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Simple analysis of quasi-reversible steady-state voltammograms

The kinetic parameters (K o and α) of a uncomplicated quasi-reversible electrochemical reaction studied by any steady-state voltammatric technique can be found directly from the values of two easily accessible experimental parameters, (E 1/4 -E 1/2 ) and (E 1/2 -E 3/4 ), where E 1/2 is the experimental half-wave potential and E 1/4 and E 3/4 are voltammetric quartile potentials