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Electrochemical Detection of Bisphenol A Based on N-Doped Carbon Quantum Dots@Carbon Nanotubes Composite.

A novel nanocomposite of N-Doped Carbon Quantum Dots@Carbon Nanotubes was synthesized in this study for electrochemical detection of bisphenol A by differential pulse voltammetry. The nanocomposite was characterized by transmission electron microscopy, scanning electron microscopy, X-ray powder diffraction and Fourier transform infrared spectroscopy. Electrochemical properties of the nanocomposite modified glassy carbon electrodes were studied via cyclic voltammetry. Differential pulse voltammetry experimental results showed that N-Doped Carbon Quantum Dots@Carbon Nanotubes/glassy carbon electrode exhibited excellent catalysis activity towards electrochemical oxidation of bisphenol A. The oxidation peak current was linearly increased with concentration of bisphenol A in the range from 0.4 μM to 40 μM, with a limit of detection of 65 nM.