{'fraction_non_alphanumeric': 0.03609515996718622, 'fraction_numerical': 0.009844134536505332, 'mean_word_length': 5.009852216748769, 'pattern_counts': {'":': 0, '<': 0, '<?xml version=': 0, '>': 0, 'https://': 0, 'lorem ipsum': 0, 'www.': 0, 'xml': 0}, 'pii_count': 0, 'substrings_counts': 0, 'word_list_counts': {'cursed_substrings.json': 0, 'profanity_word_list.json': 0, 'sexual_word_list.json': 0, 'zh_pornsignals.json': 0}}
Study on Crystal Form Transition and Non-Isothermal Crystallization of Glycidyl Methacrylate Grafted Isotactic Polybutene-1

Abstract We report the impact of grafting glycidyl methacrylate (GMA) at different degrees onto isotactic polybutene-1 (iPB-1) on the crystallization process. The study of the crystal form transition using FTIR and X-ray Diffraction (XRD) revealed that the conversion degree from form II to form I of the grafted iPB-1 (iPB-g-GMA) was higher than that of iPB-1 under the same experimental conditions and increased with increasing grafting degree. The spherulitic size of iPB-g-GMA was smaller compared to iPB-1 at the same amplification factor in Polarized Optical Microscopy (POM). The kinetic parameters of the non-isothermal crystallization process have been determined based on Differential Scanning Calorimetry (DSC) experiments and the Ozawa and Mo equation. The results showed that the crystallization rate of iPB-g-GMA was higher than that of iPB-1. The activation energy for the non-isothermal crystallization process of iPB-g-GMA (with a grafting degree of 1.54%) was lower than that of iPB-1, which further illustrated that grafting GMA on iPB-1 accelerated the crystallization rate.