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Band structure and electronic properties of the incommensurate misfit compound

The electronic properties of the incommensurate misfit compound are investigated by different methods. Linear muffin-tin orbital atomic-sphere approximation band-structure calculation shows that this material should be a metal with a Fermi level located near a minimum of the density of states. Experimentally, the electrical resistivity is hopping-like while the magnetic susceptibility is metallic-like with a strong enhancement. We suggest that these paradoxical properties can be reconciled by taking into account the effects of incommensurability and electronic correlations. A comparison with commensurate and with Ti or Cr incommensurate misfit derivatives is discussed.