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Reduction of FeO in EAF Steelmaking Slag by Blends of Metallurgical Coke and Waste Polypropylene

Abstract The reduction of FeO-containing slag by blends of metallurgical coke and waste polypropylene (PP) has been investigated through experiments conducted in a laboratory scale horizontal tube furnace. Composite pellets of EAF slag (47.1% FeO) with coke, PP and blends of coke/PP (in three different proportions) were rapidly heated at 1500 °C under high purity argon gas and the off gas was continuously analysed for CO and CO2 using an online infrared gas analyser (IR). The extent of reduction after fifteen minutes, level of carburisation and desulphurization were determined for each carbonaceous reductant. The results show that FeO can be effectively reduced from EAF slag to produce metallic iron using waste PP and its blends with coke as reductants; improvements in the extent of reduction and levels of carburisation and desulphurisation of the reduced metal were observed when coke was blended with PP.