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Bioinspired Polyacrylamide/(polyvinyl alcohol-copper acetate) Hydrogel with Cooling-triggered Shape Memory, Color Changing, and Self-healing Behavior.

Inspired by many living creatures with adjustment of shape and color in ever-changing environment, color changeable shape memory hydrogels are designed and expected to be potential candidates in the fields spanning from anti-counterfeiting to biomedical devices. However, they normally require complex synthesis, and more importantly, the cooling-induced shape recovery hydrogel is still rare and in its infancy so far. Herein, we have developed a unique color changeable shape memory hydrogel by simply incorporating polyvinyl alcohol and copper acetate into covalent polyacrylamide network. As core functional element, copper ions serve as reversible crosslinks after heating to achieve excellent cooling-triggered shape memory effect, color shifting and self-healing behavior, showing significant potential in diverse applications like grabbing, information encryption, and biomimetic designs. This work may guide the development of cooling-triggered smart hydrogels for practical applications. This article is protected by copyright. All rights reserved.