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Energy Exchange between H D (B1 Σu+, υ′, J′ ) and Ground State H2 and D2 by Interaction of Electronic Transition Dipole Moments

Steady state fluorescence experiments with mixtures of HD and H2 or D2 have given effective cross sections for energy exchange processes in collisions of electronically excited HD and ground state H2 and D2 molecules in well defined quantum states. The experimental results are compared with first order calculations using the Sharma-Brau theory of energy transfer due to the interaction of transition dipole moments.