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HETEROMETALLIC ZINC COMPOUNDS: CLASSIFICATION AND ANALYSIS OF CRYSTALLOGRAPHIC AND STRUCTURAL DATA

This review covers the heterometallic complexes of zinc, and complements two previous reviews on the inorganic and organic complexes, respectively. There are nearly fifty of these heterometallic derivatives in which the heterometal atoms include both transition and non-transition metals, both hard (class A) and soft (class B). The most common geometry found around zinc is tetrahedral. The trinuclear and polynuclear are most common, followed by binuclear and somewhat fewer tetraand hexanuclear examples. The compounds include both organic and coordination complexation around the zinc and heterometal atoms.