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Revised Analysis of the 5p4 Ground Configuration of Two-Times Ionized Xe (Xe III) and Reevaluation of Transition Probabilities for Forbidden Lines within this Configuration

The 1S0 level in the 5p4 ground configuration of Xe III has been revised. Parameter values for the 5p4 configuration have been determined by parametric fitting and the eigenvectors used to calculate transition probabilities for magnetic dipole as well as electric quadrupole transitions within the 5p4 configuration. An improved value for the ionization potential of Xe II is used to determine the energies of the 4d105s25p4 1D2- 4d95s25p6 2D5/2 (N5O2,3O2,3 (1D2)) and 4d105s5p5 1P1-4d95s25p6 2D5/2 (N5O1O2,3 (1P1)) Auger transitions in Xe, which are commonly used as reference lines in photoelectron spectroscopy.