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Rate of vibrational deactivation of Cl2 molecules by chemically active Cl atoms in gas flow media

To state more precisely our knowledge of the vibrational energy transfer with Cl2 molecules in active media of the gas flow and chemical lasers, the study of nonequilibrium vibrational relaxation of the thermally heated and partially dissociated molecular chlorine in the supersonic flow is carry out. An experimental technique, based on the sensitive spectroscopic diagnostics and numerical gasdynamic and kinetical modeling is used. The parameters of vibrational kinetics of the molecular chlorine is found. The effect of chemically active Cl atoms on the rate of V-T deactivation of Cl2 molecules is determined.