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Valence-band splitting in ordered Ga0.5In0.5P measured by polarized photoluminescence excitation spectroscopy.

The spontaneous long-range-order-induced splitting of the valence band of Ga 0.5 In 0.5 P is studied by polarized near-gap-excited photoluminescence and photoluminescence excitation. The results allow a direct determination of the size of the valence-band splitting and the relative ordering of the resultant states. Values obtained for the splitting are compared with recent calculations