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Interrogating the Structure of Molecular Cavity Polaritons with Resonance Raman Scattering: An Experimentally Motivated Theoretical Description

The formation of exciton polaritons by strongly coupling molecular electronic transitions to spatially confined photons may change photochemical processes. However, the fundamental physical drivers of these proposed changes remain unclear. To understand the role of changes to molecular structure caused by polariton formation in these photochemical processes we develop an experimentally motivated theoretical description of resonance Raman scattering from exciton polaritons. By modeling the structural parameters of light absorption in zinc tetraphenyl porphyrin and exciton polaritons formed from this molecule in nano-structured Fabry-Perot cavities, we simulate resonance Raman scattering excitation spectra from exciton polaritons and assess how these spectra depend on the polariton characteristics. We find the detuning of the cavity mode energy from that of the molecular transition can affect the structure of the resulting polaritonic states, as inferred from our simulated spectra. We also find previously u...