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Direct Z-Scheme Heterojunction of Semi-coherent FAPbBr3/Bi2WO6 Interface for Photoredox Reaction with Large Driving Force.

Metal halide perovskites with direct bandgap and strong light absorption are promising materials for harvesting solar energy, however, their relatively narrow bandgap limits their redox ability when used as a photocatalyst. Adding a second semiconductor component with the appropriate band structure offsets can generate a Z-scheme photocatalytic system, taking full advantage of the perovskite's intrinsic properties. In this work, we develop a direct Z-scheme photocatalyst based on formamidinium lead bromide and bismuth tungstate (FAPbBr3/Bi2WO6) with strong redox ability, for artificial solar-to-chemical energy conversion. With desir-able band offsets and strong joint redox potential, the dual photocatalyst is shown to form a semi-coherent hetero-interface. Ultra-fast transient infrared absorption studies employing selective excitation reveal synergetic photocarrier dynamics and demonstrate Z-scheme charge transfer mechanisms. Under simulated solar irradiation, a large driving force photoredox reaction (ca. 2.57 eV) of CO2 reduction coupled with benzyl alcohol oxidation to benzaldehyde is achieved on the Z-scheme FAPbBr3/Bi2WO6 photocata-lyst, harnessing the full synergetic potential of the combined system.