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Synthesis, stability and bonding situation of tris-, bis- and mono[9-(azuleno[1,2-b]thienyl)]methyl cations.

Stable tris-, bis- and mono[9-(azuleno[1,2-b]thienyl)]methyl cations (7a, 8a and 9a) and their derivatives, with a 6-isopropyl substituent on each azuleno[1,2-b]thiophene ring (7b, 8b and 9b) were prepared by the hydride abstraction reaction of the corresponding methane derivatives. The bonding situation of these compounds including the methane derivatives was examined by analysis of the 3J(H,H) values for the seven-membered ring from the 1H NMR spectra. The methane derivatives exhibited a significant alternating pattern in the 3J(H,H) values, which indicated that the pi-system of the azulene core is perturbed by the fused thiophene ring, showing a tendency towards a localized heptafulvene substructure. The 3J(H,H) values of 7b and 8b in the seven-membered ring revealed that the alternating C-C bond lengths in the azulene core still existed. The cations 9a and 9b, which exhibited nearly equal 3J(H,H) values in the seven-membered ring, exhibit the development of a delocalized tropylium substructure in the azulene core. X-ray crystal analysis of 6-isopropylazuleno[1,2-b]thiophene revealed substantial bond-length alternation in the seven-membered ring. Significant bond-length equalization in the seven-membered ring was also confirmed by the X-ray crystal analysis of 9b. The stability of these carbocations was examined by measurement of the pKR+ values and the redox potentials, which revealed that the bond-length alternation in the azulene core does not significantly affect the stability of the carbocations.