{'fraction_non_alphanumeric': 0.05132192846034215, 'fraction_numerical': 0.02332814930015552, 'mean_word_length': 5.376237623762377, 'pattern_counts': {'":': 0, '<': 0, '<?xml version=': 0, '>': 0, 'https://': 0, 'lorem ipsum': 0, 'www.': 0, 'xml': 0}, 'pii_count': 0, 'substrings_counts': 0, 'word_list_counts': {'cursed_substrings.json': 0, 'profanity_word_list.json': 0, 'sexual_word_list.json': 0, 'zh_pornsignals.json': 0}}
Photophysics of Derivatives of 3-Hydroxybenzo[c]coumarin.

The photophysical studies of two phenols, derivatives of 3-hydroxybenzo[c]coumarin, were performed in n-nonane matrix at 5 K. Unstructured fluorescence spectrum of the derivative bearing a salicylaldehyde moiety, whose onset is shifted by ca. 3000 cm(-1) to lower energy in respect to that of absorption, and short decay time of this emission (0.75 ns) suggested the occurrence of excited-state intramolecular proton transfer (ESIPT). The experimental results were interpreted with the aid of quantum chemistry calculations performed with the DFT and TDDFT/B3LYP/6-31++G(d,p) methods.