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An Advanced Compositional Analysis of Crude Oil-Brine Interface and the Effect of Involving Interactions on the Performance of Low Salinity Water Injection


 Despite the plethora amount of research have been conducted on the Low Salinity Water Injection (LSWI) and the pertinent mechanisms, this Enhanced Oil Recovery (EOR) method still seems not to be well understood. Although the rock/fluid interactions are used to be highlighted as the main elements of chemical mechanism of LSWI, fluid/fluid interactions have been brought into attentions much more than anytime before. Formation of microdispersion within the crude oil phase leading to wettability alteration has been proposed repeatedly as the underlying mechanism of LSWI without clarifying the functional compounds of crude oil toward this EOR method. Discovering the responsible compounds of crude oils towards Low Salinity Water (LSW) and formation of microdispersion is demanding to achieve a reliable screening tool of oil reservoir toward LSWI.
 For this purpose, the crude oils and brines were contacted for an extended period of time until the oil/water interface reached an equilibrium state right before taking crude oil samples from the interface. The Karl Fischer titration (KFT) analyses were carried out to quantify the amount of microdispersion within the crude oil phase. The crude oil sample with the strongest propensity toward microdispersion formation was further investigated through Fourier Transform Infrared (FT-IR) spectroscopy and Negative Electrospray Ionisation (NESI) mode of Fourier Transform Ion Cyclotron Resonance mass spectroscopy (FT-ICR) to evaluate the chemical compositional changes taking place at the interface due to salinity effect.
 FT-IR analyses revealed the conjugated acidic compounds or the acidic asphaltenes within the crude oil to be the most functional compounds toward microdispersion formation. Consistently, the NESI mode of FT-ICR MS suggested the carboxylic acids (with C=O functional groups) promoting the formation of microdispersion when the crude oil is swept by LSW. Also highlighted was the structure of functional carboxylic acids during LSWI that appeared to be those compounds with DBE of 1, 2, and 3 and carbon number of C15-C20.
 The results of this study represent an important step toward understanding the mechanism responsible for the LSE. The knowledge will help the oil and gas industry in the task of evaluating and ranking oil reservoirs for EOR by LSWI.