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Photocontrol of Poly(dihexylsilane) Chain Organization using a Photochromic Monolayer

Abstract The in-plane orientation of a polysilane film on photochromic monolayer was controlled by irradiation with linearly polarized visible light. The polymer backbone was aligned in the perpendicular direction to the polarization plane of actinic light. In this photoprocess, the orientational order could be controlled by the light exposure dose.