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Volumetric Properties for the Electrolyte (NaCl, NaBr and NaI) Monosaccharide (D-Mannose and D-Ribose)-Water Systems at 298.15 K

Densities have been measured for the electrolyte (NaCI, NaBr and NaI)-monosaccharide (D-mannose and D-ribose)-water solutions at 298.15 K. These data have been used to calculate the apparent molar volumes of the saccharides (V Φ,S ) and electrolytes (V Φ,E ) in the studied solutions. Infinite dilution apparent molar volumes, V Φ,S 0 and V Φ,E 0 , have been evaluated, together with the standard transfer volumes of the saccharides (Δ t V S 0 ) from water to aqueous electrolyte solutions and those of the electrolytes (Δ t V E 0 ) from water to aqueous saccharide solutions. It was shown that both the Δ t V S 0 and Δ t V E 0 values are positive and increase with increasing molalities of sodium halides and saccharides, respectively. Overall, the Δ t V S 0 and Δ t V E 0 values have the order of NaCl > NaBr > NaI except for NaI-ribose and NaI-ribose. Volumetric interaction parameters for the electrolyte-monosaccharide pairs in water were obtained and interpreted by the stereochemistry of the monosaccharide molecules and the structural interaction model.