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Loading dependent diffusion studies on aromatic hydrocarbons adsorbed in MOF-5 via PFG NMR

1. Introduction This study focuses on one of the promising metal-organic frameworks, the MOF-5 (also abbreviated: IRMOF-1), which is builT of zinc oxide clusters as metal coordination centers and terephtalic acid as organic linkers [1]. For realization of the prospective applications, knowledge about mobility of aromatic hydrocarbons adsorbed in MOF-5 is necessary. For this reason the self-diffusion coefficients of aromatic hydrocarbons in MOF-5 are studied via pulseD field gradient (PFG) NMR and compared with molecular dynamic simulations.