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Agronomic Implications of the Application of Lime plus Gypsum By‐products to a Hyperdistric Acrisol from Western Spain

Abstract: A laboratory experiment involving the use of leaching columns reproducing the topmost portion of a Hyperdystric Acrisol (FAO 1998) or plinthic Palexerult (Soil Survey Staff 2003) treated in its Ap horizon with sugar foam wastes and phosphogypsum was conducted. The amendments increased the contents in exchangeable calcium (Ca) of the Ap horizon and, to a lesser extent, also that of the AB horizon. However, the contents in exchangeable magnesium (Mg) and sodium (Na) decreased as much in Ap as they did in AB; by contrast, the potassium (K) content exhibited a less marked decrease. The potassium chloride (KCl)–extractable aluminium (Al) of the Ap horizon was dramatically decreased much more than that of the AB horizon by the amendments. In the soil solution from Ap, the amendments raised the pH and decreased the Al concentration; in that from AB, however, they caused an initial pH decrease, a tendency that reversed as the gypsum was leached and eventually led to the pH exceeding that in the soil solution from control. The first few water extractions exhibited increased Mg concentration. This trend was reversed in the second leaching cycle, where the concentrations of Mg in the amended columns were lower than those in the controls. In the soil solution, the variation of the Ca and sulphate (SO4 2–) concentrations was influenced by the salt‐sorption effect. The total Al content in soil solution from AB increased during the first leaching cycle and then decreased during the second. The amendments decreased the activities of Al3+, AlOH+2, and Al(OH)2 + in the Ap horizon and increased those of Al3+, AlSO4 +, Al(SO4)2 −, and AlF+2 in the first leaching cycle in the AB horizon. The productivity of the Ap horizon after the treatments was assessed using a wheat crop (T. aestivum, var. ‘Jabato’) in a greenhouse.