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Association in Molten Salts and Mobility Isotherms

A change with concentration in the height of the first peak of the pair distribution function g+ - of a salt in a mixture of molten salts indicates a change in the degree of association of that salt. It is shown that the changes in association observed this way from MD-simulations of binary mixtures of charge symmetric salts with a common anion are qualitatively consistent (i) with the requirements for the occurrence of the crossing of mobility isotherms (Chemla effect) and (ii) with the ideal law of mass action