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Release of Inorganic Phosphorus from Soils by Low‐Molecular‐Weight Organic Acids

Abstract Low‐molecular‐weight (LMW) organic acids are found in soils. They originate from the activities of various microorganisms in soils or may be exuded from the roots of living plants. Several of those organic acids are capable of forming stable organo‐metal complexes with various metal ions found in soil solutions. As a result, these processes may lead to the release of inorganic phosphorus (P) associated with aluminum (Al), iron (Fe), and calcium (Ca) in soil minerals. The release of P from soils by LMW organic acids may be important to the P nutrition of plants. Studies on the release of P from soils by a variety of LMW organic acids showed that, in general, the di‐ and tricarboxylic acids were the most effective in releasing P from two Iowa soils, whereas the monocarboxylic, phenolic, and mineral acids released similar amounts of P. Oxalic, malonic, citric, and, in some cases, malic and tartaric acids were the most effective in releasing inorganic P from the two surface soils studied. There was an inverse relationship between the amounts of P released from soils and the pKa values of the organic acids. The amounts of P released from soils were significantly correlated with the published stability constants for the formation of organic complexes of Al, Fe, or Ca (log KAl, log KFe, or log KCa values). In general, the aliphatic acids containing α‐caboxyl and β‐hydroxyl functional groups or phenolic acids containing ortho‐hydroxyl groups were more effective in causing the release of P from soils than similar organic acids having other functional group combinations.