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I try to visit a naked beach a minimum of when a year despite the fact that it's over 1000 miles away. My other half Katie likewise goes but only to accommodate me. For some reason, she always keeps her swimwear on! That is most likely due to the fact that she's ashamed about her huge breasts. I think I am fortunate that she is willing to humor me with her presence for that a person day during our vacation just to make me happy. We often have dedications there consisting of talking to some family and pals. Nevertheless, going to the nude beach is our trick, at least up until now anyway. Now the entire world will understand through this story!
Before I get into the nitty-gritty, let me provide you a little background about Katie. Even from a distance, as a breast guy, I might tell that she was the one for me. What very first attracted her to me was her uncommonly deep cleavage line, which I believed would lead me to a luscious set of grand breasts, and it did!
OK, I confess it. I was a somewhat shallow guy at the time and most likely still am to some degree. I was completely smitten. It was love at very first sight, at least for me anyhow! For Katie, that was another story. I tend to have an odd sense of humor constantly making self-deprecating remarks. My humor gets old after a while, and you probably understand individuals like that and try to prevent them. She is actually ashamed about her objects of magnificence, nevertheless, over the years, she has come to appreciate them more through my eyes as they are undoubtedly her most outstanding physical asset.
Few individuals have actually had the enjoyment of seeing Katie's breasts up close. She came from a stringent Midwestern household, didn't date much and hasn't had much sexual experience. I had more sexual experience than Katie, I was far from being the world's greatest enthusiast then or even now. I fell deeply in love with Katie first and after that her beautiful breasts! Yes, I'm most likely still a shallow individual, but I actually like her and those enormous cars of pleasure. Simply think of, I now had a firm set of breasts that are genuine and all to myself! If you saw those splendid breasts you would observe that are specifically out of proportion to her 5-foot 8-inch frame. Simply think of; size 44D breasts on a woman who is only 5 feet 8 inches high that they looked absolutely amazing!
The extra weight of her breasts doesn't seem to bother her although it added weight to her 200-pound frame. Listen, Katie is a big lady. You ought to see her in heels! To this day I still like her and her breasts; overweight or not. I enjoy them so much that over the years I have sucked them a lot that they extended to a 44DDD cup.
Big breasts by themselves, nevertheless, as stunning as they may be, are insufficient for a long-lasting stable relationship. Katie also has a fantastic smile, a terrific sense of humor and luckily does not take herself too seriously. She is likewise a caring mother to our kids who are now grown up and by themselves. All of those qualities go a long way towards a successful relationship which has lasted now for lots of years. Katie has another terrific quality when it concerns orgasms. In the beginning, her entire body becomes stiff and she begins to vibrate frantically. So uncontrollably often that it looks like she's having an epileptic seizure.
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Fundraiser event to update ground work and tile waterway to our existing Paw Park. Day will have vendor booths, games and activities for dogs, demonstrations and educational sessions. Music on site. Silent auction, dog races and dog and owner fashion show.
The park will have a strict social distancing and sanitization plan for all aspects of our events and programs. For the event, you can expect every volunteer, sponsor and patron to have their temperature taken before admittance to any program. Also, masks will be strongly recommended by all. At this time, all park employees will have masks on during any contact with the public.
Events on this calendar are subject to change. Please check with event organizer to ensure event is still taking place. For updates on things to do, view the Local Reopening Guide.


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F-Type Chequered Flag Celebrates 70 Years Of Jaguar Sports Cars
F-TYPE Chequered Flag Limited Edition Coupé and Convertible revealed, celebrating 70 years of Jaguar sports cars since the XK 120's introduction
Features include Chequered Flag badging, and unique branding on the headrests, tread plates and dark brushed aluminium centre console finisher
Windsor Leather interior with embossed Performance Seats, Ebony Suedecloth headlining and steering wheel with red top centre marker
Touch Pro infotainment system now with Apple CarPlay
Available in Caldera Red, Fuji White or Carpathian Grey matched with Black Contrast Roof* and 20-inch wheels in Gloss Black with Diamond Turned finish
Powered by the 300PS four-cylinder and 340PS and 380PS supercharged V6 engines exclusively with eight-speed Quickshift transmissions
Refined damper tune on F-TYPE R, improving ride comfort at low speed
29 October 2018, Dubai, United Arab Emirates:
Since the reveal of the XK 120 in 1948, sports cars have been integral to Jaguar's heritage, the culmination of this rich lineage being the F-TYPE- winner of more than 170 global awards. Now, in celebration of 70 years of Jaguar sports cars, the F-TYPE range has been enhanced by the addition of the Chequered Flag Limited Edition.
Based on the F-TYPE R-Dynamic Coupé and Convertible, and available with powerful four- and six-cylinder engines, the Chequered Flag features a range of subtle visual enhancements to the exterior and to the driver-focussed "1+1" cabin.
Highlights include a Black Contrast roof on the Coupé and a luxurious Windsor Leather interior featuring Performance seats with embossed headrests, a Dark Brushed Aluminium centre console trim finisher and – in recognition of Jaguar's motorsport successes – a steering wheel with discrete Chequered Flag logo and red leather band to mark the 12 o'clock position.
Ian Callum, Director of Design, Jaguar, said: "Perfect proportions, design purity and visual drama – every Jaguar must express these qualities, and none more so than F-TYPE. In creating the Chequered Flag we've focused on details which enhance F-TYPE's presence and promise of performance – and in doing so, made a fitting celebration of 70 years of beautiful, fast, Jaguar sports cars."
The F-TYPE's exquisite, perfectly-proportioned exterior is enhanced by the Exterior Black Design Pack, which benefits from SVO extended side sills to subtly increase visual width and give the car even greater presence and poise. The 20-inch Gloss Black wheels with Diamond Turned finish are exclusive to the Chequered Flag and perfectly complement the red finish of the brake calipers. The Chequered Flag's superbly-crafted Ebony Windsor Leather interior is offered with contrast stitching in a choice of Red or Cirrus. The slimline Performance seats, with optional heated and cooling functionality, feature headrests embossed with Chequered Flag branding.
In place of the F-TYPE R-Dynamic's Delta aluminium centre console trim, the Chequered Flag features a Dark Brushed Aluminium finisher. The texture and finish of this material perfectly complements the Ebony Windsor Leather.
The Touch Pro infotainment system features Meridian audio, a suite of connected services and, for the first time in F-TYPE, Apple CarPlay to make it easier than ever to access tailored smartphone apps using the 10-inch touchscreen.
Power comes from the 300PS/400Nm 2.0-litre four-cylinder Ingenium petrol engine or the 340PS/450Nm and 380PS/ 460Nm supercharged 3.0-litre V6 petrol engines. All offer an outstanding balance of responsiveness, power and efficiency – and all with a visceral soundtrack which reflects the F-TYPE's truly driver-focused character.
All engines are matched to eight-speed Quickshift transmissions and send drive to the rear wheels, or – in the 380PS models – the choice of Jaguar's all-wheel drive system with Intelligent Driveline Dynamics.
Additional 20MY F-TYPE enhancements
Taking learning from the SVR derivative, the damper tune on the F-TYPE R Coupé and Convertible models has been refined, giving an improved level of ride comfort at low speed. This has been achieved by reducing the damping by 24% at the lower damping velocities (up to 0.3m/s), whilst increasing overall capacity by up to 30%.
Additionally, the rear upper ball joint from the SVR has been incorporated into the F-TYPE R, with modifications to the rear knuckle and upper control arm, further enhancing capability and system robustness.
The rear camera and front park aid are now provided as standard across all F-TYPE derivatives.
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text: Gigli (2003) (part 1 of 8) by Dr. Winston O'Boogie · February 14, 2004 Page 1 of 812345678» The Cast of Characters: Larry Gigli (Ben Affleck). A large-headed, blank-faced, overacting mob hitman. Ultimately ends up Chasing J-Lo. His last name rhymes with "really", as in, he only "really" has an Italian accent for one-fourth of his scenes. The least convincing thug in movie history. Her name was Rochelle, but everyone knew her as Ricki (Jennifer Lopez). A New Age-y mob hitwoman who studies ancient martial arts, wears hip-hugging jeans, and drinks herbal tea. And, oh yeah, she's also a lesbian, but that doesn't stop Gigli from hooking up with her. The second least convincing thug in movie history. Louis (Lenny Venito). Gigli's mob boss. Doing his best impression of SNL's Jim Breuer doing an impression of Joe Pesci. Hatches the dumbest criminal plot since Cain slew Abel thinking God wouldn't find out. Has Gigli and Ricki kidnap a prosecutor's brother in order to… nah, it's better if you find out for yourselves. Brian (Justin Bartha). The prosecutor's brother, who is, as the movie takes every opportunity to remind us, mentally handicapped. Afflicted with Tourette's Syndrome and a severe case of Rain Man-itis, he's a Noble Retard, at least when he isn't jerking off to Australian weather forecasts or episodes of Baywatch. Det. Stanley Jacobellis. Christopher Walken teleports in from his home planet to do his impression of Christopher Walken. Breaks all his lines down to their constituent syllables and puts random inflections on each. Offers forth one plot point before being dragged back to the set of Kangaroo Jack. Gigli's Mom (Lainie Kazan). Hollywood's current ethnic mother of choice. She plays Gigli's Big Fat Obnoxious Momma with repulsive gusto, revealing her dislike of visible panty lines and her willingness to experiment—ugh—with other women. Mr. Starkman (Al Pacino). A mob boss who likes to turn all the dials on his Sudden Rage Meter up to eleven. Shows up for one scene to, basically, point out how stupid the movie's plot is and how dumb all of its characters are. To read the rest of this article, support the Agony Booth on Patreon. This post is available to our patrons who pledge $5 or more per month on Patreon. Click the "Unlock with Patreon" button below to sign up with Patreon or to log in with your existing Patreon account. Unlock with Patreon Already a qualifying Patreon member? Refresh to access this content. Continue to Page 2 → Tags: Al PacinoBen AffleckBiggest Movie Flops EverChristopher WalkenJennifer LopezMega RecapsRazzie Worst Picture NomineesStarring Ben Affleck's TeethValentine's Day Recaps Multi-Part Article: Gigli (2003)Next story Gigli (2003) (part 2 of 8) You may also like...Hit or Bomb? February 2020 movie predictionsFeb 6, 2020Female superhero movies, rankedJun 1, 2017Wonder Woman #1 (1987): Gods and Mortals (part 1 of 7)Jun 8, 2020 Search Advertisements Meta Log in Entries feed Comments feed WordPress.org Sitemap About the Site: The Agony Booth FAQ Meet the Staff Contact Us Text Archives: Star Trek Reviews & Recaps Movie Reviews & Recaps TV Episode Reviews & Recaps Interviews The Agonizer (Everything Else) Other Content: Article #tags Jump to a Random Article Video Shows Video Archives The Raw Feed Jump to a Random Video Latest Updated TV Shows: Star Trek (TAS)Star Trek: VoyagerStar Trek: The Next GenerationStar TrekStar Trek: PicardStar Trek: Short Treks All TV shows... 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Latest CommentsMichael Weyer on How presidential action movies ruined our politicsMichael Weyer on How presidential action movies ruined our politicsMichael Weyer on How presidential action movies ruined our politicsrtpoeman on How presidential action movies ruined our politicsrtpoeman on How presidential action movies ruined our politicsMurry Chang on What We're Streaming: July 2020Nathan Kerner on How presidential action movies ruined our politicsAJ on How presidential action movies ruined our politicsChris Hedrick on How the Snyder Cut and a child's question sum up modern fandomChris Hedrick on How the Snyder Cut and a child's question sum up modern fandom Popular Posts This Week Agonizer / Comic Book Review / Text Wonder Woman #4 (1987): Gods and Mortals (part 4 of 7) Jun 29, 2020 Agonizer / Text What We're Streaming: July 2020 Jul 1, 2020 Movies / Text How the Snyder Cut and a child's question sum up modern fandom Jun 24, 2020 Text / TV / TV Recap Star Trek (TAS) "The Counter-Clock Incident" Jun 25, 2020 Text / TV / TV Recap When Reading Rainbow went behind the scenes of Star Trek: The Next Generation Mar 24, 2015 Movies / Text How presidential action movies ruined our politics Jul 2, 2020 Movie Recap / Movies / Text The Black Hole (1979), a recap (part 6) Jun 9, 2020 Agonizer / Text Stop saying 'free speech' only applies to the government Dec 9, 2014 Text / TV / TV Recap Star Trek: Voyager "Q2" Jun 18, 2020 Movie Recap / Movies / Text Demolition Man (1993), a recap (part 1 of 6) Apr 27, 2020 Agonizer / Comic Book Review / Text Wonder Woman #3 (1987): Gods and Mortals (part 3 of 7) Jun 22, 2020 Text / TV Did Star Trek really show TV's first interracial kiss? 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I recently got rid of most of my autographed baseball collection, but I kept three:
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- Vin Scully – For obvious reasons, like the greatest announcer of all time; and
- Clayton Kershaw – Nobody likes him more than me. I have argued for a long-time that he will go down in history as the greatest Dodgers pitcher of all time (something for which I have been repeatedly belittled). The kid in the picture with Clayton is my son, who was 8 at the time (at Wrigley Field). He's now 17. The ball is really his.
The point is: I love Clayton Kershaw and while I agree that any player is expendable, I would suggest that FAZ is talking to Kershaw about staying a Dodger for life as we speak. In case, you don't know, I have the highest regard for Clayton Kershaw, which makes what I am about to say so painful: If not for Clayton Kerhsaw, the Dodgers might have won the pennant. Of course, without him, they would have never gotten to that point!
Now, mind you, I am not saying it's all his fault, but here it was: The Great Clayton Kershaw against The Very Good Jon Lester and yet Clayton was cuffed around pretty good. It could be argued that his last game of the season was his worst game of the season. Now, if he was injured, I apologize to you Clayton, but if not, this was a shutout waiting to happen. Then the Dodgers had Rich Hill who also looked unhittable in his last outing and lo' and behold, that's the pennant. Only problem was – it didn't happen.
Clayton Kershaw is the 800-pound gorilla in the room. There is every expectation that he would have pitched a shutout… maybe a perfect game – he's that good. But, when I saw him throwing 95, 96 and 97 MPH, I felt he was doomed. Clayton pitches best at 92-94 – his pitches have more movement at that speed, it seems to me.
His slider and curve weren't working. In my mind, I think it was because he was amped up, psyched up and overthrowing. Clayton is highly competitive, highly emotional and highly energetic. He's one of the hardest workers in baseball… maybe any sport, but in a clutch highly charged situation, sometimes you have to "dial it down." But, is that something he can do?
Over his 9 years in the major leagues, Clayton is 126-60 with a career 2.37 ERA. Some pitchers get close to a 2.37 ERA in a career year, but with Clayton, that's just his average. His strikeout to walk ratio is insane. He's so good during the regular season that you are surprised when he gives up 3 runs! But in the playoffs, he is 4-7 with a 4.55 ERA. That's almost twice what he does in the regular season!
Now, I will give you that while his regular season WHIP is 1.007, his playoff WHIP is only a little higher at 1.157, which suggests that he has been unlucky to some degree. Yes, that is some of it, but Clayton has not been the same pitcher in the playoffs as he has been in the regular season.
"Trade the Bum!" That's not even an option insofar as I am concerned. I say "Fix him" and I also think it's easier than we might think. I want Clayton on my team, but I want him to achieve what he is capable of achieving. I don't think he a choke artist – I just think he gets amped up too much.
How to fix it? There are probably a myriad of ways: Yoga, Pilates, Meditation, Visualization, Zen and on and on. I can't fix it. You can't fix it. Only Clayton can fix it if he wants to.
The Dodgers really didn't lose because of Clayton Kershaw, but they very might have won if he had been the Clayton we see during the season. Here's the million dollar question: Is he open to change?
He has to change something. He's still my guy!


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Discussion in 'Super Rugby' started by Jaguares, Jun 20, 2015.
New Zealand
Care to provide any evidence that supports this?
Clearly, I feel the video supports this.
For the third, and final time - we are at an impasse.
London Wasps
agreed, i don't think it stopped the try his momentum was halted and i don't think he would have been able to reach out, but i do understand the decision and don't think it's horrifically bad.
c'est la vie
great game, while I always thought the Highlanders are the better side playing in Sydney is a massive advantage for the Tahs. It's basically the hardest place to win away in super rugby.
I felt like the tah's were overconfident and expected to dominate the landers up front. But the Highlanders wouldn't have it, their gameplan was far too smart and executed well by Ben, Aaron and Lima.
The Potgieter incident. While its a shame a big game has an incident like this it was all on Potgieter. It's the players responsibility not to make contact with the head. And lets be honest it looked like Potgieter was going for the head with what was clearly a swinging arm from a few meters out. A swinging arm to the head is a yellow card, a swinging arm to the head that prevents a try is a yellow card and a penalty try. It's that simple.
Sapoanga's goal kicking is a bit up and down? At times he hits it really well but overall he's only kicking 70-71%... which is ok but nothing more.
When you commit an act of foul play that close to your own goal-line, you put yourself and your team at risk that a big decision is going to go against you. Potgeiter really wound up his right arm... there was no need for it. He would have been better simply trying to slip his arm under the ball.
Also, even if penalty try wasn't ruled, its still a yellow card and a penalty right by the posts. That makes the score 23-17 instead a 27-17 and the game restarts in the same place. To be brutally honest, the Waratahs never looked like scoring for the rest of the match, so with no penalty try, it was still four tries to one.
The penalty try did not change or affect the result of the game, it just gave Cheika and the Sydney media an excuse and something to bleat about.
I don't have a problem with the Potgeiter decision, I just feel it's a shame as instead of discussing how the Tahs were completely outplayed, we (and several media articles) are talking about the potgeiter incident. I guess the media will always gravitate to controversy.
has their been much talk of Foley over there? It was quite unreal how bad he was I think the service from his 9 was bloody average at times which didnt help but for a player of his experience to crack like he did is a bit of a wonder?
I mean jeez he's just walked into a world of hurt imo as if he's played by the Wallabies he can expect more of the same sort of play against him I suspect. Kinda like how Sopoaga was found out by the Brumbies. I think he can expect similar treatment from that game aswell.
Think you'll be surprised by how resilient Foley is, he's got bags of guts, so i wouldn't write him off after one poor game he's been good for the Tahs recently, and he fits chiekas game plan perfectly.
The 'landers pack demolished the Tahs, hard for 1/2 backs to perform off that, and that will have a nock on effect right through the team.
I read a comment today that Phipps and Foley cannot win the world cup on the back of their performance on Saturday night and I tend to agree. No ones really making excuses for the Tahs except probably some Tahs fans or maybe just Phil Kearns hahaha.
The thing about Kearns is, any praise he gives seems superficial, like he's been told he has to do it as part of his job. Ingenuine c**t.
Yeah I read that piece in the Fairfax press. There's something in that analysis - the Wallabies will necessarily be a different beast at least to some extent with the greater depth to choose from this year in particular, but given both will be coached by Cheika, it's a bit of a worry.
That said, I can't be too hard on Cheik - the man is still responsible for breaking a 20 year drought for us and thus giving Tahs fans everywhere the best year ever in our Super Rugby history (was at pretty well every home game last year including the final, so I'll be forgiving of Cheik for a while to come).
I'm not very confident this year for the World Cup, but hopefully we can give it a decent shake and shock a few people.
Kearns is rusted on NSW mate, getting a genuine compliment out of him about non NSW or non AUS is never going to happen, he'll always give a compliment between clenched teeth.
Even when he's doing the Rebels games you hear stuff like "gee the Rebels have improved this year" in an almost sarcastic tone. Thing is we feel the same way about him, I think even NSW people know it, but we just accept it as Kearnsy and Marto being Kearnsy and Marto. There for "entertainment factor" but not much else.
Cheika is the best coach for us, no doubt however I think his game plan fell over at the tahs because of the injury to Beale. I'm not saying Beale is the messiah, but you just need 2 playmaking/kicking players in the backline, foley is one of them and beale is normally the other at 12. Alternatively you could have that player at 15 but with Beale out there wasn't a similar player to do the job of the 2nd playmaker.
At least with the Wallabies, if that 2nd playmaker is injured we at least have some depth which should not disrupt things too much.
I'll be happy if the Wallabies are knocked out in the quarter finals and i'll be really happy to make the final, but that's a massive ask. Winning it - think I have more chance of winning tattslotto.
NZ will always be the team to beat, I just don't think I can handle NZ winning again, I would love to see a team who hasn't won it before get up - Ireland, France etc. I think SA are going to get found out with the majority of their team playing provincial rugby overseas and just that little bit older and slower.
Well they aren't there for their knowledge of the rugby Laws, that's for sure!!
He's just a c*nt mate, doesn't matter where he's from, it doesn't excuse his ********, fortunately we won't have to hear his God awful ranting and sulking in the final.
He's the sort of c*nt you want to beat again and again and rub it in and pull the fingers in his face every time you score. He nearly sinks you down to his level because he's such a tw*t.
:lol: To be honest I think he'd find it quite funny how much hate he inspires over in NZ from some fans. I've met him at one or two corporate sports functions, and he's a pretty funny guy that doesn't take too much very seriously. He's massively one-eyed, but he's happy to admit that and most of his smart arse commentary is said with tongue planted firmly in cheek.
I kinda feel the same way really. In fact I'd love to see Ireland get up almost as much as I'd love us to win to be honest.
So in other words he's a middle aged troll?
He epitomizes Australians/Australia sport for me, same with Shane Warne, no class, crass and ignorantly arrogant.
Calling him a troll would imply he was carrying on the way he does specifically to upset opposition fans. He's not. He's just a one eyed fan in the commentary box, much like Eddie and Stevo in the UK.
Yeah this type of behaviour doesn't generally sit well with kiwis. Kiwis that become successful tend not to forget how hard they worked to get there.
Thankfully not all of us Aussies are like that, I just hate it when kiwis say things like "typical aussies" and lump us all in the same boat, most of us are not much different to you.
Well perhaps you should get better representation at the top end. It's hard not to lump you all into that stereotype when a lot of your ex-leading sportsmen are mouthy and obnoxiously arrogant, and your current sportsmen. It's ingrained in the Australian sporting culture. It's terrible.
I feel like there was a golden age in sport in Australia over a decade ago and a lot of them were arrogant and competitive, so they think the best way of getting success is acting like this. But it's not and now it's not nearly as strong as it once were and it just comes off as stupid now.
There's self confidence and then there's just being a c*nt.
Separate names with a comma.


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Growth and vibrational spectroscopy of K2LiyNixCo1-xSO42.6H2O(y=0.1;0.2;0.3;0.4) crystals Vib. Spectrosc. (IF 1.917) Pub Date : 2020-06-10 Tiago S. Pacheco; Zélia M.C. Ludwig; Diogo R. Sant'Anna; Genivaldo J. Perpétuo; Carlos J. Franco; Edinei C. Paiva; Santunu Ghosh
The mixed crystals of the Tutton's salt doped with Li following the empirical formula K2LiyNixCo1-x (SO4)2.6H2O, were synthesized from the slow evaporation of the solvent at constant temperature. The presence of K, S, Ni, Co and O elements in the studied crystalline structure was confirmed by EDS spectroscopy using a scanning electron microscope and their quantification including Li was carried out
Quantitative determination of the penetration of a silica-based consolidant in a limestone by FTIR spectroscopy Vib. Spectrosc. (IF 1.917) Pub Date : 2020-07-02 M.L. Almoraima Gil; Manuel Luna; Rafael Zarzuela; M. Valme García-Moreno
Application of Attenuated Total Reflection - Fourier Transform Infrared spectroscopy to characterize the degradation of littered multilayer food packaging plastics Vib. Spectrosc. (IF 1.917) Pub Date : 2020-06-24 Shaileshkumar Baskaran; Mythili Sathiavelu
Multilayer packaging is used in food consumables as disposable packs. The Attenuated Total Reflection - Fourier Transform Infrared spectroscopy (ATR-FTIR) spectroscopy is used in detecting defects in manufactured food packs. The consumed food packs like chips, biscuits and chocolates are littered without recycling. This is the first study that focused on the degradation potential of littered multilayer
COMPOSITIONS OF LIQUID MIXTURES FROM NEAR-INFRARED SPECTRUM DATA VIA RADIAL BASIS FUNCTIONS AND ARTIFICIAL NEURAL NETWORKS Vib. Spectrosc. (IF 1.917) Pub Date : 2020-07-01 Hyungjoo Leea; Carlos Torres-Verdín
We introduce two methods for the calculation of compositions of liquid mixtures from near infrared (NIR) absorption spectroscopy data. Radial basis function (RBF) and artificial neural network (ANN) approaches are separately applied to establish correlations between spectral data and concentrations of each component. Principal component analysis (PCA) was implemented to establish the correlations and
Raman spectroscopy study of glass corrosion Vib. Spectrosc. (IF 1.917) Pub Date : 2020-06-12 Branislav Hruška; Tadeáš Gavenda; Filip Vašíček; Roman Svoboda
Binary sodium silicate and potassium silicate glasses with different alkali content were exposed to the corrosion environment of 35 % hydrochloric acid (HCl). Glass samples were measured by Raman spectroscopy and the spectra were compared with Raman spectra of original pristine glasses in order to observe structural changes induced by corrosion within the surface layer. The usage of confocal Raman
Prediction of strength properties of poplar alkaline peroxide mechanical pulp using near infrared spectroscopy and multivariate calibration Vib. Spectrosc. (IF 1.917) Pub Date : 2020-06-10 Long Liang; Guigan Fang; Lulu Wei; Shanming Han; Yongjun Deng; Beiping Zhu; Ting Wu
Application of near infrared (NIR) spectroscopy to pulp and paper research is almost based on chemical pulping, but little research has been directed toward the use of NIR to mechanical pulping. Compared with chemical pulp, mechanical pulp exhibits certain attractive qualities such as high pulping yield, sufficient opacity and bulk. However, because non-cellulose components (hemicelluloses and lignin)
Microstructure and Optical Vibration Features of Complex Cobalt Molybdates Synthesized by the Microwave and Conventional Hydrothermal Processes Vib. Spectrosc. (IF 1.917) Pub Date : 2020-06-29 Guilherme M. Martins; Roberto L. Moreira; Anderson Dias
Complex cobalt molybdates were prepared by conventional (CH) and microwave-assisted (MW) hydrothermal methods. Structural, morphological and vibrational properties of the obtained NaCo2(H3O2)(MoO4)2 and Co2(MoO4)(OH)2 materials were investigated. The first compound was obtained as majority phase for all tested MW processing conditions; conversely, for the CH method the second composition (desodiated)
Impact of dimethyl sulfoxide and natural lipid heterogeneity on the structural properties of sphingomyelin membranes Vib. Spectrosc. (IF 1.917) Pub Date : 2020-06-24 Beatrice Gironi; Marco Paolantoni; Andrea Nicoziani; Assunta Morresi; Paola Sassi
In the present study we focus on the effect of dimethyl sulfoxide (DMSO) on sphingomyelin (SM) model membranes composed by a binary mixture of a natural SM extract from porcine brain (BSM), and cholesterol (Chol). We compare the BSM properties with those of another natural SM extract from egg yolk (ESM), mainly palmitoyl-SM, in order to follow the effects of lipid heterogeneity on thermotropic and
On the rapid and non-destructive approach for wood identification using ATR-FTIR spectroscopy and Chemometric methods Vib. Spectrosc. (IF 1.917) Pub Date : 2020-06-27 Vishal Sharma; Jyoti Yadav; Raj Kumar; Daniela Tesarova; Adam Ekielski; Pawan Kumar Mishra
The present study offers a rapid and non-destructive approach for wood identification utilizing Attenuated total reflection Fourier transform infrared (ATR-FTIR) analytical technique with chemometric methods. This will estimate the source of origin of unknown wood samples or matching of two or more than two wood samples, for its applications in the wood and forensic science. The discrimination of wood
Vibrational and structural studies of new Cu2+ and Co2+ complexes based on croconate ion and 5,5'-dimethyl-2,2'-dipiridyl ligands Vib. Spectrosc. (IF 1.917) Pub Date : 2020-06-18 Helder Souza; Gilson Rodrigues Ferreira; Leonã S. Flores; Luiz F.C. de Oliveira
Charge-Transfer Mapping of Nanostructured GaN/Ag Surfaces using Surface Enhanced Raman Spectroscopy Vib. Spectrosc. (IF 1.917) Pub Date : 2020-06-25 Omari Kirkland; Jan L. Weyher; John R. Lombardi
In this work we present a method for mapping the degree of charge transfer (ρCT) on variously etched GaN surfaces covered by nanoclusters of silver using Raman imaging. The goal was to map ρCT across the surface of a substrate in order to discover the surface features which stimulate relatively large charge transfer from molecule to substrate. These substrates were used because they contain a variety
Rapid quantification of isoflurane in anesthetic nanoemulsions using Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy (ATR-FTIR) Vib. Spectrosc. (IF 1.917) Pub Date : 2020-06-11 Mohammad Hossein Tootoonchi; Ryan Bardsley; Thomai Panagiotou; Robert J. Fisher; Ernesto A. Pretto; Christopher A. Fraker
There is increased research into pharmaceutical nanoemulsions where the timing of quantification of active components can dictate continuous manufacturing production cost and consistency. The goal of this study was development of a rapid quantification method for isoflurane nanoemulsions using Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy (ATR-FTIR). Isoflurane was quantified
Tip-Enhanced Raman Spectroscopy Investigations of Core-Shell Ag-Proteins Nanoparticles Synthesized by Rhodotorula Mucilaginosa and Rhodotorula Glutinis Fungi Vib. Spectrosc. (IF 1.917) Pub Date : 2020-06-24 Enzo V.H. Agressott; Thiago Alves de Moura; Nathália Leal Marinho; Thiago de Lourenço e Vasconcelos; Francisco Afrânio Cunha; P.B. Fechine; Alexandre R. Paschoal; Antônio Gomes de Souza Filho
Study of the vibrational properties of haloperidol under high-pressure Vib. Spectrosc. (IF 1.917) Pub Date : 2020-06-22 Raphaela A. Lima; Jennyffer S.M. Quimbayo; Daniel L.M. Vasconcelos; Cristiano B. Silva; Josias V. Santana; Geancarlo Zanatta; Valder N. Freire; Paulo T.C. Freire
Haloperidol, with molecular formula C21H23ClFNO2, is a conventional antipsychotic drug used to relieve the symptoms of schizophrenia. Although its pharmacology has been extensively reported, only few studies focused on its vibrational features. In this work, Raman spectroscopy was used to investigate the vibrational properties of the haloperidol crystal under high-pressure conditions up to approximately
LABEL-FREE SPECTROSCOPIC IMAGING OF THE SKIN CHARACTERIZES BIOCHEMICAL CHANGES ASSOCIATED WITH SYSTEMIC SCLEROSIS Vib. Spectrosc. (IF 1.917) Pub Date : 2020-06-22 Hari Sreedhar; Mary Carns; Kathleen Aren; Shaiju S. Nazeer; Michael J. Walsh; John Varga
Systemic sclerosis (SSc) is a chronic multisystem disease associated with collagen accumulation and fibrosis, most prominent in the skin and lungs. There is considerable patient-to-patient, as well as within-patient temporal, heterogeneity in the extent and course of fibrosis. The widely used modified Rodnan skin score (mRSS) employs skin thickening as a surrogate for SSc severity; however, the value
Vibrational spectroscopy and analysis of galvanoplasty retention capacity in ceramic matrices Vib. Spectrosc. (IF 1.917) Pub Date : 2020-06-20 Fernanda A. Damasceno; Enzo V.H. Agressot; Rebecca Veldhuis; Maria de Fátima S. Rodrigues; Raimundo Nonato P. Teixeira; Larissa Kerollaine M. Gomes; Jorge Marcell C. Menezes; João H. da Silva
The clay used to remove toxic metals from water bodies has been tested by countless researchers. The incorporation of metal ions into ceramic matrices can be an alternative in the destination of residues from electroplating industries. After incorporating these ions into clay mineral structures, some properties may appear. Among these, we can mention the vibrational properties. The present work shows
Variation in wood shrinkage evaluated by the eigenvalue distribution of the near infrared spectral matrix Vib. Spectrosc. (IF 1.917) Pub Date : 2020-06-04 Harusa Tsutsumi; Hirokazu Haga; Takaaki Fujimoto
Wood interactions with water occur at the cell wall, therefore, shrinkage should be closely related to wood density. Nevertheless, woods with almost the same density often show substantially different shrinkage. This study suggests a method to evaluate variation in shrinkage based on an eigenvalue analysis of the near infrared spectral matrix. The set of eigenvalues calculated from the variance-covariance
Raman and photoacoustic spectroscopies of SnO2 thin films deposited by spin coating technique Vib. Spectrosc. (IF 1.917) Pub Date : 2020-06-12 Regiane Gordia Drabeski; Jaqueline Valeski Gunha; Andressa Novatski; Gelson Biscaia de Souza; Sergio Mazurek Tebcherani; Evaldo Toniolo Kubaski; Daniele Toniolo Dias
SnO2 thin films were grown on glass substrate using a spin-coating technique. The films grown in different layers and subjected to pressure-assisted heat treatment (PAHT) were characterized by Raman spectroscopy and Photoacoustic measurements. Raman spectroscopy showed the SnO2 presence in the grown thin film and in the substrate. In addition, PAHT can change the adsorbed oxygen and the oxygen vacancies
Exploring pre-analytical factors for the optimisation of serum diagnostics: Progressing the clinical utility of ATR-FTIR spectroscopy Vib. Spectrosc. (IF 1.917) Pub Date : 2020-06-03 James M. Cameron; Holly J. Butler; David J. Anderson; Loren Christie; Lily Confield; Katie E. Spalding; Duncan Finlayson; Stuart Murray; Zanib Panni; Christopher Rinaldi; Alexandra Sala; Ashton G. Theakstone; Matthew J. Baker
Data quality and reproducibility are vital for robust, reliable and consistent diagnostic techniques within clinical environments. Most variance within clinical laboratories occur within the pre-analytical phase, prior to obtaining and analysing data. Herein, we investigate pre-analytical considerations for the spectroscopic analysis of blood serum for the purpose of clinical diagnostics. Variables
Preliminary study on discrimination of healthy and osteoarthritic articular cartilage of canine by hollow fiber attenuated total reflection Fourier transform infrared spectroscopy and Fisher's discriminant analysis Vib. Spectrosc. (IF 1.917) Pub Date : 2020-06-01 Yuan Zhao; Dan-Ying Ma; Juan-Juan Fu; Yi-Lin Bao; Jin-Lan Tang; Lin-Wei Shang; Xiao Wang; Jian-Hua Yin
Submillimetric hollow fiber (HOF-) attenuated total reflection (ATR-) Fourier transform infrared spectroscopy (FTIRS) technique is very suitable for in situ detection of biological samples. HOF-ATR-FTIRS analysis discloses that the significant changes in collagen fiber and proteoglycan between healthy and osteoarthritic (OA) canine specimens. The technique combined with principal component analysis
Reduction of the phytotoxic effect of mercury chloride by rutin and evaluation of interactions by vibrational spectroscopy (Raman and FTIR) Vib. Spectrosc. (IF 1.917) Pub Date : 2020-05-23 Yedda M.L.S. de Matos; Daniel L.M. Vasconcelos; Antonio C.H. Barreto; Janaina E. Rocha; José B. Neto; Fabia F. Campina; Tássia T. de A. M. Guedes; Amanda K. Sousa; Raimundo N.P. Teixeira; Juan C. Alvarez-Pizarro; Henrique D.M. Coutinho; João H. da Silva
Toxic metals can cause toxicity problems in the organisms exposed to them. Many substances are able to reverse this toxicity. Among the secondary metabolites of plant origin investigated are flavonoids. To evaluate the cytoprotective activity, dry mass and possible damage to the membranes of Lactuca sativa (lettuce) seedlings subjected to different concentrations of mercury chloride in association
The role of morphology in all-dielectric SERS: A comparison between conformal (T-rex) and non conformal TiO2 shells Vib. Spectrosc. (IF 1.917) Pub Date : 2020-05-23 Irene Vassalini; Orhan Sisman; Elisabetta Comini; Ivano Alessandri
All-dielectric optical nanoantennas and resonators are attracting an ever increasing interest for enhanced Raman spectroscopy. These systems can take advantage of many factors that concur to determine their Raman response, including the type of material, refractive index contrast between interfaces, size, shape, roughness and geometrical configuration. However, the relative impact of each one of those
Raman Spectroscopy of AgNO3 Complex Encapsulated Fullerene (C60) Microcube Vib. Spectrosc. (IF 1.917) Pub Date : 2020-05-23 Ying Hou; Bei Nie; Zhe Li
IR study on adsorption of carbon dioxide on alkaline earth metal ion-exchanged titanate nanotubes at room temperature Vib. Spectrosc. (IF 1.917) Pub Date : 2020-05-21 Eri Uematsu; Atsushi Itadani; Kazuyoshi Uematsu; Kenji Toda; Mineo Sato
We investigated the adsorption of carbon dioxide (CO2) at room temperature on alkaline earth metal ion-exchanged titanate nanotubes using Fourier transform infrared (FT-IR) spectroscopy and volumetric adsorption. CO2 adsorption capabilities were found to increase with increase in the ionic radius of the alkaline earth metal ions exchanged. Alkaline earth metal ion-exchanged titanate nanotubes exhibited
Assignment of optical phonons at the zone center of distorted orthorhombic RCrO3 (R = La, Pr, Nd, Sm, Eu) perovskites using force-field lattice dynamics model Vib. Spectrosc. (IF 1.917) Pub Date : 2020-05-19 Y.M. Jana; Jyoti Saha; Saikat Nandi
Raman spectroscopy for forensic semen identification: Method validation vs. environmental interferences Vib. Spectrosc. (IF 1.917) Pub Date : 2020-05-18 Taylor Casey; Ewelina Mistek; Lenka Halámková; Igor K. Lednev
Proper identification of body fluids at crime scenes is imperative to forensic investigations, as they yield crucial pieces of DNA evidence that lead to subsequent investigation resolution and criminal justice. Nevertheless, body fluid identification can prove a burdensome process, as several ubiquitous substances found at crime scenes often resemble the appearance of a specific body fluid. Therefore
Transesterification of different vegetable oils using eggshells from various sources as catalyst Vib. Spectrosc. (IF 1.917) Pub Date : 2020-05-12 Paula Ligocki Graziottin; Morgana Rosset; Dirléia dos Santos Lima; Oscar W. Perez-Lopez
In the present study, different sources of eggshell were used as catalysts in the transesterification reaction for biodiesel production using different vegetable oils (soybean, canola, corn, and sunflower). Eggshells samples were calcinated at 800 ºC and characterized by XRD, SEM, and CO2-TPD. Transesterification reactions were performed at 65 °C for 4 h in a batch reactor with alcohol:oil molar ratio
Analysis of nonlinear structural dynamics of uncrystalized polyester under heating using a pulse-induced dynamic compression (PDC) IR method Vib. Spectrosc. (IF 1.917) Pub Date : 2020-05-12 Yuji Nishikawa; Hiroto Itou; Isao Noda; Takeshi Hasegawa
We have developed an advanced rheo-optical method, based on pulse-induced dynamic compression ATR step scan time-resolved-FT-IR spectroscopy. By inserting a massive weight between a film sample and a piezo electric actuator; a clear ring-down compression signal has been successfully detected according to inertial effect obtained from the film sample and massive weight. This rheo-optical method was
Multi-classification identification of PLS in rice spectra with different pre-treatments and K/S optimisation Vib. Spectrosc. (IF 1.917) Pub Date : 2020-05-05 Fangming Tian; Feng Tan; Peipei Zhu
Rice from neighbouring areas and of similar varieties can have a negative impact on classification and identification systems. Hence, it is important to validate methods of identifying similar varieties of rice from neighbouring areas to ensure the traceability of food quality. In this study, Raman spectroscopy and chemometric methods were used to identify and classify 14 similar varieties of rice
Nonresonant Raman spectroscopy analysis of bithiophene and quater-thiophene chains confined in graphene bilayer: A theoretical study Vib. Spectrosc. (IF 1.917) Pub Date : 2020-05-03 O. Boutahir; M. Boutahir; B. Fakrach; A.H. Rahmani; H. Chadli; A. Rahmani
This work focuses on the confinement of bi-thiophene (2T) and quater-thiophene (4T) between two monolayer graphene where the confined oligomer molecules and the bilayer graphene are bonded through van der Waals interactions. The nonresonant Raman spectra of these hybrid nanomaterials were calculated using the spectral moment's method in the framework of the bond-polarizability model. The optimum configurations
Vibrational Spectroscopic Studies of Nitrated Polycyclic Aromatic Hydrocarbons (NPAHs): A Review (1960-2019) Vib. Spectrosc. (IF 1.917) Pub Date : 2020-05-01 Kefa K. Onchoke
Nitrated polycyclic aromatic hydrocarbons (NPAHs) are ubiquitous in the environment. They are carcinogenic and mutagenic, thus posing great health risks to human health, albeit occurring at one to two orders of magnitude lower than the parent PAHs. Because of their occurrence as mixtures with parent PAHs and the existence of isomers in diverse matrices, analyses of NPAHs and identification is often
Raman spectroscopy characterization of the major classes of plasma lipoproteins Vib. Spectrosc. (IF 1.917) Pub Date : 2020-04-30 Alessandra Ricciardi; Gabriele Piuri; Matteo Della Porta; Serena Mazzucchelli; Arianna Bonizzi; Marta Truffi; Marta Sevieri; Raffaele Allevi; Fabio Corsi; Roberta Cazzola; Carlo Morasso
Raman spectroscopy has been vastly employed for the characterization of different bio-molecular species spanning from single protein to the in-vivo analysis of tissues. However, despite the huge work done, a detailed description of the Raman spectra acquired from the main classes of plasma lipoproteins is still missing. In this work, we extracted, the major classes of lipoproteins: the triacylglycerol-rich
Analysis of rat blood plasma upon acute epileptic seizures by infrared spectroscopy with chemometrics Vib. Spectrosc. (IF 1.917) Pub Date : 2020-04-30 Sevgi Türker-Kaya; Gül İlbay
Blood monitoring provides convenient and minimally invasive method to follow-up the patients suffering from epilepsy. For such analysis, Fourier transform infrared (FT-IR) spectroscopy offers rapid, versatile and relatively non-invasive approach which could determine epilepsy induced biomolecular alterations in blood. In the present study, FT-IR spectroscopy combined with chemometrics such as principal
Facile Chemical Analysis of Live Cell Activities by Fourier Transform Infrared (FTIR) Spectroscopy in the Transmission Mode Vib. Spectrosc. (IF 1.917) Pub Date : 2020-04-25 Ren Hu; Cheng Zong; Long-xiang Lin; Ting Wei; Qian Cheng; Yan-xia Jiang; Chang-jian Lin; Bin Ren; Zhong-qun Tian
A facile Fourier transform infrared (FTIR) spectroscopy is developed to detect live cell activities in the transmission mode. With the use of an O ring to aid cell culture on optical windows, live cell activities can be semi-quantitatively investigated using a commercially available demountable liquid device by FTIR spectroscopy in the transmission mode. Cellular volume adaptation to osmolarity was
An effective and rapid approach to predict molecular composition of naphtha based on raw NIR spectra Vib. Spectrosc. (IF 1.917) Pub Date : 2020-04-25 Ling Zhu; Shao Hua Lu; Yao Heng Zhang; Hong Lin Zhai; Bo Yin; Jia Ying Mi
Molecular management has become an important trend in petroleum refining, which relies on the information of petroleum composition. In this contribution, a simple and effective analytical approach is proposed for the rapid prediction of the more detailed molecular composition of naphtha samples based on raw near infrared (NIR) spectroscopy for the first time. The 101 samples of reformed naphtha were
Utilizing ATR-FTIR spectroscopy combined with multivariate chemometric modelling for the swift detection of mustard oil adulteration in virgin coconut oil Vib. Spectrosc. (IF 1.917) Pub Date : 2020-04-25 Amit; Rahul Jamwal; Shivani Kumari; Amit S. Dhaulaniya; Biji Balan; Simon Kelly; Andrew Cannavan; Dileep Kumar Singh
Virgin coconut oil (VCO), being one of the most expensive and healthy edible oil, remains at high risk of adulteration with cheaper oils like mustard oil (MO). Fourier transform infrared (FTIR) spectroscopy fitted with Attenuated total reflection (ATR) accessory was applied in combination with multivariate chemometric modelling for the differentiation and quantification of different concentration of
Low cost Raman sample substrates from conductive silver paint smear for Raman spectroscopic screening of metabolic diseases in whole blood Vib. Spectrosc. (IF 1.917) Pub Date : 2020-03-20 Zephania Birech; Annah M. Ondieki; Robert I.I. Opati; Peter W. Mwangi
This work reports on a low cost, simple to prepare and chemically stable Raman substrates based on conductive silver paint smear. The substrates were characterized Raman spectroscopically and were found to be chemically stable within the first seven days when kept at room temperature as the spectroscopic profiles were unchanged. The substrates also suppressed the background signals emanating from glass
Solvent-induced degradation of polyurethane studied by two-dimensional (2D) infrared (IR) correlationspectroscopy Vib. Spectrosc. (IF 1.917) Pub Date : 2020-03-19 Shogo Yamane; Ryota Watanabe; Seisuke Ata; Junji Mizukado; Hideyuki Shinzawa
Classification of fiber tip pens using Attenuated Total Reflectance (ATR) – Fourier Transform Infrared (FTIR) Spectroscopy in tandem with Chemometrics Vib. Spectrosc. (IF 1.917) Pub Date : 2020-03-13 Praveen Kumar Yadav; Rakesh Mohan Sharma
Fiber-tip pens have become one of the most popular writing instruments, especially for signatures, artworks, and projects. As with any other writing instrument, the forensic significance of fiber-tip pens can't be undermined. They are often encountered in cases of disputed signature, sketches, drawings, architectural projects, technical designs, and multi-colored unlawful posters. In such cases, it
Quantitative analysis of honey adulteration by spectrum analysis combined with several High-level data fusion strategies Vib. Spectrosc. (IF 1.917) Pub Date : 2020-03-12 Yang Li; Yue Huang; Jingjing Xia; Yanmei Xiong; Shungeng Min
Illegal addition of syrup to honey products would rfdeduce the natural nutritional value of honey. It is essential to develop convenient and accurate analytical methods to rapidly monitor products quality. This study investigated the potential usability of combining mid infrared(MIR) and Raman for the quantification of HFGS (high fructose syrup) in bass honey blends. Where in the partial least squares
Surface-enhanced Raman scattering of glyphosate on dispersed silver nanoparticles: a reinterpretation based on model molecules Vib. Spectrosc. (IF 1.917) Pub Date : 2020-03-12 Alessandro Feis; Cristina Gellini; Marilena Ricci; Lorenzo Tognaccini; Maurizio Becucci; Giulietta Smulevich
Glyphosate is a wide spread organophosphate herbicide whose use and associated risks is strongly debated. Many countries are regulating its use in field and it is often found in surface water. Therefore, a simple analytical method, possibly based on portable instruments, would be highly desirable. In case of many other pesticides, surface enhanced Raman scattering (SERS) spectroscopy was shown to be
Application of a data fusion strategy combined with multivariate statistical analysis for quantification of puerarin in Radix puerariae Vib. Spectrosc. (IF 1.917) Pub Date : 2020-03-07 Yaqi Wang; Yuanzhen Yang; Haojie Sun; Junping Dai; Manxi Zhao; Chuanzhen Teng; Zunhong Ke; Ming Yang; Lingyun Zhong; Weifeng Zhu
Motivated by the wide use of Radix puerariae (RP) in the food and pharmaceutical industries, a reliable approach was developed for the quantitative analysis of puerarin from RP. Data fusion strategy based on near infrared (NIR) and ultraviolet (UV) spectra is proposed herein to establish a reliable partial least squares (PLS) regression model for predicting the puerarin content, with critical variables
Infrared Spectroscopy and Multivariate Method to Quantify Methane in Gas Sample Emitted by Cows Vib. Spectrosc. (IF 1.917) Pub Date : 2020-03-06 Rafael Luis Ribessi; Amélie Vanlierde; Jarbas José Rodrigues Rohwedder; Vincent Baeten
The purpose of this work was to develop a new multivariate calibration method using partial least squares (PLS) regression to quantify methane (CH4) in samples of gases eructed by ruminants and exhaled together with the respiration of cows. Four Holstein cows were confined and received a diet of 18.7 kg of dry matter per day for 4 days. During this period, samples of the gas exhaled by these cows were
Formation of Organometallic Xenon Complexes in Conventional Fluids: A Time-resolved Infrared (TRIR) Study of the Photochemistry of W(CO)5(4AcPyr) (4-AcPyr=4-Acetylpyridine) in perfluoromethylcyclohexane (PFMCH) Vib. Spectrosc. (IF 1.917) Pub Date : 2020-03-06 Linjun Wu; Xue Z. Sun; Xue Wu; Michael W. George
The photochemistry and photophysics of W(CO)5(4-Acpy) in perfluoromethylcyclohexane (PFMCH) has been investigated using fast time-resolved infrared spectroscopy (TRIR). Analysis of these TRIR data shows that rradiation (400 nm) of W(CO)5(4-Acpy) in PFMCH results in the formation of a metal-to-ligand charge transfer (MLCT) excited state which decays (τ =330 ns) to reform mainly the parent and a small
Effective Polarization Suppression in Two-Beam 3-color Broadband Coherent Raman Micro-Spectroscopy (3CBCRS) Vib. Spectrosc. (IF 1.917) Pub Date : 2020-03-06 Laszlo Ujj; Trevor Olsson; Benny Schundelmier; Trevor Bestor
We report the extension of our formerly developed two-beam 3-color broadband coherent Raman methodology and the improvement of our tabletop system for fully polarization controlled low-frequency vibrational measurements. Each of the partial signals having different polarization, comprising the scattering could be effectively eliminated at the theoretically predicted polarization analyzer orientations
Comparative Analysis of Dentine and Gingival Fluid Molecular Composition and Protein Conformations during Development of Dentine Caries: A Pilot Study Vib. Spectrosc. (IF 1.917) Pub Date : 2020-03-06 Pavel Seredin; Dmitry Goloshchapov; Yuri Ippolitov; Jitraporn Vongsvivut
Hydroxide-catalyzed cleavage of selective ester bonds in phosphatidylcholine: An FTIR study Vib. Spectrosc. (IF 1.917) Pub Date : 2020-03-06 Vijitha Mohan; Caitlin D. Naske; Collin N. Britten; Leila Karimi; Keisha B. Walters
Thermochemical ester bond cleavage in the phospholipid phosphatidylcholine (PC) was evaluated at reaction temperatures between ca. 20–60 °C using a series of lithium and zinc halides: lithium chloride, lithium bromide, lithium iodide, zinc chloride, zinc bromide, and zinc iodide. Hydroxides, produced via reaction between lithium or zinc halides and potassium hydroxide (KOH), cleaved selective carbonyl
Visualizing different crystalline states during the infrared imaging of calcium phosphates Vib. Spectrosc. (IF 1.917) Pub Date : 2020-02-24 Vuk Uskoković
Methods utilizing relatively simple mathematical operations during physical analyses to enable the visualization of otherwise invisible correlations and effects are of particular appeal to researchers and students in pedagogical settings. At the same time, discerning the amorphous phase from its crystalline counterpart in materials is challenging with the use of vibrational spectroscopy and is nowhere
FT-NIR coupled chemometric methods rapid prediction of K-value in fish Vib. Spectrosc. (IF 1.917) Pub Date : 2020-02-21 Akwasi Akomeah Agyekum; Felix Y.H. Kutsanedzie; Viswadevarayalu Annavaram; Benjamin Kumah Mintah; Emmanuel Kwasi Asare; Bin Wang
A technique for predicting the K-value of fish freshness using Fourier Transform-Near-Infrared (FT-NIR) coupled with chemometric algorithms was developed. FT-NIR spectra of 150 fresh fish were acquired, and their respective K-value estimated using HPLC procedures. Acquired spectra were pretreated using standard normal variate (SNV) to eliminate extraneous information. The developed FT-NIR coupled chemometric
Authentication of Grappa (Italian grape marc spirit) by Mid and Near Infrared spectroscopies coupled with chemometrics Vib. Spectrosc. (IF 1.917) Pub Date : 2020-02-19 Stefano Schiavone; Benedetta Marchionni; Remo Bucci; Federico Marini; Alessandra Biancolillo
The aim of the present study is to authenticate Grappa spirits and to develop a non-destructive methodology which would allow detecting possible adulteration (by less valuable spirits) on this product. Grappa is an Italian alcoholic drink obtained by distillation of grape marks which has recently received the Geographical Indication (GI) label. As a high added-value product, it is relevant to develop
The unintentional excitation of surface phonon polaritons in ATR-FTIR spectra of geological samples Vib. Spectrosc. (IF 1.917) Pub Date : 2020-02-19 Llew Rintoul; Brooke A. Davis; Amir Moghaddam
Anomalous peaks were observed during attempts to measure micro-ATR infrared spectra of small domains (> 30 µm) of the mineral apatite that were associated with coal particles in polished epoxy grain mounts. The peaks were sharp, variable in intensity, and appeared near the high wavenumber edge of the broad ν3 band of the phosphate. Similar effects were observed in single crystals of quartz, garnet
Compressed time-domain coherent Raman spectroscopy with real-time random sampling Vib. Spectrosc. (IF 1.917) Pub Date : 2020-02-19 Shigekazu Takizawa; Kotaro Hiramatsu; Keisuke Goda
We experimentally demonstrate compressed time-domain coherent Raman spectroscopy with real-time random sampling. Specifically, we employ Fourier-transform coherent anti-Stokes Raman scattering as a platform for the spectroscopy and demonstrate reconstruction of Raman spectra from sparsely sampled time-domain interferograms using the iterative shrinkage-thresholding algorithm. We show that Raman spectra
High performance SERS substrates using high surface roughness gold nanosheets assembled by nanowires Vib. Spectrosc. (IF 1.917) Pub Date : 2020-02-18 Dapeng Xu; Zixiong Wang; Song Zhang; Wei Yang; Jian Chen
Chemometry-assisted Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) method for quantification of a novel antipsychotic agent in pharmaceuticals: A case study on ICH Q 14 concept Vib. Spectrosc. (IF 1.917) Pub Date : 2020-02-07 Sagar Suman Panda; Ravi kumar Venkata Varaha Bera; Jnyanaranjan Panda
A robust and reliable diffuse reflectance infrared fourier transform spectroscopy (DRIFTS) method was developed and validated for the quantification of a novel antipsychotic agent pimavanserin tartarate. A holistic novel concept of Analytical Procedure Development (APD) was implemented for establishing the robust nature of the method while aiming to achieve analytical excellence. Experiment room temperature
Diagnosis of hepatitis B based on Raman spectroscopy combined with a multiscale convolutional neural network Vib. Spectrosc. (IF 1.917) Pub Date : 2020-02-05 Hongchun Lu; Shengwei Tian; Long Yu; Xiaoyi Lv; Sihuan Chen
This study presents a method combining serum Raman spectroscopy with a multiscale convolution independent circulation neural network (MSCIR) for hepatitis B virus (HBV) diagnosis. It simplifies the steps of serum Raman spectroscopy data preprocessing and improves the accuracy of hepatitis B diagnosis. Serum samples were obtained from 499 healthy people and 435 HBV patients. First, feature extraction
Interaction of Polyphenols and Ag on the surface plasmon resonance absorption and Resonance Rayleigh scattering spectra Vib. Spectrosc. (IF 1.917) Pub Date : 2020-01-27 Zhe Wang; Qi Wang; Chunxia Liu; Fangyu He; Zhiguo Song; Qiubei Qiu; Jun Yan; Weiwei Zhu
Polyphenols are a kind of vital biologically active substances in fruits and vegetables. In this study, with the reductive ability in the alkaline solution, eight polyphenols[(-)-Epigallocatechin gallate (EGCG), (-)-Epigallocatechin (EGC), (-)-Epicatechin gallate (ECG), (-)-Epicatechin (EC), (-)-Gallocatechin gallate (GCG), (-)-Gallocatechin (GC), (+)-Catechin (C) and Gallic acid (GA) ] could produce
Synthesis, structure, tautomerism, intramolecular hydrogen bond, and vibrational assignment of 3-nitroso-2,4-pentanedione: A theoretical and experimental approach Vib. Spectrosc. (IF 1.917) Pub Date : 2020-01-24 Mansoureh Rakhshanipour; Homa Jalali; Vahidreza Darugar; Hossein Eshghi; Mohammad Vakili
Salient features of branched chain amino acid strain states using confocal Raman spectroscopy with adaptive principal component analysis Vib. Spectrosc. (IF 1.917) Pub Date : 2020-01-24 Abigail H.M. Casey; Carleah Dorsey; Nyia E. Chusan; Caroline A. Campbell; Gregory E. Triplett
In this study, we examined how branched-chain amino acids responded to varying experimental conditions through an adaptive principal component analysis (PCA) method. Three branched chain amino acids were chosen: L-leucine, L-valine and L-isoleucine and, four blends were created with varying ratios in order to analyze the effectiveness of this approach on multicomponent samples. Blended samples were
Vibrational spectra of NCCN, CNCN and CNNC : a study using the U(4) algebraic model Vib. Spectrosc. (IF 1.917) Pub Date : 2020-01-24 Nirmal Kumar Sarkar
A detailed study on the vibrational spectra of cyanogen(NCCN) and its isomers – isocyanogen(CNCN) and di-isocyanogen(CNNC) has been reported in this work using the U(4) algebraic model. With detailed spectral analysis, it has been shown in this study that NCCN, CNCN, CNNC and all their isotopic species can be approximated well using the U(4) algebraic model.
Temperature dependence of Raman scattering in single crystal SnSe Vib. Spectrosc. (IF 1.917) Pub Date : 2020-01-22 Xiangnan Gong; Hong Wu; Dingfeng Yang; Bin Zhang; Kunling Peng; Hanjun Zou; Lijie Guo; Xu Lu; Yisheng Chai; Guoyu Wang; Xiaoyuan Zhou
We report on the temperature-dependence Raman modes of in-plane B3g, Ag2 and out-of-plane Ag1, Ag3 in single crystals of tin selenide that grown by a modified home-made Bridgeman method. The samples are characterized by single crystal X-ray diffraction and high-resolution transmission electron microscopy to confirm their crystal structure. The temperature-dependence of Raman spectroscopy illustrates


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|Stay home - Dream big- Book your next adventure
• Book with only 25% deposit • Flexible refund policy
Discover bottomless Siberian snow powder that blankets the mountains on their isolated slopes. The conditions in the Mamay Valley is perfect, and provides ultimate backcountry experiences. Visit during the winter months between December and March for ideal backcountry skiing conditions.
Mamay Valley is located in the Khamar-Daban mountain range, which stretches across 350 kilometers of the Siberian wilderness in the southeast of Russia. The valley runs very close to one of the natural jewels of Siberia, the UNESCO-listed Baikal Lake, the largest freshwater lake by volume in the world, as well as the deepest. In the depths of winter the area is prime ski terrain that is very isolated.
The region receives a very cold climate with low temperatures and bounties of snow. Yet is much milder than the rest of Siberia.
Russian ruble.
Visit during the winter months between December and March for ideal backcountry skiing conditions.
Stay up-to-date on the best adventures!


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397 Judson Ave, Mystic, CT 06355
Well-maintained home located in a neighborhood setting within walking distance of downtown Mystic. The large family room addition located off the back of the house is great for entertaining guests or enjoying a quiet movie night at home. Cozy up by the fireplace in the living room and enjoy mornings at the breakfast bar in the kitchen. Ceiling fans are located throughout the home to keep cool during those hot summer days along with a wood stove in the family room for extra warmth during the winter. This home sits on almost a half-acre of land with privacy fencing and mature trees located along the border of the property. Relax in the private, open space backyard or test your green thumb in the gorgeous garden. With 3 bedrooms and 2 full baths, you'll have all the space you need in this beautiful Colonial home! Owner Related to agent


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Shanghai Shenhua has placed a £15million price tag on Odion Ighalo, the UK Mirror reports.
Ighalo is currently on a six-month loan deal at Manchester United.
The Nigerian striker has impressed United manager Ole Gunnar Solskjaer since his arrival.
In eight appearances, Ighalo has netted four goals for the Red Devils.[adrotate banner="11"]
It has led to suggestions that the 30-year-old could be signed to a permanent deal at Old Trafford.
Ighalo cost Shanghai Shenhua €15million (approximately £13.6 million), when he was bought from Changchun Yatai.
He became the most expensive Nigerian player, when he was sold by Watford to Changchun Yatai for a fee in the region of £21million in January 2017.
That record was first broken by Leicester City's Kelechi Iheanacho, then Everton's Alex Iwobi.[adrotate banner="8"]


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Vezi cum e vremea inainte sa iti faci planuri !
Peste 4000 iconite in ORICE culoare, ORICE dimensiune si in 5 formate: iconsDB.com
E de bineThe new standard brings a number of benefits to one of the Web's core technologies, such as faster page loads, longer-lived connections, more items arriving sooner and server push.
Why is HTTP/2 multiplexed?
HTTP/1.x has a problem called "head-of-line blocking," where effectively only one request can be outstanding on a connection at a time.
HTTP/1.1 tried to fix this with pipelining, but it didn't completely address the problem (a large or slow response can still block others behind it). Additionally, pipelining has been found very difficult to deploy, because many intermediaries and servers don't process it correctly.
This forces clients to use a number of heuristics (often guessing) to determine what requests to put on which connection to the origin when; since it's common for a page to load 10 times (or more) the number of available connections, this can severely impact performance, often resulting in a "waterfall" of blocked requests.
Multiplexing addresses these problems by allowing multiple request and response messages to be in flight at the same time; it's even possible to intermingle parts of one message with another on the wire.
This, in turn, allows a client to use just one connection per origin to load a page.
Asta e una dintre imbunatatirile majore care vin la pachet cu HTTP 2
Vezi cum e vremea inainte sa iti faci planuri !
Peste 4000 iconite in ORICE culoare, ORICE dimensiune si in 5 formate: iconsDB.com
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Home & DIY
These Pieces of Furniture Serve Multiple Purposes, and they're Simply Exquisite!
Save space and money with these clever multi-purpose furniture ideas.
An ottoman that can be dismantled and turned into a complete set of table and chairs; a simple, wooden chair that can be transformed into a kitchen ladder; an entire wall that can hide your queen-sized bed—these are some ingenious ideas that can help maximize the space in your home.
Most people who live in small houses often wish to make the most out of the spaces in their homes. So, why not build these pieces of multi-purpose furniture that can help save room and money instead?
In the video posted by Marvin Coronel, you'll see several clever design ideas that are suitable for people who would love to have just that. Pushing, pulling, and lifting these pieces of furniture may be a little trying for some, but it's truly rewarding.
Watch the video and tell us what you think.
H/T: Marvin Coronel via Facebook, CHPC New York City, Clei Resource Furniture
Home & DIY
Single Dad Teaches Fellow Fathers Proper Hair Care Tricks For Their Daughters
Although most dads are clueless when it comes to hair care, this guy is an exception.
One of the perks of having a little boy as our child is that its really easy to prepare him when we need to go somewhere.
I'm often home alone with him while my wife is in the school and so when I need to purchase something at the store or pay some bills, I'd simply dress our 3-year-old toddler with a shirt and a pair of pants. Occasionally, I'd make him wear his favorite cap or a beanie and off we go.
The same, of course, couldn't be said if your child is a girl because, you know, prepping a girl's hair requires time and extraordinary skill.
Home & DIY
Man Builds Monumental 3-Storey Treehouse for Grandkids
This granddad is The Man.
This granddad is The Man.
As a kid growing up, didn't you always want to have a treehouse in the backyard?
Lucky for two young children living in Attleboro, Massachusetts, their handyman grandfather decided his grandkids wouldn't grow up with their faces glued to electronic devices. So he decided to bring them the joy of the great outdoors by building six-year-old Jacob and four-year-old Kayla a three-storey 40-foot-tall treehouse!
Cool Pizza Necklace Allows You To Bring A Slice Wherever You Go
It's a "bold and delicious" fashion statement.
Whether you love it as a thin crust or thick crust, there's no denying that pizza is absolutely everyone's favorite.
Originally invented by the Italians, this heavenly food is made of flour and different toppings. Throughout the years, different flavors have been introduced to the pizza-consuming public. Classics such as Pepperoni and Cheese, Mexican Red Wave, Golden Chicken Delight, the Pizza Margherita, are among some of the most popular pizza flavors. There's definitely something for everyone whether you are a meat-lover or a vegetarian.
Pizza is so good the only tragedy is that you can't always have it accessible when you are on the go. But oh well, now it seems you actually can.
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prompt , knowledgeable
Antonio 830a DO NOT DROP Kitchen Suppression Inspection Semiannual Kitchen Inspection Equip Desc: (1) Ansul R-102 6G, () , () Kitchen System(s) Deficiency for Ansul R-102 6G: Same deficiency's remain from last inspection: TERMINAL LINK ABOVE PIZZA OVEN NEEDS TO BE RELOCATED UNDER FRYER **no filters covering v-style pizza oven hood, could result in a accidental discharge**
CURTIS 10-1030A 443-623-7884 cell Kitchen Suppression Inspection Semi-Annual Kitchen Inspection Equip Desc: Inspect (4) 6 Gal. Ansul Systems Inoperable Deficiency for Ansul R102 Wells 6 gallon: Same deficiency's remain: concession stand 1,2,3,4(all systems are the exact same) ansul 6gal WELLS ventless hood (1.5galx4) -appliances need to be interlocked to system, when hood is off appliance should not be able to turn on -no electric shutdown to fryer or grill -no alarm bell -paper filters need replaced and metal ones need cleaned due to heavy grease build up ***liability disclaimer form added*** concession stand 4 -thermal detectors must have short in wiring, when interlocked is plugged in system trips, as of now only way to activate system in the event of fire in with the remote pull -filters also need changed on it, filter and service light are on
03/03 CHEF JOHNATHAN 10-1030A Kitchen Suppression Inspection Ansul R-102 3-gallon: Semi-Annual Kitchen Inspection Equip. Desc.: ANSUL 3-gallon and (1) Ansul 6 Gallon Deficiency for Ansul R102 66gallon Front hood: Salamander was added to equipment line-up and needs protection. **Repipe drops for proper coverage** System has 19 flows already


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Rideau Canal Skating, 6:30-8:30 (timing is subject to weather. Pickup time may be earlier)
DRESS: Civilian, appropriate for outdoor skating. MUST have Gloves, Toque and Winter Coat regardless of weather.
Cadets will be skating on Dow's Lake for the evening. Cadets are responsible for their own transportation and renting skates if necessary. A Beaver Tail and hot chocolate will be provided to the cadets part way through the evening.
Cadets are required to sign-in and sign-out. Sign-in will be located in front of the Dow's Lake Pavillion.
ALL CADETS ARE WELCOME TO ATTEND - This is considered part of our regular training and therefore if you are unable to attend, please report an absence via the website.
Please see the weekly messages at email@example.com for information
Upcoming Events (See Calendar for details):
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Hello people,
So, I remember watching Sex and The City movie for the first time. Around the ending, Samantha is lying on the beach and she has a copy of a book. There seems to a moment of disagreement and Samantha throws the book behind her. A year later, a friend of mine suggested me a documentary. It was The Secret. I watched it and everything inside me changed. Then I watched the movie again yesterday and my exact reaction for the same scene was," stupid move, Samantha! A real. stupid. move."
You see something changed the day I woke up after watching that documentary. I wanted to be a fashion stylist at that time. To start my career I needed to have a portfolio, so that I can get an internship and for days I procrastinated thinking "one day I'm gonna start making it. One day it'll be ready, I'll send it to the best stylist and she's gonna hire me as her intern."
That day, I woke up and I decided what if I did something that day. I decided that I'll hit the stores and borrow some clothes and do the photoshoot. Me and my friends, we entered the mall and I started asking around while they waited outside the stores. I felt little. The same guys who'd smile looking at me on any other day were giving me shit about it not being possible. I kept positive and did my affirmation and visualization and I entered Levi's. I said "I want to make a portfolio I'm gonna need some clothes of my choice and I'll pay for security…Blah blah blah" and the answer was…No! I saw someone coming out of the trial room while exiting and started walking. Few moments later, the same guy comes from behind, nudges me and asks me what I really need. I repeat everything and he says," okay, I'm the manager of the store and I can arrange that". After that woodland agreed and so did Being Human.
This was my first ever positive experience out of that book. Now I know that it's not really a quick process but who has the masters in universe studies though? 6 months later after that, during a morning run I injured both of my knees. One of my acquaintances who was into sports in the engineering college had recently injured his ACL while playing cricket and had to go through an ACL reconstruction surgery. Though my symptoms didn't match to an ACL injury I didn't go to the hospital for months. I couldn't run walk or sit, hell I couldn't even stand for more than 5 minutes. With lot of courage, I decided to get it diagnosed and turned out it can be treated. Doctor said it's nothing major but I experienced no improvements.
That's when among the many books at my Aunt's place I stumbled upon "You Can Heal Your Life" by Louis L. Hay which basically used The Secret to heal the problems of life. Turned out I'm not flexible enough when it comes to my thoughts and actions and that why my body had gone stiff and that's why I have knee pain. I did the affirmations and the healing that didn't come for a year came in just 2 months. Today, I jump, run and sprint without that voice in my head saying "you'll hurt yourself"
See we all have our rock bottoms. People say nothing can be worse than not having friends, being broke, being single, being homeless but imagine not having your body with you. Imagine waking up to dreams and goals but also waking upto a defective body. I really hope this was helpful for you people and I hope you all have amazing experiences out of these two books.


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GPS Global Party Square
with Ox Mighty
Scheduled on
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|6:00 pm
|4:00 pm
|6:00 pm
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Showcasing adult contemporary global beats w/ today's hottest soca-club, mixes, tropical beats, dancehall, hits; plus regular rotation. (Format-Specialty)
Sundays 4pm to 6pm!
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Ox Mighty is a Global DJ who can easily blend Soca, Dancehall, Hip-Hop, EDM and any other musical genre into one global square. He has conquered the Boston's local Soca music circuit with mastery unmatched in the world of professional disc jockeys. Follow Ox Mighty!
GPS Global Party Square events
ALICIA The World Tour AT ROCKLAND TRUST BANK PAVILION Tuesday, August 11, 2020 at 6:30 pm ALICIA The World Tour At Rockland Trust Bank Pavilion Boston, MA


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Best Box Mattress 2020
Not interested in haggling with a salesperson or lying on a floor model? We've rounded up the top online mattress options you can buy from the comfort of your home. . According to the Sleep Council, you should change your mattress every seven years, or when you start waking up with stiffness or aches and pains. Other tell-tale signs include not sleeping as well as .
Weve tried, tested and scored the best mattresses around from the likes of Emma, Simba, Eve (and more!), so you can rest assured youve got the best one for you . Just about all of our WIRED Recommended bed-in-a-box mattresses are on sale for the holiday weekend. On top of everything else you might be dealing with during the pandemic, if your sleep is disrupted .
The holiday weekend is winding down, but you still have a chance to score big on Memorial Day deals. This list has everything you need to know in order to save a few dollars on laptops, kitchen . With all the time we have been spending at home recently, this Memorial Day weekend is a great time to treat yourself to a new mattress (and improve your sleep health). Memorial D .
Best Box Mattress 2020 : Memorial Day is undoubtedly one of the biggest shopping days of the year. Whether you've been eyeing a new refrigerator or you're in the market for a high-tech laptop, web-wide sales are available on . Whether you're starting from scratch or upgrading your bed, right now is the best time of year to buy a mattress. .
Whether you're starting from scratch or upgrading your bed, right now is the best time of year to buy a mattress. . If you need something bigger, you can use the code STRAT250 to get $250 off king and California-king sizes. Avocado, which we've dubbed the best ecoconscious mattress because of its use of organic and .


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Kolo Toure has urged the organisers of the African Cup of Nations to consider radically changing the tournament to avoid clashing with Europe's major domestic leagues.
The 2010 tournament is poised to begin in Angola and Ivory Coast international Toure has admitted the January timing is far from ideal.
Toure has regularly missed periods of the Premier League season while competing in the biennial competition for former club Arsenal.
New club Manchester City recently appointed a new manager in Roberto Mancini and have vital league games plus a Carling Cup semi-final meeting with Manchester United on the horizon which Toure will miss.
"It is very difficult to leave your team for a month to play in the African Nations," he said.
"But you are playing for your country, for your father, for your family, for your pride.
"If something can happen and something can move, it would be really fantastic for us.
"We are caught between two really important things in our lives but we have to go there and play for our pride.
"You have a great job with your club and start something. You just want to keep this focus but then you have to go to play for your country. It is not easy for us."


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- 2nd Half
- Haokip85'
- NiliSingh81'
- DrakpaGurung80'
- Nili79'
- BrownAugustine69'
- Haokip67'
- ThinleyRaj65'
- Brown64'
- SinghMorajkar62'
- Zangpo56'
- Nili55'
- Brown54'
- 1st Half
- Singh45'
- NamgyelZangpo29'
- Brown29'
- Haokip26'
- Gyeltshen16'
- González14'
- Haokip6'
Bengaluru FC - Paro FC
AFC Cup - 12 February 2020
AFC Cup – Follow the Football match between Bengaluru FC and Paro FC live with Eurosport. The match starts at 14:00 on 12 February 2020. Our live coverage lets you follow all the key moments as they happen.
Have your say by voting on who will win between Bengaluru FC and Paro FC? Enjoy some pre-match reading with related articles about these two Enjoy some pre-match reading with related articles about these two Football teams.
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