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Studies on a new composites material polyanilinezirconium(IV) tungstophosphate: a thorium(IV) selective cation exchanger

A new composite ion exchanger polyanilinezirconium(IV) tungstophosphate has been synthesized with the precipitation of zirconium tungstophosphate gel followed by polymerization of aniline in the presence of ammonium persulfate (APS). Its ion exchange capacities, ESCA, TGA, DTA, IR, X-ray, pH titrations, distribution behavior have been reported. Its utility has been explored by achieving the separation of La I I I from Th I V .