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Impact of heteroatom addition into mesoporous silica for water adsorption in the low partial pressure range

Mesoporous silicas are known to be high-performing water adsorbents in high humidity levels due to their large pore volumes. However, for low humidity conditions, these materials typically present a less expressive performance, which is a drawback for many applications. In the present report, mesoporous silica SBA-15 was functionalized with Al, Ti, Zr and Li in order to improve their performance in this condition. The influence of functionalization in porosity, morphology and acidic sites was investigated. Samples with an increased number of acidic sites and with higher microporosity when compared to pure silica were produced. This was responsible for their enhanced performance for water adsorption in low moisture conditions. Sample functionalized with zirconium in SBA-15 synthesis improved the water adsorption capacity of pure silica by three times, reaching up to 127 g kg−1 at a relative pressure of 0.2 and 570 g kg−1 close to saturation pressure. This sample was found to be a promising material to be applied in processes which require high adsorption capacities in both low and high water partial pressure ranges. Moreover, the understanding of the mechanisms behind the heteroatom functionalization can be applied to any silica material in order to enhance its attractiveness towards any polar molecule. Supplementary Information The online version contains supplementary material available at 10.1007/s10450-021-00336-6.


Introduction
The adsorption of water vapor is a process of great relevance due to its wide possibilities of application, such as in chemical and petro-chemical industry, gas and liquid drying, microelectronics, pharmaceuticals, food preservation and processing, architecture materials, cosmetics, paper making, thermal energy conversion and storage, humidity control, adsorption heat pumps, and even fresh water production from the air [1][2][3]. Therefore, there is a growing interest in the research for novel materials to be applied in this field.
Mesoporous silicas are emerging new materials being investigated for many applications, such as catalysis [4][5][6][7][8][9][10][11], environment [12][13][14][15], drug delivery [16][17][18], production of sensors [19,20], nanotechnology [21], and others. Among all classes of mesoporous silicas, the so-called SBA-15 (Santa Barbara Amorphous 15) has been attracting much attention. They present hexagonally arranged cylindrical mesopores of uniform diameter, and high values of surface area (from 500 to 1000 m 2 g −1 ) and pore volume (which can surpass 1 cm 3 g −1 ). Their pore sizes can be easily controlled by changes in the synthesis parameters, which makes their textural features tailorable for each specific application. Another interesting characteristic of this class of silicas is their relatively thick pore walls, which can range from 3 to 6 nm [22]. These thick pore walls allied to the 2D hexagonal geometry would enable these materials to have a higher resistance against degradation caused by contact with water (also called hydrothermal resistance) when compared to other classes of silica [23].
The presence of a large volume of mesopores enables these materials to present adsorption capacities up to 1000 g kg −1 when exposed to high relative humidities [24]. For a low partial pressure range, SBA-15 materials were so far found to present a small adsorption capacity [25] due to their limited attractiveness towards water molecules. Improving the performance of these materials in this range is a requirement for applications such as drying of gaseous streams, rotary desiccant dehumidifiers [3], and adsorption heat transformers [25]. This is a challenge which has been so far little explored in the literature [26].
The works of Saliba et al. [27] and Maaz et al. [25] have determined that the volume of micropores present in the structure (the corona of SBA-15 [28]) as well as the density of silanol groups on the surface have an influence on the adsorption capacity in the low partial pressure range. Therefore, their enhancement would favor the performance in this region. Another approach would be the insertion of metallic heteroatoms into the framework of silica. This hypothesis was simulated by Perez-Beltran et al. [29] for substitutions with aluminum and titanium, and experimentally tested by Endo et al. [30] with aluminum and zirconium and Wei et al. [3] with aluminum. They have observed that the insertion of these metals created local distortions in the network of silica, which in turn improved the acidity of silanol groups present on the surface, creating stronger Brønsted and Lewis acid sites. This resulted in improved hydrophilicity and enhanced the low relative pressure performance of these materials. This is thus a promising strategy.
The works cited above were pioneer and exploratory, and there are still many aspects of the impact of heteroatom insertion into mesoporous silica for water adsorption in the low partial pressure range to be explored, such as which is the best metal for insertion. For this study, two groups of samples were synthesized, one using the regular SBA-15 synthesis procedure and another using a solution pH of 1.5. Four heteroatoms were inserted into SBA-15: Al, Ti, Zr and Li. Samples were characterized using nitrogen adsorption (BET), high resolution scanning microscopy (HR-SEM), energy dispersive X-ray spectroscopy mapping (EDX), Fourier transform infrared spectroscopy (FTIR), pyridine adsorption and water adsorption. The performance of the obtained materials was then related to the features observed in the characterization techniques.

Synthesis of pure silica SBA-15
The synthesis procedure was based on the work of Zhao et al. [31]. The surfactant Pluronics P123 was dissolved into an acidic solution of deionized water and hydrochloric acid through vigorous stirring at 40 °C. When dissolution was complete, TEOS was added to the mixture. The resulting solution was stirred for 24 h at 40 °C (molar ratios 1 TEOS:5.92 HCl:177 H 2 O:0.017 P123). The slurry formed was then filtered and the powder collected was dried (100 °C). A heat treatment was executed to remove the surfactant consisted (550 °C at 1 °C min −1 , 6 h at 550 °C, cooling at 10 °C min −1) . This sample was named "PSi" (Pure Silica).

Heteroatom functionalization: co-condensation approach 1
The first co-condensation approach used for functionalization presents very similar synthesis steps to those used for the pure silica. The difference is that after 1 h of reaction of TEOS in the acid solution of P123, the metal alkoxide precursor was also added to the mixture (metal/silicon molar ratio of 0.03). The pH of synthesis used was close to 0. Then the solution was allowed to continue reacting (40 °C for 24 h). The following steps of synthesis were identical to the production of PSi. Samples produced by this method were named C1-Al, C1-Ti, C1-Zr and C1-Li.

Heteroatom functionalization: co-condensation approach 2
In the second approach used for co-condensation, the amount of HCl was reduced in order to reach a pH value of 1.5, following reports from the literature [32][33][34][35]. All the other synthesis steps and molar ratios were the same as described for the first co-condensation approach and the pure silica production, except that the solids produced were recovered through centrifugation instead of filtration, due to a more viscous solution formed at the end of the syntheses. Samples produced using this methodology were labeled C2-Al, C2-Ti, C2-Zr and C2-Li. Materials produced by all approaches, including the sample of pure silica, were subjected to a rehydroxylation procedure to finalize the synthesis in order to recover the hydroxyl groups lost during the heat treatment. This process consisted of dispersing the powders into deionized water and keeping the suspension obtained in static condition (60 °C for 6 h). After that, the suspension was filtered and the powders were dried and prepared for the characterization techniques.

Characterization and performance evaluation
Textural characteristics of samples were evaluated through nitrogen adsorption in a Micromeritics ASAP 2020C apparatus [degassing procedure at 250 °C for 24 h under vacuum, analysis under liquid nitrogen bath (− 196 °C)]. The BET method was used to calculate the surface area between relative pressures from 0.05 to 0.3 and the NLDFT method (cylindrical pores in silicon oxide model, using the adsorption branch) for the distribution of pore sizes. This Micromeritics equipment was also used to record water adsorption isotherms. The same degassing procedure was used in this case (250 °C for 24 h under vacuum). Analyses were conducted in a water bath at 5 °C.
HR-SEM and EDX mapping were performed at a FEI Quanta FEG 3D microscope equipped with a Bruker Nano X-flash 5010 EDS detector. Powders were dispersed onto carbon tape covered stubs and coated with 15 nm of carbon to improve electron conduction for imaging. A voltage of 5 kV was used for morphology images and 15 kV for chemical composition. EDX maps were processed by EDS SPRIT software from Bruker.
FTIR analyses were conducted in a Perkin Elmer Frontier spectrophotometer using an ATR accessory (range of 1350-850 cm −1 , resolution of 2 cm −1 , 80 scans). In this spectrophotometer were also recorded spectra of pyridine adsorption/desorption. For this analysis, first samples were degassed at 250 °C for 1 h under vacuum and then contacted with pyridine vapors at 60 °C for 1 h. Next, pyridine was desorbed for 10 min at 150 °C and the spectra were collected (1750-850 cm −1 , 2 cm −1 of resolution and 100 scans). For measurements of peak height and absorbance, the main Si-O-Si peak at 1060 cm −1 was taken as reference to normalize all spectra.

Characterization of pore structure and morphology
Nitrogen adsorption was performed in order to bring knowledge about the porosity of samples. Figure 1 shows the nitrogen adsorption isotherms of C1 samples, synthesized in pH ~ 0. The shape of the isotherms corresponds to type IV (a) of the most recent classification of IUPAC [36], which indicated the presence of cylindrical mesopores of uniform diameter. This information is in agreement with other SBA-15 silicas studied in the literature [18,37]. They presented surface areas from 714 to 844 m 2 g −1 (Table 1), which were even higher than the sample of pure silica (592 m 2 g −1 ). This is in accordance with reports from other researchers [38][39][40][41]. An important characteristic presented by this group were that the values of micropore surface area and volume displayed average increases of 146% and 119%, respectively, when compared to pure silica. Charan and Rao [39] also reported that the insertion of heteroatoms by co-condensation may alter the amount of micropores in SBA-15 samples. This would occur because the presence of the metals changes the energy of the surfactant-solution interface, since the metals compete with silica in the S 0 H + X − I + mechanism (S 0 H + being the surfactant hydrogen bonded to a hydronium ion, X − the chloride ion and I + the protonated inorganic species) [42]. This way, the results suggest that the presence of the metals studied herein favored a deeper entrapment of the PEO chains of P123, giving rise to a larger micropore content. This might also contribute to the increase in surface area observed for functionalized samples when compared to pure silica. Observing Fig. 1, it is possible to notice that samples C1-Li and C1-Zr presented the main mesopore size of 7.09 nm, whereas C1-Al and C1-Ti presented a larger pore, of 10.14 nm. These sizes were somewhat different from PSi, which exhibited a main mesopore size of 8.27 nm. This further indicated that the addition of the metal alkoxides into the reaction mixture changed the interaction between the inorganic species and the micelles, as discussed before. Figure 2 exhibits the isotherms of C2 samples, produced with the addition of heteroatoms in pH 1.5. The shapes of these curves were somewhat distinct from the samples of the previous group, even though they can still be classified as type IV (a). Samples C2-Ti and C2-Li showed a narrower mesopore size distribution than C2-Al and C2-Zr, with pore sizes ranging from 7.09 to 9.6 nm, which is in the same range of pore sizes observed for the other group of samples. These results suggested that the use of pH 1.5 was not favorable to the mesostructure formation with the same uniformity as observed for group C1 in the synthesis conditions used in this work.   Table 1 showed that despite the irregularity in the pore size distribution, samples of group C2 presented significant surface areas (390-566 m 2 g −1 ). For this group, it was also possible to observe the same increase in the amount of micropores when compared to PSi. The exception in this case was sample C2-Li, which presented much smaller values of overall surface area and pore volume as well as the values corresponding to micropores.
HR-SEM micrographs were performed in order to evaluate the morphology of the particles. The first sample observed was PSi, whose images are shown in Fig. 3. In this figure, it was possible to observe a typical morphology of SBA-15 silicas: rod-like particles with hexagonal crosssection [43]. It was also possible to observe the formation of a few spheres, which are also found for this type of material [44].
Images obtained for samples of the C1 group are given in Fig. 4. The overall aspect of the particles in these samples maintained the rod-like shape of PSi, also with the presence of a few spheres. The main difference observed was the length of the particles chains. Two extreme cases were C1-Zr and C1-Li. In C1-Zr, short and loose rods with rounded edges were observed. In C1-Li, on the other hand, long sequences of fibers were formed by aligned rods, which reached up to 300 µm in length. Samples C1-Al and C1-Ti formed intermediary cases, quite similar to PSi.
One hypothesis to explain this difference between the particles sizes lies on the differences in the kinetics of reaction between the alkoxides used in functionalization. The final particle size (or particle chains size) depends on the number of nuclei (seeds) and on the aggregation capability of the surfactant-silica complexes [41], which is also related to the hydrolysis and condensation rates of the sol-gel precursors. If there are many seeds in a sol (fast hydrolysis and slow condensation), particles tend to stay small, as in C1-Zr. If on the other hand there are few nuclei and the rate of condensation overcomes that of hydrolysis (for formation of new nuclei), particles grow and elongate, such as in C1-Li. Once the alkoxides are added to the solution after only 1 h of reaction of the silica precursor (the reaction mixture is still clear, indicating there were no precipitated particles yet), their addition can be a key point in the nucleation of the particles, and their different nature can lead to the distinct results of morphology observed herein.
In Fig. 5 are given the micrographs of C2 samples. The morphologies observed in this group are quite distinct from those seen in the previous group. For samples C2-Al and C2-Ti, particles became nanodonuts, as Lee and coworkers also reported for pure silica SBA-15 [45]. For samples C2-Zr and C2-Li, similar particles were observed, however they were strongly aggregated into large fragments.
It is believed that this difference observed in C1 and C2 lies on the distinct pH of synthesis used in the two cocondensation strategies (close to 0 for C1 and 1.5 for C2). Kosuge and co-workers have also reported similar effects for samples with reduced amount of HCl [43]. The use of a different pH of synthesis also alters the kinetics of hydrolysis and condensation reactions, leading to distinct morphologies for the same reasons as discussed earlier.

Characterization of heteroatom insertion
To initiate the investigation regarding the effectiveness of the insertion of heteroatoms into the framework of silica, EDX mapping was performed. Results of metal content quantification and observations comprising what was observed in the EDX maps are presented in Table 2. Some representative maps are given in Figures S1 and S2 of the Supplementary Material. It is important to remember that lithium-containing samples were not evaluated due to the fact that the metal cannot be observed by this technique.
In general, most samples presented an M/Si molar ratio close to that introduced into the synthesis sol (3 mol%), indicating that the strategies used were well succeeded. The exceptions were C1-Al and C1-Ti, which exhibited a smaller percentage of inserted metal. This is in accordance with what was observed by other researchers, such as Li et al. [41] and Bhange et al. [7]. It is believed that the low insertion of metal in these samples is related to the strongly acidic pH adopted in the synthesis. In these conditions, most of these metals remain as cations in solution, without interacting with silica, and is washed away during filtration. This is proven true as samples of group C2 (synthesized in less acidic conditions) had successful insertions for these heteroatoms. Surprisingly, zirconium was inserted despite the strongly acidic environment (C1-Zr). In fact, there has been other reports which could also introduce zirconium using this conventional SBA-15 synthesis method [46,47].
The homogeneity of the heteroatom insertion was investigated in many regions of the samples through EDX maps.  It was observed that C1 samples were homogeneous, despite the small amount of metal present in C1-Al and C1-Ti. C2 samples, however, presented regions of concentration of metal, as registered in Table 2. This suggests the formation of extra-framework oxides. The investigation regarding the isomorphic substitution of heteroatoms into the framework of silica continued through FTIR analyses. The objective was to observe if there were disturbances in the network of silica caused by the presence of foreign atoms by tracking the Si-O-Si bonds around 1060 cm −1 [39,48,49]. The maxima of the peaks associated to these bonds in functionalized samples experienced deviations around the value observed for PSi, which are shown in Fig. 6. The complete spectra are given in Figures S3 and  S4 of the Supplementary material. Most of the samples presented a negative shift, i.e. towards smaller wavenumbers. This was also observed by Honda and Hirokawa [50] for several metal insertions. Equation 1 [51] shows that the wavenumber of infrared radiation absorbed in FTIR is related to the force constant of a given bond and to the masses of the atoms involved in this bond.
where v frequency in cm −1 , k force constant in N cm −1 , μ reduced mass in Kg.
The force constant is inversely proportional to the bond length, and can even be used to calculate it from the wavenumber values [52,53]. Therefore, if the functionalized samples presented the Si-O-Si stretching peak at a smaller wavenumber, it means that Si and O atoms were more distant from each other in their framework. This may rise from the substitution of silicon by larger atoms-as it is the case for the metals investigated herein. The ionic radii for the studied metals are: Si 4+ − 0.26 Å, Al 3+ − 0.39 Å, Ti 4+ − 0.42 Å, Li + − 0.59 Å, and Zr 4+ − 0.59 Å (all for four-fold coordination) [54]. This way, it is possible to relate the negative shifts observed in the FTIR spectra to isomorphic substitutions in the silica framework. It is important to observe that the resolution used in the scans was 2 cm −1 , thus only differences above this value present true significance. For C1 samples, only C1-Zr exhibited a significant negative shift, suggesting the isomorphic substitution of Zr in the framework. C1-Ti and C1-Al did not present significant shifts, which is in accordance with the EDX results, once they presented a very small amount of metal. C1-Li presented a small negative shift which might suggest a substitution in a low level, though its value is below the resolution of the assay.
In the C2 group, samples C2-Al and C2-Zr presented very significant negative shifts. Sample C2-Ti presented a smaller value, which agrees with the observations of the EDX mapping. The low isomorphic substitution suggested by this analysis implies on a greater amount of extra-framework oxides, which possibly generated the regions of Ti concentration observed in the compositional maps. The lithiumadded sample exhibited no shift, suggesting no isomorphic substitution for this material.

Characterization of active sites
Next, pyridine adsorption tests were performed to evaluate the presence of Brønsted and Lewis acid sites. The FTIR spectra of pyridine after desorption at 150 °C are given in Figs. 7 and 8. In these spectra, peaks at 1447 cm −1 and 1599 cm −1 were clearly identified for most samples. They can be associated to pyridine covalently bonded to Lewis acid sites [55,56]. For some samples, a peak at 1492 cm −1 was also observed-this peak has been related to adsorption of pyridine in both Lewis and Brønsted acid sites, as a mixed contribution [57,58]. In literature it is also mentioned that the presence of Brønsted acid sites is demonstrated by the formation of the pyridinium ion, which produces a characteristic infrared signal at 1540 cm −1 [59,60]. Few samples in this study presented visible peaks in this region. This way, it was possible to conclude that, in general, samples investigated herein showed a stronger presence of Lewis-type of acid sites.
Observing Figure 7, it was possible to see that sample PSi exhibited significantly smaller peaks than the functionalized samples, indicating a smaller presence of acid sites. In this figure, sample C1-Li presented well-defined signals at 1599 cm −1 and 1447 cm −1 , indicating a well-succeeded functionalization for this sample. This result is in accordance with This allows one to conclude that the small presence of metal observed in the EDX analyses for these samples (0.8 mol% for C1-Al and 0.3 mol% for C1-Ti) was already sufficient to produce more active sites than those originally present in pure silica. Within this group, sample C1-Zr demonstrated the highest peaks for Lewis (1447 cm −1 and 1599 cm −1 ) and mixed contribution (1492 cm −1 ) sites, besides a small signal at 1540 cm −1 . This means that the functionalization seems to have been the most successful for this sample in the group in terms of the creation of acidic sites. This is coherent with the results of the EDX mapping and FTIR.
As an attempt to compare the overall amount of active sites in the samples, the heights of the peaks at 1447 cm −1 and 1492 cm −1 were measured and added. The peak at 1447 cm −1 was chosen to represent Lewis sites as it usual in literature [60], whereas the peak at 1492 cm −1 was chosen to indirectly represent the contribution of Brønsted sites. This seemed valid since only the samples with distinguishable signals at 1540 cm −1 showed peaks at 1492 cm −1 . Since this operation was intended only to be a comparison between the samples in this work and not a quantification of acid sites, it was carried out for all samples. It is going to be proven valuable in future comparisons in this work. The numbers found for this measurement for group C1 were: 16.92 a.u. for C1-Zr, 8.84 a.u. for C1-Li, 7.18 a.u. for C1-Al and 6.02 a.u. for C1-Ti.
Regarding samples of group C2, more evident peaks were observed for C2-Al, C2-Ti and C2-Zr, which summed 10.65 a.u., 10.59 a. u. and 11.50 a.u., respectively. These numbers showed that all C2 samples except C2-Zr showed higher amounts of acid sites when compared to their C1 analogues.

Performance evaluation
After getting to know the characteristics of the samples, their performance for water adsorption was evaluated. The isotherms collected are given in Figs. 9 and 10. As commented before, the objective of heteroatom insertion in this work was to enhance the adsorption capacity of samples in the low partial pressure range (highlighted in the figures). In general, most of the functionalized samples presented a higher adsorption capacity than pure silica in this region, showing that the overall strategy adopted herein was successful.
Considering group C1 (Fig. 9), significant increases in capacity were obtained. For this group, the increasing order of adsorption capacity observed was Zr > Li > Al > Ti. This is in alignment with the characterization results, which showed a partial insertion of metals for C1-Al and C1-Ti (EDX), with a small formation of active sites (pyridine). This way, it was possible to explain why these samples displayed a smaller capacity than C1-Zr and C1-Li, but still higher than PSi. The sample with zirconium addition, on the other hand, exhibited the highest capacity in the group and also among all samples evaluated herein, presenting 127 g kg −1 of adsorption capacity at 2 mbar. This represents a three-fold increase in the adsorption capacity of pure silica.   [64]. Its capacity was comparable to Al-MCM-41 developed by Chen et al. [1], which presented 130 g kg −1 for adsorption at 25 °C. Nevertheless, at P/P 0 = 1, their material reached 350 g kg −1 , whereas C1-Zr reached up to 570 g kg −1 . This way, C1-Zr was found to be a promising material to be applied in processes which require high adsorption capacities in both low and high water partial pressure ranges. It is important to highlight that the increase in performance for the low partial pressure range obtained with the approach reported herein does not incur in the sacrifice of the adsorption capacity in high moisture conditions.
Observing now results for group C2 (Fig. 10), C2-Al, C2-Ti and C2-Zr presented a significantly higher adsorption capacity than PSi at 2 mbar, reaching a 203% increase for C2-Al. C2-Li presented a performance very close to PSi, confirming the indication of the characterization techniques that the functionalization was not well-succeeded for this sample. In general, adsorption capacities of C2 samples were somewhat smaller than those presented by the C1 group. Characterization analyses discussed previously showed that C2 samples presented less uniform pore structures than C1 samples, and also morphologies with twisted and aggregated particles. This may hinder the diffusion and access of water molecules to adsorption sites. In summary, results showed that the use of a solution pH of 1.5 instead of close to 0 impacted negatively the formation of mesopores and the macrostructure of particles, also favoring the precipitation of metals as extra-framework oxides. However, this was the only strategy capable of quantitatively inserting Al and Ti into the structure.

Relationship between properties and performance
As commented previously, it is believed that the micropore volume and the creation of acidic sites enabled by the insertion of metallic heteroatoms into the silica framework are key features for water adsorption capacity in the low partial pressure range [65]. In order to observe the validity of this hypothesis for the set of samples developed in this work, the plot in Fig. 11 was constructed. This figure showed that only samples which associate a high micropore volume with a large amount of acidic sites present the highest adsorption capacities at 2 mbar. This can be explained through the water adsorption mechanism, as proposed by Maheshwari et al. [66] and Grünberg et al. [67]. Initially, water molecules are attracted by adsorption sites on the surface. These groups can be hydroxyl terminations and Lewis or Brønsted acid sites. This already demonstrates the importance of the presence of surface OH groups and of the creation of acidic sites on the materials. The next water molecules on the surrounding gas can be attracted to other sites available on the surface as well as to already adsorbed water molecules.

Fig. 9
Water adsorption isotherms at 5 °C of samples functionalized using the first co-condensation approach with the pure silica sample for comparison. The region considered as low partial pressure in this text is highlighted Fig. 10 Water adsorption isotherms at 5 °C of samples functionalized using the second co-condensation approach with the pure silica sample for comparison. The region considered as low partial pressure in this text is highlighted This occurs due to the fact that, unlike other adsorbates, molecule-surface and molecule-molecule interactions are energetically similar for water. From this, results the formation of isles or clusters of water molecules around adsorption sites, which grow as the process carries on. If these clusters are placed inside of micropores as those present in SBA-15, they grow until their entire volume is occupied, in a mechanism known as micropore filling. If instead they are placed on the walls of mesopores and the partial pressure keeps rising, they will continue to grow until two or more of these clusters coalesce, forming a continuous mass of water covering the entire pore diameter. It is in this moment that capillary condensation occurs, leading to the steep increase in the isotherm curves, which can be observed from 5 to 7 mbar in Figs. 9 and 10. This process continues until the entire pore volume is virtually complete, as discussed previously. This way, it is possible to understand how these two properties of the materials relate to their water adsorption capacity in the low partial pressure range.

Conclusions
This work investigated the relationship between the insertion of heteroatoms into mesoporous silica SBA-15 and the water adsorption in the low partial pressure range by comparing two groups of samples for the addition of Al, Ti, Zr and Li:C1, functionalized using the co-condensation method with the regular SBA-15 synthesis procedure; and C2, cocondensed in pH = 1.5. It was concluded that method C1 produced samples with the highest surface areas and was not capable of inserting Al and Ti. Co-condensation C2 was able to insert all heteroatoms except lithium and produced samples with smaller surface areas. Investigation regarding morphology showed the different alkoxides and pHs used in the co-condensation approach impacted the morphologies of the final materials, leading to the formation of rods, fibers and nanodonuts. Pyridine adsorption showed that functionalized samples presented a higher number of active sites than the sample of pure silica, mostly of Lewis type. Sample C1-Zr was found to be a promising material to be applied in processes which require high adsorption capacities in both low and high water partial pressure ranges. This sample showed an adsorption capacity three times higher than pure silica, reaching up to 127 g kg −1 at a relative pressure of 0.2 and 570 g kg −1 close to saturation pressure. This superior performance was explained due to the fact that this sample associated a high micropore volume with a large amount of acidic sites. It is important to highlight that the increase in performance for the low partial pressure range obtained with the approach reported herein does not incur in the sacrifice of the adsorption capacity in high moisture conditions. Finally, the understanding of the mechanisms behind the functionalization of silica with metallic heteroatoms can be applied to any silica material in order to enhance its attractiveness towards any polar molecule. The knowledge generated herein can thus be widely used by many fields of investigation. Fig. 11 Relationship between micropore volume, added heights of peaks at 1447 cm −1 and 1492 cm −1 in the pyridine adsorption spectra and water adsorption capacity in the low partial pressure range (2 mbar). Samples with highest adsorption capacity present simultaneously high micropore volume and large amount of acidic sites