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Adsorption Studies with Homologs of Superheavy Elements

In preparation of chemical studies with superheavy elements around Z = 114, the adsorption behavior of these elements and their lighter homologs on different metals has been predicted based on (semi-)empirical models and extrapolations (see e.g. [1, 2]). Adsorption studies with SHE homologs were performed on various metals, especially metals of group 10 and 11 (see e.g. [3]). The experimental results mainly confirmed the calculated data, but in a few cases great differences between predicted and experimental data were observed. Therefore, the adsorption behavior of SHE homologs on further metals is of great interest to prove the validity of the predictions. In the present work the adsorption of Tl, Pb, Bi, and Po on the group 5 metals V, Nb, Ta as well as on Mo, Ni, Ti has been studied by thermochromatography. Experimental data have been compared to predictions.