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Measurement of Ionic Transference Numbers from Electromigration on Paper

Ionic transference numbers of Copper(II) and Nickel(II) have been determined from measurements of the ionic mobilities of the respective ions in different concentrations of the electrolytes by the paper ionophoretic method. The ionic mobilities and hence the ionic transference numbers measured in different concentrations of the electrolytes have been corrected for (i) electroosmotic and (ii) barrier effects. The corrected values thus obtained have been found to be of the same order of magnitude and accuracy as those determined by other modern, more conventional and classical methods.