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Phase Transition and Anisotropic Transport of MoS 2 /Chlorophyll Van der waal Heterostructure Formed via Biomimetic Photo-electron Donation


 In atomically-thin two-dimensional Vander-Waal-heterostructure [VDWHs], phase transition due to biomimetic photoelectron donationwith molecular ad-layer has never been explored. In this pursuit, systematic quantification of biomimetic-optical-creation of stable easy-solution-processed 1T MoS2 chlorophyll (CHL-a) VDWHs has been examined. The 1T phase transformation dynamics and stabilization phenomenon have been quantified by optical anisotropy and Time-correlated-single-photon-counting. The material shows Luttinger transport phenomenon in the two-port device and supports MoS2 interfaces can be fine-tuned with the molecular ad-layer as a result of strong anisotropic finite range correlation. This is validated by Density-Function-Theory. The negative differential resistance in Luttinger transport arises from conformational heterogeneity of CHL-a related to the scaling of Van der waal distances, which regulates coupling strength with temperature as supported by Molecular-Dynamics simulation. The photo-induced evolution of novel “anisotropic heterojunction” can stimulate a plethora of function-designable 2D VDWHs creation.