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A kinetic approach to the theory of heterogeneous nucleation on soluble particles during the deliquescence stage.

Deliquescence is the dissolution of a solid nucleus in a liquid film formed on the nucleus due to vapor condensation. Previously, the kinetics of deliquescence was examined in the framework of the capillarity approximation which involves the thermodynamic interfacial tensions for a thin film and the approximation of uniform density therein. In the present paper we propose a kinetic approach to the theory of deliquescence which avoids the use of the above macroscopic quantities for thin films. The rates of emission of molecules from the liquid film into the vapor and from the solid core into the liquid film are determined through a first passage time analysis whereas the respective rates of absorption are calculated through the gas kinetic theory. The first passage time is obtained by solving the single-molecule master equation for the probability distribution of a "surface" molecule moving in a potential field created by the cluster. Furthermore, the time evolution of the liquid film around the solid core is described by means of two mass balance equations which involve the rates of absorption and emission of molecules by the film at its two interfaces. When the deliquescence of an ensemble of solid particles occurs by means of large fluctuations, the time evolution of the distribution of composite droplets (liquid film+solid core) with respect to the independent variables of state is governed by a Fokker-Planck kinetic equation. When both the vapor and the solid soluble particles are single component, this equation has the form of the kinetic equation of binary nucleation. A steady-state solution for this equation is obtained by the method of separation of variables. The theory is illustrated with numerical calculation regarding the deliquescence of spherical particles in a water vapor with intermolecular interactions of the Lennard-Jones kind. The new approach allows one to qualitatively explain an important feature of experimental data on deliquescence, namely the occurrence of nonsharp deliquescence, a feature that the previous deliquescence theory based on classical thermodynamics could not account for.