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Chloride-Enhanced Removal of Ammonia Nitrogen and Organic Matter from Landfill Leachate by a Microwave/Peroxymonosulfate System

Landfill leachate contains not only high concentrations of refractory organic matter and ammonia nitrogen, but also high concentrations of chloride ions (Cl−). The modification of reactive species of the peroxymonosulfate (PMS) oxidation system by Cl− and its priority sequence for the removal of NH4+-N and organic matter from landfill leachate remain unclear. This study investigated the removal characteristics of NH4+-N and organic matter in the microwave (MW)/PMS system with high Cl− content. The results show that increasing Cl− concentration significantly improves the production of hypochlorous acid (HOCl) in the MW/PMS system under acidic conditions, and that the thermal and non-thermal effects of MW irradiation have an important influence on the HOCl produced by PMS activation. The maximum cumulative concentration of HOCl was 748.24 μM after a reaction time of 2 min. The formation paths of HOCl are (i) SO4•− formed by the MW/PMS system interacting with Cl− and HO•, and (ii) the nucleophilic addition reaction of PMS and Cl−. Moreover, the high concentration of HOCl produced by the system can not only remove NH4+-N in situ, but also interact with PMS to continuously generate Cl• as an oxidant to participate in the reaction with pollutants (e.g., NH4+-N and organic matter). Common aqueous substances (e.g., CO32−, HCO3−, NO3−, and humic acid) in landfill leachate will compete with NH4+-N for reactive species in the system, and will thereby inhibit its removal to a certain extent. It was found that when NH4+-N and leachate DOM co-exist in landfill leachates, they would compete for reactive species, and that humic acid-like matter was preferentially removed, leading to the retention of fulvic acid-like matter. It is hoped that this study will provide theoretical support for the design and optimization of methods for removing NH4+-N and organic matter from landfill leachate with high chloride ion content.