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On the elastic contribution to crystal growth in complex environments

Based on a number of experimental studies, we propose to consider how elastic interactions between a crystal and its surroundings change crystal growing conditions. To aim to do this, we analyze the influence of some nonequilibrium modification of the Gibbs–Thomson thermodynamic condition, prescribed at the crystal boundary, on some properties of a kinetic model of protein crystal growth in a mass‐convection regime. Next, to draw the physical picture more realistically, we study the influence of a certain stochastic perturbation on the crystal growth rate. To fulfill the task we apply the description of crystal growth in terms of nonequilibrium thermodynamics at a mesoscopic level. The proposed model offers a quite comprehensive picture of the formation of modern organic crystalline materials such as non‐Kossel crystals. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)