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Nematic Potential and Order Parameter Determined from Dielectric Measurements

Abstract The Maier-Saupe theory is employed in order to calculate order parameters S from the nematic potential q. It is found that one of the basic assumptions of the Maier-Saupe theory, q~S, is approximately fulfilled. The relation between q and S is analysed for various state changes. Previously reported findings for 7 PCH that q~S, not fulfilled along isochoric changes, can be explained by taking into account the pressure and temperature dependences of q. The procedure described in this paper allows to treat experimental data for the nematic potential in a unique way, without being affected by inadequacies of experimentally determined order parameters.