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Thermodynamic Evaluation of Nano-Particle Binary Alloy Phase Diagrams

Abstract Nano-particle binary alloy phase diagrams have been evaluated from the information on the Gibbs energy and the surface tension of the bulk size on the basis of the regular solution model. As the size of the particle decreases, the liquidphase region is enlarged in those binary phase diagrams, in other words, the liquidus temperature decreases. Effect of the size of the particle on the phase equilibria is remarkable when the excess Gibbs energy is positive and its absolute value is large in solid and liquid phases.