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Heterogeneous Gold(III)-Catalysed Double Hydroamination of 2-Alkynylanilines with Terminal Alkynes Leading to N-Vinylindoles

Heterogeneous double hydroamination of 2-alkynylanilines with terminal alkynes was achieved by using a magnetic nanoparticles-supported gold(III)-2,2′-bipyridine complex and silver trifluoromethanesulfonate as catalysts to afford the corresponding N-vinylindoles in moderate to good yields under mild and solvent-free conditions. The heterogeneous gold catalyst can easily be separated from the reaction mixture by simply applying an external magnet and can be recycled up to seven times without significant loss of activity.