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Temperature Dependence of Photoluminescence for Spin-Coated Semiconductor Quantum Dots and Quantum Dot-Dye Nanoassemblies on Quartz Substrate

The attachment of pyridyl substituted porphyrin molecule to the surface of CdSe/ZnS quantum dots in solutions is realized in the competition with capping ligand TOPO molecules resulting in the specific change of photoluminescence for the quantum dots across the temperature range of 77–290[Formula: see text]K. We have shown that fixation of alone quantum dots or quantum dot-porphyrin nanoassemblies on quartz substrate changes significantly temperature dependence of photoluminescence. In contrast to the samples in a glass-forming solution no phase transition of the TOPO capping layer was observed upon removal of the capping layer.