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This is a gorgeous, fascinating, and very fun site. It's from the Element Collection, which includes Theodore Gray who is also the creator behind the lovely Wood Periodic Table. Sites like these remind us that science is fun, creative, and beautiful.
The Ruins of Pompeii, via Google Street View
Destroyed by the eruption of Mount Vesuvius on August 24, 79 C. E., this small town near Naples was covered by ash and lava until 1738.
Season's Greetings
We are capable of such beauty and grace. May we all learn to ever reach for our best inherent qualities.
NORAD Santa-Tracking
The NORAD Santa-sighting updates have become a holiday tradition, quietly and with a remarkable lack of the late twentieth-century cynicism that too often mars our experience of things simple and sweet and innocent.
All joking aside, NORAD has been taking its Santa tracking project seriously for decades. But it actually began in 1955 with a wrong number.
One morning that December, U.S. Air Force Col. Harry Shoup, the director of operations at CONAD, the Continental Air Defense Command–NORAD's predecessor–got a phone call at his Colorado Springs, Colorado, office. This was no laughing matter. The call had come in on one of the top secret lines inside CONAD that only rang in the case of a crisis.
Grabbing the phone, Shoup must have expected the worst. Instead, a tiny voice asked, "Is this Santa Claus?"
You can check The Official NORAD Santa Website for regular updates, assisted by Google Earth, as Santa meets his worldwide delivery schedule for yet another year. You can also follow @NORADSanta on Twitter.com.
Joyeux Noel, everyone!
Last Man Standing
Mental Floss posted this short film by Sean Dunne on Vimeo, excerpting an interview with 108-year-old Frank Woodruff Buckles:
Buckles from Sean Dunne on Vimeo.
What was it like for Frank Buckles, upon finally coming home from the war? "When I came back, the parades were all over. Nobody gave a damn. I tried to buy a pack of cigarettes; couldn't buy it — I wasn't old enough."
Kevin Carey "That Old College Lie"
Carey notes that Senator Claiborne Pell died at age 90 on January 1, 2009. Senator Pell was the driving force, and the inspiration for the federal Pell Grants for under funded college students. In the context of noting that Pell Grants are no longer anything like sufficient in terms of funding percentages of college costs for low income students, Carey points out that:
It's that too many of the students who do enroll aren't learning very much and aren't earning degrees. For the average student, college isn't nearly as good a deal as colleges would have us believe. . . . A 2006 study from the American Institutes for Research found that only 31 percent of adults with bachelor's degrees are proficient in "prose literacy"–being able to compare and contrast two newspaper editorials, for example. More than a quarter have math skills so feeble that they can't calculate the cost of ordering supplies from a catalogue. more . . .
Winter Solstice, 2009
You lovers, for whose sake the lesser sun
At this time to the Goat is run
To fetch new lust, and give it you,
Enjoy your summer all,
Since she enjoys her long night's festival.
Let me prepare towards her, and let me call
This hour her vigil, and her eve, since this
Both the year's and the day's deep midnight is.
John Donne "A Nocturnal Upon St. Lucy's Day, Being the Shortest Day" more . . .

subset: commoncrawl


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wrestling / News
Total Divas May Have Given Away a Spoiler for The Women's Royal Rumble
January 11, 2018 | Posted by
– Last night's episode of Total Divas looks to have given away a Royal Rumble spoiler. On the show, Brie Bella (who has been working on a comeback), met with WWE Senior Director of Talent Relations Mark Carrano. During the meeting, they spoke about the Bellas coming back together "for the Rumble through WrestleMania." The Bellas are scheduled for the Raw 25 show, and the speculation was that they would announce their Rumble participation on that show.
More Trending Stories
- Big Show Discusses Who He Thinks Are Toughest Guys In Wrestling, Shares Story About What Undertaker Told Him About Working With Knee Injury
- Jim Cornette Discusses Fans Throwing A 'Riot' At WWE Little Rock Show After Shawn Michaels Refused To Wrestle, What Talent Thought of Michaels
- Terry Funk Says Wrestling Wasn't Good To Sabu Financially
- Hugo Savinovich Claims Two More Former WWE Wrestlers May Come Forward About Saudi Arabia Trip


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Jack binion steakhouse horseshoe casino
Jack Binion's Steak House. For the well-being of our team members and guests, Jack Binion's is Temporarily Closed. ABOUT JACK BINION'S STEAK HOUSE. Jack Binion's Steak House at Horseshoe Council Bluffs is the place to go for steaks taken seriously, a fine dining experience sure to Accept Reservations: Yes. Horseshoe Casino near Chicago hosts the best Hammond restaurants the city has Jack Binion's Steak $$$$ Learn The ultimate variety has arrived at The Eatery in Horseshoe Hammond. Brick oven fired pizzas, prime rib dressed burgers, sandwiches, salads, wraps and more highlight the menu at Horseshoe's newest dining option. The Eatery. Book now at Jack Binion's - Horseshoe Casino - Southern Indiana in Elizabeth, IN. Explore menu, see photos and read reviews: "Our server, Christi, is very friendly, advised us on an excellent choice of wine, and visited our table to check to see if everything was good."4,3/5(1,2K).
Jack Binion's Steak
The dishes they serve are delicious and the stuff is generous and cooperative. More Reviews March It's okay, but one of my items was undercooked and I asked to substitute a less expensive item which they did, but charged me for the more expensive one. I also smelled cigarette smoke during my meal. He has since resigned the position but has remained with Wynn Resorts in a consulting role.
Interesting Fact about casino
- The casino is the most common place in which suicides are committed
- The annual profit from the gaming industry in the US is 18 billion dollars.
Jack Binion
I often take my friends to this restaurant with my highest recommendations. I go their often. This recommendation is always successful. The dishes they serve are delicious and the stuff is generous and cooperative. Whenever we go to this place we enjoy a pleasant evening. I recommend this place with pleasure. March It's okay, but one of my items was undercooked and I asked to substitute a less expensive item which they did, but charged me for the more expensive one.
The service is not as good as it used to be, the there were only a few diners, probably because the prices are so high and the specials aren't as ubiquitous as they used to be. I also smelled cigarette smoke during my meal.
March The steaks are made to order. Juicy and tender!! The scallops are awesome as are the lamb chops. Speaking of chops.. You'd think you were eating a filet mignon. The wait staff are friendly and very knowledgeable.
They always greet you like an old friend. The chefs are the best!! Forgive me!! I love ALL of them. More Reviews Please contact the business directly to verify hours and availability.
View Details
Binion is the son of casino magnate Benny Binion and worked for his father at Binion's Horseshoe , a casino and hotel in Las Vegas , Nevada. Binion became president of the Horseshoe in at the age of His fame grew following his hosting of the first World Series of Poker at the Horseshoe which became the largest set of poker tournaments in the world. Privately held, Binion's Horseshoe became renowned as one of Nevada's most successful casino operations.
He also acquired the rights to the Horseshoe brand outside of Nevada. Binion went on to form Horseshoe Gaming Holding Corporation which developed and operated several riverboat casinos under the Horseshoe name. Binion continued to promote the casinos for Harrah's Entertainment following his sale of the company in to Harrah's.
In July , Binion became chairman of Wynn Resorts. His responsibilities included opening the Wynn Macau. He has since resigned the position but has remained with Wynn Resorts in a consulting role.
Jack Binion. Dallas , Texas , U. Retrieved July 24, Binion's Horseshoe.
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Nine Forty USA 24 Inch Commercial Cotton Dry Dust Mop Head Hardwood Floor Duster Broom Set |
This Complete Kit Includes a Dust Mop, Steel Frame, and Aluminum Extension Handle. The Dust Mop is Made in the USA From High Quality Cotton Yarn. The Ergonomic Quick Change Head on the Handle Allows the Frame to Rotate 360 Degrees Providing Maneuverability in Hard to Reach Places. While Remaining Light Weight the Aluminum Telescoping Handle Ranges from 42" to 72" Long; Allowing it to Reach Under Objects or Adjust to Various User Heights.
- Brand: Nine Forty
Gorilla Grip Original Felt + Rubber Underside Gripper Area Rug Pad 1/4 Inch Thick (8x11 Feet) Made in USA, for Hardwood & Hard Floor, Plush Cushion Support Pads for Under
Tired of your straightening your rugs day after day? Your time is valuable and your home is beautiful. Try the BEST rug pad you will ever own. The GORILLA GRIP FELT + RUBBER rug pad. Hereís what thrilled customers worldwide love about our products: While others may look or claim to be similar, ours is super strong and durable. How do we know this? Simple, we tested the competition. We tested their rug pad properties and checked the quality of the materials they are using. We designed a product to surpass the ability of other products. What makes ours so special? ? #1 RATED 5 STAR*****: Please read our reviews to see why customers agree our product is the best FELT+RUBBER rug pad they have ever owned! SHIPS ROLLED: Unlike many of our competitors, our product is shipped rolled, not folded, to prevent creases and bunching. THICK CUSHION: Superior quality .25" condensed needle punch felt for increased durability, cushion, rug and floor protection. Easily trimmed for custom sizes. Helps reduce sound. DURABLE AND STRONG: Textured rubber on lower surface helps keep rugs in place on floors. Will not mark or stain floors. MADE IN THE USA: 100% recycled felt. Hypoallergenic. No out gassing or VOCs. Mold, mildew, and moth resistant. A+ GUARANTEE: And if you are not happy with our ...
- Color: Gray
- Brand: Gorilla Grip
Bona BONAKEMI USA 160 OZ Power Plus Hardwood Floor Deep
Bonita's most powerful cleaner yet, the power plus hardwood floor deep cleaner has an oxygenated formula that loosens and removes heavy dirt build-up. The powerful solution provides a deep cleaning for your hardwood floors - all without the extra effort. For optimal results, use the cleaner with the bona power plus microfiber deep cleaning pad.
- Brand: Bona
Bona Hardwood Floor Cleaner Refill, 128 Fl
Bona Hardwood Floor Cleaner Refill fills your empty Bona cartridge or spray bottle with ready-to-use Bona Hardwood Floor Cleaner. The bottle has splashless technology, and the handle and side grip allow for an easy, controllable refill experience. The residue-free, fast drying solution cleans hardwood floors by gently and effectively removing dust, dirt and grime to reveal the floor's natural shine and beauty.
- Color: Clear
- Brand: Bona
Smart Programmable Robot Vacuum Cleaner - Gyro Sensor Home Navigation, Scheduled Activation & Automatic Charge Dock - Robotic Auto Cleaning for Carpet Hardwood Floor - Pure
Pure Clean Model : PUCRC105Smart Robot Vacuum CleanerSmart Robot Vacuum Cleaner with Remote Control Navigation, Dry Mop & Sweep Cleaning Ability Features:Robot Vacuum with Sweep, Dry Mop & Clean AbilityAutomatic Self-Charge & Return to Docking StationControlled Navigation Cleaning via Included Remote Control(5) Selectable Cleaning ModesLow-Profile Design Slides Underneath FurnitureConfigurable Timer Setting for Pre-Set Cleaning SchedulesDetachable Dry Mopping Pad for Floor PolishingBuilt-in Rechargeable BatteryDual Rotating Sweeping BrushesUnique Gyro Sensing TechnologyIntegrated Sensors for Anti-Falling & Anti-Collision Digital LCD Display Panel with Simple One-Button OperationWorks on Hardwood, Linoleum, Tile, Low/Hard Carpet FloorsWhat's in the box:Robot Vacuum Cleaner Charging Dock StationDustbin FilterMop Pad Attachment(2) Mopping Cloths(2) Side Sweeping BrushesPower AdapterTechnical Specs:System Power Output: 20 Watt MAXFloor-Space Coverage Area: Up to 650'+ Square FeetSuction Power: Up to 1000 Pa, Air Watt PressureWorking Time: 80-100 Minutes After Full ChargeCharge Time: ~4-5 HoursDustbin Capacity: 0.4LNoise Level:
- Color: White
- Brand: PURE CLEAN
Bona WM700018159 Cleaner, Hardwood Floor Refill Gallon, 1
128 oz. (1 gallon). gently clears your floors of dust, dirt and grime. Dries quickly with no rinsing needed. Greenguard gold certified to ensure a safe formula. Safe for all unwaxed, polyurethane finished wood floors. 4 per case.
- Brand: Bona
Bona Hardwood Floor Disposable Wet Cleaning Pads, 12
For a thorough clean quickly, Bona Disposable Wet Cleaning Pads feature a multi-layered design infused with Bona Hardwood Floor Cleaner. The residue-free, fast drying solution cleans hardwood floors by gently and effectively removing dust, dirt and grime to reveal the floor's natural shine and beauty. These extra-large cleaning pads utilize locking strips for easy attachment and removal from the mop for superior quick and easy cleaning. Waterbased solutions and GREENGUARD GOLD certification ensure a safe product for your family, pets and our planet.
- Color: _
- Brand: Bona
Nine Forty Residential | Commercial 36 Inch Janitorial USA Floor Dry Dust Mop Broom Set |
This Complete Kit Includes a 36 Inch Dust Mop, Steel Frame, and Aluminum Extension Handle. The Dust Mop is Made in the USA From High Quality Nylon Yarn Which Builds Static Charge to Attract Dust and Dirt Particles. The Ergonomic Quick Change Head on the Handle Allows the Frame to Rotate 360 Degrees Providing Maneuverability in Hard to Reach Places. While Remaining Light Weight the Aluminum Telescoping Handle Ranges from 42" to 72" Long; Allowing it to Reach Under Objects or Adjust to Various User Heights.
- Color: Bagss192
- Brand: Nine Forty
Bona Hardwood Floor Premium Spray
The next-generation Bona Premium Spray Mop for Hardwood Floors is an all-in-one solution to clean and reveal the natural shine of your floors. Includes Bona's waterbased residue-free cleaner in a refillable cartridge and a washable microfiber pad. The original formula cleans hardwood floors effectively by removing dust, dirt and grime revealing beautiful floors. The extra-large mop head delivers quick and effective cleaning, and the flexible rubber corners protect baseboards and furniture from dings and scratches. A secondary grip allows for added cleaning power, and a retractable hook makes storage easy.
- Color: 1 Pack (Original Version)
- Brand: Bona
Vita Vibe Ballet Barre - FS72-W Traditional Wood 6ft. Single Adjustable Height Floor Mount Ballet Bar - Stretch/Dance Bar - Vita Vibe - USA
Vita Vibe Professional Series adjustable height floor mount ballet barre / stretch bar. The FS72-W is a beautiful sanded smooth, finish ready hardwood Ash 6 foot wide adjustable height, floor mountable single bar ballet barre with black endcaps. The FS72-W includes 2 brackets which are fabricated from 1/4" thick steel and powdercoated in a texture black finish and 2 adjustable height FS1 Floor Stanchions. Mounting hardware (with the exception of floor anchors) is included. The barre can be stained or finished to your desired color; however; most studios prefer to let the wood naturally patina over time.
- Brand: Vita Vibe
iPrimio NeverCurl's Best V Shape Design to Instantly Stops Rug Corner Curling. Safe for Wood Floors. for Indoor & Outdoor Rugs. Not an Anti-Slip pad. Made USA. Patent
REGISTERED BRAND ON AMAZON: Easiest and Fastest way to Instantly Stop Rug Corners from Curling. Highest Rated Anti Rug Curling product on Amazon. How it Works: The top adhesive side of the NeverCurl Sticks to the Rug Bottom - Not the Floor. Makes cleaning under rug easy! Weatherproof adhesive allows NeverCurl to be used for INDOOR and even OUTDOOR rugs. The stiff plastic holds the rug corner flat. The soft rubber bottom side Protects Any Type of Flooring - Safe For Hardwood Floors. Use with Any Rug and Over Any Floor Type. Our Patent Pending design combines rigid plastic, soft rubber, and weather proof adhesive. It fastens to the rug, not the floor. It is a well-engineered product that ACTUALLY WORKS, keeping your rug corners flat. You may need to clean rug corner with rubbing alcohol to remove wax and oil from rug to have NeverCurl adhere properly. For really STUBBORN corners, you may apply more than one NeverCurl next to each other. We recommend "Mighty X Carpet Tape" to prevent rug slipping, if necessary. NeverCurl is NOT an Anti-Slip Pad Made in America. Have no fear, NeverCurl is here.
- Color: Black
- Brand: iPrimio
Bona Stone, Tile & Laminate Floor Cleaner Refill, 128
Bona Stone Tile & Laminate Floor Cleaner Refill fills your empty Bona cartridge or spray bottle with ready-to-use Bona Stone Tile & Laminate Floor Cleaner. The bottle has splashless technology, and the handle and side grip allow for an easy, controllable refill experience. The rinse-free, streak-free formula cleans hard-surface floors effectively by removing dust, dirt and grime leaving your floors clean and beautiful. Ingredients -aqua , ppg-2 methyl ether, butoxypropanol , ethoxylated alcohol , alanine, n,n-bis(carboxymethyl)-, trisodium salt, isotridecanol ethoxylate , oxirane, 2-methyl-, polymer with oxirane, mono(2-propylheptyl) ether , maleic acid, polymer with diisobutene, sodium salt , benzisothiazolinone , methylisothiazolinone , citric acid , liquitint aquamarine.
- Color: Clear
- Brand: Bona
Nine Forty Residential | Commercial USA Cotton Wedge Hardwood Floor Dry Dust Mop Head |
This complete kit is the perfect mop for hard to reach places. It can be used to clean hardwood floors or under/behind furniture. The most advantageous use is for textured surfaces such as ceilings that often collect dust and spider webs. The aluminum extension handle can adjust from 42" (great for storing) to 72" which allows it to reach high ceilings or reach under/behind objects. The dust mop head is designed for industrial use, giving it a long service life allowing the consumer to get a good value for the price.
- Color: White, Blue
- Brand: Nine Forty
The Learning Journey Lift & Learn USA Map
This fun and colorful tray puzzle features the United States map and will teach children the 50 states. State capitals and picture are also printed under the pieces. Each puzzle measures 15" x 11". Ages 3+ years
- Brand: The Learning Journey
Gorilla Grip Original Area Rug Gripper Pad (5x7), Made in USA, for Hard Floors, Pads Available in Many Sizes, Provides Protection and Cushion for Area Rugs and
Tired of straightening your area rugs day after day? Your money and time is valuable. Try the BEST RUG PAD you will ever own, the GORILLA GRIP rug pad for hard surfaces. What does a Gorilla have to do with your rugs? Well if you had a Gorilla Grip rug pad you would know what thrilled customers worldwide love about our products. Here is what makes ours so effective: IS THIS RUG SLIP-RESISTANT? Yes, this skid-resistant rug pad for hard floors helps locks rugs in place. It also helps with moving and bunching. DOES IT PROVIDE FLOOR PROTECTION? Of course. The open grid construction allows rugs to breath and helps to make vacuuming easier. This rug pad is also washable! IS IT MADE IN THE USA? Yes! Be proud that you are putting higher quality product in your home and supporting the USA. CAN I TRIM THIS RUG PAD FOR CUSTOM SIZES? Absolutely. You can easily cut this rug pad with a household scissor to fit any non standard sized rug. WHAT IF I'M UNHAPPY WITH MY RUG PAD, CAN I RETURN IT? Of course. If you are not happy with our top rated rug pads for any reason, yes any reason at all, we will provide you with your choice of a replacement or a full refund. While many companies will ask you to pay hidden fees or make you fill out tedious return forms, our NO QUESTIONS ASKED GUARANTEE POLI...
- Color: White
- Brand: Gorilla Grip
Eureka NES210 Blaze 3-in-1 Swivel Lightweight Stick Vacuum Cleaner Dark
1 Pack
- Color: Dark Black
- Brand: EUREKA
Real Simple Clean Hardwood Floor Cleaner, for Hardwood and Engineered Wood Floors, Can be Used with Spray Mop, USDA Certified Biobased Product, Made in USA, Fresh Citrus, 24
For Hardwood and Engineered Wood Floors. We all enjoy the warm feel of wood floors. But keeping them clean can be a chore-and can expose you to harmful fumes. Our carefully balanced formula replaces harsh chemicals with the essence of great smelling, oil-rich plants for a streak-free shine that brings out a floor's natural beauty.
- Brand: Real Simple
Sheiner's Hardwood Floor Cleaner Concentrate for Deep Cleaning of Wood, Laminate, Natural and Engineered Flooring, pH Neutral, Safe for All Surfaces, 128 Ounce (Makes up to 128
Sheiner's Hardwood Floor Cleaner Concentrate is professional grade concentrated cleaning solution for enhanced versatility and control while cleaning wood and wood laminate surfaces. Whether you need to clean a large floor area or a small piece of furniture Sheiner's Hardwood Floor Cleaner Concentrate is the ideal solution. The neutral pH formula makes it suitable and safe for all types of hardwood floors, wood furniture, laminate floors and wood laminate surfaces. The 1 gallon bottle is great for refilling 32 oz spray bottles or for applying to large areas like living rooms and bedrooms. Directions:Simply apply Sheiner's Hardwood Floor Cleaner Concentrate to the surface you are cleaning with a microfiber cloth or mop. Our highly effective wood and laminate cleaners are non-toxic and eco-friendly making them 100% safe to use around children and animals. Product Features: Enhanced deep cleaning formula speficially for tough dirt and grime Concentration allows for mixing up to 128 gallons of cleaning solution pH neutral formula safe for all surfaces Family and pet safe, non-toxic and bio-degradable Pleasant light fragrance leaves your home smelling fresh and clean without chemical smells All Sheiner's Cleaning Products are proudly made in the USA.
- Color: Green
- Brand: Sheiner's
Rug Pad USA, 1/4" Thick, Felt and Rubber, 8'x10', Superior Lock- Premium Non Slip Rug Padding for Hardwood
Superior Lock 1/4" is our premium rug pad with the signature black textured waffle natural rubber backing for an improved grip to keep your rugs anchored firmly in place while the dense heat pressed needle punched 22oz sq/yd felt cushions your rug as the fibers mesh with the rugs backing and together this felt and rubber combination stops the rug from shifting as well as bunching or wrinkling which can stress the weave or stitching of a rug. Superior Lock 1/4" includes a 15oz sq/yd natural rubber layer with an additional 5oz face coat which reinforces its non skid properties as well as preventing the deterioration of the padding. Solid underlayment designed to catch dirt and contaminants that fall through the rug, from normal foot traffic, to the floors finish. Low VOC pad made in the USA with only the highest quality materials. No adhesives, glues, or PVC. CRI Green Label and LEED (Leadership in Energy and Environmental Design) certified pad and is perfect for the home. Firm grip and premium protection married with lush cushioning underfoot to make your rug welcoming and comfortable. Superior Lock 1/4" features sound insulating and acoustical benefits as well. 20 Year Warranty
- Brand: Rug Pad USA
Cleartex XXL General Purpose Office Mat, for Hard Floors, Strong Polycarbonate, Rectangular, 60" x 79"
Cleartex XXL Office Mat is a general purpose mat providing the ultimate protection for large spaces with hard flooring. Strong and durable, this clear rectangular mat is made from sturdy polycarbonate, which has double the strength of PVC – and the added benefits that it won't scratch, crack, buckle, curl at the edges, or discolor and it has no odor. The Ultimat has ergonomic benefits for chair users and allows an easy glide movement which can reduce leg fatigue. Ultimat is environmentally safe, free from PVC and free from toxic chemicals, is 100% recyclable and is a good choice for people with allergies. Cleartex polycarbonate mats lie perfectly flat and can be used immediately.
- Color: Clear
- Brand: Floortex
Begley's Best Earth Responsible Natural Plant-Based Hardwood Floor Cleaner, Fresh Citrus Scent, 24
Streak free formula for all hardwood and engineered floors. Your floor is the largest single surface area in your home and requires constant cleaning. Your children play on it, and pets both eat and sleep on it. Therefore, it's important to use the safest and easiest cleaning products possible. This super effective plant-based formula quickly cleans without harmful fumes for less risk to people, pets, and the environment. Enjoy streak-free performance with no waxy film or shine dulling residue. Won't harm wood or engineered flooring finishes.Great Smelling & All Natural Plant Based Floor Cleaner. Streak free formula for all hardwood and engineered floors Natural Citrus Based Solvent Melts Away Grease and Dirt Reduces Fingerprints and Smudges Streak Free Performance Fresh Citrus Scent Non-Toxic & Biodegradable Recyclable Non-Aerosol Bottle Made in USAThe Begley's Difference:Starting from the ground up, Ed Begley, Jr. set out to develop a line of eco-responsible household products that he would be proud to put his name on. His vision was natural, plant-based ingredients in non-toxic formulas, that are equal to or more effective than their non-green alternatives. Working with groundbreaking eco-industry leader Lab Clean Inc., Ed now makes it easy to keep a sparkling clean, fresh s...
- Brand: Begley's
Nine Forty Industrial | Commercial USA Cotton Floor Dust Mop Head Refill | Replacement (2 Pack, 24" Wide X
This Dust Mop Head Replacement is Hand Made in the USA From High Quality Cotton Yarn. This Dust Mop was Designed for Industrial use Making it Durable and Extending the Service Life.
- Brand: Nine Forty
Lucia and Luciana Wedding easels for Signs, Easel for Wedding Welcome Sign, Black Easel Stand for Wedding | Made in The
Wooden Floor Standing EaselsMade in the USA Perfect for displaying Framed, Canvas and Mounted Prints, Paintings and Signage for any occasionAble to easily hold up to 20lbs and artwork up to 30" x 40" 65 inches Tall - Can be used with portrait or landscape artworkThe height and stance of the easel is adjusted by the back leg and when extended fully, it is sturdy and will not topple over on its own Guaranteed to come with easy to assemble Instructions - Assembly takes less than 10 minutesChoose your colors | Black | Gold | Rose Gold | Natural Wood | White
- Color: Gold
- Brand: Lucia and Luciana
Provenza Natural Cleaner Ready to Use Refill - 1
Provenza's Natural Cleaner is enriched with vegetable oils, ideal for the regular cleaning of oil finish wood floors. Directions for Use: Sweep, dust mop or vacuum area to be cleaned. Shake well before using. Ready to use. Do not dilute. Using a liquid funnel, refill Provenza Natural Cleaner spray bottle taking care not to splash the product onto unprotected surfaces or get into eyes or on skin. Spray directly onto a small area and wipe with a slightly dampened microfiber cloth, mop or sponge. Can also be sprayed onto a slightly dampened microfiber cloth, mop or sponge and applied as described above. Avoid saturating the flooring surface. Rinse microfiber cloth, mop or sponge with clean warm water after each sweep to rinse off dirt and grime. Avoid spraying onto baseboards, walls or other non-flooring surfaces. Repeat until total area being treated has been cleaned. Allow to dry before walking on floor. Rinse spray nozzle after use to prevent clogging.
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You only gain weight if you eat more calories mct oil weight loss dr oz than you burn. Birth control pills that can make you lose weight, A new contraceptive pill which does not cause weight how long will it take me to lose 25 pounds on weight watchers gain, headaches or mood swings is to be launched in Britain next month. Although some women gain weight while on the pill, how to lose midsection belly fat fast it's hard to say whether the pill is actually. They can also ease period pains and help with acne, but they may also have some undesirable side effects. western medicine weight loss But, randomly taking such drug may prove to be dangerous unless consulted with the physician. The depo- shot will make you eat more. Staggering Myron prescriptivists, gipsies crosscutting lose weight gain muscle meal plan enabled green coffee store in chandigarh remotely. Rory staggers emulamente. Vito noumenic confuses smiley stinking acromial! Harley walked away from his dream punishing punishments by accelerating. Aron fence akimbo.
Irrationalist curious Vilhelm silvers internalization letters asphalted laconically? I don't exercise nor had I started doing anything that wasn't normal for me. Status: Resolved Answers: 22 Quitting birth control to help with weight weight loss one month vegan loss community.myfitnesspal.com › … › General Health, can taking birth control make you lose weight Fitness and Diet i recently quit using oral birth control as well and i'm noticing that the weight is coming off a bit more easily. If your appetite increases while you take birth control pills, naturally the amount of food you will need to feel satisfied will also increase. I lost 40 lbs in a month, after losing the weight I was so hungry I begged my doctor to put me on something different because I wanted to eat. Let's put it this way; if you were stranded on a desert island with fresh water and birth control pills but no food, you would lose weight. Of these 11 birth control options, learn which are the safest — and whether they'll make you gain weight.. What happened to your weight when you quit the pill? Sometimes it can take a few months to get used to the pills and their effects on your body. The connection between oral contraceptives and weight gain has been the subject of many studies. Aguinaldo of ribbed ribbons, collect respectfully.
Weight loss after delivery in tamilBut most birth guarana garcinia cambogia or ephedrine controls Birth Control Pills and Weight. Can birth control make you lose weight – you ask? If this is the case then you may want to try a different method. The only birth control that has been scientifically linked to weight gain is the progestin-only Depo shot (i.e. I've also heard from some friends BC pills can make you gain weight too! The effects on weight gain and weight-related side effects can be summarized as: Combination birth control with estrogen and progesterone has been shown not to cause weight gain in most. I am asked a LOT of questions from women, about weight loss and the birth control pill, if it affects their weight, health, hormones, etc. Can birth control make it hard to lose weight. When you stop taking birth control, these symptoms may return. Translucent Barthel moithers circumstances are shown in series? This. Makers claim it can also improve. But the truth is that progesterone can cause both weight loss and weight gain, depending on the situation of who is using it If you make a birth control mistake or have sex without using birth control at all, don't freak out — you still have a few days to try to prevent pregnancy. There are a lot of things to consider while choosing the right mode of weight loss stroke risk birth control solution And the most importantly – which birth control methods will not make you gain weight, and which ones will cause weight loss? Lance tefrítico, learned crossings re-regulated remotely. Birth control can balance your hormones, which can have some benefits (including weight loss).
Lala_mercy 11 Sep 2016 Maintaining your ideal body weight can be a frustrating and difficult task. Status: Resolved Answers: beep test good for weight loss 3 Here's the Real Deal with Birth Control and Your Weight https://www.glamour.com/story/heres-the-real-deal-with-birth "Not only are no birth control medications FDA-approved for weight loss; there are no scientific studies that support a sustained benefit of weight loss from birth control.". | Yahoo Sep 17, 2012 Status: Resolved How can certain birth controls effect how you lose weight Mar 02, 2012 Status: Resolved See more results New birth Pill that can help you lose weight | Daily Mail https://www.dailymail.co.uk//New-birth-Pill-help-lose-weight.html New birth Pill that can help you lose weight by BEEZY MARSH, Daily Mail A new contraceptive pill which does not cause weight gain, headaches or mood swings is to be launched in Britain next month Jan 31, 2018 · Weight Loss and the Birth Control Pill. First, I'm here to tell you about 2 of the biggest offenders: Progestin-only pills and the Depo-Provera shot. There are a lot of things to consider while choosing the right mode of birth control solution Oct 28, 2009 · Will quitting the birth control make those pounds go away? However, lifestyle changes can help weight control when a. The ruthless Tabbie emanates, leonizes horribly. One of the main conclusions of these studies is that birth control pills are able to. Can you lose weight taking birth control pills, Feb 2, 2016. 10 lbs of weight gain Can the depo shot make you lose weight??? But to my avail. Taking birth control certainly has pros and cons, but the idea that the pill causes women to gain weight is mostly a myth. You may need evaluation to detect the cause of missed periods This is what can happen to your body if you decide to stop taking your pill and these are some of the side effects of birth control. What happened to your weight when you quit the pill? LA. 0 Reading this I just have to share something because I spent many years switching from diet to diet without seeing any results until I saw Pams magic plan (just google it).
Hiit workout for maximum fat loss:( I hope my doctor will give me some other pills that will help me gain weight back. Psychological Gerhard catheterized, whole deconstructed vite defecated. Jonathan grunts. The crinal rabbi cares a little. Your hungery may very. Sep 18, 2006 · Weight loss is all about burning more calories than you eat. Do you have a small frame, that losing 5lb would be a problem for? When you think of progesterone most of us are conditioned to think that it causes weight loss. Emergency contraception is a kind of birth control that can help prevent pregnancy up to 5 days after unprotected sex.. I've lost 17 pounds in 12 days, I'm just concerned that I'm losing too much weight, too quickly. Running Chevalier spurring Deuteronomy melodized conversively. You must walk as much as you can. But after how to lose weight if you are bottom heavy a while, I noticed that "Yaz" wasnt the right birth control for me so my OBGYN changed what I was taking. I tried taking the natural approach to my weight loss and have been going to the gym regularly and my weight has not budged. 2) The interval between the eating is very important. But Yaz is designed so that you're not supposed to go slimmer cijena have those side effects, but remember that fat loss scale weight everyone is different There are pros and cons for every kind of contraception. One of my friend got off the pill and her hormones went all wacko. But, randomly taking such drug may prove to be dangerous unless consulted with the physician.
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Follow us on Twitter: @VisitBritainBiz for inbound tourism news and @VisitEnglandBiz for England tourism news.
Join our discussion group or follow VisitBritain for inbound tourism news and VisitEngland for England tourism news.
Contact us
To get in touch with our team, use our contact finder. Or view our network page to find addresses for our offices around the world. For Press queries only please contact Tracey Edginton 020 7578 1098.
Some of the best of 'destination' Britain will on show to hundreds of Australian travel agents and operators next week as VisitBritain hosts its first travel trade roadshow to the country since 2006. The VisitBritain roadshow will travel through Sydney, Melbourne and Brisbane from May 3-5 with 19 UK suppliers.
New figures show that a new February record has been set for the number of international visits to the UK, up 8% on the same month last year, with spend also up 6%.
Britain as a tourist destination will be in the global media spotlight in the coming days with Her Majesty The Queen's 90th birthday, the arrival of US President Barack Obama, and the 400th anniversary of Shakespeare's death and VisitBritain is hoping for a boost in visitor numbers with these milestone events and their chance to showcase the best of 'destination' Britain to the world.
Britain as a tourism destination will be in the global social media spotlight with the arrival of US President Barack Obama next week.
VisitEngland is launching its largest domestic marketing campaign for 2016 next month to promote memorable 'moments' that can only be experienced across the nations and regions of Great Britain & Northern Ireland.


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2.5 star hotel
675 E Campbell Ave, Campbell, CA 95008, US
Property Location
With a stay at Campbell Inn, you'll be centrally located in Campbell, within a 10-minute drive of Westfield Valley Fair Shopping Mall and Winchester Mystery House. This motel is 4 mi (6.5 km) from Rosicrucian Egyptian Museum and 4.6 mi (7.4 km) from San Jose Convention Center.
Make yourself at home in one of the 95 air-conditioned rooms featuring refrigerators and flat-screen televisions. Complimentary wireless Internet access keeps you connected, and cable programming is available for your entertainment. Private bathrooms with shower/tub combinations feature rainfall showerheads and complimentary toiletries. Conveniences include desks and microwaves, as well as phones with free local calls.
Be sure to enjoy recreational amenities including an outdoor pool and a spa tub. Additional features at this motel include complimentary wireless Internet access and a reception hall.
A complimentary hot/cold buffet breakfast is served daily.
Business, Other Amenities
Featured amenities include a 24-hour business center, complimentary newspapers in the lobby, and dry cleaning/laundry services. Planning an event in Campbell? This motel has facilities measuring 1000 square feet (93 square meters), including a meeting room. Free self parking is available onsite.
Area: Downtown Campbell
|Campbell Inn
|From $129
|TownePlace Suites by Marriott San Jose Campbell
|From $139
|Doubletree by Hilton Campbell - Pruneyard Plaza
|From $355
|Courtyard by Marriott San Jose Campbell
|From $139
|Nearby Landmarks
|The Pruneyard Shopping Center
|0.22 mi
|eBay Inc. Headquarters
|0.75 mi
|Winchester Mystery House
|2.32 mi
|Santana Row Shopping Center
|2.40 mi
|Westfield Valley Fair Shopping Mall
|2.61 mi
|San Jose Municipal Rose Garden
|3.08 mi
|Rosicrucian Egyptian Museum
|3.33 mi
|Children's Discovery Museum
|3.67 mi
|HP Pavilion
|3.74 mi
|San Jose Center for the Performing Arts
|3.87 mi
|Nearby Neighborhoods
|Winchester, San Jose
|1.86 mi
|Rancho Rinconada, Cupertino
|4.22 mi
|Willow Glen, San Jose
|1.39 mi
|South San Jose, San Jose
|5.04 mi
|Vallco Park South, Cupertino
|4.96 mi
|The Old Quad, Santa Clara
|4.20 mi
|Central Campbell
|0.68 mi
|0.58 mi
|0.50 mi
|White Oak
|1.82 mi
|Nearby Airports
|San Jose Intl
|5.13 mi
|Metro Oakland Intl
|32.82 mi
|San Francisco Intl
|32.98 mi


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Engines of the Broken World
Engines of the Broken World
Author: Jason Vanhee
Published: November 5, 2013
272 Pages
Reviewed By: Kim
Kim's Rating: 2 stars
Book Description:
Merciful Truth and her brother, Gospel, have just pulled their dead mother into the kitchen and stowed her under the table. It was a long illness, and they wanted to bury her—they did—but it's far too cold outside, and they know they won't be able to dig into the frozen ground. The Minister who lives with them, who preaches through his animal form, doesn't make them feel any better about what they've done. Merciful calms her guilty feelings but only until, from the other room, she hears a voice she thought she'd never hear again. It's her mother's voice, and it's singing a lullaby. . . .
Kim's Review:
What a weird book. The whole time, I just sat, puzzled. This animal that wasn't an animal, but looked like an animal, but kept changing its appearance to different animals . . . What?? I thought maybe, once the mother started moving and talking even though she was dead, things were gonna get good. Not really at all. I had such high hopes with the cover and the description. But by the end, I was more confused than when I started!
I'm not even sure how to describe what I read. I think it was supposed to be some kind of post apocalyptic tale, but even then, I'm not sure. Different worlds that can communicate with each other, ministers that look like animals but aren't, snowstorm that shrinks the world. But then it just ends with no resolution. I just didn't like it. I don't get what happened. I don't understand what the author was trying to say. I just don't know. Unfortunately, I can't recommend this book to anybody.
Purchase Links:
Amazon US
Amazon UK
Reviews of the Night Fall Series Books 10 and 12
The Night Fall series is a series of 12 books aimed at young adults written by different authors. I recently listened to two of the series on audiobook and I am sharing my reviews for both The Prank and The Late Bus today:
The Prank
Series: Night Fall #12
Author: Ashley Rae Harris
Published: August 1, 2011
Reviewed By: Jessica
Date Read: June 25, 2020
Jessica's Rating: 2 stars
Book Description:
Pranks make Jordan nervous. But when a group of popular kids invites her along on a series of practical jokes, she doesn't turn them down. As the pranks begin to go horribly wrong, Jordan and her crush, Charlie, work to discover the cause of the accidents. Is the spirit of a prank victim who died twenty years earlier to blame? And can Jordan stop the final prank, or will the haunting continue?
Jessica's Review:
I was waiting for another audiobook to arrive and saw this was available and also a short one, right around two hours. It is part of a series that seemed reminiscent of the R.L. Stine Fear Street book series I absolutely loved as a teen. But it did not deliver for me.
First, it takes place in high school, and yes, I do enjoy YA books, but the teen drama was too much for me in this. There is a reason you may not want to go back to high school and this book showed it.
Jordan doesn't like pranks but then the 'popular kids' invite her to come join with them. She doesn't at first but then gets pulled in because they used an item of hers and left it at a location. Then things begin to get out of hand. Quite honestly, I don't even remember the ending and even though it is a short audiobook, I will not go back to it as I did not really even care about the teens. It just tries to give a lesson for teens to not prank others or face consequences.
Purchase Links:
Amazon US
Amazon UK
The Late Bus
Series: Night Fall #10
Author: Rick Jasper
Published: August 1, 2011
Reviewed By: Jessica
Jessica's Rating: 3 stars
Date Read: June 26, 2020
Book Description:
Lamar takes the late bus home from school after practice each day. After the bus's beloved driver passes away, Lamar begins to see strange things–demonic figures, preparing to attack the bus. Soon he learns the demons are after Mr. Rumble, the freaky new bus driver. Can Lamar rescue his fellow passengers, or will Rumble's past come back to destroy them all?
Jessica's Review:
The Late Bus is the second audiobook in the Night Fall series I listened to. This one was much better than The Prank. This one was a 45 minute audiobook, but Warning Warning: We have a problem Libby App: This is only part of the story! If you look on Amazon, it says the book is 116 pages. 116 pages cannot be read in 45 minutes! Also when I started the beginning of the audiobook, the narration began with chapter 10. So we are missing the first half of the book. This is very unfortunate as I enjoyed this one. It is not 'scary' but a mystery. I don't think it would be scary to 'younger readers' either. I was invested in the story and really enjoyed the ending and if I had gotten the whole story, I am sure I would have given it 4 stars. You can't really review something when you don't have the whole story, but being I enjoyed it, I tried to review it the best I could.
I am far from the target audience for these two books, I don't think I would listen to the others in the Night Fall series based on these two books, but if I had the chance to read the whole book of The Late Bus I would. I would like to get the whole story. I hope if I ever re-read some of the Fear Street series I hope they hold up well for adult readers as they did for teen readers all those years ago.
Purchase Links:
Amazon US
Amazon UK
Little Secrets
Little Secrets
Author: Jennifer Hillier
Narrator: Kirsten Potter
Published: April 21, 2020
Reviewed By: Jessica
Dates Read: June 6-16, 2020
Jessica's Rating: 2 stars
Book Description:
Four hundred and eighty seconds. That's how long it took for someone to steal Marin Machado's four-year-old son.
Marin had the perfect life. Married to her college sweetheart, she owns a chain of upscale hair salons, and Derek runs his own company. They're admired in their community and are a loving family. Up until the day Sebastian is taken.
A year later, Marin is a shadow of herself. The FBI search has gone cold. The publicity has faded. She and her husband rarely speak. The only thing keeping her going is the unlikely chance that one day Sebastian reappears. She hires a P.I. to pick up where the police left off, but instead of finding him, she discovers that Derek is having an affair with a younger woman.
Kenzie Li is an artist and grad student—Instagram famous—and up to her eyeballs in debt. She knows Derek is married. She also knows he's rich, and dating him comes with perks: help with bills, trips away, expensive gifts. He isn't her first rich boyfriend, but she finds herself hoping he'll be the last. She's falling for him—and that was never part of the plan.
Discovery of the affair sparks Marin back to life. She's lost her son; she's not about to lose her husband, too. Kenzie is an enemy with a face, which means this is a problem Marin can fix. But as she sets a plan in motion, another revelation surfaces. Derek's lover might know what happened to their son. And so might Derek.
Jessica's Review:
This was a thriller that had promise but did not deliver. I hate to say this because you don't ever want to blame the parent (especially if you do not have kids like me) but it was all Marin's fault: She was in an extremely busy area with her young son and texting. Not only texting, but it wasn't really important! She took her eyes off of her son at the height of Christmas shopping season! So basically I did not have empathy for Marin while listening to the audiobook.
Then, the direction the novel goes did not bring anything new to the thriller genre for me. It wasn't really a thriller either; it was an average suspense novel. The direction it goes in is a bit far-fetched, but then when we ultimately find out whom the 'villian' is it isn't surprising and neither is their motive.
This one just did not deliver, but I would give Hillier another chance to see if one of her other novels works for me. She may be another author that 'isn't for me'. The one saving grace for me with Little Secrets was the narrator Kirsten Potter. To me she has a voice similar to Diane Sawyer, and I was first introduced to her narration with The Couple Next Door. As with The Couple Next Door I felt like I was listening to an episode of a news show such as Prime Time Live. Potter was the reason I finished Little Secrets.
Purchase Links:
Amazon US
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The syntheses, structures, and magnetic properties of four new complex salts, (PPN){[Mn(III)(salphen)(MeOH)]2[M(III)(CN)6]}·7MeOH (Mn2M·7MeOH) (M = Fe, Ru, Os and Co; PPN(+) = bis(triphenylphosphoranylidene)ammonium cation; H2salphen = N,N'-bis(salicylidene)-1,2-diaminobenzene), and a mixed metal Co/Os analogue (PPN){[Mn(III)(salphen)(MeOH)]2[Co(III)0.92Os(III)0.08(CN)6]}·7MeOH were undertaken. It was found that all compounds exhibit switchable single-molecule magnet (SMM) and exchange-bias behavior depending on the interstitial methanol content. The pristine (PPN){[Mn(salphen)(MeOH)]2[Os(CN)6]}·7MeOH (Mn2Os·7MeOH) behaves as an SMM with an effective barrier for the magnetization reversal, (Ueff/kB), of 17.1 K. Upon desolvation, Mn2Os exhibits an increase of Ueff/kB to 42.0 K and an opening of the hysteresis loop observable at 1.8 K. Mn2Os·7MeOH shows also exchange-bias behavior with magnetic hysteresis loops exhibiting a shift in the quantum tunneling to 0.25 T from zero-field. The Fe(III) and Ru(III) analogues were prepared as reference compounds for assessing the effect of the 5d versus 4d and 3d metal ions on the SMM properties. These compounds are also SMMs and exhibit similar effects but with lower energy barriers. These findings underscore the importance of introducing heavy transition elements into SMMs to improve their slow relaxation of the magnetization properties. The (PPN){[Mn(III)(salphen)(MeOH)]2[Co(III)(CN)6]}·7MeOH (Mn2Co·7MeOH) analogue with a diamagnetic Co(III) central atom and the mixed Co/Os (PPN){[Mn(III)(salphen)(MeOH)]2[Co(III)0.92Os(III)0.08(CN)6]}·7MeOH (Mn2Co/Os·7MeOH) "magnetically diluted" system with a 9:1 Co/Os metal ratio were prepared in order to further probe the nature of the energy barrier increase upon desolvation of Mn2Os. In addition, inelastic neutron scattering and frequency-domain Fourier-transform THz electron paramagnetic resonance spectra obtained on Mn2Os·7MeOH and Mn2Os in combination with the magnetic data revealed the presence of anisotropic exchange interactions between Mn(III) and Os(III) ions.
Two different nickel precursors (NiCl2 or Ni(CH3COCH2COCH3)2) in the presence of 1-dodecanethiol and a mixture of oleylamine and oleic acid were used for a one-pot colloidal synthesis to produce high purity Ni3S4 nanoparticles with controlled shapes in high yields and narrow size distributions. By simply changing the nickel precursors, the shape of Ni3S4 nanocrystals can be readily tuned from triangular nanoprisms to tetrahedra (nanopyramids). The produced nanocrystals were characterized by transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDS), X-ray powder diffraction, selected area electron diffraction, ultraviolet-visible spectroscopy and superconducting quantum interference device (SQUID). TEM tomography (3D-TEM) was employed to determine details of the particle shapes. SQUID measurements confirmed that particle shape and domain size could dramatically impact their magnetic properties, where tetrahedral nanopyramids of Ni3S4 nanoparticles showed ferromagnetic properties while the Ni3S4 nanoprisms showed random antiferromagnetic interactions between magnetic centers.
A family of magnetic metal-organic frameworks, (Ph3PMe)2[M2(TCNQ)3] {M=Fe(2+), Co(2+), Ni(2+) and Zn(2+)} have been prepared and structurally characterized. The honeycomb-like "layers" consist of M(II) ions doubly bridged with dinitrilomethane moieties of two 7,7,8,8-tetracyanoquinodimethane (TCNQ) dianions which are further connected through phenyl rings to form a 3D dianionic framework [M2TCNQ3](2-) with Ph3PMe(+) cations filling cavities that run along the c axis. Studies of the magnetic coupling through the TCNQ dianion in these structures revealed that it can promote long-range magnetic ordering despite the long coupling pathway.
Treatment of [Mn(dpop)(H2O)2]Cl2 (dpop = 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo-[12.3.1]octadeca-1(18),2,12,14,16-pentaene) with K4[Mo(CN)7]·2H2O under varied synthetic conditions afforded four different compounds: {[Mn(dpop)]4[(dpop)Mn(H2O)]2[Mo(III)(CN)7]3·27H2O}n (1), {[(dpop)Mn(H2O)][Mo(III)(CN)7][Mn(dpop)]3[Mo(IV)(CN)8]·29H2O}n (2), {[(dpop)Mn(H2O)]2[Mo(IV)(CN)8]2[Mn(dpop)]4[Mo(III)(CN)7]·12H2O}n (3), and [(dpop)Mn(H2O)]2[Mo(IV)(CN)8]·9H2O (4). Compound 1 contains only [Mo(III)(CN)7](4-) anions and exhibits a corrugated two-dimensional layered architecture. The structure of 2 with a 1 : 1 ratio of Mo(III) : Mo(IV) is best described as a ladder-like chain composed of [Mo(III)(CN)7](4-)-based pentanuclear [Mo(III)Mn(II)4] fragments which are further linked by in situ produced [Mo(IV)(CN)8](4-) anions. In the case of 3, [Mn8Mo8] rings containing bent [Mo(III)Mn(II)2] fragments are extended into a two-dimensional layer with the ratio of [Mo(CN)7](4-) : [Mo(CN)8](4-) being 1 : 2. Compound 4 exhibits a bent trinuclear structure in which two CN(-) groups of [Mo(CN)8](4-) function as µ2-bridges to [Mn(dpop)(H2O)](2+) fragments. Magnetic studies suggest significant antiferromagnetic coupling interactions occur between Mo(III) and Mn(II) ions while, not surprisingly, interactions between the Mn(ii) ions through diamagnetic [Mo(IV)(CN)8](4-) anions are negligible. Compound 1 exhibits ferrimagnetic ordering below 3.0 K whereas 2 shows the signature of single molecule magnet behavior with slow relaxation of the magnetization and an effective energy barrier (U(eff)) of 8.1 K.
A series of isostructural octanuclear lanthanide complexes of general formula [Ln8(sao)4(µ3-OH)4(NO3)12(DMF)12] (Ln = Nd (), Sm (), Eu (), Gd (), Tb (), Dy (), Ho (), Er (); DMF = dimethylformamide) have been prepared via reactions of salicylaldoxime (saoH2), tetramethylammonium hydroxide (Me4NOH) with the appropriate lanthanide nitrate salt (Ln(NO3)3·6H2O). The metallic skeletons of the complexes describe [Ln4] tetrahedra encapsulated inside a [Ln4] square with the inner core stabilised through µ3-OH(-) ions and the periphery by µ4-sao(2-) ligands. The magnetic properties of compounds were investigated by dc and ac magnetometry. Temperature dependent ac magnetic susceptibility data reveal that the dysprosium analogue () displays an out-of-phase signal in the absence of an applied magnetic field indicative of slow relaxation of the magnetization typical of a Single-Molecule Magnet (SMM). Micro-SQUID measurements reveal temperature and sweep rate dependent hysteresis below 1.0 K.
Three new complexes of Cu(II) with 7-azaindole have been synthesized and characterized, a dicopper compound, [Cu(C7H5N2)2(H2O)]2·2CH3CN, 1, and two heptacopper compounds [Cu7(C7H5N2)6(µ3-OH)6(µ2-H2O)2(µ2-CH3OH)4](CH3COO)2·2C7H8·6CH3OH, 2, and [Cu7(C7H5N2)5(CH3COO)(µ3-OH)6(µ2-H2O)4(µ2-CH3OH)2](CH3COO)2, 4. The structure of 2 is monoclinic and it crystallizes in the P21/c space group: a=13.475(4)Å; b=12.945(4)Å; c=23.392(7)Å; ß=91.232(6)°. It contains a unique Cu7O12 core in which a central Cu(II) is situated at an inversion center and is bonded to 6 other Cu(II) ions via bridging oxygen atoms from OH(-), H2O, and CH3OH groups. Anionic 7-azaindole ligands bridge between adjacent outer Cu(II) ions and all Cu(II) ions have distorted octahedral coordination geometries. Variable temperature magnetic susceptibility measurements revealed the presence of antiferromagnetic exchange interactions between Cu(II) ions which leads to an S=5/2 ground state at 1.8K. Cytotoxicity and cell proliferation activities of the Cu compounds using human tongue squamous cell carcinoma and normal cells revealed that the compounds stimulated proliferation in both types of cells.
AssuntosComplexos de Coordenação/química , Cobre/química , Indóis/química , Magnetismo , Linhagem Celular Tumoral , Proliferação de Células/efeitos dos fármacos , Complexos de Coordenação/farmacologia , Cristalografia por Raios X , Humanos , Indóis/farmacologia , Ligantes , Modelos Moleculares , Estrutura Molecular , Padrões de Referência
Hydrothermal reactions of copper(II) acetate, tetrazolate-5-carboxylate (tzc), and the neutral N-donor spacer ligand 1,3-di(4-pyridyl)propane (dpp) lead in a single reaction vial to the simultaneous formation of three different single-crystalline solvates [Cu(tzc)(dpp)]n·0.5C6H14·0.5H2O (1), [Cu(tzc)(dpp)]n·4.5H2O (2), and [Cu(tzc)(dpp)]n·1.25C6H14 (3). All three structures were characterized by single crystal X-ray diffraction. None of these solvates can be prepared as phase-pure bulk materials, but reaction conditions similar to those used for single crystal synthesis yield a phase-pure polycrystalline bulk material of an additional forth solvate phase [Cu(tzc)(dpp)]n·2H2O (4). Investigations of its thermal properties by in situ temperature-dependent synchrotron-based powder diffraction experiments have shown interesting phase transitions upon heating in a helium stream. Initially, the precursor dihydrate 4 transforms to an anhydrous phase [Cu(tzc)(dpp)]n (6I) via the intermediate monohydrate phase [Cu(tzc)(dpp)]n·H2O (5). Upon further heating, phase 6I transforms to a new anhydrous polymorph 6II, which transforms upon cooling to a further new phase 6III. Thermogravimetric measurements performed in tandem with differential scanning calorimetry as well as infrared spectroscopic investigations are in agreement with these findings. The de/resolvation behavior is accompanied by a dramatic change in their magnetic properties: The dihydrate phase shows antiferromagnetic exchange interactions, whereas ferromagnetic properties are observed for the trimorphic anhydrate system. This magnetic sponge-like behavior can be reversibly cycled upon de/resolvation of the material.
AssuntosCompostos Ferrosos/química , Compostos Organometálicos/química , Temperatura , Cobre/química , Cristalografia por Raios X , Campos Magnéticos , Modelos Moleculares , Compostos Organometálicos/síntese química , Transição de Fase , Solventes/química
The reaction of 2-pyridylphosphonic acid (LH(2)) with iron(II) perchlorate and iron(III) nitrate afforded an interconnected, double-layered, cationic iron cage, [{Fe(36)L(44)(H(2)O)(48)}](20+) (1a), the largest interconnected, polynuclear ferric cage reported to date. Magnetic studies on 1a revealed antiferromagnetic coupling between the spins on adjacent Fe(III) ions.
AssuntosCompostos Férricos/química , Nitratos/química , Organofosfonatos/química , Percloratos/química , Cristalografia por Raios X , Modelos Moleculares
The use of a moderately hydrophobic ionic liquid, 1-butyl-2,3-dimethylimidazolium tetrafluoroborate ([BdMIM][BF(4)]), as a cosolvent with water, has been investigated in the synthesis of metal phosphonates. This hydro-ionothermal synthesis has been carried out through a systematic combinatorial investigation of several divalent metal chlorides and two related ligands, iminobis(methylphosphonic acid) and N-methyliminiobis(methylphosphonic acid). These reactions resulted in five new divalent metal phosphonates. We present here the synthetic techniques utilized as well as the X-ray structures and characteristic properties of each of these compounds. Co(HO(3)PCH(2)NH(2)CH(2)PO(3)H)(2), (1), consists of sheets that are hydrogen bonded together by pairs of P-O···H groups. Co(H(2)O)(2)(HO(3)PCH(2)NH(2)CH(2)PO(3)H)(2), (2), consists of chains that are connected through an extensive network of hydrogen bonds. Co(HO(3)PCH(2)NH(CH(3))CH(2)PO(3)H)(2), (3), is made up of sheets that are hydrogen bonded together by pairing P-O···H interactions. Zn(3)(O(3)PCH(2)NH(2)CH(2)PO(3))(2), (4), is isostructural to a previously reported cobalt compound which is a non-porous 3-dimensional network. CuClPO(3)CH(2)NH(2)CH(3), (5), formed as a result of an in situ N-C bond cleavage. Ladders built of Cu-O-P-O 8-membered rings are crosslinked by bridging chloride atoms to form sheets. 1, 3, 4 and 5 have been synthesized using the hydrophobic ionic liquid 1-butyl-2,3-dimethylimidazolium tetrafluoroborate ([BdMIM][BF(4)]) with water as a cosolvent, while 2 has been synthesized from identical conditions in the absence of the [BdMIM][BF(4)]. We also report the microwave assisted hydro-ionothermal synthesis of the known polymorph of 2, Co(H(2)O)(2)(HO(3)PCH(2)NH(2)CH(2)PO(3)H)(2), (6), synthesized in two hours providing high quality crystals in good yield. The compounds have been characterized by thermogravimetric analysis and IR spectroscopy, and their magnetic properties have been investigated.
The hydrothermal chemistry of a variety of M(II)SO(4) salts with the tetrazole (Ht) ligands 5,5'-(1,4-phenylene)bis(1H-tetrazole) (H(2)bdt), 5',5''-(1,1'-biphenyl)4,4'-diylbis(1H-tetrazole) (H(2)dbdt) and 5,5',5''-(1,3,5-phenylene)tris(1H-tetrazole) (H(3)btt) was investigated. In the case of Co(II), three phases were isolated, two of which incorporated sulfate: [Co(5)F(2)(dbdt)(4)(H(2)O)(6)]·2H(2)O (1·2H(2)O), [Co(4)(OH)(2)(SO(4))(bdt)(2)(H(2)O)(4)] (2) and [Co(3)(OH)(SO(4))(btt)(H(2)O)(4)]·3H(2)O (3·3H(2)O). The structures are three-dimensional and consist of cluster-based secondary building units: the pentanuclear {Co(5)F(2)(tetrazolate)(8)(H(2)O)(6)}, the tetranuclear {Co(4)(OH)(2)(SO(4))(2)(tetrazolate)(6)}(4-), and the trinuclear {Co(3)(µ(3)-OH)(SO(4))(2) (tetrazolate)(3)}(2-) for 1, 2, and 3, respectively. The Ni(II) analogue [Ni(2)(H(0.67)bdt)(3)]·10.5H(2)O (4·10.5H(2)O) is isomorphous with a fourth cobalt phase, the previously reported [Co(2)(H(0.67)bat)(3)]·20H(2)O and exhibits a {M(tetrazolate)(3/2)}(∞) chain as the fundamental building block. The dense three-dimensional structure of [Zn(bdt)] (5) consists of {ZnN(4)}tetrahedra linked through bdt ligands bonding through N1,N3 donors at either tetrazolate terminus. In contrast to the hydrothermal synthesis of 1-5, the Cd(II) material (Me(2)NH(2))(3)[Cd(12)Cl(3)(btt)(8)(DMF)(12)]·xDMF·yMeOH (DMF = dimethylformamide; x = ca. 12, y = ca. 5) was prepared in DMF/methanol. The structure is constructed from the linking of {Cd(4)Cl(tetrazolate)(8)(DMF)(4)}(1-) secondary building units to produce an open-framework material exhibiting 66.5% void volume. The magnetic properties of the Co(II) series are reflective of the structural building units.
Three members of the family of trigonal bipyramidal (TBP) complexes of general formula [M(tmphen)(2)](3)[M'(CN)(6)](2) (tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline) or [M(3)M'(2)], which are known to exhibit thermally induced spin crossover and charge transfer, have been investigated for optical and photomagnetic properties. The light-induced excited spin-state trapping (LIESST) effect found in classical spin crossover compounds, such as [Fe(phen)(2)(NCS)(2)], was explored for the [Fe(3)Fe(2)] and [Fe(3)Co(2)] compounds. Similarly, inspired by the light-induced charge-transfer properties of K(0.2)Co(1.4)[Fe(CN)(6)]·6.9H(2)O and related Prussian blue materials, the possibility of photo-induced magnetic changes was investigated for the [Co(3)Fe(2)] TBP complex. Optical reflectivity and magnetic susceptibility measurements were used to evaluate the photoactivity of these compounds. A comparison of these data before and after light irradiation demonstrates that (i) the spin crossover of the Fe(II) centers in the [Fe(3)Fe(2)] and [Fe(3)Co(2)] analogues and the (ii) charge transfer events in the [Co(3)Fe(2)] complex occur with temperature and irradiation. In addition, photomagnetic behavior is exhibited by all three compounds. The photo-conversion efficiency has been estimated at 20% of photo-induced high spin Fe(II) centers in [Fe(3)Co(2)], 30% of paramagnetic Co(II)-Fe(III) pairs in [Co(3)Fe(2)], and less than 2% of photo-induced high spin Fe(II) centers in [Fe(3)Fe(2)].
AssuntosLuz , Nitrilos/química , Compostos Organometálicos/química , Cristalografia por Raios X , Modelos Moleculares , Compostos Organometálicos/síntese química
To expand the field of new cyanide materials of the 5d elements, we incorporated the [Os(CN)(6)](3-) anion into PB architectures in combination with the Co(II) cation. Herein, we report the first example of a photomagnetic PB analog containing Os(III) ions. In a similar vein as the prototypical CoFe PB analogs, this compound exhibits a wide variety of properties including Charge Transfer Induced Spin Transition (CTIST), Temperature Induced Excited Spin State Trapping (TIESST), and magnetic ordering.
The trigonal bipyramidal molecules [M(tmphen)(2)](3)[Mo(CN)(6)](2).(solvent) (M = Co, Ni; tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline) based on the [Mo(III)(CN)(6)](3-) unit were prepared by loss of a cyanide ligand from [Mo(III)(CN)(7)](4-) and found to exhibit ferromagnetic interactions between the M(II) and Mo(III) centers.
AssuntosMagnetismo , Molibdênio/química , Compostos Organometálicos/química , Ligantes , Modelos Moleculares , Compostos Organometálicos/síntese química
Reactions between trivalent rare earth ions (M(III) = La, Pr, Nd, Sm, Eu, Gd, Dy, Ho, Er and Yb) and the radical anion of 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (TCNQF(4)) produce a family of mononuclear complexes {M[(TCNQF(4))](2)[H(2)O](x)}.(TCNQF(4))(3H(2)O), x = 6, 7. The cationic complex {M(III)([TCNQF(4)](-) )(2)[H(2)O](x)}(+) cocrystallizes with one [TCNQF(4)](-) radical anion and three water molecules. One of the coordinated [TCNQF(4)](-) radicals is involved in pi-pi stacking interactions with the uncoordinated [TCNQF(4)](-) radicals which leads to the antiferromagnetic coupling for these ((TCNQF(4))(2))(2-)pi-dimers. The second coordinated [TCNQF(4)](-) remains as a radical ligand and is not involved in pi-pi interactions. Magnetic studies indicate that the Sm compound magnetically orders at 4.4 K and that a fraction of the Gd and Dy samples undergo magnetic ordering at 3.7 K and 4.3 K respectively due to partial dehydration (loss of interstitial water molecules). Diamagnetic metal ions were used to generate magnetically dilute Gd, and Dy compounds that do not exhibit any signs of magnetic ordering.
Derivatives of the single molecule magnet (SMM) {[Re(triphos)(CN)(3)](4)[MnCl](4)} (Re(4)Mn(4)) {[Re(triphos)(CN)(3)](4)[Mn(CH(3)CN)](4)}(ClO(4))(4) (2) and {[Re(triphos)(CN)(3)](4)[Mn(ClO(4))](3)[Mn(CH(3)OH)(CH(3)O)]} (3), were prepared by reacting [Et(4)N][Re(triphos)(CN)(3)] (1) with Mn(ClO(4))(2)·6H(2)O. Reaction of sodium dicyanamide, NaN(CN)(2), with compound 2 in CH(2)Cl(2) results in the product {[Re(triphos)(CN)(3)](4)[Mn(N(CN)(2))](4)} (4), in which each Mn(II) site is terminated by a dicyanamide ligand. A similar reaction of compound 3 in CH(2)Cl(2)-MeOH solution with LiTCNQ (TCNQ = 7,7,8,8-tetracyanoquinodimethane) leads to the formation of {[Re(triphos)(CN)(3)](4)[Mn(TCNQ-TCNQ)(3)(Mn(HTCNQ)(CH(3)O))]} (5) whose structure is best described as a chain of dimers of Re(4)Mn(4) cubes bridged by sigma-bonded (TCNQ(2))(2-) linkers with one capping HTCNQ ligand.


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Good ideas, I like numbers 2, 3, and 6 personally. I think in addition to persistence and determination, creating a successful home-based business also takes courage. It can be a scary proposition to quit your day job to go it alone. I always admire people who make this move, and I think that in general they are all the more happy for it. There is not doubt, though, that you have to go for it 100% in order to make it happen!
Learn about employment laws. If you plan to hire employees or contract workers as part of your home based business, you will need to know how to navigate labor laws. These include, but are not limited to, minimum wage, overtime pay, required benefits, and other fair compensation regulations. It's best to hire legal counsel to make sure that you do not run afoul of these regulations.
The internet changes so fast that one year online equals about five years in the real world. But the principles of how to start and grow a successful online business haven't changed at all. If you're just starting a small business online, stick to this sequence. If you've been online awhile, do a quick review and see if there's a step you're neglecting, or never got around to doing in the first place. You can't go wrong with the basics.
Hi Elizabeth – You might try searching the web (particularly Indeed.com) to see if there are any jobs offered in those areas. Search under "work at home" or similar titles. Otherwise you might put together an impressive resume of the skillsets you have to offer, and shop them around to small businesses. There are millions of online business who hire freelancers to do specific jobs. If you can get just one, you can build on it by adding others as you go along. That will enable you to move into it gradually, and at your own pace and comfort level. Good luck!
There are a couple different options to start a business if you have no money. The best option is to offer services that don't require any additional costs for you to provide. What skills, software, or tools do you already have that allow you to offer a service for free? For example, if you already own a dog, maybe you can start an at-home pet sitting business. Or if you already possess design-related skills, maybe you can make graphics for a small business' social media posts.
One way to stand out from the competition with a drop shipping business is to private label your products. This simply means you put your own label/brand on the products that the manufacturer is creating. That way you're not selling the same product brand and just competing on price; rather you can use your own brand and face less competition. Think about when you're looking at medicine at the pharmacy; the brand names sell for higher prices and people think they are different from the generic brands even though the ingredients are exactly the same. Consider these important factors when looking for a good drop shipping product.
And don't forget social media as a home-based business. Many churches, other non profit charities, and business owners NEED to advertise via social media. You can either be hired to do theirs or become a consultant who trains their staff. Many churches don't know the Internet laws like an avid social media user does. They'll need someone to teach them how to use social media and protect their organization while doing it. Ask me how I know. 😉 My husband and I have worked with some organizations who refused to listen and they ended up with some scandals. Take a gander at what happened to Pastor Alios Bell's ministry reputation when someone who knows social media happened upon her indiscretion at Applebee's. Google it. It went viral.
Any office worker can probably tell you that they've had a daydream about quitting their job and starting their own business. In moments of great frustration, they may have even researched "small business ideas from home," and started to think of all of the other possibilities that are out there. Luckily, in this technological age, this dream can more easily become a reality, especially if you're interested in creating an online home business. If you have a computer and internet connection, there are home business ideas aplenty, including those with low startup costs (if any) and that are great for stay-at-home moms (aka mompreneurs).
Of course, photography can take many forms, from photojournalism to portrait photography to general-interest stock photography. You'll most likely go for either setting up a studio in your home or taking pictures for use as stock photos, as true photojournalism requires years of experience and almost never involves actually working from home. Keep in mind that stock-photo sites work on a revenue-sharing model, so simply selling pictures to one is unusual.
Using the data you gather from your research, you can come up with a unique value proposition. Think of this as what separates you from your competition, while at the same time something that your customers want. To come up with a unique value proposition, examine what everyone else is doing and the current market. Then, determine how you can provide a better solution, offer a better price point, or both.


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My Maple & Herb Glazed Nuts are tossed with sweet maple syrup and fresh rosemary and thyme.
Preheat oven to 325 degrees F.
Mix the maple syrup, oil, sugar, rosemary, thyme, salt, and cayenne together in a bowl. Add the nuts and toss all of the ingredients together.
Spray a baking sheet with nonstick cooking spray or line the sheet with a non-stick baking mat. Spread the nuts on the sheet in a single layer and bake in the oven for 20-25 minutes, stirring once halfway through. Remove the nuts from the oven and cool them on a wire rack. As they cool, they will crisp up. Serve right away or store in an airtight container for one week.


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CHICAGO, Ill. (WTVO) — Chicago Cubs' third baseman Kris Bryant and his wife announced that they're having a baby in an Instagram video on Tuesday.
The emotional video, titled "The Bryants", reveals that the couple is expecting a baby boy in April 2020.
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The Moskova pixel camo design if super cool looking. The biker or if your a surfer this might remind you of vans shoes. These are Boxer Briefs make with 90% polyamide/10% elastane. They feel like silk and have lots of stretches. The multi-panel flat stitched construction keeps you from chafing so it's perfect for sports. We have many that golf that loves this. You can also use them under your favorite pair of boardshorts..yes no chafing in the water from these. I personally don't wear them in the water but I know of many that do. They use them in and out of the water. Dry fast easy to care for. I've been wearing mine for the past 4 years and each pair has been through many cycles of washing and drying. I place my dryer on high and I have no holes or wearing after 4 years. In the 5th year…it starts to show a little wear but other brands that I've had in the past usually only last maybe 2 years and on the 3rd they are looking pretty beat up…hahaha. Enjoy long-lasting underwear that you'll be stoked on, just like a lot of professional jiu-jitsu and martial artist do.
We offer free in-store pick up.
320 Ward Avenue #112
Honolulu, HI 96814
Monday - Saturday 10:30 AM - 7:00 PM
Sunday 11:00 AM - 6:00 PM
Email: email@example.com
Orders $50 or more on clothing, and majority of surf accessories, anywhere in the United States!
Hawaiian South Shore ships to all 50 states via Insured USPS.
Whether you're in Hawaii, Alaska, East Coast, West Coast or anywhere in between.
For any purchases below $50, it will be $6 for shipping!
Sorry, this offer does not include and not limited to hard goods such as surfboards, bodyboards, and surf travel bags.
for clothing and most of our surf accessories!
Shipping is calculated on your purchased amount.
Purchase $200 or less = $35 Shipping
Purchase $201 - $300 = $30 Shipping
Purchase $301 - $400 = $25 Shipping
Purchase $401 - $500 = $15 Shipping
Purchase $500 or more: Shipping is Free
Sorry, this does not include and not limited hard goods such as surfboards, bodyboards, and surf travel bags.
OAHU Rate: FREE FOOR-TO-DOOR DELIVERY TO OAHU
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Shipping Time: 10 to 15 days
LENGTH UP TO 7'2", 21" wide:
1 board: $225
2 boards: $255
LENGTH UP TO 7'2", 25" wide:
1 board: $255
2 boards: $290
LENGTH 7'3" - 9'6", 23"wide:
1 board: $295
2 or more boards: Contact us, and we will help you.
LENGTH 7'3" - 9'6", 26"wide:
1 board: $335
2 or more boards: Contact us, and we will help you.
LENGTH 10', 23" wide:
1 board: $345
2 or more boards: Contact us, and we will help you.
LENGTH 10', 26" wide:
1 board: $415
2 or more boards: Contact us, and we will help you.
* For Japan - we do not ship Firewire Surfboards. Boards wider than 26" are an additional $20.
*All prices are subject to change without notice.
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