text:
Logistic Companies Looking For Expansion
Companies in logistic sectors are hiring more people in the current year, the major factor driving the hiring process in new cities are latest rounds for funding and road map for expansion.
Shorting and Packing centre will experience hike of 20-25% in middle and last-mile delivery, as stated the recruitment companies Quess and PeopleStrong. Fleet and warehouse managers, loading supervisors and seafarers are considered to be secondary demanded perofiles.
TeamLease report stated that, overall employment in logistic is expected to reach an estimate of 14 million in the year 2022 from 11 million in the year 2018. Warehouse is exclusively expected to create 1,20,000 of new jobs. In the current year infrastructural development, boost in governmental policies, and the advancement of technologies are considered to be the major drivers of job growth in the logistic sector. Salaries paid to the employees will be from 15,000 to 18,000 per month and it will go up to 25,000 to 30,000 in peak seasons.
"This sector has been largely unorganized thus far, but 2020 is expected to bring in more consolidation as well as expansion in tier II and III cities, in turn leading to increased hiring," said Quess- India region chief operating officer Guruprasad Srinivasan. The recruitment company currently has about 10,000 people deployed in logistic start-ups and expects a 15% increase in mandate this year with a majority of the job roles in sorting and packing centres and middle and last-mile deliveries, he said.
"We will be hiring in junior middle positions, as well as 2-3 key leadership hires. We will also be exploring technology hiring outside India," Robinsons Chief Executive, Aditya Vazirani said.
PeopleStrong estimates that e-commerce companies are the major driving source for logistic outsourcing. The domains which will be hiring more this year are technology, analytics, and artificial intelligence as compared to frontline operation hiring over the last year.
Flipkart which is owned by Walmart, invested USD 60 million in last-mile logistic start-up named as Shadowfax. The company is planning to expand its operations, strategy and growth teams across India as well as in China.
Many logistics companies have seen growth in Series C and above stages and overall confidence in these start-ups is positive," Xpheno cofounder Kamal Karanth said.


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ABSTRACT: Magnesium is an ideal metal anode that has nearly double the volumetric capacity of lithium metal with a very negative reduction potential of −2.37 vs SHE. A sig- nificant advantage of magnesium is the apparent lack of dendrite formation during charging, which overcomes major safety and performance challenges encountered with using lithiumDownloaded by UNIV OF NEBRASKA-LINCOLN on September 1, 2015 | http://pubs.acs.org
increase the energy density of lithium ion batteries is to Table 1. Mg Cycling Efficiency and Oxidation Potentials of increase the capacity of the cathode. Because Li+ and Mg2+ have THF Solutions Containing Different Combinations of R2Mg roughly the same ionic radius (0.9 Å vs 0.86 Å, respectively), and AX3−nR'n Types of Lewis Bases and Lewis Acids, assuming the same number of cations can be inserted into Respectively, at Different Ratios, As Indicateda the same cathode host, intercalation of Mg2+ with double the Lewis Lewis acid/base Mg cycling electrolyte charge of Li+ would result in doubling the capacity of the base acid ratio efficiency decomposition potential cathode. Recently, research to double the energy density of Bu2Mg AlCl2Et 1:2.00 95 2.10 lithium ion batteries has been aimed at inserting two Li+ cations Bu2Mg AlCl2Et 1:1.75 95 2.05 into the cathode, preferably accompanied by a two electron Bu2Mg AlCl2Et 1:1.50 97 2.00 reduction at the same metal center.8−12 The challenge of Bu2Mg AlCl2Et 1:1.25 94 1.90 inserting two lithium cations for every transition metal center Bu2Mg AlCl2Et 1:1.00 96 1.80 is not trivial due to volume expansion of the intercalate, which Bu2Mg AlCl2Et 1:0.75 95 1.65 can lead to severe distortions of the crystal lattice and pulveriza- Et2Mg AlCl2Et 1:2.00 92 2.25 tion of the host. Unfortunately, attempts to insert Mg2+ have Ph2Mg AlCl2Et 1:2.00 80 2.08 been hampered by the higher ionic charge density that results Bz2Mg AlCl2Et 1:2.00 88 2.15 in slow solid state diffusion. In this Perspective, we detail recent Bu2Mg AlCl3 1:2.00 75 2.40 research aimed at discovering a high voltage insertion cathode Bu2Mg AlCl3 1:1.75 74 2.30 or high capacity conversion cathodes.Downloaded by UNIV OF NEBRASKA-LINCOLN on September 1, 2015 | http://pubs.acs.org
Figure 1. Comparison between the voltammetric behavior of THF solutions containing 0.25 M of the reaction product between 1:2 MgBu2 and AlCl2Et (DCC) (black line) and 0.4 M of the reaction product between 1:2 AlCl3 and PhMgCl (designated APC) (red line) as indicated. Conditions: 25 mV s−1, Pt wire working electrode, 25 °C. Right insert: Enlargement of the cyclic voltammograms near 0 V vs Mg R.E., comparing the overpotential for Mg deposition in the two solutions. Left insert: Charge balance upon typical Mg deposition−dissolution cycles in these solutions (100% cycling efficiency of Mg deposition). Reprinted with permission from ref 30. Copyright 2007, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Figure 2. (A) Cyclic voltammograms of HMDSMgCl (green), the reaction product generated in situ from a 3:1 mixture of HMDSMgCl to AlCl3 (blue), and the crystal obtained from a 3:1 mixture of HMDSMgCl to AlCl3 (designated GEN1) (red). Inset shows the charge balance during the deposition and the subsequent dissolution of Mg. Reprinted with permission from ref 20. Copyright 2011, Nature Publishing Group. (B) Cyclic voltammograms of 0.4 M THF solution of the reaction product generated in situ from a 2:1 mixture of Bu2Mg to EtAlCl2 (DCC) (blue) and of the crystal obtained from a 2:1 mixture of Bu2Mg to EtAlCl2 (crystallized DCC) (red). Scan rate is 0.025 V s−1. Reprinted with permission from ref 20. Copyright 2011, Nature Publishing Group.
battery, which requires magnesium electrolytes with a higher by varying the salt:solvent combination and ratios. This way, oxidative stability. Aurbach's second generation electrolyte APC each and every component of the electrolyte can be individually enhanced the oxidative stability of DCC by substitution of selected for a particular purpose. Desirable magnesium electro- the alkyl group with aromatic groups, which excludes β-H lytes are those that share the strict level of control available in elimination as a possible route to oxidative decomposition.31 the design of lithium electrolytes. However, in situ generated This electrolyte is readily generated in situ via the reaction of magnesium organohaloaluminates are complex soup mixtures one equivalent of aluminum trichloride with two equivalents of operating under dynamic equilibria that can result in formation phenyl magnesium chloride. This significantly enhances the of unwanted components. For example, the in situ generated reported oxidative stability from 2.2 to 3.2 V vs Mg on a electrolyte APC contains both corrosive and nucleophilic com- platinum working electrode and attains a Coulombic efficiency ponents that prohibit the use of aluminum current collectors32 of 100% (Figure 1). or conversion cathodes such as sulfur.20 One way to control the In lithium ion batteries, electrolytes are prepared by dis- effects of unwanted components in magnesium electrolytes is solving a lithium salt such as LiPF6 in organic solvents (ethers, to obtain simple magnesium salts that can be dissolved in the carbonates or ionic liquids). The salts and the solvents are appropriate solvents. Recently, our group has demonstrated distinct components and this allows for electrolyte optimization that in situ magnesium electrolytes purified by crystallization 3580 DOI: 10.1021/acs.jpclett.5b01219 J. Phys. Chem. Lett. 2015, 6, 3578−3591 The Journal of Physical Chemistry Letters Perspective
show improved oxidative stability, increased Coulombic aluminates are explosive and should be handled with extreme efficiency of deposition and dissolution and can sustain higher caution or avoided altogether.36 One other cause for concern is current densities.20 For example, the in situ generated elec- the triarylaluminum Lewis acids, which are highly reactive with trolyte formed from the reaction of a 3 to 1 mixture of the air and water and can spontaneously result in uncontrollable fires. Hauser base hexamethyldisilazide magnesium chloride They should also be handled by experienced organometallic (HMDSMgCl) and aluminum trichloride (AlCl3) exhibits an chemists. One way of overcoming these safety challenges associated oxidative stability of 2.5 V vs Mg (which is identical to the with the preparation of fluorinated magnesium organohaloalumi- oxidative stability of the Hauser base). The crystallized elec- nates is to use fluorinated boron Lewis acids that can yield mag- trolyte (Mg2(μ-Cl)3·6THF) (HMDSnAlCl4−n) (n = 1, 2) shows nesium organoborates that are air and moisture stable. an oxidative stability of 3.2 V vs Mg and columbic efficiency of 100% (Figure 2). Fichtner et al. have recently reported the DFT calculations have been formation of this electrolyte through the reaction of HMDS2Mg with AlCl3.22 Similarly, the electrochemically active species of demonstrated to be a very useful the crystallized reaction product between PhMgCl and AlCl3 at tool in estimating the oxidative and a ratio of 2:1 (APC) was also confirmed. Grignard reagents are reductive stability of electrolytes. highly sensitive to air and moisture and must be handled under inert environments. The early work of di Noto has shown that DFT calculations have been demonstrated to be a very useful δ-MgCl2 can be used as a substitute for Grignards in reactionsDownloaded by UNIV OF NEBRASKA-LINCOLN on September 1, 2015 | http://pubs.acs.org
Table 2. Summary of HOMO and LUMO Energy Levels and the Corresponding Redox Potentials for the Anion Component of the Crystallized Electrolytes magnesium electrolyte anion HOMO (eV) Uox‑expected (V vs Mg) Uox‑reported (V vs Mg) LUMO (eV) Ured‑expected (V vs Mg) GEN1 (HMDS)2AlCl2− a 3.2 (HMDS)AlCl3− −5.67 3.4 0.06 −2.3 APC Ph4Al− −5.38 3.1 3.2 0.02 −2.3 Ph3AlCl− −5.67 3.4 0.05 −2.3 Ph2AlCl2− −6.05 3.8 0.06 −2.3 PhAlCl3− −6.40 4.2 −0.06 −2.2 Cl4Al− −6.74 4.5 −1.38 −0.9 GEN2 Ph4B− −4.82 2.6 2.6 −0.54 −1.7 GEN3 (C6F5)3BPh− −5.56 3.3 3.7 −0.42 −1.8
a The structural flexibility of (HMDS)2AlCl2− makes its geometry difficult to optimize.
Figure 3. (A) ORTEP plot for potassium salt analog of (Mg2(μ-Cl)3·6THF)(B(C6F5)3Ph) (GEN3); (B) ORTEP plot for naked Mg salt analog ofDownloaded by UNIV OF NEBRASKA-LINCOLN on September 1, 2015 | http://pubs.acs.org
GEN3. Hydrogen atoms are omitted for clarity. There is a 25% thermal probability for the ellipsoids; (C) ORTEP for Mg(CB11H12)2/tetraglyme (MCC/G4). Reprinted with permission from ref 39. Copyright 2015, Wiley-VCH. Publication Date (Web): September 1, 2015 | doi: 10.1021/acs.jpclett.5b01219
stability will be governed by the species with the most positive platinum working electrode but due to its corrosive nature its HOMO energy. The DFT calculations predict the following window of operation is below 2.2 V on a stainless steel working oxidative stability: GEN3 (Mg2(μ-Cl)3·6THF)(B(C6F5)3Ph) > electrode. Initial attempts at the synthesis of this electrolyte from APC, (Mg2(μ-Cl)3·6THF) (PhnAlCl4−n) (n = 1 to 4) > GEN1, the reaction of one equivalent of diphenylmagnesium and two (Mg2(μ-Cl)3·6THF) (HMDSnAlCl4−n) (n = 1,2) > GEN2, equivalents of the Lewis acid B(C6F5)3 yielded the desired (Mg2(μ-Cl)3·6THF) (BPh4), which predicts that a fluorinated product in addition to other products that are presumably magnesium organoborate GEN3 (structure) can have a higher reduced on the surface of the working electrode and precluded oxidative stability than magnesium organohaloaluminates. The reversible deposition of magnesium. Mass spectrometry analysis experimental oxidative stability of these magnesium electrolytes showed exact mass and isotope patterns consistent with was confirmed to be consistent with the DFT calculations, B(C6F5)4− could be detected on the surface of the working with the electrolytes GEN3, APC, GEN1, and GEN2 yielding electrode. The appearance of B(C6F5)4− may be explained by oxidative stabilities of 3.7, 3.2, 3.2, and 2.6 V vs Mg, respec- aryl metathesis. This synthetic approach of reacting diaryl tively. Interestingly, experimental results indicate that the magnesium with boron based Lewis acids was abandoned due aluminates have superior oxidative stability for the same organic to the challenge of aryl metathesis, which results in scrambling functionality: (AlPh4)− has an oxidative stability 0.7 V higher of the aryl groups on the anion. These anions are often not than (BPh4)−. Cheng et al. have recently demonstrated accelerated compatible with magnesium anodes due to reduction. electrolyte discovery for magnesium batteries through high It would be the holy grail of electrolyte development to have throughput calculations of the redox potential, solubility and a universal synthetic method to readily convert the magnesium stability of electrolyte candidates.37 This approach may aid in dimer (Mg2(μ-Cl)3·6THF)+ into the corresponding naked the synthesis of novel magnesium battery electrolytes. magnesium analogue. Our approach to achieve this dream, The oxidative stability of many magnesium electrolytes is which we deem universal, was based on an ion exchange path- reported to be in excess of 3 V vs Mg when tested by cyclic way where the magnesium dimer of GEN3 is converted to the voltammetry on a Pt working electrode. However, their window potassium salt (Figure 3a), which can be readily converted to of operation when assembled in coin cells and operated at con- the silver salt and then exchanged to the naked magnesium salt stant current using typical aluminum or copper current collec- of GEN3 (Figure 3b).38 There is one major challenge that must tors is rarely above 2.0 V. It has been proposed that the be overcome, which is the required high purity of the starting corrosive nature of magnesium electrolytes limits their window material, most notably obtaining anhydrous Lewis acid beyond of operation to potentials less than what is observed on platinum what is commercially available. The universal aspect of this working electrodes.25,32 In order to test this hypothesis, the method relies on the use of the silver intermediate, which can removal of corrosive species such as chlorides from both the anion and the cation has been attempted. There is still an open The universal aspect of this question in our laboratory presently being investigated as to method relies on the use of the whether the magnesium dimer (Mg2(μ-Cl)3·6THF)+ is the cause of corrosion or whether the cause could be the purity of the silver intermediate, which can be starting materials. Synthetic attempts to make a chloride-free further exchanged with a wide magnesium electrolyte represent valuable efforts toward develop- variety of metal chlorides, which ment of noncorrosive electrolytes. It is worth noting that lithium opens the gate to obtaining new electrolytes such as LiTFSI do not contain chlorides but are still corrosive toward aluminum current collectors. The magnesium electrolytes for sodium, potassium, organoborate (PhB(C6F5)3)2Mg, which is the naked magnesium calcium, aluminum, zinc, or even analog of GEN3, was selected as a model candidate to test this lithium batteries. hypothesis. The oxidative stability of GEN3 is 3.7 V vs Mg on a 3582 DOI: 10.1021/acs.jpclett.5b01219 J. Phys. Chem. Lett. 2015, 6, 3578−3591 The Journal of Physical Chemistry Letters Perspective
be further exchanged with a wide variety of metal chlorides, such electrodes in symmetrical cells has been measured in our which opens the gate to obtaining new electrolytes for sodium, laboratories to be in the 300 Ω·cm2 range, very much in line potassium, calcium, aluminum, zinc, or even lithium batteries. with lithium metal anodes. This approach opens the door This method was used to obtain the model compound toward practical testing of cathodes in cells with magnesium Mg(BArF)2, which was used to evaluate the feasibility of mag- metal anodes. nesium organoborates as potentially noncorrosive electro- Although batteries with a magnesium metal anode are highly lytes.25 This electrolyte showed an oxidative stability greater desirable due to the high energy density offered by the metallic than 4.0 V vs Mg but unfortunately it had limited reductive anode, promising efforts have been reported in the area of stability that precluded the reversible deposition of magnesium. alloying anodes for magnesium ion batteries.42,43 The interest Recently, Tutusaus et al. has used the ion exchange method- in metal anodes currently stems from the challenges related to ology to develop a magnesium electrolyte Mg(CB11H12)2/ the formation of passivation layers during magnesium plating tetraglyme (Figure 3C S21) that is compatible with magnesium and stripping and anode/electrolyte/cathode incompatibilities. metal and shows Coulombic efficiencies greater than 99% and One of the major driving forces for the use of such anodes is an oxidative stability greater than 3.8 V vs Mg.39 The electrolyte the use of conventional, commercially available magnesium salts exhibits oxidative stabilities in excess of 3.5 V vs Mg on a such as Mg(TFSI)2 or Mg(ClO4)2, which have been demon- stainless steel and aluminum working electrodes on a first CV strated to be compatible with alloy anodes such as tin or scan. Hysteresis due to corrosion is not observed and a poten- bismuth. The most impressive performance of alloying anodes tial in excess of 3.0 V vs Mg can be maintained for 48 h without was achieved by controlling their nanostructure. Shao et al.Downloaded by UNIV OF NEBRASKA-LINCOLN on September 1, 2015 | http://pubs.acs.org
any visible (pitting) spikes in current. This magnesium elec- dramatically improved the discharge rates previously reported trolyte MCC/G4 is possibly the best current option for by Arthur et al.42,44 Figure 4 summarizes the cyclic voltammetry Publication Date (Web): September 1, 2015 | doi: 10.1021/acs.jpclett.5b01219
screening high voltage cathodes. In our laboratory there is of the magnesium insertion and deinsertion of bismuth nano- significant interest in developing a one-step synthesis of naked tubes as well as cycling and rate performance. Parent et al. has magnesium electrolytes without the cumbersome multiple steps recently demonstrated exceptional performance for a nano- of the ion exchange pathway. structured SnBi anode by limiting the particle size to less than Although many hurdles have been cleared in efforts to develop 40 nm.45 This work emphasizes the importance of nano- practical magnesium electrolytes the quest for a suitable cathode technology to enhance both the cycling and rate performance for a magnesium battery is still ongoing. Currently, testing of of alloy anodes. Recently, Ha et al. have demonstrated the new cathode materials in full cells is often hampered by high deposition and dissolution of Mg(TFSI)2 in glyme.46 impedance exhibited by the magnesium metal anode. It is not Cathode Materials. A promising approach to reducing the cost uncommon for the magnesium metal anode impedance to and increasing the energy density of the conventional lithium reach 1 MΩ·cm2. This causes rapid voltage and capacity decay ion battery is to identify cathode materials that can react with in the cell and can make currents pertaining to redox of cathode greater amounts of lithium than the 0.5−1 lithium ion per metal centers difficult to observe. One way to bypass this metal center in a typical intercalation cathode. For example, problem is to use an excess of electrolyte as a source of mag- VOPO4, which has a theoretical capacity of up to 2 lithium nesium and high surface area carbon as the counter electrode ions per VOPO4 resulting in a theoretical specific capacity of (anode) in a half battery/half capacitor electrochemical cell. 305 mAh/g (about 2 times that of existing commercial cathodes) This approach has been reported in conjunction with a variety has been identified as a possible component of higher capacity of cathodes in various studies40 and has also been used in our cells.47 However, materials that electrochemically intercalate laboratory. An additional advantage of this method is the ability multiple lithium ions also tend to exhibit multiple voltage to employ commercial magnesium electrolytes such as Mg(TFSI)2 plateaus. In fact, VOPO4 has been shown to deliver only about or Mg(ClO4)2 dissolved in solvents such as acetonitrile that are one-third of its theoretical capacity at voltages similar to not compatible with magnesium metal. However, it is desirable existing Li-ion batteries and about another third at potentials to lower the resistance of magnesium metal such that new over a volt lower. In addition, intercalation of >1 Li+ ion has the cathodes can be tested in full cells containing magnesium metal potential to cause substantial structural strain on the host anodes. One common method to "activate" the magnesium material and cause instability. However, it is likely that realization anode is to scratch or abrade it under an inert atmosphere. of high capacity Mg battery cathodes will also require develop- Although this method works quite well for treating electrodes ment of materials that can undergo 2-electron reduction with a small surface area such as those used for three electrode reactions involving one mole of Mg per mole of cathode cyclic voltammetry experiments, it still results in very high material. This can be illustrated by assuming a hypothetical impedance for higher surface area magnesium foil used in coin Mg/MgxVOPO4 battery. Figure 5 shows the specific capacity of cells or pouch cells. Borrowing from the early work of pioneers MgxVOPO4 as a function of x and the volumetric energy den- in Grignard organometallic chemistry who were highly skilled sity of the active materials in a Mg/MgxVOPO4 cell assuming in activating magnesium for reactions with high thermodynamic 50% excess Mg and a flat 2.5 V cell operating voltage. thresholds, a highly active magnesium anode can be prepared In addition to intercalation reactions, potential cathode reac- with magnesium obtained from reduction of metal salts.41 The tions that may allow a two-electron reduction include conver- finely divided black powder can be generated in the laboratory sion materials such as sulfur and oxygen as well as metal halides or purchased commercially as a slurry in THF (Rieke active such as CuF2. Organic cathodes also hold promise in this area. magnesium Mg*). An anode paste can be prepared under inert Extensive reviews of Mg battery cathode materials are available atmosphere with a 5% polymer solution of PVDF dissolved in the literature;48,49 recent approaches toward high capacity in THF. Some conductive carbon can be added if needed. cathodes are highlighted here. The paste can then be coated onto a current collector such as Though the VOPO4 cathode material has apparently not carbon paper/graphite foil (for example, Grafoil) or aluminum been evaluated in conjunction with Mg anodes to the best of and cut into disks to be used in battery cells. The impedance of our knowledge, V2O5 has received substantial attention as an 3583 DOI: 10.1021/acs.jpclett.5b01219 J. Phys. Chem. Lett. 2015, 6, 3578−3591 The Journal of Physical Chemistry Letters PerspectiveDownloaded by UNIV OF NEBRASKA-LINCOLN on September 1, 2015 | http://pubs.acs.org Publication Date (Web): September 1, 2015 | doi: 10.1021/acs.jpclett.5b01219
Figure 4. (A) Cyclic voltammograms of Mg insertion/deinsertion in bismuth; (B) discharge/charge profile of an Mg−Bi cell; (C) rate performance of an Mg−Bi cell; (d) cycling stability and Coulombic efficiency (CE) of bismuth electrode for reversible Mg insertion/deinsertion. Cell configuration: Mg/0.1 M Mg(BH4)2−1.5 M LiBH4−diglyme/Bi. Reprinted with permission from ref 44. Copyright 2014, American Chemical Society.
Figure 6. Schematic of Mg2+ insertion process in layered MnO2 cathode. (a) Mg2+ insertion process in dry Mg2+ electrolyte (Mg(ClO4)2/propylene carbonate). (b) Mg2+ insertion process in water containing Mg2+ electrolyte (Mg(ClO4)2·6H2O/propylene carbonate). (c) Mg2+ insertion process in dry Mg2+ electrolyte (Mg(ClO4)2/propylene carbonate) after cycling in water containing electrolyte. Reprinted with permission from ref 57. Copyright 2015, Royal Society of Chemistry.Downloaded by UNIV OF NEBRASKA-LINCOLN on September 1, 2015 | http://pubs.acs.org Publication Date (Web): September 1, 2015 | doi: 10.1021/acs.jpclett.5b01219
Figure 7. (a) CV of MnO2 nanowire electrode measured in 0.1 M Mg(ClO4)2/PC electrolyte before and after cycling in 0.1 M Mg(ClO4)2·6H2O/PC. Measurement after cycling 0.1 M Mg(ClO4)2·6H2O/PC was started at (a) discharged state and (b) charged state. Reprinted with permission from ref 57. Copyright 2015, Royal Society of Chemistry.
least about 70 m2/g all exhibited first cycle capacity of about in both the layered O1 and spinel structures over a composition 250 mAh/g, indicative of reaction of about 0.45 mol Mg per range of 0 ≤ x ≤ 0.5 at 300 K. The spinel material exhibited a mole MnO2. XRD and TEM analyses of discharged cathodes sloping voltage curve, similar to that expected for a solid revealed a largely amorphous surface layer containing Mn2+ as solution, over a range from about 1.5 to 0.7 V, whereas the well as Mg and O. The authors also performed DFT calcula- layered O1 material exhibited voltage plateaus in the same tions that, along with their analytical results, support a dis- voltage range, indicative of the formation of more stable inter- charge mechanism involving a conversion reaction to form MgO mediate phases. This calculated capacity is significantly higher and reduced Mn oxides rather than Mg-intercalated MnO2. Poor than that measured in prior studies of Mg intercalation into electrochemical reversibility of MgO and slow transport of Mg2+ TiS2, which may be explained by the differences in the behavior through this amorphous layer are possible explanations for the of different crystal structures and high polarization during rapid capacity fade seen in these materials, along with electrolyte electrochemical intercalation. Both Li+ and Mg2+ were found to decomposition and the well-known Mn dissolution phenome- preferentially occupy the octahedral sites rather than the non. Thus, this work indicates that if low-cost MnO2 is to become tetrahedral sites, although cation movement via hopping a practical cathode for secondary Mg batteries a reversible path- between octahedral sites was found to occur via passage way for MgO formation must be identified. A possible approach through the intermediate tetrahedral sites. Mg mobility was also to this may involve the use of mediators, such as the use of an found to be substantially slower than Li mobility, similar to observa- I2/DMSO complex to create a reversible Mg−O2 battery by tions for other cathode materials. It was concluded that the size Shiga.60 of the migration channel between adjacent sites had a sub-Downloaded by UNIV OF NEBRASKA-LINCOLN on September 1, 2015 | http://pubs.acs.org
Despite its obvious attractive properties, MnO2 has not stantial impact on cation mobility, and therefore, development been successfully used as a cathode material in commercial of cathode materials with increased interlayer spacing such as Publication Date (Web): September 1, 2015 | doi: 10.1021/acs.jpclett.5b01219
rechargeable Li-ion batteries. Structural instability experienced by incorporation of large, immobile cations or molecules could with Li+ intercalation into layered MnO2 does not occur with increase Mg2+ mobility and thus improve electrochemical spinel-phase LiMn2O4 and this compound is used in com- performance. This may also explain some of the positive effect mercial Li-ion batteries. Electrochemical intercalation of Mg2+ noted above for water incorporation into Mg cathode materials. into delithiated LiMn2O4 was evaluated by Cabana et al.61 It was also speculated that choosing transition metals that more Extensive electrochemical intercalation of Mg2+ into the readily rehybridize upon Mg2+ insertion and deinsertion than Ti tetrahedral sites of this cathode material was reported at a could lead to improved performance as well through reduction potential of 2.9 V vs Mg/Mg2+ with concurrent reduction of in ionic migration barriers. Mn4+ to Mn3+ in the host material. A first cycle discharge Another example of the use of Li replacement with Mg in a capacity of ∼190 mAh/g at a rate of C/20 was reported, which Li-ion cathode material was reported by Orikasa et al.63 An corresponds to a composition of about Mg0.67Mn2O4. However, electrochemical ion exchange technique was used to anodically the experiments were conducted in an aqueous electrolyte (1 M delithiate Li2FeSiO4 using 1 M LiClO4/propylene carbonate Mg(NO3)2), and although no apparent cointercalation of H2O electrolyte, followed by magnesiation in 0.5 M Mg(TFSI)2/ was detected, behavior in nonaqueous electrolytes that support acetonitrile. Subsequent cycling in the Mg electrolyte at 55 °C reversible Mg electrochemistry would need to be demonstrated demonstrated a high reversible capacity of about 330 mAh/g. for this material to be considered for use in secondary Mg The discharge curves exhibited two voltage plateaus at an batteries. A few experiments utilizing Mg(TFSI)2 in diglyme or average potential of about 2.4 and 1.8 V vs Mg/Mg2+, respec- propylene carbonate were conducted and much lower levels of tively, with approximately equal capacities (Figure 9a). Mg2+ intercalation were detected, although reversibility was These voltage plateaus apparently correspond to sequential observed. Higher voltage hysteresis was also observed for non- reduction of MgFeSiO4 to Mg0.5FeSiO4 and FeSiO4. XRD aqueous vs aqueous electrolytes, suggestive of increased kinetic studies of the material at various states of magnesiation revealed barriers for Mg2+ intercalation from nonaqueous electrolytes. that the material maintains an orthorhombic lattice with reten- Behavior in electrolytes reversible to Mg/Mg2+ was not eval- tion of the FeSiO4 3-D structure. An attractive feature of this uated. An interesting observation was that Mg2+ intercalation material is that it uses relatively inexpensive, abundant com- was primarily observed in nanoflakes created in the cathode ponents. An attempt to construct a rechargeable Mg/MgFeSiO4 material by the initial chemical delithiation procedure, whereas battery using Mg(TFSI)2/triglyme electrolyte resulted substantially micron-sized particles largely retained the cubic spinel reduced cathode capacity (166 mAh/g) and average potential structure. This supports the hypothesis that slow Mg2+ diffusion vs Mg (<1.5 V) at 100 °C (Figure 9b). The fact that only about has a substantial impact on the measured capacity of inter- half of the theoretical capacity was realized was attributed to calation cathode materials. This may also indicate that high polarization in this electrolyte; the authors noted that this techniques such as the use of nanoparticles, which are used polarization behavior is similar to what is observed in LiTFSI/ instead of micron-sized particles to improve the electrochemical triglyme electrolytes. This work clearly demonstrates the impact performance of cathode materials exhibiting slow cation diffu- of electrolyte composition on cathode material behavior. Despite sion such as LiFePO4, may promote improved performance of the performance reduction in a reversible Mg electrolyte, how- Mg intercalation cathodes. ever, this work demonstrates that it may well be possible to The performance of layered vs spinel structured cathode prepare Mg intercalation cathode materials with high capacity. materials was also investigated via a computational study of the Although intercalation of cations into transition metal behavior of Mg2+ intercalation into layered and spinel structure chalcogenides typically involves reduction of the metal centers, TiS2 by Emly and Van der Ven.62 It was concluded that both an alternative intercalation reaction involving delocalization of LixTiS2 and MgxTiS2 are stable in similar structures, with the electrons in a fullerene structure was recently reported by layered O1 structure being energetically preferred vs other Zhang et al.64 C60 fullerenes were evaluated for their ability to layered structures and the spinel structure that was found to be reversibly incorporate Mg2+ ions. Discharge at a low current metastable. Voltage curves were calculated for MgxTiS2 vs Mg density of 19 μA/cm2 exhibited two voltage plateaus at about 3586 DOI: 10.1021/acs.jpclett.5b01219 J. Phys. Chem. Lett. 2015, 6, 3578−3591 The Journal of Physical Chemistry Letters Perspective
Figure 9. Charge−discharge curves for MgFeSiO4 (current density 6.62 mA/g). a() 0.5 M Mg(TFSI)2/AN electrolyte, 55 °C. (b) 0.5 M Mg(TFSI)2/triglyme electrolyte, 100 °C. Reprinted with permission from ref 63. Copyright 2014, The Nature Publishing Group.Downloaded by UNIV OF NEBRASKA-LINCOLN on September 1, 2015 | http://pubs.acs.org Publication Date (Web): September 1, 2015 | doi: 10.1021/acs.jpclett.5b01219
been no reported work on the development of a magnesium chemistry to discover HIV protease inhibitors and acceleration for battery with energy densities comparable to lithium ion. From chemical reactions on water. He is currently a senior principal scientist our point of view, the major stumbling block is cathode at Toyota Research Institute of North America. His research interests development. One of our major concerns in developing high include future energy solutions such as multivalent batteries, lithium/ voltage cathodes is the formation of blocking films by oxidation sulfur batteries, Li-ion batteries, and fuel cells. He has numerous of the electrolyte that may be catalyzed by extremely electro- patents in the area of new battery chemistry and fuel cell.
■ positive cathodes. Ether solvents, which have been used in most successful Mg electrolytes to date, typically exhibit good ACKNOWLEDGMENTS reductive stability but their oxidative stability tends to be inferior to that of carbonate solvents used in Li-ion battery We would like to thank our colleagues and collaborators for their electrolytes. With this concern in mind, it may worthwhile for support: Dr. Gary D. Allred, Dr. Timothy S. Arthur, Dr. William C. the community to evaluate lower voltage but higher capacity Boggess, Dr. Jack Chen, Dr. Paul Fanson, Dr. Hideki Iba, conversion cathodes that will not catalyze the oxidation of Mr. Toshihiko Inoue, Mr. Yasutoshi Jagawa, Prof. Noboru magnesium electrolytes on the surface of the cathode to form Kikuchi, Dr. Hee Soo Kim, Dr. Angela Knapp, Mr. Yukinari blocking films. Kotani, Mr. Takashi Kuzuya, Dr. Chen Ling, Dr. Masaki
■ Matsui, Dr. Fuminori Mizuno, Dr. Rana Mohtadi, Dr. John G. AUTHOR INFORMATION Newman, Dr. Alexander E. Rodnyansky, Mr. Kazuaki Sato, Dr. Nikhilendra Singh, Mrs. Wei Song, Mr. Tsuyoshi Sugimoto,Downloaded by UNIV OF NEBRASKA-LINCOLN on September 1, 2015 | http://pubs.acs.org
Corresponding Author Dr. Kensuki Takechi, Dr. Oscar Tutusaus, Dr. Ruigang Zhang, *E-mail: firstname.lastname@example.com. and Dr. Jaroslav Zajicek. We would also like to thank the Publication Date (Web): September 1, 2015 | doi: 10.1021/acs.jpclett.5b01219
■ The authors declare no competing financial interest. Biographies REFERENCES Claudiu B. Bucur obtained his Ph.D. in 2008 from The Florida State (1) Xu, K. Nonaqueous Liquid Electrolytes for Lithium-Based University under the mentorship of Prof. Schlenoff. Bucur attempted Rechargeable Batteries. Chem. Rev. 2004, 104, 4303−4418. to understand the manner in which polyelectrolyte multilayers (2) Zheng, G.; Lee, S. W.; Liang, Z.; Lee, H. W.; Yan, K.; Yao, H.; assemble and how doping them with ions changes their mechanical Wang, H.; Li, W.; Chu, S.; Cui, Y. Interconnected Hollow Carbon and thermodynamic properties. Several manuscripts and a book were Nanospheres for Stable Lithium Metal Anodes. Nat. Nanotechnol. 2014, 9, 618−623. published with his findings. In 2010, he completed his postdoctoral (3) Ota, H.; Sakata, Y.; Wang, X.; Sasahara, J.; Yasukawa, E. studies at the USDA Agricultural Research Service, where he Characterization of Lithium Electrode in Lithium Imides/Ethylene investigated corrosion inhibition by biomembranes. Currently, he is Carbonate and Cyclic Ether Electrolytes II. Surface Chemistry. J. a research associate for the post-lithium-ion research group at the Electrochem. Soc. 2004, 151, A437−A446. Toyota Research Institute of North America. Bucur is fascinated by the (4) Aurbach, D.; Cohen, Y.; Moshkovich, M. The Study of Reversible synthesis and characterization of innovative materials for batteries with Magnesium Deposition by In Situ Scanning Tunneling Microscopy. multivalent anodes or sulfur cathodes. Electrochem. Solid-State Lett. 2001, 4, A113−A116. (5) Matsui, M. Study on Electrochemically Deposited Mg Metal. J. Thomas Gregory received his B.S. and M.S. degrees in Chemical Power Sources 2011, 196, 7048−7055. Engineering in 1978 and 1979, respectively, from Case Western (6) Aurbach, D.; Gofer, Y.; Schechter, A.; Chusid, O.; Gizbar, H.; Reserve University. He spent 34 years in a variety of R&D roles at The Cohen, Y.; Moshkovich, M.; Turgeman, R. A Comparison between the Dow Chemical Company in Midland, Michigan, retiring in 2013 as a Electrochemical Behavior of Reversible Magnesium and Lithium Principal Research Scientist in Dow's Energy Materials Business. His Electrodes. J. Power Sources 2001, 97−98, 269−273. work at Dow encompassed a wide variety of technology areas, (7) Gaddum, L. W.; French, H. E. The Electrolysis of Grignard including electrochemical engineering, process development and scale- Solutions 1. J. Am. Chem. Soc. 1927, 49, 1295−1299. up, polymer processing, and process economic analysis. He is widely (8) Whittingham, M. S. Lithium Batteries and Cathode Materials. recognized for his pioneering work in rechargeable magnesium battery Chem. Rev. 2004, 104, 4271−4302. (9) Nytén, A.; Abouimrane, A.; Armand, M.; Gustafsson, T.; Thomas, electrochemistry. He is currently the owner of Borealis Technology J. O. Electrochemical Performance of Li2FeSiO4 as a New Li-Battery Solutions LLC and consults in the areas of electrochemical energy Cathode Material. Electrochem. Commun. 2005, 7, 156−160. generation and storage and chemical and electrochemical process (10) Ellis, B. L.; Makahnouk, W. R. M.; Makimura, Y.; Toghill, K.; technology. Nazar, L. F. A Multifunctional 3.5 V Iron-Based Phosphate Cathode Allen G. Oliver is the Departmental Crystallographer for the for Rechargeable Batteries. Nat. Mater. 2007, 6, 749−753. Department of Chemistry and Biochemistry at the University of (11) Zhou, H.; Upreti, S.; Chernova, N. A.; Hautier, G.; Ceder, G.; Whittingham, M. S. Iron and Manganese Pyrophosphates as Cathodes Notre Dame. His background in organometallic chemistry led to his for Lithium-Ion Batteries. Chem. Mater. 2011, 23, 293−300. career in crystallography. He has served as a departmental (12) Islam, M. S.; Dominko, R.; Masquelier, C.; Sirisopanaporn, C.; crystallographer for nearly 20 years at Auckland University (New Armstrong, A. R.; Bruce, P. G. Silicate Cathodes for Lithium Batteries: Zealand), University of California, Berkeley and the University of Alternatives to Phosphates? J. Mater. Chem. 2011, 21, 9811−9818. California, Santa Cruz prior to his position at Notre Dame. (13) Connor, J. H.; Reid, W. E.; Wood, G. B. Electrodeposition of John Muldoon received his B.Sc. (Hons) in chemistry from Queens Metals from Organic Solutions V. Electrodeposition of Magnesium and Magnesium Alloys. J. Electrochem. Soc. 1957, 104, 38−41. University of Belfast. He completed his Ph.D. at University of Notre (14) Mohtadi, R.; Matsui, M.; Arthur, T. S.; Hwang, S. J. Magnesium Dame under the direction of Prof. Brown studying air oxidation of Borohydride: From Hydrogen Storage to Magnesium Battery. Angew. organics using terminal oxo complexes of late transition metals. He Chem., Int. Ed. 2012, 51, 9780−9783. worked as research associate at The Scripps Research Institute under (15) Brenner, A. Note on the Electrodeposition of Magnesium from Prof. Sharpless (Nobel Laureate in Chemistry 2001) and Prof. Fokin, an Organic Solution of a Magnesium-Boron Complex. J. Electrochem. developing applications of click chemistry including in situ click Soc. 1971, 118, 99.
(16) Carter, T. J.; Mohtadi, R.; Arthur, T. S.; Mizuno, F.; Zhang, R.; (35) Barile, C. J.; Barile, E. C.; Zavadil, K. R.; Nuzzo, R. G.; Gewirth, Shirai, S.; Kampf, J. W. Boron Clusters as Highly Stable Magnesium- A. A. Electrolytic Conditioning of a Magnesium Aluminum Chloride Battery Electrolytes. Angew. Chem., Int. Ed. 2014, 53, 3173−3177. Complex for Reversible Magnesium Deposition. J. Phys. Chem. C 2014, (17) Gregory, T. D.; Hoffman, R. J. Electrochemical Generator 118, 27623−27630. Utilizing Solid Polymer−Salt Complex. U.S. Patent 4,702,974, (36) Bochmann; Sarsfield, M. J. Reaction of AlR3 with [CPh3][B- October 27, 1987. (C6F5)4]: Facile Degradation of [B(C6F5)4]− by Transient "[AlR2]+. (18) Gregory, T. D.; Hoffman, R. J.; Winterton, R. C. Nonaqueous Organometallics 1998, 17, 5908−5912. Electrochemistry of Magnesium Applications to Energy Storage. J. (37) Cheng, L.; Assary, R. S.; Qu, X.; Jain, A.; Ong, S. P.; Rajput, N. Electrochem. Soc. 1990, 137, 775−780. N.; Persson, K.; Curtiss, L. A. Accelerating Electrolyte Discovery for (19) Aurbach, D.; Weissman, I.; Gofer, Y.; Levi, E. Nonaqueous Energy Storage with High-Throughput Screening. J. Phys. Chem. Lett. Magnesium Electrochemistry and Its Application in Secondary 2015, 6, 283−291. Batteries. Chem. Rec. 2003, 3, 61−73. (38) Bucur, C. B.; Gregory, T.; Muldoon, J. Why Grignard's Century (20) Kim, H. S.; Arthur, T. S.; Allred, G. D.; Zajicek, J.; Newman, J. Old Nobel Prize Should Spark Your Curiosity. In Rechargeable G.; Rodnyansky, A. E.; Oliver, A. G.; Boggess, W. C.; Muldoon, J. Batteries; Zhang, Z., Zhang, S. S., Eds.; Green Energy and Technology; Structure and Compatibility of a Magnesium Electrolyte with a Springer International Publishing: New York, 2015; pp 611−635. Sulphur Cathode. Nat. Commun. 2011, 2, 427. (39) Tutusaus, O.; Mohtadi, R.; Arthur, T. S.; Mizuno, F.; Nelson, E. (21) Wan, L. F.; Prendergast, D. The Solvation Structure of Mg Ions G.; Sevryugina, Y. V. An Efficient Halogen-Free Electrolyte for Use in in Dichloro Complex Solutions from First-Principles Molecular Rechargeable Magnesium Batteries. Angew. Chem., Int. Ed. 2015, 54, Dynamics and Simulated X-Ray Absorption Spectra. J. Am. Chem. 7900−7904.Downloaded by UNIV OF NEBRASKA-LINCOLN on September 1, 2015 | http://pubs.acs.org
Soc. 2014, 136, 14456−14464. (40) Gershinsky, G.; Yoo, H. D.; Gofer, Y.; Aurbach, D. (22) Zhao-Karger, Z.; Zhao, X.; Fuhr, O.; Fichtner, M. Bisamide Electrochemical and Spectroscopic Analysis of Mg2+ Intercalation Based Non-Nucleophilic Electrolytes for Rechargeable Magnesium into Thin Film Electrodes of Layered Oxides: V2O5 and MoO3. Publication Date (Web): September 1, 2015 | doi: 10.1021/acs.jpclett.5b01219


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Manager of SMB Sales - Vodafone Business Unit
- náměstí Junkových 2808/2, 155 00 Praha-Stodůlky, Czech Republic
- Unlimited Contract
- Full-time work
We are at the start of an exciting new journey as we bring together two great organisations with an ambition to improve lives with our leading edge technology and innovations and build a truly Gigabit Society.
Role summary
Development of the indirect sales network and internal Business to Door team. Leads team of Business partners and B2D manager. Proactively reacting on market development and adjusting sales approach with aim to achieve sales targets.
# Direct reports: 7
Key Responsibilities
- Responsibilities for achieved sales results
- Leadership and motivation direct subordinates
- Further development of partnership with external business partners as sales channel
- Development of B2D sales channelsales team coaching
- Looking for new business opportunities
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Check out our career page and see how it works.
Critical Knowledge & Skills
- A dynamic and flexible personality
- Analytical thinking (focus on value), ability to self-organize own work
- Focus on results
- Strategic and logical thinking, independence
- Driving license B
- Min. Finished high school
Desired Experience
- Proven experience and achievements in sales management
- Proven experience and expertise in the Telco industry
ContactVodafone Czech Republic a.s.
Monika Jeřábková
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If you do not believe in a few items from the position description, it does not matter. Everything can be learned and we will be glad to help you.


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We waved off our Zambian children after the local team made the programme sustainable. As the need was so great in Lesotho, we wanted to grow our programmes there – and we could, thanks to meeting and hiring Mochesane, our Country Director who we had met a few years previously.
Please help us carry on our work!
Thanks for your support :)


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The Subtle Art of Not Giving a F*ck (Compact Disc)
A Counterintuitive Approach to Living a Good Life
HarperOne, 9781441711366
Publication Date: September 13, 2016
Other Editions of This Title:
Digital Audiobook (9/12/2016)
Hardcover (9/13/2016)
Paperback, Large Print (12/31/2018)
Compact Disc (9/13/2016)
Paperback (1/5/2021)
For the past few years, Mark Manson-via his wildly popular blog-has been working on correcting our delusional expectations for ourselves and for the world. He now brings his hard-fought wisdom to this groundbreaking book. A much-needed grab-you-by-the-shoulders-and-look-you-in-the-eye moment of real-talk, filled with entertaining stories and profane, ruthless humor.


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Traeger's, unlike other models, have a temperature probe, these sensors tell it if the temperature is too low and automatically feeds more pellets to the fire. You can set up the temperature in 5-degree increments. Other brands and cheaper versions only offer three settings low, medium and high. There is no sensor to monitor the temperature. If you are purchasing a pellet grill it is because you can set it and forget it. If you plan to hoover then it makes more sense to use a standard smoker or to transform your grill into a smoker.
Bake, braise, grill, smoke, and sear – all of these cooking techniques can be fully experienced by just using one unit of backyard cooker! Yes, you can definitely do different kinds of cooking to your pork, beef, fish, pizza, or pie by just using the Camp Chef Smokepro STX Pellet Grill without burning charcoals and woods to start the cooking process.
Choosing the one perfect pellet grill that could change your cooking experience is easier said than done. There is just so know you have to know before committing to it. Though I did give you a run-through of all the basic and important things to look for in a pellet grill before buying one, it is still a scratch on the surface. It is tiring to have to go from store to store to find the quality ones that you can choose from. So, to come to your rescue once again, I will now give you the some pellet grill review.
Cooking a lot of food is easy when using Camp Chef's Flat Top Grill. The large surface area will enhance your cooking experience giving you plenty of room to work so cooking is done efficiently. Included is an interchangeable flat top griddle making it easy to cook pancakes, bacon and eggs, sausage, and hash browns - all at once. Then switch to grilled burgers, kabobs, and chicken for the next meal. Four individual burners provide heat in specific areas creating heat zones that will help you manage hot foods. Built in matchless ignition knobs control the heat and flame. Fold-down side shelves and roller wheels are added for convenience.
Hey Jeff – I think that due to pellet smokers requiring much of the wood pellet for "fuel" leaving a smaller part for the "smoke" means that you want as much of the smoke to stay in the chamber for as long as possible. Just my opinion. I've not used charcoal pellets. Those I've spoken with who have used them weren't extremely happy with the results. Regarding the water pan, I feel that pellet smokers don't typically require water pans. However, you can surely use one and see how your results go.
I spent months checking out Memphis, Fast Eddy, Mak, and Yoder grills. I must say the Yoder is by far the most robust pellet grill of them all. I noticed many reviews with 3 or 4 star ratings for price and I must disagree; fit, finish, build quality, and material robustness of the Yoder was better than the Memphis Pro & Elite...and we all know how expensive the Memphis is.
With the summer right around the corner, it's about that time of the year that consumers are thinking about hosting outdoor picnics and having their friends and family in the backyard. Now, to make this year special, many people are flocking towards purchasing pellet grills. In efforts to assure our readers that each grill on today's list is the absolute best, we performed an update on this buying guide. Included in this update, readers will get to learn about the criteria that we used to evaluate each grill and a list of answers to some commonly asked questions. Before the summer arrives, check out this update!
After looking at a lot of pellets smoker grill reviews, it is easy to see that this is a pretty decent model. It is just so functional. So if you are looking to purchase something that is more than a pellet smoker, this is the product for you. Make sure to follow the instructions carefully when assembling it and be sure to gauge cooking time since this is a fast one.
The Green Mountain Grills Davy Crockett smoker lets you get more than what you paid for. At a surprisingly low price, you get to have tons of great features that are sure to elevate your BBQ experience. For its price, we were quite surprised to see that it satisfied most of the features on our review. We tested over fifty products, and even the expensive ones were no match for this product. In terms of value per dollar, this product deserves the top spot.
Second, It would be just my wife and me BBQing so I'm looking small. I'm considering the REC TEC Mini Portable Wood Pellet Grill (RT-300) after reading your reviews. Having only ever BBQed with hard wood coals on a Webber, is there going to be a taste fall-off going to the pellet grill as far as charring and/or smoke? I'd hate to spend that kind of money and get bland steaks. Really, steak is all we ever cook outside, though that would probably change with a nice grill.
Of course, we recommend our pellets and have proven them to work fantastically with all of our grills, but we would never be short-sighted enough to say that our owners must only use our pellets. That just seems a bit, well, wrong. From our testing and customer feedback, the following brands all worked very well: B&B, BBQrs Delight, Cooking Pellets.com, Lumberjack and Smoke Ring.
Tech geeks: A tech geek will also prefer a Pellet smoker grill and some of the latest grills including Green Mountain Grills came up with some exciting tech functionality like Wi-Fi! Just imagine, hanging with friends and monitoring your pork with your smartphone? You can increase and decrease temperature and control pellet feed without even touching the grill. This gives you the ability to cook while you work!
Kevin, your recommendation rocked. The Pro is one of the best pieces of grilling and smoking iron I have had my hands on in a long time! Better than the Backwoods? Well depends on how much work you want to do! Maybe not, they are first class, but ease of use? I use the Backwoods a couple times a year, the Pro has already done 8 cooks in 5 weeks. Love it.
Remote Accessibility: This level of control and observing is critical on the grounds that the container does not generally sustain the pellets into the wood screw accurately and the fire in the firepot can go out. The Davy Crockett will tell you that the container is not sustaining wood pellets and that the temperature is dropping. The Davy Crockett application will reveal to you something isn't right.
Seeking to produce the pellet cooker that is both a great smoker and a powerful grill. The truth is that burning pellets in a controlled way is not the best method for producing high grilling temperatures. Most pellet grills top out at 500 degrees F while the hottest units can hit 600 degrees F. This pellet cooker is in reality, a combination grill with a large smoking space, and a small but powerful direct grilling area. Reasonably priced with quality construction, this is definitely a pellet grill to look at.
It's got built in manual controls, but there's also the option to download an app to your phone so you can control your smoker through your wifi! Honestly, this really impressed me, and I don't know why other manufacturers aren't all over this. Apparently there's a cloud based app coming out soon so you can control your grill anywhere you can get internet, so you could be sitting at your kids football game whilst checking the status of your post-victory feast! The controls are also fully programmable, so you could for example set it to smoke for 5 hours and then cook for 2, finishing just as you pull up onto your drive.
Although I marked price high. I would buy it again, tomorrow. I was a novice. I had never smoked anything when I bought this. It is amazing and if you asked my friends and family I should have opened a bar & grill. It's grills better than any gas grill u can buy. The YS640 only gets better with time you get good at using it. It's the best cooker on earth. If your considering paying over $800 for a cooker. Spend the money... you will not regret it. My cousins have Traegers.. and they smeared by them. One weekend at my cabin one has ordered his the other don't have the money yet. I have used it a minimum of 2 days a week and have already got my money out of it by not ruining meat. The guys at Yoder have a monopoly. No one makes a cooker that could stand up to it. THANK YOU YODER. YOU HAVE MADE SOME GREAT HOLIDAY MEMORIES FOR ME AND MY FAMILY. Remember if your on the borderline don't know if it's worth a little more. By the 12th month of owning it. You will look at your wife or girlfriend and say "I'm so glad I spent a little extra and got that. It's beautiful.
While the Green Mountain Grills Davy Crockett Pellet Grill is compatible with most iOS and Android devices, I want to stress, check the compatibility of your device with the grill before purchasing because it would suck to buy this grill only to find out that this feature is not compatible. Also, if you do not plan on using the grill on some elevated surface, the legs are not tall so the grill sits close to the ground. Regardless, this is a GREAT smoker: your meat will come out tender and juicy with that authentic BBQ taste we all love! Neither of these cons affects the quality of your BBQ and both can be worked around.
OK. I'm rambling a bit. To your point regarding Traeger. I think that the models you can buy at big box stores (Costco etc) are OK. I still hear a few complaints about blistering paint etc. But… their Pro Series Models are a different story. The new management at Traeger has come a long way in their efforts to reaffirm the Traeger brand as a legitimate BBQ Pellet Smoker brand that everyone from the backyarder to competition pitmasters can get behind. To that end, they only allow specialty retailers carry the Pro Series models, which are built with a bit more heft and better PID controls, electronics, etc. You can find these at Ace Hardware stores, places like the Whiskey Bent BBQ Supply store we have here in Lakeland, FL (there is now one in Odessa, FL) as well. You can find a Traeger Pro model by going to http://www.traegergrills.com/dealers.
Do you enjoy hassle and stress-free living? If you want to enjoy the juicy smoked BBQ ribs with your friends and family without feeling disturbed, then the automatic smoker is the top choice for you. The automatic smoker, a pellet smoker, makes for an ideal choice. Do you know why it has it has earned the reputation of the best among all the easy to use smokers? You will find the automatic features incredibly easy to use and this convenient product's simplicity stands out.
Another pellet smoker from industry leaders Traeger. The Lil Tex Elite is an upscaled Junior Elite, and whilst it's still a good quality smoker and grill with a powerful burner and excellent heat output, plus all of Traeger's usual electronic gizmos. There's just not enough of a difference between this and the Junior Elite, especially not when you consider the increased price tag, which is disappointing.
I haven't posted here before, but have been reading and finding a lot of good information on this site. I am in the market for a pellet grill so have been researching some of them listed on this site. Out of Yoder, Green Mountain, Memphis and MAK I really like price, features and looks of the Yoder YS640. I was wondering if anyone has used Louisianna pellet grills? For example, the CS680? I don't see it mentioned much on bbq blog sites so not sure if it is a good brand. Thanks for any advice.
When looking at a pellet grill also consider the material its made from. A majority of pellet grills on the market are made from painted steel. However, the quality of that steel and the paint can vary. A good high-temp powder coat paint can stand up to high heat without blistering or flaking. This is essential, because once the steel is exposed, it will rust. Even if the grill body is painted well, you have to look inside. The fire pot and diffuser plate have the potential to corrode and are two of the most common parts that need replacing. With some painted steel grills, such as Traegers®, you can can upgrade the grill and hopper lids to stainless steel, as well as the firepot, diffuser, and drip pan.
The first time I grilled something on it -- pulled pork, which takes a long time on the grill -- the fire kept going out on me. My husband called the company, and they said they knew they had that problem. So he told the nice lady on the end of the line that what they needed to do was to add something to the hopper to keep it jiggling just a little so that the pellets continued to go down. "We're working on a solution," she said. "I just told you the solution," my husband, who's a mechanic and loves solving mechanical problems using unusual, but straightforward solutions. His trick? -- get one of those cheap, plastic, clip-on fans and clip it to the hopper, pointing the fan down into the hopper. The fan jiggles it just enough. The air into the hopper "couldn't hurt, either," he told me.


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joachim neander wrote:I know this photograph very well. I discussed the matter in much detail in my PhD dissertation. It is, of course, written in German, but available even thru amazon.com. As it is also in the stock of many public libraries, an interested reader can get it via interlibrary loan from his/her next public library.
To make it short (and omitting many details): The photograph shows part of the Boelcke-Kaserne at Nordhausen, Germany....In some of the former hangars and garages a sub-camp of CC Mittelbau was established at the end of January 1945, when the evacuation transports from Auschwitz and Gross Rosen arrived with many, many sick prisoners, unfit for work in the "Mittelbau Project," the excavation of big underground caves west of Nordhausen, intended for the deployment of an aircraft factory and an oil refinery. The sick prisoners were left there with a minimum of food, no health care, no beds (only straw on the concrete floor), no heating. All severely sick prisoners from the main camp "Dora" and the other sub-camps of Mittelbau were also sent to sub-camp Boelcke-Kaserne. The appalling living conditions made that the death rate in this camp was extremely high.
....The prisoners were prevented at gunpoint from entering the air raid shelters on the premises. A few hours after the last air raid, the SS abandoned the Boelcke Kaserne sub-camp (the evacuation of the Mittelbau camps was beginning) and left the dead and dying inmates to their fate.
It is not correct to assign ALL the dead to the RAF bombing. If the prisoners had been allowed to hide in air raid shelters during the air raid, if the camp authorities had cared for the ca. 600 who had survived the bombing, and if these men had not been seriously ill due to neglect and maltreatment, the overall death toll would have been significantly less.
I happen to know people from that area of Germany. And they recall quite weary prisoners marching through their village at the end of the war. They also went to that museum after the end of the "DDR" and I should add that it seems they've paddled back their on many of the allegations you made. The statement that "The prisoners were prevented at gunpoint from entering the air raid shelters" sounds a bit absurd. Not that it's physically impossible and the rest sounds rather like exaggeration of certainly deteriorating conditions at the end of the war. You did check those allegations concerning maltreatment of prisoners on the possibility, whether this is just communist propaganda, didn't you?
Finally it should be noted that the German wiki entry on Nordhausen already revised the claims concerning this picture:
Etwa 1200[2] bis 1300[3] Tote forderte die Bombardierung unter den Häftligen des Außenlagers Boelcke-Kaserne. Die Bomben detonierten auf den Lagerstraßen und in den Unterkunftsblocks.[4] Die Aufnahme zeigt das Kasernengelände mit den geborgenen Leichen.
I assume you understand the German text.
The text clearly states that the picture shows recovered corpses after the bombing. Hence your statement "It is not correct to assign ALL the dead to the RAF bombing" is wrong as we are discussing the picture here.


text: 80 feet of frontage on desirable Argentia Beach. If you've been looking for a large lakefront lot to build your dream cabin at the lake, this could be it. This area is connected to the municipal sewer system & gas & power at the property line, & there is a drilled well. The 80ft frontage lot next door is also for sale.


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Salt and pepper mills and shakers from brands including Le Creuset, Peugeot, Omcan and Swissmar. They are available in a variety of colours and styles to suit your table settings. Perfect for restaurants, cafes and more, you can find a set of salt and pepper shakers to add an extra touch of seasoning to your food.


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Cookie Cutter Blyss Frog by TMP
3d printed cutter to be used with Blyss Kiss Me set. Hand was only, not dishwasher safe.
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Smyrna Town Manager Harry Gill, Jr. announced his retirement, effective Aug. 31, at the Town Council meeting Tuesday. Gill has served as Town Manager since 2013.
Members of the Rutherford County Legislative Delegation announced that they will memorialize fallen Blue Angels Captain Jeff Kuss with a proclamation and bridge dedication on Saturday, November 11, 2017.
The Town of Smyrna will soon announce a permanent honor for fallen Blue Angels Pilot, Captain Jeff Kuss.
The TSSAA suspended a football referee involved in a collision with a Glencliff player because of discrepancies in his background information dealing with a statutory rape charge in 2006.
The celebration will consist of an official ribbon cutting and opening of the revitalized Historic Train Depot and refurbished Assembly Hall as well as the kickoff celebration of Smyrna's new Farmers Market
The Smyrna Town Centre will no longer have a fitness center due to the overhead involved. Smyrna Town Manager Harry Gill, Jr. commentated…
At least one of the 22 applicants for the Smyrna Town Manager position will be very familiar. Former Rutherford County Director of Schools Harry Gill, Jr. has thrown his hat into the pool of replacements for Mark O'Neal, who resigned last month after 21-years.
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Strand WC2 Emergency Electrician
Journeymen are electricians who have completed their Apprenticeship and who are already found with the community, condition, or countrywide licensing physique for being capable within the electrical trade. Master Electricians have done perfectly in the trade to get a timeframe, generally seven to 10 years, and possess handed an exam to reveal outstanding understanding of the National Electrical Code, or NEC.
a far more prevalent exercise in automobile lockouts is using wedges. Wedges differ in dimension and condition Electrician to perform results by using a broad number of various helps make and types. although some wedges might appear extra refined than Many others They may be utilised because of their confirmed monitor data and is not going to damage the automobile.
Aside from the requirement of a lot of these auto keys, dropping one can create fairly the necessity for concern. The more Regulate the fob has more than the automobile, the greater dire it is for you to Speak to an auto locksmith. With the help of your neighborhood locksmith, all current vital fobs is usually faraway from the car's onboard Laptop.
Visit your local locksmith. Depending on the sophistication of your automobile vital you could possibly Use a new Digital important programmed by a locksmith. numerous new vehicle keys Have got a microchip in them to circumvent duplication. even so, For those who have a critical by using a transponder in it you'll be able to likely receive a new a person in a locksmith for $fifty.
Drain Relining and Sewer Relining are very simple, fast and more inexpensive than digging up your drains. It's been confirmed for more than 25 several years world wide and greater than ten years in Australia.
you might characterize you inside the arbitration or have a lawyer (or Several other representative) act on the behalf. Upon receipt of the arbitration more hints assert, Angie's List may perhaps assert any counterclaims it may have more information in opposition to the complaining celebration.
Jeffrey pine, Jeffrey's pine, Pinus jeffreyi, black pine tall symmetrical pine of western North America possessing long blue-green needles in bunches of 3 and elongated cones on spreading considerably pendulous branches; occasionally labeled as a number of ponderosa pine
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Journeyman electricians can get the job done unsupervised provided which they function In keeping with a grasp's way. usually, states this page usually do not present journeyman permits, and journeyman electricians together with other apprentices can only operate less than permits issued into a learn electrician. Apprentices may not do the job with out immediate supervision. [10]
Locksmithing isn't really straightforward do the job. Getting a essential education and learning will give you the foundational expertise you'll need to be familiar with the greater Superior mechanical rules employed on The task.
Any disputes about discovery or requests for extensions shall be submitted immediately to the arbitrator for prompt resolution. In ruling on any discovery dispute or extension ask for, the arbitrator shall choose into account the character, amount, and scope in the fundamental arbitration declare, the fee together with other go right here exertion what will be linked to offering the requested discovery, the case program, and whether or not the asked for discovery is needed for the sufficient preparing of the assert or protection.
But each and every condition has its possess necessities, so be use this link sure to Check out together with your point out's Section of licensing, labor, or purchaser affairs.
substitute the battery. for those who observe your critical Performing improperly more than the span of a couple of days it might be the battery dying. A substitute battery for just a important fob will likely be affordable and can be found on the net, at an auto-locksmith or electronics store.


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Social Media at Work: Balancing Risks and Rewards
As technologies advance and converge, they provide an increasingly mobile workforce with seemingly endless ways to connect and interact with colleagues, customers and clients. But at what risk?
Joe, a sales executive at a professional services firm, decided to walk back to the office after a meeting. The meeting with his target client went well -- so well he felt sure that he had secured the business. He pulled out his mobile device to update his social networking status. "Walking down 5th Ave. On my way back to the office. Great meeting with potential client."
Across town, Martin, who works at a competing professional services firm, was taking a break from his busy morning and logged into a social networking site on his laptop. Seeing the post, Martin knew exactly who Joe had been meeting with that morning. Martin picked up the phone and scheduled a meeting of his own. Soon after, Martin had secured the new business, leaving Joe to wonder how such a good opportunity had slipped through his fingers.
Assessing the dangers
As technologies advance and converge, they provide an increasingly mobile workforce with seemingly endless ways to connect and interact with colleagues, customers and clients. But at what risk?
Companies recognize that anywhere/anytime access presents enormous opportunities to improve customer relationships, boost sales and accelerate growth. But there are also risks in terms of data access and data leakage. The rise of social media heightens the risk that corporate strategies, new product development or other sensitive information could be inadvertently -- or intentionally -- shared with competitors or other inappropriate counterparties. Employees may also harm the business and its brand though simple association, uploading inappropriate comments or other content in their personal lives that is perceived to reflect on the company.
Ernst & Young's 2010 Global Information Security Survey found that 60% of organizations perceive an increase in the level of risk they face due to social networking, cloud computing and the use of personal devices. In truth, given these new technologies and practices, such risks can include "Joe's"minor lapse in judgment or a truly severe enterprise security breach.
Your company can establish barriers that severely limit the embrace of mobility, networking, blogs, wikis, tweets and other forms of user-generated, content. But, in doing so, you not only discourage creativity, you also forfeit opportunities for breakthroughs in collaborative capability and overall performance. The failure to embrace mobility and networking can leave your business at a significant disadvantage relative to your peers.
This article was originally published on 02-02-2011
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Caratteristiche: Vitigno: Sauvignon blanc. Zona di produzione: La tenuta "Mock" si trova in località Laitago della città di Bolzano, superficie 2,5 ettari collinari, 500 mt. di altitudine. Inizio vendemmia: settembre. Tipo di vinificazione: pressatura soffice e fermentazione a temperatura controllata. Caratteristiche organolettiche: vino bianco delicato, aromatico, di colore giallo paglierino,lo distingue il suo caratteristico profumo di sambuco, molto morbido e di grande persistenza aromatica in bocca. Grado alcolico: 13,0 % Vol. Zucchero residuo: 3,0 g/l.
Da servire: 10-12°C
Allergic-Info: This wine can contain sulfites
Alcoholic content: 13.00 %
The fine stone mushroom liver pâté of the butcher's shop Villgrater, home-made liver pâté improved with stone mushrooms, ideally as an occasionally snack, ideally as a bread spread on any bread kinds.
>> dettaglio
Based on its fullness and body, it is an extraordinary Vernatsch.
Incredibly and in the taste perfectly, so describe some customers our deer salami which stands firm every comparison. Particularly liked with hors-d'oeuvre plates, cold plates etc. in combination with other lusciousness our house.
Vernatsch is a traditional South Tyrolean grape, greatly contributing to the local wine culture through its uncomplicated drinkability. New quality parameters and modern production methods have ensured that its popularity has continued to increase in recent years. In the village Missian this grape finds the best conditions to create this succulent fruity and elegant red wine.
This Pinot Grigio is pale yellow to sandy in color and subtle in its bouquet, with fruity notes of pears and candied furits. The eloquent, harmonious body emphasizes its dry, full-bodied taste and round finish.


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Back to where you came from
Geometric Art
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"Lost In The Night And Far Away From Home"
(I Am My Own Ghost In The Night)
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Buy art prints at SAATCHI Online Gallery
Abstract Painting 2014
Size: 28x22 cm (11x9 inch) with frame.
Sold to: Sundsvall, Sweden
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YQCA Information
Date: March 26, 2020 To: YQCA Families RE: YQCA Web Based Certification – Flash Sale! In light of the recent COVID-19 pandemic, the YQCA Board is announcing a 25% flash sale on the web based certification. Here is how to take advantage of this opportunity ...
Andrew Hoffman's YouTube Channel
Field Report from Andrew: (Andrew Hoffman is a Graduate Research Assistant with the OSU Terrestrial Wildlife Ecology Lab) Right now we are in the thick of amphibian breeding season and, given patterns this year, I suspect it will stay active for the next ...
Backyard Bird by Carrie Elvey, The Wilderness Center
Spring migration is always an exciting time for birders. This year, many of our usual activities have been curtailed. Stay-at-home birding may not have been on our agenda for this Spring but the slower pace of life now can offer some great opportunities ...
Oline Quality Assurance Training SALE for April ONLY
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2017 Webinars- Profiles in Service
2017 Webinars- Profiles in Service Please consider participating or viewing our quarterly OCVN webinars. This year the series will focus on volunteer service and highlight what service volunteer naturalists are participating in Ohio and beyond as well as ...
Seneca County 4-H Update (3/27/2020)
We hope that you are all doing well and staying healthy in the time of this global pandemic. We understand that these are trying times with a lot of uncertainty, which in return brings a lot of questions. We do not know when things will return back to &qu ...
COVID-19 and Food Safety
The Coronovirus 2019 (COVID-19) pandemic is a rapidly evolving situation. Science-based information is available and updated as new information becomes available at the CDC and Ohio Department of Health. The following resources are specific to specia ...
2020 CFAES Distinguished Senior Award Virtual Showcase
The 2020 CFAES Distinguished Senior Award recipients were to receive their formal recognition during the awards celebration to be hosted by CFAES, on Wednesday, March 25, 2020 at the OSU Fawcett Event Center. However, due to the worldwide outbreak of COVI ...
Join the Spring 2020 Email Wellness Challenge!
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We all want to achieve the best women's clothing shoes and accessories this season. What exactly can we look out for in these products? Read on to discover! When shopping for women clothing shoes and accessories, it's advisable to plan ahead. Don't just start buying random things that look nice. First, you need to fully familiarize yourself with your system type.
Women that are petite will manage to benefit most from slim narrow belts. Try to use some color contrast to include some shape and curve to your body. You might also desire to stick to fabrics which can be flowing and soft. Avoid buying fashion items which have very bold prints.
Vintage Clothing And Jewelry Online
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Country Clothing Boutique
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How to Purchase CBD online and get the cheapest deals
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Obtain the suitable online pharmacy- The to start with phase to buying CBD oil on the web would be to locate the ideal pharmacy. There are a lot of online pharmacies but not all can be dependable. Test out the license of the on the internet pharmacy prior to purchasing from them. This will guarantee that you get the ideal merchandise and you do not have to deal with any concern as very well. Not only that, you should really also look at out the evaluations and testimonials of the web page. That will give you a fairly good strategy about the quality of CBD oil and goods furnished by the web page. https://cbd-oil-for-pain.org/ In a planet of frauds, you have to be certain that you get the authentic items. Also do test the focus of the CBD oil in the products they promote right before likely ahead to Obtain CBD Crystal from them.
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Best Maryland Sports Betting Apps & Online Sportsbooks
Legal in Maryland Sports Betting and Mobile Betting Apps in 2019: TVG, TwinSpires, Xpressbet, Fanduel DFS
Expected mobile sports betting apps in 2020 and further: FanDuel sports betting, Maryland DraftKings sportsbook app.
Best betting via Maryland online sportsbooks and apps: Kentucky Derby, Preakness Stakes, Belmont Stakes, state and local horse/greyhound races. If legalized, look for all major professional sports to be legal.
Maryland mobile sports betting
The only online sports betting currently allowed in the state of Maryland is on horse and greyhound racing. There are several race tracks throughout the state of Maryland, but most people prefer to place bets via online sportsbook and mobile betting app. This is considered legal in the state of Maryland, and state lawmakers are hoping to use this as a framework to legalize sports betting. There was an attempt to legalize sports betting apps in the state of Maryland in 2019, but that was quickly shot down. Daily fantasy sports apps such as FanDuel and DraftKings are currently legal in the state, and they will likely be the first to offer sports betting apps if it ever becomes legal.
More about gambling in Maryland
- Sports Betting in Baltimore, MD
- Rocky Gap Casino & Sportsbook Review
- Sportsbook at MGM National Harbor Casino: Promotions Expected
- Online sports betting in Maryland
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This is the product page for: Black Paisley Print Tunic
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A laid-back top for easy weekend dressing. With its relaxed longline fit and pretty paisley print, this monochrome number is easy-to-wear and simple to style. The length means it's ideal to wear over leggings for a chic but comfy ensemble, but jeans work too. Heels are a must to step it up for evening, while trainers should be your daytime footwear go-to.
Model is 177cm/5ft10 and is wearing a UK size 16
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UK PM Johnson: we can get on top of coronavirus in 12 weeks
In his daily update, the Prime Minister said Britain is in talks to buy a coronavirus antibody test that could be a game changer if it works and already scientists are making progress in finding medicines that can fight the disease.
Johnson also said scientists were making headway in removing the "cloak of invisibility" that surrounds the virus to fully understand its workings.
He urged businesses to stand by their employees and said that "this time is going to be different" when helping small businesses to get back on their feet, which he said was not the case after the last financial crisis.
However, the government may have to impose stricter measures in London to tackle the coronavirus because compliance with the advice in parts of the capital has been patchy, Boris Johnson added


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2019 Winter Audit Intern
The Programme
Sometimes the search for an internship can feel like you are climbing a mountain. The professionals at Larson & Company are experienced trail guides and can lead you to the next step in your career. We offer hands-on career experience from real client work, giving you an overview of the entire audit cycle, not just one aspect of an audit. At Larson & Company, we believe in your potential and can help you reach new heights by providing an integrated internship experience.
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- Some travel may be required outside of the state.
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Required Skills and Abilities
- Accounting majors (BS/BA, MS/MA, MAcc/MBA).
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- Closing Date:16th Jun 2019, 6:00 pm
Enter an employer or university you want to find in our search bar.


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Man Sues for Former Work Injury
September 17, 2007
A previous employee of the Providence & Worcester Railroad Co. recently filed a suit against the company for an injury he endured while he was employed.
The man claims he was injured while working three years ago and is still suffering from his injuries.
The complaint was filed last week in the federal district court.
The Complaint
Dennis J. Madore filed the suit, which was backed by the Federal Employers' Liability Act.
Madore claims he was struck by a hammer while working in the company's engine room and blames the company's lack of protection and safety for their workers for his injuries.
Madore Still Deals With Injuries
Madore claims that as a result of his injury, he became sick and sore.
He also says he steals deals with a great deal of pain throughout his body from the impact of the hammer when the incident occurred.
Madore has reportedly been incapable of working since the accident and "will continue to be so incapacitated in the future," says the suit.
The suit doesn't specify what sort of compensation Madore seeks through the suit.
(Source: Worcester Business Journal)
Have you or someone you know been injured while at work? Contact an experienced FELA attorney today who will help you to receive compensation for any injuries that you have endured.