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Dielectric Properties During Phase Transition of the LiTaO 3 -SiO 2 Glasses

Dielectric responses during phase transition from the LiTaO 3 -SiO 2 glasses which are produced by twin roller quenching from melt have been studied. An electrical property is measured using Impedance/Gain-phase analyzer with continuous heating. We also measure the thermal properties using differential thermal analysis. Electrical anomaly of a few dielectric peaks with heating has been observed. This effect is explained on the basis of the structural relaxation and multiple phases occurring from supercooled phase, crystallization and spinodal decomposition which exist in the mixture of LiTaO 3 and SiO 2 .