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Studies on the structural, thermal, and dielectric properties of fabricated Nylon 6,9/CaCu3Ti4O12 nanocomposites

Abstract Nylon 6,9/CaCu3Ti4O12 (CCTO) nanocrystal composites with relatively high dielectric permittivity (220 at 100 Hz) were fabricated by melt mixing followed by hot pressing. The CCTO nanoceramics were synthesized using the oxalate precursor route, and the transmission electron microscopy studies exhibited that the crystallites are in the range of 20–200 nm. The nanocomposites were characterized using X-ray diffraction, scanning electron microscopy, thermogravimetric analysis, differential scanning calorimetry, and impedance analyzer to study their structural, thermal, and dielectric properties. The introduction of CCTO nanoparticles into the matrix had influenced the thermal properties. The effective dielectric permittivity of the nanocomposite increased by the augmentation of CCTO content in the Nylon 6,9. Our experimental outcomes showed that the fixed dielectric permittivity of such two-phase composite was established above 200 when the CCTO concentration was closer to its percolation threshold. The room temperature dielectric permittivity as high as 220 at 100 Hz has been achieved when the CCTO content increased to 58 vol% in the polymer and this was increased to 3845 at 150°C. The increase in AC conductivity with the increase in the CCTO content in the polymer matrix supported the hopping of the charge carrier conduction mechanism.