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Energetics and kinetics of surfaces and interfaces in the Fe-Pb system

The energy and the diffusivity of interfaces in the solid Fe-liquid Pb system have been investigated in the temperature range 650-900°C. Grain-boundary grooves are formed at the solid Fe-liquid Pb interface and these have been studied by atomic force microscopy. From the topography of the grooves the relative interfacial energies and interfacial diffusivities are obtained. It is found that liquid Pb does not wet the grain boundaries in Fe. Possible mechanisms for the growth of the grain-boundary grooves are discussed.