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Interactions of Metal Nanoclusters with Light: Fundamentals and Applications

The interactions of materials with light determine their applications in various fields. In the past decade, ultrasmall metal nanoclusters (NCs) have emerged as a promising class of optical materials due to their unique molecular‐like properties. Herein, the basic principles of optical absorption and photoluminescence of metal NCs, their interactions with polarized light, and light‐induced chemical reactions, are discussed, highlighting the roles of the core and protecting ligands/motifs of metal NCs in their interactions with light. The metal core and protecting ligands/motifs determine the electronic structures of metal NCs, which are closely related to their optical properties. In addition, the protecting ligands/motifs of metal NCs contribute to their photoluminescence and chiral origin, further promoting the interactions of metal NCs with light through various pathways. The fundamentals of light–NC interactions provide guidance for the design of metal NCs in optical applications, which are discussed in the second part. In the last section, some strategies are proposed to further understand light–NC interactions, highlighting the challenges and opportunities. It is hoped that this work will stimulate more research on the optical properties of metal NCs and their applications in various fields.