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Solvent effects on the crystal structure of silver pentacyanocyclopentadienide: supramolecular isomerism and solvent coordination.

Several coordination polymers of silver(i)-pentacyanocyclopentadienide (PCC) were studied by X-ray diffraction to examine the effects of different solvents on supramolecular isomerism of the PCC-ligand. While alcohols yield supramolecular isomers of [Ag(PCC)] without coordination of solvent molecules, less polar solvents show coordinate binding. The influence of solvent polarity can be observed by a gradual change in the lattice structure featuring distinct motifs.