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Novel Control Strategy for Membrane Biofouling by Surface Loading of Aerobically and Anaerobically Applicable Photocatalytic Optical Fibers Based on a Z-Scheme Heterostructure Zr-MOFs/rGO/Ag3PO4 Photocatalyst.

The high replacement cost of modified membranes in antibiofouling application is inevitable. Here, surface-loaded photocatalytic optical fibers (POFs) were developed as antibiofouling strategies to replace membrane modification. To prepare aerobically and anaerobically applicable POFs, novel visible light-driven zirconium-based metal-organic framework/reduced graphene oxide/Ag3PO4 (Zr-MOFs/rGO/Ag3PO4) Z-scheme heterojunctions were constructed and coated on optical fibers. After loading the POFs on the membrane surface, the antibiofouling capability of the POFs was demonstrated during membrane filtration of bacteria and foulants under visible light irradiation. The disinfection efficiencies of the POFs against Escherichia coli and Staphylococcus aureus reached 95.7 and 92.4%, respectively, by aerobic treatment and 90.3 and 85.5%, respectively, by anaerobic treatment. For the inactivated bacteria, cell membrane and membrane-associated functions were destroyed, accompanied by antioxidant enzyme decomposition, loss of cell respiration and adenosine triphosphate (ATP) synthesis capacity, and leakage and oxidation of protein, lipid, potassium, DNA, and RNA. During membrane filtration of model foulants and membrane bioreactor sludge, the POFs significantly alleviated the membrane flux decline by foulant disintegration. By qualitative and quantitative detection and quenching tests of reactive species, aerobically generated •O2- and •OH and anaerobically generated •OH from POFs played dominant roles in the antibiofouling process. This work provides unique insights into membrane fouling control based on environmentally friendly and efficient photocatalytic technology.