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Impact glass spherules in the Chicxulub K‐Pg event bed at Beloc, Haiti: Alteration patterns

We have investigated six impact glass spherules from the K‐Pg event bed at Beloc, Haiti, using optical and electron microscopy, electron microprobe and in situ laser ablation–mass spectrometry (LA‐ICP‐MS; 37 trace elements, spot size 90–35 μm), in order to understand geochemical changes during alteration. The mm‐sized glass spherules are partly or totally altered to smectite, but original textural features are preserved. The average trace‐element composition of glass matches that one of the upper continental crust. Hints for a “meteoritic component” are lacking (Ni/Cr < 1.3; Pt below detection limit). Compared to this fresh glass, smectites are strongly depleted in trace elements, except for Li, Sc, V, Ni, Ga, Ge, and Ba. The chondrite‐normalized REE distribution patterns are flat with subchondritic abundances, related to their very low degree of crystallinity. We observe a positive Eu and a strong negative Ce anomaly; the latter is explained by formation of an organic Ce4+‐complex, soluble under reducing conditions. Zr/Hf of glasses and smectites is chondritic to superchondritic (35–40), whereas Nb/Ta in smectite is subchondritic (5–12) compared to Nb/Ta in the glass (~14–18). The low Nb/Ta is due to the low Nb concentrations in the smectite. Using in situ techniques with high spatial resolution, we have documented for the first time the significant changes in diagnostic elemental ratios during alteration of glass spherules. This has to be taken into account in the interpretation of geochemical data of not only impact materials but also volcanic glass, especially if bulk rock methods are used.