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Weekly Bulletin – February 24, 2019
President's Day Holiday Schedule
Monday Holiday – Presidents' Day
St. Francis Church will observe
Presidents' Day on Monday, February 18.
One Mass will be celebrated at 11:30 AM.
There will be no confessions, and the church offices, switchboard and St. Francis Adult Education Center will be closed for the day.
Gaudete et Exsultate: Apostolic Exhortation of Pope Francis
Chapter 3: In the Light of the Master
"Blessed are the pure of heart, for they shall see God."
This beatitude speaks of those whose hearts are simple, pure, and undefiled, for a heart capable of love admits nothing that might harm, weaken or endanger that love. The Bible uses the heart to describe our real intentions, the things we truly seek and desire, apart from all appearances. "Man sees the appearances but the Lord looks into the heart." God wants to speak to our hearts; there he desires to write his law. In a word, he wants to give us a new heart.
Certainly, there can be no love without works of love, but this beatitude reminds us that the Lord expects a commitment to our brothers and sisters that comes from the heart. For "if I give away all I have, and if I deliver my body to be burned, but have no love, I gain nothing."
A heart that loves God and neighbor genuinely and not merely in words, is a pure heart, it can see God…Keeping a heart free of all that tarnishes love: That is holiness.
The Pastor's Corner – February 17, 2019
Today's Gospel from St. Luke is his version of the Sermon on the Mount although Jesus delivers this from "level ground." It is shorter than Matthew's version and ends with a series of "Woes." The first part addresses those who are open to God because they do not find fulfillment now, but are dealing with life's imperfections. These are those whose "souls are restless." They recognize the importance of God in their lives. The "woes" are directed to those who are smug and have little need for God. These "Sermons" from Luke and Matthew are at the core of Jesus' teaching and are at the heart of our lives. Compare this Gospel with the one from Matthew. See the Book Review below.
There are two Pilgrimages being advertised here at St. Francis. The first is this November and it will take pilgrims to the Shrines of France. We begin the pilgrimage in Geneva, Switzerland and then move into France, stopping at the famous Basilica of the Visitation in Annecy and the Basilica of Notre Dame de Fourviere in Lyon, and on to chateaux country with the Cathedral of Chartres and the monastery at Mont St. Michel. We will visit St. Thérèse's home of Lisieux and end up in Paris. Sign up now. Pilgrimage Information and registration forms are available at the reception desk or you may email me at firstname.lastname@example.com.
Next week, I will give information on our 2020 Pilgrimage to the famous Passion Play in the German town of Oberammergau performed every ten years since the 1600's.
-Fr. Andrew Reitz, O.F.M.
Weekly Bulletin – February 17, 2019
Click here for the weekly bulletin for
Sunday, February 17, 2019
Bereavement Ministry Support Group – New Series
While grief is a very private experience, those who have lost loved ones can benefit from the witness and support of others who have lost someone special in their lives.
The St. Francis Bereavement Ministry offers an opportunity for the bereaved to connect with others who grieve, and to seek a path of healing as they come to terms with their loss.
A Bereavement Support Group will meet on eight Tuesdays from:
February 12 to April 2,
from 6:00 to 7:30 PM.
Please call Fr. Brian Smail, O.F.M. at 212-736-8500, Ext. 204 to inquire. Interested persons should be at least six months into the grieving process.
Pre-registration is required.
Mass of the Anoint of the Sick
In anticipation of the Feast of our Lady of Lourdes (February 11th) we will be celebrating special Mass of the Anointing of the Sick on Saturday, February 9th at 11:00 AM
The Sacrament of the Anointing of the Sick brings the presence and healing power of Christ to those who are ill. We invite all who are sick and those who would like to pray for them to come to this celebration.
Is anyone among you sick? They should summon the elders of the church, and they should pray over them and anoint them with oil in the name of the Lord, and the prayer of faith will save the sick, and the Lord will raise them up. If they have committed any sins, they will be forgiven. Therefore, confess your sins to one another and pray for one another, that you may be healed. (James 5:14-16)
Gaudete et Exsultate: Apostolic Exhortation of Pope Francis
Chapter 3: In the Light of the Master
"Blessed are the merciful, for they will receive mercy."
Mercy has two aspects. It involves giving, helping and serving others, but it also includes forgiveness and understanding. Matthew sums it up in one golden rule: "In everything, do to
others as you would have them do to you." Giving and forgiving means reproducing in our lives some small measure of God's perfection, which gives and forgives superabundantly.
In the Gospel of Luke, we hear the words, "Be merciful even as your Father is merciful. Judge not, and you will not be judged; condemn not so you will not be condemned; forgive and you
will be forgiven; give and it will be given to you… The measure you give will be the measure you get back."
Seeing and acting with mercy: That is holiness.
The Pastor's Corner – February 10, 2019
I wish to share with you some excerpts from a recent letter by Cardinal Dolan on the New York State abortion legislation:
"This chilling law, if you have not heard, insists on the right to an abortion up to the moment of birth; drops all charges against an abortionist who allows an aborted baby, who somehow survived the scissors, scalpel, saline, and dismemberment, to die; mandates that, to make an abortion more convenient and easy, a physician need not perform it; and could be used to suppress the conscience rights of healthcare professionals not to assist in the grisly procedure. All this in a state which already had the most permissive abortion climate, and one of the highest rates of abortion, in the nation…
In the 'throw-away' culture that Pope Francis so often decries, we saw actual celebrations at the passage of a bill that makes it even easier to dispose of a life that someone might find inconvenient or troublesome, for any reason at all. Those who told us that abortion had to remain safe, legal, and rare, now have made it dangerous, imposed, and frequent…
I'm a pastor, not a politician, and as a pastor, I am obliged to challenge our political leaders, to urge them to re-examine their priorities, and to respect and protect the unborn baby in the womb as strongly and passionately as we should the undocumented immigrant, the single mom worrying how she will feed her family, our dying grandparents, or the poor struggling to make it."
-Fr. Andrew Reitz, O.F.M.
Recent News & Events
Fr. Timothy Shreenan's Homily - July 5, 2020 July 9,2020
Celebrating the Blessed Mother July 9,2020
St. Francis of Assisi is Coming Back! June 9,2020
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Magazine article Screen International
Odin's Eye Takes Worldwide Rights to Horror-Comedy 'DeadTectives' (Exclusive)
Article excerpt
Sales will begin at the American Film Market.
Odin's Eye Entertainment have acquired worldwide rights to upcoming horror-comedy feature DeadTectives.
Sales for the movie will begin at the American Film Market, which begins next week, with a trailer and scenes to be shown to distributors.
DeadTectives follows a team of hapless paranormal detectives on a reality TV series, who go on a quest to a haunted house in Mexico in order to get better ratings.
However, the house they find turns out to actually be haunted, and with no ghost-hunting skills they must find a way to escape with their lives.
The movie stars Chris Geere (Trollied, Waterloo Road) and Mexican actress Martha Higareda (Fuera del Cielo), and is helmed by first-time feature director Tony West (writer of The Soup). …

subset: commoncrawl


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It's been a while since we've heard anything about Netflix's upcoming series, Cursed. Based on the book by Frank Miller and Tom Wheeler, Cursed stars Katherine Langford as Nimue. The series is a re-telling of the classic Arthurian legend, told through Nimue's eyes.
In Cursed, Vikings and Westworld's Gustaf Skarsgard plays Merlin. In a recent Instagram post, the Skarsgard brother posted a look of his character.
Skarsgard also revealed that Cursed will premiere this summer. Are you looking forward to Cursed?
Make sure to check out our podcasts each week including Geek Vibes Live, Top 10 with Tia, Wrestling Geeks Alliance and more!
A girl with too many fandoms to count.


text: Cruise ships to be used as hospitals for non-Covid-19 Posted by Elise Kirsten on 26 March 2020 Carnival Corporation, a US-based company which owns several cruise lines, has said that it will make its ships available to hospital patients who test negative for the coronavirus. The offer, extended to various governments and medical facilities, will help free up hospital beds on land for the treatment of Covid-19 patients. Along with @CarnivalPLC below is our latest announcement on how we are extending help to governments & health authorities during this time. @HALcruises @PrincessCruises @pandocruises pic.twitter.com/fuoFRgDEY3 — Carnival Cruise Line (@CarnivalCruise) March 19, 2020 'With the continued spread of Covid-19 expected to exert added pressure on land-based health care facilities, including a possible shortage of hospital beds, Carnival Corporation and its brands are calling on governments and health authorities to consider using cruise ships as temporary health care facilities to treat non-Covid-19 patients, freeing up additional space and expanding capacity in land-based hospitals to treat cases of Covid-19,' the company stated. 'As part of the offer, interested parties will be asked to cover only the essential costs of the ship's operations while in port.' The company says that its ships can quickly be converted to serve as hospitals with up to 1,000 rooms and that these rooms can have remote patient-monitoring devices installed with 'cardiac, respiratory, oxygen saturation and video-monitoring capabilities,' the statement said. 'The rooms also have bathroom facilities, private balconies with access to sun and fresh air, as well as isolation capabilities, as needed. 'Additionally, cruise ships being used as temporary hospital facilities to treat non-Covid-19 patients would have the ability to provide up to seven intensive care units in the ship's medical centre, equipped with central cardiac monitoring, ventilators and other key medical devices and capabilities. 'Similar to land-based health facilities, cruise ships can also house multiple medical functions in disparate locations by using different decks on the ship to separate each required medical area.' According to Times Live, South Africa's health department has not yet responded as to whether it would consider this offer. Image credit: Carnival Corporation Related Posts Go Danish-style luxury camping in Japan 14 August 2020 A Japanese camping ground has taken the idea Hygge and turned it into a luxury... read more UK hosts first socially distanced music festival 14 August 2020 The UK has begun to reopen their entertainment industry, which has taken a knock amid... read more Special sighting of humpback whale calves in PE 14 August 2020 Photographer Stuart Gillmer captured an incredible sighting in Port Elizabeth of two separate mother humpback... read more PREV ARTICLE NEXT ARTICLE


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But even an insatiable appetite and overwhelming tiredness are no match for the sudden arrival or breakdown of pure romantic love, or unbridled sexual lust. These are, after all, the states of mind that inspired every one of our direct ancestors to relentlessly pursue love and sex until they succeeded at least once in getting their genes into a new generation. The advent of online dating, then, must have seemed like an incredible idea. Whereas in the past the pool of single men a woman could potentially meet and attract was limited by who she happened to physically be around during daily life, now it was exponentially larger. Now the number of men she could date was limited only by how far she would eventually be willing to travel to spend time with them in person. However, things turned out to be more complicated than that. Just as freshly-online businesses, expecting to amass untold fortunes in a new, global market, found themselves in competition with internet businesses that they would never have otherwise had to compete with, so too did online daters face the prospect of having to stand out as special and attractive amongst a much larger pool of singletons than they were used to. Every man and woman online still has criteria that must be met by people who want to date him or her, and every guy and girl is still in direct competition with every other person of their gender. In that case, then, is the acquisition of love and sex online just as easy or difficult for men and woman as it is offline?
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Jen Johnson Real or Fake? Dr Phil tried to determine whether Jen Johnson was a real person. He offered to send her Marine boyfriend Craig and a camera crew to meet her in person. Dr Phil had an update about Jen Johnson, the online girlfriend who was supposed to meet her Marine boyfriend for the first time, and Internet dating advice. It is fascinating to watch Dr Phil play chicken with a possible Internet con artist. Online Dating Imposter I would say that the best thing she has going for her is she is obviously from the United States, where it is harder to get away with scamming people in this manner.
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Bowling Green State University professors of gerontology, Dr. Charlie Stelle, have been researching the landscape and found that people over 60 represent the most rapidly growing demographic in online dating. The study authors also delved into the question of which features make a dating site a good fit for seniors. You can read an article about the ongoing study by clicking here.
Creating 38 "undateable" profiles as an interactive scientific investigation into online dating, Robyn unwittingly sets in motion the social experiment of our generation.
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A Dad Dating Simulator now have a whole new way to experience the Dream Daddy universe as Oni Press is publishing a series of comic books based on the sim. From developer Game Grumps, Dream Daddy has players assume the role of a single dad who has moved to the town of Maple Bay with his daughter. He then meets and romances a number of other single dads in the town.
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Season 16 11 full episodes Episode 11 – Dog Bites Bear 2 weeks ago Milestone th episodeStewie and Brian get into a friendship-ending fight after Brian commits a terrible act to one of Stewie's beloved toys. Meanwhile, Peter refuses to wash his hand after meeting his favorite breakfast cereal mascot, Boo Berry. Smitten with her, he enters a show dog competition, in which the winner gets to breed with her. Meanwhile, Peter and Lois go to extreme measures to try to convince Chris that "Arthur Valentine" doesn't exist.
Episode 9 – Don't Be a Dickens at Christmas 2 months ago In this special holiday episode, a selfish Peter loses his Christmas spirit and is visited by ghosts of Christmas past, present and future who take him on a journey around Quahog in the style of Charles Dickens' "A Christmas Carol". Episode 8 – Crimes and Meg's Demeanor 2 months ago Peter encourages Meg to attend a high school party, where she takes up drinking, which both concerns and delights her father.
Meanwhile, Brian begins spying on his neighbors and suspects Principal Shepherd of a crime. Episode 7 – Petey IV 2 months ago On Thanksgiving weekend, Peter discovers an alternate ending in the Russian version of one of his favorite films and writes to Vladimir Putin, who comes to Quahog. Meanwhile, a strapped-for-cash Brian gets a job at a suicide hotline center and attempts to strike up a romance with a co-worker.
Episode 6 – The D in Apartment 23 3 months ago When Brian posts an offensive tweet that goes viral and the rest of the Griffins are also treated as outcasts, he's forced to move out of the Griffin house. Episode 5 – Three Directors 3 months ago In a special anthology-style episode, Peter gets fired from his job at the brewery in the signature styles of three famous Hollywood film directors.
Episode 4 – Follow the Money 3 months ago After Chris gets a special one-dollar bill for his birthday and quickly loses it, the dollar gets passed from character to character throughout Quahog. Episode 3 – Nanny Goats 4 months ago The Griffins get a nanny for the kids; Peter and Lois get an opportunity to reconnect. Episode 2 – Foxx in the Men House 4 months ago Peter becomes friends with a cool, handsome paramedic named Stryker Foxx.
If you date online, take precautions to protect yourself. Here are six things to keep in mind to help you spot and avoid scammers on online dating sites. If you fall into this category, be especially wary of people that you meet through dating websites. The AARP also says that seniors are a common target of these scams.
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Explainer Culture How to supercharge your online dating Dating services gather tons of data about their users, so we asked: What's the best way to get a date? Here's what they said. Here's why you can't get a date online 2: There's a guy in a banana suit holding a startlingly obese cat. He's looking for love. And he's on Tinder. Swipe left and find a guy holding a dead deer by the antlers.
Perhaps you'll be entranced by the creature's lifeless eyes. There's something that banana man, Bambi-killer and the Jeep fan have in common: They're all hoping you see something in their photos that pulls you in, that you'll want to find out what's beneath the banana suit, if you will. But it's not going to work.
Blond Powers Brian is superhumanly strong, able to lift 90 tons, and possesses enhanced reflexes, stamina and senses sufficient to pierce holograms, but not on a par with Wolverine. He can also fly up to mph for prolonged periods. He derives his energies from the friction between dimensions, focused in a matrix centered on the U.
Not a Match: My True Tales of Online Dating Disasters is about one guy who experienced more than his fair share. Brian Donovan, a writer and comedian whose work has appeared on Late Night with Jimmy Fallon, NPR, and Chapelle's Show, has been on over Internet dates in a /5(6).
The Road To Reality A strange name, an unmistakable voice, and an explosive and energetic on-screen personality have created a dramatic fan following as the "Pig Man" burst onto the scene with a self-confidence capable of revolutionizing outdoor television programming as we know it. In the midst of his adolescence, non-indigenous pigs were quickly becoming a problem in Central Texas. Locals in the Mexia area distinctly recall the Brian Quaca they knew as a willing and able teen motivated to self-eradicating their oversize pest problem even from a young age.
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As he quickly approached a total rebuild count of guns, his clients were captivated by the high-energy hunts he engaged himself in. Guiding his clients in Texas on these monster hogs he spoke of, they witnessed first-hand the intensity Quaca possessed during his missions to capture or kill pigs at all costs including his own personal injury. It was a man willing to persevere as if each client would make or break him.
His days as a part-time used car salesman and part-time riflesmith were quickly drawing to an end.
Prosecutors say in April, Tekashi waited in a car outside an NYC office building and recorded while his manager and other associates robbed some of Tekashi's rivals. The incident where shots were fired at Barclays Center is also detailed Finally, the docs describe an incident in July where Tekashi allegedly ordered a hit on a rival There's also a photo of the gun recovered at Tekashi's Brooklyn home back in September by the feds, an AR style rifle.
Tekashi will be back in court Tuesday to ask a judge for bail.
Apr 14, · 17 Forgotten Dating Shows. BY Roger Cormier. April 14, It has now been 20 years since the premiere of Singled Out, MTV's popular dating show featuring Chris Hardwick and Jenny McCarthy (then.
First impressions are everything so make sure you nail your online dating message. Your mother always told you so and you never really believed it too much, but the fact is that first impressions really count. Online dating gives you a bit of an advantage in that you can strategically plan that first message so it hits home with a bit of a punch. Unlike an everyday face to face meeting where the words just tumble from your mouth in no apparent order.
So why is it that so many guys and girls yes girls too fail miserably in avoiding the move from the Inbox to the trash can? Extensive research into online dating statistics show that there are some set rules that we all need to follow. Tone down the Netspeak Netspeak is the main culprit when it comes to unsuccessful first mails. The words if you can call them that ur, r, u, ya, cant, hit, realy, luv,and wat, are the top nine worst words to use in an opening message. Mails that contain these words will get practically no replies proving that intelligence or maybe just good grammar is an attractive trait in both sexes.
Surprisingly, though, ha ha and lol were considered ok to use.
These guys are all smart and really funny! But as far as dating profiles go…. A mix of seriousness added in would make these profiles perfect! Very youthful profiles because, well, these men are young. These guys have revealed very little about who they are, in a sense. I bet they would be worth meeting!
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Here is a list of the 10 best Chinese dating websites for foreigners. Signing up is free and you can create your own account and browse thousands of profiles immediately with just easy steps. They have two levels of membership, Free and paid memberships. You can contact as many members as you want. It is a challenge to understand Chinese language, but no worry, many members on the site know some English and besides the site offers automatic translation service, which is usually not provided by other dating sites.
Their service is really the best of all Chinese dating sites. This dating site is the best one to look for a friend, love or even marriage with Chinese girls. I recommend it heartily and have it highly rated in our ranking, click the button below to check it for yourself… 2. You have enough dating options on Asiandating.
Blind Date This is a very funny show with pop-up captions with funny facts while we watch a couple on a blind date. If that person deems them inappropriate, they simply shout 'Next' to get a chance with the next potential suiter. There is a lot of drama and intensity, making this great tv. For the Love of Ray J 7 points – added 9 years ago by carmen – Who Wants to Marry a Multi-Millionaire 5 points – added 9 years ago by carmen –
Online dating should be simple. FirstMet is one of the largest online dating sites with over 30 million people looking to chat, flirt, and date. You can sign up with Facebook, making it quick and easy to create rich, authentic online profiles, so you can begin meeting men or women near you immediately.
So, lets look at a few typical examples of bad profiles: I like sports and good wine. I am looking to a meet an intelligent, beautiful woman for dating and relationship. However, it has one major flaw that will make many women skip over it. It looks just like a thousand of other profiles. Lets look at another bad profile: I love hiking, watching baseball, and bbq on weekends. Again, this profile has a very weak beginning….
Now, lets look at an example of a profile that will stand out through both the way they are written and their content.


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Dimesio.S Of Queen Purple Mattress
Approaching 2019, the market for mattresses are bombarded with many different businesses. Dimesio.S Of Queen Purple Mattress
The post below has the best 8 mattresses of 2018. They are detailed in no particular order.
If you get on the hunt for the best mattress, then you can not fail if you choose one of the mattresses below.
Puffy Mattress
- Many individuals claimthat Puffy Mattress is undoubtedly, among the most comfy mattresses out there.
- They say that's is similar to sleeping on a cloud. Additionally, clients who suffer from back pain assert to sense alleviation with Puffy's Adaptive Flexible Cloud Technology. One of the things that make Puffy mattress stand out, is that you don't only get a 101 night sleep trial. But also a lifetime warranty.
- For the money, this is among the best mattresses available. Very large quality mattress. Puffy is made-to-order so it will take two days until it's sent to you.
- Puffy's top layer is a Cooling Cloud Stress Relief Foam; CertiPUR-US Accredited . That is what is accountable for creating you feel as if you're sleeping on a cloud. The bottom layer of Puffy is made of Firm Core Support Foam, which can be CertiPUR-US certified.
Dreamcloud Mattress
- Dreamcloud is an outstanding mattress option. With a superior natural latex coat, DreamCloud supplies a good bounce, and extra contour.
- A number of DreamCloud's finest features are it's cashmere and flax yarn blend; along side it's stitched handles. With a cost of $1199 for a Queen, you can't fail.
- A luxury hybrid that provides a full 365 night sleep trial, versus the Normal 100 night trial. New pocket coil technology allows the manufacturing price to be more economical, as well as the savings are passed directly to the client.
Layla Mattress
- The double-sided Layla mattress which allows sleepers to select between different firmness levels, depending on which side they decide to confront up. The sensation of the product is different than any other you have really felt. Moreover, it allows you to keep cool, and spring back tremendously rapidly. Dimesio.S Of Queen Purple Mattress
- The cozy layer for the milder side of this mattress consists of 3 inches of aluminum infused memory foam (3.5 pound density). This is a fairly thick layer of memory foam, and it is a gentle fabric which will allow the sleeper to sink for pressure relief.
- Layla provides a four month sleep trial period, together with a lifetime guarantee. Most manufacturers just have a 10 year guarantee. So, this is not merely a huge selling point for Layla, it also speaks for their quality.
Nest Bedding Mattress
- The top rated and best rated mattress brand on the internet, is Nest Bedding. Sporting a lifetime guarantee, together with a lifetime comfort guarantee, they place emphasis on wanting their clients to be fulfilled.
- With Nest Bedding, their models can all be seen with different firmness options. Together with the lineup consisting of two memory foam beds, 1 3 and latex hybrids, you are certain to find the mattress that's the right match for you. Therefore it doesn't matter if you're milder, thicker , sleep on your side, or you also deal with chronic pain. Nest can match your tastes .
- They were one of online's first brands to sell mattresses. Having a lineup of six beds which were different, Nest mattresses are created with each sleeper in mind.
Nature's Sleep
- Since Nature's Sleep is made up of 4 layers of polyurethane, it is different than most other mattresses out there. Nature's 4 layers provide support for people who are thicker. All these 4 layers also help by decreasing motion transfer significantly.
- Among Nature's layers is comprised of Vitex Memory Foam. . This coating not only helps assist the sleeper. It also provides them with pressure relief This aids for an outstanding evenings rest.
- Nature's Sleep provides a 20 year guarantee, as opposed to the conventional 10 year guarantee from most other mattress brands. This mattress is a little bit more costly than a few. But with a fantastic warranty, and Emerald Gel construction, it is well worth the money.
Plushbeds Mattress
- Plushbeds mattresses are toxin free, and are certified using GreenGuard Gold status. This implies every mattress isn't just comfortable, but secure as well.
- Plushbeds are latex mattresses, where they only use natural, organic substances. A total of three mattress models are from the companies present lineup: Each mattress has a total of 6 different firmness levels. In the King and Cal King you can also divide the firmness levels
- Free transport is supplied by Plushbeds. Together with a 100 night sleep trial, and 25 year guarantee. Dimesio.S Of Queen Purple Mattress
Loom & Leaf Mattress
- The Loom & Leaf mattress by Saatva is a memory foam mattress that happens on the luxury memory foam gamers like TEMPUR-Pedic. Loom & Leaf is one of very few online memory foam mattresses which isn't compressed and shipped in a box.
- The Loom & Leaf utilizes conductive memory foams; such as a convoluted memory foam laminated with cooling gel in the top layer, also supporting that is a base layer of high-density polyfoam. This all adds up to a very supportive, pressure-relieving feel.
- With Loom & Leaf offering both firm and relaxed models, they cater to stomach sleepers of any weight.
- Loom & Leaf brings to the table, a 120 night sleep trial, partnered with a 15 year warranty. If you are not satisfied they offer you a full refund.
Nectar Mattress
- Nectar is most likely the most popular and hottest mattress in the marketplace at the time of this writing. It's incredible comfort does not leave you disappointed The support of Nectar is great, and it does not have an excessive amount of sinkage.
- While most mattress brands provide a 10 year guarantee, Nectar has it's own Forever Warranty.
- The top layer of Nectar mattress, Is Composed of Quilted Gel Visco Elastic Memory Foam. Additionally, it contains gel memory foam along with Polyurethane Support Foam.
- Most mattress manufacturers have a 100 night sleep trial; Nectar gives you a complete year to test theirs.
If you're searching for a mattress, it is important to consider the next…
Mattress Comfort and Support
Comfort and support are the two largest variables to consider, once you're looking to buy a new mattress.
If you lie on a mattress, it must do a couple of things. It ought to properly support your body. It should also sink and contour to your body in the ideal places; to ensure your spine stays aligned, as you break through the night
It's imperative to have proper alignment from top to bottom as you sleep. This is imperative to be certain that you receive a nutritious rest, and to make certain you're reducing your spine and neck pain. As a mattress is being supportive, it is important that it supplies you with stress relief also.
Your stress points are responsible for you having a rough nights sleep, even if you go around at night a good deal.
Memory Foam mattresses have earned their way to the spotlight, by not being comfy, but as both supportive.
Should You Pick Stiff or Soft?
That is along the same lines, as when we speak about relaxation and support. Dimesio.S Of Queen Purple Mattress
It is important that a mattress is not too hard, or too soft.
A mattress needs to be neutral as it could be, to ensure your body and backbone stay in a neutral position.
If a mattress is too stiff, it is going to irritate your stress points, inducing pinched nerves and quitting adequate blood circulation.
If you wake up frequently with the feeling of pins and needles, then probably your mattress is too rigid.
And if you wake up with frequent back pain, then most likely that is because your mattress is too soft. This ends in a concaving impact, like a hammock. Which makes your backbone stand out of recovery.
It is important to locate a mattress using a neutral sense, that will surely be equally rigid and also soft in the perfect places.
Appropriate Temperature Level
Among the very typically overlooked over attributes of a mattress is that the breathability or fever neutrality of the mattress material. One of the greatest features of memory foam mattresses, is that their capacity to conform to a body.
Irregardless, foam mattresses which have reduced layers are well known to cause what is known as"the oven result".
Essentially,a mattress grabs your fever,forcing one to rest also sexy. |What happens in summary, is that a mattress absorbs the body heat; causing one to sleep sexy }
Most mattress businesses nowadays use modern technology, to create exceptional materials.
Their sole purpose is to get a mattress that has breathability, but at precisely the exact same time distributes your own body warmth equally, letting you sleep cool
Some brand names get this much better than some of their rivals. Dimesio.S Of Queen Purple Mattress
It is no surprise if you're looking a top top excellent mattress, which they don't come cheap .
It is a large investment to make, so once you buy one, it's crucial to locate a mattress that will certainly last you for years.
It's quite important that you find a mattress that has been constructed to last a very long period of time.
Should you will invest the money on a mattress that is brand new , look for a single that uses in a 10 year warranty
Quick Links to Other Best Mattresses:


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guide to teaching percussion / Harry R. Bartlett
Contributor(s): Bartlett, Harry R.Call number: 786.807 G946 Material type: BookSeries: College Instrumental Technique Series. Publisher: Dubuque, Iowa. : WM. C. Brown, c1964 Description: xiii, 168 p. : ill, music.Subject(s): Percussion instruments -- Study and teching
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|DW_General Book
|786.807 G946 (Browse shelf)
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|786.74 R958S 2009 Sound synthesis and sampling
|786.74 T739M Master electronics in music
|786.76 M987 The music machine :
|786.807 G946 guide to teaching percussion
|786.81923 A848B Brazilian percussion
|786.9 B632E Early percussion instruments :
|786.9 M398D Drums, tomtoms and rattles :
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Ferro-quadrupolar ordering in PrTiAl
Origin of the non-magnetic phase transition in PrTiAl, reported earlier in the macroscopic study, has been asserted microscopically using elastic and inelastic neutron scattering techniques. It has been shown spectroscopically that the crystalline-electric-field ground state is a non-magnetic doublet, whereas the excited states are two triplets ( and ) and a singlet (). The diffraction experiment under external magnetic field shows that the non-magnetic transition is indeed ferro-quadrupolar ordering, which takes place as a consequence of cooperative removal of the ground-state-doublet degeneracy. It is therefore concluded that PrTiAl is another rare example of Pr compounds exhibiting non-magnetic quadrupolar order.
I Introduction
Even when the magnetic dipolar degree of freedom is completely suppressed by a crystalline-electric field (CEF) from surrounding atoms, some elements can still have higher-rank-tensor degrees of freedom, such as electric quadrupoles, giving rise to mysterious low-temperature non-magnetic anomalies. Morin and Schmitt (1990) Such anomalies include relatively simple ferro- and antiferro-quadrupolar ordering, Suzuki et al. (1997, 2004); Iwasa et al. (2002) as well as much elaborate incommensurately-modulated-quadrupolar order. Onimaru et al. (2005) In metals, those degrees of freedom may couple with conduction electrons. In case of quadrupoles, the coupling results in a non-trivial quadrupolar Kondo effect, which is a very intriguing issue of active research. Cox (1987); Cox and Zawadowski (1998) In reality, however, the quadrupolar (or higher-order) degree of freedom frequently coexists with dipolar terms, and thus its interplay with the dominant dipolar ordering results in much complicated behavior, Kuwahara et al. (2007); Tanaka et al. (2004); Hirota et al. (2000) prohibiting us to elucidate phenomena solely due to the higher-order degree of freedom. Hence, systems with a ground state possessing only higher-order degree of freedom are of particular interest.
Such a ground state may possibly be realized with a Pr ion in cubic CEF, since the non-magnetic, but quadrupolar- and octupolar-active, doublet may be the ground state for the electronic configuration in a certain range of CEF parameters. Lea et al. (1962) Therefore, many attempts have been made to find cubic Pr intermetallic compounds with the CEF ground state being the doublet. A recent outcome of intensive material search is the ternary Pr ( Ti, V, Ru, Ir, …, and Zn and Al) intermetallic compounds. Onimaru et al. (2010); Sakai and Nakatsuji (2011); Onimaru et al. (2011) Pr belongs to the cubic space group , where the Pr ion, with the local site symmetry (), is located at the center of a perfect Friauf polyhedron with the coordination number 16, consisting of atoms. Niemann and Jeitschko (1995); Thiede et al. (1998) A growing number of macroscopic studies on the Pr compounds have revealed a variety of intriguing low-temperature phenomena in this system, ranging from possibly ferro- and antiferro-quadrupolar ordering to superconductivity.
In the present study we choose PrTiAl, Sakai and Nakatsuji (2011) one of the Pr series compounds. Magnetic susceptibility measurements on PrTiAl show Curie-Weiss behavior at high temperatures K, yielding an effective moment size of . In the high-temperature range, the electrical resistivity shows increasing behavior, a sign of magnetic Kondo effect, indicating a considerable coupling between the and conduction electrons. As temperature is decreased, the magnetic susceptibility becomes almost temperature independent below K. This suggests that the ground state is non-magnetic. Nevertheless, the specific heat and the electric resistivity show clear anomaly at K, and therefore, there should remain non-magnetic degree of freedom that orders at such a low temperature. As the estimated entropy of subsystem at K reaches , it has been suggested that the ground state is the non-magnetic doublet. Assuming this ground state, PrTiAl could have active quadrupolar or octupolar degree of freedom at sufficiently low temperatures, and hence one of those degrees of freedom may be the order parameter for the non-magnetic transition observed in the specific heat and resistivity measurements. As the sharp specific-heat anomaly at becomes strongly broadened under high magnetic field, ferro-quadrupolar ordering is inferred. Sakai and Nakatsuji (2011)
To confirm this scenario, the CEF splitting has to be determined using a spectroscopic technique. However, up to now no spectroscopic study on the CEF splitting in PrTiAl (nor even in any Pr compounds) has been reported. Furthermore, for conclusive understanding of the non-magnetic transition, it is essential to determine the symmetry of its order parameter, but this has not been explored experimentally at all. In the present study, we, therefore, undertook neutron inelastic-scattering and diffraction experiments to determine the CEF splitting scheme, and to pin down the nature of the ordering degree of freedom in PrTiAl.
Ii Experimental details
Single crystals of PrTiAl were grown by an Al self-flux method under vacuum, using the pure starting elements, 99.99%-Pr, 99.9%-Ti, and 99.999%-Al. The largest single piece of grown crystals was approximately 50 mg, which was used in the single crystalline diffraction study. As a polycrystalline sample, we have collected a few hundreds of tiny single crystals, amounting roughly 1 gram in total.
For the inelastic experiment, the polycrystalline sample was wrapped in an aluminum foil, and sealed in a standard aluminum sample can with He exchange gas. The sample can was set to a He closed-cycle refrigerator, to a He closed-cycle refrigerator, or to a 6 T vertical field magnet, depending on necessity of the lowest temperature and the magnetic field. The inelastic experiment has been carried out using the ISSP-GPTAS(4G) triple-axis spectrometer installed at JRR-3, Tokai, Japan. Pyrolytic graphite (PG) 002 reflections were used for both the monochromator and analyzer, which were set in a horizontally-and-vertically (doubly) focusing condition to increase counting efficiency. The collimations were 40'(Open)-3RC-7RC-30S, where 3RC, 7RC and 30S stand for radial collimators with 3 and 7 blades, and a slit with 30 mm opening before the detector. The final neutron energy was fixed to 14.7 meV, and a PG filter was inserted between the 3rd collimator and analyzer to eliminate the higher harmonic neutrons.
For the diffraction experiment, the 50 mg single crystal was used with the 100 and 010 axes in the scattering plane. The single crystal, set in a standard aluminum can, was top-loaded into the 6 T vertical field magnet with the field parallel to the 001 axis, or into the ILL-type Orange cryostat if external field is not necessary. The elastic experiment has been performed also using ISSP-GPTAS, with a vertically focusing (horizontally flat) PG 002 monochromator; the spectrometer was operated in the double axis mode without the analyzer. The incident neutron energy was selected as meV, calibrated using a standard AlO powder sample. Several collimation conditions were employed depending on necessity of resolution, and two PG filters were inserted to eliminate the higher harmonic neutrons completely.
Iii Experimental results and discussion
iii.1 Inelastic scattering experiment on CEF excitations
First, we measured the inelastic scattering spectra in wide temperature and energy ranges using a polycrystalline sample, aiming at determining the CEF level scheme of the Pr ions. Figure 1 shows the neutron inelastic scattering spectra at the three temperatures , 50, and 250 K, and at the momentum transfer Å. Strongly temperature dependent peak was observed around meV, whereas only weak, or negligible, temperature dependence was seen for the peaks above 17 meV. From their -dependence (not shown), we concluded that the peaks above 17 meV are due to phonon contributions. We also found that the intensity increase around meV at 250 K can be roughly reproduced by the Bose temperature factor (), and thus this spectral weight is also due to the phonon scattering. Therefore, we conclude that (observable) magnetic excitations exist only in the low energy region meV.
Next, we measured the temperature dependence of the inelastic spectra in the low energy region. Shown in Fig. 2 are the low-energy spectra in a wide temperature range observed at Å. Before discussing the temperature dependence in detail, we first make a comment on the higher energy upturn commonly seen in all the spectra [except the one in Fig. 2(g), which will be described later]. This is due to the increase of background from contaminating main beam; at high energies meV and at a relatively low Å, the scattering angle becomes quite low, and thus with the horizontally focusing analyzer the contamination from the main beam becomes serious, giving rise to this increase of the background level. This background was separately estimated, and removed in the following fitting procedure.
Other than the upturn, there appear two inelastic peaks in the spectra. These peaks were clearly observed at K (); an relatively sharp inelastic excitation peak was observed at meV, whereas an additional broad peak was observed as a hump around meV, as shown in Fig. 2(f). The spectra at the elevated temperatures are shown in Fig. 2(a-e). As the temperature is increased, the 6 meV and 9.5 meV peaks become weaker and broader. Nonetheless, they are still observable at high temperatures as K, indicating that they are robust excitations, originating from single-site effect. Together with their dependence (not shown), we conclude that they are CEF excitation peaks.
To check the change of the CEF excitation spectrum across the non-magnetic transition , the inelastic spectra were measured above and below with higher statistical accuracy. Shown in Fig. 2(g) are the two spectra at K and 4 K. For these scans, the supplemental radiation shield was placed along the main beam path, which completely suppresses the upturn of the background. As is apparent in the figure, there is no detectable difference in the peak width as well as intensity for the two spectra within the present energy resolution and statistical accuracy. As we will see in the next subsection, the CEF excitations have considerably large intrinsic width (of the order of a few meV) even at low temperatures. It is, therefore, reasonable that a small change of energy levels due to the ordering at 2 K (corresponding to an energy scale of roughly 0.2 meV) cannot affect the peak profile significantly.
iii.2 Determination of CEF Hamiltonian parameters
For the single Pr ion (the total angular momentum ) under the point symmetry (), the CEF Hamiltonian may be written as: Lea et al. (1962)
where , and are the Stevens operator equivalents, Hutchings (1964) and and are the factors given in Ref. [Lea et al., 1962]. CEF removes the ninefold degeneracy of the -electron -multiplet into four levels (), corresponding to the irreducible representations , and of , respectively. The transition strengths between these CEF splitting levels are then calculated as:
where , or , and and are the Boltzmann constant and the partition function, respectively. The scattering function from a powder sample may be given by a sum of spectral weights of the CEF transitions:
where , , and are the number, the magnetic form factor, Lisher and Forsyth (1971) and the Lande factor of the Pr ions, respectively. In the present analysis, we assume a pseudo-Voigt function as a profile function of the inelastic peaks, which is a reasonable approximation of an intrinsic Lorentzian-shaped excitation convoluted by a Gaussian-shaped instrumental resolution: Thompson et al. (1987); Wertheim et al. (1974)
In the above equations, is the full-width at half-maximum (FWHM) of the intrinsic Lorentzian-shaped spectral weight function of the CEF excitations. For the width of the Gaussian-shaped instrumental resolution, , we assume energy dependent with the elastic width meV determined using the vanadium standard.
By performing least-square fitting to the observed spectra in a temperature range of K simultaneously, we obtained the optimum CEF parameters as: and meV. In the fitting procedure, the Lorentzian widths for the excitations between the ground state and excited states are set as adjustable, however between the excited states are fixed to 3 meV, since they appear only in the spectra at high temperatures with weak intensity. The fitting results for all the spectra with different temperatures are shown by the solid lines in Fig. 2(a-f), whereas the profiles of each CEF excitation peak and the background are given by the dotted and dash-dotted lines. The reasonable coincidence between the calculated and observed spectra in a wide temperature range validates the obtained CEF parameters. Temperature dependence of the peak widths between the ground state and the first excited state () and that between the ground state and the second excited state () is shown in Fig. 3. The uncertainty of the width for the higher energy peak is considerably large, and thus we can hardly discuss the its temperature dependence. On the other hand, the width for the lower energy peak exhibits clear decreasing behavior as temperature is lowered. Interestingly, both the widths remain considerably large even at the lowest temperature. This may suggest remaining dipole/quadrupole fluctuations due to the coupling to the conduction electrons. However, it should be noted that such broad peaks may also originate from finite dispersion of the CEF excitations. At the present moment we think this possibility is not likely; if this is the case, the peak should be narrower at higher temperatures, where the dispersion becomes weaker. However, to unambiguously settle this issue, future single-crystal inelastic scattering study is necessary.
The resulting energy level scheme is illustrated in Fig. 4. The ground state is the non-magnetic but quadrupolar (and octupolar) active doublet. The first and second excited states are both magnetic triplets belonging to the (5.61 meV) and (9.30 meV) irreducible representations. The highest-energy excited state is consequently the non-magnetic singlet state at 13.47 meV, which cannot be be seen in a neutron scattering spectrum. The list of determined energies levels and corresponding wave functions is given in Table. I.
|Wave functions
iii.3 Order parameter
It has been confirmed in our neutron inelastic experiment that the ground state is non-magnetic doublet in PrTiAl, consisting of the two wave functions, and , as listed in Table I. For the doublet, two components of quadrupolr moments, and , are allowed to be finite, as well as one higher-order octupolar moment, . (The bar stands for possible permutation of the three operators.) Hence, one of them may be the order parameter responsible for the mysterious non-magnetic transition observed around 2 K in the macroscopic measurements. The quadrupolar and octupolar order parameters cannot be directly measured using neutron scattering because of the absence of the significant coupling between the neutron and the multipole moments. Nevertheless, magnetic (dipole) moment, neutron-observable, can be induced by mixing the excited magnetic states into the non-magnetic ground state under finite external magnetic field. The mixing, and consequently the size and direction of the induced moment, depend on the symmetry of the ground- and excited-state wave functions. Therefore, one may distinguish the wave-function symmetry, and accordingly the symmetry of the order parameter, using the neutron scattering under external field. Effantin et al. (1985)
Much specifically, for the finite order parameter , the degenerated wave functions split into two as and . On the other hand for , linear combinations of the wave functions, and will be the energy-split eigenfunctions. For , will split into and . Under the magnetic field along 001 (i.e. ), the order parameter will give rise to extra (additional) induced dipole moment along , , whereas for the rest, no coupling between the multipolar order and induced dipole moment is expected. Shiina et al. (1997) Therefore, we may distinguish by observing appearance of extra induced moment under the external field along in the ordered phase.
With the above expectation in mind, we have performed neutron diffraction experiment under magnetic field along . A number of positions in the plane were investigated using the scans, with or without the external magnetic field, and at K () as well as 9 K (). The investigated positions are shown in Fig. 5(a); closed circles stand for the positions where the nuclear Bragg reflections are allowed, whereas triangles denote nuclear forbidden positions.
Representative results of the scans are shown in Fig. 5(b-f). At the 220 position shown in Fig. 5(b), results at 1.6 K and 9 K under zero field perfectly coincides with each other, confirming the absence of the ferromagnetic dipolar ordering. By applying T along the 001 direction at K, the scattering intensity increases weakly, indicating that the ferromagnetically aligned dipole moments are induced by the external magnetic field. As the temperature is lowered to K, significant increase of the scattering intensity was observed, suggesting an appearance of the extra induced moment. The temperature dependence of the scattering intensity will be discussed later in detail.
Such an increasing behavior of the scattering intensity below under the finite field is also detected for the 440 reflection, shown in Fig. 5(c). Since the nuclear Bragg reflection intensity, which is supposed to be temperature independent in this low temperature range, is relatively strong compared to the 220 reflection, the increase of the scattering intensity at K (and at T) is less prominent for 440. Nevertheless, the increase is roughly 200 counts/3 minutes, which is indeed a similar value as we observed for the 220 reflection. Such increase of the reflection intensity was not observed at other nuclear allowed positions, as exemplified by the 620 reflection shown in Fig. 5(d). However, this is simply due to their much stronger nuclear intensity compared to the magnetic signal; we cannot obtain necessary statistical accuracy to detect magnetic signal for these reflections within a reasonable experimental time.
The nuclear forbidden positions, such as the 110 and 330 reflections, were then checked in a similar manner. Resulting scans are shown in Fig. 5(e) and 5(f). As can be seen in these figures, no increase of the scattering intensity was detected as temperature is decreased to K even under the finite external field T. From these observations, we conclude that the increase of the scattering intensity under finite external field below can be observed only on top of the allowed nuclear Bragg reflections, and therefore the ordering in PrTiAl cannot be staggered one, but is ferro-type ordering.
To see if the increase of the scattering intensity under finite external field is indeed a signature of a phase transition, we have checked the temperature dependence of the reflection intensity, which is, in the present case, the square of the induced moment. The temperature dependence of the 220 and 440 reflection intensity under T is shown in Fig. 6(a). Drastic increase can be see at K, indicating that cooperative ordering of the induced magnetic moments take place at this temperature. Shown in Fig. 6(b) are the corresponding temperature dependence of the reflection intensity measured under zero external field. As is clearly seen, there appears no critical increase of the reflection intensity, indicating that there is no ordering of the dipole moments under zero field.
External field dependence of the 220 reflection intensity is shown in Fig. 7. Apparently, the reflection intensity shows continuous dependence. This certifies that the phase at T and K is continuous to that at zero field. In other words, the critical behavior observed under T is not due to the field-induced ordering of dipole moments, but due to the spontaneous ordering of quadrupole (or octupole) moments, which was observed as the non-magnetic anomaly in the macroscopic measurements in zero field. By normalizing the field-induced intensity of the 220 reflection at T in the ordered phase ( K) using the purely nuclear reflection intensity obtained at K and T, we estimated the size of the induced moment as 0.41(3) . This is in a good agreement with those obtained in the similar (but much complicated incommensurately ordered) intermetallic compound PrPb. Onimaru et al. (2005)
The critical increase of the field-induced dipole moment was clearly observed for below as shown in Fig. 6(a). As mentioned earlier, this increase can be expected only in an ordered phase with finite quadrupolar order parameter, but not for nor . The observed dependence of the squared induced-moment (Fig. 7) is also what is expected for the ordered phase. We, hence, conclude that the ferro-quadrupolar ordered phase is established below with the finite order parameter .
Iv Summary
We have performed both the polycrystalline-inelastic and single-crystal-diffraction experiments on PrTiAl. Two CEF peaks were observed in the inelastic experiment, which were assigned to the and levels of the Pr ions. The ground state for is confirmed to be the non-magnetic doubly degenerated state. In the diffraction experiment, the field-induced dipole moment shows critical increase at , appearing on the top of the nuclear allowed reflections. From those results, we conclude that the ferro-quadrupolar order with the finite order parameter is established in PrTiAl.
The present authors thank Prof. T. Onimaru for valuable discussions. This work is partially supported by Grant-in-Aids for Scientific Research (No. 21684019 and No. 20560612) from JSPS, and by Grant-in-Aid for Scientific Research on Innovative Areas "Heavy Electrons" from MEXT, Japan.
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