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Efficient separation of propylene and propane on SAPO-17 molecular sieve

In this study, the separation performance of propylene and propane on SAPO-17 molecular sieve was investigated by static and dynamic adsorption. The adsorbent possessed good regeneration behavior because the strong adsorption of propylene at room temperature was eliminated by ion exchange treatment. Dynamic adsorption experiments revealed that the kinetic separation selectivity of propylene and propane was as high as 1980, which could be attributed to the energy barrier difference when diffusing through the eight-membered ring of SAPO-17 molecular sieve. The breakthrough experiments verified the good separation performance of the SAPO-17 adsorbent, which suggests that it has considerable application potential in propylene/propane separation.