars! Eureka! In her post, Green and Clean mom apologizes for her wild enthusiasm about finding these cups, but I instantly shared her thrill.


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John Byrne is replaced by Mike Carlin. Just as well—this series wasn't very good. i applaud Byrne for trying and like that back in the 1980s Marvel could afford to allow a creator to try and fail, rather than cut it off after the first few issues.
What we get Is a font issue showing Thing fight Rhino. There's more to it than that—it's a real fun story—but that's the highlight. It ends with Thing turning Rhino over to Project Pegasus, after Rhino tells Thing he just wants to be human again—not stuck in his massive grey skin. (Nice opportunity fir some Thing-empathy there, coming right on the heels of him finding out that is best friend is dating his ex-fiancee.)
It is a good issue to transition to a new creative team.
We get an explanation on the letters page. Of course we now know that the she-hulk series referred to will be one of the most brown groundbreaking pieces of work John Byrne ever did for Marvel.
Creators: Mike Carlin and Ron Wilson/Joe Sinnot
Grade: C+
For the complete history of the MU, year by year, go here.
And see my Ratings of Runs on comics here.
rhino. guardsman.


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2002 Honda S2000
Started on May 17 by OEMTim
2002 Honda S2000 AP1
See more:
Jan 3, 2018 10:52 a.m.Austincrx:
- Another '02 driver! Lets hear about your mods! New swaybars F&R is a must, and only about $525 for a (pretty) good set!
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text: Located on the northern tip of the San Pedrito peninsula facing north into the breeze and views across the lagoon to the new water taxi terminal, these TWO waterfront lots on the point offer 292 ft water frontage, 11,500+ sq ft of space. Still considered to be a "local" neighborhood, there have been several new concrete homes built in the last two years as expats realize the potential for property value increases in this neighborhood less than ½ mile to the airport and town center. With lagoon front lots running $1,000 US per ft waterfront, these point lots stand out as an exceptional "buy & hold"! A true diamond in the rough with reclamation of land potential!


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A British computer security researcher once hailed as a "hero" for helping stem a ransomware outbreak and later accused of creating malware to attack the banking system said...Read more
A British computer security researcher once hailed as a "hero" for helping stem a ransomware outbreak and later accused of creating malware to attack the banking system said...Read more
Both members of the band Her's from Liverpool have died in a car crash while touring the US, their label confirmed on Thursday evening. Stephen Fitzpatrick and Audun...Read more
Chinese telecoms giant Huawei said revenues topped $100bn in 2018 despite a US-led campaign against the business on fears it poses a security threat. The firm said revenue...Read more
A payment processing firm that used to be owned by Royal Bank of Scotland has been sold in a deal worth $43bn (£32bn). WorldPay has been bought by...Read more
The United States and Saudi Arabia have hamstrung global efforts to scrutinise climate geoengineering in order to benefit their fossil fuel industries, according to multiple sources at the...Read more
The first official trailer for the final season of Game of Thrones has landed, and it's clear that everyone is gearing up for the fight of their lives....Read more
The transatlantic skies could become a little more crowded as US airline JetBlue considers launching new routes from New York and Boston to London. The 20-year old company...Read more
The United States was drawn to play Ukraine, Nigeria and Qatar in the Under-20 World Cup in Poland. The U.S. coached by Tab Ramos opens Group D play...Read more
Oil prices rose on Monday as Washington and China appeared to edge closer to a trade deal, dampening fears over the outlook for global economic growth. International Brent...Read more
In October, Twitter said it is redesigning conversations on the platform in an effort to encourage friendlier and more useful discussions. Now the company is ready to test...Read more


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In 1989 I volunteered with the campaign to pass a bond issue for Colorado Springs School District 11. Despite the district's obvious needs, the ballot issue failed at the polls. While dejected volunteers tried to console each other at what was meant to be a celebratory occasion on election night, Douglas Bruce crashed the party.
As you might expect, he had opposed the measure.
"What?" he said. "No cookies and cake for visitors?"
Bruce had led a campaign of disinformation, replete with fake news and counter-factual assertions — in other words, lies. The city's economy was shaky, the anti-public school right was gathering strength locally and a majority of voters bought into Bruce's fabrications.
I knew then that Bruce was a relentless, intelligent and vicious politician. I thought that city voters would soon understand the error of their ways and ignore his anti-tax screeds, but I couldn't have been more mistaken.
Two years later, Bruce persuaded Colorado Springs voters to approve a tax-and-revenue-limiting charter amendment that turned out to be the first iteration of the statewide Taxpayer's Bill of Rights amendment. At the same election, city voters also OK'd another Bruce-authored measure that phased out a half-cent sales tax earmarked for capital improvements.
That 1991 election still resonates. Bruce's charter amendment led to a quarter of a century of public sector underinvestment.
"If that capital improvement tax had remained in effect," said Mayor John Suthers at a recent pre-election forum sponsored by Leadership Pikes Peak, "we would have had nearly a billion dollars for infrastructure — for roads, for stormwater and everything else."
But egged on by Bruce, voters decided to kick the can down the road, and let someone else pay for it.
That's been a common (but not invariable) theme in local politics, and Bruce has always been there. Interestingly, he always reads from the same script, makes the same unsubstantiated charges and often succeeds.
Makes sense, I guess. If the rubes still love your shtick, why change it?
Last week's forum (which I moderated) featured debates on the proposed city stormwater fee and District 11's mill levy override (see page 16). Suthers and Laura Carno spoke for and against (respectively) the stormwater fee, while Lauren Hug and (you guessed it!) Douglas Bruce discussed the D-11 issue.
The latter was an interesting match-up, one that seemed to pit future against past, optimism against pessimism, young against old.
Hug, an articulate, enthusiastic 30-something attorney whose children attend D-11 schools, spoke of D-11's triumphs and challenges, of eager students and dedicated teachers stuck in buildings with an average age of more than 50 years, many without modern HVAC systems or air conditioning. She noted the effects of the statewide teacher shortage as well as the rapid changes in education, technology and workplace environments in the last two decades.
Bruce recited his standard tropes. D-11 has plenty of money, but it's all used to fund useless government administrative employees. Saying that the tax increase is "for the children" is false — "D-11 holds little children captive for the purpose of enriching D-11. They want more money from struggling families."
In one of the more interesting segments of the debate, Bruce railed against the city's 8.25 percent sales tax. Ironically, the 1991 Bruce-inspired phase-out of the Capital Improvements Program tax made necessary the .625 percent "road tax" and the stormwater fee, so Bruce bears some responsibility for that 8.25 percent total sales tax rate (including levies from the state, county, city and the Pikes Peak Rural Transportation Authority).
During and after the debate, Bruce was in fine fettle. Despite his recent travails (a couple of stints in the slammer for tax evasion and parole violation) the old warrior still has plenty of rhetorical tricks. At the beginning of the debate he announced that he would sit rather than stand to debate, because it put him on the same level as his listeners.
Bruce is our own Don Quixote, brandishing a rusty sword, and still spoiling for a fight. Good for him — but bad for our city.


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Developer Toolkit for Electric Mobility
With more and more electric vehicles on the road, new challenges arise for drivers: How far can I go with one charge? How do I maximize my battery use? Where and when can I charge? With TomTom Maps APIs and SDKs, any developer can address these questions and help EV drivers forget about range anxiety. See what you can build!
Build an EV route planner that gives EV drivers all the information they need to travel any distance. Use the TomTom Routing API to accurately estimate how much energy is required for a trip using parameters specific to the vehicle. Add our exclusive eco-routing feature to calculate energy-efficient routes with accurate battery consumption calculations, even taking into account the route profile and expected traffic. For longer trips, use the TomTom Long Distance EV Routing API to show where and when to charge along the way.
Enable drivers to easily plan a route with optimized EV charging stops on the way. By defining the chargingMode, drivers can calculate the most optimal route based on the vehicle's specific charging behavior.
Drivers can calculate the most energy-efficient route based on accurate battery consumption calculations, and maximize how far a vehicle can go by setting the vehicleEngineType parameter to electric and routeType to eco.
Common routing parameters such as acceleration and uphill efficiency can be used to define an advanced electric consumption model. This is needed for precise EV routing and reachable range calculations.
See in which areas of the world we can calculate routes for electric vehicles.
Help EV drivers find compatible and available EV charging stations nearby or along their route using the TomTom Search API.
Help drivers find EV charging stations. By specifying a connectorSet, results can be restricted to only show EV charging stations that support the relevant connector type.
Show drivers relevant EV charging stations along the route.
Help drivers find EV charging stations around specific locations before a trip, or find the closest station at any time while driving.
Check the availability of EV charging stations. Results can be restricted to only show the EV charging stations that matter to the driver, based on availability, location and connector type.
See in which areas of the world we have information about EV charging stations and their real-time availability.
Take range anxiety out of the EV driving experience. Use the TomTom Routing API to show EV drivers how far their vehicle can go with the current charge. Combine it with the TomTom Search API to show available EV charging stations within their reachable range.
Show EV drivers how far they can go. Use calculateReachableRange request to get a reachable range polygon based on the specific electric consumption model, terrain characteristics and traffic.
See in which areas of the world we can calculate reachable range.
Check out our blog and tutorials for tips and tricks on how to use our APIs and SDKs to build apps for electric vehicle drivers.
Discover TomTom Maps SDK for AndroidGet started
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Benefit from 2,500 free transactions per day on all TomTom Maps APIs. If you are also developing mobile applications, check out our SDKs for Android and iOS to benefit from unlimited free maps and traffic flow tiles!


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for the nth of times, i've been planning and drafting a blog post in malay but i ended up screwing everything for i cannot write like how i speak..for the love of God, i really REALLY need to practice my malay writing..this is beyond embarrassing 😦
anyway, i was tweeting with a friend..nothing serious..he was describing about the weather there and he's been fortunate enough to see some "up-skirt" scenes 😛 so i jokingly teased him that he should really get married because he couldn't seem to be able control himself to behave 😆 then he replied something like "nobody wants me" with a sad face..awww~ 😐
he caught me into thinking – how could that be..?i mean, how could he be so certain that nobody would like to take him as her boyfriend or a better half..?he's a man, the gentleman..so to me, really, it's more logical for the reason to be he's being very selective in considering somebody to be special to him..alright i'm not talking about the person i communicated with specifically, but this could be a possible generalisation for guys, really..
no matter how modern the technological advancements evolve and take the society into a highly civilized nation, most people would choose to remain conventional when it comes to finding a suitable partner i.e it's always the guys who have to "chase" after the girls..and most girls really think it's such a HUGE embarrassment if she has to confess to the guy that she likes him..it's even beyond humiliating if the confession doesn't turn out successful..so yea, we do believe that the first move should come from the guys..
so no guys, it's not that nobody wants you, it's just nobody sees you as paying extra attention to anyone and of course, why should they respond to something uncertain and risk themselves on unnecessary embarrassment..?
it's more logical if the single girls say that nobody wants her rather than accusing them for being too fussy in choosing a partner..they really could list down some endless criteria for a partner and work their asses off into finding such a person (dressing up to work, acting demure and graceful, showing some brain achievements etc) but the question remains – could we get it..?
should i list down my criteria as an example here to make you understand..? 😉
but yea, girls don't really have the authority to make the first move..the nature is sort of hindering us from doing it for it will be going against our demure femininity..
the most that girls can do is to give a subtle hint like being concern or purposely let her stare gets caught up..but sometimes guys are too dumb to pick up the hint..and as for guys..gosh..girls would always notice it even if your hint was feather-subtle but they'd not get involved as they couldn't see any determination..who'd want to risk embarrassment on something so uncertain..?but we hate it too if you get too confident because it simply annoys our ass off..it only tells us you're capable of doing/saying the same things to every other girls..and nope, girls don't like even an inch of risk of compromise..


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Our Autumn Groups Guide is out now! Click here to view.
Created specifically for tour operators, social clubs and group bookers of 10 or more, our Groups Guide is a quarterly guide to live entertainment across the UK.
The guide now features content opportunities as well as a chance to advertise events with group rates, as well as features, interviews and event information.
The guide is available digitally now. If you'd like a physical copy, please contact our sales team using the online form.


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I learn best by seeing and then doing, but the PT and I have an agreement that if it involves manipulating Isaiah himself, then I'll do that (if anyone is going to break him, it'll be me...and I don't plan to go too far passed his comfort zone).
This week his PT showed me how to position Isaiah better in his chair. It is cushions and blankets galore.
The goal is to bring his shoulders forward.
Woah, look how long my arms look mom!
I'm working on that now whenever Isaiah is in his chair...
Just trying to eat my monkey friend's face, nothing to see here...
The big thing that we worked on, the thing that made me nervous...is putting Isaiah on his SIDE. I do this when he's on me, but I've never manipulated him to his side in the play pen, and we've got to get this kid off of his back as much as we can (hopefully tummy time is in the near future...we're waiting until after this next PAM treatment)
Here he is the very first time on his SIDE!
Are you people serious??? What are you doing to me, ladies?!?
As you can see, he wasn't so thrilled with it. It lasted maybe 5 minutes. But this morning, now that Isaiah is feeling better after his little breathing episode yesterday and a night of restful sleep, I got brave...
Ooooh, this position isn't so bad.....woah, that seahorse guy that plays music has a belly that lights up? How did I never see this before?
Hmmm, I wonder if I can reach you...
Holy Cow! YES! I CAN touch you! This is SO AWESOME! MOM, take my picture from every angle possible!!
Ok, Isaiah... (proud-mommy-armed-with-a-camera-alert)
aaaaaaaand sleepover.
So, I'm not sure if you can tell, but I'm pretty excited that we're getting Isaiah off of his back and REACHING for toys! We're just so proud of him. He was so comfortable that he fell asleep! He ended up staying in this position for about an hour; that's a big improvement. Next time, we'll try laying him on his left side, just to mix it up.
Happy weekend all!


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Hey everyone!
I'm Jess and i'm here to talk about makeup, beauty, and plus size fashion. As a uk size 16-18 and a self confessed beauty addict, I thought I'd share my experience with you guys! I'm obsessed with trying new beauty products so you'll see a lot of that on here, along with my fave products and beauty box unboxings and hauls!
I'll also be posting reviews of products, tutorials, outfit inspo and general musings.
A little bit more about me: I'm a massive nerd, and love anything geeky and Sci-Fi. Lately I started watching Anime, and I now have a newfound love for it! I'm training to become an accountant, so I'm busy basically all the time, but I still make time for blogging! I'm also a lipstick addict, and my collection has overflown from the makeup bag I keep them in and into my vanity drawer! Note to self: buy larger bag to keep lippies in!
To write to me about potential PR or opportunites, or if you just want to chat, you can find me at
Hope you guys like it!
Ciao for now,
Twitter! @Jessica_Simone1 || Instagram: Beautybyjessblog || Youtube Channel ||
Want to get in touch with me? Send me an email at email@example.com


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10 Tips for passing your Theory test
Keeping in mind that the ultimate goal of preparing for your driving theory test is to make sure you're a competent and safe driver, here
Simply click or dial the number below to be connected to use the service.
Calls cost £1.50 connection fee plus £1.50 per minute plus your phone provider's access charge.
This website and telephone connection service number is operated by 118 Connect Ltd and is not affiliated with, or operated by, DVLA. A direct number can be obtained from DVLA's website at no or lower cost by clicking here. If you do not wish to use this premium rate connection service, are disconnected or put on hold, we recommend you call using a direct number which can be found in the link above. Callers must be over 18 and have the bill payer's permission.
Service provider helpline: 03303327663
The DVLA customer service team can be contacted by telephone using our connection phone number which is charged at a premium rate, alternatively you may contact them directly at no or lower cost using their helpline, or other contact details, provided on their own website.
There are many reasons you may wish to contact DVLA. This may be a simple query, or you may wish to discuss a complaint, or perhaps you just need some assistance. Many things can be handled over the telephone but some matters may need to be handled in person or in writing.
When you call to speak with a customer support representative, they are there to assist you with your phone call and provide support and help with many problems you may have over the telephone. If you are put on hold, in a queue, or expect your call to last for a while we suggest that you may instead wish to contact DVLA using their direct telephone number rather than our connection service as this will be less costly.
Keeping in mind that the ultimate goal of preparing for your driving theory test is to make sure you're a competent and safe driver, here
Things You Need To Know About Getting A DVLA Personalized Number Plate Many people considering getting a DVLA personalised number are discouraged by the fact
Unlike the old paper licences, UK photocard Driving Licences need to be renewed every ten years to keep the photograph current. According to the DVLA,
Updating addresses after moving is something most people have to do and changing the address on a driving licence is one of them. After you
Driver and Vehicle licensing agency is the executive agency Department for Transport that is located in Swansea. This agency is responsible for vehicle and driver
Vehicle Excise Duty (Car Tax) Car tax is expected to rise in 1st April in the United Kingdom which marks the third increase in vehicle
DVLA Head Office
Longview Road,


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When most telecom and cable companies across the US are charging exorbitant rates for mediocre, capped broadband, Google charges only $70 (plus taxes) per month for its Gigabit broadband service – Fiber. The service was first introduced in Kansas City, MO, but the tech giant from Mountain View, CA has been quietly expanding the footprints of the service over the past few years. Google Fiber is already available in several towns across the length and breadth of the country, and now, Google has some good news for internet users in The Heart of Dixie. The company, on Monday, announced that it intends to start operations in the town of Huntsville, Alabama, using infrastructure that's being built by Huntsville Utilities. While Google has not officially announced when it will launch its services in the city, some sections of the local media are reporting an ETA of mid-2017.
While Huntsville is by no means the first city in the Deep South slated to get Google Fiber, it will most definitely be the first in the state of Alabama to get the enviable new internet service from Google. The service is currently available in just four metropolitan areas in the US, including Provo, UT; Austin, TX; Atlanta, GA and Kansas City, MO. Google has also confirmed that it will launch its services in a whole host of other towns including Charlotte and Raleigh-Durham, NC; Nashville, TN; Salt Lake City, UT; San Antonio, TX and now, Huntsville, AL. The company, however says that unlike in most other areas where it is building its own infrastructure from scratch (with a few exceptions), it will be "working with a municipality-owned network to bring our high speed service to Huntsville".
As mentioned already, Google is not building its own infrastructure in Huntsville, unlike most of the other cities where it is rolling out the services. The company generally builds out its own optic fiber network for its FTTH connections in most areas where Fiber's operational, but the company does point out some notable examples to the contrary. According to the official Google Fiber blog, the company apparently purchased the entire optic fiber network from the city to roll out its services in Provo, Utah. Meanwhile, in Atlanta, Google tapped into some existing fiber infrastructure in select areas, although most of the fiber network in the city is actually its own. It remains to be seen how long it takes for Google to finally start services in Huntsville, but residents in the area will be hoping that it will happen sooner rather than later.


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The Great British Bake Off is back on our screens and in true bake-off style here at Aeromark we wanted to embrace our hidden talents.
On September the 17th Charlotte and Lizzy held a homemade bake sale in aid of Alzheimer's Society. Many members of our team contributed to the sale by creating different delicious bakes, which were later sold for a small donation amongst the team. Once we were all too full to eat anymore the girls gathered the unbought cakes and donated them to the Kings Arms Project, a local homeless shelter in Bedford, so that no goodies went to waste.
Here at Aeromark we like to not only help one another but help our local community and charities close to our hearts.


text: |Hi! I'm Denise, 22 years old and I play the flute. I am in the second year of the Masters Molecular Life Sciences. Upcoming year I will be the treasurer of QHarmony. I hope to make the upcoming year a fun year with beautiful concerts and fun activities!If you want to get in contact, you can email me.


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Homemade Hemp Milk 3 Ways
Homemade Hemp Milk 3 Ways! Make your own hemp milk with no straining required using 2 to 3 ingredients! A delicious dairy free alternative...
Turmeric contains antioxidants, vitamins, and nutrients that are attributed to over 600 potential health benefits. It's powerful nutrition that encourages normal joint function, cardiovascular health, colon health, brain function, & liver health.
It supports the adrenal glands, red cell formation, and helps convert carbs into glucose thus giving you energy. It's a major supporter of your cardiovascular and nervous system.
Blending up soups, smoothies, dips, and sauces becomes second nature when you have an efficient easy to use kitchen appliance such as the Vitamix.
This processor has multiple optimized speeds and stainless steel blades that help slice, shred, puree, and chop food quickly, easily, and quietly.


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Telehouse East India
Client: Mace
Location: London
Project Value: £1,250,000.00
Total Project Programme: 40 weeks
Completed: Nov 2017
Management – Provide a full time manager responsible for program, support of our design team and organising the daily running of the project.
Internal - Face block work forming plant rooms, loading bay, meet me rooms, data rooms, internal corridors and back of house storage to the ground floor and the Mezz floor. All works included for the design and installation of block work support wind posts.
External – Face brickwork/blockwork cavity walls in Staffordshire slate blue's with black mortar to the ground floor, including plants, ramps and walk ways. All finished with bullnose special bricks
Project Details
Dave Scannell
RIW Site Manager
Mark Simpson
RIW HSEQ Manager


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City of Gig Harbor hosts Dignitaries for Special Ribbon Cutting
Gig Harbor, Wash., May 21st, 2015 – On Saturday, June 6th, at 11am, Gig Harbor's Mayor Jill Guernsey will host United States Senator Maria Cantwell and United States Congressman Derek Kilmer for a special ceremony and ribbon cutting for the Gig Harbor sandspit and lighthouse property. The event will take place at the sandspit, located at the mouth of Gig Harbor bay. The public is invited to attend the ceremony via marine access only.
The City invited Senator Cantwell and Congressman Kilmer to celebrate this momentous occasion after many years working to acquire the property, in which they were both instrumental during the process. The land, which is currently under the jurisdiction of the U. S. Coast Guard, became available after the Howard Coble Coast Guard and Marine Transportation Act of 2014 passed Congress in December. The Act included a provision transferring ownership of the property surrounding the lighthouse to the City of Gig Harbor.
The City of Gig Harbor would eventually like to have a park on the sand spit on which the lighthouse stands. Due to surrounding private property, the park would be a marine park accessible only from the water.
For more information about the ribbon cutting event, please contact Shawna Wise at the City of Gig Harbor at (253) 853-7638.
Gig Harbor – Washington's Maritime City. www.gigharborguide.com.


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This 2017-2018 flu season has been a rough one for seniors and others who have a compromised immune system. According to statistics from the Center for Disease Control, the most predominant form of flu virus seen this season in seniors is the influenza A (H3N2) strain, representing 87.8% of the viruses represented among those 65 and older. Seniors who live in nursing homes as opposed to a home setting are more likely to be exposed to the flu virus since they share an environment with dozens of other residents and staff. What does this mean for your loved one in a nursing home?
The influenza strain H3N2 is particularly dangerous for seniors and children and results in more deaths and hospitalizations than other types of the flu virus. According to data from the National Center for Health Statistics, just over 8% of senior deaths occurring the week ending January 13, 2018, were the result of influenza and pneumonia, a statistic that is higher than normal. But nursing homes are combating the potential problem by taking a proactive approach to minimizing the spread of the virus and preventing seniors from being exposed to it at all.
Government Safety Plans
In a facility where many people share the same common space, the government requires strict adherence to regulations meant to minimize the impact of the flu. Group-living homes are compelled to report two or more flu cases to the county or local health board. In this way, nursing home staff and administrators can be provided with antiviral drugs and preventative measures to keep the virus from spreading throughout the community. This early containment is vital since even healthy seniors have a lower immune system than the average adult. Those who are on medication or have cardiovascular disease, diabetes or other medical conditions are even more susceptible.
Minimizing The Impact Of The Flu
Many nursing homes in the country focus on preventing resident exposure to the flu by emphasizing hand-washing and minimizing visitors to the facility. But this doesn't keep the flu at bay. Once an influenza case has been confirmed, the job of the nursing home staff becomes stopping it from spreading. One way to contain the flu is to reduce the chance for seniors to interact and spread the virus. This can be done in many ways:
- Keep seniors contained in their rooms
- Quarantine those seniors who are ill
- Treat residents with Tamiflu, which is known to reduce the duration of the flu by a day or two
- Provide flu and pneumonia shots to seniors who haven't had their yearly immunizations
- Limit group/social activities during local outbreaks
While keeping seniors relegated to their rooms may seem like an extreme step, it has been done successfully in many areas of the country. For example, at Poway's Villa Pomerado Convalescent Care Center in San Diego, residents were put in lock-down at the beginning of 2018 after 92 residents tested positive for Influenza A. This has served to keep residents from passing the virus to other residents and kept many vulnerable residents out of the ICU.
Past The 2017-2018 Flu Season
Flu season in the United States usually runs from October through May, with peaks between December and February). This means that there is still a month of peak activity to anticipate. If your senior loved one is living in one of the thousands of nursing homes across the country, chances are high that the flu will impact his nursing home at some point this year. You can ensure the health of your loved one by being vigilant; contact the nursing home administration and ask about the measures they are taking to combat this year's flu outbreak, and don't be afraid to bring up deficiencies you notice while visiting your loved one.


text: Mixtape Madness Mixtape Madness | CB MAB Review (Video) July 24, 2018 Share this:TwitterFacebookLike this:Like Loading... Post navigation ← The 90s Room | My Housewife And Kids (Video) Mixtape Madness | Yxng Bane & DBE Mixtape Review, Not3s Vs His Label Relentless (Video) → About 90sbabyshow 90s Baby Show is a short Podcast brought to you by Fred & Temi discussing both modern day and past life experiences from a 90s baby perspective. Prepare to laugh, reflect, disagree, and open your mind to a 90s baby's point of view Twitter: Follow @90sbabyshow Follow @fr3dsantana Follow @temiAlchemy View all posts by 90sbabyshow → Leave a Reply Cancel reply Enter your comment here... Fill in your details below or click an icon to log in: Email (required) (Address never made public) Name (required) Website You are commenting using your WordPress.com account. ( Log Out / Change ) You are commenting using your Google account. ( Log Out / Change ) You are commenting using your Twitter account. ( Log Out / Change ) You are commenting using your Facebook account. ( Log Out / Change ) Cancel Connecting to %s Notify me of new comments via email. Notify me of new posts via email. Basic HTML allowed.


text: LinkedIn App Upgrades For Smartphone & iPad Mobile Users LinkedIn, the world's largest professional social network with more than 175,000,000 members in over 200 countries, recently updated their Android and combo iPhone plus iPad apps, to entice mobile users for more engagement. Their website will be rolling out similar features to its users over the next few weeks. Real-time is a must in today's… Read More


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Italy's Milan/Cortina elected host of 2026 Winter Olympic Games
LAUSANNE, Switzerland -- Italian cities Milan/Cortina were elected host of the 2026 Winter Olympic Games at the 134th session of the International Olympic Committee (IOC) here on Monday.
IOC President Thomas Bach announced Milan/Cortina as the winner after they beat Sweden's Stockhom/Are 47-34 in a vote by 83 IOC members.
Giovanni Malago, President of the Italian National Olympic Committee, was emotional after the victory.
"We have so many things to say but I am very really emotional," he said at a press conference. "This is a very important result, not only for me, but for the whole country.