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Thermodynamic properties of liquid Bi–Sn alloys

Abstract The thermodynamic properties of liquid Bi–Sn alloys were measured over the whole composition range by an electromotive force (emf) method using a liquid electrolyte. The basic thermodynamic functions were calculated from the corresponding excess functions by using the Gibbs–Duhem integration at 723 K. The liquid Bi – Sn system was classified as a subregular solution and an asymmetrical curve of enthalpy of mixing vs. composition was found.