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Solution Growth of Ultralong Gold Nanohelices.

Metallic nanohelices are extremely rare and, to date, have never been synthesized by a direct solution method. In this work, we report ultralong Au nanohelices grown in solution under ambient conditions. They are ultralong with several tens of micrometers in length, with extraordinary aspect ratio (length/diameter greater than 22 300) and the number of pitches (more than 22 000 pitches). The pitch and width are uniform within each helix but vary widely among the helices. Crystal analyses showed that the facets, twin boundaries, grain sizes, and orientations are aperiodic along the helices. The apparent smooth curving is only possible with a large number of surface steps, suggesting that these structural features are the mere consequence of the helix formation rather than the cause. We propose that the nanowires are formed by the active surface growth mechanism and that the helicity originates from the random and asymmetrical blocking of nuclei embedded within the floccules of ligand complexes, in the form of either asymmetric binding of ligands or asymmetric diffusion of growth materials through the floccules. The separate growth environment of these nuclei causes constant helicity within each helix but differing helicity among the individuals. The embedding also provides a robust environment for the sustained growth of the nanohelices, leading to their record length and consistency.