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Surface elasticity effect on the size-dependent elastic property of nanowires

A modified core-shell (MC-S) model is proposed to investigate the effect of surfaceelasticity on the elastic properties of nanowires under bending and tension loading modes. The continuous exponential function based on bulk elasticity is applied to the surface region of nanowires to better describe the elasticity in the surface layer. Two parameters related to the surface, namely, the inhomogeneous degree constant α , and the transition region of this inhomogeneous state r s (i.e., surface layer thickness), are introduced for examining the size effects of the elastic modulus of the overall nanowires. A strong size dependence of elasticity is revealed under both bending and tension loads. Furthermore, the theoretical solution for an effective Young’s modulus with relevant experiments, as well as the results of a molecular statistical thermodynamics (MST) method for zinc oxide (ZnO)nanowires, and a molecular dynamics (MD) simulation for silicon (Si) nanowires, are compared. It is shown that the theoretical curves not only agree well with the experimental data, but also fit the computational results (MST or MD) approximately below 20 nm. As a result, our model can predict the behavior of surfaceelasticity, with respect to the lateral size of nanostructures at a relatively small scale, no matter how stiff or soft the surface of the nanomaterials.