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Aldehydes as Additives in AOT-based Microemulsions: Influence on the Electrical Percolation

Abstract The influence of alkyl-aldehydes upon electric percolation of AOT-based microemulsions has been studied. The number of carbons in the hydrocarbon chain was varied between 0 and 5 atoms (chain length between 0 and 7.33 Å). Two different behaviors were found, while the presence in the microemulsion of short chains aldehydes implies a decrease in the percolation temperature, aldehydes with 4 or 5 carbon atoms in the hydrocarbon chain increase the percolation threshold. This opposite behavior has been justified in terms of aldehyde location in the microheterogeneous system.