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Thermodynamic Study of Al-Ge-Sn Ternary Alloys by E.M.F. Measurements

Abstract An electrode potential study of liquid Al-Ge-Sn alloys has been conducted with the cell Al | Al3+ in KCl + LiCl | Al in Al-Ge-Sn in the temperature range 683 K ≦ T ≦ 1273 K. Aluminium partial mixing functions were determined for alloys. These measurements allow us to give the surface corresponding to aluminium partial free energy at 1273 K and the liquidus surface of the Al-Ge-Sn phase diagram.