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Mxenes Derived Laminated and Magnetic Composites with Excellent Microwave Absorbing Performance

Two dimensional materials have been widely identified as promising microwave absorbers, owing to their large surface area and abundant interfaces. Here, a novel laminated and magnetic composite derived from Mxene was designed and successfully synthesized via facile hydrothermal oxidization of nickel ion intercalated Ti3C2. Highly disordered carbon sheets were obtained by low temperature hydrothermal oxidization, and the in-situ produced TiO2 and NiO nanoparticles embedded closely between them. This layered hybrid exhibits excellent microwave absorbing performance with an effective absorbing bandwidth as high as 11.1 GHz (6.9–18 GHz) and 9 GHz (9–18 GHz) when the thickness is 3 and 2 mm, respectively. Besides the high dielectric loss, magnetic loss and ohmic loss of the composite, the amorphous nature of obtained carbon sheets and multi-reflections between them are believed to play a decisive role in achieving such superior microwave absorbing performance.

the enhanced microwave absorbing performance of modified Ti 3 C 2 Mxene and its derives in 2016 and 2017, respectively, which opened a new way to the study of high performance microwave absorbing materials.Ti 3 C 2 as a representative of Mxene family who possess active surface functional terminations, which could give rise to remarkable defects polarizations was proved to be responsible for the promising MA ability. Besides, the divers surface modifications of Mxene by ion intercalation, annealing and oxidization could offer tunable microwave absorbing properties 24,25 .
The high electrical conductivity of Ti 3 C 2 is one big obstacle for the application as MA materials which should have intensified polarizations and moderate conductivity. Hydrothermal treatment of Ti 3 C 2 will derive oxidized MXene (MO), a kind of titania-carbon hybrid material 26 . It should be noted that the introduction of oxidation will greatly decrease the conductivity and increase the polarization defects within Ti 3 C 2 , which seems to be an effective approach to enhance the MA properties of Ti 3 C 2 . What is more, numerous reports have confirmed that carbon nanostructure with the incorporation of magnetic particles can effectively improve the EMW absorbing capacity of composites 27,28 . Therefore, it is highly expected that incorporating magnetic species into oxidized Mxene could be an effective route to obtain high performance EMW absorbing materials.
Herein, we demonstrate a facile synthesis route towards the preparation of amorphous carbon supported laminated and magnetic hybrids (denoted as NiO&TiO 2 @C) by the hydrothermal oxidation of nickel ions intercalated Ti 3 C 2 . The relatively low temperature (180 °C) of hydrothermal oxidation makes the as-formed atomically thin carbon sheets highly disordered, and the in-situ oxidized TiO 2 and NiO nanoparticles embedded closely into each carbon layers to form a sandwich-like structure. The structure, magnetic, microwave electromagnetic responses and absorbing properties of the as-prepared composites were investigated. The results indicate that the composites exhibit excellent MA performance due to multi-mechanisms of microwave attenuation. Furthermore, our proposed method provides an important guideline to insert other metal ions into Mxenes and to derive other metal oxide hybrids, which expands the applications of Mxenes.

Results and Discussion
Composition and microstructure. Figure 1(a) shows the typical morphology of Ti 3 C 2 with an accordion-like structure. Aluminum atoms are extracted and the sonication makes the layered structure swelled. Energy dispersive X-ray spectroscopy ( Fig. 1(d)) reveals that the laminated materials are composed of Ti, C, O and F. The excess O and F signal could be ascribed to the surface terminations (-F and/or -OH), and possibly the intercalated water and hydrofluoric acid between Ti 3 C 2 layers 13 . After Ni 2+ intercalation, MXene still keeps the lamellar morphology, but the inner space of MXene most likely is filled with Ni ions (as shown in Fig. 1(b)). During the hydrothermal oxidization, the Ti atoms and the inserted Ni ions are in-situ oxidized to anatase TiO 2 and nickel oxide respectively. The as-produced hybrids still keep a laminar structure. 2D carbon sheets with embedded TiO 2 and NiO nano-particles can be observed from the lateral dimension ( Fig. 1(c)). EDS spectrum ( Fig. 1(f)) demonstrates that the sheets of composite consisted of Ti, C, O, and Ni elements.
TEM was also carried out for comprehensive structural characterizations. Figure 1(g) shows a cross section image of a particle of the NiO&TiO 2 @C composites, exhibiting the typical structure and morphology of the hybrid. Plenty of oxide nano-particles are observed on the surface and inside each layers. Figure 1(h) shows a few-layer composite of NiO&TiO 2 @C which most probably consists of several carbon sheets coated with plenty of oxide nano-particles. In Fig. 1(i), a monolayer carbon sheet coated with few nano-particles is observed, inset shows SAED pattern confirming the structure of amorphic carbon.
Powder X-ray diffraction (XRD) was conducted to investigate the structure evolution of the as-synthesized composites ( Fig. 2(a)). For the original Ti 3 C 2 , the typical diffraction peak (002) appears at around 2θ = 8.98°, indicating that the interlayer distance of Ti 3 C 2 is about 0.98 nm according to Bragg equation: 2dsinθ = nλ. After Ni 2+ intercalation, this peak shifted to a lower angle around 2θ = 6.72° as shown in Fig. 2(a), indicating that the c-lattice parameter expanded to about 1.32 nm. In previous studies, it was already well studied that a variety of cations and small molecules, including Li + , Na + , K + , Mg 2+ , Al 3+ and DMSO, DMF, Amine, etc 13,18,29,30 , can be inserted into Mxene layers. The ion radius of Ni 2+ is smaller than that of Na + and K + , therefore, nickel ions could obviously intercalate into the interlayer of Ti 3 C 2 , if the metal ions and Mxene particles do not chemically react. The driving force which occurs the insertion is that the terminations (-OH and -F) of MXene possess a stronger hydration effect with Nickle ions.
For further details of the as-prepared composites, Raman spectrum and X-ray photoelectron spectroscopy (XPS) were recorded before and after hydrothermal treatment. As can be seen from Fig. 2(b), the Raman spectrum (C curve) of the NiO&TiO 2 @C composite shows a typical anatase structure. This is because the Raman activity of anatase is higher than that of nickel oxide, and the major components of the as-prepared composites is anatase TiO 2 . Raman spectrum of Ti 3 C 2 (A curve) is well consistent with the previously reported results 13 . The shift at 153 cm −1 is believed to be an E g vibration mode of Ti-O bond compared to the results of C-curve 31 . Nickel ion intercalation made the E g vibration of Ti-O bond at 153 cm −1 intensified (curve B), for the reason that the expansion in c-direction caused by intercalation could weaken the interaction between the layers, and trigger the delamination which will expose more Ti-O bonds to the surface. The D and G peaks of carbon appears at around 1420 and 1580 cm −1 . Hydrothermal treatment makes these two peaks broadened, indicating that the carbon sheets of the hybrid are highly disordered amorphous carbon 32 .
A comparison of XPS spectrum of Ti 3 C 2 and the as-prepared NiO&TiO 2 @C composite provides details concerning chemical composition and surface chemistry. In Fig. 2(c), C1s XPS indicates that the distinct peak of Ti-C bond of Ti 3 C 2 at 281.7 eV disappeared completely after the hydrothermal treatment, and the peak of amorphic C-C bond intensified. This is well consistent with the previous results of Raman spectrum, that the as-produced carbon sheets are highly disordered under the relatively low temperature of hydrothermal. Ti2p and O1s XPS ( Fig. 2(d,e)) results confirm that the peak of Ti-C bond vanished after hydrothermal oxidization, and the peak of Ti-O bond of TiO 2 intensified, indicating the formation of TiO 2 . Ni2p XPS (Fig. 2(f)) of the composite shows the www.nature.com/scientificreports www.nature.com/scientificreports/ 2p 3/2 and 2p 1/2 doublets at 856.3 and 874.4 eV of NiO, and 862.2 and 881.1 eV of Ni 2 O 3 respectively, revealing the formation of nickel oxide. A Ni atom ratio of 3.5at% was also obtained from the XPS spectrum, which confirms the previous point that the amount of as-formed nickel oxide is small, and it is undetected by XRD.
Based on the above results, the structural evolution from Ti 3 C 2 to NiO&TiO 2 @C can be described as following (showing in Fig. 3). When Ti 3 C 2 powders are immersed in the green NiCl 2 solution (1 M), the nickel ions and the water molecules will spontaneously intercalate into the interlayers of Ti 3 C 2 , which results in an expansion in the c-lattice parameter. The following hydrothermal treatment in-situ oxidized the intercalated nickel ions and the Ti atoms of Mxene to NiO and TiO 2 respectively, and finally the amorphous carbon based sandwich-like materials, which is denoted as NiO&TiO 2 @C are formed. The low temperature (180 °C) of hydrothermal makes the as-formed carbon layers highly disordered, and the synthesized oxides could prevent the carbon layers from stacking. electromagnetic responses and Microwave absorbing properties. Figure 4(a-c) shows the frequency dependencies of complex permittivity and permeability in the range of 2-18 GHz. Both the real and imaginary part of permittivity of NiO&TiO 2 @C composites climb with the increasing of mass ratio. It is worth noting that the permittivity of the composite/paraffin with the mass ratio of 1:2 are all below 5 with the tested frequency, which are significantly smaller than those of pure Mxene 22,23 . Besides, the real permeability of NiO&TiO 2 @C composites seems to keep around 1.5 within the whole examined frequency range, while the imaginary part decrease gradually from 0.9 to 0.02. It is reasonable that this obvious enhancement of complex permeability of NiO&TiO 2 @C composites compared with that of pure MXene (i.e.μ r ≈ 1) is originated from in-situ decoration of NiO. What is more, this synergistic effect of decreased permittivity and enhanced permeability brings them closer, which is quite essential to improve impedance matching. Moreover, both complex permeability and permittivity fluctuate obviously within examined frequency range, which is favorable to microwave attenuation. The derived carbon layers keep the composites a relatively high conductivity. This can be seen from the relatively low real and imaginary part of permittivity. And this could be beneficial to the transmission of microwave energy to www.nature.com/scientificreports www.nature.com/scientificreports/ heat energy for the enhancement of induced micro current, including current caused by the change of electric field and the eddy current caused by changes of magnetic field. Figure 4(d) displays the reflection loss of the composite/paraffin with different mass ratio at the fixed coating thickness of 3 mm. Composite/paraffin hybrids with a mass ratio of 1:2 possess the best microwave absorption properties with an effective absorption bandwidth of 11.1 GHz (6.9-18 GHz). Figure 5(a) shows the calculated reflection loss (RL) of composites with NiO&TiO 2 @C over 2~18 GHz at five typical values of thickness with the mass ratio of 1:2. As clearly seen, the RL keeps lower than −10 dB over a broad range of 9 GHz (9-18 GHz) when the thickness of absorber fixes at only 2 mm, which suggests more than 90% of energy of incident EMW has been absorbed. When the thickness is 3 mm, an even broader range of 11.1 GHz (6.9-18 GHz) was achieved, and an optimal RL of −25 dB (corresponding to 99.5% absorption) was also achieved at 15.2 GHz. The RL value is lower than −10 dB within 5.2-9.5 GHz range at 4 mm, and 4.6-7.4 GHz range at 5 mm respectively. Compared to that of pure MXene 23 and oxidized MXene 24,25 , NiO&TiO 2 @C composites possess broadened effective absorption bandwidth, which confirms that oxidization and magnetism are helpful to attenuate microwave energy here.
Moreover, we noticed that the optimal absorption peak downshifts to lower frequency range when the coating layer gets thicker. According to the resonant absorb theory, when microwave is incident on an absorber sample backed by a perfect conductor, the predicted matching thickness d m cal at the matching frequency f is given by 33 :  where μ(f) and ε(f) are complex permeability and permittivity at the frequency of f, respectively. The calculated d m cal based on Eq. (3-1) is shown in Fig. 5(a), which is well consistent with the d m mat obtained from reflection loss results. Thus, the attenuation peaks of NiO&TiO 2 @C composites shift to lower frequency with increasing sample thickness. And this result indicates that quarter-wavelength absorption is one of effective way to improve microwave absorption for the modified carbon based composite.
The dielectric loss tangent (tan δ E = ε″/ε′) and the magnetic loss tangent (tan δ M = μ″/μ′) were also calculated based on the permittivity and permeability as shown in Fig. 5(b). The maximum values of both the dielectric and magnetic loss tangent exceed 0.6, suggesting a strong attenuation capability. The collaboration of dielectric and magnetic loss is supposed to be responsible for broadening the microwave absorbing band.
The magnetic responses of NiO&TiO 2 @C composites are believed to be helpful to enhance the microwave absorbing performance. For further confirmation of the magnetic properties of the NiO&TiO 2 @C composite, magnetization curve was examined at room temperature. As shown in Fig. 5(c), there exist small hysteresis loop at lower field at room temperature, indicating the existence of a ferromagnetic component. The saturation magnetization (M s ), remnant magnetization (M r ) and coercivity (H c ) values are 0.11569 emu/g, 2.3152E-3 emu/g and 69.302 G respectively. Since the TiO 2 particles are non-magnetic, obviously magnetism of the composites originates from NiO nanoparticles. It should be noted that the magnetism of NiO&TiO 2 @C composites is quite weak so that the measuring errors could seriously affect the tested results both the permeability data and magnetism. To minimize the adverse effect caused by measuring errors, we usually prepare 2 samples and test each for 3 times. Furthermore we could not evaluate the contribution of microwave absorption caused by magnetic loss based on the electromagnetic responses and magnetization curves directly. However it can be determined based on the above results that there indeed exists magnetic responses in NiO&TiO 2 @C composites which could help to attenuate microwave energy. Figure 6 exhibits a comparison of EMW absorbing ability between the widely studied graphene-based absorbers and the as-derived NiO&TiO 2 @C composite. As mentioned before, the most commonly used strategy is to assemble magnetic particles with graphene, which were expected to be an effective way to broaden the www.nature.com/scientificreports www.nature.com/scientificreports/ bandwidth. However, the MA ability of the assembled graphene-based composites are limited by the magnetic properties of the particles and the instinct characteristic of graphene. As can be seen from Fig. 6, the MA ability of most graphene-based composites are in the lower right zone, which means a poor effective bandwidth. Graphene foams show extremely broad bandwidth (>52 GHz) 3 , but it can not be easily applied as a coating material, because of its porous 3D structure. In this work, the as-prepared NiO&TiO 2 @C hybrids exhibit an excellent MA ability: extremely broaden bandwidth at low thicknesses. The main reasons behind are the highly disordered carbon sheets and the combination of multi-attenuation mechanism. The former possesses lots of defects and dipoles that could produce strong dielectric loss, and the later could attenuation EM energy in different ways. Apparently can be seen, the MA ability of NiO&TiO 2 @C composites in this work is much better than that of Mxene-derived TiO 2 /C composites 25 , which indicates that magnetic components plays an important role for microwave absorptions.  www.nature.com/scientificreports www.nature.com/scientificreports/ However, except for the mechanism mentioned above, more attention should be devoted to the mechanisms of intrinsic dielectric loss for the superior microwave absorption performance of the NiO&TiO 2 @C composites. As illustrated in Fig. 7, the superior MA properties could be classified into several aspects. Firstly, the impedance improvement is believed to be beneficial for NiO&TiO 2 @C composites. Due to the relatively higher resistivity and dielectric constant, the in-situ produced oxide (TiO 2 and NiO) nanoparticles could effectively reduce the electrical conductivity of pristine Ti 3 C 2 (from 1500 S/cm to 15 S/cm) 16,26 , As a result, the composites have a relatively low apparent dielectric constant, which provides a good impedance matching with EMW in air.
Secondly, eddy current effect within highly conductive carbon layers, which induced by alternating incident EMW would allow the conversion of electromagnetic energy into thermal energy. Simultaneously, during the migration procedure of electrons along carbon layer, scattering effect from lattice vibration and inevitable defects 34,35 on the amorphous carbon layers of as-prepared NiO&TiO 2 @C would also make a contribution to the overall microwave attenuation, leading to electric accumulation around these defects, and as a result, hopping migration. Thirdly, as demonstrated in Fig. 5(b), magnetic loss also makes a contribution to the overall MA performance of NiO&TiO 2 @C composites. Due to the resistance from the inhomogeneity and defects in material, the motion of oriented magnetic domain wall in NiO is inclined to lag behind the incident magnetic field, which in accordance with results in Fig. 5(b). It is this magnetization process that responsible for the conversion of electromagnetic energy into thermal energy. In addition, multiple reflections between the carbon layers, and scattering from the oxide particles could also further enhance the absorbing ability of the composite. In a word, the excellent microwave absorption performance of NiO&TiO 2 @C composites is attributed to the compensatory effect of the three components (NiO, TiO 2 and amorphous carbon layers) of the composites. From the above discussion, it is highly expected that the NiO&TiO 2 @C composite could be a candidate for high performance microwave absorbing materials.

Conclusions
A novel laminated and magnetic composite, labeled as NiO&TiO 2 @C, is successfully designed and synthesized via a facile ion intercalation and hydrothermal route. FESEM, TEM, XRD, Raman and XPS characterizations reveal the laminated hybrids composed of amorphous carbon sheets with embedded nickel oxide and anatase TiO 2 nanoparticles. The composites possess a relatively low permittivity and high dielectric loss as well as a good impedance matching for microwave absorbing materials. The reflection loss (RL) indicates this novel composite has a superior MA ability with a broad range of 6.9-18 GHz (3 mm) and 9-18 GHz (2 mm), respectively while RL is lower than −10 dB. Meanwhile, an optimal RL of −25 dB (corresponding to 99.5% absorption) could be achieved. Furthermore, the excellent microwave absorbing performance is attributed to the compensatory properties of each components. The three components (NiO, TiO 2 and carbon layer) of the composites could combine the advantages www.nature.com/scientificreports www.nature.com/scientificreports/ of each part, making the best use of the contributions to microwave absorption. These novel composites have a great potential in developing lightweight, high efficiency and wide range microwave absorbing materials.

Methods
Materials preparation. Ti 3 C 2 was synthesized by etching the aluminum atoms from Ti 3 AlC 2 powders (commercially available, purity ≥99%, Fosman Scientific company, Beijing) immersed in aqueous HF solution (49 Wt%) in a ultrasonic homogenizer (JY96-IIN, Scientz) and sonicated for 4 h. After the treatment, the mixture was separated by centrifuge and the sediments were washed with deionized water until the pH reached approximately 6.0. Subsequently, the clay-like sediments were immersed in 1 M NiCl 2 solution to derive Ni 2+ intercalated Mxene, after which the mixture was sealed in a steel kettle and heated up to 180 °C and held at the temperature for 12 h in an air drying oven to form nickel oxide-titania-carbon (NiO&TiO 2 @C) composites. The final products were washed with distilled water and ethanol for sevral times and then dried at 60 °C under vacuum and denoted as NiO&TiO 2 @C.
Characterization. The phase composition and crystal structure were confirmed by X-ray Diffraction (XRD) with a powder X-ray diffractometer (D/max-2400, Rigaku) using Cu Kα radiation (λ = 1.54056 Å) and a step scan of 0.02° with 1 s per step. The microstructure was characterized by Scanning Electron Microscopy (SEM) on a Zeiss Supra 50VP, Germany, and TEM operated at 200 k on JEM 2100, Japan; Energy-Dispersive Spectroscopy (EDS) was performed with this instrument (Oxford EDS, with INCA software). The Raman spectrum of all samples were measured on a microspectrometer (inVia, Renishaw plc, Gloucestershire, UK) using an Ar ion laser (514.5 nm) and a grating with 1800 lines mm −1 . X-ray Photoelectron Spectroscopy (XPS) (using a PHI 5000, ULVAC-PHI, Inc., Japan) was also used to analyze the surface components and their chemical states. Magnetic hysteresis loops were characterized using a vibrating samples magnetometer (Lakeshore 7404) at room temperature.
For the characterization of dielectric responses ranging from 2 GHz to 18 GHz, donut-shaped samples with 7.0 mm outer diameter and 3.0 mm inner diameter were prepared by mixing the as-prepared hybrids powders with molten paraffin (weight ratio equals to 1:2), and the electromagnetic parameters (relative permittivity ε r and permeability μ r ) of each sample were determined through coaxial line method with a vector network analyzer (Agilent AV3618).
To evaluate the microwave absorption performance of the prepared NiO&TiO 2 @C composites, the reflection loss (RL) values were calculated based on the relative complex permeability and permittivity at a given layer thickness according to the transmission line theory 33  where Z in is the normalized input impendance, j is the imaginary unit, c is the speed of light, f is the microwave frequency, and d is the thickness of the coating layer.