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35Cl NQR Spectroscopy on Salts and Molecular Compounds of Trichloroacetic Acid

The temperature dependence of salts M(1)H(Cl3CCOO)2 and molecular compounds of trichloroacetic acid with amines and benzaldehydes, TCA · X, was studied, The data fit rather well to the known dependence of the mean frequency shift Δ  on the pkadifference of X with respect to TCA. A linear relation is observed between the bleaching out temperature Tb of the 35Cl NQR lines and Δ  for M(1)H(Cl3CCOO)2 and for TCA · X, X = benzaldehydes.