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Co-Aromatization of n-Butane and Methanol over PtSnK-Mo/ZSM-5 Zeolite Catalysts: The Promotion Effect of Ball-Milling

The ball-milling (BM) method benefits the stabilization and dispersion of metallic particles for the preparation of the PtSnK–Mo/ZSM-5 catalyst. Based on the TPR, H2-TPD, XPS, and CO-FTIR results, the Pt–SnOx and MoOx species were formed separately on the BM sample. During the aromatization of cofeeding the n-butane with methanol, the yield of the aromatics is 59 wt.% at a n-butane conversion of 86% at 475 °C over the Pt Mo BM catalyst. The more weak acid sites also contribute to the aromatics formation with the less light alkanes formation. For the Pt Ga catalysts, the slow loss of activity suggests that the BM method can restrain the coke deposition on the Pt-SnOx species, because of a certain distance between the Pt–SnOx and GaOx species on the surface of ZSM-5.