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Different choices of scaling in homogenization of diffusion and interfacial exchange in a porous medium

Several choices of scaling are investigated for a coupled system of parabolic partial differential equations in a two‐phase medium at the microscopic scale. This system may be regarded as modelling a reaction–diffusion problem, the Stokes problem of single‐phase flow of a slightly compressible fluid or as a heat conduction problem (with or without interfacial resistance), for example. It is shown that, starting with the same problem on the microscopic scale, different choices of scaling of the diffusion coefficients (resp. permeability or conductivity) and the interfacial‐exchange coefficient lead to different types of macroscopic systems of equations. The characterization of the limit problems in terms of the scaling parameters constitutes a modelling tool because it allows to determine the right type of limit problem. New macroscopic models, not previously dealt with, arise and, for some scalings, classical macroscopic models are recovered. Using the method of two‐scale convergence, a unified approach yielding rigorous proofs is given covering a very broad class of different scalings. Copyright © 2008 John Wiley & Sons, Ltd.