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Ionic transport studies in silver borophosphate glass system with silver iodide

In this paper we report electrochemical properties of AgI-Ag2O-B2O3-P2O5 glass system prepared by melt quench technique. X-Ray diffraction analysis has been carried out to understand the formation of glass network and its degree of crystallinity. The glass transition temperature (Tg) is studied using TG-DTA thermograms. Electrochemical Impedance Spectroscopy has been employed to study ionic conductivity of the glass system from ambient up to 373K and frequency range from 20Hz to 2MHz. In order to understand transport properties of the glass system, various parameters such as activation energy (Eσ) and oxygen packing density (OPD) have been discussed.In this paper we report electrochemical properties of AgI-Ag2O-B2O3-P2O5 glass system prepared by melt quench technique. X-Ray diffraction analysis has been carried out to understand the formation of glass network and its degree of crystallinity. The glass transition temperature (Tg) is studied using TG-DTA thermograms. Electrochemical Impedance Spectroscopy has been employed to study ionic conductivity of the glass system from ambient up to 373K and frequency range from 20Hz to 2MHz. In order to understand transport properties of the glass system, various parameters such as activation energy (Eσ) and oxygen packing density (OPD) have been discussed.