{'fraction_non_alphanumeric': 0.03618817852834741, 'fraction_numerical': 0.014475271411338963, 'mean_word_length': 4.845070422535211, 'pattern_counts': {'":': 0, '<': 0, '<?xml version=': 0, '>': 0, 'https://': 0, 'lorem ipsum': 0, 'www.': 0, 'xml': 0}, 'pii_count': 0, 'substrings_counts': 0, 'word_list_counts': {'cursed_substrings.json': 0, 'profanity_word_list.json': 0, 'sexual_word_list.json': 0, 'zh_pornsignals.json': 0}}
Open and closed states of a porphyrin based molecular turnstile.

The molecular turnstile 1 composed of a stator based on an Sn(IV)-porphyrin bearing two sets of monodentate coordinating sites (pyridyl and benzonitrile) and a handle bearing a 2,6-pyridinediamide moiety as a tridentate unit was synthesised. In the absence of metal behaving as a blocking agent, the handle freely rotates around the stator (open state). In the presence of Pd(II), the closed state of the turnstile 1-Pd resulting from the simultaneous binding of the metal centre by both the dianionic tridentate site and one of the two pyridyl units is generated. The reaction of 1-Pd with the organometallic 2,6-diphenylpyridine Pt(II) complex 11 leads to the heterotrinuclear (Pt, Sn, Pd) species 13, resulting from the binding of the platinum complex by 1-Pd.