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Polar domain fluctuations in doped liquid nitrobenzene.

Improved spectral measurements of the narrow spike in the high resolution hyper-Rayleigh light scattering spectrum for deuterated liquid nitrobenzene (C(6)D(5)NO(2)) doped with triflic acid (CF(3)SO(3)H) determined that the reorientation time for the dopant-induced polar domains is 2.9 micros in the dilute limit. Two models based on ions dissolved in nitrobenzene fit the measured spectral broadening function.