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New Polymers for Optimizing Organic Photovoltaic Cell Performances

The performance of an organic solar cell critically depends on the materials used in the active layer. Desirable characteristics of active layer materials include an intense optical absorption covering broad range of the solar spectrum to maximize photon capture, the ability to effectively separate charges upon photo‐excitation, high charge mobility to allow efficient charge transport to the electrodes, and suitable HOMO and LUMO levels to ensure a high device voltage. In order to optimize these properties simultaneously, we have designed and synthesized conjugated polymers containing alternating electron‐donating and electron‐accepting units. Based on one of the low band gap polymers we designed and synthesized previously, poly[2,6‐(4,4‐bis‐(2‐ethylhexyl)‐4H‐cyclopenta[2,1‐b:3,4‐b′]dithiophene)‐alt‐4,7‐(2,1,3‐benzothiadiazole)], we carried out both side chain and main chain modifications in order to improve performance even further. By incorporating fluorene repeating units into the main chain, it is possible to adjust the absorption characteristics of the polymers while maintaining a desirable HOMO level and good charge carrier mobility. The solubility profile of the polymer can be adjusted by modifying the side chains, and soluble polymer with mobility as high as 7×10−2 cm2/Vs is realized when a combination of 2‐ethylhexy and hexyl groups are used as side chains. These polymers should be promising candidates for high performance solar cells according to a recently published model (3).